1
M. Okamoto 1 , K. Kakushima 2 , P. Ahmet 1 , Y. Kataoka 2 , A. Nishiyama 2 , N. Sugii 2 , K. Tsutsui 2 , K. Natori 1 , T. Hattori 1 , and H. Iwai 1 1 Frontier Research Center, Tokyo Institute of Technology 2 Interdisciplinary Graduate School of Science and Technology, Tokyo Institute of Technology [email protected] Extraction of Energy Band Diagram of AlGaN/GaN with SiO 2 Capped Annealing using X-ray Photoelectron Spectroscopy ρ c is currently 10 -5 cm -2 . ρ c is necessary with 10 -6 cm -2 for lateral GaN device Power electronics material Resistance of GaN Conclusions XPS measurement of AlGaN Purpose Al 1s with SiO 2 -capped annealing shifted to large band energy N vacancy can be formed AlGaN layer SiO 2 -capped annealing can expect the formation by uniform contact by combining it with TiSi 2 electrode We would like to thank Prof. Nohira with Tokyo City University for XPS measurement non annealing annealing 0 500 600 400 300 700 800 900 950 200 100 0 500 600 400 300 700 800 900 950 200 100 3.0 2.5 2.0 1.5 1.0 0.5 0.0 0 500 600 400 300 700 800 900 950 200 100 0 500 600 400 300 700 800 900 950 200 100 3.0 2.5 2.0 1.5 1.0 0.5 0.0 Voltage[V] 0 500 600 400 300 700 800 900 950 200 100 0 500 600 400 300 700 800 900 950 200 100 3.0 2.5 2.0 1.5 1.0 0.5 0.0 0 500 600 400 300 700 800 900 950 200 100 0 500 600 400 300 700 800 900 950 200 100 3.0 2.5 2.0 1.5 1.0 0.5 0.0 TiSi 2 with SiO 2annealing TiSi 2 without SiO 2annealing Voltage[V] 2.0 0.5 1.0 1.5 0.0 -0.5 -1.0 -1.5 -2.0 -5 -2 -1 -3 -4 0 1 2 3 4 5 -5 -2 -1 -3 -4 0 1 2 3 4 5 Current[mA] Volt age [V] 2.0 0.5 1.0 1.5 0.0 -0.5 -1.0 -1.5 -2.0 2.0 0.5 1.0 1.5 0.0 -0.5 -1.0 -1.5 -2.0 -5 -2 -1 -3 -4 0 1 2 3 4 5 -5 -2 -1 -3 -4 0 1 2 3 4 5 Current[mA] Volt age [V] TiSi 2 without SiO 2annealing TiSi 2 with SiO 2annealing 2.0 0.5 1.0 1.5 0.0 -0.5 -1.0 -1.5 -2.0 -5 -2 -1 -3 -4 0 1 2 3 4 5 -5 -2 -1 -3 -4 0 1 2 3 4 5 Current[mA] Volt age [V] 2.0 0.5 1.0 1.5 0.0 -0.5 -1.0 -1.5 -2.0 2.0 0.5 1.0 1.5 0.0 -0.5 -1.0 -1.5 -2.0 -5 -2 -1 -3 -4 0 1 2 3 4 5 -5 -2 -1 -3 -4 0 1 2 3 4 5 Current[mA] Volt age [V] TiSi 2 without SiO 2annealing 2.0 0.5 1.0 1.5 0.0 -0.5 -1.0 -1.5 -2.0 -5 -2 -1 -3 -4 0 1 2 3 4 5 -5 -2 -1 -3 -4 0 1 2 3 4 5 Current[mA] Volt age [V] 2.0 0.5 1.0 1.5 0.0 -0.5 -1.0 -1.5 -2.0 2.0 0.5 1.0 1.5 0.0 -0.5 -1.0 -1.5 -2.0 -5 -2 -1 -3 -4 0 1 2 3 4 5 -5 -2 -1 -3 -4 0 1 2 3 4 5 Current[mA] Volt age [V] 950 o C TiSi 2 without SiO 2annealing TiSi 2 with SiO 2annealing Al 1s with SiO 2 -capped annealing shifted to large band energy N vacancy is formed about 1.7×10 17 cm -3 Al1s 0.2eV SiO 2 AlGaN GaN Band Structure of Al 1s Tunneling currents increase N vacancy is formed AlGaN layer O atom from SiO2-capped is possible to be in N vacancy TiSi 2 electrode with SiO 2 -capped annealing is obtained decrease trend Currentvoltage characteristics TiN/TiSi 2 Fabrication Process Results Introduction Low metal function which reacts area metalTiSi 2 electrode (metal function 4.5eV melting point 1540 o C) Nitrogen vacancy by SiO 2 T.Hasizume,J.Vac.Sci. Technol,B 21(4)(2003) Realization of low contact resistance Low contact resistance of approach ①Forming nitrogen vacancy Tunneling AlGaN layer 100 1000 1000 10 1 0.1 0.01 C g =35nF/cm 2 L ch =0.5µm V g -V th =5V 縦型 GaN デバイス 限界 ρ c =10µΩcm 2 1µΩcm 2 0.1 µΩcm 2 0.01 µΩcm 2 横型 Si デバイス限界 750V 60% Loss Limit of vertical GaN devices Limit of lateral devices Lateral GaN device Voltage(V) R on A (mcm 2 )

Extraction of Energy Band Diagram of AlGaN/GaN …...Extraction of Energy Band Diagram of AlGaN/GaN with SiO2 Capped Annealing using X-ray Photoelectron Spectroscopy ρcis currently

  • Upload
    others

  • View
    12

  • Download
    0

Embed Size (px)

Citation preview

Page 1: Extraction of Energy Band Diagram of AlGaN/GaN …...Extraction of Energy Band Diagram of AlGaN/GaN with SiO2 Capped Annealing using X-ray Photoelectron Spectroscopy ρcis currently

M. Okamoto1, K. Kakushima2, P. Ahmet1, Y. Kataoka2, A. Nishiyama2, N. Sugii2, K. Tsutsui2, K. Natori1, T. Hattori1, and H. Iwai11Frontier Research Center, Tokyo Institute of Technology

2Interdisciplinary Graduate School of Science and Technology, Tokyo Institute of [email protected]

Extraction of Energy Band Diagram of AlGaN/GaN with SiO2 Capped Annealing using X-ray Photoelectron Spectroscopy

ρc is currently 10-5 Ωcm-2.

ρc is necessary with 10-6 Ωcm-2

for lateral GaN device

Power electronics materialResistance of GaN

Conclusions

XPS measurement of AlGaN

Purpose

Al 1s with SiO2-capped annealing shifted to large band energy

N vacancy can be formed AlGaN layer SiO2-capped annealing can expect the formation by uniform contact by combining it with TiSi2 electrode

We would like to thank Prof. Nohira with Tokyo City University for XPS measurement

non annealing

annealing

0 500 600400300 700 800 900 9502001000 500 600400300 700 800 900 950200100

3.0 2.52.01.51.00.50.00 500 600400300 700 800 900 9502001000 500 600400300 700 800 900 950200100

3.0 2.52.01.51.00.50.0

TiSi2 with SiO2annealing

TiSi2 without SiO2annealing

Voltage[V]0 500 600400300 700 800 900 9502001000 500 600400300 700 800 900 950200100

3.0 2.52.01.51.00.50.00 500 600400300 700 800 900 9502001000 500 600400300 700 800 900 950200100

3.0 2.52.01.51.00.50.0

TiSi2 with SiO2annealing

TiSi2 without SiO2annealing

Voltage[V]

2.0

0.51.01.5

0.0

-0.5

-1.0-1.5

-2.0-5 -2 -1-3-4 0 1 2 3 4 5-5 -2 -1-3-4 0 1 2 3 4 5

Curre

nt[m

A]

Voltage [V]

2.0

0.51.01.5

0.0

-0.5

-1.0-1.5

-2.0

2.0

0.51.01.5

0.0

-0.5

-1.0-1.5

-2.0-5 -2 -1-3-4 0 1 2 3 4 5-5 -2 -1-3-4 0 1 2 3 4 5

Curre

nt[m

A]

Voltage [V]

950oCTiSi2 without SiO2annealing

TiSi2 with SiO2annealing

2.0

0.51.01.5

0.0

-0.5

-1.0-1.5

-2.0-5 -2 -1-3-4 0 1 2 3 4 5-5 -2 -1-3-4 0 1 2 3 4 5

Curre

nt[m

A]

Voltage [V]

2.0

0.51.01.5

0.0

-0.5

-1.0-1.5

-2.0

2.0

0.51.01.5

0.0

-0.5

-1.0-1.5

-2.0-5 -2 -1-3-4 0 1 2 3 4 5-5 -2 -1-3-4 0 1 2 3 4 5

Curre

nt[m

A]

Voltage [V]

950oCTiSi2 without SiO2annealing

2.0

0.51.01.5

0.0

-0.5

-1.0-1.5

-2.0-5 -2 -1-3-4 0 1 2 3 4 5-5 -2 -1-3-4 0 1 2 3 4 5

Curre

nt[m

A]

Voltage [V]

2.0

0.51.01.5

0.0

-0.5

-1.0-1.5

-2.0

2.0

0.51.01.5

0.0

-0.5

-1.0-1.5

-2.0-5 -2 -1-3-4 0 1 2 3 4 5-5 -2 -1-3-4 0 1 2 3 4 5

Curre

nt[m

A]

Voltage [V]

950oCTiSi2 without SiO2annealing

TiSi2 with SiO2annealing

Al 1s with SiO2-capped annealing shifted to large band energy

N vacancy is formed about 1.7×1017cm-3

Al1s

0.2eV

SiO2 AlGaN GaN

Band Structure of Al 1s

Tunneling currents increase

N vacancy is formed AlGaN layer

O atom from SiO2-capped is possible to be in N vacancy

TiSi2 electrode with SiO2-capped annealing is obtained decrease trend

Current‐voltage characteristics

TiN/TiSi2

Fabrication ProcessResults

Introduction

①Low metal function which reacts area metal→TiSi2 electrode(metal function 4.5eV melting point 1540oC)

② Nitrogen vacancy by SiO2T.Hasizume,J.Vac.Sci. Technol,B 21(4)(2003)

Realization of low contact resistance

Low contact resistance of approach

①Forming nitrogen vacancy ②Tunneling AlGaN layer

100 1000 1000

10

1

0.1

0.01オン抵抗

, Ron

A(m

Ωcm

2 )

Cg=35nF/cm2

Lch=0.5µmVg-Vth=5V

縦型

GaNデバイス限界

ρc=10µΩcm2

1µΩcm2

0.1µΩcm2

0.01µΩcm2

損失60%減横型

Siデバイス限界

750V 横型GaNデバイス

60% Loss

Limit o

f vert

ical G

aNde

vices

Limit of la

teral devices Lateral GaN

device

Voltage(V)

R o

n A

(mΩ

cm2 )