Introduction to Process Safety

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    1. INTRODUCTION TO PROCESS SAFETY

    CH4101 Chemical, Biological & Plant Safety

    Dr. Foo Swee Cheng

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    ENGINEERING ETHNICS

    1. Defend the truth

    2. Expose questionable practice that will lead to unsafe product/ process

    Royal Academy of Engineering:http://raeng.org.uk/societygov/engineeringethics/principles.htm

    Accuracy and rigour

    Honesty and integrity

    Respect for life, law and public good

    Responsible leadership: listening and informing

    Discussion: Nicoll High collapse, 20 April 2004 Singapore Nicoll 40 years: http://www.nce.co.uk/features/nce-40-years/no11-nicoll-highway-collapse/8629881.article

    Insurance: http://news.asiaone.com/News/The+Straits+Times/Story/A1Story20080420-60781.html

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    http://raeng.org.uk/societygov/engineeringethics/principles.htmhttp://www.nce.co.uk/features/nce-40-years/no11-nicoll-highway-collapse/8629881.articlehttp://news.asiaone.com/News/The+Straits+Times/Story/A1Story20080420-60781.htmlhttp://news.asiaone.com/News/The+Straits+Times/Story/A1Story20080420-60781.htmlhttp://www.nce.co.uk/features/nce-40-years/no11-nicoll-highway-collapse/8629881.articlehttp://raeng.org.uk/societygov/engineeringethics/principles.htm
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    SAFETY TERMS: DEFINITIONS

    Hazard: Potential source of harm/loss/damage

    Risk: Probability of a certain harm/loss/damage

    Individual Risk (IR): IR = (Frequency) x (Severity)

    Societal Risk (SR): SR = (IR) x (population) = FN

    Incident: The result of uncontrolled hazard(s)

    Accident: An incident which results in consequent loss

    Accident Scenario: A sequence of events which propagatesthe accident

    Accident outcome: The consequences of an accident

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    SHE (Safety, Health & Environment) HAZARDS

    Chemical hazards: Toxicity of artificial/ natural materials

    Physical hazards: Flammability of artificial/ natural materials

    Fire/ Thermal radiation: Heat

    Explosion: Overpressure generated by fire

    Biological: Living organisms e.g. bacteria, viruses, fungi

    Contaminants: Healthcare/ food/ animal husbandry

    Process materials: Vaccine production

    Effects: Communicable or non-communicable diseases

    Can reproduce itself in host Ergonomic: work load/ tools/ organization on human

    Force/ energy/ repetitiveness/ anthropometrics/ time

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    SAFETY AND HEALTH

    Safety: Accidental/ abnormal release of HAZARDS

    Acute/ high level release: large quantity in a short time

    High consequence: Acute damage to property/ population/environment

    Health: Operational/ Fugitive release of HAZARDS

    Chronic/ low level emissions: Small quantity over a long time

    Low consequence: Chronic damage to sensitive population/

    environment in continuous/ long-term exposure

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    PROCESS HAZARDS AND EFFECTS Fire: Thermal effects

    Explosion: Over-pressure effects

    Toxicity: Toxic/ Health effects

    Biological effects: Two unique features; e.g. ebola virus

    Communicable (person-person transmission)

    Reproduce itself in host (make use of host resources)

    AccidentType

    Probability ofoccurrence

    Potential forFatalities

    Potential forEconomic Loss

    Fire High Low Intermediate

    Explosion Intermediate Intermediate High

    Toxic Low High Low

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    COMPARING PROCESS AND PERSONAL SAFETY

    Equal risk curves: R = C1F1= C2F2

    Process Safety

    Hazard: Highly hazardous (GHS cat 1 & 2); large quantity

    Severity: High; Death/ severe disable

    Hazard zone: Large; zone often extends to offsite

    Frequency: Low; High reliability system; less no. facilities

    WSH personal safety

    Hazard: Less hazardous; Wide range; less quantity

    Severity: Low; Wide rangeHazard zone: Small; zone confined to location of use

    Frequency: High; System less reliable; more no. facilities

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    Risk curve

    C

    F

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    PROCESS SAFETY vs PERSONAL SAFETY

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    OSH/ WSHManagement

    Risk Curve

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    PROCESS SAFETY MANAGEMENT (1)Reduce Loss Event Frequency

    Inherently safer design: moderate/ simplify Process Reliability: Reliability engineering

    Component reliability & System structure

    Process Integrity: Maintenance

    Prevent system failure: Reliability maintenance/ growth program

    Operation reliability

    Competency of operators

    Technical support for operators

    Human factor engineering/ Safety culture

    Incident management

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    PROCESS SAFETY MANAGEMENT (2)Reduce Loss Event Consequence

    Inherently safer design: minimize/ substitute/

    Minimize: Reduce the quantity of hazard in loss event

    Amount of stock in individual storing units

    Amount of material in individual process units

    Substitute: Replace a hazardous material with less hazardous one

    Direct materials (incorporated into products): Use less hazardousroute

    Less hazardous/ amount of intermediates/ by-products/ wastes

    Indirect materials not incorporated into products: Use lesshazardous materials

    Solvents/ Catalysts/ Energy/ heating media

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    PROCESS SAFETY STRATEGY: DEFENSE IN DEPTH

    NORMAL OPERATIONALCONTROL SYSTEM

    ALARM SYSTEM

    SAFETY INTERLOCK/

    EMERGENCY SHUTDOWNSYSTEM

    RELIEF SYSTEM

    Seriousness

    of event

    Divert material safely

    Stop the operation or part of

    operation

    Bring unusual situation to theattention of a plant operator

    Closed-loop control to

    maintain process withinacceptable operating region F

    ourindependentprotection

    layers(IPL

    )

    CHEMICAL PLANT PROCESS

    Protection

    Systems

    ControlSyste

    ms

    BPCS

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    WSH MANAGEMENT

    Workplace pollution prevention

    Prevention system reliability

    Protection system reliability

    Operator reliability

    Workers exposure control/ monitor

    Manage exposure dose: level x time

    Biological/ medical control/ monitor

    Early detection excessive absorption

    Manage sensitive workers

    Hierarchy of Control

    Elimination

    Substitution

    Engineering control

    Administrative control

    Administrative control

    Personal protection

    Early detection/ treatment

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    RISK ACCEPTANCE CONCEPTS

    Except in extraordinarycircumstances

    Risk reduction impracticalor cost disproportionateto gain

    Cost of reduction exceedthe improvement

    To ensure r isk remainsat this level

    Unacceptable region

    No exposure allowed

    ALARP region

    Risk is tolerated only

    if a benefit is desired

    ALARP required

    Broadly acceptable region

    ALARP not required

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    EXAMPLE: AN RISK ACCEPTANCE CRITERIA

    Public Risk Criteria Occupational Risk

    Unacceptable Risk

    10-3Unacceptable Risk

    Tolerable if emergencyprocedures and protectiveequipment are in place

    10-4Acceptable for manufacturing,warehouses, open spaces,parkland, golf courses, etc.

    Tolerable if emergencyprocedures are in place

    10-5Acceptable for commercialoffices, low density residential

    Negligible risk

    10-6Negligible risk - No land userestrictions

    IR/yr

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    http://ch4101_1%20qra%20nea_guidelines%20_pcd_2013.pdf/
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    ACCIDENT STATISTICS

    Singapore, MOM: Accident frequency Rate (AFR)

    AFR: Accidents per 1,000,000 man-hrs worked

    Singapore, MOM: Accident Severity Rate (ASR)

    ASR: Man-days lost per 1,000,000 man-hrs worked

    Fatal Accident Rate (FAR)

    British: Fatalities per 100,000,000 man-hrs worked

    MOM: fatalities per 100,000 workers per year

    Fatality Rate (FR): Deaths per person per year

    Individual Risk (IR): The chance of death per person per year

    Relationship between (FAR) and (FR)

    British: (FAR)(man-hrs worked/person-year)/(108) = (FR)

    MOM: (FAR)/(100,000) = (FR)

    Read: Textbook 1 3 Accident and Loss Statistics, page 4 12

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    EXAMPLE: Accident Rates

    Factory A (100 workers): #man-hours worked per year:

    100 x 50 x 5 x 8 = 200,000 man-hrs No. of accidents: 5 per year

    AFR (MOM): 5 x 1,000,000 / 200,000 = 25

    Total number of MC-days: 10 days per year

    ASR (MOM): 10 x 1,000,000 / 200,000 = 50

    No. of Fatalities: 1 per year

    FAR (British): 1 x 100,000,000 / 200,000 = 500

    FAR (MOM): 1 x 100000/100 = 1000

    Fatality Rate (FR): 1/100 = 1 x 10

    -2

    per person per year British: man-hr worked per person = (FR)/(FAR)

    (1/100)/(500/100,000,000) = 2000 man-hrs per person-year

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    SAFETY TARGETS: FAR OR FR

    For planning or design To meet national or company requirements

    e.g.Singapore 2018 target: FR = < 1.8 by 2018

    Plant risk:

    Mult iple/ Overall risk: (FAR) < 2

    Single/ Each risk: FAR < 0.4

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    ACCIDENT PROCESSES

    Initiation:

    Event that starts the accident

    Propagation:

    Event/ events that maintain/ expand the accident

    Termination:

    Event/ events that stop the accident/ diminish it in size

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    ACCIDENT MITIGATION PRINCIPLES

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    Initiation Diminish

    (Prevent/ removethe potential ofaccident causing

    events)

    Grounding and bonding

    InertingExplosion proof electricalGuardrails and guardsMaintenance proceduresHot work permitsHuman factors designProcess design

    Awareness of dangerous properties of chemicals

    Propagation Diminish

    (Reduce potentialfor accident to

    continue escalation)

    Emergency material transferReduce inventories of flammable materialsEquipment spacing and layoutNonflammable construction materialsInstallation of check and emergency shutoff valves

    Termination Increase

    (Increase capacityto terminate the

    accident)

    Fire-fighting equipment and proceduresRelief systemsSprinkler systemsInstallation of check and emergency shutoff valves

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    JOHORE TANK FIRE

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    Initiation: Lightning?

    Propagation: Spread to another tank

    1/3 of content in 2ndtank transferredbefore catching fire

    Termination: Fire put out in 67 hours

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    LEARNING OBJECTIVES

    Understand the basis concepts/ definitions of safety, health &

    environmental terminology/ principles in

    Hazards

    Risk: Frequency & Consequence

    Risk management principles

    Accident processes

    Safety performance indicators: Accident statistics

    The differences between

    Safety and health

    Process safety and WSH/ personal safety

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    END

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