2
copper or copper alloys compris- ing an oxidizing agent, which can oxidize the copper or copper alloy and is selected from cupric ion source compounds; an organic acid or an inorganic acid; a halide ion source compound; a polymer compound, which contains poly- amine or polyimine chains or a cationic group or both in the amount of 0.000001 to 1.0% by weight; and water. PROCESS FOR TREATING TINNED SURFACES U.S. Patent 5,965,205. Oct. 12, 1999 M. Yoshida, assignor to Henkel Corp., Gulph Mills, Pa. A process for treating a tinned metal surface in order to form a corrosion-protective, paint-adher- ent coating comprising bringing the metal surface being treated into contact with an aqueous liq- uid coat-forming composition hav- ing a pH of not more than 6.0 and comprising water and 0.5 to 30 parts by weight of phosphate ions; 0.1 to 10 parts by eight of con- densed phosphate ions; and 0.1 to 20 parts by weight of water- soluble polymer molecules. HOT-DIP COATING APPARATUS U.S. Patent 5,965,210. Oct. 12, 1999 M. Tada et al., assignors to Kawasaki Steel Corp., Hyogo, and Mitsubishi Heavy Industries, Ltd., Tokyo A hot-dip coating method in which a steel strip is coated as it is fed upwardly through a slit in a bottom of a coating tank, the im- provement comprising making a COST EFFECTIVE INDUSTRIAL WASTEWATER SYSTEMS COMPLIANCE @s WLlEn RECYCLE REUSE ! ProChemTech International, Inc. NATIONWIDE SUPPLIER OF SYSTEMS WHICH INTEGRATE CHEMISTRY AND EQUIPMENT FOR COST EFFECTIVE TREATMENT, REUSE, AND RECYCLE OF INDUSTRIAL WASTEWATER WE MANUFACTURE : INCLINED PLATE CLARIFIER SYSTEMS FROM 5 TO 1000 GPM SEQUENTIAL BATCH SYSTEMS FROM 250 TO 5000 GALLON MEMBRANE SYSTEMS FROM 2 GPM TO 250 GPM ION EXCHANGE SYSTEMS FROM 2 TO 100 GPM SMALLER UNITS ARE SKID MOUNTED AND FULLY ASSEMBLED - READY TO RUN Phone 8 14-265-0959 FAX 814-265-1263 www.prochemtech.com Circle 067 on reader information card flow velocity of the molten metal uniform across a breadth of the strip by directing the molten metal through a flow restricting buffer as the molten metal enters the coating tank at the inlets. ELECTROLESS COPPER PLATING SOLUTION U.S. Patent 5,965,211. Oct. 12, 1999 K. Kondo et al., assignors to Nippondenso Co., Ltd., Kariya, Japan A process for formation of a cop- per plating film, which comprises immersing a material to be plated in an electroless copper plating solution of copper ions; a reducing agent; a pH-adjusting agent; a tri- alkanolmonoamine or a salt thereof in an amount sufficient to act as a complexing agent and ac- For a FREE Book List Circle 560 on Reader Information Card - Kushner Electroplating School “Training Electroplaters Since 1947” TRAINING FORBETTERMETAL FINISHING ELECTROPLATING KNOW HOWII (/ CORRESPONDENCE PROGRAMS c/ GROUP TRAINING PROGRAMS d ON-SITE TRAINING PROGRAMS d CUSTOM TRAINING PROGRAMS 732 Glencoe Court, Sunnyvale, CA 94087 (408) 749-8652 . Fax (408) 749-0176 E-mail: [email protected] www.platingschool.com Circle 047 on reader information card 116 Metal Finishing

Electroless copper plating solution

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Page 1: Electroless copper plating solution

copper or copper alloys compris- ing an oxidizing agent, which can oxidize the copper or copper alloy and is selected from cupric ion source compounds; an organic acid or an inorganic acid; a halide ion source compound; a polymer compound, which contains poly- amine or polyimine chains or a cationic group or both in the amount of 0.000001 to 1.0% by weight; and water.

PROCESS FOR TREATING TINNED

SURFACES

U.S. Patent 5,965,205. Oct. 12, 1999 M. Yoshida, assignor to Henkel Corp., Gulph Mills, Pa.

A process for treating a tinned metal surface in order to form a corrosion-protective, paint-adher- ent coating comprising bringing

the metal surface being treated into contact with an aqueous liq- uid coat-forming composition hav- ing a pH of not more than 6.0 and comprising water and 0.5 to 30 parts by weight of phosphate ions; 0.1 to 10 parts by eight of con- densed phosphate ions; and 0.1 to 20 parts by weight of water- soluble polymer molecules.

HOT-DIP COATING APPARATUS

U.S. Patent 5,965,210. Oct. 12, 1999 M. Tada et al., assignors to Kawasaki Steel Corp., Hyogo, and Mitsubishi Heavy Industries, Ltd., Tokyo

A hot-dip coating method in which a steel strip is coated as it is fed upwardly through a slit in a bottom of a coating tank, the im- provement comprising making a

COST EFFECTIVE INDUSTRIAL WASTEWATER SYSTEMS

COMPLIANCE

@s WLlEn

RECYCLE

REUSE

! ProChemTech International, Inc.

NATIONWIDE SUPPLIER OF SYSTEMS WHICH INTEGRATE CHEMISTRY AND EQUIPMENT FOR

COST EFFECTIVE TREATMENT, REUSE, AND RECYCLE OF INDUSTRIAL WASTEWATER

WE MANUFACTURE : INCLINED PLATE CLARIFIER SYSTEMS FROM 5 TO 1000 GPM

SEQUENTIAL BATCH SYSTEMS FROM 250 TO 5000 GALLON MEMBRANE SYSTEMS FROM 2 GPM TO 250 GPM ION EXCHANGE SYSTEMS FROM 2 TO 100 GPM

SMALLER UNITS ARE SKID MOUNTED AND FULLY ASSEMBLED - READY TO RUN

Phone 8 14-265-0959 FAX 814-265-1263

www.prochemtech.com

Circle 067 on reader information card

flow velocity of the molten metal uniform across a breadth of the strip by directing the molten metal through a flow restricting buffer as the molten metal enters the coating tank at the inlets.

ELECTROLESS COPPER PLATING

SOLUTION

U.S. Patent 5,965,211. Oct. 12, 1999 K. Kondo et al., assignors to Nippondenso Co., Ltd., Kariya, Japan

A process for formation of a cop- per plating film, which comprises immersing a material to be plated in an electroless copper plating solution of copper ions; a reducing agent; a pH-adjusting agent; a tri- alkanolmonoamine or a salt thereof in an amount sufficient to act as a complexing agent and ac-

For a FREE Book List

Circle 560 on Reader

Information Card

- Kushner Electroplating School

“Training Electroplaters Since 1947”

TRAINING FOR BETTER METAL FINISHING ELECTROPLATING KNOW HOW II

(/ CORRESPONDENCE PROGRAMS

c/ GROUP TRAINING PROGRAMS

d ON-SITE TRAINING PROGRAMS

d CUSTOM TRAINING PROGRAMS

732 Glencoe Court, Sunnyvale, CA 94087 (408) 749-8652 . Fax (408) 749-0176

E-mail: [email protected] www.platingschool.com

Circle 047 on reader information card

116 Metal Finishing

Page 2: Electroless copper plating solution

celerator; an iron ion compound selected from a group consisting of at least one of ferrous halide salts, ferric halide salts, ferrocya- nide compounds, and ferric cya- nide compounds as a reaction ini- tiator; and at least one compound selected from the group consist- ing of pyradazine methylpiperi- dine, 1,2-di-(2-pyridyljethylene, 1,2-di-CpyridylIethylene, 2,2’- dipyridylamine, 2,2’-bipyridyl, 2,2’-bipyrimidine, 6,6’-dimethyl- 2,2’-dipyridyl, di-2-pyridylketone, N,N,N’,N’-tetraethylethylenedi- ame, naphthalene, M-naphthy- ridine, 1,6-naphthyridine, tetra- thiafurvalene, cw,a,a-terpyridine, phthalic acid, isophthalic acid, and 2,2’-dibenzoic acid as an agent for effecting physical properties of the plating film.

AQUEOUS DISPERSIONS OF A TRANSPARENT POWDER COATING

U.S. Patent 5,965,213. Oct. 12, 1999 L. Sacharski et al., assignors to BASF Coatings AG, Muenster- H&-up, Germany

A method of coating vehicle bodies

4

GRINDERS-LAPPERS-POLISHERS

PUMP n SLURRIES ‘PARTICULATE MAlTER ’ COATINGS . CORROSIVE CHEMI

n HIGH ACCURACY ‘LOW MAINTENANCE aVARIABLE FLOW . FAST/EASY CLEAN-UP

BARNANT COMPANY l-800-637-3739 FAX : 847-381-7053

E-mail: [email protected] Website: www.barnant.com

d

Circle 008 on reader information card Circle 089 on reader information card

of sheet metal and/or plastic by applying a coating by means of electrostatically assisted high- speed rotation or pneumatic ap- plication wherein the coating comprises an aqueous dispersion of a transparent powder coating, consisting of a solid powder com- ponent A and an aqueous compo- nent B, wherein component A is a transparent powder coating comprising at least one epoxy group-continuing binder having a content of glycidyl-containing monomers of from 30 to 45%, and at least one crosslinking agent, and component B is an aqueous dispersion comprising at least one nonionic thickener; and further wherein the aqueous dispersion has a pH between 5.5 and 6.5.

COPPER- AND TIN-PLATED CONNECTOR

U.S. Patent 5,965,279. Oct. 12, 1999 N. Yu, Montmirail, France, assignor to Axon Cable SA, Montmirail, France

An electrical conductor made of copper-plated and tin-plated alu- minum.

SOLUKLEEN & SOLUCOAT

Designed with mulfiple objecfives in mind: . Available in liquid or powder l Expert technical support n Concentrated to reduce costs . Extended bath life & -educed sludge

Solukleen and Solucoat products are

formulated with your specific application in mind. WORKING SOLUTIONS offers these

products in drums & bulk containers. For more detah contact

tiotW9

s luti ns WORKING SOLUTIONS, INC. 4810 Nett Street l Houston, TX 77007 l-800-829-4419 Fax: 713-862-5591

E-mail: cmclrxC?pdq.net www.workingsolutions.net

MECHOD FOR MEASURING CYANIDE

U.S. Patent 5,965,450. Oct. 12, 1999 N.P. Kelada, Glen Ellyn, Ill.

A system for measuring total cya- nide, dissociable cyanide, and complex cyanide in a sample com- prising photoillumination means for irradiating the sample and dissociating cyanides contained therein; means to carry to allow radiation from the photoillumina- tion means to cause dissociation of cyanides in the sample and a distillation section configured for distilling dissociated cyanides in the sample by heat generated by the photoillumination means; means for acidifying the sample; means to inhibit thiocyanate dis- sociation located between the pho- toillumination means and means to carry the sample; and measur- ing means for recovering cyanide and generating a recordable sig- nal indicative of the amount of cyanide in the sample.

AGUEOUS CLEANER

U.S. Patent 5,965,509. Oct. 12, 1999

M.C. Welch et al., assignors to BASF

Highly Efficient/Low Emission Design for Greatly Reduced Solvent Consumption

l NESHAP Compliant l Accepts All Currently Approved Solvents

l Phimary &!!d COLD TffAPm Refrigeration Provided by one Compressor

l Containment Pan . OPTlOhlAL EQUIPMENT l Super Heat

l Totally Enclosed Automated Work Areas l AW-SD Automatic

Programmable Hoist l RRS Rotating Basket System l HES (Hi& Efficiency System)

Total Work Area Enclosure l Solvent Recovery Still

l Ultrasonics

ULTFU-KOOL, INC. can st,” extend the Lfe of your ex,stq rqupnent by mst&ng out trademark retrofit Comphance

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September 2000 117