FT-IRf t - i r / r a m a n s p e c t r o m e t e r
Thermo Scientific FT-IR
Gain clarity about your sample
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FT-IR 49

4 FT-IR 50 53 54

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11
PAS / ATR 4 4 FT-Raman Raman × × × × 5 × ×
× × × × × × ×
1
× × × ×
× × × × × × × × × × 9 9 7 8 6 × 9 10
2 /3
PAS Adv. ATR12
×
1 2
10 cm
9 MicroStage50 µm
10 11 FT-Raman
12 ATROMNIC6.2
ATR KBr
× × × × × 5 5 5 × ×
× × × × × × × × × × × × × × × ×
1 × ×
× × × × × × × ×
× × × × × × × × × × × × × × × × × × × × × × × × × 6 6 6 × × ×
2 × /3 × × ×
Adv. ATR12 Adv. ATR12 Adv. ATR12 K-K K-K K-M
5
http://www.thermoscientific.jp/support-landing/faq/ft-ir-raman-faq.html
Thermo ScientificTM NicoletTM FT-IR
Nicolet iSTM50 FT-IR Nicolet iS10 FT-IR Nicolet iS5 FT-IR
Nicolet iNTM10
Nicolet AlmegaTM Nicolet 380 FT-IR
Nicolet iS50 FT-IR
1
6


ATR

ATR1-2

ABX1-1
P/N iS50 ABX 840-230700 iS50 ABX 840-233000 iS50 ABXCaF2/Si 840-233100 iS50 ABXCaF2/Si 840-233200 iS50 ABX 840-236400 KBr/Ge7,800350 cm−1 840-128900 XT-KBr11,000375 cm−1 840-140900 27,0002,800 cm−1 840-129300 70050 cm−1 840-129400 CaF2/Si13,5001,200 cm−1 840-129500
Nicolet iS50 FT-IR
1
7
FT-RamanThermo Scientific Nicolet iS50 1-3
P/N iS50 840-233600 1064 nmInGaAs
CaF2/Si13,5001,200 cm−1 840-129500 XT-KBr11,000375 cm−1 840-140900 iS50 Polystyrene 840-237900 4 mL200 869-120700

300
P/N iS50 GC-IR 840-228300 MCT-A OMNIC Series Thermo Scientific Nicolet Vapor Phase

1-5

1-4
Nicolet iS50 FT-IR
1
8
Thermo Scientific Nicolet TGA-IR

TGA-IR1-8 TGA TGATG/DTA 3D Thermo Scientific OMNIC Specta
P/N Nicolet TGA-IR 840-253900 Nicolet TGA-IROMNIC Series 840-254200 Nicolet TGA-IROMNIC SeriesVapor 840-254500 13-876-2 TGAKBr 840-257500 TGAZnSe 840-257600
1-9 PM-IRRAS
VCD iS50iS50R FT-IR
P/N 840-235300 PM-IRRAS 840-235400 PM-IRRAS PEMMCT-A
PM-IRRAS/FT-VCD 840-235500 PM-IRRAS PEMFT-VCDMCT-A
FT-VCD 840-235600 50 kHzPEM FT-VCDMCT-A iS50 002-939700 PM-IRRAS 470-464800 FT-VCD 470-464700 FT-VCD 470-194400 IRRAS 470-261400 IRRAS 840-222000 SSP 81,975 cm−1 470-175900 SSP 43,950 cm−1 470-175800
2iD Nicolet iS5 FT-IR
iD iS5
2ZnSeGe AR

2-1
P/N iD7 ATR iS5: 869-172900 iD7 ATRAR869-168800 iD7 ATR869-168900 iD7 ZnSe ATR 869-169000 iD7 Ge ATR 869-169100 iD7 ATR / 869-169200
iS5
2 iD Nicolet iS5 FT-IR
iD iS5
P/N iD5 1ATR 869-142500 iD5 1ATRZnSe 869-142600 iD5 1ATRGe 869-142700 869-128600 869-128700 869-128800 869-128900 ZnSe 869-129000 Ge 869-129100 AMTIR 869-129200 Si/ZnSe1 869-129300 ZnSe3 869-129500 3 869-129600 869-129700 Smart iTRiD5 714-006400 Smart iTRiD5 714-006500 Smart iTRiD5 714-006600 Smart iTRiD5 714-006700 Smart iTRiD5 O 714-052000
2-3
2-4
11
P/N F. S. ATRZnSe 0072-390 F. S. ATRZnSe 0072-390T ZnSe 0072-703 ZnSe 0072-603 Ge 0072-713 Ge 0072-613 Si 0072-753 Si 0072-653
ATR3-1
P/N F. S. Performer ATR 0078-190 470-277800 ZnSe 0039-703 ZnSe 0039-603 Ge 0039-713 Ge 0039-613 Si 0039-753 Si 0039-653 AMTIR 0039-743 AMTIR 0039-643 470-221200 0039-555
Performer1ATR3-2
P/N F. S. ThunderDome ATR 0074-190
ThunderDome1ATR3-3
Thermo ScientificCPC
P/N F. S. 0073-490 Si-Carb 0030-130 400100 3000-561 320100 3000-562
CPC3-4
P/N 0070-190 iS10iZ10iS50 iS5 840-218800


P/N ATR Smart iTR 222-247000 ATR Smart iTRZnSe 222-247100 ATR Smart iTR/Ge 222-247200 ATR Smart iTRZnSe/Ge 222-247300 Smart iTR 222-247900 869-128600 869-128800 iTR USBZnSe130 222-248000 iTR USB60 222-248100 iTR USBGe60 222-248200 USB 277-002600 USB 277-002400 869-128900 ZnSe 869-129000 Ge 869-129100 AMTIR 869-129200 Si/ZnSe1 869-129300 ZnSe3 869-129500 3 869-129600 869-129700 ZnSe130 869-129800 60 869-129900 Ge60 869-130000
4-2


4-1
P/N iTX ATR 869-174400 iTX ATRAR869-168800 iTX ATR 869-168900 iTX ZnSe ATR 869-169000 iTX Ge ATR 869-169100 iTX ATR / 869-169200
4ATR
P/N ATRZnSe 0031-3T ATRZnSe 0031-3 ATRZnSe 0031-2
ZnSe Ge 30° 714 45° 703 713 60° 705 715
ZnSe Ge AMTIR Si 40° 602 612 45° 603 613 643 653 60° 605 615 645

P/NNicolet 38097Nicolet 4700/6700/8700 iS10iZ10iS5099 P/NXXXARKNo.
P/NNicolet 38097Nicolet 4700/6700/8700 iS10iZ10iS5099
ARK 0031-XXX
4 ATR
110 USB 300
P/N GladiATR Vision 1ATRiS50iS10 81032321 GladiATR Vision 1ATRiS5 81032322
ATRMicromATR / MicromATR Vision

30 cm−1 Ge500 cm−1 DuraSamplIR/DuraScope DuraSamplIR
4-6
ATRMIRacle
S/N ZnSeGeSi MIRacle
4-7
4ATR
4-9
P/N Si-CheckIR JPSTJ-0157 Si-CheckIR Ge 60 JPSTJ-0157-01 12 inch Si-CheckIR JPSTJ-0157-12
ATRVariGATR

P/N ATR 222-232300 GATR 222-232500 222-260500
4-8


4
200 20 MPa3000 psi28 mL 30041 MPa6000 psi 80
4-10
P/N JPGS10507 ATR JPGS10525 JPGS10585 ATR JPGS10586 JPGS10590 ATR JPGS10592
4 ATR
P/N 1ATRSeagull 869-059100
ATRVeeMax
4-12
P/N VeeMAX JP013-1140 ATR ZnSe 45° JP013-4021 ATR Ge 45° JP013-4041 ATR Si 45° JP013-4081 ATR ZnS 45° JP013-4091 JP013-3300 ATR
5
P/N Refractor2™ 81031889 Si 81031890 SuperCharged™ ZnSe 81031891
5-2
P/N 10SpeciS50iS10 81032315 10SpeciS5 81032316
5-3
Thermo Scientific Smart SAGA5-1
P/NNicolet 38097Nicolet 4700/6700/8700 iS10iZ10iS5099
5

P/N −UV 81030780
Nicolet 4700/6700/8700iS505-5
Nicolet 4700/6700/8700iS50
1585° UV
P/N 81030782 150 81030781 81030777
5-4
6
19

1×10−6 Torr13×10−4 Pa
P/N 900 81031885 500 81031886 900 81031887 Heat Chamber-150500 81031888
6-2
6-3
P/N The Selector JPGS19900 φ4 mmφ11 mm φ12 mm JPGS19930
UpIR



P/N Smart Diffuse 0028-4 Si-Carb 0030-130 400100 3000-561 320100 3000-562
Thermo Scientific Smart Diffuse6-1
P/NNicolet 38097Nicolet 4700/6700/8700 iS10iZ10iS5099
7

P/N Smart Integrating Sphere 840-172400 OMNIC7.3
7-2


MCT 10 cm 10° φ10 mm×2 4000–500 cm−1
7-1
8
FT-IR
FT-IR 1 95/ 13 13
2 9 10 ppb
6 10 ppm
5 10 ppm10 ppb
3H2O EI 4


2 m 200 mL 50 psi 185
P/N 2 mKBr 840-056100 2 mZnSe 840-058800 2 mBaF2 840-056500 185 840-056600 268-759400 BaF2 699-056900 KBr 699-056700 ZnSe 699-056800
8-2

10 m 2.0 L 200 psi 185

P/N 10 mKBr 840-137800 10 mZnSe 840-058500 10 mBaF2 840-058600 185 840-138200 268-759400 840-138300 BaF2 699-057200 KBr 699-057000 ZnSe 699-057100
8-3


×1×2O-×4×1
P/N 10 cm 869-147000 5 cm 869-146900
8-1
2
32 mmφ 7000-XXX NaCl KBr CaF2 BaF2 ZnS Ge Quartz ZnSe Si 451 452 453 454 456 461 462 463 465
P/NXXXNo.
9
KBr
P/N 3 mm 81032148 137 mm 0016-125 0016-112 3 mm 0016-133 137 mm 0016-117 7 mm 0016-113 3 mm 0016-115 1 mm 0016-116 0016-121 7 mm 3000-034 3 mm 3000-040 1 mm 3000-037 13 mm6 0016-118 7 mm 0016-119 137 mm 3000-033 7 mm 3000-032 3 mm 3000-039 1 mm 3000-036 7 mm 3000-035
P/N 016-721300 016-721400 7 mm 016-721500 7 mm 016-721600 7 mm 016-721700

9-1
9-2


P/N 13 mm 0016-213 25 mm 0016-225
9-3
9-4
9-5
9
13
0.050.10.20.51.0 mm PTFE
9-6
P/N Omni Cell 869-149200
6 µm H41×W23 mm
2
P/N
25×24 mm
NaCl 869-159100 869-160300 KBr 869-159200 869-160400 CaF2 869-159300 869-160500 BaF2 869-159400 869-160600 ZnSe 869-159500 869-160700 KRS-5 869-159600 869-160800 CsI 869-159700 869-160900 Quartz 869-159800 869-161000 AgBr 869-159900 869-161100 Si 869-160000 869-161200 ZnS 869-160100 869-161300


9-7
25 mmφ NaCl KBr CaF2 BaF2 ZnS Ge Quartz ZnSe Si
25 mm 316 317 318 319 321 326 327 328 330
P/NXXXNo.
P/N 25 mm 0018-012 7000-XXX
25 mm12 P/N 0.015 mm12 0018-017 0.025 mm12 0018-018 0.05 mm12 0018-019 0.1 mm12 0018-020 0.2 mm12 0018-021 0.5 mm12 0018-022 2 0018-023

P/N
13 mm×2 mm 25 mm×4 mm 32 mm×3 mm
32 mm×3 mm
NaCl 7000-301 7000-316 7000-451 7000-466 KBr 7000-302 7000-317 7000-452 7000-467 CaF2 7000-303 7000-318 7000-453 7000-468 BaF2 7000-304 7000-319 7000-454 7000-469 ZnS 7000-306 7000-321 7000-456 7000-471 KRS-5 7000-307 7000-322 7000-457 7000-472 CsI 7000-308 7000-323 7000-458 7000-473 Ge 7000-311 7000-326 7000-461 7000-476 Quartz 7000-327 7000-462 7000-477 ZnSe 7000-313 7000-328 7000-463 7000-478 Si 7000-330 7000-465 7000-480



9-8

9-9
P/N JP112-1000 12–15 mm JP112-2010 16–20 mm JP112-2020 21–25 mm JP112-2030 26–30 mm JP112-2040 PC JP076-1410 JP170-1000
400HC-400S
9-10
P/N HC-400S JPSTJ-0176 HC-400S PC JPSTJ-0177 32×3 mm KBr 7000-452 32×3 mm KBr 7000-467
9

9-11
MappIR

9-12
P/N MappIR 8 inch JP016-2840 MAP300 12 inch JP017-2840 6 inch JP073-3860 4 inch JP073-3840 2 inch JP073-3820

9-13
P/N JPGS03970 JPGS03971 152550100250500 µmJPGS03972 200 JPGS03973
9
IR
P/N ST-IR 2512 0020-300 ST-IR 2512 0020-301
9-15

9-14
P/N MAIRS TN10-1500 MAIRS TN60-1000 KBr 840-072000 470-151400
MAIRSMCTNicolet 6700/8700 iS50 MAIRS
MAIRSMultiple-Angle Incidence Resolution Spectrometry
MAIRS
10

P/N FlexIR 81031893 ATR ZnSe 81031894 81031895 81031896 ATR Ge 81031897 ATR 81031898
10-1

LC - F T I R
32
LCFTIRLC-Transform
13-1
P/N HTX LC-Transform JPHTX-LCTR-H001-T Ge1 mm5 JPHTX-LCTR-LC5030

PA 30111-1
1 mmφ500×500 µm
8 mm 40 psi2.8 kgf/cm2
14-1
×
× 1

Nicolet iN10/iN10MX14-2 ATR
P/N Tip ATR 350GeATR 840-194800 D-SlidIRATR 81032313
P/N 840-199700
P/N 840-199800
P/N iN101 inch×3 inch 714-020200 iN10ATR 714-020300 iN10 714-020400 iN10 714-020100
Tip ATR 350
P/N x15Reflachromat 0045-403 x32Reflachromat 0045-405 x15 0045-401 x152 mm 0045-436
P/N x4 0045-455 x10 0045-456 x20 0045-457 x40 0045-458
ATR P/N FeelIR ATR 81032311 FeelIR 81032312
14-3
14
P/N ATRGe Tip 840-169500 ATRGe 0045-420 ATRSi 0045-419 Ge Tip 840-169600 Ge Tip 470-267500 Ge 0045-422 Si 0045-421 0045-561
14-4
14-5
14
P/N Continuµm 840-159200 Continuµm 840-159300
P/N Blue 450-480 nm 4009-700 Green 510-550 nm 4009-701 UV 330-385 nm 4009-702 Blue Violet 400-440 nm 4009-703
Model S84
ContinµmiN10DXR 500 -190+5002 4 mm
14-7
P/N Model S84 JPSTJ-M84-01 Model-84S JPSTJ-M84L-02 JPSTJ-M84-02 20×2 mm BaF2 JP915-3316 JP170-1000

14-8
P/N /2.0 mm 81032481 /1.6 mm 81032480 /2.0 mm1 JPSTJ-0194DH /1.6 mm1 JPSTJ-0195DH JPSTJ-0194B 3 JPSTJ-0194S


14
14-10 P/N 100 0047-432
1”X35 0042-554 1”X35 0042-544 Gold EZ-Spot5 0042-555 Aluminum EZ-Spot 5 0042-545 13 mm2 4006-713
0036-507 0036-508
LN2 470-064700
5 inch 222-043901 3 inch 268-736400
DICContinuµm14-11 P/N DIC 0045-446 0045-448 0045-347
14
14-12
Mini-Plane


14-15
/MV-SliceIR

14-13
14
14-16


14-17
P/N JPQP-3RH JPQP-3LH JPQP-3RLH



14-19
14
14-20
HM325
15
41
DXR Smart 15-1
P/N DXR 780 nm 840-187100 DXR HP780 nm 840-187200 DXR 633 nm 840-198500 DXR 532 nm 840-187400
P/N 780 nm 840-187500 633 nm 840-187600 532 nm 840-187700
P/N DXR 840-188400 840-188500 840-TABWELL 840-188600 840-188700 840-188800 840-188900 180 840-189000 165 mm 840-098300 813 mm 840-098400 869-118600
P/N DXR 840-188000 780 nm5 m 840-188100 532 nm5 m 840-080400
15
42
DXR15-2
P/N DXR 780 nm 840-187100 DXR HP780 nm 840-187200 DXR 633 nm 840-198500 DXR 532 nm 840-187400
P/N 780 nm 840-187500 633 nm 840-187600 532 nm 840-187700
P/N 0042-475 699-069700 0042-477
P/N 10xBF 222-242700 20xBF 222-242800 50xBF 222-242900 100xBF 222-243000 20xBF 222-203300 10xBF 222-203200 x4 0045-455 BF → BD BF 268-782000 10x 222-187400 20x 222-188300 50x 222-188400 100x 222-188600 50x 222-188500 100x 222-188700 50x/ 222-233200 100x 222-233300 222-233401 222-216600 4 0045-410 5 222-186900
P/N DXR 840-188000 780 nm5 m 840-188100 532 nm5 m 840-080400
16

P/N OMNIC Specta9,183 833-036200 OMNIC Specta 13,197 833-036300 OMNIC Specta 11,968 833-036400 OMNIC Specta 17,567 833-036500 OMNIC SpectaTGA 9,947 833-036600 OMNIC Specta 18,601 833-036700 OMNIC Specta 3,264 833-036800 OMNIC Specta 14,178 833-036900
OMNIC Specta
OMNIC Series16-3 KineticsGC-IRTGA-IR 3DGram-SchmidtChemigram
Thermo Scientific TQ Analyst16-4 TQ AnalystPLSPCR
Thermo Scientific Val ProTM
16-5
OMNIC DS16-6 Windows® 21CFR Part 11
OMNIC16-7

44
Aldrich18,254 Aldrich 834-019500 DVD1,199 Aldrich 834-019600 DVD1,200 Aldrich 834-019700 DVD1,311 Aldrich 834-019800 DVD1,653 Aldrich 834-019900 DVD1,229 Aldrich 834-020000 DVD822 Aldrich 834-020100 DVD1,523 Aldrich 834-020200 DVD466
Aldrich 17-2
Aldrich 17-5
Hummel 17-6
Chemir/Polytech LaboratoriesDr.John Kokosa CAS 834-008300 DVD1,799
17-7
17-8

45
17-16
834-010600 DVD1,961
17-10
17-14
834-007800 DVD3,549
17-17
17-11
17-15
17-13

46
17-18
17-19
17-22
NIR 17-20
17-21
TGA 17-25
EPA 17-26
17-27

47
17-33
17-34
17-35
17-36
17-28
Sigma 17-31
SigmaTM 17-29
Sigma 17-30
17-32

48
ATR 17-37
ATR17-38
irAnalyze

18FT-IR
49
HeNe Nicolet 380 713-015400 713-015500 008-710003 840-097800 840-077700 Nicolet
4700/6700/8700 714-055300 711-001000 714-118700 122-756200 840-077700
Nicolet iS5 714-059100 714-056000 Diode 714-056200 714-059200
Nicolet iS10 714-016200 714-016300 714-009800 714-014900 714-014100 Nicolet iS50 714-094900 714-095000 714-087800 714-081800 714-093600 Nicolet iN10 714-016200 714-009800 714-014900 714-014100
Continuµm/Centaurus 4004-526
ATRλ1/e dp 1ATR dp2n1, n2 θE0n1, n2, θ α
1dp 2πn1sin2θ-n2/n121/2
λ
cosθ E02
cm1
/ ZnSe 45°

ZnSe 2.4
45 0.50 0.67 1.00 1.25 1.54 2.01 3.34 5.01 iTXiTROrbit DuraSamplIR GoldenGate
60 0.28 0.37 0.55 0.69 0.85 1.11 1.84 2.77
Ge 4.0
30 0.30 0.40 0.60 0.75 0.93 1.20 1.85 ATR Seagull
40 0.19 0.25 0.38 0.48 0.59 0.76 1.27 OMNI-Sampler
45 0.17 0.22 0.33 0.41 0.51 0.66 1.02 iTXiTROrbit OMNI-Sampler
60 0.13 0.17 0.25 0.32 0.39 0.51 0.78 Seagull 65 0.12 0.16 0.24 0.30 0.37 0.48 0.74
51
FT-IR
500 1000 1500 2000 2500 3000 3500 4000
V=0.4747 cm/s f=1000 Hzµ=5.6 µm V=0.3165 cm/s f=400 Hzµ=8.9 µm V=0.1581 cm/s f=200 Hzµ=12.6 µm
α0.001 cm2/s
µm

PASµ
µ =α/πf1/2
κα = κ/ρCp
κ :J s−1 m−1 K−1 ρ :kg m−3 Cp :J kg−1 K−1
f :Hz
V :cm s−1 ν :cm−1
f



52
FT-IR
Kubelka-Munk
Kubelka-Munk
fR= {1-R2ν}/2Rν Rν/
↓ ↓ ↓ Kubelka-Munk
2 1
Kramers-KronigKK 2
↓ ↓ Kramers-Kronig

↓ ×2
ATR cm−1
@1000 cm−1
%
NaCl 40,000625 1.49 91.54 mm
KBr 40,000400 1.52 90.54 mm
Csl 40,000200 1.74 922 mm
CaF2 50,0001,111 1.39 904 mm
BaF2 50,000740 1.42 903 mm
AgCl 25,000360 1.98 843 mm
ZnS 17,000720 17,000950 2.2 701 mm
Sapphire 50,0001,600 50,0001,780 1.74 702 mm
AMTIR 11,000625 11,000840 2.5 682 mm
Ge 5,500475 5,500675 4.0 502 mm
ZnSe 20,000454 20,000650 2.4 651 mm
Si 8,300660 36070
8,3001,500 360120 3.4 552.5 mm
CdTe 20,000360 2.67 405 mm
Diamond 4,5002,500 1,66733 4,200200 2.4 701 mm
KRS-5 20,000250 20,000400 2.37 702 mm
Quartz 25,0002,200 1.4 903 mm
g/100gH2O@25

knoop#
CaF2 0.0013 900 3.18 158
BaF2 0.17 500 4.83 82
AgCl 0.00015 200 6.47 EDTA 9.5
ZnS 0.00069 300 4.08 178
Sapphire 1,700 4.00 1,370
AMTIR 300 4.40 170
Ge 270 5.32 550
ZnSe 300 5.27 137
Si 300 2.33 HFHNO3 1,150
CdTe 300 6.2 56
Diamond 750 3.51 7,000
KRS-5 0.05 200 7.37 EDTA 40
Quartz 1,200 2.203 HF 820
54

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