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Hydrogen RHIA & NAGHydrogen: The smallest molecule, the biggest impact!7 October, 2021
Rick Claus – Sales Engineer Hydrogen
T: +31(0) 6 4887 05 28
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Introduction to Linde
→ The leading industrial gases and
engineering company
→ Formed in 2018 with the merger of
Linde AG and Praxair, Inc – two world-
class companies with nearly 140
years of shared history and successful
achievements
→ Proven critical project execution
knowledge in diverse geographies
→ Best-in-Class Safety Performance
OneLinde
Uniting with a shared Vision,
Mission and Strategic Direction,
and demonstrating our Values
and Behaviors in everything we
do
2 million+customersEstablishing a more diverse and
balanced portfolio
100+countriesEnabling strong, complementary positions in
all key geographies and end markets
$27 billionReported sales in 2020With 7% represented by hydrogen
~80,000employeesAchieving our full potential, individually
and collectively
6,500+active patent assets
worldwideLeading with innovative products, solutions
and technologies
→ Linde Gas Benelux is headquartered in
Schiedam
→ ~220 employees
→ Production facilities and offices in
Ijmuiden, Rotterdam Botlek ,
Eindhoven, Hedel, Dieren,
Grimbergen and Namen
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Hydrogen colors
H2 production from SMR
with emitted CO2
Grey Hydrogen
CO2
Grey H2 production with
CO2 removal, storage or
reuse
Blue Hydrogen
CO2
Co
lor/
Pro
cess
End
use
s
Brown Hydrogen Green Hydrogen
Electrolysis with renewable
energies without CO2
emissions
H2 production from coal
with emitted CO2
Existing
applicationsAll applications All applications
New
applications
in transition
Chemistry & Energy
CO2
Clean Hydrogen
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The hydrogen molecule
= Atomic number 1
= Atomic mass of 1.00797
= Great abundance in the universe
= Nuclear fusion in the sun
= Not a natural element on earth
= Produced via chemical processes
Number, data, facts
Properties of hydrogen
– 1 m³ of gaseous hydrogen (GH2) at 15 ° C, 1.013 bar (a) = 0.09 kg
– 1 m³ of gaseous hydrogen (GH2) at 15 ° C, 50 bar (a) = 4.1 kg
– 1 m³ of gaseous hydrogen (GH2) at 15 ° C, 200 bar (a) = 15.0 kg
– 1 m³ liquid hydrogen (LH2) at -253 ° C, 1.013 bar (a) = 70.8 kg
– 1 kg hydrogen corresponds to 33.33 kWh calorific value (= 3.3 l heating oil, 2.4 kg methane)
10/12/2021 Footer
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Supply concept gaseous hydrogen trailer
Main facts
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Compression /
Trailer filling
Trailer
TransportStorage in
pressure vessel
➢ Power consumption
1-3 kWh/kg
➢ Fully automatic filling
process including
analysis
➢ ISO 14687 and
NEN-EN 17124
➢ Pressure 200-500 bar
➢ Load ca. 300-1100 kg
hydrogen
➢ High transport costs
because of rel. low
load.
➢ Technically relatively
simple
➢ Pressure 50-200 bar;
Density 4-15 kg/m3
➢ Length / height up to
approx. 20 m
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Supply concept gaseous hydrogen trailer
GH2 Trailer
7
0
100
200
300
400
500
0 200 400 600 800 1.000 1.200
bar
kg
8
Supply concept GH2 trailer
On-site storage
Trailer change Mid. pressure tank High pressure tank
Exchange of empty trailers for full trailers
• Fast delivery• High supply pressures• Requires a lot of space• Extensive planning required
45 bar container (vertical / horizontal)• Small footprint (vertical)• Filling volume up to approx. 440 kg /
tank (115 m³ volume)• Height up to 21 m• Only when low pressure is required up
to approx. 20 bar
200 bar container (vertical / horizontal)• Small footprint, low height (approx.
11 m)• Filling volume up to approx. 300 kg /
tank (22 m³ volume)• High supply pressures
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Supply concept Liquid hydrogen trailer
Main facts
9
Liquefaction /
Trailer filling
LH2 Trailer
Transport
Cryogenic insulated tank
➢ Liquefaction at -253 °C
➢ Energy consumption
7-10 kWh / kg, including
nitrogen precooling
➢ Load approx. 3000-
3500 kg hydrogen
➢ Max. Pressure of 9
bar
➢ Proven technology
➢ Compact
(70 kg/m3)
LH2
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Supply concept Liquid hydrogen trailer
LH2 trailer / storage on site
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40 ft – ~ 3000 kg load 44 ft – ~ 3500 kg load Up to 13 m in height, up
to ~ 5000 kg content
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The Linde product portfolio
Biomethane Reforming Leuna
• Green hydrogen from biomethane
via steam reformer
• CO2 reduction min. 50% *
2022: PEM electrolysis in Leuna
• 24 MW (4,800 Nm³) capacity
• World's largest PEM electrolysis plant
• CO2 reduction at least 75% *
GH2
GH2
GH2
LH2
Energiepark Mainz
− Green hydrogen via PEM electrolysis
(4 MW)
− CO2 reduction at least 75% *
−
Audi e-gas plant Werlte
• Pilot project power-to-gas with
alkaline electrolysis (6 MW)
• Linde has an acceptance agreement
• CO2 reduction at least 75% *
* inkl. Konditionierung und Transport
Chempark Dormagen
• 340 bar gaseous hydrogen
• TÜV sud certified green hydrogen
GH2
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ITM Power - relationship at a glance
First success story in green H2 partnership
▪ Construction of the worlds largest PEM electrolyzer 24mW at Linde’s industrial park at Leuna Chemical Complex, Germany
▪ Operational in 2022
▪ Supplying green gaseous and liquified H2, avoiding up to 40.000 MT CO2e per year
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Norled H2 ferry project, REN
MF HYDRA – World’s first LH2 driven ferry
MF HYDRA:• Length 82m
• Capacity 80 cars and 299 passengers
• LH2-tank capacity 4 tons
• PEM FC 400 kW
• Battery 1,5 MWh
L .Vartia
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Norled H2 ferry project, REN
MF HYDRA - Linde Engineering’s solution
• Linde Engineering to carry out the: development, Engineering,
Manufacturing, Installation and commissioning of Liquid
Hydrogen Fuel System
• Linde Engineering Scope of delivery :
I. LH2 Tanks
II. Water Bath Vaporizer
III. Piping
IV. Bunkering System
• Experience with DNV requirements and approval process
L .Vartia
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Linde Hydrogen Fueltech for hydrogen mobility
Decarbonize transportation.
Supply for H2 busses/trucks Supply for H2 forklift trucksSupply for H2 cars Supply for H2 trains
Compression(ionic compressor)
Pumping(cryo-pump)
Stand-alone dispenser(350/700 bar)
Integrated dispenser(700 bar mobile fueling)
Service/Maintenance(smart operation)
Linde subsidiary (100%), supplier of hydrogen infrastructure solutions
reliable H2 supplies through state-of-the-art fueling station systems
✓ >200 fueling stations installed worldwide
✓ Supplier of the world’s biggest hydrogen bus depot in California
✓ Supplier of the world’s first H2
station for passenger trains✓ >1.5 million fuelings of cars,
buses & forklifts
Tokyo
16
About Linde Hydrogen FuelTech GmbH
Solutions and services to enable H2 mobility projects worldwide
About Linde Hydrogen FuelTech
Experience: +15 years of technology development
Products: H2-refueling systems (HRS) & services
Scope of work: Development of key components, process & system
design, manufacturing, installation & commissioning, after sales
services
Manufacturing Locations: Germany, Austria and China
7%
APAC
19%
74%EMEA
USA >200
Number of Linde HRS installed
Best in class - Out of experience!
✓ Highest efficiency ~1,3 kWh/kg 1
✓ Highest reliability > 97% 2
✓ Highest safety Zero incidents at any HRS in operation
1 based on Ionic Compressor platform versions2 based on all Ionic Compressor based HRS commissioned in the last 24 months
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Making our world more productive
Enabling the energy transition
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Back-up slides
1910/12/2021 Footer
Safety precoutions
– PGS-35
– Hydrogen installations for delivering hydrogen to vehicles and equipment
– ATEX zone 0, 1 or 2
– Spark free tools
– Anti-static clothing
– Safety distances
– Flashback arrestor
Safety
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Linde’s capabilities today: experts in H2 production & handling technologies.
Well prepared – missing link closed for green H2 production.
ProductionDistribution & Storage End-useApplications
Industry
Feedstock
Transportation
Fuel
Power Generation
& Buffering
Industry Heat
SMR
Electrolysis
Combustion/heating
Compression
Purification
Recycling
LiquefactionGasification
Pipeline
Bulk Refuelling(De-) Hydrogenation
(Green) Power Procurement
‘Last Mile’ handling
Cavern
ΩCCUS Technologies
Processing ‘Last Mile’ distribution
Heating & Power
for Buildings
Processing
R CH2
21
ITM Power - relationship at a glance
Jointly getting ready for market ramp-up in green H2
▪ ITM Power specialise in the manufacture of integrated hydrogen energy systems
▪ Founded in June 2001
▪ ~180 FTEs
▪ Factory for 1,000 MW annual output, with first phase of 300 MW p.a. production started 2021
Linde’s role:
▪ 20% minority share
▪ 50/50 JV with ITM Power on market & project development, feasibility studies, proposals & sales, and project mgmt. coordination relating to EPC projects in market segments mobility, refinery, steel, chemistry and other Power-2-X, and preferred supplier for Linde Gas
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Infrastructure
Unrivalled H2 network: global reach, strong local presence
1600+ Liquid and Gaseous H2 trailersOperation of 150+ steam methane
reformers and PSAs
Largest H2 liquefaction capacity in the world
with 170 tons/day
From production Through processing To storage and distribution
80+ electrolyzers installed
Joint Venture with ITM Power providing PEM
electrolysis plant solutions
Vast experience in H2 compression 40+
installed 1000+ km H2 pipeline
World leader in cryogenics. 20,000+ cryogenic tanks supplied*
Solutions for on-site production
* more than 20,000 cryogenic tanks for liquefied gases supplied since 1960
200+ Liquid and Gaseous H2 refueling stations
23
Gearing up for clean hydrogen
How Linde supports customers and industry partners
Hydrogen production with electrolysis
Global green gas solutions at industrial scale using ITM
Power’s modular PEM electrolysis technology and Linde’s
world class EPC expertise and technologies.
Renewable energy storage
Experienced partner in the development of energy parks.
Operating the first commercial high-purity H2 cavern for
over a decade.
Hydrogen Refueling Stations
Highly efficient and fast fueling concepts for cars, trucks,
trains, forklifts and buses. Worldwide leader in installed H2
refueling stations.
Carbon capture, utilization and storage
Linde offers proven CCUS technologies and is part of
numerous R&D alliances to leverage government funding.
Industry feedstock
Trusted supplier of heavy industries, such as steel,
chemicals and refining, Linde is well equipped to support
the transition to a low carbon production.
Infrastructure
Over 1000 km of H2 pipeline. Decades of experience in
operating high-purity, high-pressure H2 pipelines. Largest
global hydrogen liquefaction capacity and distribution fleet of
liquid and gaseous trailers.
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Innovative business model.
Build-own-operate model for hydrogen production and filling or refueling station.
Supply contract
Linde Gas Customer
Planned compensation
(various models)
State-of-the-art production and
compaction technology
Investment, assembly
& Commissioning
Operation, service, maintenance
& Insurance
Back-up supply
& Logistics
Continuous &
safe H2 supply
Hydrogen plants:Production, Tailer filling & Refueling station
Supply connection (electricity, water, etc.)