"'.,.----~..-~_..-...--------,="".,.•.,,--.,.---------,_ ...---------------.~::,I • ,

F YP.S~ P.ot,anvBv••,,! latus,

(to be implemented with effect. from J,-,:n~,1992)

OJURSES:-

P~r I: BO,I.t.

Paper II' BO.l.2.-

r...o"",r Cryptogams and Higher Cryptog-&ll-~Lowel' Cryptogams (Fil'st T"mn)Higher Crypt:>g?.ms (2.ocond Term)

Marpl)oloi!;y <:pf Angiosperms (furternal and,Inwinal), Gymn.cos~rm.sand 'faxonOOlY ofAngiosperm;; _

Morphology of AngioS}.-.erms(E:tternal and Internal) (First Term)GYWlOOpe= and Taxonomy ofAngiosperms (Second Terro)

P~r 111:90.1.3.- Pr~cticalsbas~i on Theory Paper-I& P~r-IIi,e. 00.1.1 * fXJ.1.2.

I'II

SI'I17192/

II,

",

•

,

I

[N.B. : i)

ii)

Local ~ursiOll5 should ffi arranged.

hoperly prep;u:ed ro:i.niDum flve i,erbariurnSooet5 from the ~ ITisited slr,,-'.ld ,-,esubmitted along with =cursion report]

•

--------------- ~----g.._~-~~-----.-'~•

•F.Y.B.Sc.

Paper-- I ,ffi-1.1;;Lo"",r Cryptogam.;; and High",r Crypt?gaffiS

•~,

(Viruses, fu,~teria, Algae, Fungi and Lkl1ens)(Total Beriods=36)

A~ Yiruses- (3)A-1. IntJ:oduction-

i) Natureii) Ultrast=ct>.1I"liii) Reprodu,~tioniv) Economic iInportance r;f Virus",:>

(inducling at least two m.s...ase3 each of plant/animal(~J

B-- BaG!eria- (5)B-1. Introduction (G8neral characters)

i) Gl'ilSsification of bacteria on the basis of sl1ap;lii) Nutrition

iii) fulpr'xh~tioniv) Economicill"(lOrtanceof bacteria (P"sit.ive and Negative)

c- Algae-C-l. Introduction:

i) General characters of Alga.;.ii ) Habit and babitat

iii) Structure of thallusiv) Reprcductionv) EconomiciJllP)rt.ance (in brief)

''I

C-2. Classification of algae with r-=ason.s a=rding to G.M.Smithupm cla:;"es giving at least two examples of eacb class.

(2)

C-3. Stud,)'of Life Cycle ofa) Nastoeb) SargassUl1l

(3)

''I

I

~,.

(4)

(3)«)

B"lIpgj -Introductirn :i) Gen",ral charscters of Fungi

til Habit a.'ld habitatiii) Structureiv) Nutritionv) Reproduction

vi) Economic:i.mport;anceof fungi

I;-1;-1.

D-3. Study cf Lif~ Cycle of:i) Rhi::oo;usii) Agaricus

D-2_ Classification of fungi with ~asons according to G.M.Smithupto d~5 giving at least two examples of each .:l3.Ss.

(2)

E- Lichens: (2)

E-1. GIDeral account with reference to-i) O::currence

ii) Sw~ct'-'re of thallus (extemal and internal)iii) TYPes of lichensiv) Econcmtc~rtarIc-= of licr,..-IlS.

Snm9192/

2

-.~.--.~-----.",.-=-----_._---_...---~ '-."......••.•

• •

A

HWHER CB'fPlQ.;AMS

(Bryophyte" and pteridophytes)(To~-al Periods=36)

B:rygphvtes-

1\-1- Introd"Ctioo:

i) -Distinguishingfeatures of the group (6)ii) Alternation of generations.iii) CUtlin",Classification of BryC'Phytes "ith reasOll3

according to G.M.Sndthupm Classes """ntioning at leasttW0 examples of each class.

1\-2- StlID)rof Life Cy.:,le of:

a)0)With

kiccli;!F\mariareference

(8)(6)

')ii)... ,lU.Jiv)v)

vi)vii)viii)

ix}

C!assiflcatl011 ••ith reason~Habit bIld habitatE:xVernal wld Internal structure of garrewphy'tesVegetative reproduction.Se",,-al reproiuction and structure of s<>-X orgar.:sfertilizationStnlcb..\r09 of T"":tul.'3sp:>re>plJy'WStructur", and germination of sp::>resAlternation of g>'!nera"tions(fuvelorroent not expected)

B: Pterl donbyj:es:

B-i. Introductjpn: (6)

i) Distingui$hing fM-t:I.1r'= .., Qf the group.ii) Alkrnatic,n of generati,..ns.iii) Ultime classifkation of Pteriodophytes with reasons

aoooJ:ding to G.M.Smith upto classes !!>"ntioning' at loaasttwo examples f= each class.

B-2. :>tl.Jt1y.ci Li.fe. Cycle ci;..

a)b)

~lagin811aEquj 5""tnm

(8)(6)

i)ii)iii)iv)v)

v'l":iijviii)

;x)")

ti)ti'l

with reL8rt--llce t,,) -Cla5sificati~n with rea5')fiZHabit and babitatExternaland internal strl.lcturesof s~h,yt.e.Veg<;>tativ"" reproduction.A sexual rBProductionPosition and structure of strobilus and sp:>rangiumC~rm1nationo:f sporesStructure of l!l3.turegam;lwpbytePosition and structure of sex organsF<.rtil1zationStruet.ur€, of tll3.ture '*lbryoAlternation of generations.(devel~prent not expeGted)

Sr1nl8192/

3

-~------------------~-_.-.---PEpsr-II EO.

(External and Internal) ;

First Term' - 11orph~logyof Angiosperrrs (Exte:rnal and Internal)(TotQl perlods= 36)

A. Morpoology(External)-

A.I) Introduction, distinguishing f"a:UlNg of the (2)group, Alternation of generations.

A.2) Root "Y5tem-~finiti,:>n, Types of r':JOt-PrillW'l',Seoondazy & Tertiary;

-Ac!v,,"ntitiO:15roots- fibrcus. foliar.-Modifjcati.l:llii - a) Modified tap ~=-t.:;;-fusiform,napiform, CQnieal & tuberous.

b) f1.:xlifiedbranch I'Co)t- pneumatophon.

oj Modified advO'ntitiO"ll! r')(;Its - tubeJ:Ql.1.S,fa?ci'~<lted,nodulose,fIDniliform, annulated,prop or stilt'rcots,climbing, sucking or haustoria,rEspiratory,.,piph\rtic,assimilatpryr:>ow. (3)

A.S) St.em:- D;finitioll,

a) Form>of stern-i) EI..;,ct,or strong ilj weakstems _Pl"Ostr"te, dicumbent, dif:fu3e, croMping, twining. climbing

a) Undergrc..md lJ)illfication-rhi<:OI1B, tuber, 1:ulb,oonn.b) Sub-~rial !OCOdification-runn",r, swlun.

offset. sucker.oj Aerialmodificat~an-StBmbendell, (3)

tbo=, phylloclade, cladode, oolbils.

A.4) Leaf-

,,) I:Bfiniti~.n & part., of leaf. stiIU18.Sand kindsof "Ul'Ules, apex, ll>il"gin, surface, sha.re &venati.on of leaf, si!l1Pleand COlIlP=lIdleaves.

b) t1odification of leaves- leaf -v.mdril, leaf spines,scale leaves, phyllcd"" pitch=r and bladd"'r.

c) PJ-wllo-taxy-altarnate, <:>prosite & whorled. (3)

SI1M9192;

,

"'•..~-_._.----====~-----------=---~~

,(2)

A.S) Flower _ Do=finition, parts, flower as a nxxlifiea shOOt,Calyx 3Ild 36stivation; CYralla "t}"P'3Sandaestivation; Androecium, cohesion <II1.da~sion;Gynoecium _ poslti<;'n of ovan" plaeentati<:>lls (6)

A.'1) Fruit - [",Hnit.ion, olas3ifi,~ati~'nanddis]?"rsI'lof (3)~ and fruits.

B. Morphology(Int.emal)

B.l. Tissue _ Definition, classification of rneristematic' tissueon ~ l;ia.gisof pcJsitionand origin. (3)

a} Simpl",Tissu,,"s- Pal.,"""cl1yna,CollenC'1"qroa,Scle~.b) ComPloeoxtissues - Xylemand Phloemc) Types of vasculOU"bmdJ"''' . (~)

B.3) PriIrary Structure .,.f Dicowledcnousa)b)0)

B.4) Pr~ry Strucb..:lreof Monocotyledonous

a) Stemb) R<xotc} lAaf

SnI1l9192/

(3)

(3)

~----Sec>:>ndTerm: ~P='11llS and Taxonorw ot Angiosperms.

(Total periods = 36)

A- Gymnosp?:rnIS:

A-I Intrcduction

i) Distinguizhing featuras of the gl:'JUFil) Alternation of genp.ratioo.iii) o.,t line c1assificaticn-a=ciJ.ng to Chaml:Yerlain"s

Clc.sBlfLntion upt...:,class",,, wi."h reasons giving atleast, t<:oex..~les in ",a.~hcl",-".~. (5)

A-2 Study of Life cYcle of L.'ypaswith ",.,fer»nc.=to :

"ii)iii)Iv)

.,."vii)

viii)il)

81assification with rea5crl.5!Jabit and h",bitatExternal lOC>rpl1i)logy-root,stern and leaf.Anato::fmr of -a) NomElroot & ooralldd rootb) radris0) leafletV,,~tive reprcduetl=Mc~rphvl"gy of male <X>w.'& mal", g1llllE!TDphytel1orphology of f&nal~ reprQduC'tive 00dy (lI1"..ga;;p:,roph,yll)and female garretop~.Ovule' and erribry0Pcllination and fertili;;ation.(DeveloI'ID'?ntnot exp:.cted) (10)Seed st.lUCture and germination.(Developrent not expected)

B- Anriosoouns:

aJ IRfinition and SOOP3of 1'axancrrw.b) Binomial 1K'rrenclatllre,cJ CUtHnedm:,ification of B-onthamand Hocker upto

zeries (5)

B-3. Herbariumit's techniques and -scope.

B-~_

""Iiii)iv).)vel

Study of farnilie~ with reference to ;Cla%ification with reasvns(kneral lOC>rpholog:l.oalcr.aractersDistinguishing charactersFloral fornv.laFloral diagramEconcrnic imp:>rtance1: A.'lonacea~ 2: PapilionacBa'" (!,,,,-bacca,,,)3: RubiaGea 4: eonv"lvulaceae5: AcanthaC"'..-ae 6: tWctaginaceae7: Euprorbiaceae 6: l\m'll'yllidaceae ( 14)

<2)

StmB192/

'.

,

---------~".~~-----------------------"-~,,;;;,

Papgr III. 00.1.3. Pra.~tical Cow's';' [fused on 'l'h3ory P'3.p<?r-I(Bo.l.1.) ~d Raper-II tBo.l.2.)}

(Total Pr~tlcals-24JFIRST 'l'W1

[lower Czyptogam.~, I1orpholol1Yc-f ~-i05P9rms (Ext.ernal andInt-.lrnal) ]

P.S.= Permanent Slide,1. a)

i)H)

iii)

C)

Viruses: Observation of following any two vinlS-affected plants (D=ID:mstration)YellO'wvein disease of Lady-s Fing.;,r/paI>-;yaLittle leaf of Bri.nja1.Witches bro-:4l1

Bact.€'ria: Gramstaining of bacteria.

2- Algae:

3. S-U,WQt SargJlSS'lID

i) T.S.Gfaxis

P.S { i) T.8 of secondaLylateral (leaf){ ii) T.8 -llEle conceptacle.{ iii) T.S -female conceptacle.

4. Flmgj'Study of Rhizopus

i) Observation of Mycelium, Stolen & S];Orangiophore.

P.S. 1) Sexual stages- (zygosp:>re).

5. Study of Agaricus

i) Morphology of Spo~-ocarp11) T.5.of gills.P.S. i)ii)

L.S.of Sporocarp.T.8. of gills.

6. Lichens: [Dem:m.stration]

Formsof lichens - a) Crusto.se.b) Folioseoj Fruticose

Snm9191/

P,B. i)ii)

T.S.of thallusV.S.of ~thecium

--------

..,.

Morphology of :ro':It. and it's ro:difications (as pel' syl1aclls)

8. Mm'Poologyof s'tern and it'", nxxiifications (as per s-.l1la"tus)

9. Morphology <;,fleaf and it 3 nr..<:lificationg (as po;orsyl1a1::us)

10. Study c-f Inflorescence and its types including special,=-,.

i) GalYxii) Corollaiii) Andrt:.eciumiv) Q:Imoecium

•

P.S. i)ii)

Placentatioo.Ae"tivation,

12. Study of t.1s.•.•ues (~tratiOllJP.S. i) Meri~tem (L.S.)

H) Xylem and phloem (1'.8.& L.s.)Hi) Types of vascular bmdles.

13. Ana"tc>lw' Primary stl."UCture ofa) STem~ SunflOl'o"3r'" Maizeb) Root - Sl.mflOW9I"&,' Maize

P,8. i) Leaf- Sunflooier & Maize (T.S.)

Brypphvtes:

14. Study of R1c.~j5i

i)ti)

P.S.{l}{iii

Mountir.g of rhizoids and scales.T.:'>. of thallus1'.5. of thallus sOO;;ing antheridia and archegoniaT.S.of tJlallus s~ing Sp:lrophyte.

15 Study of Funaria

i)ii)

P.S. {[(

EM17192/

Mounting of rhizoidsT.E.of stemi) V.S.of antheridial head.ii) V.S.of archegonial headiii) V.S.of capsule.

,••

Study of 5e1agjnella

P.S.i)i)iii)

T.5. of s'ten> (il) fuLlnting of 3;>:>r>:sT.5.of ~~t (ii) T.8. of rhizor-horeV.S. of strobi.lus.

17_ Study of EaUiS"'tJ'ID

"iilP.S. {

[[

T.5.of stem passing through ,th? inwrnooe.Mounting of Sp:.rangiophore and Spores.i) T.5.of l'x>t.ii) T ,S. ",f rhizomeiii) V.S. of Strobilus.

1.8,19. GymnO$perms'Study of Cycas

P.S.

i)iiliii)

iv)[[

T.5. of rachisT.3. of pinnaStLucture of male cone, microsporcphyll,microsporanium and mounting of pollen grains.Ob5erv"tion of IIEgasporophy11.i) T,8.ofcoral,loidroot11) V,S. of ovule.

2\),21,22 & 23.

Studyof fartlilies (as ~r syllal:us)

24. Herbarium -techniques.

-~------XX---------XX----------xx

SMM7192

9

•

1

:~ iii I +",-11 rt 1 T

5k",lctor,

4) Th:::ro viII b,: two papers. P"psr ] and Paf"Jur II. For c;8chpapJr thsro will b~ thr~~ l~ctur~s per woek.S;ccti'ln-I- Physi cal Ch.:mistr-y •••. 2 lol;tun;s per wc::k.50ction-II-InoI'9"l'1ic Chemistry,., 1 lcctur~ [J"r )Jc,ck.

Papcr-II- S",cti'Jn I -Org8nic Chomistry _, 2 lcctur':'s ;:Jcr lJ~~,k.

Papc:r-II- Scction-II_Inorg8nic Chamistry.1 l"ctur-, P'H wrrk.

[nch suction wi!l cr)nsist of tuio parts.

Part_ A-1st LJI'm portion: Part_B ; lInd torm porticn.

• 00 m",rks •

20 markS.

-----.-CO markS.

.. '" marks •

• • 20 markS •

Total

2. Pilpcr-II, Part-A Sccti:m I Organic Chomistry.

S_l;ti8n_I1 In'JrC). Ch"rniatry.

TermEnd~~~natio~ :-1. papElr-I, P.']rt-K S,.ction I Phy.Ch<Jmistry •• _

S~cti(ln II Inarg.Chamistl'Y ..

T otJ.l ••. 60 mOlrks.

Annual [xomj n~ti~n : Part- Ii., Part_ B =

1. PaflCr-I, Part- II &. -B S"c. I Ph\.Chcm. 20 + 31! = 545~c.1I Inorg,Chofll. 10 + 16= 26

Tata}. 80 marks,

8 S8c_I Urg.ChcJm"Part-

"Soc. II Inng.Chc'll. 111

A + Part-B =

+ 34 = 54+16 •• 26

Total 80 marks,

•.~~---------------------•

•

(2 )

F.Y.B.5c. PHYSICAL CHEMISTRY 'pA.!:'-S~:::-I (SClction-I):t --_._"'~- ..-'-_...

PkRT- 8, "(Sc'Co[1'd Twrm)

4 • .Q1.5.TB.I.8.U1:1D!:c JAW :-.-- '

'.•

Stt1tcmcmt and oX:J1""Btion "f vcrnst'n distributionlaw(thGrmQdynamic dcriv<ltion is not cxpoctLcI), <lp,Jlicability

Dfld limitatiDns of distribution law, modification ofdistribution law with rufJrcncu to assGciation and dissocia-tion of soIutD, "pplicc.ticns of distribuLion law a"d thoory

of oxtraction. Lo:;ctUJ;OS (5)

Rof-I :_ Chapter 8, Pag~s 298-302. "Rof_II:_ ChaptJr 18, page'5 531-5]8', 542-552.

5. Trsnsf.:ll'Gnco and transf8;onco numbJr". Hittorf's rulCl andd2tJrmj nation of tramfcr~ncc numb-Jrs by Hittorf 's m~thod

using unattackablc olQctrndcs.Elllctrolytic conductanc(;, dEtermination of conduc-

tancc, variation of c",nducts-nco with con<;ortrntions, E"uiva-lQnt conductElnciJS 3t infi,nita dil,~tion, Ka!'llrausch's law endits appliciJtiorl5, Effoct of ether factors on conduetan<;C',

Appli<;<ltion of <;ondu<;tflncfCll1()asur~m:mts: (n)solubility ofaifficultly s'Jlublcr s<llts (b)OlJt.Jrmination of degroe ofiOflisati'Jn (c) COl1ductomotric titraticns and thGiradv(!ntag"s.

flef-I:_ ChaptlH 18_405_411,

R~f-II-Chartor 24- 704-710.Chaptar-25- 716-722,

locturBs-(8)

414-424, 431-434.

725-733 •

•6. MathEtmatic~l Pr"pArations

(i) Log,nithm - rules Of lagariths (Without prooF)charactsristics a1d mentissa, nega'tivEl logarithms,

"application to f'lH. <;alculations and sOlvin':J numbsricalproblams involving change of bosc of lngarithm.

RaF. 3 chapter 2 pages 7-15

(ji) G1''l",hical rcpresentation_ Graph papers. co-ordinates

of", point._ equation of a st.line. slope~ and intercal"ts.Charact«risti-cs coFso.line. Ploting of graphs based onEtxperifllBntal- data of chamical origin. ..••

ReF.3 .• Ch"'pt",r 'I POgES 23-30.

;ii i) OiFf'rontial calculus - rules of difFBrenti'ltion •

.... ~ ...

\.

NORTH I'lAHAR"SHTR" UldVER5ITY, J"LGADr,.

F,Y.B.Sc. : £!i.Y1!.f:'iL Ci-'.E:f\'lLS1.~1; Pal~()r_I (ScctLJn_l)

(First TLr"')

(8 )L~ctur~s_

1. ~TO~1.L~TB.L1_CL~:_Ruthc;.rf'Jrd's x- ,neticl,;; seatLring Clx,'''rimoJnt,

Ruth:nford'E '-It:Jfilic mad~l and its dr~,-'bClcks, I'loeclay'e w:rrk

and its imp.-ntanc" ( no numbcrical fJr'Jl:lem8), Disc'~v=ry Jf

ncutrc'n, Lin" Sp~lctra of at::Hns, [alm~'r 's f'lrrnuliJ, Hydr'Jg.::nSpLlctrum. Ritl'! c8mbinstion principle,

Bohr's at,.'mic mod~l. Doriv"ti')n of riJdius :Jf or.it,DOl'ivatinn of Olcrgy of '?n ",1, ctron, Odgin of hydrogonspcctrum and cXrJlainCltion, failLJros ,:.f fohr'" mOdEl,

Sommorficld's rnodificllti:m af Bohr's m0d~l, quantum numbers,

LJ;Jto at~mie 'lumbar 1'1.a~sigrling quantLJmnumbors to ~!~.ctl'i:"'SRef.1 Ch::lp.14_ P'lg(Js- 6DA-610, lj_b~L

Ref.2 Ch,~p.1 - Pc,g£'s- 9-14,1~_32,50_S72. D:i£.E_ASIqlJ_~.5THTE :_

G"s' cuustant R and its valLJJs in diff8rcnt units,kin~tic thc'ory of gas~s, IksLJm)ticns r)f kin,;tie theory,RI'l5 v;:;locity, O,.rivati[:;n of kirlr.tic g2S aqLJatiOrl, Du-duction

of BoyloJ's Charl.;s, Avog.adr'.)'s, Dalton's an"; Gl'ah;Jm's l;JWfl'.~m kin~tic gas "qLJatior'" v-'locitics of gets mc.l~culos• •

(only dcfinatiuns 3nd intur-rll<ltionShip), Th3 kineticcn(;rgy of translalicn, Andic8bility of th~_ ido<:ll gas l<:lws,com~'1'8ssibili.tl' fclet::ll'. vandcr- l.'cH'l's ,ou,~tHJn of statv,critical ilh~num,-na in I qc:ids, The P-V-T rd"tians of gasEs

and liquids, Th3 ~~inci;11> of continuity af :o:;"t s,A,'pliC'ati,'n of I/"ndcr vaal's e:;uaticn to iscth~rmal" ofCO2, DQtJrmjnation of vand~l' waal's constants, law Dfcorl'osponding S~a.t3S.

Lcctur(Js_12

Ref. 1:_ Cha"Llr 1, Pagos 10-12. 15-31. 47-55.

Aof. 2:- Chapt"r 2, PagJs 301..,302, 306-317, 322_33~.

ADSORPTION :_-- ..-Adsor;,tiCln of gas"s by snlids, TypC'a of adsc..rpticn,

HdS'lrptio;' isothC'l'ms, fr\lLJndlich's ()quntiCJn, Longmui-T"Sndsorption is'Jth,,rm and its dcril/atiJn, Hf'i'licatiQns ofadsorptiCJrt with rcfLr~r;c" to chromatagra;Jhy.

L"ctuT'ol'_ 4R~f. 1:_ Chn;:Jt~r 20, pag\l5 810-817.Ref. 2:- Ch"ph.l' 23, P,1g0S fl85-69S.

cunt •• 2.,

,

,

,

•,

(3 )

(witnour proof), parti81 diffGrentL'ltior: (LJithnur prODf)

pEJrt<ll"ing to algebra, Exponential and logarithmic fUflctionsGx;]mflles rcl'ltcch to chcmi stry.

REef.3 ChaptCir 7, pag~'s 72-828 pag8~ 63_90.

iV) Int"'gral calculus - Rulas of intE;gNtion ( lJithour prooF)

portaining to algatra. and dxponenti"l function. IntegNtion batw~~r 1bGtween limits. Exa:npl"s ,81at8d to chGmistry.

R8f.3 Chapter - 11 pagas _ 115 _ 125.

'0,) SignifiCclnlc of" - appli~atio" to tho corlpound interest l;JW to

physical clismistry. ExponentiLll 8.quations. examples I'81nte:d tD

ehEmi stry.

Rsf. :1 Chapter - 12 pag"" 132 -140LectuNs - (10)

£1.81..1 Principles of physical chemistry by S.H. Maron and prut

IVth Edition.11 Essentials of physical chemistry by 8.S. Bahl Clnd G.O. Tuli.jlI MClthEfr'Cltical preparation of physical ch~mistry

by c". Dfmi",ls.r',agrow Hill book eompany.

.•

,NORTH MAHAR••5HYR" U~IVER5IfYJ JnLG"ON.

,.Y.B.Sc.CHEI"lISTRY 5YLLA['Uo..- _. - ----, ..._---- ._-._.,' ..~_..

•

INORc:,rdC CHDUSTRY

SECT IO~I _ 1I-- _ _.-PAP[R _ rE.ar,t ...; A

(I) Volumetric ~nalysis : (3i1-21 Voluf'l"tric I'.nalYBisI-:Z~' Cla~<;ific"tion of rn.,cti:H1s in volur.letric Analysis.

1-23 EquivalEnt ,,-'right,;, ~;Drr:lal solutions.

1-24 IldvQnhlg8~ of th8 use of the equivalent syst<?m for tho,

prcparEltion of standnrd solutions.

1_25 Prcpar"tiun of standard 8:;1utior1s

1-25 Primary sb-,ndard substcmcGs

RcF.-1 pages 3B to 50.

(2) Techniquo Llf l/oIu,n"tric (titrimetric An:Jlyeis)II_17 Unit of volun,'"

11_19 Volumetric "Il""!'"tus11-20 Volumetric n"SKs11-21 PipettesI 1-22 Buret ts ~

11-25 Storage acid pr~s rvation of solutirns for VGlumootrjc

Analysj.s.

R"f.-1 p"'gflS 191 to 207.

(3 'I Experiment<:ll tG'chnjqUG InorgF.lnic An2.lY3is

II_1 BQlancI<. w3ights and weighting

11_2 DG'scription of typical P.nalytic<ll balance

Il_3 RGqlirIOfilents of govd balanc{]

11_5 Car,' and us"' of ba.lance

11-6 Methods of ~8ighing

11_7 Errors In ~8ighing

II-8 CalQbr<ltion of ~Dights

Ref. 1 pBgos 140 to 1Sg;' .'

olom'-'nts and

RGf._1 GJuantitativ"

: ,•.~;

(4) Sym..:Lr~

Inorganic P.nalys.io

by_ P.. I. Vogol (Third [dn)

Symc.l~ry 0pC:l'i!tiDns

the. Dry

Cotton.

of group

by F.P..

Conc""rts <:lnd Mod 1 fl'~ s 0 norganlc,Chc:mistryby Douglas and r1r:: Daricl>'ag,--s 476 to479

Ch'_mieal "ppli"'[ltiDn"

Rcf._ (2)

- -

--~-~,--

~ORTH f'lilH,1,Rn5HTRA UNIVF::RSlTY, JAlr;"ml.

T.'!,".8.,.5." •. C.h:.m.i.~.tn 5ylLeJlusHjORG.,NIC CHEI'l15fRY

I) 80ndinn H' m~l 1" "'u .,e" • s 'nc:! structuI'. (7)1) Att inm~"t "f st",bL cunfigur~.ticn.ii) Typ,,; of bond (,,) Ionic (b) Cov~l_ nt (c) Ccordin'lt

(eJ) m, t .11ie (only intruduction:md d"fin"ti':Jns.)

iii) V"l:nc~ bend th_nry.,,) H,itl~r london th;ory (.,ssumpti,n)b) I-'.uling sl~.t r t!l,~ory

c) Canc.,pt of "tot)lic orbit~l (lv~rl"p -end COrld fDrITI"ti"'n

Hybrirlj zatilln to

_"'pisin the shape,.

81gm" ',n,j pi b.'nds

Nun_pd"r and r'fJ] 61' c"val nt bonds

80nding in t h,. following molecuLes using pure. S & p

orhit",ls H2, F2, HF, 02 • N2

V) Hyb:rdi zotic:>n ;- (a) Need of c()nc. pt of

,,;.;p1,,1n the obse-I'V' d covalency and to

d)i v)

of S'JffiL moll",ulrs.(b) D. Fin(l\;ion of Hyt;,ridil"tiGn.

( )op,op', op] ,,"p2~ Shap' s of mol. luI s involving ~ ~ ~ ,u~ ,

, 2 3Dr S~~d, d SP orlJondin>.) and shap_ 5 uf

L FZ' SF:.>, CHIl, PCL5,

d2 • d3Sp3 hybrid orbitals,

th;: following mol ,cul:s

SF5'if7i ( (r:lCOl)a)-Z

Co_ordinatior<(,)Co_ordination comp"unds, N"m,f1' latur: rrJr

II VI) Ca..•.,,,dirlO'tion ch,r:1i!try :- Co_ordirlatior> ,numb,rs and

g.-om: tri s Tn'" 5 of ligands, I"or,](.risl!l ir>

Rrf.-1-H N " coneis, Inorganic ch_mistry-

by- J.D. L Thi rei (dn•

Pag. 5 24 " 31,49 to 5B,~£> -J, 61

2- , N: w guid " ('1od, rn Val"ncy The ory.

by - G. I • BrClwn Thrid Ed"

P"'9ClS 106 " 114,162 " 164. ,-I

'-1,-, -,' ocry cnttnn & lJilKingofl3- (j,sic norgsrnc ~ n•• ~~

(Third Editio,,)

P,;lJ~s- 125 tel 1384- Cone' pt "nd MOldIs of lnl,HI]8nic chemistry

by _ Donglrrs ;Ond DEmirl Third Edition 1976

Paq; f- 52 to 56

-._------~....--•• •

(First T:m)

compounds(12 L, ,,'tur .5)

1; Structur m d prop' rti:s of Orgar'licAtomic-'"rbitals (Ref. 1.5)

(1 .ctrDnic configurat,i"" "HOdpallli. Excilisionprincipl'. (Jicf~"1;'"1.6)Mel'eulor orbitals (fi'rf. 1- 1.7)CCl-v1l1 nt bond (Rof.1- 1.S)

Hybridizatic,,'1 lJith c'xampl,. s of M' than ,Ethan; ,Eht,n"nnd Ethyn. (R,-f. 1;-1.9,1.1n,1,11. R-'r.2:-3.3)Sond 1, ngth. ~o"d '::n, rgy. FDrld Ilngl- .(Rc:f .2.:-3.4,3.5)6:;nd Po1a,rity "nd PolElrity of mOlrcul,s.

R~f. 1:-1,15,1.16)

1.7 QU3.ntitfltiIJ an1l1ysis "f etbon; Hydrog!'l. Nitrugen,5ulphur,8nd H'Jl')g-n (r'lntion th, num,'S only f"r

different m..th;:d~ 'If _~timqti n) R;f.1:,..2.27,13.12.1.8 Prcbl--ms r lilted ts -mpiricnl, molecular and otructuJ;'iJl

f"Jr:nul<:>of Org:lni6 CD",pound~ (R f.1:-2.28,2.29)

• 1• 1

",1 .,

1 .4

"5

" • 6

2) N"~l ne12tur of Orgcnie Cor.'p"unds. (4 l~ctur s)2.1 Trivial Syst"",.

2.2 IUF'"C SY8t,-m (Scud nts ."nould only b,. "bl to Kncu

tho. fHWI. ,'nd !;tructuT,;l formula cf' Orgi'nic Campounds:_•.ilkDn's, klk:'ncs, Alkyn;s,iHKyl, H<:>lid,"". "lc.JhoJsAId, hydes, K,.tones, Acids, Est~r Etn,'rs J hmin s)Rrf.2:-1,2.2)

3}JydrtlGtll"oon... (8 llctUHS)3.1 Industri,~l S'Jure uf alkoln- -0. (R,.f.1-:1.13):3.2 Industrial >'ourc VS L<lbordt"r.y pI' pcr[]tion

(Ref. 1- 3.14, 3.1,,)3.3 flr.action of alK::lnrs (Rc:f.1_ 3.18)3.4 Alk~n.s Prop"rl!ltiCln .-md R.--ctions

(R,f. 1-7.11, A.1, 8.2)3.5 Alkyn,s Pr p.'r.,tion "rIC! R ,ctions.

(Rcf._ 1-11.6, 11.7)

•

"', r..wl' - -: ..,r• •

.

ORG,,(\! :r-c- ." ._--

4),

Synth sis "nd R,"ctiupa. (1D L-ctur, 5)

4.1 Alkyl h:::lid 5 (R--f.1"S,3'.5';7,5.i3)4.2 AlcClr\C'ls. (R f. 1-17.j,17.2,1?.3';17.R~18.2)4.3 illdrryd-s :::nd k ton 5 ( R f. 1-21.4,21.7)4.4 C"rboxylic "cid :!nd thrir d,-r,iv-tiv •

(R f. 1-23.6,23.9,24.6,24.7,24.'J,24.10,24.11,24,17,24.15, 0, 24.16)

4.5 ~min 5 ( (R-f.1.-2!.B,27.1)

5) ArDmQtic Compounds (6 L, ctur s)

5.1 StNctur of B nz n (~f. 1-13.2,13.3)5.2 Ri!,ctiDns of B nz n (8 f. 1-13.4)5.3 Nom ncl,~tur of b nz n derlvCltiv (R f. 1-13.11)

5.4 Ph nol-Pr- pQr~tiun "nd R ~ctilns .(R f;.1'.:'1£l'~5,2B.5)

6) Structur Qr>d

5.1 lnducti v5.2 Electr--,m

5.3 R- sone-nc,

R ;:lc:ti vi ty

Eff ct.ric Efr ct,Jf-f- o::t-

(8 L ctur 5)

•5.4 Hyp r conjug-~tion

5.5 TQut"m rismfi.5 Hydr g'.n bonding.5.7 El;cric uff ct.

(r-f.3 & 4- R 1 v nt "'9 5)

6 f.1:- Or-gonic

R," f.2 ,. Org-'nicR f.3 , OI'g 'ni C

R f.4 ,- " Gui d

Ch mistry by Morrison &S,"yd ( [ditiDn 5th)Ch mistry by Pin, N ndr"icksOn,cr~m 1nd'H,-,mn-,",-nd

Ch mistry by I.L.Fin''I' Vo.-I Edition.

book of reaction m cr.:'nism by p t T' 5yk s.

•

•

,

NORTH ~1AHnR,.,SHTRI\ UNIVeRSITY, JP,LGiiON.

I:L..f...:~c;'Chf~iJLtry_5Y.l~1.s~( INORG~t,'IC CHeMISTRY)

•( S~_CTIO~ - 11)

[l-ctr~nic configur"ti ,n ~f I-m rita _(i.) Kufb<::u Principl-

(ii) Hund's rul- of Maximum multiplicity(iii) Sh~V 6 of S, P, d 'Jrbit ...,ls

(3 )2) Long form of tl"l' P ri;)dic tc:bl Gnd ~,'OriQdic pr"p rti- ,,_

'i)' Gut linr of long form of p riodie t,Jbl.-.,.

ii) Cl~'ssifjc"ti-'n ,f '-I m-nts in t rms of S,P,d F bloCk

-Ie"ments. in'-rt g,~s ,1 m nts, r pr"s nt.'tiv" ,l-m,nts,tL'nsiti"n ,-L-mrnts ,::nd l.nWT tr'nsition l'm,-nts.

Iv) P riudic 1,:"" p riodvc in prop'rti s thI";)ughcut thr

p; ri,J'dic t~bl,- -'(only 'g' n r-'} tr, nds in rl1ch blOCkS ~r<'

~xpect8d. trend in "ny perticulftr group Dr any partieul'-I'

period is not 8Xp" ctod.

(a) Size of '1tom [lOci ions(b) Ioni ntion energy

(e) Electron offini ty(d) Electroneg.,tivity(E1) M"t~.llic chc:r,ccer

(F) Rsactivity.(0)

Ref. (1) ConciR~ In::lrg'1nic chemistry _ by J.D.Lee

Pnges - 92 to 103. P'"'ge No.1fi IIIrrJ Ed.(2) A new guide to Modern Vdancy Theory by-

by- G.I. Broun (Third Ed.)P:ge6 - 25 to 31.

93) Bnsie Inorg']nie chemistry by Cotton..,.bJilkinson

P"gc s 43 to 4fi

•

NORTH I'1"Hi\R,i~KTR" urnVERSITY. J ••LGnGN.

r..-:..1.J_,.5.e. Chemi..!try Syllsb.C's ..•..

( 1no1'g 'nie C"Bmis:'ry ) P,ut-8 (Second Torm)

1. III) Chemistry of I1ydrogen :- Position in the periodic L'ble,Isotopes of Hydrogen, Ortho "nd Pc:Jr- flyjrog"n;properties of !'lolecul,-r liydrogen;The bonding of Hydrogen Hydr"gen bond; Hydrisos.Acids cmd B"ses Arrhenius Bronsted "nd LEl.lil! theory

Ref: .•. 1) A new cnncisB In<Jrg.:Jnic Chemistry by J.D. Lea(Third Editiorl)

(P"985. 117-122)2) B"si" 1no1'g:1nic Chemistry by Cotton ,~nd lJilkineson(Third Edition) (P~ges.200-215) (191-92) (5) ~

-

2. Ill) 5-BloCk ElemlOlnts:-- ..."_ ...- ..-.", .- - _.-Alk"li-mst-ls ;- ElBctronic shUCtUI'8. Gener'.l prOpElrtiE'S;

Chsmics1 properties; sOllubility and HydNti~n 8'Jlutions

of met,'ls in liquid ammcni",; stability of oxy-s::llts;Hdides, sxtr"'ction of mst"ls; compounds with c!lrbon;Drg~nic compounds cOffi"l"'s. Anom,Jlous_ behaviourof lithium"nd its di"gonClI rslationship.

Alk,~lino Earth Mst~le;_ Elsctr"nic structure: Generalpropertiss Anomdous beh'lviourYof 8sryllinm' Solubility

"nd L"ttic" energy, Chemical prorerties,Qr9"nometc.llit:r::,m[JOundSj CDllp16X(lS; extNlcti:ln of met,~ls; DiffersncBbetwe ••n EO ,ryllium "nd other gr 'up Ii elements. (7)

Ref.-1- Concise Inrlrg~nic ch"mistry by J.D. Lee(Third Edition)

(r,lges 128 to 151)

2- 8~,sic Inorgc.nic chomistry by Cottan end

WilKinson (Third EditiCln) (p'ges 217 to 229)ReF.:_ 8Jsic Inor[j!Jnic chemistry by catt"n and Wilkinson

,(192 to 197)

•

-------------_.---------~-"" .

(0) Physico1 Expcrimcnts:_ (Any riv~)1) Determination of r101acul~r W"ight by victor Mayer's methDd.2) Determjnation of hset of neutralisation of Weak acid &

hence its heat of ionisation.3) Heat of so¥.ution of KN03/ NH4Cl

4) To study the adsorption Df acetic acid on 1lctiV<ltsd

charcoal and to verity langmLiri\ 8dsoTption isotherm,S) uetsrmination of dissociation constant of 8<;etic acid

by conductometric measuremEnts.6) Determination of equivalent weight of Mg/Ml by eudiometax.7) Parlition coefficient of bElflZoic acid between benzene

& Watsr.

OR12 in CCL4 and lJatElr.

(8) ORGANIC CHEMISTRY:_

1) Drgnnic estimations (Any Two)(a) Aniline (8) Phenol (C) Acetone

2) Determine Physic<Jl conSTants I'1P/HP of given compound.Det'-'rmine the type of orgnnie compounds (ACid,b2sc,noutral) IdGntification of groups such as • COOH._OH

(alcohol).-OH(Phenol)_COOR (G'ster), -1:~0, _CHO (aldshYde),Amines, -IIID2

At least nine organic compounds to be studied.

•

--

(C) INORGANICCHEI'115TRY.

1) Qualitative Analysis:_ Powders containing onG cationand ono qnion (eXCluding Phosphates ",nd boratos)Minimum 10 powders.

2) Volumetri'c Analysis

i) Preparation of st"-nderod Na2 C03 solution and st..lJn-d(lrisation of givgn Hcl solution.

ii) Prcporntion of standEred OXalic acid solution.standerisation of KMnC4solution "nd estimation oF'Iron.

iii) Preparation of standard K2 Cr207 solution. Stilnd er-isation of Na2 52 03' ond e9timotion of Copper iod omG_trically.

iv) PrGparGtion of standard Zn504

solution.

5tandarisation of [DTA. Totol hardness of Water.3) Gravametric Analysis:_

1) Use of balance. Dotermino the loss per gram ofNnHC03 ond henc~ perc-entDgo purity.

2) Determine loss po; gram nnd percQnt"gC' compo"-!.tion ofNn2C03 anll NnHCO:;in the mixture Na2C03 + NaHC0

3

:- Examination will be of aixSCHEMl FOR PRACTICtlL EXAMINIlTIDNhr.duration

The distribution of marks For various exporimantos will be as;~

1) Physical chemistry oxpcriment _ 3D2) Orgsnic oompound -10

3) Volumetric snslysis/Grav.;matric/orgenic estimation _ 254) Inorganic Qualitativa _ 155) eral - 10 ."6) Journel _ 10

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