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Heteroatom Chemistry Volume 17, Number 3, 2006 Guest Editorial In his inaugural Editorial in January 2004, Fran¸ cois Mathey announced plans for thematic issues of Heteroatom Chemistry, where “specialists will de- scribe the latest advances in hot fields of heteroatom chemistry.” Boron was chosen to launch this ini- tiative. It is one of the most unique and individual elements of the periodic table. Four areas of modern boron chemistry are high- lighted. Two timely reviews bring readers up to date on novel views of aromaticity in three-membered rings, and the use of organoboron compounds to form fas- cinating heteroatom-containing cyclo-pentadienes. A third review, on the chemistry of transition metal borylene complexes (M = BR), belongs in this issue but was inadvertently published earlier [Heteroatom Chemistry 2005, 16(7), 566–572]. c 2006 Wiley Periodicals, Inc. Four papers report new studies with carboranes that are pushing the frontiers of weakly coordinating anion chemistry. There is irony to be found here. Car- bon has become an important heteroatom. One pa- per gives double value, advancing the coordination chemistry of boron and putting carborane anions to good use. We hope you enjoy reading these papers. It was fun watching them come in. They set the stage for continued focus on the elements that especially fascinate us. Chris Reed University of California, Riverside December 23, 2005 173

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Heteroatom ChemistryVolume 17, Number 3, 2006

Guest Editorial

In his inaugural Editorial in January 2004, FrancoisMathey announced plans for thematic issues ofHeteroatom Chemistry, where “specialists will de-scribe the latest advances in hot fields of heteroatomchemistry.” Boron was chosen to launch this ini-tiative. It is one of the most unique and individualelements of the periodic table.

Four areas of modern boron chemistry are high-lighted.

Two timely reviews bring readers up to date onnovel views of aromaticity in three-membered rings,and the use of organoboron compounds to form fas-cinating heteroatom-containing cyclo-pentadienes.A third review, on the chemistry of transition metalborylene complexes (M = BR), belongs in this issuebut was inadvertently published earlier [HeteroatomChemistry 2005, 16(7), 566–572].

c© 2006 Wiley Periodicals, Inc.

Four papers report new studies with carboranesthat are pushing the frontiers of weakly coordinatinganion chemistry. There is irony to be found here. Car-bon has become an important heteroatom. One pa-per gives double value, advancing the coordinationchemistry of boron and putting carborane anions togood use.

We hope you enjoy reading these papers. It wasfun watching them come in. They set the stage forcontinued focus on the elements that especiallyfascinate us.

Chris ReedUniversity of California, Riverside

December 23, 2005

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