ERM INC - ALUMINUM RICH FILL STUDY PROJECT - … · 14A 14B 14BFD ISA 15AFD 15B 16AB 17A 17B 18A 18B 14AFB 15BFB 5CFB. Section 1 Quality Assurance Review ... (Form VA), the laboratory

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ERM-North CcntraUnc.102 Wilmot Road • Suite 300 • Deerfield, Illinois 60015 • (708) 940-7200 • (708) 940-9280 Fax

May 20, 1991

Mr. Richard BoiceU.S. Environmental Protection AgencyRegion V, Mail Code 5HS-11230 S. Dearborn StreetChicago, Illinois 60604

RE: Midco IIAluminum-Rich Fill StudyERM Project No. 0184

Dear Mr. Boice:

Enclosed is the information which you requested during a May 2, 1991 telephone conversationwith Roy O. Ball of ERM-North Central, Inc. The information transmitted to you includes:

1. Copies of the Chain of Custody forms, and

2. A copy of the Environmental Standards, Inc. Data ValidationReport.

Also, for your information, the letter code at the end of the sample number identifies the depthat which the sample was collected (i.e., A = 0-2 feet, B = 2-4 feet, C = 4-6 feet, etc.).

Please contact Roy Ball or me if you have any questions.

Very truly yours,

ERM-NORTH CENTRAL, INC. //J

Paul J. KopydlowskiSenior Project Geologist

BRANCHdb

Enclosures .

An affiliate of The Environmental Resources Management Group with offices worldwide

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QUALITY ASSURANCE REVIEW

OF THE MTDCO H SITE,

GARY, INDIANA

March 29, 1991

Prepared for:

ERM-NORTH CENTRAL, INC.102 Wilmot Road

Suite 300Deerfield, IL 60015

Prepared by:

ENVIRONMENTAL STANDARDS, INC.1220 Valley Forge Road

P.O. Box 911Valley Forge, PA 19481

QUALITY ASSURANCE REVIEW

OF THE MIDCO H SITE,

GARY, INDIANA

March 29, 1991

Prepared for:

ERM-NORTH CENTRAL, INC.102 Wilmot Road

Suite 300Deerfield, IL 60015

Prepared by:

ENVIRONMENTAL STANDARDS, INC.1220 Valley Forge Road

P.O. Box 911Valley Forge, PA 19481

TABLE OF CONTENTS

Introduction

Section 1

Section 2

Section 3

Section 4

Inorganic Quality Assurance Review

A. Inorganic and Conventionals Data

B. Conclusions

Analytical Results - Inorganic Data

Inorganic Data Support Documentation

A. SDG1A

B. SDG11AFD

Project Case Narratives and Chain-of-Custodies

Introduction

This quality assurance review is based upon a review of all data generated from the 35 soilsamples and 3 aqueous field blanks that were collected between March 11-15, 1991, for theMidco II site of Gary, Indiana. The samples that have undergone a rigorous quality assurancereview are listed on Table 1.

This review has been performed in accordance with the following references:

"Functional Guidelines for Evaluating Inorganics Analyses" and "Region V SpecialAnalytical QC Requirements for the Zeeman Graphite Furnace Atomic AbsorptionSpectrophotometric Method." (U.S. EPA, 1988).

The reported analytical results are presented as a summary of the data in Section 2. All of theanalytical data were examined to determine contractual compliance relative to the analyticalrequirements and deliverables specified in EPA's Contract Laboratory Program (CLP) protocol.Qualifier codes have been placed next to the results so that the data user can quickly assess thequantitative reliability of any results. Details of this quality assurance review are presentedbelow in the narrative section of this report. This report was prepared to provide a criticalreview of the laboratory analyses and reported analytical results. Rigorous quality assurancereviews of laboratory-generated data routinely identify various problems associated withanalytical measurements, even from the most experienced and capable laboratories. The natureand extent of problems identified in this critical review should not be interpreted to mean thatthose results that do not have qualifier codes are less than valid.

TABLE 1

SAMPLES INCLUDED IN THIS QUALITY ASSURANCE REVIEW

ERM-North CentralSample Number

M2FS-1AM2FS-1BM2FS-1C

M2FS-10AM2FS-10BM2FS-10CM2FS-11AM2FS-11BM2FS-11CM2FS-2AM2FS-2BM2FS-2CM2FS-3A

M2FS-3BM2FS-3CM2FS-4BM2FS-5AM2FS-5B

M2FS-5BFD(Field Duplicate)

M2FS-9BCM2FS-11AFD

(Field Duplicate)M2FS-12BM2FS-13A

Sample DeliveryGroup

> :V:k:: 1A

1A1A1A1A1A1A1A1A1A1A

1A1A

1A1A

1A

1A

1A

1A

1A

11AFD

11AFD11AFD

LaboratorySample Number

1AIB1C

10A10B10C11A11B11C2A2B2C3A3B3C4B5ASB

5BFD

9BC11AFD

12B13A

TABLE 1 (Cont.)

ERM-North CentralSample Number

M2FS-13BM2FS-14A

M2FS-14BM2FS-14BFD

(Field Duplicate)M2FS-15A

M2FS-15AFD(Field Duplicate)

M2FS-15BM2FS-16ABM2FS-17AM2FS-17BM2FS-18AM2FS-18B

M2FS-14AFB(Field Blank)M2FS-15BFB(Field Blank)M2FS-5CFB(Field Blank)

Sample DeliveryGroup11AFD11AFD11AFD

;•: :'-;;u;;}||?llAFD . :

11AFD'''^f:!jf'liAFi>'

11AFD11AFD11AFD11AFD11AFD11AFD11AFD

11AFD

11AFD

LaboratorySample Number

13B14A14B

14BFD

ISA15AFD

15B16AB17A17B18A18B

14AFB

15BFB

5CFB

Section 1 Quality Assurance Review

A. Inorganic and Conventional; Data

The inorganic analysis of 35 soil samples and 3 aqueous field blanks was performed by NorthernLaboratories of Valparaiso, Indiana. The samples were analyzed by CLP protocols foraluminum and arsenic. Arsenic was analyzed by ICP and Zeeman GFAA spectrophotometricmethods due to the potential interferences of high aluminum concentrations. A copy of theRegion V Special Analytical Services QC requirements for the Zeeman GFAA method isincluded in the support documentation (Section 3).

The results for this data set were submitted in two distinct sample delivery groups as specifiedon Table 1. The findings in this report are based upon a rigorous review of holding times, blankanalysis results, pre- and post-digestion spike recoveries, laboratory duplicate analyses,instrument sensitivity, calibrations, ICP interference checks and quantitation of positive results.The analytical results are provided in Section 2 of this report.

Overall, the inorganic and conventional* data quality was fair. Contractual criteria (CLP) andreporting requirements were met for this data set, with the exception of the following. It shouldbe noted that the following issues are contractual in nature and may not necessarily affect datausability. Data usability is addressed in a subsequent section.

Correctable Deficiencies

1. A case narrative was not included with the data package submitted for validationassociated with SDG11AFD.

2. The data packages submitted for validation did not include the Chain-of-Custodiesassociated with every sample in both data packages. ERM-North Central was contactedand supplied the Chain-of-Custodies.

3. The concentration units for several preparation blank results were not reported on theblank forms (Form His). These should have been reported in soil units (mg/Kg).

4. The laboratory did not provide the standard additions forms (Form VIII's) in either datapackage. However, the Method of Standard Additions (MSA) was not required for anyof the arsenic results reported.

5. The laboratory did not calculate and report the post-digestion spike recoveries for arsenicby GFAA in the raw data as required (SOW788, B-9). This necessitated extra time forthe data reviewer to calculate these values in order to evaluate overall matrix effects.

-page 2

6. The laboratory misreported the result for arsenic in sample M2FS-5A as 16.4 mg/Kg.According to the raw data, the data reviewer calculated a result of 19.1 mg/Kg, and thisrecalculated result has been added to the data table. In order to substantiate thisrecalculation, the raw data associated with arsenic in sample M2FS-5A has been includedat the end of the support documentation (Section 3).

7. The laboratory did not provide the post-digestion spike forms (Form VB) in the datapackage for both SDGs or prepare and analyze a post-digestion spike sample for arsenicby ICP in sample M2FS-2A and aluminum in sample M2FS-17B. The recovery forarsenic in the corresponding sample was low (67.9%), and for aluminum, the recoverywas high (125.196). According to SOW788, E-10, if the spike recovery falls outside thecontrol limits (75-125%), a post-digestion spike must be performed.

8. The laboratory did not put the proper client identification numbers on the QC forms.The prefix "M2FS" was not included as part of the identification numbers.

9. The laboratory mislabeled an ICV as a CCV in the raw data associated with the arsenicanalysis by GFAA for SDG1A.

10. The inorganic data analysis sheet for aluminum and arsenic by ICP in sampleM2FS-11AFD (page 3) was missing from the data package. Results for these analyteswere found in the raw data and entered on the data tables.

11. The laboratory did not flag arsenic by Zeeman GFAA for SDG11AFD with an "*"qualifier code. The absolute difference between the sample and duplicate result wasgreater than the CRDL. As per SOW788, E-12, the laboratory should have qualifiedarsenic in SDG11AFD with an "*" qualifier code.

Noncorrectable Deficiencies

1. The laboratory did not analyze the CRDL standard for arsenic (by ICP) at 2x IDLconcentration as per SOW788, E-6, since the IDL for arsenic by ICP (49.0 ng/i.) wasgreater than the CRDL (10 /ig/L). All CRDL results for arsenic observed in the rawdata were less than the instrument detection limit (IDL).

2. The laboratory apparently added the incorrect spike concentrations for arsenic (by ICP)in spike samples in SDG1A and in samples M2FS-13B and M2FS-17B. According tothe spike sample recovery form (Form VA), the laboratory added either 1000 fag/L or500 pg/L arsenic but should have added 2000 pg/L for aqueous and soil samples(SOW788, E-ll). Similarly, the laboratory added the incorrect spike concentration ofarsenic by GFAA for samples M2FS-17B, M2FS-13B and M2FS-15BFB. Concentrationsof 90.64 pi/L, 34.39 /zg/L and 20.0 pg/L arsenic were added, but 40.0 /ig/L arsenicshould have been added for the GFAA znalyses of these samples. S-milarly, 2500 jig/L

-page 3

of aluminum was added to sample M2FS-SCFB for the matrix spike analysis of thissample for aluminum but 2000 j»g/L should have been added for aqueous samples.

The laboratory did not prepare and analyze an ICP serial dilution sample for arsenic andaluminum in both SDGs as required (SOW788, E-13).

Comment

The laboratory spiked soil samples M2FS-17B, M2FS-13B, M2FS-3A and M2FS-2Awith 200,000 jig/L aluminum which is not required by CLP protocol. However, theresults obtained for this analysis was used to evaluate soil matrix effects on the aluminumanalysis.

With regard to data usability, principal areas of concern include matrix spike recoveries,Contract Required Detection Limit (CRDL) standards and laboratory duplicates. Based on arigorous review of the data provided, the following qualifiers are offered. These data qualifiersshould be considered when evaluating the data. It should be noted that the following datausability issues represent an interpretation of the quality control results obtained for the projectsamples. Quite often data qualifications address issues relating to the sample matrix problems.Similarly, the validation guidelines routinely specify areas of the data that require qualification,yet the methods used for analysis do not require any corrective action by the laboratory.Accordingly, the following data usability issues should no! necessarily be construed as anindication of laboratory performance.

Inorganic Data Qualifiers

The positive results for arsenic analyzed by ICP and Zeeman GFAA seem to beanomalous. However, the concentrations of arsenic reported by the ICP method appearto be entirely due to the interference from aluminum. Consequently, the positive resultsfor arsenic by ICP should be considered unreliable and have been flagged "R" on thedata tables. The calculated concentrations of arsenic due to the ICP interference ofaluminum can be found in the beginning of the support documentation of the report(Section 3).

The positive results for arsenic by Zeeman GFAA for samples M2FS-1C, M2FS-3C,M2FS-13B, M2FS-15AFD, M2FS-13A and M2FS-15B should be considered estimatedand have been flagged "J" on the data tables. High (> 110%) recoveries were observedfor arsenic in the Contract Required Detection Limit (CRDL) standards.

The positive results for aluminum for every sample in SDG1A except M2FS-2A shouldbe considered estimated and have been flagged "J" on the data tables. A very low(-60.7%) recovery was observed for aluminum in the matrix spilre sample.

-page 4

The positive results for aluminum in samples M2FS-11AFD, M2FS-12B, M2FS-13A,M2FS-14A, M2FS-14B, M2FS-14BFD, M2FS-15A, M2FS-15AFD, M2FS-15B,M2FS-16AB, M2FS-17A, M2FS-17B, M2FS-18A and M2FS-18B and for arsenic byZeeman GFAA in samples M2FS-13A, M2FS-14B, M2FS-15AFDand M2FS-15B shouldbe considered estimated and have been flagged "J" on the data tables. High (> 125%)recoveries were observed for these elements in the corresponding matrix spike sampleanalyses.

The positive results for arsenic by Zeeman GFAA in samples M2FS-11C, M2FS-3A andM2FS-5A should be considered estimated and have been flagged "J" on the data tables.Low (<85%) recoveries were observed for arsenic in the post-digestion matrix spikeanalyses of these samples.

The positive results for arsenic by Zeeman GFAA in samples M2FS-13A, M2FS-13B,M2FS-14B, M2FS-15AFD and M2FS-15B should be considered estimated and have beenflagged "J" on the data tables. The absolute difference between the sample and duplicateresults were greater than the CRDL for arsenic.

The positive results for arsenic by Zeeman GFAA for samples M2FS-1C, M2FS-1 IB andM2FS-11C should be considered estimated and have been flagged "J" on the data tables.High (>20%) relative standard deviations were observed between the duplicate bums inthe above mentioned samples.

The laboratory analyzed samples M2FS-11AFD and M2FS-13A at a 10 fold dilution dueto ICP interferences in the undiluted samples. Since the concentrations of both sampleswere similar, the undiluted results were reported for arsenic in both samples.

-page 5

B. Conclusions

This quality assurance review has identified several aspects of the data set that have requiredqualification. In general, the data represents fair quantitative analyses, with the exception ofarsenic by ICP, which should be considered rejected for all samples with positive results. Toconfidently use any of these analytical results from the data sets examined, the data users shouldunderstand the qualifications and limitations stated in this report.

Report prepared by: Report reviewed by:

William E. Strohben, Jr. Dofiald J. LancasterQuality Assurance Chemist Senior Quality Assurance Chemist

Report approved by:

Rock J. VitaleQuality Assurance Specialist/Principal

ENVIRONMENTAL STANDARDS, INC. Date: H/l | 9 11220 Valley Forge RoadP.O. Box 911Valley Forge, PA 19481

(215) 935-5577

SECTION 2

ANALYTICAL RESULTS - INORGANIC DATA

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SECTION 3

INORGANIC DATA SUPPORT DOCUMENTATION

A. SDGIA

PROJECT NAME:

SUPPORT DOCUMENTATION FOR THE REVIEW OFINORGANIC ANALYTICAL DATA PACKAGE

TYPE or ..........CONTRACT L A B O R A T O R Y ,

• —— - Rf V IEWER:R e v i e w DATE

THE FOLLOWING TABLE INDICATESAREAS WHICH WERE EXAMINED INDETAIL, THE IDENTIFIED PROBLEMAREA) . AND SUPPORT DOCUMENTATION-ATTACHMENTS!

APPLICABLE SAMPLE No't-.

AREAS EXAMINEDIN DETAIL

CMECK(V) IF YESOR FOOTNOTE LETTERFOR COMMENTS BELOW

PROBLEM AREASIDENTIFIED

CHECKtV) IF YES.OR FOOTNOTE NUMBERFOR COMMENTS BELOW

SUPPORTDOCUMENTATION

ATTACHMENTS

CHECK IV) IF YES~OR IDENTIFY

ATTACHMENT NO.

HOLDING TIMES

BLANK ANALYSIS RESULTSMATRIX SPIKES (PRE-OISESTION)

DUPLICATESOUANTITATION OF RESULTSDETECTION LIMITS/SENSITIVITYINITIAL CALIBRATIONSCONTINUING CALIBRATIONSLABORATORY CONTROL STANDARDSICP LINEAR RANGE ANALYSIS

ICP INTERFERENCE CHECKSICP SERIAL DILUTIONS9FAA POST- DIGESTION SPIKESSFAA DUPLICATE BURNSGFAA STANDARD ADDITIONSOTHERS

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(1) RESULT REPORTED BY THE LRBORRTORV RND CONFIRMED BV REUIEUIER(2} RESULT INFERED FROM INSTRUMENT PRINTOUTS AND/OR SUPPOATING DATA

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TABLE 2. EXAMPLE OF AHALVTE CONCEMTRATION EQUIVALENTS (MG/L) ARISING FROMINTERFERENTS AT THE 100 MG/L LEVEL

1Analyte

AluminumAntimonyArsenicBariumBerylliumBoronCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMolybdenumNickelSeleniumSiliconSodiumThalliumVanadiumZinc

Wavelength,n»

308.215206.833193.696455.403313.042249.773226.502317.933267.716228.616324.754259.940220.353279.079257.610202.030231.604196.026

288.158588.995190.864292.402213.856

Al Ca

0.471.3—— —0.04—— —

———— —

0.170.02

0.005

0.05

0.23—

—0.30—— —

cr Cu

2.90.44

——— —

—0.08— —

0.03™——0.110.01——0.07——

0.050.14

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—0.320.030.01 0.010.0030.0050.003—_ _0.130.002 0.0020.03

0.09_ _——

0.005—

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0.21

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0.020.040.04

0.03—

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— _— — __——— — __

0.29

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U.S. Environmental Protection AgencyCLP Sample Management Office __________P.O. Box 818, Alexandria, Virginia 22313 ! SAS Number |PHONE: (703) 557-2490 or FTS 557-2490 j____________j

SPECIAL ANALYTICAL SERVICESClient Request

j j Ragional Transmittal j ! Telephone Request

A. EPA Region/Client:

B. RSCC Representative:

C. Telephone Number:

D. Date of Request:

I. Site Name:

Please provide below a description of your request for Special AnalyticalServices under the Contract Laboratory Program. In order to most efficient!;obtain laboratory capability for your request, please address the followincconsiderations, if applicable. Incomplete or erroneous information ma;result in delay in the processing of your request. Please continue responsion additional sheets, or attach supplementary information as needed.1. General description of analytical service requested: Analysis of TA:

1-- . metals by SOW 7/88, except arsenic will be determined by GFAA usincZeeman background correction, L'Vov platform atomization, and nicke:nitrate matrix modifier (Use of Zeeman, L'Vov platform -nickel nitrateis non-negotiable) .

2. Definition and number of work units involved (specify whether wholisamples or fractions; whether organics or inorganics; whether aqueoujor soil and sediments; and whether low, medium, or high concentration)

sediments and soils with arsenic values ranging betwee:and' ng/kg for past samplings from same area.

3. Purpose of analysis (specify whether Superfund (Remedial o:Enforcement), RCRA, NPDES, etc.):

c4. Estimated date(s) of collection:

5. Estimated date(s) and method of shipment:

6. Number of days analysis and data required after laboratory receipt ofsamples:

Laboratory should report results within . days after receipt ofsamples.

: 7. Analytical protocol required (attach copy if other than a protocoli ^—- currently used in this program):I CLP Statement of Work SOW 7/88 shall be used for analysis ot metals,

except arsenic, which will be tested according to the specialI instructions specified in Attachments 2 and 3.

8. Special technical instruction (if outside protocol requirements, specify •i_ compound names, CAS numbers, detection limits, etc.):

see Attachment 1

9. Analytical results required (if known, specify format for data sheets,\____ QA/QC reports, Chain-of-Custody documentation, etc.). If not completed,

format of results will be left to program discretion.

See Attachment 1

10. Other (use additional sheets or attach supplementary information, asneeded):

11. Name of sampling/shipping contact:

Phone: •• -.'•

H-3

I. DATA REQUIREMENTS

Parameter: Detection Limit Precision Desired,(±* or Cone.)

Arsenic 10 ug/1 in the 25% RPD for valuesdigestate or 2 greater than.equal tong/Jcg wet weight 10 mg/Xg wet weightin the sample, or

±10 eg/kg wet weight ifvalues are less than10 Jng/Xg wet weight.

13. QC REQUIREMENTS

Audits Required frequency of Audits Limits* f% or Cone.)

See Attachment 2

III. ACTION REQUIRED IF LIMITS ARE EXCEEDED:TUG

**•uw i i r-MJ^-i tj ,See Attachment 2

'please return €EtT~reiju«s£. to the/Sample Management Office as soon aspossible to expedite processing" "Wf—your, request for special analyticalservices. Should you have any questions or neTd—any-assistance, please callthe Sample Management Office. / ~~~ -

H-4

02X0B/1991 15'Sl FROM US EPfl REGION S RERB TO 9170894lj3iBkJ r.K

Attachment 1

8. Analysis of arsenic shall be performed by graphite furnace atomicabsorption (GFAA) using Zeeman background correction only (this is notnegotiable). L'Vov platform atomiration and Ni (NO,), matrix modifiershall also be used. If the acceptance control limits for the matrixspike and laboratory duplicate audits specified in Section III are notset, all QC audits and the associated samples must be redigested andreanalyzed; however, reanalysis of digestates and QC audits can be doneif appropriate, prior to redigestion.For the arsenic matrix spike, the concentration of the added arsenic inthe digestate (200 ml final volume) shall be 250 ug/1. This correspondsto 50 mg/kg wet weight in the sample.

9. The deliverable* package shall be in accordance with the CLP statementof work, SOW 7/88 for inorganic analyses. A case narrative stating theanalytical conditions used for arsenic will be included. The narrativeshall include the following:

A. Arsenic Temperature ProgramB. Sample volume injectedC. Matrix modifier volume injected and concentration0. Analytical spike volume and concentration

All copies must be legible. Raw data for undiluted samples must alsobe included even if the result is not reported due to dilutionsperformed in subsequent runs.

02/08X1991 15:52 FROM US EPfl REGION 5 RERB TO 917089409280 P. 05

ATTACHMENT 2

OC Requirements

Zeeman Graphite Furnace Atomic Absorption Speetrophotometrie Method

Audits Required

Calibration Blank

Preparation Blank

Lab Duplicate

Matrix Spika

Lab Control Sample

ICVs and CCVs

ICB (by MSA)

ICV (by MSA)

CCV (by MSA)

Freouenev of Audits

Initially and after•vary 10 samplesOne per 10 samples(or 1 per sampledelivery group,whichever is morefrequent)One per 10 samples(or 1 per sampledelivery group,whichever is morefrequent)One per 10 samples(or 1 per sampledelivery group,whichever is morefrequent)

One per sat of samples

initially ICVS, andCCVS after every 10samplesOnce at beginning ofthe runOnce at beginning ofthe runOnce every 5 samplesand at the end ofthe run.

Control Limits

± IDL

± 10 ug/1

See Section IUnder "PrecisionDesired1'

80-120* recovery

85-115* recovery

90-110* recovery

± 5 ug/1

85-115* Recovery

85-115* Recovery

02/08/1391 IS'52 FROM US EPfl REGION 5 RERB TO 917089409230 P.07

ATTACHMENT 3

Special Instructions for As by Z-GFAA

Follow the CLP statement of work SOW 7/88 with the following exceptions.

1. All samples, standards and QC audits shall be analyzed by GFAA usingZeeman background correction, L'Vov platform atomization and nickelnitrate matrix modifier.

2. A four point linear calibration curve with r > 0.995 is to be used.

3. The matrix spike added for arsenic shall be 250 ppb in the digestate(200 ml final volume). This corresponds to SO mg/kg wet weight in thesample. All samples and QC audits will have analytical spikes at 20ug/1.

If sample dilutions are needed for the sample to be within thecalibration range, select a dilution factor such that the diluted sampleresult is at least 25% of the maximum linear range but yet does notexceed the linear range.

5. If the matrix spike recovery is outside of the sot to 120% range, thelab may reanalyze the sample before redigesting.

6. it the analytical spike is outside of the 85-115* R range and the resultis greater than IDL, the sample may be rerun. If the analytical spikeis still outside the acceptance range, the sample must be diluted usingthe criteria in Item ^. When the original sample result is less than25% of the linear range, use a dilution factor < 5.

7. If the analytical spike recovery is outside of the acceptance range of85-115% R after dilution, as per items 6 and 7, Method of StandardAdditions (MSA) must be used.

a. Use spikes of 0, 10, 20, and 30 ug/1.b. The following QC audits must be successfully run by MS A before

analyzing samples:

IC8 r 2 .995 Limit ± IDL-ICV r > .995 Limit ± 15% of true value

c. A CCV must be run by KSA every 5 samples during an MSA analyticalrun. A CCV by MSA must also be run after the last sample. The CCVaust have r > .995 and the result must be within ± 15% of the truevalue (85% to 115% recovery)

d. If dilution of a sample is required, for the sample to be withinthe linear range of the MSA, select a dilution factor such that thediluted result is no lesu than 20 ug/1.

02/08/1991 15'53 FROM US EPS REGION S RERB TO 9170B9409280 P.08

«. If th* first HSA result for a diluted sample has an r < .995,repeat the USA once with an additional dilution factor that givesa diluted result no !•>• than 10 ug/1, or reanalyze the dilutedsample by MSA.

f. If an undiluted saaple containing less than 30 ug/1 of As has anHSA r < .995, repeat the HSA once with a dilution factor of 5 orless, or reanalyze the sample by HSA.

Background Pk Area (A-s): O.043 Background Pk Height (A): 0.05OBlank Corrected Pk Area (A-*): -O.OO1Concentration (ug/L ): -O.3

Mean Cone (ug/L ): -0.7 SO: O.43

~heck sample is within range -10.0 - 10.O

RSD(*): 73.73

As Seq. No.: 00265 A/S Pos.: 31 Date: 02/20,'

ReplicPeak Area (A-s): -0.005Background Pk Area (A-s): 0.801Blank Corrected Pk Area- (A-s): -0.009Concentration (ug/L ): -2.1

Replicate 2Peak Area (A-s): 0.006Background Pk Area (A-s): 0.805Blank Corrected Pk Area (A-s): O.002Concentration (ug/L ): 0.5

Mean Cone (ug/L ): -0.3

Time: 10:21Peak Height (A): 0.184Background Pk Height (A): 2.149

Time: 10:23Peak Height (A): 0.396Background Pk Height (A): 2.111

SO: 1.83 RSD(%): 235.4

As ID: AS Position 32mIPS-m$ <.h/o)AReplicate 1Peak Area (A-s): 0.114Background Pk Area (A-s): 0.797lank Corrected Pk Area (A-s): 0.110

Concentration (ug/L ): 25.4

Replicate 2Peak Area (A-s): 0.105Background Pk Area (A-s): 0.7SOBlank Corrected Pk Area (A-s): 0.101

Saq. No.: C0266 A/S Pos.: 32 Date: 02/20/

Concentration (ug/L

Mean Cone (ug/L ):

): 23.4

Time: 10:25Pe.ak Height (A): 1.04SBackground Pk Height (A): 1.870

Time: 10:23ak Height (A): 0.603

Background Pk Height (A): 1.907

SD: 1.45 RSD(%): 5.95

As ID: AS Position 33 Seq. No. 00267. A/S Pos.: 33 Date: 02/20/

Peak Area (A-s): 0.032Background Pk Area (A-s): 0.723Blank Corrected Pk Area (A-s): 0.02SConcentration (ug/L ): 6.5

Replicate 2Peak Area (A-s): 0.012Background Pk Area (A-s): 0.735Blank Corrected Pk Area (A-s): 0.009Concentration (ug/L ): 2.0

T i ma : 1 0 : 30Peak Height (A): 0.348Background Pk Height (A):

Time: 10:32Peak Height (A): 0.756Background Pk Height (A):

1.810

1.889

Mean Cone (ug/L . ): 4 .3

. yj<jA,\£ii_\ 'JZ~\ (\<l\«5 /KT)V -'I MO, 371 \i.Wl) \—————^r=r^

U.S. EPA - CLP

2AINITIAL AND CONTINUING CALIBRATION VERIFICATION

Lab Nan*: KJoftrMERiO IftaoftnrpeiSS Contract:

Lab Code: KlLC Case Ho.: Cftffl SAS No.:

Initial Calibration Source:

SDG No.: !<=>

Continuing Calibration Source: EPft - LY

Concentration Units: ug/L

11[Analyte1| Aluminura_j Antimony"I Arsenic| Barium1 Beryllium— 'dmium

icium| cnromiumI Cobalt| Copper|lronILead(Magnesiumj Manganese[Mercury| Nickel^ _j Potassiumj Selenium(SilverI SodiumlThallium_[Vanadium"(Zinc __ ~I cyanide1

Initial CalibrationTrue Found %R(1)

•4T.MX

"5I.1O 10^.1

1

Continuing CalibrationTrue Found *R(1) Found %R(1)

35ZZ

———

x>/m.So IOU.M

>/MM.fe

•<»M.S

H

F

-r

(1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115

FORM II (PART 1) - IN

ill 7/88

U.S. EPA - CLP


Lab Naae:Lab Coda: KH-g

Initial Calibration Source: EPfl - L.V

Continuing Calibration Sourc«:

U\ao*f>TO<lts Contract: Ut-61-Olâ

Case No.: Eftnr> SAS No.: SDG No.:

- L.V


II| AnalyteI| Aluminua_| AntinonyI Arsenic| BariumI Berylliua.'"admiuin

Iciuo| i-nrojniunI CobaltI Copp«rI IronI Lead| Magnesiumj ManganeseI Mercury| Nickel_] _j Potassiun| SeleniumI SilverI Sodium(Thalliun| Vanadium| Zinc ~I Cyanide

Initial CalibrationTrue Found *R(1)

*" '**

I

L/M9.no

•

104,1

Continuing CalibrationTrue Found %R(1) Found *R(1)

MTî/'

4T.SO

'

IO0.9

/,/MM.So

•

'

15.1

____

M

r_

^

(1) Control Limits: Mercury 80-120; Other Metals 90-110; cyanide 85-115


7/RS

U.S. EFA - CLP


Lab Name: Mt>ATH6«io

Lab Code: N(.g Case No.: 6ftmInitial Calibration Source: gpfl - LI/

Contract:

SAS No.: SDG No.: Ifl

Continuing Calibration Source: Cpft - LV


11lAnalyte1| Aluminum_|Antimony_(Arsenic| Barium __1 Beryllium'"••dmium

Icium| chromiumI Cobalt1 Copperllron(Leadj Magnesium(Manganese1 Mercury(Nickel^ _j Potassium| Selenium1 Silver1 Sodium|Thalliun_(Vanadium"IZinc ___( Cyanide

Initial CalibrationTrue Found *R(1)

1 1 ___

Continuing CalibrationTrue Found *R(1) Found *R(1)

^

_3iM_

————

————

/^

H5.(»0•

lo.a •

1

M

F



U.S. EPA - CLP


Lab Name: NORTHERNJ-ABORATORIES___

Lab Code: NLE__ Case No.: ERM_

Initial Calibration Source: EPA-LV__

Continuing Calibration Source: EPA-LV__

Contract: 68-D9-0153

SAS No.: _____ SDG No.: 1A_


Analyte

I Aluminum1 Antimony] ArsenicIBariumIBeryllium

idmium, -alciurn! Chromium: Cobalt1 Copperi IroniLead1 Magnesium1 Manganese! Mercury(Nickel1 PotassiumISeleniumISilver1 SodiumIThalliumi Vanadium:zinc1 Cyanidei

Initial CalibrationTrue Found *R( 1 )

47.4/

50 ".10 105.7'

Continuing CalibrationTrue Found %R( 1 ) Found %R( 1 )

47.4

/I/

49.60 104.6

S

/47.30 99.8

11 .1i MIiINRINRIFINRINR:INR;INRINR!INR:INRINRINRINR;NRINRINRINRINRINRINRINRINRINRINR



7/88

U.S.. ERA - CLP


Lab Name: NORTHERNJ.ABORATORIES___






Concentration Units: ug/L1t11Analyte

! Aluminum_! Antimony_! Arsenic! Barium! "eryllium

dmium _, -alciumI ChromiumICobalt __! Coooer! IronI Lead! MagnesiumI Manganese! MercuryiNickel{Potassium! Selenium_ISilver __! Sodium[Thallium! Vanadium_! Zinc! Cyanidet



47.4

/

/

__ 46.40 _97.9

SI/___ 44.50 93.9

tj M

;NR!NR:F_!NRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR


FORM II (PART 1 ) - IN

s-t7/88

U.S. EPA - CLP




Initial Calibration Source: • EPA-LV__


Contract: 68-09-0153


Concentration Units: ug/L1

1 Analyte

I Alumi num1 Antimony_! Arsenic _1 Barium __!°eryllium

dmium, -dlcium1 Chromium[Cobalt __1 CopperllroniLead1 Magnesium1 ManganeseI Mercury1 Nickel1 Potassium1 Selenium_ISiluer1 Sodium1 Thallium1 VanadiumIZinc1 CyanideJ

Initial CalibrationTrue Found %R( 1 )


47.4/

4<T.90 94.7

/S

46.10 97.3

rI

i M

INRINR1 pINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR



7/88

U.S. EPA - CLP


Lab Name: NORTHERN_LABORATORIES___





SAS No.: _____ SDG No.: 1A.


1

AnalyteiAluminum_' Antimony! Arsenic! BariumiBeryllium

•dmium. jlciumI ChromiumICobalt! Copper1 IronI Lead! Magnesium! Manganese[Mercury _iNickel __iPotassiumI SeleniumISilverI Sodium! Thai 1 ium1 Vanadium1 Zinc1 Cyanide|



47.4

/

v/__ 46.80 _98.7

I/47.20 _99.6

i ti i! MIi i

!NR:INR:!F_!!NR|!NR|INR!INR IINR!INR IINR:INR;INR;INR!INR]INR!INR]INR!INR IINR!INR !INR IINR!INRIINR]i i

(1) Control Limits: Mercury 80-120; Other Metals 90-110: Cyanide 85-115


7/88

U.S. EPA - CLP




Initial Calibration Source: EPA-LV_

Continuing Calibration Source: EPA-LV_



Concentration Units: ug/L1111 Analytei1 Aluminum1 Antimony1 Arsenic1 Barium __'"^ryllium

idmium _; calciumI ChromiumICobalt1 Copper __1 IroniLead1 Magnesium1 ManganeseiMercury _iNickeliPotassium1 SeleniumISiluer1 SodiumiThallium1 Vanadium_1 ZincICyanidei


( 1 ) Control Limits

Continuing CalibrationTrue Found %R( 1 ) Found *R( 1 )

47.4

SL^

50.30 106.1

: Mi|NR~!NRIFINR!NRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR

Mercury 80-120: Other Metals 90-110; Cyanide 85-115


U.S. ERA - CLP


Lab Name: NORTHERNJ.A80RATORIES___



Continuing Calibration Source: EPA-LV.


SAS No .: _____ SDG No .: 1A


1 Analyte

1 Alufni numI Antimony1 Arsenic1 Barium1 Beryllium

idmiumjlcium

1 ChromiumICobaltI Copper1 Iron'.LeadI Magnesium1 Manganese1 Mercury _[Nickel1 Potassium1 SeleniumISilwer1 Sodium|Thallium_1 Vanadium.1 Zinc1 Cyanide1


f

47.4


/,/48.70 102.7

1

Continuing CalibrationTrue Found *R( 1 ) Found %R( 1 )

47.4

/L/48.90 103.2

xf 47.40 100.0

11

! M

INRINRi pINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRi

Mercury 80-120; Other Metals 90-110: Cyanide 85-115


7/88

U.S. ERA - CLP


Lab Name: NORTHERNJLABORATORIES___


Initial Calibration Source: EPA-LV_

Continuing Calibration Source: EPA-LV_




] Analytei1 Aluminum_! Antimony_! Arsenic! Barium __1 Beryllium

'idmiuro. jlcium! Chromium! Cobalt; Copper __,' Iron!Lead! Magnesium', Manganese! MercuryiNickel[Potassium! Selenium! Silver! Sodium|Thallium_! vanadium_! Zinc! Cyanide!

Initial CalibrationTrue Kound *R( 1 )


.

————


47.4//

48.00 101 .3

,i/

___ 48.90 103.2

i M1

INR;NRIFINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR

Mercury 80-120; Other Metals 90-11O; Cyanide 85-115


7/88

U.S. EPA - CLP


Lab Name: NORTHERNJ.ABORATORIES___ Contract: 68-D9-0153

Lab Code: NLE__ Case No.: ERM_ SAS No.: _____ SDG No.: 1A_

Initial Calibration Source: EPA-LV____

Continuing Calibration Source: EPA-LV_____


! Analytei! Aluminum_1 Antimony! Arsenic! Barium1 beryllium

admium, calcium! ChromiumI Cobalt! Copper! IroniLead! Magnesium{Manganese! MercuryiNickel! Potassium[SeleniumISilver! Sodium __|Thallium_! VanadiumIZinc! Cyanide!



——

Continuing CalibrationTrue Found *R( 1) Found %R( 1)

47.4

/L/__ 4 .00 103.4

;t/

__ 47 . 40100.0

Mercury 80-120; Other Metals 90-110; Cyanide 85-115

1

1

i M1

INRINR!F_INRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR


7/88

U.S. EPA - CLP



Lab Coda: NLE__ Case No.: ERM_






1

lAnalyte

! Aluminum! Antimony! Arsenic! BariumIBeryllium

dmium, wdlcium _! Chromium_i Cobalt1 Copper: Iron! LeadiMagnesium! ManganeseiMercurviNickel __iPotassium! Selenium_! Si Ivor! Sodium! Thallium! Vanadium_! ZincICyanide _


47.4

( 1) Control Limits

^

\S49.40 104.2


47.4

/•I/48.10 101.5 47.80 100.8

1

! M

INKINRIFINR!NR',NRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR



7/88

U.S. EPA - CLP


Lab Name: NORTHERN J.ABORATORIES___





SAS No.: _____ SOG No.: 1A_

Concentration Units: uo/L1

1[Analyte

Aluminum_! Antimony_! Arsenic] Barium! Beryl Hum! Cadmium' "ilcium

iromium_! Cobalt _ I! CopoerllronItead! Magnesium{Manganese! MercuryINickel __! Potassium! SeleniumISilver! Sodium!Thallium_! VanadiumIZinc! Cyanide _

Initial CalibrationTrue Found *R( 1)


47.4 47.50 100.2 47.40 100.0

itii MINRINRIFINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR•

(1) Control Limits: Mercury 80-120; Other Metals 90-110! Cyanide 85-115

FORM II (PART. 1) - IN

7/88

U.S. EPA - CLP


Lab Name: NORTHERNJ.ABORATORIES___ Contract: 68-09-0153





! Analyte

! Alumin'jm_1 Antimony! Arsenic _! Barium! Beryllium

idmiumjlcium

I ChroT'ium_1 Cobalt! Copper! IronI Lead! Magnesium! Manganese! MercuryiNickel1 Potassium1 Selenium_[Silver __! Sodium __! Thallium_! Vanadium_! Zinc! Cyanide|


i/_2172.0

__ 948.0

' 1 ) Control Limits

_2053.00

_ 945.40

_94.5

_99.7


i/ ,/_ 2172.0

__ 948.0

_2039.00

_ 920.40

.

_93.9

_97.1

_1981 .00

_ 927.70

J91.2

_97.9


iii

:'• Mi

I'P"}NR!P_INR!NRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR

" FORM II (PART 1) - IN

4.17/88

U.S. EPA - CUP





Continuing Calibration Source: EPA-LV.


SAS No.: _____ 'SDG No.: 1A.


Analyte

AluminumAntimonyArsenicBarium __"eryllium

dmiumâlcium _ChromiumCobaltCooperIronLeadMagnesiumManganeseMercuryNickel __PotassiumSeleniumSilverSodium __Thallium_Vanadium_ZincCyanide


' 1 ) Control Limits

Continuing CalibrationTrue Found^ %R( 1 ) Found %R( I )

_ 2172.0

948.0

_2015.00

911 .10

.

_92.8

_96.1

i M

!P_INR|P_INRINRINRINPINRINRINRINRINRINRI NRINRINRINRINRINRINRINRINRINRINR

Mercury 80-120; Other Metals 90-11O; Cyanide 85-115


7/88

U.S. EPA - CLP







SAS No.: _____ SOG No.: 1A

Concentration Units: ug/Lr1

1 Analyte

1 Aluminum_1 Antimony_1 Arsenic _1 Barium __ISeryllium

dmium _. -alcium1 Chromium_ICobalt __1 Cooper1 IroniLead1 Magnesium1 ManganeseI MercuryiNickel1 PotassiumI Selenium_1 Silver __! SodiumI Thallium1 Vanadium1 ZincICyanide1

Initial CalibrationTrue Founo> %R( 1 )

X

_ 2172.0

__ 948.0

_2054.00

_ 983.80

_94.6

103.8

————

Continuing CalibrationTrue Found *R( 1 ) Found \R( 1 )

_ 2172.0

__ 948.0

_2068.00

_ 959.50

_95.2

101 .2

_2065.00

_ 939.40

_95.1

_99 .1

i

INRIPINRINRINRINRINRINRINRINRINRINRINRINRINC;INRINRINRINR1 MR|NPINRINR

(1) Control Limits: Mercury 80-120: Other Metals 90-110; Cyanide 85-115


llJ7/88

U.S. ERA - CLP



Lab Code: NLE__ Case No.: ERM_ SAS No.:

Initial Calibration Source: EPA-LV_____


Contract: 68-D9-O153

SDG No.: 1A_


1 Analytei! Aluminum_1 Antimony_! Arsenic! Barium! Beryllium

'dmiumi -dlcium _! ChromiumICobalt! Copper __! I'on!Lead! Magnesium! Manganese! Mercury[Nickel1 Potassium! Selenium[Silver! Sodium1 Thallium_! Vanadium_1 Zinc1 Cyanide!


I

—— -

'

Continuing CalibrationTrue Found, %R( 1 ) Found %R( 1 )7 \s

_ 2172.0

___ 948.0

2061 .00

_1010.00

94.9

106.5

_2059.00

949.30

_94.8

100.1

i Mi

IPINRIP-INRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR1 NRINRINRINRINR

(1) Control Limits: Mercury 80-120: Other Matals 90-110; Cyanide 85-115


7/88

U.S. ERA - CLP


Lab Name: NORTHERN_LABORATORIES___ Contract: 68-D9-0153





! Analyte

! Alumi num! Antimony! Arsenic! Barium! Beryl 1 ium

•dmium _, jlcium! Chromium1 Cobalt! CoDDer1 IroniLead[Magnesium! Manganese! MercuryiNickel! Potassium1 Selenium! Silver! Sodium! Thai Hum! VanadiumIZinc! Cyanide[


————


2172.0

__ 948.0

2063.00

_ 968.60

_95.0

102.2

_2080.00

979.70

95.8

103.3

M l

P 'MR!P_'NR!NR !NR !NR !NR 'NR !MR 'NR 1

NR!NR!NR !NR!NR;NR!NR!NR !NR !NR!NR!NR !NR



7/88

U.S. ZPA - CL?

2BCSDL STANDARD FOR AA AND ICP

Lab Naa«:

Lab Code: MLE Case No.: ERfnAA CRDL Standard Source:

ICP CRDL Standard Source:

Contract:

SAS No.:


SDG No.

111I Analyte1| Aluminum| Antinony1 Arsenic1 Barium| BerylliunI Cadmiumalciun

, -hroniun1 Cobalt| Copper1 IronILead{Magnesium| Manganese1 Mercury1 Nickel| PotassiumISeleniua[Silver1 Sodium|Thallium_| Vanadium|2inc1

CRDL S

True

10. o

tandard fc

Found\\

^\— , /ras.s )•

'

1r AA

tR

^•3.0:- ——— -

True

CRDL Sta:InitialFound

idard

*R

for ICPFina]

FoundL*R

FORM II (PART 2) - IN7/88

U.S. EPA - CLP

2BC3DL STANDARD FOR AA AND ICP

Lib Name:

Lab Code: MLE case No.:AA CRDL Standard Source:ICP CRDL Standard Source:

Contract:

SAS Ko.: SDG No.: IA


111lAnalyte1(Aluminum| Antimonyj Arsenic1 Barium| Beryllium1 Cadmium' -"alcium.ironiun

I Cobalt| Copper(Iron[Lead| Magnesium| Manganese1 MercuryI Nickel| Potassium| SeleniumI Silver1 SodiumI Thallium| VanadiumIZinc1

CRDL S

True

10. 0

tandard fo

Found

i_J _, /

( ai.aiu/^^_^s

'

r AA

*R

__f'iis.o~~ ^~

I

True

1

CRDL StaiInitialFound

idard i

*R

tor ICPFina.

FoundL*R

FORM II (PART 2) - IN7/88

U.S. EPA - CLP

2BCRDL STANDARD FOR AA AND ICP



AA CRDL Standard Source: SPEX_______

ICP CRDL Standard Source: __________




1

! Analyte

! Aluminum_! Antimony_! Arsenic] Barium __! Beryllium

idmiumjlcium

! Chromium! Cobalt! Copper __! IroniLead! Magnesium! Manganese! Mercury _iNickel! Potassium1 Selenium! Silver! Sodium!Thallium_', Vanadium1 Zinc!

CRDL Standard for AA

True Found %R

10.0

VL/

25.10 3>

CRDL Standard for ICPInitial Final

True Found %R Found %R


7/88

U.S. ERA - CLP







SAS No.: _____ SDG No.: 1A


Analyte

AluminumAntimonyArsenicBariumberylliumadmium

CalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZinc

CRDL £

True

10.0

standard fc

Found

14.20

r AA

*R

4152 :o>~-=a-X

True

.

CRDL StarInitialFound

idard f

*R

or ICPFinal

Found %R

5S

It ; T - & ( 4&, 5'/*/

ice.,

' AJCfO pt-ni'-TsFORM II (PART 2) - IN

7/88

U.S. EPA - CLP







SAS NO .: _____ SDG No . : 1A_


Analytei»! AluminumAntimony_! Arsenic! Barium! Beryllium

dmium, jlcium! Chromium! Cobalt1 Copper! Iron!Lead! MagnesiumManganese! MercuryiNickel! Potassium|Selenium_1 Silver! SodiumIThallium! VanadiumIZinc|


True Found %R

10.0 12.60 <£J26~.o;

_____



10- - - AJ«


7/88

U.S. ERA - CLP

3BLANKS





Preparation Blank Matrix (soil/water): SOIL_

Preparation Blank Concentration Units (ug/L or mg/kg ):fMG/Ki

Analyte

I Alumi numi Antimony! Arsenic

•r ium, -eryllium1 Cadmium1 Calcium! Chromium! Cobalt1 Copoer! Iron'LeadMagnesiumManganese! MercuryiNickel! Potassium! Selenium! Silver! Sodium|Thallium_! Vanadium! ZincICyanidej

InitialCalib.Blank(ug/L) C

26.0

49.0

U

U

-

~"

~~

j

Continuing CalibrationBlank (ug/L)

1 C 2 C 3 C

26. 0

49. 0

U

u™

E

26.0

49.0

U

U

'

-

26.0

49.0

U

U

-

-

-

-

Prepa-rationBlank— ——— 1~

__ (.25.327

9.159

C

>U

-

-

-

1 M

IPINRIPINR]NRINRINR|NR_!NRINRINR"INRINRINR!NR_INR.INR"INRINP"INRINRINRINRINRi

FORM III - IN7/88

U.S. EPA - CLP

3BLANKS




SAS No.: _____ SOG No.: 1A.

Preparation Blank Matrix (soil/water): SOILX"rNPreparation Blank Concentration Units (ug/L or mg/kg):( MG/KG)

1 Analyte

I Alumi num_1 Antimony,' '-senic

.r ium1 BerylliumI Cadmium• Calcium1 Chromium.1 Cobalt1 Cooper1 1 r o nHead1 MagnesiumiManganese1 MercuryINickel1 Potassium1 Selenium_! Silver1 Sodium1 Thallium,' Vanadium1 Z i noICyanide;


26.0

49.0

U

U

—

•


1 C 2 C 3 C

—— $1 ,49.0

Bw

U

-

) 26.0

49.0

U

U

-

-

26.0

49.0

U

U

-

-

-

-

-

Prepa-ration]Blank/ C

_L_30.100'-- —— --"9.800

J,

U

-

-

-

1

t

IPINR1 °|NR_INR.

|NR~INRINRINRINRINRINRÎNR|NR_INRINRINRINRINRINR|NR_|NR_

FORM III - IN7/8=1

U.S. EPA - CLP

3BLANKS



Preparation Blank Matrix (soil/water): _



Preparation Blank Concentration Units (ug/L or mg/kg):

1 Analyte

1 Aluminum_1 Ant imony_1 Arsenic

sriumêryl Hum

1 Cadmium1 Ca 1 cium. _.' Chromium1 Cobalt. .' Copoer1 Ii-oniLeadI Magnesium1 Manganese1 MercuryiNickel1 PotassiumI 3elenium_ISilver1 SodiumiThallium1 Vanadium_IZincICyanide!


-

-

-

_


1 C 2 C 3 C

26.0

49.0

U

U

-

26.0

49.0

U

U

-

-

-

26.0

49.0

U

U

-

---

---

Prepa-rationBlank C

-

-

-

-

-

-

11

! M1! D

!NR_IPINRINP.|NR_! NP._INR..INRINR."INPINRINRINRINRINR.|NR_:NR_INR.INR|NR_|NR_INR|NR_i

FORM III - IN7/88

U.S. EPA - CLP

3BLANKS

tab Name: NJoRTHegO Contract:SAS No.:Lab Code: K]L£ Case No.: ERng

Preparation Blank Matrix (soil/water):Preparation Blank Concentration Units (ug/L or ng/kg) W

SDG No.

1111I Analyte1| Aluminum_j Antimony"j Arsenic| Barium• •'erylliumidmium| Calciumj ChromiumI Cobalt ~I Copper(Iron(Lead(Magnesiumj ManganeseI Mercury(Nickel __j Potassium(Selenium(Silver ~j Sodium(Thalliumj Vanadium(Zinc1 Cyanide1

InitialCalib.Blank(ug/L)

J.o

c

u

~_

I

~


1 C 2 C 3

3.0 y

I

II_

II_

3.0 U

_

c

~_

I

1Prepa-rationBlank

V=^V^ ^r

C

~

~

K

f

TORK III - IN

(.(T

7/88

U.S. SPA - CLP

3BUNKS

Lab Name: KjoftTHeao

Lab code: NIE Case No.: EBng

Preparation Blank Matrix (soil/water): SOIL.

Preparation Blank Concentration Units (ug/L or ng/kg)

Contract: Ul-M-oig3

SAS No.: SDG No.

1111I Analyte1| Aluminum_|Antinony_1 Arsenicj Bariumerylliunadmium

j Calcium| ChromiumI Cobaltj Copper(Iron[Leadj Magnesium(Manganese1 MercuryI Nickelj Potassium(SeleniumI Silver ~j Sodium(Thallium(Vanadium(ZincI Cyanide1

InitialCalib.Blank(ug/L)

3.0

C

u

Iz~


1 C 2 C 3

VO uI

~__

~

~

~

5.0 SI

~

I

I

3.0

C

5

I

Prepa-rationBlank

O.LJO

C

tt

M

E_

FORM III - IN

f.Q

7/88

U.S. EPA - CLP

3BLANKS




SAS No .: _____ SDG No .: 1A

Preparation Blank Matrix (soil/water): ____


1

Analyte

1 Aluminum1 Antimony1 Arsenic

rium, erylliumI Cadmium1 Calcium[ChromiumICobalt1 Copper! Iron[Lead1 Magnesium1 Manganese1 MercuryiNickel1 Potassium1 Selenium1 Silver1 Sodium1 Thallium_1 Vanadium!Zinc1 Cyanide|


3 .0 U

-


1 C _ 2 C 3 C

3.0 U

-

-

-

-

3.0 U

-

-

-

3.0 U

-

—

Prepa-rationBlank C

-

-

-

I

11

! M

!NR_!NR_j pINR|NR_!NR_INRINRINR|NR_INR|NR_INR|NR_|NR_|NR_|NR_INRINRINR|NR_INR|NR_INR•

FORM III - IN7/88

U.S. ERA - CLP

3BLANKS







1t

11

1 Analyte

Aluminum_! Antimony' Arsenicarium

, deryllium1 Cadmium1 Calcium[ Chromium_! CobaltICocoer1 IroniLead1 Magnesium1 Manganese1 Mercury[Nickel! Potassium1 Selenium[Silver! Sodium!Thallium_[Vanadium!Zinc1 CyanideJ


—

-

-

-

_


1 C 2 C 3 C

3.0 U

_

3.0 U

-

3.0 U

-

-

-

-

Prepa-rationBlank C

_

_

-

-

111I

! M1

!NR_!NR_IF|NRINR;NRINRINRINRINRINRINRINRINRINRINR|NR_|NR_INRINRINRINRINR|NR_t

FORM III - IN7/88

U.S. EPA - CLP

3BLANKS



Preparation Blank Matrix (soil/water):


SAS No .: _____ SDG No .: 1A


Analyte

Aluminum_AntimonyArsenic

riumoerylliumCadmiumCalciumChromiumCobalt •CopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

InitialCalib.Blank( ug/L ) C

-

-

-

_


1 C 2 C 3 C

3.O U

-

_

3.0 U

-

-

-

3.0 U

-

-

-

-

Prepa-rationBlank C

-

-

-

-

-

-

11

! M

|NR_INRIFINRINRINRINRINR|NR_INR|NR_INRINR_INRINRINRINR|NR_INRINR|NR_INRINRINR

FORM III - IN7/88

U.S. EPA - CLP

3BLANKS






Preparation Blank Concentration Units (ug/L or mo/kg):

1••1

Analyte

1 Aluminum_1 Antimony1 Arsenic! "irium

rylliumIcadmium _1 CalciumIChromiumI Cobalt1 Copper1 IroniLead1 MagnesiumI Manganese1 MercuryiNickel1 Potassium1 Selenium_1 Silver1 Sodium1 Thallium_1 Vanadium_! Zinc1 Cyanide|


——— —ij*-"

f 3.2V^_ __ _

— .B

-

-

-

-


1 C 2 C 3 C

- ^) 3.0^^ u

-

3.0 U

-

-

3.0 U

-

_

-

Prepa-rationBlank C

-

-

-

-

\1

1

I ..

INRINRIF|NR_1NR_|NR_INRINR|NR_INRINRINRINRINR'NR_INR|NR_|NR_|NR_|NR_INRINRINR|NR_i

FORM III - IN

1 I

7/88

U.S. EPA - CLP

3BLANKS


Lab Code: NLE__ Case No.: ERM_ SAS No.: ____ SDG No.: 1A_


Preparation Blank Concentration Units (ug/L or mg/kg): ____

1

1

1 Analyte

1 Aluminum_1 Antirrony_! Arsenic'~ir ium

jryllium1 Cadmium1 Calcium,'Chromium_ICobalt1 Copper1 IroniLead1 MagnesiumI Manganese1 MercuryiNickel1 Potassium1 Selenium1 Silver1 Sodium1 Thallium,1 VanadiumIZinc1 Cyanide1


-

-

-

-


1 C 2 C 3 C

3.0 U

™

~~

3.0 U

-

_

3.0 U

—

-

-

Prepa-rationBlank C

-

-

-

_

-

-

1! M

|NR~INRIFINR!NR_|NR_INRINRINRINRINR|NR_INR|NR_INRINRINRINRINRINR"|NR_|NR_INR!INR^

FORM III - IN

id

7/88

U.S. EPA - CLP

3BLANKS

Lab Name: NORTHERN_LA80RATORIES___





Preparation Blank Concentration Units (ug/L or dig/kg):

11Analyte

I Alufni num1 Antimony! Arsenic

irium, jeryl Hum1 Cadmium1 CalciumIChromium1 Cobalt! Copper1 IroniLead1 Magnesium1 Manganese(MercuryiNickel1 PotassiumISeleniumISiluer1 SodiumiThallium1 VanadiumIZinc1 CyanideI


3.0 U

-

-

-


1 C 2 C 3 C

3.0 U

-

-

3.O U

-

-

-

-

-

3.0

-

U

-

-

-

-

Prepa-rationBlank C

-

-

-

-

-

-

-

111

! M

INKINRIFINRINRINRINRINRINRINRINRINRINRINRINR|NR_INRINRINR|NR_|NR_|NR_|NR_INRt

FORM III - IN7/88

U.S. EPA - CLP

3BLANKS





SAS No .: _____ SDG No . : 1A


1

1 Analytei1 Aluminum1 Antimony1 Arsenic

iriumjryllium

1 Cadmium1 Calcium1 Chromium1 Cobalt1 Copper1 IroniLead1 Magnesium1 Manganese1 MercuryiNickel1 Potassium1 SeleniumISilver1 SodiumiThallium1 VanadiumIZincICyanide1



1 C 2 C 3 C

3.0 U

——

-

-

-

Prepa-rationBlank C

-

-

-

-

—

: MINRINRIFINRINRINRINRINR!NRINRINRINRINR|NR_INR|NR_INRINR|NR_INRINRINRINRINRt

FORM III - IN7/88

U.S. EPA - CLP

ICP INTERFERENCE CHECK SAMPLE

Lab Name: NORTHERN_LABORATORIES___ Contract: 68-09-0153

Lab Code: NLE__ Case No.: ERM_ SAS No: _____ SDG No.: 1A.

ICP ID Number: JA 9000____ ICS Source: EPA0689____


TrueSol. Sol.

Analyte A ASt', Aluminum_! Antimony_] Arsenic! Barium! Beryl lium! Cadmium! Calcium' ChromiumiCobalt! Copper! IronItead! MagnesiumI Manganese! MercuryiNickelI Potassium! SeleniumISilver! Sodium!Thallium_! VanadiumIZinc!

481000

0

_4697OO

0

Initial FoundSol. Sol.

A AS , %RS -/

_507100

1549

_503800.0

1466.0

107.3

Final FoundSol. Sol.

A s AB ^ %Ri/ ^^

_5 13600

1421

_511700.0

1376.0

108.9

FORM IV - IN

7/88

U.S. EPA - CLP


Lab Name: NORTHERN_LA80RATORIES___

Lab Code: NLE__ Case No.: ERM_ SAS No:

ICP 10 Number: JA 9000____ ICS Source: EPA0689.


____ SDG No.: 1A.


True! Sol. Sol.! Analyte A AB

Aluminum_! Antimony1 Arsenic! Barium[Beryl lium1 Cadmium _! Calcium _! Chromium.Cobalt! Copper1 IroniLead[Magnesium! ManganeseMercuryiNickel1 Potassium! SeleniumISilver! Sodium! Thallium1 Vanadium1 Zinc|

481000

0

_469700

0

Initial FoundSol . Sol .

A AB %Ri^ _s_5 12800

1448

_503700.0

1407.0

107.2


A AB %R

_492700

1392

_488900.0

1431 .0

104.1

FORM IV - IN

7/88

U.S. EPA - CLP

5ASPIKE SAMPLE RECOVERY

EPA SAMPLE NO .

Lab Name: NORTHERN_LABORATORIES. Contract:68-D9-0153 3A

Lab Code: NLE_

Matrix: SOIL

Case No.: ERM_ SAS No.: SDG No.: 1A_

Level (low/mod): _LOW_

% Solids for Sample: _67.3

Concentration Units (ug/L or mg/ka dry weight): MG/KG11

Analyte

1 AluminumI Antimony1 Arsenic1 Barium1 Beryllium1 Cadmium

ilcium, -nromiumICobalt1 Copper1 IronI LeadI MagnesiumI Manganese1 Mercury1 Nickel1 PotassiumI Selenium1 Silver1 SodiumiThalliumI VanadiumIZincI Cyanide1

ControlLimit

75-125

Spiked SampleResult (SSR)

201664.1902

987.8158

C

i>

SampleResult (SR)

x237741.4562

716.1961

CSpike

Added ( SA )

59435.36

297.18

%R

91 .4

i ii ii i

Q! MI) IP !

INR !IP :INR!INR!INR!!NR!INR!INR:INR!INR;INR:INR!INR:INR!INR:INR!INR!INR:INR;INR!INR;INR;INR!i i

Comments: Al -

FORM V (Part 1) - IN 7/88

U. S. SPA - CLP


EPA SAMPLE HO.

Lab Name: MoftTHSftNl

Lab Code: NILE

Matrix: SOIL

Case Ho.: Cftm

Contract:

SAS No.: ___ SDG Ho.: I ft

Level (low/med):

* Solids for Sample: go."I

Concentration Units (ug/L or ag/kg dry weight):

Analyte

Aluminumj AntinonyArsenicBarium| BerylliuB'.Cadmium

ilciiaa, -nrcmiua1 CobaltI CopperIronLeadMagnesium(Manganese1 Mercury[NickelI PotassiumSeleniun

1 SilverSodium

I ThalliumI VanadiumIZincj Cyanide1

ControlLimit4R


/-|*.aua? v/

c

fSanple

Result (SR)

l<4. TITi

c

y

SpikeAdded (SA)

<n.fa

*R

So.o

Q

111

«l

P

Coaoents:

FORM V (Part 1) - IN

0. S. EPA - CLP


EPA SAMPLE NO.

L»h Name: WORTH CUM LflSoRpiToais j

Lab Code: MLF Case No.: EH"Matrix: ôn.

Contract: t/f-M-ops-4 1 ^6C- S1

•> SAS No.: SDG No.: IftLevel (low/aed) : '-ocO

111

* Solids for Sample: UU.5

Concentration Units (ug/L or ag/kg dry weight):

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumIciumnromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

ControlLimit*R

" ~


/-m. 6i?a v

.

c7*

SampleResult (SR)

Q.aîa

c

M

SpikeAdded (SA)

Sl.-lto

..

*R

<M.S

Q M

F

.

Comnents:

FORM V (Part 1} - IK

U.S. EPA - CLP


EPA SAMPLE NO.

Lab Name: NORTHERN_LABORATORIES_ Contract:68-09-0153 2A

Lab Code: NLE_

Matrix: _SOIL.

Case No.: ERM_ SAS No .: SDG No . : 1A

Level (low/med): _LOW_

Solids for Sample: _73.5

Concentration Units (ug/L or mg/kg dry weight): MG/KG

1f

! Analyte

1 Alumi num! AntimonyI Arsenic! Barium! Beryllium! Cadmiumilciumnromium

ICobaltICooperI Iron1 Lead! MagnesiumI Manganese! MercuryiNickelI Potassium! SeleniumI Silver1 Sodium! Thall ium! Vanadium! Zinc1 Cyanide!

ControlLimit%R

75-125


261759.4046

775.1613

CSample

Result (SR)

225454.5454

617.1923

CSpike

Added (SA)

46514.33

232.57

%R

78.1— ,*• ——

r £+7 Q

IIIi

Q ' M

IP| NR

^1 pÎNR

INRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR;

Comments:


A~.O Nam«:

U.S. EPA - CLP

DUPLICATES

contract:

EPA SAMPLE NO.I————I Ift b I

Lab Code: NJLE Case Ho.: ERm

Matrix (soil/water) : son-* Solids for Sample: So."!

SAS Ho.: _____ SDG Ho.: Ift

Level (low/ned): uouJ* Solids for Duplicate: So. "I

Concentration Units (ug/L or ng/kg dry weight) :

11JAnalyte1| Aluminumj Antimony(Arsenic1 Barium(Beryllium1 Cadmium[Calciumj Chromium1 Cobalt1 Copper(Iron(Lead| Magnesium(Manganese(Mercury[Nickel(Potassium(Selenium(Silver(Sodium(Thallium(Vanadium(Zinc(Cyanide1

ControlLimit Sample (S)

IM. -111!

c

u

_

Duplicate (D)

/'«. 11.5-1 '

.

c

u

RPD

. — ,I •ft+He- \\ )" — *"

11 *1

Q M

r

FORM VI - IN

7/88

EFA SAMPLE NO.I—————————————! 966 b

U.S. EPA - CLP

6DUPLICATES

Name: ..KJoftTHERiO CflaoRftToeies Contract: l«3-fr'

Lab Code: Mt-g case No.: Eftm SAS No.: ____ SDG No.:Matrix (soil/water): So It- Level (low/Bed):

* Solids for Sample: lp(j.6 % Solids for Duplicate:

Concentration Units (ug/L or ag/Xg dry weight):

1(Analyte1(Aluminumj AntimonyI Arsenic1 Barium(Beryllium1 Cadmium(Calcium| Chromium(Cobalt1 Copperllron(Lead(Magnesium(ManganeseI Mercury(Nickel(Potassium(Selenium(Silver1 Sodium| Thallium(VanadiumIZinc(Cyanide1

ControlLimit

1Sample (S)

ta. 9913

c

-uDuplicate (D)

————————— ,13. 4IOS "

III I

C| | RPDII

/ l lI I

UllI II II II II II II II II II II II II II II II II II IMI II II I

Q M

F

FORM VI - IN

7/88

U.S. EPA - CLP

'6DUPLICATES

EPA SAMPLE NO.



Matrix (soil/water): SOIL_


2AContract: 68-09-0153


Level (low/med): _LOW_

* Solids for Duplicate: _73.5


i,' Analyte

I Aluminum! AntimonylArsenic1 BariumiBeryllium1 CadmiumICalcium1 Chromium; Cobalt! Copper! IronI Lead! MagnesiumI ManganeseI Mercury(Nickel! PotassiumI SeleniumISiluer! SodiumiThallium! VanadiumIZincI CyanideI


225454.5454

617.1923_

C

•

^

Duplicate (D)

230307.2953"

618.1093

C

•

v<

RPD>

2 .1>

0.1

1 11 1

Ql Ml

IP 1INR!IP 1INR!INR!INRIINR!INRIINR!INR!INR!INR:|NR|INR!INR;INRIINR;INR|INR;INR|INR!INR!INR;

FORM VI - IN7/88

U.S. EPA - CLP

ERA SAMPLE NO.DUPLICATES





3AContract: 63-09-0153


Level (low/med): _LOU_

Solids for Duplicate: _67.3

Concentration Units (ug/L or mg/kg dry weight): MQ/KG

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide


237741.4562

716.1961

CC/"

JDuplicate (D)

224758.0029

642.8252

C

-0'

^

RPD

5.6

10.8

iii

0! M1

INR1 PINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR

FORM VI - IN7/88

U.S. EPA - CLP

LABORATORY CONTROL SAMPLE

Lab Name: McftTHEftiO LRBoRRTORies Contract:

Lab Code: NILE Case No.: Eftm SAS No.:

Solid LCS Source: EPfi

Aqueous LCS Source:

SOS No.:

iiI Analytei| Aluainuin_I Antimony^1 ArsenicI Barium _j BerylliumI CadmiuD1 Calcium|r-"romiuB| jalt ~1 i-opper[ironILead[Magnesiuaj Manganese[Mercury1 Nickel[Potassium[Selenium[Silver ~[Sodium|Thallium_| Vanadium"1 2inc ___[Cyanide1

Aqueous (ug/L)True found *R

————

SolidTrue Found C

qn.o iuq ,o

""

(ng/kg)Limits *R

U3S.O un«».o 10*. T

FORM VII •- in

7/88

U.S. EPA - CLP


Name: NoftTHgtNj

âb Code: MLg Case No.: 6ft fn

Solid LCS Source: CPfl

\queous LCS Source:

Contract:

SAS Ko.: SD3 No.

iI Analytei1 Alumnum_I Antimony"i Arsenic ~! BariumI Beryllium; Cadmiumi Calcium! Chromium' 'salt ~l^^pperI IroniLead ____| Magnesium| Manganese1 MercuryI NickelI PotassiumI Selenium1 SilverI Sodium|Thallium_I Vanadium"I ZincI Cyanide1

Aqueous (ug/L)True Found %R

•

SolidTrue Found C

«>n.o •us. 9

I

I

~_

"_

1(ag/kg) |

Limits tR

03S.O ll^.O

, •

ST. a

———

FORM VII - IN

7/88

U.S. EPA - CLP




Solid LCS Source: EPA0387____

Aqueous LCS Source: __________


SAS NO.: _____ SOG No.: 1A

1

Analyte

Aluminum_Antimony_' Arsenic! Barium1 Beryllium! Cadmium

ilciumt ~nromiumi Cobalt! Copper! IroniLead[Magnesium! Manganese! MercuryiNickel! Potassium1 SeleniumISilver! Sodium;Thallium_1 Vanadium!Zinc! Cyanide


Solid (mg/kg)True Found C Limits %R

__ 325.0

917.0

350.4

9O9.6

s

?--

-

225.0

635.0

424.0

1199.0

107.8

99 .2

11111

FORM VII - IN7/88

U.S. EPA - CLP








11

lAnalyte

! Aluminum_! Antimony[Arsenic! Barium __1 Beryllium'• radmium

ilcium, chromiumICobalt! Copper! IroniLead! Magnesium1 Manganese! MercuryiNickel! Potassium! SeleniumISilver! Sodium!ThalHum_! Vanadium!Zinc1 Cyanide _

Aqueous ( ug/L )True Found %R

.


__ 325.0

_ .917.0

329.0

_ 1013.5

-

-

——

225.0

635.0

__ 424.0

1199.0

101 .2

110.5

FORM VII - IN7/88

U.S. EPA - CLP

10, Instrument Detection Limits (Quarterly)

_^D Name: NORTHERNJ-ABORATORIES___ Contract: 68-09-0153

Lab Code: NLE__ Case No.: ERM_ SAS No.: _____ SDQ No.: 1A_

ICP ID Number: JA_900O____ Date: 01/22/91

Flame AA ID Number : __________

Furnace AA ID Number : __________

Analyte

I Alumi num1 Antimony1 Arsenic1 Barium1 Beryllium1 Cadmium1 CalciumIChromiumICobalt1 CooperI IroniLead1 Magnesium1 Manganese1 Mercury1 NickelI Potassium1 SeleniumISilver1 SodiumiThallium! Vanadium1 Zinc1

Wave-length(nm)

308.22

193.70

_

Back-ground

CRDL(ug/L)

2006010200

^5000

105025100

5000150.240

5000510

500010SO20

IDL !( ug/L ) 1 M

26.0 IPINR

49.0 IPINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR1

Comments:

FORM X - IN

U.S. EPA - CLP

10' 'Instrument Detection Limits (Quarterly)

Lab Name: NORTHERNJ-A80RATORIES___ Contract: 68-D9-0153


ICP ID Number: __________ Date: 01/22/91


Furnace AA ID Number : PE_5100PC__

111

1 Analyte

1 Aluminum[Antimony1 Arsenici Barium! Beryllium1 Cadmium1 Calcium1 Chromium! Cobalt1 Coooer1 IroniLead! Magnesium1 ManganeseI MercuryiNickelI Potassium1 Selenium1 Silver1 SodiumiThalliumt VanadiumIZinc

Wave-length(nm)

193.70

Back-ground

BZ

CRDL(ug/L)

2006010

55

50OO1050251003

5000150.240

500O510

5000105020

1

IDL !(ug/L) ! Mi

!NR!NR

3.01FiNRINRINR!NRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR

Comments:

KORM X - IN

U.S. EPA - CLP

11AICP Interelement Correction Factors ( A n n u a l l y )

Lab Name: NORTHERNJ-ABORATORIES___ Contract: 68-D9-0153


ICP ID Number: JA 9000____ Date: 01/11/91

11

! Analytei! Aluminum1 Antimony_1 Arsenic! Barium! Beryllium! Cadmium! Calcium! Chr omium_"obalt

jpperi IroniLead! Magnesium! Manganese! MercuryiNickel1 Potassium! Selenium!Silver __! Sodium_._iThallium! Vanadium!Zinc

Wave-length(nm)

308.22_206.83 _193.70493.41313.04 _. .226.50317.93267.72 _228.62324.75 _259.94220. 3O279.08_257.61 _

231.60_766.49 _

328.07_589.00 _

292.40213.86

Interelement Correction Factors for : !

0000000000-000.0

00

0_0

00

Al

.0000000

.0000000

.0015368

.0000000

.0000000

.0000000

.0000000

.0000000

.0000000

.0000000

.0003940

.OOOOOOO

.OOOOOOO

.0000000

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

! o!_o! o! o! oi 0! o! 0: o! o! o! o! o!_o1

! 0!_oI! o!_01

! o: oi

Ca

.0000000_

.0000000_

.OOOOOOO

.OOOOOOO

.0000000_

.0000000_

.OOOOOOO

.0000000_

.OOOOOOO

.0000000_

.OOOOOOO

.OOOOOOO

.OOOOOOO

.ooooooo_

.OOOOOOO

.ooooooo_

.OOOOOOO

.0000000_

.OOOOOOO

.OOOOOOO

0000000_000000..0

00

0.0

00

Fe

.0000000!

.0000000!

.0003451 !

.0000000!

.0000000!

.0000000!

.0000000!

.0000000!

.0000000!

.0000000!

.0000000!

.0000000!

.OOOOOOO!

.OOOOOOO![

.0000000!

.OOOOOOO![

.0000000!

.0000000!1

.OOOOOOO!

.OOOOOOO!

00_0_00_0_00,0_0o000

,0_0

0_0

0o

Mg

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

.OOOOOOO

! o_0! 0:_o!_0!_0! o! o! o! 0! o! 0! 0! _0J! o! o1! 0! o1

! o! o

1t

CR !!

.OOOOOOO!

.0017572!

.0005659!

.OOOOOOO!

.OOOOOOO!

.OOOOOOO!

.OOOOOOO!

.OOOOOOO!

.OOOOOOO!

.0000000!

.OOOOOOO!

.OOOOOOO!

.OOOOOOO1

.0000000;'

.OOOOOOO!

.OOOOOOO!!

.OOOOOOO!

.0000000!J

.OOOOOOO!

.OOOOOOO!

Comments :

FORM XI (Part 1) - IN 7/88

U.S. EPA - CLP

11BICP Interelement Correction Factors (Annually)




1

! Analyte

! Aluminum! Antimony! Arsenic! Barium1 Beryllium! Cadmium! Calcium! ChromiumICobalt' "opper

•on; Lead! Maanes ium! Manaanese! MercuryiNickel! Potassium1 Selenium! Silver1 SodiumIThallium! Vanadium!Zinc!

Wave-length(nm)

308.22206.83 "193.70493.41313.04226.50317.93267.72228.62324.75259.94220.30279.08257.61

231 .60766.49

328.07589.00

292.40213.86

Interelement C

CU_ MN_

0.0000000! 0.00000000.0000000! 0.00000000.0000000! 0.00000000.0000000! 0.00000000.0000000! 0.00000000. OOOOOOO! 0.00000000.0000000! 0.00000000. OOOOOOO! 0. OOOOOOO0 . OOOOOOO ! 0 . OOOOOOO0 . OOOOOOO ! 0 . OOOOOOO0.0000000! 0.00097640.0000000! 0. OOOOOOO0. OOOOOOO! 0. OOOOOOO0.0000000! 0.0000000

1

C. OOOOOOO! 0. OOOOOOO0.0000000! 0.0000000

1

0 .OOOOOOO ! 0 .OOOOOOO0 .OOOOOOO ! 0 .OOOOOOO

1

0.0000000! 0.00000000.0003439! 0.0000000

1

orrection Factors for :

NI_ V _ __

0.0000000! 0.0020894!O. OOOOOOO! 0.0000000!O. OOOOOOO! O. 0020262!O. OOOOOOO! 0. OOOOOOO!0. OOOOOOO! 0.0000000!0 . OOOOOOO ! O . OOOOOOO !O. OOOOOOO! 0.0000000!-O.O002500! O. OOOOOOO!0. OOOOOOO! O. OOOOOOO!0. OOOOOOO! 0.0000000!0. OOOOOOO! 0. OOOOOOO!-0 . 0045230 ! 0 . OOOOOOO !0 . OOOOOOO ! 0 . OOOOOOO !0 . OOOOOOO ! 0 . OOOOOOO !

! ;0 . OOOOOOO ! 0 . OOOOOOO !0. OOOOOOO! 0. OOOOOOO!

I r

0. OOOOOOO! 0. OOOOOOO!0. OOOOOOO! 0. OOOOOOO!

1 1

0.0000000! 0.0000000!O. OOOOOOO! 0.0000000!

! !

Comments'

» FORM XI (Part 2) - IN

U.S. EPA - CLP

12TCP Linear Ranges (Quarterly)


Lab Code: NLE__ Case No.: ERM_ SAS No.: _____ SDG No.


1A

1

! Analyte

! Aluminum! Antimony! Arsenic! Barium! Beryllium! Cadmium! Calcium! Chromium! Cobalt! Coooer! IroniLead! Magnesium! Manganese! MercuryiNickel! PotassiumISelenium[Silver! Sodium! Thallium! VanadiumIZinc!

tiInteg. jTime !(sec.) !i

5.00!5.00!5.00!5.00!5.00!5.00!5.00!5.00!5.00!5.00!5.00!5.00!5.00!5.00!

1

5.00!5.00! i5.00!5.00!

I5.00!5.00!

•

Concentration( ua/L )

700000.0300000.0500000.0100000.0100000.0300000.0-400000.0300000.0500000.030000O.O300OOO.O800000.01000000.0200000.0

sooooo.o1000000.0

200000.0500000.0

200000.0200000.0

M

NR

NR

NR

Comments:

FORM XII - IN

U.S. ERA - CLP

13PREPARATION LOG


Lab Code: NLE__ Case No.:_ERM_

Method: P


SAS No.: _____ SDG No.:lA_

: EPA! Sample! No.i!10AilOBHocI11A! US!11C!1A!1Blie!2A!2A 0i2A S!2Bi2C!3A!3A D!3A S!3B ______!3C!4B!5A!5BI5BFDI9BCILCSS1LCSSiPBSIPBSi

i

PreparationDate

02/15/9102/15/9102/15/9102/15/9102/15/91_02/15/91 _02/15/9102/15/9102/15/9102/15/9102/15/9102/15/9102/15/9102/15/9102/15/9102/15/91_02/15/91_02/15/91 _02/15/9102/15/9102/15/9102/15/9102/15/9102/15/91_02/15/91 _02/15/9102/15/9102/15/91

Weight(gram )

1.070.931.041 .051 .08

_ 1 .01 _1 .011 .020.971 .101 .161 .171 .021 .011 .001 .031 .001 .061 .181 .081 .011 .081 .141.001 .02

_ 1 .051 .071 .00

Volume(mL)

200200200200200

__ 200 _2OO2OO20020020020020020020020O200200200200200

... 200 _200200200

__ 200 _20O200

FORM XIII - IN 7/88

U.S. EPA - CLP

13PREPARATION LOG



Method: F_


SAS No.: _____ SOS No.:lA_

EPASampleNo.

10A10B10C11A11B11C1AIB1C2A2B2C3A383C485A5B5BFD9BCLCSSLCSSPBSPBS1 A b(A S<<6t 0lie. s

PreparationDate

02/15/9102/15/9102/15/9102/15/9102/15/9102/15/91_02/15/9102/15/91_02/15/9102/15/9102/15/9102/15/91_02/15/9102/15/9102/15/9102/15/9102/15/91_02/15/9102/15/91_02/15/9102/15/91_02/15/9102/15/9102/15/91OS lull 1co / 1 » H ioa/is Hioa/ialVi

Weight(gram)

0.951.011.010.951 .041.081.201 .021 .03

_ 1 .01 _1 .141 .030.961.051 .180.981 .180.980.971 .111.050.971 .011 .00i . ni. atI.OI1. 10

Volume(mL)

2002002002002002002OO200200

__ 200 _2002002002OO20020020020O2002OO200200200200aooaooaooaoo

FORM XIII - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG

Lab Name: NORTHERNJ-ABORATORIES__

Lab Cods: NLE__ Case No.: ERM_

Instrument ID Number: JA 9000____

Start Date: 02/20/91


SAS No .: _____ SDG No .: 1A_

Method: P_

End Date: 02/20/91

EPAAnalytes

! Sample! NO.

!SOISISISISISIICV1 ICVIICBMCSft

1 ICSABIPBSILCSSIM2FS-1AIM2FS-1AIM2FS-1CIM2FS-2CICCV!CCV!CCBIM2FS-2AIM2FS-2A[M2FS-2ADIM2FS-2ADIM2FS-2ASIM2FS-2ASIM2FS-2BIM2FS-1BIM2FS-1B1ZZZZZ: ccvi

D/F I Time', * R {AjSjAlB' ' ' 1 ' R ' C ' Ai i t L i B i 5 t At i i I i i

1.00! 1808! IX! IX!1.0011810! !X! !Xl1.0011812! IX! ix!1. 00!1814| |X| |X|1.0OI1816! !Xl !x!1.0011818! !X! IX!1.0011820! IX! ! 11.0011823! ! 1 |x!1.00! 1826! IX! !Xl1.0011829! !Xl |Xl1.00118321 !x! Ix!1.0011835! IX! !x!1.00!1841| |X| |X|1.0011844! !Xl |X!1.0011847! 1 ! IX!2.0011850! !Xl | 11.00I18S3I IX! !x!1.0011859! IX! |X!i.oo!i90i| |xj ! !1.0011903! 1 ! IX!1.0011905! IX! IX!1.0011908! I ! !x!2.0O!1911| IX! ! I1.0011914! ! ! IXl2.00S1917! IX! ! 11.0011920! ! ! |Xl5.0011923! !x! ! !1.00119261 |Xj |x!1.0O!1929| ! ! |X!2.0011932! !X! ! 11.0011936! 1 ! ! I1 .00119381 IX! I 1

BECDCACRC0CuFEPB

MG

MNHG

NIK SE

AG

NATL

V 2N

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG

Lab Name: NORTHERNJ.ABORATORIES__


Instrument ID Number: JA 9OOO



SAS No.: _____ SDG No.:1A_

Method: P_

End Date: 02/20/91

EPASampleNo.

CCVCCBM2FS-3B_M2FS-3C_M2FS-4BM2FS-4B_M2FS-5AM2FS-5ACRI-CSA;SAB

CCVCCVCCB

1 1

D/F iTimei * Ri ii ii i1.00! 1940!1.0011942!1 .00!1945!1.00! 1948!1.0011951!2.0011954!1.00! 1957!

___ 2 .00 ! 2000 ! ______1.0012005!1 .00! 2003!1.00!201l!1.00! 2013!1.00!2015!1.0012017!| |! ii ii i

i i! ]! !! !! || JI !

i i! !! !

Analytes

AL

X

X

X

S8

-

——

-

AS

XXXXX

X

XX

X

x

BAB£CDCA

Q

RC0CuFEP

BMG

MNHG

NI

K SE

AG

NA

TL

V zN

FORM XIV - IN 7/88

CfQ

U.S. EPA - CLP

14ANALYSIS RUN LOG



Instrument ID Number: JA 900O



SAS No.: _____ SDG No.:lA.

Method: P_

End Date: 02/21/91

EPAAnalytes

! Sample! No.1

:?o| 5ISIsi S!SIICV:icv: ICBii

-CSA! ICSABIPBS: LCSS1M2FS-5BIM2FS-5BIM2FS-3A1M2FS-3A!CCViccv:CCB•>2FS-3AD[M2FS-3AD[M2FS-3AS;M2FS-3AS!M2FS-5BFtiM2FS-5BFt!M2FS-9SC!M2FS-9BC!ccv1CCV!CCB|

D/F iTime! * R !A!S!A|B1 1 1 i 1 p 1 e 1 Ai i i L i a i 5 i A1 1 1 1 1 1

1.0011123! IX! IX!1.0011125! !X! IX!1.0011127! IX! !X!1 .0011129! !X! !X!1. 0011131! !X! IX!1.00I1133! IX! !X!1.0011136! IX! ! !1.0011139! ! ! !X!1.0011142! IX! !X!1.0011145! !X! !X!1.0011148! IX! !X!l.OOlllSl! IX! !X!1.00!11S4! !X! !X!1.0011157! !X! IX!1 .00! 1201! ! ! !X!2.0011204! IX! ! !1.00!l207! ! ! !x!2.0011212! IX! ! !1.COI1214! !x! ! !1.0011216! ! ! !X!1.00!l218! !X! !X!1.0011222! ! ! !x!2.0011225! !X! ! !1.0011228! IX! ! !1.0OI1237! ! ! !x!1.0011240! ! ! IX!2.00! 1243! !x! ! I -1.0011246! ! ! !X!2.0011354! !X! ! !1.0011356! IX! ! !1.0011359! ! ! !x!1.0011401! !X! !x!

BECDCACRC0

CuFEPB

MG

MNHG

NI

K SE

AG

NATL

V Z ! •N \t

<1

• 1'1'!1

t'''<'i<iii'iiciit•tiii'J

FORM XIV.- IN 7/83

U.S* EPA - CLP

14ANALYSIS RUN LOG

_jb Name: NORTHERNJ-ABORATORIES__


Instrument ID Number: JA 9OOO____



SAS No.: _____ SDG No .: 1A.

Method: P_

End Date: 02/21/91

Anal/tea! EPA! Sample! No.iJM2FS-10AIM2FS-10AIM2FS-10BIM2FS-10BIM2FS-10CIM2FS-10CIM2FS-11AIM2FS-11AIZZZZZ!CCV' -cvCB

;M2FS-118IM2FS-11BIM2FS-11C! zzzzzIZZZZZizzzzzIZZZZZIZZZZZIZZZZZIccvIccvICCBIZZZZZ1 ZZZZZIZZZZZ: zzzzzIZZZZZIZZZZZIZZZZZ1 zzzzzt

1 t

D/F !Tim«| * R1 11 1

1.0011404!2.00!l407!1 .001 1410!2.0011413!1.0011416!3.0011419!1.0011422!2.00I142S!1.0011429!1 .00! 1431!1 .00! 1433!1 .0011435!1.0011439!2.0011442!1.00! 1445!1 .00!l449!1 .00! 1452!1.0011502!1.00! 1505!1. 00 ! 1508!1.00!1525!1.00J1527!1. 00! 1529!1. 00! 1531!1. 00! 1534!1 .00! 1537!1.0011540!1.00!l544!1.00!l547!1.00 11550!1.0011601!1. 00! 1604!

AL

X

y

v

X

X

XX

X

X

sB

AS

X

X

X

X

XXX

X

XX

BA3ECD

1

CACRC0

CuFEPB

MG

MNHG

NIK SE

AG

NA

•p^

_

V zN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG

Lab Name: NORTHERN_LABORATORIES__

Lab Code: NLE__ Casa No.: ERM.

Instrument ID Number: JA 9000___




Method: P_

End Date: 02/21/91

EPASampleNo.

ZZZZZ __ccvccvCCBCRIICSAICSABccvccv"CV:a

1

D/F iTime1

___ 1 .00! 16031.0OI16101 .00116121. 00! 16141.00116141.00|1620

___ 1 .00! 1623___ 1 .0011625

1 .00116251 .0011627

___ 1.0011629i

i!i

i

i|iii

iiiiiii!

* R

——————

——————

Analytts

AL

X

XXXXXX

X

sB

-

-

AS

XXXXX

XX

BABEC0CACRC0CuFEPB

MG

MNHGNIK SE

AGNATL

V zN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG



Instrument ID Number: PE S100PC__



SAS No.: _____ SDG NO.:1A_

Method: F_

End Date: 02/18/91

! EPA! Sample! No.i!SO!S10IS25!S50Isioo!ICV! ICB!CRA!OBS

3SA,_cssILCSSA ___|M2FS-1A_IM2FS-1AA1M2FS-1ADIzzzzz _IZZZZZ!ccvICCV!CCB!M2FS-2A_!M2FS-2AA|M2FS-2C_1M2FS-5A|M2FS-1A_|M2FS-4B_!M2FS-2B_!M2FS-3C_IM2FS-1BizzzzzICCV!CCB

1 11 11 1

D/F iTime! * Ri ii ii i1.0010938!1.0010942!1.00! 0947!1.0010952!

___ 1 .00 ! 0957 ! ______1.00!lOO2!1.00! 1007!l.OOilOll!1.0011016!1.0011021! 105. 0

100.0011025!_ 100 .00 ! 103O! _ 114 .0

1 .00! 1035!1 .00!1040!1 -00!1045!

___ 1.0011049! ______1 .0011054!1.0011059!1.00! 1059!1 .00!1104!1.00!1108!1.00!1113!l.OOilllS!1.0011122!1.0011127!1.0011131!1 .0011136!1.00!1140!

___ 1.0011146! ______1.0011155!

___ 1 .00 ! 1203 ! ______1.00! 1208!

i i• i

Analytes

ALS:A|BB|S|Ai i

t y 11 y 1t y 1f y 1

1 y 11 y 11 y I1 y i1 y '1 y 11 y I1 y 11 11 1

1 I

1 y 1

' X '1 y 1

1 1

1 1

| |

f 1

1 1

1 1

1 1

1 »

1 y 11 y 1

BEcDCACRC0cuF£PB

MG

MNHGNIK 5£

AG

NATL

V zN

FORM XIV - IN 7/8S

U.S. EPA - CLP

14ANALYSIS RUN LOG

Lab Name: NORTHERNJ.ASORATORIES__


Instrument ID Number: PE 5100PC__



SAS No.: _____ SOG No.:lA.

Method: F_

End Date: 02/18/91

I ERA! Sample! No.

!SO!S10:S25: sso:sioo! ICVIIC8ICRA|M2^S-3B_?7ZZ.2FS-1A

IM2FS-1AA!M2FS-1ADIM2FS-1AW|M2FS-2A_IM2FS-2AAIzzzzz!CCV!CC8', M2FS-2CIM2FS-2CAIM2FS-1C(M2FS-1CAIM2FS-2B;M2CS-2BAIM2FS-1S1M2FS-18AIZZZZZIZZZZZICCVICCBIM2FS-3Si

i ii i

D/F ITIme! * RI I1 11 |

1 .001154511 .0011550!1.00:1555:1.00:1559:1 .00! 1604!1 .00! 16O9:1 .00! 1614!1.0011618!1.0O!1623!1 .Oo:i628!5.00! 1633!5.00!1637!5.00! 1642!5.00! 1647!5.0011652!5. 00! 1657 i1 .00! 1701!1.00! 17O6!1.0011711!5.0011715:5.00! 1720 i5.0011725!5.00117291 99.55.0O!l734l5.00! 1738!5.0O1 1743i5.0OI1747!1 .0011752!1 .00! 1757!1 .OOllSOl 11 .00! 1806!5.0011811 1

1 !

Analytes

LS|A|BB|S|A

1 1

1 y i

iX!:xi1 y 1

1 y 1

1 y t

ixr1 y 1

1 1

1 1

1 11 1

1 1

t I

! x !1 v '

_IX!IX!I I

| |t I

1 y 1

1 y 1

1 1

! !

BE£

D A^Rc0cu

FEPB

MG

MN^

GNI^ sE

AG

NA

TI

VN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG


Lab Code: NLE__ Case No.t ERM_




SAS No .: _____ SDG No .: 1A_

Method: F_

End Date: 02/18/91

EPASampleNo.

M2FS-3BAM2FS-3C_M2FS-3CAM2FS-4BM2FS-4BAM2FS-5A_M2FS-5AAM2FS-1ASZZZZZ'VCB

1

D/F JTimeiii5.00118155.00118205.0011825

___ 5.00|18305.00|18345.00118395.00118445. 00! 18491 .00118531.00! 18581 .00! 19O3

1

1

1

1

1

|

1

|

1

1

1

1

|

1

1

|

1

1

* R

93.5

——————

——————

——————

Analytes

ALSB

AS

XX

Xy

BA

BECDCACR

C0CuFEPB

MG

MNHG

NI

K SE

AG

NATL

V ZN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG


Lab Cod«: NLE__ Case No.: ERM_





Method: F_

End Date: 02/19/91

! EPA! Sample! No.

ISOIS10IS25ISSOisioo1 ICV! ICBiCRA' TZZT

'.ZZZ! zzzzzIZZZZZ'•ZZZZZ'7.ZZZZ!PSS!°BSAIZZZZZ!CCVICCBILCSS,'LCSSA __!M2FS-58_!M2FS-5B~|M2FS-5B_1M2FS-5B>2FS-5B_!M2FS-5BIZZZZZ! ZZZZZIccv• ccaIM2FS-3A'

1 1t t

D/F iTime! * Ri ii i

1 .0011131!1.0011136!1 .00! 1141!1 .0011146!1 .0011150!1 .00! 1155!1 .00! 1200!1 .00! 12O5!1 .00! 1209!1 .00! 1214!1 .00! 1219!1 .00! 1224!1 .0011228!1 .00! 1233!1.00!l238i1.0011243! 110.01. 00! 1248!1.00!l253!1 .0011257!

100.00il302!_ 100. 00 !1307| __ 93.5__ 15.0011311! ______

12.0O! 1316!10. 00 11320!7.00! 1325!5.0011329!1.00!1334!1.0011338!1 .0011343!1 .0011348!1 .00! 1352!1 .00! 1357!i i

Anal/tes

AL

S!A|BB!S!A

i i

:x[I y I

!x|IX!1 y 1

IX!'x!1 y 1

1 I

1 I1 y 1

1 1

1 y 1

' X '|x|!x[i ii ii i1 ji ii ii ii i

«:x!_ix:_• t

8ECD A R 0 U E B

MG

MN

HG

NI

K SE

AG

NA

TL

y

-

Z!CNlN

I1

I1

;i|1

-;•!''i|i|'!ii

-,'i|iii

ii1

FORM XIV - IN 7/86

U.S. EPA - CLP

14ANALYSIS RUN LOG

Lab Name: NORTHERN_LA80RATORIES__





SAS No.: _______ SDG No.:lA_

Method: F_

End Date: 02/19/91

;' EPA! Sample! No.

!"2FS-5BFtIM2FS-9BCIM2FS-9BO:IM2FS-10AIM2FS-10BIZZZZZIZZZZZIzzzzzIZZZZZ'-cv:a

iM2FS-10CIM2FS-11AIM2FS-11B1M2FS-11CIzzzzzIzzzzzIccvICCBIccv!CC8IM2FS-5B|M2FS-3A_IM2FS-9BCIM2FS-9BCCIM2FS-9BCSIM2FS-10AIM2FS-5BF6IM2FS-10CIzzzzzizzzzzIccv]

i i

D/F ilime! * Ri ii ii i1 .001 1402!1 .0011406!1 .0011411!1 .00!l416!1 .001 1421 !1 .001142611 .0011430!1 .001 143511 .0011440!1 .001144411 .001 144911 .00! 1454!1 .001 1458!

__ 1 .001 1503!1 .00! 1507!1.0011512!1 .001 1516!1 .0011521 !1 .00! 1526!1 .0011546!1 .00! 1551!5. 00! 1556!5.00!1600!5. 00! 1605!5.0011610!5.0011614!5.00! 1619!5.0011624!5. 00! 1629!1.0011634!1 .00! 1639!1 .00! 1643!i i

Analytes

ALsB

AS

XV

XXXX

X

8A8EC0CACRC0CuFEP8

MG

MNHG

NIK SE

AG

NATLy Z

N

-

FORM XIV - IN 7/83

U.S. EPA - CLP

14ANALYSIS RUN LOG

Lab Name: NORTHERN_LABORATORIES___ Contract: 68-D9-0153

Lab Code: NLE__ Case No.: ERM__ SAS No.: _____ SOQ No.:lA.

Instrument ID Numbers PE 5100PC___ Method: F_

Start Date: 02/19/91 End Date: 02/19/91

1 1 I I1 1 I I! EPA ! ! !! Sample ! D/F |Time! * RI No. ! ! !1 1 I I

ICCB ! 1.0011648!|M2FS-11A| ___ 5.00! 1653! ______IM2FS-11B! 5.00(1657!IM2FS-11C! 5.0011702!IM2FS-10B! 5.0O!l7O7!IM2FS-5B ! 10. 00 ! 1711!IM2FS-3A ! 10. 00! 1716!1M2FS-3AA! 10. 00|1720! 84.5! M2FS-9BC ! __ 10 .00 ! 1725 ( ______"ZZZZ I 1.00! 1729!ZZZZ __ ! ___ 1 .00 ! 1734 ,' ______

, CCV ! 1.0011739!ICCB ! 1.0011743!IM2FS-9BC6 10.0O!l748!IM2FS-9BCS 10.0011753!!M2FS-10A! 10. 00! 1757!IM2FS-10A4 __ 10.00! 1802! __ 97.5|M2FS-5BFb! 10. 00 !1807|! M2FS-5BF6& __ 10 .00 ! 1812 ! ______IM2FS-10C! 10.00J1817!IM2FS-11A! 10.00!l822!IZZZZZ ! 1.0011826!IZZZZZ ! 1.0011831!ICCV ! 1.00! 1836!!CCB ! 1.0011840!IM2FS-11B! 10.00!184S!IM2FS-11B4 __ 10.0011849,' __ 87.5IM2FS-11C! 10.0011854!! M2FS-1 iCH ___ 10 .00 ! 1858 ! __ 82 .0IM2FS-10B! 10.00|1903!! zzzzz __ ! __ i .00 ! 1908 ! ____ICCV ! 1.0011912!i i i i

Analytes

ALS!A!BBiSlA

1 1

1 y '

1 1

j |1 11 11 y r

1 u '1 1

I t

1 1

1 •£ 1

| |I |

_!x|' v 'I iI iI II iI I1 i

_!x|1 y 1

_!x|lx|

_!x|_!x|_

1 i1 i1 y 11 1

BECDCACRC0CuFEPB

MGMNHGNIK SE

AG

NATL

V zN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG



Instrument ID Number: PE 5100PC_„



SAS No.: _____ SOQ No.:lA_

Method: F_

End Date: 02/19/91

EPASampleNo.

CCB

D/F

1.00

Time

1917

* R

——————

~~

——————

______

Analytes

ALSB

AS

X

BA

BECDCACR£

0CuFEpB

MG N

HG

NIK SE

AG

NA 1

V zN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG

Lab Name: NORTHERNJ.A80RATORIES__





SAS No.: _____ SDQ No.:lA_

Method: F_

End Date: 02/20/91

1

; EPA! Sample! No.i!SOIS10|S25 ____IS50IS100!ICV!ICB!CRA|M2FS-5B_'M2FS-5BA2FS-5BA

,i12FS-9BCIM2FS-9BO!M2FS-5BFfclM2FS-SBF»IM2FS-10B|M2FS-10B<(!CCVICCBIM2FS-10CIM2FS-10C*IM2FS-11AIM2FS-11A*!M2FS-1A_IM2FS-5AIM2FS-9BCIIM2FS-9BCIIZZZZZizzzzzIccvICCB|M2FS-2A_i

i ii i

D/F JTimei * RI 11 t1 1

1.00! 06591___ 1 .00 ! 0703 ! ______

1.00|0708|1.001071311.0010718!1 .0010723!1.0010727!1.0010732!15.00! 0737!15.00!074l!

__ 15.0010746! __ 94.015.00!075l!

__ 15.0010756! _ 113.5IS.OOiOSOl!

» __ 15.0010805! _ 105.5__ 15 .00 ! 0810 ! ________ 15 .00 ,' 0815 ! __ 99 .5

1 .00! 0820 I1 .0010824!15. 00! 0829!

__ 15.0010834,' _ 111.015.00! 0838!15.00|0843! 115.010.0010847!10. 00! 0852!

__ 15.00! 0856! ______6 __ 15.00|090l! _ 126.0

1.0010906!1.0010910!1.0010915!1 .00! 0920!10.00!0924!

, i

Analytes

AL

SlAlSBiS!A

1 I

|x!1 y 1

_!x!1 v I

!x!_1 y 1

1 w I

1 y 1

1 u '1 1

1 y 1

!x!1 w '

_!x!1 y '

_'x!!x!

_!x!1 v '1 y t

1 u '1 y 1

1 u '

1 1

!x!-!x!i i

i i1 v '

1 y 11 11 1

BE

-

CDCACR

,

C0CuFEPB

MG

MNHG

NI

K SE

AG

NATL

V ZN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG






SAS No.: _____ SDG No.:iA_

Method: F_

End Date: 02/20/91

! EPAI Sample! No.tIZZZZZ,' M2FS-2CIM2FS-2CAIM2FS-2BIM2FS-2BAIM2FS-1BIM2FS-1BAIM2FS-1BA! ZZZZZ'rev

•a...2FS-4B1M2FS-4BA[M2FS-SA!M2FS-5AA|M2FS-1A_1M2FS-1AAiccv!CCBiccvICCB! ZZZZZIM2FS-2AIM2FS-2AA|M2FS-3B_IM2FS-3BAIM2FS-1AD|M2FS-1AD»i ZZZZZIZZZZZIZZZZZIZZZZZ|

i ii ii iD/F ITime! * Ri ii ii i1.00! 0929!10. 00! 0934!10.00|0938| 98.5

__ 10.00|0943| ________ 10.0010948! 115.0__ 10. 00! 0953! ______

10. 00! 0958!__ 10. 00! 1002 I _ 118. 0

, 1.00! 1007!1.00!l012!1 .0011016!

__ 10 .00 1 1021 ! ________ 10. 00 I 1025] _ 122.0__ 15. 00 110301__ 15 .00 ! 1034 ! __ 78 .5__ 15 .00 ! 1039 ! ________ 15. 00 [1044! _ 119.5

1.0011048!1. 00! 1053!1.0011059!1.00!ll04!1 .00!1109!

__ 15.0011113! ________ 15.0011118! 109.0__ 10.0011123! ________ 10.0011127! _ 119.5__ 15.0011132!__ 15.0011137! 111.5

1.0011142!1.0011147!1.0011147!1.0011152!

1 1

An*lyt»«

M

LS1A1BBlSlA

1 1

1 1

1 v *

_:*!_!x!_1 v >

1 v 'I " ii it u '

1 u '

1 v '

!x!_;xi1 u '1 y 1

1 v '

1 v 1

1 y 1

' V '

1 v 1

1 V '

1 v '

'y '1 y 1

1 y 1

1 1

E 0 A R

i

0 U E B GMNHG

NI

| SE

AG

NA

TL

V ZN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG


Lab Cods: NLE__ Case No.: ERM_




SAS No.: _____ SDQ No.:lA_

Method: F_

End Date: 02/2O/91

EPASampleNo.

CCVCCB

D/F

1.001.00

Time

11561201

———

———

* R

——————

_^_^— ___^««

~ ~~

— ————

—————

—————

——————

——————

Anal/tec

AL

•

SB

AS

XX

BA

BECDCACRC0CUFEPB

MS

MNHGNIK SE

AG

NATL

V zN

FORM XIV - IN 7/88

// J

U.S. EPA - CLP

14ANALYSIS RUN LOG



Instrument ID Number: P6 5100PC__,



SAS No.: _____ SOG No.:lA_

Methods F_

End Date: 02/22/91

! EPA! Sample! No.

ISOIsioIS2S!S50isioolicvIICBICRA! ZZZZZ1 'ZZZZ:zzzz _

...zzzz1 ZZZZZ __! ZZZZZ! zzzzz _! ZZZZZ! ZZZZZIccvICCB! ZZZZZ! ZZZZZ __! ZZZZZ! ZZZZZIM2FS-1B1M2FS-1BAIM2FS-1AS: zzzzz! ZZZZZIM2FS-9BCSIccvIces1

1

1 11 |1 |

D/F JTlme! * Ri ii ii t1.0011004!

___ 1.00 ! 1008 i _________ 1.0011013! ______

l.OOllOlS!1.00I1023!1. 00! 1028!1. 00! 1032!1.0011037!1. 00 ! 1042!l.OO 11046!

___ 1 .00! 1051!___ 1.00|1056! _____

1.00,' 1101 !1.00!ll06!i .00! 1110!

___ 1.0011115! ______1.00! 1120!1.00!1125!1.00!ll30!1.0011134!

___ 1.00J1139!1.00!1143!1.0011148!

__ 15. 00 [1153! ______15.00J1157! 97.0

__ 15. 00! 1202! ______1.0011206!1. 0011211!

__ 15. 00 [1215! ______1.0011220!1.0011225!

i *t i

Anal/tea

AL

SiAiBBjSiA

1 t

1 v '1 V I

_!x|__!x!

1 v *1 v '

_!x!___!xj

i ri ii ii ii ii ii i

_!_!_i i1 V 1

_!x!__:_!_1 11 11 V 1

_!x|__!x|_

1 |1 |

1 y 1t y •t y 11 i1 t

BEC0CACRC0CuFEPB

•

MG

MNHG

NIK SE

AG

NA L

V zN

FORM XIV - IN 7/88

B. SDG11AFD

PROJECT NAME:.

SUPPORT DOCUMENTATION FOR THE R E V I E W OFINORGANIC ANALYTICAL DATA P A C K A G E

AFFLICABLl SAMFLt ""'• •TYPE or ANALYSIS: .CONTRACT L A B O R A T I

— • - R f V I E W E R : .R E V I E W DATE :.

THE FOLLOWINQ TABLE INDICATESAREAS WHICH WERE EXAMINED INDETAIL, THE IDENTIFIED PROBLEMAREA], AND SUPPORT DOCUMENTATION-ATTACHMENT],

AREAS EXAMINEDIN DETAIL

CHECK!*) IF YCSOR FOOTNOTE LETTERFOR COMMENTS BELOW

PROBLEM AREASIDENTIFIED

CHECK («/i ir resOK FOOTNOTE NUMBERFOR COMMENT] 8CLOW

SUPPORTDOCUMENTATION

ATTACHMENTS

CHECX(V) IF YES*0* IDENTIFY

ATTACHMENT NO.

HOLOINS TIME)

BLANK ANALYSIS RESULTS

MATRIX SPIKES IPRE-OIGESTION)DUPLICATESOUANTrTATION OF RESULTS

DETECTION LIMITS/SENSITIVITY

INITIAL CALIBRATIONS

CONTINUING CALIBRATION)LABORATORY CONTROL STANDARDSICP LINEAR RANGE ANALYSIS

ICP INTERFERENCE CHECKSICP SERIAL DILUTIONSSFAA POST- OISESTION SPIKE]

«FAA DUPLICATE 8URNSSFAA STANDARD ADDITIONSOTHERS

'*I/1

I/I/v\/LXI/I/y/I/*i/[/I/

/

-

/ / / ^ / /

I/l

-

••

-

I/

!X

/ /

1

'T*/J•JtSJyy\fjj

i i i

i&V Tt>

BLflNK RNRLVSIS RESULTS FOR INORGRNICSPflRflMETER TVPE/MflTRIH SflMPLE * SOURCE CONTflMINflNT (CONCENTRRTION)

tis

A| //_

I«C,0

K«/L

LRBORflTORV REPORTED FIELD BLflNK IS COMPHRED WITH THE SHMPLE DRTfl IN B THBULRTION FORM WITHIN THESRMPLE RNRLVTICRL DRTfl SUMMRRV.COMMENT; :

(1) RESULT REPORTED BV THE LRBORRTORV HNO CONFIRMED BV REUIEWER______________12) RESULT INFERED FROM INSTRUMENT PRINTOUTS fl.ND/OR SUPPORTING DRTR

U.S. ERA - CLP






SAS No.: _____ SDG No.: 11AFD

Continuing Calibration Source: SPEX_

Concentration units: ug/L1

1 Analyte

1 Aluminum_I Antimony1 Arsenic _1 Barium __1 Beryllium

admiumalcium

1 Chromium_1 Cobalt1 Copper1 IroniLead1 Magnesium1 ManganeseI Mercury _iNickel __1 Potassium1 Selenium_I Silver __! Sodium1 Thallium_1 Vanadium_! Zinc1 Cyanide|


•"_ 2172.0

__ 948.0

( 1) Control Limits

_2054.00

_ 983.80

_94.6

103.8

Continuing CalibrationTrue Found^ %R( 1 ) Found %R( 1 )

^ ,^_ 2010.0

__ 948.0

_2068.00

_ 959 . 50

102.9

101 .2

_2065.00

_ 939.40

102.7

_99.1


! M

!P_;NRIP_IFINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR


U.S. EPA - CLP


Lab Name: NORTHERN_LABORATORIES. Contract: 68-09-0153



Continuing Calibration Source: SPEX_______

SDG No.: 11AFD


11 Analytei1 Aluminum_1 Antimony_1 Arsenic _1 Barium __1 Beryllium

•dmium _, -ilcium _1 Chromium_i Cobalt __1 Coooer1 Iron1 Lead1 Magnesium1 Manganese1 MercuryiNickel1 Potassium1 Selenium[Silver __I Sodium|Thallium_1 Vanadium_IZinc1 Cyanide!



Continuing CalibrationTrue Found^. *R( 1 ) Found %R( 1 )

""^ . _ 2010.0

___ 948.0

_2061 .00

1010.00

102.5

106.5

_2059.00

949.30

102.4

100.1

1! M

!P_;NRIP_!F_!NRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRI



U.S. ERA - CLP


Lab Name: NORTHERNJ.ASORATORIES___

Lab Code: NLE__ Case No.: ERM.

Initial Calibration Source: EPA-LV


SAS No.: SDG No.: 11AFD_



1! Analyte

! Aluminum_! Antimony_1 Arsenic! Barium __! Beryllium

idmium, .alcium _1 Chromium_ICobalt! Coooer1 IroniLead! Magnesium1 Manganese1 Mercury _i Nickel! Potassium!Selenium_] Silver __I SodiumiThallium_! Vanadium_! Zinc! Cyanide _



————


i/ . /_ 2010.0

__ 948.0

_2063.00

968.60

102.6

102.2

_208$.00

_ 979.70

103.5

103.3

i M

!P_INR;p_|F_INRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRI

Mercury 80-120: Other Metals 90-110: Cyanide 85-115


U.S. EPA - CLP






SDG No.: 11AFD



! Analyte

! Aluminum_! Antimony_! Arsenic _! BariumI Beryllium

dmium, .dlcium! ChromiumICobalt! Cooper! Iron!Lead! Magnesium! ManganeseI MercuryiNickel1 Potassium1 Selenium_! Silver! SodiumI Thallium.J Vanadium_IZinc! Cyanidet

Initial CalibrationTrue Fouwd %R( 1 )

_ 2172.0

__ 948.0

(1) Control Limits

_2053.00

_ 946.80

_94.5

_99.9

————


_ 2010.0

__ 948.0

_2053.00

_ 935.40

102.1

_98.7

_2042.00

_1001.00

101 .6

105.6


iiI M

IP!INRIP|F_INRINRINRINRINRINRINRINRINRI NRINRINRINRINR;NR[NRINRINRINRINRi _ _


U.S. EPA - CLP




Initial Calibration Source: EPA-LV.

Continuing Calibration Source: SPEX__


SAS No.: _____ SOG No.: 11AFD_


I Analyte

! Aluminum_! Antimony_! Arsenic! BariumIBeryllium•' ~%dmium

jlcium _! Chromium! Cobalt1 CoDDer! Iron!Lead1 Magnesium! Manganese! MercuryiNickel{Potassium! Selenium! Silver! Sodium!Thallium_1 Vanadium_!Zinc! Cyanide _


( 1) Control Limits

————


. / f_ 2010.0

948.0

_2049.00

978.40

101 .9

103.2

_2043 .00

953.50

101 .6

100.6


i Mr

IP_INRIPINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR


.1 -. 7/88

U.S. EPA - CLP






SOG No.: 11AFD_

Continuing Calibration Source: SPEX.


1

I Analyte

! Alumi num—! Antimony_1 Arsenic _! Barium1 Beryllium1 "admium

ilcium _i Chromium_ICobalt! Coooer1 Iron!Lead! Magnesium! Manganese! Mercury! Nickel1 Potassium!Selenium_ISilver! Sodium|Thallium_1 vanadium! Zinc! Cyanide!

Initial CalibrationTrue Found 4R( 1 )

i/_ 2172.0

__ 948.0

_2075.00

_ 988.30

_95.5

104.3


^ /_ ,2010.0

___ 948.0

_2063.00

_ 980.20

102.6

103.4

_20?7.00

_1013.00

103.3

106.9

: Mi

!P_INR!P_INRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR

(1) Control Limits: Mercury 80-120: Other Metals 90-110; Cyanide 85-115


7/88

U.S. EPA - CLP


Lab Name: NORTHERNJ-ABORATORIES. Contract: 63-09-0153



Continuing Calibration Source: SPEX______

SD6 No.: 11AFD


1! Analyte

! Aluminum! Antimony! Arsenic! Barium! Beryllium! '"^dmium _

IciumI chromium_! Cobalt1 Cooper; Iron! Lead! MagnesiumI Manganese1 Mercury _iNiekel! Potassium! Selenium_! Silver1 Sodium!Thallium_! Vanadium_,'Zinc! Cyanide!

Initial CalibrationTrue Found 4R( 1 )

47.4


/y

49.80 105.1


47.4

J(*/

47.90 101 .1

S

s47.20 —99.6

i

i Mi|NR~INR!F_INRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR1 NRINRINR



7/88

U.S. EPA - CLP


Lab Name: NORTHERNJ.ASORATORIES___





SDG No. : HAFD


1111 Analyte

! Aluminum_! Antimony_! Arsenic! Barium __! Beryllium'admium.alcium _

! Chromium_ICobalt! Copper1 IronI Lead! Magnesium! Manganese[MercuryiNickel1 Potassium! SeleniumISilver! Sodium __1 Thallium_I VanadiumIZinc1 Cyanide>




47.4

/,/47.70 100.6

————

! MtINKINR|F_INRINRINR;NRiNRINRINR; NRINRINRINRINRINRINRINRINRINRINRINRINRINR



7/88

U.S. EPA - CLP


Lab Name: NORTHERN .LABORATORIES___ Contract: 68-09-0153

Lab Code: NLE__ Case No.: ERM_ SAS No.: _____ SDG No.: 11AFD.




1 Analyte

! Aluminum_! Antimony_! Arsenic! Barium __[Beryllium1 " "*dmium

.Icium _1 Chromium_[Cobalt _ I[Copper __I Iron[Lead! Magnesium! Manganese! Mercury[Nickel __[ Potassium[ Selenium_[ Silver! Sodium!Thallium_[ Vanadium[Zinc[ Cyanide _


47.4


/\/50.10 105.7

————


47.4

/i/

49. 6O 104.6

1

i M

INRINR|F_INR[NR[NR1 NRINR[NR[NR[NR[NR[NRINRINR[NRINRINR[NRINR[NRINR[NR[NR



7/88

U.S. EPA - CLP



Lab Code: NLE__ Case No.! ERM_


Continuing Calibration Source: SPEX____


SAS No.: _____ SDG No.: 11AFD.


! Analyt*

I Aluminum_! Antimony_! Arsenic! Barium ,.,[Beryllium' •xdmium _

,lcium1 Chromium_! Cobalt! Cooper! IronILeadi Magnesium! Manganese! MercuryiNickel __1 Potassium! Selenium_! Silver1 Sodium __; Thallium! Vanadium_! Zinc! Cyanide|


47.4


f\/

48.70 102.7

————


47.4

/\s

48.90 103.2

/<_/

47,40 100.0


1

! M

INRINRIFINRINRINRINRINR!NRINRINRINRINRINRINRINRINRINRINRINRI NRINRINRINR

FORM II ( P A R T 1) - IN

7/88

U.S. EPA - CLP




Initial Calibration Source•• EPA-LV____



SDG NO.: 11AFD


1 Analyte

1 Aluminum_1 Antimony_1 Arsenic1 Barium1 Beryllium"idmiumjlcium

1 Chromium1 Cobalt1 Coooer1 Iron[LeadiMagnesium1 Manganese1 Mercury[Nickel1 Potassium1 Selenium_ISilver __1 Sodium __1 Thallium1 Vanadium1 Zinc1 Cyanide _



Continuing CalibrationTrue Found %R( 1 ) Found

47 .4

/i/

48.00 101.3

//

48.90

*R(1)

103.2


11! M

INK!NR;F_INRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRI NRINRINR


7/88

U.S. EPA - CLP



Lab Code: NLE__ Case No.: ERM_ SAS No.: _____ SDG No.: 11AFD_




11 Analyte

1 Aluminum_I Antimony_1 Arsenic _1 Barium __i Beryllium

•dmium. -IciumI Chromium_ICobalt1 CopoerllronILead1 Magnesium1 Manganese[Mercury[Nickel __1 Potassium1 Selenium_1 Silver1 Sodium1 Thallium1 Vanadium_1 Zinc1 Cyanide|



————

————


47.4

/~l/

__ 49.00 103.4

siX

47.40 100.0

>1 M

INRINR|F_INRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRi



7/88

U.S. EPA - CLP


Lab Name: NORTHERNJLABORATORIES. Contract: 68-09-0153




SDG No.: 11AFD_


! Analytei! AluminumI Antimony1 Arsenic! Barium __IBeryllium1 r-dmium _' .cium _! Lnromium_; Cobalt __1 Copper! IronI Lead! Magnesium! Manganese! MercuryI Nickel __! Potassium! Selenium_ISilver __! Sodium __1 Thallium_1 Vanadium_IZinc! Cyanide _



————

————


47.4

/

./

47.40 100.0

>

L/__ 46.00 _97.0

i Mi

INRINR!F_INRJNR!NR!NRINR;NRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR

Mercury 80-120; Other Metals 90-110! Cyanide 85-115


5" I7/88

U.S. EPA - CLP





Continuing Calibration Source: SPEX____


SAS No.: SDG No.: 11AFD


11

! Analyte

1 Aluminum_I Antimony_1 Arsenic1 Barium __1 Beryllium' "sdmium _

ilcium _1 Chromium[Cobalt! Cocoer1 IronItead1 Magnesium1 Manganese1 MercuryINickel __1 Potassium1 SeleniumISiluer __1 Sodium|Thallium_1 VanadiumIZinc1 Cyanide1


47.4


/i/

48.20 101 .7


x"

47.4

/

I/45.40

.

_95.8

/v46.30

—————

_97.7

————

! M

INR!NR|F_INRINRINRINRINR;NRINRINRINRINRINR,'NRINRINRINRINRINR;NRINRINRINR



7/88

U.S. EPA - CLP


Lab Name: NORTHERNJ.A80RATORIES___ Contract: 68-09-0153





1 AnalyteiI Alumi num_I Antimony1 ArsenicISariumIBeryllium

•.dm i urn, alcium1 ChromiumICobalt _ I; Copper __1 IroniLead1 Magnesium1 Manganese1 MercuryiNickel1 PotassiumISelenium_1 Silver1 Sodium1 Thallium1 Vanadium_1 Zinc1 Cyanide[



————

————

————


/

47.4

//

45.60 _96.2 ————

1! M

INR"INR|F_INRINR;NRINRINRINRINRINRINRINRINRINRINRINRINRINRI NRINRINRINRINRI



7/88

U.S. EPA - CLP







SDG No.: 11AFD


1 Analytei1 Aluminum_1 Antimony_1 Arsenic1 Barium __1 Berylliuml.r.admium _

Icium _; nromium_1 Cobalt1 Copper1 Iron1 Lead1 Magnesium1 Manganese1 Mercury[Nickel1 Potassium1 Selenium_.'Silver1 Sodium1 Thallium_1 Vanadium_!ZincI Cyanidej


47 .4


/i /

47.40 100.0

————

Continuing CalibrationTrue Found %R( 1 ) Found %R,( 1 )

47.4

/I/46.80 _98.7

/

I/44T10 _93.0


1t

1 M1

INRIP_|F_INRINRINR!NRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR


7/88

U.S. EPA - CLP


Lab Name: NORTHERN_LABORATORIES_ Contract: 68-D9-01S3




SOG No.: 11AFD


! Analxte

! Aluminum_! Antimony_! Arsenic! Barium1 Beryllium1 Cadmium _

alciumi chromiumICobalt1 Copper! IroniLead! Magnesium! Manganese! MercuryiNickel __! Potassium! Selenium_1 Silver! Sodium __iThallium_! Vanadium_! Zinc! Cyanide _i



————

————


47.4

/,/__ 48.10 101.5

/\/

__ 47 .10

——_99.4

————

Mercury 80-120! Other Metals 90-110; Cyanide 85-115

! M!

INR:IP_!,'F_;INR!INR;!NR;INR!INR;INR!INR!INR!INR;I N R IINR!INRIINR!,'NR!INR !INR!INR;!NR !INR!INP!INR!


7/88

U.S. ERA - CLP


Lab Name: NORTHERN_LA80RATORIES___ Contract: 68-09-0153





1 Analxte

1 Aluminum_1 Antimony_1 ArseniciBarium1 Beryllium1 '"idmium

Icium; >_nromium_1 Cobalt __I Copper __1 IronI Lead1 Magnesium[Manganese1 MercuryiNickel1 Potassium1 Selenium_ISilver1 SodiumlThallium_1 Vanadium_1 Zinc1 Cyanide;


47.4


/\/

47.60 100.4

————


47.4

/\s47. 8O 100.8


i M

INR"IP;F_INKINR!NRINRINRINR;NRINRINRINRINRINRINRINRINRINRINR;NRINRINRINR


7/88

U.S. EPA - CLP







Continuing Calibration Source: SPEX.


Analyte- i1 Aluminum_! Antimony_! Arsenic! Barium! Beryllium! r»dmium _

Iciumi wnromiufn! Cobalt,' Copcer! IronI Lead1 Magnesium! Manganese! MercuryJickel

^-Potassium! Selenium_! Silver1 Sodium __!Thallium_1 Vanadium_iZinc1 Cyanide _


47.4


/y49.40 104.2

————


^ /

47.4

/[/48.10 101.5

/^47.80 100.8


1111: MiINR!P_!F_INRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRi ^__


7/88

U.S. EPA - CLP


Lab Name: NORTHERN_LABORATORIES_ Contract: 68-D9-0153




SDG No.: 11AFD.


1 Analyte

1 Aluminum_1 Antimony_1 Arsenic _! Barium1 Beryllium1 '"admium

Icium; cnr omiumICobalt1 Copoer1 Iron1 Lead1 Magnesium1 Manganese1 Mercury1 Nickel __1 Potassium1 Selenium[Silver __1 Sodium __1 Thallium_1 Vanadium_1 ZincI Cyanide _



————

————


/

47.4

/w/

__ 47.50 100.2

/

/4 .40 100.0

! M

INRIP|F_INRINRINRINRINRINRINRINRINRINR!NRINRINRINRINR;NR!NR;NRINRINRINRt

Mercury 80-120! Other Metals 90-110: Cyanide 85-115


5 If 7/88

U.S. EPA - CLP

28CRDL STANDARD FOR AA AND ICP








1

1 Analyte

! Aluminum_! Antimony_I ArsenicIBarium1 Beryllium' "admium

ilcium,' chromium! Cobalt' Copper! Iron! Lead1 Magnesium! Manganese! MercuryiNickel! Potassium! SeleniumISilver! Sodium! Thallium_! Vanadium_! Zinc!


True Found *R

10.0

/t/12.60

''~>J126.0.




7/88

23CRDL STANDARD FOR AA AND ICP

Lab Naae: NoftTHeftM

Lab Code: MLg case No.: Eflm

.VA CRDL Standard Source:


Contract

SAS No.: SDG No.: I IAPfc


111lAnalyte1| Aluainua| Antinony_1 ArsenicI BariusIBerylliuaI Cadaiuai alciua

irociuiI .obaltI CoDoerllrcnILead(Magnesius(ManganeseI MercuryI NickelIPotassiuajseleniuaI SilverISodiua[ThalliunI VanadiumIZinc1

CRDL £

True

IO.O

tandard ft

Found

/I/ao.so /

ir AA

*R

^ ——— J303.0 1—— — 1

True

—————

CRDL StaInitialFound

ndard

tR

for ICPFina

Found1

*P,

A 2-0 -

?GRM II (?ART 2) - i:.'

7/88

23CRDL STANDARD FOR AA AND 1C?

Lab Naae: NJoftTHCRM

Lab Code: MLE" Case No.:AA CRDL Standard Source:TCP CRDL Standard Source:

Contract:

SAS No.: SDG No.: IJAFb


111I Analyte1| Aluainua(Antinony(Arsenic1 aariua| Berylliua| Cadniumi<"alciua

.ro=iu=1 i_ofcaltI CopperllronILead| Magnesium[Manganese[Mercury1 NickelI Potassiun| Seleniua[SilverI SodiumIT.Ialliua| Vanadiua[Zinc1

1I CRDL £1I True

lo. o

tandard fe

Found

/•as ."10

r AA

*R

asi.o

True


1

idard

«R

for ICPFina

Found1%R

FORM II (PART 2) -7/88

U.S. EPA - CLP

2BCRDL STANDARD FOR AA AKD ICP

Lab Naae: Mo«THg<tM

Lab Code: MLg Case No.:

AA CRDL Standard Source:


Contract: (jg-

SAS No.: SDG No.: U f t P f c ,


111lAnalyte1| Aluminum| Antimony1 Arsenic| Barium| Beryllium! Cadmium' \lcium

ironiuB[Cobalt| Copper1 Iron[Lead| Magnesium(ManganeseI Mercury1 NickelI PotassiumI Selenium1 Silver1 SodiumI Thallium| VanadiumIZinc1

CRDL S

True

Id.O

tandard fc

Found

IM.SO

r AA

*R

ma.o

True


idard

iR

for ICPFina

FoundL*R

11

FORM II (PART 2) - IN7/8S

U.S. ERA - CLP







SAS No.: _____ SDG No.: HAFD_


Analyte

Aluminum_Antimony_ArsenicBariumBerylliumradmium.Icium

chromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThallium_VanadiumZinc


True Found %R

10.0

/-

13.20 _132.0

— - —— -

-

———————————




7/88

U.S. EPA - CLP

28CRDL STANDARD FOR AA AND TCP




TCP CRDL Standard Source: __________




I Analyte

1 Aluminum_1 Antimony_! Arsenic! BariumI Beryllium' "idmium

.Iciumi chromiumiCobalt! Cooper,' IroniLead! Magnesium! Manganese! Mercury,' NickelI Potassium! SeleniumISilver] SodiumIThallium! VanadiumIZinc!


True Found %R

10.0

/i/

10. 9O _109.0

—————

—————


True Found *R Found %R

I7S


7/88

U.S. EPA - CLP









! Analyte

[Aluminum! Antimony1 Arsenic! Barium! Beryllium' "idmium

ilcium! ChromiumICobaltI Coooer,' IroniLead! Magnesium' Manganese! MercuryiNickel! Potassium! Selenium! Silver! Sodium1 Thallium[VanadiumIZinc!

CRDL !

True

10.0

standard f<

Found

/i/

11.50

>r AA

%R/

115.0

True


ndard 1

%R

'or ICPFina

FoundL*R


7/88

U.S. EPA - CLP

3BLANKS


Lab Code: NLE__ Case No.: ERM_ SAS No.: _____ SOG No.: 11AFD.

Preparation Blank Matrix (soil/water): WATER

Preparation Blank Concentration Units (ug/L or mg/kg): UG/L_

1 Analyte

[ Aluminum.I Antimony_' Arsenic

i ryllium] Cadmium1 Calcium! Chromium1 Cobalt! Copper1 IronILead1 Magnesium! Manganese1 MercuryiNickel1 Potassium[ Selenium(Silver! Sodium1 Thallium.1 VanadiumIZinc1 Cyanide!

InitialCalib.Blank( us/L ) C

26.0

49.0

U

U


1 C 2 C 3 C

31.9 JBD 26.0

49. 0O Oeq. s/«

——

U

dl

49.0- -,

uu

—

—

_

-

-

26.0

49.00 0

uu

-

-

-

Prepa-rationBlanket

{\77.9

49.0 U

-

ii

IPINRIP!NR_|NR_1 NR_

INR^|NR_INR|NR~INRINR!INR|NR_INR"INR!i NR_|NR_

INR!|NR_

FORM III - IN7/88

U.S. EPA - CLP

3BLANKS




Preparation Blank Concentration Units (ug/L or mg/kg): MG/KG

11 Analyte

1 Aluminum_1 Antimony_1 ArsenicISarium

;ry Ilium, uadmium1 Calcium[ Chromium1 Cobalt! Cooper! IroniLead1 Magnesium1 Manganese! MercuryiNickel; Potassium1 Selenium_1 Silver! Sodium1 ThalliumI VanadiumIZinc1 Cyanide!

initialCalib.Blank(ug/L) C

~


1 Ê 2 .JC 3 - C

26.0

49.0Q_ 0 ——ftj.8/

uurU.li

™"

26.0

49.0i ——— 9— e —11

uu

-

-

-

-

26.0

49.0

U

U

-

-

-

-

Prepa-rationBlank £

[/__/?/. 360TB-

9.800i—'U

-

-

-

1

! M1

IP,'NRIPIFINRINRINRINRINRINR|NR_INRINR|NR_INR|NR_INRINR|NR_|NR~|NR_INRÎNRINR

FORM III - IN

LI7/88

U.S. EPA - CLP

3BLANKS







1

! Analytei! Aluminum_1 Antimony_! ArsenicI R^r ium

rylliumi cadmium1 Calcium1 Chromium_i Cobalt! Copper1 IroniLead1 Magnesium1 Manganese1 MercuryiNickel1 Potassium1 Selenium_1 Silver! Sodium1 Thallium_1 Vanadium_1 Zinc1 Cyanide!

InitialCalib.Blank( ug/L )/e

___ 26.0 _

49.0

U

U

-


1 C 2 x C 3 C

___ 26 . 0_

49.0

U

U

^

___ 26. 0_

49.0

U

U

-

-

-

-

_

-

-

— £5:.3^49.0

3)

U

-

-

Prepa-rationBlank C

___ /16.804•55 ——————

9.608

B,

U

-

—

:—

_

1 M

|NR~IP|NR_INR|NR_

|NR~INRINRINR|NR~INRJNR|NR_|NR_INRINR|NR_INRINRINRINRINR!

FORM III - IN7/88

U.S. EPA - CLP

3BLANKS







t1

1 Analyte

I Aluminum_1 Antimony_1 Arsenic' "irium

-ryllium1 CadmiumICalciumI Chromium1 Cobalt1 Coooer1 Iron'Lead1 Magnesium1 Manganese1 MercuryiNickel __1 Potassium1 SeleniumISilver1 Sodium! Thallium_[VanadiumIZinc1 Cyanide _


-


1 / C 2 C 3 C

——— 26'°-49.0

U

u

~

-

-

~~

-

-

Prepa-rationBlank C

-

-

-

-

11

1! M1

IPINRt p!NR_INR|NR~INR;NR|NR_INR|NR_|NR_|NR_INRINRINR!NR_INRINRINR|NR~INR|NR_|NR_

FORM III - IN7/88

U.S. EPA - CLP

3BLANKS



Preparation Blank Matrix (soil/water):




11

1 Analyte

I Alumi num_1 Antimony_1 Arsenic' ""ariumeryllium

1 Cadmium1 Calcium1 ChromiumICobalt! Copper1 Iron!LeadI Magnesium1 Manganese1 Mercury,' Nickel1 Potassium1 Selenium1 Silver1 Sodium1 Thallium_1 Vanadium_1 ZincICyanideii


w'

26.0

49.0

U

V

-


l^C 2 / C 3 C\s i/

26.0

49.0

U

U

™

26.0

49.0

U

U

-

-

Prepa-rationBlank C

-

1

1 M

IPINKIPINR.INR]INR.INR"INRINRINR,INR.INRINR.1 NR.INR.INR.INR.INR.|NR_INR\NR~|NR_.!NRINR!

FORM III - IN7/88

U.S. EPA - CLP

3BLANKS





Preparation Blank Matrix (soil/water): WATER

Preparation Blank Concentration Units (ug/L or ma/kg): UG/L_

1 Analytei1 Aluminum_1 Antimony_! Arsenic. ,' "Tium

ryllium1 Cadmium1 Calcium! Chromium1 Cobalt! Cooper! Iron,'LeadI Magnesium1 Manganese! MercuryiNickel1 Potassium1 SeleniumISilver1 Sodium! ThalliumI Vanadium_IZinc1 Cyanide;•


3.0 U

-


1 C 2 C 3 C

3.0 U

-

-

3.0 U

-

-

-

-

-

-

3.0 U

-

-

Prepa-rationBlank C

3.0 u

~*

-

-

1

111! M1

INR;NR_IF;NR_(NR_|NR_';NR_|NR_INR|NR_|NR_|NR_INR|NR_;NR_|NR~INR|NR_|NR_|NR_|NR_|NR_INRINRI

FORM III - IN7/88

U.S. EPA - CLP

3BLANKS




Preparation Blank Concentration Units (ug/L or ing/kg): MG/KG

I

I Analyte

I Aluminum_! Antimony_I Arsenic' ar ium

iryllium! Cadmium! CalciumI ChromiumiCobaltI Copper __! IronI LeadI Magnesium! ManganeseI MercuryiNickelI PotassiumI Selenium_I Silver! Sodium|Thallium_I Vanadium_I ZincI CyanideI


3.0 U

——


1 C 2 C 3 C

3.0 U

^

—

-

-

-

-

-

-

Prepa-rationBlank C

0.606 U

-

11\ MiINR.INRIF "INR.INR.INR"INR_!NRINR"1 NR.INR.INR.INRINR"INR.INR.INR.i NRINR^|NR_|NR_INR|NR_|NR_

FORM III - IN7/88

U.S. EPA - CLP

3BLANKS







1

1

! Analyte

! Aluminum_! Antimony! Arsenic'ariumeryllium

! Cadmium! CalciumI ChromiumiCobaltICoooer1 Iron!Lead! Magnesium.'Manganese! MercuryiNickel! Potassium1 S«lenium_! Silver1 Sodium! Thallium_t VanadiumI Zinc[Cyanide;


rs72-_BJ


1 C 2 C 3 C

3.0 u

—

—

3.0 U

-

3.0 U

-

-

Prepa-rationBlank C

0.606 U

-

-

-

-

! M

INRINR"IFINR;NR"INR"INR!i NRINR!INRINR|NR_INR.|NR_|NR_INR'|NR_INRINRINRINR|NR_INRINR

FORM III - IN

1 I7/88

U.S. EPA - CLP

3BLANKS





SAS No.! _____ SDG No.: 11AFD_

Preparation Blank Concentration Units ( ufl/L or mg/kg):

1 Analyte

1 Aluminum_1 Antimony_I Arsenic' ~ •'rium

ryllium1 Cadmium1 CalciumI Chromium1 Cobalt1 Copper[ Iron!Lead1 MagnesiumI ManganeseI Mercury[NickelI Potassium1 Selenium_ISilver! Sodium|Thallium_1 Vanadium1 Zinc1 CyanideI


-

-


1 C 2 C 3 C

3.0 U

~

-

3.0 U

-

-

-

-

3.0 U

-

-

-

-

Prepa-rationBlank C

-

-

1

11! M

;NR_|NR_IF|NR_;NR_|NR_|NR_|NR_|NR_INR!|NR_!NR_INR|NR_!NR_!NR_!NRINRINRINR!|NR_|NR_;NR_INR1

FORM III - IN

^ /7/88

U.S. EPA - CLP

3BLANKS




Contract: 68-D9-01S3

SAS NO.: _____ SDG No.: 11AFD

Preparation Blank Concentration Units (ug/L or ms/ks)!

II

Analyte

! Aluminum_! Antimony_! Arsenic! "Tium

ryllium! CadmiumICalciumI Chromium! Cobalt! Copper! IronI Lead! MagnesiumManganese! MercuryiNickel! PotassiumSelenium_! Silver! Sodium|Thallium_! VanadiumIZinc'Cyanidei


——

——


1 C 2 C 3 C

3.0 U 3.0

-

U

-

-

_

_

-

-

Prepa-rationBlank C

-

-

-

111

1 M

|NR_|NR_IF;NR_;NR;NR_INR_|NR_;NR_INR|NR_!NR;NR_|NR_|NR_|NR_|NR_|NR_!NR|NR_;NR_|NR_!NR_|NR_

FORM III - IN7/88

U.S. EPA - CLP

3BLANKS







1

lAnalyte

1 Alumirtum_1 Antimony_1 Arsenic1 arium

sryllium; Cadmium! Calcium,' ChromiumICobalt1 Coooer1 IroniLeadI Magnesium! Manganese1 MercuryiNickel1 Potassium1 Selenium_1 Silver1 Sodium[ThalliumI VanadiumIZincICyanide!


3.0 U


1 C 2 C 3 C

3.0 U

~

"**

3.0 U

-

-

-

-

-

3.0-U

-

-

-

-

Prepa-rationBlank C

-

]11

! M

INR|NR~;FINRINR!!NR.INRINR!INRINR"INR!INRÎNR!1 NR_INR"INRINRINRINRÎNRINRINRINR"|NR_I

FORM III - IN7/38

U.S. EPA - CLP

3BLANKS


Lab Code: NLE__ Case No.: ERH_




Preparation Blank Concentration Units (ug/L or mg/ks):

1 Analyte

1 Aluminum_1 Antimony_1 Arsenic! "->rium

ryllium1 CadmiumICalcium1 Chromium1 CobaltICocDer1 Iron!Lead1 Magnesium1 Manganese1 MercuryiNickel1 Potassium1 Selenium_1 Silver1 Sodium1 Thallium_1 VanadiumIZinc! Cyanide


3.0 U

-


1 C 2 C 3 C

3.0h£U

™~^

3.0 U

-

-

_

3.0tjU

-

-

_

Prepa-rationBlank C

-

-

-

-

1! M

!NRIPIF|NR_|NR_|NR_INR!|NR~INR|NR_INRINR|NR_|NR_INR|NR_INR|NR_|NR_|NR_|NR~|NR_INR|NR_

FORM III - IN7/88

U.S. ERA - CLP

3BLANKS






Preparation Blank Concentration Units (ug/L or mo/kg):

1

1

i Analyte

I Aluminum_! Antimony_! Arsenic! Barium

rylliumi -ddmium! Calcium|Chromium_ICobalt! Cooperllron'.LeadI Magnesium! Manganese! MercuryiNickel1 Potassium! Selenium_ISilver! Sodium!Thallium_I VanadiumIZinc! Cyanide


-

-

~


1 C 2 C 3 C

3.0

1

•*U

_

-

-

-

-

•v-

-

-

-

-

-

prepa-rationBlank C

-

—

1

I

i M

INRIPIF!NR_'!NR_'|NR_|NR_'|NR_'INR 'INRINRINR;NR|NR_INR|NR_INRINR|NR_INR '|NR_'|NR_;|NR_|!NR_:1 1

FORM III - IN7/88

U.S. EPA - CLP

3BLANKS

Lab Name: NORTHERN .LABORATORIES___






1

1

! Analyte

! Aluminum_! Antimony_! Arsenic! Rarium

'rylliumi _admium! Calcium! ChromiumICobalt! Coocer! IroniLeadi Magnesium'Manganese! MercuryiNickel! Potassium! Selenium_1 Silver! Sodium! Thallium! vanadium! Zinc! CyanideI


3.0 U

-


1 C 2 C 3 C

• V O3.0

-

U

™

0 0

..

-

-

-

-

-

_

/N « -

-

-

-

-

Prepa-rationBlank C

iJ<J.«/IMlll

-

-

_

iiii

i M

|NR_IPIFINR|NR~|NR_|NR_INR!|NR~|NR_|NR~|NR~'NR_INR|NR_|NR_INR!NRINRINR|NR_|NR_INR|NR~

FORM III - IN

11

7/88

U.S. EPA - CLP

3BLANKS






Preparation Blank Concentration Units (ug/L or ms/ks):

! Analyte

1 Aluminum_I Antimony_1 Arsenic! °^rium

ryllium1 i_admium,' Calcium1 Chromium1 Cobalt! Cocoer1 IroniLead1 Magnesium1 Manganese! MercuryiNickel1 PotassiumI SeleniumI Silver! Sodium1 Thallium_1 VanadiumIZincICyanide;


3.0 U

tContinuing Calibration

Blank (ug/L)1 C 2 C 3 C

3.0 U 3.0 U

-

-

-

-

3.0 U

-

-

-

Prepa-rationBlank C

-

-

1

1! M

INRINKIF!NR_!NR;NR!NR_!NR_|NR_!NR_;NR_!NR_INR,'NR_!NR_INRINRINR|NR_INR|NR_|NR_!NR_INRt

FORM III - IN7/88

U.S. EPA - CLP

3BLANKS




Preparation Blank Concentration Units (ug/L or mo/kg): ____

1 Analyte

1 Aluminum_1 Antimony_1 Arsenic1 ~irium

ryllium1 Cadmium1 Calcium1 Chromium'! Cobalt1 Copper1 IroniLead1 Magnesium! Manganese! MercuryiNickel1 Potassium1 Selenium! Silver1 Sodium1 Thallium1 VanadiumiZinc! Cyanide!


-

-

-


1 C 2 C 3 C

3.0SU

_ J^ 4/1*4(41 -

-

-

-

0.0 £

-

Prepa-rationBlank C

ftffnUi

-

-

_

-

11111

! M

INRIPIF|NR_|NR_|NR_INRINR;NRINRINRINRINR;NRINRINRINRINR!NR|NR_INRINRINR|NR_

FORM III - IN7/88

U.S. EPA - CLP



Lab Code: NLE__ Case No.: ERM_ SAS No:

ICP ID Number: JA 9OOO____ ICS Source: EPA0689


____ SDG No.: 11AFD.

Concentration Units: ug/L11! True! Sol. Sol.! Analyte A AB

! Aluminum_! Antimony_! Arsenic! Barium1 Beryllium! Cadmium _; Calcium'Chromium_Cobalt

1 Coooer! IroniLead! Magnesium[Manganese'MercuryiNickel[Potassium! Selenium_ISilver! Sodium!Thallium_! Vanadium!Zinc!

481000

0

_469700

0


A . AB %Ris L/_506500

1459

______

_508200.0

1491.0

108.2


A AB . %R.S ^/

_511300

1572

_516SOO.O

1585.0

110.0

FORM IV - IN

7/88

U.S. EPA - CLP


Lab Name: NORTHERN .LABORATORIES___


ICP ID Number: JA 9000____


SAS No: SDG No.: 11AFD_

ICS Source: EPA0689.

Concentration Units: ug/L11I True! Sol. Sol.1 Analyte A AB

! Aluminum_1 Antimony! Arsenic! Barium! Beryllium! CadmiumIcalcium1 Chromium_Cobalt: CopperllroniLeadiMagnesium[Manganese! MercuryiNickel! Potassium|Selenium_iSilver! Sodium1 Thallium_! Vanadium_! Zinc1

481000

0

_469700

0


A / AB / *R*/ )/

_507100

1549

_503800.0

1466.0

107.3


V ABL/ %R

_5 13600

1421

_511700.0

1376.0

108.9

FORM IV - IN

7/88

U.S. EPA - CLP

4ICP INTERFERENCE CHECK SAMPLE

Lab Name: NORTHERNJ-ABORATORIES___ Contract: 68-09-0153

Lab Code: NLE__ Case No.: ERM_ SAS No: _____ SDG No.: 11AFD_

ICP ID Number: JA 9000____ ICS Source: EPA0689____


! True! Sol. Sol.! Analyte A ABi! Aluminum_! Antimony_! Arsenic! Barium! Beryllium! CadmiumICalcium! ChromiumCobalt! Copper| Iron! LeadI Magnesium! Manganese| Mercury! NickelPotassium

1 Selenium.Silver! Sodium __ .Thallium.! Vanadium!Zinc!

481000

0

_469700

0

——————


A , AB / *R// '

_505600

1548

_503400.0

1617.0

107.2


A / AB *R

_50S500

1601

_503'600.0

1663.0

107.2

FORM IV - IN

7/88

U.S. EPA - CLP


EPA SAMPLE NO.

Lab Name: NORTHERN_LABORATORIES. Contract:68-D9-0153 13B

Lab Code: NLE_

Matrix: _SOIL.

Case No .: ERM_ SAS No .: SDG NO.: 11AFD_

Level (low/mod): _LOW_


Concentration Units (ug/L or rag/kg dry weight): MG/KS1

1I Analyte

I Aluminum_1 Antimony1 Arsenict Barium[Beryllium!radmium .

Iciumi nromium1 Cobalt) Cooper1 IronILeadI Magnesium1 ManganeseiMercuryINickelI PotassiumISelenium1 Silver1 SodiumIThallium1 VanadiumIZine1 Cyanide,'

ControlLimit*R

75-125_

75-125

Spiked SampieResult (S£R)

__ 242632. 2918_

797.9543

c

-

SampleResult (SR)

__ 186347.5220

601.0136

C

-

SpikeAdded (SA)

__ 46704.96

233.52

%R

_ 120.5

84.3

Qi M

_;p_~|NRIPINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRI

Comments:

FORM V (Part 1 ) - IN 7/88

U.S. EPA - CLP


EPA SAMPLE NO.

Lab Name: NORTHERN_LABORATORIES_ Contract:68-D9-0153 138

Lab Code: NLE_

Matrix: _SOIL.

Case No.: ERM_ SAS No.: SDG No.: 11AFD_



Concentration Units (ug/L or mg/kg dry weight): MG/KG11

; Analytei! Aluminum! Antimony1 Arsenic! Barium! Beryllium! Cadmium

ilciumi ~nromium! Cobalt1 Copper! IroniLead{Magnesium! Manganese! MercuryiNickel! Potassium! SeleniumISilver! Sodium!Thallium_! VanadiumIZinc! Cyanide!

ControlLimit%R

75-125


51.9317\/V

c1

SampleResult (SR)

11.2893

C

B

SpikeAdded (SA)

34.39

%R

118.2

i t

Q; MIINR;INR!IF 1i'NR|INR:INR!INR;!NR|!NR|INR!INR;INR;INR;INR;INR;i N R i;NR|;NR;INR;i N R i;NR;|NR!;NR;INR;i i

Comments:

FORM V (Part 1) - IN • 7/88

U.S. EPA - CLP


EPA SAMPLE NO.

Lab Name: NORTHERN_LABORATORIES. Contract:68-09-0153 15BFB

Lab Code: NLE__

Matrix: _WATER.Case No.: ERM _ SAS No.: SDG No.: 11AFD_

Level (low/med):


Concentration Units ( ug/L or mg/kg dry weight): UG/L_11

1 Analyte

1 Aluminum1 Antimony1 ArsenicI Barium1 Beryllium! Cadmium

Iciumi ,nromiumi Cobalt1 Copper1 Iron! LeadI MagnesiumI Manganese1 MercuryiNickelI PotassiumI SeleniumI Silver! Sodium[Thallium1 VanadiumIZincI Cyanidei

ControlLimit%R

75-125


/L/

22.2000

CSample

Result (SR)

3.0000

C

U

SpikeAdded (SA)

20.00

*R

111 .0

1 11 11 11 1

Q; M;i i:NR;INR;IF :INR:INR!INR!INK;INR;INR!INR;JNR;INR;(NR!INR;INR!INR!INR;INR!INR!INR;INR;INR!INR!INR;! ;

Comments:


U.S. EPA - CLP


EPA SAMPLE NO.

Lab Name: NORTHERN_LABORATORIES_ Contract:68-D9-0153 17B

Lab Code: NLE_

Matrix: _SOIL.

Case No.: ERM_ SAS No.: _____ SDG No.: 11AFD_

___ Level (low/med): _LOU___



1! Analyte

! Aluminum_! Antimony! Arsenic! BariumI Beryllium! i~admium

Iciumi >,nromium[Cobalt! CooDer: Iron1 Lead! Magnesium, Manganese! MercuryINickel! Potassium! Selenium! SilverI Sodium! Thallium' VanadiumIZinc1 Cyanide!

ControlLimit*R

75-125_

75-125


__ 304119'.7802_

942.8647

C

-

SampleResult (SR)

_ 226237.7239

632.2081

£

-

SpikeAdded (SA)

__ 62255.84

311.28

*R

— ffz'sTg99.8

Q

N

M !

P !NR!P !NR!NR !NR!NR!NR!NR!NR!NR!NR!NR!NR!NR !NR;NR!NR!NR!NR;NR!NR !NR!NR!

!

Comments:


U.S. EPA - CLP


EPA SAMPLE NO.

Lab name: NORTHERN_LABORATORIES_ Contract:68-D9-0153 17B

Lab Code: NLE_

Matrix: _SOIL.

Case No.: ERM_ SAS No.: _____ SDG No.: 11AFD_

___ Level (low/med): _LOW___



Analyte

1 Aluminum1 Antimony1 Arsenic1 Barium! Beryllium! Cadmium,

ilcium. .nromium! Cobalt; Coooer! Iron'.Lead' Magnesium; ManganeseMercury ,! NickelPotassium

1 Selenium[Silver; SodiumiThallium1 vanadiumIZinc1 Cyanide1

ControlLimit%R

75-125


\79.7607

Cf1f

SampleResult (SR)

12.9603

C

u

SpikeAdded (SA)

90.64

%R

88.0

1I

QJ M

INRINRIPINRINRINRINRINRINRINRINR;NR;NRINRINRINR;NRINRINR;NRINR;NR!NR;NR1

Comments:


U.S. EPA - CLP


EPA SAMPLE NO.

Lab Name: NORTHERN LABORATORIES. Contract:68-09-0153 5CFB

Lab Code: NLE__

Matrix: _WATER.

Case No.: ERM_ SAS No.: SDG No.: 11AFD_



Concentration Units ( ug/L or mg/kg dry weight): UG/L_

1 Analyte

I AluminumI AntimonyI Arsenic! Barium1 Beryllium\ cadmium

Icium^nromiumCobaltCopper ...Iron!Lead1 Magnesium! Manganese! MercuryINickelI Potassium1 SeleniumISilveri SodiumiThalliumI Vanadium1 ZincI Cyanide!

ControlLimit%R

75-125


14000.0000

511.5000

CSample

Result (SR)

11220.0000

50.5000

CSpike

Added (SA)

2500.00

50O.OO

*R

111 .2

92.2

i

iQ I M

i

IP!NRIPINRINRINRINRINRINRINRINRINRINRINRINR!NR!NRINRINRINRINRINRINRINR!

Comments:


U.S. ERA - CLP

DUPLICATESEPA SAMPLE NO.





138Contract: 68-D9-0153 _ ____



* Solids for Duplicate: _79.3

Concentration Units (ug/L or ma/kg dry weight): MG/KG

111 Analyte

1 AluminumI Antimony1 Arsenic1 BariumI Beryllium1 Cadmium1 CalciumI Chromium1 CobaltICoooer! IronI Lead1 Magnesium1 Manganese[MercuryiNickel\ Potassium1 SeleniumISilver1 Sodium1 Thallium_1 Vanadium!Zinc1 Cyanide1


186347.5219

601 .0136

C Duplicate ,(D)

185769.6284

605.9780

C RPD

0.3

0.8

1 1

oi MIi iIP !|NR|IP !!NR!!NR|INR I!NR|INRI!NR|INR!!NR|!NR|INR!INR!INR:INR;|NR|INRIINR |INR |I N R IINRIINR!I N R I! !

FORM VI - IN

011

7/88

U.S. ERA - CLP


13BLab Name: NORTHERNJ.ABORATORIES___ Contract: 68-D9-0153


Matrix (soil/water): SOIL_ Level (low/med): _LOU_

* Solids for Sample: _79.3 * Solids for Duplicate: _79.3


lAnalyte

I Aluminum! Antimony1 Arsenic! Barium! BerylliumI Cadmium! CalciumI Chromium! Cobalt! Copper! IronILead! Magnesium! Manganese! MercuryiNickel1 Potassium! Selenium! Silver! Sodium! Thallium_I Vanadium!Zinc1 CyanideI


//11 .2893

C

B

Duplicate (D)

/•^

7. 2059

C

u

RPD

_ _£200 . OJ>i i -*^

i ii r

Q! Mli iINR IINR!IF !INR!INR!INR!INR!INR!|NR|INR!INR!INR IINR!INR!INR IINR!INR!INR |INR IINR IINR!INR!INR;INR!

A S - ft6iou/f£ cpo<"FtfL

jr

FORM VI - IN7/88



Matrix (soil/water): WATER


U.S. EPA - CLP

6DUPLICATES

. Contract: 68-D9-O153

EPA SAMPLE NO.

15BFB

SAS No . : SDG No.: 11AFD_

Level (low/med): LoW

* Solids for Duplicate: °" °

Concentration Units (ug/L or mg/kg dry weight): UG/L_

11 Analyte

1 Aluminum1 Antimony1 Arsenic1 BariumiBeryllium1 CadmiumI Calcium1 Chromium1 Cobalt1 CooperI IroniLead! MagnesiumI Manganese1 MercuryiNickelI PotassiumISeleniumISilver1 SodiumIThalliumI Vanadium1 ZincICvanide!


/j/

3.0000

C

U

Duplicate (D)

/,/

3.00OO

C

U

RPD

111

0| M

INRINRIFINR;NRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR| NR[

FORM VI - IN7/88

U.S. EPA - CLP

EPA SAMPLE NO.DUPLICATES

17BLab Name: NORTHERNJ-ABORATORIES___ Contract: 68-09-0153

Lab Code: NLE__ Case No.: ERM_ SAS No.: _____ SOG No.: 11AFD_


% Solids for Sample: _64.9 * Solids for Duplicate: _64.9


1 Analytei1 Aluminum1 Antimony1 Arsenic1 Barium1 BerylliumI Cadmium'.Calcium1 Chromium1 Cobalt1 Copper1 Iron!LeadI Magnesium1 Manganese1 MercuryiNickel1 Potassium1 Selenium: Silver1 SodiumiThallium1 VanadiumIZincI Cyanide!


226237.7239

632.2081

C Duplicate GO")

260934. S680

734.7175

C RPD

14.2

15.0

11

oi MIP!NRIPINRINRINRINRINRINRINRINRINRINRINRINR]NRINRJNRINRINRINRINRINRINRI

FORM VI - IN7/88

U.S. EPA - CLP


17BLab Name: NORTHERNJ-ABORATORIES___ Contract: 68-D9-0153



* Solids for Sample: _64.9 * Solids for Duplicate: _64.9


1 Analyte

! Antimony _

! Barium __I Beryllium! Cadmium _! Calcium _! Chromium! Cobalt _ I! Copper __1 IroniLead ____[Magnesium(Manganese! MercuryiNickel __! Potassium!Selenium_! Silver __! Sodium[Thallium,! Vanadium_1 Zinc ____! Cyanide _

I rControl ! |Limit I I Sample (S)i i

!!.. /: ;___L/.I 2.96o:

c

—u

-

! Duplicate (D)

/! /! L/ 20. 2500

i

i

i

I t I I Ii! :: : :C I ! RPD ! ! 0 i M !

! ! ! ! NR ;! ! !NR|

B I.QOO.OJ I_|F_|! —— ! ! NR !! ! !NP!! ! !NR!

. ! ! ! NR !! ! ! NR !! ! !NR!

_ ! ! ! NR J_ ! _______ !_|NR|

! !~:NR!_ ! ____ !_!NR;

! !~!NR'I I 1 !NR!! ! ! ! ! NR ;

I '• illNR!! : INR!! ! !NR!

_ ! ____ i-:NR;

San

FORM VI - IN7/88

U.S. EPA - CLP

EPA SAMPLE NO.DUPLICATES



Matrix (soil/water): WATER


5CFBContract: 68-09-0153

SAS No.: _____ SDG No.: 11AFD_

Level (low/med): UO>AJ

* Solids for Duplicate: °'°

Concentration Units (ug/L or mg/kg dry weight): UG/L_

1

lAnalyte

! Aluminum1 Antimony! Arsenic! Barium! Beryllium! Cadmium! Calcium! Chromium,' Cobalt! Cooper! IroniLead! Magnesium! Manganese! MercuryiNickel! Potassium! SeleniumISiluer! SodiumIThallium! VanadiumIZinc! CyanideI


11220.0000

50.5000

C Duplicate/ (D)

11390.0000

49.000O

C

U

RPD

1 .5

goo.q

Q] M

IPINRIPINRINRINRINRINRINRINRINRINRINR1 NRINRINRINRINRINRINRINR;NRINR;NR!

-\s -

FORM VI - IN7/88

U.S. EPA - CLP








1

! Analyte

I Alumi num_! Antimony_! Arsenic! Barium[Beryllium1 Cadmium

Icium, .iromium! Cobalt! Copper __! Iron! Lead1 MagnesiumI Manganese1 Mercury! Nickel __! Potassium1 Selenium_! Silver! Sodium! Thallium_1 Vanadium_! Zinc! Cyanide1

Aqueous ( ug/L )True Found %R

—————

Solid (ma/kg)True Found / C Limits %R

•__ 325.0

__ 917.0

333.2

__ 902 . 8-

-

-

-

-

-

225.0

__ 635.0

424.0

_ 1199.0

102.5

_98 . 5

-

'i'

FORM VI: - IN7/.SS

U.S. EPA - CLP








! Analyte

! Alumi num_! Antimony_! Arsenic] Barium! Beryllium] Cadmium"alcium,hromium_

[Cobalt; __ICoooer! Iron[Lead! Magnesium! Manganese! MercuryiNickel! Potassium! SeleniumISilver! Sodium;Thallium_! VanadiumIZinc! Cyanide!


_____


917.0 __ 960.8

-

-

-

-

-

-

635.0 _ 1199.0 104 .6

FORM VII - IN7/88

U.S. EPA - CLP



Lab Code; NLE__ Case No.: ERM_


Aqueous LCS Source: ___________



1

! AnalyteiI Aluminum_! Antimony _I Arsenic! BariumIBeryllium! Cadmium' -Icium. .iromiumI Cobalt __! Copper1 IroniLead[Magnesium1 Manganese! MercuryiNickel! Potassium! Selenium_,' Silver! Sodium; Thallium_! Vanadium_IZincJCyanide!


Solid (mg/kg)True Found/ C Limits %R

\/325.0

__ 917.0

346.0

_ 1060.2

-

-

-

__ 225.0

__ 635.0

424.0

1199.0

106.5

115.6

'!

1

1

FORM VII - IN7/88

U.S. EPA - CLP








1

lAnalytei! Aluminum_! Antimony _,' Arsenic.! Barium __! Beryllium! Cadmium

Icium; - .iromiumi CobaltICoooer! IroniLead! Magnesium[Manganese! Mercury! Nickel __! PotassiumISeleniumISilver .! Sodium __iThallium_! Vanadium_1 Zinc! Cyanide!

Aqueous ( ug/L )True Found *R

Solid (mg/kg)True Found/ C Limits %R

917.0 659.2 635.0 1199.0 _71 .9

FORM VII - IN

U.S. EPA - CLP




Solid LCS Source: __________

Aqueous LCS Source: EPA-LV_____



1

! Analyte

! Aluminum_! Antimony_! Arsenic1 Barium! Beryllium! Cadmium _

\lcium. nromium1 Cobalt! Copoer! Iron[Lead! Magnesium! Manganese! MercuryiNickel __! Potassium! Selenium! Silver! Sodium __|Thallium_! Vanadium_! Zinc! Cyanide

Aqueous (ug/L)True Found *R

_2172.0

948.0

_1744 .00

970.00

_80.3_

102. 3_


~

-

-

-

-

-

-

1

FORM VII - IN7/88

U.S. EPA - CLP




Solid LCS Source: __________

Aqueous LCS Source: EPA-LV_____



! Analytei! Aluminum! Antimony! Arsenic1 BariumISeryllium! Cadmium' Icium

•romium'Cobalt! Coooer! IroniLead1 Magnesium! Manganese! MercuryiNickel! Potassium! S«lenium_!Silv«r! Sodium! Thallium_' Vanadium_IZinc] Cyanide!

Aqueous (ug/L)True Found *R

23.7 __ 23 . 90100. 8_


_

-

-

-

FORM VII - IN7/88

U.S. EPA - CUP

10Instrument Detection Limits (Quarterly)

j Name: NORTHERN .LABORATORIES___ Contract: 68-09-0153


TCP ID Number: JA_900O____ Date: 01/22/91


Furnace AA ID Number : __________

1

1 Analyte

1 Aluminum1 Antimony1 Arsenic1 Barium1 Beryllium1 Cadmium1 CalciumI Chromium1 CobaltICoooerllronILead1 Magnesium(Manganese1 MercuryiNickel.I PotassiumI Selenium_I SilverI Sodium1 Thallium.I VanadiumIZinc

Uave-length(nm)

_308.22_

193.70

Back-ground

CRDL( ug/L )

200601020055

50001050251003

5000150.240

5000510

500010 J

50. 20

11

IDL i(us/L) I M

26.0 IPiNR

49.0 IP!NR!NRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINR1

Comments:

FORM X - IN 7/88

U.S. EPA - CLP

10Instrument Detection Limits (Quarterly)

L_J Name: NORTHERNJ-A80RATORIES___ Contract: 68-09-0153


ICP ID Number: __________ Date: 01/22/91

Flame AA ID Number : ___________

Furnace AA ID Number : PE_5100PC__

1

! Analytei1 AluminumI Antimony1 Arsenic1 Barium1 Beryllium1 Cadmium! Calcium1 Chromium1 CobaltICopcer1 IroniLead! Magnesium1 Manganese1 MercuryiNickel! Potassium1 Selenium_ISilver! SodiumiThallium'VanadiumIZinc

Wave-length(nm)

193.70

Back-ground

BZ

CRDL(ug/L)

20060102005

50OO1050251003

5000IS0.240

5000510

5000105020

11

IDL j(US/L) j M

1NR!NR

3.0IF!NR!NR!NRINR!NRINRINRINRINRINRINRINRINRINRINRINRINRINRINRINRi

Comments:

FORM X - IN 7/88

U.S. EPA - CLP

11AICP Interelement Correction Factors (Annually)

Lab Name: NORTHERN_LABORATORIES_ Contract: 68-09-0153


ICP ID Number: JA 9000____ Date:

SDG No.: 11AFD_

01/11/91

1 1! ! Wave-! ! length! Analyte ! ( nm )i i! Aluminum_!_308 .22 _! Antimony_| _206 .83 _! Arsenic _ ! _193 .70 _i Barium __ !_493.41 _!Beryllium!_313.04 _I Cadmium | 226.50! Calcium _ !_317.93 _! Chromium_| _267 .72 _! Cobalt __ l_228.62 _

pper __ ! _324 .75 _, -,'on ____ |_259.94 _iLead | 220.30! Magnesium !_279 .08 _! Manganese | _257 .61 _1 Mercury !iNickel __ i_231 .60 _1 Potassium ! _766 . 49 _! Selenium !! Silver __ | _328 .07 _! Sodium __ ! _569 .00 _iThallium !! Vanadium !_292.40 _!Zinc | 213.86i i

Intei-element C

Al Ca

0 . 0000000 ! _0 . 00000000 .0000000 ! _0 .00000000.0015368! 0.00000000.0000000! 0.0000000_0. 0000000! 0.0000000_0 . 0000000 ! _0 . 0000000__0 . 0000000 ! _0 . 0000000__0 .0000000 ! _0 .0000000__0 . 0000000 ! _0 . 0000000__o .0000000 ! _o .ooooooo_-0 .0003940 ! _0 .OOOOOOO_0 . OOOOOOO ! 0 . 0000000_0 . OOOOOOO ! _0 . OOOOOOO_0 . OOOOOOO ! _0 .0000000_

1

_0 .OOOOOOO ! _0 . OOOOOOO __0 . OOOOOOO ! _0 . 0000000_

1

_0 . OOOOOOO ! _0 . OOOOOOO__0 .OOOOOOO ! _0 . OOOOOOO _

1

_0 . OOOOOOO ! _0 . OOOOOOO_0. OOOOOOO! 0.0000000

1

:orrection Factors for : |

Fe Mg CR_ !

_0 .OOOOOOO ! _0 .OOOOOOO ! _0 .OOOOOOO ]_o .0000000 ! _o .0000000 ! _o .0017572 !_0 .0003451 ! _0 . OOOOOOO ! _0 . 0005659 !~o .0000000 ! _o .0000000 ! _o .0000000 ;~~0 . OOOOOOO ! 0 . OOOOOOO j _0 . OOOOOOO !~o .0000000 ! o .0000000 ,' _o .0000000 !_o . ooooooo ! _o . ooooooo ! _o . ooooooo !_o .ooooooo ! _o .ooooooo ! _o .ooooooo !_0 . OOOOOOO ! _0 . OOOOOOO ! _0 . OOOOOOO 1_0 .OOOOOOO ! _0 .OOOOOOO ! _0 .OOOOOOO i_o . ooooooo ! _o . ooooooo ; _o . ooooooo !o.oooooool o.oooooool o. ooooooo!_o . ooooooo ! _o . ooooooo ! _o . ooooooo !J3 .OOOOOOO ! ~0 .OOOOOOO ! _0 .OOOOOOO !

_o. ooooooo! _o . ooooooo |_o .ooooooo;_0 . OOOOOOO ! ~0 . OOOOOOO ! _0 . OOOOOOO !

1 1 1

_0 . OOOOOOO ! _0 . OOOOOOO ! _0 . OOOOOOO !_0 .OOOOOOO ! _0 .OOOOOOO ! _O .OOOOOOO !

_o .ooooooo ! _o .ooooooo ! _o .ooooooo l0.0000000! 0.0000000! 0. OOOOOOO!

1 1 1

Comments:

KORM XI (Part 1) - IN 7/88

U.S. ERA - CLP

usICP Interelement Correction Factors (Annually)

Contract: 68-09-0153Lab Name: NORTHERNJLABORATORIES___

Lab Code: NLE__ Case No.: ERM_ SAS No.: _____


SDG No.: 11AFD_

! Analyte

1 Aluminum_! Antimony_! Arsenic _[Barium __! Beryllium] Cadmium _! Calcium _! Chromium_! Cobalt

ipper

,' Lead ____1 Magnesium'Manganese[Mercury _[Nickel __[ PotassiumI Selenium_I Silver __[Sodium __|Thallium_[ Vanadium_! Zinc ____

Wave-length(nm)

308.22_206.83_193.70.-493.41.-313.04._226.50__317.93-267.72._228.62__324.75_259.94_220.30__279.08_257.61_

_231.60__766.49

_328.07._589.00_

-292.40._213.86.

CU_

Interelement Correction Factors for

MN

00000000000000

00

00

00

. ooooooo [

.00000001

.00000001

.00000001

.ooooooo!

.00000001

. ooooooo ;

.ooooooo!

.00000001

.OOOOOOO!

.ooooooo!

.ooooooo!

.00000001

.000000011

.ooooooo!

.ooooooo!!

.ooooooo!

.ooooooo!1

.ooooooo!

.0003439!!

00000000000000

00

00

00

.ooooooo

.ooooooo

.ooooooo

.ooooooo

. ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.0009764

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

0000000-0000-000

00

0o00

.ooooooo!

.ooooooo!

.ooooooo!

.ooooooo!

.ooooooo!

.ooooooo!

.ooooooo!

.0002500!

.ooooooo!

.00000001

.ooooooo!

.0045230!

.ooooooo!

.000000011

.OOOOOOO!

.ooooooo!1

.ooooooo!

.OOOOOOO!1

.ooooooo!

.ooooooo!1

00000000000000

00

00

00

.0020894

.ooooooo

.0020262

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

.ooooooo

1!1I

1111!!!!!1]I1111

Comments:

FORM XI (Part 2) - IN

U.S. EPA - CLP

12ICP Linear Ranges (Quarterly)



ICP ID Number: JA 9000____


SAS No.: _____ SDG No.

Date: 01/22/91

11AFD_

1

! Analyte

! Aluminum_1 Antimony! Arsenic! Barium! Beryllium! Cadmium! Calcium _! Chromium! CobaltICoPoer! IroniLead! Magnesium1 Manganese! MercuryiNickel[Potassium(Selenium! Silver! Sodium! Thallium! VanadiumIZinc1

t1

Integ. tTime !(sec.) !i

5.00!5.00!5.00!5.00!5.00!5.00!5.00!5.00!5.00!5.00!5.00!5.00!5.00!

___ 5.001.1

5.00!5.00!

1

5.00!5.00!

1

5.00!5.00!

Concentration( U8/L )

______ 700000.0300000.0500000.0100000.0100000.0300000.04000OO.O300000.05000OO.O300OOO.O300000.0800000.0100000O.O

______ 200000 .0_

500000.01000000. O

20OOOO.O5000OO.O

200000.020OOOO.O

M

———

NR

NR

NR

Comments:

FORM XII - IN 7/8E

U.S. EPA - CLP

13PREPARATION LOG



Method: P_


SAS No.: _____ SDG No.:llAFD

! ERA! Sample! No.

! 11AFDI12BI13A!13BI13BOI13BSI14A!14AFB|14BI14BFD:ISAI15AFDI15BI15BFB1 16ABI17AI17B!17B&I17BS ____I18A!18BI5CFBISCFBb!5CFB«!ILCSSILCSSILCSWIPBSIPBSIPBW|

J

PreparationDate

02/19/9102/19/91_02/19/91 __02/19/91_02/19/91 _02/19/9102/19/9102/19/91_02/19/91 _02/19/9102/19/9102/19/9102/19/9102/19/9102/19/91_02/19/91_02/ 19/9102/19/9102/19/9102/19/9102/19/9102/19/9102/19/9102/19/91

_02/ 19/91J32/19/91_02/19/9102/19/91_02/19/9102/19/91

Weight(or am)

_ 1 .05_ 1.02 __ 1.151.061.111.081 .03

0.981.051 .000.971 .08

0 .96_ 0.95 _0 .991 .01

_ 0.99 _1 .061 .00

1 .03_ 1.00 _

1 .00_ 1 .02 __

VolumeCrnL)

__ 200__ 200__ 200

200200200200100200200200200200100200

__ 200 _200200

__ 200 _20O2001001001OO20020010020O

__ 200 _100

FORM XIII - IN 7/88

U.S. EPA - CLP

13PREPARATION LOG



Method: F_


SAS No.: _____ SDG No.:llAFD.

! EPA! Sample! No.

IllAFD ___! 12BI13AI13B|138fe ____!13BS ____I14A1 14AFB!14S114BFDUSA! 15AFD,'ISB! 15BFB! 1SBFB6llSBFBs!16ABI17A! 178I17B& ____I17B5 ____I18A! 18BISCFBILCSSILCSS!LCSUIPBS!PBSIPBU|

PreparationDate

02/18/91J32/18/91 _JJ2/18/9102/18/9102/18/91_02/18/9102/18/91_02/18/9102/18/9102/18/9102/18/91_02/18/91 _02/18/9102/18/9102/18/9102/18/9102/18/91_02/18/91_02/18/91_02/18/91_02/18/91_02/18/91_02/18/91_02/18/91_02/18/91_02/18/91_02/18/91_02/ 18/91_02/18/91_02/18/91

Weight(gram)

_ 1.01 _1.081.041.05

__ 1 .05 ___ 1.10 _

1 .05

1 .080.951 .00

_ 1 . 06 _1 .02

1 .081.021 .071 .051 .021 .081 .08

_ 0.98 _0.97

0.990.99

Volume(mL)

__ 200 ___ 200 _

200200

__ 200 ___ 200 _

200100200200200

__ 200 _200100100100200200200

__ 200 ___ 200 _

20020O10O

~200100200200...100

FORM XIII - IN 7/88

U.S. ERA - CLP

14ANALYSIS RUN LOG






SAS No.: _____ SDG No.:llAFD_

Method: P_

End Date: 02/21/91

t

i EPA,' SampleI No.

!SOIS!SIS! SIS1 ICV1 ICVlies'~*I

.SA1ICSAB1 ZZZZZ1ZZZZZ1 ZZZZZ1 ZZZZZi ZZZZZ! ZZZZZ:ccv1CCV1CCB1 ZZZZZ1 ZZZZZi ZZZZZ1 ZZZZZ1 ZZZZZ1 ZZZZZ1 ZZZZZ1 ZZZZZ1CCV1CCV1CCB

1 1

D/F ilimei * R1 11 |

1 .00!1123!1.0011125:1.0011127!1.0011129!1.001112911.00! 1131!1 .001113611.001113911 .0011142!1 .OOl 114511 .0011148!1 .001 1151 11 .00! 1154!1.0011157!1.0011201!1.001120411 .00! 1207!1.0011212!1.0011214!1.0011216!1.0011218!1.0011222!1 .0011225!1.0011228!1 .0011237!1.001124011 .0011243!1.0011246!1 .0011354!1.00! 1356!1.00! 1359!1 .0011401!

Analytes

L;B|S|Ai i iX I 1 v *

xi_ix:_x| !x|y 1 1 V >

x! |x;X I 1 v I

V 1 1 II 1 y I

x:_:xjx|_|x!x| |x[x| Jxji i i

i i *i * ii i it i ii i i

X i i ii i y i

X I 1 v I

1 i ii i ii i ii i ii i ii i tt i i

X I i i1 1 y 1

x!_!x,'_i i i

E D A 0 u E BMG«NHG

NIK SE

AG

NATL

V zN

FORM XIV - IN 7/80

U.S. EPA - CLP

14ANALYSIS RUN LOG




Start Date: O2/21/91



Method: P_

End Date: 02/21/91

! EPAI Sample! No.

! ZZZZZ! ZZZZZ! ZZZZZ! ZZZZZ! ZZZZZ! ZZZZZ! ZZZZZ; zzzzz! ZZZZZ

V, -V!CCB! ZZZZZ! ZZZZZ! ZZZZZiPBS!LCSS!M2FS-16A5IM2FS-17A1M2FS-18A! ZZZZZICCVICCV:ccsIM2FS-18BIM2FS-18B!M2FS-178!M2FS-17BIM2FS-17&IM2FS-17BIM2FS-17B3IM2FS-17BS

1 1

D/F ilime! * Ri ii ii i1 .OO! 1404!1 .OO!1407!1 .00! 1410!1 .OO! 1413!1 .OO! 1416!1 .OO! 1419!1 .00! 1422!1.0011425!1 .OO! 1429!1 .OO! 1431 !1.0011433!1 .OO! 1435!1 .OO! 1439!1 .OO!1442!1 .00! 1445!1.00! 1449!1.0011452!1 .OO115O2!1.00! 1505!1 .OOilSOS!1.0011525!1.00!l527!1 .0011529!1.0011531!1 .0011534!2.OO! 1537!1.0011540!2.0011544!1 .OO! 1547!2.OOil550!1 .OO! 1601 !5.0011604!

I 1

Analytes

LieI

i

I

i

jJi

x !

x 'i "~ii

x!_x:_X!_x|x'_x!xj_x:x!ix|x!

S

XX

XXXX

XXX

y

X

X

A E D ACRC0CuFEPB

MG N

HG

N K SE

AG

NATL

V zN

FORM XIV - IN 7/88

U.S. ERA - CLP

14ANALYSIS RUN LOG



Instrument ID Number: JA 9OOO



SAS NO.: _____ SDQ No.:llAFD.

Method: P_

End Date: 02/21/91

ERASampleNo.

Z2ZZZ __CCVCCVCCBCRIICSAICSABCCVCCVCB

D/F

___ 1.001.00

___ 1.001.001.001.001.001.001 .001 .00

Time

1608161016121614161716201623162S16271629

———

———

% R

——————

——————

Analytes

L

X

X

XX

X

SB

-

AS

XXXX

XX

BABECDC CR

C0CuFEPB

MG

MN G

NIK SE

A NA

TL

V 2N

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG






SAS No.: _____ SDG No.rllAFD.

Method: P_

End Date: 02/21/91

1

! EPA! Sample! No.1

ISO! SISt eISISIICV! ICV: ice' -91

JSA! ICSAB:PBSILCSS1M2FS-11AIIM2FS-11AIIM2FS-12BIM2FS-12B: zzzzz! CCVICCVICCB1M2FS-14B1M2FS-14B! M2FS-13AIM2FS-13AIM2FS-14BH1M2FS-14AIM2FS-15BIM2FS-15B! ZZ2ZZ!CCV

! ! ! An«lyt«si i >D/F ITime! % R |A|S!AiB

! I |L|B:S:A1 1 1 1 1 1

1.0011731! IX! !x!1.0011733! ix! !Xi1.00! 1735! IX! !x!1.0011737! IX! !X!1.0011739! IX! IX!1.OOI1741! IX! IX!1.0011743! !x! ! !1.0011745! I ! IX 11.0011747! !X! IX!1.0011751! IX! IXl1.00J1754! IX! IX!1.0011757! IX! IX!1.0011800! IX! IX!1.0011803! IX! !X!

o 1.0011806! ! I IX!& 10.0011810! IX! ! !

1.0011813! ! ! IX!2.0011816! _ IX! !!1.0011824! ! ! ! !1.00! 1826! IX! ! !1.00! 1828! ! ! !x!1.0011830! IX! !X!1.00! 1833! I ! IX!2.0011836! !xl I 11.0011839! ! ! !x!10.00!1842! IX! I I

•h 1.0011845! IXl !X!1.0011848! !X! IX!1.0011851! ! ! !X!2.0011854! IX! I I1.0011902! I I I !1.0011904! !xl ! !

1 ! I I I !

BE D A R 0 U E B G

MN G

NI

KE

AG

NA L

V zN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG



Instrument ID Number: JA 9000___




Method: P_

End Date: 02/21/91

1

1 EPA! Sample! No.iiccv!CCB1M2FS-15AIM2FS-15AIM2FS-15A'i M2FS-13BIM2FS-13B!M2FS-13Bt1M2FS-13B1" ->FS-13Bs

.FS-13BS,' ZZZZZICCVICCVIcesICRI! ICSAIICSAB __: ICSABICCVIccv: CCB __[1

1

;1!1

i

1 11 1r i

D/F inme! % R1 11 11 1

1.00! 190611.00! 190811.001191112.00119141

ffe ___ 1.00|1917|1.001192012.0011923!

, ___ 1.0011926! ______i 2.00119291

1.0011939!5.0011942!

___ 1 .00 I 1950 1 ______1 .0011952!1.00! 195411 .0011956!1.0011959!1.0012002!

___ 1.0012005! ______1 .00! 2005!1.0012007!

___ 1 .0012009!___ 1.0012011! ______

; |1 |I ji i1 ii ii i] ;

i i

Analytes

A|S|A|BL|B|S!A

1 1 1

1 1 v '

x!_|x|_!_|x!_

y t 1 1

x! |X|1 1 y 1

xj ! !1 1 y 1

y I I I

1 1 y 1

X I 1 1

X I 1 1

!_|x|X I 1 y i

X I i v ti | A |X I 1 y i

x:_ix}_x!_!X!_y 1 1 t

! !x!X I 1 y i

1 1 11 t 11 1 ii 1 i

i 1 1i 1 11 1 1

1 1 i

BEc0cACRc0cuFEPB

MG

MNHG

NIK SE

AG

NATL

V zN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG

,_ab Name: NORTHERN_LABORATORIES__






Method: P_

End Date: 02/22/91

EPAAnalytes

! SampleI No.1

:soISISis] 5ISIICVIICVIICBICRI:SA

, iCSAB1P8UILCSWILCSW

D/F 1 Time I % Ri i

1. 00 i 1302!1 .001 130411 .OOl 130611.00! 130711 .0011309:1 .001 131111.001131211.0011314!1.0011316!1.0011319!1 .0011322!1 .00! 1325!1 .00! 1328!1.0011334!1 .0011337!

1M2FS-5CFS 1.00113401|M2FS-5CF8|IM2FS-5CF81 ZZZZZICCVICCVICCBIM2FS-15BH|M2FS-14Aij:CRI! ICSA1 ICSABICCVICCVICCB|[!

t> 1.0011343!IS 1.00113461

1.0011349!1.0011351!1.0011353!1.00! 1355!

6 ___ 1.001135816 ___ 1.0011401!

1 .0011404!1.001140711.0011410!1.0011412!1 .00! 1414!1 .0011416!

1 1

I |

A!S|A|BUlBlSiA

i i iV 1 1 V I

X I 1 v 'i 1*1y 1 < V *

x!_!x;x! |xlX I 1 y '

v 1 1 11 1 y 1

X I 1 y 11 _t A 1

xl :x|xl |x|x! lx!x! |x|xl 1 !

1 1 y 1

xl !x|xl |x|XI |X|

1 1 1

X I 1 11 1 V '

x| !x!x I ! x !X I 1 y 1

x! |x!x! |xlx! |x|y 1 1 I '

1 1 w >

xl !x|> i ii i i• i i

BEcD

Q

AcR

C0cu E

PQ

MG N

HG

NIK S

EAG

N1

\J ZN

FORK XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG







Method: F_

End Date: 02/19/91

1 EPA! Sample! No.

ISOIS101S2S1S501S1OO1 ICVlies!CRA1 ZZZZZ1 -zzzz _:zzz

1 ZZZZZ! ZZZZZ! ZZZZZ! ZZZZZ1 ZZZZZ1 ZZZZZ!CCV1CCB1 ZZZZZ! ZZZZZ! zzzzz! ZZZZZ1 ZZZZZ1 ZZZZZ1 zzzzz1 ZZZZZ1PBW!PBUIAIccv1CCBIZZZZZZ1

1 1

1 1

D/F ITime!1 11 11 1

1.0010654!1 .001065911 .0010704!1.0010708!1 .0010713!1.0010718!1 .0010723!1 .0010727!1.0010732!

___ 1.00! 0737!1 .00 10742!1 .0010746!1.0010751!1 .0010756!1 .0010801!1 .0010806!1.0010811!1 .0010815!1.0010820!1 .0010825!1.0010829!1.0010834!1 .0010839!1.0010843!1 .0010848!

___ 1 .001085211.0010857!1.0010901!1 .001090611 .0010910!1 .0010915!1 .0010920!

* R

_102.0

Anal/tes

A S|A,'BL B l S l A

1 1

_ _lx|!x!_1 v '

- _|x||x|_1 y '

_!x!I X !i ii i_ — ' 1 1 • —[ [i ii ii ii i

!x|1 v I

1 11 11 11 11 1

1 11 11 y '1 v '

1 y <

_:x!i i

BE

CD

CA

CR

C0

Cu

FE

PB

MG

MN

HG

NI

K SE

AG

NA

TL

V zN

FORM XIV - IN 7/8S

l/L*

U.S. EPA - CLP

14ANALYSIS RUN LOG







Method: F_

End Date: 02/19/91

EPASampleNo.

ZZZZZZZZZZZZZZZZZZZZM2FS-15BILCSULCSUAM2FS-14AM2FS-14A— :V

ii

D/F ITime

1 .00109241.00109291 .00109341 .OO10939

ftS __ 1 .00109441 .OO 109481.0010953

•6 ___ 1 .0010958raa_i .0011003• 1.00110071 .0011015

1

1

;;|i!;iijt

Iii

ijIi

!

% R

86.5

_ 100.5

——————

Analytes

* SB

A

XXxxXX

BABE D A R

C0 u E B

MG

MNHG

NI

K SE G

NATL

V zN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG






SAS NO.: _____ SD6 No.:llAFD_

Method: F_

End Date: 02/19/91

EPASampleNo.

SOS10S25S50S100ICVICBCRAM2FS-5CF8"2FS-5CF*>FS-15B*

M2FS-15*M2FS-15B(jM2FS15BFIZZ222Z22ZZZZZZZCCVCCS

i ii ii iD/F ilimei % R

1 11 11 1

1.0011131!1.0011136!1.0011141!1 .00! 1146!1.0011150!1.0011155!1 .00! 1200!1.00! 1205!1.00! 1209!

h 1.0011214!fc ___ 1 .0011219!3& __ 1.00! 1224!aa _ i .oo|i228lbA 1.0011233!

1.0011238!1.001124311 .0011248!1.0011253!1 .00 11257!i t

i ii ti ii ii ii ii i[ II !i ii i| !! ii r

Analytes

* S|A|BBISlA

1 1

1 v 'I v '

1 v I

1 v I1 v '1 v 1

!X|IX!1 v '

1 y '

1 X i! x l!x|lx I• '1 j1 |ix|!x|j [i ii ii ii ii ii ii i

i ii ii ii ti i

BEcDCA

Q

RC0cuFEPB

MG

MN G

Nj

K SE

AG

NATL

V zN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG







Method: F_

End Date: 02/20/91

I EPA! Sample! No.iISO1S101S25ISSO1S1001ICV! ICB1CRAIZZZZZ1 -?zzz

.ZZZ! ZZZZZ!ZZZZZIZZZZZ! ZZZZZ! zzzzz1 ZZZZZICCVices! ZZZZZ! ZZZZZ! ZZZZZIZZZZZ1 ZZZZZ! ZZZZZ! ZZZZZIZZZZZI ZZZZZIZZZZZICCVices: zzzzz

1 11 t

D/F ITime! * R1 11 1I 1

1.0010659!1. 0010703!1 .00! 0708!1.00!0713!1 .00! 0718!1.0010723!1.00! 0727!1.0010732!1.00! 0737!1.00! 0741!1 .00! 0746!1.00! 0751!1 .0010756!1 .00! 0801!1 .00! 0805!i .ooioeio!1 .0010815!1 .0010820!1 .00! 0824!1 .OO!O829!1 .00! 0834!1 .0010838!1 .0010843!1 .00(0847!1 .0010852!1 .00! 0856!1 .0010901!1.0010906!1 .0010910!1 .0010915!1 .001092011 .0010924!

1 1

Analyt«sA SIAIB

B!S|A1 11 v 11 y 11 v I1 y 1

1 v I

'x!_!xj_!x|1 t1 t1 11 t1 11 1t t1 11 1

'y '1 y '1 11 11 11 11 1

1 11 11 11 1t v '1 y 1

1 11 1

BEcDcAcRc0cuFE

pB

MG

MNHG

NIK sE^G

NAT V z

N

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG







Method: F_

End Date: 02/20/91

\ EPA! Sample! No.1

1 ZZZZZi ZZZZZ! ZZZZZ: zzzzz! ZZZZZ! ZZZZZ: zzzzz: zzzzz! ZZZZZ' rv

.B! ZZZZZ! ZZZZZ! ZZZZZ! ZZZZZ! ZZZZZ! ZZZZZICCV1CCBiccvICCB! ZZZZZ1 ZZZZZ! ZZZZZ! ZZZZZi zzzzz! ZZZZZ! ZZZZZ! ZZZZZ: zzzzz! ZZZZZICCV

1 1

D/F JTime! % R1 1

1 .0010929!1 .0010934!1 .001093811 .0010943!1 .0010948!1 .00! 0953!1 .00! 0958!1 .OOI1002!1.0011007!1.00! 1012!1 .00!1016!1 .OO! 1021!1 .0011025!1 .0011030!1 .00! 1034!1.00! 1039!1 .0011044!1 .0011048!1 .OOI1OS3!1 .OO 11059!1.0011104!1 -OO!1109!1 .OO!1113!1 -OOilllS!1 .00!1123!1 .00)1127!1.00!1132!1.00!1137!1 .00!1142!1 .0011147!1 .0011152!1 .00(1156!

1 1

Analyta

L B S

xXXX

X

A E D ACo

c0

cu

FE

PB

MG

MN

HG

NI

K1

AG

NA

TL

V 2N

FORM XIV - IN 7/88

U.S. ERA - CLP

14ANALYSIS RUN LOG

Lab Name: NORTHERNJLABORATORIES__






Method: F_

End Date: 02/20/91

EPAAnalytes

! Sample | D/F iTimei \ R1 No. ! ! !

1CCB ! 1.0011201!IM2FS-13A! 1.0011206!!M2FS-14Btrj 1. 00! 1210!IM2FS-14A! 1.001121511M2FS-13B! 1.0011220!!M2FS-13Bk 1.0011224!1M2FS-15B! 1.001122911M2FS-15A! 1.00112331!M2FS-15Afl> 1.0011238!1'7ZZZ 1 1.0011242!

ZZZ 1 1.0011247!iLCV ! l.OO 11252!!CCB 1 1.0011256!1M2FS-14B! 1.0011301!1M2FS-12B| 1.00|13O6l!M2FS-11A*& ._ 1.0011310!!M2FS-16Afi 1.001131511M2FS-17A! 1.001132011M2FS-17B! l.OO 11325!1M2FS-17B& 1.0011330!1M2FS-18A! l.OO! 133411M2FS-18B! 1.001133911ZZZZZ ! l.OO 11344!1CCV 1 1.0011348!!CCB 1 1.0011353!le€S ———— ! ———— 1.00! 1053! ——————— '1 1 I It 1 I I1 1 I I

< 1 I I1 1 I I

ALsB

AS

X

XX

XX

BABE

<}

CD

»/,

CA

sl

CR 0

CUFEPB

MG

MNHG

NI

K

I GNA

T V zN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG







Method: F_

End Date: 02/20/91

1

1 ERA! Sample! No.1

ISOIS10!S25IS50IS100! ICVIICB!CRA1M2FS-17A"">FS-17B

FS-17BIM2FS-17BIM2FS-18AIM2FS-18AIZZZZZ! ZZZZZIZZZZZICCVICCBIM2FS-18B1M2FS-18B*', M2FS-16A!1M2FS-16ASIM2FS-17A1M2FS-17A"1M2FS-17B1M2FS-17B*! ZZZZZ

I Ii i

D/F iTime! % R1 11 11 1

___ 1 .0011451! ______1.00! 1456!1 .0011501!1 .0011506!1 .0011510!1.0011516!1 .00! 1520!1.00! 1525!5.00I1S29!

S 5.0011534!5.00I1S39!

& 5.0011544!5.0011549!5.0011554!1.00|1558i1 .0011603!1 .0011608!1 .0011613!1 .0011617!5. OO 1162215.0011627!5.0011631!

<\ ___ 5.0011636!__ 10.00116411

1 .0011645!1 .0011650!1 .0011654!1 .0011659!

! ZZZZZ ! 1.0011703!!CCV ! 1.00117081ICCB 1 1.00117131IM2FS-18A! __ 10. 00 I 17171 ______i I • i

Analytes

AL

SlAlBBlSlA

1 1

1 y '1 w 1

1 y 1

|x|1 y >

!x|1 y 1

1 y *

1 1

1 1

1 1

1 1

t I

1 1

1 y 1

!x|i ii ii ii ii ii ii it i|x!1 y 11 |

1 |

BE

CDCACRC0Cu

fz. pB

MG

MNHG

NI

K S AG

NA

TL

V zN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG

Lab Name: NORTHERNJLABORATORIES__






Method: F_

End Date: 02/20/91

EPA !Sample ! D/FNo. 1i

M2FS-18AM2FS-16AJM2FS-16A(M2FS-18BM2FS-18&MSFS-178CM2FS-17BdZZZZZZZZZZ __<-rv

B

1.001.00

k __ i.ooi .0010.00

1 10.00<3 __ 10.00

1 .00___ 1 .00

1.001 .00

Time

17221727173117361741174617511755180018051809

% R

_-*+**»

——————

——————

Analytes

A

£

SB

(is

AS

5

XX

BA

BECDCACRC0Cu

FEPB

MG

MN

HG

NI

SE

£

GNATL

V zN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG

uab Name: NORTHERNJ.ABORATORIES__



Start Date'- 02/21/91



Method: F_

End Date: 02/21/91

\ EPA! Sample! No.iISOIS10!S251S50:sioo! ICVlies1CRA1PBSiOBSA:ss

.i-CSSA __1M2FS-16AS1M2FS-16A*1M2FS-17A1M2FS-17A/1ZZ22Z1CCV1CCB1M2FS-17B1M2FS-17BJ1M2FS-17BC1M2FS-17BCIM2FS-18A1M2FS-18A*1M2FS-18B1M2FS-18B*IZZZZZ

D/F iTime! % R1 1

1 1

1 .001072511 .0010729!1 .0010734!1 .001073911 .0010744!1 .0010749!1 .0010754!1.00! 0758!1 .001080311.0010808! 99.0

100.0010812!_ 100 .00 | 0817 ! __ 99 .0

15.0010822!() __ 15.0010827! __ 97.0

15.0010832!__ 15.0010837! 111.0

1 .00! 0841!1 .0010846!1.0010851!

__ 1 5 . 00 ! 0855 1 ; ______k 15.0010900! 97.0> 15.0010905!>g __ 15 .0010909! __ 97.0

15.001O9141__ 15.0010913! 101.5__ 15.00|0923| ________ 15.0010927,' __ 97.0

1.00! 0932!1ZZZZZ 1 1.0010936!!CCV ! 1.0010941!1CCB ! l-OO 10946!IM2FS-11AH1 1

•fc 5. OO 10950!i i

Analytes

LS i A ! BB!S!A

1 1

1 v l

|x|_|X|IX!1 y 1

1 y l

' y '1 y I

' V '

'X!1 v '

!X|!xj1 y l1 v '1 y 11 11 y 1

'y '1 y 1

1 y I1 y '

_!X!__:x;_|x|1 y 1

1 j^ »1 l

1 v '

!X!i ii i

BE

CDCACR

C0

Cu

FEPS

MG

M|HG

NIK

.

SE

AG

NATL

V zN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG


Lab Code: NLE_— Case No.: ERM_





Method: F_

End Date: 02/21/91

EPASampleNo.

M2FS-13B(M2FS-14BM2FS-15BM2FS-12BM2FS-1SAM2FS-13AM2FS-15AJ!ZZZZZZZZZZT;Va

M2FS-14AM2FS-14BI!M2FS-13BZZZZZ22ZZZZZZZZCCVCCB

1 11 t1 1

D/F ITime! % R1 11 11 1

k 5.0O!095S!5.OOI10OO!S.OOilOOS!5.0011010!5.0O! 1014!5.00! 1019!

"Ts 5. 00! 1024!1 .0011029!1.00! 1033!1.00! 1038!1 .00! 1043!5. 00! 1047!

Lft 5. 00! 1052!5. 00! 1056!1 .00! 1101!l.OOillOS!1. OOllllO!1.0011115!1 .00! 1119!

i it ii ii ii ti ii ii ii ii ii i| |

Analytes

ALsB

Ae

Xy

Xy

BA

BECDCACRC0CuFEPB

MG

MN

HG

NI

K S AG

NAj V z

N

FORM XIV - IN 7/38

U.S. ERA - CLP

14ANALYSIS RUN LOG

LaO Name: NORTHERN_LABORATORIES__






Method: F_

End Date: 02/22/91

EPASampleNo.

SOS10S25S50S100ICV ____ICBCRAM2FS-11AI(""FS-11AI*

-S-14Bn2FS-14B<!M2FS-13AM2FS-13AIM2FS-15BM2FS-15B*ZZZZZCCVCCB

1 1

D/F jTime! % Ri ii ii >1 .0010723!1 .00! 0727!1 .00! 0732!1 .00! 0737!1.00! 0742!1 .0010747!1 .0010752!1 .0010756!

•b 10.0010801!t£ _ 10 .00 I 0805 ! _ 121 .0

10. OO! 0810!k 10.0010815! _ 101.0

10. 00 : 0820!__ 10 .00 ! 0825 ! _ 100 .5

10.0010830!__ 10 .00 1 0834 ! _ 110 .0

1 .OOIO839!1 .00! 0844!1 .0010849!

t 1

1 1

1 1

[ I

1 1

1 1

1 1

1 1

1 1

! ;! !

Analytes

AL

SIAIBB!S|A

I 1

1 y 1

!x|!x}1 y I

1 y 1

1 v '

:xi|x|lx|_|x|lx|I v '

i y '1 y '1 y '1 11 y 1

1 y 11 11 I

1 1

1 1

1 1

1 j

1 1

BECD

CACRC0

CuFEPB

MQ

MN

HG

NI

K SE

AG

NATL

V zN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG

l_ab Name: NORTHERN_LA80RATORIES__






Method: F_

End Date: 02/22/91

: EPA! Sample! No.1

ISO!S10!S25IS50!S100IICV!ICBICRAIM2FS-14A'"2FS-14A*!

;FS-12B,M2FS-12B>IM2FS-13BIM2FS-13B|M2FS-15Af!IM2FS15AR*! ZZZZZ!CCVICCBIM2FS-15A1 ZZZZZ!M2FS-13BtiIM2FS13BD4IZZZZZ: zzzzz: zzzzz!M2FS-13KIM2FS-17B1! ZZZZZ:ccvICCBIM2FS-14A

D/F irime! * Ri ii ii i1.001100411.001100811.001101311.0011018!1 .00! 102311.0011028!1 .0011032!1 .0011037!10.0011042!10.00! 1046!10.00! 1051 !10.0011056!lO.OOlllOl!

__ 10.00|1106| __ 80.5b 10.00!lllO!« __ 10.0011115! __ 80.5

1 .0011120!1.0011125!1 .OO! 1130!10.OOI1134I1 .0011139110.00!ll43i

__ 10.00|1148! 100.01.0011153!1 .0011157!1.00! 1202!15.0011206!

__ 15.00!l21l!1 .0011215!1.00! 1220!1.0011225!15.0011229!

! !

Analytes

AL

SIAIBB!S|A

1 1

_!x|!x|_:xi-!x|.ix:!x|!x|1 v »

1 11 1

' V 'ly 1 .

' y '* v 'i i1 y 1

1 y 1I 1

1 1

1 y 1

_!x;i i1 ji i1 y 1

!x|1 1

!X|_!X!

1 y 11 I

BECDCACR

C0CuFEPB

MG

MNHG

NI

K SE

AG

NA

T V zN

FORM XIV - IN 7/88

U.S. EPA - CLP

14ANALYSIS RUN LOG






SAS No.: _____ SOG No.:llAFD.

Method: F_

End Date: 02/22/91

EPASampleNo.

M2FS-14A<M2FS-12BM2FS-12B/M2FS-15AM2FS-15A<ZZZZZ __'TZZZ __ZZZZZZZZ*va

12FS-14BI1•12FS-14BILCSSLCSSAPBSPBSACCVCCB

i iD/F ilimei * Ri i

i i__ 15 .00 ! 1234 ! _ 101 .0__ 15.00! 1239! ________ 15 .00 ! 1243 ! _ 106 .0

15.0011248!It __ 15. 00! 1253! __ 90.0___ 1 .00 ! 1258 ! ______

1 .00! 13O3!1 .00! 1308!1 .00! 1312!1 .0011317!1.0011322!

b __ 10. 00! 13261 ______t£ __ 10.00! 1331 ! _ 108.0

100. OO! 1335!100.0011340! 52.0

1 .0011344!1.00! 1349! 90.51.0011354!1 .OO! 1358!i i

i ii ii ii ii i| || || ]

i i[ [i <! !

Analytes

A SlAlBBlSlA

1 1

1 y 1

1 v 1

1 y 'i A i1 y 1

j x [1 \1 1

1 1

1 y 1

_!*!_IX];xj1 y 1

lx!i X i

_!x!__!x!_

1 11 i1 I1 iI |1 iI i

I I1 i

1 II t

I 1

1 II i

BECD

CACRC0 u

FEP8

MG

MN

HG

Nj

K SE

AG

NATL

V zN

FORM XIV - IN 7/88

SECTION 4

PROJECT CASE NARRATIVES AND CHAIN-OF-CUSTODIES

NORTHERN LABORATORIESA NvMon 01 CoMtto CoMt Amlyfetf SffvteMENVIRONMENTAL CONSULTING AND TESTING

R E C E I V E DMAR 15 JS91

CENTRAL; me.Case Narrative

These samples were analyzed under the CLP Statement of Work 7/88.The analysis of arsenic by graphite furnace atomic absorption wasperformed with Zeeman background correction, L'vov platformatomization, and a nickel nitrate matrix modifier. A copy of thearsenic program has been included with this narrative. Analyticalspikes were added at a concentration of 20 ppb. Due to the highconcentration of aluminum in these samples, severe interferenceswere encountered in the analysis of arsenic. Successive dilutionswere made to reduce the interferences so that a value for arseniccould be obtained. All raw data, undiluted and diluted, isincluded in the data package.

Beth Janssen, CLP/Metals Manager

?dnn rt IMRPDI Awn no V/AI

cKn-nortn central, it.,.Sample Chain of Custody

Satan Locafcn

fiLr

olContainers

7\Remfflte

"5F7^<zr

•y vo.<

y- M=U

Sample Relinquished Cy: Date Tune Sample Received by: Date Tune (or Tr

COPtS; V*aoSrefa«ic(»saaa<p»vs»n(**pniw(lDH)a*i» Veto* aw Mailed bjttaaay. HHaa)>rk>lBMUu(llaERMbrllK. ft* apy retried by sarffci. GoU oqjy Ma opy as \

ERM-North Central, f IKSample Chain of Custody

OOHE& W *Y«Io»oâoa»ipM»s«»|*>ship«M«lotoB*»y. Veto* apyirtamedbr Hboraay. If -cpr te be .awed c ERU tr te Pink copy rdaihed by saiplef. Gold apt «*a copy

ERM-North Central, in(.Sample Chain of Custody

.^dtoma./ ..'. 'to (•:.t-\ __ Mav.^/

ERMSampleNutter

Dab Tim Sabn LocationCortainers

Remarks

•••ill

Mo I/IDS'1 t/ of

Sample Relinquished by: Daten Tune Sample Received by: Dale Time Reason (of Transfer

COPIES: W Yebw copies accompany sanpb stjmert to ttnatoy. refcv copy Manx! by Hwatoy. V wtotetdumdttERMtarlte . Hr* copy retained by an?*). GcH tcpy etfra op/as I

ERM-NofthCcntraliiTChain of Custody

Renaks

Awr*/ I/y

!>*•>

• /w'/V I/r.\)» y

not i fSample Reinquished tif. Dab TIM Sampte ReoeiMd tif. Dab Tme Reason for Transfer

31

OOTCS:

ERM'North Central 1C .nVv* Sample Chain of Custod

top* tewt f-H

EfiUDM fim Sfefen Dcain Remarks

/'Y* &tt/

T___-j ..s'______^

^3 - // A'V«/«> - />&

1 1 - l i t ]

-kfrSample Haina»itot by: Date

hr>Tma Sampte Racew^ by; Dale rine Reason far Tr

DOPES »«W«

Documents

ERM INC - ALUMINUM RICH FILL STUDY PROJECT - … · 14A 14B 14BFD ISA 15AFD 15B 16AB 17A 17B 18A 18B 14AFB 15BFB 5CFB. Section 1 Quality Assurance Review ... (Form VA), the laboratory