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Performance Products Agrochemical Formulants Global Product Information

Huntsman Agro Brochure 2010 update:agro brochure Library/a... · New technology developments include ... for use in agrochemical formulations over many ... formulations. AVAILABLE

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Performance Products

Agrochemical FormulantsGlobal Product Information

NSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM ERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMRSPERSE® TERSPERSE® TERSPERSE® TERSPERSE® TERSPERSE®

® TERWET® TERWET® TERWET® TERWET® TERWET® TERWET® TTERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX®

JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® NSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM ERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMRSPERSE® TERSPERSE® TERSPERSE® TERSPERSE® TERSPERSE®

® TERWET® TERWET® TERWET® TERWET® TERWET® TERWET® TTERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX®

JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® NSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM ERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMRSPERSE® TERSPERSE® TERSPERSE® TERSPERSE® TERSPERSE®

® TERWET® TERWET® TERWET® TERWET® TERWET® TERWET® TTERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX®

JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® NSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM ERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMRSPERSE® TERSPERSE® TERSPERSE® TERSPERSE® TERSPERSE®

® TERWET® TERWET® TERWET® TERWET® TERWET® TERWET® TTERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX®

JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® ERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMRSPERSE® TERSPERSE® TERSPERSE® TERSPERSE® TERSPERSE®

® TERWET® TERWET® TERWET® TERWET® TERWET® TERWET® TTERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX®

JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® NSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM ERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMRSPERSE® TERSPERSE® TERSPERSE® TERSPERSE® TERSPERSE®

® TERWET® TERWET® TERWET® TERWET® TERWET® TERWET® TTERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX®

JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® NSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM ERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERM

Table of Contents

Huntsman Agrochemical Formulants . . . . . . . . . . . . . .2

Applications Table . . . . . . . . . . . . . . . . . . . . . . . . . . . .4

NANSA® Anionic Surfactants . . . . . . . . . . . . . . . . . . . .6

TERSPERSE® Dispersants . . . . . . . . . . . . . . . . . . . . . .8

TERWET® Wetting Agents and Adjuvants . . . . . . . . .10

TERMIX® Tank Mix Adjuvants . . . . . . . . . . . . . . . . . .12

TERMUL® Emulsifiers . . . . . . . . . . . . . . . . . . . . . . . . .14

JEFFSOL® AG Solvents . . . . . . . . . . . . . . . . . . . . . . .18

Contact Information . . . . . . . . . . . . . . . . . . . . . . . . . .20

IntroductionHuntsman is a global manufacturer and marketer of

differentiated chemicals. Its operating companies

manufacture products for a variety of global industries

including chemicals, plastics, automotive, aviation, textiles,

footware, paints and coatings, construction, technology,

agriculture, health care, detergent, personal care, furniture,

appliances and packaging. Originally known for pioneering

innovations in packaging and, later, for rapid and integrated

growth in petrochemicals, Huntsman today has 11,000

employees and operates from multiple locations worldwide.

The Performance Products division of Huntsman is a global

leader in the development of differentiated chemical

products for industrial and domestic use. The Perfomance

Products business division includes the strategic business

units of Agrochemicals (AG), Coatings, Polymers & Resins

(CPR), Resources Fuels & Lubes (RFL) and Process

Additives (PA). The Performance Products division of

Huntsman is able to provide industry aligned technical and

product support through a range of facilities and offices in

various regions worldwide.

For more information, we invite you to visit our web site

www.huntsman.com/agrochemicals.

1

Huntsman

Huntsman’s Agrochemicals strategic business unit actively

seeks to be the supplier of choice for surfactants,specialty

solvents and amines in the global market. We seek to

achieve this through advancing technology, a thorough

understanding of regulatory compliance, manufacturing

expertise and global logistics management. We supply

additives for use in major agrochemical market segments

including crop protection products, animal health, home

and garden, professional and tank mix adjuvants.

Huntsman offers a wide range of specialty inerts for

assisting pesticide use and delivery. These include

emulsifiers and solvents for emulsifiable concentrates and

aqueous emulsions, dispersants, wetters and humectants

for suspension concentrates, dispersants and wetters for

water dispersible granules and wettable powders, built-in

wetting agents and adjuvants for soluble liquid concentrates

as well as a range of specialty additives for suspoemulsions,

capsule suspensions and tank mix adjuvants.

Huntsman Agrochemical Formulants

2

The Huntsman Advanced Technology Center (HATC) in The Woodlands, Texas is Huntsman’s global research and technology

headquarters. The HATC is dedicated to supporting our customers with innovative new products and designs.

New technology developments include more effective and

environmentlly friendly agricultural adjuvants, new generation

polymeric dispersants and solvents, as well as low foam

wetting agents and highly efficient emulsifiers. We continue

to provide solutions to formulation problems for all major

formulation types used for agrochemicals, with particular

expertise in water dispersible granule technologies,

suspensions and structured surfactant formulations.

Our dedication to the industry also extends into the

regulatory process with succesful US-EPA approvals for

new solvents and surfactants being achieved and

commitment to ensure compliance for our products under

the European REACH system. The success of our technical

efforts in product development and formulations is

evidenced by the number of proprietary, patented

technologies that have been commercialized by Huntsman

for use in agrochemical formulations over many years.

The Huntsman Agrochemicals business unit includes a

team of dedicated sales and technical professionals with a

strong background in the industry covering key regions of

the world. Supporting each region are committed technical

teams, with development laboratory facilities in Australia,

Belgium, China and the United States.

This brochure contains typical properties of the Huntsman

range of global agrochemical formulants. For more

information on products offered by Huntsman please visit

our web site at www.huntsman.com/agrochemicals.

3

Huntsman European Technology Center, Everberg, Belgium.

Products in the Huntsman surfactant series are typically used

in formulations as dispersants, wetting agents, emulsifiers

and agricultural spray adjuvants. Dispersants facilitate the

dispersion and suspension of active particles of dry and liquid

flowables in the formulation and the application tank. Wetting

agents lower the surface tension of aqueous solutions and

can improve the degree of surface coverage and penetration

of the pesticide. Emulsifiers form stable mixtures of an oil or

solvent solutions in water, enabling an easy-to-apply tank-

mix. Adjuvants can improve foliar retention and penetration

or adjust the tank mix properties to improve the overall

effectiveness and efficacy of the pesticide.

The Performance Products division of Huntsman offers a

whole range of surfactants as well as specialty solvents

and specialty amines for the agrochemical industry. In

addition to the general Huntsman product range,

dedicated products and their uses include:

Huntsman Agrochemical Formulants Guide

4

Emulsifiable Water Suspension WettableConcentrates Dispersible Concentrates Powders

Huntsman Product Description (EC) Granules (WG) (SC) (WP)

NANSA® anionic surfactants

TERSPERSE® nonionic, anionic and anionic/ nonionic blended dispersants

TERWET® built-in adjuvantsand functional wetting agents

TERMIX® tank-addedadjuvants and compatibilizers

TERMUL® nonionic, anionic and blendedemulsifiers

JEFFSOL® AG solvents

Huntsman Asia Pacific Technology Center,

Shanghai, China

Emulsions in Suspo Capsule Oil Soluble TankMicroemulsions Water or Oil Emulsions Suspensions Dispersion Liquids Mix

(ME) (EW)(EO) (SE) (CS) (OD)(OF) (SL) Adjuvants

5

Huntsman Australia Technology Center,

Victoria, Australia

PRODUCT DESCRIPTION These anionic surfactants are amine salts or metal salts of alkylbenzene sulfonic acids.

USE and APPLICATION Calcium salts have a generally low HLB value and are useful as emulsifiers in EC

formulations. Certain sodium salts are useful as wetting agents in dry and liquid

formulations.

AVAILABLE CHEMISTRY Both linear and branched dodecylbenzene sulfonic acids are available. The salts

include sodium, calcium and amines, such as alkylamines and alkanolamines.

40 CFR EXEMPTIONS 180.910/930 Alkyl (C8-C24) benzenesulfonic acid and its NH4, Ca, Mg, K, Na and

Zn salts.

180.920 Diethanolamine salts of alkyl (C8-C24) benzenesulfonic acid. Not to exceed

7% of pesticide formulation. Dimethylaminopropylamine, isopropylamine,

ethanolamine, and triethanolamine salts of alkyl (C8-C24) benzenesulfonic acid.

NANSA® Anionic Surfactants

6

Sodium Salts

NANSA® Appearance Density Flash Pour Viscosity Active EPAAnionic @ @ 25°C Point, Point, @ 25°C, Content 40 CFR180

Surfactants Description Use 25°C g/ml PMCC, °C °C cP % w/w Listing

SS 50 Linear alkylate SL, Viscous liquid 1.03 >120 N/A 4800 50 Yesin water SC

HS 80/S Linear alkylate SC, Powder 0.45* N/A N/A N/A 80 YesWG, WP

HS 90/S Linear alkylate SC, Powder 0.45* N/A N/A N/A 90 YesWG, WP

* Bulk Density

Alkylbenzene Sulfonic Acids

NANSA® Appearance Density Flash Pour Viscosity Active EPAAnionic @ @ 25°C Point, Point, @ 25°C, Content 40 CFR180

Surfactants Description Use 25°C g/ml PMCC, °C °C cP % w/w Listing

SSA Linear alkylate EC, Liquid 1.05 >150 -10 1200 >95 YesSL

SBA Branched alkylate EC, Viscous liquid 1.05 >150 -10 12,500 >94 YesSL

7

Calcium Salts

NANSA® Appearance Density Flash Pour Viscosity Active EPAAnionic @ @ 25°C Point, Point, @ 25°C, Content 40 CFR180

Surfactants Description Uses 25°C g/ml PMCC, °C °C cP % w/w Listing

EVM 50/NS Linear alkylate in EC, Viscous liquid 1.02 35 -9 8000 50 Yesnaphtha solvent / EW propylene glycol

EVM 60/2EG Linear alkylate in EC, Viscous liquid 0.98 63 <0 7500 60 Yes2-ethylhexanol EW

EVM 62/H Branched alkylate in EC, Viscous liquid 0.99 22 -9 3000 61 Yesiso-butanol EW

EVM 62/N Linear alkylate EC, Liquid 0.98 25 <-10 700 61 Yesin n-butanol EW

EVM 63/B Linear alkylate in EC, Liquid 1.00 26 <-10 1300 63 Yesiso-butanol EW

EVM 70/B Linear alkylate in EC, Viscous liquid 1.02 33 -6 12,500 69 Yesiso-butanol EW

EVM 70/13 Linear alkylate in EC, Viscous liquid 1.02 36 -6 9500 70 Yesn-butanol EW

EVM 70/2E Linear alkylate in EC, Viscous liquid 0.99 63 <-10 1900 57 Yes2-ethylhexanol/ EW propylene glycol

Amine Salts

NANSA® Appearance Density Flash Pour Viscosity Active EPAAnionic @ @ 25°C Point, Point, @ 25°C Content 40 CFR180

Surfactants Description Uses 25°C g/ml PMCC, °C °C cP % w/w Listing

YS 94 Isopropylamine EC, Viscous liquid 1.03 >120 -10 4000 96 Yessalt based on a EW,linear alkylate SC

TS 50/F Triethanolamine salt SC, Liquid 1.05 >90 -10 2000 51 Yesbased on a linear SLalkylate in water

PRODUCT DESCRIPTION These agricultural surfactants may be oligomers, polymers or alkoxylates. They are

used as dispersants or as dispersant/wetter combinations.

USE and APPLICATION • Dispersants in WP and WG formulations

• Dispersants in aqueous suspension concentrates (SC) and suspoemulsions (SE)

• Wetter/dispersants in aqueous suspension concentrates

• Dispersants for oil based suspensions (OD)

BENEFITS • Dispersants in high active loading formulations

• Reduced aging problems in WG formulations

• Wetter/dispersant combinations that are liquid at room temperature

40 CFR EXEMPTIONS 180.960 - Polymers that meet the definition under 40 CFR 723.250 are exempt from

the requirement of a tolerance.

TERSPERSE® Dispersants

Naphthalene Sulfonate Formaldehyde Condensate (NSF)

Appearance Density Viscosity EPATERSPERSE® @ @ 25°C, Flash Point Pour @ 25°C, 40 CFR180Dispersants Description Uses 25°C g/ml °C, PMCC Point, °C cP Listing

2001 NSF Sodium SC Liquid 1.20 >90.0 <10 90 Yessalt, 40%

2020 Alkyl-NSF sodium salt SC, WP, WG Powder 0.5* N/A N/A N/A Yes

2100 NSF sodium salt SC, WP Powder 0.5* N/A N/A N/A Yes

2105 NSF sodium salt SC, WP Powder 0.5* N/A N/A N/A Yes

2158 NSF sodium salt SC, WP Powder 0.5* N/A N/A N/A Yes

* Bulk Density

Nonionic Wetter and Dispersant

Appearance Density Viscosity EPATERSPERSE® @ @ 25°C, Flash Point Pour @ 25°C, 40 CFR180Dispersants Description Uses 25°C g/ml °C, PMCC Point, °C cP Listing

4894 Nonionic wetter SC Liquid 1.00 >100 7 800 Yesand dispersant package

4896 Nonionic wetter SC Liquid 1.04 >100 9 1400 Yesand dispersant package

8

9

Ethoxylated Tristrylphenol Derivatives (TSP)

Appearance Density Viscosity EPATERSPERSE® @ @ 25°C, Flash Point, Pour @ 25°C, 40 CFR180Dispersants Description Uses 25°C g/ml °C, PMCC Point, °C cP Listing

2201 Phosphate, free acid SC, SE Viscous 1.13 >150 8 5800 Yesliquid

2202 Phosphate SC, SE Viscous 1.14 >150 10 >15,000 Notriethanolamine (TEA) salt liquid

2203 Phosphate TEA SC, SE Liquid 1.10 >90 -7 2500 Nosalt in glycol

2208 Phosphate TEA SC, SE Liquid 1.15 110 <-10 610 Nosalt in glycol solvent

2218 Sulphate SC, SE Viscous 1.17 >150 16 >20,000 Yesammonium salt liquid

2219 Sulphate SC, SE Liquid 1.10 >150 <-12 600 Yesammonium salt in glycol

2222 Phosphate SC, SE Liquid 1.05 >110 <0 <400 Yespotassium salt in glycol

Polymerics

Appearance Density Viscosity EPATERSPERSE® @ @ 25°C, Flash Point, Pour @ 25°C, 40 CFR180Dispersants Description Uses 25°C g/ml °C, PMCC Point, °C cP Listing

2500 Acrylic graft SC, SE Liquid 1.07 >100 <0 200 Yesco-polymer surfactant

2510 Polycondensed fatty SC, SE Paste 0.94 >100 45 N/A Yesacid/alkylene oxide adduct

2520 Modified polyester SC, SE Viscous 1.00 >75 >21 5000 Yescondensate Liquid

2700 Polymeric anionic WG, SC Powder 0.3* N/A N/A N/A Yessurfactant

2735 Polymeric anionic SC, WG Liquid 1.17 >100 <0 1200 Yessurfactant

4890 Polymeric amine condensate OD Liquid 0.85 75 <-5 400 No

*Bulk Density

PRODUCT DESCRIPTION These products can contain any or all types of surfactants or blends. Anionic, nonionic,

cationic and amphoteric surfactants are present in this product family. Blends of the

surfactants may contain solubilizers and solvents to aid in handling these materials.

USE and APPLICATION These products are used as wetting agents or built-in adjuvants in agricultural

formulations. They can be used in soluble liquid (SL), suspension concentrate (SC),

soluble powder (SP), soluble granule (SG), water dispersible granule (WG), and

wettable powder (WP) formulations.

BENEFITS • Improved efficacy of SL formulations

• Ease of addition of powders in SC formulation manufacture

• Improved dispersion of WG formulations

40 CFR EXEMPTIONS Includes 180.910, 920, 960

TERWET® Wetting Agents and Adjuvants

Wetting Agents and Adjuvants

Appearance Density Viscosity EPATERWET® @ @ 25°C, Flash Point, Pour @ 25°C, 40 CFR180

Surfactants Description Uses 25°C g/ml °C, PMCC Point, °C cP Listing

107 Anionic/nonionic Sticky Viscous 1.07 >100 11 7000 Yessurfactant blend paraquat liquid

220 Ethoxylated tallow Glyphosate Liquid 1.05 >149 <0 250 Yesamine formulations

245 Alcohol alkoxylate Wetting Liquid 1.00 >170 <0 900 Yesagent

436 Formulated nonionic Glyphosate, low Liquid 1.14 >100 <0 1100 Yessurfactant blend aquatic toxicity

1004 Anionic wetting WG, WP, SC Powder 0.4* N/A N/A N/A Yesagent formulations

1007 Anionic wetting WG, WP, SC Powder 0.4* N/A N/A N/A Yesagent formulations

1010 Anionic wetting WG, WP, SC Liquid 0.5* N/A N/A N/A Yesagent formulations

1108 Anionic/nonionic Wetting Liquid 1.05 >100 <0 100 Yessurfactant blend agent

1109 Nonionic surfactant Wetting Liquid 1.00 >149 <0 50 Yesblend agent

1118 Alcohol Wetting Liquid 0.99 >100 6 106 Yesethoxylate agent

10

11

Wetting Agents and Adjuvants

Appearance Density Viscosity EPATERWET® @ @ 25°C, Flash Point, Pour @ 25°C, 40 CFR180

Surfactants Description Uses 25°C g/ml °C, PMCC Point, °C cP Listing

1170 Ethylene diamine Glyphosate, Liquid 1.09 >149 <0 560 Noalkoxylate low toxicity

1211 Formulated nonionic Glyphosate, Liquid 1.10 >150 -18 28 Yessurfactant blend low toxicity

1215 Formulated nonionic Glyphosate, Liquid 1.14 >100 <0 535 Nosurfactant blend low aquatic tox.

1216 Formulated nonionic Glyphosate, Liquid 1.15 >149 -18 148 Yessurfactant blend low toxicity

1221 Alkyl Diamine Glyphosate, Paste 1.02 >150 37 N/A YesAlkoxylate SG

1227 Dialkylsulphosuccinate SC wetter Liquid 1.09 100 <-10 300 Yesin glycol solvent

1248 Formulated nonionic Glyphosate, Paste 1.05 >100 32 N/A Yessurfactant blend SG

1250 Formulated nonionic High strength Viscous 1.10 >100 <4 3500 Yessurfactant blend glyphosate liquid

1251 Ethoxylated tallow Glyphosate, Liquid 1.02 >150 <0 50 Yesamine adjuvant

1255 Ethoxylated tallow Glyphosate, Liquid 0.98 >150 1 3.5 Yesamine adjuvant

1300 Polyalkylene glycol Broadacre Liquid 1.10 171 <0 75 Yessoil wetter

3001 C8/10 alkyl Adjuvant Viscous 1.15 >100 -9 2500 Yespolyglucoside liquid

3750 Formulated ethoxylated Glyphosate, Liquid 1.05 >137 <0 250 Yestallow amine blend adjuvant

3780 Formulated ethoxylated Glyphosate, Liquid 1.05 >137 <0 250 Yestallow amine blend adjuvant

3784 Ethoxylated tallow Glyphosate, Liquid 1.03 >160 0 180 Yesamine adjuvant

3788 Ethoxylated tallow Glyphosate, Liquid 1.15 >100 <-20 450 Yesamine blend adjuvant

7010 Decyl alcohol Wetting Liquid 0.96 135 -3 30 Yesethoxylate agent

* Bulk Density

PRODUCT DESCRIPTION These products are defined by their function and are mainly used outside of the

formulated product. Most are added to the spray tank in the field. Members of this

group are added to the spray tank to boost functionality of the pest control product. All

classes of surfactants may be used in this product group. Definitions for these

functions can be found in ASTM Standard E 1519, Terminology Relating to Agricultural

Tank Mix Adjuvants. These products promote activity in the spray tank as wetting and

compatibility agents.

USE AND APPLICATION Listed below are some of the common functions:

• Wetting agents

• Compatibility agents

• Spreader/stickers

• Crop oil emulsifiers/modified vegetable oil emulsifiers

• Drift control products

40 CFR EXEMPTIONS These products are currently not regulated by the U.S. EPA but the components commonly

used in these products may meet a variety of 180.900 series exemptions from tolerance.

TERMIX® Tank Mix Adjuvants

Wetting Agents

Appearance DensityTERMIX® @ @ 25°C Flash Point, Pour Point, Viscosity pH Drave’sAdjuvants 25°C g/ml PMCC, °C °C @ 25°C 1% Aq Wetting

5017 Liquid 1.00 146 -12 120 7 7 seconds

5210 Liquid 1.09 164 -12 323 6 3.4 seconds

5212 Liquid 1.08 174 -8 349 6 3.9 seconds

5225 Liquid 1.05 138 <-17.5 155 5 15 seconds

Crop Oil Emulsifiers

Appearance DensityTERMIX® @ 25°C, Flash Point, Pour Point, Viscosity pH Adjuvants 25°C g/ml PMCC, °C °C @ 25°C 1% Aq

5300 Liquid 0.98 138 -17.8 120 4-7

5347 Liquid 0.99 138 -17.8 290 4-7

12

Compatibility Agents

Appearance DensityTERMIX® @ @25°C, Flash Point, Pour Point, Viscosity pH Adjuvants Uses 25°C g/ml PMCC, °C °C @ 25°C 1% Aq

1190 Buffer / compatibilizer Liquid 1.13 115 <-15 500 1-3

5270 Compatibilizer for Liquid 1.14 112 -12 830 2-3drift control agents

5484 Compatibilizer, Liquid 1.17 >280 -14 112 5-7tank cleanser

5856 Oil compatibilizer Liquid 1.06 240 -7 236 6

13

Spreader / Sticker

Appearance Density EPATERMIX® @ @ 25°C Flash Point, Pour Point, Viscosity pH 40 CFR180Adjuvants 25°C g/ml PMCC, °C °C @ 20°C 1% Aq Listing

5910 Liquid 0.99 99 -28 207 6-8 Yes

Defoamer

Appearance Bulk Density, EPATERMIX® @ @ 25°C pH 40 CFR180Adjuvants Description 25°C g/ml 1% Aq Listing

WG Defoamer Blend Powder 0.4 4-5 Yes

TERMUL® Emulsifiers

PRODUCT DESCRIPTION These products are anionic and nonionic surfactants. Primarily used in blends with each

other, they provide the primary emulsifier for emulsifiable concentrates, concentrated

emulsions, microemulsions and suspoemulsion formulations. In some cases individual

anionic or nonionic surfactants may be used.

USE AND APPLICATION These surfactants can be used in emulsifiable concentrates (EC), suspoemulsions (SE),

emulsions in water (EW), and microemulsions (ME).

40 CFR EXEMPTIONS Most are exempt under 180.900 series.

Nonylphenol Alkoxylate

Appearance Density EPATERMUL® @ @ 25°C Flash Point, Pour Point 40 CFR180

Emulsifiers Use 25ºC g/ml PMCC, °C °C HLB Listing

200 EC, EW, SC Solid 1.03 >150 30 16.1 Yes

5370 EW, EC Liquid 1.06 275 23 14.5 Yes

5600 EW, EC Liquid 1.07 280 20 18.0 Yes

7220 EW, EC Liquid 1.05 270 <0 12.3 Yes

Ethoxylated Castor Oil

Appearance Density EPATERMUL® @ @ 25°C Flash Point, Pour Point 40 CFR180

Emulsifiers Use 25°C g/ml PMCC, °C °C HLB Moles EO Listing

1283 EC, EW, SE Liquid 1.06 >240 11 11.7 30 Yes

1284 EC, EW, SE, ME Paste 1.05 >150 20 12.6 36 Yes

1285 EC, EW, SE, ME Paste 1.05 >150 36 14.4 54 Yes

2507 EC, EW, SE Liquid 1.05 >150 16 12.0 32 Yes

3512 EC, EW Liquid 1.01 >150 <-10 7.3 12 Yes

3532 EC, EW Liquid 1.01 >150 11 12.0 32 Yes

3540 EC, EW Paste 1.05 >150 28 13.0 40 Yes

14

Alcohol Alkoxylate

Appearance Density EPATERMUL® @ @ 25°C Flash Point, Pour Point 40 CFR180

Emulsifiers Use 25ºC g/ml PMCC, °C °C HLB Listing

203 EC, EW, SC Solid 1.04* >149 33 17.5 Yes

5429 EC, EW, SC Solid 1.04* 230 37 14.5 Yes

5500 EC, EW Liquid 1.05 210 20 14.5 Yes

7240 EC, EW Liquid 0.98 >149 5 12.2 Yes

* at 38ºC

Matched Pairs

Appearance Density EPATERMUL® @ @ 25°C Flash Point, Pour Point 40 CFR180

Emulsifiers Use 25ºC g/ml PMCC, °C °C HLB Listing

3403 EC Liquid 1.01 25 <0 13.9 No

3404 EC Liquid 1.03 25 <-10 12.2 No

3409 EC Liquid 0.99 20 11 14.7 Yes

15

TERMUL® Emulsifiers continued

16

Tristyrylphenol

Appearance Density EPATERMUL® @ @ 25°C Flash point, Pour Point 40 CFR180

Emulsifiers Use 25°C g/ml PMCC, °C °C HLB Moles EO Listing

3115 EC, EW, SC, SE Liquid 1.09 >188 -25 13.5 N/A Yes

3130 EC, EW, SC, SE Liquid 1.10 >100 <0 10.5 10 Yes

3140 EC, EW, SC, SE Liquid 1.12 >150 12 12.4 14 Yes

3150 EC, EW, SC, SE Liquid 1.10 >150 17 12.5 16 Yes

3162 EC, EW, SC, SE Paste N/A >150 30 13.5 20 Yes

3170 EC, EW, SC, SE Solid N/A >150 35 14.5 25 Yes

3180 EC, EW, SC, SE Solid N/A >150 39 15.0 29 Yes

3190 EC, EW, SC, SE Solid N/A >150 35 15.6 35 Yes

3194 EC, EW, SC, SE Solid N/A >150 45 16.2 40 Yes

3195 EC, EW Solid N/A >150 54 17.0 54 Yes

3196 EC, EW Powder N/A >150 58 17.3 60 Yes

Formulated Emulsifier Anionic/Nonionic Blends

Appearance Density EPATERMUL® @ @ 25°C Flash point, Pour Point 40 CFR180

Emulsifiers Use 25°C g/ml PMCC, °C °C HLB Listing

3640 EC Liquid 0.99 67 <0 13 Yes

5030 EW Paste 1.03 59 23 13.6 Yes

5123 EC, EW Liquid 1.02 >100 18 13.8 Yes

5390 EC Viscous liquid 1.00 87 20 14 Yes

7011 EC Liquid 1.04 33 4 12.5 Yes

7250 EC Liquid 1.04 35 <0 11.9 Yes

17

Specialty Anionic Emulsifiers

Appearance Density EPATERMUL® @ @ 25°C Flash Point, Pour Point 40 CFR180

Emulsifiers Description Use 25ºC g/ml PMCC, °C °C HLB Listing

217 Anionic emulsifier EC Liquid 1.03 32 <-5 N/A Yes

3665 Dialkylsulphosuccinate EC, OD Liquid 1.01 43 <-50 N/A Yesin aromatic solvent

5243 Alkyletherphosphate EC Liquid 1.03 116 13 14 Yesblend

3230 Catanionic EC, EW Liquid 1.05 >100 -8 N/A Yes

PRODUCT DESCRIPTION The JEFFSOL® AG 1500 series of agricultural solvents are pure forms of alkylene

carbonates or various blends of the propylene and butylene forms. Other solvent

chemistries are also available including esters, hydrocarbons and amides.

USE and APPLICATION The JEFFSOL® AG products are excellent solvents for many organic and inorganic

materials. Additional uses include veterinary, wood preservation and viscosity reducers.

• Solvent/Co-solvent in emulsifiable concentrate (EC) formulations

• Solvent/Co-solvent in microemulsifiable concentrate formulations

• Solvent/Co-solvent in emulsion in water (EW) formulations

• Formulation component for tank-mix adjuvancy

BENEFITS • Excellent solvency properties

• High boiling point

• Low toxicity

• High flash point

• Low odor

• Readily biodegradable

• Non VOC according to Directive 1999/13/EC

• Evaporation rate, 25°C (n-BuAc = 1.00) is <0.005

40 CFR EXEMPTIONS 180.950 1,3-Dioxolan-2-one, 4-methyl-; JEFFSOL® AG 1555 propylene carbonate.

JEFFSOL® AG Solvents

18

19

JEFFSOL® AG 1500 – Carbonate Solvents

Density Viscosity EPAJEFFSOL® @ 25°C Flash Point, @ 25°C, Freeze/Melt Boiling Point, Relative % Water % Solvent 40 CFR180Solvents g/ml PMCC, °C cP Point, °C °C, initial Polarity into Solvent into Water Listing

AG 1555 1.20 135 2.1 <-48 242 High 8.1 25.4 Yes

AG 1581 1.13 108 2.1 <-10 189 High 50.0 50.0 Yes

Butylene 1.14 121 3.2 <-48 244 Low 3.1 7.2 NoCarbonate

Glycerine 1.39 >200 4.4 -60 118 High ∞ ∞ NoCarbonate

JEFFSOL® Solvents

Density Viscosity EPAJEFFSOL® @ 25°C Flash Point, @ 25°C, Freeze/Melt Boiling Point, % Water % Solvent 40CFR180Solvents Type g/ml PMCC, °C cP Point, °C °C, initial into Solvent into Water Listing

AG 1710 Fatty acid 1.09 121 2.8 <-48 244 5.3 3.1 Nodi-ester

AG 1715 Fatty acid ester 0.92 >200 9.5 <-20 165 <1.0 <1.0 No

AG 1723 Aromatic 0.87 177 14.4 -5 345 <1.0 <1.0 Nohydrocarbon

AG 1730 Alkyl morpholine 0.97 138 10.7 -29 295 9 <1.0 Yesamide

AG 1740 Alkyl 0.88 118 11 -21 250 <50 <1.0 Yesdimethylamide

AG 1741 Alkyl 0.87 120 11 -6 290 <50 <1.0 Yesdimethylamide

American HeadquartersHuntsman Performance Products10003 Woodloch Forest DriveThe Woodlands, Texas, USA 77380Tel: +1 281 719 6000Fax: +1 281 719 6055

Asia Pacific HeadquartersHuntsman Performance Products 150 Beach RoadGateway West #37-00Singapore 189720Tel: +65 6 297 3363Fax: +65 6 296 3368

European HeadquartersHuntsman Performance ProductsEverslaan 45B-3078 Everberg BelgiumTel: +32 2 758 9211Fax: +32 2 758 9112

AustraliaHuntsman Performance Products61 Market Road, BrooklynVictoria, Australia 3012Tel: +61 3 9316 3646Fax: +61 3 9316 3647E-mail: [email protected]

BrazilHuntsman Performance ProductsAv Professor Vicente Rao, 9004706-900 Sao Paulo, BrazilTel: +55 11 5532 4412Fax: +55 11 5532 7307

ChinaHuntsman Performance Products49F Maxdo Centre8 Xingyi RoadShanghai 200336 ChinaTel: +86 21 2325 7888 Fax: +86 21 2325 7908

FranceHuntsman Performance ProductsBoite Postale 19F-55300 St MihielHan-sur-Meuse, Meuse, FranceTel: +33 3 2991 7300Fax: +33 3 2991 7399

GermanyHuntsman Performance ProductsZweigniederlassung HamburgBaumwall 520459 Hamburg, GermanyTel: +49 4037 6700 Fax: +49 4037 670 150

IndiaHuntsman International (India) PVT. LTD. Research & Application House,E-Wing, Saki Village, Chandivali Farm Road, Andheri(East), Mumbai - 400072IndiaTel: +91 22 4050 6301 Fax: : +91 22 4050 6300

ItalyHuntsman Performance ProductsVia Cavour 5046043 Castiglione delle Stiviere, ItalyTel: +390 376 6371Fax: +390 376 637 323

Japan Huntsman Performance Products KIBC North Bldg. 3F, 5-5-2Minatojima Minamimachi, Chuo-kuKobe 650-0047Japan Tel: +81 78 304 3924 Fax: +81 78 304 3980

MalaysiaHuntsman Performance ProductsFifth floor, Wisma Avon13A Jalan 21946100 Petaling JayaSelangor Darul Ehsan, MalaysiaTel: +60 3 7958 7133Fax: +60 3 7958 1677

MexicoHuntsman de Mexico, SA de CVMontesito 38Piso 21 Ofna. 38, Col. Napoles03810 Mexico D.F.Tel: +52 55 9000 2911Fax: +52 55 9000 2010

New ZealandHuntsman Chemical Company75 France St, Eden TerraceAuckland 1010New ZealandTel: +64 9 275 8902Fax: +64 9 275 8943

SpainHuntsman Performance ProductsPoligono Zona Franca SectorCalle 43, No. 1008040 Barcelona. SpainTel: +34 93 336 9700Fax: +34 93 336 3610

TaiwanHuntsman Performance Products No. 19, Industrial Third Road, Kuan Yin, Taoyuan County, Taiwan ROC Tel: +886 3 483 5243 Fax: +886 3 483 6412

NANSA®, TERSPERSE®, TERWET®,TERMIX®, TERMUL® and JEFFSOL® areregistered trademarks of Huntsman Corporationor an affiliate thereof in one or more, but not all,countries.

Copyright © 2010 Huntsman Corporation or anaffiliate thereof. All rights reserved.

Warning: Products manufactured from thesechemicals may present a fire hazard ifimproperly used. Each manufacturer and userof such products should determine whetherthere are potential hazards in a specificapplication and take the necessary precautions.

Huntsman Corporation warrants only that itsproducts meet the specifications stated herein (ifany). Typical properties, where stated, are to beconsidered as representative of currentproduction and should not be treated asspecifications. While all the informationpresented in this document is believed to bereliable and to represent the best available dataon these products, HUNTSMAN MAKES NOWARRANTY OR GUARANTEE OF ANY KIND,EXPRESS OR IMPLIED, INCLUDING BUT NOTLIMITED TO ANY WARRANTY OFMERCHANTABILITY OR FITNESS FOR APARTICULAR PURPOSE, NON-INFRINGEMENTOF ANY INTELLECTUAL PROPERTY RIGHT OFANY THIRD PARTY, OR WARRANTIES AS TOQUALITY OR CORRESPONDENCE WITHPRIOR DESCRIPTION OR SAMPLE, AND ANYUSER OF PRODUCTS DESCRIBED HEREINSHOULD CONDUCT A SUFFICIENTINVESTIGATION TO ESTABLISH THESUITABILITY OF ANY PRODUCT FOR ITSINTENDED USE AND ASSUMES ALL RISKAND LIABILITY WHATSOEVER RESULTINGFROM THE USE OF SUCH PRODUCT,WHETHER USED SINGLY OR INCOMBINATION WITH OTHER SUBSTANCES.Product(s) described in this publication may behazardous and/or toxic and require specialprecautions in handling. For all product(s)described herein, the user should obtain fromHuntsman detailed information onhazardousness and/or toxicity, together withproper shipping, handling, and storageprocedures, and should comply with allapplicable safety and environmental standards.The behaviour, hazardousness and/or toxicity ofthe product(s) referred to in this publication inmanufacturing processes and their suitability inany given end-use environment are dependentupon various conditions such as chemicalcompatibility, temperature, and other variables,which may not be known to Huntsman. It is thesole responsibility of the user of such product(s)to evaluate the manufacturing circumstancesand the final product(s) under actual end-userequirements and to adequately advise andwarn future purchasers and users thereof.

www.huntsman.com/agrochemicals

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NSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM ERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMRSPERSE® TERSPERSE® TERSPERSE® TERSPERSE® TERSPERSE®

® TERWET® TERWET® TERWET® TERWET® TERWET® TERWET® TTERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX®

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® TERWET® TERWET® TERWET® TERWET® TERWET® TERWET® TTERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX®

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® TERWET® TERWET® TERWET® TERWET® TERWET® TERWET® TTERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX®

JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® NSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM ERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMRSPERSE® TERSPERSE® TERSPERSE® TERSPERSE® TERSPERSE®

® TERWET® TERWET® TERWET® TERWET® TERWET® TERWET® TTERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX®

JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® ERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMRSPERSE® TERSPERSE® TERSPERSE® TERSPERSE® TERSPERSE®

® TERWET® TERWET® TERWET® TERWET® TERWET® TERWET® TTERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX®

JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® NSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM ERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMRSPERSE® TERSPERSE® TERSPERSE® TERSPERSE® TERSPERSE®

® TERWET® TERWET® TERWET® TERWET® TERWET® TERWET® TTERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX® TERMIX®

JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® AG JEFFSOL® NSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM NANSA® EVM ERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERMUL® TERM

10003 Woodloch Forest DriveThe Woodlands, Texas 77380 USATel: +1 281 719 6000

Huntsman Advanced Technology Center 8600 Gosling Rd. The Woodlands, Texas 77381 USA Tel: +1 281 719 7400

NYSE: HUN

www.huntsman.com/agrochemicals