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# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
Jr.IIT-JEE Mains Model Paper
Test Date:15/08/2016
Key & Solutions:
Key
Mathematics
1. b 2. c 3. b 4. a 5. c 6. a 7. d 8. a 9. a 10. a
11. d 12. c 13. a 14. d 15. c 16. a 17. d 18. a 19. d 20. b
21. b 22. a 23. c 24. a 25. c 26. a 27. c 28. a 29. a 30. d
Physics
31. b 32. a 33. c 34. a 35. c 36. b 37. a 38. c 39. d 40. c
41. b 42. b 43. a 44. c 45. c 46. b 47. b 48. b 49. d 50. a
51. a 52. a 53. c 54. b 55. a 56. a 57. a 58. b 59. b 60. a
Chemistry
61. d 62. b 63. a 64. c 65. a 66. b 67. a 68. b 69. c 70. c
71. b 72. c 73. c 74. c 75. b 76. a 77. c 78. d 79. a 80. d
81. d 82. d 83. d 84. d 85. c 86. b 87. b 88. b 89. a 90. a
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
Answers & Solutions
1.
2.
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
3.
4.
5.
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
6.
7.
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
8.
9.
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
10.
11.
12.
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
13.
14.
15.
16.
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
17.
18.
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
19.
20.
21.
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
22.
23.
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
24.
25
26.
27.
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
28.
29.
30.
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
PHYSICS
31. (b) 26
dsv tdt
Impulse = P = m(vf – vi) = 2(6 × 1 – 0) = 12 N-s.
32. (a) After collision 2
1
2
ev u
and 1
1
2
ev u
Here, u = initial speed of ball 1 v2 = 2v1 when 1
3e .
33. (c) Change in linear comentum .p F t
Here, F
is weight, i.e., mg
1 10 1 10 / .p mg t kg m s
34. (a) At maximum extension velocity of both the blocks will be same. Let v be the common velocity of the
blocks (towards right). From conservation of linear momentum.
(3 + 6) v = 6 × 2 – 3 × 1 = 9 or v = 1 m/s
Now let x be the maximum extension in the spring.
From conservation of mechanical energy: 2 2 221 1 1 13 1 6 2 200 9 1
3 2 2 2x
or 23 24 200 9x or 18
200x or x = 0.3 m
or x = 30 cm.
35. (c) Using impulse = change in linear momentum
We have,, .f i
F t m v v
or 2 3 2 1 2fi j k v i j
or 6 3 6fv i j k
2 2 26 3 6 9 / .
fv m s
36. (b) Force on the bullet becomes zero at 0 = 600 – (2 × 105) t or t = 0.003 s
Impulse 0.003
0F dt 0.003
5
0600 2 10 0.9t dt N s .
37. (a) From conservation of mechanical energy
2 21 1
2 2rk x v
Here, = reduced mass of the blocks 2 2
2 3
m mm
m m
and vr = relative velocity of the two.
Substituting in Eq. (1), we gt 2 22
3rkx mv
3
2r
kv x
m
38. (c)
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
1
sin2 2
r
r
30º
From conservation of linear momentum mu = 2mv cos 30º or 3
uv . . . . .(i)
Now relaive velcoity of separation
erelative velcoity of approach
in common normal direction.
Hence, / 3 2
cos30º 33 / 2
v ueu u
.
39. (d)
Let v be the velocity of ball after collision, collision elastic
e = 1 or relative velocity of separation = relative velocity of approach
v – 1 = 4 + 1 or v = 6 m/s (away from the wall)
40. (c) In perfectly inelastic collision between two particles, linear momentum is conserved. Let be the
angle between the velocities of the two particles before collision. Then
2 2 2
1 2 1 22 cosp p p p p
or 2
2 22 2 cos
2
vm mv mv mv mv
or 1 = 1 + 1 + 2 cos
or 1
cos2
or = 120º.
41. (b) Let u be the velocity of ball before collision.
Speed of ball after collision will become
2 25
.82 2 2
u uv u
Fraction of KE lost in collision
2 22
2
1 1
5 32 2 1 1 .1 8 8
2
mu mvv
umu
42. (b)
Let v1 and v2 be the velocities of the two masses after collision in the same direction. Then
m1v = m1v1 + m2v2 . . . . . .(1)
and v2 – v1= = ev . . . . . .(2)
Solving Eq.s (1) and (2) we get, 1 2
1
1 2
v m emv
m m
For v1 to be positive m1 > em2 or 1
2
me
m .
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
43. (a) Let speed of block is v. Then from conservation of linear momentum in horizontal direction velocity
of cylinder will be 2v in opposite direction .2
Mas m
Now from conservation of mechanical energy, we have 221 12
2 2mgh Mv m v
Here, h = R – r = 1.0 m
Substituting the values, we get (1)(10)(1) 2 21 12 1 4
2 2v v or
23 10v
10
/ .3
v m s
44. (c) Let vr be the velocity of bullet with respect to gun and v the velocity of gun. Then
From the two figures it is clear that > 45º.
45. (c) 2
2av
F ava
Here, 3 3 6 310 / , 20 10 /kg m av m s and
22
2104 4
da
Substituting the values 2
3 6
3
4
10 20 105.1 10 .
104
F N
46. (b) Block just reaches the top of the wedge, it implies that velocity of block with respect to wedge at the
top of the wedge is zero. Let v be the horizontal velocity of both at this instant.
Then from conservation of linear momentum, we have (2m + m)v = mu
or 3
uv
Now from conservation of mechanical energy, we get 2 21 13
2 2mu m v mgh or
22 3 2
9
uu gh
or 22
2 33u gh or u gh .
47. (b)
48. (b) The rope tension is the same both on the left and right hand side at every
instant, and consequently momentum of both sides are equal
Mv M m v m vr v or 2
r
mv v
M
Momentum of the centre of mass is P = P1 + P2 or 2 comMv Mv Mv
2
com r
mv v v
M .
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
49. (d) Horizontal and vertical components of initial velocity are:
20 2 cos45º 20 /xu m s and 20 2 sin 45º 20 /yu m s
After 1s horizontal one part comes to rest. Hence, from conservation of linear momentum vertical
component of second part will become 20 /yv m s . Therefore, maximum height attained by the
second part will be H = h1 + h2
Here h1 = height attained in 1s = (20)(1) 2110 1 15
2m
and h2 = height attained after 1s 2220
202 2 10
yvm
g
20 15 35H m
50. (a)
When the string jerks tight both particles being to move with velocity components v in the direction
AB. Using conservation of momentum in the direction AB
mu cos 30º = mv + mv or 3
4
uv
Hence, the velocity of ball A just after the jerk is 3
4
u
51. (a) Relative velocity of separation = relative velocity of approach = v (as e = 1)
Time of next collision 2 r
v
.
52. (a) Inc case of perfectly inelastic collision the velocity of combined mass will be 2
v
21
22 4
vKE m
210.2 0.2
2 4
v
or 2 2 /v m s
In case of perfectly elastic collision
First particle stops and the second acquires the same velocity v 21
2KE mv
or 210.2 0.1
2v or v = 2 m/s
Therefore, minimum value of v is 2 m/s in case of perfectly elastic collision and maximum value of v
is 2 2 /m s in case of perfectly inelastic collision.
53. (c) After collision balls exchange their velocities
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
i.e., 2Av gh and 2 4 2 2Bv g h gh
Height attained by A will be 2
2
AA
vh h
g
But path of B will be first straight line and then parabola as shown in figure.
After calculation we can shown that 13
4Bh h
4
13
A
B
h
h .
54. (b) j component, i.e., component of velocity parallel to wall remains uncharged while i component will
become 12 .
2i or i
Therefore, velocity vector of the sphere after it hits the walls is 2i j .
55. (a) Retardation due to friction a = g = (0.25) = (10) = 2.5 m/s2.
Collision is elastic, ie, after collision first block comes to rest and the second block acquires the
velocity of first block. Or we can understand it in this manner that second block is permanently at rest
while only the first block moves. Distance travelled by it will be
22 55
2 2 2.5
vs m
a
Final separation will be (5 – 2) = 3 m.
56. (a) Let the masses are unequal
From conservation of linear momentum;
or 1 1 2 2 1 2m v v m v v or 1 2m m
i..e, mass of both the particle should be same
Secondary, relative velcoity of separation
erelative velcoity of approach
1 2
1 2
1v v
v v
i.e., e = 1 or collision is elastic.
57. (a) In an elastic oblique collision both particles move at right angles after collision if mass of both the
particle are same provided one particle is at rest before collision.
58. (b) Let mass of gun is M and that of shell is m. The two cases are shown in figure as below:
Here, v1 and v2 are the recoil speeds of the gun in two cases. Using conservation of linear momentum
in horizontal direction in two cases:
1 1m v v Mv
1
mvv
M m
. . . . . (1)
2 2cos30ºm v v Mv . . . . . (2)
2
3
2
mvv
M m
From Eqs.(1) and (2), we get 1
2
2
3
v
v .
59. (b) 3
2 104 0.0032
2.5r
dmF v N
dt
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
60. (a) Let P1 and P2 be the momenta of A and B after collision.
Then, applying impulse = change in linear momentum for the two particles, we get
For B : J = P1 . . . . . (1)
For A : J = P – P2 or P2 = P – J . . . . . (2)
Coefficient of restitution 1 2 1 21.
P P P P J J P J Je
P P P P
CHEMISTRY
61. (d) Due to H-bonding in NH3.
62. (b) .
PV PV Rn k
RT kN T N
.PV
n N No of moleculeskT
63. (a) 2
'
O MP P mole fraction of 2O
M
P
P
mole fraction 2
132
3
16 32
w
Ow w
.
64. (c) Greater the value of ‘a’ i.e., intermolecular forces of attraction for gas, the easily the gas will be
liquid.
65. (a) 1 1
2 2
8:AV
u TRTu
M u T
1
2
2
0.3 300 1200, 0.3 0.6
1200 300or u ms
u
.
66. (b) Density of a gas, 1
;PM
e e P and eRT T
.
67. (a) 21
3PV mnu
For one mole, 2 21
3PV Mu P u
68. (b) Use 0
1,
vr P T
t m
2 2 2
2 2 2
32, 20sec
5 2
H O H
O H O
r M r x tt
r M r x .
69. (c) 3
rms
RTU
M
Thus, 2
3 5050
2rms H
RU at K
. . . . . (1)
2
3 800800
32rms O
RU at K
. . . . . (2)
So,
2
2
50 321
2 800
rms H
rms O
U
U
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
70. (c) According to Grahan’s law of diffusion 1
r PM
at constant temperature.
1
2A A B A B
B B A B A
r P M P M
r P M P M
.
71. (b) 1 1PV
Z ornRT
Thus, 22.4mV litre
72. (c) 1 22 2
3 3
2 28rms rms
RT RTu H and u N
2 27rms rmsu H u N
2 27rms rmsu H u N
or 1 23 3
72 28
RT RT
2 2
1 22 12
2 4N H
T Tor T T or T T
73. (c) 3 3
2rms
RTu and KE RT
M
2
rms
Eu
M
74. (c) For positive deviations Z > 1, i.e., the condition when repulsive forces predominates. Also, at high P,
V is small and b cannot be ignored, but eh factor 2
a
V can be neglected in comparison to P.
Thus, 1Pb
ZRT
75. (b) 3 400
40rms
Ru X
2 60
MPY
Ru
M
4M .
76. (a) 3 8 1C H n mol
4 2CH n mol
Total mole = (n1 + n2)
mole fraction of 13 8
1 2
nC H
n n
n
P RTV
1 2320
760
n nRT
V
3 8 23C H CO ,
4 2CH CO
CO2 formed = (3n1 + n2)
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
1 23448
760
n n RT
V
1 2
1 2
3 4481.4
320
n n
n n
1 20.25n n
mole fraction of 13 8
1 2
0.2n
C Hn n
Thus, (a)
77. (c) By Avogadro’s law, equal volumes of gases contain equal number of moles.
3 2 24 5 4 6NH g O g NO g H O g
3 24 6mLNH mLH O
3 250 75mLNH mLH O
2 25 6mLO mLH O
2 260 72mLO mLH O
Stoichiometrically, O2 is consumed completely
Thus, 72 mL H2O(g) hence (c).
78. (d)
1 1
2 1
0 01 1
0 02 1 se
x x
y y
A B C D
set Ix x
t IIy y
2
21
2 11c
x yK
y yx
since x = 0.5
2
3y
Fraction of A converted into products 2 / 3 1
0.332 3
Hence, (d)
79. (a) 5 3 2
20.5 2 mol
PCl PCl Cl
Q (reaction quotient)
3 2
5
2 2
2 2 40.5
2
PCl Cl
PCl
Thus, Q = KC, reaction mixture is in equilibrium
1
5
0.50.25
2PCl mol L
Hence (a)
80. (d)
1 2
2 2
2 3
P P
NO O NO OK amd K
NO O NO
1 2
2 3
2 2
1 1
P P
NO O NO
K K NO O NO O
3
2
OK
O O
83
50 35
13.3 10
6 10 5 10K
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
81. (d) 2 4 22N O NO
1 92 2 46
2 30.61
0.5 .
82. (d) At the initial state if only reactants are used Q = 0, but from initial stage to attain equilibrium is
continuously increase with time till it because equal to K.
83. (d) KP is a characteristic constant for a given reaction and changes only with temperature.
84. (d) For the reaction ; 2 4 22
g gN O NO
2 24..... 1c
aK
a a V
Where, a is initial mole on N2O4 in V liter vessel and is degree of dissociation of N2O4.
If volume is reduced to V/2, the initial concentration of N2O4 becomes 2
.
2
a a
V V
An increase in concentration of reactants leads to forward reaction, i.e., the decomposition of N2O4 to
have constant value of Kp.
85. (c)
2
3
1 3
2 2
NHK
N H . . . . . . . .(i)
2
2
2 2
NOK
N O . . . . . . . .(ii)
2
3 2 1/ 2
2 2
H OK
H O . . . . . . . .(iii)
2 3
2
2 5/2
3 2
NO H OK
NH O
By inspiration of (i), (ii) and (iii)
2 3 332 2 22 3
2 3 3/2
1 2 2 3 2 2
NO N H H OK K
K N O NH H O
2 3
2
2 5/2
3 2
NO H OK
NH O
86. (b) 2 2 3
1;
2SO O SO H ve ; Follow Le Chatelier principle.
87. (b) 2 4 21 0
1 0.20 2 0.20
2N O NO
Mole of 2 4 1N O mole
Dissociated 2 4
1 200.2
100N O mole
2 4NP O at 300 K = 1 atm,
2 4NP O at 600 K = 2 atm
Total mole present at eq. = 1 – 0.20 + 0.40 = 1.20
1 1
2 2
P n
P n (at constant T, V)
2
2 1
1.2P P1 = 2.4 atm
# 2-1-520 to 526 Vijaya Sri Sai Celestia II Floor, Nallakunta, Hyderabad 500 044 m : +91 7799880649
88. (b) 1 1 0
1 1 2
2
x x x
A B C
2
2
481
1
x
x
or
2
91
x
x
1
11x
Thus, 10 10 2
11 11 11
2A B C 10 10 2 22
11 11 11 11Total mole
Mole fraction of
2
11122 11
11
C .
89. (a) The formation of SO3 is exothermic and thus at high temperature backward reaction will proceed to
give lower percentage yield.
90. (a) 2/2 /4
2
2 2P P PP
NOCl NO Cl
r
5P .
2 2 4 4
P P P P