For inspection purposes only. Consent of copyright … Periclase 1Ltd. 501.00056.00004 Waste Classification Testing November 2011 SLR 1.0 INTRODUCTION This report presents the results

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Premier Periclase Boyne Road, Drogheda, Co. Louth

Waste Classification Test Report

November 2011 SLR Ref: 501.00056.00004.Rev0

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Premier Periclase Ltd. i 501.00056.00004 Waste Classification Testing November 2011

SLR

CONTENTS

1.0 INTRODUCTION .......................................................................................................... 1 1.1 Background ....................................................................................................... 1 1.2 Structure of this Report .................................................................................... 1

2.0 SAMPLING AND TESTING ......................................................................................... 2

3.0 ASSESSMENT ............................................................................................................ 3 3.1 Assessment Methodology ................................................................................ 3 3.2 Classification .................................................................................................... 4

4.0 CLOSURE .................................................................................................................... 5

TABLES

Table 3.1 Summarised Soil Analyses (Screened against IWAC) (mg/kg) ........................ 3

APPENDICES

Appendix A - Laboratory Results ...................................................................................... 6

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Premier Periclase Ltd. 1 501.00056.00004 Waste Classification Testing November 2011

SLR

1.0 INTRODUCTION

This report presents the results of laboratory tests on samples of waste arisings generated by the production of sintermagnesia at Premier Periclase Ltd. at Boyne Road Drogheda., Co. Louth.

The testing was undertaken in order to classify wastes which are currently disposed at an on-site landfill facility close to the production site in accordance with EU standards and protocols.

1.1 Background

Premier Periclase Ltd. (PPL) commenced production on the site of an old cement plant in 1980. Since production began, waste arisings have been deposited to landfills on the site, with some of the older landfills having been closed and successfully restored in the recent past. The existing landfill lies at the eastern end of the PPL site.

The EPA recently contacted PPL and requested that the principal waste streams which are currently disposed of at the landfill (namely lime dust, slaker grits, preheater stone, reactor grits and reject lime) are classified in accordance with Annex II of the Landfill Directive (99/31/EC) and Council Decision 2003/33/EC on acceptance of waste at landfills.

1.2 Structure of this Report

Section 2 of this report provides details of the sampling and testing procedures implemented during the site visit in September 2011 and of subsequent laboratory testing. Section 3 presents the laboratory test results and screens them against EU inert waste acceptance criteria.

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2.0 SAMPLING AND TESTING

At the request of Premier Periclase Ltd. eight samples were taken from the principal waste streams currently disposed of in the landfill. The site was visited by staff from SLR Consulting on 29th September 2011. Waste samples were taken under the supervision of Premier Periclase staff.

Eight samples in total were taken from five different materials, with the sampling labelling system as follows

S1 Slaker Grits

S2 Lime Fines

S3 Lime Fines

S4 Preheater Stone

S5 Preheater Stone

S6 Tank form reactor grits

S7 Tank form reactor grits

S8 Reject Lime

Of the eight samples taken six were selected for testing and delivered to an independent externally accredited environmental testing laboratory the same day. Leachate and solid samples were then prepared and tested in accordance with the requirements of Council Decision 2003/33/EC, due to the reactive nature of the material deviations from the standard procedure were necessary in order to carry out some of the tests. These deviations are listed in the laboratory results in Appendix A.

The complete results are presented in Appendix A. A summary of the results received is presented in Section 3 overleaf.

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3.0 ASSESSMENT

3.1 Assessment Methodology

Of the eight samples taken six were tested using the Waste Acceptance Criteria in order to establish the waste classification in accordance with EU waste acceptance criteria for landfills. The results of the analytical testing were screened against the Inert Waste Acceptance Criteria set down in Article 2.1.2.1 of Council Decision 2003/33/EC, refer to Table 1 below.

The complete results of the soil chemical analysis are presented in Appendix A.

Contaminants S1 S2 S3 S4 S6 S8

Inert Waste Acceptance

Limit 2003/33/EC

mg/kg

Petroleum Hydrocarbons

BTEX <0.024 <0.024 <0.024 <0.024 <0.024 <0.024 6

PCBs <0.021 <0.021 <0.021 <0.021 <0.021 <0.021 1

EPH C10-40 2.93 6.64 1.38 3.8 6.72 12.4 500

PAH <10 <10 <10 <10 <10 <10 100

Leachate (WAC)

Arsenic Dissolved <0.0012 0.008 0.008 <0.0012 0.0264 <0.0012 0.5

Barium Dissolved 11.6 2.6 2.45 1.37 10.20 13.6 20

Cadmium Dissolved <0.001 0.00218 0.00164 <0.001 <0.001 <0.001 0.04

Chromium Dissolved 0.249 0.546 0.542 0.389 0.354 0.575 0.5

Copper Dissolved <0.0001 0.07 0.066 0.04 0.0306 0.04 2

Lead Dissolved 0.022 0.018 0.1100 0.153 0.018 0.04 0.5

Molybdenum Dissolved

0.077 0.714 0.71 0.25 0.134 0.10 0.5

Nickel Dissolved 0.197 0.362 0.338 0.223 0.193 0.217 0.4

Selenium Dissolved <0.0039 0.104 0.108 0.0123 0.0606 <0.0039 0.1

Zinc Dissolved 0.0394 0.0336 0.0554 0.0424 0.0102 0.00777 4

Mercury Dissolved <0.0001 <0.0001 <0.00001 <0.0001 <0.0001 <0.0001 0.01

Fluoride 8.92 5.15 5.83 7.16 5.94 6.71 10

Chloride 32 377 401 43 7370 38 800

Sulphate 1470 16900 17900 4170 445 2380 1000

Dissolved Organic Carbon

32.2 <30 <30 60.8 125 46.4 500

Total Dissolved Solids 77100 87900 90900 74600 89800 78600 4000

Phenols Monohydric <0.16 <0.16 <0.16 <0.16 <0.16 <0.16 1 ** Dissolved Organic Carbon

*** Total Dissolved Solids.

Table 3.1 Summarised Soil Analyses (Screened against IWAC) (mg/kg)

Table 3.1 above shows the results of the samples tested screened against the Inert Waste Acceptance Criteria (IWAC) for acceptance of waste at inert waste facilities.

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The following observations were noted within the reported data:

Three samples S2, S3 and S8 taken from Lime Fines and reject lime material yielded dissolved Chromium concentrations in the region of 0.54mg/kg, exceeding the 0.5mg/kg screening value for acceptance of waste at inert landfill facilities. Chromium exists in different forms of which Cr (III) and Cr (VI) are the most common, with Cr(III) occurring naturally in rocks, soil, volcanic dust and living organisms. Cr(IV) is generally only present as a result of industrial activity, and can occur as a result of many different processes including manufacture of colorants, alloys, chrome plating, magnetic tape and numerous others.

Two samples again samples S2 and S3 yielded dissolved Molybdenum concentrations in the region of 0.71mg/kg, greater than the 0.5mg/kg waste acceptance limit for inert landfills. Molybdenum occurs at high levels naturally on the east coast and can occur as a result of shaley Carboniferous Limestone. Molybdenum is used in alloys, electrodes and catalysts and is also enriched in organic sediments.

Two samples, S2 and S3 taken from the Lime Fines yielded high Selenium concentrations in the region of 0.108mg/kg, marginally in excess of the waste acceptance limit for inert landfills (0.1mg/kg). Selenium can be introduced through coal burning, mining, smelting of sulphide ores and is used in the glass industry, food supplements, vulcanized rubber, photography, light cells and solar cells.

Five of the six samples tested with the exception of S6 (tank form reactor grits) yielded high sulphate concentrations ranging from 1,470mg/kg to 17,900mg/kg, with samples S2 and S3 recording the highest values of 16,900mg/kg and 17,900mg/kg respectively. These values are significantly in excess of the 1000mg/kg inert waste acceptance limit for sulphate. One sample (S6) yielded a high chloride concentration, of the order of 7,370mg/kg. This is over nine times the 800mg/kg screening value for waste acceptance at inert landfills.

All of the samples exceeded the limits set out for total dissolved solids, with values ranging from 74,600mg/kg to 90,900mg/kg, significantly exceeding the 4,000mg/kg limit for waste acceptance at inert landfills.

3.2 Classification

All of the samples tested exceed the inert waste acceptance criteria for at least one parameter. The two samples of lime fines material exceeded the criteria for chromium, selenium, molybdenum, sulphates and total dissolved solids.

The remaining samples exceeded the criteria for sulphates and total dissolved solids, with the exception of sample S6 (tank form reactor grits) which exceeded the criteria for chlorides and total dissolved solids.

On the basis of these test results, the tested materials would be classified as non-hazardous for waste disposal purposes at a landfill facility.

All the samples tested exceeded the total dissolved solids threshold of 60,000 mg/kg for non-hazardous landfills. However, as the sulphate and chloride criteria are both satisfied, it means that these materials can be classified as non-hazardous.

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4.0 CLOSURE

This report has been prepared by SLR Consulting Ireland with all reasonable skill, care and diligence, and taking account of the manpower and resources devoted to it by agreement with the client. Information reported herein is based on the interpretation of data collected and has been accepted in good faith as being accurate and valid.

This report is for the exclusive use of Premier Periclase Ltd. no warranties or guarantees are expressed or should be inferred by any third parties. This report may not be relied upon by other parties without written consent from SLR.

SLR disclaims any responsibility to the client and others in respect of any matters outside the agreed scope of the work.

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Appendix A - Laboratory Results

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Unit 18A

Rosemount Business Park

Ballycoolin

Dublin 11

Tel : (0035) 3188 29893

SLR Consulting Ireland

CSA House

Unit 7

Dundrum Business Park

Windy Harbour

Dublin

Dublin14

Attention: Tom Moore

CERTIFICATE OF ANALYSIS

Location:

Your Reference:

Sample Delivery Group (SDG):

Customer:

Date: 21 October 2011

D_SLRCON_DUB

111003-45

Premier

We received 8 samples on Friday September 30, 2011 and 6 of these samples were scheduled for analysis which was

completed on Friday October 21, 2011. Accredited laboratory tests are defined within the report, but opinions,

interpretations and on-site data expressed herein are outside the scope of ISO 17025 accreditation.

Should this report require incorporation into client reports, it must be used in its entirety and not simply with the data

sections alone.

All chemical testing (unless subcontracted) is performed at ALcontrol Hawarden Laboratories.

Report No: 155897

Operations Manager

Sonia McWhan

Approved By:

Alcontrol Laboratories is a trading division of ALcontrol UK Limited

Registered Office: Units 7 & 8 Hawarden Business Park, Manor Road, Hawarden, Deeside, CH5 3US. Registered in England and Wales No.

Page 1 of 17

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CERTIFICATE OF ANALYSISSDG:

Job:

Client Reference:

111003-45 Location:

Customer:

Attention:

Order Number:

Report Number:D_SLRCON_DUB-74 SLR Consulting IrelandPremier

Tom Moore

1550155897

Superseded Report:

Validated

Received Sample OverviewLab Sample No(s) Customer Sample Ref. AGS Ref. Depth (m) Sampled Date

4417846 29/09/2011S1

4417847 29/09/2011S2

4417850 29/09/2011S4

4417853 29/09/2011S5

4417854 29/09/2011S6

4417855 29/09/2011S7

4417856 29/09/2011S8

Only received samples which have had analysis scheduled will be shown on the following pages.

09:40:43 21/10/2011

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111003-45 Location:

Customer:

Attention:

Order Number:


Tom Moore

1550155897

Superseded Report:

Validated

SOLID

Results Legend

X Test

NNo Determination

Possible

Lab Sample No(s)

Customer

Sample Reference

Depth (m)

Container

AGS Reference

44

178

46

44

178

47

44

178

48

44

178

50

44

178

54

44

178

56

S1

S2

S3

S4

S6

S8

250g

Am

be

r Jar (A

L40

0g T

ub (A

LE

21

4)

60g

VO

C (A

LE

215)

250g

Am

be

r Jar (A

L40

0g T

ub (A

LE

21

4)

60g

VO

C (A

LE

215)

250g

Am

be

r Jar (A

L40

0g T

ub (A

LE

21

4)

60g

VO

C (A

LE

215)

250g

Am

be

r Jar (A

L40

0g T

ub (A

LE

21

4)

60g

VO

C (A

LE

215)

250g

Am

be

r Jar (A

L40

0g T

ub (A

LE

21

4)

60g

VO

C (A

LE

215)

250g

Am

be

r Jar (A

L40

0g T

ub (A

LE

21

4)

60g

VO

C (A

LE

215)

Anions by Kone (w) All NDPs: 0

Tests: 6

X

X

X

X

X

X

CEN Readings All NDPs: 0

Tests: 6

X

X

X

X

X

X

Dissolved Metals by ICP-MS All NDPs: 0

Tests: 6

X

X

X

X

X

X

Dissolved Organic/Inorganic

Carbon

All NDPs: 0

Tests: 6

X

X

X

X

X

X

Fluoride All NDPs: 0

Tests: 6

X

X

X

X

X

X

GRO by GC-FID (S) All NDPs: 0

Tests: 6

X

X

X

X

X

X

Mercury Dissolved All NDPs: 0

Tests: 6

X

X

X

X

X

X

Mineral Oil All NDPs: 0

Tests: 6

X

X

X

X

X

X

PAH by GCMS All NDPs: 0

Tests: 6

X

X

X

X

X

X

PAH Value of soil All NDPs: 0

Tests: 6

X

X

X

X

X

X

PCBs by GCMS All NDPs: 0

Tests: 6

X

X

X

X

X

X

Phenols by HPLC (W) All NDPs: 0

Tests: 6

X

X

X

X

X

X

Sample description All NDPs: 0

Tests: 6

X

X

X

X

X

X

Total Dissolved Solids on

Leachates

All NDPs: 0

Tests: 6

X

X

X

X

X

X

Total Organic Carbon All NDPs: 0

Tests: 6

X

X

X

X

X

X

09:40:43 21/10/2011

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Attention:

Order Number:


Tom Moore

1550155897

Superseded Report:

Validated

Sample Descriptions

very fine <0.063mm 0.063mm - 0.1mm 0.1mm - 2mm 2mm - 10mm >10mmfine medium coarse very coarse

Grain Sizes

Colour Description Grain size Inclusions Inclusions 2

4417846 S1 White Chalk 0.063 - 0.1 mm Stones N/A

4417847 S2 Beige Ballast <0.063 mm Stones N/A

4417848 S3 Beige N/A <0.063 mm N/A N/A

4417850 S4 White Gravel > 10 mm N/A N/A

4417854 S6 White Sand 0.1 - 2 mm Stones N/A

4417856 S8 White N/A > 10 mm N/A N/A

Customer Sample Ref. Depth (m)Lab Sample No(s)

These descriptions are only intended to act as a cross check if sample identities are questioned, and to provide a log of

sample matrices with respect to MCERTS validation. They are not intended as full geological descriptions.

We are accredited to MCERTS for sand, clay and loam/topsoil, or any of these materials - whether these are derived from

naturally ocurring soil profiles, or from fill/made ground, as long as these materials constitute the major part of the sample.

Other coarse granular materials such as concrete, gravel and brick are not accredited if they comprise the major part of the

sample.

09:40:43 21/10/2011

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111003-45 Location:

Customer:

Attention:

Order Number:


Tom Moore

1550155897

Superseded Report:

Validated

ISO17025 accredited.

mCERTS accredited.

Deviating sample.

Aqueous / settled sample.

Dissolved / filtered sample.

Total / unfiltered sample.

Subcontracted test.

% recovery of the surrogate standard to

check the efficiency of the method. The

results of individual compounds within

samples aren't corrected for the recovery

Trigger breach confirmed

#

M

§

aq

diss.filt

tot.unfilt

*

**

(F)

Results Legend

AGS Reference

Lab Sample No.(s)

SDG Ref

Date Received

Date Sampled

Sample Type

Depth (m)

Customer Sample R

MethodLOD/UnitsComponent

S1

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417846

S2

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417847

S3

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417848

S4

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417850

S6

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417854

S8

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417856

Mineral oil >C10-C40 <1 mg/kg TM061 2.93§ #

6.64§ #

1.38§ #

3.8§ #

6.72§ #

12.4§ #

Surrogate Value - TM061 38.5§

40.1§

41.7§

40.5§

42.5§

42.2§

Mineral Oil Surrogate %

recovery**

% TM061 77.1§

80.3§

83.4§

81§

85.1§

84.4§

Organic Carbon, Total <0.2 % TM132 <0.2 #

<0.2 #

0.63 #

<0.2 #

<0.2 #

<0.2 #

PCB congener 28 <3 µg/kg TM168 <3 #

<3 #

<3 #

<3 #

<3 M

<3 #


<3 #

<3 #

<3 #

<3 M

<3 #


<3 #

<3 #

<3 #

<3 M

<3 #


<3 #

<3 #

<3 #

<3 M

<3 #


<3 #

<3 #

<3 #

<3 M

<3 #


<3 #

<3 #

<3 #

<3 M

<3 #


<3 #

<3 #

<3 #

<3 M

<3 #

Sum of detected PCB 7

Congeners

<21

µg/kg

TM168 <21

<21

<21

<21

<21

<21

Coronene <2 mg/kg TM213 <2

<2

<2

<2

<2

<2

Polyaromatic

hydrocarbons, Total 17

<10

mg/kg

TM213 <10

<10

<10

<10

<10

<10

09:40:43 21/10/2011

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Job:

Client Reference:

111003-45 Location:

Customer:

Attention:

Order Number:


Tom Moore

1550155897

Superseded Report:

Validated

GRO by GC-FID (S)


mCERTS accredited.

Deviating sample.




Subcontracted test.






#

M

§

aq

diss.filt

tot.unfilt

*

**

(F)

Results Legend

AGS Reference

Lab Sample No.(s)

SDG Ref

Date Received

Date Sampled

Sample Type

Depth (m)

Customer Sample R


S1

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417846

S2

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417847

S3

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417848

S4

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417850

S6

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417854

S8

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417856

Methyl tertiary butyl ether

(MTBE)

<5 µg/kg TM089 <5§ #

<5 #

<5§ #

<5 #

<5§ #

<5§ #

Benzene <10

µg/kg

TM089 <10§ #

<10 #

<10§ #

<10 #

<10§ M

<10§ #

Toluene <2 µg/kg TM089 4.07§ #

<2 #

9§ #

7 #

<2§ M

<2§ #

Ethylbenzene <3 µg/kg TM089 <3§ #

<3 #

<3§ #

<3 #

<3§ M

<3§ #

m,p-Xylene <6 µg/kg TM089 <6§ #

<6 #

6§ #

11 #

<6§ M

<6§ #

o-Xylene <3 µg/kg TM089 <3§ #

<3 #

<3§ #

3 #

<3§ M

<3§ #

sum of detected mpo

xylene by GC

<9 µg/kg TM089 <9§

<9

<9§

14

<9§

<9§

sum of detected BTEX by

GC

<24

µg/kg

TM089 <24§

<24

<24§

<24

<24§

<24§

09:40:43 21/10/2011

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Customer:

Attention:

Order Number:


Tom Moore

1550155897

Superseded Report:

Validated

PAH by GCMS


mCERTS accredited.

Deviating sample.




Subcontracted test.






#

M

§

aq

diss.filt

tot.unfilt

*

**

(F)

Results Legend

AGS Reference

Lab Sample No.(s)

SDG Ref

Date Received

Date Sampled

Sample Type

Depth (m)

Customer Sample R


S1

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417846

S2

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417847

S3

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417848

S4

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417850

S6

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417854

S8

.

Soil/Solid

29/09/2011

30/09/2011

111003-45

4417856

Naphthalene-d8 %

recovery**

% TM218 95

99.5

93.2

92.3

93.1

94

Acenaphthene-d10 %

recovery**

% TM218 92.6

89.2

91.2

90.2

94.1

91.2

Phenanthrene-d10 %

recovery**

% TM218 90

88.1

89.4

86.7

93.6

89.7

Chrysene-d12 %

recovery**

% TM218 77.2

88.5

79.3

71.8

88.6

79.8

Perylene-d12 % recovery** % TM218 74.8

87.7

81.1

71.4

91.7

75.8

Naphthalene <9 µg/kg TM218 10.9 #

17 #

12.4 #

10.5 #

<9 M

21.2 #

Acenaphthylene <12

µg/kg

TM218 <12 #

<12 #

<12 #

<12 #

<12 M

<12 #

Acenaphthene <8 µg/kg TM218 <8 #

<8 #

<8 #

<8 #

<8 M

<8 #

Fluorene <10

µg/kg

TM218 <10 #

<10 #

<10 #

<10 #

<10 M

<10 #

Phenanthrene <15

µg/kg

TM218 <15 #

<15 #

<15 #

15 #

<15 M

<15 #

Anthracene <16

µg/kg

TM218 <16 #

<16 #

<16 #

<16 #

<16 M

<16 #

Fluoranthene <17

µg/kg

TM218 <17 #

<17 #

<17 #

<17 #

<17 M

<17 #

Pyrene <15

µg/kg

TM218 <15 #

<15 #

<15 #

<15 #

<15 M

<15 #

Benz(a)anthracene <14

µg/kg

TM218 <14 #

<14 #

<14 #

<14 #

<14 M

<14 #

Chrysene <10

µg/kg

TM218 <10 #

<10 #

<10 #

<10 #

<10 M

<10 #

Benzo(b)fluoranthene <15

µg/kg

TM218 <15 #

<15 #

<15 #

<15 #

<15 M

<15 #

Benzo(k)fluoranthene <14

µg/kg

TM218 <14 #

<14 #

<14 #

<14 #

<14 M

<14 #

Benzo(a)pyrene <15

µg/kg

TM218 <15 #

<15 #

<15 #

<15 #

<15 M

<15 #

Indeno(1,2,3-cd)pyrene <18

µg/kg

TM218 <18 #

<18 #

<18 #

<18 #

<18 M

<18 #

Dibenzo(a,h)anthracene <23

µg/kg

TM218 <23 #

<23 #

<23 #

<23 #

<23 M

<23 #

Benzo(g,h,i)perylene <24

µg/kg

TM218 <24 #

<24 #

<24 #

<24 #

<24 M

<24 #

PAH, Total Detected

USEPA 16

<118

µg/kg

TM218 <118

<118

<118

<118

<118

<118

09:40:43 21/10/2011

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111003-45 Location:

Customer:

Attention:

Order Number:


Tom Moore

1550155897

Superseded Report:

Validated

-

-

-

-

-

-

-

-

-

CEN 10:1 STAGE BATCH TEST

WAC ANALYTICAL RESULTS REF : BS EN 12457/2

Client Reference

Mass Sample taken (kg)

Mass of dry sample (kg)

Particle Size <4mm

0.175

>95%

Site Location

Moisture Content Ratio (%)

Dry Matter Content Ratio (%)

2.40

97.7

Case

Depth (m)

Customer Sample Ref.

Sampled Date

Lab Sample Number(s)

SDG 111003-45

4417846

29-Sep-2011

S1

Solid Waste Analysis

ANC to pH 4 (mol/kg)


pH (pH Units)

PAH Sum of 17 (mg/kg)

Mineral Oil (mg/kg)

Sum of 7 PCBs (mg/kg)

Sum of BTEX (mg/kg)

Loss on Ignition (%)

Total Organic Carbon (%)

Eluate Analysis

Leach Test Information

Date Prepared

pH (pH Units)

Conductivity (µS/cm)

Temperature (ºC)

Volume Leachant (Litres)

Volume of Eluate VE1 (Litres)

Solid Results are expressed on a dry weight basis, after correction for moisture content where applicable

Stated limits are for guidance only and ALcontrol cannot be held responsible for any discrepancies with current legislation

Mcerts Certification does not apply to leachates

21/10/2011 09:40:47

10-Oct-2011

12.45

0.898

20.40

9,410.00

<10.0

2.93

<21.0

<24.0

<0.200 -

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

Premier

0.092

Result ResultLimit of Detection Limit of Detection

C2 Concⁿ in 10:1 eluate (mg/l) A2 10:1 concⁿ leached (mg/kg)Murphy Limits

of Detection

mg/kg dry

Murphy LoD

mg/kg dry substanceResult

<100.0

<500.0

<1.0

<6.0

<30,000.0 mg/kg dry substance

-----Arsenic <0.00012 <0.0012 0.5<0.00012 <0.0012 --

-----Barium 1.16 11.6 20<0.0003 <0.003 --

-----Cadmium <0.0001 <0.001 0.04<0.0001 <0.001 --

-----Chromium 0.0249 0.249 0.5<0.00022 <0.0022 --

-----Copper 0.00276 0.0276 2<0.00085 <0.0085 --

-----Mercury Dissolved (CVAF) <0.00001 <0.0001 0.01<0.00001 <0.0001 --

-----Molybdenum 0.00769 0.0769 0.5<0.00024 <0.0024 --

-----Nickel 0.0197 0.197 0.4<0.00015 <0.0015 --

-----Lead 0.00224 0.0224 0.5<0.00002 <0.0002 --

-----Antimony 0.00033 0.0033 0.06<0.00016 <0.0016 --

-----Selenium <0.00039 <0.0039 0.1<0.00039 <0.0039 --

-----Zinc 0.00394 0.0394 4<0.00041 <0.0041 --

-----Chloride 3.2 32 800<2 <20 --

-----Fluoride 0.892 8.92 10<0.5 <5 --

-----Sulphate (soluble) 147 1470 1000<2 <20 --

-----Total Dissolved Solids 7710 77100 4000<50 <500 --

-----Total Monohydric Phenols (W) <0.016 <0.16 1<0.016 <0.16 --

-----Dissolved Organic Carbon 3.22 32.2 500<3 <30 --

09:40:43 21/10/2011

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111003-45 Location:

Customer:

Attention:

Order Number:


Tom Moore

1550155897

Superseded Report:

Validated

-

-

-

-

-

-

-

-

-



Client Reference



Particle Size <4mm

0.175

>95%

Site Location



0.100

99.9

Case

Depth (m)


Sampled Date


SDG 111003-45

4417847

29-Sep-2011

S2




pH (pH Units)


Mineral Oil (mg/kg)


Sum of BTEX (mg/kg)



Eluate Analysis


Date Prepared

pH (pH Units)


Temperature (ºC)






21/10/2011 09:40:47

10-Oct-2011

12.53

0.900

20.60

9,740.00

<10.0

6.64

<21.0

<24.0

<0.200 -

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

Premier

0.090



of Detection

mg/kg dry

Murphy LoD


<100.0

<500.0

<1.0

<6.0


-----Arsenic 0.000787 0.00787 0.5<0.00012 <0.0012 --

-----Barium 0.26 2.6 20<0.00003 <0.0003 --

-----Cadmium 0.000218 0.00218 0.04<0.0001 <0.001 --

-----Chromium 0.0546 0.546 0.5<0.00022 <0.0022 --

-----Copper 0.00669 0.0669 2<0.00085 <0.0085 --


-----Molybdenum 0.0714 0.714 0.5<0.00024 <0.0024 --

-----Nickel 0.0362 0.362 0.4<0.00015 <0.0015 --

-----Lead 0.00759 0.0759 0.5<0.00002 <0.0002 --

-----Antimony 0.000198 0.00198 0.06<0.00016 <0.0016 --

-----Selenium 0.0104 0.104 0.1<0.00039 <0.0039 --

-----Zinc 0.00336 0.0336 4<0.00041 <0.0041 --

-----Chloride 37.7 377 800<2 <20 --

-----Fluoride 0.515 5.15 10<0.5 <5 --




-----Dissolved Organic Carbon <3 <30 500<3 <30 --

09:40:43 21/10/2011

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111003-45 Location:

Customer:

Attention:

Order Number:


Tom Moore

1550155897

Superseded Report:

Validated

-

-

-

-

-

-

-

-

-



Client Reference



Particle Size <4mm

0.175

>95%

Site Location



0.110

99.9

Case

Depth (m)


Sampled Date


SDG 111003-45

4417848

29-Sep-2011

S3




pH (pH Units)


Mineral Oil (mg/kg)


Sum of BTEX (mg/kg)



Eluate Analysis


Date Prepared

pH (pH Units)


Temperature (ºC)






21/10/2011 09:40:47

10-Oct-2011

12.53

0.900

20.40

9,790.00

<10.0

1.38

<21.0

<24.0

0.630 -

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

Premier

0.090



of Detection

mg/kg dry

Murphy LoD


<100.0

<500.0

<1.0

<6.0


-----Arsenic 0.000763 0.00763 0.5<0.00012 <0.0012 --

-----Barium 0.245 2.45 20<0.00003 <0.0003 --

-----Cadmium 0.000164 0.00164 0.04<0.0001 <0.001 --

-----Chromium 0.0542 0.542 0.5<0.00022 <0.0022 --

-----Copper 0.00663 0.0663 2<0.00085 <0.0085 --


-----Molybdenum 0.0711 0.711 0.5<0.00024 <0.0024 --

-----Nickel 0.0338 0.338 0.4<0.00015 <0.0015 --

-----Lead 0.011 0.11 0.5<0.00002 <0.0002 --

-----Antimony 0.000279 0.00279 0.06<0.00016 <0.0016 --

-----Selenium 0.0108 0.108 0.1<0.00039 <0.0039 --

-----Zinc 0.00554 0.0554 4<0.00041 <0.0041 --

-----Chloride 40.1 401 800<2 <20 --

-----Fluoride 0.583 5.83 10<0.5 <5 --




-----Dissolved Organic Carbon <3 <30 500<3 <30 --

09:40:43 21/10/2011

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111003-45 Location:

Customer:

Attention:

Order Number:


Tom Moore

1550155897

Superseded Report:

Validated

-

-

-

-

-

-

-

-

-



Client Reference



Particle Size <4mm

0.175

>95%

Site Location



2.59

97.5

Case

Depth (m)


Sampled Date


SDG 111003-45

4417850

29-Sep-2011

S4




pH (pH Units)


Mineral Oil (mg/kg)


Sum of BTEX (mg/kg)



Eluate Analysis


Date Prepared

pH (pH Units)


Temperature (ºC)






21/10/2011 09:40:47

10-Oct-2011

12.44

0.898

20.50

8,430.00

<10.0

3.80

<21.0

<24.0

<0.200 -

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

Premier

0.092



of Detection

mg/kg dry

Murphy LoD


<100.0

<500.0

<1.0

<6.0


-----Arsenic <0.00012 <0.0012 0.5<0.00012 <0.0012 --

-----Barium 0.137 1.37 20<0.00003 <0.0003 --

-----Cadmium <0.0001 <0.001 0.04<0.0001 <0.001 --

-----Chromium 0.0389 0.389 0.5<0.00022 <0.0022 --

-----Copper 0.00359 0.0359 2<0.00085 <0.0085 --


-----Molybdenum 0.0245 0.245 0.5<0.00024 <0.0024 --

-----Nickel 0.0223 0.223 0.4<0.00015 <0.0015 --

-----Lead 0.0153 0.153 0.5<0.00002 <0.0002 --

-----Antimony 0.000187 0.00187 0.06<0.00016 <0.0016 --

-----Selenium 0.00123 0.0123 0.1<0.00039 <0.0039 --

-----Zinc 0.00424 0.0424 4<0.00041 <0.0041 --

-----Chloride 4.3 43 800<2 <20 --

-----Fluoride 0.716 7.16 10<0.5 <5 --





09:40:43 21/10/2011

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111003-45 Location:

Customer:

Attention:

Order Number:


Tom Moore

1550155897

Superseded Report:

Validated

-

-

-

-

-

-

-

-

-



Client Reference



Particle Size <4mm

0.175

>95%

Site Location



38.1

72.4

Case

Depth (m)


Sampled Date


SDG 111003-45

4417854

29-Sep-2011

S6




pH (pH Units)


Mineral Oil (mg/kg)


Sum of BTEX (mg/kg)



Eluate Analysis


Date Prepared

pH (pH Units)


Temperature (ºC)






21/10/2011 09:40:47

11-Oct-2011

12.35

0.866

21.40

10,200.00

<10.0

6.72

<21.0

<24.0

<0.200 -

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

Premier

0.124



of Detection

mg/kg dry

Murphy LoD


<100.0

<500.0

<1.0

<6.0


-----Arsenic 0.00264 0.0264 0.5<0.00012 <0.0012 --

-----Barium 1.02 10.2 20<0.0003 <0.003 --

-----Cadmium <0.0001 <0.001 0.04<0.0001 <0.001 --

-----Chromium 0.0354 0.354 0.5<0.00022 <0.0022 --

-----Copper 0.00306 0.0306 2<0.00085 <0.0085 --


-----Molybdenum 0.0134 0.134 0.5<0.00024 <0.0024 --

-----Nickel 0.0193 0.193 0.4<0.00015 <0.0015 --

-----Lead 0.00177 0.0177 0.5<0.00002 <0.0002 --

-----Antimony <0.00016 <0.0016 0.06<0.00016 <0.0016 --

-----Selenium 0.00606 0.0606 0.1<0.00039 <0.0039 --

-----Zinc 0.00102 0.0102 4<0.00041 <0.0041 --

-----Chloride 737 7370 800<10 <100 --

-----Fluoride 0.594 5.94 10<0.5 <5 --

-----Sulphate (soluble) 44.5 445 1000<2 <20 --



-----Dissolved Organic Carbon 12.5 125 500<3 <30 --

09:40:43 21/10/2011

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EPA Export 23-12-2011:04:28:21


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Customer:

Attention:

Order Number:


Tom Moore

1550155897

Superseded Report:

Validated

-

-

-

-

-

-

-

-

-



Client Reference



Particle Size <4mm

0.175

>95%

Site Location



0.100

99.9

Case

Depth (m)


Sampled Date


SDG 111003-45

4417856

29-Sep-2011

S8




pH (pH Units)


Mineral Oil (mg/kg)


Sum of BTEX (mg/kg)



Eluate Analysis


Date Prepared

pH (pH Units)


Temperature (ºC)






21/10/2011 09:40:47

10-Oct-2011

12.47

0.900

20.40

8,920.00

<10.0

12.4

<21.0

<24.0

<0.200 -

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

Premier

0.090



of Detection

mg/kg dry

Murphy LoD


<100.0

<500.0

<1.0

<6.0


-----Arsenic <0.00012 <0.0012 0.5<0.00012 <0.0012 --

-----Barium 1.36 13.6 20<0.0003 <0.003 --

-----Cadmium <0.0001 <0.001 0.04<0.0001 <0.001 --

-----Chromium 0.0575 0.575 0.5<0.00022 <0.0022 --

-----Copper 0.00369 0.0369 2<0.00085 <0.0085 --


-----Molybdenum 0.00974 0.0974 0.5<0.00024 <0.0024 --

-----Nickel 0.0217 0.217 0.4<0.00015 <0.0015 --

-----Lead 0.00437 0.0437 0.5<0.00002 <0.0002 --

-----Antimony 0.000167 0.00167 0.06<0.00016 <0.0016 --

-----Selenium <0.00039 <0.0039 0.1<0.00039 <0.0039 --

-----Zinc 0.000777 0.00777 4<0.00041 <0.0041 --

-----Chloride 3.8 38 800<2 <20 --

-----Fluoride 0.671 6.71 10<0.5 <5 --





09:40:43 21/10/2011

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1550155897

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Validated

Notification of Deviating SamplesSample

Number

Customer

Sample Ref.Depth (m) Matrix Test Name Component Name Comment

4532966 S3 SOLID GRO by GC-FID (S) Benzene Container with Headspace provided

for volatiles analysis

4532966 S3 SOLID GRO by GC-FID (S) Ethylbenzene Container with Headspace provided


4532966 S3 SOLID GRO by GC-FID (S) m,p-Xylene Container with Headspace provided


4532966 S3 SOLID GRO by GC-FID (S) Methyl tertiary butyl ether (MTBE) Container with Headspace provided


4532966 S3 SOLID GRO by GC-FID (S) o-Xylene Container with Headspace provided


4532966 S3 SOLID GRO by GC-FID (S) sum of detected BTEX by GC Container with Headspace provided


4532966 S3 SOLID GRO by GC-FID (S) sum of detected mpo xylene by GC Container with Headspace provided


4532966 S3 SOLID GRO by GC-FID (S) Toluene Container with Headspace provided


4515797 S1 SOLID GRO by GC-FID (S) Benzene Matrix interference

4515797 S1 SOLID GRO by GC-FID (S) Ethylbenzene Matrix interference

4515797 S1 SOLID GRO by GC-FID (S) m,p-Xylene Matrix interference

4515797 S1 SOLID GRO by GC-FID (S) Methyl tertiary butyl ether (MTBE) Matrix interference

4515797 S1 SOLID GRO by GC-FID (S) o-Xylene Matrix interference

4515797 S1 SOLID GRO by GC-FID (S) sum of detected BTEX by GC Matrix interference

4515797 S1 SOLID GRO by GC-FID (S) sum of detected mpo xylene by GC Matrix interference

4515797 S1 SOLID GRO by GC-FID (S) Toluene Matrix interference

















4474624 S8 SOLID Mineral Oil Mineral oil >C10-C40 Sample holding time exceeded

4474624 S8 SOLID Mineral Oil Mineral Oil Surrogate % recovery** Sample holding time exceeded

4474624 S8 SOLID Mineral Oil Surrogate Value Sample holding time exceeded
















Note : Test results may be compromised

09:40:43 21/10/2011

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Order Number:


Tom Moore

1550155897

Superseded Report:

Validated

Table of Results - AppendixREPORT KEY

#

PFD

No Determination Possible

No Fibres Detected

ISO 17025 Accredited

Possible Fibres Detected

*

»

M

EC

Subcontracted Test

Result previously reported

(Incremental reports only)

MCERTS Accredited

Equivalent Carbon

(Aromatics C8-C35)

Results expressed as (e.g.) 1.03E-07 is equivalent to 1.03x10-7

Note: Method detection limits are not always achievable due to various circumstances beyond our control

NDP

NFD

Method No Reference DescriptionWet/Dry

Sample ¹

Surrogate

Corrected

PM024 Modified BS 1377 Soil preparation including homogenisation, moisture screens of

soils for Asbestos Containing Material

PM114 Leaching Procedure for CEN Two Stage BatchTest 2:1/8:1

Cumulative

PM115 Leaching Procedure for CEN One Stage Leach Test 2:1 & 10:1

1 Step

TM061 Method for the Determination of

EPH,Massachusetts Dept.of EP, 1998

Determination of Extractable Petroleum Hydrocarbons by

GC-FID (C10-C40)

TM089 Modified: US EPA Methods 8020 & 602 Determination of Gasoline Range Hydrocarbons (GRO) and

BTEX (MTBE) compounds by Headspace GC-FID (C4-C12)

TM090 Method 5310, AWWA/APHA, 20th Ed., 1999 /

Modified: US EPA Method 415.1 & 9060

Determination of Total Organic Carbon/Total Inorganic Carbon

in Water and Waste Water

TM104 Method 4500F, AWWA/APHA, 20th Ed., 1999 Determination of Fluoride using the Kone Analyser

TM123 BS 2690: Part 121:1981 The Determination of Total Dissolved Solids in Water

TM132 In - house Method ELTRA CS800 Operators Guide

TM152 Method 3125B, AWWA/APHA, 20th Ed., 1999 Analysis of Aqueous Samples by ICP-MS

TM168 EPA Method 8082, Polychlorinated Biphenyls by

Gas Chromatography

Determination of WHO12 and EC7 Polychlorinated Biphenyl

Congeners by GC-MS in Soils

TM183 BS EN 23506:2002, (BS 6068-2.74:2002) ISBN

0 580 38924 3

Determination of Trace Level Mercury in Waters and Leachates

by PSA Cold Vapour Atomic Fluorescence Spectrometry

TM184 EPA Methods 325.1 & 325.2, The Determination of Anions in Aqueous Matrices using the

Kone Spectrophotometric Analysers

TM213 In-house Method Rapid Determination of PAHs by GC-FID

TM218 Microwave extraction – EPA method 3546 Microwave extraction - EPA method 3546

TM259 by HPLC Determination of Phenols in Waters and Leachates by HPLC

¹ Applies to Solid samples only. DRY indicates samples have been dried at 35°C. NA = not applicable.

09:40:43 21/10/2011

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Order Number:


Tom Moore

1550155897

Superseded Report:

Validated

Test Completion DatesLab Sample No(s)


Depth

Type

AGS Ref.

4417846 4417847 4417848 4417850 4417854 4417856

S1 S2 S3 S4 S6 S8

SOLID SOLID SOLID SOLID SOLID SOLID

Anions by Kone (w) 12-Oct-2011 12-Oct-2011 12-Oct-2011 12-Oct-2011 13-Oct-2011 12-Oct-2011

CEN 10:1 Leachate (1 Stage) 10-Oct-2011 10-Oct-2011 10-Oct-2011 10-Oct-2011 11-Oct-2011 10-Oct-2011

CEN Readings 12-Oct-2011 12-Oct-2011 12-Oct-2011 12-Oct-2011 13-Oct-2011 12-Oct-2011

Dissolved Metals by ICP-MS 13-Oct-2011 12-Oct-2011 12-Oct-2011 12-Oct-2011 13-Oct-2011 13-Oct-2011

Dissolved Organic/Inorganic Carbon 14-Oct-2011 14-Oct-2011 14-Oct-2011 14-Oct-2011 14-Oct-2011 14-Oct-2011

Fluoride 12-Oct-2011 12-Oct-2011 12-Oct-2011 12-Oct-2011 13-Oct-2011 12-Oct-2011

GRO by GC-FID (S) 18-Oct-2011 18-Oct-2011 21-Oct-2011 18-Oct-2011 18-Oct-2011 18-Oct-2011

Mercury Dissolved 12-Oct-2011 12-Oct-2011 12-Oct-2011 12-Oct-2011 13-Oct-2011 12-Oct-2011

Mineral Oil 13-Oct-2011 13-Oct-2011 13-Oct-2011 13-Oct-2011 13-Oct-2011 13-Oct-2011

PAH by GCMS 13-Oct-2011 15-Oct-2011 13-Oct-2011 13-Oct-2011 13-Oct-2011 17-Oct-2011

PAH Value of soil 12-Oct-2011 12-Oct-2011 12-Oct-2011 12-Oct-2011 12-Oct-2011 12-Oct-2011

PCBs by GCMS 12-Oct-2011 12-Oct-2011 12-Oct-2011 12-Oct-2011 12-Oct-2011 12-Oct-2011

Phenols by HPLC (W) 12-Oct-2011 13-Oct-2011 13-Oct-2011 13-Oct-2011 13-Oct-2011 13-Oct-2011

Sample description 10-Oct-2011 10-Oct-2011 10-Oct-2011 10-Oct-2011 10-Oct-2011 10-Oct-2011

Total Dissolved Solids on Leachates 12-Oct-2011 12-Oct-2011 12-Oct-2011 12-Oct-2011 13-Oct-2011 12-Oct-2011

Total Organic Carbon 12-Oct-2011 12-Oct-2011 12-Oct-2011 12-Oct-2011 12-Oct-2011 12-Oct-2011

09:40:43 21/10/2011

Page 16 of 17

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Job:

Client Reference:

111003-45 Location:

Customer:

Attention:

Order Number:


Tom Moore

1550155897

Superseded Report:

Appendix1. Results are expressed on a dry weight basis (dried at 35ºC) for all soil analyses except for the following:

NRA Leach tests, flash point, ammonium as NH4 by the BRE method, VOC TICS, SVOC TICS, TOF-MS

SCAN/SEARCH and TOF-MS TICS.

2. Samples will be run in duplicate upon request, but an additional charge may be incurred.

3. If sufficient sample is received a sub sample will be retained free of charge for 30 days after analysis is

completed (e-mailed) for both soil jars, tubs and volatile jars. All waters and vials will be discarded 10 days

after the analysis is completed (e-mailed). All material removed during an asbestos containing material

screen and analysed for the presence of asbestos will be retained for a period of 6 months after the analysis

date. All samples received and not scheduled will be disposed of one month after the date of receipt unless

we are instructed to the contrary. Once the initial period has expired, a storage charge will be applied for

each month or part thereof until the client cancels the request for sample storage. ALcontrol Laboratories

reserve the right to charge for samples received and stored but not analysed.

4. With respect to turnaround, we will always endeavour to meet client requirements wherever possible, but

turnaround times cannot be absolutely guaranteed due to so many variables beyond our control.

5. We take responsibility for any test performed by sub-contractors (marked with an asterisk). We endeavour

to use UKAS/MCERTS Accredited Laboratories, who either complete a quality questionnaire or are audited

by ourselves. For some determinands there are no UKAS/MCERTS Accredited Laboratories, in this instance

a laboratory with a known track record will be utilised.

6. When requested, the individual sub sample scheduled will be screened in house for the presence of

asbestos fibres and asbestos containing material by our documented in house method TM048 based on HSG

248 (2005), which is accredited to ISO17025. If a specific asbestos fibre type is not found this will be reported

as “Not detected”. If no asbestos fibre types are found all will be reported as “Not detected” and the sub

sample analysed deemed to be clear of asbestos. Is an asbestos fibre type is found it will be reported as

detected (for each fibre type found). If asbestos is present either as asbestos containing material or loose

fibres no further analysis will be undertaken. The quantity of asbestos present is not determined unless

specifically requested.

7. If no separate volatile sample is supplied by the client, the integrity of the data may be compromised if the

laboratory is required to create a sub-sample from the bulk sample -similarly, if a headspace or sediment is

present in the volatile sample. This will be flagged up as an invalid VOC on the test schedule or recorded on

the log sheet.

8. If appropriate preserved bottles are not received preservation will take place on receipt. However, the

integrity of the data may be compromised.

9. NDP -No determination possible due to insufficient/unsuitable sample.

10. Metals in water are performed on a filtered sample, and therefore represent dissolved metals -total metals

must be requested separately.

11. Results relate only to the items tested.

12. LODs for wet tests reported on a dry weight basis are not corrected for moisture content.

13. Surrogate recoveries -Most of our organic methods include surrogates, the recovery of which is

monitored and reported. For EPH, MO, PAH, GRO and VOCs on soils the result is not surrogate corrected,

but a percentage recovery is quoted. Acceptable limits for most organic methods are 70 -130 %.

14. Product analyses -Organic analyses on products can only be semi-quantitative due to the matrix effects

and high dilution factors

employed.

15. Phenols monohydric by HPLC include phenol, cresols (2-Methylphenol, 3-Methylphenol and

4-Methylphenol) and Xylenols (2,3 Dimethylphenol, 2,4 Dimethylphenol, 2,5 Dimethylphenol, 2,6

Dimethylphenol, 3,4 Dimethyphenol, 3,5 Dimethylphenol).

16. Total of 5 speciated phenols by HPLC includes Phenol, 2,3,5-Trimethyl Phenol, 2-Isopropylphenol,

Cresols and Xylenols (as detailed in 15).

17. Stones/debris are not routinely removed. We always endeavour to take a representative sub sample from

the received sample.

18. In certain circumstances the method detection limit may be elevated due to the sample being outside the

calibration range. Other factors that may contribute to this include possible interferences. In both cases the

sample would be diluted which would cause the method detection limit to be raised.

19. Mercury results quoted on soils will not include volatile mercury as the analysis is performed on a dried

and crushed sample.

20. For the BSEN 12457-3 two batch process to allow the cumulative release to be calculated, the volume of

the leachate produced is measured and filtered for all tests. We therefore cannot carry out any unfiltered

analysis. The tests affected include volatiles GCFID/GCMS and all subcontracted analysis.

21. For all leachate preparations (NRA, DIN, TCLP, BSEN 12457-1, 2, 3) volatile loss may occur, as we do

not employ zero headspace extraction.

22. We are accredited to MCERTS for sand, clay and loam/topsoil, or any of these materials -whether these

are derived from naturally occurring soil profiles, or from fill/made ground, as long as these materials

constitute themajor part of the sample. Other coarse granular material such as concrete, gravel and brick are

not accredited if they comprise the major part of the sample.

23. Analysis and identification of specific compounds using GCFID is by retention time only, and we routinely

calibrate and quantify for benzene, toluene, ethylbenzenes and xylenes (BTEX). For total volatiles in the C4

-C10 range, the total area of the chromatogram is integrated and expressed as ug/kg or ug/l. Although this

analysis is commonly used for the quantification of gasoline range organics (GRO), the system will also

detect other compounds such as chlorinated solvents, and this may lead to a falsely high result with respect

to hydrocarbons only. It is not possible to specifically identify these non-hydrocarbons, as standards are not

routinely run for any other compounds, and for more definitive identification, volatiles by GCMS should be

utilised.

GC MSDIRECT INJECTIONNONEGLYCOLS

HPLCLIQUID/LIQUID SHAKETCEMINERAL OIL by IR

HPLCLIQUID/LIQUID SHAKETCETPH by INFRA RED (IR)

GC MSSOLID PHASE EXTRACTIONDCMPHENOLS MS

GC MSLIQUID/LIQUID SHAKEDCMTRIAZINE HERBS

GC MSLIQUID/LIQUID SHAKEDCMPEST OCP/OPP

HPLCSOLID PHASE EXTRACTIONDCMFREE SULPHUR

GC MSLIQUID/LIQUID SHAKEDCMSVOC

GC MSSTIRRED EXTRACTION (STIR-BAR)HEXANEPCB TOTAL

GC MSSTIRRED EXTRACTION (STIR-BAR)HEXANEPCB 7 CONGENERS

GC FIDSTIRRED EXTRACTION (STIR-BAR)HEXANEMINERAL OIL

GC FIDSTIRRED EXTRACTION (STIR-BAR)HEXANEEPH CWG

GC FIDSTIRRED EXTRACTION (STIR-BAR)HEXANEEPH

GC MSSTIRRED EXTRACTION (STIR-BAR)HEXANEPAH MS

ANALYSISEXTRACTION

METHODEXTRACTION

SOLVENTANALYSIS

LIQUID MATRICES EXTRACTION SUMMARY

GC MSDIRECT INJECTIONNONEGLYCOLS

HPLCLIQUID/LIQUID SHAKETCEMINERAL OIL by IR

HPLCLIQUID/LIQUID SHAKETCETPH by INFRA RED (IR)

GC MSSOLID PHASE EXTRACTIONDCMPHENOLS MS

GC MSLIQUID/LIQUID SHAKEDCMTRIAZINE HERBS

GC MSLIQUID/LIQUID SHAKEDCMPEST OCP/OPP

HPLCSOLID PHASE EXTRACTIONDCMFREE SULPHUR

GC MSLIQUID/LIQUID SHAKEDCMSVOC

GC MSSTIRRED EXTRACTION (STIR-BAR)HEXANEPCB TOTAL

GC MSSTIRRED EXTRACTION (STIR-BAR)HEXANEPCB 7 CONGENERS

GC FIDSTIRRED EXTRACTION (STIR-BAR)HEXANEMINERAL OIL

GC FIDSTIRRED EXTRACTION (STIR-BAR)HEXANEEPH CWG

GC FIDSTIRRED EXTRACTION (STIR-BAR)HEXANEEPH

GC MSSTIRRED EXTRACTION (STIR-BAR)HEXANEPAH MS

ANALYSISEXTRACTION

METHODEXTRACTION

SOLVENTANALYSIS

LIQUID MATRICES EXTRACTION SUMMARY

Identification of Asbestos in Bulk Materials & Soils

The results for identification of asbestos in bulk

materials are obtained from supplied bulk materials or

those identified as potentially asbestos containing

during sample description which have been

examined to determine the presence of asbestos

fibres using Alcontrol Laboratories (Hawarden)

in-house method of transmitted/polarised light

microscopy and central stop dispersion staining,

based on HSG 248 (2005).

The results for identification of asbestos in soils are

obtained from a homogenised sub sample which has

been examined to determine the presence of

asbestos fibres using Alcontrol Laboratories

(Hawarden) in-house method of transmitted/polarised

light microscopy and central stop dispersion staining,

based on HSG 248 (2005).

-Fibrous Tremolite

-Fibrous Anthophyllite

-Fibrous Actinolite

Blue AsbestosCrocidolite

Brown AsbestosAmosite

White AsbestosChrysotile

Common NameAsbestos Type

-Fibrous Tremolite

-Fibrous Anthophyllite

-Fibrous Actinolite

Blue AsbestosCrocidolite

Brown AsbestosAmosite

White AsbestosChrysotile

Common NameAsbestos Type

Visual Estimation Of Fibre Content

Estimation of fibre content is not permitted as part of our UKAS accredited test other than: -

Trace -Where only one or two asbestos fibres were identified.

Further guidance on typical asbestos fibre content of manufactured products can be found

in HSG 264.

The identification of asbestos containing materials and soils falls within our schedule of

tests for which we hold UKAS accreditation, however opinions, interpretations and all other

information contained in the report are outside the scope of UKAS accreditation.

GC-MSSONICATEDCM:ACETONEWET

SEMI VOLATILE ORGANIC

COMPOUNDS

GC-EZSHAKERHEXANE:ACETONEWET

POLYAROMATIC HYDROCARBONS RAPID

GC

GC-EZSHAKERHEXANE:ACETONEWETC8-C40 (C6-C40) EZ FLASH

GC-MS

MICROWAVE

TM218.HEXANE:ACETONEWET

POLYAROMATIC

HYDROCARBONS (MS)

GC-MSEND OVER ENDHEXANE:ACETONED&CPCB TOT / PCB CON

GC-FIDEND OVER ENDHEXANE:ACETONED&CEPH CWG BY GC

GC-FIDEND OVER ENDHEXANE:ACETONED&CEPH (CLEANED UP)

GC-FIDEND OVER ENDHEXANE:ACETONED&CEPH (MIN OIL)

GC-FIDEND OVER ENDHEXANE:ACETONED&CEPH (DRO)

GC-MSSOXTHERMHEXANE:ACETONED&CPESTICIDES

GC-MSSOXTHERMHEXANE:ACETONED&CHERBICIDES

GC-MSSOXTHERMDCMWETPHENOLS BY GCMS

HPLCSOXTHERMDCMD&CELEMENTAL SULPHUR

GRAVIMETRICSOXTHERMCYCLOHEXANED&CCYCLOHEXANE EXT. MATTER

GRAVIMETRICSOXTHERMDCMD&CSOLVENT EXTRACTABLE MATTER

ANALYSISEXTRACTION

METHODEXTRACTION

SOLVENT

D/C

OR WETANALYSIS

SOLID MATRICES EXTRACTION SUMMARY

GC-MSSONICATEDCM:ACETONEWET

SEMI VOLATILE ORGANIC

COMPOUNDS

GC-EZSHAKERHEXANE:ACETONEWET

POLYAROMATIC HYDROCARBONS RAPID

GC

GC-EZSHAKERHEXANE:ACETONEWETC8-C40 (C6-C40) EZ FLASH

GC-MS

MICROWAVE

TM218.HEXANE:ACETONEWET

POLYAROMATIC

HYDROCARBONS (MS)

GC-MSEND OVER ENDHEXANE:ACETONED&CPCB TOT / PCB CON

GC-FIDEND OVER ENDHEXANE:ACETONED&CEPH CWG BY GC

GC-FIDEND OVER ENDHEXANE:ACETONED&CEPH (CLEANED UP)

GC-FIDEND OVER ENDHEXANE:ACETONED&CEPH (MIN OIL)

GC-FIDEND OVER ENDHEXANE:ACETONED&CEPH (DRO)

GC-MSSOXTHERMHEXANE:ACETONED&CPESTICIDES

GC-MSSOXTHERMHEXANE:ACETONED&CHERBICIDES

GC-MSSOXTHERMDCMWETPHENOLS BY GCMS

HPLCSOXTHERMDCMD&CELEMENTAL SULPHUR

GRAVIMETRICSOXTHERMCYCLOHEXANED&CCYCLOHEXANE EXT. MATTER

GRAVIMETRICSOXTHERMDCMD&CSOLVENT EXTRACTABLE MATTER

ANALYSISEXTRACTION

METHODEXTRACTION

SOLVENT

D/C

OR WETANALYSIS

SOLID MATRICES EXTRACTION SUMMARY

09:40:50 21/10/2011

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Documents

For inspection purposes only. Consent of copyright … Periclase 1Ltd. 501.00056.00004 Waste Classification Testing November 2011 SLR 1.0 INTRODUCTION This report presents the results