14
fC,;r '- '.J ~ MATERIAL SAFETY DATA SHEET k vA ~~ .200~ ISSUE DATE: 10/01/98 Rupe~ Gibbon & Spider P.O. BOX 425 BEALDSBURG7 CA. 95448 I -PRODUCT IDEimnCA110N PRODUCT NAME YELLOWMX-8G PRODUCT CODE NUMBER aiEMICALFAMJLY AZO COLOR INDEX NAME ; T.S.C.A.STATUS INCOMPLIANCE II -HAZARDOUSINGREDIENTS HAZARDOUS COMPONENTS; NON HAZARDOUS CURRENTTLV'S: NOTESTABUSHED XU. PHYSICALDATA APPEARANCE "."..." POWDER COLOR YElLOW ODOR NONE SOLUBILnYlNWATER SOWABLE pH NODATA IV -FIRE AND EXPLOSION DATA FLASHPOINT Not Applicable EX'nNGL1SHING MEDIA Water, Dry Chemical, CO2, Foam SPECIAL FIRE FIGHTING PROCBDURES/UNUSUAL FIREOR EXPLOSION ~RDS: P.irefigbtm should be equipped with protective clothing &.scIf-a>nUined breatbing apparatus to pnx.ect against potentially toxic&;irritating fume!. IJ1 cas~ of fireor explosion, bep unnecessary jxople away. Isolate .hazard area" any mtry. Stay upwiJ1d, out of low areas, aDd vent.iIatc closed spaCes before eIrtering . ~ PAGEl PRODUCT: YELLOW MX-8G

k vA ~~ .200~ - School Specialty

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fC,;r'-'.J ~

MATERIAL SAFETY DATA SHEET

k vA ~~ .200~

ISSUE DATE: 10/01/98Rupe~ Gibbon & SpiderP.O. BOX 425BEALDSBURG7 CA. 95448

I -PRODUCT IDEimnCA110N

PRODUCT NAME YELLOWMX-8GPRODUCT CODE NUMBERaiEMICALFAMJLY AZOCOLOR INDEX NAME ;T.S.C.A. STATUS INCOMPLIANCE

II -HAZARDOUS INGREDIENTS

HAZARDOUS COMPONENTS; NON HAZARDOUS

CURRENTTLV'S: NOTESTABUSHED

XU. PHYSICAL DATA

APPEARANCE "."..." POWDERCOLOR YElLOWODOR NONESOLUBILnYlNWATER SOWABLEpH NODATA

IV -FIRE AND EXPLOSION DATA

FLASH POINT Not ApplicableEX'nNGL1SHING MEDIA Water, Dry Chemical, CO2, FoamSPECIAL FIRE FIGHTING PROCBDURES/UNUSUALFIRE OR EXPLOSION ~RDS: P.irefigbtm should be equipped with protective clothing &. scIf-a>nUined

breatbing apparatus to pnx.ect against potentially toxic &; irritating fume!.IJ1 cas~ of fire or explosion, bep unnecessary jxople away. Isolate

.hazard area" any mtry. Stay upwiJ1d, out of low areas, aDd vent.iIatcclosed spaCes before eIrtering .

~

PAGElPRODUCT: YELLOW MX-8G

v .HEALTH EFFECTS DATA

ANIMAL TOXICrrY ORAL. LD50 (INGES-nON) MAY CAUSE IRRITATIONFISH, LC.sO NODATAEYE EFFECTS MAY CAUSE IRRlTAll0NSKIN EFFECTS MAY CAUSB IRRITAll0N.HUMAN EFFECTS OF OVEREXPOSURE MAY CAUSE ~PIRATORY tRRITA11ON TO

SOME PEOPLE

VI -EMERGENCY AND FJRST AID PROCEDURES

EYE CONTACT WasI1 immcdiatcJy with large amount.! o{watcr. occasionally lifting t11e upper and lowerlids until no evidencc of product remain. Get medical attention. Do not wear contactle11scs while handling.

SKIN CONTACT Wa5f1 immcdiateiy with soap and plc1ty ofwa1er. Ifa temporary skin reactionOCaJrs. itshould be treated as allergic contact dc:ri1atitis. Launder a>z1tamiJ1ated cJothing beforereuse.

INGESTION IfswaJlo~, do not induce vomiting. Qua1iflcdmedicaJ persOm'ld should remove theprcxiuct by gastric levage and catharsi.!. Oct medical attention.

JNHALA TION Ifinhalcd, remove to flab air If not breathing, give artificial respiration. preferablymouth to mouth. Ifbreathing is difficult, give oxygen. Call a physician.

VII -EMPLOYEE PROTECTION RECOMMENDAnONS

EYE PROTECTION ... ...EmpIO)'ee! should Wt:ar protccti\-e eye-goggles.

SKIN PROTECTION This materia! may be absorbed via thcdcm1al coote ifpmJongai or \'I1idespread skincontact OCCUr!. Employees should avoid skin caJtact by wearing pfO~tive clothing.tons slecve shtrts, pants, robber gloves, aDd boot.. arc J~(III~lrj~ Additionalprotection such as impervious suits are reccmnatded when the pctectial for dennalCODta.ct is significant Employees should wash their bauds am face before eating anddrinldng and shower -d)OroughIy before leaving work.

RESPIRATORY PROTECTION NIOSH approved dust respirator.

10. Use local veatilatioa if dustiDs is a problem.VEN11LA TION

.Emersency

showers and eye wash stations shouJd be available.OTHER

PRODUCT: YELLOW MX-8G p ."-GE 2

~

VIII -REACTIVITY DATA

STAB1UTf STABLEPOLYMERJZATION OOES NOT OCCURINCOMPATIBILITY (~IATERIALS TO AVOID) NONEI-IAZARDOUS DECO~1POSmON PRODUCTS '. BURNiNo MAY PRODUCE OXIDES OF CARBON

ctN1TROGEN

IX -SPILL OR LEAK PROCEDURES

IN CASE MA TERJAL IS RELEASEDISPILLED: Do DOt touch or walk through ~ spiUed materiAl: stop leak if~ can do it withalt risk. Take up with sand or other non-c:ombustiblcabsorbent materials and p1a= inw containers for later disposal. Scrubspilled arca with deter:ger1t, flush with ~ous amount of 1\'atcr.

WASTE DISPOSAL MEnIOD: Waste dispos..l should bo iJ1 accordanoo with e:tisMa fedetaJ, statc and Iocaie:rviroJUnerifal regulations.

x -SPECIAL PRECAVnONS AND STORAGE DATA

HANDLING AND STORING PRECAunONS: Store in dry p~ away from exeessM heat, in original orsintilar \vaterproof container. Reseal container inunediateJy after use. Avoid uaneceuazy ccntact

XI. SffiPPING DATA

PROPER SHIPPING NAME ;... NON-HAZARDOUSD.O.T. HAZARD CLASSIFICATION Non-Regu1atcdFRT. CLASS PACKAGE DYEMATERIALS

m-APPROVALS

DATE PRINTED 10/31/98DATE APPROVED 08/01/98

PAGE 3PRODUCT: YELLOW MX-8G

~-.,.MATERIAL SAFETY DATA SHEET

1011ZENECA Inc.Wilmington, Delaware 19897Phone (24 hr.) Technical: (302) 886-3000Medical: (800) 327-8633

Issue Date: OS/27/94

Rev.:cms:E54408

SEC'l':ION 1 NAME & HAZARD SUMMARY-

MateriaJ. name:PROCION@ Red MX-8B

Hazard summary (as defined by OSHA Hazard C~)nication Standard,29 CFR 1910.1200);Physica1 hazards: NoneHealth hazards: Skin irritant, eye irritant, ,pulmonary (lung) sensitizer

Read the entire MSDS ~o~ a more thorouqh eva1uation of the hazards.-

SEC'l'iON 2 INGREDJ:EN'l'S OSHA PEL--Azo dichlorotriazine reactive dye I Not listedOther nonhazardous ingredients I Not listed

Ingredients not precise~y identi£ied are p~oprietary or nonhazardous. Va~uesare not product speci£ications. .

~ --

SECTION 3 PHYSICAL DATABoi~ing point: Not app~icab~eVapor pressure (mmHg at 20oC): No dataVapor density (air = ~): No data

So~ubility in water: 50 g/~pH: No dataSpecific gravity: About 1% Volati~e by vo~ume: Neg~igibleAppearance and odor: Red odor~ess powder

SECTION 4 FIRE AND :-.XPLOSION HAZARD DATAF~ash point (and method): Not app~icab~eAutoignition temp.: No data ..

F~ammab~e limits (STP): Not app~icable

Extingu.ishing media:Water fog, foam, carbon dioxide, dry chem.ica1, halogenated agents.

Speciax fire fighting protective equipment:Self-contained breathing apparatus with full £acepiece and protectiveclothi.ng.

Unus.ual. fire and expl.osion hazards:This product may foDn expl.osive dust cl.ouds .in air.

Page 2

MATERIAL SAFETY DATA SHEET (continued)

PROCiQN' ~ MX~SECTiON 5 REACT:IVJ:'l'Y DATA --,-- ==

-..,~,. .-ab ' l. 'St J.. J..ty:

Stabl.e under normal. conditions.

Incompatibi~ity (mater~a~s to avoid):Oridizing agents.

Hazardous decomposition products:Combustion products: Carbon dioxide, carbon monoride, nitrogen ondes,ammonia, s~fur oxides, ha~ogen, ha~ogen acids, possib~e trace amounts ofcarbonyl. hal.ide. .

Hazardous po1ymerization:WiJ.1 not occur.

SECTION 6 HEALTH HAZARD ASSES~Genera1:

Limited toxicity data are avai1able on this specific product; this healthhazard assessment is based on the resu1ts of screeninq tests.

Ingestion:

The acute ora~ LDSO in rat is above 5 g/kg. Re~ative to other materia~s, asing~e dose of this product is practica~~y nontoxic by ingestion.

Eye contact: :This materia1 is s1ight1y irritating in rabbit eye studies; a simi1ar degreeof irritation wi11 probab1y occur after human eye contact.

Skin contact:This materia1 is s1ight1y irritating in rabbit derma~ irritation studiesIrritation may deve~op £o1~owing repeated and/or pro1onged contact withhuman skin.

Sk.in absorption:This product is not likely to be absorbed through human skin.

Inha1ation:

A1though the potentia1 for respiratory sensitization is expected to be 1owfrom exposures to dusts generated. from this dyestuff, some individua~s havedeve1oped respiratory a11ergic reactions after repeated and/or pro1ongedexposures to high atmospheric concentrations of dust from some reactivedyes, of which Procion dyes are one type. Cough, tightness in chest, and/orasthmatic wheezing may be signs of respiratory a11ergy.

Other effects of ~verexposure:No other adverse clinical effects are known to be associated with exposuresto this material.

F~rst a~d procedures:~: Wash materia1 off the skin w~th p1enty of soap and water. Ifredness, ~tching or a burning sensat~on deve1ops, get medica1 attent~on.---continued---

,.'" Page 3

MATERIAL SAFETY DATA SBEE'l' (cont.inued)

PROCIOH Red MX-8B

First aid procedures (cont.inued):~: Immediate1y f1ush with p1enty of water for at .1east ~5 minutes. Ifredness, itching or a burning sensation deve~ops, have eyes exam;ned andtreated by medica1 personne1.Ingestion: Give one or two g1asses of water to drink. If gastro.intest.ina~symptoms deve1op, cons~t medica1 personne1. (Never give anything by mouthto an unconscious person.)Inha~ation: Remove victim to fres~ air. If cough or other respiratorysymptoms deve1op, consu~t medica~ personn~.

-SECTION 7 SPILL OR LEAK PROCEDURES --

Steps to be taken .in case materia1 is re~eased or spi1~ed:Wear skin, eye and respiratory protection during c~eanup. Sweep up andrecover or mix materia~ with moist absoDbent and shove1 .into wasteconta.iner. Wash down spi11 area with water and f~ush to a sewer serviced bya wastewater treatment £aci1ity. Use care to m;n;m; ze the amount o£dyestuff that reaches the sewer.

Disposal. method:Discarded product is not a hazardous waste under RCRA, 40 CFR 26l..

Container disposa1:Empty container retains product residue. O~serve a11 hazard precautions.Do not distribute, make avai1ab1e, furnish.:or reuse empty container exceptfor storage and shipment of origina1 product. Remove a11 product residueand puncture or otherwise destroy empty container before disposa1.

~- ~~-~SECTION 8 SPECIAL PROTECTION INFORMATIONTLV@ or suggested contro1 va1ue:

No ACGIH TLV or OSHA PEL assigned. Minimize exposure in accordance with

good hygiene practice.

Ventil.ation:

Use l.ocal. exhaust to keep exposures to a minimum.

Respiratory protection (specify type) :If needed, use MSHA-NIOSH approved respirator for dusts, mists and fumeswhose TLV is g~ater than 0.05 mq/m?

Protective c~othinq:G~oves, apron and aDD covers to avoid skin contact (see Section 9).

Eye protection:Chemical. tight goggl.es.

Other protective equipment:Eyewash station and safety shower in work area.

Page 4

MATERIAL SAFETY DATA SHEET (continued)

CERCLA and SARA Regu~ations (40 CFR 355, 370, and 372) :This product does not contain any chemica~s subject to the reportingrequirements of SARA Section 313-

The infoz:mation herein is given in good faithbut no warranty, expressed or imp1ied, is made.

11/3/86

Prepared/Reviewed:

***Thia ~ine or section contains revisions or new statements sincethe ~ast issue date.

Precautions to be taken in han~ing or storing:Fo~~ow procedures specified in the Nationa~ Fire Protection AssociationCodes and Standards for handling exp~osi ve dusts. Maintain goodhousekeeping to avoid dust bui~dup. Avoid skin contact; stains may bedifficu~t to remove without injuring the skin. Prevent eye contact.Minimize inha~ation exposure to dusts. A sensitized individua~ sho~d notbe exposed to the product which caused the sensitization.

***SECTION 10 REGULATORY INFORMA~ION .-~ TSCA (Toxic Substances Control Act) ~ations, 40 CFR 710:

All. ingredients are on the TSCA Chemi.cal. Substance Inventory.

or; 11' \.,

MATERIAL SAFETY DATA SHEET

ISSUE DATE: 07/01/98Rupert, Gibbon & SpiderP.O. BOX 425HEALDSBURG, CA.. 95448

~. PRODUCT WENm1CATION

PRODUCT NAME TURQUOISE MX-GPRODUCTCODENUMBER.CHEMICAL FAMILY AZO iJYESTUFFS

COLORINDBXNAME "

T.S.C.A. STATUS IN COMPLIANCE

II .HAZARDOUS INGREDIENTS

NONE AS PER. SARA TITLE ill. SEC. #313: NOT LISTEDHAZARDOUS COMPONENTS:

CURRENT TL V.S: NOT ESTABLISHED

OJ -PHYSICAL DATA

APPEARANCE POWDERCOLOR BLUEODOR ODORLESSSOLUBILITY IN W AT.ER SOLUBLEpH NODATA

IV .FIRE AND EXPLOSION DATA

FLASH POINT NotAppli~1eEX1lNGUISHING MEDIA Water, Dry Cbsnicai, CO2, FoamSPECIAL FIRE F~GHTING PROCBDURES/UNUSUALFIRE OR EXPLOSION HAZARDS: ~irefighters should be equipped Mdt p~ve clothing &. self-coDt.1inm

.breathmg appamtus to proteCt against pote1rtJa11y toxic & irritating fumes.In case of firo or explosion, keep unnecessary ~Ie away. Isolatebazardarea & any ~. Stay upwind, out of low areas. and ventilateclosed spaces before eDterlI2g .

PAGElPRODUCT: TURQUOISE MX-G

~,..'. t..

v -HEALTH D'FECfS DATA

ANIMAL TOXICrrY ORAL -LDSO (INGES"I10N) NO DATAFISH 1('.50 NO DATA,EYE EFFECTS MODERATELY IR.RrrATINO TO RABBITSSKIN EfFECTS ~ON.IRRlTATING 'I'O ~Bn'SllUMAN EFFECTS OF OVEREXPOSURE MAY CAUSE RESPIRATORY IRRtrATION

VI- E.'1ERGENCY AND nRST AID PROCEDURES

EYE CONTACT ..Wash immediately wjth Jarge 8nX)UDts of water. occasionally IiftiI1g the uppcr and lowerlids until no evidence of product remain. Gct medical attention. Do n<:x: wear contact1enses while haadIins.

SKIN CONTACT Ws,h immediatcly ,'fith soap arxj pl~ of water. Ifa temporary "skin reactJon occurs, itshould be treated a:i allergic cootact derntatitil. T~U.-~cr ~tammated clothing beforereuse.

IlII:GESTION IlswaJ1owed. do not ilkiuce vomiting. Qualified Ine(ljcai personoel should remove tfJCproduct by gastric: levage and cathams. Get medical atterrtion.

lNHALA TION Ifinhaled, remove to fresh ajr. Ifnot breathins, giw artificial ~piration. prd'crablymoutb to mouth. tfbreathing is difficult, gi\'e oxygen. Can a physician.

VII -EMPLOYEE PROTECTION RECOMMENDAnONS

BYE PROTECTION Employces should wearpra.ective eye-goggjes.

SKIN PROTECnON This material may be absorbed via the dem1a1 route lfprolonged or widespread skincontact occurs. EmplOyee1lhouId 3.\tJJd skin contact by we3rlna protective clothiDg.Long slecw shirts, panes, cubber gloves, and boots are I~:-(,y~~~-i~-! Additionalprotection such as impervious suits ale r:oonunended whe:2 the potend.a1 for dennaJcontact is significant. Employees shoold wash their hands aIxi face before eatiag anddrinking and showor thoroughly before leaving work.

RESPIRATORY PROTECTION NIOSH approvQd dust respinrtor.

VENTILATION Use local ventilatiOri if dusting is a problem.

ornER :...Emergcncy showers and eyewash stations should be avaiJabJe.

PAGElPRODUCf: TURQUOISE MX-G

""t'...

vm -REACTIVITY DATA

STABIUTY STABLEPOLYMERIZATION DQF;S NOT OCCURINCOMPATJBJLl1Y (MATERIALS TO AVOm) OXDIZING AGENTSHAZARDOUS DECOMPOSITION PRODUCTS BURNING WU PRODUCE OXlDBS OF CARBON

MONOXIDE, NUROGEN OXIDES, AMMONIA,SULFUR OXIDES, HALOGEN. HALOGEN ACmS,POSSIBLE TRACE AMOUNTS OF CARBONYLHALLDE.

IX .SPILL OR LEAK PROCEDURES

IN CASE MATERIAL IS RELEASED/SPILLED: Do not touch or walk through the spiUed ma=ia1: stop leak Ifyou can do it without risk. Tab up with sand or other non-combusubleabsorbent materials ad p= -ront-ail!ers for later disposal. Scrubspilled area wid! det2rga1t, flush with ccploas amount ofwatcr.

WASTE DISPOSAL MErnOD: Waste disposal should be in accordance with existing federal. Stat2 and localen"iromnenta! regulations.

X. SPECIAL PRECAUTIONS AND STORAGE DATA

HANDLING AND STORlNG PRECAunONS: Store in dry place. away from excessive heat, in original orsimilar \vaterproof containcr. Reseal CQDtaincr immediately after use. Avoid unDecessaxy contact.

XI- SHIPPING DATA

PROPER SHIPPING NAME NON-}tAZARDOUSD.O.T.HAZARDCLASS1FICATtON N~1atedFRT. CLASS PACKAGE 1NX MATERIAL

XII- APFROV ALS

DATE PRINTED 07/23/98DATE APPROVED 03/01/98

PAGE 3PRODUCT: TURQUOISE MX-G

.'

pg 1MATERIAL SAFETY DATA SHEETP 11.20

,

MARCH 14, 1997

RUPERT GIBBON & SPIDER. INC.P.o. Box 425

~ealdsburg, CalifCJ'nia 95448

SODA ASH

ORDER NO~ Q19~3~B14PROD t«J: 04621203

VAt.. "'ATERS t-« ROGERS INC. tbOO HunTON BLDQ. SEATTLE, WA 99104-1~61

ENERf;:E:NC'( '~S9 1ST I\NCE ~ FOR EHEROEt'«::y ASS ISTAI'J(';E IN"JULVlt.tG CHEt11C"LS CAt_L CHe:HTREC

(SOO, "P!"-~300;

FtIt PROOt1C r "tlV RN_E9 INFortH"TION CON1ACT YOUR LOCAL. V"N &.J"lERS It Rooms BRANCH OFFICE

I'ROD\'t::'.T T nF:"'TIFt c"r I ON--- :--~-~-

21C1~3~elJ "IVO 1 CE:~1221,?:'.Qt: 'J~ T(?'? t~ !tJ' t "'Efl11: 30: 38

f'ROO:

Ol1-6212Q3

FOOHUU\; NA2 CO3 DATE ISSUED: 11/94tiAZARD RATING (MANJFACTURE"It) 9UPERCEDES: NONE

t-fE"L TH: 2 t-tAlARD RATING SCPLE:f:"IRE: 0 O~f1INIMAL 3~BERIOUSRE"CTIVITY: 0 1~5LIGHT ~DgEVEREsrec 1 AL: NONE 2=MODER A 1"E

t"'~ "nl)OU" J "t~~D1F:NTg E:<rOSURE LIHIT9. PPH

09'.'" ACG Itt OTHERcrn'raf'JENT CI\S t"o. ;.. PEL TLV LJMJ r -HAZARD

SODIUM CAR8at~TE (4~7-17-e! 77~ t~a~~ NONE t~NE IRft ITANT

PHYS l*.:l\l. J'RtlPER T.IEB ";" \

BOILING POINT, DEG F: N/I\ \.IAP{JR FRE9S\1RE. MH t4G/20 DEO C: N/AMELlING POINT, DEO F: 1~6" VAPOR DENSITY CAIA-I): NI'AsrECIFIC GRAVITY (WATERml): ;;!. :733 WATER SOt.U8ILITY, 7.: 30ArPE,,"""'CE AND DOOR: E'J"r'UR"TION RATE (BUTYL ACETATEe1): NI'A

ODORLESS. WHITE PO"'D~ 00 GP.r...tULM 5tL1 D on CRYSTAL.

FfRRf ~TO.MEA8URE9

,cPl1'20 MATERIAl R"FETY DATA SJ'fEET PO ~

,

MOUTI" TO HI Ut~ONSCIOU8 OR <:nfMJLSING PERSON.

ffE/\L TH IIAlARD INFORMATION ";' PRIMARY ROUTES OF EXPOSURE: It",fAlA r lOt... SKIN OR .EYE CONTACT.

SIGNS AND SYMPTOMS OF EXP09Uf~EI~ALATION: BREATHING DUST t1AY IRRITATE THE tlJSE AND THRrnT AND

CA'J5E COUGJ~ING AND CI-teST DISC(:I"1Ftlf11 EXCESSIVE CONTACT CAN CAUSE DAMAGETO THE NASAL SEPTl.I1.

EYE C~TACT: DUSTS WILI- JRR I TATE TfiE EYEh At"D PRtLONQED CONTACTMAY DAMAGE THE EYES.

SKIr~ CONTACT: PRCLONGED OR REPEAlED CONTI\CT WITH THE DUST MAYIRRITATE TtlE ~IN WITH BLI5TEnrNG AND~"e:f)tES9. 9tLUTICN9 MAY CAUSE9EVERE I RRITATICr. DR BURNS. -

S""'LLD..JED: 9t.JALLOOIt~G LARGE OUAt~TITJE9 MAY CAUSE NAUSEA, VOMITING.ABDCMIr~AL f'A If.,. DIARRt£A AI'ID CDLLI\P9E.

CJnONIC EFFECTS OF EXPOSURE.: t1/\Y ~AtJBE S~"!3ITIZATION.HE:DICAL Ca-lDITIONS GEI'£RAlLY AGtJRAVt,TFD BY EXPf.J8URE: ~--

"'ONE REPOR TED.

10X ICI Toy [\t'\TAo

ORAL:

RATS LD~O = 4 G/KQ

DERMAL: RABBITS ~OO MG/24 ..IA, 110DEA"lE IRRITATION

It.lfALATION: NO DATA FWND.

CARC If-QGE"NIC ITY: TH IS f1ATEniAl IS f~O r COr-iSI DERED TO BE A CARCINOgENBY THE r"ATIOt~AL TOXICD..OGY PAlJGRAM, tIE I,..rERI'IATIc:I'lAL AgENCY FORRESEARCH CJ'~ CANCER, OR TttE OCf:vrl\TIUNAL FI\FETY AND HEAL TW-t ADMINI STRATION

0 mER DA T A: t-irnE

'.PERA""'IAI. rp'IIECl 108'1 ' VEt"'TILA1'l[1'~: LOCAL MECHANICAL E'XHAU8T VENTILATION CAPABLE OF MAIN-

T/,tNJI'G DUST EMISSIONS AT THE" POJNT OF USE BELOW THE PEL.

RESP IRI\TORY PROTECTION: IF USE C[1'.I() I TIOl'J9 GEt'ERATE DUSTS, WEAR A NIO8H-r,PF A OVED RE5PIRAT~ APPROPRIA1E FOO TI1J5E EMIBSION LEVELS. APPROPRIATERESP IRATORS MAY BE A FULL FACEPJECE OR A '~LF MASK AIR-PURIFYINg CART-R lOGE RESPIRATOR WITH pnRTIC\.R.nTE r IL TEAS, A SELF-COr~TAINED BREATHINg"FPARATUS IN THe: "R~SSURE DEMNfn '--JOE, DR A 5\.rPLIEO'-AIR RESPIRATm.

EYE PROTECTIOt~: CI.fE:MICAL GOGGL~S AND FULL FACE SHIELD. IT 19 QEIERALLYRECOGNIZED THAT Ca'lTACT LEJ-ISES SHOULD NOT BE ,-I(]ft,~ WHEN WORKING WITHCtEMICAL~ 8~C~~ CONTACT L~N~~ MnY CONTn!8U~ TO TH~ ee:~ft ITY ~ ANEY~ It~RY.

PPOTECTI VE CLOTHING: LONQ-Rl EE\'En 9"IRT. TRlltJSERB. SN=ETY BHCEB. RUBBERGLDVE8. AND RUBBER APRON. .

;' '.,Ol.tER PROTECTIVE tEASt~ES: I\N J:'YFW" AI , "'.NO SAFETY SHOt.£R 9~OVLD BENEAftBY AND READY FOR USE.

" FIRE N-IO F:XP'.~IO"I JNFORMATION

~

xFLAS.. PO INT, DEQ F: N/A FLA~BLE L It1ITS IN AIR,M~THOD USED: N/A LOWER: N/A UPPER: N/A

EX1INGUISlfINQ MEDIA: USE '-H\IER SrnAY. DRY CHE:t1ICAL, CO2, OR ~cOt-IJLJ:'QAf1. .

SPECIAL FIRE FIGHTINg PROCEDURES: rtJ1F: f"lGlfTERS SlfnULD HEAR £ELF-ClJ'-lfi\INe:n BREATHING AP""RA1US A"'n '""LL rRUtEc, Ive CLunil Nt;. USE WATERSPRAY TO COOL I"EARS"{ C[!Nlr,INEffS I\fm niRUCrURE5 EXPOSED TO FIRE.

PPtlu: 04"21203 11:30:38 2"1 tU\t t~"A J t-IVO ICE: 21q~3:5814C\IST 2!221q~O

P1120 MATER tAL MFET.Y DATA 9HEET PO 3

~--- ,,

Ut.JU9UAL F IRE AND EXPL09J ot~ 1ft-It-ROB:IGNITIDt~.

EXTINGUISH ALL NEARBY SOURCES OF

~---

'~ZAROOUS REACTJVITY---' ~-

SfABJLITY: STABLE. POLYMERIZATION: WILL NOT OCCUR

CONVITIONS TO AVOID: DPEr.. rt."'leS, WELDING ARCS, OR DTffER HIgH TEM-

rERATURE SOURCES I.a-fICH MAY INDUCE Tf'ERMnL DECt:R1rnsITIm.

HATERIALS TO AVOID: ACIDS.~

HAZ"RDOUS DECD1PO9IT ICJII PRUUU(; IS:.. MI\Y t_JBERI\TE CARBON HOr-IJX IDE.CARB ON 0 lOX I DE OR OX] DEB tF arm I (Ir1.

SPILL, I_E"K, " n "19"'09"'- PRUCEDlmE8 I\CTION TO T"KE FOR SPILLS OR LEAKS: I-EAR PROTECTIVE l=OUIPMENT INCLUDINg

nUB BErt BOOTS, RUBBER GLOVES. RUBDen "rRDN. "NO A SELF-CONTAINEDBREnTffING APPARATUS IN TJ-te: pn~SSlmE DEMI\ND MODE DR A BUPPLIED-AIRnESPIRATDn. IF Tf-E SPILL t1R LEnK 19 SMALL, A FULL FACEP IECE AIR-run I FYIN9 CI\Rln I DQE nESP InnTon EOV!prED WI T'i PARTICULATE FIL TERB MAY BESAT I SF'AC100Y. IN ANY EVEr"T. nL'.,nY9 WEnR EYE PROTECT ][1'1. Fon SMALLsr ILLS, 81£EP UP AND DIsrOSE tF If~ nUT-nrrnOVED wnSTE CONTAI NI!:RS. FOOLI\r!GE 9P ILLS. !3tfOVEL INTO UOT~""'P"UVEO WASTE cor"TAIN~RS. K~E" OUT OFSEWERS, STORM DRAINS. sunrACE HA'fER~, nND SOIL.COf'!f"LY WIT'" ALL.. Af'f'LICABLe: t;DVEP.Nt"ENTnL. nE9ULI\TIDNS or.. SPILL R~PCRTING,

AND t-W'fOLIN9 AND DlepDSAL OF ~ST~.

DISPOSf'lL t1ETHOD9: DIsrOSE Or-- COMTf'I'1It.fl\TED PRODUCT AND H"TER I~9 USEDIN Ct_EnNIN9 ur SPILLS un LEAKS If-! A t1lVmEA I\prnOVED FOR THIS MATERIAL.CUNSUL..T APPRDPRIA1E FEDEnAL. STATE nND LOCAL REGULATORY AGENCIES TO"SCERTI\ I f~ ~R orER Dr Sf'DSAL.. rR DC~DtmES.r.rnTE: -EMPTY CONTAINERS CAN "".IIE RES lQUEa. gASES N~D MISTS "ND ARE

SUDvECT TO PRDrER WASTE [)ISf"(1~t_, n9 A80VE.

sr"EC I"l. ~"~cl\Ur l(W\Ig STOR"GE Af"D HAf"DLlt"g PREC"tlT Il"f9: R IIXtE IN A COOL. DRY, WELL-VENTILATED

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r,!OT GET IN EYES. (J'" SJ<IH. OR '"1\1 Ct.nTHINg.

REPAIR AND MAINTENANCE rREC"\}rlr.'r-.f~' NJNE.

OTJfER PRECAUTIONS: CONT"INF.f~9, E'JEH "TIIOSE r}tAI' fll\VE BEEN EMPTIED, WILL

RETAIN PRODUCT RESIDUE: "ND Vt\FORS. "LWAYS OBEY ttAZI\RD WARNINgg AND

liN.,OLE EMPTY CaNT AI NERS "9 I r: 1 J 'EY "'ERE FU-L..

--FOR Af)()ITft}t'II\L It-fFonI1ATION-'-~~ :'-

CtJl'.fT"CT DWQl.AS EisNER. TECI't"ICI\L UJ RECTOR. VAt., WATERS Ic ROQERS INC.

DURING BU8Ir..e:S8 Ht1\.~A. rnCIF"IC lIME (206)1147-~"lt..,., ,

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DR It1PLIED WARRnr~TIES If" MP:p.r:I"',..r"BILIt-y "'~O FITNESS rDR A rARfICULARpunrQ5E, WITH n~SPECT 10 lIfe: ~nUDUCT OR l""'DnmTla'8 rRDYIIED ~"EIN. -*

"LL It.n:OR'11\Ttt:l'~ APPEI\RING IlEttEIN JS BASED UPON D"TA OBTAl8'ED FROM THE

nl'\f.I'JF~TUREft At~Dl'on ~~CtJGHJZED 1l=:C,tt.llcnL sounCES. WHILe: THe: INfC"ORMA-TIUN IS B~LIEve:O ~U BE nccvnnTE. vw~n MnK~S r«J REPRESENfATIONS AS TOITS ACCURACY DR SUP'FICIENCY. COf'JDJrID1'f9 Uf'" USE ARE n~YDND VWM*S CON-

T~OL N~D THEREI""ORE VSERS ME r!Esrmt318LE. TO VEnIFY THIS DATA \:limEn

THEIR m.,N OPERATINQ CU~DITltJN!! TU DE rERMIfE Wt-IETHEn 1.£ pnCDUCT ISSUI T"BLE FDR TliE In PARTI C\A.i\" f"

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RELATE TO ITS USE IN' COMB Ir.IAT TnN HI1-'~ At"Y OTHER MATERIAL m IN ANY OTJ.£RF'RCCESS.

END t1 S D 8 ****.*** (J F

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