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ELECTRONS AND THEIR LOCATION. ELECTRON ADDRESSES. RULES TO REMEMBER. HEISENBERG UNCERTAINTY PRINCIPLE –Cannot know the exact location of an electron. Fundamentally impossible to know both the location and momentum/velocity of an electron at the same time. - PowerPoint PPT Presentation
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ELECTRONS AND THEIR LOCATION
ELECTRON ADDRESSES
RULES TO REMEMBER HEISENBERG UNCERTAINTY PRINCIPLE –
Cannot know the exact location of an electron. Fundamentally impossible to know both the location and momentum/velocity of an electron at the same time.
The quantum mechanical model merely suggests the probability of the electron location.
No circular orbits – Sorry Bohr! Instead: orbitals - the 3-dimensional region
is which there is a high probability of finding an electron in an atom
Aufbau Principle Electrons fill the lowest possible energy
level. Energy levels correspond to period
number on the Periodic Table. How many energy levels are there?
orbitals
Textbook definition: the 3-dimensional region is which there is a high probability of finding an electron in an atom
s on page 371p on page 372d on page 374
Pauli Exclusion Principle No more than two (2) electrons in an
orbital.
Hund’s Rule(s)1. Orbitals of equal energy must fill singly
before doubling. (ex. all d’s must fill with 1 electron each
before the second electron can fill in – like dealing cards)
2. All electrons in singly occupied orbitals have the same spin direction
3. Pairs of electrons in the same orbital have opposite spin.
QUANTUM NUMBERS Describe the electron’s “address” 1st Quantum is the principle quantum –
describes the energy level, or period. 2nd Quantum describes the shape of the
orbitals. s,p,d,f 3rd Quantum describes the orientation of
the orbital 4th Quantum describes the spin of the
electron
Energy Levels
kinds of orbitals
# of each kind
# of electrons
Total # of electrons
Energy levels
kinds of orbitals
# of each kind
# of electrons
Total # of electrons
1 s 1 2 2
Energy levels
Kinds of orbitals
# of each kind
# of electrons
Total # of electrons
1 s 1 2 2
2 sp
13
26
8
Energy levels
Kinds of orbitals
# of each kind
# of electrons
Total # of electrons
1 s 1 2 2
2sp
13
26
8
3spd
135
2610
18
Energy levels
Kinds of orbitals
# of each kind
# of electrons
Total # of electrons
1 s 1 2 2
2 sp
13
26
8
3 sPd
135
2610
18
4 spdf
1357
261014
32
n n kinds odd #’s (total:n2)
2 x # of orbitals
2n2
What do you think the 5th energy level looks like?
The pattern stops – it looks like the 4th energy level
What about 6 & 7?
Quick Quiz A. How many electrons can the p
orbitals hold if filled? B. How many kinds of orbitals are in the
4th energy level? C. What are the orbitals of the 2nd
energy level? D. How many f orbitals are there? E. How many electrons can any one
orbital hold? F. At most, how many electrons in the
2nd energy level?
Orbital Diagrams or Orbital Configurations
Use boxes and arrows to represent electrons in various energy levels.
Boxes must be labeled with regard to energy level and orbitals.
orbital configuration
H
1s
orbital configuration
H
He1s
1s
orbital configurationH
He
Li1s
1s
1s 2s
orbital configurationH
He
Li
Be1s
1s
1s
2s1s
2s
orbital configuration
B
C1s
1s
2s 2p
2p2s
orbital configuration
N1s 2s 2p
Practice
Draw orbital diagrams for elements # 4,6,9,15, and 26
Lewis Dot Structures Element symbol represents atom nucleus and
inner electrons. Dots around the symbol represent valence
(outermost energy level) electrons.
Lewis dot structure
Symbol1
Lewis dot structure
Symbol1 2
Lewis dot structure
Symbol1 23
Lewis dot structure
Symbol1 2
4
3
Lewis dot structure
Symbol1 2
4
53
Lewis dot structure
Symbol1 2
4
536
Lewis dot structure
Symbol1 2
74
536
Lewis dot structure
Symbol1 2
745386
practice
Draw Lewis Dot structures for elements 1-11
Bohr Models Use concentric circles to represent energy
levels and the number of electrons in each.
Bohr model
H1-
Bohr model
Li2-
1-
Bohr model
Ne2-
8-
Bohr model
S2-
8-6-
Bohr model
K
2-
8-8-
1-
Practice Draw Bohr models for elements # 2, 3, 5, 9,
and 16