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EMS Griltex produces speciality copolymer adhesives for use in the composites sector. EMS products are ideal for the production of thermoplastic composites via the RTM process and for the reinforcement of woven carbon, glass, basalt and aramids. They offer great toughening properties in finished epoxy composites and improved CAI, delamination and peel strength performance. Email [email protected] or call 07917 005 938 for details on how EMS products could help your manufacturing processes.
Citation preview
1
Griltex Hotmeltsfor Composites
www.emsgriltech.com
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Content
Page
Griltex Hotmelts for:
Reinforcement of UD-tapes, knitted,woven and multiply fabrics 3
Thermoplastic Composites 10
3
Reinforcement of UD-tapes and fabrics
Especially designed High Performance Polymers
for applications in Composites
made from epoxi-resins and
- Carbon fibers
- Mineral fibers (Glass, Basalt)
- Polymer fibers (Kevlar, Aramide)
- Natural fibers
4
Properties
Stabilising of unidirectional filaments
multiply, woven and knitted fabrics
nonwovens
⇒ Better and easier handling
⇒ Antifray
⇒ Gluing of multiple layers to one component
⇒ Production of preforms without additional auxiliaries
5
Mechanical Benefits CAI
High positive influence on impact
CAI values rise by 65% - Delamination areas decrease by 85%
18g/m2 Griltex, RTM 6; Testmethod: AITM 1.0010
CAI
0
50
100
150
200
250
300
Reference D 2433E D 2351E D 2419E
MP
a
Delamination area
0
1000
2000
3000
4000
5000
6000
7000
Reference D 2433E D 2351E D 2419E
mm
2
6
Mechanical Benefits Peeling Force
Polymers are insoluble in Epoxi resin
⇒ Maintain the Tg of Epoxi-matrix
High peeling forces between Griltex High Performance Polymers and epoxi-resins
⇒ Maintain adhesion from Epoximatrix to fibers.
Bisphenol-A and amine hardener cured at RT on a Griltex polymer film over 16 h
Peel Strength
0
20
40
60
80
100
120
140
160
D 2433E D 2351E D 2419E StandardCoPES
FlexibleCoPES
StandardCoPA
PA12 EVA PE
[N/5
cm]
7
Mechanical Benefit ILSS
ILSS-values increase up to 36%
18g/m2 Griltex; RTM 6; Test method: ASTM D2344M; Values at 120°C in preparation
ILSS - Test
0
10
20
30
40
50
60
70
80
Reference D 2433E D 2351E D 2419E
MPa
23°C 80°C
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Technical Data
Griltex Polymer
D 2433E D 2351E D 2419E
Melting range* °C 98-107 95-103 130-140
Glass Transition temperature* °C 18 18 17
Melt viscosity**(160°C/2.16Kg)
Pas 450 226 330
Melt volume rate**(160°C/2.16Kg) cm3/10' 23 48 32
Density*** g/cm3 1.31 1.31 1.31
* DSC** ISO 1133*** ISO 1183
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Application Techniques
→ Hotmelt lamination
→ Powder scattering
→ Powderdot, Pastedot
→ Meltblown
→ Webs
Suitable for all standard application techniques :
Meltblown hotmelt by standard spray head.
10
Thermoplastic Composites
Matrix material by EMS high performance polymers
→ Easy to handle
→ Short cycle times
→ Reformable by temperature
Applications
→ Orthoses
→ Guards
→ Sports equipment
→ Organosheets
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Technical Data
Griltex Polymer
2A D 1428A
Melting range* °C 120-130 175-180
Glass Transition temperature* °C 15 45
Melt viscosity**(°C/2.16Kg)
Pas 560@160°C
180@ 230°C
Melt volume rate**(°C/2.16Kg) cm3/10' 18
@160°C50
@ 230°C
Density*** g/cm3 1.02 1.01
Use Matrix MatrixSurface
AvailabilityGranulesPowderSuspension
GranulesPowder
* DSC** ISO 1133*** ISO 1183
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EMS-GRILTECH [email protected]
Europe Americas
EMS-CHEMIE AG EMS-CHEMIE AG (North America) Inc.Business Unit EMS-GRILTECH Business Unit EMS-GRILTECHVia Innovativa 1 2060 Corporate WayCH-7013 Domat/Ems P.O. Box 1717Phone: +41 81 632 72 02 Sumter, SC 29151-1717, USAFax: +41 81 632 74 02 Toll free: +1 877 367 83 23E-mail: [email protected] Phone: +1 803 481 61 90
Fax: +1 803 481 61 29E-mail: [email protected]
Asia Japan
EMS-CHEMIE AG (Asia) Ltd. EMS-CHEMIE AG (Japan) Ltd.Business Unit EMS-GRILTECH Business Unit EMS-GRILTECH36, Kwang Fu South Road Osaka Office, Umeda Shinmichi Bldg.Hsin Chu Industrial Park 1-1-5, Dojima, Kita-kuFu Kou Hsiang, Hsin Chu Hsien Osaka 530-0003, JapanTaiwang, R.O.C. Phone: +81 6 6348 1655Phone: +886 35 983 335 Fax: +81 6 6348 1702Fax: +886 35 985 731 E-mail: [email protected]: [email protected]
Issued by: Technical Service Coatings + AdditivesEMS-CHEMIE AG business unit EMS-GRILTECH
Date: March 2012
Copyright: All rights reserved to EMS-CHEMIE AG.Any unauthorized copying and publishing is forbiddenGRILTEX is a registered trademark of EMS-CHEMIE AG