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I I H I I I I
SFUND RECORDS CTR
88015018
July 30, 1991
SFUND RECORDS CTR
0222-00A56
AR0762
DATA SUBHIHAL FOR JUNE 1991 FOR HAZARDOUS WASTE AREA
HASSAYAMPA LANDFILL NARICOPA COUNTY, ARIZONA
I fl fl I H I
fl
ERROL L. MONTGOMERY & ASSOCIATES, INC. CONSULTANTS IN HYDROGEOLOGY
1075 EAST FORT LOWELL ROAO, SUITE B
TUCSON, ARIZONA 85719 (602)881-4912
TELEX: 165597 MONTE TUC
w H J ^ Consulting Engineers
CONESTOGA-ROVERS & ASSOCIATES
382 WEST COUNTY ROAD D
ST. PAUL, MINNESOTA 55H2
TELEPHONE (612)639.0913
ERROL L. MONTGOMERY & ASSOCIATES, INC. CONSULTANTS IN HYDROGEOLOGY
1075 EAST FORT LOWELL ROAD, SUITE B TUCSON, ARIZONA 85719 (602)881-4912 TELEX: 165597 MONTE TUC FAX: (602)881.1609
ERROL L. MONTGOMERY, P.G. J. W. HARSHBARGER, P.G., P.E.
DONAID K. GREENE, P.E. WIILIA.W R. VICTOR, P.G.
EDWARD VV PEACOCK, P.G. R0NA1.D H. DEWITT, P.G.
MARK M. CROSS, P.G. DENNISG. HALL, P.G.
ANDREW A. MESSER. P.G. TODD KEAY, P.G.
JAMESS. DAVIS. PG MICHAEL J. ROSKO, P.G. LAURA J. STRAUSS, P.G.
July 30, 1991
Thomas J. Dunkelman (H-7-2) Remedial Project Manager U. S. ENVIRONMENTAL PROTECTION AGENCY 75 Hawthorne Street San Francisco, California 94105
RE; DATA SUBMITTAL FOR JUNE 1991
Dear Mr. Dunkelman:
In accordance with Section XII.A of the Administrative Consent Order dated February 19, 1988, for the Hassayampa Landfill Remedial Investigation / Feasibility Study (RI/FS), this data submittal has been prepared for data obtained or received during the period from June 1-30, 1991.
In accordance with the distribution procedures for this project, two additional copies of this data submittal are enclosed herewith. If you have questions or require further discussion, please contact us.
Very truly yours,
ERROL L. MONTGOMERY & ASSOCIATES, INC,
l U/yy^^ /^- VicA^ - ^ ( ^ ^ William R. Victor
SENT VIA FEDERAL EXPRESS Enclosures cc: Jackie Maye (3)
Grant J. Gibson (3) James G. Derouin (2) David Machlowitz (2) David P. Kimball (2) Kim E. Williamson (2) Charles A. Bischoff (1) Errol L. Montgomery (1) Terry A. Thompson (1)
Lt. Col. Ray Swensen (1) Uilliam J. Cheesenian (1) Roger K. Fertand (1) Robert U. Hacker (1) Alan Abbott (1) G. Van Velsor Wolf (1) Richard C. Keiffer (1) Robert H. Brauer (1) E. Powell / C. Case (1)
Carl C. Meier (1) Charles 0. Geadelmann (1) G. S. Hagy (1) Cindy Lewis (1) G. Eugene Neil (1) Stephen M. Quigley (1) Rod Whitten (1) Louis C. Thanukos (1)
July 30, 1991
DATA SUBMITTAL FOR JUNE 1991 FOR HAZARDOUS WASTE AREA
HASSAYAMPA LANDFILL MARICOPA COUNTY, ARIZONA
CONTENTS
Page
INTRODUCTION 1
DATA FOR TOPOGRAPHIC SURVEY 2
DESCRIPTION OF CORE SAMPLES FROM EXPLORATION BORING EX-2 2
LABORATORY CHEMICAL RESULTS 3 DATA VALIDATION FOR LABORATORY CHEMICAL ANALYSES 4
EPA Method 601/602 4 EPA Method 624 6 EPA Method 622 6
RESULTS OF WATER LEVEL MEASUREMENTS 6
DATA FOR CONSTRUCTION FOR VADOSE ZONE MONITOR BORING VB-4 7 CONSTRUCTION OF VADOSE ZONE MONITOR BORINGS 8
TABLES
Table
1 SUMMARY OF TOPOGRAPHIC SURVEY FOR MONITOR WELLS, EXPLORATION BORING, AND SOIL BORINGS, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
2 LOCATION COORDINATES FOR MONITOR WELLS, EXPLORATION BORINGS, SOIL BORINGS, AND VADOSE ZONE MONITOR BORINGS, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
3 SUMMARY OF LABORATORY CHEMICAL RESULTS FOR COMMON CONSTITUENTS AND ROUTINE PARAMETERS IN GROUNDWATER SAMPLES FROM MONITOR WELLS, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
4 SUMMARY OF LABORATORY CHEMICAL RESULTS FOR TRACE CONSTITUENTS IN GROUNDWATER SAMPLES FROM MONITOR WELLS, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
5 SUMMARY OF LABORATORY CHEMICAL RESULTS FOR VOLATILE ORGANIC COMPOUNDS IN GROUNDWATER SAMPLES FROM MONITOR WELLS, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
6 SUMMARY OF LABORATORY CHEMICAL RESULTS FOR VOLATILE ORGANIC COMPOUNDS IN WATER SAMPLES OBTAINED FROM DRILLER'S WATER TRUCK, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
TABLES - CONTINUED
7 SUMMARY OF LABORATORY CHEMICAL RESULTS FOR VOLATILE ORGANIC COMPOUNDS IN QUALITY CONTROL BLANKS FOR WATER SAMPLES FOR HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
8 SUMMARY OF LABORATORY CHEMICAL RESULTS FOR EPA METHOD 625 FOR SEMI-VOLATILE ORGANIC COMPOUNDS IN GROUNDWATER SAMPLES FROM MONITOR WELLS, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
9 SUMMARY OF LABORATORY CHEMICAL RESULTS FOR EPA METHOD 625 FOR SEMI-VOLATILE ORGANIC COMPOUNDS IN QUALITY CONTROL BLANKS FOR WATER SAMPLES FOR HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
10 SUMMARY OF LABORATORY CHEMICAL RESULTS FOR EPA METHOD 608 FOR ORGANOCHLORINE PESTICIDES AND POLYCHLORINATED BIPHENYLS (PCBs) IN GROUNDWATER SAMPLES FROM MONITOR WELLS, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
11 SUMMARY OF LABORATORY CHEMICAL RESULTS FOR EPA METHOD 608 FOR ORGANOCHLORINE PESTICIDES AND POLYCHLORINATED BIPHENYLS (PCBs) IN QUALITY CONTROL BLANKS FOR WATER SAMPLES FOR HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
12 SUMMARY OF LABORATORY CHEMICAL RESULTS FOR EPA METHOD 522 FOR ORGANOPHOSPHORUS PESTICIDES IN GROUNDWATER SAMPLES FROM MONITOR WELLS, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
13 SUMMARY OF LABORATORY CHEMICAL RESULTS FOR EPA METHOD 632 FOR CARBAMATES AND UREA PESTICIDES IN GROUNDWATER SAMPLES FROM MONITOR WELLS, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
14 SUMMARY OF WATER LEVEL MEASUREMENTS FOR MONITOR WELLS AT HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
15 SUMMARY OF VADOSE ZONE MONITOR BORING CONSTRUCTION DETAILS, HAZARDOUS WASTE AREA, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
16 RESULTS OF TRACE GAS ANALYZER MEASUREMENTS, VADOSE ZONE MONITOR BORINGS, HAZARDOUS WASTE AREA, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
17 LITHOLOGIC DESCRIPTIONS FOR SPLIT-SPOON SAMPLES FROM VADOSE ZONE MONITOR BORINGS, HAZARDOUS WASTE AREA, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
11
ILLUSTRATIONS
Figure
1
2
3
LOCATION MAP FOR MONITOR WELLS AND SOIL BORINGS, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
DETAILED LITHOLOGIC DESCRIPTIONS AND GRAPHIC LOG FOR CORE FROM EXPLORATION BORING EX-2
LOCATION MAP FOR VADOSE ZONE MONITOR BORINGS, FORMER HAZARDOUS WASTE DISPOSAL AREA, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
SCHEMATIC DIAGRAM OF CONSTRUCTION FOR VADOSE ZONE MONITOR BORING VB-4
APPENDIX
Appendix
A LABORATORY CHEMICAL RESULTS
111
July 30, 1991
DATA SUBMITTAL FOR JUNE 1991 FOR HAZARDOUS WASTE AREA
HASSAYAMPA LANDFILL MARICOPA COUNTY, ARIZONA
INTRODUCTION
In accordance with Section XII.A of the Administrative Consent Order
dated February 19, 1988, for the Hassayampa Landfill Remedial Investigation
/ Feasibility Study (RI/FS), this data submittal has been prepared for
pertinent data obtained or received during the period from June 1-30, 1991.
The following data are included:
results of topographic survey for locations and altitudes of new monitor wells and soil borings that was conducted on May 29 and June 3;
detailed description of the continuous core obtained from exploration boring (C-l-5)3daa7[EX-2] from the depth interval from 50 to 73 feet;
results of laboratory chemical analyses for a sample of water obtained from the Buckeye municipal water supply system where the driller's water truck was filled;
results of laboratory chemical analyses for groundwater samples obtained on May 13 from monitor wells (C-l-5)3daa2[MW-2UA], (C-l-5)3daa4[MW-3UA], (C-l-5)3dab5[MW-4UA], (C-l-5)3dab6[MW-4UB], and (C-l-5)3dbd2[MW-8UA];
results of laboratory chemical analyses for groundwater samples obtained during the period from May 2 to 22 from monitor wells (C-l-5)3dac3[MW-9UA], (C-l-5)3dac2[MW-9UB], (C-l-5)3dda3[MW-10UA], and (C-l-5)3dda4[MW-lOUB] during pumping test operations;
results of water level measurements obtained from monitor wells at the Landfill on June 18 prior to groundwater sampling;
• construction details and lithologic descriptions for a split-spoon soil sample from vadose zone monitor boring VB-4, which was constructed on June 28;
• results of air quality monitoring during drilling operations for vadose zone monitor boring VB-4.
The laboratory chemical results received in June for samples of soil and
residual waste obtained from soil borings SB-17, SB-18, and SB-19 were
submitted separately in a supplemental data submittal dated July 29, 1991.
DATA FOR TOPOGRAPHIC SURVEY
Surveyed measurements of altitude of land surface at new monitor wells
and soil borings are given in Table 1. Surveyed locations for the new
monitor wells, exploration boring, soil borings, and vadose zone monitor
borings are given in Table 2; locations are given as coordinates with an
origin point at monitor well (C-l-5)3dab3[MW-lUA]. Locations are shown in
Figure 1.
DESCRIPTION OF CORE SAMPLES FROM EXPLORATION BORING EX-2
Detailed lithologic descriptions for continuous core obtained from a
depth interval from 50 to 73 feet below land surface from exploration boring
EX-2 is shown on Figure 2. A summary lithologic description for exploration
boring EX-2 was given in the Data Submittal for May 1991, dated June 28,
1991.
LABORATORY CHEMICAL RESULTS
Final laboratory chemical results were received in June 1991 for certain
water samples obtained during the period from May 2 to May 30. These water
samples were obtained in accordance with the scope of voluntary work dated
March 8, 1991, and with the EPA-required scope of work dated April 22, 1991.
Groundwater samples obtained during pumping test operations at monitor wells
MW-9UA, MW-9UB, MW-IOUA, and MW-IOUB, during the period from May 2 to May 22
were analyzed by the chemical laboratory for common constituents and routine
parameters, trace constituents, volatile organic compounds, semi-volatile
organic compounds, and organochlorine pesticides and polychlorinated
biphenyls (PCBs). Groundwater samples obtained on May 13 from wells MW-2UA
and MW-3UA were analyzed by the chemical laboratory for organophosphorus,
carbamate, and urea pesticides using EPA methods 622 and 632.
In addition, groundwater samples obtained on May 13 from wells MW-4UA,
MW-4UB, and MW-8UA were analyzed by the chemical laboratory for volatile
organic compounds using EPA method 601/602. A sample of water from the
Buckeye municipal water system, where the driller's water truck was filled
during drilling operations in 1991, was obtained on May 30 and was analyzed
by the chemical laboratory for volatile organic compounds using EPA method
601/602. The municipal water system was sampled because small concentrations
of volatile organic compounds had been detected in two samples of water from
the driller's water truck and in samples of groundwater obtained from the
recently completed monitor wells during development operations.
Results for common constituents and routine parameters in groundwater
samples are given in Table 3. Results for trace constituents in groundwater
samples are given in Table 4. Results for volatile organic compounds in
groundwater samples are given in Table 5. Results for volatile organic
compounds in water samples obtained from the driller's water truck and from
the Buckeye municipal water system are given in Table 6. Results for
volatile organic compounds in quality control blanks are given in Table 7.
Results for semi-volatile organic compounds in groundwater samples are given
in Table 8. Results for semi-volatile organic compounds in quality control
blanks are given in Table 9. Results for organochlorine pesticides and PCBs
in groundwater samples are given in Table 10. Results for organochlorine
pesticides and PCBs in quality control blanks are given in Table 11. Results
for organophosphorus pesticides in groundwater samples and quality control
blanks are given in Table 12. Results for carbamate and urea pesticides in
groundwater samples and quality control blanks are given in Table 13.
DATA VALIDATION FOR LABORATORY CHEMICAL ANALYSES
Laboratory chemical results were evaluated in accordance with the
Quality Assurance Project Plan (QAPP), dated January 29, 1988, and in
accordance with the Montgomery & Associates Quality Assurance / Quality
Control (QA/QC) procedures. Samples were submitted to Analytical Technolo
gies, Inc. (ATI), Phoenix, Arizona, for chemical analyses.
With the following exceptions, the data validation for groundwater
samples obtained by Montgomery & Associates during the period from May 2 to
30, 1991, indicated that sampling procedures, sample chain-of-custody,
laboratory methods, and representativeness of results met criteria given in
the QAPP.
EPA Method 601/602
Small concentrations of methylbenzene (toluene) were detected in the
groundwater sample obtained from monitor well MW-4UA, in the sample
duplicate, and in the field blank (Tables 5 and 7). During the period of
record, methylbenzene was not been detected for monitor well MW-4UA unless
it was also been detected in the corresponding quality control blanks.
Methylbenzene was detected in many of the groundwater samples obtained
during the March 1991 groundwater sampling round. Results from March 1991
suggested that the source of the methylbenzene was not the groundwater, but
was contamination that occurred during or after sampling. Further investiga
tion was conducted to determine the source of the methylbenzene. Results of
a review of sampling and sample handling procedures indicated that the source
of the methylbenzene may have been the adhesive in a new batch of tape
routinely used to secure the sample bottles for shipment. A survey of the
new batch of tape using a HNU trace gas analyzer indicated the presence of
organic vapors. Subsequently, a roll of the tape was submitted to ATI for
analysis of methylbenzene using EPA method 8020. Results of this analysis
indicated that following volatile organic compounds were detected: 1,100
milligrams per kilogram (mg/kg) methylbenzene; 1.3 mg/kg total dimethylben
zenes; 1.1 mg/kg ethylbenzene; and 0.078 mg/kg benzene. Based on these
results and results from the March 1991 sampling round, the source of the
methylbenzene detected in the March 1991 groundwater samples, trip blanks,
and field blanks is believed to have been the tape. In late May, that bad
batch of tape was discarded and use of the tape was discontinued.
Because the tape was still in use on May 13 and because methylbenzene
was also detected in the field blank, the source of methylbenzene detected
in groundwater samples obtained on May 13 from well MW-4UA is attributed to
laboratory or field contamination.
Small concentrations of benzene were detected in a groundwater sample
obtained on May 13 from monitor well MW-4UB and the corresponding field
blank. Benzene was not detected in the duplicate sample, nor has it been
detected previously in any groundwater samples obtained from well MW-4UB.
Based on results of QA/QC documentation and results discussed above for
laboratory chemical analyses of the tape, the source of benzene in the
groundwater sample obtained on May 13 from well MW-4UB is attributed to
laboratory or field contamination.
EPA Method 624
For laboratory chemical analyses conducted for groundwater samples
obtained from well MW-9UA during pumping test operations and the associated
trip blank (laboratory accession no. 105644), percent recovery of the
surrogate compound l,2-dichloroethane-D4 is slightly higher than laboratory-
established criteria due to equipment difficulties. No volatile organic
compounds were detected in either of these samples, and the higher surrogate
recovery should not affect the validity of the data.
EPA Method 622
For laboratory chemical analyses conducted for groundwater samples
obtained from wells MW-2UA and MW-3UA (laboratory accession no. 105704), an
independent laboratory control standard was not analyzed for EPA method 622
because a source for a secondary standard was not available. Analysis of the
matrix spike and matrix spike duplicate was not possible due to insufficient
sample. Duplicate analyses of a blank spike were conducted with acceptable
results, except for disulfoton. Historical laboratory data indicate that
disulfoton is not recovered consistently from water.
Data from analysis of standards indicate that results for the compounds
tetraethyl diphosphate (TEPP), acephate, and monocrotophos should be
considered qualitative due to low response level resulting from poor
compatibility with procedures in this method. These compounds were not
detected in any of the groundwater samples or quality control blanks.
RESULTS OF WATER LEVEL MEASUREMENTS
Groundwater level measurements from monitor wells at the Landfill that
were obtained on June 18 prior to groundwater sampling on June 18 are given
in Table 14.
DATA FOR CONSTRUCTION FOR VADOSE ZONE MONITOR BORING VB-4
When the four vadose zone monitor borings were constructed on May 24,
it was the intention of the HSC to construct three of the vadose zone monitor
borings between Pit 1 and the nearest area where volatile organic compounds
had been detected in groundwater samples obtained from monitor wells, and to
construct the fourth boring southeast from this area. Abandoned ADHS monitor
well HS-1 was selected as the reference point in this area. Locations for
the borings were approximately aligned with soil boring SB-19, which is
located at Pit 1, and abandoned ADHS monitor well HS-1. Identifiers for
these vadose zone monitor borings are VB-1, VB-2c, VB-2f, and VB-3; locations
are shown on Figure 3. Results from construction of the four vadose zone
monitor borings on May 24 and initial sampling operations on June 4 were
given in an interim report by Montgomery & Associates and CRA, dated June 27,
1991.
The HS-1 site was professionally surveyed in 1987 and was marked by
Montgomery & Associates personnel after abandonment of the well in 1988.
However, it appears that the staked location of the HS-1 site was accidently
moved during construction of a fence-line berm by the Maricopa County
Landfill Department in the summer of 1989. Evaluation of recent survey data
for the new monitor wells at the landfill and the vadose zone monitor borings
indicated that the site staked in the field for abandoned well HS-1 at the
time the vadose zone borings were constructed was not correct. Shallow
digging was conducted on June 20 to find the buried column of cement that now
fills the former HS-1 wellbore. The HS-1 site was located and was marked
with a vertical galvanized steel pipe set in cement; the location agrees with
the 1987 survey and is shown on Figure 3. Therefore, all of the four vadose
zone monitor borings are located between Pit 1 and well HS-1.
Although the HSC believed that the vadose zone monitor borings would
provide the information for which they were installed, the HSC still wanted
to construct a boring southeast from the area nearest to Pit 1 where volatile
organic compounds have been detected in groundwater samples obtained from
monitor wells. Therefore, the HSC authorized construction of a fifth vadose
zone monitor boring a few feet southeast from the newly marked location for
well HS-1 (Figure 3). Plans for this additional boring were given in a
letter dated June 26, 1991, from Montgomery & Associates to EPA. Construc
tion of boring VB-4 was completed on June 28.
CONSTRUCTION OF VADOSE ZONE MONITOR BORINGS
On May 24, 1991, vadose zone monitor borings VB-1, VB-2f, VB-2c, and VB-
3 were constructed at the hazardous waste area by Heber Mining & Exploration
Company, Phoenix, Arizona, using a hollow-stem flight auger. On June 28,
Heber Mining & Exploration Company constructed vadose zone monitor boring VB-
4 at the hazardous waste area. Auger flights were cleaned between borings
and drill cuttings were transported to the on-site lined excavation that was
used for storage of drill cuttings from the recently constructed monitor
wells and soil borings. Field observations were made by Montgomery &
Associates personnel.
Construction details for the borings are summarized in Table 15 and are
shown for vadose zone monitor boring VB-4 on Figure 4. Vadose zone monitor
borings VB-1, VB-2f, VB-2c, and VB-3 were cased with flush-threaded, two-inch
diameter, blank and perforated Schedule 80 polyvinyl chloride (PVC) casing.
Vadose zone monitor boring VB-4 was cased with flush-threaded, two-inch
diameter, blank and perforated Schedule 40 PVC casing. For each vadose zone
monitor boring, the PVC casing was installed inside the hollow-stem auger
flights to prevent caving of the borehole wall during installation. When the
complete string of casing was in place, the auger flights were removed from
the borehole. All materials used to construct the borings were new and
clean. Vadose zone monitor borings VB-1, VB-2c, VB-3, and VB-4 were designed
to yield soil gas samples from the coarse-grained part of the upper alluvial
deposits unit, as defined in the final RI Report. Boring VB-2f was designed
to yield soil gas samples from the fine-grained part of the upper alluvial
deposits unit. The coarse-grained part of the upper alluvial deposits unit
overlies the fine-grained part; the contact between these parts of the unit
is gradational. Montgomery & Associates personnel determined the approximate
depth of the contact by: (1) using lithologic data obtained from nearby soil
borings and monitor wells; (2) observing the reaction of the drilling rig to
drilling conditions; (3) inspection of drill cuttings; and (4) inspection of
a few soil samples that were obtained using a split-spoon sampler for
confirmation purposes. Descriptions of the split-spoon samples are given in
Table 16.
Air quality was monitored during the drilling operations using an HNU
trace gas analyzer; results are summarized in Table 17 and indicate that
vapors were present in the borings. Annular seals and locking air-tight
casing security caps were installed at the top of the vadose zone monitor
borings to allow the gasses in the borings to equilibrate with soil gas in
the vadose zone.
J
TABLE 1. SUMMARY OF TOPOGRAPHIC SURVEY FOR MONITOR WELLS, EXPLORATION BORING, AND SOIL BORINGS ,
HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
WELL/BORING IDENTIFIER
Monitor Wells
MW-IUA HW-IUB HW-2UA HW-2UB HW-3UA HW-3UB HW-4UA HW-4UB MW-5UA HU-61IA MW-6UB HW-7UA MW-8UA MW-9UA MW-9UB MW-IOUA HW-IOUB HS-1^
HS-2'' HS-s"
STATE WELL NUMBER
(C-1-5)3dab3 (C-1-5)3dab1 (C-1-5)3daa2 (C-1-5)3dab4 (C-1-5)3daa4 (C-1-5)3daa3 (C-1-5)3dab5 (C-1-5)3dab6 (C-1-5)3dab7 (C-1-5)3daa5 (C-1-5)3daa6 (C-1-5)3dab8 (C-1-5)3dbd2 (C-1-5)3dac3 (C-1-5)3dac2 <C-1-5)3dda2 (C-1-5)3dda3 (C-1-5)3daa1
(C-1-5)3dac
(C-1-5)3dda1
Exploration Borinqs
EX-1 EX-2
Soil Borinqs
SB-1 SB-2 SB-3 SB-4 SB-5 SB-6 SB-7 SB-8 SB-9 SB-10 SB-11 SB-12 SB-13 SB-14 SB-15 SB-16 SB-17 SB-18 SB-19 AB-1 AB-2 AB-3
(C-1-5)3dab2 (C-1-5)3daa7
— — — ... — — — ... — — — — — ... — — — — — ... —
ALTITUDE OF LAND SURFACE (feet.msl)^
925.1 924.1 914.6 913.9 914.9 914.7 913.7 913.9 915.9 915.9 916.13 920.3 927.0 915.48 915.49 912.18 911.88 915.2
917.5 910.4
924.6 915
909.0 909.0 915.3 913.2 914.3 915.3 922.9 920.2 913.9 914.4 918.0 913.0 913.9 910.3 915.0 920.8 914.08 915.02 916.49 914.2 914.7 916.4
DISTANCE FROH HEASURING POINT TO LAND SURFACE
(feet)
1.4 1.6 4.0 5.1 1.8 1.5 2.0 2.3 9.6 1.5 1.5 1.3 1.3 1.3 1.5 1.1 1.2 2.6 0.2 2.0
—
— —
— — —
— — —
—
—
—
—
ALTITUDE OF UATER LEVEL
HEASURING POINT (feet.msl)^
926.53 925.68 918.55 918.95 916.68 916.18 915.69 916.19 925.45 917.41 917.65 921.62 928.31 916.79 915.99 913.25 913.05 917.81
917.72 912.37
—
—
—
Feet above mean sea level
Honitor well HS-1, which was constructed by Arizona Department of Health Services (ADHS), was abandoned on June 8, 1988. Honitor wells HS-2 and HS-3 which were constructed by ADHS, were abandoned in Hay, 1991.
TABLE 2. LOCATION COORDINATES FOR MONITOR WELLS, EXPLORATION BORINGS, SOIL BORINGS, AND VADOSE ZONE MONITOR BORINGS HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
IDENTIFIER
'^l^m SUSJEc ' R£v jo,'
SURVEYED LOCATIONS^ X-COORDINATE Y-COORDINATE (EASTING) (NORTHING)
o.V
MONITOR WELLS
MW-IUA MW-IUB MW-2UA MW-2UB MW-3UA MW-3UB MW-4UA MW-4UB MW-5UA MW-6UA MW-6UB MW-7UA MW-8UA MW-9UA MW-9UB MW-IOUA MW-IOUB HS-1 HS-2 HS-3
EXPLORATION BORINGS
EX-1 EX-2
SOIL BORINGS
SB-1 SB-2 SB-3 SB-4 SB-5 SB-6 SB-7 SB-8 SB-9 SB-10 SB-11 SB-12 SB-13
0.00 -39.78 345.30 321.03 577.56 602.73 326.60 301.01 -195.02 460.80 450.10 177.60 -360.40 17.90 43.80 841.50 860.70 476.46 -41.64 856.15
16.86 430.95
764.44 652.24 422.31 152.50 -229.36 458.00 -40.50 161.86 495.80 315.82 313.76 607.99 461.60
0.00 43.55
-166.81 -166.51 -108.71 -106.84 216.70 217.41 296.83 342.00 311.10 192.90
-539.00 -788.30 -806.30
•1,245.30 •1,251.70
354.79 -725.40
•1,236.61
-14.68 375.57
-62.21 142.35 440.53 456.24 469.47 345.04 92.85
•100.94 184.50 186.97 36.98
-167.07 38.10
TABLE 2. LOCATION COORDINATES FOR MONITOR WELLS, EXPLORATION BORINGS, SOIL BORINGS, AND VADOSE ZONE MONITOR BORINGS HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
IDENTIFIER
SB-SB-SB-SB-SB-SB-AB-AB-AB-AB-AB-AB-
•14 •15 •16 •17 •18 •19 •1 •l' .2 .2" -3'' -3
TOP END TOP END TOP END
VADOSE BORINGS
X-COORDINATE (EASTING)
651.80 315.40 160.20 348.60 335.20 347.10 359.20 352.70 514.10 534.30 350.80 351.30
,SURVEYED LOCATIONS' Y-COORDINATE (NORTHING)
203.00 295.50 218.90 278.00 322.50 414.70 252.40 279.80 287.70 262.40 387.70 415.30
VB-1 VB-2f VB-2C VB-3 VB-4
406.74 431.84 440.59 468.24 484.56
394.57 378.12 373.29 361.64 353.27
Locations with reference to origin at monitor well MW-IUA. X-coordinates increase to the east; Y-coordinates increase to the north.
AB-1, AB-2, and AB-3 are angle soil borings; "top" represents coordinates at land surface of the top of the boring, "end" represents coordinates for bottom of the boring projected to land surface.
UELL
I D E N T I F I E R '
HW-lUA D MU-lUA MW-IUA MW-IUA MU-lUA d u p MW-IUA MW-IUA d u p MU-lUA NW-1UA dup MU-lUA MU-1UA dup MU-IUA MW-IUA duo MW-1UB D MU- lUB MU- lUB MU- lUB MW-IUB MW-IUB MU- lUB MW-IUB MU-2UA D MW-2UA MU-2UA MW-2UA MW-2UA MU-2UA HU-2UA MU-2UA MU-2UA MW-2UB D MU-2UB MW-2UB HW-2UB MW-2UB MU-2UB MW-2UB MW-2UB
MU-JUA D MU-3UA MU-3UA HW-3UA MU-JUA MW-JUA MW-JUA MU-JUA MW-JUB D MU-JUB MU-JUB MU-JUB MW-JUB MU-JUB MW-JUB
SAMPLE
FIELD
0UJ78 014*12 006099 006177 006178 006J75 006J76 006569 006570 006758 006759 010799 010800 014383 0U425 00608J 006171 006360 006552 006739 010781 014382 014421 006071 006088 006164 006363 006554 006740 0107B8 014379 014414 006070 006174 006362 00655J 006741 010787 014ja7 014413 006075 006165 006364 006556 006742 010789 014384 014426 006073 006175 006365 006743 010790
IDEMTIFIER LAB
16208 806006-01 80913J-15 812527-14 612527-15 908706-06 908706-07 003588-02 003588-03 006599-11 006599-12 103882-17 103882-18 804087-01 806096-01 809086-14 812527-08 908692-01 003557-02 006576-02 103882-01 804069-01 806047-01 809086-02 8091JJ-17 812527-01 908692-OJ 003557-04 006576-03 103882-07 804029-01 806006-03 809086-01 812527-11 908692-02 003557-03 006576-04 103882-06 805024-01 806006-02 809086-06 812527-02 908692-04 003557-06 006576-05 103882-08 805010-01 806096-02 809086-04 812527-12 908692-05 006576-06 103882-09
DATE
SAMPLED
04-08-88 05-31-88 09-20-88 12-06-88 12-06-88 08-24-89 08-24-89 03-08-90 03-08-90 06-07-90 06-07-90 03-22-91 03-22-91 04-27-88 06-14-88 09-14-88 12-06-88 08-23-89 OJ-06-90 06-06-90 03-20-91 04-25-88 06-09-88 09-13-88 09-20-88 12-05-88 08-23-89 03-06-90 06-06-90 03-21-91 04-18-88 06-01-88 09-13-88 12-06-88 08-23-89 03-06-90 06-06-90 03-21-91 05-05-88 06-01-88 09-13-88 12-05-88 08-23-89 03-06-90 06-06-90 03-21-91 04-29-88 06-16-88 09-13-88 12-06-88 08-23-89 06-06-90 03-21-91
Ca
3.75 5.9
15 22 20 18.4 18.2 15.2 15.3 19.9 20.3 16.0 14.4 15.J 14.J IB 24 21.9 21.J 2J.5 27.4 17.6 16.2 17 17 15 24.9 21.9 26.0 24.0 14.1 15.9 20 29 JO. J 26.4 J1.2 J2.0 35.1 36.3 19 22 26.0 28.2 28.5 32.4 18.3 21.0 23 31 31.8 32.6 31.2
TABLE
Mq
0.36 2.91 4.1 4.6 5.0 5.64 5.44 5.2 5.2 6.6 6.8 3.9 3.1 7.0 7.28 7.6 7.1 6.53 7.7 7.9 8.5 8.2 9.97 9.0 8.8 8.2 8.00 7.6 8.3 8.8 7.8 8.01
10.0 9.3
10.2 10.5 11.1 11.2 21 8.36
10.0 12.6 11.4 14.0 12.5 13.4 8.8 9.99
10.4 9.8
10.6 11.2 10.B
3 . SUMMARY OF
Na
2 3 6 . 5 174 153 153 151 168 169 158 159 167 163 155 147 100 103 88.8 92.5
129 95.0
114 104 197 181 184 170 169 189 170 172 181 105 116 102 99.2
112 101 112 106 234 222 219 205 222 217 205 220 106 111 104 105 116 116 108
K
10.6 4.9 2.3 1.6 1.6 1.4 1.5 1.2 1.3
ND ND
1.1 1.1 1.8 2.1 1.6 1.8 1.7 1.7 1.6 1.8 2.8 1.7 1.5 1.7 1.4 I .J 1.1 I .J 1.0 2.9 2.9 1.7 1.7 1.8 1.6 1.8 1.6 4.4 J.9 J.5 2.8 1.7 1.2 1.4 ND 3.3 2.2 1.9 2.0 2.2 1.9 2.0
LABORATORY CHEMICAL RESULTS FOR COHMON
CO
138 62
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
2 ND ND ND
6 ND ND ND ND ND ND ND ND
8 3
ND ND
2 ND ND ND
3 3
ND NO ND ND ND ND
1 NO ND ND
2 ND ND
IN CONSTITUENTS
GROUNDWATER SAMPLES FROM MONITOR UELLS HASSAYAMPA
3-
.4
.4
6
0 6
4
~ 6
2
4
HCO^
ND 90
242 246 248 239 233 235 232 254 260 185 168 212 241 223 235 233 2JJ 2J8 228 251 281 JOO 284 J17 288 300 295 336 161 215 229 246 228 239 238 230 224 168 355 307 279 271 278 266 210 260 250 271 242 250 233
LANDFILL , HARICOPA COUNTY, ARIZONA
COHHON CONSTITUENTS
(mi 11
Cl
109 8 5 . 2 75.7 73.0 71.6 75 74 74 74 82 SJ 77 77 J1.1 J2.5 25.9 32.8 J l 34 34 35
106 98.5 81.8 72.8 78.9 81 84 86 82 46.J 47.8 J8.7 49.0 43 48 50 43
257 202 161 149 130 190 150 160 44.7 49.2 36.4 49.4 41 50 45
i grants
SO,,
91 106 122 119 119 82 76
132 132 120 120 110 100 50.8 42 49 47 47 54 50 48 88.2 98.0
124 108 121 55
116 130 110 45 40 49 49 46 55 52 54 77 86
122 112 65
112 120 110 56.3 48 60 56 26 50 51
D
per I i t e r l
_NQ3_
6.9 4.8
11.2 3.61 3.94 4.5 4.2 2.7 2.9 4.9 4.8 2.4 2.2
11.1 12.7 15.6 12.4 8.66 9.6
11 10 16 14.8 11.8 9.7 8.41 6.90 6.9 6.6 6.0
13.9 16.1 17.8 15.3 12.8 12.6 16 11 38.2 JJ.5 16.J 21.5 12.0 19.5 16 16 12.5 15.4 16.J 12.8 12.1 13
...13
ND ND 0.08 ND ND 0.03 0.04 0.17 0.17 0.04 0.04 0.15 0.24 ND
ND ND ND ND ND ND ND ND 0.05 0.07 0.19 NO ND ND ND ND ND ND 0.11 ND ND ND ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND
F
0.24 2.26 2.24 2.09 2.13 2.11 2.15 2.31 2.27 2.24 2.24 1.93 1.91 1.48 1.64 1.36 1.26 1.55 1.55 1.63 1.53 1.59 1.72 2.08 2.15 2.08 1.90 2.04 1.96 1.97 1.2 1.21 1.15 1.05 1.08 1.22 1.16 1.13 1.10 1.68 1.77 1.71 1.75 1.86 1.81 1.79 1.23 1.28 1.25 1.12 1.21 1.25 1.23
KND ROUTINE PARAMETERS
P0.1
0.2
ND ND ND ND ND ND ND ND ND ND ND ND ND 0.25 ND ND ND ND ND 0.28
— ND ND ND ND ND ND ND 0.08
0.14 ND ND ND ND ND
... — 0.32 ND ND ND NO ND 0.29 ND 0.06 ND ND ND ND
P
0.11 0.12 NO ND ND ND ND NO ND ND ND ND ND 0.097 0.44 0.05 ND ND ND ND
0.09 ND ND ND ND ND 0.07 ND
0.10 0.15 ND NO NO ND ND O . U 0.12 0.J4 0.10 ND ND ND ND
0.092 0.64 ND ND ND ND
Alk
235 178 198 202 203 196 191 193 190 208 213 154 140
•-174 197.4 183 193 195 191 195 190
• 217 230 246 233 260 236 246 242 280 145 182 188 202 191 196 195 192 190 144 291 252 229 222 228 222 •i74 213.2 205 222 202 205 194
SiO..
34 29.9 14.9 20.9 22.3 26.4 26.7 25.0 25.2 28.0 29.7 19.9 18.2 24.1 22.1 24.0 23.5 27.5 25.9 28.2 28.2 26.7 26.3 28.1 15.3 27.5 29.4 30.6 31.3 32.7 28^4 22.8 26.6 24.8 27.2 26.7 27.9 28.7 28.7 26.1 28.7 29.1 31.5 31.4 32.1 J4.2 27.2 23.3 27.0 24.9 28.2 28.7 29.7 .
^ 0 ^ ^
TOS
674 526 550 520 512 540 520 510 510 560 560 470 430 360 329 364 347 400 460 420 400 660 650 578 606 599 590 610 620 580 460 440 410 400 430 390 460 410
1,004 858 732 757 710 800 740 750 380 420 434 444 440 480 430
*<fv: *C
Temp'
27.6 30.0 25.9 24.7 24.7 25.0 25.8 25.1 25.1 26.6 26.6 25.0 25.0 25.2 27.0 25.0 23.8 25.0 23.7 25.4 24.4
— 25.6 25.2 25.2 24.4 25.0 24.5 25.0 23.8 24.8 25.5 26.1 24.8 25.0 24.5 25.1 24.2 24.1 26.8 26.0 25.3 25.0 25.3 26.0 25.1 25.5 25.2 25.6 25.0 25.0 24.9 24.1
^e/ Z^//!.,
^ % . ELECTR re*t> CONDUCTANCE-; V
(lin*io/cm)° ' F ie ld
1,000 800 980 860 860 850 850 840 840 870 870 860 860 600 700 650 600 710 645 720 650
— 1,050 1,100 1,050
960 1,100 1,000 1,080 1.000
625 675 760 760 790 700 750 710 6
1,525 1,150 1,200 1,250 1,280 1,350 1,200 1.290
625 725 760 800 800 760 740
Lab
1,170 920 797 834 827 833 822 805 802 880 890 760 740 671 604 554 584 614 599 630 630
1,140 1,090
850 939 965 947 921 970 950 674 730 643 666 674 642 690
pH F ie ld
10.4 9.67 7.92 7.82 7.82
...
... 7.55 7.55 7.61 7.61 7.67 7.67 7.79 7.84 7.92 7.68 8.14 8.01 7.83 8.00
7.71 7.79 7.82 7.68
— 7.78 7.56 7.70 9.4 8.29 7.90 7.76
7.96 7.81
.900/683" 7.92 2,970 1,410 1,100 1,230 1,120 1,240 1,200 1.200
646 724 597 700 647 720 700
8.28 8.71 7.84 7.73
... 7.78 7.64 7.70 8.65 7.69 7.74 7.66
... 7.81 7.89
Lab
10.4 9.7 8.2 8.0 8.1 8.2 8.3 7.8 8.2 8.2 8.2 7.7 7.7 7.9 8.1 8.1 8.1 8.4 8.2 8.1 8.0 8.5 7.8 8.1 8.1 8.0 8.3 S. l 7.9 7.8 8.7 8.4 8.1 8.1 8.4 8.1 8.0 8.0 8.4 8.4 8.1 8.2 8.4 B.O 7.9 7.8 8.4 8.0 7.9 8.0 8.4 8.1 7.9
TABLE 3. SUMMARY QF LABORATORY CHEMICAL RESULTS FOR COHMON CONSTITUENTS AND ROIITINE PARAMETERS IN GROUNDUATER SAHPLES FROH MONITOR UELLS HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
UELL
IDENTIFIER*
MW-4UA D HU-4UA MW-4UA MW-4UA MU-4UA MW-4UA MU-4UA MU-4UA MU-4UB D MU-4UB MU-4UB HU-4UB MU-4UB MU-4U6 MU-4UB MW-4UB HU-SUA D HU-5UA D dup MU-5UA MU-5UA dup HU-5UA HU-SUA MU-SUA dup HU-5UA HW-SUA dup MU-SUA MW-SUA MU-SUA HU-5UA duo HW-6UA HW-6UA;-.^:! ' -HU-6UA' HU-6UA dup MW-6UA HU-6UA dup MU-6UA HU-faUB MU-7UA MW-7UA HU-7UA MW-7UA MU-SUA MU-8UA dup MU-8UA MW-SUA MU-8UA MU-9UA MW-9UB MU-IOUA HU- lOue HS-.J . : !V ... HS-V^^::"--.--.---HS-1 :•;•:-:
HS-i : i i iS:s HS-1 iS-S.i:i:-''
SAHPLE
FIELD
014391 014427 006078 006166 006373 006558 006746 010792 014399 014428 006077 006176 006374 006557 006745 010793 014406 014407 014430 014431 006076 006167 006168 006367 006368 006563 006757 010796 010797
004325 • HASS-A^ ^ 0 0 6 5 6 J ' 006561 006754 006755 010794 010883 004392 006562 006756 010798 0O4J95 004J97 006564 006752 010782 004457 014758 004461 004464 S9905 •• MT8148 08294 08295 0B296
IDENTIFIER LAB
805060-01 8O61J0-01 809086-09 812527-OJ 908706-04 003557-08 006576-09 103882-11 805105-01 806170-01 809086-08 812527-13 908706-05 003557-07 006576-08 103882-12 805139-01 805139-02 807002-02 807002-03 809086-07 812527-04 812527-05 908692-07 908692-08 003572-04 006599-10 103882-14 103882-15 911782-05
"::..i8288:i:.:.;-.-;: 003572-01 003572-02 006599-08 006599-13 103882-13 104835-02 002577-02 003572-03 006599-09 103882-16 002577-05 002577-06 003572-05 006599-06 103882-02 105644-01 105570-01 105723-01 105873-02
• • . . . • • : '• S i : i i i i
i: S"'SiZ.i ' . . • • • . •' ' . ' : • • • : • : . . : . '
• ' ' ' . . : : • • ; . : • • •
DATE
SAMPLED
05-13-88 06-22-88 09-14-88 12-05-88 08-24-69 03-06-90 06-06-90 03-21-91 05-19-88 06-28-88 09-14-88 12-06-88 08-24-89 OJ-06-90 06-06-90 OJ-21-91 05-26-88 05-26-88 06-J0-88 06-J0-88 09-13-88 12-05-88 12-05-88 08-23-89 08-23-89 OJ-07-90 06-07-90 OJ-22-91 OJ-22-91 11-28-89 11-28-89 03-07-90 03-07-90 06-07-90 06-07-90 03-21-91 04-23-91 02-07-90 03-07-90 06-07-90 03-22-91 02-08-90 02-08-90 03-07-90 06-07-90 03-20-91 05-07-91 05-02-91 05-14-91 05-22-91 05-13-82 05-1J-82 09-1*-82 09-14-82 09-14-82
Co .
11.2 9.9
16 22 21.8 18.1 22.1 22.2 10.0 17.5 21 28 29.3 24.0 29.4 29.0 11.1 11.3 20.7 21.1 91 63 69 64.6 67.7 51.7 73.8 55.4 55.1 26 JO.O 23.0 22.8 28.6 28.4 27.5 33.2 20.0 16.5 20.3 19.2 17.4 17.8 13.8 17.5 16.6 20.8 81.5 60.4 205 io
— 36 36 •14
«q .
3.6 7.67 9.5 8.8 9.86 9.4
10.1 10.2 4.7 8.75 9.0 8.0 9.21 8.8 9.5 9.4 4.52 4.62
10.86 11.12 38.4 25.6 26.9 25.5 26.7 22.4 27.8 21.6 21.5 11.9 J1.9 10.9 10.7 11.4 11.1 10.5 9.8 8.9 8.0 8.5 8.9 5.7 5.8 4.8 5.4 6.0 8.2
23.9 27.5 49.6
» 12 12 . 14
Na .
165 185 183 178 191 176 183 191 109 104 102 99.2
110 97.8
109 104 177 175 154 158 291 219 225 25J 263 232 249 224 225 178 184 172 175 177 170 172 101 176 185 179 185 131 130 139 140 136 149 123 242 187
'190
... IBO 180 17B
K
3.4 1.6
ND ND ND ND
1.0 ND
5.1 2.2 1.5 1.7 1.9 1.7 2.0 1.6 5.4 5.0 1.6 2.0 1.9 1.3 1.5 1.3 1.4 1.2
ND ND ND
1.1 : • Z : ^ : ^ . - : • . • • . :
......... ,...p...... ND ND ND
1.0 2.3 1.1
ND ND ND ND ND ND ND
1.0 1.6 3.9 1.2 3.6
NO
... 2.9 Z.99 2.7
t^Ol-
10.8
— ND ND ND ND ND ND
14.4 ND ND ND ND ND ND NO
6 6
ND NO ND ND ND
2.4 ND ND ND ND ND ND
: ; . . ; . . ; . ; . • . • . • : • • . • • ;
::::.^j^.:.::.K«.:
NO ND ND ND ND ND ND ND NO ND ND ND ND ND
6 ND ND ND
6
0 0 0
HC03
267 329 3J7 350 329 326 325 317
' 168 240 244 256 233 229 229 221 240 239 273 272 25J 277 287 254 261 268 261 J46 254 J2J
::iis..:::... ~J2S-"-
J29 323 322 322 222 317 314 J 20 J07 245 244 244 2J4 235 268 144 256 196
^ 8 ^
234 242 242
COHHON CONSTITUENTS ( m i l l
Cl
61 66 64 64
n 77 80 79 4 1 . J6 29 42 41 45 45 4J 75 73.
106 107 297 235 197 230 235 220 300 200 200
79
6 8 8 9
T ~ 4 6 6
T " 2
77.5 75 75 82 85 69 49 69 66 69
" . 55 56 57 65 56 64
210 250 480 105-
— 113 111 104
i grams
SOl-
82.9 97
120 111 71
118 120 98 49.J 76 49 46 J5 49 SO 44 80.5 89.5
126 129 J9S 264 189 US 147 232 230 170 170 126 111 124 122 120 120 110 38
109 124 110 100 60 T i 85 83 64 78 61 87
190
n i " ... i ra 109 112
> per I i t e r l
N O T .
8.3 7.1 8.8 7.88 7.5 8.2 8.7 9.9
11.5 • 9.4
14.8 12.5 13.2 13.1 16 13 11.4 8.8 7.5 7.8
17.8 13.9 13.3 12.1 12.1 12.9 14.2 15 15 6.5 5.8 4.6 4.8 4.6 4.7 4.1
15 7.2 7.5 7.3 7.3 4.6 4 .7 4.1 4.2 4.1 8.1
25 38 22 5.6
... 6.0 5.0 5 .1
Ma-
No ND ND ND 0.04 ND ND ND 0.2 ND ND ND 0.04 NO ND ND ND ND NO ND ND ND ND ND ND ND O.OJ ND ND NO
•i-i-mii. "w"'""
ND ND ND ND ND 0.04 ND ND ND 0.04 ND ND ND ND 0.03 0.03 ND 0.04
O.IS 0.18 ND NO
F
2.28 2.33 2.20 2.10 2.11 2.JJ 2.20 2.19 I.JO 1.36 1.J4 1.29 1.25 1.J5 1.25 1.22 2.19 2.20 2.17 2.22 1.96 1.90 1.98 1.89 1.87 2.15 2.05 2.25 2.09 1.68
;;;:::1v74:f 1.72 1.75 1 .68 1.70 1.64 1 .04 2.56 2.71 2.64 2.49 2.60 2.61 2.66 2.52 2.58 2.J2 0.83 1.52 0.66 i.5f~ .... 1.32 1.50 1.50
POl-
0.1 0.09 0.10 ND NO ND ND ND
... ND ND ND ND ND ND NO
... ND ND 0.12 ND ND ND ND NO ND ND ND ND
• : : - . r • , . : • • • • • • .
. , . ^ ^ : i : . . . ND ND 0.05 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
' i . m i i i . m ' i -
. ; _ • : . ' : :
sm.m
p
0.14 0.092 0.23 ND ND 0.05 ND ND 0.33 ND 0.22 ND ND ND ND ND 1.18 0.38 ND ND 0.27 NO ND ND ND ND ND ND ND ND
. : - ^ S S i i 1
'd:or' 0.05 NO ND ND HD ND 0.44 0.02 ND ND 0.07 NO 0.50 ND ND ND ND ND
...
...
...
Alk
237 270 276 287 270 267 266 264 162 197 200 210 191 188 188 184 207 206 224 223 207 227 235 212 214 220 214 288 212 265 271 269 270 265 264 268 185 260 257 262 256 201 200 200 192 196 229 120 213 163
— — ... ... ---
1122
24.2 29.3 31.9 29.8 33.5 33.8 34.6 35.7 25.7 20.7 26.4 24.5 27.9 27.4 27.9 28.7 22.0 21.0 26.2 27.2 26.1 25.6 24.6 28.1 27.8 26.7 28.7 29.7 29.5 36.6
•: m , s . i s ' • 3 * : o - "
33.6 34.9 34.9 35.5 27.8 32.9 32.1 33.4 35.1 31.2 30.6 28.9 31.0 11.7 31.2 28.0 37.4 32.9
...
...
TDS
532 651 590 598 630 600 640 560 408 404 392 396 440 410 420 290 514 528 640 638
1,270 1,041
900 980
1,000 950
1,050 780 730 600 629 580 590 600 610 480 410 570 570 590 360 430 410 360 450 430 510 700 960
1,700 667
— 659 650 646
Teffo*^
26.9 26.7 25.0 24.7 25.0 24.0 24.9 24.4 26.8 25.7 24.8 24.8 25.0 23.9 25.2 24.6 26.8 26.8 26.0 26.0 24.7 24.7 24.7 25.0 25.0 24.0 25.1 24.5 24.5 23.1
::»iv::'--... ' 23 JV''
23.9 25.3 25.3 24.2 24.9 24.6 24.3 25.0 24.3 24.0 24.9 24.6 25.9 24.5 24.0 23.8 25.1 25.0
--.-— .... ... ...
ELECTRICAL
CONDUCTANCE (B j rho /cm)
F ie ld
850 950
1,070 1,080 1,090 1,000 1,040 1.060
660 650 740 710 750 690 720 700 850 850
1,000 1,000 2,800 2,050 2,050 2,000 2,000 1,650 1,900 1,600 1.600
975 . . ; : . : : • . • . ; . • ; . ; : ;
' '•' '•97^ ' 975
1,020 1,020 1.000
740 900 950
1,000 990 690 700 750 800 800 890
1.200 1.550 2.230
— ... -,. ... "•
Lab
852 894 884 948 961 957 980 940 602 665 598 644 663 638 670 640 876 872
1,000 999
1,730 1,660 1,310 1,570 1,570 1,460 1,680 1,400 1.400
933 •:V:.965-::.
867 • 890 950 950 920
- 652 902 897 920 930 687 689 636 710 690 800
1.030 1.570 2.190 I.JOd'
— 1,090 1,080 1,060
P« F ie ld
8.74 7.92 7.98 7.76
... 8.11 7.94 8.01 8.89 7.78 7.76 7.65
— 7.91 7.80 7.92 8.66 8.66 7.85 7.85 7.60 7.51 7.51
— — 7.79
7.57 7.63 7.63 7.51
I . . . . . ; : . . . , •:
" • 7 : 7 5 " 7.75 7.76 7.76 7.77 7.85 8.27 8.00 7.80 7.99 8.21 7.90 8.05 7.74 7.87 7.98 7.62 7.89 7.28
— — .... ... ...
L a b .
8.7 8.2 8.2 8.1 8.3 8.3 8.2 8.2 9.0 7.8 8.2 8.1 8.3 8.1 8.0 8.0 8.6 8.6 B.O 8.0 8.3 8.0 7.9 8.4 8.3 8.1 8.1 7.7
_ L 8 8.0
i 7 : i "8.2 8.2 8.2 8.2 7.9 8.2 8.2 8.3 8.3 8.1 8.2 8.2 8.3 8.2 8.1. 8.5 7.? B.2.
-Z4 ^7f — 7.6 7.6 7.7
TABLE J. SUHMARY OF LABORATORY CHEMICAL RESULTS FOR COHMON CONSTITUENTS AND ROUTINE PARAHETERS IN GROUNDUATER SAHPLES FROH MONITOR UELLS HASSAYAHPA LANDFILL, MARICOPA COUNTY, ARIZONA
UELL
IDENTIF IER"
HS-1 H S - I . . HS-1 • HS-.2 ; HS-2 . t i s - 2 -HSrZ HS-2 HS-2 HS-2 HS-2 HS-2 HS-2 HS-2 HSrJ . ; . :.,,..•.:•,
HSrJ, • : •> ; • : • • • • : . ; :^
»s-iiZsma-K y y s : : : m : - m
«s-j:.;;s-:-f::. HS-J HS-J HS-J HS-J KS-J HS-J HS-3 HS-3
SAMPLE
FIELD
Mlf0229
-- ' . 004017 39903 08297 HY0227 .
. . . 0D401B 006081 006173 006372 006565 006750 010784
3 9 9 0 4 " MY8147 0 8 2 9 8 H t n 2 3 0
004016 0060S2 006097 006170 006370 006568 006749 010786
IDENTIFIER
LAB
3 0 4 3 - 2
3 0 4 3 - 3 8 0 9 0 8 6 - 1 2 8 1 2 5 2 7 - 1 0 908706 -OJ 0 0 3 5 7 2 - 0 6 0 0 6 5 9 9 - 0 4 103882 -03
: : . , , . . . . . . . . . . ; : ; : : • : . : . . • . - . : • •
• i i i m / i i . ; ; • ; • ; • ; ;
.:...: : : ; . . : : . ; : : : : y . •.•.:•••:•:.•:
:.: S.y:SS:: :::•!:
. . . . • . • : . . . . • . . . . . • . .
3043-1 8 0 9 0 8 6 - 1 3 8 0 9 1 3 3 - 1 8 8 1 2 5 2 7 - 0 7 9 0 8 7 0 6 - 0 1 0 0 3 5 8 8 - 0 1 0 0 6 5 9 9 - 0 3 103882-05
DATE
SAHPLED
0 5 - 1 8 - 8 J 0 4 - 1 5 - 8 7 . . 0 7 - 1 5 - 8 7 0 5 - 1 2 - 8 2 : 0 9 - 1 4 ^ 8 2 0 5 - 1 8 - 8 3 0 4 - 1 5 - 8 7 0 7 - 1 5 - 8 7 0 9 - 1 4 - 8 8 1 2 - 0 6 - 8 8 0 8 - 2 4 - 8 9 0 3 - 0 7 - 9 0 0 6 - 0 7 - 9 0 0 3 - 2 1 - 9 1 0 5 - 1 2 - 8 2 0 S r : i 2 r a 2 v ; 0 9 - r « i r S 2 -
0 5 : . 1 8 r 8 3 t 04-15^87; . ; ; 0 7 - 1 5 - 8 7 0 9 - 1 4 - 8 8 0 9 - 2 0 - 8 8 1 2 - 0 5 - 8 8 0 8 - 2 4 - 8 9 0 3 - 0 8 - 9 0 0 6 - 0 7 - 9 0 0 3 - 2 1 - 9 1
Ca
. . . • . . .
25 26
• * • *
. . .
. . . 16 22 2 2 . 5 1 8 . 6 2 3 . 8 2 3 . 2
.-.86.. ..>!.•; :::r-;- iS i
smz : . : . r . ? r . •:••::;:•
p . : . : - ; : •!•
• • - • - . • • • • • • • • "
50 59 48 6 6 . 5 5 1 . 6 6 7 . 4 6 1 . 9
Mq .
izzsm • • • • • • . • . . • " • • • • • • • • •
••••v:6 S^.y-
. M i 6 •:';••!••
iiimZZ: ; ; • ; . . - . : • •
••• - • • ; " • • • • • • • • •••
8 . 4 7 . 7 8 . 5 8 8 . 6 9 . 4 9 . 2
i iO: - .S iS • . : . V - i :•..•::
:;:Ms:s ^ i - T m S : S S'Si::mm • • ' " • - - - • • ' " • • • ' •
3 2 . 1 3 2 . 4 2 9 . 4 3 2 . 3 2 7 . 8 3 2 . 0 2 9 . 5
N«
f>Ni?'V¥:: S i ' - ^ m -: • : . • : • : • " • • : : : : . • : • . • : • : • •
•:::15?: S
'm9Z ; : • : •?• ' * . ; ' : ! • !
" • • : : : ' • • • •
151 148 160 163 159 159
S^Ui: •: : ; * * • ? • • • • : • : :
sw^iZ ; ' .. . : ; M ' T S I
243 239 228 260 253 255 246
K
SSfAi 'SS
ss::m,ms • • • • • . . • . • • • • •
SW Siir-:^; •••• . . l i - : » ; • • . : • • ?
.;::-..:.:.: -V: •.•.::.•::.
ND ND ND ND ND ND
. S - ' T S S S S
m-isiii. ::•:;.•:::. ii^.x
amsM
1.0 1.4 1.1 1.4 1.2
ND 1.2
CO.,
m^^iiss • • • " . v : - • • • • • •
mm.oZ •MWi. S ] ' r s m : . ™:.?.;:V:: .:.•
ND ND ND ND ND ND
S S S i ^ i i i :::•.::; i.^-;-.::^-
WZOZ:
iZZm • • " • • " • ^ • ' • • • • • • •
ND ND ND ND ND ND ND
HCO3
mZZ:i: '.:• z : * " ! "? -^ : - : • : •
................ . m : i M t . S :
a^m:s Z-:''s: ii.i:::.:;.:::.!:... i
287 301 284 284 283 275
;•;•.••. i J ? : ; ; mi^r.zm S i ^ t
iSsZmZ: ' • • " - • : ' - • • • • •
267 259 293 261 261 262 253
COHMON CONSTITUENTS^
( m i l l
Cl
;>li||:ft :.-;:>:59:y.:::;;:-i S ^ S S S S i
• : : . : - r . ; r ? : : . : : . : : : • . : : .
' j - r s m • • . : : • : • . : • • • : • : • . - : • : • :• •:•
5 3 . 4 6 1 . 4 65 65 73 62
270
.... 2 7 1 .
. . : •
297 285 286 310 J I O 260 280
i grams
S O 1 .
i - r i i m S • • • - ^ : - : : . . .
. : _ • ! ; • ! . . . : : . : •
!! 8 4 :•!•.;
i -MZ i-sssm i m i , i i i . : : : • • : . • . : • . : •: : •:•:-
94 7J 45
102 9 J 86 8 0
. . . . VO
. . . — --'.
92 94 88 59
102 88 84
p e r l i t e r
NO,
Ss-if'Zs -• 2 . 3 •;••<"
. . . . . : : . : . ^ . . ^ : . : . . . •
! - • " ? : : • ; : : • >
i:s^:i-m S"/" •:...
i s : : j ^ \ : m .•.«:^..5....::.
1 0 . J 7 . 0 0 6 . 6 6 . 8 6 . 6 6 . 4
...:::*i.::-.-i,*-.;?;. '--.-»•.:•••!.
zmzs 5N;46;6i:
• • j i ; j - - -4 3 . 3 4 1 . 9 4 2 . 3 36 39 40 38
)
N H T
^^iio *•.!•.: simsm ,_..,...,.. i -ST'Si . sKD-v-i'
imSi
W " ND NO 0 . 0 4 ND ND ND
. w - ^ ;•::;•;
JNO;!.-;.::. ..NB-:" S
WZsi. i j ^ . i : . i -
ND 0 . 0 6 ND 0 . 0 6 ND ND ND
F
iri^.-*.S:i • • • • ; v ; ' i - • • : : • • • •
• • • * • ; • ; " " " •
:;:-.2;-38...:
;:2i4:1;s
smi • : • : • : • • • ••••
2 . 3 1 2 . 3 6 2 . 1 4 2 . 4 4 2 . 3 3 2 . 3 4 1 .32
. . . 1 .23
• . - ,
— 1 .29 1 .38 1 .19 1.25 1 .40 1 .31 1.31
POl
i i iMZ :!•.•:..:•:'' ' ' . : i '
Ssmm. -;.:* sma ss..s: .i.-.:i.»', :.-.: . : : : : • : : : : . . • : : • . . :
0 . 3 0 ND ND 0 . 0 6 ND ND
.-.--....
. L l ,
0 . 5 4 ND ND ND ND ND ND
P
SZZ-i s: - s "''s:s'"'-!..:.*-r.....:.l ; - - V * \ i ; •;;;•;:
si::, msi ,:-iS4::!V J... . : ; • ; ! . : ! • : •
0 . 3 6 ND ND ND ND ND
• . : - . * . . : .
: ! - r ^ * : : s ; a m ^ i s
SiSir-iSm my-ZsS:
0 . 5 4 ND ND ND ND ND ND
A l k
;:-sv;J:- .-: : : . . : : • . . . ; . : . - . : . : . . .
::::;;T^^^.::;::.-
i - ^z-mi - i . s : . r - ' ' i : s • ! • - • - : • • : . • • ;
- m . m - i :" ••::•• V:::.::..:::.:.:.::;
235 247 233 233 232 229
s Z i i . s ' i
S S : : ^ m i :
i Si rZii i i.m-rSS::S: • - . . . . . . ^ . ^ . . . . . . . . . . .
219 212 240 214 214 215 211
S i O ,
. . . r - -
*.* . . . .... .--2 9 . 6 2 7 . 6 3 1 . 5 3 0 . 8 3 1 . 0 3 4 . 0
sm^...i,. WiV;..---
msmm :m:vS:S
3 4 . 5 19 .5 J 2 . 7 J 6 . 4 J 4 . 0 J 7 . 8 J 7 . 6
T D S .
:mm-mi ..... . :. .: :
• ' • • • • • • • • • " • ; • • • •
;.-:;::...;:.515v. .. ,.-::.5j2;:. .;.:V::..-.r;.: i : : i . i , s m • • ' • • • • • • • • - - ^ • • • • '
474 509 540 550 510 530
1 ,053
. . —.. 1 . 0 5 2
---• : . :
I .OJO 1 ,070 1 ,029 1 ,080
920 1 ,040
950
Temp"
.«. 2 9 . 5
"'* • - H
2 5 . 9 2 5 . 0 2 4 . 4 2 5 . 0 2 4 . 6 2 5 . 0 2 4 . 5
. ^ . i . - r - * : . - • :
sZZ,s Smi'SZ :sis~s[ss " 2 6 : i "
2 5 . 4 2 5 . 2 2 4 . 8 2 5 . 0 2 4 . 0 2 5 . 2 2 4 . 7
ELECTRICAL
CONDUCTANCE (mnho /cm)
F i e l d
S i i i ' ' m : ' 1 .106 : : i - r ' r .S
••'r.T-T''^' : : i : . -m. : :S . Z : ~ m - f
" 8 0 0 925 910 925 875 950 900
..--.
— — . . .
2 , 1 0 0 2 , 0 0 5 2 , 0 2 5 2 , 0 0 0 2 , 0 0 0 1 ,900 1 ,900 1.875
Lab
. . .
. . .
. . . 1 ,010
.870
. . .
. . .
. . . 786 816 822 809 830 820
2 , 0 4 0 •
1 , 7 2 0
— . . . —
1 ,700 1 ,620 1 ,510 1 ,720 1 ,630 1 ,670 1 .700
pH F i e l d
: • . ; • : • , ; . -
: • : : • • - , v ; - . : . :
' • • 7 : 6 9 ••••
•; : . : ' . " * • • • • • : •
••••! i V r ' r ^ . . ;
• : ' • " " : ; • ::.
• • ' • 7 / 7 0 • •
7 . 8 8 7 . 8 0
— 7 . 9 8 7 . 8 9 8 . 0 6
. . . — — — —
7 . 3 8 7 . 5 5 7 . 5 5 7 . 4 6
— 7 . 6 6 7 . 5 2 7 . 7 2
Lab
. . . r
. . . ; . . 7 . 7 7 . 9
. . . .... : . . 8 . 1 8 . 1 8 . 1 8 . 2 8 . 3 8 . 0 7 . 6
. - . 7 . 6
— — — 7 . 9 7 . 9 8 . 0 8 . 1 7 . 9 8 . 0 7 . 7
D B Sample obtained during well developrnent
dup s Duplicate sarrple
Ca • Calciun Hg • Hagnesiun Na - Sodiun
K ' Potassiun CO3 = Carbonate
KCO3 B Bicarbonate Cl = ChVoride SO4 s Sulfate NO3 = Nitrate (as M)
TeiTp = Tenperature (degrees Celsius)
M/i#io/cin = Micron^os per centimeter
NH3
F PO4
P Alk
SiOj TDS ND
' Ammonia (as N)
= Fluoride : Phosphate (ortho) (as P)
• Phosphorus (total)
' Alkalinity (as CaC03)
> Silica
•• Total dissolved solids : None detected • Not analyzed
NOTE: Except for highlighted samples, samples analyzed by
Analytical Technologies, Inc., Phoenix, Arizona.
Groondwattrsamptt not .obtained by Errot L. Hontgonery & Associates. 1962 Sampie obtained iny Arizona Departtnent of Health Services
1963 Sampl* obtained by Ecology and Environmant, Inc. 1987 Sample obtained by Maricopa County .
1989 Sample obtained by Arizona Departsient of Environmental 12uality
Inc^
Electrical conductance initially measured in the laboratory uas reported to be 6,900 nni\o/cm, which is anomalous. A second laboratory rneasurement made after a holding time of 73 days uas 6fi3 tuit\o/cm. The second laboratory measurement corroborates the field measurements; the initial laboratory measurement is not considered to be representative.
' o ^ ^ ^
UELL IDENTIFIER"
HW-lUA D MW-IUA MW-IUA MW-IUA MW-IUA dup MU-lUA MU-lUA dup MU-lUB D MU-lUB MW-IUB MU-lUB MW-IUB MW-2UA D MW-2UA MU-2UA MW-2UA MW-2UA MU-2UA MW-2UB 0 MW-2UB MU-2UB MU-2UB MU-2UB MW-3UA D MU-3UA HU-3UA HW-3UA MW-3UA HW-3UB D HW-3UB MW-JUB MW-JUB HW-JUB HW-4UA D HW-4UA HW-4UA MW-4UA HU-4UA HW-4UB D HW-4UB MU-4UB MW-4UB HW-4UB HW-SUA 0 HU-5UA D dup HW-SUA HW-SUA dup HW-SUA HU-SUA HU-SUA dup KU-5UA MU-SUA dup MU-6UA MU-6UA NU-6UA dup MU-6UA MU-6UA dup
SAMPLE FIELD
014J78 014412 006099 006177 006178 006J75 006376 014383 014425 006083 006171 006360 014382 014421 006071 006088 006164 006363 014379 014414 006070 006174 006362 014387 014413 006075 006165 006364 014384 014426 006073 006175 006365 014391 014427 006078 006166 006373 014399 014428 OD6077 006176 006374 014406 014407 014430 014431 006076 006167 006168 006367 006368 00432S 006560 006561 006754 006755
IDENTIFIER LAB
16208 806006-01 809133-15 812527-14 812527-15 908706-06 908706-07 804087-01 806096-01 809086-14 812527-08 908692-01 804069-01 806047-01 809086-02 809133-17 812527-01 908692-03 804029-01 806006-03 809086-01 812527-11 908692-02 805024-01 806006-02 809086-06 812527-02 908692-04 805010-01 806096-02 809086-04 812527-12 908692-05 805060-01 806130-01 809086-09 812527-03 908706-04 805105-01 806170-01 809086-08 812527-13 908706-05 805139-01 805139-02 807002-02 807002-03 809086-07 812527-04 812527-05 908692-07 908692-08 911782-05 003572-01 003572-02 006599-08 006599-13
DATE SAHPLED
04-08-88 05-31-88 09-20-88 12-06-88 12-06-88 08-24-89 08-27-89 04-27-88 06-14-88 09-14-88 12-06-88 08-23-89 04-25-88 06-09-88 09-13-88 09-20-88 12-05-88 08-23-89 04-18-88 06-01-88 09-1J-88 12-06-88 08-2J-89 05-05-88 06-01-88 09-1J-88 12-05-88 08-23-89 04-29-88 06-16-88 09-13-88 12-06-88 08-23-89 05-13-88 06-22-88 09-14-88 12-05-88 08-24-89 05-19-88 06-28-88 09-14-88 12-06-88 08-24-89 05-26-88 05-26-88 06-30-8S 06-30-88 09-13-88 12-05-88 12-05-88 08-23-89 08-23-89 11-28-89 03-07-90 03-07-90 06-07-90 06-07-90
Al
0.44 ND 0.47 ND ND ND ND ND 0.2 0.04 ND ND ND ND 0.07 ND ND ND ND ND 0.04 ND ND ND ND ND ND ND ND ND ND NO ND ND ND 0.05 ND ND 0.2 ND ND ND ND ND 0.2 NO ND ND ND ND ND ND ND
Sb
ND ND ND — — — ... ND ND ND --. ND ND NO NO — ... ND ND ND — ... ND ND ND ... ... ND ND ND ...
ND ND ND
ND ND ND ... — ND ND ND ND ND — — ... ND
...
...
As
ND 0.011 ND ND ND NO ND ND NO 0.007 0.006 0.007 ND ND ND ND ND ND ND ND 0.005 ND ND ND ND 0.008 ND ND ND ND ND ND ND ND 0.010 0.010 0.008 0.008 ND ND 0.008 NO 0.005 ND NO NO ND 0.020 ND ND NO ND 0.007 0.006 0.005 ND 0.005
Ba
ND ND ND ND ND 0.03 0.02 0.10 0.07 0.12 0.09 0.06 0.06 0.07 ND NO ND 0.02 0.11 0.07 0.07 0.10 0.07 0.08 0.11 ND ND 0.02 0.06 ND ND ND 0.04 ND ND ND ND O.OJ NO ND 0.08 O.OB 0.07 ND ND 0.06 0.07 ND ND ND O.OJ O.OJ ND
...
TABLE 4.
Be
ND ND ND —
— ND ND ND
— ND ND ND ND
— ND ND ND — — ND ND ND
ND ND ND
... ND ND ND
— ND ND ND ...
ND ND ND ND NO —
— — ND — — — ...
SUHMARY IN
OF LABORATORY CHEMICAL RESULTS FOR TRACE GROUNDWATER SAHPLES FROH
HASSAYAMPA LANDFILL, MARICOPA
B
0.5 O.J 0.45 0.44 0.44 0.46 0.46 0.2 0.2 0.2 0.22 0.25 0.2 0.4 0.4 0.40 0.57 0.41 ND ND 0.2 0.21 0.19 0.5 0.2 0.5 0.59 0.50 0.2 0.2 0.2 0.20 0.20 ND 0.4 0.4 0.49 0.40 O.J 0.2 0.2 ND 0.17 0.5 0.4 0.45 0.51 0.5 0.54 0.5J 0.44 0.46 0.J8
— — — ...
Cd
ND ND ND O.OOJ ND ND ND ND ND ND ND ND 0.005 ND ND ND ND ND 0.004 ND ND ND ND 0.004 ND ND NO ND NO ND ND ND ND ND ND ND O.OOJ ND ND ND ND ND ND ND ND 0.005 0.006 O.OOJ O.OOJ 0.004 ND ND ND — — — ...
, Cr
0.042 0.024 ND ND ND NO ND ND 0.02 ND O.OJ ND ND ND ND ND 0.02 ND ND ND ND O.OJ ND ND 0.020 ND ND ND ND ND ND O.OJ NO ND NO O.OJ 0.02 ND ND ND ND 0.02 ND ND ND 0.02 O.OJ 0.02 ND ND ND ND 0.02 0.02 0.02 0.02 ND
Co
ND ND ND
— — ND ND ND
ND ND MD NO
— ND ND ND — — ND ND ND
ND ND ND
— ND ND NO
— ND ND ND ...
ND ND ND ND ND
...
— ND — — ... ...
HONITOR COUNTY,
UELLS ARIZONA
CONSTITUENTS
TRACE C O N S T I T U E N T S "
...(mil
CU
0.017 ND ND ND ND ND ND ND ND NO ND ND ND ND NO ND ND ND ND ND ND 0.011 ND ND ND ND ND ND ND ND ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND 0.015 0.02J ND O.OU 0.019 ND ND 0.015 ND ND ND ND
igrams per liter
CN
ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.01
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.01 ND ND 0.01 ND NO ND ND 0.01 ND ND ND ND ND ND ND ND ND ND ND ND ND
...
Fe
0.JJ7 0.099 ND ND ND 0.101 0.106 0.0J4 1.71J 0.0 JB 0.0J2 ND 0.J76 0.158 NO ND ND 0.175 ND 0.065 0.0 JB ND 0.014 0.076 0.J90 NO 0.J67 0.091 ND ND ND ND 0.020 0.5J4 0.048 ND 0.0J2 0.011 0.J26 0.052 0.063 NO 0.012 0.774 0.517 0.035 ND ND 0.033 0.038 0.040 0.072 0.031 0.024 0.015 0.012 ..0.020
)
Pb
NO ND ND ND ND 0.002 0.002 ND ND 0.005 ND 0.006 ND ND NO ND ND 0.005 ND ND ND 0.002 0.010 ND ND ND ND 0.004 ND ND 0.002 ND 0.005 ND ND ND ND 0.005 ND ND ND ND 0.003 ND ND ND ND NO ND NO 0.004 0.005 0.013 ND ND ND ND
Hn
ND ND 0.216 0.306 0.310 0.110 0.100 0.018 0.043 ND ND ND 0.032 0.022 0.056 0.067 0.029 0.068 0.011 ND ND ND ND 0.040 0.011 0.039 0.061 0.066 NO ND 0.013 ND ND 0.028 ND ND ND ND 0.016 0.022 ND NO ND 0.022 0.024 ND ND 0.028 0.014 0.021 0.015 0.014 ND
— ...
HS
0.0002 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.0003 ND ND ND ND ND 0.0002 ND ND NO ND 0.0003 ND ND ND ND ND ND ND ND ND ND 0.0004 NO ND ND ND ND ND ND ND ND ND ND ND
...
Ni
ND ND ND ND ND ND NO ND ND ND ND ND 0.043 ND ND ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO NO NO ND ND ND ND ND ND ND ND ND ND —
— ...
Se
ND ND ND — — — — ND ND ND — — ND ND ND ND
— ND ND ND
— ND ND ND — — ND NO NO — ND ND ND
— ND NO ND
— ND ND ND ND ND — —
— ND
...
-'4
ia .
ND ND ND
—
— ND ND ND — NO ND ND ND — — ND ND ND — — ND ND ND — — ND ND ND — ND ND ND — — ND ND ND
ND ND ND ND ND — — — ND
...
V^<' v^>^
^^ 'V/y,.
^ o K ' i ^
Tl
ND ND ND — — — ND ND ND — — ND ND ND ND — — ND ND ND
ND ND ND — — ND ND ND — — ND ND ND — ND ND ND ... — ND ND ND ND ND —
— NO — —
...
' ^
A
fy '^Ix
sn ,
ND ND ND
ND ND ND
ND ND ND ND
ND ND ND
ND ND ND
ND ND ND
— ND ND ND
ND ND ND ... ND ND ND ND ND —
— ND
...
...
. .vi-! . . . ^ V
0.06 0.04 0.02 ND ND ND ND ND 0.03 0.01 0.02 0.02 0.03 0.05 ND 0.01 ND ND ND 0.02 0.01 0.02 ND ND 0.04 ND ND ND ND 0.02 ND 0.02 ND 0.02 0.03 0.03 0.04 0.04 0.02 0.02 0.01 0.03 0.02 0.03 0.03 0.03 0.03 ND 0.02 ND ND ND 0.04 0.03 0.03 0.03 0.03
Zn
0.202 0.079 0.175 1.52 0.970 0.461 0.409 0.276 0.191 0.513 0.246 0.162 0.021 0.205 0.382 0.300 0.344 0.370 ND 0.171 0.496 0.287 0.464 0.022 0.095 0.320 0.339 0.159 ND 0.072 0.516 0.440 0.080 0.079 0.056 0.326 0.241 0.153 0.074 0.051 0.293 0.289 0.213 0.023 0.017 0.117 0.065 0.910 0.492 0.666 0.299 0.264 0.060 0.111 0.157 0.173 0.323
TABLE 4. SUHMARY OF LABORATORY CHEHICAL RESULTS FOR TRACE CONSTITUENTS IN GROUNDUATER SAHPLES FROH MONITOR WELLS HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
UELL IDENTIFIER'
MU-6UB
SAMPLE IDENTIFIER FIELD LAB
DATE SAMPLED
TRACE CONSTITUENTS" .(mi 11igrams per liter).
010883 104835-02 04-23-91
Al
ND
Sb
ND
_Ha_
0.007 0.081 0.15 ND 0.029 0.006
*a.
ND
Tl
ND
Sn
ND 0.017 0.010 MW-TUA HW-TUA HW-7UA
004392 006562 006756
002577-02 003572-03 006599-09
02-07-90 03-07-90 06-07-90
0.011 0.006 0.006
0.027 0.021 0.022
0.02 0.01 0.02
0.016 0.118 0.042
0.002 ND ND
ND 0.03 0.03 0.03
0.142 0.091 0.184
HU-BUA HU-SUA dup HU-8UA MU-8UA
004395 004397 006564 006752
002577-05 002577-06 003572-05 006599-06
02-08-90 02-08-90 03-07-90 06-07-90
ND ND
ND ND
0.009 0.008 0.006 ND
0.048 0.048 0.043 0.049
ND ND
ND ND
0.02 0.02 ND ND
ND ND
ND ND ND
ND ND
0.011 ND
ND ND
0.032 0.032 0.087 0.203
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
0.03 0.03 0.02 ND
ND ND
MW-9UA 004457 105644-01 05-07-91 0.009 0.061 0.38 ND 0.016 0.021 0.002 ND 0.030 0.093 HU-9UB 014756 105570-01 05-02-91 ND 0.165 ND 0.029 ND 0.010 ND 0.014 0.243
004461 105723-01 05-14-91 0.115 0.17 0.015 ND 0.025 0.166 HU-IOUB H$-1 HS-1 HS-1 HS-1 HS-1 HS-1 HS-1 HS-1 HS-2 HS-2 HS-2 HS-2 HS-2 HS-2 HS-2 HS-2 HS-2 HS-3 HS-J HS-3 HS-3 HS-3 HS-3 HS-3 HS-1 HS-1
004464
J9905 H T B U 8
08294
08295 08296
MY0229 MT0919 NY0921
3 9 9 0 J HY8146
08297 MY0227 HY0918. 006081 006095 00617J 006J72
J9904 M T 8 U 7
08298 MT02JO My0917 . 006082 006097 006170 006170
1 0 5 8 7 1 - 0 2 . : • • : . . : • ; • ; - : . • . : : : • ; • . . .
:•• " • : . • ; . • • • : : . : . . ; • : : . • •
i:: :m: •• !•<.•>< : : , . . , : . . ; . . : : . , . : . : . : . . . : • : : • . : . :
. . : . . • . : : . : . : . . • . ^ ; : : : : : - - ;
v . : : . . . . : . . . . . - ^ . : • . . : : : . . : . . .
sms-msm. : :S : : i : i S H i
s.mss m:s--i 8 0 9 0 8 6 - 1 2 8 0 9 1 J J - 2 1 8 1 2 5 2 7 - 1 0 908706 -OJ
• : • • • • : : • : . ; . . : : . . ; . ; : ; : : : • : : . . • . : .
.:!...•:!•.• m S ••••
s . • > . . • < ! < • • • • ; ; ; • . • : • . : .
8 0 9 0 8 6 - 1 3 8 0 9 1 J J - 1 8 8 1 2 5 2 7 - 0 7 9 0 8 7 0 6 - 0 1
0 5 - 2 2 - 9 1 0 5 - 1 3 - 8 2 0 5 - 1 J - 8 2 0 9 - 1 4 - 8 2 0 9 - 1 4 - 8 2 0 9 - 1 4 - 8 2 . 0 5 - 1 8 - 8 3 O 9 - 0 5 - B 4 . 0 9 - 0 5 - 8 4 0 5 - 1 2 - 8 2 0 5 - 1 2 - 8 2 0 9 - U - 8 2 0 5 - 1 8 - 8 3 O 9 - 0 S - a 4 0 9 - 1 4 - 8 8 0 9 - 2 0 - 8 8 1 2 - 0 6 - 8 8 0 8 - 2 4 - 8 9 0 5 - 1 2 - 8 2 0 5 - 1 2 - 8 2 0 9 - 1 4 - 8 2 0 5 - 1 8 - 8 3 0 9 - 0 5 - W 0 9 - 1 4 - 8 8 0 9 - 2 0 - 8 8 1 2 - 0 5 - 8 8 0 8 - 2 4 - 8 9
ND
W>
— ... ;
• . . « •
2 . 4 0 , 1 1 6 0 . 0 8 9
...
.*, . .--... D . 0 7
— ND ND
... .... 0 . 2 9 0 . 1 8 3 0 . 0 2 ND ND ND
ND
....-
... :... ...
• •
.... ... ... ND
— —
: : . : • : . • : :
' i . . ' . ••:
• : - . * U i
- . . . . . •
NO
ND
—
ND . . N D • : : ; ; • : .
:MDmi: - :
: M Z i • • N D : i s
• : : - m - - S s m i . i ' i ; . i-msms ! - . - N D . :••••>••;
:.-i:ND::-i>4.:.S-
: v M D ' i M : :
smmSi O . 0 0 7
0 . 0 0 5 0 . 0 0 6
• : . ^ ^ ^ . : : • : • • .
;;. NO :.:.;;.!..<:
iMOii • . :NO: : ; :> : . : . - -
. . - ; - • • : : : . -
• i io " "•• ND ND NO
0 . 2 4 0 : . , N D ....:•:,.••.!.
: - ;0 i30^-: : : . : . « D .;.;:;:!•..:••
i W S i S i W>Si
SiiDiS.:': i. 0.046.: .0;04?-
• j N o s i : ::i)IOSi. SHtt - i : : ; : :0 i046s
0 . 0 7
— 0 . 0 6 0 . 0 6
• . . . ^
ND NO 0 . 1 2 0 . 1 0 3 0 . 1 5 0 . 1 6 0 . 1 4
0 . 1 2
ND
:.:. ....: : . : : : i . . : : : : ; : . ,
: • . . - - - : • . • . : : . • • :
: : • • . . V f . : : ; : : • .
- . • • ; ; • . • • ; • • ; ; : • . : •
i m S i : : : : S
V ^ . l i : - J;;-!;-
:iS^MmSS:i
;:-:..iv; :::;:.:;;:¥.
;::o;ooo9.;: • ND
— — —
: - ' - ^ \ S : i
.:.-rr *•::..:::.;:.:::
- , ^ i , ^ i : : \ - i i i
I ' r t S - S S :
ND ND
—
0 . 5 1
— 0 ; 3 2 0 . 3 2 0 . 3 4 0 . 3 3 0 . 5 0 — •
. --- .
: 0 . 3 7 0 . 3 9 0 . 5 0
'... 0 . 4
0 . 4 1 0 . 4 0
. •
0 . 1 8 0 . 4 0 0 . 4 3
... 0 . 4 0 . 3 5 0 . 4 1 0 . 3 8
ND
NO NO W
HO . . NO
0.OO093 O.0O068
ND NO ND . 0 . 0 0 0 6 6 NO
ND ND
0 . 0 0 8 NO KD
.... ND 0 . 0 0 3 0 . 0 0 4
ND
ND
MD W) • ND . «D .. . ND 0.012 0 . 0 0 5
0 , 0 2 0 0 . 0 2 9 0 . 0 2 4 0 . 0 1 7 0 . 0 2
— 0 . 0 4 ND
; . : " - ; . : . . : • •
SMS t! s;o.oi2;? i^wmim
• • . . : * . . . . • • . . : ; : : •
ND ND 0 . 0 3 ND
ND
...
...
... -.-. ... *---.-... ND
— —
: : ; • . . - : • •
. . ^ . • - : : ;
•••:-.;i-v
.:.::».;.:: ND ND
—
ND NO UD 0 . D 2 3 O . O U 0 . 0 1 2
.HO 0 . 0 2 2 no NO. . ND . . NO NO. 0 . 0 1 8 . ND •
ND ND
•ND' . 0 . 0 7 0 0 . 0 1 4 «D . . . •
ND ND 0 . 0 1 2 ND
ND . • . . . - : . : . - . :
i - W i f l i : . . . . - - ^ • . . • . . . .
: . . . : . . : . . •
s m , S i \
; i l & : : : -
smms . - • j ^ ^ - : .
..^.^,.„..,
.Sm' :t ND ND ND ND
imx::s. ssi-issm i : . . , ^ . •.:.•.;.•:
• • m m i : i
m • ND 0 . 0 1 ND
ND 0 . 1 8 0 . 2 B
. 0 . 4 3 0 . 1 5 0 . 1 5 2 . 3
. 0 . 0 2 8 . 0 . 1 8 1
ND 0 . 0 9 0 D . 0 2 . ND S . 1 9 6 ND
— ND ND 0 . 1 3 .
. 0 . 3 5 0 . 1 0 . 0 . 2 4 0 . 0 8 3 ND ND ND ND
0 . 0 0 4 ND 0 . 0 5 2 NO ND ND NO 0 . 0 0 3 . 0 . 0 0 2 7
0 . 0 0 7 : ND NO NO . ND •
— ND 0 . 0 0 7 . . . •
0 . 0 0 6 ND 0 . 0 0 6 3 0 . 0 0 2 8 NO NO ND 0 . 0 0 6
ND 1.31' 1 . 4 0 . 4 5 0 . 2 5 0 . 2 5 0 . 9 9 0 . 0 3 5 0 . 0 3 0 W)
w> NO
m NO . ND
ND ND HE) 0 . 0 2 5 M) W) 0 . 0 0 4 ND ND ND ND
ND • :W)-.-::k):; ••;•
• • • • i a ) ;.:;..:.•;
insy:sm • : : iB i : :m
i-Mo^m. i i t e ^ i s i
• N O . ' "
: • . . ! - . - - -•::!
- W X ' i S i :
i i imm:: : ; : : IS ) : : : ;;:•.••;
S'HDss,: NO
ND ND
r:.-.r-:!:••:•
;..;W):::;:::.'^
•!.:m>\Sm ' • . i © •••••••••;:
: : . . . : r : y :
NO ND NO ND
ND ..:.:. . . . ' . ; i - i : i - i i asm i Z:::^i--Z^
•;:.: . , • : : ; ; • . ; : : . : • ,
: : : ;^*NO:.: i . : : . : :
s-iuoims • 0 : 0 1 3 ! i : sms-> : i
• : : : • • . : : : . . - - • . • ' i -
: : ; • • ; • : : : : : . . * - : . . . ; : :
.:.:.::;.;-::..;;..:: Sisioitazi ND
ND ND
' ::...-Tr.. ';•;:: i : : - : :m. - i iS .
S S i m ^ s ND
NO NO NO
ND ..:ND : .:.:ND .:
::;:UD : :.:.:ND....f ntB)....; : : • • : : • . • - . ; : ; ; :
; • ; N O ••:•••
Sua a. - T - ; . :
sw- i urns -:.-:•''-li..
:: 'm>Si ND
— — —
:.:.iiOS:r
V^NO;::.
• • : . - - . .
ND ND
ND •••: - . :
:.:;.N0:.:-..: :ND;:; .
:::ilD:. ••; :.:..ND:.:;:. . ; . : : « ) • : . • ; : :
• i m •
: . . . ] ip i
m m . ; "»ID?F
.::::ND..:
u M i i , NO
—
• . i . r . i i ^
:*:NO;:.
: : : . N D . :
' W ) i
ND ND
— —
ND
—
,,,. ^~
— . *--,.-r - "
ND
— — — — -.* *.-— • - -
ND ND
—
ND ... • • . • • .
O . O W : . • . • • - - - . : . . . . .
-.::•:: : • : . . : • •
• i - ^ r r T .. .• •
: : ; : « o ::::••:•••;;•
;r;^0i019::-: . H D .••-.•:•
. . . - . . : : : ; : • : : ; :
• • : - - T r r Z - Z
• - " r T Z Z
NO •
— — —
• • • - . • ' - Z z .
• • , • - • - : : : : • . : , . - ,
0 . 0 2 8 . : NO ND
— —
ND -r'~
...
...
...
... ---. ... ... ... 0 . 0 2
— 0 . 0 4 0 . 0 3
...
... — ... 0 . 0 1
0 . 0 2 0 . 0 2 ND
0 . 1 9 0 W 0 . 0 4 S tffi . K> • ND m • ' 0 . 0 1 9 0 , 0 1 2 W) .• 0 , 0 3 5 K> 0 . 0 2 4 K ) . 0 . 3 9 4
— 0 . 2 2 1 0 . 1 2 8
ND 0 . 0 3 5
m 0 . 1 3
0 . 3 5 9 0 . 2 0 4 0 . 3 0 6 0 . 2 8 6
D « Sample ob
d u p c D u p l i c a t e
A l • A l u n i m m
Sb « A n t i m o n y As » A r s e n i c B« • B a r i u n Be « B e r y l l i u n
B « B o r o n Cd > C a i l i i i u i i Cr » C h r o m i u n
a i n e d
sample
d u r i n g w e l l d e v e
Co = C o b a l t
Cu s Copper CN ' C y a n i d e Fe = I r o n Pb = Lead Mn • Hanganese Hg B H e r c u r y Ni « N i c k e l
opment
Se
Ag T l Sn
V Zn ND
...
= = E
S
S
K
E
K
S e l e n i u n
S i l v e r T h a l l i u n T i n V a n a d i u n Z i n c None d e t e c t e d Not a n a l y z e d
Except for h i g h l i g h t e d samples, samples analyzed by Ana ly t i ca l Technologies, I n c . , Tempe, Ar izona.
GrciundMiter t w p t e not obta ined by E r ro l 1.. Hontsonery t Associates, i n c . 19a2:«nd 1984 M«!ple obta ined by A r i i o rw Department o f HeaUh Serv ice* . 19B3:«aiipl«: pbt«liD«1 by Ecology and Environment, Inc .
WELL IDENTIFIER^
MW-IUA D HW-lUA MW-IUA MW-IUA MW-IUA MW-IUA dup MW-IUA MW-1UA (dup MW-IUA HW-1UA dup MW-IUA MW-IUA MW-IUA dup HW-1UB D MW-IUB MW-1UB HW-IUB MW-IUB MW-1UB HW-IUB MW-1UB MW-2UA D MW-2UA MW-2UA HW-2UA dup MW-2UA HW-2UA HW-2UA MW-2UA HW-2UA HW-2UB D MW-2UB HW-2UB HW-2UB MW-2UB HW-2UB MW-2UB MW-2UB MW-3UA D MW-3UA MW-3UA MW-3UA MW-3UA MW-3UA HU-3UA HW-3UA
SAHPLE FIELD
014378 014412 006084 006099 006177 006178 006375 006376 006569 006570 006758 010799 010800 014383 014425 006086 006171 006360 006552 006739 010781 014382 014421 006088 006089 006164 006363 006554 006740 010788 014379 014414 006087 006174 006362 006553 006741 010787 014387 014413 006091 006165 006364 006556 006742 010789
IDENTIFIER LAB
16208 806006-01 809086-15 809133-15 812527-14 812527-15 908706-06 908706-07 003588-02 003588-03 006599-11 103882-17 103882-18 804087-01 806096-01 809133-02 812527-08 908692-01 003557-02 006576-02 103882-01 804069-01 806047-01 809133-04 809133-05 812527-01 908692-03 003557-04 006576-03 103882-07 804029-01 806006-03 809133-03 812527-11 908692-02 003557-03 006576-04 103882-06 805024-01 806006-02 809133-07 802527-02 908692-04 003557-06 006576-05 103882-08
TABLE 5. SUMHARY OF LABORATORY
DATE SAHPLED
04-08-88 05-31-88 09-14-88 09-20-88 12-06-88 12-06-88 08-24-89 08-24-89 03-08-90 03-08-90 06-07-90 03-22-91 03-22-91 04-27-88 06-14-88 09-20-88 12-06-88 08-23-89 03-06-90 06-06-90 03-20-91 04-25-88 06-09-88 09-20-88 09-20-88 12-05-88 08-23-89 03-06-90 06-06-90 03-21-91 04-18-88 06-01-88 09-20-88 12-06-88 08-23-89 03-06-90 06-06-90 03-21-91 05-05-88 06-01-88 09-20-88 12-05-88 08-23-89 03-06-90 06-06-90 03-21-91
DATE ANALYZED
04-21-88 06-03-88 09-22-88 09-29-88 12-16-88 12-15-88 08-30-89 08-29-89 03-15-90 03-15-90 06-13-90 04-04-91 04-04-91 05-02-88 06-27-88 09-28-88 12-14-88 08-28-89 03-12-90 06-08-90 04-02-91 05-02-88 06-15-88 09-28-88 09-28-88 12-13-88 08-28-89 03-13-90 06-08-90 04-03-91 04-23-88 06-03-88 09-28-88 12-15-88 08-29-89 03-13-90 06-08-90 04-03-91 05-16-88 06-03-88 09-28-88 12-13-88 08-28-89 03-13-90 06-08-90 04-03-91
CHEMICAL RESULTS FOR IN GROUNDWATER SAHPLES
HASSAYAMPA LANDFILL
EPA METHOD
624 624 601 624 624 624
601/602 601/602 601/602 601/602 601/602 601/602 601/602 624 624 624 624
601/602 601/602 601/602 601/602 624 624 624 624 624
601/602 601/602 601/602 601/602 624 624 624 624
601/602 601/602 601/602 601/602 624 624 624 624
601/602 601/602 601/602 601/602
DCM
ND 14 ND 6 11 18 47 3.4 6.0 4.9 4.8 3.6 3,0 10 ND ND 15 2.2 ND 2.0 2.0 8 5 ND ND NO 2.2 ND 2.2 ND 14 10 5 ND ND ND ND ND 14 9 ND ND 2.1 ND 2.1 ND
RT
RFT RT RT F R RT RT RT RFT RFT R
RT R
RT RFT RT RT
R
RT
R RT RFT
R RT
R
RT
FROM , HARICOPA
DHK
19 R ND — ND NO ND — — — ... — — — ND ND ND ND — — — — ND ND ND ND ND — ... — — 18 R ND ND ND — — — ... ND ND ND ND ... — — ...
ND
VOLATILE HONITOR WELLS COUNTY
-DCE
11 15.5 16 111 127 547 380
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
10 40 99 56 40
, ARIZONA
ORGANIC :OMPOUNDS
VOLATILE ORGANIC
i.i-DCA
ND 2 1.3 ND 5 8 30 19.3 7.2 7.5 14.9 17.9 18.5 ND ND ND ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
COMPOUNDS'' (microaram.<: m r litprl
MEK
ND ND — NO 31 FT 39 FT — — — ... — — — ND ND 22 T 24 FT — — — — ND ND 57 T 23 T ND — ... — — ND ND ND 34 FT — — — ... ND ND ND ND ... — — ...
TCA
ND 3 0
ND 9 11 25 22 6 6. 13 6 7
ND ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
9
7 9 8 0 7 8
HB
ND ND — 3 2 3 ND ND ND ND ND ND 8.3 ND 1 3 1 ND ND ND ND ND ND 4 ND ND ND ND ND 2.5 ND ND 2 3 ND ND ND 1.1 ND ND 2 NO NO ND ND 1.1
RFT F F
FT
RFT F
RFT
FT
RFT F
FT
RFT
FT
* ^ i ^ ^ . ^
TCE
ND ND ND ND ND ND ND ND ND ND 0.3 ND 0.2 ND ND ND ND ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO ND
' % \
OTHER CONSTITUENTS
NO ND ND ND DMB 2 T ND ND ND ND 1,2-DCE 0.6 1,2-DCE 1.1 DCDFH=0.3 DCDFH=0.4: 1.2-DCA=0 HBK Tr ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
i
TABLE 5. SUMHARY OF LABORATORY CHEHICAL RESULTS FOR VOLATILE ORGANIC COMPOUNDS IN GROUNDWATER SAHPLES FROH MONITOR WELLS HASSAYAHPA LANDFILL, MARICOPA COUNTY. ARIZONA
VOLATILE ORGANIC COHPOUNDS WE
IDENT
MW-3UB HW-3UB HW-3UB MW-3UB HW-3UB MW-3UB HW-3UB HW-3UB HW-4UA HW-4UA MW-4UA MW-4UA HW-4UA MW-4UA MW-4UA MW-4UA HW-4UA MW-4UA HW-4UA MW-4UB MW-4UB HW-4UB HW-4UB MW-4UB MW-4UB MW-4UB HW-4UB HW-4UB HW-4UB MW-5UA HW-5UA HW-5UA HW-5UA HW-5UA HW-5UA MW-5UA HW-5UA HW-5UA MW-5UA MW-5UA MW-5UA MW-5UA MW-5UA
LL IFIER^
D
D
dup
dup D
duD D D,dup
dup
dup
dup
dup
SAHPLE FIELD
014384 014426 006090 006175 006365 006555 006743 010790 014391 014427 006093 006094 006166 006373 006558 006746 010792 010909 010910 014399 014428 ,006092 006176 006374 006557 006745 010793 010907 010908 014406 014407 014430 014431 006076 006098 006167 006168 006367 006368 006563 006757 010796 010797
IDENTIFIER LAB
805010-01 806096-02 809133-06 812527-12 908692-05 003557-05 006576-06 103882-09 805060-01 806130-01 809133-09 809133-10 812527-03 908706-04 003557-08 006576-09 103882-11 105704-09 105704-10 805105-01 806170-01 809133-08 812527-13 908706-05 003557-07 006576-08 103882-12 105704-07 105704-08 805139-01 805139-02 807002-02 807002-03 809086-07 809133-14 812527-04 812527-05 908692-07 908692-08 003572-04 006599-10 103882-14 103882-15
DATE SAMPLED
04-29-88 06-16-88 09-20-88 12-06-88 08-23-89 03-06-90 06-06-90 03-21-91 05-13-88 06-22-88 09-20-88 09-20-88 12-05-88 08-24-89 03-06-90 06-06-90 03-21-91 05-13-91 05-13-91 05-19-88 06-28-88 09-20-88 12-06-88 08-24-89 03-06-90 06-06-90 03-21-91 05-13-91 05-13-91 05-26-88 05-26-88 06-30-88 06-30-88 09-13-88 09-20-88 12-05-88 12-05-88 08-23-89 08-23-89 03-07-90 06-07-90 03-22-91 03-22-91
DATE ANALYZED
05-02-88 06-27-88 09-28-88 12-15-88 08-28-89 03-13-90 06-08-90 04-03-91 05-17-88 06-29-88 09-28-88 09-29-88 12-13-88 08-30-89 03-14-90 06-09-90 04-03-91 05-22-91 05-22-91 05-27-88 07-02-88 09-28-88 12-15-88 08-29-89 03-13-90 06-11-90 04-03-91 05-22-91 05-22-91 05-27-88 05-27-88 07-13-88 07-13-88 10-12-88 09-29-88 12-13-88 12-13-88 08-28-89 08-29-89 03-13-90 06-13-90 04-04-91 04-04-91
EPA HETHOO
624 624 624 624
601/602 601/602 601/602 601/602 624 624 624 624 624
601/602 601/602 601/602 601/602 601/602 601/602 624 624 624 624
601/602 601/602 601/602 601/602 601/602 601/602 624 624 624 624 601 624 624 624
601/602 601/602 601/602 601/602 601/602 601/602
DCM
ND ND ND 6 ND NO ND 2.5 9 ND ND ND 7 ND ND ND ND ND ND 11 ND ND 8 ND ND ND 3.5 ND ND 10 ND ND ND ND NO ND 10 ND NO ND ND ND ND
RT
RFT R
RT
RT
RT
RFT
RT
RT
DHK
ND ND ND ND — — — — ND NO ND ND ND — — — — — — 10 R ND ND ND — — — ... — — ND ND ND ND — ND ND ND — ... — ... — ...
" i i i - D C E "
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.3 0.4 ND ND ND ND ND ND ND ND ND ND ND ND ND ND
0.3 ND ND ND ND ND
0.9 1.8 0.7 0.9
"V,\
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO ND ND ND ND ND ND
...(micrograms •DCA MEK
ND ND ND 32 FT — — — — ND ND ND ND 36 FT — — — — — — NO ND ND 24 FT — — — ... — — ND ND ND ND — ND 12 FT 22 FT — ... — ... — ...
per TCA
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO ND ND ND ND ND ND
liter).. ME
ND ND 2 2 ND ND ND 6.1 ND ND 2 2 NO NO ND ND 0.9 0.7 0.6 ND ND 2 2 ND ND ND 14.8 ND ND ND ND ND ND — ND ND ND ND ND ND ND 18.2 ND
RFT F
FT
RFT RFT
FT F F
RFT F
FT
FT
'"TCE"
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO NO ND ND ND NO ND ND ND 0.3 ND ND ND ND ND ND ND ND ND ND NO ND ND 0.2 0.2 ND
OTHER CONSTITUENTS
ND ND ND ND ND ND ND ND ND ND ND ND ND ND TCTFA 0.6 T ND TCTFA=15.9 TCTFA=28; CM=0.9 TCTFA=27 ND ND ND ND ND ND ND ND BENZENE=0.5 F ND ND ND 1,2-DCE 10 ND ND ND NO ND TCTFA 1.4 TCTFA 1.7 TCTFA 2.1 T ND 1,2-DCA=0.2; TCTFA=2.0 TCTFA=5.0
TABLE 5. SUMMARY OF LABORATORY CHEHICAL RESULTS FOR VOLATILE ORGANIC COHPOUNDS IN GROUNDWATER SAMPLES FROM HONITOR WELLS HASSAYAMPA LANDFILL, HARICOPA COUNTY, ARIZONA
WELL IDENTIFIER^
SAHPLE IDENTIFIER FIELD LAB
DATE SAMPLED
OATE ANALYZED
EPA HETHOD DCH DHK 1.1-DCE 1.1-DCA
VOLATILE ORGANIC COHPOUNDS .(microgranis per liter)...
HEK TCA HB TCE OTHER CONSTITUENTS
HW-6UA m'im rtu-6iJA HW-6UA HW-6UA HW-6UA dup MW-6UA
MW-6UA dup
HW-6UA
HW-6UA
004316 HASS-A 004323 004325 004330 004331 006560
911752-01 911768-01 <iiifm-o:ii 911782-05 912546-01 912546-02 003572-01
11-22-89
Mamm\ i1-2i3-89 11-28-89 12-05-89 12-05-89 03-07-90
12-01-89
aiiomim 1: 1-01-89 11-29-89 12-06-89 12-06-89 03-13-90
601/602 601/602 WilM: 601/602 624 624
601/602
006561 003572-02 03-07-90 03-13-90 601/602
006754 006599-08
010794 103882-13
06-07-90
03-21-91
06-13-90 601/602
2,4 R
\iii6aami
ND ND ND 5.3 RT
5.7 RT
4.4 RT
ND
ND ND
04-03-91 601/602 2.5 RFT
Ocm ND
3 3
140
140
266
212
ND am w ND ND ND 2.4
1.9
5,0
12.6
ND ND
7.9 T ND
15,4
20,7
ND
2.6 FT
2.5
5.0
11,1
ND
mmmm ND ND ND ND
7.4 T
4 ,5 T
•mimimm 0 .6 ND ND ND ND
0 .4 &:;sNB|:*;:g
0 .3-ND ND ND
2 .5
ND
mmm PCB 0 ND TCTFA TCTFA
TCTFA
:2;"ttffA-5:v-t
6 7
TCTFA 180 T; TCFH 4.4; PCE 1.0; 1,2-DCP 0.2 TCTFA 130 T; TCFH 3,9; PCE 1,2 1,2-DCE 1.2; PCE 2,1; TCFH 6.5; TCTFA 359 TCFM=4,8; TCTFA=133; 1.2-DCP=1,0: PCE=4.1
MW-6UB 0
HW-6UB
010876 104730-02 04-17-91 04-18-91 601/602
010883 104835-02 04 - 23-91 05 - 03-91 624
ND
ND ND
ND
ND
ND
ND ND
ND
ND
6,6
ND
ND
ND
1,2-DCA=0,2; TCTFA=2,1 RT ND
MW-7UA 0 HW-7UA HW-7UA HW-niA : .;. HW-TUA HW-7UA MW-7UA HW-8UA D HW-8UA HW-8UA dup HW-8UA HW-8UA HW-8UA dup MW-8UA HW-8UA HW-8UA duD
004333 004391 004392
: ; «W-?UA 006562 006756 010798 004335 004395 004397 006564 006752 006753 010782 101902 010903
912583-01 002577-01 002577-02 19186 ••-003572-03 006599-09 103882-16 912583-03 002577-05 002577-06 003572-05 006599-06 006599-07 103882-02 105704-02 105704-03
12-07-89 02-07-90 02-07-90 oa- 'Oy-M 03-07-90 06-07-90 03-22-91 12-08-89 02-08-90 02-08-90 03-07-90 06-07-90 06-07-90 03-20-91 05-13-91 05-13-91
12-20-89 02-16-90 02-16-90 02 -14 -90 03-13-90 06-13-90 04-04-91 12-20-89 02-16-90 02-17-90 03 -14 -90 06-13-90 06 -13 -90 04 -02 -91 05-22-91 05-23-91
601 /602 624 624
601 /602 601 /602 601 /602 601 /602 601 /602
624 624
601 /602 601 /602 601 /602 601 /602 601 /602 601 /602
ND ND ND
mmmmmm ND
ND NO ND ND ND ND ND ND 2 , 4 RFT ND ND
ND ND ND
;:;:::;:;;i^:t:+<;:x:;
ND ND ND —
. . .
— . . .
NO ND ND
aammm ND ND ND ND NO ND ND ND ND ND ND ND
ND ND ND
mmmmmm ND
ND ND ND ND ND ND ND ND ND ND ND
NO ND ND
mmmmm - : : — — NO ND ND — — . . .
. . .
ND ND ND
mmmm • . • . . . - . . . . ^ . . . . . . . . . . . . • .
ND NO ND ND ND ND
0 , 7 ND ND ND ND
ND ND 1 RFT
mmmmmm ND ND 2 ,8 FT 0 , 7 T 2 RFT 1 RFT ND ND ND ND ND ND
ND ND ND
amam • • • • - W " " "
NO ND ND ND ND ND ND ND
1.7 ND ND
ND ND ND
miitcmmmmmmmmiimmmmm .......™............................................
ND ND ND TCTFA 1 T ND ND ND ND ND ND ND
HW-9UA D HW-9UA HW-9UB D MW-9UB HW-IOUA D MW-IOUA HW-IOUB D HW-IOUB
014751 004457 014749 014758 014753 004461 014757 004464
104861-01 105644-01 104737-01 105570-01 104890-01 105723-01 105548-03 105873-02
04-25-91 05-07-91 04-17-91 05-02-91 04-29-91 05-14-91 05-02-91 05-22-91
05 -07 -91 05-20-91 04-26-91 05 -15 -91 05 -09 -91 05 -25 -9 0 5 - 1 2 - 9 06 -02 -91
601 /602 624
601 /602 601 /602 601 /602
624 601 /602
624
ND
ND ND ND ND
ND ND
ND
ND
ND
ND
ND ND
ND ND ND
ND ND
ND
ND ND ND
ND ND
ND ND ND
ND
: : :
ND
ND
ND
ND
ND
ND ND ND NO
ND
0,5 ND ND
ND ND
ND ND
ND
ND
NO ND
ND
ND ND
ND ND
1,2-DCA=0.5 ND 1,2-DCA=0.4 ND 1,2-DCA=0.6 T ND 1,2-DCA=0,8 ND
TABLE 5, SUHMARY OF LABORATORY CHEHICAL RESULTS FOR VOLATILE ORGANIC COHPOUNDS IN GROUNDWATER SAHPLES FROM HONITOR WELLS HASSAYAMPA LANDFILL, HARICOPA COUNTY, ARIZONA
WELL
IOE»
H S - 1
HS-^1
HS-^I
H$-1
H 5 ' 1
H S - 1
H $ - 1
H S - 1
H ^ ' l .
H S - 1
HS-1
HS-1
HS-i;'.' HS-2 HS-2 HS:-2 h$*2 HS-2 HS-2 HS-2 HS-2 HS-2 HS-2 HS-2 HS-2 HS-2 HS-5 H$-3 HS-3 HS-J HS-5.. HS-3 HS-3 HS-3
JTIFIER^
SsiiffiSSi;:;:;:;:;:;:;:;
illill i i i i i i i i i .
iiiiiiiiii^:
;:;:;|:;:;:;:::;::::;;:;::;;::S;
; : ; : ; : ; i ; : : : ; : ; : ; ; . : ; : : : ; :o:-;;:o:
dup
; : ; ; ; ; : : : • ; ; ; : ; : : : : : ; : : ; : : : : : : : ; ; : : ; :
;;;;|:;;|:;;|;;;:|;:::;:| ::;:::::::::: :;::i:::::::::? I:;:;:;::;::;:::;;:::;::::;::;:;:;;;:
:;:;:::::;:;:::;:::;:;:;:;:;:::;:|: • • • • • • • • • ' • • • • ' • • • ' " • ' • • • • • • • • '
dup
ssHsg ;S :sss :s " : | | ; ; | : : | H | | | :
;:::::;:;:;:;:;;;:;:;:;:;: i;;:::;: i: i:
:||;;;;||;:|::;;;:|; ::::::::::::::;:::::::;:::;:::::::::::
SAHPLE FIELD
mmmm iziZ:ZZ^^iyZZAz:^
iiiiii
IDENTIFIER LAB
;;i;::o:;:;:;:;:o;;:;:;:;:;:;:;:;;;:;.;.;;;:;;
:;:::;:;:;:;;::::;:::|:i;::o::;|:;:::;:::; ^^
iiiiiiiiiii WMmmhmammmm m M M
iiiiiii IIIIIIII
I S i M i liiiiiii: i:iii::::::::l:i:::::
'""Mii^oiif 014409
014410
: -YH06: . :. Y 1 7 H ' : . i r235r : ;.Y4i6a
004018 004018 006095 006173 006372 006565 006750 006751 010784
; : : * U 0 7 -: Y171S ^
.^:^Y23?3.-: : : ,Y4t67
004016 ' 006097 006170
ii;iii:;::::i:i:ii:::
iii:i:|:i::::ii:ii :::::::::::::::::::;::::::::::::::::::::::::::::: i:;:;ii;;:;:;:;:;:::;:i::;:;:;:::;::>;::::::;:::
IIIIIIII; *'''mPf'" 805139-04
805139-05
• : . : - : . : . : . : ^ : . : . : - ; . : . : . : - : - : - : : : ^ ! : : - : > . . . : . : - :
|::|;:;:|||;|;:;:;:|;:;:;:| ;:::;:::::|::;;;:;;;:;8:::::;::S:;:;|:
mmmsi mmmii "'' 3 0 4 ^ 1 " ' ' 8770790-01 809133-11 812527-10 908706-03 003572-06 006599-04 006599-05 103882-03
mmmmmmmm aaaaaaaaaam :::;:::::::::::;::::::::::::::::::::::::: : • ; • : • ; • : • : • : : : • ; • : • • • : • ; • : : : > • : • : : : • : • : • : • : > : • •
mrnms^mmm " " " 3 t t 4 ^ - 1 ' ' " " 809133-13 812527-07
DATE SAMPLED
05-13-82
q9.-U>-82^
09-14-82^ 09-14-82
09-H-82.
65-18-85
09*05%. . 0^rQ5-84 04-15.-87:^
^ 07 -15 -87 05-26-88
05-26-88
OS-12-82. 09-14-82^ .D5-ia-83..: ( 3 9 T 0 5 - 8 4
0 4 - 1 5 * 8 7 . . 07-1S-87 07 -15 -87 09-20-88 12-06-88 08-24-89 03 -07 -90 06-07-90 06-07-90 03-21-91
; 05 -12 -82 09-14-62 .
. 05-18rf t5: 09-05 -84 04 -15 -87 07 -15 -87 09-20-88 12-05-88
DATE
ANALYZED
am mii
II : : : : : : ! : ; : : • : : :
' ' '07 05
05
am ill:
: ; : : : ; : ; : • : : : ; : : : : : : : ; : ; : : ; ; :
:liliil :;::x.::::':;:|:;:;:i:;:;:;
iiiiiiiiii ::iiiiiii:
iiiiii::iii ':v:::::::::;i;:;:;:;;;:::;:
*::::::::::;:::::::::::::::: - iPW •27-88
•27-88
S:H:;:S;:;:;:;:::H:;
aaaaaaa liiiiiii ig;;:;:;:;:;:;:;:;:::;:::
l§:|:;:|;:;:|; ' '07-1iS-8/''
07 09 12 08 03 06 06 04
|;:;:;;;:;:;:
" 07 -09-12-
•20-87 29-88 15-88 29-89 14-90 13-90 12-90 03-91 m m m m mmim-iiSi
mmmmiii
fpgf" 29-88 14-88
EPA METHOD
lisiiiiiiii iiiii:iii::iiiiii
iiiiiiiiiiiiiiiii
li:iiiilii::ii
:;:;:;:::;:;:;:;:;:::;:;|;:;:;|;:;;|:
iiiiiiii "''WflWi''
624
624
m:mmmmm aaamaam iiiii iiiiiiiii :::::::::::::::*:;:S:§:J:8:;: :
Wmi&M •6017602 601/602
624 624
601/602 601 /602 601 /602 601/602 601 /602
;S:::;:;:B;S:;::S:;:;:;:::;:;::
l:i:i:|:i:::::|::i:|::i:|:l
Wmmi 6017602
624 624
DCH
•:::;:il:i:i:ill:::| smmismmmi
Iiiiiiiiiiiiiii:
iiiiiiiiiiii llllllllli 11111111 iiiiiiiiiiiiiii
i:iiiiiiliiiil:iilii iiiiiiilil:::iii l l l l l l :::::::j|g:;:::::::::::,.::::,::::::
ND
ND
mmmmmm mmmmm a m m m m . amamam amaamam .-..... jj................................
NO ND ND ND ND ND ND 2 , 4 RFT
mmmmmm l:|:i:8l::i:::::::::::::i amaaaaaaa a^ immmm amaaaaaaa m
5 RFT
15 RT
DHK
ii:i|i:iii|iiil
iiiiiiiiiii WiMaa :;iili?ii
iiiiiiiiii Iilll iiiiiiiiii mmm
III • " • - • ' • - • - • • • ' • '
NO
ND
mimm amm mi imm Iiiiiiiiii :|:|;;:;iji;ii:i;|:;:|;;
' • • " ' • - " - • - • • • ' • ' •
ND ND
— — — . . . —
mmm amm amm mmm aamm ' • • • ' • ' - • - - • • ' • • • • •
NO ND
l . i -DCE
| i : i | | : | | |
iiiiiiiiiiiiiiiiii
llli::iil::iiliiiii: iiiiiiiiiiiiiiil
iiiiiiiiiiiiiiiiii
iiiiiiiiiiiiiiiiii
iiiiiiiiiiiiiiiiiiiii ll:i:|:iPs::|:::i:|:;:;:
iiiiiiiiiiiiiii
:::::::¥:«:j|:™:;:;:;::::::::
910
830
mimmmmm aamammm mamaaam mmmmmm i::::Hel:::::::::::::::?:::::i:l .:.:.:.:.:.:.:...:.:.:.:.ij:. .:.:.
ND ND ND ND ND ND ND ND
rnHmmmm mjiMmmm :|:|:|:::fift:::i:i:i:i:i:i:i::: i:::Hel:i::::i::::i immiiiiiiamm .:.:.:.:. «:.:.:.:.:...:.:.:...:.:.:.
ND ND
"*i,"i-"
iiiiiii
iiiiiiiiii i:i1li3:ii
l l l l
illii iiiiiii
iiiiiii i:lil*::i i:;i:iNii
20
21
mtmrn aMm mmm amm mima W ' ND ND ND ND ND ND ND ND ND:-:-ND:;.
. ND:.
. MD HD: ND ND ND
VOLATILE ORGANIC COMPOUNDS"
, , ( m i c r o g r a m s oer l i t e r ) DCA HEK
Iiiiiiiiiiiiiiiiii
iiiiiiiiiiiiiiiiiiii l:illii|:iiiiiliiiil iiiiiiiiiiiiiiiiii:!
iiiiiiiiiiiiiiiiiiiii
iiiii|iii||ii|i
iiii:i:iliil:lli:iii :||il|:l|il:|;
• ' • ' • ' • " • ' • ' ' ' • ' • • ' • ' • - • ' - ' • - • ' • ' • ' •
ND
ND
mmmmmm aaammiama mmaamaa Wmmna •mmmii*m'*m " ' ' • • • • • • • • • • • • • • • • • • - - " - • " • • • " •
— NO 26 FT
— — — . . . —
mmmmwDmm a a m m m m maammma mammmm mimmimmm ' • • • • • • • • • • • • • • • • • • • ' • • - - • - • • • • • •
NO ND
TCA
i:iiiiiiilii|i|i:i
iiiiiiiiiiii ii;^^il:iilli^ iiiiiliiiiiiliii
iiiiiiiiiii iiiiiiiiiiiii liiiiiiQSiiiiiii ::l|::i^:::i:iii: :|||i::l;;|l|l:; :;:::::::™::™«¥: ::l
150
170
mmiummm mamam mmtitmm mgmmm aaamam • " • • " • " • N D " ' ' ' ' " " ' ' '
ND ND ND ND ND ND ND ND
mmimimm iil:iNi:::::i:i:::i: ammmm :iiihBil:i::i:i:i: l:|:il.HR:|:|:::i::i:|:: '""""""Nb"""""""""
ND ND
HB
iii:i|i|ii:iiiiiiiiiiii
iiiiiiiiiiiiiii liiiiiiiii:i:::ii ili:iiliiii:;i
iiiiiiiiiiiiiiil
iiiiiiiiiiiiiii
:li:liiiliil:ii:i^ ::::::;:Ne:::::::::;:::::::;::|::; iiiiiiiiiiiii
""W""'' ND
NO
mjiimmm mmmmm ::::;::*ieiii::i aamamm aamoaam """'lio'"""""""'""""
NO 2 RFT
ND ND ND ND ND 1 . 0 FT
mmmimm mmmmm a m m m m a m m m m ammmmm ' " •Nt i " ' " " " " ' " " "
2 RFT
ND
" T C E "
ii:liiiii:i:|:i
iiiiiiiiiiii :|::i:iHii:i::: ::|:::|Ni:i:ii
iiiiiiiiiiii
iiiiiiiiii
iiiiiiiiiiiiii aamaa mam
'"" '8:4 '" 46
52
sisNB:;::::;::::::
a a m m mmmm aamm a a m m """""i>iD"'""'""'
ND ND ND ND ND ND ND ND
issNe::;;:?:;:;; :::i;:N»::::::::::::: l:i:|:|:|:i<e:iii ::::::::::Nii:i::::::: i:|:|::Hi::li::: """""NO""""'""
NO NO
OTHER CONSTITUENTS
. TCFM T r ; PCTFA**f TCTFA** TCF« 75 ; TCTFA** F; OCT FA**:.... •
•TCFH..95 •::.•••• TCFH 190;.TCTFA** F;
.".DCTFA** ' ••• TCFH:5? TCTFA**F;
• OCTFA** • TCFH 32 TCTFA 610* * ; - . :STy Tr F; f>CE T r ; •1v3^DH8 Tl*
:.PCE 25 . . •• •• •••pCE-25' " • :.PCE 22;:^1^2-PCA 80O;
i ,2-DCE 160; DBCH 4 4 j CB 15; T ^ A : PC6 3 , 8 PCE 2 1 ; TCFH 10; TCTFA 500 PCE 23 ; TCFH 2 0 ; TCTFA 600
;-;;:;:^:;:;S::::;;|;;:;::;:::;;;:;:|j ; ; ; ; ; : ; j ^ ; ; ; : | | : | | ; : ; | | ; ; ; ; : : : ; | | ^ ^
:|ij^::|;|| i i l l l l i l l j^ ::::::: ;:;::sss55ss;K;s:::;:;::::::ss liiii::iili;:iii:iii:iiiiiiiiiii:|;:li ••'••••TCTF/f"1'^;'3'"^^^"^^^"^^^"^'^""''^"""""'
ND ND ND ND ND ND ND ND
mifsMimimimmmmimimimmmai aoiiimaaaaaamammaaaaam aai^aaammaimaimmaaaaaa :;;|jfli:||||||;:|||;:i|;||||:|;g:;:;|| ::::?iifli5;:i:::;:;:;:i:;:M:;:;:;:;:;:;:;:i:;:::;:;:s ::.:.:.™,.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:
ND ND
TABLE 5, SUMHARY OF LABORATORY CHEMICAL RESULTS FOR VOLATILE ORGANIC COMPOUNDS IN GROUNDWATER SAHPLES FROM HONITOR WELLS HASSAYAHPA LANDFILL. HARICOPA COUNTY, ARIZONA
WELL IDENTIFIER^
SAHPLE IDENTIFIER FIELD LAB
DATE SAHPLED
DATE ANALYZED
EPA HETHOD DCH DMK 1.1-DCE
VOLATILE ORGANIC COMPOUNDS"
(micrograms per liter),,. 1.1-DCA MEK TCA HB TCE OTHER CONSTITUENTS
HS-3 HS-3 HS-3 HS-3
006370 908706-01 006568 003588-01 006749 006599-03 010786 103882-05
08-24-89 03-08-90 06-07-90 03-21-91
08-29-89 03-15-90 06-12-90 04-03-91
601/602 2 601/602 ND 601/602 ND 601/602 5.1
7 R
RFT
ND ND ND ND
ND ND ND ND
ND ND ND ND
ND ND ND NO ND ND 0.6 FT ND
ND ND NO ND
D = Sample obtained during well development dup = duplicate sample
CB = Chlorobenzene
CH = Chloromethane DBCH = Dibromochloromethane
1,1-DCA = 1,1-Dichloroethane 1,2-DCA = 1,2-Dichloroethane DCDFH = Dichlorodifluoromethane
1,1-DCE = 1,1-Dichloroethene 1,2-DCE = 1,2-Dichloroethene
DCH = Dichloromethane (Hethylene Chloride) 1,2-DCP = 1,2-Dichloropropane DCTFA = Dichiorotrifluoroethane DHB = Dimethylbenzene (Total Xylenes)
1,3-DHB = 1,3-Dimethyl benzene DHK = Dimethylketone (Acetone) HB = Hethylbenzene (Toluene)
HBK = Hethyl butyl ketone (2-Hexanone) MEK = Methyl ethyl ketone (2-Butanone) PCE = Tetrachloroethene
STY = Styrene (Ethenylbenzene) TBH = Tribromomethane TCA = 1,1,1-Trichloroethane TCE = Trichloroethene
TCTFA = Trichlorotrifluoroethane (Freon 113) TCFH = Trichlorofluoromethane (Freon 11) ND = Not detected R = Detected in reagent blank F = Detected in field blank T = Detected in trip blank
— = Constituent not included in method Tr = Trace concentration; positively identified using mass spectrometer,
but detected belou limit of quantitation for EPA method. 624 ** = Tentatively identified; number is tentative concentration
(Arizona Department of Health Services, 1985) * = Hay be invalid or partially invalid due to introduction of
contamination during field sampling or laboratory analysis (Arizona Department of Health Services, 1985)
NOTE: Except for sample identifier 8770790-01 and highlighted samples, all samples uere analyzed by Analytical Technologies, Inc., Phoenix, Arizona, Sample identifier 8770790-01 uas analyzed by Clayton Environmental Consultants, Inc. Pleasonton, California,
:;:;$ii
TABLE 6. SUHHARY OF LABORATORY CHEHICAL RESULTS P R r i l^/I|^|AD\/ FOR VOLATILE ORGANIC COMPOUNDS IN UATER SAMPLES OBTAINED. i l L i y - l m M N A K T
FROH DRILLER'S WATER TRUCK HASSAYAHPA LANDFILL, HARICOPA COUNTY, ARIZONA
SUBJECT TO REVTSTOM
SAHPLE
FIELD
014377
014424
004319
004320
004334
014747
014755
010925''
IDENTIFIER
LAB
16157
806047-02
911752-02
911752-03
912583-02
104696-02
105548-01
105972-02
DATE
SAMPLED
03-28-88
06-10-88
11-22-89
11-22-89
12-07-89
04-11-91
05-01-91
05-30-91
DATE
ANALYZED
04-06-88
06-16-88
11-30-89
11-30-89
12-20-89
04-24-91
05-12-91
06-05-91
EPA HETHOD
624
624
601/602
601/602
624
601/602
601/602
601/602
VOLATILE ORGANIC COMPOUNDS" (micrograms per liter)
ND
ND
HB=4,7 T
HB=0.9 T
ND
TCE=0.3; 1,2-DCA=0.4
1,2-DCA=0.6
ND
ND = None detected MB = Methylbenzene (Toluene) TCE = Trichloroethene
1,2-DCA = 1,2-Dichloroethane T = Detected in trip blank
Buckeye municipal water supply at location where drillers' water uas obtained in 1991
NOTE: Samples analyzed by Analytical Technologies, Inc., Phoenix, Arizona
TABLE 7,
LAB SAHPLE IDENTIFIER
SUHHARY OF LABORATORY CHEHICAL RESULTS FOR VOLATILE ORGANIC COHPOUNDS IN QUALITY CONTROL BLANKS FOR WATER SAMPLES FOR HASSAYAHPA LANDFILL, HARICOPA COUNTY, ARIZONA
SAHPLE TYPE DATE
ANALYZED EPA
HETHOO
VOLATILE ORGANIC COHPOUNDS"
.,,(micrograms per liter)...
DCH DMK HB TCH BDCH DBCH OTHER CONSTITUEferS
3043-04 3043 16208
804029 804069 804069 804087 805010 805024 805060 805060 805105-02 805105 805139-03 805139-06 805139-07 805139 806006-04 806006 806047-03 806047 806096-03 806096 806130-02 806130 806170-02 806170 807002-01 807002-04 807002 809086-16 809086 809086
FIELD BLANK TRIP BLANK REAGENT BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK FIELD BLANK FIELD BLANK TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK FIELD BLANK TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK REAGENT BLANK
07-16-87 07-16-87 04-21-88 04-23-88 05-02-88 05-02-88 05-02-88 05-02-88 05-16-88 05-17-88 05-17-88 05-27-88 05-27-88 05-27-88 05-27-88 05-27-88 05-27-88 06-03-88 06-03-88 06-15-88 06-15-88 06-27-88 06-27-88 06-29-88 06-29-88 07-02-88 07-02-88 07-13-88 07-13-88 07-13-88 09-22-88 09-22-88 10-11-88
601/602 601/602 624 624 624 624 624 624 624 624 624 624 624 624 624 624 624 624 624 624 624 624 624 624 624 624 624 624 624 624 601 601 601
ND ND Tr 14 13 Tr Tr Tr Tr ND Tr 20 15 NO ND 25 15 24 7 13 5 13 5 12 Tr 5
Tr ND NO Tr 10 4,5 3,2
R T
R T
R T R T R T R T R T R T
R T T
—
Tr Tr NO ND ND ND Tr 20 R Tr T ND Tr ND ND ND Tr ND Tr NO 15 ND Tr ND Tr 11 R 15 T ND ND ND
...
ND ND ND ND ND ND ND ND ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND ND ND NO ND 9 ND ND ND ND ND
ND ND ND ND ND ND ND ND ND 7
ND ND ND 9 7
ND ND ND ND ND ND ND Tr ND ND ND ND 1
ND ND ND ND NO
ND ND ND ND ND NO ND ND ND 5 ND ND ND 7 6 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
ND NO NO ND ND ND ND ND ND 3 ND ND ND 4 3 ND NO ND ND ND ND ND ND NO ND ND ND ND ND ND ND ND ND
ND ND EB=1: 0MB=1 ND ND ND ND ND ND ND ND NO ND TBM=Tr ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
809133-01 809133-12 809133-16 809133 809133 812527-06 812527-09 812527-16 812527-17 812527 812527 812527
FIELD BLANK FIELD BLANK TRIP BLANK REAGENT BLANK REAGENT BLANK FIELD BLANK FIELD BLANK TRIP BLANK TRIP BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK
09-28-88 09-29-88 09-28-88 09-28-88 09-29-88 12-14-88 12-15-88 12-13-88 12-14-88 12-13-88 12-14-88 12-15-88
624 624 624 624 624 624 624 624 624 624 624 624
ND 7 6 7 10 ND ND 8 43 Tr 8 7
RT RF FT FT
R R T T T
ND ND ND Tr Tr 21 R ND ND ND Tr F Tr F ND
2 2 2 2 3 2 2 ND ND ND NO NO
RT RT RF FT FT
10 11 ND ND ND ND ND ND ND ND ND ND
8 8 ND ND ND ND ND ND ND ND ND ND
4 4 ND ND ND ND ND ND ND ND ND NO
ND ND ND ND DMB=1 HEK=20 T MEK=25 T HEK=18 F; DHB=2 R HEK=10 F 1,1,2,2-PCA=1; DMB=3 T ND ND
TABLE 7, SUHHARY OF LABORATORY CHEHICAL RESULTS FOR VOLATILE ORGANIC COHPOUNDS IN QUALITY CONTROL BLANKS FOR WATER SAHPLES FOR HASSAYAHPA LANDFILL, HARICOPA COUNTY, ARIZONA
LAB SAHPLE IDENTIFIER
908692-06 908692-09 908692 908692
SAHPLE TYPE
FIELD BLANK TRIP BLANK REAGENT BLANK REAGENT BLANK
DATE ANALYZED
08-08 • 08-08-
28-89 28-89 28-89 29-89
EPA HETHOD
601/602 601/602 601/602 601/602
VOLATILE ORGANIC COMPOUNDS"
(micrograms per liter)...
DCH
2.7 R 7.5 R 8.1 FT 8.5 FT
DHK HB TCH
ND ND ND ND
0.9 ND ND ND
ND ND ND ND
BDCH DBCM
ND ND ND ND
OTHER CONSTITUENTS
ND ND ND ND
908706-02 908706-08 908706 908706
FIELD BLANK TRIP BLANK REAGENT BLANK REAGENT BLANK
08-08-08 • 08^
29-89 29-89 29-89 30-89
601/602 601/602 601/602 601/602
2.8 R ND 8.5 F
ND
ND ND ND ND
0.9 1.0
ND ND
ND ND ND ND
0.9 ND ND ND
ND ND ND ND
911752-04 911752 911752
TRIP BLANK REAGENT BLANK REAGENT BLANK
IV ^ ' [ •
12-
30-89 30-89 01-89
601/602 601/602 601/602
ND 8.5
10,8
2.9 ND ND
NO 0.2 0.3
ND ND ND
ND ND ND
ND ND ND
?11768-02 STRrPSgLANlcaiJ:::
l l l l -
Q1:*89;f::::g:i:i:::60.17602B miii: ima sKo:s tma smui mm 911782-06 911782 911782
TRIP BLANK REAGENT BLANK REAGENT BLANK
01-89" 29-89 30-89
601/602 601/602 601/602
"ND 9.5 8.5
ND^ ND ND
ND NO 0.2
ND ND NO
ND ND ND
TCTFA ND ND
=3.9
912546-03 912546
TRIP BLANK REAGENT BLANK
12-12^
06-89 06-89
624 624
10 8
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
912583-04 912583 912583 912583-04 912583
TRIP BLANK REAGENT BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK
12-20-89 12-19-89 12-20-89 12-20-89 12-19-89
601/602 601/602 601/602 624 624
13.1 R 5.7 T 2.6 T 19 R 6 T
003557-01 003557-09 003557 003557 003557
ND ND
2.2 ND ND Tr ND
0 ND ND ND ND
4 ND ND ND ND ND
ND NO ND ND NO
ND ND ND ND ND
002577-03 002577-04 002577 19187
FIELD BLANK TRIP BLANK REAGENT BLANK TRIP BLANK :
02-16-90 02-17-90 02-16-90 02-14-90
624 624 624
601/602
ND 28 Tr
mmm
RF FT
12 ND Tr --•
R
F
2 1 2
Sssdaj-s:; • • i • , , • •
RT RF FT
ND ND ND NO
ND ND ND
: NO
ND ND ND ND . :
ND TCTFA=1 ND NO
FIELD BLANK TRIP BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK
03-03-03 • 03 • 03-
13-90 12-90 12-90 13-90 14-90
601/602 601/602 601/602 601/602 601/602
NO 5.8 R 4,2 T 2,0 T
ND
NO ND ND ND ND
NO ND ND ND ND
WO ND ND ND ND
NO ND ND ND ND
NO TCTFA ND ND ND
=1.2
003572-07 003572-08 003572 003572 003588-04 003588 006576-07 006576-01 006576 006576
FIELD BLANK TRIP BLANK REAGENT BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK FIELD BLANK TRIP BLANK REAGENT BLANK REAGENT BLANK
03-14-90 03-13-90 03-13-90 03-14-90 03-15-90 03-15-90 06-09-90 06-11-90 06-08-90 06-11-90
601/602 601/602 601/602 601/602 601/602 601/602 601/602 601/602 601/602 601/602
ND 6,7 R 2.0 T ND 6.9 R 2.3 T ND 9,2 R 7,5 T 9.1 T
— — ... — — — ... — — ...
ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND ND NO
ND ND ND ND ND ND NO ND ND ND
ND TCTFA=0,9; 1,1,1-TCA=0,4 ND ND 1,1,1-TCA=0.7 ND ND ND ND ND
006599-01 006599-02 006599 006599 006599
FIELD BLANK TRIP BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK
06-12-90 06-12-90 06-11-90 06-12-90 06-13-90
601/602 601/602 601/602 601/602 601/602
ND 7.9 R 9.1 T 7.6 T 7,1 T
ND ND ND ND ND
ND ND ND ND ND
ND ND ND ND ND
ND ND ND ND ND
ND ND ND ND ND
TABLE 7 . SUMMARY OF LABORATORY CHEHICAL RESULTS FOR VOLATILE ORGANIC COHPOUNDS IN QUALITY CONTROL BLANKS FOR WATER SAHPLES FOR HASSAYAHPA LANDFILL, HARICOPA COUNTY, ARIZONA
105704-01 105704-11
VOLATILE ORGANIC COMPOUNDS" ...(micrograms per liter)...
LAB SAMPLE IDENTIFIER
103882-04 103882-10 103882-19 103882-20 103882-21 103882 103882 103882 103882 103882
SAMPLE TYPE
FIELD BLANK FIELD BLANK TRIP BLANK TRIP BLANK TRIP BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK
DATE ANALYZED
04-03-91 04-03-91 04-09-91 04-09-91 04-10-91 04-02-91 04-03-91 04-04-91 04-09-91 04-10-91
EPA METHOD
601/602 601/602 601/602 601/602 601/602 601/602 601/602 601/602 601/602 601/602
DCH
2.6 RT 15.4 RT 2.6 RF 5.7 RF 2.7 RF 2.3 FT 4.0 FT 10.0 FT 5.8 FT 7.5 FT
DHK HB
1.5 13.6 0, 1, 1,
ND ND ND ND ND
TCH
ND NO ND ND NO NO ND ND ND ND
BDCH
ND ND ND ND ND ND ND ND ND ND
DBCH OTHER CONSTITUENTS
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
104696-01 104696 104730-01 104730 104737-02 104737 104835-01 104835 104861-02 104861 104890-02 104890 105548-02 105548 105570-02 105570 105570 105644-03 105644 105644
TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK REAGENT BLANK
04-24-91 04-24-91 04-18-91 04-18-91 04-26-91 04-25-91 05-03-91 05-03-91 05-07-91 05-07-91 05-10-91 05-09-91 05-12-91 05-11-91 05-16-91 05-15-91 05-16-91 05-18-91 05-17-91 05-20-91
601/602 601/602 601/602 601/602 601/602 601/602 624 624
601/602 601/602 601/602 601/602 601/602 601/602 601/602 601/602 601/602 624 624 624
ND ND 7.3 R 2.6 T 3.0 ND 6 R 8 T 2,7 ND ND ND ND 17,7 ND 2.8 2.3
ND ND ND
—
—
ND ND
: : : —
—
. . .
ND ND ND
ND ND ND ND ND ND ND ND 3.2 ND 1.9
ND 0.8 ND ND ND ND ND ND ND
4.0 ND ND ND 0.7 ND ND ND ND ND 3.7 ND ND ND ND ND ND ND ND ND
3,7 ND ND ND ND NO ND ND ND ND 3,3 ND ND ND ND ND ND ND ND NO
2.3 ND ND ND ND ND ND ND ND ND 2.0 ND ND ND ND ND ND ND ND ND
1,2-DCA=0,6 DHB=1,5,- T-1.3-DCPE=0.2 TCTFA=2.4 R TCTFA=1.6 T ND ND HBK=12; STY=2; DMB=2 ND NO ND 1,2-DCA=0,6 ND ND ND ND ND ND ND ND ND
TRIP BLANK FIELD BLANK
05-22-91 05-23-91
601/602 601/602
2.4 ND
ND 2.5
ND ND
ND ND
ND NO
ND DHB=1.9; EB=0.6
BENZENE=0.6;
105704 105704 105723-02 105723 105873-01 105873 105972-01 105972
REAGENT BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK TRIP BLANK REAGENT BLANK
05-22-91 05-23-91 05-25-91 05-24-91 06-02-91 06-02-91 06-05-91 06-05-91
601/602 601/602 624 624 624 624
601/602 601/602
ND ND ND ND ND ND ND NO
—
ND ND ND ND
ND ND ND ND ND ND ND ND
ND ND ND ND ND ND ND ND
ND ND NO NO ND ND NO ND
ND ND ND ND ND ND ND ND
CE=0.7 CE=1.0 ND ND ND ND ND CE=2,0
TABLE 7, SUHHARY OF LABORATORY CHEHICAL RESULTS FOR VOLATILE ORGANIC COHPOUNDS IN QUALITY CONTROL BLANKS FOR WATER SAHPLES FOR HASSAYAHPA LANDFILL, HARICOPA COUNTY, ARIZONA
^ BDCH = Bromodichloromethane TBH = Tribromomethane (Bromoform)
CE = Chloroethene (Vinyl Chloride) 1,1,1-TCA = 1,1,1-Trichloroethane DBCH = Dibromochloromethane TCH = Trichloromethane (Chloroform) DCH = Dichloromethane (Hethylene Chloride) TCTFA = Trichlorotrifluoroethane (Freon 113)
T-l,3-DCPE = Trans-1,3-Dichloropropene — = Constituent not included in method DHB = Dimethylbenzenes (Total Xylenes) ND = None detected DHK = Dimethylketone (Acetone) Tr = Trace concentration; positively identified using mass spectrometer, EB = Ethenylbenzene (Styrene) but detected belou limit of quantitation for EPA method 624 HB = Hethylbenzene (Toluene) R = Detected in reagent blank HEK = Hethyl ethyl ketone (2-Butanone) T = Detected in trip blank
1,1,2,2-PCA = 1,1,2,2-Tetrachloroethane F = Detected in field blank
NOTE: Sanple.obtainexJ.by Arizona DepartitMnt. of E Quality
Except for lab sample identifier 19187, samples analyzed by Analytical Technologies, Inc, Tempe, Arizona, Lab sample identifier 19187 analyzed at Arizona Department of Health Services State Laboratory, Phoenix, Arizona,
WELL IDENTIFIER^
HW-lUA D HW-lUA HW-lUA HW-IUA HW-lUA dup HW-IUB D HW-IUB HW-IUB HW-IUB
HW-3UA 0
HW-3UA HW-3UA HW-3UA
HW-4UB D
TABLE 8, SUHHARY FOR SEHI-VOLATI HONITOR WELLS
SAHPLE IDENTIFIER FIELD LAB
OF LABORATORY CHEHICAL RESULTS FOR EPA HETHOD 625 LE ORGANIC COHPOUNDS IN GROUNDWATER SAHPLES FROH HASSAYAHPA LANDFILL, HARICOPA COUNTY, ARIZONA
014378 014412 006099 006177 006178
16208 806006-01 809133-15 812527-14 812527-15
DATE SAHPLED
04-08-88 05-31-88 09-20-88 12-06-88 12-06-88
DATE ANALYZED
04-27-88 06-09-88 10-12-88 12-21-88 12-21-88
SEHI-VOLATILE ORGANIC COMPOUNDS (micrograms per liter)
Phenol 18 ND ND Isophorone 11 NO
014383 804087-01 04-27-88 05-11-88 Di-n-butylphthalate Tr 014425 806096-01 06-14-88 07-20-88 *Branched Hydrocarbon 20 006086 809133-02 09-20-88 10-04-88 ND 006171 812527-08 12-06-88 12-20-88 Bis(2-ethylhexyl)phthalate 11 R
HW-2UA D HW-2UA HW-2UA
014382 014421 006088
804069-01 806047-01 809133-04
04-25-88 06-09-88 09-20-88
05-11-88 06-21-88 10-04-88
Di-n-butylphthalate Tr ND Isoporone Tr; *407 Octamethyl Cyclotetrasiloxane 1000; '576 Decamethyl Cyclopientasi loxane 200
HW-2UA dup HW-2UA HW-2UB D HW-2UB HW-2UB HW-2UB
006088 006164 014379 014414 006087 006174
809133-19 812527-01 804029-01 806006-03 809133-03 812527-11
09-20-88 12-05-88 04-18-88 06-01-88 09-20-88 12-06-88
10-13-88 12-20-88 05-04-88 06-09-88 10-04-88 12-20-88
ND ND Bis(2-ethylhexyl)phthalate Tr ND ND ND
014387 805024-01
014413 006091 006165
806006-02 809133-07 812527-02
05-05-88 05-20-88 *Hydrocarbon (C16) 20; •Hydrocarbon (C15) 20
06-01-88 06-09-88 ND 09-20-88 10-04-88 ND 12-05-88 ^12^0-88 ND
HW-3UB D
HW-3UB HW-3UB HW-3UB HW-4UA D
HW-4UA HW-4UA
HW-4UA dup HW-4UA
014384
014426 006090 006175 014391
014427 006093
006093 006166
805010-01
806096-02 809133-06 812527-12 805060-01
806130-01 809133-09
809133-20 812527-03
04-29-88
06-16-88 09-20-88 12-06-88 05-13-88
06-22-88 09-20-88
09-20-88 12-05-88
05-11-88
07-20-88 10-04-88 12-21-88 05-23-88
08-01-88 10-12-88
10-13-88 12-20-88
Di-n-butylphthalate Tr; Bis(2-ethylhexyl)phthalate 13 R ND ND ND Di-n-butylphthalate 10 R; Bis(2-ethylhexyl)phthalate 25 ND N-nitrosodiphenylamine Tr; Phenanthrene Tr; Anthracene Tr ND Bis(2-ethvlhexYl)phthalate 11 R
014399 805105-01 05-19-88 06-02-88
HW-4UB HW-4UB HW-4UB
014428 006092 006176
806170-01 809133-08 812527-13
06-28-88 09-20-88 12-06-88
08-05-88 10-04-88 12-21-88
Bis(2-ethylhexyl)phthalate 42; •Branched Hydrocarbon (C15) 20 •Branched Hydrocarbon (C13) 20 *Branched Hydrocarbon (C15) 20 •Branched Hydrocarbon (C13) 10 ND NO ND
TABLE 8, SUMMARY OF LABORATORY CHEHICAL RESULTS FOR EPA HETHOO 625 FOR SEHI-VOLATILE ORGAMIC COHPOUNDS IN GROUNDWATER SAHPLES FROH HONITOR WELLS, HASSAYAHPA LANDFILL, MARICOPA COUNTY, ARIZONA
WELL IDENTIFIER^
HW-5UA D
HW-5UA D dup
HW-5UA MW-5UA dup HW-5UA HW-5UA HW-5UA dup HW-6UA M«'6UA- ;••„• „ •;, HW-6UB HW-7UA HW-8UA HW-8UA duD HW-9UA HW-9UB MW-IOUA HW-IOUB HS-2 HS-2 HS-3 HS-3
SAHPLE FIELD
014406
014407
014430 014431 006098 006167 006168 004325 HASS-A 010883^ 004392 004395 004397 004457 014758 004461 004464 006095 006173 006097 006170
IDENTIFIER
LAB
805139-01
805139-02
807002-02 807002-03 809133-14 812527-04 812527-05 911782-05
mmmimmm •104835-02
002577-02 002577-05 002577-06 105644-01 105570-01 105723-01 105873-02 809133-11 812527-10 809133-13 812527-07
DATE SAHPLED
05-26-88
05-26-88
06-30-88 06-30-88 09-20-88 12-05-88 12-05-88 11-28-89
mmmmmmi: 04-23-91 02-07-90 02-08-90 02-08-90 05-07-91 05-02-91 05-14-91 05-22-91 09-20-88 12-06-88 09-20-88 12-05-88
DATE ANALYZED
06-08-88
06-08-88
08-05-88 08-05-88 10-12-88 12-20-88 12-20-88 12-06-89
mimai'mB9m 05^^D2-91 02-14-90 02-15-90 02-14-90 05-16-91 05-15-91 05-30-91 06-06-91 10-12-88 12-20-88 10-12-88 12-20-88
SEHI-VOLATILE ORGANIC COHPOUNDS" (microqrams per liter)
Bis(2-ethylhexyl)phthalate 12 R; •Hydrocarbon (C16) 20; •Hydrocarbon (C13) 10 •Branched Hydrocarbon (C13) 10; •Branched Hydrocarbon (C15) 20; •Branched Hydrocarbon (C13) 10 ND ND ND NO ND •Oxygenated Hydrocarbon (C5) 400
ND NO ND ND ND ND ND ND ND ND ND ND
D = Sample obtained during uell development
dup = Duplicate sample
Tr = Trace concentration; positively identified using mass spectrometer,
but detected below limit of quantitation for EPA method 625, ND = Not detected R = Detected in reagent blank
= Additional compounds detected and semi-quantitated
NOTE: Sample ditained.by Arfiona. P«partB>erit of"EnviYonfnental <!kjati?y
Except for laboratory sample identifier 18289, samples analyzed by Analytical Technologies, Inc. Phoenix, Arizona. Laboratory sample identifier 18289 analyzed by Arizona Department of Health Services State Laboratory, Phoenix, Arizona.
LAB SAHPLE IDENTIFIER
TABLE 9. SUHMARY OF LABORATORY CHEHICAL RESULTS FOR EPA HETHOO 625 FOR SEMI-VOLATILE ORGANIC COHPOUNDS IN QUALITY CONTROL BLANKS FOR WATER SAMPLES
FOR HASSAYAHPA LANOFILL, HARICOPA COUNTY, ARIZONA
SAHPLE TYPE DATE
ANALYZED
SEMI-VOLATILE ORGANIC COMPOUNDS" (micrograms per liter)
16208 804029 804069 804087 805010 805024 805060 805105 805139-
805139 806006 806047 806096 806130 806170 807002-807002 809133 809160-809160 809167-809167 812527-812527-812527 911782 002577-002577 104835 105570 105644 105723 105873
03
01
01
01
06 09
03
REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK FIELD BLANK
REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK FIELD BLANK REAGENT BLANK REAGENT BLANK FIELD BLANK REAGENT BLANK FIELO BLANK REAGENT BLANK FIELD BLANK FIELO BLANK REAGENT BLANK REAGENT BLANK FIELD BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK
04-27-88 04-29-88 04-29-88 05-10-88 05-10-88 05-20-88 05-23-88 06-02-88 06-09-88
06-09-88 06-08-88 06-21-88 07-20-88 08-01-88 08-04-88 08-05-88 08-04-88 10-04-88 10-13-88 10-13-88 10-13-88 10-13-88 '2-20-88 12-20-88 12-20-88 2-06-89
02-15-90 02-14-90 05-02-91 05-15-91 05-16-91 05-30-91 06-06-91
Di-n-butvlphthalate Tr; Bis(2-ethvlhexvl)phthalate Tr ND Bis(2-ethylhexvl)phthalate Tr Bis(2-ethvlhexYl)phthalate Tr Bis(2-ethylhexYl)phthalate Tr Bis(2-ethylhexyl)phthalate Tr Di-n-butylphthalate Tr Oi-n-butvlphthalate Tr •Branched Hydrocarbon 400; •Hexamethyt Cyclotrisiloxane 300; •Octamethyl Cyclotetrasiloxane 500; •Decamethyl CycIopentasiloxane 100 Di-n-butvlphthalate Tr: Bis(2-ethvlhexvl)phthalate Tr Di-n-butvtphthalate Tr: Bis(2-ethylhexyl)phthalate Tr Di-n-butylphthalate Tr; Bis{2-ethYlhexyl)phthalate Tr •Branched Hydrocarbon 10 Di-n-butvlphthalate 10: Bis(2-ethvlhexvl)phthalate Tr Di-n-butylphthalate Tr ND Di-n-butylphthalate Tr Di-n-butvlphthalate Tr ND ND ND ND ND ND Bis(2-ethylhexyl)phthalate 14 ND ND ND ND ND ND ND ND
ND = None detected
Tr = Trace concentration; positively identified using mass spectrometer, but detected belou limit of quantitation for EPA method 625
•Additional compounds detected and semi-quantitated
NOTE: Samples analyzed by Analytical Technologies, Inc., Phoenix, Arizona
WELL
IDENTIFIER'
HW-lUA D HW-lUA HW-lUA
TABLE 10. SUHMARY OF LABORATORY CHEHICAL RESULTS FOR EPA METHOD 608 FOR ORGANOCHLORINE PESTICIDES AND POLYCHLORINATED BIPHENYLS (PCBs)
IN GROUNDWATER SAHPLES FROH HONITOR WELLS HASSAYAHPA LANDFILL, HARICOPA COUNTY, ARIZONA 0.
SAHPLE IDENTIFIER FIELD
014378 014412 006099
LAB
16208 806006-01 809133-15
DATE
SAHPLED
04-08-88 05-31-88 09-20-88
DATE
ANALYZED
05-06-88 06-16-88 09-28-88
ORGANOCHLORINE PESTICIDES AND PCBs
(micrograms per liter)
ND ND ND
HW-IUB HW-IUB HW-IUB HW-2UA HW-2UA HW-2UA HW-2UA MW-2UB HW-2UB HW-2UB HW-3UA MW-3UA HW-3UA HW-3UB HW-3UB HW-3UB HW-4UA HW-4UA HW-4UA HW-4UA HW-4UB HW-4UB HW-4UB
D
D
dup D
D
D
D
dup D
014383 014425 006086 014382 014421 006088 006088 014379 014414 006087 014387 014413 006091 014384 014426 006090 014391 014427 006093 006093 014399 014428 006092
804087-01 806096-01 809133-02 804069-01 806047-01 809133-04 809133-19 804029-01 806006-03 809135-03 805024-01 806006-02 809155-07 805010-01 806096-02 809155-06 805060-01 806130-01 809135-09 809155-20 805105-01 806170-01 809153-08
04-27-88 06-14-88 09-20-88 04-25-88 06-09-88 09-20-88 09-20-88 04-18-88 06-01-88 09-20-88 05-05-88 06-01-88 09-20-88 04-29-88 06-16-88 09-20-88 05-15-88 06-22-88 09-20-88 09-20-88 05-19-88 06-28-88 09-20-88
05-06-88 07-07-88 09-28-88 05-21-88 07-07-88 09-28-88 09-24-88 05-06-88 06-16-88 09-28-88 05-22-88 06-16-88 09-28-88 05-21-88 07-07-88 09-28-88 05-26-88 07-13-88 09-28-88 09-28-88 06-15-88 07-13-88 09-28-88
ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO
HW-5UA D HW-5UA D dup HW-5UA HW-5UA dup HW-5UA
014406 014407 014450 014451 006098
805159-01 805159-02 807002-02 807002-05 809133-14
05-26-88 05-26-88 06-50-88 06-30-88 09-20-88
06-15-88 06-15-88 07-14-88 07-14-88 09-28-88
ND ND ND ND NO
MW-6UA HW-6UB HW-7UA HW-8UA HW-8UA dup MW-9UA HW-9UB MW-IOUA MW-IOUB HS-2 HS-3
004325 010883 004392 004395 004397 004457 014758 004461 004464 006095 006097
911782-05 104835-02 002577-02 002577-05 002577-06 105644-01 105570-01 105723-01 105875-02 809155-11 809155-15
11-28-89 04-23-91 02-07-90 02-08-90 02-08-90 05-07-91 05-02-91 05-14-91 05-22-91 09-20-88 09-20-88
12-06-89 05-07-91 02-15-90 02-15-90 02-15-90 05-20-91 05-16-91 05-29-91 06-05-91 09-28-88 09-28-88
ND ND ND ND ND ND ND ND NO ND ND
D = Sample obtained during uell developnient
dup = Duplicate sample
^ ND = Not detected
NOTE: Samples analyzed by Analytical Technologies, Inc., Phoenix, Arizona
LAB SAMPLE
IDENTIFIER
TABLE 11. SUHMARY OF LABORATORY CHEHICAL RESULTS FOR EPA HETHOD 608 FOR ORGANOCHLORINE PESTICIDES AND POLYCHLORINATED BIPHENYLS (PCBs)
IN QUALITY CONTROL BLANKS FOR WATER SAHPLES FOR HASSAYAHPA LANDFILL, HARICOPA COUNTY, ARIZONA
SAMPLE TYPE
DATE ORGANOCHLORINE PESTICIDES AND PCBs"
ANALYZED (micrograms per liter)
16208 804029 804069 804087 805010 805024 805060 805105 805139-03 805139 806006 806047 806096 806130 806170 807002-01 807002 809133 809160-01 809160 809167-01 809167 911782 002577-03 002577 104835 105570 105644 105723 105875
REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK FIELD BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK FIELD BLANK REAGENT BLANK REAGENT BLANK FIELD BLANK REAGENT BLANK FIELD BLANK REAGENT BLANK REAGENT BLANK FIELD BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK REAGENT BLANK
05-06-88 05-06-88 05-21-88 05-06-88 05-21-88 05-22-88 05-26-88 06-15-88 06-15-88 06-15-88 06-15-88 06-29-88 06-30-88 07-13-88 07-13-88 07-14-88 07-14-88 09-28-88 09-30-88 09-30-88 09-30-88 09-50-88 12-06-89 02-15-90 02-15-90 05-07-91 05-16-91 05-20-91 05-29-91 06-04-91
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO ND ND ND
ND = Not detected
NOTE: Samples analyzed by Analytical Technologies, Inc., Phoenix, Arizona
WELL IDENTIFIER^
HW-2UA MW-2UA dup
HW-5UA
TABLE 12. SUHHARY OF LABORATORY CHEHICAL RESULTS FOR EPA HETHOO 622 FOR ORGANOPHOSPHORUS PESTICIDES IN GROUNDWATER SAHPLES FROH HONITOR WELLS
HASSAYAHPA LANDFILL, HARICOPA COUNTY, ARIZONA
SAHPLE IDENTIFIER
FIELD
010904 010905
010906
LAB
105704-04 105704-05
105704-06
DATE
SAMPLED
05-13-91 05-13-91
05-13-91
JATE ANALYZED
05 05
05
-27-91 -27-91
-27-91
ORGANOPHOSPHORUS PESTICIDES'^
(milligrams per liter) ,--
ND ND
ND
QUALITY CONTROL BLANKS:
FIELD BLANK REAGENT BLANK
010911 105704-11 105704
05-13-91 —
05-27-91 05-27-91
ND ND
dup = Duplicate sample
• ND = Not detected
NOTE: Samples analyzed by Analytical Technologies, Inc., Phoenix, Arizona
WELL
IDENTIFIER^
TABLE 15. SUHHARY OF LABORATORY CHEHICAL RESULTS FOR EPA HETHOO 652 FOR CARBAHATES AND UREA PESTICIDES IN GROUNDWATER SAHPLES FROH HONITOR WELLS
HASSAYAHPA LANDFILL, HARICOPA COUNTY, ARIZONA
SAMPLE IDENTIFIER
FIELD LAB DATE
SAMPLED DATE
ANALYZED
MW-2UA HW-2UA dup
010904 010905
105704-04 105704-05
05-13-91 05-13-91
06-05-91 06-05-91
ND ND
HW-5UA 010906 105704-06 05-15-91 06-06-91 ND
QUALITY CONTROL BLANKS:
FIELD BLANK REAGENT BLANK
010911 105704-11 105704
05-15-91 ...
06-06-91 06-05-91
BAYGON=25 ND
dup = Duplicate sample
ND = Not detected
NOTE: Samples analyzed by Analytical Technologies, Inc., Phoenix, Arizona
TABLE 14. SUMMARY OF WATER LEVEL HEASUREHENTS ,. FOR MONITOR WELLS AT HASSAYAMPA LANDFILL ' P R E L I M I N A R Y
WELL IDENTIFIER
(C-1-5)5dab5[MW-IUA]
(C-1-5)3dab1[MW-IUB]
(C-1-5)3daa2[HW-2UA]
(C-1-5)5dab4[HW-2UB]
(C-1-5)3daa4[HW-3UA]
DATE HEASURED
08-10-88 08-12-88 09-14-88 09-20-88 10-20-88 12-01-88 12-05-88 12-06-88 08-23-89 02-13-90 03-06-90 06-06-90 04-18-91 06-18-91
08-10-88 08-12-88 09-14-88 09-20-88 10-20-88 12-01-88 12-05-88 12-06-88 08-25-89 02-15-90 05-06-90 06-06-90 04-18-91 06-18-91
08-10-88 08-12-88 09-13-88 09-20-88 10-20-88 12-01-88 12-05-88 08-23-89 02-13-90 03-06-90 06-06-90 04-18-91 06-18-91
08-12-88 09-13-88 09-20-88 10-20-88 12-01-88 12-05-88 12-06-88 08-25-89 02-15-90 03-06-90 06-06-90 04-18-91 06-18-91
08-10-88 08-12-88 09-13-88 09-20-88 10-20-88 12-01-88 12-05-88
HARICOPA COUNTY, ARIZONA
HEASURING POINT ALTITUDE
( f ee t .
926,
925,
918,
918,
916.
msl)"
.53
.68
.55
.95
,68
^u<ijscr To'Rivis;
DEPTH TO WATER LEVEL
( f e e t ) "
85.11 85,51 85,50 85,45 85,41 83,70 85,64 83,65 83,76 83.83 84.11 84,11 84,62 84,66
109,65 109,70 108,07 107.71 106.14 106.57 106.67 106.62 110.60 106.96 107.53 110.96 110.04 111.87
76,01 76.62 76.17 76.06 76.12 76.39 76.34 76,59 76,75 76,99 77,05 77.51 77.64
105.65 102.01 101.49 100.07 100.75 100.90 100,85 104,97 101.22 102.10 105,52 104.55 106.67
73.42 72.91 73.72 73.70 73.59 73.79 74.40
WATER LEVEL ALTITUDE
( f e e t , msl)
843,42 843,22 843.03 843.08 843,12 842,83 842,89 842,88 842.77 842.70 842,42 842,42 841,91 841.87
816.03 815.98 817.61 817.97 819.54 819.11 819.01 819.06 815.08 818.72 818,15 814,72 815,64 813.81
842.54 841.93 842.38 842.49 842.43 842.16 842,21 841,96 841,80 841,56 841,50 841.04 840.91
815.30 816.94 817.46 818,88 818.22 818.05 818.10 813,98 817,73 816,85 813,43 814,40 812,28
843,26 843.77 842.96 842.98 843.09 842,89 842,28
TABLE 14, SUHHARY OF WATER LEVEL HEASUREHENTS FOR MONITOR WELLS AT HASSAYAHPA LANDFILL HARICOPA COUNTY, ARIZONA
WELL IDENTIFIER
(C-1-5)5daa4[HW-5UA] (continued)
(C-1-5)5daa5[MW-3UB]
(C-1-5)3dab5[MW-4UA]
(C-1-5)3dab6[MW-4UB]
(C-1-5)3dab7[MW-5UA]
DATE MEASURED
08-23-89 02-05-06-04-06
08 08 09 09 10 12 12 12 08-02-05-06-04-06-
08-08-09 09 10 12 12 08 02-03-06-04-06-
OS-OS-09-09-10-12-12-08-02-05-06-04-06-
09 09 10 12 12-08 02-03-06-04-06-
15 06 06 18 IS
10 12 13 20 20 01 05 06 23 15 06 06 18 18
10 12 15 20 20 01 05 24 13 06 06 18 18
10 12 14 20 20 01 06 24 15 06 06 18 18
15-20-20-OlOS-23-13-
90 90 90 91 91
•88 •88 •88 •88 •88 •88 •88 •88 •89 •90 •90 90 91 91
88 SS 88 •88 •88 •88 •88 •89 •90 •90 •90 91 91
88 SS 88 88 88 88 88 •89 90 90 90 91 91
88 88 88 88 88 89 90
07-90 06-90 18-91 1S-91
HEASURING POINT ALTITUDE (feet.
916
916
915
916
925
msl)"
84
18
69
19
45
DEPTH WATER
(fee
74 74 74 74 75 75
100 100 98 98 96
TO
77 29 70 64 14 41
.51
.45
.55
.10
.52 97.33 97.49 97.40 101 .72 97.87 98 102 101 103
71 71 71 71 71 72
.65
.32
.31 46
58 86 86 .79 .87 .04
72,34 72 .24 72.52 72 72 73 73
.69
.74
.20 32
98.37 98.21 96 96 95 95 95 99 95 96 99 100 101
81 81 81 81 81 81 81 82 SI 82 82
76 49 01 14 16 .21 .68 .03 69 53 14
29 10 30 53 44 58 69 00 98 39 49
WATER LEVEL ALTITUDE (feet
841 842 841 842 841 841
815 815
msl)
91 39 98 04 54 43
67 73
817.65 818 819 818 818 SIS 814 SIS 817 813 814 812
844 843 843 843 845 845 845 845 845 843 842 842 842
817 817
OS 66 85 69 78 46 31 53 86 87 72
11 83 83 90 82 65 35 45 17 00 95 49 37
82 98
819.43 819 821 821 821 816 820 820 816 815 815
844 844 844 843 844 843 843 843 843 843 842
70 IS 05 03 98 51 16 50 66 05
16 35 15 92 01 87 76 45 47 06 96
TABLE 14. SUHHARY OF WATER LEVEL HEASUREHENTS FOR HONITOR WELLS AT HASSAYAMPA LANDFILL HARICOPA COUNTY, ARIZONA
WELL IDENTIFIER
(C-1-5)5daa5[HW-6UA]
(C-1-5)3daa6[MW-6UB]
(C-1-5)3dab8[MW-7UA]
(C-1-5)3dbd2[HW-8UA]
(C-1-5)3dac3[HW-9UA]
(C-1-5)3dac2[MW-9UBl
(C-1-5)3dda3[HW-IOUA]
(C-1-5)5dda4[HW-IOUB]
(C-1-5)3daa1[HS-1]
(C-1-5)3dac1[HS-2]
DATE HEASURED
02-13-90 03-07-90 06-06-90 04-18-91 06-18-91
06-18-91
02-13-90 03-07-90 06-06-90 04-18-91 06-18-91
02-13-90 03-07-90 06-07-90 04-18-91 06-18-91
06-18-91
06-18-91
06-18-91
06-18-91
12-22-81
04- -82
05-13-82
09-14-82
02-08-84
09-05-84
04-01-87
07-15-87
12-22-81 04- -82 05-15-82 09-14-82 02-08-84 09-05-84 04-01-87 07-15-87 08-12-88 09-14-88 09-20-88 10-20-88 12-01-88 12-06-SS 08-24-89 02-13-90 03-07-90 06-07-90 04-18-91
MEASURING POINT ALTITUDE (feet, msl)^
917.41
917.65
921.63 921.62
928.31
916.79
915,99
913,25
915.05
915.19'=
917.sr
915,09"=
917.48®
917,72
DEPTH TO WATER LEVEL
(feet)"
73.93 74.20 74.25 74,73 74.86
102.20
78,37 78.72 78.58 79.02 79.14
87.81 88.04 88.18 88.72 88.72
78.41
104,50
WATER LEVEL ALTITUDE (feet, msl)
843.48 843.21 843.16 842.68 842.55
815.45
843.26 842.90 843.04 842.60 842.48
840.50 840.27 840.50 859.59 839.59
858.38
811.49
77.27
100.96
835.98
812,09
917.52
68.1 ' 68.2 " 68.02*
68.2/^
68.59'
68.35< 71.87
72.63
73,7''
73.8 ' 73,72"
73.84'
73,62"
73.65'
77,00 77.56 78.56 78.61 78.30 78.47 78.72 78.72 78.89 78.83 79.05 79,30 79,43
847.1
847,0 847,17
846.92
846.80
846.84
845.94
845,18
841,4
841.3 841.37
841.25
841.47
841.44
840,48
839,92 839,16 859.11 859,42 859.25 859.00 859.00 858.85 838.89 838.67 838,42 838,09
TABLE 14, SUHHARY OF WATER LEVEL HEASUREHENTS FOR HONITOR WELLS AT HASSAYAHPA LANDFILL HARICOPA COUNTY, ARIZONA
WELL IDENTIFIER
(C-1-5)3dda1[HS-3]
DATE HEASURED
12-22-81
04- -82 05-13-82
09-14-82 02-08-84
09-05-84 04-01-87
07-15-87 08-12-88 09-14-88 09-20-88 10-20-88 12-01-88 12-05-88 08-24-89 02-15-90 03-08-90 06-07-90 04-18-91
HEASURING POINT ALTITUDE (feet, msl)^
909,80"=
912,06®
912,37
DEPTH TO WATER LEVEL
(feet)"
69,6 "
69.9 " 69.8 "
69.63'*
69.88'*
70.03'*
75.55 75.97 75.09 75,21 74,94 75.05 75.28 75,15 75.69 75.75 76.00 76.57 76.34
WATER LEVEL ALTITUDE (feet, msl)
840.2 839,9 840.0 840.17 839.92 839.77 838.73 838.09 837.28 837.16 857.43 837.34 837,09 837.22 836.68 836.62 836.37 836.00 836.03
NOTE: msl = Hean sea level
a Top of galvanized steel coupling on sounder access pipe; altitude surveyed
Depth belou measuring point; measured using an electrical uater level sounder
Altitude of land surface reported by Arizona Department of Health Services (1985)
Depth below land surface. Measurement obtained by Arizona Department of Health Services.
Heasuring point uas notch in top of uncapped four-inch diameter PVC casing
TABLE 15.
BORING IDENTIFIER
VB-1
VB-2f VB-2C
VB-5 VB-4
DATE COMPLETED
05-24-91 05-24-91 05-24-91 05-24-91 06-28-91
.BOREHOLE.
DIAHETER (inches)
8 8 8 8 8
DEPTH (feet)
58.5
51
58.5
58.5 40
SUMHARY OF VADOSE ZONE HONITOR BORING CONSTRUCTION DETAILS HAZARDOUS WASTE AREA HASSAYAHPA LANDFILL
HARICOPA COUNTY, ARIZONA
INSIDE DIAHETER (inches)
2 2 2 2 2
.CASING"
OUTSIDE DIAHETER (inches)
2-5/8
2-3/8
2-3/8
2-3/8
2-3/8
DEPTH INTERVAL (feet)
0-38.5
0-50
0-58.5
0-58.5 0-40
SCREENED INTERVAL (feet)
5.5-38.5"
40-50'=
3.5-38.5"
3.5-5-
38.5" 40
CEHENTED INTERVAL (feet)
0-2 0-2 0-2 0-2 0-2
BENTONITE SEAL
INTERVAL (feet)
34-56. ...d ...d
d
GRAVELi/PACK INTERVAL (feet)
36.5-44, 50-51
Schedule 80 flush threaded PVC casing; VB-4 constructed using schedule 40 flush-threaded PVC casing.
PVC uell screen is 0,1-inch by 2-inch horizontal machine-cut slots;
3 slots per round, 126 slots total per linear foot
PVC uell screen is 0.06-inch by 2-inch horizontal machine-cut slots; 3 slots per round, 126 slots total per linear foot
No bentonite seal
No gravel or sand pack
No, 30 silica sand in interval from 36,5 to 38 feet;
interval from 44 to 50 feet contains fill material from borehole ualI
NOTE: All depths are in feet belou land surface
TABLE 16. LITHOLOGIC DESCRIPTIONS FOR SPLIT-SPOON SAMPLES FROM VADOSE ZONE MONITOR BORINGS
HAZARDOUS WASTE AREA HASSAYAMPA LANDFILL DOC, , , . „ . , . r .
MARICOPA COUNTY, ARIZONA i^L'^UMTMRY SUBJECrTfo^EVlsTON
BORING IDENTIFIER
VB-1
DEPTH (feet)
35
37.5
DESCRIPTION
Gravel and silty sand
Sandy silt and clay
BLOW COUNTS FOR
SPLIT-SPOON SAMPLER
93
75
SPLIT-SPOON PENETRATION (inches)
18
4
VB-2f
VB-2C
VB-3
VB-4
40
38
Sandy silt and clay
35 Silty sand with gravel
36.5 Sandy silt and clay
36 Sandy silt and clay
Sandy silt and clay
75
100
75
75
60
7
2
4
2
NOTE: Depth in feet below land surface
TABLE 17, RESULTS OF TRACE GAS ANALYZER HEASUREHENTS VADOSE ZONE HONITOR BORINGS
HAZARDOUS WASTE AREA HASSAYAHPA LANOFILL
HARICOPA COUNTY, ARIZONA
-PRELIMINARY SUBJECTTO^vTsTo;.,
BORING IDENTIFIER
VB-2f
VB-2c
VB-1
VB-3
VB-4
DATE
05-24-91
05-24-91
05-24-91
05-24-91
06-28-91
TIHE DEPTH (feet)'
05:30 06:13 06:15 06:16 06:21 06:27 06:33 06:50 07:00 08:28
09:00 09:18 09:22 09:25 09:39 09:55
10:35 10:40 10:46 10:54 11:04 11:16
11:42 11:49 11:54 12:14
07:10 07:11 07:15 07:18 07:20 07:25 07:28 07:32 07:50 07:55 08:00 08:15 09:30
0 5
10 20 30 40 45 51 51
— 15 25 30 36,5 58.5
10 20 50 55 57.5 58.5
5 20 50 38.5
0 0 5
10 15 20 25 30 —
35 38 40 40
CONCENTRATION OF TRACE GASES
(parts per million) BREATHING
BACKGROUND'-
1.5'
0,3
r 0,3 0.4 0,3 0,3
0.3
1-
0.3
0.3
°Z 0.4 0.4 0.4 0,5
0.4 0.5 0.4 0.6 0,6 0.5
ZONE"
0.3 0.6 1.5 0.5 0.6 0.3
0.4-0.6-0.4-0.8-1.0 1-
0,5-1-
0,5 0,5
0.4 0.3 0,4 0,2 0.5 0.3 0.4
TOP OF BOREHOLE®
,5
,4 .8 .49 2-3 1-7« 1
0.5
0,4 0.4
59 5-15 5 1-2 19
5-209
59 5-109
2-3
1.0 10-209
2-39
1009
0.5 0.1 0.2 0.2 0.2 0.3
0.2 1.5 0.8 6.0
Concentration of trace gases measured using HNU Hodel PI 101 portable trace gas analyzer with 10.2 eV
probe; in general, concentrations are maximum concentrations observed during field measurement.
Depth, in feet belou land surface, of drill bit at time of trace gas measurement.
'' Heasurement obtained upwind from work zone.
Heasurement obtained in work areas in vicinity of drilling rig
® Heasurement obtained at top of open borehole, or at top of augers
Heasurement obtained near operating engine of drilling rig
9 Heasurement obtained one foot inside top of augers
= Heasurement not obtained or not recorded
ILLUSTRATIONS
DEPTH. GRAPHIC LOG IN FEET
BELOW LAND SURFACE
UTHOLOGIC DESCRIPTION
50.0
51.0
52.0
53.0
54.0
55.0
56.0
57.0
58.0
59.0
60.0
61.0
62.0
63.0
64.0
65.0
66.0
67.0
68.0
69.0
70.0
71.0
72.0
73.0
4-
50.0-50.3
50.3-51.0
51.0-56.0
56.0 56.0-56.5 56.5-56.9
56.9-56.95 56.95-57.8
57.8-57.9 57.9-59.3
59.3-61.4
61.4-64.6
64.6 64.6-70.0
70.0-71.1
71.10-71.15 71.15-71.25 71.25-71.6 71.6-72.7
72.7-73.0
Subangular to subrounded gravel, clasts of volcanic ond metamorphic rocks, 0.5 to 3 inches in diometer Sand, silt, and clay; very fine to fine sond 50/5, silt and clay 50%; dark brown (7.5 YR 4 /4 ) to pinkish white (7.5 YR/8 /2 ) ; non-lithified to strongly lithified with carbonate cement; lithification consisls of and disseminated carbonate cementation, and carbonate concretions 0.5 to 1 inch in diameter. Reaction to acid: none to strong. Weakly fractured. Very thin fractures lined with waxy, grayish-brown clay skins, carbonate, and traces of black manganese oxide coating. Medium to coarse sand grains fill some fractures. Discontinuous rootlet molds are common and ore lined with black manganese oxide coatings. Slightly sticky. Core is broken.
Sand, silt, and clay; very fine sand 50%, silt and clay 50%; brown (7.5 YR 5 /4 ) to strong brown (7.5 YR 4 / 6 ) ; weakly to strongly lithified; lithification consists of disseminated carbonate cementation, 0.25— to 1.0—inch carbonate nodules, and of consolidated sediment with no carbonate cementation. Reaction to ocid: none to strong. Weakly fractured. Very th in vert ical f rac tu res l ined with black manganese oxide coa t ing , and with waxy clay skins. Very thin horizontal fractures are lined with waxy clay skins. Discontinuous rootlet molds are common and are lined with black manganese oxide coatings. Slightly sticky. Core Is unbroken.
Break in core, base of first cored intervol.
Grovel ond cobbles of granitic gneiss, caved from borehole woll.
Basalt; black; fractured, weathered, and vesicular; silty and sandy carbonate cement in froctures. Sandy corbonote is brown (7.5 YR 5 /4 ) . Basalt is aphanitic with altered olivine phenocrysts 0.02 to 0.04 inch in diameter; 25% vesicles that range in size from 0.04 to 0.2 inch in diameter. Twenty percent of vesicles are completely filled with white calcite or wilh silty, light—brown, carbonate cement.
Silty, brown, carbonate cement in horizontal fracture.
Basalt; black, dark gray. Basalt is ophanitic with altered olivine phenocrysts 0.02 to 0.04 inch in diameter; 25% vesicles that range in size ifrom 0.02 to 0.6 inch in diameter. Vertical fracture portially open, 0.02 to 0.08 inch in width, and partially filled with silty, light—brown, carbonate cement. Some vesicles visibly interconnected. Vesicles odjocent to vertical fracture are filled with white calcite or with silty, light—brown, carbonate cement. Break In core at 57.4 feet.
Light—brown sandy silt.
Basalt; block, dark gray. Basalt is aphanitic with olivine phenocrysts 0.02 to 0.04 inch in diameter, some altered, some reploced with calcite; 30% vesicles that ronge in size from 0.02 to 1.2 inches in diameter. Vertical fracture 0.04 to 0.1 inch in width, and filled with silty, l ight-brown, carbonote cement. Some vesicles visibly Interconnected. Vesicles adjacent to vertical fracture are filled with white calcite or with silty, light—brown, carbonate cement. Some vesicles portially filled with calcite crystals.
Basalt; black, dark gray. Basalt is aphanitic with olivine phenocrysts 0.02 to 0.04 inch in diameter, some altered; 30% vesicles that range in size from 0.02 to 1.2 inches in diameter. Vertical fracture from 59.3 to 59.5 feet, and from 60.8 to 61.4 feet, 0.04 to 0.1 inch in width, ond filled with silty, light—brown, carbonate cement. Some vesicles partially filled with calcite crystals.
Basalt; block, dark gray. Basalt is ophanitic with olivine ond plagioclase phenocrysts 0.01 to 0.04 inch in diameter, most are fresh; 40% vesicles that range in size from 0.01 to 0.08 inch in diameter. Vertical fracture 0.04 to 0.12 inch in width, and filled with layered white and light—brown carbonate cement and with brown cloy. Some vesicles filled with light—brown carbonate cement or with white calcite. Some vesicles partially filled with calcite crystals.
Break in core, base of second cored interval.
Basalt; black, dark gray. Basalt is aphanitic with olivine and plagioclase phenocrysts 0.01 to 0.04 inch in diometer, many phenocrysts replaced with calcite; 30% vesicles range in size from 0.01 to 0.02 inch in diameter. Vertical fracture, from 64.6 to 64.8, 0.04 to 0.12 inch in width, ond filled with layered white and light—brown carbonate cement and with brown clay. Horizontal fractures from 64.8 to 65.2 filled with light-brown carbonate cement and with brown clay. Some vesicles filled with light—brown carbonate cement or with white calcite. Band of 1/4—inch diameter vesicles from 65.2 to 65.4 feet. Thin, discontinuous, horizontal fractures filled with white calcite from 68.2 to 68.6 feet.
Basalt; black, dark gray. Basalt is aphanitic with olivine phenocrysts 0.01 to 0.04 inch in diometer, most ore fresh; 25% vesicles that range in size from 0.01 to 0.2 inch diameter. Some large vesicles partially filled with calcite crystals. Some small vesicles filled with white calcite. 50% of olivine phenocrysts are altered from 71.0 to 71.1 feet.
Light—brown carbonate cement layer.
Basalt; black. Basalt is aphanitic with altered olivine phenocrysts 0.01 to 0.04 inch in diameter; 15% vesicles that range in size from 0.04 to 0.2 inch in diameter. Vesicles are mostly ovoid in shape. Upper port contains many fine vesicles.
Interioyered sand, and sandy silt and cloy; strong brown (7.5 YR 4 / 6 ) ; fine to coarse sand 50%, silt and cloy 50%; non-lithif ied. Reaction to ocid: none to weak. Sticky.
Sand; strong brown (7.5 YR 4 / 6 ) ; fine sand 100%; weakly to moderately lithified with carbonate cement. Reaction to acid: weak to strong. Non— sticky. Fine sandy silt and clay layer from 72.1 to 72.2 feet.
No recovery. Total depth drilled was 73.0 feel.
Note: U.S. Geological Survey color classification given in parentheses.
FIGURE 2. DETAILED LITHOLOGiC DESCRIPTIONS AND GRAPHIC LOG FOR CORE FROM EXPLORATION BORING EX-2
E X P L A N A T I O N
0 50 100 150 200 250 300 0MW-1UA UNIT A MONITOR WELL AND IDENTIFIER
eMw-iUB UNIT B MONITOR WELL AND IDENTIFIER
(()HS-1
QEX-1
ABANDONED MONITOR WELL AND IDENTIFIER; CONSTRUCTED BY ARIZONA DEPARTMENT OF HEALTH SERVICES; H S - 1 ABANDONED JUNE 1988; H S - 2 AND H S - 3 ABANDONED MAY 1991
EXPLORATION BORING AND IDENTIFIER
FEET
fREUMiiVARy
A SB-1 VERTICAL SOIL BORING AND IDENTIFIER
A AB-1 ANGLED SOIL BORING AND IDENTIFIER
FIGURE 1. LOCATION MAP FOR MONITOR WELLS AND SOIL BORINGS, HASSAYAMPA LANDFILL, MARICOPA COUNTY, ARIZONA
SB-19 (at Pit 1)
VB-1
VB-2f VB-2C
2 0 ' V B - 4
MW-5UA
EXPLANATION 10 20 30 40 50
ABANDONED VERTICAL SOIL BORING AND A SB-19 IDENTIFIER. DRILLED THROUGH PIT 1;
ABANDONED MAY 2, 1991
FEET
V V B - 1 VADOSE ZONE MONITOR BORING AND IDENTIFIER
^
ABANDONED MONITOR WELL AND IDENTIFIER. HS-1 CONSTRUCTED BY ARIZONA DEPARTMENT OF
HEALTH SERVICES; ABANDONED JUNE 1988
FIGURE 3 . LOCATION MAP FOR VADOSE ZONE MONITOR BORINGS FORMER HAZARDOUS WASTE DISPOSAL AREA, HASSAYAMPA LANDHLL, MARICOPA COUNTY, ARIZONA
DEPTH BELOW LAND SURFACE,
IN FEET
LOCKING SECURITY CAP
a-INCH BOREHOLE-
CEMENT
2-INCH BLANK SCHEDULE 80 -PVC CASING. THREADED JOINTS
2-INCH PERFORATED SCHEDULE 40 PVC CASING, THREADED JOINTS
(0.1—inch, horizontal machine—cut slots)
PVC CAP, THREADED JOINT-
COARSE-GRAINED PART OF
UPPER ALLUVIAL DEPOSITS UNIT
• • n iS: .UMINARY w.if t o REVISION
/ ^ 38
38.5 \ .
FINE-GRAINED PART OF UPPER ALLUVIAL DEPOSITS UNIT
RGURE 4 . SCHEMATIC DIAGRAM OF CONSTRUCTION FOR VADOSE ZONE MONITOR BORING VB-4
APPENDIX A
LABORATORY CHEMICAL RESULTS
XAN: Ana / j j ( \ A n a l y t i c a l T e c h n o l o g i e s , Inc. saaos. sist street suite B-I 13 Phoemx, AZ 85044 (602)496-4400
ATI I.D. 105570
June 13, 1991
Errol L. Montgomery & Associates 1075 E. Fort Lowell Road Suite B Tucson, AZ 85719
Project Name/Number: Hassayampa/662-A
Attention: Bill Victor
On 05/03/91, Analytical Technologies, Inc. received a request to analyze aqueous sample(s). The sample(s) were analyzed with EPA methodology or equivalent methods. The results of these analyses and the quality control data, which follow each set of analyses, are enclosed.
601/602 analyses were added on 05/15/91 for samples 0414758 and 014760. 624 analyses were cancelled on 05/15/91 for samples 014758 and 014760.
Due to equipment failure, the Laboratory Control Standard for Method 601/602 is not available for 05/16/91.
If you have any questions or comments, please do not hesitate to contact us at (602) 496-4400.
# ^
Michael G. Barry Project Manager
Lorraine Davis QA Coordinator
RVW:jat Enclosure
Robert V. Woods Laboratory Manager
l-..!..'.tj
J U N •; - ' o r '
VZ'i. Arcuc, i:;c.
Corporate Offices: 5550 Morehouse Drive San Diego. CA 92121 (619) 458-9141
A - 1
A ^ AnalyticalTechnologies, Inc. 9830 S. 51st Street Suite 8-113 Phoenix. AZ 85044 (602) 496-4400
ATI I .D . 105570
J u l y 16 , 1991
Errol L. Montgomery & Associates 1075 E. Fort Lowell Road Suite B Tucson, AZ 85719
Project Name/Number: Hassayampa/662-A
Attention: Bill Victor
On 05/03/91, Analytical Technologies, Inc. received a request to analyze aqueous sample(s). The sample(s) were analyzed with EPA methodology or equivalent methods. The results of these analyses and the quality control data, which follow each set of analyses, are enclosed.
Enclosed is an amended report for the method 601/602 reagent blank and the method 608 matrix spike results. We apologize for any inconvenience this may have caused.
601/602 analyses were added on 05/15/91 for samples 0414758 and 014760. 624 analyses were cancelled on 05/15/91 for samples 014758 and 014760.
Due to equipment failure, the Laboratory Control Standard for Method 601/602 is not available for 05/16/91.
If you have any questions or comments, please do not hesitate to contact us at (602) 496-4400.
; | f ,4^ f . a Michael G. Barry Project Manager
Lorraine Davis QA Coordinator
RVW:j at Enclosure
Robert V. Woods Laboratory Manager
KL'.:t.wta
.C -,0' I U L - ^ '-'••
i,o:lT:o^•l^•^ ' ^ ^ • ^ '''-
Corporate Offices: 5550 Morehouse Drive San Diego. CA 92121 (619) 453-9M1
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CLIENT PROJECT # PROJECT NAME
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA
ATI I.D. : 105570
DATE RECEIVED : 05/03/91
REPORT DATE : 06/12/91
ATI # CLIENT DESCRIPTION MATRIX DATE COLLECTED
01 02 03
014758 014 7 60 TRIP BLANK 014759
AQUEOUS AQUEOUS AQUEOUS
05/02/91 04/26/91 05/02/91
TOTALS
MATRIX
AQUEOUS
# SAMPLES
3
ATI STANDARD DISPOSAL PRACTICE
The samples from this project will be disposed of in thirty (30) days from the date of this report. If an extended storage period is required, please contact our sample control department before the scheduled disposal date.
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/hi^-^(y9 pr Inc.
GENERAL CHEMISTRY RESULTS
CLIENT PROJECT # PROJECT NAME
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA
ATI I.D. : 105570
DATE RECEIVED : 05/03/91
REPORT DATE : 06/10/91
PARAMETER UNITS 01
CARBONATE (CACO3) BICARBONATE (CAC03) HYDROXIDE (CAC03) TOTAL ALKALINITY (AS CAC03) CHLORIDE CYANIDE, TOTAL CONDUCTIVITY, (UMHOS/CM) FLUORIDE AMMONIA AS NITROGEN NITRATE AS NITROGEN PH PHOSPHATE,ORTHO (AS P) SULFATE TOTAL DISSOLVED SOLIDS PHOSPHOROUS,TOTAL
MG/L MG/L MG/L MG/L MG/L MG/L
MG/L MG/L MG/L UNITS MG/L MG/L MG/L MG/L
<1 120 <1 120 210 <0.01 1030 0.83 0.03 25 7.9 <0.05 51 700 <0.05
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GENERAL CHEMISTRY - QUALITY CONTROL
CLIENT : MONTGOMERY & ASSOCIATES PROJECT # : 6 6 2-A PROJECT NAME : HASSAYAMPA ATI I.D. : 105570
PARAMETER
CARBONATE BICARBONATE HYDROXIDE TOTAL ALKALINITY CHLORIDE CYANIDE, TOTAL CONDUCTIVITY(UMHOS/CM) FLUORIDE AMMONIA AS NITROGEN NITRATE AS NITROGEN PH PHOSPHATE, ORTHO SULFATE TOTAL DISSOLVED SOLIDS PHOSPHOROUS,TOTAL
UNITS
MG/L MG/L MG/L MG/L MG/L MG/L
MG/L MG/L MG/L UNITS MG/L MG/L MG/L MG/L
ATI I.D.
10557001
10557001 10488707 10555503 10557001 10557001 10557001 10557001 10557001 10557001 10555501 10557001
SAMPLE RESULT
<1 120 <1 120 210 0.05 2290 0.83 0.03 25 7.9 <0.05 61 1800 <0.05
DUP. RESULT
<1 122 <1 122 200 0.08 2280 0.86 0.03 25 7.9 <0.05 62 1800 <0.05
RPD
NA 2
NA 2 5 29
0.4 4 0 0 0
NA 2 0
NA
SPIKED SAMPLE
NA NA NA NA 720 0.30 NA 1.53 0.55 55 NA 0.53 120 NA 0.56
SPIKE CONC
NA NA NA NA 500 0.25 NA 0.85 0.50 40 NA 0.50 61 NA 0.50
% REC
NA NA NA NA 102 96 NA 94 104 100 NA 106 97 NA 112
% Recovery = (Spike Sample Result
Spike Concentration
RPD (Relative Percent Difference)
Sample Result) X 100
(Sample Result - Duplicate Result)
Average Result X 100
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METALS RESULTS
/ h ^ ^ - ' (yO> P r
CLIENT PROJECT # PROJECT NAME
MONTGOMERY 662-A HASSAYAMPA
& ASSOCIATES
ATI I.D. : 105570
DATE RECEIVED : 05/03/91
REPORT DATE : 06/12/91
PARAMETER UNITS 01
SILVER ALUMINUM ARSENIC BARIUM BERYLLIUM CALCIUM CADMIUM COBALT CHROMIUM COPPER IRON MERCURY POTASSIUM MAGNESIUM MANGANESE SODIUM NICKEL LEAD ANTIMONY SELENIUM SILICA TIN THALLIUM VANADIUM ZINC
MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L
<0.010 <0.05 <0.005 0.165 <0.005 81.5 <0.005 <0.010 <0.010 <0.010 0.029 <0.0002 3.9 23.9 0.010 123 <0.020 <0.002 <0.05 <0.005 28.0 <0.03 <0.005 0.014 0.243
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METALS - QUALITY CONTROL
CLIENT PROJECT # PROJECT NAME
MONTGOMERY S< ASSOCIATES 562-A HASSAYAMPA ATI I.D, 105570
PARAMETER UNITS ATI I.D. SAMPLE RESULT
DUP. RESULT RPD
SPIKED SPIKE % SAMPLE CONC REC
SILVER ALUMINUM ARSENIC BARIUM BERYLLIUM CALCIUM CADMIUM COBALT CHROMIUM COPPER IRON MERCURY POTASSIUM MAGNESIUM MANGANESE SODIUM NICKEL LEAD ANTIMONY SELENIUM SILICA TIN THALLIUM VAl-JADIUM ZINC
MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L
10557001 10557001 10557001 10557001 10557001 10557001 10557001 10557001 10557001 10557001 10557001 10557001 10557001 10557001 10557001 10557001 10557001 10560909 10557001 10560907 10557001 10557001 10489603 10557001 10557001
<0.010 <0.05 <0.005 0.165 <0.005 81 <0 <0 <0 <0 0.
.5
.005
.010
.010
.010 029
<0.0002 3.9 23.9 0.010 123 <0.020 0.002 <0.05
005 0 03 005
014
<0, 28, <0 <0 0
<0.010 <0.05 <0.005 0.164 <0.005 81.4 0.005 <0.010 <0.010 <0.010 0.030 <0.0002 3.8 23.9 0.010 124 <0.020
002 05 005 ,5 ,03 ,005 014
<0, <0, <0 27 <0 <0 0
NA NA NA 0.6 NA 0.1 NA NA NA NA 3
NA 3 0 0 .8
0.243 0.245 0
NA NA NA NA 1
NA NA 0 8
074 99 050 255 096
131 0.102 097 102 096 997 0048 5
0, 0, 0, 0 0 59 49.0 0.114 172 0.082 0.045 0.98 0.038 244 0.110 0.053 0.116 0.354
0.100 1.00 0.050 0.100 0.100 50.0 0.100 0.100 0.100 0.100 1.00 0.0050 50.0 25.0 0.100 50.0 0.100 0.050 1.00 0.050 214 0.100 0.050 0.100 0.100
74 99 100 101 96 99 102 97 102 96 97 96 111 100 104 98 82 86 98 76 101 110 106 102 111
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration
RPD (Relative Percent Difference)
X 100
(Sample Result - Duplicate Result)
Average Result X 100
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Page No. 06/13/91
QUALITY CONTROL REPORT
ANALYTE INIT DATE OF CORR. QC ANALYSIS COEFF. NAME
VALUE TRUE LOWER UPPER UNIT FOUND VALUE CONTROL CONTROL
LIMIT LIMIT
** ACCESSION NUMBER: 105570
ALKALINITY CHLORIDE CYANIDE E. CONDUCTIVITY FLOURIDE AMMONIA NITRATE pH O-PHOSPHATE SULFATE TDS TOTAL PHOSPHORUS SILVER ALUMINUM ARSENIC BARIUM BERYLLIUM CALCIUM CADMIUM COBALT CHROMIUM COPPER IRON MERCURY POTASSIUM MAGNESIUM MANGANESE SODIUM NICKEL LEAD ANTIMONY SELENIUM SILICA TIN THALLIUM VANADIUM ZINC
MKW WF WF LML MKW TLK WF MKW WF CW EB CW KJB KJB SES KJB KJB KJB KJB KJB KJB KJB KJB JJH KJB KJB KJB KJB KJB SES KJB SES KJB KJB SES KJB KJB
05/13/91 05/09/91 05/08/91 05/06/91 05/14/91 05/22/91 05/13/91 05/13/91 05/03/91 05/13/91 05/06/91 05/15/91 05/16/91 05/16/91 05/15/91 05/16/91 05/16/91 05/23/91 05/2 0/91 05/17/91 05/20/91 05/16/91 05/20/91 05/08/91 05/23/91 05/23/91 05/16/91 05/23/91 05/16/91 05/16/91 05/16/91 05/16/91 05/23/91 05/16/91 05/15/91 05/17/91 05/20/91
NA 0.999 0.999 NA 0.998 0.999 0.999 NA 0.999 0.999 NA 0.999 NA NA 0.999 NA NA NA NA NA NA NA NA 0.999 NA NA NA NA NA 1.000 NA 1.000 NA NA 0.999 NA NA
APG4 87 lO.OQC MACRO O.OIMK APG792 WP987 WP1188 FISHER WP1188 STOCK# APG3 66 ERA992 ICAP2 I CAP 3 WP378 ICAP3 ICAP3 ICAP4 I CAP 3 ICAP3 I CAP 3 ICAP3 ICAP3 WP1085 ICAP4 ICAP4 ICAP3 ICAP4 I CAP 3 WP287 SV 1 WP287 I CAP 4 ICAP3 WP186 ICAP3 ICAP3
124 10.6 0.25 1270 0.60 0.20 2.06 6.87 0.36 9.9 122 4.3 0.092 1.00 34.5 0.101 0.095 10.1 0.104 0.104 0.102 0.097 1.01 2.17 11.1 10.2 0.103 9.9 0.100 16.0 1.00 26.3 11.1 0.10 20.5 0.102 1.04
124 10 oO 0.25 1413 0.60 0.20 2.00 6.86 0.39 10.0 119 5.0 0.100 1.02 30.9 0.095 0.100 10.0 0.105 0.100 0.097 0.095 1.00 2.03 10.0 10.2 0.100 10.0 0.103 20.4 1.04 21.3 10.0 0.09 20.0 0.100 1.00
108 8.5 0,21 1201 0.51 0.15 1.71 5.83 0.31 9.6 102 4.1 0.088 0.92 23.5 0.081 0.085 8.6 0.091 0.085 0.076 0.076 0.855 1.83 8.5 9.4 0.083 8.5 0.090 14.7 0.87 16.3 8.5 0.07 13.7 0.088 0.850
132 11.2 0.29 1625 0.69 0.25 2.27 7.89 0.47 10.5 138 5.2 0.112 1.12 38.4 0.110 0.115 11.3 0.118 0.115 0.118 0.113 1.16 2.23 11.5 10.8 0.118 11.5 0.116 26.0 1.20 26.3 11.5 0.12 26.3 0.112 1.15
MG/L MG/L MG/L UHMOS MG/L MG/L MG/L pH MG/L MG/L MG/L MG/L MG/L MG/L UG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L UG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L UG/L MG/L MG/L UG/L MG/L MG/L
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GAS CHROMATOGRAPHY - RESULTS
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 601/502;
ATI I.D. : 10557001
CLIENT PROJECT # PROJECT NA>:E CLIENT I . D . SAMPLE I A T R I X
MONTGOMERY 6 5 2 - A HASSAYAMPA 014758 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/02/91 05/03/91 N/A 05/15/91 UG/L
1
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHANE CHLOROFORM CHLOROMETHANE DIBROMOCHLOROMETHANE 2-CHLOROETKYL VINYL ETHER 1, 3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DI CHLOROD I FLUOROMETfiANE 1,1-DICHLOROETHANE 2-DICHLOROETHANE 1-DICHLOROETHENE 2-DICHLOROETHENE(TOTAL) , 2-DICHLOROPROPANE
CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1,1,1-TRICHLOROETHANE 1,1,2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
SURROGATE PERCENT RECOVERIES
BROMOCHLOROMETHANE (%) BROMOFLUOROBENZENE (%)
<0. <0. <0. <0. <0. <0. <0. <0. <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <2 <0 <0 <0 <0 <0 <0 <0 <0 <0
5 2 2 2 2 5 2 2 2 2 5 5 5 2 2 2 2 2 2
.2
.2
.5
.0
.2
.2
.5
.2
.2
.2
.5
.2
.5 <2.0
99 98
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GAS CHROMATOGRAPHY - RESULTS
ATI I.D, 10557002
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 601/502)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY & ASSOCIATES 652-A HASSAYAMPA 0147 60 TRIP BLANK AQUEOUS
DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
04/26/91 05/03/91 N/A 05/16/91 UG/L
1
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHANE CHLOROFORM CHLOROMETHANE DIBROMOCHLOROMETHANE 2-CHLOROETHYL VINYL ETHER 1,3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1 , 1-DICHL0R0ETHAJ>JE 1,2-DICHLOROETHANE 1,1-DICHLOROETHENE 1,2-DICHLOROETHENE(TOTAL) 1,2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1,1,1-TRICHLOROETHANE 1,1,2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
<0. <0. <0. <0. <0. <0. <0. <0. <0. <0. <0. <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <2 <0 <0 <0 <0 <0 <0 <0 <0 <0
5 2 2 2 2 5 2 2 2 2 5 5 5 2 2 2 2 2 2 .2 2 .5 .0 .2 .2 .5 .2 .2 .2 .5 .2 .5
<2.0
SURROGATE PERCENT RECOVERIES
BROMOCHLOROMETHANE (%) BROMOFLUOROBENZENE (%)
83 97
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GAS CHROMATOGRAPHY RESULTS
REAGENT BLANK
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 601/502)
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MONTGOMERY S< ASSOCIATES 652-A HASSAYAMPA REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105570 05/15/91 05/15/91 UG/L N/A
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHANE CHLOROFORM CHLOROMETHANE DIBROMOCHLOROMETPIANE 2-CHLOROETHYL VINYL ETHER 1, 3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1 , 1-DICHLOROETHANE 1, 2-DICHLOROETHANE 1 , 1-DICHLOROETHENE 1, 2-DICHLOROETHENE(TOTAL) 1, 2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1., 1, 1-TRICHLOROETHANE 1,1,2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
<0. <0. <0. <0. <0. <0. <0. <0. <0. <0. <0. <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 2.i <0 <0 <0 <0 <0 <0 <0 <0 <0
5 2 2 2 2 5 2 2 2 2 5 5 5 2 2 2 2 2 .2 .2 2 .5 3 .2 .2 .5 .2 .2 .2 .5 .2 .5
<2.0
SURROGATE PERCENT RECOVERIES
BROMOCHLOROMETHANE (%) BROMOFLUOROBENZENE (%)
90 85
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GAS CHROMATOGRAPHY - RESULTS
REAGENT BLANK
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 6 0 1 / 5 0 2 )
CLIENT PROJECT # PROJECT NAJ/E CLIENT I . D .
MONTGOMERY & ASSOCIATES 6 6 2 - A HASSAYAMPA REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105570 05/16/91 05/15/91 UG/L N/A
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHANE CHLOROFORM CHLOROMETHANE DIBROMOCHLOROMETHANE 2-CHLOROETHYL VINYL ETHER 1,3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1 , 1-DICHLOROETI-LANE 1 , 2 - D I C H L O R O S T F L A N E
1 , 1-DICHLOROETHENE 1 , 2-DICHLOROETHENE(TOTAL) 1 , 2-DICHLOROPROPANE C I S - 1 , 3 - D I C H L O R O P R O P E N E TRANS-1,3-DICKLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1 ,1 ,2 ,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1,1,1-TRICKLOROETHANE 1,1,2-TRICKLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENE,? TRICHLOROTRIFLUOROETHANE
<0. <0. <0. <0. <0. <0. <0. <0. <0. <0. <0. <0. <0. <0. <0. <0. <0, <0, <0, <0, <0, <0, 2. <0-<0 <0 <0 <0 <0 <0 <0 <0 <2
5 2 2 2 2 5 2 2 2 2 5 5 5 2 2 2 2 2 2 2 2 5 3 2 2 5 ,2 ,2 .2 .5 .2 .5 .0
SURROGATE PERCENT RECOVERIES
BR0M0CHL0R0N'-ETH.\: 3E { % ) BROMOFLUOROBENZENE (%)
103 91
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QUALITY CONTROL DATA
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 601/6 02) ATI I.D,
CLIENT PROJECT # PROJECT NAME REF I.D.
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA 10599934
DATE ANALYZED SAMPLE MATRIX UNITS
105570
05/20/91
UG/L
COMPOUNDS
DUP. DUP SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC RPD
1,1-DICHLOROETHENE TRICHLOROETHENE TETRACHLOROETHENE BENZENE BROMODICHLOROMETHANE CHLOROFORM 1,1, 1-TRICHLOROETHANE TOLUENE CHLOROBENZENE M-XYLENE
<0.2 <0.2 <0.2 <0.5 <0.2 <0.2 <0.2 <0.5 <0.5 <0.5
20 20 20 20 20 20 20 20 20 20
20 20 19 18 19 20 19 18 19 17
100 100 95 90 95 100 95 90 95 85
20 18 18 18 19 20 18 15 18 16
100 90 90 90 95 100 90 80 90 80
0 11 5 0 0 0 5 12 5 6
% Recovery = (Spike Sample Result - Sample Result;
Spike Concentration X 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of Spiked Sample X 100
A-13
AJS AnolyticolTechnologies,I
7y>oj-9ub T'T
ACCESSION: 105570
QUALITY CONTROL DATA: METHOD 601/602
589
CLIENT: MONTGOMERY AND ASSOCIATES UNITS: UG/L ANALYSIS DATE: 05/15/91
1,1-DICHLOROETHENE TRICHLOROMETHANE 1,1,1-TRICHLOROETHANE BROMODICHLOROMETHANE TRICHLOROETHENE TETRACHLOROETHENE CHLOROBENZENE BENZENE METHYLBENZENE 1,2-DICHLOROBENZENE 1,3-DIMETHYLBENZENE
TRUE VALUE 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0
FOUND 21.2 21.8 19.2 19.7 21.4 20.5 20.2 19.1 18.2 20.9 19.5
% RECOVERY 106 109 96 99 107 103 101 96 91 105 98
% SURROGATE RECOVERY 102 % BROMOCHLOROMETHANE (BCM) 83 % BROMOFLUOROBENZENE (BFB)
A-14
A j S AnalyticolTechnologies
GCMS - RESULTS
/v;(A^-^(;/3> i'y,
ATI I.D. : 10557001
TEST : SEMI-VOLATILE ORGANICS (EPA 5 25;
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY 662-A HASSAYAMPA 014758 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/02/91 05/03/91 05/06/91 05/15/91 UG/L
1
COMPOUNDS RESULTS
N-NITROSODIMETHYLAMINE PHENOL ANILINE BIS(2-CHLOROETHYL)ETHER 2-CHLOROPHENOL 1,3-DICHLOROBENZENE 1 , 4-DICHLOROBENZENE BENZYL ALCOHOL 1 , 2-DICHLOROBENZENE 2-METHYLPnENOL BIS(2-CHLOROlSOPROPYL)ETHER 4-METHYLPHENOL N-NITROSO-DI-N-PROPYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE 2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2-CHLOROETHOXY)METHANE 2,4-DICHLOROPHENOL 1, 2,4-TRICHI-OROBENZENE NAPHTHALENE 4-CHLOROANILINE HEXACHLOROBUTADIENE 4-CHLORO-3-METHYLPHENOL 2-METHYLNAPHTHALENE HEXACHLOROCYCLOPENTADIENE 2,4,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2-CHLORONAPHTHALENE 2-NITROANILINE DIMETHYLPHTHALATE ACENAPHTHYLENE 3-NITROANILINE ACENAPHTHENE 2,4-DINITROPHENOL 4-NITROPHENOL DIBENZOFURAN 2,4-DINITROTOLUENE 2, 6-DINITROTOLUENE
<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <50 <10 <10 <50 <10 <50 <50 <10 <10 <10
(CONTINUED NEXT PAGE) A-15
A j S AnolyticolTechnologies,Inc.
GCMS - RESULTS
TEST : SEMI-VOLATILE ORGANICS (EPA 525)
M^-'^US pT
ATI I.D. : 10557001
COMPOUNDS RESULTS
DIETHYLPHTHALATE 4-CHLOROPHENYL-PHENYLETHER FLUORENE 4-NITROANILINE 4,6-DINITRO-2-METHYLPHENOL N-NITROSODIPHENYLAMINE 4-BROMOPHENYL-PHENYLETHER HEXACHLOROBENZENE PENTACHLOROPHENOL PHENANTHRENE ANTHRACENE DI-N-BUTYLPHTHALATE FLUORANTHENE BENZIDINE PYRENE BUTYLBENZYLPHTHALATE 3,3'-DICHLOROBENZIDINE BENZO(n)ANTHRACENE BIS(2-ETHYLnEXYL)PHTHALATE CHRYSENE DI -N-OCTYLPHTI-L?J.ATE BENZO ( b ) FLUORAIJTHENE BENZO(k)FLUORA:>ITHENE BENZOJa)PYRENE I N D E N O ( 1 , 2 , 3 - c d ) P Y R E N E DIBENZO(a,h)ANTHRACENE B E N Z O ( g , h , i ) P E R Y L E N E
<10 <10 <10 <50 <50 <10 <10 <10 <50 <10 <10 <10 <10 <100 <10 <10 <20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
I
SURROGATE PERCENT RECOVERIES
NITR0BENZENE-D5 (%) 2-FLUOROBIPHENYL (%) TERPHENYL (%) PHEN0L-D6 (%) 2-FLUOROPHENOL (%) 2,4,G-TRIBROMOPHENOL (%)
58 59 123 37 54 42
A-16
A fA\Aj-^lUfb p l
AJS AnalyticolTechnologies,Inc.
ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)
TEST : SEMI-VOLATILE ORGANICS (EPA 525)
ATI I.D. : 10557001
COMPOUNDS
NO ADDITIONAL COMPOUNDS
RESULTS
<20
A-17
AjS AnalyticolTechnologies,Inc.
GCMS - RESULTS
REAGENT BLANK
^'/S, .A^O^'^^UB P r
TEST : SEMI-VOLATILE ORGANICS (EPA 625)
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MONTGOMERY & ASSOCIATES 562-A HASSAYAMPA REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105570 05/06/91 05/15/91 UG/L N/A
COMPOUNDS RESULTS
N-NITR0S0DIMETHYIJy4INE PHENOL ANILINE BIS(2-CHLOROETHYL)ETHER 2-CHLOROPHENOL 1,3-DlCHLOROBENZENE 1,4-DICHLOROBENZENE BENZYL ALCOHOL 1,2-DICHLOROBENZENE 2-METHYLPHENOL BIS(2-CHLOROISOPROPYL)ETHER 4-METHYLPHENOL N-NITROSO-DI-N-PROPYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE 2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2-CHLOROETHOXY)METHANE 2,4-DICHLOROPHENOL 1,2,4-TRICHLOROBENZENE NAPHTHALENE 4-CHLOROANILINE HEXACHLOROBUTADIENE 4-CHLORO-3-METHYLPHENOL 2-METHYLNAPHTHALENE HEXACHLOROCYCLOPENTADIENE 2,4,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2-CHL0R0NAPHTHAI,ENE 2-NITROANILINE DIMETHYLPHTHALATE ACENAPHTHYLENE 3-NITROANILTNE ACENAPHTHENE 2,4-DINITROPHENOL 4-NITROPHENOL DIBENZOFURAN 2,4-DINITROTOLUENE 2,6-DINITROTOLUENE DIETHYLPHTHALATE 4-CHLOROPHENYL-PHENYLETHER
<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <50 <10 <10 <50 <10 <50 <50 <10 <10 <10 <10 <10
I
(CONTINUED NEXT PAGE) A-18
A j S AnolyticolTechnologies,lr
GCMS - RESULTS
REAGENT BLANK
f l i S . MUJ'^^^fi ' 1 1
ATI I.D. : 105570
TEST : SEMI-VOLATILE ORGANICS (EPA 625)
COMPOUNDS RESULTS
FLUORENE 4-NITROANILINE 4 , 6-DINITRO-2-METHYLPHENOL N-NITROSODIPHENYLAMINE 4-BROMOPHENYL-PHENYLETHER HEXACHLOROBENZENE PENTACHLOROPHENOL PHENANTHRENE ANTHRACENE DI-N-BUTYLPHTHALATE FLUORANTHENE BENZIDINE PYRENE BUTYLBENZYLPHTHALATE 3,3'-DICHLOROBENZIDINE BENZO(a)ANTHRACENE BIS(2-ETHYLHEXYL)PHTHALATE CHRYSENE DI-N-OCTYLPHTHALATE BENZO(b)FLUORANTHENE BENZO(k)FLUORANTHENE BENZO(a)PYRENE INDENO(1,2,3-cd)PYRENE DIBENZO(a,h)ANTHRACENE BENZO(g,h,i)PERYLENE
SURROGATE PERCENT RECOVERIES
>) %)
NITROBENZENE-DS 2-FLUOROBIPHENYL TERPHENYL (%) PHEN0L-D6 (%) 2-FLUOROPHENOL (%) 2,4,G-TRIBROMOPHENOL (%)
<10 <50 <50 <10 <10 <10 <50 <10 <10 <10 <10 <100 <10 <10 <20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
67 67 107 45 55 38
A-19
A AJS AnolyticalTechnologies, Inc.
QUALITY CONTROL DATA
TEST : SEMI-VOLATILE ORGANICS (EPA 625)
CLIENT PROJECT # PROJECT NAME REF I.D.
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA 10599905
]Vi-0'^uy2> T l i
ATI I.D,
DATE ANALYZED SAMPLE MATRIX UNITS
105570
05/15/91 SOIL UG/L
COMPOUNDS
DUP. DUP, SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC RPD
1, 2,4-TRICHLOROBENZENE ACENAPHTHENE 2,4-DINITROTOLUENE PYRENE N-NITROSO-DI-N-PROPYLAMINE 1, 4-DICHLOROBENZENE P ENTACHLOROPHENOL PHENOL 2-CHLOROPHENOL 4-CHLORO-3-METHYLPHENOL 4-NITROPHENOL
<10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <50
50 50 50 50 50 50 100 100 100 100 100
31 32 26 52 26 37 61 50 52 47 40
52 64 52 104 52 74 51 50 52 47 40
33 37 31 55 29 38 55 52 58 47 41
66 74 62 110 58 76 55 52 58 47 41
6 14 18 6 11 3 5 4 11
• 0
2
% Recovery = (Spike Sample Result - Sample Result;
Spike Concentration X 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of Spiked Sample X 100
A-20
' ~ h n L U - ' i ( ^ ^ 75/
/ \ AnolyticalTechnologies,lr
ACCESSION: 105570
LABORATORY CONTROL STANDARD: BN/A 889 METHOD: 62 5
CLIENT: MONTGOMERY AND ASSOCIATES UNITS: UG/L ANALYSIS DATE: 05/15/91
PHENOL 1,2-DICHLOROBENZENE HEXACHLOROETHANE ISOPHORONE 2-NITROPHENOL 2,4-DIMETHYLPHENOL HEXACHLOROBUTADIENE 4-CHLORO-3-METHYLPHENOL 2-METHYLNAPHTHALENE ACENAPHTHYLENE 4-NITROPHENOL 2,6-DINITROTOLUENE 4-CHLOROPHENYL PHENYLETHER N-NITROSODI-N-PHENYLAMINE PENTACHLOROPHENOL DI-N-BUTYLPHTHALATE PYRENE BIS(2-ETHYLHEXYL)PHTHALATE
TRUE LIMIT
100 UG/L 100 UG/L 100 UG/L 100 UG/L 100 UG/L 100 UG/L 100 UG/L 100 UG/L 100 UG/L 100 UG/L 100 UG/L 100 UG/L 100 UG/L 100 UG/L 100 UG/L 100 UG/L 100 UG/L 100 UG/L
OBSERVED VALUE
60 73 94 84 85 69 98 76 77 66 51 89 82 64 54 92 116 155
%
60 73 94 84 85 69 98 76 77 66 51 89 82 64 54 92 116 155
LIMIT
37-147 49-151 66-158 46-134 33-159 22-148 70-150 30-166 50-138 51-117 MDL-173 49-145 52-140 56-136 23-169 43-151 50-156 41-191
A-21
k
A i S AnolyticalTechnologies,Inc.
/>i^v-^(/^ /^7~
GAS CHROMATOGRAPHY - RESULTS
ATI I.D. : 10557001
TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 508)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY 6 62-A HASSAYAMPA 014758 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/02/91 05/03/91 05/06/91 05/16/91 UG/L
1
COMPOUNDS RESULTS
ALDRIN ALPHA BHC BETA BHC GAMMA BHC (LINDANE) DELTA BHC ALPHA-CHLORDANE 4,4'-DDD 4,4'-DDE 4,4'-DDT DIELDRIN ENDOSULFAN I ENDOSULFAN II ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE ENDRIN KETONE HEPTACHLOR HEPTACHLOR EPOXIDE METHOXYCHLOR TOXAPHENE AROCLOR 1016 AROCLOR 1221 AROCLOR 123 2 AROCLOR 124 2 AROCLOR 124 8 AROCLOR 12 54 AROCLOR 126 0 GAMMA-CHLORDANE
<0.05 <0.05 <0.05 <0.05 <0.05 <0.5 <0.1 <0.1 <0.1 <0.1 <0.05 <0.1 <0.1 <0.1 <0.1 <0.1 <0.05 <0.05 <0.5 <1.0 <0 <0
<0, <0, <0 <0 <0
<0.5
SURROGATE PERCENT RECOVERIES
DBC ( % 120
A-22
/2,8, c/^^''(^uQ j > r
A A j S AnalyticalTechnologies, Inc.
GAS CHROMATOGRAPHY RESULTS
REAGENT BLANK
TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 608)
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105570 05/06/91 05/16/91 UG/L N/A
COMPOUNDS RESULTS
ALDRIN ALPHA BHC BETA BHC GAMNIA BHC (LINDANE) DELTA BHC ALPHA-CHLORDANE 4,4'-DDD 4,4'-DDE 4,4'-DDT DIELDRIN ENDOSULFAN I ENDOSULFAN II ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE ENDRIN KETONE HEPTACHLOR HEPTACHLOR EPOXIDE METHOXYCHLOR TOXAPHENE AROCLOR 1016 AROCLOR 122] AROCLOR 123 2 AROCLOR 124 2 AROCLOR 124B AROCLOR 1254 AROCLOR 126 0 GAM14A-CHL0RDANE
<0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0
• < o
<1 <0 <0 <0 <0 <0 <0 <0 <0
.05
.05
.05
.05
.05
.5
.1
.1
.1
.1
.05
.1
.1
.1
.1
.1
.05
.05
.5
.0
.5
.5
.5
.5
.5
.5
.5
.5
SURROGATE PERCENT RECOVERIES
DBC 101
A-23
0r?/J-9u:^ ?"/
/ \ AnolyticolTechnologies,lr
QUALITY CONTROL DATA ATI I.D,
TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 608) 105570
CLIENT PROJECT # PROJECT NAME REF I.D.
MONTGOMERY & ASSOCIATES 5 6 2-A HASSAYAMPA 10599907
DATE ANALYZED SAMPLE MATRIX UNITS
05/09/91 SOIL UG/L
COMPOUNDS
DUP. DUP SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC RPD
GAMMA BHC HEPTACHLOR ALDRIN DIELDRIN ENDRIN DDT
<0 <0 <0 <0 <0 <0
05 05 05 1 1 1
2.0 2.0 2.0 2.0 2.0 2.0
2 2 2 2 2 2
1 0 1 1 1 1
105 100 105 105 105 105
2 1 2 2 2 2
1 8 1 1 1 0
105 90 105 105 105 100
0 11 0 0 0 5
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration X 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike Result Sample Result
Average of Spiked Sample 100
A-24
A^i'j-'^uS P T
^ J S ^ AnolyticolTechnologies, Inc.
ACCESSION: 105570
LABORATORY CONTROL STANDARD: METHOD: 608
CLP
CLIENT: MONTGOMERY AND ASSOCIATES UNITS: UG/L ANALYSIS DATE: 05/15/91
COMPOUND
GAMMA BHC HEPTACHLOR ALDRIN DIELDRIN ENDRIN 4,4-DDT
TRUE VALUE
2.0 2.0 2.0 2.0 2.0 2.0
FOUND
2.2 2.2 2.1 2.1 2.2 2.1
% REC
110 110 105 105 110 105
A-25
,1 #
/ j J i \ AnalyticalTechnologies, Inc. 9330 S. sist street suite B-I 13 Ptioenlx, AZ 35044 (602)496-4400
ATI I.D. 105644
June 24, 1991
Errol L. Montgomery & Associates 1075 E. Fort Lowell Road Suite B Tucson, AZ 85719
Project Name/Number: Hassayampa 662-A
Attention: Bill Victor •
On 05/09/91, Analytical Technologies, Inc. received a request to analyze aqueous sample(s). The sample(s) were analyzed with EPA methodology or equivalent methods. The results of these analyses and the quality control data, which follow each set of analyses, are enclosed.
The method 624 sample 004457 and 004459 (trip blank) surrogate percent recovery for 1,2-dichloroethane-D4 is out of ATI acceptable criteria due to equipment failure. We apologize for any inconvenience this may cause.
If you have any questions or comments, please do not hesitate to contact us at (602) 496-4400.
Michael G. Barry Project Manager
(p<MA^yU^yU^ Lorraine Davis QA Coordinator
RVW:clf Enclosure
(2y>Lr I/. 0(mA Rober t V. Woods L a b o r a t o r y Manager
Corporate Offices: 5550 Morehouse Drive San Diego. CA 92121 (619) 458-9141
A-26
A j S AnolyticolTechnologies,I
CLIENT PROJECT # PROJECT NAME
nc.
MONTGOMERY & ASSOCIATES 652-A HASSAYAMPA
ATI I.D. : 105644
DATE RECEIVED : 05/09/91
REPORT DATE : 06/21/91
ATI # CLIENT DESCRIPTION MATRIX DATE COLLECTED
01 02 03
004457 004458 004459 TRIP BLANK
AQUEOUS AQUEOUS AQUEOUS
05/07/91 05/07/91 05/06/91
TOTALS
MATRIX
AQUEOUS
# SAMPLES
3
ATI STANDARD DISPOSAL PRACTICE
The samples from this project will be disposed of in thirty (30) days from the date of this report. If an extended storage period is required, please contact our sample control department before the scheduled disposal date.
A-27
AlU/ - 1(^A
^JSj AnolyticolTechnologies, nc.
GENERAL CHEMISTRY RESULTS
CLIENT PROJECT # PROJECT NAME
MONTGOMERY 662-A HASSAYAMPA
& ASSOCIATES
ATI I.D. : 105644
DATE RECEIVED : 05/09/91
REPORT DATE : 06/21/91
PARAMETER UNITS 01
CARBONATE (CAC03) MG/L 6 BICARBONATE (CAC03) MG/L 223 HYDROXIDE (CAC03) MG/L <1 TOTAL ALKALINITY (AS CAC03) MG/L 229 CHLORIDE MG/L 64 CYANIDE, TOTAL MG/L <0.01 CONDUCTIVITY, (UMHOS/CM) 800 FLUORIDE MG/L 2.32 AMMONIA AS NITROGEN MG/L 0.03 NITRATE AS NITROGEN MG/L 8.1 PH UNITS 8.5 PHOSPHATE,ORTHO (AS P) MG/L <0.05 SULFATE MG/L 7 8 TOTAL DISSOLVED SOLIDS MG/L 510 PHOSPHOROUS,TOTAL MG/L <0.05
A-28
)7)UJ-9^A
A / ^ AnalyticalTechnologies, Inc.
GENERAL CHEMISTRY - QUALITY CONTROL
CLIENT : MONTGOMERY & ASSOCIATES PROJECT # : 56 2-A PROJECT NAME : HASSAYAMPA
PARAMETER
CARBONATE BICARBONATE HYDROXIDE TOTAL ALKALINITY CHLORIDE CYANIDE, TOTAL CONDUCTIVITY(UMHOS/CM) FLUORIDE AMMONIA AS NITROGEN NITRATE AS NITROGEN PH PHOSPHATE, ORTHO SULFATE TOTAL DISSOLVED SOLIDS PHOSPHOROUS,TOTAL
UNITS
MG/L MG/L MG/L MG/L MG/L MG/L
MG/L MG/L MG/L UNITS MG/L MG/L MG/L MG/L
ATI I.D.
10564401
10564401 10564401 10554401 10564401 10564401 10554401 10554401 10564401 10554401 10554401 10564401
SAMPLE RESULT
6 223 <1 229 64 <0.01 800 2.32 0.03 8.1 8.5 <0.05 78 510 <0.05
ATI
DUP. RESULT
4 222 <1 226 64 <0.01 804 2.35 0.03 8.1 8.5 <0.05 78 520 <0.05
I.D.
RPD
40 0.4 NA 1 0
NA 0.5
2 0 0 0
NA 0 2
NA
: 105644
SPIKED SAMPLE
NA NA NA NA 170 0.24 NA 4.87 0.48 18.7 NA 0.54 160 NA 0.51
SPIKE CONC
NA NA NA NA 100 0.25 NA 2.50 0.50 10.0 NA 0.50 78 NA . 0.50
% REC
NA NA NA NA 106 96 NA 102 90 105 NA 108 105 NA 102
X 100 % Recovery = (Spike Sample Result - Sample Result)
Spike Concentration
RPD (Relative Percent Difference) = (Sample Result - Duplicate Result) X 100
Average Result
A-29
A j S AnolyticolTechnologies,!
METALS RESULTS
^ 1^ ~ c j \ j 4
CLIENT PROJECT # PROJECT NAME
MONTGOMERY & ASSOCIATES 652-A HASSAYAMPA
ATI I.D. : 105644
DATE RECEIVED : 05/09/91
REPORT DATE : 05/21/91
PARAMETER UNITS 01
SILVER ALUMINUM ARSENIC BORON BARIUM BERYLLIUM CALCIUM CADMIUM COBALT CHROMIUM COPPER IRON MERCURY POTASSIUM MAGNESIUM MANGANESE SODIUM NICKEL LEAD ANTIMONY SELENIUM SILICA TIN THALLIUM VANADIUM ZINC
MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L
<0.010 <0.05 0.009 0.38 0.051 <0.005 20.8 <0.005 <0.010 0.015 <0.010 0.021 <0.0002 1.6 8.2 <0.010 149 <0.020 0.002 <0.05 <0.005 31.2 <0.03 <0.005 0.030 0.093
A-30
A j S AnolyticolTechnologies ., Inc.
METALS - QUALITY CONTROL
CLIENT : MONTGOMERY & ASSOCIATES PROJECT # : 65 2-A PROJECT NAME : HASSAYAMPA ATI I.D,
)viv-i^4
105644
PARAMETER UNITS ATI I.D. SAMPLE RESULT
DUP. RESULT RPD
SPIKED SPIKE % SAMPLE CONC REC
SILVER ALUMINUM ARSENIC BORON BARIUM BERYLLIUM CALCIUM CADMIUM COBALT CHROMIUM COPPER IRON MERCURY POTASSIUM MAGNESIUM MANGANESE SODIUM NICKEL LEAD ANTIMONY SELENIUM SILICA . TIN THALLIUM VANADIUM ZINC
MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L
10564401 10564401 10554401 10564401 10564401 10564401 10564401 10554401 10564401 10564401 10564401 10564401 10563801 10554401 10564401 10564401 10554401 10564401 10551301 10564401 10564401 10554401 10564401 10564401 10564401 10554401
<0.010 <0.05 0.009 0.38 0.061 <0.005 20.8 <0.005 <0.010 0.015 <0.010 0.021 <0.0002 1.6 8.2 <0.010 149 <0.020 0.002 <0.05 1 <0.005 31.2 <0.03 <0.005 0.030 0.093
<0.010 <0.05 0.007 0.37 0.060 <0.005 20.9 <0.005 <0.010 0.017 <0.010 <0.020 <0.0002 1.9 8.2 <0.010 156 <0.020 <0.002 <0.05 <0.005 31.7 0.03 <0.005 0.031 0.092
NA NA 25 3 2
NA 0.5 NA NA 6
NA NA NA 17 0
NA 5
NA NA NA NA 2
NA NA 3 1
0.098 1.03 0.051 1.37 0.162 0.101 71 .4 0.095 0.103 0.112 0.113 0.920 0.0047 57.0 32.8 0.100 245 0.095 0.051 1.03 0.042 237 0.10 0.047 0.134 0.210
0.100 1.00 0.050 1 .00 0.100 0.100 50.0 0.100 0.100 0.100 0.100 1.00 0.0050 50.0 25.0 0.100 100 0.100 0.050 1.00 0.050 214 0.10 0.050 0.100 0.100
98 103 84-99 101 101 101 95 103 96 113 90 94 111 98 100 95 95 98 103 84 96 100 94 104 117
X 100 % Recovery = (Spike Sample Result - Sample Result)
Spike Concentration
RPD (Relative Percent Difference) = (Sample Result - Duplicate Result)
Average Result X 100
A-31
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A j S AnalyticalTechnologies,Inc.
Page No. 06/19/90
QUALITY CONTROL REPORT
ANALYTE INIT DATE OF CORR. QC ANALYSIS COEFF. NAME
VALUE TRUE LOWER UPPER UN FOUND VALUE CONTROL CONTROL
LIMIT LIMIT
** ACCESSION NUMBER: 105644
METHOD 200.7 SILVER ALUMINUM BORON BARIUM BERYLLIUM CALCIUM CADMIUM COBALT CHROMIUM COPPER IRON POTASSIUM MAGNESIUM MANGANESE SODIUM NICKEL ANTIMONY SILICA TIN VANADIUM ZINC
METHOD 23 9.2 LEAD
NM 05/21/91 NA ICAP21 0.099 NM 05/21/91 NA ICAP31 0.984 KJB 05/15/91 NA ICAP7 0.98 NM 05/21/91 NA ICAP3 0.101 NM 05/21/91 NA ICAP3 0.097 KJB 05/15/91 NA ICAP4 10.0 NM 05/23/91 NA ICAP3 0.102 NM 05/21/91 NA ICAP3 0.105 NM 05/23/91 NA ICAP3 0.101 NM 05/21/91 NA ICAP3 0.100 NM 05/23/91 NA ICAP3 0.985 KJB 05/23/91 NA ICAP4 11.1 KJB 05/15/91 NA ICAP4 10.1 NM 05/21/91 NA ICAP3 0.101 KJB 05/15/91 NA ICAP4 10.0 NM 05/21/91 NA ICAP3 0.095 NM 05/21/91 NA SVI 1.00 KJB 05/15/91 NA ICAP4 11.4 NM 05/21/91 NA ICAP3 0.09 NM 05/21/91 NA ICAP3 0.100 NM 05/21/91 NA ICAP3 0.103
100 02 99 095 100
10.0 0.105 0.100 0.097 0.095 1.00 10.0 10.2 0.100 10.0 0.103 1.04 10.0 0.09 0.100 0.109
088 920 90 081 085 6 091 085 076 076 855 5 4 083 5 090 87 5 07 088 092
0, 0, 0, 1,
KJB 05/20/91 0.999 WP2871 21.6 20.4 14.7
0.112 1.12 1.07 0.110 0.115 11.3 0.118
115 118 113 16
11.5 10.8 0.118 11.5 0.116 1.20 11.5 0.12 0.112 0.126
26.0
MG MG MG MG MG MG MG MG MG MG MG MG MG MG MG MG MG MG MG MG MG
UG
METHOD 245.1 MERCURY NM 05/14/91 0.999 WP1085 2.23 2.03 1.83 2.23 UG
METHOD 160.1 TDS LML 05/10/91 NA APG366 134 119 102 138 MG
METHOD 300.0 SULFATE CW 05/14/91 0.999 ST0CK2 9.8 10.0 9.6
METHOD 3 65.3 ORTHO PHOSPHATE CW 05/09/91 0.999 WP1188 0.35 0.39 0.31 TOTAL PHOSPHORUS CW 05/15/91 0.999 ERA992 4.3 5.0 4.1
10.5
0.47 5.2
MG
MG MG
A-32 \
f ^
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Ajj^ AnolyticolTechnologies, Inc.
Page No. 06/19/90
ANALYTE
QUALITY CONTROL REPORT
INIT DATE OF CORR. QC VALUE TRUE LOWER UPPER UNIT ANALYSIS COEFF. NAME FOUND VALUE CONTROL CONTROL
LIMIT LIMIT
** ACCESSION NUMBER: 105644
METHOD 150.1 pH
METHOD 353.2 NITRATE
METHOD 3 50.3 AMMONIA
METHOD 3 4 0.2 FLUORIDE
METHOD 120.1 CONDUCTIVITY
METHOD 3 35.2 CYANIDE
METHOD 3 25.2 CHLORIDE
METHOD 310.1 ALKALINITY
METHOD 279.2 THALLIUM
METHOD 27 0.2 SELENIUM
METHOD 2 06.2 ARSENIC
MKW 05/20/91 NA
NM 05/14/91 0.999
TLK 05/28/91 0.999
MKW 05/22/91 0.999
SH 05/09/91 NA
WF 05/15/91 0.999
WF 05/09/91 0.999
MKW 05/20/91 NA
KJB 05/22/91 0.999
KJB 05/22/91 0.998
NM 05/20/91 1.000
FISHER 6.87 6.86 5.83 7.89 pH
QC1188 2.00 2.00 1.71 2.28 MG/L
WP987 0.19 0.20 0.14 0.21 MG/L
APG792 3.02 3.01 2.97 3.11 MG/L
O.OIMK 1370 1413 1201 1625 UMHOS
QCMACR 0.28 0.25 0.21 0.29
lO.OQC 10.6 10.0 8.5
APG487 123 124 108
11.2
132
WP186 19.4 20.0 13.7 26.3
WP287 21.9 21.3 16.3 26.3
378-12 34.0 30.9 23.5 38.4
MG/L
MG/L
MG/L
UG/L
UG/L
UG/L
A-33
r ^
/ \ AnalyticalTechnologies,Inc.
GCMS - RESULTS
/V) k^ - ^ t//1
ATI I.D. : 10564401
TEST : VOLATILE ORGANICS (EPA 624)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY 662-A HASSAYAMPA 004457 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/07/91 05/09/91 N/A 05/20/91 UG/L
1
COMPOUNDS RESULTS
CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHAN E 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES
SURROGATE PERCENT RECOVERIES
l,2-DICHLOROETHANE-D4 (%) BROMOFLUOROBENZENE (%) T0LUENE-D8 (%)
A-34
<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1
124 105 106
r^iK/ - ^ u / \
A / \ AnolyticolTechnologies,Inc.
ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)
TEST : VOLATILE ORGANICS (EPA 524)
ATI I.D. : 10564401
COMPOUNDS
NO ADDITIONAL COMPOUNDS
RESULTS
<5
A-35
/ K AnolyticolTechnologies
GCMS - RESULTS
r-/3. y i ^ i^ - fuA
ATI I.D. : 10564403
TEST : VOLATILE ORGANICS (EPA 6 24)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY & ASSOCIATES 652-A HASSAYAMPA 004459 TRIP BLANK AQUEOUS
DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/05/91 05/09/91 N/A 05/18/91 UG/L
1
COMPOUNDS RESULTS
CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1, 2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1, 2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1, 3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4 - M E T H Y L - 2 - P E N T A : J 0 N E (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES
SURROGATE PERCENT RECOVERIES
l,2-DICHLOROETHANE-D4 (%) BROMOFLUOROBENZENE (%) . T0LUENE-D8 (%)
<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 < 1 •
<1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1
126 100 100
A-36
T.^. for'
AJS AnalyticolTechnologies,Inc.
ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)
A
TEST : VOLATILE ORGANICS (EPA 5 24)
ATI I.D. : 10554403
COMPOUNDS
NO ADDITIONAL COMPOUNDS
RESULTS
<5
A-37
."B 4c-: TB.
AjS AnolyticolTechnologies,Inc
GCMS - RESULTS
REAGENT BLANK
TEST : VOLATILE ORGANICS (EPA 624)
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MONTGOMERY & ASSOCIATES 562-A HASSAYAMPA REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105644 05/17/91 05/17/91 UG/L N/A
COMPOUNDS RESULTS
CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1, 1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES
SURROGATE PERCENT RECOVERIES
l,2-DICHLOROETHANE-D4 (%) BROMOFLUOROBENZENE (%) T0LUENE-D8 (%)
<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1
101 98 102
A-38
AjS AnalyticalTechnologies,Inc.
GCMS - RESULTS
REAGENT BLANK
/e,J^. Ai iA^-^i /A
TEST : VOLATILE ORGANICS (EPA 5 24)
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MONTGOMERY & ASSOCIATES 552-A HASSAYAMPA REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105544 05/20/91 05/20/91 UG/L N/A
COMPOUNDS RESULTS
CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES
<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 < 1 < 1 < 1 < 1 <1 < 1 <1 < 1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1
SURROGATE PERCENT RECOVERIES'
l,2-DICHLOROETHANE-D4 (%) BROMOFLUOROBENZENE (%) T0LUENE-D8 (%)
120 95 102
A-39
TyiiO'^^iL^
A A j S AnolyticalTechnologies,Inc.
QUALITY CONTROL DATA
TEST : VOLATILE ORGANICS (EPA 5 24)
CLIENT PROJECT # PROJECT NAME REF I.D.
MONTGOMERY & ASSOCIATES 6 5 2-A HASSAYAMPA 10599935
ATI I.D, : 105644
DATE ANALYZED : 05/17/91 SAMPLE MATRIX : UNITS : UG/L
COMPOUNDS
DUP. DUP, SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC RPD
1,1-DICHLOROETHENE TRICHLOROETHENE CHLOROBENZENE TOLUENE BENZENE
<1 <1 <1 <1 <1
50 50 50 50 50
55 49 51 51 41
110 54 98 48 102 51 102 51 82 41
108 96 102 102 82
2 2 0 0 0
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of Spiked Sample X 100
A-40
Jy iLV'^uy
/ \ AnolyticolTechnologies,lr
ACCESSION: 105644
QUALITY CONTROL DATA: 589 METHOD 624
CLIENT: MONTGOMERY & ASSOCIATES UNITS: UG/L ANALYSIS DATE: 05/17/91
1,1-DICHLOROETHENE CHLOROFORM 1,1,1-TRICHLOROETHANE BROMODICHLOROMETHANE TRICHLOROETHENE TETRACHLOROETHENE CHLOROBENZENE BENZENE TOLUENE
TRUE VALUE
50 50 50 50 50 50 50 50 50
FOUND
56 61 48 48 49 53 51 41 52
% R
112 122 96 96 98 106 102 82 104
% SURROGATE RECOVERY 116% l,2-DICHLOROETHANE-D4 101% BROMOFLUOROBENZENE (BFB) 100% TOLUENE - D8
A-41
/ #
l V L V - 9 ^ ^
/ j \ AnolyticolTechnologies
ACCESSION: 105644
QUALITY CONTROL DATA: 589 METHOD 624
CLIENT: MONTGOMERY & ASSOCIATES UNITS: UG/L ANALYSIS DATE: 05/20/91
1,1-DICHLOROETHENE CHLOROFORM 1,1,1-TRICHLOROETHANE BROMODICHLOROMETHANE TRICHLOROETHENE TETRACHLOROETHENE CHLOROBENZENE BENZENE TOLUENE
TRUE VALU
50 50 50 50 50 50 50 50 50
E FOUND
60 58 47 48 47 51 49 41 51
% R
120 116 94 96 94 102 98 82 102
% SURROGATE RECOVERY 115% 1,2-DICHL0R0ETHANE-D4 98% BROMOFLUOROBENZENE (BFB) 101% TOLUENE - D8
A-42
i
AJS AnalyticalTechnologies,Inc.
GCMS - RESULTS
/i^uy^^t/A
ATI I.D. : 10564 4 01
TEST : SEMI-VOLATILE ORGANICS (EPA 625
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX : AQUEOUS
MONTGOMERY & ASSOCIATES 562-A HASSAYAMPA 004457
DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/07/91 05/09/91 05/13/91 05/16/91 UG/L
1
COMPOUNDS RESULTS
N-NITROSODIMETHYLAMINE PHENOL ANILINE BIS(2-CHLOROETHYL)ETHER 2-CHLOROPHENOL 1, 3-DICHLOROBENZENE 1, 4-DICHLOROBENZENE BENZYL ALCOHOL 1, 2-DICHLOROBENZENE 2-METHYLPHENOL BIS(2-CHLOROISOPROPYL)ETHER 4-METHYLPHENOL N-NITROSO-DI-N-PROPYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE 2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2-CHLOROETHOXY)METHANE 2,4-DICHLOROPHENOL 1, 2,4-TRICHLOROBENZENE NAPHTHALENE 4-CHLOROANILINE HEXACHLOROBUTADIENE 4-CHLORO-3-METHYLPHENOL 2-METHYLNAPHTHALENE HEXACHLOROCYCLOPENTADIENE 2 ,4,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2-CHLORONAPHTHALENE 2-NITROANILINE DIMETHYLPHTHALATE ACENAPHTHYLENE 3-NITROANILINE ACENAPHTHENE 2,4-DINITROPHENOL 4-NITROPHENOL DIBENZOFURAN 2,4-DINITROTOLUENE 2,6-DINITROTOLUENE
<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <50 <10 <10 <50 <10 <50 <50 <10 <10 <10
A-43 (CONTINUED NEXT PAGE)
A j S AnolyticalTechnologies,Inc.
GCMS - RESULTS ATI I.D.
'h^LiJ-9uy<l
10564401
TEST : SEMI-VOLATILE ORGANICS (EPA 625)
COMPOUNDS RESULTS
DIETHYLPHTHALATE 4-CHLOROPHENYL-PHENYLETHER FLUORENE 4-NITROANILINE 4,6-DINITRO-2-METHYLPHENOL N-NITROSODIPHENYLAMINE 4-BROMOPHENYL-PHENYLETHER HEXACHLOROBENZENE PENTACHLOROPHENOL PHENANTHRENE ANTHRACENE DI-N-BUTYLPHTHALATE FLUORANTHENE BENZIDINE PYRENE BUTYLBENZYLPHTHALATE 3,3'-DICHLOROBENZIDINE BENZO(a)ANTHRACENE BIS(2-ETHYLHEXYL)PHTHALATE CHRYSENE DI-N-OCTYLPHTHALATE BENZO(b)FLUORANTHENE BENZO(k)FLUORANTHENE BENZO(a)PYRENE INDENO(1,2,3-cd)PYRENE DIBENZO(a,h)ANTHRACENE BENZO(g,h,i)PERYLENE
<10 <10 <10 <50 <50 <10 <10 <10 <50 <10 <10 <10 <10 <100 <10 <10 <20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
SURROGATE PERCENT RECOVERIES
NITROBENZENE-DS (%) 2-FLUOROBIPHENYL (%) TERPHENYL (%) PHEN0L-D6 (%) 2-FLUOROPHENOL (%) 2,4, 6-TRIBROMOPHENOL (%)
48 45 55 33 38 22
A-44
AJS AnalyticalTechnologies, Inc.
ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)
A
TEST : SEMI-VOLATILE ORGANICS (EPA 625)
ATI I.D. : 10564401
COMPOUNDS
NO ADDITIONAL COMPOUNDS
RESULTS
<20
A-45
12.5. AAu^/-<s}l/A
A j S AnalyticolTechnologies, ^
Inc.
GCMS - RESULTS
REAGENT BLANK
iTEST : SEMI-VOLATILE ORGANICS (EPA 525)
CLIENT PROJECT # I PROJECT NAME ICLIENT I.D.
MONTGOMERY & ASSOCIATES 562-A HASSAYAMPA REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105644 05/13/91 05/15/91 UG/L N/A
COMPOUNDS RESULTS
N-NITROSODIMETHYLAMINE PHENOL ANILINE BIS(2-CHLOROETHYL)ETHER 2-CHLOROPHENOL I 1,3-DICHLOROBENZENE 1,4-DICHLOROBENZENE BENZYL ALCOHOL 1, 2-DICHLOROBENZENE I2-METHYLPHENOL I BIS(2-CHLOROISOPROPYL)ETHER 4-METHYLPHENOL IN-NITROSO-DI-N-PROPYLAMINE HE.XACHLOROETHANE NITROBENZENE ISOPHORONE I 2-NITROPHENOL I 2,4-DIMETHYLPHENOL BENZOIC ACID I BIS(2-CHLOROETHOXY)METHANE 2,4-DICHLOROPHENOL 1,2,4-TRICHLOROBENZENE NAPHTHALENE 4-CHLOROANILINE
I HEXACHLOROBUTADIENE 4-CHLORO-3-METHYLPHENOL
I 2-METHYLNAPHTHALENE HEXACHLOROCYCLOPENTADIENE 2,4,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL
j 2-CHLORONAPHTHALENE I 2-NITROANILINE DIMETHYLPHTHALATE
j ACENAPHTHYLENE 3-NITROANILINE
' ACENAPHTHENE 2,4-DINITROPHENOL
I 4-NITROPHENOL I DIBENZOFURAN 2,4-DINITROTOLUENE
j 2,6-DINITROTOLUENE DIETHYLPHTHALATE 4-CHLOROPHENYL-PHENYLETHER
<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <50 <10 <10 <50 <10 •<50 <50 <10 <10 <10 <10 <10
(CONTINUED NEXT PAGE) A-46
^jS^ AnolyticalTechnologies, Ir
GCMS - RESULTS
REAGENT BLANK
TEST : SEMI-VOLATILE ORGANICS (EPA 625)
7^-~B. -Tor-VILO-^ IAA
ATI I.D. 105544
COMPOUNDS RESULTS
FLUORENE 4-NITROANILINE 4 , 6-DINITRO-2-METHYLPHENOL N-NITROSODIPHENYLAMINE 4-BROMOPHENYL-PHENYLETHER HEXACHLOROBENZENE PENTACHLOROPHENOL PHENANTHRENE ANTHRACENE DI-N-BUTYLPHTHALATE FLUORANTHENE BENZIDINE PYRENE BUTYLBENZYLPHTHALATE 3,3'-DICHLOROBENZIDINE BENZO(a)ANTHRACENE BIS(2-ETHYLHEXYL)PHTHALATE CHRYSENE DI-N-OCTYLPHTHALATE BENZO(b)FLUORANTHENE BENZO(k)FLUORANTHENE BENZO(a)PYRENE INDEN0(1,2,3-cd)PYRENE DIBENZO(a,h)ANTHRACENE BENZO(g,h,i)PERYLENE
SURROGATE PERCENT RECOVERIES
NITROBENZENE-DS (%) 2-FLUOROBIPHENYL (%) TERPHENYL (%) PHEN0L-D6 (%) 2-FLUOROPHENOL (%) 2,4,6-TRIBROMOPHENOL (%)
<10 <50 <50 <10 <10 <10 <50 <10 <10 <10 <10 <100 <10 <10 <20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
69 63 57 42 47 46
A-47
/ K AnolyticalTechnologies,!
VIU;-<^MA
QUALITY CONTROL DATA
TEST : SEMI-VOLATILE ORGANICS (EPA 525)
CLIENT PROJECT # PROJECT NAME REF I.D.
MONTGOMERY & ASSOCIATES 652-A HASSAYAMPA 10599915
ATI I.D.
DATE ANALYZED SAMPLE MATRIX UNITS
: 105644
05/16/91
UG/L
COMPOUNDS
DUP. DUP, SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC. RPD
1,2,4-TRICHLOROBENZENE ACENAPHTHENE 2,4-DINITROTOLUENE PYRENE N-NITROSO-DI-N-PROPYLAMINE 1,4-DICHLOROBENZENE PENTACHLOROPHENOL PHENOL 2-CHLOROPHENOL 4-CHLORO-3-METHYLPHENOL 4-NITROPHENOL
<10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <50
50 50 50 50 50 50 100 100 100 100 100
29 25 32 30 28 29 48 61 67 78 62
58 52 64 60 55 58 48 61 67 78 62
27 26 29 30 25 30 47 62 68 79 71
54 52 58 60 50 60 47 52 58 79 71
7 0 10 0 11 3 2 2 1 1 14
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of Spiked Sample 100
A-48
A j S AnalyticolTechnologies,I
tnwJ -HlA;^
ACCESSION: 105644
LABORATORY CONTROL STANDARD 889 BN/A METHOD 625
CLIENT: MONTGOMERY & ASSOCIATES UNITS: UG/L ANALYSIS DATE: 05/15/91
PHENOL 1,2-DICHLOROBENZENE HEXACHLOROETHANE ISOPHORONE 2-NITROPHENOL 2,4-DIMETHYLPHENOL HEXACHLOROBUTADIENE 4-CHLORO-3-METHYLPHENOL 2-METHYLNAPHTHALENE ACENAPHTHYLENE 4-NITROPHENOL 2,6-DINITROTOLUENE 4-CHLOROPHENYL PHENYLETHER N-NITROSODI-N-PHENYLAMINE PENTACHLOROPHENOL DI-N-BUTYLPHTHALATE PYRENE BIS(2-ETHYLHEXYL)PHTHALATE
TRUE VALUE
100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100
OBSERVED VALUE
60 73 94 84 85 69 98 76 77 66 51 89 82 64 54 92 116 155
% R
60 73 94 84 85 69 98 76 77 66 51 89 82 64 54 92 116 155
A-49
^ ^
/Vl Ux - < ^ u A
AjS AnolyticolTechnologies, Inc.
GAS CHROMATOGRAPHY - RESULTS
ATI I.D, 10564401
TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 508)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY 662-A HASSAYAMPA 004457 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/07/91 05/09/91 05/13/91 05/20/91 UG/L
1
COMPOUNDS RESULTS
ALDRIN ALPHA BHC BETA BHC GAMMA BHC (LINDANE) DELTA BHC ALPHA-CHLORDANE 4,4'-DDD 4,4'-DDE 4,4'-DDT DIELDRIN ENDOSULFAN I ENDOSULFAN II ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE ENDRIN KETONE HEPTACHLOR HEPTACHLOR EPOXIDE METHOXYCHLOR TOXAPHENE AROCLOR 1016 AROCLOR 1221 AROCLOR 123 2 AROCLOR 1242 AROCLOR 1248 AROCLOR 1254 AROCLOR 1260 GAMMA-CHLORDAl^JE
<0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <1 <0 <0 <0 <0 <0 <0 <0 <0
.05
.05
.05
.05
.05
.5
.1
.1
.1
.1
.05
.1
.1
.1
.1
.1
.05
.05
.5
.0
.5
.5
.5
.5
.5
.5
.5
.5
SURROGATE PERCENT RECOVERIES
DBC (%) 101
A-50
fZ.e>. Po/2. / ^ ^ - ' i u A
K ^JS^ AnolyticolTechnologies, Inc.
GAS CHROMATOGRAPHY - RESULTS
REAGENT BLANK
TEST : ORGANOCHLORINE
CLIENT PROJECT # PROJECT NAME CLIENT L . D .
P E S T I C I D E S AND P C B ' S
MONTGOMERY & ASSOCIATES 5 6 2 - A HASSAYAMPA
. REAGENT
COMPOUNDS
ALDRIN ALPHA BHC BETA BHC GAMMA BHC (LINDANE) DELTA BHC ALPHA-CHLORDANE 4 , 4 ' - D D D 4 , 4 ' - D D E 4 , 4 ' - D D T DIELDRIN ENDOSULFAN I ENDOSULFAN I I ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE ENDRIN KETONE HEPTACHLOR HEPTACHLOR EPOXIDE METHOXYCHLOR TOXAPHENE AROCLOR 1 0 1 6 AROCLOR 1 2 2 1 AROCLOR 1 2 3 2 AROCLOR 124 2 AROCLOR 124 8 AROCLOR 1 2 5 4 AROCLOR 12 6 0 GAMMA-CHLORDAN E
BLANK
(EPA 6 0 8 ) ATI I . D . DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
RESULTS
- < 0 . 0 5 < 0 . 0 5 < 0 . 0 5 < 0 . 0 5 < 0 . 0 5 < 0 . 5 < 0 . 1 < 0 . 1 < 0 . 1 < 0 . 1 < 0 . 0 5 < 0 . 1 < 0 . 1 < 0 . 1 < 0 . 1 < 0 . 1 < 0 . 0 5 < 0 . 0 5 < 0 . 5 < 1 . 0 < 0 . 5 < 0 . 5 < 0 . 5 < 0 . 5 < 0 . 5 < 0 . 5 < 0 . 5 < 0 . 5
! 1 0 5 6 4 4 ! 0 5 / 1 3 / 9 1 : 0 5 / 2 0 / 9 1 : UG/L : N/A
SURROGATE PERCENT RECOVERIES
DBC (%) 104
i
A-51 I
'huz ' JuA
A J S AnolyticolTechnologies,Inc
QUALITY CONTROL DATA I ATI I.D, TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 6 08)
I CLIENT PROJECT # PROJECT NAME I REF I.D.
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA 10599909
DATE ANALYZED SAMPLE MATRIX UNITS
: 105644
: 05/20/91
: UG/L
COMPOUNDS
DUP. DUP, SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC RPD
[GAMMA BHC I HEPTACHLOR ALDRIN [DIELDRIN I ENDRIN DDT
<0.05 <0.05 <0.05 <0.1 <0.1 <0.1
2.0 2.0 2.0 2.0 2.0 2.0
2 2 2 2 2 2
2 1 1 1 1 0
110 105 105 105 105 100
2 2 2 2 2 2
2 1 1 1 1 0
110 105 105 105 105 100
0 0 0 0 0 0
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of Spiked Sample X 100
A-52
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A j S AnalyticalTechnologies, Inc.
I ACCESSION: 105644
LABORATORY CONTROL SAMPLE METHOD 608
CLIENT: MONTGOMERY & ASSOCIATES UNITS: UG/L ANALYSIS DATE: 05/20/91
ACTUAL FOUND % REC
LINDANE HEPTACHLOR ALDRIN DIELDRIN ENDRIN DDT
2 2. 2. 2. 2. 2
2, 2, 2, 2, 1, 1,
105 105 100 100 95 90
I
A-53
/ j j j ^ AnalyticalTechnologies, Inc. 9830 S. 51st Street Suite B-113 Ptioenix. AZ 35044 (602) 496-4400
ATI I.D. 105704
June 24, 1991
Errol L. Montgomery & Associates 1075 E. Fort Lowell Road Suite B Tucson, AZ 85719
Project Name/Number: Hassayampa 662-A
Attention: Bill Victor
On 05/13/91, Analytical Technologies, Inc. received a request to analyze aqueous sample(s). The sample(s) were analyzed with EPA methodology or equivalent methods. The results of these analyses and the quality control data, which follow each set of analyses, are enclosed.
Method 632 analyses were performed by ATI, San Diego. Method 622 analyses were performed by ATI, Renton.
An independent Laboratory Control Standard is not included with the Method 622 analyses due to the. lack of availability of a secondary standard source.
If you have any questions or comments, please do not hesitate to contact us at (602) 496-4400.
• ^ - k ^ f Michael G. Barry Project Manager
Lorraine Davis QA Coordinator
RVW:jat Enclosure
Robert V. Woods Laboratory Manager
Corpofote Offices: 5550 Moretiouse Drive San Diego. CA 92121 (619) 458-9141
A-54
>jjij^ AnalyticalTechnologies, Inc. 9830 S. 51st Street Suite B-113 Ptioenix, AZ 35044 (602) 496-4400
ATI I . D . 105704
J u n e 24 , 1991
Errol L. Montgomery & Associates 1075 E. Fort Lowell Road Suite B Tucson, AZ 85719
Project Name/Number: Hassayampa 662-A
Attention: Bill Victor
9
I I
On 05/13/91, Analytical Technologies, Inc. received a request to analyze aqueous sample(s). The sample(s) were analyzed with EPA methodology or equivalent methods. The results of these analyses and the quality control data, which follow each set of analyses, are enclosed.
Method 63 2 analyses were performed by ATI, San Diego, analyses were performed by ATI, Renton.
Method 622
An independent Laboratory Control Standard is not included with the Method 622 analyses due to the lack of availability of a secondary standard source.
Enclosed is an araended report for method 601/602 Laboratory Control Standard and Method 632 sample 010911. In addition Method 632 showed three unidentified peaks for sample 010911. We apologize for any inconvenience this may have caused.
If you have any questions or comments, please do not hesitate to contact us at (602) 496-4400,
' % i b ^
Michael G. Barry Project Manager
( _ ,, CA*K'\y- (Jardi Robert V. Woods Laboratory Manager
••'—U'l I'fu
Lorraine Davis QA Coordinator
RVW: j at Enclosure
J/J/.
I
Corporate Offices; 5550 Morehouse Drive San Diego, CA 92121 (619) 458-9141
A-55
/ i . \ / j j ^ AnalyficalTechnologies,lnc.
] ATI I.D. # 105704
METHOD 622 CASE NARRATIVE
CLIENT PROJECT # PROJECT NAME
MONTGOMERY & ASSOCIATES 662-A
CASE NARRATIVE ORGANOPHOSPHORUS PESTICIDES
One liter of sample was extracted with methylene chloride by continuous liquid:liquid extraction. The methylene chloride was reduced and exchanged to hexane. Final volume was ten milliliters.
The extracts were analyzed by GC-FID on DEI and DB1701 megabore (0.53 mm id) capillary columns.
Insufficient sample was provided to perform a matrix spike and spike duplicate. Blank spikes were extracted in duplicate. Results are within limits with the exception of Disulfoton. Historical data indicate that this compound recovers inconsistently, especially from reagent water.
Acephate disappeared from the initial standard of the sequence on the DB1701 column. By the end of the sequence, it disappeared from the analysis altogether. This compound is susceptible to active sites, and its disappearance is indicative of an active site problem. TEPP and moncrotophos exhibited poor linearity. Consequently, low recoveries were obtained in the continuing standards. The results for all three of these compounds should be qualified, as all three have shown poor reproducibility of response level and low compatibility with this method setup.
No other problems were encountered with this sample set.
A-56
i A j S AnalyticalTechnologies,Inc.
CLIENT PROJECT # PROJECT NAME
MONTGOMERY & ASSOCIATES 662-A (NONE)
ATI I.D. : 105704
DATE RECEIVED : 05/13/91 3
REPORT DATE : 06/21/91
I ATI # CLIENT DESCRIPTION MATRIX DATE COLLECTED
01 02 03 04 05 06 07 08 09 10 11
010901 010902 010903 010904 010905 010906 010907 010908 010909 010910 010911
TRIP BLANK AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS
05/1 05/1 05/1 05/1 05/1 05/1 05/1 05/1 05/1 05/1 05/1
3/91 3/91 3/91 3/91 3/91 3/91 3/91 3/91 3/91 3/91 3/91
I
TOTALS i
MATRIX
AQUEOUS
# SAMPLES
11
ATI STANDARD DISPOSAL PRACTICE
The samples from this project will be disposed of in thirty (30) days from the date of this report. If an extended storage period is required, please contact our sample control department before the scheduled disposal date..
A-57 I
A j S AnolyticalTechnologies ,lnc.
GAS CHROMATOGRAPHY - RESULTS
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 501/502)
ATI I.D. 10570401
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY & ASSOCIATES 562-A (NONE) 0109 01 TRIP BLANK AQUEOUS
DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 N/A 05/22/91 UG/L
1
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHANE CHLOROFORM CHLOROMETHANE DIBROMOCHLOROMETHANE 2-CHLOROETHYL VINYL ETHER 1, 3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DI CHLORODIFLUOROMETHANE 1,1-DICKLOROETHANE 1, 2-DICHLOROETHANE 1, 1-DICHLOROETHENE 1,2-DICHLOROETHENE(TOTAL) 1, 2-DICKLOROPROPANE CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1,1,1-TRICHLOROETHANE 1,1,2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
SURROGATE PERCENT RECOVERIES
BROMOCHLOROMETHANE (%) BROMOFLUOROBENZENE (%)
<0. <0, <0, <0. <0. <0, <0. <0, <0 <0
<0 <0
<0.5 <0.5 <0.5 <0. <0, <0.
2 2 2
<0.2 <0.2
<0.2 <0.5 2.4 <0. <0, <0 <0, <0 <0 <0, <0
2 2 5 2 2 2 5 2
<0.5 <2.0
99 85
A-58
yh^~ ^ u A I ^JLS AnolyticalTechnologies,Inc. ^
GAS CHROMATOGRAPHY - RESULTS
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 501/602
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE M-ATRIX
MONTGOMERY 662-A (NONE) 010902 AQUEOUS
& ASSOCIATES
ATI I.D, 10570402
DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 N/A 05/22/91 UG/L
1 I COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHANE CHLOROFORM CHLOROMETHANE DIBROMOCHLOROMETHANE 2-CHLOROETHYL VINYL ETHER 1,3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1,1-DICHLOROETHANE 1,2-DICHLOROETHANE 1,1-DICHLOROETHENE 1,2-DICHLOROETHENE(TOTAL) 1,2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1,1,1-TRICHLOROETHANE 1,1,2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
SURROGATE PERCENT RECOVERIES
BROMOCHLOROMETHANE (%) BROMOFLUOROBENZENE (%)
<0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <2 <0 <0 <0 <0 <0 <0 <0 <0 <0 <2
.5
.2
.2
.2
.2
.5
.2
.2
.2
.2
.5
.5
.5
.2
.2
.2
.2
.2
.2
.2
.2
.5
.0
.2
.2
.5
.2
.2
.2
.5
.2
.5
.0
i I I
101 94
A-59
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A J S AnalyticolTechnologies,Inc.
GAS CHROMATOGRAPHY - RESULTS
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 601/602)
ATI I.D. : 10570403
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY 6 6 2-A (NONE) 010903 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 N/A 05/23/91 UG/L
1
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON T E T P J > L C H L O R I D E
CHLOROBENZENE CHLOROETHANE CHLOROFORM CHLOROMETHANE DIBROMOCHLOROMETHANE 2-CHLOROETHYL VINYL ETHER 1, 3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1,1-DICHLOROETHANE 1,2-DICHLOROETHANE . 1,1-DICKLOROETHENE 1, 2-DICHLOROETHENE(TOTAL) 1, 2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1,1,1-TRICHLOROETHANE 1,1,2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
SURROGATE PERCENT RECOVERIES
BROMOCHLOROMETHANE (%) BROMOFLUOROBENZENE (%)
<0. <0. <0. <0. <0. <0. <0 <0. <0. <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <2 <0 <0 <0 <0 <0 <0 <0 <0 <0 <2
5 2 2 2 2 5 2 2 2 2 5 5 5 2 2 2 2 2 2 2 .2 .5 0 .2 .2 .5 .2 .2 .2 .5 .2 .5 .0
104 95
A-60
rv\\Kt - i j /u 3 I AiS AnolyticolTechnologies,Inc.
GAS CHROMATOGRAPHY - RESULTS
ATI I.D, 10570407
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 601/50 2)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MA.TRIX
MONTGOMERY 562-A (NONE) 010907 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 N/A 05/22/91 UG/L
1
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHANE CHLOROFORM CHLOROMETHANE DIBROMOCHLOROMETHANE 2-CHLOROETHYL VINYL ETHER 1,3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1,1-DICHLOROETHANE 1, 2-DICHLOROETHANE 1,1-DICHLOROETHENE 1, 2-DICHLOROETHENE(TOTAL) 1, 2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1,1, 1-TRICHLOROETHANE 1,1, 2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
SURROGATE PERCENT RECOVERIES
BROMOCHLOROMETHANE (%) BROMOFLUOROBENZENE (%)
0.5 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <2 <0 <0 <0 <0 <0 <0 <0 <0 <0 <2
.2
.2
.2
.2
.5
.2
.2
.2
.2
.5
.5
.5
.2
.2
.2
.2
.2
.2
.2
.2
.5
.0
.2
.2
. 5
.2
.2
.2
.5
.2
. 5
.0
i
97 92
A-61
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A J S AnolyticalTechnologies,Inc.
GAS CHROMATOGRAPHY - RESULTS
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 601/602)
ATI I.D. : 10570408
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY 662-A (NONE) 010908 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 N/A 05/22/91 UG/L
1
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHANE CHLOROFORM CHLOROMETHANE DIBROMOCHLOROMETHANE 2-CHLOROETHYL VINYL ETHER 1,3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1,1-DICHLOROETHANE 1,2-DICKLOROETHANE 1,1-DICHLOROETHENE 1,2-DICHLOROETHENE(TOTAL) 1,2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1,1,1-TRICKLOROETHANE 1,1,2-TRICKLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
SURROGATE PERCENT RECOVERIES
BROMOCHLOROMETHANE (%) BROMOFLUOROBENZENE (%)
<0. <0. <0. <0. <0. <0. <0. <0. <0. <0. <0, <0, <0. <0. <0, <0, <0, <0, <0, <o. <0 <0.5 <2.0 <0.2 <0.2 <0.5 <0.2 <0.2 <0 <0 <0 <0 <2.0
107 95
A-62
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A J S AnolyticalTechnologies,Inc.
GAS CHROMATOGRAPHY - RESULTS
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 601/602)
ATI I.D. 10570409
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MJVTRIX
MONTGOMERY 662-A (NONE) 010909 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 N/A 05/22/91 UG/L
1
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHANE CHLOROFORM CHLOROMETHANE DIBROMOCHLOROMETHANE 2-CHLOROETHYL VINYL ETHER 1, 3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1,1-DICKLOROETHANE 1, 2-DICHLOROETHANE 1,1-DICHLOROETHENE 1,2-DICHLOROETHENE(TOTAL) 1, 2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1,1,1-TRICKLOROETHANE 1,1,2-TRICKLOROETHANE TRICHLOROETKENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
SURROGATE PERCENT RECOVERIES
BROMOCHLOROMETHANE (%) BROMOFLUOROBENZENE (%)
<0 <0 <0 <0 <0 <0 <0 <0 0.9 <0 <0 <0 <0 <0 <0 <0 0.3 <0 <0 <0 <0 <0 <2 <0 <0 0.7 <0 <0 <0 <0 <0 <0 28
I
100 84
A-63
/V)i^ - ^ u A a /up
A J S AnalyficalTechnologies,lnc.
GAS CHROMATOGRAPHY - RESULTS
ATI I.D, 10570410
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 601/602)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE Mji TRIX
MONTGOMERY 662-A (NONE) 010910 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 N/A 05/22/91 UG/L
1
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHANE CHLOROFORM CHLOROMETHANE DIBROMOCHLOROMETHANE 2-CHLOROETHYL VINYL ETHER 1,3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1,1-DICHLOROETHANE 1,2-DICHLOROETHANE 1,1-DICHLOROETHENE 1,2-DICHLOROETHENE(TOTAL) 1,2-DICKLOROPROPANE CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE. 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1,1,1-TRICHLOROETHANE 1,1,2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
SURROGATE PERCENT RECOVERIES
<0. <0, <0, <0, <0, <0. <0. <0 <0 <0. <0 <0.5
5 2 2 ,2
.2 ,2 ,2 .2 .5
<0. <0, <0, <0, 0.4 <0, <0, <0, <0. <0 <2.0 <0.2 <0.2 0.6 <0. <0 <0 <0 <0 <0.5 27
BROMOCHLOROMETHANE (%) BROMOFLUOROBENZENE (%)
106 86
A-64
P / ^ i J D S ^/V/JT
A J S AnalyticalTechnologies,Inc.
GAS CHROMATOGRAPHY - RESULTS
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 601/602)
ATI I.D. 10570411
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MJ TRIX
MONTGOMERY 662-A (NONE) 010911 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 N/A 05/23/91 UG/L
1
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHANE CHLOROFORM CHLOROMETHANE DIBROMOCHLOROMETHANE 2-CHLOROETHYL VINYL ETHER 1,3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1,1-DICHLOROETHANE 1, 2-DICHLOROETHANE 1,1-DICHLOROETHENE 1, 2-DICHLOROETHENE(TOTAL) 1, 2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1,1,1-TRICHLOROETHANE 1,1, 2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
SURROGATE PERCENT RECOVERIES
BROMOCHLOROMETHANE (%) BROMOFLUOROBENZENE (%)
0.6 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0.5 <0.5
5 2 2 2 2 2 2 2 2
<0 <0 <0 <0 <0 <0 <0 <0 <0 0.6 <2.0 <0.2 <0.2 2.5 <0 <0 <0 <0 <0 1.9 <2
102 85
A-65
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GAS CHROMATOGRAPHY - RESULTS
rhuj-'^L^'B ^di^3 y>^-jij- H u - ^ > c-(l<ci F.B. ^
•SiM,
REAGENT BLANK
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 5 01/6 02)
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MONTGOMERY & ASSOCIATES 562-A (NONE) REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105704 05/22/91 05/22/91 UG/L N/A
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHAJ^E CHLOROFORM CHLOROMETKANE DIBROMOCHLOROMETHANE 2-CHLOROETKYL VINYL ETHER 1, 3-DICFJ.OROBENZENE 1,2 & 1,4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1,1-DICHLOROETHANE 1, 2-DICHLOROETHANE 1,1-DICHLOROETHENE 1, 2-DICKLOROETHENE(TOTAL) 1, 2-DICKLOROPROPANE CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1,1,1-TRICHLOROETHANE 1,1,2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
SURROGATE PERCENT RECOVERIES
<0. <0 <0 <0 <0 <0 <0 <0 <0 <0~. 2
BROMOCHLOROMETHANE (%) BROMOFLUOROBENZENE (%)
<0, <0, <0, <0, <0, <0, <0, <0, <0, <0, <0. <0. <2. <0 <0 <0 <0 <0 <0 <0 0.7 <0.5 <2.0
93 84
5 5 5 2 2 2 2 2 2 2 2 5 0 .2 .2 ,5 ,2 ,2 .2 ,5
A-56
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GAS CHROMATOGRAPHY - RESULTS
REAGENT BLANK
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 601/602;
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MO.NTGOMERY & ASSOCIATES 662-A (NONE) REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105704 05/23/91 05/23/91 UG/L N/A
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHANE CHLOROFOR-M CHLOROMETHANE DIBROMOCHLOROMETHANE 2-CHLOROETHYL VINYL ETHER 1, 3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1,1-DICHLOROETHANE 1, 2-DICHLOROETHANE 1,1-DICHLOROETHENE 1, 2-DICHLOROETHENE(TOTAL) 1,2-DICKLOROPROPANE CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1,1,1-TRICHLOROETHANE 1 , 1 , 2-TRICHL0R0ETFJ\NE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
BROMOCHLOROMETHANE BROMOFLUOROBENZENE
SURROGATE PERCENT RECOVERIES
(%) (%)
<0. <0, <0. <0. <0, <0, <0, <0, <0, <0, <0, <0, <0, <0, <0. <0, <0, <0, <0, <0, <0, <0, <2, <0. <0 <o. <0 <0 <0 <0 1.0 <0.5 <2.0
98 95
5 2 2 2 2 5 2 2 2 2 5 5 5 2 2 2 2 2 2 2 2 5 .0 .2 ,2 5 .2 ,2 .2 ,5
A-57
A j S AnolyticolTechnologies,Inc.
QUALITY CONTROL DATA ATI I.D,
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 6 01/502)
CLIENT PROJECT # PROJECT NAME REF I.D.
MONTGOMERY & ASSOCIATES 662-A (NONE) 10599949
DATE ANALYZED SAMPLE MATRIX UNITS
105704
05/22/91
UG/L
COMPOUNDS
DUP. DUP. SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC, RPD
1,1-DICHLOROETHENE TRICHLOROETHENE TETRACHLOROETHENE BENZENE BROMODICHLOROMETHANE CHLOROFORM 1,1,1-TRICHLOROETHANE TOLUENE CHLOROBENZENE M-XYLENE
<0.2 <0.2 <0.2 <0.5 <0.2 <0.2 <0.2 <0.5 <0.5 <0.5
20 20 20 20 20 20 20 20 20 20
19 20 20 20 19 20 18 20 20 22
95 100 100 100 95 100 90 100 100 110
18 19 18 18 18 19 17 18 18 20
90 95 90 90 90 95 85 90 90 100
5 5 11 11 5 5 6 11 11 10
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration X 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of Spiked Sample X 100
A-68
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ACCESSION: 105704
QUALITY CONTROL DATA: METHOD 601/602
589
CLIENT: MONTGOMERY AND ASSOCIATES UNITS: UG/L ANALYSIS DATE: 05/22/91
1,1-DICHLOROETHENE TRICHLOROMETHANE 1,1,1-TRICHLOROETHANE BROMODICHLOROMETHANE TRICHLOROETHENE TETRACHLOROETHENE CHLOROBENZENE BENZENE METHYLBENZENE 1,2-DICHLOROBENZENE 1,3-DIMETHYLBENZENE
TRUE VALUE
20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0
FOUND
19.6 20.3 19.2 20.3 20.5 20.2 19.9 19.3 19.2 21.8 20.4
REC
98 102 96 102 103 101 100 97 96 109 102
; SURROGATE RECOVERY 103 % BROMOCHLOROMETHANE (BCM) 84 % BROMOFLUOROBENZENE (BFB)
A-59
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ACCESSION: 105704
QUALITY CONTROL DATA: METHOD 601/602
589
CLIENT: MONTGOMERY AND ASSOCIATES UNITS: UG/L ANALYSIS DATE: 05/23/91
1,1-DICHLOROETHENE TRICHLOROMETHANE 1,1,1-TRICHLOROETHANE BROMO DICHLOROMETHANE TRICHLOROETHENE TETRACHLOROETHENE CHLOROBENZENE BENZENE METHYLBENZENE 1,2-DICHLORO BEN Z ENE 1,3-DIMETHYLBENZENE
TRUE VALUE
20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0
FOUND
19.6 20.9 19.7 20.5 20.8 19.8 19.3 18.4 18.8 22.5 20.4
% REC
98 105 99 103 104 99 97 92 94 113 102
% SURROGATE RECOVERY 110 % BROMOCHLOROMETHANE (BCM) 83 % BROMOFLUOROBENZENE (BFB)
A-70
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GAS CHROMATOGRAPHY - RESULTS
ATI I.D. : 10570404
TEST : ORGANOPHOSPHORUS PESTICIDES (EPA METHOD 5 22)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY 652-A (NONE) 010904 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 05/15/91 05/27/91 MG/L
1
COMPOUNDS RESULTS
ACEPHATE AZINPHOS METHYL (GUTHION) BOLSTAR (SULPROFOS) CHLORPYRIFOS (DURSBAN) COUMAPHOS DEMETON (TOTAL) DIAZINON DICHLORVOS DIMETHOATE DISULFOTON EPN ETHION ETHOPROP FENSULFOTHION FENTHION MALATHION MERPHOS METHYL CHLORPYRIFOS METHYL PARATHION MEVINPHOS MONOCROTOPHOS NALED PARATHION PHORATE RONNEL STIROPHOS SULFOTSPP TEPP TOKUTHION (PROTHIOFOS) TRICHLORONATE
SURROGATE PERCENT RECOVERIES
ETHYL AZINPHOS (%)
(TETRACHLORVINPHOS)
<2 <2 <0 <0 <1 <1 <0 <0 <2 <0 <0 <0 <0 < 1 <0 <0 < 1 <0 <0 <0 <5 <5 <0 <0 <0 <0 <0 <0 <1 <0
5 0 50 50 0 0 50 50 0 50 50 50 50 0 50 50 0 50 50 50 0 0 50 50 50 50 50 50 0 50
I
111
A-71
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GAS CHROMATOGRAPHY - RESULTS
TEST : ORGANOPHOSPHORUS PESTICIDES (EPA METHOD 622)
ATI I.D. : 10570405
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MJITRIX
MONTGOMERY 662-A (NONE) 010905 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 05/16/91 05/27/91 MG/L
1
COMPOUNDS RESULTS
ACEPHATE AZINPHOS METHYL (GUTHION) BOLSTAR (SULPROFOS) CHLORPYRIFOS (DURSBAN) COUMAPHOS DEMETON (TOTAL) DIAZINON DICHLORVOS DIMETHOATE DISULFOTON EPN ETHION ETHOPROP FENSULFOTHION FENTHION MALATHION MERPHOS METHYL CHLORPYRIFOS METHYL PAJIATHION MEVINPHOS MONOCROTOPHOS NALED PARATHION PHORATE RONNEL STIROPHOS SULFOTEPP TEPP TOKUTHION (PROTHIOFOS) TRICHLORONATE
SURROGATE PERCENT RECOVERIES
ETHYL AZINPHOS (%)
;TETRACHLORVINPHOS)
<2 <2 <0 <0 <1 <1 <0 <0 <2 <0 <0 <0 <0 <1 <0 <0 <1 <0 <0 <0 <5 <5 <0 <0 <0 <0 <0 <0 <1 <0
5 0 50 50 0 0 50 50 0 50 50 50 50 0 50 50 0 50 50 50 0 0 50 50 50 50 50 50 0 50
101
A-72
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GAS CHROMATOGRAPHY - RESULTS
ATI I.D. 10570406
TEST : ORGANOPHOSPHORUS PESTICIDES (EPA METHOD 6 22)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY 562-A (NONE) 010905 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 05/16/91 05/27/91 MG/L
1
COMPOUNDS RESULTS
ACEPHATE AZINPHOS METHYL (GUTHION) BOLSTAR (SULPROFOS) CHLORPYRIFOS (DURSBAN) COUMAPHOS DEMETON (TOTAL) DIAZINON DICHLORVOS DIMETHOATE DISULFOTON EPN ETHION ETHOPROP FENSULFOTHION FENTHION MALATHION MERPHOS METHYL CHLORPYRIFOS METHYL PARATHION MEVINPHOS MONOCROTOPHOS NALED PARATHION PHORATE RONNEL STIROPHOS SULFOTEPP TEPP TOKUTHION
(TETRACHLORVINPHOS)
(PROTHIOFOS) TRICHLORONATE
<2 <2 <0 <0 <1 <1 <0 <0 <2 <0 <0 <0 <0 <1 <0 <0 <1 <0 <0 <0 <5 <5 <0 <0 <0 <0 <0 <0 <1 <0
5 0 50 50 0 0 50 50 0 50 50 50 50 0 50 50 0 50 50 50 0 0 50 50 50 50 50 50 0 50
9
I
SURROGATE PERCENT RECOVERIES
ETHYL AZINPHOS (%) 100
A-73
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GAS CHROMATOGRAPHY - RESULTS
ATI I.D. 10570411
TEST : ORGANOPHOSPHORUS PESTICIDES (EPA METHOD 5 22)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY 562-A (NONE) 010911 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 05/16/91 05/27/91 MG/L
1
COMPOUNDS RESULTS
ACEPHATE AZINPHOS METHYL (GUTHION) BOLSTAR (SULPROFOS) CHLORPYRIFOS (DURSBAN) COUMAPHOS DEMETON (TOTAL) DIAZINON DICHLORVOS DIMETHOATE DISULFOTON EPN ETHION ETHOPROP FENSULFOTHION FENTHION MALATHION MERPHOS METHYL CHLORPYRIFOS METHYL PARATHION MEVINPHOS MONOCROTOPHOS NALED PARATHION PHORATE RONNEL STIROPHOS SULFOTEPP TEPP TOKUTHION (PROTHIOFOS) TRICHLORONATE
SURROGATE PERCENT RECOVERIES
ETHYL AZINPHOS (%)
(TETRACHLORVINPHOS)
<2. <2. <0. <0. <1. <1, <0, <0, <2, <0, <0, <0, <0, < 1 , <0, <0, < 1 , <0, <0, <0. <5 <5 <0 <0 <0 <0 <0 <0 <1 <0
5 0 50 50 0 0 50 50 0 50 50 50 50 0 50 50 0 50 50 50 0 0 50 50 50 50 50 50 0 50
102
A-74
A J S Anolytii A j S AnolyticolTechnologies, Inc.
GAS CHROMATOGRAPHY - RESULTS
REAGENT BLANK
TEST : ORGANOPHOSPHORUS PESTICIDES (EPA METHOD 6 22
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MONTGOMERY & ASSOCIATES 662-A (NONE) REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105704 05/16/91 05/27/91 MG/L N/A .
COMPOUNDS RESULTS
ACEPHATE AZINPHOS METHYL (GUTHION) BOLSTAR (SULPROFOS) CHLORPYRIFOS (DURSBAN) COUMAPHOS DEMETON (TOTAL) DIAZINON DICHLORVOS DIMETHOATE DISULFOTON EPN ETHION ETHOPROP FENSULFOTHION FENTHION MALATHION MERPHOS METHYL CHLORPYRIFOS METHYL PARATHION MEVINPHOS MONOCROTOPHOS NALED PARATHION PHORATE RONNEL STIROPHOS SULFOTEPP TEPP TOKUTHION
(TETRACHLORVINPHOS)
(PROTHIOFOS) TRICHLORONATE
<2. <2. <0. <0. <1. <1. <0. <0. <2. <0. <0, <0. <0. <1. <0. <0, < 1 , <0, <0,
<o, <5 <5 <0 <0 <0 <0 <0 <0 <1 <0
5 0 50 50 0 0 50 50 0 50 50 50 50 0 50 50 0 50 50 50 0 0 5 0 50 50 50 50 50 0 50
I
SURROGATE PERCENT RECOVERIES
ETHYL AZINPHOS (%) 101 I
A-75
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QUALITY CONTROL DATA
TEST : ORGANOPHOSPHORUS PESTICIDES (EPA METHOD 6 22
CLIENT PROJECT # PROJECT NAME REF I.D.
MONTGOMERY & ASSOCIATES 562-A (NONE) 10699901
ATI I.D.
DATE ANALYZED SAMPLE MATRIX UNITS
105704
05/27/91 AQUEOUS UG/L
COMPOUNDS
DUP. DUP. SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC. RPD
AZINPHOS METHYL DIAZINON DISULFOTON MALATHION METHYL PARATHION PARATHION
<2, <0. <0. <0 <0 <0
0 50 50 50 50 50
21 4.2 3 7 0 1
22.8 4.02 68 01 55 96
109 21.8 96 4.07 32 *0.687 107 4 71 4 97 5
87 65 57
104 97 13 * 104 93 109
4 1 84 3 27 12
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration X 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of Spiked Sample
* Result out of limits due to sample matrix interference
X 100
A-76
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GAS CHROMATOGRAPHY - RESULTS
TEST : CARBAMATES AND UREA PESTICIDES
ATI I.D, 10570404
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX : AQUEOUS
MONTGOMERY & ASSOCIATES 6 6 2-A (NONE) 010904
DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 05/17/91 06/05/91 UG/L
1
COMPOUNDS RESULTS
BAYGON BENDIOCARB BROMACIL CARBARYL CARBOFURAN CHLORPROPHAM (CIPC) DIURON EPTC LINURON METHOMYL NEBURON OXAMYL (VYDATE) PROPHAM
<5 <2 <1 <1 <5 <1 <0 <0 <0 <2 <0 <2 <1
I
A-77
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GAS CHROMATOGRAPHY - RESULTS
ATI I.D. 10570405
TEST CARBAMATES AND UREA PESTICIDES
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX : AQUEOUS
MONTGOMERY & ASSOCIATES 6 6 2-A (NONE) 010905
DATE SAMPLED DATE. RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 05/17/91 06/05/91 UG/L
1
COMPOUNDS RESULTS
BAYGON BENDIOCARB BROMACIL CARBARYL CARBOFURAN CHLORPROPHAM (CIPC) DIURON EPTC LINURON METHOMYL NEBURON OXAMYL (VYDATE) PROPHAM
<5 <2 <1 <1 <5 <1 <0, <0, <0 <2, <0, <2 <1
A-78
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GAS CHROMATOGRAPHY - RESULTS
ATI I.D 10570406
TEST : CARBAMATES AND UREA PESTICIDES
CLIENT PROJECT PROJECT CLIENT j
# NAME .D.
SAMPLE MATRIX : AQUEOUS
MONTGOMERY 6 6 2-A (NONE) 010906
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 05/17/91 05/06/91 UG/L
1
COMPOUNDS RESULTS
BAYGON BENDIOCARB BROMACIL CARBARYL CARBOFURAN CHLORPROPHAM (CIPC) DIURON EPTC LINURON METHOMYL NEBURON OXAMYL (VYDATE) PROPHAM
<5 <2 <1 <1 <5 <1 <0 <0 <0 <2 <0 <2 <1
A-79
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GAS CHROMATOGRAPHY - RESULTS
ATI I.D 10570411
TEST CARBAMATES AND UREA PESTICIDES
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX : AQUEOUS
MONTGOMERY & ASSOCIATES 662-A (NONE) 010911
DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/13/91 05/13/91 05/17/91 06/06/91 UG/L
1
COMPOUNDS RESULTS
BAYGON BENDIOCARB BRO-MACIL CARBARYL CARBOFURAN CHLORPROPHAM (CIPC) DIURON EPTC LINURON METHOMYL NEBURON OXAMYL (VYDATE) PROPHAM
23 <2 <1 <1 <5 <1 <0. <0. <0. <2, <0. <2. <1
A-80
A AJS AnolyticalTechnologies,Inc.
GAS CHROMATOGRAPHY - RESULTS
REAGENT BLANK
T~|B.
TEST : CARBAMATES AND UREA PESTICIDES
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MONTGOMERY Sc ASSOCIATES 6 6 2-A (NONE) REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105704 05/17/91 06/05/91 UG/L N/A
COMPOUNDS RESULTS
BAYGON BENDIOCARB BROMACIL CARBARYL CARBOFURAN CHLORPROPHAM (CIPC) DIURON EPTC LINURON METHOMYL NEBURON OXAMYL (VYDATE) PROPHAM
<5 <2 <1 <1 <5 <1 <0.5 <0.1 <0.5 <2.5 <0.5 <2.5 <1
A-81
A
TEST
/ \ AnolyticalTechnologies,Inc.
QUALITY CONTROL DATA
CARBAMATES AND UREA PESTICIDES
CLIENT PROJECT # PROJECT NAME REF I.D.
MONTGOMERY & ASSOCIATES 662-A (NONE) 10699907
* wJ -2U.A j-
7li M p
ATI I.D.
DATE ANALYZED SAMPLE MATRIX UNITS
: 105704
06/05/91 AQUEOUS UG/L
COMPOUNDS
DUP. DUP SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC RPD
BROMACIL NEBURON LINURON CABARYL
<1.0 <0.50 <0.50 <1.0
10.0 2.5 2.5 10.0
8.0 2.2 2.4 8.6
80 88 95 86
8.0 2,4 2.5 8.7
80 96 100 87
0 9 4 1
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of Spiked Sample 100
A-82
A j S AnalyticalTechnologies
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ACCESSION: 105704
LABORATORY CONTROL STANDARD METHOD 63 2
CLIENT: MONTGOMERY AND ASSOCIATES UNITS: UG/L ANALYSIS DATE: 06/08/91
COMPOUND TRUE VALUE OBSERVED
VALUE % REC
BENDIOCARB EPTC
20 1.0
20.5 1.05
103 105
I
A-83
Al
/ j j X A n a l y t i c a l T e c h n o l o g i e s , Inc. 9330 s. sist street suite B-I 13 ptioenix, AZ 35044 (602)495-4400
ATI I.D. 105723
June 26, 1991
Errol L. Montgomery & Associates 1075 E. Fort Lowell Road Suite B Tucson, AZ 85719
Project Name/Number: Hassayampa/662-A
Attention: Bill Victor
On 05/15/91, Analytical Technologies, Inc. received a request to analyze aqueous sample(s). The sample(s) were analyzed with EPA methodology or equivalent methods. The results of these analyses and the quality control data, which follow each set of analyses, are enclosed.
Dates for inorganic analyses are given on the quality control report form.
If you have any questions or comments, please do not hesitate to contact us at (602) 496-4400.
^-k^ Michael G. Barry Project Manager
>. Ua-ryL
Robert V. Woods Laboratory Manager
• ij
M\ RVW:jat Enclosure
. • • ' • , • r • • •
Corporate Offices: 5550 Moretiouse Drive San Diego. CA 92121 (619) 458-9141
A-84
/ ^ AnolyticolTechnologies, Inc.
CLIENT : MONTGOMERY & ASSOCIATES PROJECT # : 652-A PROJECT NAME : HASSAYAMPA
ATI I.D. : 105723
DATE RECEIVED : 05/15/91
REPORT DATE : 06/21/91
ATI # CLIENT DESCRIPTION MATRIX DATE COLLECTED
01 02
004461 004460 TRIP BLANK
AQUEOUS AQUEOUS
05/14/91 05/14/91
MATRIX
AQUEOUS
TOTALS
# SAMPLES
2
ATI STANDARD DISPOSAL PRACTICE
The samples from this project will be disposed of in thirty (30) days from the date of this report. If an extended storage period is required, please contact our sample control department before the scheduled disposal date.
A-85
AjS AnolyticolTechnologies,I
Jy^iO'JoUy^
GENERAL CHEMISTRY RESULTS
CLIENT PROJECT # PROJECT NAME
MONTGOMERY 652-A HASSAYAMPA
ATI I.D. : 105723
DATE RECEIVED : 05/15/91
REPORT DATE : 05/21/91
PARAMETER UNITS 01
CARBONATE (CAC03) MG/L <1 BICARBONATE (CAC03) MG/L 213 HYDROXIDE (CAC03) MG/L <1 TOTAL ALKALINITY (AS CACO3) MG/L 213 CHLORIDE MG/L 250 CYANIDE, TOTAL MG/L <0.01 CONDUCTIVITY, (UMHOS/CM) 157 0 FLUORIDE MG/L 1.52 AMMONIA AS NITROGEN MG/L <0.03 NITRATE AS NITROGEN MG/L 38 PH UNITS 8.2 PHOSPHATE,ORTHO (AS P) MG/L <0.05 SULFATE MG/L 87 TOTAL DISSOLVED SOLIDS MG/L 960 PHOSPHOROUS,TOTAL MG/L <0.05
A-86
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GENERAL CHEMISTRY - QUALITY CONTROL
CLIENT PROJECT # PROJECT NAME
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA ATI I.D. : 105723
PARAMETER UNITS ATI I.D. SAMPLE RESULT
DUP. RESULT RPD
SPIKED SPIKE % SAMPLE CONC REC
CARBONATE MG/L BICARBONATE MG/L HYDROXIDE MG/L TOTAL ALKALINITY MG/L CHLORIDE MG/L CYANIDE, TOTAL MG/L CONDUCTIVITY(UMHOS/CM) FLUORIDE MG/L AMMONIA AS NITROGEN MG/L NITRATE AS NITROGEN MG/L PH UNITS PHOSPHATE, ORTHO MG/L SULFATE MG/L TOTAL DISSOLVED SOLIDS MG/L PHOSPHOROUS,TOTAL MG/L
10572301
10572301 10572301 10572301 10475003 10572301 10572301 10572301 10572301 10572301 10572301 10572301
<1 213 <1 213 250 <0.01 1570 1.52 <0.03 38 8.2 <0.05 87 960 <0.05
<1 211 <1 211 250 <0.01 1490 1.53 <0.03 37 8.2 <0.05 87 970 <0.05
NA 1
NA 1 0
NA 5 1
NA 3 0
NA 0 1
NA
NA NA NA NA 500 0.24 NA 3.05 0.50 89 NA 0.49 180 NA 0.44
NA NA NA NA 250 0.25 NA 1.50 0.50 50 NA 0.50 87 NA 0.50
NA NA NA NA 100 96 NA 102 100 102 NA 98 107 NA 88
X 100 % Recovery = (Spike Sample Result - Sample Result)
Spike Concentration
RPD (Relative Percent Difference) = (Sample Result - Duplicate Result)
Average Result X 100
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METALS RESULTS
Ivu j ' Jouyi
CLIENT PROJECT # PROJECT NAME
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA
ATI I.D. : 105723
DATE RECEIVED : 05/15/91
REPORT DATE : 06/21/91
PARAMETER UNITS 01
SILVER ALUMINUM ARSENIC BORON BARIUM BERYLLIUM CALCIUM CADMIUM COBALT CHROMIUM COPPER IRON MERCURY POTASSIUM MAGNESIUM MANGANESE SODIUM NICKEL LEAD ANTIMONY SELENIUM SILICA TIN THALLIUM VANADIUM ZINC
MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L
<0.010 <0.05 <0.005 0.37 0.115 <0.005 60.4 <0.005 <0.010 0.015 <0.010 <0.020 <0.0002 1.2 27.5 <0.010 242 <0.020 0.003 <0.05 <0.005 37.4 <0.03 <0.005 0.025 0.166
A-88
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METALS - QUALITY CONTROL
CLIENT PROJECT # PROJECT NAME
MONTGOMERY & ASSOCIATES 56 2~A HASSAYAMPA ATI I.D. : 105723
PARAMETER UNITS SAMPLE DUP. SPIKED SPIKE %
ATI I.D. RESULT RESULT RPD SAMPLE CONC REC
SILVER ALUMINUM ARSENIC BORON BARIUM BERYLLIUM CALCIUM CADMIUM COBALT CHROMIUM COPPER IRON MERCURY POTASSIUM MAGNESIUM MANGANESE SODIUM NICKEL LEAD ANTIMONY SELENIUM SILICA TIN THALLIUM VANADIUM ZINC
MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L
10572301 10572301 10572301 10572301 10572301 10572301 10572301 10572301 10572301 10572301 10572301 10572301 10572301 10572301 10572301 10572301 10572301 10572301 10569401 10572301 10564401 10572301 10572301 10564401 10572301 10572301
<0.010 <0.05 <0.005 0.37 0.115 <0.005 60.4 <0.005 <0.010 0.015 <0.010 <0.020 <0.0002 1.2 27.5 <0.010 242 <0.020 0.006 <0.05
005 4 03 005
025
<0. 37 <0 <0 0
<0.010 <0.05 <0.005 0.35 0.115 <0.005 61.8 <0.005 <0.010 0.015 <0.010 <0.020 <0.0002 1.5 28.0 <0.010 248 <0.020 0.006 <0.05
005 4 03 005
024
<0, 37, <0, <0 0
0.166 0.156
NA NA NA 6 0
NA 2
NA NA 0
NA NA NA 22 2
NA 2
NA 0
NA NA 0
NA NA 4 0
0, 0 0 1 0 0
090 97 049 23 213 099
116 0.101
102 112 093 985 0045 5
0, 0, 0, 0 0 55 54.8 0.098 673 0.095 0.061 0.98 0.042 250 0.10 0 . 047 0.126 0.272
0. 100 1.00 0.050 1.00 0.100 0.100 50.0 0.100 0.100 0.100 0.100 1.00 0.0050 50.0 25.0 0.100 500 0.100 0.050 1.00 0.050 214 0.10 0.050 0.100 0.100
90 97 98 85 98 99 111 101 102 97 93 98 90 109 109 98 85 95 110 98 84 99 100 94 101 106
X 100 % Recovery = (Spike Sample Result - Sample Result)
Spike Concentration
RPD (Relative Percent Difference) = (Sample Result - Duplicate Result) X 100
Average Result
A-89
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Page No. |06/25/91
.ANALYTE
QUALITY CONTROL REPORT
INIT DATE OF CORR. QC ANALYSIS COEFF. NAME
VALUE TRUE LOWER UPPER UNIT FOUND VALUE CONTROL CONTROL
LIMIT LIMIT
** ACCESSION NUMBER: 105723
METHOD 2 00.7
SILVER I ALUMINUM i BARIUM BERYLLIUM ,BORON CALCIUM 'CADMIUM COBALT I CHROMIUM I COPPER IRON MERCURY POTASSIUM I MAGNESIUM MANGANESE I SODIUM I NICKEL LEAD ANTIMONY TIN I THALLIUM VANADIUM
I ZINC ! SILICA
METHOD 270.2
I SELENIUM
JJH JJH JJH JJH JJH KJB JJH JJH JJH JJH JJH JJH KJB KJB JJH KJB JJH KJB JJH JJH KJB JJH JJH KJB
05/28/91 05/28/91 05/28/91 05/28/91 05/24/91 05/24/91 05/28/91 05/28/91 05/28/91 05/28/91 05/28/91 05/22/91 05/24/91 05/24/91 05/28/91 05/24/91 05/28/91 05/20/91 05/28/91 05/28/91 05/22/91 05/28/91 05/28/91 05/30/91
NA NA NA NA NA NA NA NA NA NA NA 0.999 NA NA NA NA NA 0.999 NA NA 0.999 NA NA NA
ICAP2 I CAP 3 ICAP3 ICAP3 ICAP7 I CAP 4 I CAP 3 I CAP 3 I CAP 3 ICAP3 I CAP 3 WP989 ICAP4 ICAP4 I CAP 3 ICAP4 I CAP 3 WP287 SVI I CAP 3 WP186 I CAP 3 I CAP 3 ICAP4
0.099 0.98 0.099 0.099 1.00 10.5 0.101
102 100 .092 .981 .99 .9
10.5 0.099 9.6 0.100 21.6 0.98 0.09 19.4 0.100 0.102 11.4
0. 0. 0, 0, 1, 9,
0.100 1.02 0.095 0.101 0.99 10.0 0.105 0.100 0.097 0.095 1.00 2.02 10.0 10.2 0.100 10.0 0.103 20.4 1.04 0.09 20.0 0.100 0.109 10.0
0 0 0 0 0 8 0 0 0. 0. 0. 1. 8. 9. 0. 8. 0. 14
088 92 081 085 90 6 091 085 076 076 855. 46 5 4 083 5 090 7
0.87 0.07 13.7 0.088 0.092 8.5
KJB 05/22/91 0.998 WP287 21.9 21.3 16.3
112 12 110 115 07
11.3 0.118
115 118 113 16 58
11.5 10.8 0.118 11.5 0.116 26.0 1.20 0.12 26.3 0.112 0.126 11.5
26.3
MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L UG/L MG/L MG/L MG/L MG/L MG/L UG/L MG/L MG/L UG/L MG/L MG/L MG/L
UG/L
METHOD 2 06.2
ARSENIC JJH 05/20/91 1.00 378-12 34.0 30.9 23.5
METHOD 310.1
ALKALINITY MKW 05/20/91 NA APG487 123 124 108
38.4
132
UG/L
MG/L
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Page No. 2 06/25/91
ANALYTE
QUALITY CONTROL REPORT
INIT DATE OF CORR. QC VALUE TRUE LOWER UPPER UNIT ANALYSIS COEFF. NAME FOUND VALUE CONTROL CONTROL
LIMIT LIMIT
** ACCESSION NUMBER: 105723
METHOD 325.2
CHLORIDE
METHOD 335.2
CYANIDE
METHOD 120.1
CONDUCTIVITY
METHOD 340.2
FLUORIDE
METHOD 350.3
AMMONIA
METHOD 3 53.2
NITRATE
METHOD 150.1
PH
METHOD 365.3
NM 05/28/91 0.999 QCIO.O 10.6 10.0 8.5 11.5 MG/L
WF 05/15/91 0.999 QCMACR 0.28 0.25 0.21 0.29 MG/L
SH 05/20/91 NA O.OIMK 1370 1413 1201 1625 UMHOS/CM
MKW 05/22/91 0.999 APG792 3.02 3.01 2.97 3.11 MG/L
TLK 05/28/91 0.999 WP987 0.19 0.20 0.14 0.21 MG/L
NM 05/23/91 0.999 QC1188 1.99 2.00 1.71 2.28 MG/L
MKW 05/20/91 NA FISHER 6.87 6.86 5.83 7.89 pH
ORTHO PHOSPHATE CW 05/15/91 0.999 WP1188 0.35 0.39 0.31 TOTAL PHOSPHOROUS
CW 05/15/91 0.999 ERA992 4.3 5.0 4.1
0.47 MG/L
5.2 MG/L
SULFATE CW 05/22/91 0.999 ST0CK2 9.8 10.0 9.6 10.3 MG/L
METHOD 160.1
TDS MKW 05/16/91 NA APG366 108 119 102 138 MG/L
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GCMS - RESULTS
ATI I.D. : 10572301
TEST : VOLATILE ORGANICS (EPA 624)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY & ASSOCIATES 562-A HASSAYAMPA 004461 AQUEOUS
DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/14/91 05/15/91 N/A 05/25/91 UG/L
1
COMPOUNDS RESULTS
CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES
SURROGATE PERCENT RECOVERIES
l,2-DICHLOROETHANE-D4 (%) BROMOFLUOROBENZENE (%) T0LUENE-D8 (%]
A-92
<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1
112 106 91
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ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)
TEST : VOLATILE ORGANICS (EPA 624)
ATI I.D. : 10572301
I
COMPOUNDS
NO ADDITIONAL COMPOUNDS
RESULTS
<5
A-93
AjS AnolyticolTechnologies, Inc.
GCMS - RESULTS
TEST : VOLATILE ORGANICS (EPA 6 24)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA 004460 TRIP BLANK AQUEOUS
ATI I.D. : 10572302
DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/14/91 05/15/91 N/A 05/25/91 UG/L
1
COMPOUNDS RESULTS
CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1, 2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES
SURROGATE PERCENT RECOVERIES
l,2-DICKLOROETHANE-D4 (%) BROMOFLUOROBENZENE (%) T0LUENE-D8 (%)
A-94
<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1
115 105 92
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AJS AnolyticolTechnologies,Inc.
ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)
TEST : VOLATILE ORGANICS (EPA 624)
ATI I.D. : 10572302
COMPOUNDS
NO ADDITIONAL COMPOUNDS
RESULTS
<5
A-95
AjS AnolyticolTechnologies, Inc.
GCMS - RESULTS
REAGENT BLANK
TEST : VOLATILE ORGANICS (EPA 6 24
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MONTGOMERY & ASSOCIATES 552-A HASSAYAMPA REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105723 05/24/91 05/24/91 UG/L N/A
COMPOUNDS RESULTS
CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1, 2-DICHLOROETHANE 2-BUTANONE (MEK) 1, 1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES
SURROGATE PERCENT RECOVERIES
l,2-DICHLOROETHANE-D4 (%) BROMOFLUOROBENZENE (%) T0LUENE-D8 (%)
<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1
107 99 100
A-96
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QUALITY CONTROL DATA
TEST : VOLATILE ORGANICS (EPA 624)
CLIENT : MONTGOMERY & ASSOCIATES PROJECT # : 56 2-A PROJECT NAME : HASSAYAMPA REF I.D. : 10599910
lyicu ' / o L<-
ATI I.D. : 105723
DATE ANALYZED : 05/28/91 SAMPLE MATRIX : UNITS : UG/L
COMPOUNDS
DUP. DUP, SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC, RPD
1,1-DICHLOROETHENE TRICHLOROETHENE CHLOROBENZENE TOLUENE BENZENE
<1 <1 <1 <1 <1
50 50 50 50 50
41 47 45 44 41
82 94 90 88 82
43 48 46 44 42
86 95 92 88 84
5 2 2 0 2
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration X 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of Spiked Sample X 100
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ACCESSION: 105723
LABORATORY CONTROL SAMPLE: METHOD 624
589
CLIENT: MONTGOMERY AND ASSOCIATES UNITS: UG/L ANALYSIS DATE: 05/24/91
1,1-DICHLOROETHENE CHLOROFORM 1,1,1-TRICHLOROETHANE BROMODICHLOROMETHANE TRICHLOROETHENE TETRACHLOROETHENE CHLOROBENZENE BENZENE TOLUENE
TRUE VALUE
50 50 50 50 50 50 50 50 50
FO
55 55 45 48 48 50 50 39 48
% REC
110 110 90 96 96 100 100 78 96
% SURROGATE RECOVERY 111 % l,2-DICHLOROETHANE-D4 107 % BROMOFLUOROBENZENE (BFB) 94 % TOLUENE - D8
A-98
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ACCESSION: 105723
QUALITY CONTROL DATA: 589 METHOD 624
CLIENT: MONTGOMERY AND ASSOCIATES UNITS: UG/L ANALYSIS DATE: 05/28/91
1,1-DICHLOROETHENE CHLOROFORM 1,1,1-TRICHLOROETHANE BROMODICHLOROMETHANE TRICHLOROETHENE TETRACHLOROETHENE CHLOROBENZENE BENZENE TOLUENE
TRUE VALUE
50 50 50 50 50 50 50 50 50
FOUND
46 44 49 47 47 48 45 41 44
%
92 88 98 94 94 96 90 82 88
% SURROGATE RECOVERY 93 % l,2-DICHLOROETHANE-D4 94 % BROMOFLUOROBENZENE (BFB) 94 % TOLUENE - D8
A-99
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GCMS - RESULTS
lyjLO' /OUJ^
ATI I.D. : 10572301
TEST : SEMI-VOLATILE ORGANICS (EPA 625)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY 662-A HASSAYAMPA 004461 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/14/91 05/15/91 05/15/91 05/30/91 UG/L
1
COMPOUNDS RESULTS
N-NITROSODIMETHYLAMINE PHENOL ANILINE BIS(2-CHLOROETHYL)ETHER 2-CHLOROPHENOL 1,3-DICHLOROBENZENE 1,4-DICHLOROBENZENE BENZYL ALCOHOL 1,2-DICHLOROBENZENE 2-METHYLPHENOL BIS(2-CHLOROISOPROPYL)ETHER 4-METHYLPHENOL N-NITROSO-DI-N-PROPYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE 2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2-CHLOROETHOXY)METHANE 2, 4-DICHLOROPHENOL 1, 2 , 4-TRICHLOROBENZENE NAPHTPiALENE 4-CHLOROANILINE HEXACHLOROBUTADIENE 4-CHLORO-3-METHYLPHENOL 2-METHYLNAPHTHALENE HEXACHLOROCYCLOPENTADIENE 2,4,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2-CHLORONAPHTHALENE 2-NITROANILINE DIMETHYLPHTHALATE ACENAPHTHYLENE 3-NITROANILINE ACENAPHTHENE 2,4-DINITROPHENOL 4-NITROPHENOL DIBENZOFURAN 2,4-DINITROTOLUENE 2,6-DINITROTOLUENE
<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <50 <10 <10 <50 <10 <50 <50 <10 <10 <10 A-lOO
(CONTINUED NEXT PAGE)
A j S AnolyticolTechnologies, Inc.
GCMS - RESULTS
TEST : SEMI-VOLATILE ORGANICS (EPA 6 25)
Ty^z-J-Zouji
ATI I.D. : 10572301
COMPOUNDS RESULTS
DIETHYLPHTHALATE 4-CHLOROPHENYL-PHENYLETHER FLUORENE 4-NITROANILINE 4 , 6-DINITRO-2-METHYLPHENOL N-NITROSODIPHENYLAMINE 4-BROMOPHENYL-PHENYLETHER HEXACHLOROBENZENE PENTACHLOROPHENOL PHENANTHRENE ANTHRACENE DI-N-BUTYLPHTHALATE FLUORANTHENE BENZIDINE PYRENE BUTYLBENZYLPHTHALATE 3,3'-DICHLOROBENZIDINE BENZO(a)ANTHRACENE BIS(2-ETHYLHEXYL)PHTHALATE CHRYSENE DI-N-OCTYLPHTHALATE BENZO(b)FLUORANTHENE BENZO(k)FLUORANTHENE BENZO(a)PYRENE INDENO(1,2,3-cd)PYRENE DIBENZO(a,h)ANTHRACENE BENZO(g,h,i)PERYLENE
<10 <10 <10 <50 <50 <10 <10 <10 <50 <10 <10 <10 <10 <100 <10 <10 <20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
SURROGATE PERCENT RECOVERIES
NITROBENZENE-DS (%) 2-FLUOROBIPHENYL (%) TERPHENYL (%) PHEN0L-D6 (%) 2-FLUOROPHENOL (%) 2,4,6-TRIBROMOPHENOL (%)
65 50 72 55 58 27
A-101
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ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)
A
TEST : SEMI-VOLATILE ORGANICS (EPA 625;
ATI I . D . : 1 0 5 7 2 3 0 1
COMPOUNDS
NO ADDITIONAL COMPOUNDS
RESULTS
<20
A-102
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GCMS - RESULTS
TEST
REAGENT BLANK
SEMI-VOLATILE ORGANICS (EPA 625)
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MONTGOMERY & ASSOCIATES 652-A HASSAYAMPA REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105723 05/15/91 05/30/91 UG/L N/A
COMPOUNDS RESULTS
<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <50 <10 <10 <50 <10 <50 <50 <10 <10 <10 <10 <10
N-NITROSODIMETHYLAMINE PHENOL ANILINE BIS ( 2-CHLOROETHYL)ETHER 2-CHLOROPHENOL 1,3-DICKLOROBENZENE 1,4-DICHLOROBENZENE BENZYL ALCOHOL 1,2-DICHLOROBENZENE 2-METHYLPHENOL BIS(2-CHLOROISOPROPYL)ETHER 4-METHYLPHENOL N-NITROSO-DI-N-PROPYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE 2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2-CHL0R0ETH0XY)METHANE 2,4-DICHLOROPHENOL 1,2,4-TRICHLOROBENZENE NAPHTHALENE 4-CHLOROANILINE HEXACHLOROBUTADIENE 4-CHLORO-3-METHYLPHENOL 2-METHYLNAPHTHALENE HEXACHLOROCYCLOPENTADIENE 2,4,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2-CHLORONAPHTHALENE 2-NITROANILINE DIMETHYLPHTHALATE ACENAPHTHYLENE 3-NITROANILINE ACENAPHTHENE 2,4-DINITROPHENOL 4-NITROPHENOL DIBENZOFURAN 2,4-DINITROTOLUENE 2,6-DINITROTOLUENE DIETHYLPHTHALATE 4-CHLOROPHENYL-PHENYLETHER
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GCMS - RESULTS
REAGENT BLANK
TEST : SEMI-VOLATILE ORGANICS (EPA 525)
'^•E,-9or:
?y)LO- / o u A
ATI I.D. : 105723
COMPOUNDS RESULTS
FLUORENE 4-NITROANILINE 4,5-DINITRO-2-METHYLPHENOL N-NITROSODIPHENYLAMINE 4-BROMOPHENYL-PHENYLETHER HEXACHLOROBENZENE PENTACHLOROPHENOL PHENANTHRENE ANTHRACENE DI-N-BUTYLPHTHALATE FLUORANTHENE BENZIDINE PYRENE BUTYLBENZYLPHTHALATE 3,3'-DICHLOROBENZIDINE BENZ0(a)ANTHRACENE BIS(2-ETHYLHEXYL)PHTHALATE CHRYSENE DI-N-OCTYLPHTHALATE BENZO(b)FLUORANTHENE BENZO(k)FLUORANTHENE BENZO(a JPYRENE INDENO(1,2,3-cd)PYRENE DIBENZO(a,h)ANTHRACENE BENZO(g,h,i)PERYLENE
SURROGATE PERCENT RECOVERIES
NITROBENZENE-DS (%) 2-FLUOROBIPHENYL (%) TERPHENYL (%) PHEN0L-D6 (%) 2-FLUOROPHENOL (%) 2,4,6-TRIBROMOPHENOL :%)
<10 <50 <50 <10 <10 <10 <50 <10 <10 <10 <10 <100 <10 <10 <20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
64 59 68 53 59 38
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TEST
QUALITY CONTROL DATA
SEMI-VOLATILE ORGANICS (EPA 625)
CLIENT PROJECT # PROJECT NAME REF I.D.
MONTGOMERY & ASSOCIATES 562-A HASSAYAMPA 10699901
ATI I.D,
DATE ANALYZED SAMPLE MATRIX UNITS
105723
05/25/91 AQUEOUS UG/L
COMPOUNDS
DUP. DUP. SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC.
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Saraple Result
Average of Spiked Sample 100
RPD
1, 2,4-TRICHLOROBENZENE ACENAPHTHENE 2, 4-DINITROTOLUENE PYRENE N-NITROSO-DI-N-PROPYLAMINE 1, 4-DICHLOROBENZENE PENTACHLOROPHENOL PHENOL 2-CHLOROPHENOL 4-CHLORO-3-METHYLPHENOL 4-NITROPHENOL
<10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <50
50 50 50 50 50 50 100 100 100 100 100
23 24 30 37 26 24 98 60 59 72 57
46 48 60 74 52 48 98 60 59 72 57
23 22 25 33 23 20 102 60 62 72. 63
46 44 50 56 46 40 102 60 62 72 63
0 9 18 11 12 18 4 0 5 0 10
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ACCESSION: 105723
LABORATORY CONTROL STANDARD 889 BN/A METHOD 625
CLIENT: MONTGOMERY AND ASSOCIATES UNITS: UG/L ANALYSIS DATE: 05/3 0/91
PHENOL 1,2-DICHLOROBENZENE HEXACHLOROETHANE ISOPHORONE 2-NITROPHENOL 2,4-DIMETHYLPHENOL HEXACHLOROBUTADIENE 4-CHLORO-3-METHYLPHENOL 2-METHYLNAPHTHALENE ACENAPHTHYLENE 4-NITROPHENOL 2,6-DINITROTOLUENE 4-CHLOROPHENYL PHENYLETHER N-NITROSODI-N-PHENYLAMINE PENTACHLOROPHENOL DI-N-BUTYLPHTHALATE PYRENE BIS(2-ETHYLHEXYL)PHTHALATE
TRUE VALUE
100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100
OBSERVED VALUE
44 86 97 92 96 76 109 80 73 83 29 84 76 103 55 98 113 141
% R
44 86 97 92 96 76 109 80 73 83 29 84 76 103 55 98 113 141
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GAS CHROMATOGRAPHY - RESULTS
ATI I.D. : 10572301
TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 608)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY 662-A HASSAYAMPA 004461 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/14/91 05/15/91 05/20/91 05/29/91 UG/L
1
COMPOUNDS RESULTS
ALDRIN ALPHA BHC BETA BHC GAMMA BHC (LINDANE) DELTA BHC ALPHA-CHLORDANE 4,4'-DDD 4, 4'-DDE 4,4'-DDT DIELDRIN ENDOSULFAN I ENDOSULFAN II ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE ENDRIN KETONE HEPTACHLOR HEPTACHLOR EPOXIDE METHOXYCHLOR TOXAPHENE AROCLOR 1016
1221 1232 1242 1248 1254 1250
AROCLOR AROCLOR AROCLOR AROCLOR AROCLOR AROCLOR GAMMA-CHLORDANE
SURROGATE PERCENT RECOVERIES
<0.05 <0.05 <0.05 <0.05 <0.05 <0.5 <0 <0 <0 <0
<0 <0 <0 <0 <0
<1 <0
<0 <0
<0 <0
<0.05
<0.05 <0.05 <0.5
<0.5
<0.5 <0.5
DBC (%) 109
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GAS CHROMATOGRAPHY - RESULTS
7?B- To/.-yy>uJ - /C>U.;>\
REAGENT BLANK
TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 508
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MONTGOMERY & ASSOCIATES 562-A HASSAYAMPA REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105723 05/20/91 05/29/91 UG/L N/A
COMPOUNDS RESULTS
ALDRIN ALPHA BHC BETA BKC GAMMA BHC (LINDANE) DELTA BHC ALPHA-CHLORDANE 4,4'-DDD 4,4'-DDE 4,4'-DDT DIELDRIN ENDOSULFAN I ENDOSULFAN II ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE ENDRIN KETONE
1 HEPTACHLOR j HEPTACHLOR EPOXIDE
METHOXYCHLOR . TOXAPHENE
AROCLOR 1016 ^ AROCLOR 1221
AROCLOR 1232 1 AROCLOR 124 2 1 AROCLOR 1248
AROCLOR 1254 , AROCLOR 126 0
GAMMA-CHLORDANE
DBC (% )
SURROGATE PERCENT RECOVERIES
<0.05 <0.05 <0.05 <0.05 <0.05 <0.5 <0.1 <0.1 <0.1 <0.1 <0.05 <0.1 <0.1 <0.1 <0.1 <0.1 <0.05 <0.05 <0.5 <1.0 <0.5 <0 <0 <0 <0 <0 <0.5 <0.5
106
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QUALITY CONTROL DATA ATI I.D.
TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 608) J 105723
CLIENT PROJECT # PROJECT NAME REF I.D.
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA 10572301
DATE ANALYZED SAMPLE MATRIX UNITS
05/29/91 AQUEOUS UG/L
COMPOUNDS
DUP. DUP SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC RPD
GAMMA BHC HEPTACHLOR ALDRIN DIELDRIN ENDRIN DDT
<0.05 <0.05 <0.05 <0.1 <0.1 <0.1
2.0 2.0 2.0 2.0 2.0 2.0
2.2 2.1 2.1 2.2 2.2 2.2
110 2.1 105 2.0 105 2.0 110 2.1 110 2.2 110 2.2
105 100 100 105 110 110
5 5 5 5 0 0
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of Spiked Sample 100
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ACCESSION: 105723
LABORATORY CONTROL SAMPLE: METHOD 608
CLP
CLIENT: MONTGOMERY AND ASSOCIATES UNITS: UG/L ANALYSIS DATE: 05/25/91
TRUE VALUE FOUND % REC
LINDANE HEPTACHLOR ALDRIN DIELDRIN ENDRIN DDT
2. 2. 2 2 2. 2.
2. 2. 2. 2. 2, 1,
100 100 100 105 100 90
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;
Xj ( \ AnalyticalTechnologies, Inc. 9330 s. 51st street suite B-I 13 Ptioemx, AZ 35044 (602)496-4400
June 26, 1991
Errol L. Montgomery & Associates 1075 E. Fort Lowell Road Suite B Tucson, AZ 85719
Project Name/Number: Hassayampa/662-A
Attention: Bill Victor
ATI I.D. 105873
On 05/23/91, Analytical Technologies, Inc. received a request to analyze aqueous sample(s). The sample(s) were analyzed with EPA methodology or equivalent methods. The results of these analyses and the quality control data, which follow each set of analyses, are enclosed.
Dates for inorganic analyses are given on the quality control report form.
If you have any questions or comments, please do not hesitate to contact us at (602) 496-4400.
• ^ • ^ M M .
Michael G. Barry-Project Manager
Robert V. Woods Laboratory Manager
RVW:sdd Enclosure
. 1 ' J . < i\...- - i.
Corporate Offices: 5550 MoretXJuse Drive San Diego, CA 92121 (619) 458-9141
A - 1 1 1
A j S AnolyticalTechnologies,lr
CLIENT PROJECT # PROJECT NAME
MONTGOMERY & ASSOCIATES 552~A HASSAYAMPA
ATI I.D. : 105873
DATE RECEIVED : 05/23/91
REPORT DATE : 06/25/91
ATI # CLIENT DESCRIPTION MATRIX DATE COLLECTED
01 02 03
004463 TRIP BLANK 004464 004465
AQUEOUS AQUEOUS AQUEOUS
05/22/91 05/22/91 05/22/91
TOTALS
MATRIX
AQUEOUS
# SAMPLES
3
ATI STANDARD DISPOSAL PRACTICE
The samples from this project will be disposed of in thirty (30) days from the date of this report. If an extended storage period is required, please contact our sample control department before the scheduled disposal date.
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GENERAL CHEMISTRY RESULTS
CLIENT PROJECT # PROJECT NAME
MONTGOMERY & ASSOCIATES 652-A HASSAYAMPA
ATI I.D. : 105873
DATE RECEIVED : 05/23/91
REPORT DATE : 05/25/91
PARAMETER UNITS 02
CARBONATE (CACO3) BICARBONATE (CACO3) HYDROXIDE (CAC03) TOTAL ALKALINITY (AS CACO3) CHLORIDE CYANIDE, TOTAL CONDUCTIVITY, (UMHOS/CM) FLUORIDE AMMONIA AS NITROGEN NITRATE AS NITROGEN PH PHOSPHATE,ORTHO (AS P) SULFATE TOTAL DISSOLVED SOLIDS PHOSPHOROUS,TOTAL
MG/L MG/L MG/L MG/L MG/L MG/L
MG/L MG/L MG/L UNITS MG/L MG/L MG/L MG/L
<1 163 <1 163 480 <0.01 2190 0.56 0.04 22 7.6 <0.05 190 1700 <0.05
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GENERAL CHEMISTRY - QUALITY CONTROL
CLIENT : MONTGOMERY & ASSOCIATES PROJECT # : 66 2~A PROJECT NAME : HASSAYAMPA
PARAMETER
CARBONATE BICARBONATE HYDROXIDE TOTAL ALKALINITY CHLORIDE CYANIDE, TOTAL CONDUCTIVITY(UMHOS/CM) FLUORIDE AMMONIA AS NITROGEN NITRATE AS NITROGEN PH PHOSPHATE, ORTHO SULFATE TOTAL DISSOLVED SOLIDS PHOSPHOROUS,TOTAL
UNITS
MG/L MG/L MG/L MG/L MG/L MG/L
MG/L MG/L MG/L UNITS MG/L MG/L MG/L MG/L
ATI I.D.
10587302
10587302 10587302 10587302 10587302 10587302 10587302 10587302 10587302 10587302 10587302 10587302
SAMPLE RESULT
<1 163 <1 163 480 <0.01 2190 0.66 0.04 22 7.6 <0.05 190 1700 <0.05
ATI
DUP. RESULT
<1 161 <1 161 490 <0.01 2150 0.65 0.04 22 7.6 <0.05 190 1700 <0.05
I.D.
RPD
NA 1
NA 1 2
NA 2 0 0 0 0
NA 0 0
NA
: 105873
SPIKED SAMPLE
NA NA NA NA 1000 0.23 NA 1.52 0.47 63 NA 0.51 370 NA 0.49
SPIKE CONC
NA NA NA NA 500 0.25 NA 0.88 0.50 40 NA 0.50 190 NA 0.50
% REC
NA NA NA NA 104 92 NA 98 85 102 NA 102 95 NA 98
X 100 % Recovery = (Spike Sample Result - Sample Result
Spike Concentration
RPD (Relative Percent Difference) = (Sample Result - Duplicate Result)
Average Result X 100
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METALS RESULTS
CLIENT PROJECT # PROJECT NAME
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA
y>iuj--jouB
ATI I . D . : 105873
DATE RECEIVED : 05/23/91
REPORT DATE : 06/25/91
PARAMETER UNITS 02
SILVER ALUMINUM ARSENIC BORON BARIUM BERYLLIUM CALCIUM CADMIUM COBALT CHROMIUM COPPER IRON MERCURY POTASSIUM MAGNESIUM MANGANESE SODIUM NICKEL LEAD ANTIMONY SELENIUM SILICA TIN THALLIUM VANADIUM ZINC
MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L
<0.010 <0.05 <0.005 0.51 0.240 <0.005 205 <0.005 <0.010 <0.010 <0.010 <0.020 <0.0002 3.5 49.6 <0.010 187 <0.020 0.004 <0.05 <0.005 32.9 <0.03 <0.005 <0.010 0.190
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METALS - QUALITY CONTROL
CLIENT : MONTGOMERY & ASSOCIATES PROJECT # : 56 2-A PROJECT NAME : HASSAYAMPA
/^/^-^ - JOuT^
ATI I . D . : 105873
PARAMETER UNITS ATI I SAMPLE
D. RESULT DUP. RESULT RPD
SPIKED SPIKE % SAMPLE CONC REC
SILVER ALUMINUM ARSENIC BORON BARIUM BERYLLIUM CALCIUM CADMIUM COBALT CHROMIUM COPPER IRON MERCURY POTASSIUM MAGNESIUM MANGANESE SODIUM NICKEL LEAD ANTIMONY SELENIUM SILICA TIN THALLIUM VANADIUM ZINC
MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L
10587302 10587302 10592104 10587302 10587302 10587302 10587302 10587302 10587302 10587302 10587302 10587302 10587302 10587302 10587302 10587302 10587302 10587302 10586501 10587302 10591701 10587302 10587302 10587302 10587302 10587302
<0.010 <0.05 <0.005 0.51 0.240 <0.005 205 <0.005 <0.010 <0.010 <0.010 <0.020 <0.0002 3.6 49.6 <0.010 187 <0.020 <0.002 <0.05 <0.005 32.9 <0.03 <0.005 <0.010 0.190
<0.010 <0.05 <0.005 0.50 0.241 <0.005 209 <0.005 <0.010 <0.010 <0.010 <0.020 <0.0002 3.4 50.4 <0.010 182 <0.020 <0.002 <0.05 <0.005 33.4 <0.03 <0.005 0.011 0.190
NA NA NA 2
0.4 NA 2
NA NA NA NA NA NA 6 2
NA 3
NA NA NA NA 2
NA NA NA 0
0.093 10.3 0.044 1.51 0.344 0.095 261 0.102 0. 100 0.105 0.097 1.03 0.0050 52.3 75.4 0.104 230 0.085 0.049 0.97 0.055 55.2 1.06 0.055 0.107 0.301
0.100 10.0 0.050 1.00 0.100 0.100 50.0 0.100 0.100 0.100 0.100 1.00 0.0050 50.0 25.0 0.100 50.0 0.100 0.050 1.00 0.050 21.4 1.00 0.050 0.100 0.100
93 103 88 100 104 95 112 102 100 105 97 103 100 97 107 104 86 86 98, 97 110 104 106 110 107 111
X 100 % Recovery = (Spike Sample Result - Sample Result)
Spike Concentration
RPD (Relative Percent Difference) = (Sample Result - Duplicate Result) X 100
Average Resul t
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li ANALYTE
QUALITY CONTROL REPORT
INIT DATE OF CORR. QC VALUE TRUE LOWER UPPER UNIT ANALYSIS COEFF. NAME FOUND VALUE CONTROL CONTROL
LIMIT LIMIT
** ACCESSION NUMBER: 105873
METHOD 310.1 ALKALINITY
METHOD 160.1 TDS
TLK 05/29/91 NA
TLK 05/31/91 NA
METHOD RFA 3 53.2 NITRATE NM 06/03/91 0.999
METHOD RFA 325.2 CHLORIDE
METHOD 3 35.2 CYANIDE
METHOD 12 0.1 CONDUCTIVITY
METHOD 34 0.2 FLUORIDE
METHOD 350.3 AMMONIA
NM 06/06/91 0.999
WF 05/23/91 0.999
SH 05/24/91 NA
TLK 06/07/91 0.999
TLK 06/03/91 0.998
METHOD 3 65.3 TOTAL PHOSPHORUS CW 05/23/91 1.000
APG487 62 62 54
APG366 128 120 102
QC1188 1.99 2.00 1.71
QCIO.O 10.6 10.0 8.5
MACRO 0.24 0.25 0.21
O.OIM 1310 1413 1201
APG792 2.99 3.01 2.97
WP987 0.18 0.20 0.14
ERA992 4.2 5.0 4.1
METHOD 150.1 PH
METHOD 3 65.3 ORTHOPHOSPHATE CW 05/23/91 1.000 WP1188 0 . 3 6 0 . 3 9 0 . 3 1
METHOD 3 0 0 . 0 SULFATE CW 0 5 / 2 4 / 9 1 0 . 9 9 9 ST0CK2 9 . 7 1 0 . 0 9 . 6
METHOD COLD VAPOR ( 2 4 5 . 1 ) MERCURY J J H 0 6 / 0 5 / 9 1 0 . 9 9 9
6 6 MG/L
1 3 8 MG/L
2 . 2 8 MG/L
1 1 . 5 MG/L
0 . 2 9 MG/L
1 6 2 5 UMHO/CM
3 . 1 1 MG/L
0 . 2 1 MG/L
5 . 3 MG/L
TLK 0 5 / 2 9 / 9 1 NA FISHER 6 . 8 5 6 . 8 6 5 . 8 3 7 . 8 9 PH
0 . 4 7 . MG/L
1 0 . 4 MG/L
TMA989 1 . 9 6 2 . 0 2 1 . 4 6 2 . 5 8 UG/L
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QUALITY CONTROL REPORT
ANALYTE INIT DATE OF CORR. QC ANALYSIS COEFF. NAME
VALUE TRUE LOWER UPPER UNIT FOUND VALUE CONTROL CONTROL
LIMIT LIMIT
** ACCESSION NUMBER: 105873
METHOD ICP SILVER ALUMINUM BORON BARIUM BERYLLIUM CALCIUM CADMIUM COBALT CHROMIUM COPPER IRON POTASSIUM MAGNESIUM MANGANESE SODIUM NICKEL ANTIMONY SILICA TIN VANADIUM ZINC
METHOD GFAA THALLIUM SELENIUM LEAD ARSENIC
(200.7) SES SES SES SES SES SES SES SES SES SES SES SES SES SES SES SES SES SES SES SES SES
06/12/91 06/13/91 06/12/91 06/12/91 06/12/91 06/12/91 06/12/91 06/12/91 06/12/91 06/12/91 06/12/91 06/12/91 06/12/91 06/12/91 06/12/91 06/12/91 06/12/91 06/12/91 06/13/91 06/12/91 06/12/91
(279.2,-270.2;239.2 JJH SES SES SES
06/05/91 06/11/91 06/03/91 06/04/91
NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
;206.2) 0.999 1.000 0.999 1.000
ICAP2 I CAP 3 ICAP7 I CAP 3 I CAP 3 ICAP4 ICAP3 I CAP 3 ICAP3 ICAP3 ICAP3 ICAP4 ICAP4 I CAP 3 ICAP4 ICAP3 SVI ICAP4 ICAP3 I CAP 3 I CAP 3
WP186 WP28 7 WP287 WP378
0.099 10.1 0.99 0.099 0.092 10.0 0.099 0.101 0.099 0.099 1.02 9.9 10.2 0.100 10.2 0.093 0.95 11.0 0.98 0.098 0.101
21.4 23.5 20.0 31.0
0.095 10.0 0.99 0.098 0.094 10.0 0.104 0.100 0.102 0.094 0.999 10.1 10.2 0.102 10.5 0.105 0.98 10.0 1.00 0.100 0.109
20.0 21.3 20.4 30.9
0.079 8.5 0.90 0.088 0.083 8.6 0.086 0.085 0.089 0.079 0.896 8.6 9.5 0.090 9.9 0.085 0.88 8.5 0.85 0.088 0.083
13.7 16.3 14.7 23.5
0.111 11.5 1.07 0.108 0.105 11.3 0.122 0.115 0.115 0.110 1.10 11.7 11.0 0.115 11.0 0.124 1.08 11.5 1.15 0.112 0.135
26.3 26.3 26.0 38.4
MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L MG/L
UG/L UG/L UG/L UG/L
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GCMS - RESULTS
ATI I.D. 10587301
TEST : VOLATILE ORGANICS (EPA 624)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA 004463 TRIP BLANK AQUEOUS
DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/22/91 05/23/91 N/A 06/02/91 UG/L
1
COMPOUNDS RESULTS
CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES
SURROGATE PERCENT RECOVERIES
l,2-DICHLOROETHANE-D4 (%) BROMOFLUOROBENZENE (%) T0LUENE-D8 (%)
<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1
89 102 101
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ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)
TEST : VOLATILE ORGANICS (EPA 624)
ATI I.D. : 10587301
COMPOUNDS
NO ADDITIONAL COMPOUNDS
RESULTS
<5
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GCMS - RESULTS
ATI I.D. : 10587302
TEST : VOLATILE ORGANICS (EPA 6 24)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA 004464 AQUEOUS
DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/22/91 05/23/91 N/A 06/02/91 UG/L
1
COMPOUNDS RESULTS
CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1 -DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1, 2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES
SURROGATE PERCENT RECOVERIES
l,2-DICHLOROETHANE-D4 (%) BROMOFLUOROBENZENE (%) T0LUENE-D8 (%)
A-121
<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1
94 101 104
/ ^ S AnalyticolTechnologies,Inc.
ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)
A
TEST : VOLATILE ORGANICS (EPA 5 24)
ATI I.D. : 10587302
COMPOUNDS
NO ADDITIONAL COMPOUNDS
RESULTS
<5
A-122
AjS AnalyticalTechnologies,
I 'B. 5 r T."B. y-
iy?u -you'd
GCMS - RESULTS
REAGENT BLANK
TEST : VOLATILE ORGANICS (EPA 6 24)
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MONTGOMERY & ASSOCIATES 652-A HASSAYAMPA REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105873 05/02/91 06/02/91 UG/L N/A
COMPOUNDS RESULTS
CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1 ,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1 ,2 ,2-TETRACHLOROETHANE 1 , 2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1 ,1 ,2-TRICHLOROETHANE BENZENE C I S - 1 , 3 - D I C H L O R O P R O P E N E 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK)
"4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES
SURROGATE PERCENT RECOVERIES'
l,2-DICHLOROETHANE-D4 (%) BROMOFLUOROBENZENE (%) T0LUENE-D8 (%)
<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 < 1 <1 <1 < 1 < 1 <1 <1 < 1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1
87 102 101
A-123
A j S AnolyticalTechnologies,Inc.
yhu)-you.i}>
TEST
QUALITY CONTROL DATA
VOLATILE ORGANICS (EPA 524)
CLIENT PROJECT # PROJECT NAME REF I.D.
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA 10699903
ATI I.D. 105873
DATE ANALYZED : 06/02/91 SAMPLE MATRIX : AQUEOUS UNITS : UG/L
COMPOUNDS
DUP. DUP. SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC. RPD
1,1-DICHLOROETHENE TRICHLOROETHENE CHLOROBENZENE TOLUENE BENZENE
<1 <1 <1 <1 <1
50 50 50 50 50
47 49 50 50 39
94 48 98 52 100 53 100 53 78 41
96 104 106 105 82
2 5 6 6 5
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration X 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of Spiked Sample X 100
A-124
lr>Ld -/DulZ)
A^J^ AnalyticalTechnologies, I
ACCESSION: 105873
QUALITY CONTROL DATA: METHOD 624
589
CLIENT: Montgomery & Associates UNITS: UG/L ANALYSIS DATE: 06/02/91
1,1-DICHLOROETHENE CHLOROFORM 1,1,1-TRICHLOROETHANE BROMODICHLOROMETHANE TRICHLOROETHENE TETRACHLOROETHENE CHLOROBENZENE BENZENE TOLUENE
TRUE VALUE
50 50 50 50 50 50 50 50 50
FOUND
47 49 46 48 48 48 48 39 48
%
94 98 92 96 96 96 96 78 96
% SURROGATE RECOVERY 88% l,2-DICHLOROETHANE-D4 105% BROMOFLUOROBENZENE (BFB) 98% TOLUENE - D8
A-125
\ IT
^JS^ AnalyticolTechnologies, Inc
7^/L)-'Jy^u'2>
GCMS - RESULTS
ATI I.D. : 10587302
TEST : SEMI-VOLATILE ORGANICS (EPA 625)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA 004464 AQUEOUS
DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/22/91 05/23/91 05/28/91 06/05/91 UG/L
1
COMPOUNDS RESULTS
N-NITROSODIMETHYLAMINE PHENOL ANILINE BIS(2-CHLOROETHYL)ETHER 2-CHLOROPHENOL 1, 3-DICHLOROBENZENE 1,4-DICHLOROBENZENE BENZYL ALCOHOL 1, 2-DICHLOROBENZENE 2-METHYLPHENOL BIS(2-CHLOROISOPROPYL)ETHER 4-METHYLPHENOL N-NITROSO-DI-N-PROPYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE 2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2-CHLOROETHOXY)METHANE 2 , 4-DICHLOROPHENOL 1,2,4-TRICHLOROBENZENE NAPHTHALENE 4-CHLOROANILINE HEXACHLOROBUTADIENE 4-CHLORO-3-METHYLPHENOL 2-METHYLNAPHTHALENE HEXACHLOROCYCLOPENTADIENE 2,4,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2-CHLORONAPHTHALENE 2-NITROANILINE DIMETHYLPHTHALATE ACENAPHTHYLENE 3-NITROANILINE ACENAPHTHENE 2,4-DINITROPHENOL 4-NITROPHENOL DIBENZOFURAN 2,4-DINITROTOLUENE 2,6-DINITROTOLUENE
<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <50 <10 <10 <50 <10 <50 <50 <10 <10 <10
A-126
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AjS AnolyticolTechnologies, Inc.
GCMS - RESULTS ATI I.D.
p?^v ' -you^
10587302
TEST : SEMI-VOLATILE ORGANICS (EPA 6 2 5 )
COMPOUNDS RESULTS
DIETHYLPHTHALATE 4-CHLOROPHENYL-PHENYLETHER FLUORENE 4-NITROANILINE 4 , 6-DINITRO-2-METHYLPHENOL N-NITROSODIPHENYLAMINE 4-BROMOPHENYL-PHENYLETHER HEXACHLOROBENZENE PENTACHLOROPHENOL PHENANTHRENE ANTHRACENE DI-N-BUTYLPHTHALATE FLUORANTHENE BENZIDINE PYRENE BUTYLBEN ZYLPHTHALATE 3 , 3 ' - D I C H L O R O B E N Z I D I N E BENZO(a)ANTHRACENE BIS(2-ETHYLHEXYL)PHTHALATE CHRYSENE DI-N-OCTYLPHTHALATE BENZO(b)FLUORANTHENE BENZO(k)FLUORANTHENE BENZO(a)PYRENE INDENO(1,2,3-cd)PYRENE DIBENZO(a,h)ANTHRACENE BENZO(g,h,i)PERYLENE
<10 <10 <10 <50 <50 <10 <10 <10 <50 <10 <10 <10 <10 <100 <10 <10 <20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
SURROGATE PERCENT RECOVERIES
NITROBENZENE-DS (%) 2-FLUOROBIPHENYL (%) TERPHENYL (%) PHEN0L-D5 (%) 2-FLUOROPHENOL (%) 2,4,6-TRIBROMOPHENOL (V
109 102 102 85 87 88
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/ j j ^ AnolyticolTechnologies, Inc.
ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)
TEST : SEMI-VOLATILE ORGANICS (EPA 625)
ATI I.D. : 10587302
COMPOUNDS
NO ADDITIONAL COMPOUNDS
RESULTS
<20
A-128
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GCMS - RESULTS
REAGENT BLANK
TEST : SEMI-VOLATILE ORGANICS (EPA 625)
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MONTGOMERY & ASSOCIATES 562-A HASSAYAMPA REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105873 05/28/91 06/06/91 UG/L N/A
COMPOUNDS RESULTS
N-NITROSODIMETHYLAMINE PHENOL ANILINE BIS(2-CHLOROETHYL)ETHER 2-CHLOROPHENOL 1, 3-DICHLOROBENZENE 1,4-DICHLOROBENZENE BENZYL ALCOHOL 1,2-DICHLOROBENZENE 2-METHYLPHENOL BIS(2-CHLOROISOPROPYL)ETHER 4-METHYLPHENOL N-NITROSO-DI-N-PROPYLAMINE HEXACHLOROETHANE NITROBENZENE ISOPHORONE 2-NITROPHENOL 2,4-DIMETHYLPHENOL BENZOIC ACID BIS(2-CHLOROETHOXY)METHANE 2, 4-DICHLOROPHENOL 1, 2,4-TRICHLOROBENZENE NAPHTHALENE 4-CHLOROANILINE HEXACHLOROBUTADIENE 4-CHLORO-3-METHYLPHENOL 2-METHYLNAPHTHALENE HEXACHLOROCYCLOPENTADIENE 2,4,6-TRICHLOROPHENOL 2,4,5-TRICHLOROPHENOL 2-CHLORONAPHTHALENE 2-NITROANILINE DIMETHYLPHTHALATE ACENAPHTHYLENE 3-NITROANILINE ACENAPHTHENE 2,4-DINITROPHENOL 4-NITROPHENOL DIBENZOFURAN 2,4-DINITROTOLUENE 2,6-DINITROTOLUENE DIETHYLPHTHALATE 4-CHLOROPHENYL-PHENYLETHER
<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <50 <10 <50 <10 <10 <50 <10 <50 <50 <10 <10 <10 <10 <10
(CONTINUED NEXT PAGE) A-129
AJS AnolyticalTechnologies,Inc. A ^ GCMS - RESULTS
REAGENT BLANK
TEST : SEMI-VOLATILE ORGANICS (EPA 6 25)
PIB- Per:
ATI I.D. 105873
COMPOUNDS RESULTS
FLUORENE 4-NITROANILINE 4 , 6-DINITRO-2-METHYLPHENOL N-NITROSODIPHENYLAMINE 4-BROMOPHENYL-PHENYLETHER HEXACHLOROBENZENE PENTACHLOROPHENOL PHENANTHRENE ANTHRACENE DI-N-BUTYLPHTHALATE FLUORANTHENE BENZIDINE PYRENE BUTYLBENZYLPHTHALATE 3,3'-DICHLOROBENZIDINE BENZO(a)ANTHRACENE BIS(2-ETHYLHEXYL)PHTHALATE CHRYSENE DI-N-OCTYLPHTHALATE BENZO(b)FLUORANTHENE BENZO(k)FLUORANTHENE BENZO(a)PYRENE INDENO(1,2,3-cd)PYRENE DIBENZO(a,h)ANTHRACENE BENZO(g,h,i)PERYLENE
SURROGATE PERCENT RECOVERIES
NITROBENZENE-DS (%) 2-FLUOROBIPHENYL (%) TERPHENYL (%) PHEN0L-D6 (%) 2-FLUOROPHENOL (%) 2,4, 6-TRIBROMOPHENOL (%)
<10 <50 <50 <10 <10 <10 <50 <10 <10 <10 <10 <100 <10 <10 <20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
60 55 54 45 49 45
A-130
A AJS AnolyticolTechnologies,Inc.
QUALITY CONTROL DATA
SEMI-VOLATILE ORGANICS (EPA 6 25) TEST
CLIENT PROJECT # PROJECT NAME REF I.D.
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA 10699907
'»^i<j-yooc'd>
ATI I.D,
DATE ANALYZED SAMPLE MATRIX UNITS
105873
06/08/91 AQUEOUS UG/L
COMPOUNDS
DUP. DUP. SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC RPD
1,2,4-TRICHLOROBENZENE ACENAPHTHENE 2,4-DINITROTOLUENE PYRENE N-NITROSO-DI-N-PROPYLAMINE 1,4-DICHLOROBENZENE P ENTACHLOROPHENOL PHENOL 2-CHLOROPHENOL 4-CHLORO-3-METHYLPHENOL 4-NITROPHENOL
<10 <10 <10 <10 <10 <10 <50 <10 <10 <10 <50
50 50 50 50 50 50 100 100 100 100 100
30 30 29 26 35 29 92 57 58 62 74
60 60 58 52 72 58 92 57 58 62 74
31 29 28 25 33 27 92 58 60 65 73
62 58 55 50 66 54 92 58 60 65 73
3 3 4 4 9 7 0 2 3 5 3
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of Spiked Sample 100
A-131
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/ \ AnalyticolTechnologies,I
ACCESSION: 105873
LABORATORY CONTROL STANDARD: 889 BN/A METHOD 625
CLIENT: MONTGOMERY & ASSOCIATES UNITS: UG/L ANALYSIS DATE: 05/30/91
PHENOL 1,2-DICHLOROBENZENE HEXACHLOROETHANE ISOPHORONE 2-NITROPHENOL 2,4-DIMETHYLPHENOL HEXACHLOROBUTADIENE 4-CHLORO-3-METHYLPHENOL 2-METHYLNAPHTHALENE ACENAPHTHYLENE 4-NITROPHENOL 2,6-DINITROTOLUENE 4-CHLOROPHENYL PHENYLETHER N-NITROSODI-N-PHENYLAMINE PENTACHLOROPHENOL DI-N-BUTYLPHTHALATE PYRENE BIS(2-ETHYLHEXYL)PHTHALATE
TRUE VALUE
100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100
OBSERVED VALUE
44 86 97 92 96 76 109 80 73 83 29 84 76 103 55 98 113 141
% REC
44 86 97 93 96 76 109 80 73 83 29 84 76 103 55 98 113 141
A-132
ti
A j S AnalyticalTechnologies, Inc.
I r ) iy0- iou2>
GAS CHROMATOGRAPHY - RESULTS
ATI I.D. 10587302
TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 608)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY 662-A HASSAYAMPA 004464 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/22/91 05/23/91 05/29/91 06/05/91 UG/L
1
COMPOUNDS RESULTS
ALDRIN ALPHA BHC BETA BHC GAMMA BHC (LINDANE) DELTA BHC ALPHA-CHLORDANE 4,4'-DDD 4,4'-DDE 4,4'-DDT DIELDRIN ENDOSULFAN I ENDOSULFAN II ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE ENDRIN KETONE HEPTACHLOR HEPTACHLOR EPOXIDE METHOXYCHLOR TOXAPHENE AROCLOR 1016 AROCLOR 1221 AROCLOR 123 2 AROCLOR 124 2 AROCLOR 124 8 AROCLOR 1254 AROCLOR 126 0 GAMMA-CHLORDANE
<0. <0. <0. <0. <0. <0. <0. <0. <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <1 <0 <0 <0 <0 <0 <0 <0 <0
05 05 05 OS 05 5
05
05 05 .5 .0 .5 .5 .5 .5 .5 .5 .5 .5
SURROGATE PERCENT RECOVERIES
DBC (% ) 116
A-133
A ^JS^ AnalyticalTechnologies, Inc.
GAS CHROMATOGRAPHY - RESULTS
7?V3. for :
TEST
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
REAGENT BLANK
ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 608) ATI I.D.
MONTGOMERY & ASSOCIATES DATE EXTRACTED 66 2-A DATE ANALYZED HASSAYAMPA UNITS REAGENT BLANK DILUTION FACTOR
105873 05/29/91 06/04/91 UG/L N/A
COMPOUNDS RESULTS
ALDRIN ALPHA BHC BETA BHC GAMMA BHC (LINDANE) DELTA BHC ALPHA-CHLORDANE 4,4'-DDD 4,4'-DDE 4,4'-DDT DIELDRIN ENDOSULFAN I ENDOSULFAN II ENDOSULFAN SULFATE ENDRIN ENDRIN ALDEHYDE ENDRIN KETONE HEPTACHLOR HEPTACHLOR EPOXIDE METHOXYCHLOR TOXAPHENE AROCLOR 1016 AROCLOR 12 21 AROCLOR 123 2 AROCLOR 124 2 AROCLOR 124 8 AROCLOR 1254 AROCLOR 126 0 GAMMA-CHLORDANE
SURROGATE PERCENT RECOVERIES
< 0 . 0 5 < 0 . 0 5 < 0 . 0 5 < 0 . 0 5 < 0 . 0 5 <0. <0 <0 <0 <0 < 0 . 0 5 <0 . <0, <0 . <0. <0 < 0 . 0 5 < 0 . 0 5 < 0 . 5 <1 <0
0 5
DBC ( % )
< 0 . 5 < 0 . 5 < 0 . 5 < 0 . 5 < 0 . 5 < 0 . 5 < 0 . 5
109
A-134
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/ \ AnolyticalTechnologies,Inc.
QUALITY CONTROL DATA ATI I.D,
TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 608) 105873
CLIENT PROJECT # PROJECT NAME REF I.D.
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA 10599902
DATE ANALYZED : 05/05/91 SAMPLE MATRIX : AQUEOUS UNITS : UG/L
COMPOUNDS
DUP. DUP, SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC, RPD
GAMMA BHC HEPTACHLOR ALDRIN DIELDRIN ENDRIN DDT
<0.05 <0.05 <0.05 <0.1 <0.1 <0.1
2.0 2.0 2.0 2.0 2.0 2.0
1.9 1.8 1.7 1.9 1.8 2.0
95 90 85 95 90 100
2.1 1.9 1.8 2.1 2.2 2.1
105 95 90 105 110 105
10 5 5 10 20 5
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of Spiked Sample 100
A-135
> ? ^ ' ^ ^ ^ 3
/ \ AnolyticolTechnologies,!r
ACCESSION: 105873
QUALITY CONTROL STANDARD - CLP METHOD 608
CLIENT: MONTGOMERY & ASSOCIATES UNITS: UG/L ANALYSIS DATE: 06/04/91
COMPOUND
LINDANE HEPTACHLOR ALDRIN DIELDRIN ENDRIN
OBSERVED TRUE VALUE VALUE
2.0 1.8 2.0 1.7 2.0 1.8 2.0 1.8 2.0 1.7
%
90 85 90 90 85
REC
A-136
4
AjJ^ AnalyticalTechnologies, Inc. 9830 S. 51st Street Suite B-113 Ptioenix, AZ 85044 (602) 496-4400
ATI I.D. 105972
June 18, 1991
Errol L. Montgomery & Associates 107 5 E. Fort Lowell Road Suite B Tucson, AZ 85719
Project Name/Number: Hassayampa 662-A
Attention: Bill Victor
On 05/30/91, Analytical Technologies, Inc. received a request to analyze aqueous sample(s). The sample(s) were analyzed with EPA methodology or equivalent methods. The results of these analyses and the quality control data, which follow each set of analyses, are enclosed.
If you have any questions or comments, please do not hesitate to contact us at (602) 496-4400.
"M-lm/h-Michael G. Barry P ro jec t Manager
U y (I- i < Robert V. Woods Laboratory Manager
(y^iyiAyKy..ryui^ plj'^Uiy--^,^.^ Lorraine Davis QA Coordinator
RVW:jat Enclosure
Corporate Offices: 5550 Morehouse Drive San Diego. CA 92121 (619) 458-9141
A-137
AJJ!I^ Analyt icalTechnologies, Inc. 9330 S. 51st Street Suite 8-113 Ptioenix. AZ 85044 (602) 496-4400
ATI I.D. 105972
July 16, 1991
Errol L. Montgomery & Associates 1075 E. Fort Lowell Road Suite B Tucson, AZ 85719
Project. Name/Number: Hassayampa 662-A
Attention: Bill Victor
On 05/30/91, Analytical Technologies, Inc. received a request to analyze aqueous sample(s). The sample(s) were analyzed with EPA methodology or eguivalent methods. The results of these analyses and the quality control data, which follow each set of analyses, are enclosed.
Enclosed is an amended report for the Method 601/602 Laboratory Control Standard.
If you have any questions or comments, please do. not hesitate to contact us at (602) 496-4400.
pkf-Michael G. Barry Project Manager
Lorraine Davis QA Coordinator
RVW:jat Enclosure
Robert V. Woods Laboratory Manager
Pi^-'tiift'Ll
Corporate Offices: 5550 Moretiouse Drive San Diego, CA 92121 (619) 458-9141
A-138
AjS AnolyticolTechnologies, Inc.
CLIENT PROJECT # PROJECT NAME
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA
ATI I.D. : 105972
DATE RECEIVED : 05/30/91
REPORT DATE : 06/11/91
ATI # CLIENT DESCRIPTION MATRIX DATE COLLECTED
01 02
010924 TRIP BLANK 010925
AQUEOUS AQUEOUS
05/30/91 05/30/91
TOTALS
MATRIX
AQUEOUS
# SAMPLES
2
ATI STANDARD DISPOSAL PRACTICE
The samples from this project will be disposed of in thirty (30) days from the date of this report. If an extended storage period is required, please contact our sample control department before the scheduled disposal date.
A-139
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GAS CHROMATOGRAPHY - RESULTS
ATI I.D, 10597201
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 501/602)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA 010924 TRIP BLANK AQUEOUS
DATE DATE DATE DATE
SAMPLED RECEIVED EXTRACTED ANALYZED
UNITS DILUTION FACTOR
05/30/91 05/30/91 N/A 06/05/91 UG/L
1
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHANE CHLOROFORM CHLOROMETHANE DIBROMOCHLOROMETHANE 2-CHLOROETHYL VINYL ETHER 1,3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1,1-DICHLOROETHANE 1,2-DICHLOROETHANE 1,1-DICHLOROETHENE 1,2-DICHLOROETHENE(TOTAL) 1,2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1,1,1-TRICHLOROETHANE 1,1,2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
<0 <0 <0 <0 <0 <0 <0 <0 <0 <0
<0, <0. <0. <0 <0 <0 <0 <0 <0 <0
<0 <0 <0 <0 <0 <0 <0 <0
<0.5 <0.5
<2.0 <0.2
<2.0
SURROGATE PERCENT RECOVERIES
BROMOCHLOROMETHANE (%) BROMOFLUOROBENZENE (%)
92 107
A-140
A j S AnalyticalTechnologies,Inc.
Svcitit-'-re
GAS CHROMATOGRAPHY - RESULTS
ATI I.D, 10597202
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 601/602)
CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX
MONTGOMERY 562-A HASSAYAMPA 010925 AQUEOUS
& ASSOCIATES DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
05/30/91 05/30/91 N/A 05/05/91 UG/L
1
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHANE CHLOROFORM CHLOROMETHANE DIBROMOCHLOROMETHANE 2-CHLOROETHYL VINYL ETHER 1 , 3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1,1-DICHLOROETHANE 1 , 2-DICHLOROETHANE 1 , 1-DICHLOROETHENE 1 , 2-DICHLOROETHENE(TOTAL) 1 , 2-DICHLOROPROPANE CIS-1 ,3 -DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1,1,1-TRICHLOROETHANE 1,1,2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
SURROGATE PERCENT RECOVERIES
BROMOCHLOROMETHANE (%) BROMOFLUOROBENZENE (%)
<0. <0. <0. <0. <0. <0. <0. <0. <0. <0. <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <0 <2 <0 <0 <0 <0 <0 <0 <0 <0 <0 <2
5 2 2 2 2 5 2 2 2 2 5 5 5 2 2 2 2 2 2 2 .2 .5 .0 .2 .2 .5 .2 .2 .2 .5 .2 .5 .0
112 115
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GAS CHROMATOGRAPHY - RESULTS
REAGENT BLANK
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 601/602)
CLIENT PROJECT # PROJECT NAME CLIENT I.D.
MONTGOMERY & ASSOCIATES 662-A HASSAYAMPA REAGENT BLANK
ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR
105972 06/05/91 06/05/91 UG/L N/A
COMPOUNDS RESULTS
BENZENE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROBENZENE CHLOROETHANE CHLOROFORM CHLOROMETHANE DIBROMOCHLOROMETHANE 2-CHLOROETHYL VINYL ETHER 1, 3-DICHLOROBENZENE 1,2 & 1,4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1, 1-DICHLOROETHANE 1, 2-DICHLOROETHANE 1, 1-DICHLOROETHENE 1 , 2-DICHLOROETHENE(TOTAL) 1, 2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE ETHYLBENZENE METHYLENE CHLORIDE 1,1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE TOLUENE 1 , 1 , l-TRICHLOROETPLANE 1,1,2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE TOTAL XYLENES TRICHLOROTRIFLUOROETHANE
<0 <0 <0.2 <0.2 <0.2 <0.5 <0.2 <0.2 <0.2 <0.2 <0.5 <0.S <0.5 <0.2 <0 <0 <0 <0 <0 <0
2 2 2 2 2 2
<0.2 <0.S <2.0 <0.2 <0.2 <0.5 <0, <0 <0 <0 2.0 <0.S <2.0
2 2 2 5
SURROGATE PERCENT RECOVERIES
BROMOCHLOROMETHANE (%) BROMOFLUOROBENZENE (%)
95 82
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QUALITY CONTROL DATA
TEST : VOLATILE HALOCARBONS/AROMATICS (EPA 501/602) ATI I.D. 105972
CLIENT PROJECT # PROJECT NAME REF I.D.
MONTGOMERY 662-A HASSAYAMPA 10699906
& ASSOCIATES DATE ANALYZED SAMPLE MATRIX UNITS
05/05/91 AQUEOUS UG/L
COMPOUNDS
DUP. DUP. SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC RPD
1,1-DICHLOROETHENE TRICHLOROETHENE TETRACHLOROETHENE BENZENE BROMODICHLOROMETHANE CHLOROFORM 1,1,1-TRICHLOROETHANE TOLUENE CHLOROBENZENE M-XYLENE
<0.2 <0.2 <0.2 <0.5 <0.2 <0.2 <0.2 <0.5 <0.5 <0.5
20 20 20 20 20 20 20 20 20 20
17 18 17 17 20 19 18 18 16 17
85 90 85 85 100 95 90 90 80 85
15 17 17 17 19 18 18 17 16 17
80 85 85 85 95 90 90 85 80 85
6 5 0 0 5 5 0 6 0 0
% Recovery = (Spike Sample Result - Sample Result)
Spike Concentration 100
RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result
Average of Spiked Sample X 100
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ACCESSION: 105972
QUALITY CONTROL DATA: 589 METHOD 601/602
CLIENT: Montgomery and Associates UNITS: UG/L ANALYSIS DATE: 06/05/91
1,1-DICHLOROETHENE TRICHLOROMETHANE 1,1,1-TRICHLOROETHANE BROMODICHLOROMETHANE TRICHLOROETHENE TETRACHLOROETHENE CHLOROBENZENE BENZENE METHYLBENZENE 1,2-DICHLOROBENZENE 1,3-DIMETHYLBENZENE
TRUE VALUE
20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0
FOUND
18.1 20.9 20.4 22.0 20.4 19.7 18.7 19.8 20.6 21.5 20.5
% REC
91 105 102 110 102 99 94 99 103 108 103
% SURROGATE RECOVERY 108% BROMOCHLOROMETHANE (BCM) 8 6% BROMOFLUOROBENZENE (BFB)
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