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OU&2L,
MONTGOMERY WATSON
February 23. 1999
RECEIVED
FEB 2?SUPERFUND DIVISION
L v..,..
MW #1217431.010305
Ms. Diana EngemanEPA Project CoordinatorSuperfund Branch, Waste Management DivisionU.S. Environmental Protection Agency. Region VII726 Minnesota AvenueKansas City, KS 66101
RE:: Former Manufactured Gas Plant SiteClinton, IowaDocket No. VII-97-F-0020
Dear Diana:
Enclosed for your use and files are copies of the qua l i ty control data from the U n i v e r s i t y ofIowa Hygienic Laboratory for the soil and groundwater split samples collected at theClinton manufactured gas plant site. Montgomery Watson reviewed the data and updatedthe project database by assigning "I" flags to samples potential ly effected by q u a l i t y controldata outside the prescribed l imi ts . For your convenience, an electronic copy of the updateddatabase files w i l l be sent via e-mail.
If you have any questions, please feel free to contact Bruce Greer at (608) 252-3948 or me.
Sincerely,
Randy J. Kroneman. P.G.Project Manager
/rjk:vasEnclosurescc: Bruce Greer, Alliant/Interstate Power Company
Johanshir Golchin. Iowa Department of Natural Resources (2 copies)Laura Clemenson. Sverdrup Environmental
SOQ085842SUPERFUND RECORDS
1 1 1 0 / A.j'iyj[)(;:, Moi'if-'j lW3?? 7938
Tel SIS 253 0830Fax 515253959?
, ?o?i Response Factor Report 7201
Method : J:\7201\METHODS\SOIL8260.M (RTE Integrator)Title : GC/MS TCL 8260 volatiles for low level soilsLast Update : Mon Dec 15 08:50:31 1997Response via : Continuing Calibration
Calibration Files
1)2)3)4)5)6)7)8)9)
10)11)12)13)14)15)
16)17)18)19)20)21)22)23)24)25)26)27)
9 Q \£. O /
29)30)31)32)33)34)35)36)37)38)39)
10100
ITTCTCTMTCTTTGTTCTCSTCT
T
TCTCMTCMTCTTCTCTCTCTCTC
ISTMTCTCTMTCT f~*
GTCTCS"-./-,
=5349103. D 20=5349105. D 200
Compound
Bromochlorome thaneChl or ome thaneVinyl ChlorideBromome thaneChloroethane1 , 1 -DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2 -Dichloroethene (t1 , 1 -Dichlo roe thaneChloroform1 , 2 - Dichlo roe thane-d41 , 2 -Dichlo roe thane2 -Butanone
1 , 4 -Dif luorobenzene1,1,1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBromodlchlorome thaneCis- 1 , 3 -DichloropropeTrans - 1 , 3 -Dichloropro1,1,2 -TrichloroethaneDibromochlorome thaneBromof orm
("*}") 1 (~>T~O ^ n 7 pn £» - (\ 5^ _ 1 1 A. \J 1_ \-J *^ ~ » 1 £* C 1 1C V_4 -J
Toluene-d84 -Methyl -2 -PentanoneTolueneTetrachloroethene2 -HexanoneChlorobenzeneEthyl benzeneXylene (total)StyreneBromof luorobenzene1,1,2,2 -Tetrachloroet
11101311133231
00100000000
101001001VJ
0
= 534!= 534!
10
.707
.405
.230
.891
.400
.807
.055
. 872
.795
.357
. 942
. 846
.558
.874
.642
.564
. 131
.416
.453
.833
. 727
. 707
.405
. 599
.654
.286
. 976
.581
. 555
.747
. 103
. 528
.641
. 173
. 855
. 858
3131
11101311133231
00_^
00rs•-J
00000
10]_0rf\^
•i
^~
04 .D06 .D
20
.502
.142
.088
.808
.276
.463
.OG6
.684
.647
.084
.640
.455
.237
.561
.581
.506
.023
.371
.413
.765
.664
.651
.370
.551
.591
.113
.851
.435
.498
.605
. 993
.475
.578
.054
.713
. 767
11101301i.1.33231
00000000000
10100000100
50
50
.554
. 189
. 105
.830
.283
.323
. 928
.617
.618
.007
.539
.623
. 112
.508
- - T c
. 576
. 507
. 993
. 366
.401
.745
.648
.641
.360
. 541
.604
. 199
.805
.394
.492
.559
. 968
.465
.574
.048
.774
.755
1
-t rpT-vD ID
1 .0 .1 .0 .1 .3 .0 .1 .1 .3 .3 .2 .3 .1 .
-t >"pr-iD I D
0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0.
"* TTDID
1 .0 .1 .0 .0 .0 .0 .0 .1 .0 .0 .
= 53
00
401 1933 0033 1804 0257 1293 3723 0615 1603 1012 3524 3430 2043 2293 1
585 0514 0988 0355 0403 0757 0652 0640 0352 0538 0570 0
134 1781 0377 1477 0557 0955 0462 0573 0048 1726 0713 C
49S01
200
.518
. 887
.090
.841
.301
.387
.669
.641
.628
. 063
.553
.409
.999
.240
.598
. 524
. 998
.357
.412
.768
. 667
. 658
.355
. 539
. 584
. 175
.763
.400
.478
. 544
. 968
.472
.583
.070
.733
. 702
I .
11101301133231
00100000000
101c000c10'•J
D
A.vg
. 536
. Ill
. 109
. 835
. 304
.455
. 888
.686
. 658
. 104
. 640
. 552
. 190
.495
. 596
.523
. 026
.373
.417
. 774
.672
.660
. 368
.553
.601
. 182
. 835
.437
. 500
. 602
. 997
.430
. 591
.078
.761
. 759
%
71864A*i
620644477
16
44565.144545
51C56
1365i-i4™3
RSD
.22
. 35
. 56
.21
. 32
. Cl
. 31
.40
. 71
.67
. 30
.23
. 04
.86
. 51
. 59
. 34
. 63
. 04
.42
. 77
.21
. 82
. 66
.38
. 71
. 19
. 73
.45
. 95
. 07
. 71
. 37
. 95
. 4 9
. * t
= Out of RangeSOIL8260.M Mon Dec 15 11:21:03 1997 ?aae 1
Quantitation Report (Not Reviewed)
Data File : J:\7201\DATA\5349S02.D Position: 1Acq On : 15 Dec 1997 8:21 am Operator: JNSample : VSTD050 , INIT.CAL. , 8260-Heated Purge Inst : 7201Misc : 5ul V-1147A+5ul V-1147B+5ml ofw Multiplr: 1.00MS Integration Params: rteint.pQuant Time: Dec 15 8:49 1997 Quant Results File: SOIL8260.R1
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
M (RTE Integrator)for low level soils,
J: \7201\METHODS\SOIL8260GC/MS TCL 8260 volatilesMon Dec 15 13:34:11 1997Continuing Cal File: J:\7201\DATA\5314S02SOIL8260
,D
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) Bromochloromethane16) 1 , 4 -Dif luorobenzene28) Chlorobenzene-d5
System Monitoring Compounds13) 1, 2-Dichloroethane-d4Spiked Amount 50.00029) Toluene-d8Spiked Amount 50.000
38) Bromof luorobenzeneSpiked Amount 50.000
Target Compounds2) Chloromethane3) Vinyl Chloride4) Bromomethane5) Chloroethane6) 1 , 1 -Dichloroethene7) Carbon Disulfide8) Acetone9) Methylene Chloride
101119
11Range
15Range
23Range
.31
.82
.56
.1976.2088.7286
128114117
65- 114
98- 110
95- 115
108579543768465874
284756Recovery
558694Recovery
360595Recovery
505050
72
50
62
.00
.00
.00
.76=. 12=.37=
ug/Kgug/Kgug/Kg
ug/Kg145.52ug/Kg100 .24ug/Kg124 .74
0.010.000.00
0.00%#
0.00%
0 .00%#
Qvalue45557777
10) 1, 2 -Dichloroethene (total) 911) 1 , 1 -Dichloroethane12) Chloroform14) 1, 2 -Dichloroethane15) 2-Butanone17) 1, 1, 1-Trichloroethane18) Carbon Tetrachloride19) Benzene20) Trichloroethene21) 1 , 2 -Dichloropropane22) Bromodichloromethane23) Cis-1, 3-Dichloropropene
810119
10111112121314
24) Trans- 1 , 3 -Dichloropropene 1525) 1 , 1 , 2-Trichloroethane26) Dibromochloromethane27) Bromof orm30) 4-Methyl-2-Pentanone31) Toluene32) Tetrachloroethene33) 2-Hexanone
16172314151716
.81
.03
.79
. 91
.20
. 99
.01
.86
.78
.86
.01
.35
.46
.68
.16
.43
.55
.88
.38
.55
.76
.22
.77
.03
.03
.40
. 19
.20
5062946496764384966383624397
1177813063837575971291734391
16443
168707 121129132 14311998490164
1393083608461C0810175584351254m 1326477384240337896163744312953275748539757199217213216405269352300343700195491294125323403375202649606229097260464
8279643537540553566542565443465666576451534854464046
.25
.68
.71
.68
. 54
.70
.45
. 11
.24
. 12
.09
.03
. 63
. 11
.01
. 52
.26
.21
. 08
.21
.00
.63
.03
. 13
.69
. 58
.64
.57
ug/Kgug/Kgug/Kgug/Kgug/Kg#ug/Kgug/Kgug/Kgug/Kg#ug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kg
10099979880999591
99999910099
10088949999999899100100979910093
(#) = qualifier out of range (m) = manual integration5349S02.D SOIL8260.M Mon Dec 15 08:49:58 1997 Page 1
Quantitation Report (Not Reviewed)
Data File : J:\7201\DATA\5349S02.D Position: 1Acq On : 15 Dec 1997 8:21 am Operator: JNSample : VSTD050 , INIT.CAL. , 8260-Heated Purge Inst : 7201Misc : 5ul V-1147A+5ul V-1147B+5ml ofw Multiplr: 1.00MS Integration Params: rteint.pQuant Time: Dec 15 8:49 1997 Quant Results File: SOIL8260.RE
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
M (RTE Integrator)for low level soils
J:\7201\METHODS\SOIL8260GC/MS TCL 8260 volatilesMon Dec 15 13:34:11 1997Continuing Cal File: J:\7201\DATA\5314S02SOIL8260
.D
Compound R.T. Qlon Response Cone Unit Qvalue
34)35)36)37)39)
ChlorobenzeneEthylbenzeneXylene (total)Styrene1,1,2,2 -Tetrachloroethane
1919212123
.69
.83
.68
.81
.47
11210610610483
450832216489267209488108351533
4950505354
.68
.42
.93
.69
.24
ug/Kgug/Kg#ug/Kgug/Kgug/Kg
10089889099
(#) = qualifier out of range (m) = manual integration5349S02.D SOIL8260.M Mon Dec 15 08:49:58 1997 Page 2
Quantitation Report
Data File : J:\7201\DATA\5349S02.DAcq On : 15 Dec 1997 8:21 amSample : VSTD050 , INIT.CAL. , 8260-Heated PurgeMisc : 5ul V-1147A+5ul V-1147B+5ml ofwMS Integration Params: rteint.pQuant Time: Dec 15 8:49 1997
Position:Operator:Inst :
1JN7201
Multiplr: 1.00
Quant Results File: SOIL8260.RES
MethodTitleLast UpdateResponse via
Abundance
650000 •I
i
600000 !J
550000J
500000
450000 i
400000
350000
300000 •
250000
200000
150000
100000 '•
50000•\
J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soils.Mon Dec 15 13:34:11 1997Continuing Cal File: J:\7201\DATA\5314S02.D
TIC: 5349S02.D
1 .
;,uu.iw.Tlme-> 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00
5349S02.D SOIL8260.M Mon Dec 15 08:50:02 1997
2000 2loO 22oO 2.OO 24.00 25.0026.00
Page 3
MethodTitleLast UpdateResponse via
Continuing Calibration Report 7201
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samplesThu Dec 18 11:40:00 1997Continuing Calibration
Continuing Calibration File: 5352S07.D
Min. RRF :Max. RRF Dev :
Compound
0.000 Min. Rel. Area : 50%25% Max. Rel. Area : 150%
AvgRF CCRF
(tt) = Out of Range5352S07.D CS8260.M Thu Dec 18 11:40:16 1997
%Dev Area%
123456789
1011121314151617
181920212223242526272829303132
333435363738394041
I
TTCTCTTTCMTTTGTTCTCSTCT
ITCTCTCMTCMTTCI
TCTCTCTTCTC
ISTTCMT*^i L.L
TCM
TC
Bromochlorome thaneDichlorodif luorome thaneChlorome thaneVinyl ChlorideBromome thaneChloroethaneTrichlorof luorome thane1, 1-DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2-Dichloroethene (total)1 , 1 -DichloroethaneChloroform1 , 2 -Dichloroethane-d41 , 2 -Dichloroethane2 -Butanone
1 , 4 -Dif luorobenzene1,1,1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBromodichloromethaneDibromome thane2 -ChloroethylvinyletherCis-1 , 3-DichloropropeneTrans -1,3 -Dichloropropene1,1,2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thaneBromof orm
Chlorobenzene-dSToluene-d84 -Methyl -2 -PentanoneTolueneTetrachloroethene2 -HexanoneChlorobenzene1,1,1, 2 -TetrachloroethaneEthylbenzene
13111031401134230
100100000000000
110100100
.000
.324
.528
.405
.269
.897
.061
.479
.665
.480
.882
.874
.545
.048
.529
.199
.749
.000
.617
.543
.053
.378
.411
.752
.352
.062
.631
.570
.297
. 533
.481
.431
.000
.216
. 117
.489
.534
.293
.016
.484
.484
12111021401133220
100000000000000
110100000
.000
.118
.260
.284
.149
.853
.781
.401
.172
.407
.695
.766
.318
.746
.383
.747
.601
.000
.580
.517
.976
.350
.376
.686
.322
.056
.574
.505
.262
.472
.435
.371
.000
.251
.097
.427
.517
.130
.960
.458
.466
0.36.17.8.9.4 .9.5.10.15.10.5.6.7.5.14.19.
0 .6.4 .7.7.8.8.8 .10.9.
11.11 .11 .9.
13 .
0 .-2 .16.4 .3 .
55.5.5.3 .
03#565913610745817
007365838048558
095116$657
1195680849799971009792
1011021031021149895
121102104101102103103104101101101102102104100
11811992
10210345**
1C11C2102
Page 1
Continuing Calibration Report 7201
Method : J:\7201\METHODS\CS8260.M (RTE Integrator)Title : GC/MS TCL + CS 8260 for 5ml water samples.Last Update : Thu Dec 18 11:40:00 1997Response via : Continuing Calibration
Continuing Calibration File: 5352S07.D
Min. RRF : 0.000 Min. Rel. Area : 50%Max. RRF Dev : 25% Max. Rel. Area : 150%
Compound AvgRF CCRF %Dev Area%
4243444546474849
GTCTCSTCTTTT
Xylene (total)StyreneBromofluorobenzene1,1,2, 2 -Tetrachloroethane1,2,3 -Trichloropropane1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene
01000000
.599
.072
.767
.473
.385
.953
.982
.866
01000000
.563
.018
.764
.440
.333
.926
.948
.836
6507
13233
.0
.0
.4
.1
.5
.8
.5
.5
10010011610299102102101
(#) = Out of Range SPCC's out = 0 CCC's out = 05352S07.D CS8260.M Thu Dec 18 11:40:17 1997 Page 2
Quantitation Report (Not Reviewed)
J:\7201\DATA\5352S07.D18 Dec 1997 11:02 amVSTD050 , CONT.CAL. , 82605ul V-1147A+5ul V-1144E+5ml ofw
MS Integration Params: rteint.pQuant Time: Dec 18 11:35 1997
Data FileAcq OnSampleMisc
Position:Operator:Inst :Multiplr:
1JN72011.00
Quant Results File: CS8260.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Mon Dec 08 10:36:44 1997Continuing Cal File: J:\7201\DATA\5342S02.DCS8260
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)18)33)
Bromochlorome thane1 , 4 -Dif luorobenzeneChlorobenzene-d5
10.11.19.
308157
128114117
113733629589506148
505050
.00
.00
.00
ug/1ug/1ug/1
000
.00
.00
.00
System Monitoring Compounds15) 1,2-Dichloroethane-d4 11.18 65Spiked Amount 50.000 Range 76 - 11434) Toluene-d8 15.20 98Spiked Amount 50.000 Range 88 - 110
44) Bromofluorobenzene 23.72 95Spiked Amount 50.000 Range 86 - 115
271030Recovery
633141Recovery
386616Recovery
47
50
49
.64
.55
.39
ug/195.
ug/1101.ug/198 .
28%
10%
78%
0
0
0
.00
.00
.00
Target Compounds2)3)4)5)6)7)8)9)
10)11)12)13)14)16)17)19)20)21)22)23)24)25)26)27)28)29)30)31)
Dichlorodi f luoromethaneChlorome thaneVinyl ChlorideBromome thaneChloroethaneTrichlorof luoromethane1 , 1 -DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1, 2 -Dichloroethene (total)1 , 1 -DichloroethaneChloroform1 , 2 -Dichloroethane2 -Butanone1,1,1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBromodichlorome thaneDibromome thane2 -ChloroethylvinyletherCis- 1 , 3 -DichloropropeneTrans- 1 , 3 -Dichloropropene1,1, 2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thane
445556777798
10119
10111112121313161415161617
.32
.80
.01
.78
. 89
.29
. 19
.99
.22
.85
.77
.87
.01
.35
.63
.68
. 15
.44
.55
.89
.39
.55
. 91
.54
.76
.22
.91
.77
85506294641019676438496638362439711778
1306383
1746375759776129
24087714331614604513063997064316266159286474483463181927882040623773784260783124716836036507532556461444022018223649143199820296635034361599317840164700297032273632
23333540414041403842434342413942424142424243414141424242
.45
.38
.23
.48
.63
.78
.78
.59
.72
.33
.31
.33
.84
. 12
.93
. 19
.85
.88
.30
.49
.49
.02
.71
.97
.77
.03
.34
.83
Qvalueug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1
100999999999997
100769593100100999799
10010099
10010094991001001009699
(#) = qualifier out of5352S07.D CS8260.M
range (m) = manualThu Dec 18 11:35
integration34 1997 Page 1
Quantitation Report
J:\7201\DATA\5352S07.D18 Dec 1997 11:02 amVSTD050 , CONT.CAL. , 82605ul V-1147A+5ul V-1144E+5ml ofw
MS Integration Params: rteint.pQuant Time: Dec 18 11:35 1997
Data FileAcq OnSampleMisc
(Not Reviewed)
Position: 1Operator: JNInst : 7201Multiplr: 1.00
Quant Results File: CS8260.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Mon Dec 08 10:36:44 1997Continuing Cal File: J:\7201\DATA\5342S02.DCS8260
Compound R.T. Qlon Response Cone Unit Qvalue
32)35)36)37)38)39)40)41)42)43)45)46)47)48)49)
Bromoform4 -Methyl - 2 - PentanoneTolueneTetrachloroethene2-HexanoneChlorobenzene1,1,1,2 -TetrachloroethaneEthylbenzeneXylene (total)Styrene1,1,2,2 -Tetrachloroethane1,2,3 -Trichloropropane1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene
231415171619191921212323262627
.04
.11
.40
.19
.25
.69
.80
.84
.69
.81
.49
.90
.21
.40
.05
1735891164431121311061061048375146146146
2337434923572228426172765961
485653231642235915285100515374222464168517468741479736423099
413943431842434342424342434342
.21
.18
.26
.56
.93
.95
.42
.41
.45
.33
.45
.03
.10
.45
.89
ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1
99969999961009910099981001009910099
(#) = qualifier out of5352S07.D CS8260.M
range (m) = manualThu Dec 18 11:35
integration35 1997 Page 2
Quantisation Report
Data File : J:\7201\DATA\5352S07.DAcq On : 18 Dec 1997 11:02 amSample : VSTD050 , CONT.CAL. , 8260Misc : 5ul V-1147A+5ul V-1144E+5ml ofwMS Integration Params: rteint.pQuant Time: Dec 18 11:35 1997
Position: 1Operator: JNInst : 7201Multiplr: 1.00
Quant Results File: CS8260.RES
MethodTitleLast Update
: J:\7201\METHODS\CS8260.M (RTE Integrator): GC/MS TCL + CS 8260 for 5ml water samples.: Mon Dec 08 10:36:44 1997
Response via : Continuing Cal File: J:\7201\DATA\5342S02.DAbundanceI 8500001
800000;
750000ij
700000J
650000
600000
550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
0
TIC: 5352S07.D
ll
\ I 11 ,U 1,1————WV,V^
Tlme-> 5.00 6.00 7.00 8.00 9.00 1000 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00 27.00 28.00 29.00
5352S07.D CS8260.M Thu Dec 18 11:35:39 1997
3o!oo siloo
Page 3
Continuing Calibration Report 7201
MethodTitleLast UpdateResponse via
J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soilsFri Dec 19 09:24:41 1997Continuing Calibration
Continuing Calibration File: 5353S02.D
Min. RRF : 0.000 Min. Rel.Max. RRF Dev : 25% Max. Rel.
123456789
101112131415
161718192021222324252627
282930313233343536373839
ITTCTCTMTCTTT1
GTTCTCSTCT
ITCTCMTCMTCTTCTCTCTCTCTC
ISTMTCTCiMTCTCGTCTCS
(#) = Out5353SC2 .D
Compound
Bromochlorome thaneChlorome thaneVinyl ChlorideBromome thaneChloroethane1 , 1 -DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2 -Dichloroethene (total)1, 1 -DichloroethaneChloroform1 , 2 -Dichloroe thane -d41 , 2 -Dichloroethane2 -Butanone
1 , 4 -Dif luorobenzene1,1, 1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneB r orr.od i c h 1 o r orr.e t ha neCis- 1 , 3 -DichlorcpropeneTrans -1,3 -Dichloropropene1,1,2 -TrichloroethaneDibromochlorome thaneBromof orm
Chlcrobenzene-d5Toluene-d84 -Methyl -2 - PentanoneTolueneTetrachloroethene2 -HexancneChlorobenzeneEthylbenzeneXyler.e i total)StyreneBrorrof luorcbenzene1,1,2,2 -Tet rachlcroethane
of Range SPCC'SOIL8260.M Fri Dec 19 09
Area :Area :
50%150%
AvgRF
1.1 .1 .1 .0 .1.3 .0 .1.J_ .
3 .3 .2 .3 .1.
1 .0 .0 .1 .0.0 .0 .c .0 .0 .0 .0 .
1 .1 .0.1 .0 .0 .0 .0 .0 .1 .0 .0 .
s out =:26 : 35
000536111109835304455888686658104640552190495
000596523026373417774672660368553601
000182835437500602997480591078761759
01997
CCRF
110101301123221
100u00G00000
1101c000n1
o0
ccc
. 000
. 168
. 956
.044
.772
.268
.436
.885
. 598
.626
.983
.482
. 513
. 971
.326
.000
.578
.510
. 984
.359
. 391
.742
. 625
. 609
.345
.535
. 584
. 000
.201
.733
. 376
.492
.484
. 953
.452
.560
. 043
.781
. 72C
' s cut = 0
%Dev
0231457200513-1
16
11
032436467632
0-11241
194553
-25
.0
. 9
. 0
.9
. 6
. 7
. 5
.4
.2
. 9
. 9
.3
.6
. 8
. 3
. 0
. 1
. 5
. 1
.6
.2
. 1
. 9
. 7
.2
.4
. 7
. 0
.6
.2
. 3
.6
. 7
.4
. 8
. 1
. 3
. 6
. 1
Area%
1068085
10099
10511010110510710510510210294
106107107105104103106102101102105103
10510596
10410591
1041021C3105106100
Paae !
Quantitation Report (Not Reviewed)
Data FileAcq OnSampleMisc
J:\7201\DATA\5353S02.D Position: 119 Dec 1997 8:51 am Operator: JNVSTD050 , CONT.CAL. , 8260-Heated Purge Inst : 72015ul V-1147A+5U1 V-1144E+5ml ofw Multiplr: 1.00
MS Integration Params,: rteint.pQuant Time: Dec 19 9:23 1997 Quant Results File: SOIL8260.RE
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
M (RTE Integrator)for low level soils.
J: \7201\METHODS\SOIL8260GC/MS TCL 8260 volatilesThu Dec 18 08:17:58 1997Continuing Cal File: J:\7201\DATA\5352S02SOIL8260
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) Bromochloromethane16) 1 , 4 -Dif luorobenzene28) Chlorobenzene-d5
System Monitoring Compounds13) 1, 2-Dichloroethane-d4Spiked Amount 50.000
29) Toluene-d8Spiked Amount 50.000
38) Bromof luorobenzeneSpiked Amount 50.000
Target Compounds2) Chloromethane3) Vinyl Chloride4) Bromomethane5) Chloroethane6) 1 , 1 -Dichloroethene7) Carbon Disulfide8) Acetone9) Methylene Chloride
101119
11Range
15Range
23Range
.30
.82
.56
. 1976. 1988.7186
128114117
65- 114
98- 110
95- 115
115450577324490234
290080Recovery
588618Recovery
382976Recovery
505050
48
49
49
.00
.00
.00
.93=.89=. 77=
ug/Kgug/Kgug/Kg
ug/Kg97.86%
ug/Kg99.78%
ug/Kg99.54%
0.000.000.00
0.00
0.00
0 . 00
Qvalue45557777
10) 1 , 2 -Dichloroethene (total) 911) 1 , 1 -Dichloroethane12) Chloroform14) 1 , 2 -Dichloroethane15) 2-Butanone17) 1 , 1 , 1-Trichloroethane18) Carbon Tetrachloride19) Benzene20) Trichloroethene21) 1 , 2 -Dichloropropane22) Bromodichloromethane23) Cis- 1 , 3 -Dichloropropene
810119
10111112121314
24) Trans- 1 , 3 -Dichloropropene 1525) 1, 1, 2-Trichloroethane26) Dibromcchloromethane27) Bromoform30) 4-Methyl-2-Pentanone31) Toluene32) Tetrachloroethene33) 2-Hexanone
16172314151716
.79
.00
.77
.88
.19
.97
.01
.85
. 77
.85
.00
.34
.47
.68
. 15
.43
.55
.88
.38
.54
.76
.21
.76
.02
. 03
.39
. 19
.21
5062946496764384966383624397
117781306383757597
1291734391
16443
13490011040012047489089146429396742102127184531
4949515151505850
375533m 103344407401951343055153141333475294429568262207526225639428374360939351342199442308668337394359500674405241260237167
50515154515150515151515152515354515253
.32
.27
.15
.20
.48
.94
. 98
.41
.06
.45
.12
. 13
.18
.88
. 97
.94
.27
.39
.83
. 00
.30
.02
.89
.26
.63
.61
.36
.06
ug/Kgug/Kgug/Kgug/Kgug/Kg#ug/Kgug/Kgug/Kgug/Kgtfug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kgug/Kg
100999798831009693
999999
10099
1009094
10098999999
10010097
1009994
(#) = qualifier out of range (m) = manual integration5353S02.D SOIL8260.M Fri Dec 19 09:24:09 1997 Page
Quantitation Report (Not Reviewed)
Data FileAcq OnSampleMisc
J:\7201\DATA\5353S02.D Position: 119 Dec 1997 8:51 am Operator: JNVSTD050 , CONT.CAL. , 8260-Heated Purge Inst : 72015ul V-1147A+5ul V-1144E+5ml ofw Multiplr: 1.00
MS Integration Params: rteint.pQuant Time: Dec 19 9:23 1997 Quant Results File: SOIL8260.RE
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soilsThu Dec 18 08:17:58 1997Continuing Cal File: J:\7201\DATA\5352S02.DSOIL8260
Compound R.T. Qlon Response Cone Unit Qvalue
34)35)36)37)39)
ChlorobenzeneEthylbenzeneXylene (total)Styrene1,1,2,2 -Tetrachloroethane
1919212123
.69
.83
.67
.80
.46
11210610610483
467380221812274712511127353113
5152515254
.84
.60
.96
.38
.65
ug/Kgug/Kg#ug/Kg#ug/Kgug/Kg
10087879299
(#) = qualifier out of range (m) = manual integration5353S02.D SOIL8260.M Fri Dec 19 09:24:10 1997 Page 2
Quantitation Report
Data File : J : \7201\DATA\5353S02.D Position: 1Acq On : 19 Dec 1997 8:51 am Operator: JNSample : VSTD050 , CONT.CAL. , 8260-Heated Purge Inst : 7201Misc : 5ul V-1147A+5ul V-1144E+5ml ofw Multiplr: 1.00MS Integration Params: r teint .pQuant Time: Dec 19 9 :23 1997 Quant Results File: SOIL8260.RES
Method : J : \7201 \METHODS\SOIL8260 .M (RTE Integrator)Title : GC/MS TCL 8260 volatiles for low level soils.Last Update : Thu Dec 18 08:17:58 1997Response via : Continuing Cal File: J : \7201\DATA\5352S02.D
Abundance
800000
; 750000
700000
650000
600000
550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
TIC: 5353S02.D
Jiu'i ii
I-',0-
I
Time-> 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00 27.00 28.00 29.00 30.00 31.00
5353S02.D SOIL8260.M Fri Dec 19 09:24:13 1997 Page
f, '
MethodTitleLast UpdateResponse via
Continuing Calibration Report 7201
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samplesMon Dec 22 08:34:24 1997Continuing Calibration
Continuing Calibration File: 5356S02.D
Min. RRF : 0.000 Min. Rel. Area : 50%Max. RRF Dev : 25% Max. Rel. Area : 150%
Compound AvgRF
123456789
1011121314151617
181920212223242526272829303132
333435363738394041
I
TTCTCTTTCMTTTGTTCTCSTCT
ITCTCTCMTCMTTCI
TCTCTCTTCTC
ISTTCMTCTTCM
TC
Bromochlorome thaneDichlorodif luorome thaneChlorome thaneVinyl ChlorideBromomethaneChloroethaneTrichlorof luorome thane1, 1-DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2-Dichloroethene (total)1, 1 -DichloroethaneChloroform1 , 2 -Dichloroethane-d41 , 2 -Dichloroethane2-Butanone
1 , 4 -Dif luorobenzene1,1, 1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBromodichlorome thaneDibromome thane2 -Chloroethyl vinyl etherCis- 1 , 3 -DichloropropeneTrans- 1 , 3 -Dichloropropene1,1, 2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thaneBromof orm
Chlorobenzene-d5Toluene-da4 -Methyl -2 -PentanoneTolueneTetrachloroethene2 -HexanoneChlorobenzene1,1,1, 2 -TetrachloroethaneEthylbenzene
13111031401i
34230
100100000000000
1101001cc
.000
.324
. 528
.405
.269
.897
.061
.479
.665
.480
. 882
. 874
.545
. 048
.529
.199
.749
. 000
.617
.543
. 053
.378
.411
.752
.352
. 062
.631
.570
.297
. 533
.481
.431
. 000
.216
. 117
.489
. 534
.293
. 016
.484
.484
CCRF
I2I11031401134230
100100000000000
110100100
.000
.163
.361
.365
.248
.916
.012
.540
.631
.574
. 934
. 974
. 704
.257
.486
.285
.812
.000
.660
.583
.127
.408
.439
.810
.387
.069
.682
.618
.321
. 580
.530
.482
.000
.229
.127
. 616
.587
.203
. 104
.533
. 529
%Dev Area%
0341021
-21
-40
-19-2-5-4-51
-2-8
0-7-7-7-7-7-7
-10-11-8-8-8-8
-10-11
0-1-8-8
-1030-8
-10-9
.0
. 9#
.9
.8
.6
. 1
.6
.2
. 7
.6
. 7
.3
. 5
.2
. 7
. 7
.4
.0
.0
. 5
. 0
. 7
.0
.6
. 1
.2
. 1
.5
.2
. 8
.3
. 9
.0
. 1
.8
. 5
. 0
. 9#
.6
. 0
.3
10450#75789193929594
11310099100101103102112
104100100100102103104107108103106107108108111
10410310610210361
103105102
(#) = Out of Range5356S02.D CS8260.M Mon Dec 22 08:36:51 1997 Page 1
Continuing Calibration Report 7201
Method : J:\7201\METHODS\CS8260.M (RTE Integrator)Title : GC/MS TCL + CS 8260 for 5ml water samplesLast Update : Mon Dec 22 08:34:24 1997Response via : Continuing Calibration
Continuing Calibration File: 5356S02.D
Min. RRF : 0.000 Min. Rel . Area :Max. RRF Dev : 25% Max. Rel. Area :
4243444546474849
GTCTCSTCTTTT
Compound
Xylene (total)StyreneBromof luorobenzene1,1,2,2 -Tetrachloroethane1,2, 3 -Trichloropropane1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene
50%150%
AvgRF
01000000
.599
.072
.767
.473
.385
.953
.982
.866
CCRF
01000110
.655
.187
.768
.529
.419
.062
.096
.956
%Dev Area%
-9-10-0
-11-8
-11-11-10
.3
.7
.2
.9
. 9
.4
.5
.4
103103103109110103105102
(#) = Out of Range SPCC's out = 0 CCC's out = 05356S02.D CS8260.M Mon Dec 22 08:36:52 1997 Page 2
Quantitation Report (Not Reviewed)
J:\7201\DATA\5356S02.D22 Dec 1997 8:00 amVSTD050 , CONT.CAL. , 82605ul V-1147A+5ul V-1144E+5ml ofw
MS Integration Params: rteint.pQuant Time: Dec 22 8:33 1997
Data FileAcq OnSampleMisc
Position:Operator:Inst :Multiplr:
1JN72011 .00
Quant Results File: CS8260.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Fri Dec 19 16:43:40 1997Continuing Cal File: J:\7201\DATA\5352S07.DCS8260
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)18)33)
Bromochlorome thane1 , 4 -Dif luorobenzeneChlorobenzene-d5
111
0.1.9.
308156
128114117
99006539587447141
505050
.00
.00
. 00
ug/1ug/1ug/1
0.0.
-0.
000002
System Monitoring Compounds15) l,2-Dichloroethane-d4 11.18 65Spiked Amount 50.000 Range 76 - 11434) Toluene-d8 15.19 98Spiked Amount 50.000 Range 88 - 110
44) Bromofluorobenzene 23.72 95Spiked Amount 50.000 Range 86 - 115
246161 52.17 ug/1 0.00Recovery = 104.34%
549512 49.12 ug/1 -0.02Recovery = 98.24%
343625 50.30 ug/1 0.00Recovery = 100.60%
Target Compounds2)3)4)5)6)7)8)9)
10)11)12)13)14)16)17)19)20)21)22)23)24)25)26)27)28)29)30)31)
Dichlorodifluorome thaneChlorome thaneVinyl ChlorideBromome thaneChloroethaneTrichlorofluorome thane1, 1 -DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2 -Dichloroethene (total)1, 1-DichloroethaneChloroform1 , 2 -Dichloroethane2 -Butanone1,1,1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBromodichlorome thaneDibromome thane2 -ChloroethylvinyletherCis- 1 , 3 -DichloropropeneTrans- 1 , 3 -Dichloropropene1,1, 2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thane
445556777798
10119
10111112121313161415161617
.30
.79
.00
.76
.88
.29
. 18
. 97
. 17
. 84
.76
.85
.00
.34
.57
.67
. 15
.42
. 54
. 87
.38
.54
. 90
. 53
.76
.21
. 91
.76
8550629464
101967643849663836243971177813063831746375759776
129
21411713478613518212357190644
298199152468458514284131914762001573667134215133251948037935618631476860808321990023700743682920886337418
367938333699173179313212286011
51545354535454553557575556596756565758585860625961616160
.06
.02
. 17
.33
.64
. 16
.98
.50
.23
. 05
.24
.81
.82
.78
.54
.92
.41
.74
.27
.47
. 99
.03
.31
.36
.25
.34
. 52
. 98
Qvalueug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1
100999999999997
1006098959910010097
100100100991001009599
1001001009899
(#) = qualifier out of range (m) = manual integration5356S02.D CS8260.M Mon Dec 22 08:33:37 1997 Page 1
Quantitation Report
Data File : J:\7201\DATA\5356S02.DAcq On : 22 Dec 1997 8:00 amSample : VSTD050 , CONT.CAL. , 8260Misc : 5ul V-1147A-t-5ul V-1144E+5ml ofwMS Integration Params: rteint.pQuant Time: Dec 22 8:33 1997
(Not Reviewed)
Position: 1Operator: JNInst : 7201Multiplr: 1.00
Quant Results File: CS8260.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Fri Dec 19 16:43:40 1997Continuing Cal File: J:\7201\DATA\5352S07.DCS8260
Compound R.T. Qlon Response Cone Unit Qvalue
32)35)36)37)38)39)40)41)42)43)45)46)47)48)49)
Bromoform4 -Methyl -2 -PentanoneTolueneTetrachloroethene2-HexanoneChlorobenzene1,1,1, 2 -TetrachloroethaneEthylbenzeneXylene (total)Styrene1,1,2,2 -Tetrachloroethane1,2,3 -Trichloropropane1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene
231415171619191921212323262627
.03
.06
.39
.18
.23
.69
.79
.82
.67
.80
.47
.88
.21
.40
.06
1735891164431121311061061048375146146146
2600775667572235726254290660
493499238128236503292809530681236728187483474780489869427318
646556567757585658586062575757
. 91
. 15
.60
.77
.79
.51
. 18
.74
. 13
.28
.23
.97
.33
.79
. 16
ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1
10097100100971009998
10098
1009999
10099
(#) = qualifier out of range (m) = manual integration5356S02.D CS8260.M Mon Dec 22 08:33:38 1997 Page 2
Quantitation Report
Data File : J:\7201\DATA\5356S02.DAcq On : 22 Dec 1997 8:00 amSample : VSTD050 , CONT.CAL. , 8260Misc : 5ul V-1147A+5ul V-1144E+5ml ofwMS Integration Params: rteint.pQuant Time: Dec 22 8:33 1997
Position: 1Operator: JNInst : 7201Multiplr: 1.00
Quant Results File: CS8260.RES
MethodTitleLast Update
: J:\7201\METHODS\CS8260.M (RTE Integrator): GC/MS TCL + CS 8260 for 5ml water samples.: Fri Dec 19 16:43:40 1997
Response via : Continuing Cal File: J:\7201\DATA\5352S07.D
I I
Abundance TIC: 5356S02.D850000
800000
i 750000II
700000I
650000
; 600000I
550000
500000
450000
400000ij 350000
300000
250000
200000
150000
100000
50000
0Tlme-> 500 6.00 700 8.00 9.00 10.0011.0012.0013.0014.0015.0016.0017:0018.0019.0020.0021.0022.0023.0024.0025.0026.0027.0028.0029.0030.00
5356S02.D CS8260.M Mon Dec 22 08:33:42 1997
*o ,
II!I
Ii
li
i
Page 3
fMof-Vi'MethodTitleLast UpdateResponse via
Continuing Calibration Report 7201
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples,Fri Feb 27 13:55:43 1998Continuing Calibration
Continuing Calibration File: 5058S07.D
Min. RRF : 0.000 Min. Rel . Area :Max. RRF Dev : 25% Max. Rel. Area :
Compound
1234S67891011121314. 51617
18.9:o212223242526272829)03132
3354
2556)7•89:0
;i-.2':3
:4
:5
-.6i7
I
TTCTCTTTCMTTTGTTCTCSTCT
ITCTCTCMTCMTTCI
TCTCTCTTCTC
ISTTCMTCTTCM
TCGTCTCSTCTT
Bromochlorome thaneDichlorodif luorome thaneChlorome thaneVinyl ChlorideBromome thaneChloroethaneTrichlorof luorome thane1, 1 -DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2 -Dichloroethene (total)1 , 1 -DichloroethaneChloroform1 , 2 -Dichloroethane-d41 , 2 -Dichloroethane2 -Butanone
1 , 4 -Dif luorobenzene1,1,1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBr omod ichl or ome thaneDibromome thane2 -ChloroethylvinyletherCis- 1 , 3 -DichloropropeneTrans -1,3 -Dichloropropene1,1,2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thaneBrorr.of orm
Chlorobenzene-d5Toluene-d84 -Methyl -2 -PentanoneTolueneTetrachloroethene2 -HexanoneChlorobenzene1,1,1,2 -TetrachloroethaneEthylbenzeneXylene (total)StyreneBromof luorobenzene1,1,2,2 -Tetrachloroethane1,2,3 -Trichloropropane1 , 3 -Di chlorobenzene
10101011401T
33120
100100000000000
10010000c00000c
50%150%
AvgRF
.000
.849
.283
. 967
. 344
.819
.774
.436
.953
.292
.696
.788
.281
.671
.351
.423
.553
.000
. 558
.499
. 058
. 385
. 393
.635
. 337
.000
. 584
.498
.291
.472
.438
.412
. 000
. 716
. 105
.409
. 523
.209
. 971
.427
.464
. 561
. 992
.592
.445
. 321
. 906
10111011501133120
100100000000000
T
0010c1
0.">••J
0^
co
Q
c
CCRF
.000
. 787
.240
. 069
.211
. 792
.763
.487
. 023
.353
. 704
. 839
.256
.643
.284
.334
.570
. 000
.547
.488
.053
.387
.379
.610
.334
.000
.573
.486
.285
.454
.427
.395
. 000
.740
. 105
.475
. 557
.203
. 015
.442
.437
. 581
. 040
.618
.453
. 310
. 930
%Dev
073
-10930
-3-1
-20-0-20043
-3
0220
-03300121324
0-30
-4-62-4-3-5-3-4-4-13
-2
.0
.3
.4
. 5
. 9
.3
.6
.5
.4
.9
.5
. 9
. 7
.8
. 9
. 7
. 0
.0
. 1
.2
.5
. 7
.4
. 9
. 7
.0
. 9
. 5
. 9
.6
. 5
. 1
. 0
.4
. 0
. 7
.6
.8
.6
. 5
. 0
.6
. 8
.4
.8
. 3
. 7
Area%
85768187778283878610488878686868796
8686868789878794Otf
889093919193
858783899088898339888889999283
1,4-Dichlorobenzene 0.936 0.950 -1.4 881,2-Dichlorobenzene 0.818 0.835 -2.1 90
(#) = Out of Range SPCC's out = 0 CCC's out = 0
5058S07.D CS8260.M Fri Feb 27 13:58:43 1998
Quantitation Report (QT Reviewed)
J:\7201\DATA\5058S07.D27 Feb 1998 1:22 pmVSTD050 CONT CAL5UL V1161E, V1161A + 5ML OFW
MS Integration Params: rteint.pQuant Time: Feb 27 13:58 1998
Data FileAcq OnSampleMisc
Position:Operator:Inst :Multiplr:
1LL72011.00
Quant Results File: CS8260.R2S
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Thu Feb 26 08:53:10 1998Continuing Cal File: J:\7201\DATA\5057S02.DCS8260
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)18)33)
Bromochlorome thane1 , 4 -Dif luorobenzeneChlorobenzene-d5
101119
.29
.81
.56
128114117
118710670107551551
50.50.50.
000000
ug/1ug/1ug/1
000
.00
.00
.00
System Monitoring Compounds15) 1,2-Dichloroethane-d4 11.18Spiked Amount 50.000 Range 7634) Toluene-dS 15.19Spiked Amount 50.000 Range 88
44) Bromofluorobenzene 23.72Spiked Amount 50.000 Range 86
65 152427 54.69 ug/1 0.00114 Recovery = 109.38%98 408161 54.99 ug/1 0.00110 Recovery = 109.98%95 340766 54.18 ug/1 0.01115 Recovery = 108.36%
Target Compounds2)3)4)5)6)7)8)9)
10)11)12)13)14)16)17)19)20)21)22)23)24)25)27)28)29)30)31)32)
Dichlorodifluorome thaneChlorome thaneVinyl ChlorideBromome thaneChloroethaneTrichlorof luorome thane1 , 1 -DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2 -Dichloroethene (total)1, 1 -DichloroethaneChloroform1 , 2 -Dichloroethane2 -Butanone1,1,1 -Tri chloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2-DichloropropaneB romodichl or ome thaneDibromome thaneCis- 1 , 3 -DichloropropeneTrans- 1 , 3 -Dichloropropene1,1,2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thaneBromof orm
444556776788
10119
10111112121313141516161723
.29
.78
.97
.75
.86
.26
.17
.97
.97
.83
.25
.85
.00
.34
.41
.68
. 14
.43
.54
.87
.39
.53
.54
.76
.21
. 91
.76
.03
8550629464
10196764384966383624397
11778130638317475759776129173
9344914724812691914378194014
209334176507596294419122C2293436676m38655943249027710267627
3662523272927054202594382542864CS5732240863840643254591 9 1 j 6 9304522286304264605
48495449485151514952
1035151504751505150505049504949494946
.68
.05
. 94
.53
.71
.23
.51
.37
.35
.24
. 95
.82
.83
.79
. 37
. 17
.40
.26
.31
.95
.55
.39
. 38
.53
. " 3
. 30
. 1 5
. 10
Qvalueug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1
100100999310099971009393
10010010093
10010010099
10010093
10010C10:99100100
(#) = qualifier out of range5058S07.D CS8260.M Fri
(m) = manualFeb 27 13:58
integration57 1998 Page 1
Quantitation Report
J:\7201\DATA\5058S07.D27 Feb 1998 1:22 pmVSTD050 CONT CAL5UL V1161E, V1161A + 5ML OFW
MS Integration Params: rteint.pQuant Time: Feb 27 13:58 1998
Data FileAcq OnSampleMisc
(QT Reviewed)
Position: 1Operator: LLInst : 7201Multiplr: 1.00
Quant Results File: CS8260.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Thu Feb 26 08:53:10 1998Continuing Cal File: J:\7201\DATA\5057S02.DCS8260
Compound R.T. Qlon Response Cone Unit Qvalue
35) 4-Methyl-2-Pentanone 13.99 58 57779 48.59 ug/1 9936) Toluene 15.40 91 813654 52.05 ug/1 10037) Tetrachloroethene 17.19 164 307255 51.62 ug/1 10038) 2-Hexanone 16.16 43 111824 48.14 ug/1 10039) Chlorobenzene 19.69 112 559980 51.90 ug/1 10040) 1,1,1,2-Tetrachloroethane 19.80 131 243754 51.20 ug/1 9941) Ethylbenzene 19.82 106 268781 51.71 ug/1 9942) Xylene (total) 21.68 106 320410 51.13 ug/1 9943) Styrene 21.81 104 573396 50.86 ug/1 9945) 1,1,2,2-Tetrachloroethane 23.48 83 249732 49.81 ug/1 9946) 1,2,3-Trichloropropane 23.89 75 171212 47.41 ug/1 9947) 1,3-Dichlorobenzene 26.21 146 513032 51.45 ug/1 10048) 1,4-Dichlorobenzene 26.40 146 523919 51.05 ug/1 9949) 1,2-Dichlorobenzene 27.05 146 460568 50.63 ug/1 99
(tf) = qualifier out of range (m) = manual integration5058S07.D CS8260.M Fri Feb 27 13:58:58 1998 Page 2
Quantitation Report
Data File : J:\7201\DATA\5058S07.DAcq On : 27 Feb 1998 1:22 pmSample : VSTD050 CONT CALMisc : 5UL V1161E, V1161A + 5ML OFWMS Integration Params: rteint.pQuant Time: Feb 27 13:58 1998
Position: 1Operator: LLInst : 7201Multiplr: 1.00
Quant Results File: CS8260.RES
MethodTitleLast UpdateResponse via
Abundance800000
J : \7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Fri Feb 27 13:55:43 1998Continuing Cal File: J:\7201\DATA\5057S02.D
TIC: 5058S07.D
750000;ii
700000j
650000
600000
550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000I '
*, j
ii
0 '
5058S07.D CS8260.M
.uv. . . . . . .5.00 6.00 7.00 8.00 9.00 10.00 11.00 12!00 13.00 14.00 15.00 16.00 17.00 1800 19.00 2000 2liOO 22.00 23XX) 24.00 25.00 2600 27lOO 28.00 29!00 30.00 3liOO
Fri Feb 27 13:59:01 1998 Page 3
/. 4-
MethodTitleLast UpdateResponse via
Continuing Calibration Report 7001
J:\7001\METHODS\CS8260LO.M (RTE Integrator)GC/MS TCL 8260 5ml volatiles for water samplesMon Jun 08 08:33:42 1998Continuing Calibration
Continuing Calibration File: 1159S02.D
Min. RRF : 0.000 Min. Rel.Max. RRF Dev : 25% Max. Rel.
123456789
1011121314151617
181920212223242526272829303132
333435363738394041
(#)115
I
TTCTCTTTCMTTTGTTCTCSTCT
ITCTCTCMTCMTTCI
TCTCTCTTCTC
ISTTCMTCTTCMTC
= Out9S02 .D
Compound
Bromochlorome thaneDichlorodif luorome thaneChlorome thaneVinyl ChlorideBromome thaneChloroethaneTrichlorof luorome thane1, 1-DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2-Dichloroethene (total)1, 1-DichloroethaneChloroform1 , 2-Dichloroethane-d41 , 2 -Dichloroethane2 -Butanone
1 , 4 -Dif luorobenzene1,1,1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroether.e1 , 2 -DichloropropaneBromodichlororr.e thaneDibromome thane2 -Chloroethyl vinyl etherCis- 1 , 3 -DichloropropeneTrans- 1 , 3 -Dichloropropene1,1, 2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thaneBromof orm
Chlorobenzene-d5Toluene-d84 -Methyl -2 -PentanoneTolueneTetrachloroethene2 -HexanoneChlorobenzeneEtihyl benzene1,1,1,2 -Tetrachloroethane
of RangeCS8260LO.M Mon Jun 08 0£
Area :Area :
50%150%
AvgRF
112111321012366120
100100000000000
110200T_
00
! : 33 : 50
.000
.484
. 923
.342
. 939
. 905
.322
.810
. 909
. 107
.837
.223
.008
. 152
.896
.630
.344
.000
.682
. 577
. 112
.403
.284
.383
.139
.000
.352
.242
. 122
.220
. 190
. 101
.000
.354
.033
. 062
. 599
. 062
. 099
.654
.382
1998
CCRF
1.0.2 .1 .1 .1 .2 .2 .8 .0.1.2 .5.5.1.2 .0.
1 .0 .0 .0 .0 .0 .0 .0 .
-0 .0.0 .0 .0 .0 .0 .
1 .1 .0 .1 .0 .0 .0 .0 .0 .
70
000982400024642596444334481358894633071082802120366
000564466985350246320109OOOtf307219105190167083
000303033714477073948575325
01
%Dev Area%
0331723151626172267331815175
19-6
0171911131316210
129
14131218
03
-01620
-16131214
.0
.8#
.9
. 7
.3
.2
. 4#
.0
.3
. 7#
.2#
. 1
.6
.4
.0
.4
.2
.0
.2
.2
.4
.2
.4
.4
.4
.0
. 7
.3
.4
. 5
.2
. 1
. 0
.8
.2
. 9
.4
.2
. 7
. 1
. 9
Pa
14597
118115123118105120119103123117123121139120136
1461151161291301261191130
124120119122123107
143135122120113133123124120
iqe
Continuing Calibration Report 7001
Method : J:\7001\METHODS\CS8260LO.M (RTE Integrator)Title : GC/MS TCL 8260 5ml volatiles for water samples.Last Update : Mon Jun 08 08:33:42 1998Response via : Continuing Calibration
Continuing Calibration File: 1159S02.D
Min. RRF : 0.000 Min. Rel. Area : 50%Max. RRF Dev : 25% Max. Rel. Area : 150%
Compound AvgRF CCRF %Dev Area%
4243444546474849
GTCTCSTCTTTT
Xylene (total)StyreneBromof luorobenzene1,1,2, 2 -Tetrachloroethane1,2, 3 -Trichloropropane1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene
00000000
.683
.953
.551
. 168
. 123
.783
.765
.596
00000000
.580
.874
.498
. 142
.094
.650
.614
.471
15.8.9.
15.23 .17.19.21.
13636060
125127125117106111108105
(#) = Out of Range SPCC's out = 0 CCC's out = 01159S02.D CS8260LO.M Mon Jun 08 08:33:51 1998 7001 Page 2
Quantitation Report (Not Reviewed)
Data File : J:\7001\DATA\1159S02.DAcq On : 8 Jun 1998 8:06 amSample : VSTD010, Cont.Cal. , 8260-25mlMisc : 5ul V-1185B+5ul V-1185A+35ul MeOHMS Integration Params: rteint.pQuant Time: Jun 8 8:31 1998
Position:Operator:Inst :Multiplr:
9JN70011.00
Quant Results File: CS8260LO.RH
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7001\METHODS\CS8260LO.M (RTE Integrator)GC/MS TCL 8260 5ml volatiles for water samplesMon Jun 08 07:16:32 1998Continuing Cal File: J:\7001\DATA\1156I12.DCS8260LO
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)18)33)
Bromochlorome thane1 , 4 -Dif luorobenzeneChlorobenzene-d5
79
13
.78
.14
.94
128114117
46161415962282799
101010
.00
.00
.00
ug/1ug/1ug/1
0-00
.00
.01
.00
System Monitoring Compounds15) l,2-Dichloroethane-d4 8.43 65Spiked Amount 10.000 Range 76 - 11434) Toluene-da 11.42 98Spiked Amount 10.000 Range 88 - 11044) Bromofluorobenzene 16.53 95Spiked Amount 10.000 Range 86 - 115
83171 9.55 ug/1 0.00Recovery = 95.50%
368399 9.12 ug/1 -0.01Recovery = 91.20%
140972 8.46 ug/1 0.00Recovery = 84.60%#
Target Compounds2)3)4)5)6)7)8)9)
10)11)12)13)14)16)17)19)20)21)22)23)24)25)27)28)29)30)31)32)
Dichlorodif luorome thaneChloromethaneVinyl ChlorideBromome thaneChloroethaneTrichlorof luorome thane1, 1-DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 2-Dichloroethene (total)1, 1-DichloroethaneChloroform1 , 2 -Dichloroethane2 -Butanone1,1, 1-Tri chloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBromodi chloromethaneDibromome thaneCis- 1 , 3 -DichloropropeneTrans- 1 , 3 -Dichloropropene1,1, 2 -Tri chloroethane1 , 3 -DichloropropaneDibromochlorome thaneBromof orm
44444556567678788899
109
101111121215
.00
.21
.37
.76
.89
.33
.84
.32
.40
. 11
.50
.94
.83
.52
. 17
. 38
. 82
.79
.68
.76
. 02
.86
.68
.36
.73
.00
.61
.57
8550629464
1019676438496638362439711778
130638317475759776129173
453391108044724975797736521128351077213915111650687415
243581m2341022346089788016875
234774193980409840145494102212133214453011276149125343481792406949934510
6878878878
1688897788887888887
.69
.12
. 90
.47
. 15
.27
.25
.23
. 07
.45
. 15
.45
.31
.27
.37
.89
. 97
.81
.93
.60
. 15
. 74
. 51
.23
. 15
.38
. 39
.33
Qvalueug/1ug/1ug/1ug/1ug/1ug/1ug/1 #ug/1ug/1ug/1ug/1 #ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1 nug/1ug/1ug/1ug/1ug/1ug/1
97979899999778979699
979998889897829197936699
100100949697
(#) = qualifier out of range (m) = manual integration1159S02.D CS8260LO.M Mon Jun 08 08:31:11 1998 7001 Page 1
Quantitation Report
Data File : J:\7001\DATA\1159S02.DAcq On : 8 Jun 1998 8:06 amSample : VSTD010, Cont.Cal. , 8260-25mlMisc : 5ul V-1185B+5ul V-1185A+35ul MeOHMS Integration Params: rteint.pQuant Time: Jun 8 8:31 1998
(Not Reviewed)
Position:Operator:Inst :Multiplr:
9JN70011 .00
Quant Results File: CS8260LO.RE<
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7001\METHODS\CS8260LO.M (RTE Integrator)GC/MS TCL 8260 5ml volatiles for water samplesMon Jun 08 07:16:32 1998Continuing Cal File: J:\7001\DATA\1156I12.DCS8260LO
Compound R.T. Qlon Response Cone Unit Qvalue
35) 4-Methyl-2-Pentanone 10.60 58 386 0.34 ug/1 9836) Toluene 11.54 91 484825 8.08 ug/1 8337) Tetrachloroethene 12.73 164 134892 7.67 ug/1 9238) 2-Hexanone 11.84 43 20511 9.35 ug/1 # 9939) Chlorobenzene 14.02 112 268198 8.28 ug/1 10040) Ethylbenzene 14.64 106 172848 8.94 ug/1 9441) 1,1,1,2-Tetrachloroethane 14.11 131 91919 8.11 ug/1 9942) Xylene (total) 15.38 106 163971 8.45 ug/1 # 4443) Styrene 15.32 104 247065 8.56 ug/1 # 6145) 1,1,2,2-Tetrachloroethane 16.07 83 40144 7.89 ug/1 9646) 1,2,3-Trichloropropane 16.51 75 62105 16.87 ug/1 # 3447) 1,3-Dichlorobenzene 19.34 146 183815 7.51 ug/1 9348) 1,4-Dichlorobenzene 19.60 146 173768 7.29 ug/1 9349) 1,2-Dichlorobenzene 20.23 146 133195 7.12 ug/1 91
(#) = qualifier out of range (m) = manual integration1159S02.D CS8260LO.M Mon Jun 08 08:31:12 1998 7001 Page 2
Quantitation Report
Data File : J:\7001\DATA\1159S02.DAcq On : 8 Jun 1998 8:06 amSample : VSTD010, Cont.Cal. , 8260-25mlMisc : 5ul V-1185B+5ul V-1185A+35ul MeOHMS Integration Params: rteint.pQuant Time: Jun 8 8:31 1998
Position: 9Operator: JNInst : 7001Multiplr: 1.00
Quant Results File: CS8260LO.RES
MethodTitleLast UpdateResponse via
Abundance600000
550000
! 500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
, Yo -•Tlme-> 4.00
J:\7001\METHODS\CS8260LO.M (RTE Integrator)GC/MS TCL 8260 5ml volatiles for water samples.Mon Jun 08 07:16:32 1998Continuing Cal File: J:\7001\DATA\1156I12.D
TIC:1159S02.D
<n«
• ;:> ''UUUiiUJ>.y^-- ^.y>--» , VW-^v
!o
Mi , : ,l.liy.WJiJ ill5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 J8.00 19.00 20.00 21.00 22.00
1159S02.D CS8260LO.M Mon Jun 08 08:31:16 1998 7001 Page 3
Quantitation Report (Not Reviewed)
J:\7201\DATA\5353V06.D Position: 119 Dec 1997 11:30 am Operator: JN9709455MS, SB36-SL-16-205MS, M.Watson Inst : 72015g + 5ml ofw-t-Sul SSIS V-1147A+5ul MS V-114 Multiplr: 1.00
MS Integration Params: rteint.pQuant Time: Dec 19 12:02 1997
Data FileAcq OnSampleMisc
Quant Results File: SOIL8260.RE;
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soilsFri Dec 19 09:24 :41 1997Continuing Cal File: J:\7201\DATA\5353S02.DSOIL8260
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)16)28)
Bromochlorome thane1 , 4 -Dif luorobenzeneChlorobenzene-d5
101119
.32
.83
.57
128114117
126352
592791559765
505050
. 00
. 00
. 00
ug/Kgug/Kgug/Kg
000
.02
.00
.00
System Monitoring Compounds13) 1,2-Dichloroethane-d4 11.21 65Spiked Amount 50.000 Range 76 - 114
29') Toluene-d8 15.21 98Spiked Amount 50.000 Range 88 - 110
38) Bromofluorobenzene 23.73 95Spiked Amount 50.000 Range 86 - 115
Target Compounds6) 1,1-Dichloroethene 7.21 967) Carbon Disulfide 8.00 768) Acetone 7.27 439) Methylene Chloride 7.87 84
14) 1,2-Dichloroethane 11.43 6215) 2-Butanone 9.63 4319) Benzene 11.44 7820) Trichloroethene 12.56 13024) Trans-1,3-Dichloropropene 15.41 7531) Toluene " 15.41 9134) Chlorobenzene 19.70 112
329496 52Recovery
648563 50Recovery
402971 48Recovery
.07=
. 98=
. 68=
ug/Kg104 . 14%ug/Kg101 . 96%ug/Kg97.36%
0 .02
0 . 02
0 .02
Qvalue171300 53
8081 088742 395455 18043 1
22236 6709940 56241840 526440 0
795256 54539772 53
.63
. 93
.83
. 36
. 07
. 66
.42
.63
. 83
.56
.44
ug/Kg# '<•'ug/Kg#ug/Kgug/Kg#ug/Kgug/Kgug/Kg • ' }ug/Kg 10 *ug/Kg#ug/Kg ic.^ug/Kg .c-)
'"7 °o817599848093
> 96r 94
1100100
{#) = qualifier out of5353V36.D SCIL8260.M
range (rrO = manual integrationFri Dec 19 12 : C2 : 55 1997 Page 1
Quant itation Report
Data File : J:\7201\DATA\5353V06.D Position: 1Acq On : 19 Dec 1997 11:30 am Operator: JNSample : 9709455MS, SB36-SL-16-205MS, M.Watson Inst : 7201Misc : 5g+5ml ofw+5ul SSIS V-1147A+5ul MS V-114 Multiplr: 1.00MS Integration Params: rteint.pQuant Time: Dec 19 12:02 1997 Quant Results File: SOIL8260.RES
MethodTitleLast UpdateResponse via
Abundance600000
550000
500000
450000
400000
350000
300000
250000
J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soils,Fri Dec 19 09:24:41 1997Continuing Cal File: J:\7201\DATA\5353S02.D
TIC: 5353V06.D
200000o~.
150000
100000
50000I
Time~> 500 6.00 7.00 800 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00 27.00 28.00 29.00 30.00 31.00 i
5353V06.D SOIL8260.M Fri Dec 19 12:03:01 1997 Page 2
Quantitation Report (Not Reviewed)
J:\7201\DATA\5353V07.D Position:•19 Dec 1997 12:11 pm Operator:9709455MSD, SB36-SL-16-205MSD, M.Watson Inst :5g+5ml ofw+5ul SSIS V-1147A-t-5ul MS V-114 Multiplr:
MS Integration Params: rteint.pQuant Time: Dec 19 12:43 1997
XData FileAcq OnSampleMisc
JN72011 . 00
Quant Results File: SOIL8260.RE£
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
M (RTE Integrator)for low level soils
J:\7201\METHODS\SOIL8260GC/MS TCL 8260 volatilesFri Dec 19 09:24:41 1997Continuing Cal File: J:\7201\DATA\5353S02SOIL8260
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)16)28)
Bromochlorome thane1 , 4 -Dif luorobenzeneChlorobenzene-d5
10 .11 .19.
328356
128114117
119477591312496975
505050
.00
.00
.00
ug/Kgug/Kgug/Kg
000
.02
.01
. 00
System Monitoring Compounds13) 1,2-Dichloroethane-d4 11.21 65Spiked Amount 50.000 Range 75 - 114
29) Toluene-d8 15.21 98Spiked Amount 50.000 Range 63 - 110
38) Bromofluorobenzene 23.72 95Spiked Amount 50.000 Range 86 - 115
Target Compounds6) 1,1-Dichloroethene7) Carbon Disulfide8) Acetone9) Methylene Chloride
14) 1,2-Dichloroethane15) 2-Butanone19) Benzene20) Trichloroethene21) 1,2-Dichloropropane24) Trans-1,3-Dichloropropene31) Toluene34) Chlorobenzene
309850 51.61 ug/Kg 0.02Recovery = 103.22%
600847 50.35 ug/Kg 0.02Recovery = 100.70%
384953 49.58 ug/Kg 0.01Recovery = 99.16%
Qvalue7877
119
111212151519
.22
.00
.07
.37
.45
.56
.45
. 57
. 56
.40
.41
.69
96764384624378
130637591
112
1607896943
393853859761413961
666191225900
9245698
749865510238
530
18114
575300
5453
. 05
.85
.63
.01
.07
.40
.23
. 14
.20
.79
. 84
. 84
ug/Kgtt '--ug/Kgtfug/Kgug/Kg#ug/Kgug/Kgug/Kg 'Hug/Kg <-X;ug/Kgttug/Kgtfug/Kg -.0ug/Kgicb
'"< 817582808178969411
100100
(#) = qualifier out of5353V07.D SOIL8260.M
range (m) = manualFri Dec 13 12:
jration1997 Page
Quantitation Report
Data File : J:\7201\DATA\5353V07.D Position: 1Acq On -.19 Dec 1997 12:11 pm Operator: JNSample : 9709455MSD, SB36-SL-16-205MSD, M.Watson Inst : 7201Misc : 5g+5ml ofw+5ul SSIS V-1147A+5ul MS V-114 Multiplr: 1.00MS Integration Params: rteint.pQuant Time: Dec 19 12:43 1997 Quant Results File: SOIL8260.RES
MethodTitleLast UpdateResponse via
Abundance550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
M (RTE Integrator)for low level soils
J:\7201\METHODS\SOIL8260GC/MS TCL 8260 volatilesFri Dec 19 09:24:41 1997Continuing Cal File: J:\7201\DATA\5353S02 ,D
TIC: 5353V07.D
II
Time»> 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00 27.00 28.00 29.00 30.00 31.00__ j
S353V07.D SOU,8260.M Fri Dec 19 12:43:59 1997 Page 2
J 7YJ-Data FileAcq OnSampleMisc
Quantitation Report (Not Reviewed)
J:\7001\DATA\1160V16.D Position: 129 Jun 1998 4:10 pm Operator: JN
9803564MS, SO-MS, M.Watson , 8260-25ml Inst : 70015ul V-1185B+5ul MS V-1184B+35ul MeOH Multiplr: 1.00
MS Integration Params : rteint.pQuant Time: Jun 9 16:34 1998 Quant Results File: 25M8260.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7001\METHODS\25M8260.M (RTE Integrator)GC/MS TCL method 8260 25ml volatiles.Tue Jun 09 14:29:37 1998Continuing Cal File: J:\7001\DATA\1160S11.D25M8260
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)16)28)
Bromochlorome thane1 , 4 -Dif luorobenzeneChlorobenzene-d5
79
13
.80
.17
.98
128114117
33310318147224484
101010
.00
.00
.00
ug/1ug/1ug/1
000
.00
.00
.00
System Monitoring Compounds13) 1,2-Dichloroethane-d4Spiked Amount 10.00029) Toluene-d8Spiked Amount 10.000
38) BromofluorobenzeneSpiked Amount 10.000
Target Compounds5) Chloroethane6) 1,1-Dichloroethene7) Carbon Disulfide8) Acetone9) Methylene Chloride
14) 1,2-Dichloroethane15) 2-Butanone19) Benzene20) Trichloroethene22) Bromodichloromethane24) Trans-1,3-Dichloropropene25) 1,1,2-Trichloroethane31) Toluene33) 2-Hexanone34) Chlorobenzene
8.45 65
11.45 98
16.57 95
76709 11.97 ug/1 0.00Recovery = 119.70%
284604 9.65 ug/1 0.00Recovery = 96.50%
123827 10.30 ug/1 0.00Recovery = 103.00%
5565687899
1111111114
.87
.87
.34
.45
. 13
.82
.23
.82
.71
.71
.58
.48
.58
.92
.06
6496764384624378
1308375979143112
1116738945628181
18423852183
339828101445
1261256637207
368311186
203831
0.219.820.200. 160 .270 .480 . 14
10.858 .980. 120.37
11 .059.360.129.49
ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1
Qvalue# 45#<%0/0 85# 76# 58# 65# 62# .., 59' ' 100;?<-°'o 94# 61# 1# . 14C-'w 99tt 35• S'% 99
(#) = qualifier out of1160V16.D 25M8260.M
range (m) = manual integrationTue Jun 09 16:34:30 1998 7001 Page 1
Quantitation Report
Data File : J:\7001\DATA\1160V16.DAcq On : 9 Jun 1998 4:10 pmSample : 9803564MS, SO-MS, M.Watson , 8260-25mlMisc : 5ul V-1185B+5ul MS V-1184B+35ul MeOHMS Integration Params: rteint.pQuant Time: Jun 9 16:34 1998
Position: 12Operator: JNInst : 7001Multiplr: 1.00
Quant Results File: 25M8260.RES
MethodTitleLast UpdateResponse via
Abundance
700000
650000
600000
550000
500000
450000
400000
350000
300000 !
250000 '
200000
150000
100000
50000
J:\7001\METHODS\25M8260.M (RTE Integrator)GC/MS TCL method 8260 25ml volatiles.Tue Jun 09 14:29:37 1998Continuing Cal File: J:\7001\DATA\1160S11.D
TIC: 1160V16.D
Time-> 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00
1160V16.D 25M8260.M Tue Jun 09 16:34:32 1998 7001 Page 2
/*J A .Quantisation Report (Not Reviewed)
Data File : J:\7001\DATA\1160V17.D Position:Acq On : 9 Jun 1998 4:42 pm Operator:Sample : 9803564MSD, SO-MSD, M.Watson , 8260-25ml Inst :Misc : 5ul V-1185B+5ul MS V-1184B+35ul MeOH Multiplr:MS Integration Params: rteint.pQuant Time: Jun 9 17:06 1998 Quant Results File:
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7001\METHODS\25M8260.M (RTE Integrator)GC/MS TCL method 8260 25ml volatiles.Tue Jun 09 14:29:37 1998Continuing Cal File: J:\7001\DATA\1160S11.D25M8260
13JN70011 .00
25M8260.RES
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)16)28)
Bromochlorome thane1 , 4 -Dif luorobenzeneChlorobenzene-d5
79
13
.80
. 17
.98
128114117
34314215
375810170
101010
. 00
.00
.00
ug/1ug/1ug/1
000
.00
. 00
.00
System Monitoring Compounds13) 1,2-Dichloroethane-d4Spiked Amount 10.000
29) Toluene-d8Spiked Amount 10.000
38) BromofluorobenzeneSpiked Amount 10.000
Target Compounds6) 1,1-Dichloroethene7) Carbon Disulfide8) Acetone9) Methylene Chloride
14) 1,2-Dichloroethane19) Benzene20) Trichloroethene22) Bromodichloromethane24) Trans-1,3-Dichloropropene25) 1,1,2-Trichloroethane31) Toluene33) 2-Hexanone34) Chlorobenzene
8.46 65
11.45 98
16.57 95
2
1
73339Recovery87391Recovery
18193Recovery
11
10
10
.09
. 17
.26
ug/110ug/101ug/102
1
1
1
90%
70%
60%
0
0
0
.00
.00
.00
56568899
1111111114
.87
.34
.52
. 13
.81
.82
.71
.71
. 57
.47
.57
.82
.06
9676438462781308375979143112
816595409281
21954155
345876108086
15373426
36158388462
185211649
Qvalue100000
11900
10100
10
.52
. 19
.24
.31
. 50
.16
.67
. 15
.49
.86
.30
. 13
.28
ug/1 >o£**°ug/1ug/1 #ug/1 #ug/1 #ug/1 >"-*<•ug/1 <T~'c/<-ug/1 #ug/1 #ug/1 #ug/1 !£**£ug/1 tfug/1 -o^c/
9185587852
> 99> 98361
13» 9735
o 99
(#) = qualifier out of range (m) = manual integration1160V17.D 25M8260.M Tue Jun 09 17:06:48 1998 7001 Page 1
Quantitation Report
J:\7001\DATA\1160V17.D9 Jun 1998 4:42 pm9803564MSD, SO-MSD, M.Watson
Position: 13Operator: JN
8260-25ml Inst : 7001
Data FileAcq OnSampleMisc : 5ul V-1185B+5ul MS V-1184B+35ul MeOHMS Integration Params: rteint.pQuant Time: Jun 9 17:06 1998 Quant Results File
Multiplr: 1.00
: 25M8260.RES
MethodTitleLast UpdateResponse via
Abundance900000
850000
800000
j 750000
i 700000
650000
600000
550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
Tlm«-> 4.00 5.00 6.00 7.00
1160V17.D 25M8260.M
J:\7001\METHODS\25M8260.M (RTE Integrator)GC/MS TCL method 8260 25ml volatiles.Tue Jun 09 14:29:37 1998Continuing Cal File: J:\7001\DATA\1160S11.D
TIC: 1160V17.D
8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00
Tue Jun 09 17:06:50 1998 7001
IB!OO ig!oo 2oloo 21^00 ^22.00 23.00
Page 2
9 7 0 9 2 7 7 2 7* Quantitation Report (Not Reviewed)
Data FileAcq OnSampleMisc
J:\7201\DATA\5349B07.D Position: 215 Dec 1997 11:23 am Operator: JNVBLK15 , METHOD BLANK , Heated Purge Inst : 72015ml ofw+5ul SSIS V-1147A Multiplr: 1.00
MS Integration Params: rteint.pQuant Time: Dec 15 11:52 1997 Quant Results File: SOIL8260.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soilsMon Dec 15 08:50:31 1997Continuing Cal File: J:\7201\DATA\5349S02.DSOIL8260
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) Bromochloromethane16) 1,4-Difluorobenzene28) Chlorobenzene-d5
System Monitoring Compounds13) 1,2-Dichloroethane-d4Spiked Amount 50.000
29) Toluene-d8Spiked Amount 50.000
33) BromofluorobenzeneSpiked Amount 50.000
Target Compounds4) Bromomethane7) Carbon Disulfide8) Acetone9) Methylene Chloride
10) 1,2-Dichloroethene (total)12) Chloroform14) 1,2-Dichloroethane15) 2-Butanone17) 1,1,1-Trichloroethane18) Carbon Tetrachloride19) Benzene20) Trichloroethene22) Bromodichloromethane23) Cis-1,3-Dichloropropene24) Trans-1,3-Dichloropropene27) Bromoform30) 4-Methyl-2-Pentanone31) Toluene32) Tetrachloroethene33) 2-Hexanone34) Chlorobenzene35) Ethylbenzene36) Xylene (total)37) Styrene39) 1,1,2,2-Tetrachloroethane
10.31 12811.82 11419.58 117
11.19 65Range 76 - 114
15.20 98Range 88 - 110
23.72 95Range 86 - 115
57778
10119
1011111213141523141517161919212123
.78
.98
.08
.84
.28
.03
.35
.47
.71
. 18
.44
.55
.39
.56
.78
.03
. 11
.41
.20
.24
.71
.83
.69
.81
.48
94764384968362439711778
13083757517343911644311210610610483
141124 50.00 ug/Kg 0.00706483 50.00 ug/Kg 0.00587020 50.00 ug/Kg 0.02
334843 45.24 ug/Kg 0.00Recovery = 90.48%
649851 46.16 ug/Kg 0.00Recovery = 92.32%
419166 46.13 ug/Kg 0.00Recovery = 92.26%
Qvalue125 0.04 ug/Kg# 2
13172 1.40 ug/Kg 864525 1.73 ug/Kg 623104 0.68 ug/Kg# 82515m 0.11 ug/Kg#906 0.09 ug/Kg# 37975 0.11 ug/Kg# 42761 0.18 ug/Kg# 62631 0.08 ug/Kg# 18640 0.09 ug/Kg# 462479 0.18 ug/Kg# 551709 0.33 ug/Kg# 84519 0.05 ug/Kgtf 18913 0.10 ug/Kgtf 43930 0.10 ug/Kgtf 43
1338 0.16 ug/Kg# 2812939 1.37 ug/Kg 864449 0.27 ug/Kg 932695 0.47 ug/Kg 98
15122 2.30 ug/Kg 883419 0.30 ug/Kg# 561666 0.31 ug/Kg# 281277 0.19 ug/Kg# 16940 0.56 ug/Kg 1002017 0.23 ug/Kgtf 79
(#) = qualifier out of range (m) = manual integration5349B07.D SOIL8260.M Mon Dec 15 11:52:13 1997 Page 1
Quantitation Report
Data File : J:\7201\DATA\5349B07.DAcq On : 15 Dec 1997 11:23 amSample : VBLK15 , METHOD BLANK , Heated PurgeMisc : 5ml ofw+5ul SSIS V-1147AMS Integration Params: rteint.pQuant Time: Dec 15 11:52 1997 Quant Results File: SOIL8260.RES
Position: 2Operator: JNInst : 7201Multiplr: 1.00
MethodTitleLast UpdateResponse via
J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soils,Mon Dec 15 08:50:31 1997Continuing Cal File: J:\7201\DATA\5349S02.D
TIC: 5340B07.D
550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
Tim«-> 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 25.00 26.00 27.00
5349B07.D SOIL8260.M Mon Dec 15 11:52:17 1997 Page 2
Quantisation Report
Data File : J:\7201\DATA\5352B08.DAcq On : 18 Dec 1997 11:44 amSample : VBLK18 , METHOD BLANK , 8260Misc : 5ml ofw+5ul SSIS V-1147AMS Integration Params: rteint.pQuant Time: Dec 18 12:17 1997
(Not Reviewed)
Position: 2Operator: JNInst : 7201Multiplr: 1.00
Quant Results File: CS8260.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Thu Dec 18 11:40:00 1997Continuing Cal File: J:\7201\DATA\5352S07.DCS8260
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)18)33)
Bromochlorome thane1 , 4 -Dif luorobenzeneChlorobenzene -d5
101119
.31
.83
.57
128114117
110480597940503455
505050
.00
.00
.00
ug/1ug/1ug/1
0.000.020.00
System Monitoring Compounds15) 1 , 2 -Dichloroethane-d4Spiked Amount 50.00034) Toluene-dSSpiked Amount 50.00044) Bromof luorobenzeneSpiked Amount 50.000
11Range
15Range
23Range
.2076.2188.7286
65- 114
98- 110
95- 115
265584Recovery
604741Recovery
384297Recovery
50
48
49
.44=.01=.97=
Target Compounds2)3)5)9)
10)11)12)13)14)16)17)19)20)21)22)23)24)25)27)28)29)30)31)32)36)37)38)39)
Dichlorodifluorome thaneChlorome thaneBromome thaneCarbon DisulfideAcetoneMethylene Chloride
445777
1, 2-Dichloroethene (total) 91 , 1-Dichloroe thaneChloroform1 , 2 -Dichloroethane2 -Butanone1,1,1 -TrichloroethaneCarbon TetrachlorideBenzeneTrichloroethene1 , 2 -DichloropropaneBromodichlorome thaneDibromome thaneCis- 1 , 3 -Dichloropropene
810119
1011111212131314
Trans- 1 , 3 -Dichloropropene 151,1, 2 -Trichloroethane1 , 3 -DichloropropaneDibromochlorome thaneBromof ormTolueneTetrachloroethene2 -HexanoneChlorobenzene
1616172315171619
.29
.81
.77
.98
.16
.86
.78
.87
.02
.35
.59
.69
. 15
.43
.56
.89
.39
.55
.57
.79
.23
. 93
. 77
.04
.40
. 19
. 19
.70
855094764384966383624397
11778
13063831747575977612917391
16443112
656535
1002488323384883948
222727252959436
2095946
4530829
17273309257330673003133231772292253176172422379453851
00002100000000000000000000
280
.14
.19
.39
.53
.60
.30
.24
.30
.33
.49
.33
.30
. 15
.39
.20
.38
.40
.67
.45
.50
.43
.56
.44
.57
. 53
.47
. 92
.40
ug/1100 .ug/196.
ug/199.
ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1
88%
02%
94%
0.02
0.00
0.00
Qvalue#####
##
####
##
####
#
#
42423
76569863439758624564787544958359585689997965879263
(#) = qualifier out of5352B08.D CS8260.M
range (m) = manualThu Dec 18 12:17
integration26 1997 Page 1
Data FileAcq OnSampleMisc
Quantitation Report
J:\7201\DATA\5352B08.D18 Dec 1997 11:44 amVBLK18 /METHOD BLANK , 82605ml ofw+5ul SSIS V-1147A
MS Integration Params: rteint.pQuant Time: Dec 18 12:17 1997
(Not Reviewed)
Position: 2Operator: JNInst : 7201Multiplr: 1.00
Quant Results File: CS8260.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Thu Dec 18 11:40:00 1997Continuing Cal File: J:\7201\DATA\5352S07.DCS8260
Compound R.T. Qlon Response Cone Unit Qvalue
40)41)42)43)45)46)47)48)49)
1,1,1,2 -TetrachloroethaneEthylbenzeneXylene (total)Styrene1,1,2,2 -Tetrachloroethane1,2,3 -Trichloropropane1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene
191921212323262627
.81
.83
.67
.81
.49
.72
.21
.40
. 05
1311061061048375146146146
13971174148238542905
230350 T-5475 *57515599
00000
**,££•000
.30
.25
.26
.38
.66
.59
.60
.67
ug/1ug/1ug/1ug/1ug/1"ug/1ug/1ug/1ug/1
tf##
##
64412778743949695
(#) = qualifier out of5352B08.D CS8260.M
range (m) = manualThu Dec 18 12:17
integration27 1997 Page 2
Quantitation Report
Data File : J:\7201\DATA\5352B08.DAcq On : 18 Dec 1997 11:44 amSample : VBLK18 , METHOD BLANK , 8260Misc : 5ml ofw+5ul SSIS V-1147AMS Integration Params: rteint.pQuant Time: Dec 18 12:17 1997
Position: 2Operator: JNInst : 7201Multiplr: 1.00
Quant Results File: CS8260.RES
MethodTitleLast UpdateResponse via
Abundance' 550000 ,
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Thu Dec 18 11:40:00 1997Continuing Cal File: J:\7201\DATA\5352S07.D
TIC: 5352BOB.D
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
/-A -A_. -'.
Tlm«-> 5.00 6.00 7.00 B.OO 9.00 10 00 11.00 12.00 13 00 14.00 15.00 16 00 17.00 18.00 19.00 20.00 21 00 22.00 23.00 24!6o 2s!oO 2s!oO 2/lod 2s!oO 29!oO 31X00 3l!6o "''
5352B08.D CS8260.M Thu Dec 18 12:17:30 1997 Page 3
Quantitation Report
Data File : J:\7201\DATA\5353B03.DAcq On : 19 Dec 1997 9:30 amSample : VBLK19 , METHOD BLANK , Heated PurgeMisc : 5ml ofw+5ul SSIS V-1147AMS Integration Params: rteint.pQuant Time: Dec 19 10:02 1997
(Not Reviewed)
Position: 1Operator: JNInst : 7201Multiplr: 1.00
Quant Results File: SOIL8260.RE5
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
M (RTE Integrator)for low level soils
J:\7201\METHODS\SOILS260GC/MS TCL 8260 volatilesFri Dec 19 09:24:41 1997Continuing Cal File: J:\7201\DATA\5353S02.DSOIL8260
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)16)28)
Bromochlorome thane1 , 4 -Dif luorobenzeneChlorobenzene-d5
101119
.31
.82
.57
128114117
112558464
972116912
505050
.00
.00
.00
ug/Kgug/Kgug/Kg
000
.01
.00
.01
System Monitoring Compounds13) 1,2-Dichloroethane-d4Spiked Amount 50.00029) Toluene-d8Spiked Amount 50.000
38) BromofluorobenzeneSpiked Amount 50.000
Target Compounds7) Carbon Disulfide8) Acetone9) Methylene Chloride
14) 1,2-Dichloroethane33) 2-Hexanone
11.19 65Range 75 - 114
"l5.2: 98Range 83 - 110
"23.72 95Rancre 85 - 115
7.99 767.13 437.85 84
11.81 6216.23 43
294256 51Recovery
551457 50Recovery
358911 49Recoverv
115739351051
166147252
29
. 15,97.294761
ug/Kg103 .66%ug/Kg100 . 58%ug/Kg 098 .82%
0.00
0 . 01
01
Qvalueug/Kgtfug/Kg#ug/Kg#ug/Kgtfug/Kg#
7551334756
(#) = qualifier out of5353B03.D SOIL3260.M
range (m; =Fri Eer
manual integration19 10:02:41 1997 Page 1
Quantitation Report
Data File : J:\7201\DATA\5353B03.DAcq On : 19 Dec 1997 9:30 amSample : VBLK19 , METHOD BLANK , Heated PurgeMisc : 5ml ofw+5ul SSIS V-1147AMS Integration Params: rteint.pQuant Time: Dec 19 10:02 1997
Position: 1Operator: JNInst : 7201Multiplr: 1.00
Quant Results File: SOIL8260.RES
MethodTitleLast UpdateResponse via
Abundance500000
450000
400000 •
350000
300000
250000
200000
150000
100000
50000
J:\7201\METHODS\SOIL8260.M (RTE Integrator)GC/MS TCL 8260 volatiles for low level soilsFri Dec 19 09:24:41 1997Continuing Cal File: J:\7201\DATA\5353S02.D
TIC: 5353B03.D
ia9
Time--> 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 2200 23.00 24.00 25.00 26.00 27.00 28.00 29.00 3000 31.00 j
5 3 5 3 B 0 3 . D SOIL8260.M Fri Dec 19 1 0 : 0 2 : 4 4 1997 Page 2
Quantitation Report
Data File : J:\7201\DATA\5356B03.DAcq On : 22 Dec 1997 8:41 amSample : VBLK22 , Method BlankMisc : 5ml ofw+5ul SSIS V-1147AMS Integration Params: rteint.pQuant Time: Dec 22 9:14 1997
(Not Reviewed)
Position: 2Operator: JNInst : 7201Multiplr: 1.00
Quant Results File: CS8260.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL -i- CS 8260 for 5ml water samples.Mon Dec 22 08:34:24 1997Continuing Cal File: J:\7201\DATA\5356S02.DCS8260
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)18)33)
Bromochlorome thane1 , 4 -Dif luorobenzeneChlorobenzene-d5
10.11.19.
328257
128114117
113471608321512993
505050
.00
. 00
.00
ug/1ug/1ug/1
000
.02
.02
. 00
System Monitoring Compounds15) l,2-Dichloroethane-d4Spiked Amount 50.00034) Toluene-d8Spiked Amount 50.00044) Bromof luorobenzeneSpiked Amount 50.000
Target Compounds2) Dichlorodif luoromethane9) Carbon Disulfide10) Acetone11) Methylene Chloride19) 1, 1, 1-Trichloroethane21) Benzene25) Dibromomethane36) Toluene37) Tetrachloroethene38) 2-Hexanone39) Chlorobenzene41) Ethylbenzene46) 1, 2, 3-Trichloropropane47) 1, 3-Dichlorobenzene48) 1 , 4 -Dichlorobenzene49) 1 . 2 -Dichlorobenzene
11.19Range 76
15.20Range 88
23.71Range 86
65 288923114 Recovery98 617644 48110 Recovery95 395455 50115 Recovery
51.20 ug/1
4777
101113151716192023262627
.32
.99
. 15
.84
.67
.45
.56
.42
.19
.23
.67
.09
.71
.21
.40
.05
85764384977817491
1644311210675146146146
75393262472127761057184271825971276
2885211681962
241467331234214185
£'
0 .02
99
16
102 .40%ug/197.98%
ug/1 0100 .32%
0 . 02
00
Qvalue001200000
1300&000
.15
.89
.90
.91
. 13
. 13
.15
. 16
.21
.87
. 10
.36
.30
.30
.43
ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1ug/1
#
#
#####
###
42805699325017607994426743959291
(#) = qualifier out of range (m) = manual integration5356B03.D CS8260.M Mon Dec 22 09:14:40 1997 Page 1
Quantisation Report
Data File : J:\7201\DATA\5356B03.DAcq On : 22 Dec 1997 8:41 amSample : VBLK22 , Method BlankMisc : 5ml ofw+5ul SSIS V-1147AMS Integration Params: rteint.pQuant Time: Dec 22 9:14 1997
Position: 2Operator: JNInst : 7201Multiplr: 1.00
Quant Results File: CS8260.RES
MethodTitleLast UpdateResponse via
Abundance
550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Mon Dec 22 08:34:24 1997Continuing Cal File: J:\7201\DATA\5356S02.D
TIC: 5356B03.D
o£
O
Io
Time-> 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 2300 24.00 25.00 26.00 27.00 28.00 29.00 30.00 31.00___{
5356B03.D CS8260.M Mon Dec 22 09:14:45 1997 Page 2
Quantitation Report
Data FileAcq OnSampleMisc
J:\7201\DATA\5058B08.D27 Feb 1998 2:04 pmVBLK27 METHOD BLANK5UL V1161E + 5ML OFW
MS Integration Params: rteint.pQuant Time: Feb 27 14:36 1998
(Not Reviewed)
Position: 2Operator: LLInst : 7201Multiplr: 1.00
Quant Results File: CS8260.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Fri Feb 27 13 :55:43 1998Continuing Cal File: J:\7201\DATA\5058S07.DCS8260
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)18)33)
Bromochlorome thane1 , 4 -Dif luorobenzeneChlorobenzene-d5
111
019
.29
.81
.57
128114117
128135709132595366
505050
.00
.00
.00
ug/1ug/1ug/1
0.0.0.
,00.00.00
System Monitoring Compounds15) 1,2-Dichloroethane-d4Spiked Amount 50.00034) Toluene-d8Spiked Amount 50.000
44) BromofluorobenzeneSpiked Amount 50.000
Target Compounds9) Carbon Disulfide
11) Methylene Chloride38) 2-Hexanone46) 1,2,3-Trichloropropane47) 1,3-Dichlorobenzene48) 1,4-Dichlorobenzene49) 1,2-Dichlorobenzene
11. 18Range 76
15.20Range 88
23 .73Range 86
65- 114
98- 110
95- 115
167891 51.02 ug/1 0.00Recovery = 102.04%
436926 49.58 ug/1 0.00Recovery = 99.16%
372930 50.69 ug/1 0.00Recovery = 101.38%
771623262627
.96
.83
. 18
.73
.22
.41
. 06
76844375146146146
353747641088
188537158617071100
010
000
270945
141511
ug/1ug/1ug/1ug/i-ug/1ug/1ug/1
Qvalue# 76
95# 30
43678158
(#) = qualifier out of range (m) = manual integration5058B08.D CS8260.M Fri Feb 27 14:36:44 1998 Page 1
Quantitation Report
Data File : J:\7201\DATA\5058B08.DAcq On : 27 Feb 1998 2:04 pmSample : VBLK27 METHOD BLANKMisc : 5UL V1161E -t- 5ML OFWMS Integration Params: rteint.pQuant Time: Feb 27 14:36 1998
Position: 2Operator: LLInst : 7201Multiplr: 1.00
Quant Results File: CS8260.RES
MethodTitleLast UpdateResponse via
Abundance
J:\7201\METHODS\CS8260.M (RTE Integrator)GC/MS TCL + CS 8260 for 5ml water samples.Fri Feb 27 13:55:43 1998Continuing Cal File: J:\7201\DATA\5058S07.D
TIC: 5058B08.D
450000.
400000]
350000
300000
250000
200000
150000
100000.
50000
;!o
Tlme-> 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19100 20.00 21.00 22.00 23.00 24.00 25.00 26.00 27XX) 2s!do 29.00 30.00 3l!oO
5058B08.D CS8260.M Fri Feb 27 14:36:45 1998 Page 2
Quantitation Report
Data File : J:\7001\DATA\1159B03.DAcq On : 8 Jun 1998 8:42 amSample : VBLK08 , Instrument BlankMisc : 5ul V-1185B+40ul MeOHMS Integration Params: rteint.pQuant Time: Jun 8 9:06 1998
8260-25ml
(Not Reviewed)
Position: 10Operator: JNInst : 7001Multiplr: 1.00
Quant Results File: CS8260LO.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7001\METHODS\CS8260LO.M (RTE Integrator)GC/MS TCL 8260 25ml volatiles for water samplesMon Jun 08 08:31:20 1998Continuing Cal File: J:\7001\DATA\1159S02.DCS8260LO
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)18)33)
Bromochlorome thane1 , 4 -Dif luorobenzeneChlorobenzene-d5
7 .9.
13.
771494
128114117
39358368693264997
101010
.00
.00
.00
ug/1ug/1ug/1
000
.00
.00
.00
System Monitoring Compounds15) 1,2-Dichloroethane-d4Spiked Amount 10.000
34) Toluene-d8Spiked Amount 10.000
44) BromofluorobenzeneSpiked Amount 10.000
Target Compounds10) Acetone11) Methylene Chloride29) 1,1,2-Trichloroethane35) 4-Methyl-2-Pentanone46) 1,2,3-Trichloropropane
8Range
11Range
16Range
427642885386
5.406. 11
11.4310 .7316 .53
651149811095115
4384975875
76329 10Recovery
342940 9Recovery
138493 10Recovery
8792148
42238193
61298
00
76
93
48
6229
0.22
ug/1107.60%ug/199.30%
ug/1 0104.80%
0 .00
0 .00
00
ug/1ug/1ug/1ug/1ug/1
Qvalue# 56tf#n#
64133535
(#) = qualifier out of range (m) = manual integration1159B03.D CS8260LO.M Mon Jun 08 09:07:01 1998 7001 Page 1
Quantitation Report
Data File : J:\7001\DATA\1159B03.DAcq On : 8 Jun 1998 8:42 amSample : VBLK08 , Instrument BlankMisc : 5ul V-1185B+40ul MeOHMS Integration Params: rteint.pQuant Time: Jun 8 9:06 1998
8260-25ml
Position: 10Operator: JNInst : 7001Multiplr: 1.00
Quant Results File: CS8260LO.RES
MethodTitleLast UpdateResponse via
J:\7001\METHODS\CS8260LO.M (RTE Integrator)GC/MS TCL 8260 25ml volatiles for water samplesMon Jun 08 08:31:20 1998Continuing Cal File: J:\7001\DATA\1159S02.D
TIC: 1159B03.D
450000
400000
350000
300000
250000
200000 ,
150000 •
100000 .
50000
0T!me-> 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00
1159B03.D CS8260LO.M Mon Jun 08 09:07:02 1998 7001 Page 2
c <j • A.-^y-.-'-v «.-970">Z77 Response Factor Report 7002
Method : J:\7002\METHODS\8270.M (RTE Integrator)Title : GC/MS method 8270 TCL extractables.Last Update : Tue Dec 16 10:12:52 1997Response via : Continuing Calibration
Calibration Files
1)2)3)4)5)6)7)8)9)
10)11)12)13)14)15)16)
17)18)19)20)21)22)23)24)25)26)27)28)29)30)
31)32)33)34)35)36)37)38)39)40)41)
50120
ISSSSMTCTCMTCTCMTCTCTCTTCMTCTC
ISTCTCCTCTCTCTCTMCTTTCTMCT
ITCTCTSCTTT1
CTCTi.
=2350502.0 20=2350505.0 160
Compound
1 , 4 -Dichlorobenzene-d2 - FluorophenolPhenol -d52 -Chlorophenol-d41 , 2 -Dichlorobenzene-dPhenolbis (2-Chloroethyl) eth2 -Chlorophenol1 , 3 -Dichlorcbenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene2 -Methylphenol2,2' -oxybis ( 1 -Chlorop4 -Methylphenoln-Nitroso-di-n-propylHexachloroe thane
Naphthalene-d8Nitrobenzene-d5NitrobenzeneIsophorone2 -Nitrophenol2 , 4 -Dimethylphenolbis (2 -Chloroethoxy) me2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzenNaphthalene4-ChloroanilineHexachlorobutadiene4 -Chloro- 3 -methylphen2 -Methylnaphthalene
Acenaphthene-dlOHexachlorocycl open tad2,4,6 -Trichlorophenol2,4,5 -Trichlorophenol2 - Fluorobiphenyl2 -Chloronaphthalene2 -NitroanilineDimethylphthaiateAcenaphthylene2 , 6 -Dir.it re toluene3 -Nitroanil ine
=2350503 .D=2350507. D
50 20
11101II11113I00
.332
.581
.249
.765
.947
.524
.463
.542
.547
.316
. 166
.255
.395
.976
.609
1110111111]_3100
.314
.622
.281
.840
.819
.554
.380
.673
.640
.513
.163
.325
.270
. 992
.573
111011111103110
80
80
_ _ _ T C
.415
.660
.274
.690
.620
.611
.203
.315
.294
.053
.866
.593
.215
.146
.621
=2350504 .D
120 160 Avg
•> rr TaTD- - - -1.2571.3851.0460.5411.6131.5001.1861 .2851.2820.9460.7843 .4871.2481.0910.551
111011111003110
.320
.393
.019
.471
.463
.422
.059
.197
. 153
.798
.639
.247
.183
.016
.541
111011111103110
.328
.528
.174
.661
.692
.522
.258
.402
.383
.125
.924
.381
.262
. 044
.579
%RSD
48
112311412141425254666
.28
.52
.05
. 17
.26
.58
.85
. 12
.65
. 58#-40#.51.42. 90.03
___ __ _ _ _ _ T QTD- - - - - - - - ___
0000000000000
0001101100
.397
.437
.859
.266
.365
.433
.344
.358
. 967
.436
.222
.357
.617
.413
.462
.502
. 152
. 030
.523
.248
.778
. 353
.306
0000000000000
00
11110
.385
.408
.809
.226
.322
.448
.282
.361
.992
.299
.217
.282
.601
.355
.401
.226
.069
.295
.798
.296
0000000000000
000110110c
.426
.448
.889
.217
. 308
.454
.291
.350
.942
.459
.218
.311
.598
_ _ T C-L k.
.447
. 390
.419
. 115
. 065
. 532
.287
.740
. 349
.371
0.3670.3800 .7950.2160 .2970 . 3990 .2880 .2890.7950.4030 . 1820.3040.497
-i rr>T~\3 I U- - - -
0 .3890 .3730.3800 . 8710 . 9000.4751. 1051 .4490 . 3070 . 343
0000000000000
0000000100
.356
.357
.783
. 195
.257
.374
.248
.260
.685
.376
. 162
.264
.435
.366
.324
.322
.757
. 789
.438
.965
.247
.288
.337
0000000000000
0001001100
.386
.406
.827
.224
.310
.422
.291
.324
. 876
.395
.200
.304
.550
.394
.390
.406
.024
. 970
.492
. 180
.603
. 318
. 339
795
11128
11141415131114
9121819128
121597
.05
.38
.46
.65
.67
.12
.81
.31
.98
.75
.38
.54
.52
.38
.79
.56
. 52
.62
. 99
.06
.23
.60
. 91
= Out of Range8270.M Tue Dec 16 14:10:18 1997 Page 1
MethodTitleLast UpdateResponse via
Response Factor Report 7002
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 10:12:52 1997Continuing Calibration
42)43)44)45)46)47)48)49)50)
51)52)53)54)55)56)57)58)59)60)61)62)
63)64)65)66)67)68)69)70)
71)72)73)74)75)76)77)78)
50120
CMTTMTCTCMTTCTCTT
ITTSCTCTCMTCTTCTTCT
ICMTSTCTTCTT
ITCTCTCTCTCTCT
=2350302. D 20=2350305.0 160
Compound
Acenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2 , 4 -DinitrotolueneDiethylphthalateFluorene4 -Chlorophenyl-phenyl4 -Nitroaniline
Phenanthrene-dlO4, 6-Dinitro-2 -methylpn-Nitrosodiphenylamin2,4, 6-Tribromophenol4 -Bromophenyl -phenyleHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi-n-butylphthalateFluoranthene
Chrysene-dl2PyreneTerphenyl-dl4ButylbenzylphthalateBenzo [a] anthracene3,3' -DichlorobenzidinChrysenebis (2-Ethylhexyl) phth
Perylene-dl2Di -n-octylphthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneIndeno [1,2,3 -cd] pyrenDibenz [a , h] anthraceneBenzo [g, h, i] perylene
=2350303 .D=2350307.0
50 20
1.0950.2080.1211.5770.4471.3311.2400.6450.239
0. 1780.4450.1980.2590.3620.2330.9900.6020.9711.1791. 146
1.0560.7380.4650.9790.1770.9670.616
1.0641.0621.0380.9480.9760.7540.833
1.163
1.6090.4061.2941.2550.669
0 .4900.1830.2570.368
1.0340.8940.9771.1981. 147
1.0350.7570 .4390 . 9800.2200.9700.610
1.0040. 9971.0950.8910.8840.6510.737
80
80
1 .0460.2080.1261 .4320.4391.2511.1760.6460.286
. _ _ _ _ !0. 1480.4430.2140.2540.3430.1980.9330.7340.9281 . 1391.075
- - - - - I0.9850.7020 .4660. 9470.2170.8990.557
- - - - - I1.0391.0940. 9010.9420.9690.7590.858
=2350304 .D
120 160 Avg
0 .0 .0.1 .0.1.0.0 .0.
STD0.0.0.0.0.0.0.0.0 .0 .0 .
STD0.0 .0 .0.0.0 .0 .
STD0 .0 .0 .0.0 .0 .0 .
849240148158382056982548285
140359179224293203785620787988919
834569407806203770438
893878738827841639765
0.7190.2270.1431.0080 .3620.9200.8220.4650.294
0.1040 .2890.1570.1810.2470.1740.6650.5910.6650 .8370 .801
0.6910.4860.3550.7130. 1810.6660.339
0 .7600.7950.7950 .7340 .5950 .4470.561
000101100
00000000011
0000000
0000000
. 974
.220
.135
.357
.407
. 170
.095
.595
.276
.143
.405
.186
.235
.322
.202
.881
.688
.866
. 068
.018
. 920
.650
.426
.885
.200
.855
.512
.952
.965
.913
.868
.853
.650
.751
%RSD
18 . 937.059.60
19.478.96
15.0017. 1014 .489.09
21 . 1119.7711 .4814 . 1315. 9612 .0217.3818.6215.6814 . 3715.02
16 .8018 .0710.8613.559.97
15.5623 .48
13 .2113 .0816.7510.2818 . 1819.4615. 58
Out of Range8270 .M Tue Dec 16 14:10:24 1997 Page 2
Quantitation Report (Not Reviewed)
Data FileAcq OnSampleMisc
J:\7002\DATA\2350S02.D16 Dec 1997 9:02 amSSTD0502ul of S-1020B
MS Integration Params: LSCINT.PQuant Time: Dec 16 10:11 1997
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 09:40:03 1997Continuing Cal File: J:\7002\DATA\2350S02.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) 1 , 4 -Dichlorobenzene-d417) Naphthalene-dS31) Acenaphthene-dlO51) Phenanthrene-dlO63) Chrysene-dl271) Perylene-dl2
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol -d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2-Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000
35) 2-FluorobiphenylSpiked Amount 100.000
54) 2 , 4 , 6-TribromophenolSpiked Amount 150.00065) Terphenyl-dl4Spiked Amount 100.000
Target Compounds6) Phenol7) bis (2-Chloroethyl) ether8) 2-Chlorophenol9) 1 , 3-Dichlorobenzene10) 1 , 4 -Dichlorobenzene11) 1 , 2 -Dichlorobenzene12) 2-Methylphenol
81013162326
7Range
8Range
8Range
8Range
9Range
12Range
15Range
20Range
.68
.46
.68
.95
.37
.75
.2321. 1810.4433.9316.4235.2643.4010.7133
152136164188240264
112- 11099
- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
69576244938138865252027279863266428
115849Recovery
137496Recovery
108587Recovery66518Recovery
121651Recovery
199952Recovery62493Recovery
258234Recovery
404040404040
50
50
50
50
50
50
50
50
.00
.00
.00
.00
.00
.00
.00=.00=.00=.00=.00=.00=.00=
. 00=
ngngngngngng
ng33
ng33
ng33
ng50
ng50
ng50
ng33
ng50
000000
0.33%
0.33%
0.33%
0.00%
0.00%
0. 00%
0.33%
0.00%
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Qvalue
13) 2 , 2 ' -oxybis ( 1 -Chloropropan14) 4 -Methylphenol15) n-Nitroso-di -n-propylamine16) Kexachloroethane19) Nitrobenzene20) Isophorone21) 2-Nitrophenol22) 2 , 4 -Dimethylphenol
888888889999999
. 19
.32
.46
.64
.70
.95
.92
. 98
.09
. 17
.36
.44
.75
.89
.83
9493
12814614614610845108701177782
139107
169359132548127251134150134530114449101425283051121296849085294813371826305081478111742
505050505050505050505050505050
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
. 00
ngngngngngngngngngngngngngngng
#
#
9979999810098894199948697989797
(#) = qualifier out of range (m) = manual integration2350S02.D 8270.M Tue Dec 16 10:11:55 1997 Page 1
Quantitation Report (Not Reviewed)
Data File : J:\7002\DATA\2350S02.DAcq On : 16 Dec 1997 9:02 amSample : SSTD050Misc : 2ul Of S-1020BMS Integration Params: LSCINT.PQuant Time: Dec 16 10:11 1997
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 09:40:03 1997Continuing Cal File: J:\7002\DATA\2350S02.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
23)24)25)26)27)28)29)30)32)33)34)36)37)38)39)40)41)42)43)44)45)46)47)48)49)50)52)53)55)56)57)58)59)60)61)62)64)66)67)68)69)
bis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6 -Trichlorophenol2,4, 5 -Trichlorophenol2 -Chloronaphthalene2 -NitroanilineDime thylpht ha lateAcenaphthylene2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2 , 4 -DinitrotolueneDie thylpht ha lateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline4 , 6-Dinitro-2-methylphenoln-Nitrosodiphenylamine4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluoranthenePyreneButylbenzylphthalateBenzo [a] anthracene3,3' -Dichlorober.zidineChrysene
810101010101111121212121213131313131313141414141414141515161617171718192021232323
.32
.22
.36
.48
.55
.71
.25
.62
.00
.14
.22
.53
.76
.06
.38
.26
.58
.75
.79
.84
.07
.09
.52
.82
.74
.93
.98
.00
.83
.24
.62
.01
.46
. 11
.24
.86
.43
.88
. 32
.23
.44
9316218012812722510714223719619616265163152165138153184109168165149166204138198169248284266178167178149202202149228252228
1325481053101095182962041335756802410917018898571610801358709917871390842
2166253086796127753118190036360942106627379777675
2310542151831119724144155989
140339814761139457346131188518961930597037137536112536947716261534246162084
338307
505050505050505050505050505050505050505050505050505050505050505050505C50505C505050
.00
.00
. 00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
. 00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
. 00
. 00
. 00
.00
.00
.00
.00
. 00
ngngngngngngngngngngngngngngngngngngng #ng #ngngngngngng #ngngngngngngngngngngngngngngng
9996971001009998999998989797999889969533849786989896649796979910099949999939292999899
(#) = qualifier out of range (m) = manual integration2350S02.D 8270.M Tue Dec 16 10:12:00 1997 Page 2
Quantisation Report
J:\7002\DATA\2350S02.D16 Dec 1997 9:02 amSSTD0502ul of S-1020B
MS Integration Params: LSCINT.PQuant Time: Dec 16 10:11 1997
Data FileAcq OnSampleMisc
(Not Reviewed)
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 09:40:03 1997Continuing Cal File: J:\7002\DATA\2350S02.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
70)72)73)74)75)76)77)78)
bis (2-Ethylhexyl)phthalate 23Di -n-octylphthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneIndeno [1,2, 3-cd] pyreneDibenz [a, h] anthraceneBenzo [g, h, i] perylene
24252526292930
.25
.65
.84
.89
.61
.60
.58
.44
149149252252252276278276
215561354340353564345698315677324997250958277325
50.50.50.50.50.50.50.50.
0000000000000000
ngngngngngngngng
9796979998869593
(ft) = qualifier out of range (m) = manual integration2350S02.D 8270.M Tue Dec 16 10:12:01 1997 Page 3
Quantitation Report
Data File : J:\7002\DATA\2350S02.DAcq On : 16 Dec 1997 9:02 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.PQuant Time: Dec 16 10:11 1997
Position:Operator:Inst :Multiplr:
1ES70021.00
Quant Results File: 8270.RES
MethodTitleLast UpdateResponse via
Abundance
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 09:40:03 1997Continuing Cal File: J:\7002\DATA\2350S02.D
TIC: 2350S02.D
650000
600000
550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
0
W
1
M
?"•*?«£~9 5
"p°z5s"**.
V)
1
u.
itii
,
- - • ., ..
1Cr
<0
1&
— -9 °^ ij ~ *s '15
i3
!
~'- i
z
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11
i
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Time-> 6.00 8.00
2350S02.D 8270.M
10.00 12.00 14.00 16.00 18.00 2000
Tue Dec 16 10:12:11 1997
22.00 24.00 26.00 28.00 30.00 32.00 34.00
Page 4
Evaluate Continuing Calibration Report
•JrData File : J:\7002\DATA\2351S02.D Position: 1Py^Acq On : 17 Dec 1997 9:31 am Operator: ES/ Sample : SSTD050 Inst : 7002
Misc : 2ul of S-1020B Multiplr: 1.00MS Integration Params : LSCINT.P
Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Tue Dec 16 14:37:18 1997Response via Single Level Calibration
Min. RRF 0.000 Min. Rel . Area : 50% Max. R.T. Dev O.SOminMax. RRF Dev 25% Max. Rel. Area : 150%
123456789
10111213141516
1718192021222324252627282930
313233343536373839
ISSSSMTCTCMTCTCMTCTCTCTTCMTCTC
ISTCTCCTCTCTCTCTMCTTTCTMCT
IT1-i.
CTCTSCTr»~.
TCT
Compound
1 , 4 -Dichlorobenzene-d42 - FluorophenolPhenol -d52 -Chlorophenol -d41 , 2 -Dichlorobenzene-d4Phenolbis (2-Chloroethyl) ether2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene2 -Methylphenol2,2' -oxybis (1-Chloropropane4 -Methylphenoln-Nitroso-di-n-propylamineHexachloroe thane
Naphthalene-daNitrobenzene-d5NitrobenzeneIsophorone2 -Nitrophenol2 , 4 -Dimethylphenolbis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2, 4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methyl phenol2 -Methylnaphthalene
Acenaphthene-dlOHexachlorocyclopentadiene2,4, 6 -Trichlorophenol2,4, 5 -Trichlorophenol2 - Fluorobiphenyl2 -Chloronaphthalene2 -Nit roanil ineDime thylpht ha lateAcenaphthylene
AvgRF
1111011111103110
10000000000000
100010011
.000
.328
.528
.174
.661
.692
.522
.258
.402
.383
.125
.924
.381
.262
.044
.579
.000
.386
.406
.827
.224
.310
.422
.291
.324
.876
.395
.200
.304
.550
.000
.394
.390
.406
.024
. 970
.492
. 180
.603
CCRF
1111011111112100
10000000000000
10001]_011
.000
.253
.441
.232
.718
.719
.320
.419
.502
.502
.282
.010
.313
.318
.829
.546
.000
.348
.371
.749
.270
.361
.396
.370
.382
. 965
.465
.236
.342
.626
. 000
.429
.497
. 516
. 179
. 055
.410
.224
.761
%Dev Area%
055
-4-8-113
-12-7-8
-14-931-4205
0989
-20-166
-27-17-10-17-18-12-13
0-8
-27-27-15-816-3-9
.0
.6
.7
. 9
.6
.6
.3
.8
. 1
.6
.0
.3
.6#
.4
.6
. 7
.0
.8
.6
.4
.5
.5
.2
.!#
.9
.2
. 7
.0
. 5
.8
. 0
. 9
.4#
.!#
. 1
.8
. 7
. 7
. 9
170tf160#155#168#160#151#148165#166tf166#166#148121161#145153#
162#142137141164#160tf148174#172tf161#172#172*1155#164#
166#172#178#170#170#170#130162tf164tt
Dev (min)
0000000000000000
00000000000000
000000000
.00
.00
.00
.00
. 00
.00
. 00
.00
. 00
. 00
. 00
.00
. 00
.00
.00
.00
.00
.00
. 00
. 00
. 00
.00
. 00
. 00
.00
. 00
.00
.00
. 00
. 00
. 00
. 00
. 00
. 00
.00
. 00
. 00
. 00
. 00
(#) = Out of Range2351S02.D 8270.M Wed Dec 17 13:39:40 1997 Page 1
Evaluate Continuing Calibration Report
^ Data File : J:\7002\DATA\2351S02.D Position: 1WT Acq On : 17 Dec 1997 9:31 am Operator: ES/ Sample : SSTD050 Inst : 7002
Misc : 2ul of S-1020B Multiplr: 1.00MS Integration Params : LSCINT.P
Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Tue Dec 16 14:37:18 1997Response via Single Level Calibration
Min. RRF 0.000 Min. Rel. Area : 50% Max. R.T. Dev O.SOminMax. RRF Dev 25% Max. Rel. Area : 150%
4041424344454647484950
515253545556575859606162
6364656667686970
71727374757677
CTTCMTTMTCTCMTTCTCTT
ITTSCTCTCMTCTTCTTCT
ICMTSTCTTCTT
ITCTCTCTCTCT
Compound
2 , 6 -Dinitro toluene3-NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzofuran2 , 4 -DinitrotolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline
Phenanthrene-dlO4 , 6-Dinitro-2-methylphenoln-Nitrosodiphenylamine2,4, 6 -Tribromophenol4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi-n- butyl phthalateFluoranthene
Chrysene-dl2PyreneTerphenyl-dl4Butyl benzyl phthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysenebis (2 -Ethylhexyl ) phthalate
Perylene-dl2Di-n-octyl phthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneIndeno [1,2,3 -cd] pyreneDibenz [a, h] anthracene
AvgRF
00000101100
10000000001110000000
1000000
.318
.339
. 974
.220
.135
.357
.407
.170
.095
.595
.276
. 000
.143
.405
.186
.235
.322
.202
. 881
.688
.866
.068
.018
.000
.920
.650
.426
.885
.200
.855
.512
.000
.952
. 965
. 913
.868
.853
.650
CCRF
00100101100
10000000001111000000
1000000
.355
.382
.074
.213
.119
.561
.447
.253
.223
.659
.315
.000
.173
.454
.181
.252
.349
.243
.968
.826
. 971
.081
. 108
.000
.055
.745
.435
. 983
.274
. 959
.535
. 000
.812
.865
.823
. 967
. 923
.724
%Dev
-11-12-10
311-15-9-7
-11-10-14
0-21-122-7-8
-20-9
-20-12-1-8
0-14-14-2
-11-37-12-4
014109
-11-8
-11
.6
.7
.3
.2
. 9
.0
.8
. 1
. 7
.8
. 1
.0
.0
. 1
. 7
.2
.4
.3
.9
. 1
. 1
.2
.8
.0
.7
.6
.1
. 1
. on
.2
. 5
. 0
. 7
.4
. 9
. 4
.2
.4
Area%
166**207**162**170**162**164**166**156**163**169**218**
167**163**170**153**163**161**174**163**229**167**153**1621*
168**168**170**157**169**259**167**146
193**147157**153**197**183**186**
Dev (min;
00000000000
000000000000
00000000
0000000
. 00
.00
.00
. 00
. 00
.00
. 00
. 00
.00
.00
.00
. 00
. 00
.00
.00
.00
.00
.00
. 00
. 00
. 00
. 00
.00
.00
.00
.00
.00
.00
.00
. 00
.00
.00
.00
. 00
.00
.00
. 00
.00
(#) = Out of Range2351S02.D 8270.M Wed Dec 17 13:39:46 1997 Page 2
Evaluate Continuing Calibration ReportrData File : J:\7002\DATA\2351S02.DAcq On : 17 Dec 1997 9:31 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.P
Position:Operator:Inst :Multiplr:
MethodTitleLast UpdateResponse via
Min. RRFMax. RRF Dev
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 14:37:18 1997Single Level Calibration
1ES70021. 00
0.000 Min. Rel. Area : 50%25% Max. Rel. Area : 150%
Max. R.T. Dev O.SOmin
Compound
Benzo[g,h,i]perylene
AvgRF
0.751
CCRF
0.780
%Dev Area% Dev(min)
-3.9 181# 0.0078 CT
(#) = Out of Range2351S02.D 8270.M
SPCC's out = 0 CCCWed Dec 17 13:39:47 1997
s out = 3Page 3
Quantitation Report (Not Reviewed)
Data FileAcq OnSampleMisc
J:\7002\DATA\2351S02.D17 Dec 1997 9:31 amSSTD0502ul of S-1020B
MS Integration Params: LSCINT.PQuant Time: Dec 17 10:08 1997
Position:Operator:Inst ;Multiplr:
1ES70021.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 14:37:18 1997Continuing Cal File: J:\7002\DATA\2350S02.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) 1 , 4 -Dichlorobenzene-d417) Naphthalene-d831) Acenaphthene-dlO51) Phenanthrene-dlO63) Chrysene-dl271) Perylene-dl2
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol -d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2 -Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000
35) 2-FluorobiphenylSpiked Amount 100.000
54) 2 , 4 , 6-TribromophenolSpiked Amount 150.000
65) Terphenyl-dl4Spiked Amount 100.000
Target Compounds6) Phenol7) bis (2-Chloroethyl) ether8) 2-Chlorophenol9) 1 , 3 -Dichlorobenzene
10) 1 , 4 -Dichlorobenzene11) 1 , 2 -Dichlorobenzene12) 2-Methylphenol
81013162326
7Range
8Range
8Range
8Range
9Range
12Range
15Range
20Range
.67
.45
.66
.93
.36
.74
.2321.1710.4433.9116.4135.2543.3810.7033
152136164188240264
112- 110
99- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
118615395982230024421255470272514557
185714
404040404040
47
.00
.00
.00
.00
.00
.00
.02Recovery =
213623Recovery
182723Recovery
106492Recovery
172294Recovery
338925Recovery95482Recovery
438095Recovery
45
49
46
43
51
45
50
.57=.35=.95=.80=.16=.70=.48=
ngngngngngng
ng31
ng30
ng32
ng46
ng43
ng51
ng30
ng50
-0-0-0-0-0-0
0.35%
0.38%
0.90%#
-0.95%
0.80%
-0. 16%
-0.47%
-0.48%
.01
.01
.02
.01
.01
.01
. 00
.00
.00
.01
.00
.01
.02
.01
Qvalue
13) 2 , 2 ' -oxyb is (1 -Chloropropan14) 4 -Methylphenol15) n-Nitroso-di -n-propylamine16) Hexachloroethane19) Nitrobenzene20) Isophorone21) 2 -Nitrophenol22) 2 , 4 -Dimethylphenol
888888889999999
. 19
.32
.46
.63
.69
. 93
.91
. 97
.09
. 17
.34
.44
.74
.88
.83
9493
12814614614610845108701177782
139107
25492719577821040422274922265819007914979334298619539012287580894183666370528133866178598
444348484848433547424442435049
. 15
.32
.49
. 70
. 54
. 71
.31
. 54
.24
.44
.81
.48
. 56
. 81
.43
ngngngngngngngngngngngngngngng
#
#
889088999998979599838787957695
(#) = qualifier out of range (m) = manual integration2351S02.D 8270.M Wed Dec 17 10:08:43 1997 Page 1
Quantitation Report (Not Reviewed)
Data File : J:\7002\DATA\2351S02.DAcq On : 17 Dec 1997 9:31 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.PQuant Time: Dec 17 10:08 1997
Position;Operator;Inst :Multiplr:
1ES70021.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 14:37:18 1997Continuing Cal File: J:\7002\DATA\2350S02.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
23)24)25)26)27)28)29)30)32)33)34)36)37)38)39)40)41)42)43)44)45)46)47)48)49)50)52)53)55)56)57)58)59)60)61)62)64)66)67)68)69)
bis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6 -Trichlorophenol2,4, 5 -Trichlorophenol2 -Chloronaphthalene2 -NitroanilineDimethylphthalateAcenaphthylene2 , 6 -Dinitro toluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2 , 4 -DinitrotolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline4 , 6-Dinitro-2-methylphenolr.-Nitrosodiphenylamine4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluor ant henePyreneButylbenzylphthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysene
810101010101111111212121213131313131313141414141414141415161616171718192021232323
.32
.20
.35
.48
.54
.69
.24
.61
.98
. 13
.21
.51
.74
.05
.37
.25
.57
.73
.78
.82
. 05
.08
.50
.80
.72
.91
. 97
.99
.82
.22
.61
.99
.45
. 10
.22
.84
.41
.87
.31
.22
.42
9316218012812722510714223719619616265163152165138153184109168165149166204138198169248284266178167178149202202149228252228
1957781833171888634776572299511168661690363100841232891430111483213034591179023518305064071019511099123087836124234223
4489231285833604003515501896049051291279
239127132694183581128036509673434831511407568962583669620130255989578039161004563749
45535349535347505153515139494950624951494949474951654850484852486850454849465C7749
.68
.84
.33
.87
.24
. 13
.89
.75
.97
.87
.40
.25
.18
.02
.52
.22
.46
.05
.22
.04
.49
.97
.08
.31
. 11
.93
.77
.97
.72
.20
. 14
.88
.60
.00
.83
. 35
. 94
.84
.22
. 17
.58
ngngngngngngngngngngngngng #ngngngng tfngng #ng #ngngngngngng #ngngngngngngngngngngngngngngng
1009698981009892100999996967610010088789742889382989992698598949999
10096999994958910098100
(#) = qualifier out of2351S02.D 8270.M
range (m) = manual integrationWed Dec 17 10:08:46 1997 Page 2
Quantitation Report
J:\7002\DATA\2351S02.D17 Dec 1997 9:31 amSSTD0502ul of S-1020B
MS Integration Params : LSCINT.PQuant Time: Dec 17 10:08 1997
Data FileAcq OnSampleMisc
(Not Reviewed)
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 14:37:18 1997Continuing Cal File: J:\7002\DATA\2350S02.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
70)72)73)74)75)76)77)78)
bis (2-Ethylhexyl)phthalate 23Di-n-octylphthalateBenzo [b]Benzo [k]Benzo [a]Indeno [1Dibenz [aBenzo [g,
f luoranthenef luoranthenepyrene,2,3 -cd] pyrene,hj anthraceneh, i] perylene
24252526292930
.24
.64
.83
.88
.60
.58
.56
.42
149149252252252276278276
314379522354556669529456621750593943465639501740
43.38.40.39.50.47.48.46.
4016766599310484
ngngngngngng fngng
999999100100
t 10010099
(#) = qualifier out of range (m) = manual integration2351S02.D 8270.M Wed Dec 17 10:08:46 1997 Page 3
Quantitation Report
Data File : J:\7002\DATA\2351S02.DAcq On : 17 Dec 1997 9:31 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.PQuant Time: Dec 17 10:08 1997
Position:Operator:Inst :Multiplr:
1ES70021.00
Quant Results File: 8270.RES
MethodTitleLast UpdateResponse via
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 14:37:18 1997Continuing Cal File: J:\7002\DATA\2350S02.D
Abijndaace
900000
850000
800000
750000
700000
650000
600000
550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
0trim*->
TIC:2351S02.D
n
|
ww—
M
?£
|~
'
fji i 'tf
i _ L. __ r,,_
« «! - i
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2
1z
1
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t * *** ^-J -
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, .1 '.i
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ji , _ ; : . :; •., i
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8.00 1(XOO 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 2800 30.00 32.00 34.00
2351S02.D 8270.M Wed Dec 17 10:08:54 1997 Page 4
Evaluate Continuing Calibration Report <p 70 j X/2.' % 7o9v c3' -
J Data File : J:\7002\DATA\2354S02.D Position: 'l^T Acq On : 20 Dec 1997 8:09 am Operator: ESF Sample : SSTD050 Inst : 7002
Misc : 2ul of S-1020B Multiplr: 1.00MS Integration Params : LSCINT.P
Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Fri Dec 19 10:25:03 1997Response via Single Level Calibration
Min. RRF 0.000 Min. Rel. Area : 50% Max. R.T. Dev O.SOminMax. RRF Dev 25% Max. Rel. Area : 150%
123456789
10111213141516
1713192021222324252627282930
313233343535373339
ISSSSMTCTCMTCTCMTCTCTCTTCMTCTC
ISTCTCCTCTCTCTCTMCTTTCTMCT
ITCTCTSCTTTCT
Compound
1 , 4 -Dichlorobenzene-d42 - FluorophenolPhenol -d52 -Chlorophenol-d41 , 2 -Dichlorobenzene-d4Phenolbis (2-Chloroethyl) ether2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene2 -Methylphenol2,2' -oxybis ( 1 -Chloropropane4 -Methylphenoln-Nitroso-di-n-propylamineKexachloroe thane
Naphthalene-d8Nitrobenzene-d5NitrobenzeneIsophorone2 -Nitrophenol2 , 4 -Dimethylphenolbis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3-methylphenol2 -Methylnaphthalene
Acenaphthene-dlOHexachlorocyclopentadiene2,4,6 -Tri chlorophenol2,4,5 -Tri chlorophenol2 -Fluorobiphenyl2 -Chloronaphthalene2 -NitroanilineDime thylphthal ateAcenaphthylene
AvgRF
11I1011111103110
10000000000000
100010011
.000
.328
.528
. 174
.661
.692
. 522
.258
.402
.383
. 125
. 924
.381
.262
.044
.579
.000
.386
.406
.827
.224
.310
.422
.291
.324
.876
.395
.200
.304
.550
. 000
. 394
.390
.406
.024
. 970
.492
. 180
.603
CCRF
11110111111I2100
10000000000000
100011011
.000
.362
.574
.272
.734
. 903
.428
.465
.568
. 547
.329
.069
.740
.437
. 947
. 571
.000
.381
.403
. 802
.258
.371
.413
.350
.350
. 970
.469
.210
.357
.623
.000
.281
.467
.484
. 155
. 050
.468
.244
.800
%Dev
0-2-3-8
-11-126
-16-11-11-18-1519
-1391
0103
-15-192
-20-8
-10-18-5
-17-13
028-19-19-12-84
-5-12
.0
.6
.0
.3
.0
.5
.2
.5
.8
. 9
. 1
. 7
.0
. 9
.3
.4
. 0
.3
. 7
. 0
.2
. 7
. 1
.3
. 0
.7
.7
.0
.4
.3
.0
. 7#
.7
.2
.8
.2
. 9
.4
.3
Area%
152tf155#151#154#145148142152#154#152 it153#139128156#147142
149143137139145151#142152#1461491608141149150#
144'98
146139144147129144146
Dev (min)
0000000000000000
00000000000000
000000000
.00
.00
.00
.00
.00
.00
.00
. 00
. 00
. 00
. 00
.00
.00
.00
.00
.00
.00
. 00
.00
.00
.00
.00
.00
.00
.00
.00
.00
. 00
.00
. 00
. 00
.00
.00
. 00
.00
. 00
. 00
.00
.00
(#) = Out of Range2354S02.D 8270.M Sat Dec 20 08:55:37 1997 Page 1
Evaluate Continuing Calibration Report
^Data File : J:\7002\DATA\2354S02.D Position: 1Acq On : 20 Dec 1997 8:09 am Operator: ESSample : SSTD050 Inst : 7002Misc : 2ul of S-1020B Multiplr: 1.00MS Integration Params : LSCINT.P
Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Fri Dec 19 10:25:03 1997Response via Single Level Calibration
Min. RRF 0.000 Min. Rel . Area : 50% Max. R.T. Dev O.SOminMax. RRF Dev 25% Max. Rel. Area : 150%
' CTTCMTTMTCTCMTTCTCTT
ITTSCTCTCMTCTTCTTCT
ICMTSTCTTCTT
ITCTCTCTCTCT
Compound
2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2 ,4-Dinitro tolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline
Phenanthrene-dlO4 , 6-Dinitro-2-methylphenoln-Nitrosodiphenylamine2,4,6 -Tribromophenol4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluoranthene
Chrysene-dl2PyreneTerphenyl-dl4ButylbenzylphthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysenebis (2 -Ethylhexyl) phthalate
Perylene-dl2Di-n-octylphthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneIndeno [1,2,3 -cd] pyreneDibenz [a, h] anthracene
AvgRF
00000101100
10000000001110000000
1000000
.318
.339
. 974
.220
.135
.357
.407
. 170
. 095
.595
.276
.000
.143
.405
. 186
.235
.322
.202
.881
.688
.866
.068
. 018
.000
.920
.650
.426
.885
.200
.855
. 512
. 000
.952
. 965
. 913
.868
.853
.650
CCRF
00100101100
100000000011110c1000
111_
1000
.345
.400
. 105
. 108
. 125
.575
.453
.288
.217
.637
.354
.000
. 106
.474
. 190
.254
.355
.224
.993
. 872
. 996
. 164
. 133
.000
. 070
.755
.453
.006
.279
. 976
.583
. 000
.232
. 120
. 114
. 963
. 983
.785
%Dev Area%
-8-18-13507
-16-11-10-11-7
-28
025-17-2-8
-10-10-12-26-15-9
-11
0-16-16-6
-13-39-14-13
0-29-16-22-10-15-20
.5
.0
.4
.9#
.4
. 1
.3
. 1
. 1
. 1
.3#
. 0• 9#. 0.2. 1.2. 9. 7• 7#.0.0. 3
.0
.3
.2
.3
.7
.5#
.2
. 9
. 0
.4#
. 1
. 0
. 9
.2
.8
141188#14575148144146139141142214tf
13883147133135135132138200#142136136
136133139132140214#137129
112129113120113112116
Dev (min)
00000000000
000000000000
00000000
0000000
.00
.00
. 00
.00
. 00
.00
.00
. 00
.00
.00
.00
.00
. 00
. 00
. 00
. 00
. 00
. 00
. 00
. 00
.00
. 00
. 00
.00
. 00
. 00
. 00
. 00
. 00
. 00
. 00
. 00
.00
. oc
. 00
.00
.00
. 00
•) = Out of Range54S02.D 8270.M Sat Dec 20 08:55:43 1997 Paae 2
Evaluate Continuing Calibration ReportrData File : J:\7002\DATA\2354S02.DAcq On : 20 Dec 1997 8:09 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.P
Position: 1Operator: ESInst : 7002Multiplr: 1.00
MethodTitleLast UpdateResponse via
Min. RRFMax. RRF Dev
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Single Level Calibration
0.000 Min. Rel. Area25% Max. Rel. Area
50% Max. R.T. Dev150%
0.50min
Compound
Benzo[g,h,i]perylene
AvgRF
0.751
CCRF
0.756
%Dev Area% Dev(min)
-0 .7 101 0.0078 CT
(#) = Out of Range SPCC's out = 0 CCC's out = 02354S02.D 8270.M Sat Dec 20 08:55:43 1997 Paqe 3
Quantitation Report (Not Reviewed)
Data File : J:\7002\DATA\2354S02.DAcq On : 20 Dec 1997 8:09 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.PQuant Time: Dec 20 8:46 1997
Position:Operator;Inst :Multiplr:
1ES70021.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2353S02.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) 1, 4-Dichlorobenzene-d4 8.6517) Naphthalene-dS 10.4231) Acenaphthene-dlO 13.6451) Phenanthrene-dlO 16.9163) Chrysene-dl2 23.3371) Perylene-dl2 26.71
System Monitoring Compounds2) 2-Fluorophenol 7.21Spiked Amount 150.000 Range 213) Phenol -d5 8.15Spiked Amount 150.000 Range 104) 2-Chlorophenol-d4 8.41Spiked Amount 150.000 Range 335) 1, 2-Dichlorobenzene-d4 8.90Spiked Amount 100.000 Range 1618) Nitrobenzene-d5 9.39Spiked Amount 100.000 Range 35
35) 2-Fluorobiphenyl 12.22Spiked Amount 100.000 Range 43
54) 2 , 4, 6-Tribromophenol 15.36Spiked Amount 150.000 Range 1065) Terphenyl-dl4 20.67Spiked Amount 100.000 Range 33
Target Compounds6) Phenol 8.177) bis (2-Chloroethyl) ether 8.298) 2-Chlorophenol 8.439) 1, 3-Dichlorobenzene 8.61
10) 1 , 4 -Dichlorobenzene 8.6711) 1, 2 -Dichlorobenzene 8.9212) 2-Methylphenol 8.8913) 2 , 2 ' -oxybis (1 -Chloropropan 8.9514) 4-Methylphenol 9.0715) r.-Nitroso-di-n-propylamine 9.1516) Hexachloroethane 9.3219) Nitrobenzene 9.4220) Isophorone 9.7221) 2-Nitrophenol 9.8622) 2, 4-Dimethylphenol 9.80
152136164188240264
112- 11099
- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
94931281461461461084510870
1177782139107
105463 40.00 ng364772 40.00 ng199973 40.00 ng347860 40.00 ng380266 40.00 ng297255 40.00 ng
179589 52.81 ngRecovery = 35
207531 52.47 ngRecovery = 34
167720 50.93 ngRecovery = 3396709 49.33 ngRecovery = 49
173636 52.91 ngRecovery = 52
288619 50.31 ngRecovery = 5082804 52.03 ngRecovery = 34
359011 52.03 ngRecovery = 52
250842 52.73 ng188285 53.09 ng193194 50.23 ng206712 49.83 ng203917 49.97 ng175196 49.21 ng140909 49.58 ng361210 53.45 ng189445 52.02 ng124797 54.58 ng75326 50.95 ng183842 52.69 ng365745 52.91 ng117744 50.41 ng169264 50.17 ng
-0.02-0.02-0.02-0.02-0.02-0.02
-0.02.21%
-0.02.98%
-0.02.95%
-0.02.33%
-0 .02.91%
-0 .02.31%
-0 .02.69%
-0 .02.03%
Qvalue909391999898
100959887999497
# 7895
(#) = qualifier out of range (m) = manual integration2354S02.D 8270.M Sat Dec 20 08:46:25 1997 Page 1
Quantitation Report (Not Reviewed)
Data File : J:\7002\DATA\2354S02.DAcq On : 20 Dec 1997 8:09 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.PQuant Time: Dec 20 8:46 1997
Position: 1Operator: ESInst 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2353S02.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
23)24)25)26)27)28)29)30)32)33)34)36)37)38)39)40)41)42)43)44)45)46)47)48)49)50)52)53)55)56)57)58)59)60)61)62)64)66)67)68)69)
bis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5 -Trichlorophenol2 -Chloronaphthalene2 -NitroanilineDimethylphthalateAcenaphthylene2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2 , 4 -DinitrotolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline4,6-Dinitro-2 -methylphenoln-Nitrosodiphenylamine4 - Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi-n-butylphthalateFluoranthenePyreneButylbenzylphthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysene
810101010101111111212121213131313131313141414141414141415161616171718192021232323
.29
. 19
.33
.46
.52
.67
.22
.58
. 95
. 11
.19
.49
.71
.03
.34
.22
.55
.71
.76
. 80
.03
. 06
.48
.78
.70
.88
. 94
.96
.80
.20
. 59
.97
.43
.07
.20
.83
.38
.85
.29
.20
.39
9316218012812722510714223719619616265163152165138153184109168165149166204138198169248284266178167178149202202149228252228
1882851597091596764423332139289569016295428413670281116791121050262571116916310913450024861801000542761902709931205393667113153321867304293159239885964625120615311032715438897198
431850379208433103506223492747508422215254478170132749463990
5247484949475048524850495550504953505354505051494958545051505049515051495150505150
.99
. 90
.36
.95
.96
.71
.73
.71
. 16
.93
. 10
.84
.00
.67
.66
.73
.86
. 13
. 84
.08
.21
.45
.05
.83
.23
.28
.02
.31
.08
. 93
. 58
. 53
. 84
. 58
. 62
. 82
. 93
. 68
.44
.79
. 98
ngngngngngngngngngngngngngngngngng ftngng tfngngngngngngng #ngngngngngngngngngngngngngngng
9998100981009795
10099999798851009994859942929690
10010095743999969999
10099
10099989790
1DO9999
(#) = qualifier out of range (m) = manual integration2354S02.D 8270.M Sat Dec 20 08:46:27 1997 Page 2
Quantisation Report
Data FileAcq OnSampleMisc
J:\7002\DATA\2354S02.D20 Dec 1997 8:09 amSSTD0502ul of S-1020B
MS Integration Params: LSCINT.PQuant Time: Dec 20 8:46 1997
(Not Reviewed)
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2353S02.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
70)72)73)74)75)76)77)78)
bis (2-Ethylhexyl)phthalate 23.Di-n-octylphthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneIndeno [1,2, 3-cd] pyreneDibenz [a, h] anthraceneBenzo [g, h, i] perylene
24.25.25.26.29.29.30 .
2162818658555339
149149252252252276278276
277186457769416004413876357820365260291564280746
5152494949585958
.77
.38
.08
.57
.76
.98
. 50
.74
ngngngngngng #ngng
9899989998
1009998
(#) = qualifier out of2354S02.D 8270.M
range (m) = manual integrationSat Dec 20 08:46:28 1997 Page 3
Quantitation Report
Data File : J:\7002\DATA\2354S02.DAcq On : 20 Dec 1997 8:09 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.PQuant Time: Dec 20 8:46 1997
Position: 1Operator: ESInst 7002Multiplr: 1.00
Quant Results File: 8270.RES
MethodTitleLast UpdateResponse via
[Abundance
J : \7002 \METHODS\8270 .M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J : \7002\DATA\2353S02.D
TIC: 2354S02.D950000
900000
850000
800000
750000
700000
650000
600000
550000 *
500000 \{
450000 ;j
400000
350000
300000
250000
200000
150000
100000
50000
o ••-. -•..
«".?
——
PK«
r>oi-
dllo
rophtn
ol-4
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irt
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51;
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1
'ju*:Time-> 8.00 10.00
2354S02.D 8270.M
12.00 14.00 16.00 18.00 20.00
Sat Dec 20 0 8 : 4 6 : 3 4 1997
22100 24.00 26.00 2soO 30.00 32.00 34.00
Page 4
Evaluate Continuing Calibration Report c A9709V?/,
^ Kta File : J:\7002\DATA\2363S03.D Position: 1•HVcq On : 29 Dec 1997 10:40 am Operator: ES^T Sample : SSTD050 Inst : 7002r Misc : 2ul of S-1020B Multiplr: 1.00
MS Integration Params : LSCINT.P
Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Fri Dec 19 10:25:03 1997Response via Single Level Calibration
Min. RRF 0.000 Min. Rel. Area : 50% Max. R.T. Dev O.SOminMax. RRF Dev 25% Max. Rel. Area : 150%
123456789
10111213141516
1718192021222324252627282930
313233343536373839
ISSSSMTCTCMTCTCMTCTCTCTTCMTCTC
ISTCTCCTCTCTCTCTMCTTTCTMCT
ITCTCTSCTTTCT
Compound
1 , 4 -Dichlorobenzene-d42 - FluorophenolPhenol -d52 -Chlorophenol -d41 , 2 -Dichlorobenzene-d4Phenolbis (2-Chloroethyl) ether2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene2 -Methylphenol2,2'- oxybi s ( 1 - Chloropropane4 -Methylphenoln-Nitroso-di -n-propylamineHexachloroe thane
Naphthalene-dSNitrobenzene-d5NitrobenzeneIsophorone2 -Nitrophenol2 , 4 -Dimethylphenolbis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4 -Chloro-3 -methyl phenol2 -Methylnaphthalene
Acenaphthene-dlOHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5 -Tri Chlorophenol2 - Fluorobiphenyl2 -Chloronaphthalene2 -NitroanilineDime thylphthal ateAcenaphthylene
AvgRF
111101111I103110
10000000000000
100010011
.000
.328
.528
.174
.661
.692
.522
.258
.402
.383
.125
. 924
.381
.262
. 044
.579
.000
.386
.406
.827
.224
.310
.422
.291
.324
.876
.395
.200
.304
.550
.000
.394
.390
.406
.024
.970
.492
. 180
.603
CCRF
1111011111112100
10000000000000
100011011
.000
.334
.612
.277
.753
.931
.453
.482
.571
. 546
.331
. 128
.813
.395
.969
.579
.000
.388
.414
.806
.251
.366
.416
.348
.340
.976
.483
.201
.353
.621
.000
.263
.459
.454
.163
. 068
.492
.228
.806
%Dev Area%
0-0-5-8
-13-144
-17-12-11-18-2216
-1070
0-0-22
-12-181
-19-4
-11-22-0
-16-12
033-17-11-13-100
-4-12
.0
.5
.5
.8
. 9
. 1
. 5
.8
. 1
.8
.3
. 1
.8
.5
.2
. 0
. 0
. 5
.0
. 5
. 1
. 1
.4
.6
.9
.4
.3
.5
. 1
.9
. 0
.2#
. 7
. 8
.6
. 1
. 0
. 1
. 7
135135138138133134129137137135136130117135134128
134131127126126134129135127135148121132135
12579124113126130117123127
Dev (min)
0000000000000000
00000000000000
000000000
.00
.00
.00
.00
.00
. 00
.00
.00
.00
.00
.00
.00
.00
. 00
.00
. 00
.00
.00
.00
.00
. 00
.00
.00
.00
.00
.00
.00
.00
.00
. 00
.00
.00
.00
.00
.00
.00
.00
.00
. 00
(#) = Out of Range2363S03.D 8270.M Mon Dec 29 11:23:30 1997 Page 1
Evaluate Continuing Calibration Report
l W&ta File : J:\7002\DATA\2363S03.D Position: 1jj PAcq On : 29 Dec 1997 10:40 am Operator: ESf Sample : SSTD050 Inst .- 7002' Misc : 2ul of S-1020B Multiplr: 1.00
MS Integration Params : LSCINT.P
Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Fri Dec 19 10:25:03 1997Response via Single Level Calibration
Min. RRF 0.000 Min. Rel . Area : 50% Max. R.T. Dev O.SOminMax. RRF Dev 25% Max. Rel. Area : 150%
4041424344454647484950
515253545556575359€05132
S3343556'~158>9'0
'12'34
' 56'7
CTTCMTTMTCTCMTTCTCTT
ITTSCTCTCMTCTTCTTCT
ICMTSTCTTCTT
ITCTCTCTCTCT
Compound
2, 6 -Dinitro toluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2, 4 -Dinitro tolueneDiet hylphthal ateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline
Phenanthrene-dlO4, 6 -Dinitro -2 -methylphenoln-Nitrosodiphenylamine2,4, 6-Tribromophenol4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluoranthene
Chrysene-dl2PyreneTerphenyl -d!4Butylbenzylph thai ateBenzo [a] anthracene3,3' -DichlorobenzidineChrysenebis (2-Ethylhexyl) phthalate
Perylene-dl2Di -n-octylphthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneInder.o [ 1 , 2 , 3 -cd] pyreneDibenz [a, h] anthracene
AvgRF
00000101100
10000000001110000000
1000000
.318
.339
. 974
.220
.135
.357
.407
. 170
. 095
.595
.276
.000
. 143
.405
. 186
.235
.322
.202
.881
.688
. 866
.068
.018
.000
. 920
.650
.426
.885
.200
.855
.512
.000
. 952
.965
. 913
.868
. 853
.650
CCRF
0.0.1 .0 .0.1.0.1.1 .0.0.
1.0.0 .0.0.0 .0.1 .0.1 .1 .1.1.1.0.0.0.0.0.0.
1.1 .1 .1 .0 .0 .0.
354401144094107573449279219617325
000104488175251345170010880008197142
000119762501981227944622
000496174202971622511
%Dev Area%
-11-18-175720-15-10-9
-11-3
-17
027-205
-6-715-14-27-16-12-12
0-21-17-17-10-13-10-21
0-57-21-31-112721
.3
.3
.5
.3#
.7
.9
.3
.3
.3
. 7
.8
.0
.3#
.5
. 9
.8
. 1
.8
.6
.9#
.4
. 1
.2
.0
. 6
.2
.6
.8
. 5
.4
. 5
.0
. 1#
. 7• 7#. 9.!#.4
125163tf13056
110124125120123119170#
1186912910411411386121173#123120118
113120117122114145111115
791128892815154
Dev (min)
00000000000
000000000000
00000000
0000000
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
. 00
. 00
. 00
. 00
. 00
. 00
. 00
.00
. 00
.00
.00
.00
. 00
. 00
. 00
.00
. 00
. 00
.00
.00
.00
. 00
. 00
. 00
.00
(#) = Out of Range2363S03.D 8270.M Mon Dec 29 11:23:36 1997 Page 2
Evaluate Continuing Calibration Report
File : J:\7002\DATA\2363S03.Dicq On : 29 Dec 1997 10:40 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.P
Position:Operator:Inst :Multiplr:
MethodTitleLast UpdateResponse via
Min. RRFMax. RRF Dev
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Single Level Calibration
1ES70021 .00
0.000 Min. Rel. Area : 50%25% Max. Rel. Area : 150%
Max. R.T. Dev O.SOmin
Compound
Benzo[g,h,i]perylene
AvgRF
0.751
CCRF
0.486
%Dev Area% Dev(min)
35.3tf 461* 0.00CT
(#) = Out2363S03.D
of Range8270. M Mon
SPCC's out = 0 CCC 'Dec 29 11:23:36 1997
s out = 3?aae 3
Quantitation Report (Not Reviewed)
J:\7002\DATA\2363S03.D29 Dec 1997 10:40 amSSTD0502ul of S-1020B
MS Integration Params: LSCINT.PQuant Time: Dec 29 11:17 1997
Data FileAcq OnSampleMisc
Position:Operator:Inst :Multiplr:
1ES70021 .00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2363S02.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) 1 , 4 -Dichlorobenzene-d417) Naphthalene-d831) Acenaphthene-dlO51) Phenanthrene-dlO63) Chrysene-dl271) Perylene-dl2
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol -d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2 -Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000
35) 2-FluorobiphenylSpiked Amount 100.000
54) 2 , 4 , 6-TribromophenolSpiked Amount 150.00065) Terphenyl-dl4Spiked Amount 100.000
Target Compounds6) Phenol7) bis (2-Chloroethyl) ether8) 2-Chlorophenol9) 1 , 3 -Dichlorobenzene
10) 1 , 4 -Dichlorobenzene11) 1 , 2 -Dichlorobenzene12) 2-Methylphenol
81013162326
7Range
8Range
8Range
8Range
9Range
12Range
1 5Range
20Range
.69
.47
.69
.96
.39
.78
.2621.2010.4633.9416.4335.2743.4110.7333
152136164188240264
112- 11099
- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
93837327872173340297710317544211728
156439Recovery
189134Recovery
149762Recovery88367Recovery
159163Recovery
252004Recovery65195Recovery
302483Recovery
404040404040
52
51
51
48
50
49
54
48
.00
.00
.00
.00
.00
.00
. 90=.93=.73=.29=.72=.46=.96=. 90=
ngngngngngng
ng35
ng34
ng34
ng48
ng50
ng49
ng36
ng48
.27%
.62%
.49%
.29%
.72%
.46%
.64%
. 90%
000000
0
0
0
0
0
0
0
0
Qvala888888
13) 2 , 2 ' -oxybis ( 1 -Chloropropan 914) 4 -Methylphenol 915) n-Nitroso-di -n-propylamine 916) Hexachloroethane19) Nitrobenzene20) Isophorone21) 2-Nitrophenol22) 2 , 4-Dimethylphenol
99999
.22
.34
.48
.66
.71
.96
.94
.00
. 11
. 19
.37
.46
. 77
.91
.85
9493
12814614614610845108701177782139107
22653117048617387218432018130615611413230533000316367611369667907169864330489102947149906
515051515049505053545050505151
. 90
.71
.04
.54
.32
.00
.21
. 99
. 76
. 70
.27
. 70
.78
. 90
.34
ngngngngngngngngngngngngngngng
#
.01
.00
.00
. 00
.00
.01
.02
.01
.01
.01
.00
.00
.00
.00
ue909391999999989499909898977998
(#) = qualifier out2363S03.D 8270.M
of range (m) = manual integrationMon Dec 29 11:17:33 1997 Page 1
Quantitation Report (Not Reviewed)
Data File : J:\7002\DATA\2363S03.DAcq On : 29 Dec 1997 10:40 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.PQuant Time: Dec 29 11:17 1997
Position: 1Operator: ESInst 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2363S02.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
23)24)25)26)27)28)29)30)32)33)34)36)37)38)39)40)41)42)43)44)45)46)47)48)49)50)52)53)55)56)57)58)59)60)61)62)64)66)67)68)69)
bis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6 -Trichlorophenol2,4, 5 -Trichlorophenol2 -Chloronaphthalene2-NitroanilineDime thy IphthalateAcenaphthylene2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2,4-DinitrotolueneDie thy IphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline4,6-Dinitro-2 -methylphenoln-Nitrosodiphenylamine4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluoranthenePyreneButylbenzy IphthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysene
810101010101111121212121213131313131313141414141414151515161617171718192021232323
.34
.24
.38
.50
.57
.72
.27
.63
.01
. 16
.24
. 54
.77
.08
.39
.28
.60
.76
.81
.86
.08
. 11
.53
.83
.75
.93
.00
.02
.85
.26
.65
.02
.48
. 12
.25
.88
.44
. 90
. 34
.25
.45
9316218012812722510714223719619616265
163152165138153184109168165149166204138198169248284266178167178149202202149228252228
17048614245113929639980419797282263144516254690569129935598327
2314591065512660373912227663186839247844203192316034083797364
2771172642081337927037838672181560932731282456319937586732747737498644538442509044413819888338957189925374563
4952494855495349605251505149495355497560495048495063605051515549485047494948485348
.53
.66
.93
.90
.03
.65
.22
.50
.32
.25
. 14
.43
.47
.32
.32
.70
.30
.40
.75
.43
.06
.05
.04
.42
.06
.39
.41
.24
.60
.34
.47
.36
.68
. 19
.79
. 15
. 19
.73
.50
.48
.59
ngngngngngngngngngngngngngngngngng #ngngngngngngngngng #ngngngngngngngngngngngngngngng
109
109999999998
1099899999999799999
109
109999999
(#) = qualifier out of range (m) = manual integration2363S03.D 8270.M Mon Dec 29 11:17:36 1997 Page 2
Quantitation Report
Data FileAcq OnSampleMisc
J:\7002\DATA\2363S03.D29 Dec 1997 10:40 amSSTD0502ul of S-1020B
MS Integration Params: LSCINT.PQuant Time: Dec 29 11:17 1997
(Not Reviewed)
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2363S02.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
70)72)73)74)75)76)77)78)
bis (2-Ethylhexyl)phthalateDi-n-octylphthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneIndeno [1,2, 3-cd] pyreneDibenz [a, h] anthraceneBenzo [g, h, i] perylene
2324252526292930
.26
.66
.86
.91
.64
.65
.62
.49
149149252252252276278276
247083395969310579318100256874164638135272128652
4648495150434744
.40
.08
.23
.17
.02
.51
.27
.27
ngngngngngng ftngng
96989899981009798
(ft) = qualifier out of range (m) = manual integration2363S03.D 8270.M Mon Dec 29 11:17:36 1997 Page 3
Quantitation Report
Data File : J : \ 7002 \DATA\2363S03 .DAcq OnSampleMisc
: 29 Dec 1997 10:40 am: SSTD050: 2ul of S-1020B
Position: 1Operator: ESInst : 7002Multiplr: 1.00
MS Integration Params : LSCINT.PQuant Time: Dec 29 11:17 1997
MethodTitleLast
: J : \7002 \METHODS\8270 .M
Quant Results File: 8270. RES
(RTE Integrator): GC/MS method 8270 TCL extractables.
Update : Fri Dec 19 10:25:03 1997Response via : Continuing Cal File: J:
Abundance850000
800000
750000
700000
650000
600000
550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
0Tlme->
\7002\DATA\2363S02.DTIC:
*
*> —.i£^
« «».} '
1S3tir
i-*— '..
ii
I ;i
•
"xC
2363S03.D
£ 10! =10
12;
i ]
1 i i
2 V --•v t 2t ]
I S]C
? 'I;!i
5.V
:l !•! t| t
''
: : • . ; { • j' 1 ' ' .' : . ; : ''.
8.00 10.00 12.00 14.00 16.00
i
i
^
i
*
18.00 20.00
I
jfvf
;1 .; i» ii
: I'. >.\. H22.00 2440 2600 28.00 3000 "12.00 34.00
Mon Dec 29 11:17:42 1997 Page 4
Evaluate Continuing Calibration Report /' «•/> f. -
H^BData File : J:\7002\DATA\2058S02.D Position: 2^TAcq On : 27 Feb 1998 8:58 am Operator: ESr Sample : SSTD050 Inst : 7002
Misc : 2ul of S-1020B Multiplr: 1.00MS Integration Params : LSCINT.P
Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Fri Feb 20 14:27:15 1998Response via Single Level Calibration
Min. RRF 0.000 Min. Rel. Area : 50% Max. R.T. Dev O.SOminMax. RRF Dev 25% Max. Rel. Area : 150%
123456789
10111213141516
1718192021222324252627282930
313233343536373839
(**20
ISSSSMTCTCMTCTCMTCTCTCTTCMTCTC
ISTCTCCTCTCTCTCTMCTTTCTMCT
ITCTCTSCTTTCT
) =
Compound
1 , 4 -Dichlorobenzene-d42 - FluorophenolPhenol -d52 -Chlorophenol -d41 , 2 -Dichlorobenzene-d4Phenolbis (2-Chloroethyl) ether2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene1 , 2 -Dichlorobenzene2 -Methylphenol2,2' -oxybis ( 1-Chloropropane4 -Methylphenoln-Nitroso-di -n-propylamineHexachlo roe thane
Naphthalene -d8Nitrobenzene-d5NitrobenzeneIsophorone2 -Nitrophenol2 , 4 -Dimethylphenolbis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -Methylnaphthalene
Acenaphthene-dlOHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2 -Fluorobiphenyl2 -Chloronaphthalene2 -NitroanilineDimethylphthalateAcenaphthylene
Out of Range58S02.D 8270. M Fri Feb 27 09
AvgRF
1 .1.I .1 .0.1 .1 .1 .1.1 .I .0.1.0.0.0.
1.0.0.0.0.0.0 .0 .0 .0.0 .0 .0 .0.
1 .0.0 .0.1 .1 .0 .1 .1 .
:56
000123169092709302054163380403182819186907620521
000361366611211295376299379936310272258567
000271441464305127342255698
:56
CCRF
1 .1.1.1.0 .1 .1.1 .1.1 .1.1.1.1.0.0 .
1 .0.0 .0.0.0.0.0.0 .0.0 .0 .0.0.
1 .0.0.0.1 .1 .0 .1 .1 .
1998
000381381216773652150415561526318002248059573504
000355373646238338424334393969394251293579
000183468489302105351190745
%Dev Area%
0-23-18-11-9
-26-9
-21-13-8
-11-22-5
-1673
01
-1-5
-12-14-12-11-3-3
-277
-13-2
032-6-502
-25
-2
.0
.0
. 1
.4
.0
.9**
. 1
. 7
.1
.8
.5
.3
.2
.8
.6
.3
. 0
. 7
.9
. 7
.8
.6
.8
.7
.7
.5
.1**
. 7
.6
. 1
.0
.5**
. 1
.4
.2
. 0
.6
.2
.8
214**249**236**222**212**236**233**218**217**206**207**214**232**210**199**196**
205**196**198**202**193**187**233**195**197**199**197**181**195**188**
199**151**185**187**191**193**201**185**196**
De
0000000000000000
00000000000000
000000000
v (min)
.00
.00
.00
.00
.00
.00
.00
. 00
.00
.00
.00
.00
.00
.00
.00
.00
.00
. DO
.00
.00
. 00
.00
.00
.00
.00
. DO
.00
. 30
.DO
. DO
.DO
. DO
. 30
. 30
. 30
. 30
. 30
. 30
. 30
Page 1
Evaluate Continuing Calibration Report
•Data File : J:\7002\DATA\2058S02.D Position: 2^Acq On : 27 Feb 1998 8:58 am Operator: ESr Sample : SSTD050 Inst : 7002
Wise : 2ul of S-1020B Multiplr: 1.00MS Integration Params : LSCINT.P
Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Fri Feb 20 14:27:15 1998Response via Single Level Calibration
Min. RRF 0.000 Min. Rel . Area : 50% Max. R.T. Dev O.SOminMax. RRF Dev 25% Max. Rel. Area : 150%
4041424344454647484950
515253545556"7£359606162
636465666768€970
71727374757677
CTTCMTTMTCTCMTTCTCTT
ITTSCTCTCMTCTTCTTCT
ICMTSTCTTCTT
ITCTCTCTCTCT
Compound
2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2 , 4 -Dinitro tolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline
Phenanthrene-dlO4, 6 -Dinitro -2 -methyl phenoln-Nitrosodiphenylamine2,4, 6-Tribromophenol4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluoranthene
Chrysene-dl2PyreneTerphenyl-dl4ButylbenzylphthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysenebis (2-Ethylhexyl) phthalate
Perylene-dl2Di -n-octylphthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyreneIndeno [1 , 2 , 3 -cd] pyreneDibenz [a, h] anthracene
AvgRF
0010C101100
10000000001110000000
1011000
.297
.301
.069
.065
.103
.466
.360
. 180
.116
.660
.212
.000
. 081
.458
. 173
.287
. 367
. 123
.956
. 729
. 932
.075
.082
. 000
. 934
. 707
.376
.911
.226
. 914
.476
.000
.908
. CIS
. 117
.925
. 907
.729
CCRF
00100101100
10000000001111000000
1011000
.303
.305
.083
.023
. 082
.587
.373
. 122
.168
.633
.234
.000
. 066
.458
. 167
.278
. 384
. 098
. 993
.860
. 976
.004
. 187
.000
. 121
.821
.372
.960
.235
. 964
.437
. 000
.898
. 059
.307
.971
.904
.696
%Dev Area%
-2-1-16420-8-34
-44
-10
018033
-420-3
-18-46
-9
0-20-161
-5-4-58
01
-4-17-504
.0
.3
.3
.6#
.4
.3
.6
. 9
.7
.1
.4
.0
.5
. 0
.5
. 1
.6
.3
.9
.0
.7
.6
. 7
.0
.0
. 1
. 1
.4
.0
. 5
.2
. 0
. 1
. 0
. 0
. 0
.3
.5
186#193#194#144211#200#188#176#201#188#257#
207#205#199#188#190#200#230#202tf220#211#188#217#
195#217#213#191#191#189#202#170#
156#148153#174#149144138
Dev (min)
00000000000
000000000000
00000000
0000000
.00
.00
.00
.00
.00
.00
. 00
. 00
.00
.00
.00
. 00
. 00
.00
.00
. 00
. 00
.00
.00
. 00
. 00
. 00
.00
. 00
. 00
. 00
.00
. 00
.00
.00
. 00
. 00
. 00
. CO
. CO
. CO
. CO
.00
(#) = Out of Range2058S02.D 8270.M Fri Feb 27 09:57:03 1998 Page 2
Evaluate Continuing Calibration Report
ata FileAcq OnSampleMisc
J:\7002\DATA\2058S02.D27 Feb 1998 8:58 amSSTD0502ul of S-1020B
PositionOperatorInst
2ES7002
Multiplr: 1.00MS Integration Params: LSCINT.P
MethodTitleLast UpdateResponse via
Min. RRFMax. RRF Dev
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Feb 20 14:27:15 1998Single Level Calibration
0.000 Min. Rel. Area25% Max. Rel. Area
50% Max. R.T. Dev O.SOmin150%
Compound
78 CT Benzo [g,h,i]perylene
AvgRF CCRF
0.756 0.784
%Dev Area% Dev(min)
-3.7 146 0.00
(#) = Out of Range2058S02.D 8270.M
SPCC's out = 0 CCC's out = 1Fri Feb 27 09:57:03 1998 Page 3
Quantitation Report (QT Reviewed)
Data File : J:\7002\DATA\2058S02.DAcq On : 27 Feb 1998 8:58 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.PQuant Time: Feb 27 9:54 1998
Position:Operator:Inst :Multiplr:
2ES70021 .00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Feb 20 14:27:15 1998Continuing Cal File: J:\7002\DATA\2051S02.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) 1, 4-Dichlorobenzene-d417) Naphthalene-dS31) Acenaphthene-dlO51) Phenanthrene-dlO63) Chrysene-dl271) Perylene-dl2
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol -d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2-Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000
35) 2-FluorobiphenylSpiked Amount 100.000
54) 2 , 4 , 6-TribromophenolSpiked Amount 150.000
65) Terphenyl-dl4Spiked Amount 100.000
Target Compounds6) Phenol7) bis (2-Chloroethyl) ether8) 2-Chlorophenol9) 1, 3 -Dichlorobenzene
10) 1 , 4 -Dichlorobenzene11) 1, 2 -Dichlorobenzene12) 2-Methylphenol
81013162326
7Range
8Range
8Range
8Range
9Range
12Range
15Range
20Range
.69
.46
.69
.95
.37
.77
.2521.1910.4533.9416.4335.2743.4110.7233
152136164188240264
112- 110
99- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
260063705267341150559584616910403634
448870Recovery
448879Recovery
395195Recovery
251138Recovery
312782Recovery
555316Recovery
116886Recovery
633055Recovery
404040404040
57
53
52
50
49
48
44
53
.00
.00
.00
.00
.00
.00
.48=.54=.27=. 14=.47=.22=.04=.98=
ngngngngngng
ng38
ng35
ng34
ng50
ng49
ng48ng29
ng53
000000
0.32%
0.69%
0.85%
0.14%
0.47%
0.22%
0.36%
0. 98%
.03
.03
.04
.03
.03
.04
.02
.02
.02
.03
.03
.03
.03
.04
Qvalue
13) 2 , 2 ' -oxybis (1 -Chloropropan14) 4 -Methylphenol15) n-Nitroso-di -n-propylamine16) Hexachloroethane19) Nitrobenzene20) Isophorone21) 2-Nitrophenol22) 2 , 4-Dimethylphenol
888888889999999
.21
.33
.47
.65
.71
.96
. 93
.99
. 11
. 18
.36
.46
.76
.91
.85
9493
12814614614610845108701177782
139107
536934373709460018507438496094428354325777405576344297186318163684329050569851209632297672
535251504948505148474650505148
. 77
.45
. 18
. 98
. 00
. 93
. 89
.80
. 92
.63
.94
.27
.46
.08
.31
ngngngngngngngngngngngngngngng
#
#
9285849910098977099798385926794
(#) = qualifier out of range (m) = manual integration2058S02.D 8270.M Fri Feb 27 09:55:16 1998 Page 1
Quantitation Report (QT Reviewed)
Data FileAcq OnSampleMisc
J:\7002\DATA\2058S02.D27 Feb 1998 8:58 amSSTD0502ul of S-1020B
Position:Operator;Inst ;
2ES7002
MS Integration Params: LSCINT.PQuant Time: Feb 27 9:54 1998
Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Feb 20 14:27:15 1998Continuing Cal File: J:\7002\DATA\2051S02.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
23)24)25)26)27)28)29)30)32)33)34)36)37)38)39)40)41)42)43)44)45)46)47)48)49)50)52)53)55)56)57)58)59)60)61)62)64)66)67)68)69)
bis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5 -Trichlorophenol2 -Chloronaphthalene2 -NitroanilineDime thylphthal ateAcenaphthylene2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzofuran2,4-DinitrotolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline4 , 6-Dinitro-2 -methylphenoln-Nitrosodiphenylamine4 -Bromophenyl -phenyletherKexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluoranthenePyreneB'_;tylbenzylphthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysene
810101010101111121212121213131313131313141414141414151515161617171718192021232323
.33
.24
.38
.50
.58
.71
.27
. 63
.00
.16
.24
.54
.77
.07
.39
.27
.59
.76
.84
.87
.08
. 10
.52
.82
.74
.94
. 01
.01
.84
.25
.65
.01
.48
. 12
.24
.87
.43
.89
.32
.25
.44
9316218012812722510714223719619616265
163152165138153184109168165149166204138198169248284266178167178149202202149228252228
37370929485234666285416434726522149925864451072377868199593208642471166149737507637743989128998129944461745
971034805m67666815916447847949795727014099723m46502m32036919439926846868590694686601715682611702186830053864144286971740023181311743065
5447484947455148354851485348505253493350505450514862474644444648564948535655505851
.59
.61
.91
.03
.81
.05
.38
.01
.80
.54
.01
.78
.62
.83
.75
.57
.09
.06
.43
. 15
. 97
.36
.00
.89
.69
.72
.71
.79
.08
.03
.77
.28
.30
.95
.77
.70
.38
.44
. 15
. 16
. 18
ngngngngngngngngngngngngng tfngngngng #ngng #ngngngngngngngngngngngngngngngngngngngngngng
9994999897999210099989796769910096829942
9490989992
97929998999898100848387989598
(#) = qualifier out2058S02.D 8270.M
of range (m) = manual integrationFri Feb 27 09:55:18 1998 Page 2
Quantitation Report
J:\7002\DATA\2058S02.D27 Feb 1998 8:58 amSSTD0502ul of S-1020B
MS Integration Params: LSCINT.PQuant Time: Feb 27 9:54 1998
Data FileAcq OnSampleMisc
(QT Reviewed)
Position: 2Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Feb 20 14:27:15 1998Continuing Cal File: J:\7002\DATA\2051S02.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
70)72)73)74)75)76)77)78)
bis (2-Ethylhexyl) phthalate 23Di-n-octylphthalateBenzo [b]Benzo [k]Benzo [a]Indeno [1Dibenz [aBenzo [g,
f luoranthenef luoranthenepyrene, 2, 3 -cd] pyrene, h] anthraceneh, i] perylene
24252526292930
.24
.65
.85
.90
.64
.66
.64
.48
149149252252252276278276
337163453169534102659538489717456119m351033m395456m
5053485450464646
.04
.82
.55
.37
.47
. 14
.97
.64
ngngngngngngngng
9798929493
(#) = qualifier out of range (m) = manual integration2058S02.D 8270.M Fri Feb 27 09:55:18 1998 Page 3
Quantitation Report
Data File : J:\7002\DATA\2058S02.DAcq On : 27 Feb 1998 8:58 amSample : SSTD050Misc : 2ul of S-1020BMS Integration Params: LSCINT.PQuant Time: Feb 27 9:54 1998
Position:Operator:Inst :
2ES7002
Multiplr: 1.00
Quant Results File: 8270.RES
MethodTitleLast UpdateResponse via
Abundance
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Feb 20 14:27:15 1998Continuing Cal File: J:\7002\DATA\2051S02.D
^TICfZ058S02.D
2200000
2000000
1800000
1600000
1400000
1200000
1000000
M
S
?|
*!*•<* '
1>vf*
800000 I
600000
400000
200000
tlm«->
i|lr
]
8.00
jj:
!i
V)«rt
a
ii
~.Y9J
i<3
j:l: i'-. -."i'1
10.00
M
|
f
9 o"* VM • —f i
s12.(
9 f
I Io, a
»-V
,! i :
• i ^ i' ; I ' ':J\ ' ; " I ' \' • ' r i " J \ ; ' i •/. '.l. K^J," l^^^V ~)0 14.00 16.0018.00
jgui20.00 2200 2440 26o 28oo 3ooo 32.00 34.00
2058S02.D 8270.M Fri Feb 27 0 9 : 5 5 : 2 6 1998 Page 4
Evaluate Continuing Calibration Report 0r
^^^Ka File : J:\7002\DATA\2155S02.D Position: 2Hfcq On : 4 Jun 1998 10:13 am Operator: ES^^Sample : SSTD050 Inst : 7002Y Misc : 2ul of S-1029C Multiplr: 1.00
MS Integration Params : LSCINT.P
Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Thu Jun 04 10:48:37 1998Response via Single Level Calibration
Min. RRF 0.000 Min. Rel. Area : 50% Max. R.T. Dev O.SOminMax. RRF Dev 25% Max. Rel. Area : 150%
123456789
1011121314151617
181920212223242526272829303132
33343536373839
ISCscSCscMTCTCMTCTCMTCTTCTCTTCMTCTC
ISCTCTCCTCTTCTCTCTMCTTTCTMCT
ITCTCTSCTT
Compound
1 , 4 -Dichlorobenzene-d42 - FluorophenolPhenol -d52 - Chlorophenol -d41 , 2 -Dichlorobenzene-d4Phenolbis (2-Chloroethyl) ether2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -DichlorobenzeneBenzyl Alcohol1 , 2 -Dichlorobenzene2 -Methylphenol2,2' -oxybis ( 1 -Chloropropane4 -Methylphenoln-Nitroso-di-n-propylamineHexachloroe thane
Naphthalene-d8Nitrobenzene-d5NitrobenzeneIsophorone2-Nitrophenol2 , 4 -DimethylphenolBenzoic Acidbis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -Methylnaphthalene
Acenaphthene - dl 0Hexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2 - Fluorobiphenyl2 -Chloronaphthalene2 -Nitroaniline
AvgRF
11110131111112110
100000000000000
1000110
.000
.273
.667
.263
.754
.764
.420
.341
.450
.461
.048
.247
.063
.367
.229
.060
.565
. 000
.332
.350
.747
.221
.323
. 197
. 918
.299
.328
. 949
.444
. 179
.306
.640
.000
.122
.378
.394
. 137
.082
.332
CCRF
1111013I111112110
100000000000000
1000110
.000
.376
.790
.337
.808
.713
.580
.281
.511
.530
.079
.359
. 137
.418
.266
.075
.596
.000
.340
.363
.781
. 199
.293
. 136
.945
.265
.320
. 969
.460
.172
.288
.663
.000
.069
.346
.377
.167
. 128
.342
%Dev Area%
0-8-7-5-72
-44
-4-4-3-9-7-2-3-1-5
0-2-3-4109
31-2112
-2-335
-3
04384-2-4-3
.0
.1
.4
.9
.2
.9
.7
.5
.2
.7
.0
.0
.0
.2
.0
.4
.5
. 0
.4
. 7
.6
.0
.3
. 0#
.9
.4
.4
. 1
.6
.9
.9
.6
.0
. 4#
.5
.3
.6
.3
.0
8891898889909089888885909091898888
848586848283639079828482828181
73507375777773
Dev (min)
00000000000000000
000000000000000
0000000
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
. 00
.00
. 00
.00
.00
.00
.00
.00
.00
. 00
. 00
.00
(#) = Out of Range2155S02.D 8270.M Thu Jun 04 11:24:54 1998 Page 1
Evaluate Continuing Calibration Report
^ Kita File : J:\7002\DATA\2155S02.D Position: 2^ Acq On : 4 Jun 1998 10:13 am Operator: ESW Sample : SSTD050 Inst : 7002^ Misc : 2ul of S-1029C Multiplr: 1.00
MS Integration Params : LSCINT.P
Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Thu Jun 04 10:48:37 1998Response via Single Level Calibration
40414243444546474849505152
535455565758596061626364
6566676869707172
7374757677
Min.Max.
TCTCTTCMTTMTCTCMTTCTCTT
ITTSCTCTCMTCTTCTTCT
ICMTSTCTTCTT
ITCTCTCT
RRF 0.000 Min. Rel .RRF Dev 25% Max. Rel.
Compound
DimethylphthalateAcenaphthylene2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2 , 4 -DinitrotolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline
Phenanthrene-dlO4,6-Dinitro-2 -methyl phenoln-Nitrosodiphenylamine2,4, 6 -Tribromophenol4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi -n-butylphthalateFluoranthene
Chrysene-dl2PyreneTerphenyl -d!4ButylbenzylphthalateBenzo [a] anthracene3,3' -DichlorobenzidineChrysenebis (2-Ethylhexyl) phthalate
Perylene-dl2Di-n-octyl phthalateBenzo [b] f luorantheneBenzo [k] f luorantheneBenzo [a] pyrene
Area :Area :
AvgRF
1100100I01100
100000000011
11100000
11111
.247
.650
.318
.359
.030
. 157
.072
.503
.425
.201
. 172
.670
.358
.000
.136
.484
. 177
.260
.343
.134
.934
. 901
.963
. 136
.016
.000
.139
.000
.466
.921
.338
.861
.586
.000
.418
.318
.272
.100
50% Max.R.T. Dev 0 .SOmin150%
CCRF
1100100101100
100000000010
11100000
11111
.218
.734
.322
.347
.053
.083
.048
.524
.409
.112
.165
.625
.294
.000
. 109
.486
.185
.252
.347
.093
.954
.881
. 985
.028
. 952
.000
.199
.049
.437
.935
.324
.879
. 544
.000
.290
.276
.317
. 108
%Dev
2-5-13
-24733-1370617
019-0-43
-130-22
-296
0-5-46
-14
-27
093
-3-0
.3
. I
.3
.3
.2-1#.3#.4.8.4.6.7.9
.0
.9
.4
.5
. 1
.2
.6#
.1
.2
.3
.5
.3
.0
.3
. 9
.2
.5
. 1
. 1
.2
. 0
.0
.2
.5
. 7
Area%
747671667443#54726569717056
665469676967536761676262
6161625960546162
6262596764
Dev (min)
0000000000000
000000000000
00000000
00000
.00
.00
.00
. 00
.00
.00
. 00
. 00
.00
. 00
. 00
.00
.00
. 00
. 00
. 00
. 00
. 00
.00
.00
.00
. 00
.00
.00
. 00
. 00
. 00
. 00
.00
.00
. 00
. 00
. 00
. 00
. 00
.00
. 00
.00
(#) = Out of Range2155S02.D 8270.M Thu Jun 04 11:25:00 1998 Page 2
Evaluate Continuing Calibration Report
a File'Acq OnSampleMisc
J:\7002\DATA\2155S02.D4 Jun 1998 10:13 amSSTD0502ul of S-1029C
Position;Operator;Inst :
MS Integration Params: LSCINT.P
MethodTitleLast UpdateResponse via
Min. RRFMax. RRF Dev
Compound
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Thu Jun 04 10:48:37 1998Single Level Calibration
2ES7002
Multiplr: 1.00
0.000 Min. Rel. Area : 50%25% Max. Rel. Area : 150%
AvgRF CCRF
Max. R.T. Dev O.SOmin
%Dev Area% Dev(min)
78 CT Indeno[1,2,3-cd]pyrene79 CT Dibenz[a,h]anthracene80 CT Benzo[g,h,i]perylene
0.844 0.921 -9.1 68 0.000.632 0.702 -11.1 70 0.000.720 0.671 6.8 62 0.00
(#) = Out of Range2155S02.D 8270.M
SPCC's out = 0 CCC's out = 1Thu Jun 04 11:25:00 1998 Page 3
Quantitation Report (Not Reviewed)
J:\7002\DATA\2155S02.D4 Jun 1998 10:13 amSSTD0502ul of S-1029C
MS Integration Params: LSCINT.PQuant Time: Jun 4 10:47 1998
Data FileAcq OnSampleMisc
Position:Operator;Inst :Multiplr:
2ES70021.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Wed Jun 03 13:57:53 1998Continuing Cal File: J:\7002\DATA\2154S04.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) 1 , 4-Dichlorobenzene-d418) Naphthalene-d833) Acenaphthene-dlO53) Phenanthrene-dlO65) Chrysene-dl273) Perylene-dl2
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol -d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2-Dichlorobenzene-d4Spiked Amount 100.00019) Nitrobenzene-d5Spiked Amount 100.00037) 2-FluorobiphenylSpiked Amount 100.00056) 2 , 4 , 6-TribromophenolSpiked Amount 150.00067) Terphenyl-dl4Spiked Amount 100.000
Target Compounds6) Phenol7) bis (2-Chloroethyl) ether8) 2-Chlorophenol9) 1 , 3 -Dichlorobenzene
10) 1 , 4 -Dichlorobenzene11) Benzyl Alcohol12) 1, 2 -Dichlorobenzene13) 2-Methylphenol
81013162326
7Range
7Range
8Range
8Range
9Range
11Range
15Range
20Range
.45
.19
.36
.60
.00
.34
.0221.9710.2233.6916. 1735.9643. 0610.3533
152136164188240264
112- 11099
- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
187018 40708757 40401186 40673428 40528111 40311922 40
321570 49Recovery
418420 48Recovery
312517 49Recovery
188871 51Recovery
301620 48Recovery
585342 49Recovery
155624 48Recovery
692533 50Recovery
.00
.00
.00
.00
.00
.00
.32=.44=.05=.17=.77=.03=.56=.93=
ngngngngngng
ng32
ng32
ng32
ng51
ng48
ng49
ng32
ng50
.88%
.29%
.70%tf
.17%
.77%
.03%
.37%
.93%
000000
0
0
0
0
0
0
0
0
.00
.00
.00
.00
.00
.01
.00
.00
.00
.00
.00
.00
.00
.00
Qvalue
14) 2 , 2 ' -oxybis ( 1 -Chloropropan15) 4-Methylphenol16) n-Nitroso-di -n-propylamine17) Hexachloroethane20) Nitrobenzene21) Isophorone22) 2-Nitrophenol
788888888889999
. 98
. 10
.24
.41
.47
.59
.71
.70
.75
.87
.94
. 11
.20
.49
.64
9493
128146146791461084510870
1177782
139
400497 49836867 49299456 49353145 50357626 50252295 47317627 51265804 51565169 49296028 50251320 50139307 50321899 49692210 49176449 48
.98
.50
.66
.20
.57
.98
.54
.06
.40
.95
.20
. 19
.43
.74
.86
ngngngngngngngngngngngngngngng
#
#
#
tf
774685999986989488947192899568
(#) = qualifier out of range (m) = manual integration2155S02.D 8270.M Thu Jun 04 10:47:59 1998 Page 1
Quantitation Report (Not Reviewed)
J:\7002\DATA\2155S02.D4 Jun 1998 10:13 amSSTD0502ul of S-1029C
MS Integration Params: LSCINT.PQuant Time: Jun 4 10:47 1998
Data FileAcq OnSampleMisc
Position: 2Operator: ESInst 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Wed Jun 03 13:57:53 1998Continuing Cal File: J:\7002\DATA\2154S04.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
23)24)25)26)27)28)29)30)31)32)34)35)36)38)39)40)41)42)43)44)45)46)47)48)49)50)51)52)54)55)57)58)59)60)61)62)63)64)66)68)69)
2 , 4 -DimethylphenolBenzoic Acidbis (2-Chloroethoxy) methane2 , 4 -Dichlorophenol1,2, 4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2 -Chloronaphthalene2 -NitroanilineDimethylphthalateAcenaphthylene2 , 6 -Dinitrotoluene3-NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzofuran2 , 4 -DinitrotolueneDiethylphthalateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline4,6-Dinitro-2 -methylphenoln-Nitrosodiphenylamine4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi-n-butylphthalateFluoranthenePyreneButylbenzylphthalateBenzo [a] anthracene
9989
10101010101111111112121213121313131313131414141414141515161617161719202122
.59
.71
. 10
.97
.10
.21
.29
.43
.93
.33
.70
.85
.93
.22
.45
.75
.06
.95
.27
.43
.49
. 53
.74
.77
.20
.48
.41
.59
.66
.68
.50
.90
.30
.66
. 12
.77
. 90
.50
.06
. 54
.95
1071059316218012812722510714223719619616265163152165138153184109168165149166204138198169248284266178167178149202202149228
25976612084383686723439328361985878040772115270325472458782034743173387189167565649171658610557869557161536173939528072416402400376446620519055786458399831356814745191482
40899521227029246778298802666741686829479865221801390791647288726616904
4945494848494948525234484849515151495050414650505050494946494949465050504848524949
.01
.18
. 17
.17
.77
.31
.37
.53
.71
.57
.60
.51
.54
.79
.80
.50
.45
.20
.31
.18
.33
.08
.85
.25
.98
.70
.82
.66
.98
.93
.38
. 58
.29
.51
.32
.73
.39
.85
.75
.80
. 99
ngng #ngngngngngngngngngngngngng #ngngngng #ngngng #ngngngngngng #ngngngngngngngngngngngngng
8686679898961001009498959999967199100907797907792839898906679969399969998989999999099
(#) = qualifier out2155S02.D 8270.M
of range (m) = manual integrationThu Jun 04 10:48:01 1998 Page 2
Quantitation Report
Data FileAcq OnSampleMisc
J:\7002\DATA\2155S02.D4 Jun 1998 10:13 amSSTD0502ul of S-1029C
(Not Reviewed)
Position: 2Operator: ESInst 7002
MS Integration Params: LSCINT.PQuant Time: Jun 4 10:47 1998
Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Wed Jun 03 13:57:53 1998Continuing Cal File: J:\7002\DATA\2154S04.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
70) 3,3'-Dichlorobenzidine 22.87 252 213855 49.05 ng71) Chrysene 23.06 228 580377 49.13 ng72) bis(2-Ethylhexyl)phthalate 22.91 149 359353 48.34 ng74) Di-n-octylphthalate 24.31 149 502924 48.96 ng75) Benzo[b]fluoranthene 25.47 252 497457 48.95 ng76) Benzo[k]fluoranthene 25.52 252 513410 51.71 ng77) Benzo[a]pyrene 26.21 252 432089 52.34 ng78) Indeno[l,2,3-cd]pyrene 29.05 276 358942 47.91 ng79) Dibenz[a,h]anthracene 29.03 278 273668 50.30 ng80) Benzo[g,h,i]perylene 29.85 276 261695 41.42 ng
99100999999991001009899
(#) = qualifier out of range (m) = manual integration2155S02.D 8270.M Thu Jun 04 10:48:02 1998 Page 3
Quantitation Report
Data File : J:\7002\DATA\2155S02.DAcq On : 4 Jun 1998 10:13 amSample : SSTD050Misc : 2ul of S-1029CMS Integration Params: LSCINT.PQuant Time: Jun 4 10:47 1998
Position: 2Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
MethodTitleLast UpdateResponse via
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Wed Jun 03 13:57:53 1998Continuing Cal File: J:\7002\DATA\2154S04.D
Abundance
1900000
1800000
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
H
I•
_
8?
1*
IfM
900000 i
800000 I.
700000 £
600000
500000
400000
300000
200000
100000
o -.. ,
tilf -• ! '
i i' !
!
.
ir
_M*
c
M*
i^§ i4
i
';| ! (
*l
Time-> 7.00 8.00 9.00 10^00 11
M
1
a-&r*
i
|
^d';-'-,!oo i2!6o
_0
1i44
J\
i;
i.j : !
yu.
n•
i
riiii
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jil
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1:._,
TIC: 2155S02.D
in
5i ;-t 1
i
.
L ,i ._._.ULL
_^1|L
1
i1 '! ; ' | 1 1
l_... _ y L - . - . - J ^ ———— " ———— -^ —— '16.00 17loO laloO 19lCK) 20!00 2VOO 22100 23lOO 24loO 2s!oO 2e!oO 27.00 2s!oO 29iOO 3o!oO 3l!oO 32!oO 33!6o
2155S02.D 8270.M Thu Jun 04 10:48:06 1998 Page 4
Evaluate Continuing Calibration Report
J^Data File : J:\7002\DATA\2159S03.D Position: 1 '* Acq On : 8 Jun 1998 10:18 am Operator: ES
Sample : SSTD050 Inst : 7002Misc : 2ul of S-1029C Multiplr: 1.00MS Integration Params : LSCINT.P
Method J:\7002\METHODS\8270.M (RTE Integrator)Title GC/MS method 8270 TCL extractables .Last Update Mon Jun 08 09:55:55 1998Response via Single Level Calibration
Min. RRF 0.000 Min. Rel. Area : 50% Max. R.T. Dev O.SOminMax. RRF Dev 25% Max. Rel. Area : 150%
123456789
1011121314151617
181920212223242526272829303132
33343536373839
ISCSCSCSCMTCTCMTCTCMTCTTCTCTTCMTCTC
ISCTCTCCTCTTCTCTCTMCTTTCTMCT
ITCTCTSCTT
Compound
1 , 4 -Dichlorobenzene-d42 - FluorophenolPhenol-d52 -Chlorophenol -d41 , 2 -Dichlorobenzene-d4Phenolbis (2-Chloroethyl) ether2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -DichlorobenzeneBenzyl Alcohol1 , 2 -Dichlorobenzene2 -Methylphenol2,2' -oxybis (1 -Chloropropane4 -Methylphenoln-Nitroso-di-n-propylamineHexachloroe thane
Naphthalene-d8Nitrobenzene-d5NitrobenzeneIsophorone2 -Nitrophenol2 , 4 -DimethylphenolBenzoic Acidbis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -Methylnaphthalene
Acenaphthene-dlOHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5 -Trichlorophenol2 -Fluorobiphenyl2 -Chloronaphthalene2 -Nitroanil ine
AvgRF
111i
013i~1X
112110
^Cc00c00vj
0ccQCC
1o^"•
_»Q
.000
.273
.667
.263
.754
.764
.420
.341
.450
.461
.048
.247
.063
.367
.229
.060
.565
.000
.332
.350
.747
.221
.323
.197
.918
.299
.328
. 949
.444
. 179
.306
.640
. 000
.122
.378
. 394
. 137
.082
.332
CCRF
11110131111112100
100000010000000
1000110
.000
.371
.816
.353
.791
.707
.524
.270
.510
.524
.042
.347
.112
.203
.203
. 974
.556
.000
.346
.363
.752
.207
.295
.122
.002
.270
.331
.979
.444
.172
.270
.631
.000
.066
.339
.367
. 195
. 127
.316
%Dev Area%
0-7-8-7-43
-35
-4-40
-8-46281
0-4-3-068
38-99
-0-303
111
045106
-5-44
.0
.7
.9
.1
.9
.2
.0
.3
. 1
.3
.6
.0
.6
.9
.1
.1
.6
.0
.2
.7
.7
.3
.7
.!#
.2
.7
.9
.2
.0
.9
.8
.4
.0
. 9#
.3
. 9
. 1
.2
.8
8890908986898887888781898882847982
778079757877528874787873757071
634 1#6263686658
Dev (min)
00000000000000000
000000000000000
0000000
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
. 00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
(tt) = Out of Range2159S03.D 8270.M Mon Jun 08 11:03:16 1998 Page 1
Evaluate Continuing Calibration Report
PF Data File : J:\7002\DATA\2159S03.DAcq On : 8 Jun 1998 10:18 amSample : SSTD050Misc : 2ul of S-1029CMS Integration Params : LSCINT.P
Method J:\7002\METHODS\8270.M (RTETitle GC/MS method 8270Last Update Mon Jun 08 09:55:
Position: 1Operator: ESInstMultipl
: 7002r: 1.00
Integrator)TCL extractables .55 1998
Response via Single Level Calibration
Min. RRF 0.000 Min. RelMax. RRF Dev 25% Max. Rel
Compound
40 T Dimethylphthalate41 CT Acenaphthylene42 CT 2, 6-Dinitrotoluene43 T 3 -Nitroaniline44 CMT Acenaphthene45 T 2,4-Dinitrophenol46 MT 4-Nitrophenol47 CT Dibenzofuran48 CMT 2 , 4-Dinitrotoluene49 T Diethylphthalate50 CT Fluorene51 CT 4 -Chlorophenyl -phenylether52 T 4-Nitroaniline
53 I Phenanthrene-dlO54 T 4 , 6-Dinitro-2-methylphenol55 T n-Nitrosodiphenylamine56 S 2 , 4 , 6-Tribromophenol57 CT 4 -Bromophenyl -phenylether58 CT Hexachlorobenzene59 CMT Pentachlorophenol60 CT Phenanthrene61 T Carbazole62 CT Anthracene63 T Di-n-butylphthalate64 CT Fluoranthene
65 I Chrysene-dl266 CMT Pyrene67 S Terphenyl-dl468 T Butylbenzylphthalate69 CT Benzo [a] anthracene70 T 3, 3 ' -Dichlorobenzidine71 CT Chrysene72 T bis (2-Ethylhexyl)phthalate
73 I Perylene-dl274 T Di-n-octylphthalate75 CT Benzo [b] f luoranthene76 CT Benzo [k] f luoranthene77 CT Benzo [a] pyrene
. Area : 50% Max.R.T. Dev 0.SOmin
. Area : 150%
AvgRF
1.2471.6500.3180.3591.0300. 1570.0721 . 5030.4251 .2011.1720 .6700.358
1.0000.1360 .4840. 1770.26C0 .3430. 1340. 9340 . 9010. 9631 . 1361 . 016
1.0001 . 1391 .0000.4660. 9210. 3380.8610 . 586
1 .0001 .4181 .3181 .2721 . 100
CCRF
1.1361.6700.3000.3201.0370.0770.0401 .5110.3731 . 0041. 1270.6020.269
1.0000.0930.4850. 1770 .2500.3530 .0750 . 9500.3540 . 9690 . 9470. 954
1.0001. 1501 .0000 .3370 . 9310 .3050 .8900.433
i . oc:1 . IZ61.2351 .3251 . 121
%Dev Area%
8. 9-1.25.710. 9-0.751. on44 4 H" ~ • ~ TT
-0.512.216.43 .810. 124 . 9
0.027. 9#-0.20.03 .8
-2 . 944 .0#-1.75.2
-0.616.66.1
0.0-1.00.017.0-1. 19.8
-3.418. 1
0 . 022 . 02.3
-4.2-1.9
606357536334#39#625154595844#
5440#5652555534#5448#5447#50
53505145#5244#5347#
5346#515755
Dev (min)
0.000.000.000.000.000.000.000.000.000.000.000.000.00
0.000.000.000.000. 000. 000. 000.000.000.000.000.00
0.000.000.000.000.000. 000.000 . 00
0 .000 . 000.000.000.00
(#) = Out of Range2159S03.D 8270.M Mon Jun 08 11:03:21 1998 Page 2
Evaluate Continuing Calibration Report
Data FileAcq OnSampleMisc
J:\7002\DATA\2159S03.D8 Jun 1998 10:18 amSSTD0502ul of S-1029C
Position:Operator:Inst :
MS Integration Params: LSCINT.P
MethodTitleLast UpdateResponse via
Min. RRFMax. RRF Dev
Compound
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Mon Jun 08 09:55:55 1998Single Level Calibration
1ES7002
Multiplr: 1.00
0.00025%
Min. Rel. Area : 50%Max. Rel. Area : 150%
Max. R.T. Dev O.SOmin
AvgRF CCRF %Dev Area% Dev(min)
78 CT Indeno[1,2,3-cd]pyrene79 CT Dibenz [a,h]anthracene80 CT Benzo[g,h,i]perylene
0.8440.6320.720
0.9150.6720.676
-8.4 58 0.00-6.3 57 0.006.1 53 0.00
(tf) = Out of Range2159S03.D 8270.M
SPCC's out = 0 CCC1Mon Jun 08 11:03:22 1998
s out = 1Page 3
Quantitation Report (Not Reviewed)
J: \7002\DATA\2159S03 .D8 Jun 1998 10:18 amSSTD0502ul of S-1029C
MS Integration Params: LSCINT.PQuant Time: Jun 8 13:13 1998
Data FileAcq OnSampleMisc
Position:Operator:Inst :Multiplr:
1ES70021.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Mon Jun 08 09:55:55 1998Continuing Cal File: J:\7002\DATA\2159S03.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) 1 , 4 -Dichlorobenzene-d418) Naphthalene-dS33) Acenaphthene-dlO53) Phenanthrene-dlO65) Chrysene-dl273) Perylene-dl2
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol -d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2 -Dichlorobenzene-d4Spiked Amount 100.00019) Nitrobenzene-d5Spiked Amount 100.00037) 2-FluorobiphenylSpiked Amount 100.000
56) 2 , 4 , 6-TribromophenolSpiked Amount 150.00067) Terphenyl-dl4Spiked Amount 100.000
Target Compounds6) Phenol7) bis (2-Chloroethyl) ether8) 2-Chlorophenol9) 1 , 3 -Dichlorobenzene
10) 1 , 4 -Dichlorobenzene11) Benzyl Alcohol12) 1 , 2 -Dichlorobenzene13) 2-Methylphenol
81013162226
7Range
7Range
8Range
8Range
9Range
11Range
15Range
20Range
.43
.17
.35
.59
.99
.33
.0221.9610.2133.6816.1735.9643
. 0510.3533
152136164188240264
112- 110
99- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
185624652748345766548613456240266677
318196Recovery
421448Recovery
313880Recovery
183616Recovery
282521Recovery
516322Recovery
121501Recovery
570205Recovery
404040404040
50
50
50
50
50
50
50
50
.00
.00
.00
.00
.00
.00
.00=.00=.00=.00=.00=.00=.00=.00=
ngngngngngng
ng33
ng33
ng33
ng50
ng50
ng50
ng33
ng50
.33%
.33%
.33%
.00%
.00%
.00%
.33%
.00%
000000
0
0
0
0
0
0
0
0
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Qvalue
14) 2 , 2 ' -oxybis (1-Chloropropan15) 4 -Methylphenol16) n-Nitroso-di -n-propylamine17) Hexachloroethane20) Nitrobenzene21) Isophorone22) 2-Nitrophenol
788888888889999
. 98
.09
.23
.40
.46
.58
.70
.69
.74
.86
. 93
.10
.19
.49
.64
9493
1281461467914610845108701177782
139
396068817720294593350379353544241860312535258092511138279045225917128927296450613750168897
505050505050505050505050505050
.00
.00
.00
.00
. 00
. 00
.00
. 00
.00
. 00
. 00
.00
. 00
.00
.00
ngngngngngngngngngngngngngngng
#
#
#
#
784685979988999688967096849665
(#) = qualifier out of range (m) = manual integration2159S03.D 8270.M Mon Jun 08 13:13:18 1998 Page 1
Quantitation Report (Not Reviewed)
Data File : J:\7002\DATA\2159S03.DAcq On : 8 Jun 1998 10:18 amSample : SSTD050Misc : 2ul of S-1029CMS Integration Params: LSCINT.PQuant Time: Jun 8 13:13 1998
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Mon Jun 08 09:55:55 1998Continuing Cal File: J:\7002\DATA\2159S03.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
23)24)25)26)27)28)29)30)31)32)34)35)36)38)39)40)41)42)43)44)45)46)47)48)49)50)51)52)54)55)57)58)59)60)61)62)63)64)66)68)69)
2 , 4 -DimethylphenolBenzoic Acidbis (2 -Chloroethoxy) methane2 , 4 -Dichlorophenol1,2,4 -TrichlorobenzeneNaphthalene4 -ChloroanilineHexachlorobutadiene4 -Chloro-3 -methylphenol2 -MethylnaphthaleneHexachlorocyclopentadiene2,4, 6 -Trichlorophenol2,4, 5 -Trichlorophenol2 -Chloronaphthalene2-NitroanilineDime thylphthal ateAcenaphthylene2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4 -Dinitrophenol4 -NitrophenolDibenzof uran2,4-DinitrotolueneDie thylphthal ateFluorene4 -Chlorophenyl -phenylether4 -Nitroaniline4 , 6-Dinitro-2-methylphenoln-Nitrosodiphenylamine4 -Bromophenyl -phenyletherHexachlorobenzenePentachlorophenolPhenanthreneCarbazoleAnthraceneDi-n-butylphthalateFluoranthenePyreneButyl benzyl pht ha lateBenzo [a] anthracene
9989
10101010101111111112121213121313131313131414141414141515161617161719202122
.58
.70
.09
.96
.09
.21
.28
.42
. 97
.32
.69
.84
.93
.21
.44
.75
.05
. 94
.25
.41
.49
.52
.74
.76
.19
.47
.39
.58
.66
.66
.48
.89
.29
.64
. 11
.75
.89
.49
.05
.52
.94
10710593
16218012812722510714223719619616265163152165138153184109168165149166204138198169248284266178167178149202202149228
24053499773817720219923270041798703362237140399220149514745284541466791586024870661364424911937218891294711381474481223310517293
65285716112843385448712026020211644066957
33261317135124223851129651407585623664763649098654026655888220950531032
5050505050505050505050505050505050505050505050505050505050505050505050505050505050
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
ngng #ngngngngngngngngngngngngng #ngngngng #ngngng ftngngngngngng #ngngngngngngngngngngngngng
8685679799961009992989997979569999988779989889284981008964819493999898989898999990
100
(#) = qualifier out of range (m) = manual integration2159S03.D 8270.M Mon Jun 08 13:13:20 1998 Page 2
Quantisation Report (Not Reviewed)
Data FileAcq OnSampleMisc
J:\7002\DATA\2159S03.D8 Jun 1998 10:18 amSSTD0502ul of S-1029C
Position:Operator:Inst :Multiplr:
1ES70021.00
MS Integration Params: LSCINT.PQuant Time: Jun 8 13:13 1998 Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Mon Jun 08 09:55:55 1998Continuing Cal File: J:\7002\DATA\2159S03.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
70) 3,3'-Dichlorobenzidine 22.87 252 173946 50.00 ng71) Chrysene 23.05 228 507613 50.00 ng72) bis(2-Ethylhexyl)phthalate 22.89 149 274012 50.00 ng74) Di-n-octylphthalate 24.30 149 368763 50.00 ng75) Benzo[b]fluoranthene 25.45 252 429371 50.00 ng76) Benzotk]fluoranthene 25.51 252 441602 50.00 ng77) Benzo[a]pyrene . 26.20 252 373829 50.00 ng78) Indeno[l,2,3-cd]pyrene 29.03 276 305087 50.00 ng79) Dibenz[a,hjanthracene 29.02 278 223935 50.00 ng80) Benzo[g,h,ijperylene 29.83 276 225447 50.00 ng
989998989998991009798
(#) = qualifier out of range (m) = manual integration2159S03.D 8270.M Mon Jun 08 13:13:20 1998 Page 3
Quantitation Report
Data File : J:\7002\DATA\2159S03.DAcq On : 8 Jun 1998 10:18 amSample : SSTD050Misc : 2ul of S-1029CMS Integration Params: LSCINT.PQuant Time: Jun 8 13:13 1998
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
MethodTitleLast UpdateResponse via
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Mon Jun 08 09:55:55 1998Continuing Cal File: J:\7002\DATA\2159S03.D
TlCf2159S03.DAbundance1900000
1800000
1700000
1600000
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1400000
1300000
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1000000
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Page 4
9709277, Quantitation Report (Not Reviewed)
Data File : J:\7002\DATA\2350E09.DAcq On : 16 Dec 1997 3:12 pmSample : GSS3816Misc : 2ul of 500ul-t-5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 16 15:49 1997
Position:Operator:Inst :Multiplr:
2ES70021 .00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 14:37:18 1997Continuing Cal File: J:\7002\DATA\2350S02.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min]
1)17)31)51)63)71)
1 , 4 -Dichlorobenzene-d4Naphthalene-dSAcenaphthene-dlOPhenanthrene-dlOChrysene-dl2Perylene-dl2
81013162326
.69
.45
.67
.94
.36
.74
152136164188240264
94556369847205383376578327502296943
404040404040
.00
.00
.00
.00
.00
.00
ngngngngngng
0000.00
.01
.00
. 00
.00
.00
. 00
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol-d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1,2-Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000
35) 2-FluorobiphenylSpiked Amount 100.00054) 2,4,6-TribromophenolSpiked Amount 150.00065) Terphenyl-dl4Spiked Amount 100.000
7Range
8Range
8Range
8Range
9Range
12Range
15Range
20Range
.2721.2010.4633.9416.4335.2543.3910.7133
112- 11099
- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
315696 100.26 ng 0.04Recovery = 66.84%
392054 104.91 ng 0.02Recovery = 69.94%
279547 94.71 ng 0.02Recovery = 63.14%
152002 84.07 ng 0.01Recovery = 84.07%
289450 78.79 ng C.01Recovery = 78.79%
418759 70.80ng 0.30Recovery = 70.80%
180578 96.69 ng 0.00Recovery = 64.46%
540480 89.43 ng O.CORecovery = 89.43%
Target Compounds6)8)9)
10)12)13)15)19)24)25)29)42)44)46)47)
Phenol2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene2 -Methylphenol2,2' -oxybis ( 1 -Chloropropann-Nitroso-di -n-propylamineNitrobenzene2 , 4 -Dichlorophenol1,2,4 -Trichlorobenzene4 -Chloro- 3 -methylphenolAcenaphthene4 -Nitrophenol2,4-DinitrotolueneDiethylphthalate
8888889910101113131414
.22
.48
.71
.71
.94
.98
. 18
.42
.24
.37
.25
.74
.83
.08
.52
94128146146108457077162180107153109165149
378340263931224341224341
7131677
222644411729
20728929343537338990350183736
1028
8276Si61009600
628966144790
.19
.31_S4..35.26.22.47.10.23.68.00.42.99.97. 15
Qyalueng i >' Ti-ng i~' cngng t (t'cng #ng #ng si/'ong #ng #ng c-i -'~ng ^ i ong L 'Ong -,T 'bng f>Wng #
9998
130984
3393372413013097953258
(#) = qualifier2350E09.D 8270
out of range (m) = manual integrationM Tue Dec 16 16:06:23 1997 Page 1
Quantitation Report
J:\7002\DATA\2350E09.D16 Dec 1997 3:12 pmGSS38162ul of 500ul+5ul IS,V=1000
MS Integration Params: LSCINT.PQuant Time: Dec 16 15:49 1997
Data FileAcq OnSampleMisc
(Not Reviewed)
Position: 2Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 14:37:18 1997Continuing Cal File: J:\7002\DATA\2350S02.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
57)61)64)70)72)
PentachlorophenolDi-n-butylphthalatePyrenebis (2-Ethylhexyl) phthalateDi-n-octylphthalate
1618202324
.62
.23
.42
.24
.65
266149202149149
2069743018
78744244852745
940
9100
.28
.27
.06
.89
.35
ngngngngng
C--
#O^o##
9978997375
(#) = qualifier2350E09.D 8270
out of range (m) = manual integrationM Tue Dec 16 16:06:25 1997 Page 2
Quantitation Report
Data File : J:\7002\DATA\2350E09.DAcq On : 16 Dec 1997 3:12 pmSample : GSS3816Misc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 16 15:49 1997
Position:Operator:Inst :Multiplr;
2ES70021.00
Quant Results File: 8270.RES
MethodTitleLast UpdateResponse via
Abundance
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 14:37:18 1997Continuing Cal File: J:\7002\DATA\2350S02.D
TIC: 2350E09.D ~2000000
1900000
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2350E09.D 8270.M Tue Dec 16 16:06:31 1997 Page 3
5/> ; A < Quantitation Report
Data File : J:\7002\DATA\2354E04.DAcq On : 20 Dec 1997 9:46 amSample : GWS3828Misc : 2ul of 500ul+5ul IS,V=1000MS Integration Params : LSCINT.PQuant Time: Dec 20 10:23 1997
(Not Reviewed)
Position: 2Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2354S028270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)17)31)51)63)71)
1 , 4 -Dichlorobenzene-d4Naphthalene-dSAcenaphthenePhenanthreneChrysene-dl2Perylene-dl2
-dlO-dlO
81013162326
.66
.42
.63
. 90
.33
. 71
152136164188240264
121629446431255233472603440499319289
404040404040
.00
.00
.00
. 00
.00
.00
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00.0,0 .0 ,0 ,
.CO
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. CO
. CO
. CO
.CD
System Monitorir.g Compounds2) 2-FluorophenolSpiked Amount 150.0003') Phenol-d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1,2-Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000
35) 2-FluorobiphenylSpiked Amount 100.00054) 2,4,6-TribromophenolSpiked Amount 150.000
65) Terphenyl-dl4Spiked Amount 100.000
7Range
8Range
8Range
8Range
9Range
12Range
15Range
20Range
.2521. 1710.4333.9016.3935.2243.3510.6733
112- 11:
99- 11C132
- 11C152
- 11:82
- 110172
- 115330
- 123244
- 144
378564 91 .39 ng 0 . Z=>Recovery = 60.93%
437192 91.33 ng O.C2Recovery = 60.89%
339217 87.69 ng 0.02Recovery = 58.46%
190048 85.20 ng O.CORecovery = 85.20%
306274 72.06 r.g 0.33Recovery = 72.06%
525357 71.51 ng 0 . : :Recovery = 71.51%
213022 96 . 90 ng 0.:0Recovery = 64.60%
745795 89. 67 ng 0.TORecovery = 89-67%
Target Compounds6)8)9)
10)12)13)15)19)25)26)29)42)44)46)47)
Phenol2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene2 -Methylphenol2,2' -oxybis ( 1 -Chloropropann-Nitroso-di -n-propylamineNitrobenzene1,2,4 -TrichlorobenzeneNaphthalene4 -Chloro- 3 -T.e thy 1 phenolAcenaphthene4 -Nitropher.ol2,4-DinitrctolueneD i e t hy 1 pht ha 1 a t e
88888899
10101113131414
.19
.45
.68
.68
. 90
.84
. 15
. 39
. 33
.45
.21
. 71
.79
. 05
.48
94128146146108457077
180128107153109165149
4322
2
2
34
2
i238
2
5
353C
0723193119391939102238527705325
591911203937?733597970701641
7072
.99
.245-9TTT5900
790
650
8563107710
. 94
. 31
.46
. 10
. 18
.73
. 10
.23
. 93
. 94
. 69
.20
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# 4# 1
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L C " '® 59# "1
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#-i'-J? 35tf 1 -''c ~ Jif ^3
(#) = qualifier out of range (m) = manual integration2354E04.D 8270.M Sat Dec 20 12:41:44 1997 Page 1
Quantitation Report
Data FileAcq OnSampleMisc
J:\7002\DATA\2354E04.D20 Dec 1997 9:46 amGWS38282ul of 500ul+5ul IS,V=1000
MS Integration Params: LSCINT.PQuant Time: Dec 20 10:23 1997
(Not Reviewed)
Position: 2Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2354S02.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
57)61)64)70)72)
PentachlorophenolDi -n-butylphthalatePyrenebis (2-Ethylhexyl) phthalateDi -n-octylphthalate
1618202324
.58
. 19
.38
.20
.62
266149202149149
2343443290
89337530742350
880
7500
.73
.24
.84
.48
.24
ng sv°bng |ng i'c 'ong #ng #
9978947475
(#) = qualifier out2354E04.D 8270.M
of range (m) = manual integrationSat Dec 20 12:41:46 1997 Page 2
Quantitation Report
Data File : J:\7002\DATA\2354E04.DAcq On : 20 Dec 1997 9:46 amSample : GWS3828Misc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 20 10:23 1997
Position: 2Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
MethodTitleLast UpdateResponse via
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2354S02.D
Abundance
1700000
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22.00 2400 30^00 32oO 3400
Page 3
Sf<Quantitation Report
Data File : J:\7002\DATA\2363E05.DAcq On : 29 Dec 1997 12:24 pmSample : GSS3840Misc : 2ul of 500ul+5ul IS,V=1000MS Integration Params : LSCINT.PQuant Time: Dec 29 13:01 1997
(Not Reviewed)
Position: 2Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2363S03.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)17)31)51)63)71)
1 , 4 -Dichlorobenzene-d4Naphthalene-dSAcenaphthene-dlOPhenanthrene-dlOChrysene-dl2Perylene-dl2
81013162326
.70
.46
.69
. 96
. 38
. 77
152136164188240264
108094407621222524371015303834195673
40.40.40.40.40.40.
000000000000
ngngngngngng
000000
.00
. 00
.00
.00
.00
. 00
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol-d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1,2-Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000
35) 2-FluorobiphenylSpiked Amount 100.00054) 2,4,6-TribromophenolSpiked Amount 150.00065) Terphenyl-dl4Spiked Amount 100.000
7Range
8Range
8Range
8Range
9Range
12Range
15Range
20Range
.2821.2110.4733. 9416.4335.2643.4110
. 7233
112- 110
99- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
304650 84.53 ng 0.03Recovery = 56.35%
376571 86.42 ng. 0.02Recovery = 57.61%
289618 83.94 ng 0.00Recovery = 55.96%
153662 75.48 ng 0.00Recovery = 75.48%
251937 63.66 ng 0.00Recovery = 63.66%
433709 67.03 ng -0.01Recovery = 67.03%
136573 84.05 ng 0.00Recovery = 56.03%
490950 84.82 ng 0.00Recovery = 84.82%
Target Compounds6)8)9)
10)12)15)24)25)29)42)44)46)47)57)61)
Phenol2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene2 -Methylphenoln-Nitroso-di -n-propylamine2 , 4 -Dichlorophenol1,2,4 -Trichlorobenzene4 -Chloro-3 -methyl phenolAcenaphthene4 -N'itrophenol2 , 4 -DinitrotolueneDiet hylpht ha latePentachlorophenolDi -n-butylphthalate
888889
101011131314141618
.23
.49
.72
. 72
. 94
. 19
.26
. 37
. 26
.75
.85
. 1C
. 53
.64
.23
9412814614610870162180107153109165149266149
356591274490226670226670
689182008
38120349627438836769654838
1531561300
1389353249
68685-3-540
690
58765792610
880
.33
. 52
.27
.23
.48
. 11
.75
.36
.78
.22
.27
. 18
.20
.29
Qvalueng J/C"Qng -.(**' a•ngng s HC/Cng #ng u-^vong *ng ^^'ong s • ~ng v-'-bng •,,"'j_ng -#»(*ng «ng -, -.-'-ng #
949299
1004
8624100959791
,"c 73539878
(#) = qualifier out of range (m) = manual integration2363E05.D 8270.M Mon Dec 29 13:01:17 1997 Page 1
Quantisation Report
Data File : J:\7002\DATA\2363E05.DAcq On : 29 Dec 1997 12:24 pmSample : GSS3840Misc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 29 13:01 1997
(Not Reviewed)
Position: 2Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2363S03.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
64) Pyrene 20.43 202 592022 69.66 ng ?i/'° 9770) bis(2-Ethylhexyl)phthalate 23.25 149 1220 0.26 ng # 45
(#) = qualifier out of range (m) = manual integration2363E05.D 8270.M Mon Dec 29 13:01:18 1997 Paae 2
Quantisation Report
Data File : J:\7002\DATA\2363E05.DAcq On : 29 Dec 1997 12:24 pmSample : GSS3840Misc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 29 13:01 1997
PositionOperatorInstMultiplr
2ES70021.00
Quant Results File: 8270. RES
MethodTitleLast UpdateResponse via
Abundance
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2363S03.D
TIC: 2363E05.D
1400000
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12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00
Mon Dec 29 13 :01 :24 1997
3400Page 3
Quantitation Report
J:\7002\DATA\2058E10.D27 Feb 1998 4:57 pmGSS48432ul of 500ul+5ul IS,V=1000
MS Integration Params : LSCINT.PQuant Time: Feb 27 17:33 1998
Data FileAcq OnSampleMisc
(Not Reviewed)
Position: 3Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Feb 27 10:27:16 1998Continuing Cal File: J:\7002\DATA\2058S02.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)17)31)51)63)71)
1 , 4 -Dichlorobenzene-d4Naphthalene-dSAcenaphthenePhenanthreneChrysene-dl2Perylene-dl2
-dlO-dlO
81013162326
.69
.46
.68
.95
.39
.79
152136164188240264
317579943139447297707201590223404602
404040404040
.00
.00
.00
.00
.00
.00
ngngngngngng
00
-0000
.00
.00
.01
.00
.01
.01
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0002} Phenol-d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1,2-Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000
35) 2-FluorobiphenylSpiked Amount 100.00054) 2,4,6-TribromophenolSpiked Amount 150.000
65) Terphenyl-dl4Spiked Amount 100.000
7Range
8Range
8Range
8Range
9Range
12Range
15Range
20Range
.2821.2010.4633.9316.4335.2743.4010.7033
112- 11099
- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
862926 78.71 ng 0.03Recovery = 52.47%
925181 84.39 ng 0.00Recovery = 56.26%
785526 81.39 ng 0.00Recovery = 54.26%
370099 60.34 ng 0.00Recovery = 60.34%
512865 61.31 ng 0.00Recovery = 61.31%
913903 62.76 ng 0.00Recovery = 62.76%
351005 118.81 ng -0.01Recovery = 79.21%
1764247 145.64 ng -0.01Recovery = 145.64%#
Target Compounds6)8)9)
10)12)13)15)19)25)26)29)42)44)46)47)
Phenol2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -Dichlorobenzene2 -Methylphenol2,2' -oxybis ( 1 -Chloropropann-Nitroso-di -n-propylamineNitrobenzene1,2,4 -TrichlorobenzeneNaphthalene4 -Chloro- 3 -methyl phenolAcenaphthene4 -Nitrophenol2, 4 -Dinitro tolueneDiethylphthalate
88.21.48
•8-rTl88999
10101113131414
.71
.93
.01
. 18
.43
. 37
.49
.26
.74
.86
.10
.52
94128146146108457077180128107153109165149
921226766014^fi77 f) p56770223942295
3421541474
4906429847
57903374806270706
2662471406
70684S-4600
750
520
836177630
.25
. 18^r&f
.85
.30
.23
.19
. 17
. 92
.43
.70
.78
.47
.79
. 11
Qvalueng -J •> *»ng rivo'ngng tj-r^cng #ng #ng.',-<3#ng #ng * v'ong tfng * u, 'ong -!.-'Gng i'V 'o#ngo^b#ng #
958799
1004
38783899779497657158
(#) = qualifier out2058E10.D 8270.M
of range (m) = manual integrationFri Feb 27 17:33:47 1998 Page 1
Quantitation Report (Not Reviewed)
Data File : J:\7002\DATA\2058E10.DAcq On : 27 Feb 1998 4:57 pmSample : GSS4843Misc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Feb 27 17:33 1998
Position:Operator:Inst :Multiplr:
3ES70021 .00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Feb 27 10:27:16 1998Continuing Cal File: J:\7002\DATA\2058S02.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
57) Pentachlorophenol61) Di-n-butylphthalate64) Pyrene
161820
632342
266149202
70) bis(2-Ethylhexyl)phthalate 23.25 149
2553554616
1496948907
1470.
90
292653
ngngng
0.14 ng
96788445
(tf) = qualifier out of range (m) = manual integration2058E10.D 8270.M Fri Feb 27 17:33:48 1993 Paae 2
Quantitation Report
Data File : J:\7002\DATA\2058E10.DAcq On : 27 Feb 1998 4:57 pmSample : GSS4843Misc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Feb 27 17:33 1998
Position: 3Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
MethodTitleLast UpdateResponse via
fTlme->
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Feb 27 10:27:16 1998Continuing Cal File: J:\7002\DATA\2058S02.D
TIC: 2058E10.DAbundance6000000
5500000
5000000
4500000
4000000
3500000
3000000
2500000
2000000
1500000 |
1000000 ;I
500000
n
v) 5 aQ P
I 1li » "
«• - ! ;- I: l i f f ! I s
!l * I -: 12 « N ]
I; Iu
8.00 10.00
2058E10.D 8270.M
16.00 18.00 20.0012.00 14.00
Fri Feb 27 17:33:50 1998
2200 24.00 26.00 28.00 30.00 32.00
Page 3
Quantitation Report (QT Reviewed)
Data FileAcq OnSampleMisc
J:\7002\DATA\2155E06.D4 Jun 1998 4:21 pm
GWS45132ul of 250ul+250ul+5ul IS,V=1000
MS Integration Params: LSCINT.PQuant Time: Jun 5 11:32 1998
PositionOperatorInstMultiplr:
2ES70021.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Thu Jun 04 10:48:37 1998Continuing Cal File: J:\7002\DATA\2155S02.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)18)33)53)65)73)
1 , 4 -Dichlorobenzene-d4Naphthalene-dSAcenaphthenePhenanthreneChrysene-dl2Perylene-dl2
-dlO-dlO
81013162326
.45
.20
.37
.61
.01
.35
152136164188240264
171311775871484288861267729455443471
404040404040
.00
.00
.00
.00
.00
.00
ngngngngngng
000000
.00
.00
.00
.00
.00
.00
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol -d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2-Dichlorobenzene-d4Spiked Amount 100.00019) Nitrobenzene-d5Spiked Amount 100.000
37) 2-FluorobiphenylSpiked Amount 100.000
56) 2 , 4 , 6-TribromophenolSpiked Amount 150.00067) Terphenyl-dl4Spiked Amount 100.000
Target Compounds6) Phenol8) 2-Chlorophenol
10) 1 , 4 -Dichlorobenzene11) Benzyl Alcohol
7Range
7Range
8Range
8Range
9Range
11Range
15Range
20Range
7888
16) r.-Nitroso-di-n-propylamine 827) 1 , 2 , 4 -Trichlorobenzene31) 4 -Chloro-3-methylphenol44) Acenaphthene46) 4 -Xitrophenol48) 2 , 4 -Dinitrotoluene49) Dierhylphthalate59) Per.rachlorophenol63) Di-n-butylphthalate66) Pyrene
(#) = qualifier out of range
101013131314161720
(m) =2155E06.D 8270. M Fri Jun 05 1
.0321.9810.2333.7116.2035.9743.0710.3633
. 99
.24
.48
.70
.96
.12
.99
.43
.54
.78
.21
.30
.91
.07
112- 11099
- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
941281467970180107153109165149266149202
159958Recovery
179864Recovery
261672Recovery
112190Recovery
201613Recovery
548672Recovery
229155Recovery
1060645Recovery
1972842678101739892386
21151118158335943951033816812m
2256642494
1462843940
979193
27
23
45
32
30
38
57
55
2648260
4529644029450
730
44
.15=.46=.70=.42=.53=.83=. 57=.44=
.89
. 82
. 56
. 52
. 94
.24
.45
.03
.01
.55
.19
. 04
. 18
. 77
ng18
ng15
ng30
ng32
ng30
ng38
ng38
ng55
ng \ng -3ng :ngng '-\ng ng c.ng <-ng \ng Mngng <-ngng n
0.00.10%#
0.00.64%
0.00. 47%#
0 .02.42%
0 .02. 53%#
0.00.83%#
0.00.38%
0.00.44%
Qvalue3 78>3 85-j 98# 15
fc # 71<» 99A 94ic 98c\c # 67# 58
1-'t 98# 78
,4 100
manual integration1 :32:51 1998 Page 1
Quantisation Report
Data File : J:\7002\DATA\2155E06.DAcq On : 4 Jun 1998 4:21 proSample : GWS4513Misc : 2ul of 250ul -t 250ul + 5ul IS,V=1000MS Integration Params: LSCINT.P
Position: 2Operator: ESInst : 7002Multiplr: 1.00
Quant Time: Jun 5 11:32 1998 Quant Results File: 8270.RES
MethodTitleLast UpdateResponse via
Abundance1300000
1200000
1100000
1000000
900000
800000
700000
600000
500000
400000
300000
200000
100000
0nma->
i'4
ir
t
l~7.
»_
|I]21
«m"
| ]
1i
|
. iv _ LOL00 8.00
H
X«i
* I** 5
9.0(
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Thu Jun 04 10:48:37 1998Continuing Cal File: J:\7002\DATA\2155S02.D
TIC: 2155E06.D
2VOO 22 26!o(i 27!()0 3o!oO 3lT6o 32!(>0 33
2155E06.D 8 2 7 0 . M Fri Jun 05 11:32:54 1998 Page 2
Data FileAcq OnSampleMisc
Quantitation Report
J:\7002\DATA\2161E06.D10 Jun 1998 12:57 pmGWS4 5 15, Montgomery Watson2ul of 250ul+250ul+5ul IS,V=1000
MS Integration Params: LSCINT.PQuant Time: Jun 10 13:31 1998
(Not Reviewed)
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Wed Jun 10 11:09:16 1998Continuing Cal File: J:\7002\DATA\2161S03.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)18)33)53)65)73)
1 , 4 -Dichlorobenzene-d4Naphthalene -d8Acenaphthene-dlOPhenanthrene-dlOChrysene-dl2Perylene-dl2
81013162326
.44
.19
.36
.60
.00
.34
152136164188240264
3589741255058582247980942581963373389
404040404040
.00
.00
.00
.00
.00
.00
ngngngngngng
000000
.00
.00
.01
.00
.01
.02
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol-d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1,2-Dichlorobenzene-d4Spiked Amount 100.00019) Nitrobenzene-d5Spiked Amount 100.000
37) 2-FluorobiphenylSpiked Amount 100.00056) 2,4,6-TribromophenolSpiked Amount 150.00067) Terphenyl-dl4Spiked Amount 100.000.
7Range
7Range
8Range
8Range
9Range
11Range
15Range
20Range
.0321.9710.2233.6916. 1835.9643.0610.3633
112- 11099
- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
455722 34.62 ng 0.00Recovery = 23.08%
456409 27.30 ng 0.00Recovery = 18.20%
634274 53.25 ng 0.00Recovery = 35.50%
285948 42.15 ng 0.00Recovery = 42.15%
462976 40.94 ng 0.00Recovery = 40.94%
842734 46.32 ng 0.00Recovery = 46.32%
318592 62.00 ng 0.00Recovery = 41.33%
1275263 91.50 ng 0.00Recovery = 91.50%
Target Compounds6)8)9)
10)11)13)16)27)31)44)46)48)49)59)63)
Phenol2 -Chlorophenol1 , 3 -Dichlorobenzene1 , 4 -DichlorobenzeneBenzyl Alcohol2 -Methylphenoln-Nitroso-di-n-propylamine1,2,4 -Trichlorobenzene4 -Chloro-3 -methyl phenolAcenaphthene4 -Nitrophenol2 , 4 -DinitrotolueneDiethylphthalatePentachlorophenolDi -n-butylphthalate
111111
78888880033341617
. 99
.24
.47
.47
.69
.69
. 94
. 11
. 98
.43
. 54
.73
.22
.29
. 91
941281461467910870180107153109165149266149
509683636119448698448698
67501325
444790382483579679731859257833292282824
2269887101
3156
.93
.60ngng
Qvaluelf'/~*)%'/•
-3-3-T64 ng3300
4735644831540
800
.33
.67
.15
.24
. 91
.30
. 17
. 15
.26
. 18
.74
.29
ngngngngngngngngngngngng
}}y-ftft/?/£#}C/oI?'/*w %21 '/-fV/uft
ftr /*-ft
79889998264719893989070589978
(ft) = qualifier out of range (m) = manual integration2161E06.D 8270.M Wed Jun 10 13:33:10 1998 Page 1
Quantitat ion Report
Data File : J:\7002\DATA\2161E06.DAcq On : 10 Jun 1998 12:57 pmSample : GWS4515,Montgomery WatsonMisc : 2ul of 250ul+250ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Jun 10 13:31 1998
(Not Reviewed)
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Wed Jun 10 11:09:16 1998Continuing Cal File: J:\7002\DATA\2161S03.D8270
Compound R.T. Qlon Response Cone Unit Qvalue
66) Pyrene 20.06 202 1265001 78.96 ng7 9i 9772) bis(2-Ethylhexyl)phthalate 22.91 149 1121 0.14 ng # 4574) Di-n-octylphthalate 24.32 149 1436 0.14 ng # 75
(#) = qualifier out of range (m) = manual integration2161E06.D 8270.M Wed Jun 10 13:33:11 1998 Page 2
Quantitation Report
Data File : J:\7002\DATA\2161E06.DAcq On : 10 Jun 1998 12:57 pmSample : GWS4515,Montgomery WatsonMisc : 2ul of 250ul+250ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Jun 10 13:31 1998
Position:Operator:Inst :Multiplr:
1ES70021.00
Quant Results File: 8270.RES
MethodTitleLast UpdateResponse via
Abundance
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Wed Jun 10 11:09:16 1998Continuing Cal File: J:\7002\DATA\2161S03.D
TTCT7161E06.D —& 1 WWW
2000000
1900000
1800000
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
900000
800000
700000
600000
500000
400000
300000
200000
100000
0
b1
1J"if*
-,'
.
1
.
a?i1f
•ff
l2
-.''-.
-
£§I
|
:-^I1*r
I
1I
J „
b!«f
!ii2
I
i
12i
L
•
M
i«1
II HI
7.00 8.00 9.00 10.00 1l!oO 12!oO 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 2l!oO 2 !oV^23!doT4Tdo 25!ooT6!oO 27!(X) 28!oO 29.'oo 3o!oO 31.'do
Wed Jun 10 13:33:14 1998
• ' I ' '•'•T'-r'-rT32.00 33.00
2161E06.D 8270.M Page 3
9 7092.7? Quantitation Report
Data File : J:\7002\DATA\2350E08.DAcq On : 16 Dec 1997 2:26 pmSample : GSB3816AMisc : 2ul Of 500ul+5ul IS,V=1000MS Integration Params : LSCINT.PQuant Time: Dec 16 15:03 1997
(QT Reviewed)
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 14:37:18 1997Continuing Cal File: J:\7002\DATA\2350S02.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min]
1) 1 , 4 -Dichlorobenzene-d417) Naphthalene-d831) Acenaphthene-dlO51) Phenanthrene-dlO63) Chrysene-dl271) Perylene-dl2
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol-d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2 -Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.00035) 2 -FluorobiphenylSpiked Amount 100.000
54) 2 , 4 , 6-TribromophenolSpiked Amount 150.00065) Terphenyl-dl4Spiked Amount 100.000
Target Compounds6) Phenol12) 2-Methylphenol
81013162326
7Range
8Range
8Range
8Range
9Range
12Range
15Range
20Range
.69
.47
.69
. 96
. 37
.75
.2721.2010.4633. 9416.4335.2743.4110.7133
152136164188240264
112- 11099
- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
85541304128158179337538349591313667
261062
404040404040
91
.00
.00
.00
.00
.00
.00
.64Recovery
365167 108 .01Recovery =
252455 94 .55Recovery
118418 72 .40Recovery =
232831 77 .07Recovery
309429 67 .93Recovery =
163509 97 .68Recovery =
527463 81 .76Recovery =
ngngngngngng
ng61
ng72
ng63
ng72
ng77
ng67
ng65
ng81
.09%
.01%
.03%
.40%
. 07%
.93%
.12%
.76%
000000
0
0
0
0
0
0
0
0
.01
.01
.01
.01
.00
.00
.04
.02
. 02
.01
. 02
. 01
.01
.00
Qvalue88
13) 2 , 2 ' -oxybis ( 1-Chloropropan 815) n-Nitroso-di -n-propylamine 947) Diethylphthalate61) Di-n-butylphthalate
1418
70) bis (2-Ethylhexyl)phthalate 23
.22
. 94
. 97
. 21
.53
.24
.25
941084570149149149
914588
1190928643
16262354
0000000
.22
.24
.17
.44
.12
. 16
.44
ngngngngngngng
tt»#tt««»
3543810587865
(#) = qualifier out2350E08.D 8270.M
of range (m) = manual integrationTue Dec 16 15:23:06 1997 Page 1
Quantitation Report
Data File : J:\7002\DATA\2350E08.DAcq On : 16 Dec 1997 2:26 pmSample : GSB3816AMisc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 16 15:03 1997
Position;Operator:Inst :Multiplr:
1ES70021.00
Quant Results File: 8270.RES
MethodTitleLast UpdateResponse via
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Tue Dec 16 14:37:18 1997Continuing Cal File: J:\7002\DATA\2350S02.D
TIC: 2350E08.DAbundance1900000
1800000
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
900000 ;800000
700000
600000 •
500000
400000
300000
200000l
100000 liII«w'l
«1 <"? m
i oj • .. "1'
\f c j 1 * J 5 t I* 1 i t ' i5 « i |
i, !l 'Tlme-> 8.00 1000 12.00 14.00 16.00 18.00 20.00 22.00 24.00
I
f
26.00 28.00
2 3 5 0 E 0 8 . D 8 2 7 0 . M Tue Dec 16 15 :23 :14 1997
30!00 32.00 34.00 j
Page 2
Quantitation Report (QT Reviewed)
Data File • J:\7002\DATA\2354E03.DAcq On : 20 Dec 1997 9:01 amSample : GWB3828AMisc : 2ul Of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 20 12:57 1997
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2354S028270
D
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) 1 , 4 -Dichlorobenzene-d417) Naphthalene-dS31) Acenaphthene-dlO51) Phenanthrene-dlO63) Chrysene-dl271) Perylene-dl2
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol -d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2-Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000
35) 2-FluorobiphenylSpiked Amount 100.000
54) 2 , 4 , 6-TribromophenolSpiked Amount 150.000
65) Terphenyl-dl4Spiked Amount 100.000
Target Compounds6) Phenol12) 2-Methylphenol19) Nitrobenzene61) Di-n-butylphthalate64) Pyrene
81013162326
7Range
8Range
8Range
8Range
9Range
12Range
15Range
20Range
.66
.43
.65
.92
.33
.71
.2521.1710.4333.9116.4035.2443.3710.6833
152136164188240264
112- 11099
- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
128075417290220373401555435986321442
420014
404040404040
96
.00
.00
.00
.00
.00
.00
.29Recovery
527661 104 .68Recovery =
411877 101 .11Recovery
195160 83 .09Recovery
309756 77 .97Recovery
502125 78 .94Recovery
201513 105 .41Recovery
775888 94 .25Recovery
ngngngngngng
ng64
ng-69
ng67
ng83
ng77
ng78
ng70
ng94
.19%
.79%
.41%
.09%
.97%
. 94%
.27%
.25%
000000
0
0
0
0
0
0
0
0
.01
.00
.01
.00
.00
.00
.05
.02
.02
.01
.01
.01
.00
.00
Qvalue
70) bis (2-Ethylhexyl) phthalate72) Di-n-octylphthalate
889
18202324
.19
.91
.40
.20
.67
.21
.62
9410877149202149149
67510114633453137274964414
0000010
. 11
.30
. 11
.30
. 12
.18
.45
ngngngngngngng
#$tttttt##
35437781
8875
(#) = qualifier out2354EO3.D 8270. M
range (m) = manual integrationSat Dec 20 12 -.58 :01 1997 Page 1
Quantltation Report
Data File : J:\7002\DATA\2354E03.DAcq On : 20 Dec 1997 9:01 amSample : GWB3828AMisc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 20 12:57 1997
Position:Operator:Inst :Multiplr:
1ES70021.00
Quant Results File: 8270.RES
MethodTitleLast UpdateResponse via
Abundance
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2354S02.D
TIC: 2354E03.D2100000
2000000
1900000
1800000
1700000
1600000
1500000
1400000
1300000
1200000
1100000
1000000
900000
800000
700000
600000
500000
400000
300000
200000
100000T
0
">1 aT)1 ? ".§ •"'! i£ |S £ </i
|V-| ]
jis i§n - ^.0™ c - uO*- • A
* S Si I 1•» I -*" a
5
i '' I I I ' |
11 •' -. ..'. • .-!..,--.-,'. _. _-
,
oV«e
c«
<
, — _-.
a.
iTime-> 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00
2354E03.D 8270.M Sat Dec 20 12:58:06 1997 Page 2
Quantitation Report
J:\7002\DATA\2363E04.D29 Dec 1997 11:39 amGSB3840A2ul of 500ul+5ul IS,V=1000
MS Integration Params: LSCINT.PQuant Time: Dec 29 12:15 1997
Data FileAcq OnSampleMisc
(Not Reviewed)
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997Continuing Cal File: J:\7002\DATA\2363S03.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) 1 , 4 -Dichlorobenzene-d417) Naphthalene-d831) Acenaphthene-dlO51) Phenanthrene-dlO63) Chrysene-dl271) Perylene-dl2
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol-d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2 -Dichlorobenzene-d4Spiked Amount 100.00018) Nitrobenzene-d5Spiked Amount 100.000
35) 2 -FluorobiphenylSpiked Amount 100.000
54) 2 , 4 , 6-TribromophenolSpiked Amount 150.000
65) Terphenyl-dl4Spiked Amount 100.000
Target Compounds6) Phenol12) 2-Methylphenol26) Naphthalene47) Diethylphthalate61) Di-n-butylphthalate
81013162326
7Range
8Range
8Range
8Range
9Range
12Range
15Range
20Range
.70
.47
.71
.98
.39
.77
.2921.2210.4833.9516.4435.2843.4310.7333
152136164188240264
112- 110
99- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
122140406920218167383823332733216344
375163
404040404040
92
.00
.00
.00
.00
.00
.00
. 12Recovery =
502798 102 . 12Recovery
377079 96 .72Recovery
180713 78 .56Recovery =
300476 76 .06Recovery =
497096 78 .36Recovery =
154410 91 .85Recovery
361117 56 .97Recovery =
ngngngngngng
ng61
ng68
ng64
ng78
ng76
ng78
ng61
ng56
.41%
.08%
.48%
. 56%
. 06%
. 36%
.23%
.97%
000000
0
0
0
0
0
0
0
0
.00
.00
.01
.01
. 00
.00
. 03
. 02
. 02
.00
.CO
. 00
.01
. 00
Qvalue88
101418
70) bis (2 -Ethylhexyl) phthalate 2372) Di-n-octylphthalate 24
.24
.95
.51
.54
.25
.26
.68
94108128149149149149
1559951
17122364652429481118
0000000
.26
.28
. 17
.34
.57
.57
. 14
ngngngngngngng
#######
354
7153786375
(#) = qualifier out of range (m) = manual integration2363E04.D 8270.M Mon Dec 29 12:16:01 1997 Page 1
Quantitation Report
Data File : J:\7002\DATA\2363E04.DAcq On : 29 Dec 1997 11:39 amSample : GSB3840AMisc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Dec 29 12:15 1997
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
MethodTitleLast Update
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Dec 19 10:25:03 1997
Response via : Continuing Cal File: J:\7002\DATA\2363S03.DAbundance TIC: 2363E04.D
1700000 :
1600000
1500000
1400000 '
1300000
1200000
1100000
1000000
900000
800000
700000
600000
500000
400000 •: ,
300000(
200000I
100000 | I
n
|
|oiT
VI
J urf> C ^*
.1 £ "
* & * — "fll I?l 1•5 w s£9 £ 2 «5" ' *r ~ - —• • • • " M ° | oS S ? ' 1 T w
!!i I i i ?3 i I ||| | ?? ? 2 ? I *
5 5 -. I £ •
* ' ! *: ia!i
LI ' !
.*'.e • .. . '.. ... . - .'Time-> 8.00 10.00
2 J 6 3 E U 4 .1) H 2 V O .M
12.00 14.00 16.00 18.00 20.00
Mon Dec 29 12 :16 : 07 1997
22.00 24.00 26.00 28.00 30.00 32.00 34.00
Page 2
Quantitation Report
Data File : J:\7002\DATA\2058E09.DAcq On : 27 Feb 1998 4:09 pmSample : GSB4843AMisc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Feb 27 16:45 1998
(Not Reviewed)
Position: 2Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Feb 27 10:27:16 1998Continuing Cal File: J:\7002\DATA\2058S02.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) 1 , 4 -Dichlorobenzene-d417) Naphthalene-d831) Acenaphthene-dlO51) Phenanthrene-dlO63) Chrysene-dl271) Perylene-dl2
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol -d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.000-5) 1, 2-Dichlorobenzene-d4Spiked Amount 100.000
18) Nitrobenzene-d5Spiked Amount 100.000
35) 2-FluorobiphenylSpiked Amount 100.00054) 2 , 4 , 6-TribromophenolSpiked Amount 150.00065) Terphenyl-dl4Spiked Amount 100.000
Target Compounds6) Phenol12) 2-Methylphenol
81013162326
7Range
8Range
8Range
8Range
9Range
12Range
15Range
20Range
.69
.47
.69
. 97
.38
.78
.2821.2010.4733.9416.4435.2843.4110.7133
152136164188240264
112- 110
99- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
341148994226459413758482668568436669
978173
404040404040
83
.00
.00
.00
.00
.00
.00
.06Recovery
1118190 94 .95Recovery
926726 89 .38Recovery
410255 62 .27Recovery
579261 65 .69Recovery
994433 66 .49Recovery
325938 102 .86Recovery
1814251 132 .22Recovery
ngngngngngng
ng55
ng63
ng59
ng62
ng65
ng66
ng68
ng132
.37%
.30%
.59%
.27%
.69%
.49%
.57%
.22%
000000
0
0
0
0
0
0
0
0
.00
.00
.00
.02
.01
.01
.03
.00
.01
.00
.01
. 00
.00
.00
Qvalue
15) n-Nitroso-di-n-propylamine19) Nitrobenzene26) Naphthalene27) 4-Chloroaniline30) 2-Methylnaphthalene58) Phenanthrene60) Anthracene61) Di-n-butylphthalate
8899
101011171718
.22
.94
.30
.44
. 50
. 50
.65
.01
.01
.25
941087077128127142178178149
5462330015921107
3439649656269188718873987
0000100000
.39
.39
.33
. 12
.43
.51
.44
. 10
. 10
.21
ngngngngngngngngngng
#tt##
#####
3541
37964290606078
(#) = qualifier out of range (m) = manual integration2058E09.D 8270.M Fri Feb 27 16:45:57 1998 Page 1
Data File : J:\7002\DATA\2058E09.DAcq On : 27 Feb 1998 4:09 pmSample : GSB4843AMisc : 2ul of 500ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Feb 27 16:45 1998
Position: 2Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
MethodTitleLast UpdateResponse via
Abundance
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Fri Feb 27 10:27:16 1998Continuing Cal File: J:\7002\DATA\2058S02.D
TIC: 205BE09.D
6000000
5500000
5000000
4500000
4000000
3500000
3000000
2500000
2000000
1500000
1000000
500000
M—• *>
I j"
I $?v-l£™c? o M
§£ a«
: i 1 1 jo 2 " " o1 ' J
3
^
0>« -',. : ——— ,Time-> 8.00 10.00
2058E09.D 8270.M
12.00 14.00 16.00 18.00 20.00
Fri Feb 27 16:46:00 1998
22.00 24.00 26.00 28.00 30.00 32.00 34.00
Page 2
{-. Quantitation Report (Not Reviewed)
Data File : J:\7002\DATA\2155E08.DAcq On : 4 Jun 1998 5:49 pmSample : GWB4513AMisc : 2ul of 250ul+250ul+5ul IS,V=1000MS Integration Params: LSCINT.PQuant Time: Jun 4 18:24 1998
Position: 1OperatorInstMultiplr
ES70021 .00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Thu Jun 04 10:48:37 1998Continuing Cal File: J:\7002\DATA\2155S02.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) 1 , 4-Dichlorobenzene-d418) Naphthalene-d833) Acenaphthene-dlO53) Phenanthrene-dIO65) Chrysene-dl273) Perylene-dl2
81013162326
.46
.21
.37
.62
.01
.35
152136164188240264
223473825349446338771354539720341367
404040404040
.00
.00
.00
. 00
.00
.00
ngngngngngng
000000
.00
.02
.02
.02
.00
. 00
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 1503) Phenol -d5Spiked Amount 1504) 2-Chlorophenol-d4Spiked Amount 150
.000
.000
.0005) 1, 2-Dichlorobenzene-d4Spiked Amount 10019) Nitrobenzene-d5Spiked Amount 10037) 2-FluorobiphenylSpiked Amount 100
.000
.000
.00056) 2 , 4 , 6 -TribromophenolSpiked Amount 15067) Terphenyl-dl4Spiked Amount 100
Target Compounds6) Phenol11) Benzyl Alcohol13) 2-Methylphenol
.000
.000
63) Di -n-butylphthalate
7Range
7Range
8Range
8Range
9Range
11Range
15Range
20Range
78817
.0321.9910.2333.71IS.2135
.9 =43. 0310.3533
.93
.71
. 71
.92
112- 11099
- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
9479108149
256759Recovery
254482Recovery
402220Recovery
174819Recovery
270482Recovery
595009Recovery
189622Recovery
1035974Recovery
35973293656
3216
33
25
53
38
38
45
53
73
0000
.41=.45=.85=.73=.50=.68=.19=.19=
.38
.55
. 10
. 16
ng22
ng16
ng35
ng38
ng38
ng45
ng35
ng73
ngngngng
.27%
.97%
. 90%
.73%
.50%
.68%
.46%
. 19%
Qvatf###
0
0
0
0
0
0
0
0
1±.
.00
.02
.00
.02
.04
.02
.02
.00
ue1
15478
(#) = qualifier out of2155EC3.D 8270.M
range (m) = manual integrationThu Jun 04 18:24:19 1998 Page I
Data File : J:\7002\DATA\2155E08.DAcq On : 4 Jun 1998 5:49 pmSample : GWB4513AMisc : 2ul of 250ul+250ul+5ul IS,V=1000MS Integration Params: LSCINT.P
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Time: Jun 4 18:24 1998 Quant Results File: 8270.RES
MethodTitleLast UpdateResponse via
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Thu Jun 04 10:48:37 1998Continuing Cal File: J:\7002\DATA\2155S02.D
)undance
1200000
1100000
1000000
900000
800000
o700000 ,-
600000 1H-
500000
400000
300000
200000
100000
: io -
i•
X?ii*|5
Yjj
:'?I
['1
f
1
,_,
me-> 7.00 8.
E
1
b«
14
' t
- - •- ~~~
O*
]2 s1 tf 5
w *I?c1
)
•
.
fIj
TIC:2155E08.D ™ ^ -— —
nVi
j
_ 1
i' 'I
a.
IA
i
Isi>
ji
:• i i
^ , \ _
''
!!u
r*
If
: : v . . _ . . . . .J, ;x_ _._ . . ————— ——— «- —— ——
00 9.00 10.00 11.00 12.00 1300 14.00 1500 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 2sloO 26.00 27.00 28.00 29.00 3000 31.00 32.00 33.00
2155E08.D 8270.M Thu Jun 04 18:24:22 1998 Page 2
Quantitation Report
J:\7002\DATA\2161E07.D10 Jun 1998 1:43 pmGWB4515B,Montgomery Watson2ul of 250ul+250ul+5ul IS,V=1000
MS Integration Params: LSCINT.PQuant Time: Jun 10 14:17 1998
Data FileAcq OnSampleMisc
(Not Reviewed)
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Results File: 8270.RES
Quant MethodTitleLast UpdateResponse viaDataAcq Meth
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Wed Jun 10 11:09:16 1998Continuing Cal File: J:\7002\DATA\2161S03.D8270
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1) 1 , 4 -Dichlorobenzene-d418) Naphthalene-da33) Acenaphthene-dlO53) Phenanthrene-dlO65) Chrysene-dl273) Perylene-dl2
System Monitoring Compounds2) 2-FluorophenolSpiked Amount 150.0003) Phenol -d5Spiked Amount 150.0004) 2-Chlorophenol-d4Spiked Amount 150.0005) 1 , 2 -Dichlorobenzene-d4Spiked Amount 100.00019) Nitrobenzene-d5Spiked Amount 100.000
37) 2 -F luorobiphenylSpiked Amount 100.000
56} 2 , 4 , 6-TribromophenolSpiked Amount 150.00067) Terphenyl-dl4Spiked Amount 100.000
Target: Compounds6) Phenol11) Benzyl Alcohol13) 2 -Methylphenol
81013162326
7Range
7Range
8Range
8Range
9Range
11Range
15Range
20Range
.45
.20
. 37
.61
. 00
. 34
.0221. 9810.2233.7016
. 1935
. 9743. 0710
. 3533
152136164188240264
112- 110
99- 110132
- 110152
- 11082
- 110172
- 115330
- 123244
- 144
3093941268441664920949340478082339818
397824
404040404040
35
.00
.00
.00
.00
.00
.00
.07Recovery =
453756 31 .49Recovery =
678707 66 .12Recovery
285331 48 .80Recovery =
492754 43 .12Recovery
1053941 50 .73Recovery =
353167 71 .02Recovery =
1394586 121 .80Recovery
ngngngngngng
ng23
ng20
ng44
ng48
ng43
ng50
ng47
ng121
.38%
.99%
.08%
.80%
. 12%
.73%
.35%
.80%
000000
0
0
0
0
0
0
0
0
.00
.01
.01
.01
.00
.01
.00
.00
.00
.00
.01
.00
.00
.00
Qvalue788
16) n-Nitroso-di -n-propylamine 846) 4 -Nitrophenol49) Diethylphthalate63) Di-n-butylphthalate
131417
. 99
. 69
.69
.99
. 37
. 21
. 91
947910870
109149149
1463662831274175020727605622
1000000
.06
.73
.17
.22
.22
. 15
.24
ngngngngngngng
####tt##
29234171
6978
(#) = qualifier out of2161E^7.2 8270.M
range (m) = manual integrationWed Jun 10 14:19:20 1993 Page 1
uuancitation Keport
Data File : J:\7002\DATA\2161E07.DAcq On : 10 Jun 1998 1:43 pmSample : GWB4515B,Montgomery WatsonMisc : 2ul of 250ul+250ul+5ul IS,V-1000MS Integration Params: LSCINT.P
Position: 1Operator: ESInst : 7002Multiplr: 1.00
Quant Time: Jun 10 14:17 1998 Quant Results File: 8270.RES
MethodTitleLast Update
J:\7002\METHODS\8270.M (RTE Integrator)GC/MS method 8270 TCL extractables.Wed Jun 10 11:09:16 1998
Response via : Continuing Cal File: J:\7002\DATA\2161S03.DAbundance
1600000 '
1500000 '
1400000
1300000
1200000 :
1100000uin
1000000 §£Q.
900000 i
t^t
800000
700000
600000
500000 :
400000 :
300000
200000
100000
o - -v.Tlme-> 7.00
u40^—f
il2S& Cfi*j**
u*/>w»"^c*a
IIo
Z, oO«*."
i
TIC:2161E07.D ~
o'
1in J">. j* inc a.i s -a • Yi ^ *•
» i' Cc c•Saz
O
?t, t
J10p
z ,
it ;i
. , '. <• ^
i
1
t
o
1 £2 |O *
9 4
£*7
VM
i
; i
.
1
rJ
I
1 ;u "Ii *
, .1I1 !
!' !'
8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.00 2s!oO 26^00 2?loO 28^00 29lOO 30.00 31.00 32iOO 33.00 ^
2161E07.D 8270.M Wed Jun 10 14:19:23 1998 Page
Montgomery Watson
1 'A 2i.O 7/.50 1 0 Chiomiurn
ICV ICH (JCV' (%Rec) (mg.'L) (%Rec )
1 <J ( .2//(0&3) 103 <00? 1039/0.12/8 996
9/04412 10.' < 0 0 2 99 8' ) .)4.>3 (08. 3) 998!
9/0<J4'>4 999/0[)4')5 992
1 J<)4'?1 (08, :i) 104 <00? 1049/0')4<)3 104
104'103;102
1 CTO')7(D8,£>) 104 <C02 104100
986:994992 !
9303615 103 <:00? 105ii; irnple 106
VV. .M -t spik€-d 110
i,r a - .icated 109i; oic.cstion) 108
930:i6/5 994 <00? 9949f. ,;> '-',5 (OS,:i) 100
101996101
Montgomery Watson
. ;
EF'A 200//o010 Copper
CX:B 1 Duplit^tti Spike(mg/L) (RPO) (%Rec ) (".
<002 91 99 1 9709277(08,5)<002 : 9/0')2/8
<002 9709412<002, 1 tt 101 9709453 (D&S)<002, 9709454<0 02 9700455
<002 1/1 85 9709491 (D4L.)<0()2J 97004 W<0 02<0 02<002
<002<002<0()2<0 02<002
<0 02<002<0 02<0 02<0 02
i •
37 102! 9801097(045).
9803615(T his samplewas not spikedor duplicatedin diciestior.)
i i
<OO2<0 02<0 02<002<>.) 02
'•• 9JJ036/59' 99 9803/45(D4S)
•
ICV ICB CCV«Re<:) (mg/L) i%Rec)
101 :!005 101956
100 x005 984 '964
9795
101 ^006 102100101
: 99'974
102 C005 102942!
'] 926!93!
934
98 4 <0 05 99996'101
982992
989 0)05 994965968
92 !
94
CCB 0.(mg/L) ,
<005<005
<OC6<005<OC6<OC6
<OC6<OC6<005<OC6<OC-5
<0.05:
<OC-5<OC6<QC<5<OC6
<0 05<005<OC6<OC6<OC6
<OC6<005<OC6<OCo<0 C6
iplicatr- SpikeR.^)) .%Rec)
1 4 95
NA 995
23? 84
I
31 94
1l> 100
Paq«; 1
Monlgnmery Watson
El 'A nO 7A>CUi I eacl
ICV ICh CCV OCB(%«ec | (mg.'L) (%Rec ) (mg/L)
97092>'7 (D&.S) 109 «.'0 ) 100 'Q 19/092/8 104 '01
9/09412 10b <0 1 102 ,019/094';3 '.04 P>) 104 cO 1
9/09454 103 ;0 19/09455 103 ^01
97094"! ;0&S) 107 oJ 1 10?' ,'.019/09433 105 -'01
107 :01107 -'.01105 c.O 1
107 <01103 ^.Q]104 v01104 -0 1
*
Montgomery Watson
EPA200 //6010
Duplicate Spike ICV ICB(HPD) (%Hec) a (%Rec) (mg/L)
29 98 9709277 (D&S) 101 i.0 059709278
9709412 995 =:0 05NA 1C6 9709453 (D&S)
97094549709455
29? 96 9709491 (D&S) 102 '00597094 ;.)3
NA 113j 9801097(DAS| 101 '• <.0 05I ' , '
i ;
9803615 100 <005(Tins samplewas not spikedor duplicatedin digestion)
9803675 981 -0059803745 (DAS)
1
Nickel
cx:vl%Hec)
104998
974988986982
103103104102103
102 i992,976;101!99
104:
105109109108
978996101101103
C:CB Duplicate Spine(mg/L) (RPD) :%Rec),
<005 58 94:
<005
<OC6<005 NA 104<OC6<OC6
<005 89 90<OC6<OC6<OG5<OC6 :
<OC6; 52 102
<005<0 05<OC6
<OG5 !<OC6<OC6<OC6<005
<OC6 :<OC6 9 t 95<OC6<OC6<() C6
MWAfSONXLS
iri
Montgomeiy Watson
\ ?i X) 7/6C 1 0
I bf K:V ICB
" (%Hec | (mg/L)
92?7(D&3) 101 <X'0?97092/8
9709412 101 «:CO?94!>3(D&:">)
97094549709455
9491 (D&5) 10;j - - C O ?9709493
!0<J7[DKiJi) 101 <CO?
9303615 101 - .CO?is samplei not spikedImplicated!()(: M ()ll)
93036/6 9» I -X 0?3/.1')(H«i >)
Zinc
C.CV(%Rec ) (
104101
102102102101
105104;
1041041021
104-101 j
996101100'
106'107110109109
10010?10?101103
:X;BTKI/L)
<0 02<0 02
<0 02<0 02<002<0 02
OJ 02<0 02<0 02<0 02<0 02
<002<0 02<0 02<0 02<0 02
<0 02<0 02<0 02<0 02v.i 02
<0 02<< J 020.) 02<0 02< )02
Montgomery Watson
EF:>A2()0 7/6U10
Duplicate Spike ICV ICB(RPD) (%Rec ) Lab * (%Rec .) (mg/L)
21 97 9709277 (D&S) 996 <0 19/09278
9709412 104 <0 1101 1CO! 9709453(08,5)
9/094549/09455
13 h 104 9709491 (DAS) 105 <0 19/09493
i
,
25 103 98010<)7(DA?,) 106 <0 1I .
iI • :
9803615 101 <01; (This sample
was not spiked; or duplicated
in ditjebtior )
9U036/5 106 <011 H. 99! <M)03/45(DM.)
i
Iron
CCV CCQ O'jphcati?%Rec) (mg/L) (RfD)
106 <0 1 1 ?106 <0 1
108 <0 1112 <0 1 32IDS' <oi104 <0 1
114 <0 1 09106 <0 1
99 8| <01109* <0 1108 : <01
109 <01 4109' <01
96 8' <01117' <01
<0 1
104 -:oi108 <01105 <0 1106 <0 1109 <0 1
88 <0192 4 <0 1 7896 4 <0 195 6 <0 191 2 -:0 1
Spike•%Rec )
92
120
6fl
100
100
Sheet!
Montgomery Wat
EPA 7060Lab*
97092779709278
9709412970945397094549709455
97094919709493
9801097
SM3113B
9803615
98036759803745
ICV(%Rec.)
105
105
105
105
100
105
son
ArICB
(mg/l)
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
senicCCV
(%Rec.)
111111
10899
105108
99102
CCB(mg/l)
<0.01
<0.01
<0.01
<0.01
"105| <0.01102
9290
<0.01
DUPLICATE(RPD)
5.4
0
NA
SPIKE(%Rec.)
115
90
NASamples were not spikedor duplicated
0
NA
during dige
85
NA
stion
samples were not spikedor duplicated dunng digestion
NA NA I -samples were not spiked
Montgorr
SM3113BLab*
980361598036759803745
'
'
........
-
iery We
ICV(%Rec.)
104
»tson
LeadICB
(mg/l)
<0.005
- - - - -
or duplicated during digestion I
ccv(%Rec.....
108116
- - —
-
- -
-- -
—
CCB {DUPLICATEjmg/l)
IjcO.OOS
" " -
(RPD)
NA
—— - — -
SPIKE(%Rec.)
97Samples were not spikedor duplicated during digestion.
.... . l _ __ .. _.J -^
r
, - . - ; - - -
_.•
This is a postdigestion spike
.. - .. —
-- —
Page 1
Sheetl
Montgomery Watson
ERA 330.Lab#
97092779709278970941297094539709454970945597094919709493
9801097
98036159803675
9803745
SulfateICV
(%Rec.)
90
103
98
101
ICBmg/l
0.07
0
0
0
CCV(%Rec.)
94
102
98
96
CCBmg/l
0
0.07
0
0
-
Spike(%Rec.)
Spikes anc
|
- -
I duplicates wererun on other samples in the run" /:: """same as a
94
Spike andrun on oth<
bove
duplicatesif samples
werein the run
Page 1
Sheetl
Montgomery Watson
EPA9010ALab*
9709278
970945397094549709455
97094919709493
901097
ERA 335.2
980361598036759803745
CyanideICV
(%Rec.)
98
Spike(%Rec.)
99A calibration blank was includedwith each run
97
89A calibration blank was includedwith each run
101 116
A calibration blank was includedwith each run
107 91A calibration blank was includedwith each run
ICV
100
CCV
102
Spike
107A calibration blank was includedwith each run |
Page 1
'•' ,-
o Pane no,,
LiHL
OOOO1
DES MOINES
B:71231BR1
TRAACS 3 O- C i
\12-31-97 10:57 BARB ROSE NH3-S
HK.-1 ANALYSIS REPORT FORM
^ DESCRIPTIONPeakl^Peak 3
RUN INFORMAL I UN SAMPLE ID
PeakQPeak?Peak:Peak:,PeakPeak]Peakl<Peak 11PeakK
#19
,.•.P^alX^r ..,:•' l.V.Fv-i^A
-- .-• i
-ur-' : 1 -g:Zup: j^^*-«t- • .up: J
k"2:^ V
_up:(. -"••p:7 -Jup:l -^upj-. -e: : -uD:2 -:up::.' -
Cup: )'!Cuo:2Lur; : ..•.:<_.- ? • 'Luc' ::•
Cup
L. L.' T'
'_!! 2':.- *-' Ch'-'..
NUL'..rJi-. •,.NULL^LK, -
'- • - ' < ' ' -C '
LUWLOW
NULLNULLNUL._.
! -4 : 1' L
i - i :r
'j. OO5.00BLANKBLANKBLANK
. . -
.00
. ! ' _ >
VV=3.50BLANK^HLANt'<L AMI
?/
9^09455
!;!••!•'
TEST #15. I'")5.160.08V.oyo.u
%:$t1 . O'J
!bio^3.450.050.061.011 . '.'•:.o.'..- •
1:!:10*2/70
o.o,:8.5.:-
NH3-S.XLS
Calculation of concentration as Mg/Kg (uG/g) from rag/1 for soil/sludge
Sample ID's
MeasuredCone.(mo/1)
Weightsampleused
% TotalResidue as%
Volumesample (I)
Test - NH3-S
9709453
9709454
9709455
9709455 DUP
9709455 SPK
SPK ADDED
9709491
9709493
0.86
0.14
1.27
1.58
2.29
0.99
0.06
8.53
5.36
5.292
5.513
5.507
5.513
5.513
5.185
5.351
87.4437
79.2157
83.015
83.015
83.015
83.015
94.2193
75.1207
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
Cone, bydry wt
18.35
3.34
27.75
34.56
50.04
21.63
1.23
212.20
Cone, as %by dry wt.
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.02
Page 1
I2-21-97
Paqe? no. OO001 B:71222BR2 12-22-97 12:03 BARB ROSE NH3-512/22/97
UHL DES MOINES TRAACS 9'JO SYSTEM ANALYSIS REPORT k 0PM
DESCRIPTIONPeaklPeak 2Peak 3Peak 4Peak: 5Feak6Peak 7Peak. 8Peak 9Peak 10Peakl1Peak 12Peak 13Peak 14Peak 15
Peak 16Peak 17Peak 18Peak 19
Peak20T'e.at 21r --..-1 ' '_•
RUN CNFORMATIQNCup I -..CJPCupCupCupCupCUDC u pCUDCUPC L. pCUDL U pCUDLupCUPC u pCueL . i ' :•
L .: "•
P
r . .-C:
L'..ID:''' " r-,
•- '-
1 - -:•
Z i- !'2 — '••'"". — ':•
4 -;:s — '•-o ~ .:7 - '•;•\ —1. —3 — '•.-
— '':
B ->2 — ••9 ->1 '"••^"•i . -i "" _
1 i1 l-
^J — ,
"
PRIMNULLNULLNULLCALBCALBCALBCALBCALBCALBCALBHIGHLOWLOWISMPNULLNULLNULL
NULL-NULLMUL. L.r",f"v«Hf-S'AMPT.'-I P
'-. -~-r-ir-''"-;. .-v.>1P
i '-" r u~-'^ IL'L LNULLf i ! i i 1r : ; j ." ~r- , i
riuL^.' • \ " '" i
SAMPLE ID TE5 . OO5 . 00BLANKBLANKBLANKO 1 0(") 5'"'i OO cje><"*"* -2 00 ooe» f3 oo oivn^-5 005 00("> i Oo 1 6REF *Y?*76r«c-TV=3.50BLANK.BLANK If.SPIKE (61 'Yc.oexL-BLANKSPIKE rr>tZ 'j&rQr.BLANK ' °BLANKBL ANt:970927797O927B97O9278 *?.,Pt97O9278 lOS%»f«c-SPK97O9412REF /CsC btec-TV = 3 . b'.iBLANKBLANKCf , pj n J (.
"'".'1O'^-' ^°3'. oo^ . '"* ':.'
sr <n4.91'b . • ) "-'O . O<v0 . Oy•j . OtJ<j . 0/3i j r_ji 1 ol1 ^ A
-.'.94
5 '. 0 4'.> . 0 'o . o 73. 48
0 . O*-~i") I'lQi . 6 11 . '. b
v > _ i : :' ' .' • ., Lj-~6 . 3 10. 341 . 351,8-?L ,
1 ' ' I'-T
1 • ""
"•-
'- ' i'.
NH3-S.XLS
Calculation of concentration as Mg/Kg (uG/g) from mg/1 for soil/sludge
Sample ID'S
MeasuredCone,(mg/l)
Weightsampleused
% TotalResidue as%
Volumesample (I)
Test = NH3-S
9709277
9709278
9709278
9709278
SPK ADDED
9709412
0.28
0.31
0.34
1.35
0.99
1.89
5.133
5.141
5.143
5.141
5.141
5.935
86.4523
78.6111
78.6111
78.6111
78.6111
85.9469
0.10
0.10
0.10
0.10
0.10
0.10
Cone, bydry wt
6.31
7.67
8.41
33.40
24.50
37.05
Cone, as %by dry wt.
0.00
0.00
0.00
0.00
0.00
0.00
Page 1
F'aae no. OOO01•03 / 16/93
UHL DES noiMEs
B:30316BR2 03-16-98 11:59 BARB ROSE NH3-C
TRAACS 800 SYSTEM ANALVSIS REPORT FORM
DESCRIPTIONPeaklPeak 3Peak 4PeakSPeak 6Peaky-Peak 8PeakPeakPeakPeakPeak 13Peak 14Peak 15
:9101 112
Peak 16Peakl?Peat.: 18Peak 19
Peal 20Peal 21Peal 22
Peat. 27Peak23Peal 2^
RUN INFORMATION SAMPLE ID TESTCUDCUDCUDCUDCUDCUDCUDCUDCUDC U DCUDCUDCUDCUDCUDCUDCUDCUDCUDC U DCUDCUD
C ._• oLLIDCUDCUDCUDC u oC U D
C -i cC ..I DL-UD
'•-. ' • C1
C ;. • ~C '.I.E.'
1 - >1 ->2 — ;2 — '•2 — "3 — '':•4 -:::5 ->6 ->"7 — 'i ->1 -:;"" — ''..T _ "•.,
8 ->2 — *'"* — ;9 - >10 -2 — •-—T i -\ *-\ _
i _• ~
14 -1 C"
__> ~~ .
16 -17 -
13 -1 '-• -20 -o — ''
—2 1 —2 22 ~- ~24 -2 5 —
PRIMNULLNULLNULLCALBCALBCALBCALBCALBCALBCALBHIGHLOWLOWISMPNULLNULLNULLNULL
NULLNULL
••• SAMP•• SAMPSAMPSAMPSAMPSAMPSAMP
••• SAMPSAMPSAMP
I SM ~'
iMLJLLSAMPSAMPSAMP
SAMPSAMP
5. GO5 . 00BLANKBLANK:BLANKO 1 (")0 501 002 007; oo5 GO5 000 1 00 1 0REFT V = -~^BLANKBLANKSP I KEBLANKSPIKEBLANKBLANKBLANK9852198521985211 : 2^8521985221:4985.22lt4""
98522DUP9 o 5 "*"'SPK*""REFT" V — ~*-BLANKS* J^i S ''""•9852::9 3 ' '1 : 2935229S5221 : 2
<
00
1 ~181 9
"'''iTi114163 IZ
"'i"1
3Z
i ) * i
*54!~ "' \~'if- T
C" C.'
75
i. 18;. 13
:: . 14O.981 .882.885. 1 15. 120. 150. 152.880. O60. O70. 981
X.«/o«Pt>
oe
4. 5
6 . -
1 5
a.I
e. • \cs.3-
c. •}-C..5
Paae no. OOOO03/16/98
B:80316BR2 03-16-98 11:59 BARB ROSE NH3-L
LJHL DES MOINES TRAACS 800 SYSTEM ANALYSIS REPORT FORM
DESCRIPTION. _-k:39Peak:4OPeak: 41Peak: 4 2Peak. 43Peak:44Peak45Peak46Peak47Peak48Peak49Peak50PeakS1Peak:52Peak53Peak54F'eak:55Peak56Peak57Peak58Peat 59Peak:60F'eat 6 1Peat 62F1 e a t.. 6 3Peak.64F'eat 65
PeakGOPeal 07'-'ear 6y
Peat. 71
RUN INFORMATIONCUD 26 -CUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDCUDLUDCUDCUDCUDCUDC LI D
C LI D
C'JOC U D
C .I D
C .IDC J.G
("_ ,_(£,
C L.I D
~2~ —
23 -29 -7O —3"-;2 — :31 -32 —~T ~T _
34 -•-•wJ —
36 -37 -38 -39 -40 -3 - •:
~ -41 -41 -47 -44 -
45 -
4o -47 -
4 £: —
4 -5 —
S ' " —:~
_<=? •cr ^ _
;5 ~
cr i __
3 *~> ~
:• SAMP: SAMP> SAMP:; SAMP; SAMPI SMPNULL
:; SAMP> SAMP> SAMP> SAMP.; SAMP> SAMP:; SAMP':•• SAMP.. SAMP. SAMPI SMPNULL
. SAMPSAMPSAMP
. SAMPSAMPSAMP
:- SAMPSAMP
SAMP
' SAMPI SMP
NULL.SAMPSAMPSAMP
SAMP
SAMP
SAMPLE ID985227698523371:49852337DUP9852337SPK9852373REF *]TV=3.00BLANK:9852374985237598523789852379985238098523819852382985238398523849852443REF QTV=3.OO 'BLANC98524509852451985245298524531:109852453 o.DUP9852453 <#•SPK98524541 : 1 00852455
1 : 1 OO98524561 : 1009852457REF <KTV =3. 00BLANI .9352453935241493O1O971:498O1O97DUP98O1097 <SPK
7! 847.54 7.5
0.13 o.l2.82("). ("i i("'. 78 o.*f-0.11 e> -12.913.67 _S-^i A^l'!57 ?.6«0.14 o • (2.5.1 a. s2! 34 C>'
I ! 2'~: 1-3-1.33 I-*
1 i.i .43 I Cs10. 44
110.34i -.:. -' 68. 551.2"
4.715. 108. 06
/oc
B:80316BR2 03-16-98 11:59 BARB ROSE IMH3-D
UHL DES MOINES TRAACS SO'.".' SYSTEM ANALYSIS REPORT FORh
P a a e no. 0 0 O 0 3O3/16/98
DESCRIPTION RUN INFORMATION SAMPLE IDPeak 75Peak 76Peak 77Peak 78Peak 79Peak SOPeak 81Peak82Peak83Peak 84
ULID :CUD :CUD:CUD:CUD:CUD :CUD:CUD :CUD :CUD :
s -~->j-jL.
~T _~~. —
I -1 -1 -1 2O
. I SMP;. NULL: NULL:•• NULL', NULL> NULL> NULL':> NULL
GAIN- SAMP
REF <$&3'T3Tt? 2.35TV=3.00BLANK 0 08BLANK CiBLANK O0 1 0 0055s
i o <;>00 500 500 _^y _ 5
9852337 Ce, nb^c-lo
O4O913171521
1 :4
NH3-S.XLS
Calculation of concentration as Mg/Kg (uG/g) from mg/1 for soil/sludge
Sample ID's
MeasuredCone.(mo/1)
Weightsampleused
% TotalResidue as%
Volumesample (I)
Test = NH3-S
9852414
9801097
9801097 DUP
9801097 SPK
SPK ADDED
3.1
4.71
5.1
8.08
4
5.0754
5.2236
5.2236
5.2236
5.2236
14.1683
73.9229
73.9229
73.9229
73.9229
0.25
0.25
0.25
0.25
0.25
Cone, bydry wt
1077.74
304.94
330.19
523.12
258.97
Cone, as% by dry
wt.
0.11
0.03
0.03
0.05
0.03
Page 1
'r-: 00(3] 1 BR2 • .»6 - l i - -9 t . I"; : L . ' 4 t.:rtRK-: POSE NH3-L'
' t-_i | Mr! i TRIALS £ • " > i^^l :-. IS PET'ijPT FLJPM
T ION RUN ] Nr OFNAT 1 OF: bAMPL E 1 L. TEST *H
P e c . l 1F'c-c-t -P'QJit 3
P..?c-t -iPeoj 5Pe^.i s.Fe^l /P e a t - 8F ' P"1 ~-i 1 ' T*
r" ' tT '^* r 1 ' '
C - C £ . I J ]Fr.,,t 1 ..-
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f - - . - . . . - . t . '.
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,- •• ... ;. ..- - •. • i - iF ,; ,. 1 '-
: - • . - . :., ....
1 •,:-,-.! ;
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CLIPC'.'PCupCupCupCupCupCupC u pCLIPC Lip
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'_" L' P
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Cup
CupC L' p
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" 1
: 1 --i *.: 2 -: 2 -: 3 -: 4 -:5 -: 6 -I /
: 1 -: i -: .'• -• _•
:t: -
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'. -: j i: 1 ..
: i '•
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: 2^: 26 -: 2" -
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t-LJ^i. i.L.iN!
NULL {/.L-NINULL. £.F l i t : 97°
BL... .1 ;i
NULL ?F J • T <f-f=•M t .' 'i
' JULl. L.I. i -: !i: i . . i ,_ i. , i., ,r ',-
it-il'iF1 ' • . i : :•':'.• - > . . -:,,,ni • •< :, - .-.
i : ..•r..nM!-' • - . • t ' . - i L .•,.:.. ^.
i I '•-...,1-U- '•y-.,^ -:- c
-HUP • • ( : : ' - . . • . . . ..
':..,hi- - c ^ i .-.,: ;TM-iNP '- ;.:.'•,.:...'. ..
-^t'lc .••..•:... ,.\i .9,-U-r 9803615;T. i t- i t -"-F.. .. .'.'.
J 3MP K--I.-J )0|i • . ' - : . .-• •
NULL i-.;i MI i.-MNP v: :•:,...,SF.M- •-•::/-:... , -
S.- IK '.';., , - . yL ' 1 _' '
iuMf V:-Jb-2-''. '
bi 'ISAMF' vyS.-r^.-^ 1SAMP ''•ti^i.I-v^S.'-iMF- •VH':.;:. . - 'v . - .
t. . o i':.. O> '' ) . « : • !".'.)!1 ). '_> 1. i . 0 7> >. S3
- i . o;.1q 1 . v0
' T. . I.H;>: . MI_• . i.' .
> . ' • t
... •.' -i^o^c. : . ..-
-- . ; i.' . .1 .•
I^^S. 0 . -
Ve»ctc. -
. '.» .
_ . 1 - «s»8. S-6
^W ' . , ^.
|L%x*-c • < i
, . -. *.*>' • ' . ' . i'"1
i -. o.-r.'. 1 . O.I
O.'JS <o.|. . c>.*t-
t'lofCjC
' . •' . . '.~
-<^0.|
/ v . ' . r '
^H--1- ^^\
1 ' . '< o "^ rc *XlC
i.i. 4c o-5> . ) . O"" •t^-1
> i. ' >'• <C.I
P=«ar rin. OO' '>02•it it 9;-.;
E:: 906 1 IBP. 2 O6- 1 1 - - -8 i :•: "-.-i i A. •; •• MI ; ' -
I H I! L>E£ HO I Mi:. S IPAACS SCO Si STEM -,N.iL • S i - PL I 'L i t : > : ' . 1 . 1
EHiSCPf PT l O t - I RUM 1 MFGRMA1 I 011 SAMP.. P I i. 1 f.-: •-.. i
Cup:28 - SAMPPe*! 42Pear 43
* 'eat 44
Peak -'4 5Pec-1 46
Feal 4 '
Fsal 48PC -I 49H&=. | ':.'.Ptiel i:.1r- ,?=-.i 5..i- c,-i \, :\
Ptf.M 5'4PC-., i y,=.
t r.-.-.t i'-;-:.
: ,,M ';v V. i, i t'U
P.v^i V."t- .-.- 1 ..1 4 .'.', '. 1
' • • ,- 1 ..-; - . : - - < ! .-:• .'.
'- . - - . - I .-. '.
! - • : •- , ,:';.Pr .-,! .-..
t .-:-..? i ...
r-.r..M .'-.;P, - c . ' - 'I-;,;. V .,
(-. :••: . ":1 : •:•
I . • ,r •.-.-..., .-iF'C.,:. • '.:•Pc-:-*l' 76
Cup : 29 -Cup: 30 -
Cup: 3 -:
Cup: 2 -.Cup: 31 -
Cup: 32 -
Cup : 33 -CLIP : ".'" -•Cup: 31:. -Cup: 36 -Cup: 3" --Cup : ":•'-'• -
C up : 3'^ -Cup : •'•!>
Cuip : >•--• •
CU.L ' : 2 -C u P : ••'! 1 -r up : 42 -• : _ • _ • p . ; ' . -L <-\{.' : -> •'• -C LI p : ' i L UT-. : • '<•:. --
r:...f: : -1
. up ; i ;. •-
...up: ''1^
:.. Lu.. : c
Cup : 2 -C u P r 2 -Cup : 2 -t 'LID: ;•'2,p: "L . . . p . 1 •Ci.-;;. : J --Cup : 1Cup: 1 20
•• SAMPSAMP
I S'MF'
NULLSAMP
^ SAMF'
TiAMF'SAMPE-..--.I--IF-SAMPBAI'-ipb, ,1-11 '
SnMF'b,-.M:--
I SM>-
-I..IL.LS^. f - l i '
'Jr,MF
! - . f - , : l i 'buMPb. . , ! • ! ' - •::.* .1 'i '
SAI-U--'
:-:.. .nrS- i l iP
i :-.! U
1 1' '•'•..(
< h 11 I.MMLL! U.ILI.MUl. 1\\ '\ ^
rJUi.L6A1M
bi..MF'
v&^6 :• } "9P.5631'-1 : 1 -PEF ifc^a'! V-3. 'j...EfLAtJt•^8563 IV S-lDUF'985631'-.' ifC^SF't'••! :i:-.632 !•v.-iti..i<"; .• ;'vi;!:..i. :'..:1".9::-!5632.'-•^•i..:, ; :. -- . d'-.t :>.-1 : 5vps.-:.':;1:."•Vc-!5.i .'.<r
1 : L',Pt.l- ICCC
1 .-- .. ' ...i:'...M 1:' :-'..-^jc3cr .
9303675- j'-, .. i •. :
•.:••-.,. -'-1 ! '::-\-:t..-.-, :-'- ..•'.- . ; . • : ; ' • . - .
1 : !•--.••'-...L.-. V
_ I.
-•-..'-..::. P:•: '_". . J . '
l r ..:\;l /Ctfi '— . . ' . ' 't : AMI
' : ! . . ' . : II> . : • .,M:-. 1 • •
. 1 •
. ' " •
''.• ' ".'
-1:':!1:.-:..--
• ' . 4 . ' . cs.f5 C3 . : 4 1 5
b<"<c ... •..-;.
' . ' . • . ) 'IfcRS^ is.;,:.
r«e- .;• -. . . •,• i
.. ; 4.5. . -P. o.f
• ' • - - .::- C.5
'.'... fc. i-
• • ' • - • ^-^cJ . 1 11• : - . • : . . . 0,6
J " .. ''i 1 1/•for«c- • . j
. 1-•".. v U . • V»*
•:>.3fc" cxfe-3
• •'" ^^*"<rL<-
v - «.«(
i . -;'.. 10
3c.-: C.-6
^<6c .,,,
' . 1 '• . 1 ".. . 1 .. ' . ^ ' - '
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V . . .>'.•:•:.. 2-.- 53
PC-.--I '"•' C u p : 11'-' ' ':-2. '-VL-:
t: 30611 FJFV2 06-11-98 13:54 BARE: ROSE NH3-D
iML bib MU1NLS 1 RAACS 8'.)'.- SVSTEM ANAL VS IS KLF'ORT FORM
L'E.SiTRIRTION RUN INFORMATION SAMPLtID
Cup: 118 - SAMR 98561' «->SF'I
C - u p i l l ^ - SAMP 98562 0F'Dfc
Cup: lit. -, SAMF' 985638"1:2
Cup: 115 - SAMP 98564191 :2
TEST tt 1
O.5B
• 1
NH3-S.XLS
Calculation of concentration as Mg/Kg (uG/g) from mg/1 for soil/sludge
Sample ID's
MeasuredCone.(mg/1)
Weightsampleused
% TotalResidue as%
Volumesample (1)
Test = NH3-S
9855946
9856339
5.5
0.57
4.4903
7.0678
20.5566
24.597
0.25
0.25
Cone, bydry wt
Cone, as% by dry
wt.
i
1489.62
81.97
0.15
0.01
Page 1
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NH3-S.XLS
Calculation of concentration as Mg/Kg (uG/g) from mg/1 for soil/sludge
Sample ID'S
MeasuredCone.(mg/1)
Weightsampleused
% TotalResidue as%
Volumesample (I)
Test = NH3-S
9856672
9856672 DUP
9856672 SPK
SPK ADDED
24.24
24.22
33.46
10
5.0177
5.0177
5.0177
5.0177
4.0694
4.0694
4.0694
4.0694
0.25
0.25
0.25
0.25
Cone, bydry wt
Cone, as% by dry
wt.II
29678.20
29653.71
40966.69
12243.48
2.97
2.97
4.10
1.22
Page 1