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Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The friction does wo rk and increases the internal energy of the surface

Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

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Page 1: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Internal Energy

The energy associated with an object’s temperature is called its internal energy, Eint

In this example, the surface is the system

The friction does work and increases the internal energy of the surface

Page 2: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Conservative Forces The work done by a conservative force on a particle

moving between any two points is independent of the path taken by the particle

The work done by a conservative force on a particle moving through any closed path is zero A closed path is one in which the beginning and

ending points are the same Examples of conservative forces:

Gravity Spring force

We can associate a potential energy for a system with any conservative force acting between members of the system This can be done only for conservative forces In general: WC = - DU

Page 3: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Nonconservative Forces

The work done against friction is greater along the brown path than along the blue path

Because the work done depends on the path, friction is a nonconservative force

A nonconservative force does not satisfy the conditions of conservative forces

Nonconservative forces acting in a system cause a change in the mechanical energy of the system

Page 4: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Conservative Forces and Potential Energy

Define a potential energy function, U, such that the work done by a conservative force equals the decrease in the potential energy of the system

The work done by such a force, F, is

DU is negative when F and x are in the same direction

f

i

x

C xxW F dx U

Page 5: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

The conservative force is related to the potential energy function through

The x component of a conservative force acting on an object within a system equals the negative of the potential energy of the system with respect to x Can be extended to three dimensions

Look at the case of a deformed spring

This is Hooke’s Law and confirms the equation for U U is an important function because a conservative force

can be derived from it

x

dUF

dx

21

2s

s

dU dF kx kx

dx dx

Page 6: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Energy Diagrams and Equilibrium

Motion in a system can be observed in terms of a graph of its position and energy

In a spring-mass system example, the block oscillates between the turning points, x = ±xmax

The block will always accelerate back toward x = 0

Page 7: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Energy Diagrams and Stable Equilibrium

The x = 0 position is one of stable equilibrium

Configurations of stable equilibrium correspond to those for which U(x) is a minimum

x = xmax and x = -xmax are called the turning points

Page 8: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Energy Diagrams and Unstable Equilibrium

Fx = 0 at x = 0, so the particle is in equilibrium

For any other value of x, the particle moves away from the equilibrium position

This is an example of unstable equilibrium

Configurations of unstable equilibrium correspond to those for which U(x) is a maximum

Page 9: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Neutral Equilibrium Neutral equilibrium occurs in a configuration when U

is constant over some region A small displacement from a position in this region will

produce neither restoring nor disrupting forces

Page 10: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

There is potential energy associated with the force between two neutral atoms in a molecule which can be modeled by the Lennard-Jones function

12 6

( ) 4U xx x

Potential Energy in Molecules

x

REPULSIVE ATTRACTIVE

Page 11: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Find the minimum of the function (take the derivative and set it equal to 0) to find the separation for stable equilibrium

The graph of the Lennard-Jones function shows the most likely separation between the atoms in the molecule (at minimum energy)

Repulsive at small separations since electron shells overlap

Attractive at large separations because of dipole interactions (even for neutral atoms)

Page 12: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Energy Review

Kinetic Energy Associated with movement of members of a

system Potential Energy

Determined by the configuration of the system Gravitational and Elastic

Internal Energy Related to the temperature of the system

Page 13: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Types of Systems

Nonisolated systems Energy can cross the system boundary in a

variety of ways Total energy of the system changes

Isolated systems Energy does not cross the boundary of the

system Total energy of the system is constant

Page 14: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Ways to Transfer Energy Into or Out of A System

Work – transfers by applying a force and causing a displacement of the point of application of the force

Mechanical Waves – allow a disturbance to propagate through a medium

Heat – is driven by a temperature difference between two regions in space

Matter Transfer – matter physically crosses the boundary of the system, carrying energy with it

Electrical Transmission – transfer is by electric current

Electromagnetic Radiation – energy is transferred by electromagnetic waves

Page 15: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Energy is conserved This means that energy cannot be created nor destroyed If the total amount of energy in a system changes, it can

only be due to the fact that energy has crossed the boundary of the system by some method of energy transfer Mathematically, DEsystem = ST

Esystem is the total energy of the system T is the energy transferred across the system

boundary Established symbols: Twork = W and Theat = Q Others just use subscripts

The Work-Kinetic Energy theorem is a special case of Conservation of Energy The full expansion of the above equation gives D K

+ D U + DEint = W + Q + TMW + TMT + TET + TER

Page 16: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Isolated System For an isolated system, DEmech = 0

Remember Emech = K + U This is conservation of energy for an isolated system with

no nonconservative forces acting If nonconservative forces are acting, some energy is

transformed into internal energy Conservation of Energy becomes DEsystem = 0

Esystem is all kinetic, potential, and internal energies This is the most general statement of the isolated system

model The changes in energy can be written out and rearranged Kf + Uf = Ki + Ui

Remember, this applies only to a system in which conservative forces act

Page 17: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The
Page 18: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Power Power is the time rate of energy transfer The instantaneous power is defined as

Using work as the energy transfer method, this can also be written as

dE

dt

avg

W

t

lim0t

W dW d

t dt dt

rF F v

The instantaneous power is the limiting value of the average power as Dt approaches zero

The power is valid for any means of energy transfer

Page 19: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Instantaneous Power and Average Power

lim0t

W dW d

t dt dt

rF F v

Page 20: Internal Energy The energy associated with an object’s temperature is called its internal energy, E int In this example, the surface is the system The

Units of Power

The SI unit of power is called the watt 1 watt = 1 joule / second = 1 kg . m2 / s2

A unit of power in the US Customary system is horsepower 1 hp = 746 W

Units of power can also be used to express units of work or energy 1 kWh = (1000 W)(3600 s) = 3.6 x106 J