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Griltex Hotmelts for Composites www.emsgriltech.com

EMS Griltex hotmelts for composites

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EMS Griltex produces speciality copolymer adhesives for use in the composites sector. EMS products are ideal for the production of thermoplastic composites via the RTM process and for the reinforcement of woven carbon, glass, basalt and aramids. They offer great toughening properties in finished epoxy composites and improved CAI, delamination and peel strength performance. Email [email protected] or call 07917 005 938 for details on how EMS products could help your manufacturing processes.

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Page 1: EMS Griltex hotmelts for composites

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Griltex Hotmeltsfor Composites

www.emsgriltech.com

Page 2: EMS Griltex hotmelts for composites

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Content

Page

Griltex Hotmelts for:

Reinforcement of UD-tapes, knitted,woven and multiply fabrics 3

Thermoplastic Composites 10

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Reinforcement of UD-tapes and fabrics

Especially designed High Performance Polymers

for applications in Composites

made from epoxi-resins and

- Carbon fibers

- Mineral fibers (Glass, Basalt)

- Polymer fibers (Kevlar, Aramide)

- Natural fibers

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Properties

Stabilising of unidirectional filaments

multiply, woven and knitted fabrics

nonwovens

⇒ Better and easier handling

⇒ Antifray

⇒ Gluing of multiple layers to one component

⇒ Production of preforms without additional auxiliaries

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Mechanical Benefits CAI

High positive influence on impact

CAI values rise by 65% - Delamination areas decrease by 85%

18g/m2 Griltex, RTM 6; Testmethod: AITM 1.0010

CAI

0

50

100

150

200

250

300

Reference D 2433E D 2351E D 2419E

MP

a

Delamination area

0

1000

2000

3000

4000

5000

6000

7000

Reference D 2433E D 2351E D 2419E

mm

2

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Mechanical Benefits Peeling Force

Polymers are insoluble in Epoxi resin

⇒ Maintain the Tg of Epoxi-matrix

High peeling forces between Griltex High Performance Polymers and epoxi-resins

⇒ Maintain adhesion from Epoximatrix to fibers.

Bisphenol-A and amine hardener cured at RT on a Griltex polymer film over 16 h

Peel Strength

0

20

40

60

80

100

120

140

160

D 2433E D 2351E D 2419E StandardCoPES

FlexibleCoPES

StandardCoPA

PA12 EVA PE

[N/5

cm]

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Mechanical Benefit ILSS

ILSS-values increase up to 36%

18g/m2 Griltex; RTM 6; Test method: ASTM D2344M; Values at 120°C in preparation

ILSS - Test

0

10

20

30

40

50

60

70

80

Reference D 2433E D 2351E D 2419E

MPa

23°C 80°C

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Technical Data

Griltex Polymer

D 2433E D 2351E D 2419E

Melting range* °C 98-107 95-103 130-140

Glass Transition temperature* °C 18 18 17

Melt viscosity**(160°C/2.16Kg)

Pas 450 226 330

Melt volume rate**(160°C/2.16Kg) cm3/10' 23 48 32

Density*** g/cm3 1.31 1.31 1.31

* DSC** ISO 1133*** ISO 1183

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Application Techniques

→ Hotmelt lamination

→ Powder scattering

→ Powderdot, Pastedot

→ Meltblown

→ Webs

Suitable for all standard application techniques :

Meltblown hotmelt by standard spray head.

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Thermoplastic Composites

Matrix material by EMS high performance polymers

→ Easy to handle

→ Short cycle times

→ Reformable by temperature

Applications

→ Orthoses

→ Guards

→ Sports equipment

→ Organosheets

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Technical Data

Griltex Polymer

2A D 1428A

Melting range* °C 120-130 175-180

Glass Transition temperature* °C 15 45

Melt viscosity**(°C/2.16Kg)

Pas 560@160°C

180@ 230°C

Melt volume rate**(°C/2.16Kg) cm3/10' 18

@160°C50

@ 230°C

Density*** g/cm3 1.02 1.01

Use Matrix MatrixSurface

AvailabilityGranulesPowderSuspension

GranulesPowder

* DSC** ISO 1133*** ISO 1183

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EMS-GRILTECH [email protected]

Europe Americas

EMS-CHEMIE AG EMS-CHEMIE AG (North America) Inc.Business Unit EMS-GRILTECH Business Unit EMS-GRILTECHVia Innovativa 1 2060 Corporate WayCH-7013 Domat/Ems P.O. Box 1717Phone: +41 81 632 72 02 Sumter, SC 29151-1717, USAFax: +41 81 632 74 02 Toll free: +1 877 367 83 23E-mail: [email protected] Phone: +1 803 481 61 90

Fax: +1 803 481 61 29E-mail: [email protected]

Asia Japan

EMS-CHEMIE AG (Asia) Ltd. EMS-CHEMIE AG (Japan) Ltd.Business Unit EMS-GRILTECH Business Unit EMS-GRILTECH36, Kwang Fu South Road Osaka Office, Umeda Shinmichi Bldg.Hsin Chu Industrial Park 1-1-5, Dojima, Kita-kuFu Kou Hsiang, Hsin Chu Hsien Osaka 530-0003, JapanTaiwang, R.O.C. Phone: +81 6 6348 1655Phone: +886 35 983 335 Fax: +81 6 6348 1702Fax: +886 35 985 731 E-mail: [email protected]: [email protected]

Issued by: Technical Service Coatings + AdditivesEMS-CHEMIE AG business unit EMS-GRILTECH

Date: March 2012

Copyright: All rights reserved to EMS-CHEMIE AG.Any unauthorized copying and publishing is forbiddenGRILTEX is a registered trademark of EMS-CHEMIE AG