6
2/5/14 1 11.1 Chemical Reactions > 1 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Chapter 11 Matter and Change 11.1 Describing Chemical Reactions 11.2 Types of Chemical Reactions 11.3 Reactions in Aqueous Solution 11.1 Chemical Reactions > 2 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Introduction to Chemical Equations Reactants written on the left. Products on the right. Read the arrow as yields, gives, or reacts to produce. Reactants products Word Equations 11.1 Chemical Reactions > 3 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Introduction to Chemical Equations You could say, “Iron reacts with oxygen to produce iron(III) oxide (rust).” Word Equations Iron + oxygen iron(III) oxide Fe + O 2 Fe 2 O 3 A skeleton equation is a chemical equation that does not indicate the relative amounts of the reactants and products. 11.1 Chemical Reactions > 4 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Chemical Equations Introduction to Chemical Equations States of matter Use (s) for a solid, (l) for a liquid, (g) for a gas, and (aq) for a substance in an aqueous solution (a substance dissolved in water). Fe(s) + O 2 (g) Fe 2 O 3 (s)

HC CH 11 sec 1 - Eastern Regional High Schoolweb.eccrsd.us/borda/public/honors/HC_CH11_1.pdf · 2/5/14 2 11.1 Chemical Reactions > 5 Copyright © Pearson Education, Inc., or its affiliates

Embed Size (px)

Citation preview

2/5/14

1

11.1 Chemical Reactions >

1 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Chapter 11 Matter and Change 11.1 Describing Chemical

Reactions 11.2 Types of Chemical Reactions 11.3 Reactions in Aqueous Solution

11.1 Chemical Reactions >

2 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Introduction to Chemical Equations

•  Reactants written on the left.

•  Products on the right.

•  Read the arrow as yields, gives, or reacts to produce.

Reactants → products

Word Equations

11.1 Chemical Reactions >

3 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Introduction to Chemical Equations

•  You could say, “Iron reacts with oxygen to produce iron(III) oxide (rust).”

Word Equations

Iron + oxygen → iron(III) oxide

Fe + O2 → Fe2O3

•  A skeleton equation is a chemical equation that does not indicate the relative amounts of the reactants and products.

11.1 Chemical Reactions >

4 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Chemical Equations

Introduction to Chemical Equations

States of matter •  Use (s) for a solid, (l) for a liquid, (g) for a

gas, and (aq) for a substance in an aqueous solution (a substance dissolved in water).

Fe(s) + O2(g) → Fe2O3(s)

2/5/14

2

11.1 Chemical Reactions >

5 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Introduction to Chemical Equations

Word Equations

Hydrogen peroxide → water + oxygen

•  “Hydrogen peroxide decomposes to form water and oxygen gas.”

11.1 Chemical Reactions >

6 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Chemical Equations

Introduction to Chemical Equations

•  A catalyst is a substance that speeds up the reaction but is not used up in the reaction.

•  A catalyst is neither a reactant nor a product, so its formula is written above the arrow in a chemical equation.

H2O2(aq) H2O(l) + O2(g) MnO2

11.1 Chemical Reactions >

7 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Interpret Data

Symbols Used in Chemical Equations

Symbol Explanation

+ Separates two reactants or two products

→ “Yields,” separates reactants from products

Use in place of → for reversible reactions

(s), (l), (g) Designates a reactant or product in the solid state, liquid state, or gaseous state; placed after the formula

(aq) Designates an aqueous solution; the substance is dissolved in water; placed after the formula

Indicates that heat is supplied to the reaction

A formula written above or below the yields sign indicates its use as a catalyst (in this example, platinum).

Δ

heat

Pt

11.1 Chemical Reactions >

8 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Hydrochloric acid reacts with solid sodium hydrogen carbonate. The products formed are aqueous sodium chloride, water, and carbon dioxide gas. Write a skeleton equation for this chemical reaction.

Sample Problem 11.1

Writing a Skeleton Equation

NaHCO3(s) + HCl(aq) → NaCl(aq) + H2O(l) + CO2(g)

2/5/14

3

11.1 Chemical Reactions >

9 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Balancing Chemical Equations

Balancing Chemical Equations

In a balanced equation each side of the equation has the same number of atoms of each element. •  Bonds holding the reactants together are broken,

new bonds are formed.

•  The atoms themselves are neither created nor destroyed; they are merely rearranged.

•  Mass is conserved.

11.1 Chemical Reactions >

10 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Balancing Chemical Equations

First write the skeleton equation.

Then use coefficients to balance the equation so that it obeys the law of conservation of mass.

11.1 Chemical Reactions >

11 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

C(s) Carbon

+ O2(g) Oxygen

CO2(g) Carbon dioxide

Reactants 1 carbon atom, 2 oxygen atoms

Product 1 carbon atom, 2 oxygen atoms

Balancing Chemical Equations

Carbon burns in the presence of oxygen to produce carbon dioxide.

•  This equation is balanced.

•  You do not need to change the coefficients. –  They are all understood to be 1.

11.1 Chemical Reactions >

12 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Balancing Chemical Equations

When hydrogen and oxygen are mixed, the product is water.

•  The formulas for all the reactants and the product are correct, but this equation is not balanced. –  As written, the equation does not obey the law of

conservation of mass.

2/5/14

4

11.1 Chemical Reactions >

13 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Balancing Chemical Equations

When hydrogen and oxygen are mixed, the product is water.

•  If you put the coefficient 2 in front of H2O, oxygen will be balanced.

11.1 Chemical Reactions >

14 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Balancing Chemical Equations

When hydrogen and oxygen are mixed, the product is water.

•  To correct this equation, put the coefficient 2 in front of H2.

11.1 Chemical Reactions >

15 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

The reaction between oxygen and hydrogen in fuel cells produces the energy to power a car. What are the products of the reaction in a fuel cell that make the fuel-cell car a zero-emission car?

CHEMISTRY & YOU 11.1 Chemical Reactions >

16 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

The reaction between oxygen and hydrogen in fuel cells produces the energy to power a car. What are the products of the reaction in a fuel cell that make the fuel-cell car a zero-emission car? Water is the product of the reaction between oxygen and hydrogen in a fuel cell. Water is not a pollutant, and so fuel-cell cars are considered “zero-emission” cars.

CHEMISTRY & YOU

2/5/14

5

11.1 Chemical Reactions >

17 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Students suspended copper wire in an aqueous solution of silver nitrate. They noticed a deposit of silver crystals on the copper wire when the copper reacted with the silver nitrate. They recorded the equation for this reaction but didn’t balance it. Write an equation and balance it.

AgNO3(aq) + Cu(s) → Cu(NO3)2(aq) + Ag(s)

Sample Problem 11.2

Balancing a Chemical Equation

11.1 Chemical Reactions >

18 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Sample Problem 11.2

2AgNO3(aq) + Cu(s) → Cu(NO3)2(aq) + 2Ag(s)

11.1 Chemical Reactions >

19 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Aluminum is a good choice for outdoor furniture because it reacts with oxygen in the air to form a thin protective coat of aluminum oxide. Balance the equation for this reaction.

Sample Problem 11.3

Balancing a Chemical Equation

Al(s) + O2(s) → Al2O3(s)

11.1 Chemical Reactions >

20 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Sample Problem 11.3

2Al(s) + O2(s) → 2Al2O3(s)

2/5/14

6

11.1 Chemical Reactions >

21 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Sample Problem 11.3

2Al(s) + 3O2(s) → 2Al2O3(s)

11.1 Chemical Reactions >

22 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Sample Problem 11.3

4Al(s) + 3O2(s) → 2Al2O3(s)

Final

11.1 Chemical Reactions >

23 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Balance the following equation.

C3H8(g) + O2(g) → CO2(g) + H2O(l)

11.1 Chemical Reactions >

24 Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved.

Balance the following equation.

C3H8(g) + O2(g) → CO2(g) + H2O(l)

C3H8(g) + 5O2(g) → 3CO2(g) + 4H2O(l)