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kanai/seminar/pdf/Lit_Kimura_M1.pdf · 6a N Me OTf N (B) CF3CH20H 70 oc toluene, rt 88% C02Me \ (A) TfOH (leq) CH2C12, -40 OC 1) KCN aq. CH2C12 2) NH20H.HCl, NaOAc, MeOH 60 % from

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Page 1: kanai/seminar/pdf/Lit_Kimura_M1.pdf · 6a N Me OTf N (B) CF3CH20H 70 oc toluene, rt 88% C02Me \ (A) TfOH (leq) CH2C12, -40 OC 1) KCN aq. CH2C12 2) NH20H.HCl, NaOAc, MeOH 60 % from
Page 2: kanai/seminar/pdf/Lit_Kimura_M1.pdf · 6a N Me OTf N (B) CF3CH20H 70 oc toluene, rt 88% C02Me \ (A) TfOH (leq) CH2C12, -40 OC 1) KCN aq. CH2C12 2) NH20H.HCl, NaOAc, MeOH 60 % from
Page 3: kanai/seminar/pdf/Lit_Kimura_M1.pdf · 6a N Me OTf N (B) CF3CH20H 70 oc toluene, rt 88% C02Me \ (A) TfOH (leq) CH2C12, -40 OC 1) KCN aq. CH2C12 2) NH20H.HCl, NaOAc, MeOH 60 % from
Page 4: kanai/seminar/pdf/Lit_Kimura_M1.pdf · 6a N Me OTf N (B) CF3CH20H 70 oc toluene, rt 88% C02Me \ (A) TfOH (leq) CH2C12, -40 OC 1) KCN aq. CH2C12 2) NH20H.HCl, NaOAc, MeOH 60 % from
Page 5: kanai/seminar/pdf/Lit_Kimura_M1.pdf · 6a N Me OTf N (B) CF3CH20H 70 oc toluene, rt 88% C02Me \ (A) TfOH (leq) CH2C12, -40 OC 1) KCN aq. CH2C12 2) NH20H.HCl, NaOAc, MeOH 60 % from
Page 6: kanai/seminar/pdf/Lit_Kimura_M1.pdf · 6a N Me OTf N (B) CF3CH20H 70 oc toluene, rt 88% C02Me \ (A) TfOH (leq) CH2C12, -40 OC 1) KCN aq. CH2C12 2) NH20H.HCl, NaOAc, MeOH 60 % from
Page 7: kanai/seminar/pdf/Lit_Kimura_M1.pdf · 6a N Me OTf N (B) CF3CH20H 70 oc toluene, rt 88% C02Me \ (A) TfOH (leq) CH2C12, -40 OC 1) KCN aq. CH2C12 2) NH20H.HCl, NaOAc, MeOH 60 % from
Page 8: kanai/seminar/pdf/Lit_Kimura_M1.pdf · 6a N Me OTf N (B) CF3CH20H 70 oc toluene, rt 88% C02Me \ (A) TfOH (leq) CH2C12, -40 OC 1) KCN aq. CH2C12 2) NH20H.HCl, NaOAc, MeOH 60 % from

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