Keith Christiansen 93 Giant Mo

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    SEG SP-2 GIANT ORE DEPOSITS

    THE GENESIS OF GIANT PORPHYRY MOLYBDENUM DEPOSITS

    J. D. Keith, E. H. Christiansen Department o

    Geo!o"#, $ri"ham %o&n" 'ni(ersit# Pro(o, 'tah'.S.A., )*+*

    an

    R. $. Carten

    '. S. Geo!o"ia! S&r(e#, /a0a# Shoo! o /ines

    Reno, Ne(aa

    '.S.A., )13-*3

    A$STRACT

    Giant porph#r# mo!#4en&m eposits are 4est e5emp!iie4# the C!ima5

    an Henerson eposits in Co!orao. The hi"h "raes o these eposits are

    pro4a4!# inherite rom ma"mati mo!#4en&m onentrations o a4o&t * to

    ppm, 6hih are hi"h or meta!&mino&s rh#o!iti ma"mas that a(era"e a4o&t 2

    ppm mo!#4en&m. Hi"h ma"mati mo!#4en&m onentrations in meta!&mino&s

    ro0s appear to 4e re!ate to hi"h ma"mati o5#"en &"aities 72 or 8 !o" &nits

    a4o(e 9:/ o5#"en 4&er; an are orre!ate 6ith hi"h nio4i&m onentrations.

    Hi"h o5#"en &"aities are !i0e!# inherite rom a!-a!0a!ine or !amproph#ri

    preeessors. Hi"h nio4i&m an mo!#4en&m are re!ate to e5treme rationationo rh#o!iti ma"mas. /&h hi"her onentrations o mo!#4en&m 7 < =,ppm;

    in the ore !&i 7an the &po!a ma"ma; are pro4a4!# ahie(e4# r#sta!!i>ation

    in the eeper portions o a ma"ma ham4er aompanie 4# on(etion o the

    e(o!(e !i?&i to the &po!a an (o!ati!e !&5in".

    E5p!oration riteria or a "iant, hi"h-"rae eposit in!&e@ =; a tetoni

    settin" that iniates a han"eo(er rom ompressiona! to e5tensiona! tetonis,

    2; thi0 ontinenta! r&st at the time o eposit ormation ma# eno&ra"e e5treme

    ierentiation an r&sta! ontamination, 8; an isotopia!!# >one ma"ma ham4er

    iniati(e o a !on"-!i(e heat so&re, *; a !ar"e, s&4-(o!ani, entra!-(ent

    ash

    !o6ome s#stem that er&pte !ess than = km3 o rh#o!ite, an ; hi"h nio4i&monentrations 7 < 3 ppm; in a s&4a!0a!ine, ma"netite-4earin" rh#o!ite.

    2)

    INTROD'CTION

    The "rae an tonna"e ata o eah

    eposit ite in this paper, as 6e!! as the

    assi"nment o eah eposit to a "enera! !ass

    7Ta4!e =;, is moiie rom the s#stem

    presente in Carten et a!. 7in press;. Deposits

    !iste in Ta4!e I are "eo"raphia!!# !oate in

    :i"&re =. Deposits onsiere in this paper

    are restrite to porph#r# /o eposits 6hih

    harateristia!!# o not ontain reo(era4!e

    C& an porph#r# /o-C& eposits 6hih

    ontain opro&t or 4#pro&t C& an "raes

    o /o 6hih a(era"e "reater than .% /o .

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    2)+ SEG SP-2 GIANT ORE DEPOSITSSEG SP-2 GIANT ORE DEPOSITS 2)3

    Ta4!e 1. Grae an tonna"e o "ranite-re!ate /o an /o-C& eposits 7moiie ater

    Carten et a!., in press;.

    Produ!ion " r#$#r%#$

    % Mo % &u m#!ri

    D#'o$i!$ oun!r( )r*d# )r*d# !on$ u!o++,1-

    GRANITE-REBATED No/ HIGH-SIBICA RH%OBITE-ABKABINE S'ITE

    10 &im*2 US&O -.1 45 -.1- min#*6#

    -.7- 5-4 )#oo)i

    0 H#nd#r$on US&O -.57 -.18- )#oo)i

    % Mor#+#r#n#

    S.R. 9**#: '#r$. omm.: 155-

    S.R. 9**#: '#r$. omm.:

    155- un'u6i$;#d d*!*

    -.8 -.1- )#oo)i un'u6i$;#d d*!*

    -.141 44 -.-- )#oo)i

    30 Ur*d US&O -.-5 1 min#d

    Bi) B#n USMT -.-5- 1-5 -.-3 min#*6#

    -.-58 34 -.-- )#oo)i

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    SEG SP-2 GIANT ORE DEPOSITS 2)3

    310 E*$! ?ounr*d UR?H -.1 -.-- 181 -.-3- )#oo)i ?. Ro2o J D.E. R*n!*

    =ri!. omm.: 158

    -.-87

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    .(

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    SEG SP-2 GIANT ORE D EPOSITS 2)121 SEG SP-2 GIANT ORE DEPOSITS

    7Ta4!e = Carten et aI., in press;. Porph#r#

    /o eposits are &rther s&4i(ie into those

    assoiate 6ith hi"h-si!iCa or a!0a!ine rh#o!ites

    6hih are rih in potassi&m, !&orine, an

    inompati4!e trae e!ements an are

    e5emp!iie 4# the C!ima5 eposit 7a!4eit apremier e5amp!e;, an those assoiate 6ith

    !ess si!ii "ranitois that e5hi4it a(era"e

    onentrations o !&orine an inompati4!e

    e!ements.

    E5amination o the "rae an tonna"e

    o += porph#r# /o an /o-C& eposits 7:i".

    2; iniates that a ontin&&m in eposit "raes

    an tonna"es ma# e5ist ho6e(er, most

    eposits onsist o to 2 mi!!ion tons o

    ore, 4&t on!# =2 eposits ontain more than

    2 mi!!ion tons o ore. These =2 eposits an4e onsiere "iant in terms o tonna"e, 4&t

    on!# t6o eposits - C!ima5 an Henerson -

    ontain o(er 2 mi!!ion tons o hi"h-"rae

    ore 7:i". = an 2;. C!ear!#, the .most

    eonomia!!# esira4!e mo!#4en&m eposit

    m&st 4e in this !ass an 4e "iant in terms

    o 4oth tonna"e 7-2 mi!!ion tons; an "rae

    , .=% /o;. Proesses an ators 6hih

    ontri4&te to the e(e!opment o these t#pes

    o eposits 6i!! 4e emphasi>e.

    The "enesis o these eposits in !i"hto more reent 6or0 on the partitionin"

    4eha(ior . an ma"mati a4&nanes o

    mo!#4en&m 6i!! a!so 4e re(ie6e. Inasm&h

    as C!ima5-t#pe ma"mas are oten e?&ate

    6ith topa> rh#o!ites, reent st&ies on the

    e(o!&tion o topa> rh#o!ites 6i!! 4e e5amine

    a!on" 6ith the (o!ani ro0s that are

    o"eneti 6ith the C!ima5-t#pe Pine Gro(e

    an 9&esta eposits in so&th6estern U!*; an

    northern Ne6 /e5io respeti(e!#. T6o !ar"e

    tonna"e eposits that are !ess 6e!!harateri>e, 4&t appear to not 4e C!ima5

    t#pes are the 9&art> Hi11: A!as0a eposit an

    /t. To!man, ashin"ton eposit proesses

    that ma# ha(e ate to pro&e the !ar"e

    tonna"es 6ith moerate-"rae ores 6i!! 4e

    re(ie6e as 6e!!.

    Se(era! st&ies in reent #ears ha(e

    !ear!# emonstrate that the mo!#4en&m in

    porph#r# eposits is eri(e in toto rom

    the ma"ma or the res&!tin" sto0s 7Stein an

    Hannah, =1) Carten et aI., =1))a, =1))4

    hite et a!., =1)=;. This 4ein" the ase, some

    ators that mi"ht pro&e a hi"h-"rae

    eposit seem reai!# apparent. These in!&ethe initia! mo!#4en&m ontent o the parent

    ma"ma an the inrease in mo!#4en&m

    ontent 6ith ierentiation. The so&re re"ion

    or the ma"ma an meta! has 4een propose

    as resiin" in the &pper r&st 7a!!ae et a!.,

    =13);, !o6er r&st 7hite et a!., =1)= Stein

    an Hannah, =1);, an mant!e 7estra an

    Keith, =1)=;. Re!ate ators that o&!

    ontro! the "rae o the eposit in!&e ho6

    eeti(e!# mo!#4en&m is se?&estere 4#

    ear!# ma"mati minera!s 7Keith an Shan0s,=1)); an ho6 stron"!# it is partitione into

    an .e(o!(e a?&eo&s phase 7Cane!a, =1)1a

    Kepp!er an #!!ie, =11=;. An# is&ssion o

    6hat ators or proesses are responsi4!e or

    (ariations in tonna"e an "rae m&st 4e"in

    6ith the so&re an ierentiation proesses

    o the ma"ma. Proesses that ontro! the

    !oation an &ration o mo!#4enite

    eposition rom the a?&eo&s phase a!so

    o4(io&s!# ontro! the "rae. These in!&e

    m&!tip!e sto0s ormin" o(er!appin" ore4oies an steep hemia! an therma!

    "raients aro&n the sto0 or p!&ton.

    The tonna"es oporph#r# mo!#4en&m

    eposits are a!so si"niiant!# aete 4# the

    ators &st mentione. Ho6e(er, aitiona!

    ators that are perhaps more iret!# !in0e

    6ith the tonna"es are the si>e an 6ater

    ontent o the parent ma"ma ham4er, an the

    si>e an shape o the ens&in" pro&ti(e sto0

    or &po!a. :or e5amp!e, i minera!i>ation

    o&rs in a 4roa, sha!!o6 &po!a a!on" theroo o a !ar"e 4atho!ith, then the tota! amo&nt

    o ma"mati 6ater an meta!s partiipatin" in

    minera!i>ation ma# a!so 4e !ar"e, 4&t

    &no&se. The ens&in" eposit o&! 4e

    !ar"e, 4&t !o6 "rae.

    /ost o these minera!i>ation ontro!s

    ha(e 4een is&sse or re(ie6e 4# other

    6or0ers. Ho6e(er, the essentia! ?&estion that

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    21 SEG SP-2 GIANT ORE DEPOSITSSEG SP-2 GIANT ORE DEPOSITS +

    -.3in" proesses

    assoiate 6ith themM e 6i!! is&ss this

    ?&estion a!on" 6ith 6hat are the 4est

    e5p!oration harateristis to &se in min" a

    "iant eposit.

    &LASSIFI&ATION AND GENERAL&HARA&TERISTI&S

    /ost !assiiation shemes or

    porph#r# mo!#4en&m eposits i(ie them

    into t6o main "ro&ps. These in!&e

    C!ima5-t#pe (ers&s ?&art> mon>onite t#pe

    7hite et a!., =1)=;, "ranite (ers&s

    "ranoiorite t#pes 7/&tsh!er et a!., =1)=;,

    a!-a!0a!ine (ers&s a!0a!i-a!i 7an a!0a!i;

    t#pes 7estra an Keith, =1)=;, an

    !&orine-enrihe (ers&s !&orine-eiient

    t#pes 7Theoore an /en>ie, =1)*;. One o

    the t6o !asses is "enera!!# t#piie 4#

    hi"h-si!ia rh#o!ites or "ranites that are rih in

    potassi&m, !&orine, an inompati4!e trae

    e!ements. Charateristis o this !ass are

    e5emp!iie 4# the C!ima5 eposit. The other

    !ass is t#piie 4# a !ess si!ii a!-a!0a!ine

    "ranitoi that e5hi4its a(era"e onentrations

    o !&orine an inompati4!e e!ements.

    C!ima5-t#pe eposits are o primar# onern

    in this paper 4ea&se the# e5hi4it 4oth

    E

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    SEG SP-2 GIANT ORE DEPOSITS 21=21= SEG SP-2 GIANT ORE DEPOSITS

    hi"h-"raes o mo!#4en&m an !ar"e

    tonna"es 7Si!!itoe, =1) hite et aI., =1)=;.

    Ho6e(er, 4oth t#pes 6i!! 4e e5amine in

    orer to &nerstan the proesses responsi4!e

    or ormation o hi"h-"rae eposits.

    The Henerson porph#r# mo!#4en&m

    eposit is one o the premier e5amp!es o a

    "iant mo!#4en&m eposit in terms o 4oth

    tonna"e an "rae 7323 mi!!on tons o .=3=!

    % /o Ta4!e =;. In aition, the most reent

    st&ies 7Carten et a!., =1))a Seeor, =1));

    represent a &!mination o 3 man #ears o

    "eo!o"ia! in(esti"ation ma0in" it one o the

    most 6e!!-st&ie porph#r# eposits in the

    6or!.

    /OB%$DEN'/ AND T'NGSTEN

    GEOCHE/ISTR% IN IGNEO'S

    ROCKS

    Inasm&h as mo!#4en&m an

    t&n"sten o&r in the same "ro&p o the

    perioi ta4!e an e5hi4it man# simi!arities in

    "eohemia! 4eha(ior, it is instr&ti(e to

    ontrast an ompare the 4eha(ior o 4oth

    e!ements to &nerstan the ore-ormin"

    proess. :or e5amp!e, 4oth mo!#4en&m

    an t&n"sten are oten se?&estere 4# the

    same ma"matiphases. S&h a omparison is

    essentia! 4ea&se

    the partitionin" 4eha(ior o + mo!#4en&m

    has not 4een in(esti"ate e5perimenta!!#

    ho6e(er, this is the (a!ene that ma# 4e most

    important in porph#r# s#stems an is the

    (a!ene ommon!# e5hi4ite 4# t&n"sten.

    The onentration o 4othmo!#4en&m an t&n"sten in the mant!e is!ess than in C=

    honrites, iniatin" that a si"niiant

    ration o Earths ori"ina! eno6ment o

    these meta!s no6 resies in the ore 7Ne6som

    an Pa!me, =1)*;. A!tho&"h mo!#4en&m an

    t&n"sten "enera!!# e5hi4it stron"!#

    inompati4!e 4eha(ior in r#sta!!i>in" ma"mas

    &e to ormation o !ar"e o5#-anions, &ner

    s&iient!# re&in" onitions 7:e-:eO;

    these meta!s ma# 4e stron"!# partitione into

    a !i?&i meta! phase, as apparent!# happene

    &rin" ore ormation. The 4est estimates o

    the mant!e a4&nane o mo!#4en&m an

    t&n"sten are .1 ppm an .= ppm,

    respeti(e!# 7Ne6som an Pa!me, =1)*

    Ne6som et a!., =1)+; 6hereas &pper r&sta!

    a4&nanes are =. ppm an 2. ppm,

    respeti(e!# 7Ta#!or an /C!ennan, =1);.These ata s&""est that t&n"sten is more

    inompati4!e an thereore more enrihe in

    the r&st than is mo!#4en&m 74# a ator o

    2 or an on!# 2 or /o;. Ne6som an

    Pa!me 7=1)*; attri4&te the more stron"!#

    inompati4!e 4eha(ior o t&n"sten to an

    o5iation state o + , 6hereas the o5iation

    state o mo!#4en&m (aries rom + to 8

    &ner terrestria! onitions. T&n"sten ma#

    e5hi4it an o5iation state o * in some o

    the most re&e "ranitoi ma"mas 7C#"anan Cho&, =1)3 Cane!a, =1));. Ne6som

    an Pa!me 7=1)*; s&""est the mo!#4en&m

    (a!enes !ess than are perhaps more

    ommon an e(iene o a * (a!ene has

    4een o4ser(e in meta!-si!iate partitionin"

    e5periments. A (a!ene o * " or

    mo!#4en&m mi"ht iniate that its

    "eohemia! 4eha(ior 6o&! 4e simi!ar to Ti

    7simi!ar har"e an ioni rai&s;. A

    orre!ation in the a4&nane o /o an Ti has

    4een o4sere 4# K&roa an Sane!! 7=1*;

    or some i"neo&s ro0s.

    Ta0er an Cane!a 7=1)3; a!so

    s&""est that the ominant o5iation state or

    mo!#4en&m in si!iate ma"mas (aries rom

    * to 8 4et6een ni0e!-ni0e! o5ie an

    "raphite-methane 4&ers. /o!#4en&m

    4eomes more inompati4!e in ma"netite an

    i!menite as o5#"en &"aCit# is inrease

    7Ta0er an Cane!a, =1)3 $o&ton et a!.,

    =1)3;.

    Assoiate a!0a!ine mai ro0s

    The presene o !amproph#re i0es at

    C!ima5, Henerson, 9&art> Hi!!, an Chia"o

    $asin an o >one ma"ma ham4ers that are

    !oore 6ith a!0a!ine mai ro0s at Pine

    Gro(e, 9&esta, an Gri>>!# Pea0

    7mi-Tertiar# (o!ani ie! in entra!

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    Co!orao; iniate that mant!e-eri(e mai

    a!0a!ine ma"mas ma# represent a portion o

    the parenta! ma"ma o C!ima5-t#pe rh#o!ites.

    There is no isotopi onstraint or e!iminatin"

    them as a portion o the so&re materia!.

    A!0a!ine i"neo&s ro0s 7minettes, !amproites,

    an nephe!inites; rom the Ceno>oi (o!ani

    ie!s in the E!0hea /o&ntains in Co!orao,

    the Be&ite Hi!!s, #omin", an the 6estern

    Co!orao P!atea&, U!*;: ha(e epsi!on N an

    epsi!on Sr (a!&es 7Thompson et aI., =11=

    o!!mer et aI., =1)* Tin"e# et aI., =11=; that

    are not ar remo(e rom those e5hi4ite 4#

    C!ima5-t#pe s#stems. Despite the "enera!!#

    !o6 onentration o mo!#4en&m in the

    mant!e 7.1 ppm;, mant!e-eri(e a!0a!ine

    ma"mas orme 4# e5treme!# sma!! e"rees

    o partia! me!tin" P = %0 ha(e s&4stantia!!#

    hi"her onentrations o mo!#4en&m that

    6o&! not !o6er the a(era"e mo!#4en&m

    ontent o a !ar"e!# r&sta! me!t. :or

    e5amp!e, Ne6som an Pa!me 7=1)*; note

    that ontinenta! a!0a!i 4asa!ts ha(e hi"h

    ontents o inompati4!e e!ements in!&in"

    mo!#4en&m onentrations &p to *. ppm

    76e!! a4o(e the r&sta! a(era"e o =. ppm;

    an Ne6som et a!. 7=1)+; report as m&h as

    +.8 ppm /o in a!0a!ine oean is!an 4asa!t.

    Shoshonites, minettes, an me!anephe!inites

    rom entra! U!*; ontain .2 to 8. ppm /o

    7&np&4!ishe ata;.

    The so&re re"ion or mai a!0a!ine

    ma"mas on the ontinents is oten propose to

    4e the metasomati>e !ithospheri mant!e.

    Hattori et a!. 7=112; e5amine the meta!

    ontent o ma"mati s&!ies rom

    metasomati>e 7amphi4o!e-4earin"; periotite

    5eno!iths rom a (ariet# o!oea!ities a

    5eno!ith rom N&ni(a0 Is!an, A!as0a

    7&ner!ain 4# ontinenta! r&st; ontaine

    ma"mati s&!ie 4!e4s 6ith &p to + ppm

    mo!#4en&m, 6hereas s&!ie 4!e4s in

    5eno!iths rom other !oa!ities ontaine no

    eteta4!e mo!#4en&m. Ins&iient ata are

    a(ai!a4!e to spe&!ate on 6hether the

    mo!#4en&m ontent o !ithospheri mant!e o

    ierent Pream4rian pro(ines ma# (ar#

    eno&"h to ao&nt or the o&rrene o

    porph#r# mo!#4en&m pro(ines.

    O5iation state an mo!#4en&m

    inompat

    i4i!it# in ma"mas

    Perhaps the "eohemia! harateristi

    inherite rom the so&re re"ion that is most

    ritia! or the e(e!opment o porph#r# /o

    ma"mas is the o5iation state o the ma"ma.

    This parameter is &namenta! 4ea&se a

    4&er para!!e! o5iation state is not easi!#

    moiie &rin" ma"mati rationation

    7Carmihae!, =11=;. This harateristi ma#

    aet the o5iation state o mo!#4en&m

    6hih in t&m aets ho6 inompati4!e it ma#

    4eha(e &rin" r#sta! rationation. As

    pre(io&s!# note, mo!#4en&m ma# e5hi4it

    (a!enes o * an 8 4et6een ni0e!-ni0e!

    o5ie an "raphite-methane o5#"en 4&ers

    7Ta0er an Cane!a, =1)3;. /ost s&4&tion

    re!ate 7a!-a!0a!ine; an !amproph#ri

    ma"mas ha(e o5iation states ro&"h!# 2-8 an

    *- !o" &nits a4o(e ni0e!-ni0e! o5ie

    respeti(e!#. I the tren o inreasin"

    inompati4i!it# o mo!#4en&m 6ith

    inreasin" 2 note 4# Ta0er an Cane!a

    7=1)3; ontin&es, then mo!#4en&m ma#

    4eome e(en more inompati4!e in

    a!-a!0a!ine an !amproph#ri ma"mas 6ith

    hi"h o5#"en &"aities 6here mo!#4en&m

    (a!enes "reater than * ma# e5ist.

    E(iene o (aria4!e inompati4i!it#

    or mo!#4en&m in (ario&s ro0 series sho&!

    4e note here. R&4ii&m is insensiti(e to

    han"es in the o5iation state o the ma"ma

    an an 4e &se in (ariation ia"rams as a

    monitor o ma"ma e(o!&tion. A p!ot o thea4&nane o t&n"sten (ers&s r&4ii&m in

    resh (o!ani ro0s ran"in" in omposition

    rom mi-oean ri"e 4asa!ts to hi"h-si!ia

    rh#o!ites sho6s !inear, stron"!# inompati4!e

    4eha(ior o(er a ran"e o a!most o&r

    orers-o-ma"nit&e 7:i". 8;. Ho6e(er, the

    enrihment o mo!#4en&m in the same ro0

    series is m&h more s&4&e inreasin" on!#

    t6o orers o ma"nit&e in aition, the

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    218SEG SP-2 GIANT ORE DEPOSITS218 SEG SP-2 GIANT ORE DEPOSITS

    enrihment tren 4ranhes aorin" to ro0

    t#pe 7:i". 8;. Oean is!an 4asa!ts an

    a!0a!ine ro0s e5hi4it a stron"er enrihment

    tren than a!-a!0a!ine 7meta!&mino&s;

    (o!ani ro0s (er# re&e stron"!#

    rationate ro0s s&h as ma&sanites,on"onites, an some topa> rh#o!ites, s&h as

    Spor /o&ntain, e(en sho6 sharp!# !o6er

    a4&nanes o mo!#4en&m 6ith inrease

    rationation, espite stron" enrihment o

    t&n"sten 7&p to 8-3 ppm E. H.

    Christiansen, &np&4!ishe ata Piha(ant et

    aI., =1)3;. The ierenes in the 4eha(ior o

    mo!#4en&m ma# 4e the res&!t o (aria4!e

    o5iation states 6ith mo!#4en&m in a !o6er

    o5iation state 78 "7MQ 4eha(in" more

    ompati4!# than at hi"her o5iation states7+ , simi!ar to t&n"stenM; 6here mo!#4en&m

    appears to 4e moerate!# inompati4!e.

    The o5iation states o most porph#r#

    mo!#4en&m s#stems are not 6e!! onstraine.

    Keith 7=1)2; emonstrate that the o5#"en

    &"ait# o the Pine Gro(e ma"ma 6as a4o&t

    2 !o" &nits a4o(e ni0e!-ni0e! o5ie 7simi!ar

    to most a!-a!0a!ine ro0s;. Christiansen et

    a!. 7=1)+; o&n that the ma"mati o5#"en

    &"ait# o the topa>-4earin" Cha!0 /o&ntain

    rh#o!ite 7oma"mati 6ith C!ima5; 6as a!soa4o&t 2-8 !o" &nits a4o(e ni0e!-ni0e! o5ie.

    Ho6e(er, some topa> rh#o!ites rom

    6est-entra! U!*; 7in!&in" Spor /o&ntitiiJ.;

    6ere o&n to 4e s&4stantia!!# more re&e,

    6ith ma"mati 2 (a!&es 2 &nits 4e!o6

    ni0e!-ni0e! o5ie. Thereore, this is

    permissi(e e(iene that C!ima5-t#pe ma"mas

    6o&! e5hi4it moest enrihment o

    mo!#4en&m 6ith ontin&e rationation,

    pro4a4!# a!on" the tren o other

    meta!&mino&s 7apparent!# more o5ii>e;ma"mas 7:i". 8;, rather than ep!etion as

    o&n in more re&e ma"mas.

    :rom the inompati4!e trae e!ement

    s#stematis, 6e on!&e that ma"mati

    onentrations o /o in meta!&mino&s,

    a!-a!0a!ine ma"mas are "enera!!# ?&ite !o6.

    This is iniate 4# the a(era"e mo!#4en&m

    ontent o ontinenta! r&st an "ranitois

    7=. ppm, Ta#!or an /Bennan, =1);.

    /ore important!#, 4ea&se the enrihment

    tren o mo!#4en&m in meta!&mino&s ro0s

    is re!ati(e!# !at thro&"h the "ranitoi re"ion

    7:i". 8;, an appro5imate ma"mati

    mo!#4en&m onentration 74et6een = an ppm 6ith an &nertaint# o on!# a e6 ppm;

    an 4e inerre rom the "ranitois r&4ii&m

    onentration. Rh#o!ites or "ranites 6ith

    r&4ii&m onentrations o o(er 1---ppm are

    rare an ommon!# are re&e t#pes that

    isp!a# mo!#4en&m ep!etion 6ith

    rationation. E(en i hi"h!# e(o!(e o5ii>e

    "raniti ma"mas e5iste 6ith onentrations

    o R4 as hi"h as 2 ppm, ma"mati /o

    onentrations preite 4# this tren 6o&!

    sti!! 4e !ess than + or 3 ppm. /oreo(er, as&r(e# o the mo!#4en&m ontents o

    s&4a!0a!ine (o!ani ro0s 6or!6ie iniates

    that onentrations in e5ess o = ppm ha(e

    not 4een o&n 7Smith, =1);. This oes not

    in!&e potentia!!# !ar"e enrihments o

    mo!#4en&m that are inerre to o&r at the

    apies o C!ima5-t#pe intr&sions 7=8,ppm,

    Carten et a!., =1))a; &e to a&m&!ation o

    a separate a?&eo&s phase 7is&sse !ater;, 4&t

    on!# to mo!#4en&m enrihment &e to r#sta!

    rationation.

    /o!#4en&m an nio4i&m

    Another e5p!anation o the moerate!#

    inompati4!e 4eha(ior o mo!#4en&m is that

    its ma"mati rationation is simi!ar to

    nio4i&m. /o!#4en&m an nio4i&m ma#

    ommon!# e5ist as ations o appro5imate!#

    simi!ar si>e an har"e in ma"mas. Oean

    is!an 4asa!ts an ontinenta! a!0a!ine ma"mas

    7e5!&in" minettes; e5hi4it hi"heronentrations o nio4i&m than o

    a!-a!0a!ine ma"mas at the same r&4ii&m

    onentrations 7:i". 8;. In aition, nio4i&m

    onentrations pro4a4!# erease 6ith

    ontin&e e(o!&tion in ma&sanite, on"onites,

    an the most e(o!(e topa> rh#o!ites

    7Christiansen et a!., =1)+ Piha(ant et a!.,

    =1)3 Con"on an Nash, =11=; as oes

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  • 7/24/2019 Keith Christiansen 93 Giant Mo

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    SEG SP-2 GIANT ORE D EPOSITS 2121 SEG SP-2 GIANT ORE DEPOSITS

    :i"&re 8. Conentrations o R4 (ers&s , /o, an N6. A; Conentrations o R4 an

    in resh terrestria! (o!ani ro0s are stron"!# orre!ate o(er a!most orers o ma"nit&e

    sho6in" that "enera!!# 4eha(es as a stron"!# inompati4!e e!ement. /i-oean ri"e 4asa!ts

    7/OR$; an oean is!an 4asa!ts 7OI$; orm istint4&t near!# ontin&o&s ie!s 7stipp!e;. The

    ie! or anesites, aites, an rh#o!ites 7AD R; e5tens rom 4&t o(er!aps the &pper en o the

    ie! or oean is!an 4asa!ts 7OI$;. :or rh#o!ites, on!# ata o!!ete rom "!ass# samp!es has

    4een in!&e. $; Conentrations o R4 an /o in most resh terrestria! (o!ani ro0s are

    stron"!# orre!ate sho6in" that /o "enera!!# 4eha(es as a moerate!# inompati4!e e!ement.

    /i-oean ri"e 4asa!ts 7/OR$; an oean is!an 4asa!ts 7OI$; orm istint 4&t near!#

    ontin&o&s ie!s. At a "i(en R4 ontent, the /o enrihment in anesites, aites, an rh#o!ites

    7AD R; rom s&4&tion >ones or ontinenta! settin"s is !ess than in 7OI$;. Hi"h!# e(o!(e

    rh#o!ites that r#sta!!i>e &ner re&in" onitions 7ma&sanites an some topa> rh#o!ites

    stipp!e pattern, !o6 2 tren; ha(e e(en !o6er /o R4 ratios, apparent!# as a res&!t o

    ma"mati ep!etion o mo!#4en&m. :or rh#o!ites, on!# ata o!!ete rom "!ass# samp!es has

    4een in!&e. C; Conentrations o R4 an N4 in resh terrestria! (o!ani ro0s re(ea! apattern

    simi!ar to that or R4 an /o in that anesites, aites, an rh#o!ites 7AD R; rom ontinenta!

    an s&4&tion >one settin"s are ep!ete in N4 ompare to oean is!an 4asa!ts 7OI$; an e(en

    some mi-oean ri"e 4asa!ts 7/OR$;. A!tho&"h apparent!# more inompati4!e than /o in most

    ma"mas, N6 4eha(es !i0e /o in that !o6 N4 R4 ratios are o&n in hi"h!# e(o!(e rh#o!iti

    ro0s iniate 4# ma"mati ep!etion o N6 in these ro0s. D ata rom Ne6som et a!. 7=1)+;,

    Go(inara& 7=1)1;, Christiansen et a!. 7=1)+;, Ko(a!en0o et a=. 7=13), =1)=;, Piha(ant et a!.

    7=1)3;, Con"on an Nash 7=11=;, T&r!e# an Nash 7=1)8;, /ahoo 7=1)=;, Hi!reth 7=1)=;

    an o&r o6n &np&4!ishe ana!#ses.

    mo!#4en&m. :or e5amp!e, the stron"!#

    re&e ma&sanite "!asses a!so sho6 a

    eo&p!in" o the 4eha(ior o nio4i&m an

    tanta!&m res&!tin" in a (er# !o6 N4 Ta ratio

    o =.3 7Piha(ant et a!., =1)3;. hether the

    4eha(ior o nio4i&m an 4e asri4e to a

    han"e in o5iation state rom Nto * in

    re&e ma"mas is &n0no6n. $&t 6hate(er

    ma"mati phases ontro! the a4&nane o

    nio4i&m ma# a!so ontro! that o

    mo!#4en&m..

    In s&mmar#, oean is!an 4asa!ts an

    ontinenta! a!0a!i 4asa!ts ma# inherit moest!#

    hi"h mo!#4en&m an nio4i&m onentrations

    rom their so&res. Ho6e(er, the hi"h o5#"en

    &"aities inherite rom the so&re re"ions o

    minettes an a!-a!0a!ine ma"mas ma# 4e o

    &namenta! importane in a!!o6in"

    mo!#4en&m onentrations to inrease &rin"

    r#sta! rationation o ma"mas re!ate to

    porph#r# mo!#4en&m eposits.

    Preser(ation o ma"mati mo!#4en&m

    an t&n"sten onentrations

    There are se(era! reasons to 4e!ie(e

    the t&n"sten an mo!#4en&m onentrations

    o man# si!ii i"neo&s ro0s oten o not

    represent ma"mati (a!&es. Perhaps most

    important!#, 4oth e!ements are s&4stantia!!#

    partitione into an a?&eo&s phase 6hen one is

    e(o!(e rom a r#sta!!i>in" "raniti ma"ma

    7Cane!a, =1)1a;. I an a?&eo&s phase esapes

    rom a p!&ton, then the t&n"sten an

    mo!#4en&m ontent o a "ranitoi 6i!! 4e

    re&e 6hereas o&ntr# ro0 mi"ht 4eome

    enrihe 4# eposition o these meta!s rom

    that !&i. The (er# proess that ma0es

    minera!i>ation possi4!e, ma0es etermination

    o ori"ina! ma"mati (a!&es a!most

    &nattaina4!e. In this re"ar, I(ano(a 7=1+8;

    st&ie the istri4&tion o t&n"sten in 4iotite

    "ranites an orre!ati(e "reisens an

    on!&e that t&n"sten ontent o the ro0s is

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  • 7/24/2019 Keith Christiansen 93 Giant Mo

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    SEG SP-2 GIANT ORE DEPOSITS 213

    :i"&re *. Conentrations o R4 (ers&s an /o or (o!ani an "ranitoi ro0s. A;

    Conentrations o in resh "ranitois rom 6estern North Ameria are "enera!!# ep!ete

    ompare to resh terrestria! ro0s o the same R4 ontent, in!&in" the anesites, aites, an

    rh#o!ites 7ADR; ommon!# assoiate 6ith t&n"sten eposits. $; Conentrations o /o in resh

    "ranitois rom 6estern North Ameria are "enera!!# ep!ete ompare to resh terrestria! ro0s

    6ith simi!ar R4 onentrations, in!&in" the anesites, aites, an rh#o!ites 7ADR; ommon!#

    assoiate 6ith porph#r# mo!#4en&m eposits. C; J&"in" rom the orre!ation o R4 an /o

    in "!ass# rh#o!iti ro0s, the /o onentrations in the rh#o!iti ma"ma at Pine Gro(e ma# ha(e

    4een as hi"h as 8 ppm. Ho6e(er, onentrations o /o in the (o!ani ro0s ran"e to as !o6 as

    .2 ppm as a res&!t o post-ma"mati !osses in!&in" !oss o a (o!ati!ephase &rin" er&ption an

    meteori !eahin" 7Keith an Shan0s, =1));. In!&es &np&4!ishe ata o J. D. Keith.

    primari!# a &ntion o a!teration. Keith et a!.

    7=1)1; mae the same on!&sion rom a

    st o the CanT&n" "ranitois, North6est

    Territories. :i"&re 7 i!!&strates that thet&n"sten ontent o. "ranitois rom 6estern

    North Ameria 7Keith, &np&4!ishe ata;

    satter a4o(e an most!# 4e!o6 the tren

    esta4!ishe or resh anesites, aites, an

    rh#o!ites. Keith et a!. 7=1)1; a!so e5amine

    the mo!#4en&m ontent o 4arren an

    t&n"sten-re!ate "ranitois rom 6esternNorth

    Ameria. No orre!ation o mo!#4en&m.

    ontent 6ith e"ree o ierentiation, si>e o

    assoiate eposit, or other trae e!ement

    onentrations 6as o&n. As 6as the ase ort&n"sten, the mo!#4en&m onentrations in

    these "ranitois "enera!!# are s&4stantia!!# !ess

    than those o resh anesites, aites, an

    rh#o!ites 7:i". *;.

    /o!#4en&m onentrations o ro0s

    rom a porph#r# mo!#4en&m eposit 6o&!

    a!6a#s 4e s&spet o 4ein" either enrihe

    7espeia!!# 6ithin 8 m oan ore >one,

    /&tsh!er et aI., =1)=; or ep!ete 4#

    h#rotherma! !eahin" or !oss o a

    mo!#4en&m-rih a?&eo&s phase. E(en resh(o!ani ro0s ma# e5hi4it mo!#4en&m

    onentrations !o6er than pre-er&ption

    ma"mati (a!&es &e to !oss o a

    mo!#4en&m-4earin" a?&eo&s phase or to

    !eahin"4# meteori !&is. Keith an Shan0s

    7=1)); o&mente that at !east 1 o the

    mo!#4en&m in the non-6e!e t& o Pine

    Gro(e 6as !eahe 4# meteori 6ater in

    aition, the# inerre that (er# resh

    oma"mati rh#o!ite o44!es eroe rom an

    e5tr&si(e ome ha !ost -3 o their

    ori"ina! mo!#4en&m ontent &e to esape oma"mati (o!ati!es 7:i". *;. A!tho&"h

    meas&re mo!#4en&m onentrations in resh

    Pine Gro(e ro0s ran"e rom .2 to =.)2

    ppm, the pre-er&ption ma"mati !e(e! ma#

    ha(e 4een as hi"h as -8 ppm 7:i". 70 the

    ierene ma# ha(e 4een !ost to meteori

    !eahin" or e"assin" o the ash !o6 t&

    short!# ater er &ption. Conse?&ent!#, it is

    ii&!t to etermine the ma"mati t&n"sten

    an mo!#4en&m onentrations o e(o!(e

    6ater-rih "ranites an rh#o!ites./o!#4en&m has.4een o&n in &maro!i

    r&sts assoiate 6ith simi!ar rh#o!iti t&s

    7ies, =121;. E(en stron"!# ierentiate

    rh#o!iti ma"mas s&h as those that orme

    the mo!#4enite eposits at C!ima5 an

    Henerson, ma# ori"ina!!# ha(e ontaine

    on!# a4o&t * ppm mo!#4en&m ma"mas 6ith

    !o6er r&4ii&m an nio4i&m - s&h as those

    rom 9&art> Hi!! an /o&nt To!man - ma#

    ha(e ori"ina!!# ha . mo!#4 en& m

    onentrations !oser to -2 ppm. At&a!

    ma"mati onentrations o mo!#4en&m or

    these eposits ma# 4e &nattaina4!e or the

    reasons &st o&t!ine. I+ s&h mo!#4en&m

    nio4i&m-r&4ii&m orre!ations ha(e some

    (a!iit#, then the more nio4i&m-r&4ii&m-rih

    ma"mas mi"ht 4e e5pete to pro&e !ar"er

    tonna"es o hi"her "rae mo!#4en&m ore.

    :i"&re i!!&strates that eposits 6ith hi"her

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  • 7/24/2019 Keith Christiansen 93 Giant Mo

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    211SEG SP-2 GIANT ORE DEPOSITS211 SEG SP GIANT ORE DEPOSITS

    :i"&re . R4 an N6 onentrations in si!ii i"neo&s ro0s assoiate 6ith porph#r#

    mo!#4en&m eposits in 6estern North Ameria are simi!ar to other mem4ers o the anesite,

    aite, rh#o!ite "ro&p 6or! 6ie. Graniti ro0s at 'raHenerson are the most rationate

    7iniate 4# their hi"h onentrations o the inompati4!e e!ements R4 an N4; an host the

    hi"hest "rae /o eposit. R4, N6: an /o ore "rae erease re"&!ar!# in the se?&ene PineGro(e, 9&esta, 9&art> Hi!!, an /t. To!man.

    nio4i&m an r&4ii&m onentrations o ha(e

    !ar"er tonna"es o hi"h "rae ore.

    PETROGENESIS O: /AG/A

    REBATED TO CBI/A-T%PE

    /OB%$DEN'/ DEPOSITS

    Bo6er an &pper r&sta! so&res

    Do the i"neo&s ro0s assoiate 6ith

    "iant porph#r# mo!#4en&m eposits inherit a

    speia! omposition rom their ma"ma so&re

    re"ion that istin"&ishes them rom !esser

    epositsM Is there a &ni?&e tetoni settin" or

    epoh or their e(e!opmentM In this re"ar,

    hite et a!. 7=1)=; propose that 4ea&se the

    Co!orao Ro0# /o&ntain re"ion e5hi4its

    man# eposits or minera! o&rrenes

    enrihe in mo!#4en&m, t&n"sten, an!&orine, this iniates a !on"-term so&re

    or these e!ements in the &ner!#in"

    ontinenta! !ithosphere 7=.3 Ga;. The#

    s&""este that C!ima5-t#pe ma"mas 6ere

    "enerate 4# rationa! me!tin" o the !o6er

    r&st o!!o6e 4# rationa! r#sta!!i>ation o

    eah 4ath o ma"ma as it iapiria!!# rose

    thro&"h the r&st. hite et a!. 7=1)=; s&""est

    the ma"mas 6o&! 4e enrihe in

    mo!#4en&m an other inompati4!e trae

    e!ements as a onse?&ene. hat !e(e!s omo!#4en&m enrihment 6o&! 4e ahie(e

    4# this proess are not speiie, 4&t the#

    s&""est that C!ima5-t#pe "ranitois are rather

    !i0e the topa> rh#o!ites o $&rt et a!. 7=1)2;.

    E5tensi(e ata on the mo!#4en&m ontent o

    topa> rh#o!ites are not a(ai!a4!e, 4&t Keith

    an Shan0s 7=1)); o&n that resh topa>

    rh#o!ite rom so&th6estern 'tah 6ith nio4i&m

    an r&4ii&m onentrations simi!ar to those

    at Henerson ontaine 8.8 7- .2; ppm

    mo!#4en&m. T&r!e# an Nash 7=1)8; o&n

    rom 2 to + 7- =.; ppm mo!#4en&m in

    (itroph#res rom topa> rh#o!ite !a(as at

    Sme!ter Kno!!, 'tah. There is no e(iene

    that topa> rh#o!ites "enera!!# ontain hi"her

    onentrations o mo!#4en&m than these

    (a!&es.

    Stein 7=1)); in(esti"ate the !ea,

    stronti&m, s&!&r, an o5#"en isotope ratios

    an rare earth-e!ement ompositions o ores,

    an o (o!ani an p!&toni ro0s rom the

    Co!orao minera! 4e!t the "enesis o

    C!ima5-t#pe s#stems 6as o parti&!ar

    onern. Her ata 6ere interprete to iniate

    that a!! the Baramie-Tertiar# intermeiate to

    e!si ma"mas 7in!&in" a!-a!0a!ine; ha a

    !o6er r&sta! ori"in ho6e(er, C!ima5-t#pe"ranites 6ere propose to ha(e ori"inate

    rom a &ni?&e !o6er r&sta! so&re 7not

    re!ate to a!-a!0a!ine ma"matism;. The

    ma"mati harateristis ritia! to

    C!ima5-t#pe minera!i>ation a?&ire rom this

    &ni?&e so&re are not speiie.

    In their re(ie6 o the Henersoneposit, Carten et *I. 7=1))4; s&""est that a

    &ni?&e ma"ma that ontaine hi"h

    onentrations o ore omponents 6as not

    re?&ire to orm the eposit. The# ar"&e that

    the initia! onentration o mo!#4en&m in the

    ore-re!ate ma"ma is not as ritia! to ore

    ormation as the t#pe an &ration

    o rationation proesses in a hi"h-!e(e!

    ma"ma ham4er.

    The a(era"e mo!#4en&m ontent o

    the !o6er an &pper r&st is estimate to 4e

    .) an =. ppm respeti(e!# 7Ta#!or an

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    8 SEG SP GIANT ORE DEPOSITSSEG SP-2 GIANT ORE D EPOSITS 8/Bennan, =1);. One o the trst attempts to

    eme a speia! mo!#4en&m-rih so&re or

    C!ima5-t#pe eposits 6as ana!#sis o the

    mo!#4en&m ontent o Iaho Sprin"s

    :ormation an the Si!(er P!&me Granite

    ahone# 7=1+); o&n an a(era"e o ppm

    an 2-8 ppm /o in these respeti(e ro0

    t#pes. On this 4asis, a!!ae et a=. 7=13);

    s&""este that the t&n"sten an mo!#4en&m

    o the C!ima5 an Henerson eposits 6ere

    eri(e rom these &pper r&sta! host ro0s.

    Ho6e(er, !ater isotopi st&ies 7hite etaI.,

    =1)= Stein, =1)); ha(e emonstrate

    that C!ima5-t#pe ma"mas an ore eposits in

    the Co!orao minera! 4e!t o&!

    not ha(e inorporate an# appreia4!e

    amo&nt o these &pper r&sta! ro0s.

    /ost reent 6or0ers ha(e propose

    that the ma"ma so&re o C!ima5-t#pe s#stems

    an topa> rh#o!ites is in the !o6er r&st

    7hite et aI., =1)= Christiansen an i!son,

    =1)2 Christiansen et aI., =1)) Stein, =1));

    a!tho&"h enrihe &pper mant!e has 4een

    propose a!so 7estra an Keith, =1)=;.

    hite et a!. 7=1)=; note that the initia!

    )3Sr)+Sr (a!&es or &na!tere C!ima5an

    Henerson ro0s (aries 4et6een .3 -

    .3=. Stein 7=1)); o&n si"nitant!# hi"her

    an 6ie!# (ar#in" (a!&es o .3) to .3*

    or C!ima5 an Henerson ro0s. Cha!0

    /o&ntain rh#o!ite is a re!ati(e!# &na!tere

    topa>-4earin" e5tr&si(e ome that is

    oma"mati 6ith the C!ima5 rh#o!ites ,Bur! et

    aI., =1)2;. Stein 7=1)); reporte a )3Sr)+Sr

    (a!&e o .3) or Cha!0 /o&ntain an-

    the ompositions o 8 samp!es rom

    Henerson. Epsi!on N or these samp!es

    ran"e rom -1. to -1.1. These (a!&es are

    inistin"&isha4!e rom the hi"h en epsi!on

    N o Pream4rian 7=.+ to =.) Ga; 4asement

    ro0s, s&""estin" to :armer an DePao!o7=1)*; that the "raniti ma"mas 6ere eri(e

    e5!&si(e!# rom mi-Protero>oi r&st.

    Ho6e(er, it sho&! 4e note that DePao!o

    7=1)=; o4ser(e that Protero>oi r&st in

    Co!orao o&! ha(e ha epsi!on N as !o6 as

    -=* &rin" the mi!e Tertiar#. I s&h r&st

    6as in(o!(e in the "enesis o C!ima5-t#pe

    rh#o!ites then a si"nitant mant!e omponent

    6ith hi"her epsi!on N m&st ha(e 4een

    present e(en in this ma"ma s#stem.

    /oreo(er, the o&rrene o i"neo&s ro0s6ith epsi!on N (a!&es as !o6 as -=8 7Johnson

    an :ririh, =11; in the same re"ion an

    4roa!# oe(a! 6ith Henerson is onsistent

    6ith the in(o!(ement o si"nitant

    mant!e-eri(e ma"ma at Henerson. As

    note 4e!o6, Johnson et a=. 7=1)1; a!so

    propose a simi!ar mi5e 7mant!e an r&sta!;

    herita"e or the ma"mas that !e to the

    ormation o the 9&esta eposit.

    Tetoni settin"

    Si!!itoe 7=1); s&4i(ie porph#r#

    mo!#4en&m eposits into rit-re!ate an

    s&4&tion-re!ate eposits that orrespon

    air!# 6e!! to C!ima5-t#pe an the other

    ate"ories respeti(e!#. Se(era! a&thors ha(e

    reo"ni>e that e6 /o eposits o&r in

    .3= - .3== or C!ima5 samp!es. :&se #o&n" is!an ar settin"s 7i.e. Canianian,

    ash-!o6 !u++ assoiate 6ith the C!ima5-t#pePine Gro(e eposit in U!*;: 6hih is

    &ner!ain 4# Protero>oi r&st o the same a"e

    as C!ima5, has an initia! )3Sr)+Sr (a!&e o

    .311 7Christiansen an i!son, =1)2;.

    A!tho&"h sparse, N isotopi ata ma#

    re(ea! more a4o&t the so&re7s; o C!ima5

    t#pe rh#o!ites, 4ea&se the# are pro4a4!# !ess

    aete 4# h#rotherma! a!teration an

    6a!!-ro0 ontamination than Sr isotope

    ratios. :armer an DePao!o 7=1)*; reporte

    Ta4!e =;, an a!most a!6a#s in areas &ner!ain4# at !east thin ontinenta! r&st 7Si!!itoe,

    =1) estra an Keith, =1)= Christiansen

    an i!son, =1)2;. A!tho&"h some ha(e

    !aime that C!ima5-t#pe s#stems orre!ate

    6ith thi0er ontinenta! r&st, others s&""est

    that the# are inepenent o r&sta! thi0ness

    7estra an Keith, =1)=;. Perhaps the most

    ommon!# s&""este tetoni settin" or

    C!ima5-t#pe s#stems is &rin" the han"eo(er

    rom ompressiona! to e5tensiona! tetonis

  • 7/24/2019 Keith Christiansen 93 Giant Mo

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    SEG SP-2 GIANT ORE D EPOSITS 8=8= SEG SP GIANT ORE DEPOSITS

    7Si!!itoe, =1) estra an Keith, =1)=

    /&tsh!er et aI., =1)= hite et aI., =1)=

    $oo0strom, =1)=;. Some a&thors preer to

    onsier this settin" as atetoni or 4a0-ar

    spreain" rather than simp!# rit-re!ate.

    The han"eo(er tetoni settin" hasa!so reent!# 4een o&mente or the Co&!ee

    D am intr&si(e s&ite 7Car!son an /o#e, =11;

    that hosts the C&-rih /t. To!man eposit

    6hose ore-re!ate "ranite porph#r# !ear!#

    e(o!(e rom a ominant (o!&me o

    "ranoiorite 7Car!son an /o#e, =11;.

    A it io na ! !# , a p os t -o ro"en i ,

    e5tension-re!ate settin" has 4een propose or

    the 9&art> Hi!! eposit 7H&son et a!. , =1)=;.

    The @u*r! Hi!! intr&si(e omp!e5 6as

    emp!ae in the Coast 4atho!ith ater it ha4een e5tensi(e!# &p!ite an eroe. A

    re"iona! e5tension-re!ate oint s#stem

    ontro!s emp!aement o man# !amproph#re

    i0es as 6e!! the 9&art> Hi!! intr&sions.

    Ho6e(er, the initia! )3Sr)+Sr (a!&es o .3=

    or the 9&art> Hi!! intr&sions o not ier

    si"niiant!# rom those o the o!er

    s&4&tion-re!ate p !&ton i ro0s.

    Aitiona!!#, the 9&art> Hi!! intr&sions sho6

    minima! enrihment o ?-: !&orine, an

    other inompati4!e e!ements 7H&son et a!. ,=1)=;.

    Cr#sta! rationation rom a!-a!0a!ine

    preeessors

    D espite a&m&!ation o a !ar"e

    amo&nt o ata on the petro"eneti an

    isotopi e(o!&tion o C!ima5-t#pe rh#o!ites, a

    n&m4er o ierin" so&re ro0s are

    permissi4!e. 9&esta an Pine Gro(e sho6

    man# petro"eneti simi!arities. Pine Gro(e728-22 /a :i". =; is !oate in the Inian

    Pea0 (o!ani ie! that pro&e ominant!#

    hi"h-K a!-a!0a!ine aiti ash !o6s rom 82

    to 23 /a 7$est et a!., =1)1;. /ore than

    , 0m8 o ash !o6 t& 6as er&pte.

    Sma!!er (o!&mes o hi"h-K a!-a!0a!ine

    rh#o!ite, trah#anesite, an minor aite

    6ere er&pte near the Inian Pea0 (o!ani

    ie! at =)-28 /a an are ro&"h!#

    ontemporaneo&s 6ith the ineption o

    e5tension in the area 7$est et aI., =1)3;. The

    Pine Gro(e porph#r# mo!#4en&m eposit

    o&rs in the eroe (ent o an ash-!o6 ome

    omp!e5 &st east o the rim o the InianPea0 a!era omp!e5. Initia! er&ptions 4e"an

    6ith hi"h-si!ia rh#o!ite an !ater er&ptions

    sim&!taneo&s!# (ente rh#o!iti an aiti

    ma"ma. Hi"h-si!ia rh#o!ite s&4se?&ent!#

    i!!e the (ent to orm omes an intr&e to

    sha!!o6 !e(e!s to orm a C!ima5-t#pe eposit.

    The o-er&pte aiti ma"ma e5hi4its a moe

    an maor-e!ement omposition (er# simi!ar to

    the (o!&mino&s aiti ash-!o6s that 6ere

    emp!ae &rin" the O!i"oene an to other

    intermeiate (o!ani ro0s o the same a"e728-2= /a; to the 6est 7$est et ai., =112;.

    Short!# ater omp!ete r#sta!!i>ation o the

    ma"ma ham4er, trah#anesiti ma"ma

    intr&e the (ent an other portions o the

    r&st an o(ere the t& o Pine Gro(e

    aross the re"ion. Keith 7=1)2; emonstrate

    that + rationation o aiti ma"ma,

    &sin" o4ser(e phenor#st proportions an

    ompositions, o&! pro&e the maor

    e!ement omposition o the Pine Gro(e

    rh#o!ite. The a(ai!a4!e Sr isotopi ata are

    onsistent 6ith this iea no si"niiant

    ierenes e5ist 4et6een the Sr-isotopi

    ompositions o the Pine Gro(e ma"ma an

    the o!er aites o the Inian Pea0 (o!ani

    ie!.

    Johnson an Bipman 7=1));

    in(esti"ate the ori"in o the meta!&mino&s

    an a!0a!ine (o!ani ro0s o the Batir

    (o!ani ie!, host o the 9&esta eposit 7:i".

    =;, in the Rio Grane rit near the

    Co!orao-Ne6 /e5io 4orer. /a"matism in

    the Batir ie! 722 - 2). /a an ==-= /a;

    is appro5imate!# oe(a! 6ith C!ima5-t#pe

    s#stems 7i.e. C!ima5, Henerson, /t.

    Emmons; arther north a!on" the Rio Grane

    rit. In aition, the a"e o ma"matism spans

    the ineption o ritin" in the area 72+ /a;.

    /o!#4en&m minera!i>ation is assoiate 6ith

    6anin" sta"es o a!era ma"matism. The

  • 7/24/2019 Keith Christiansen 93 Giant Mo

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    82 SEG SP GIANT ORE DEPOSITS82SEG SP3 GIANT ORE DEPOSITS

    ;i);#$! )r*d#$ o+ or# *r# *$$oi*!#d =i!; !;#

    Su';ur Gu; 'u!on ,3< M*0 !;*!

    in!rud#d !;# $ou!;#rn rim o+ !;# @u# !*

    *d#r* ,o;n$on #! *. : 15850. o;n$on *nd

    Li'm*n ,15880 $u))#$!#d !;*! - %

    +r*!ion*!ion o+ * '*r#n!* m*)m* $imi*r !o

    !;# &*6r#$!o L*k# mono)r*ni!#: * $i);!(

    od#r r#$ur)#n! 'u!on: oud 'rodu# !;#

    m*Cor*nd !r*###m#n! om'o$i!ion o+ !;#

    Su';ur Gu; 'u!on. T;#( $u))#$! !;*! *

    6*$# #%# in!#rm#di*!# om'o$i!ion m*)m*:

    #2#m'i+i#d 6( !;# m*Cori!( o+ !;# o*

    o*ni *nd 'u!oni rok$: '#r$i$!#d in !;#

    *r#* +or m.(. T;# in+#rr#d mono)r*ni!#'*r#n! i$ #r( $imi*r !o !;# d*i!# o#ru'!#d=i!; !;# r;(oi!i Pin# Gro%# m*)m* *nd !;#6*$# ## om'o$i!ion o+ !;# Indi*n P#*ko*ni +i#d ,B#$! #! *I.: 15850.

    A ri!i* u#$!ion!;*!$;oud6# *$k#d

    i$ =;#!;#r !;# '#!ro)#n#!i 'ro#$$#$#2#m'i+i#d 6( Pin# Gro# *nd @u#$!*

    m*)m*!i$m o'#r*!#d *! o!;#r &im*2!('#'or';(r( Mo $($!#m$. Book$!rom ,15810$!*!#$ !;*! !;# &im*2!('# d#'o$i!$ in !;#&oor*do min#r* 6#! our *on) !;# *2#$ o+$i);!( od#r **k*in# 'u!on$ ,mo$!(#$$ !;*n 7- M*0 . T;#r# *r# *6ou! 3-mo(6d#num 'ro$'#!$ =i!; u' !o -. 1 %MoS min#r*i*!ion in: !;# min#r* 6#! *ndmo$! o+ !;#$# *r# *$$oi*!#d =i!; 6ro*d(**k*in# i)n#ou$ rok$ *nd *''#*r !o 6#$u6du!ion r#*!#d. H# no!#$ !;*! !;# &im*2ik# r;(oi!# 'or';(ri#$ o+ !;#9in+i#d 'ro$'#! ,3

  • 7/24/2019 Keith Christiansen 93 Giant Mo

    19/37

    88SEG SP3 GIANT ORE DEPOSITS88 SEG SP-2 GIANT ORE DEPOSITS

    *r# *$o 'o$$i6#. For #2*m'#: !;# 8* M*

    Gri1( P#*k Tu++: o*!#d *''ro2im*!#( )

    km $ou!;=#$! o+!;# &im*2 d#'o$i!: *ri#$ in

    om'o$i!ion +rom ;i);$ii* r;(oi!# *! !;#

    6*$# !o o=$ii* r;(oi!# *! !;# !o' o+ *

    $in)# #rod#d ooin) uni! !=o ;#!#ro)#n#ou$

    !u++ *(#r$ *$o on!*in d*i!# !o m*+i *!i!#+i*mm# ,o;n$on *nd Fridri;: =11;. Ini!i*1

    84Sr8Sr r*!io$ r*n)# +rom .3=3 !o *$ o= *$

    .311 *nd #'$ion Nd *u#$ *r( 6#!=##n

    13.- *nd -==.8 $imi*r *ri*!ion$ *r##2;i6i!#d 6( P6 *nd - i$o!o'#$. o;n$on *ndFridri; 7=11; 'oin! ou! !;*! !;# mo$! m*+iom'o$i!ion 73 =!% Si0 i$ !oo m*+i !o 6# *'*r!i* m#! o+ ru$!* rok$ !;i$ m*)m*!iom'o$i!ion i$ 6#$! #2'*in#d 6(

    *''ro2im*!#( =!% r($!* +r*!ion*!ion o+6*$*!i m*)m*: *om'*ni#d 6( - !o *=!% *$$imi*!ion o+ Pro!#rooi ru$!. T;#mor# $iii 'or!ion$ o+ !;# m*)m* =#r#mod##d !o ;*# +orm#d 6( r($!*

    +r*!ion*!ion *om'*ni#d 6( *!#$!*)# ru$!**$$imi*!ion . E%id#n# +or !ate-sta"e*$$imi*!ion inud#d i$o!o'i di$#uii6rium6#!=##n =;o#rok +i*mm# *nd #*r( *nd*!#r($!*iin) ';#nor($!$ $#'*r*!#d +rom!;# $*m# +i*mm#. T;#( no!# !;*! =i!;ou! !;#+or!ui!ou$ #ru'!ion o+ !;# mor# m*+i 'or!ion$o+ !;# m*)m* ;*m6#r: !;#( =oud ;*#dr*=n !;# #rron#ou$ onu$ion !;*! !;# !u++=*$ )#n#r*!#d 6( 1--% ru$!* m#!in). T;#;i);$ii* 'or!ion o+ !;# Gri1( P#*k Tu++

    =ou1d +i! a!! o+ !;# i$o!o'i ri!#ri* +ord#ri*!ion +rom * &im*2!('# $our#

    ,S!#in: =1)) S!#in *nd &rok: =11;, in $'i!#o+ i!$ in+#rr#d m*n!# ;#ri!*)#.

    Isotopia!!# >one m*)m*ham4ers

    Pu!oni *nd o*ni rok$ r#*!#d !o!;# @u#$!* *d#r* *nd 'or';(r( mo(6d#numd#'o$i! *$o $;o= #id#n# o+ d#ri*!ion +rom;#mi*( *nd i$o!o'i*( on#d m*)m*;*m6#r$. T;# @u#$!* *d#r* +orm#d u'on

    #ru'!ion o+ < -- km3 o+ !;# ;i);$ii*'#r*1k*1in# Am*1i* Tu++ ,o;n$on *nd

    Li'm*n: =1));. Pr#*d#r* in!#rm#di*!#

    om'OSI!Ion o*ni rok$ ;*# r#*!i%#1(

    uni+ormini!i*1 84Sr8Sr r*!io$ o+*''ro2im*!#(

    .3 ,id#n!i* !o !;# in!#rm#di*!# **$ o+

    !;# S*n u*n o*ni +i#d Li'm*n #! *. :

    =13) o;n$on #! *I. : =11;. Ini!i*1

    84Sr8Sr

    r*!io in !;# Am*1i* Tu++ inr#*$#$

    mono!oni*( =i!; d#r#*$in) Sr ontent+rom .33 !o .31), !;# Sr'oor !u++r#'r#$#n!in) !;# #*r( #ru'!ion$ . L*!#$!*)#roo+=*rd *$$imi*!ion o+ Pro!#rooi rok$ i$'ro'o$#d *$ !;# 'r#+#rr#d #2'*n*!ion o+ !;#inr#*$in) ini!i* 84Sr8Sr r*!io$ oninin)#id#n# o+ !;i$ mod# i$ !;# roo+=*rdinr#*$# in !;# 'ro'or!ion o+ iron$ =i!;Pro!#rooi or#$ r#*!i# !o T#r!i*r( iron$=i!; no Pro!#rooi or#$ . T;#Momin#r*i#d Su';ur Gu; 'u!on #2;i6i!$ *n*n*o)ou$ !r#nd o+ d#r#*$in) ini!i*

    84Sr+8Sr r*!io$ ,+rom . 3) !o .3+3; =i!;

    inr#*$in) Sr on!#n!. T;# in+#rr#d '*r#n!

    ,&*6r#$!o L*k# 'u!on0 ;*$ *n ini!i* 84Sr8Sr

    r*!io o+ .38 ,o;n$on #! *I. : 155-0.

    L*!#$!*)# roo+=*rd on!*min*!ion m*( *$o

    *u$# $om# o+ !;# *r)# *ri*!ion$ in ini!i*

    84Sr8Sr no!#d in !;# &im*2: H#nd#r$on: *nd

    M!. Emmon$ r;(oi!#$ ,S!#in: =1));. S!#in

    *nd &rok 7=11; r#C#! !;*! 'o$$i6ii!(

    6#*u$# !;# in+#rr#d 'ro'or!ion$ o+ =*rok

    n##d#d !o 'rodu# !;# *ri*!ion$ *r#

    $u6$!*n!i*( di++#r#n! +or !;# Nd: Sr: *nd P6

    i$o!o'i on$!r*in!$. Ho=##r: o;n$on #! *.

    7=11; #noun!#r#d #r( $imi*r i$o!o'iinon$i$!#ni#$ in mod#in) !;# *!#$!*)#*$$imi*!ion o+ !;# Su';ur Gu; ,@u#$!*0'u!on.

    No! * ;i);## m*)m* ;*m6#r$ or'o$!*d#r* 'u!on$ $;o= #id#n# o+

    *!#$!*)# *$$imi*!ion. I+ *!#$!*)# roo+=*rd*$$imi*!ion i$ * ommon 'ro#$$ in&im*2!('# m*)m* ;*m6#r$: !;#n =;*!'ro#$$ i$ r#$'on$i6# +or *u$in)*$$imi*!ion U!im*!#(: !;# *n$=#r i$ r#*!#d!o ;#*!: =;#!;#r 6( r($!*i*!ion or 6(und#r'*!in) or inC#!ion o+ n#= m*)m*. T;#+*! !;*! &im*2!('# m*)m*$ m*( $;o=on$i$!#n! i$o!o'i #id#n# o+ *!#$!*)#*$$imi*!ion o+ roo+ rok$ $;oud no! 6#

  • 7/24/2019 Keith Christiansen 93 Giant Mo

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    8* SEG SP-2 GIANT ORE DEPOSITSSEG SP-2 GIANT ORE DEPOSITS 8

    s&rprisin" inasm&h as one o the most 6ie!#

    reo"ni>e harateristis o this eposit t#pe

    is the o&rrene o m&!tip!e intr&sions an

    ore 4oies that are "enera!!# emp!ae 4#

    assimi!ation an stopin".

    Chonrite-norma!i>e rare-earth

    e!ement patterns rom C!ima5, Henerson,

    9&esta, an Pine Gro(e 7is&sse in a !ater

    setion; sho6 e(iene o some r#sta!!i>ation

    an rationation o the parent ma"mas

    4et6een intr&si(e &nits this o&! 4e one

    so&re o heat or assimi!ation. A!! o&r

    o these eposits 6ere apparent!# e(e!ope

    &rin" the han"e rom s&4&tion-ontro!!e

    to e5tensiona! tetonis. Thompson et a!.

    7=11=; s&""este that e5tension-re!ate mai

    ma"ma assoiate 6ith the Rio Grane rit

    p!a#e a s&4stantia! ro!e in e5tenin" the !ie

    o pre-rit (o!anism appro5imate!# 4# 8

    m.#. :or e5amp!e, the S&!ph&r G&!h p!&ton

    728-2 /a;, 6hih hosts the 9&esta eposit,

    ma# ha(e e(o!(e rom pre-rit ma"mas that

    6ere 0ept a!i(e 4# 4asa!ti ma"matism

    re!ate to ritin" 72+ /a;. Thereore,

    &nerp!ate mai ma"ma at 9&esta ma# ha(e

    4een responsi4!e or the "ra&a! e!e(ation in

    initia! )3Sr)+Sr assoiate 6ith roo6ar

    assimi!ation.E(iene or e5tension-re!ate

    trah#anesite &nerp!atin" o the Pine Gro(e

    ham4er is perhaps e(en more on!&si(e in

    s&4stantiatin" a ro!e or e5tension-re!ate

    ma"mas. Trah#anesiti ma"mas 6ere

    !ear!# assoiate 6ith e5tensiona! tetonis

    rom 22 to =) /a aross the

    Pio he- / ar#s(a ! e (o ! an i 4e ! t .

    Trah#anesite ma"ma o-er&pte 6ith the

    t& o Pine Gro(e an intr&e the (ent &st

    ater ina! onso!iation o the ma"maham4er. Keith an Shan0s 7=1)); s&""este

    that the trah#anesiti ma"ma ma# ha(e

    pro(ie the heat to a!!o6 the 6ater-rih Pine

    Gro(e ma"ma to asen to s!i"ht!# hi"her

    !e(e!s in the r&st 6itho&t so!ii#in".

    hite et a!. 7=1)=; an Stein an

    Cro0 7=11; point o&t that assimi!ation o

    hi"h!# raio"eni o&ntr# ro0s aro&n

    C!ima5 an Henerson o&! not ha(e 4een a

    (er# si"niiant ma"ma moi#in" proess.

    Ho6e(er, e(en a tri(ia! amo&nt o

    assimi!ation 7-2 o Si!(er P!&me Granite,

    $oo0strom et aI., =1)); ma# e5p!ain the

    monotoni inrease in initia! )3Sr)+Sr (a!&es

    4et6een oma"mati rh#o!ite intr&sions. e

    o not propose that !ate-sta"e assimi!ation is

    ain" an#thin" speia! to the ma"ma

    ham4er, 4&t it ma# point to a on)i#d heat

    so&re at the 4ase o the s#stem that permits

    e5tene r#sta! rationation, (o!ati!e !oss,

    an perhaps (o!ati!e !&5in" 6itho&t rapi!#

    so!ii#in" the entire ham4er. Isotopi

    >onation o the hi"h-!e(e! ma"ma ham4er

    ma# 4e one si"nat&re o that heat so&re.

    hite et a!. 7=1)=; a!so note that

    4asa!ti (o!anism is not assoiate, on a !oa!

    sa!e, 6ith C!ima5-t#pe s#stems. Ho6e(er,

    e!si ro0s at C!ima5, Henerson, an

    Chia"o $asin are ontemporaneo&s 6ith

    minor (o!&mes o ross-&ttin" 4iotite-rih

    !amproph#re i0es 7$oo0strom, =1)=

    $oo0strom et aI., =1));. Aitiona!!#, mi!!#

    a!0a!ine to transitiona! 4asa!ts 72*-2 /a;

    interm"er 6ith 4asin-i!! seimentar# ro0s

    o the $ro6ns Par0 :ormation 6est o

    the Co!orao minera! 4e!t 7Thompson eta!.,

    =11=;. $oo0strom 7=1) =; s&""ests that the

    !amproph#res represent a ierent t#pe o

    4imoa! s&ite. Some ha(e s&""este that

    !o6er therma! inp&t ma# res&!t in se!eti(e

    partia! me!tin" o !ess rerator# p!&ms in a

    p!&m p&in" mant!e 6ith the res&!tin" me!t

    4ein" isotopia!!# enrihe an o a!0a!ine

    ainit# 7Thompson et aI., =11 = Perr# et aI.,

    =1)3;. C!ima5, Henerson, ai! Chia"o

    $asin are s&iient!# remo(e rom areas os&4stantia! ritin" that rit-re!ate therma!

    inp&t ma# ha(e 4een !o6, 4&t s&iient to

    e5ten the !ie o the ma"ma ham4ers.

    In s&mmar#, 6hen on!# hi"h-si!ia

    rh#o!ite is er&pte or e5pose or

    e5amination, the petro"enesis is am4i"&o&s

    7Christiansen an i!son, =1)2 Johnson an

    :ririh, =11;. Inasm&h as hi"h-si!ia

    rh#o!iti ma"mas !ie near the ternar#

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    SEG SP-2 GIANT ORE DEPOSITS 88+ SEG SP-2 GIANT ORE DEPOSITS

    minim&m, a (ariet# o so&re materia!s an

    petro"eneti paths ma# #ie! essentia!!# the

    same 4&!0 omposition. e see no reason

    that topa> an C!ima5-t#pe rh#o!ites o&! not

    4e e(e!ope 4# either partia! me!tin" o

    !o6er r&sta! e!si "ran&!ite 7Christiansenet a!. ,

    =1)) Stein, =1)) Stein an Cro0, =11

    hite et aI., =1)=;, ierentiation . o

    s&4&tion-re!ate hi"h-K a!-a!0a!ine

    ma"mas 7Keith et aI . , =1)+ estra

    an Keith, =1)=;, or e5treme rationation

    o rit-re!ate 4asa!ti ma"ma si"niiant!#

    ontaminate 4# !o6er r&st . Ho6e(er,

    rh#o!ites "enerate4# these proesses ma# not

    4e e?&a!!# apa4!e o "eneratin" a "iant

    eposit.

    &ON&ENTRATION AND

    TRANSPORTATION ME&HANISMS .

    a!!ae et a!. 7=1+); emphasi>ethat

    =-=2 km3 o ma"ma is neee to s&pp!#

    the mo!#4en&m o&n in the C!ima5 ore

    4oies. Carten et a! . 7=1))a; on!&e that

    enrihment o ore omponents in t4e .&po!a

    o&rsprior to the onset o r#sta!!i>ation an

    that the initia! onentration o mo!#4en&m

    in the parent ma"ma ham4er is not as

    si"niiant to ore ormation as the t#pe an

    &ration o proesses that e!i(er

    mo!#4en&m to the &po!a. Intermin"!e

    4arren an pro&ti(e sto0s at Henerson

    ha(e the same isotopi omposition 7:armer

    an DePao!o, =1)*; an pro4a4!# represent

    s&essi(e ra&"hts rom a !ar"e, persistent

    ma"ma ham4er that 6as onti"&o&s 6ith

    eah intr&sion. Carten et a!.7=1))a; a!so

    on!&e that either (ariations in resiene

    time or (ariations in the eiienies o

    rationation proesses o&! ao&nt or the

    intermin"!in" o4arren an pro&ti(e sto0s .

    Cr#sta!!i>ation

    Cane!a 7=1)1a; states that partitionin"

    o mo!#4en&m into an a?&eo&sphase is most

    eiient 6hen an initia!!# r# me!t

    rationates at sha!!o6 epth or 6hen me!t

    e(o!(es 6ater at "reat epth, he s&""ests that

    in either ase e(o!&tion o (apor &rin"

    r#sta!!i>ation 7seon 4oi!in"; is more

    eeti(e in remo(in" /o rom the me!t than

    an# reasona4!e irst 4oi!in" senario.Ho6e(er, there is no reason to 4e!ie(e the

    C!ima5!('# rh#o!iti ma"mas are r# C=

    H2; an o not e(o!(e an a?&eo&s phase

    &nti! the !ast e6 perent o the ma"ma

    r#sta!!i>es. Keith an Shan0s 7=1));

    o&mente a hi"h 6ater &"ait# an ontent

    or the Pine Gro(e rh#o!ites most rh#o!iti

    ma"mas are pro4a4!# sat&rate or near!#

    sat&rate 6ith 6ater 6hen the# er&pt. In

    aition, rh#o!ites that appear to ha(e er&pte

    rom Pine Gro(e, 9&esta, C!ima5, anHenerson ha(e !ess than 8 phenor#sts.

    The a!ternati(e Cane!a 7!1)1a;

    proposes or "eneratin" a mo!#4en&m-rih

    ma"ma--e(o!(in" an a?&eo&s phase at "reat

    epth--ma# ha(e some app!iation to

    r#sta!!i>ation o rier, intermeiate-or-mai

    ma"ma at the roots o a stratiie ma"ma

    s#stem. I 4&o#ant !&is that e(o!(e as a

    res&!t o r#sta!!i>ation at epth an e5trat

    mo!#4en&m rom the ma"ma the# tra(erse

    an then o!!et eiient!# in a hi"h-!e(e! &p o! a , then the# ma# or m a

    mo!#4en&m-rih ma"ma an onse?&ent!#

    ontri4&te to ore ormation.

    Some ha(e propose that !itt!e

    aitiona! r#sta!!i>ation or ierentiation o

    the parent ma"ma ham4er o&rre rom the

    time o emp!aement o one sto0 to the ne5t

    7Keith an Shan0s, =1)) Carten et aI.,

    =1))a;. :or e5amp!e, >ironi&m an nio4i&m

    onentrations are appro5imate!# the same or

    a!! sto0s at Henerson. Ho6e(er, re!ati(e!#onstant onentrations o these e!ements are

    perhaps not &n&s&a! or meta!&mino&s

    ma"mas r#sta! rationation an o&r an

    maintain re!ati(e!# onstant (a!&es or

    >ironi&m, nio4i&m, an mo!#4en&m.

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    8+ SEG SP-2 GIANT ORE DEPOSITS

    >*ri*!ion$ in *'orm#!'*r!i!ionin)

    In orthoma"mati h#rotherma! !&is,

    /o oes not appear to 4e omp!e5e an

    transporte 6ith either CI or : in at,

    Kepp!er an #!!ie 7=11=; o&n that

    mo!#4en&m is most stron"!# partitione into

    an a?&eo&s phase 7KDF .; 6hen CI an

    : are a4sent. Conse?&ent!#, i o&r

    on!&sions re"arin" the ma5im&m

    enrihment, - ppm, o mo!#4en&m in

    ma"mas are orret, none o the

    e5perimenta!!# etermine (aporme!t

    partition oeiients or mo!#4en&m 6o&!

    pro&e an e5treme!# mo!#4en&m-rih ore

    !&i 7one 6ith tho&sans o ppm /o; rom a

    6ater-rih rh#o!iti me!t at sha!!o6 epths

    7Kepp!er an #!!ie, =11= Ta0er

    an Cane!a, =1)3; .

    Bo6enstem et a!. 7=11=; in(esti"ate

    the opper ontent o me!t in!&sions in ?&art>

    phenor#sts rom the pera!0a!ine rh#o!ites

    rom Pante!!eria. The# o&n 8 ppm opper in

    matri5 "!ass an in me!t in!&sions 6ith

    rat&res to the r#sta! s&rae. Non-e"asse

    me!t in!&sions ontaine 2 ppm opper an

    me!t in!&sions that a!so ontaine !ar"e (apor

    4&44!es ontaine &p to 8 ppm opper.

    The# a!&!ate that the (aporme!t partition

    oeiients or opper ma# 4e 6e!! o(er

    = this (a!&e is m&h hi"her than those

    etermine e5perimenta!!# 7- Cane!a an

    Ho!!an, =1)*;. Bo6enstem et a=. 7=11=;

    propose that the stron"er partitionin" o

    opper into the !&i phase o&! 4e &e to

    more a(ai!a4!e CI in the !&i phase than in

    the e5periments. This mi"ht ha(e 4een a&se

    4# a hi"h CO2H2 ratio, renerin" HeU more

    issoiate. The# a!so emphasi>e thatr($!*i*!ionindu#d (o!ati!e sat&ration

    7seon-4oi!in"; ma# not 4e neessar# or the

    pro&tion o C&-rih !&is. E5so!(e

    (o!ati!es 6ere present in pante!!erite ma"ma

    6ith on!# = r#sta!s an in rh#o!ite rom

    the a!!e# o Ten Tho&san Smo0es 6ith on!#

    2 phenor#sts 7Bo6enstem et aI. , =11=;.

    Simi!ar!#, there are se(era! reasons

    6h# the (aporme!t partitionin" oeiients o

    mo!#4en&m in nat&ra! s#stems ma# 4e

    si"niiant!# hi"her than e5perimenta!!#

    etermine (a!&es. :or instane, porph#r#

    mo!#4en&m s#stems ha(e 2 onitions o

    a!-a!0a!ine ro0s 7a4o&t 2 !o" &nits a4o(e

    NNO; that are 6e!! a4o(e the 2s

    in(esti"ate e5perimenta!!# the trens o the

    e5perimenta! ata s&""est that mo!#4en&m

    sho&! 4e e(en more stron"!# partitione into

    the a?&eo&s phase &ner s&h hi"h 2

    onitions. Cane!a 7=1)14; a!so spe&!ates

    that i the o5iation state o mo!#4en&m in

    the a?&eo&s phase is hi"her than in the me!t,

    then the tenen# o mo!#4en&m to enter the

    (apor phase ma# 4e ompo&ne.

    Keith an Shan0s 7=1)); re(ie6e the

    e(iene that e5tension-re!ate trah#anesiti

    ma"mas 6ere episoia!!# inete into the

    4ase o the Pine Gro(e ma"ma ham4er. I

    s&h ma"mas are inete into the 4ase o a

    aiti or rh#o!iti ma"ma ham4er, the#

    6o&! ?&enh or r#sta!!i>e an re!ease

    (o!ati!es that o&! 4e !&5e thro&"h the

    ma"ma ham4er. Bamproph#ri ma"mas or

    !ess primiti(e K-rih mai ma"mas that are

    "enera!!# (o!ati!e-rih, ma# ha(e interate

    6ith C!ima5, Henerson, 9&art> Hi!!, an

    other porph#r# mo!#4en&m s#stems to

    pro&e simi!ar (o!ati!e !&5in".

    I s&h a mo!#4en&m-transportin"

    ma"mati !&i phase e5iste an 6as

    CO2-rih, then e(iene o CO2 in

    hi"h-temperat&re !&i in!&sions sho&!

    perhaps4e o&n. Binnen an i!!iams-Jones

    7=11; note that a?&eo&s-ar4oni !&i

    in!&sions are ommon in !&orine-eiient

    mo!#4en&m eposits, 4&t are sare in

    !&orine-rih eposits. Ho6e(er, hite et

    a=. 7=1)=; note that a ar4onate a&"hterminera! is present in some !&i in!&sions

    rom Henerson. Seeor 7=1)); o&n

    simi!ar a&"hter minera!s in !&i in!&sions

    rom a rhoohrosite-4earin" a!teration

    assem4!a"e at Henerson . Th&s, CO2-rih

    !&i in!&sions ha(e 4een o4ser(e at C!ima5

    an Henerson, 4&t are not a4&nant

    7Seeor, =1)) Ha!! et a!. =13*;.

    H#persa!ine !&i in!&sions are

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    SEG SP GIANT ORE DEPOSITS

    r*r# in !;# Fd#+ii#n! d#'o$i!$: 6u! ommon in&im*2!('# $($!#m$ ,Linn#n *nd 9ii*m$on#$: 155-0 . T;#$# d*!* $u))#$! !;*!o*!i# +u2in) 6( * &Ori; +uid ';*$# in&im*2!('# $($!#m$ m*( no! 6# * $i)ni+i*n!'ro#$$.

    An*($i$ o+ o*ni )*$ #mi$$ion$

    +rom*!i# o*no#$ indi*!#$ !;*! $u+urou$)*$#$ *r# #mi!!#d u'on !;# in+#rr#d *rri* o+

    n#= m*)m* *! !;# 6*$# o+ * m*)m* ;*m6#r.

    A! !;#+- ondi!ion$ o+ **k*in# m*)m*$:

    S- *nd HS =oud 6# 'r#$#n! =i!; *6ou!

    $u6A#Mu* +u)*i!i#$ ,9;i!n#(: 15880. T;# o=

    $ou6ii!( o+ S- in m*)m*$ m*( *o= * +u2

    o+ S-6#*rin) o*!i#$ !o ri$# !;rou); *

    on#d m*)m* ;*m6#r *nd '#r;*'$ $*#n)#

    mo(6d#num. Mo(6d#num i$ no! om'#2#d

    =i!; $u+ur 6u! !;# '*r!i!ionin) 6#;*ior o+

    mo(6d#num r#*!i# !o * +uid ';*$# !;*! i$

    ri; in *n o2idi#d $u+ur $'#i#$ ;*$ no! 6##nin#$!i)*!#d. Ind##d: +u2in) o+ Sri; +uid$

    !;rou); * m*)m* i$ 'ro6*6( re?&ire !o

    *oun! +or *r)# *moun! o+ m*)m*!i $u+ur

    *$$oi*!#d =i!; * )i*n! 'or';(r( mo(6d#num

    d#'o$i!. T;# o= $ou6ii!( o+ $u+ur in

    ;i);$ii* r;(oi!i m#!$ *r)u#$ +or $u; *

    'ro#$$: 6u! m*$$ 6**n# *u*!ion$ !o !#$!

    !;i$ $#n*rio =oud ino# mu; un#r!*in!(.

    Con(etion an (o!ati!e

    !&5in"

    T;#r# *r# $##r* r#*$on$ !o $u$'#!!;*! !;# 'ro#$$ o+ m#!* #nri;m#n! ino#$on#!ion *nd o*!i# +u2in) !;rou); **r)# oum# o+ !;# ;*m6#r. ?#i!; #! *.,1580 doum#n! !;*! *r)# 6ok$ o+6io!i!#ri; ,

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    8) SEG SP-2 GIANT ORE DEPOSITSSEG SP-2 GIANT ORE DEPOSITS 8)

    &rin" !&i o!!etion, then the !ar"er, or

    hi"her "rae, the eposit o&! 4e. Certain!#

    a sin"!e, 6e!!-sit&ate (ent 6o&!4e optima!.

    Smith 7=131; pointe o&t that entra!

    (ent (o!anoes o not er&pt more than a4o&t

    = 0m8 o ash !o6 t& !ar"er er&ption

    (o!&mes are re!ate to a!eras 6here

    m&!tip!e (ents are pro4a4!# in(o!(e, as is

    the ase o the 0m8 Ama!ia T& e5pe!!e

    rom the 9&esta a!era. Se(era! res&r"ent

    7or s!i"ht!# #o&n"er; p!&tons o&r a!on" the

    rin" rat&re an e!se6here a!! o the

    intr&sions are (aria4!# minera!i>e 6ith

    mo!#4enite 7Johnson et aI., =1)1;. In

    aition, the mo!#4enite-4earin" S&!ph&r

    G&!h an $ear Can#on p!&tons onnet at

    epth 7Beonarson et aI., =1)8;, 4&t on!#

    the S&!ph&r G&!h p!&ton is ore-"rae.

    /&!tip!e (ents or a!era-re!ate s#stems

    ma# not 4e as !i0e!# topro&e a sin"!e "iant

    eposit.

    The = @= ratio o ham4er (o!&me to

    er&ption (o!&me 7Smith, =131; s&""ests that

    a entra! (ent (o!ano that er&pts the

    ma5im&m = 0m8 o&! see no more than

    1--- 0m8, 4&t m&h !ess ma# 4e re?&ire

    onsierin" that = 0m8 o ma"ma strippe

    o 8 ppm o mo!#4en&m 6o&! s&pp!# a!! themeta! neee to orm the Henerson eposit.

    CHARACTERISTICS O: THE

    DEPOSITIONAB SITE

    There is no e(iene to iniate that

    C!ima5-t#pe s#stems more eiient!# eposit

    mo!#4en&m rom a ma"mati ore !&i than

    other t#pes 4&t the# ma# o it in a sma!!er

    (o!&me o ro0 t7; pro&e a hi"her "rae.

    Carten et a!. 7!1))a; ientiie one o theprimar# ontro!s or the eposition o

    mo!#4enite at Henerson as the presene o

    K-e!spar a!on" (ein mar"ins. estra an

    Keith 7=1)=; note a !inear orre!ation

    4et6een K>O ontent o h#rotherma!!#

    a!tere ro0 an "rae, K2-rih sto0s ma#

    ha(e e?&i!i4rate 6ith a !ar"er (o!&me o

    ma"mati 6ater prior to onso!iation, an

    there4# ori"ina!!# ontaine a "reater amo&nt

    o mo!#4en&m 7hite et a!., =1)=;.

    Ho6e(er, on a me sa!e, mo!#4enite

    r#sta!s are preerentia!!# eposite a!on"

    K-e!spar r#sta!s re!ati(e to ?&art> or other

    minera!s. Seriite separates mo!#4enite rom

    the K-e!spar. The hi"h moa! a4&nane o

    K-e!spar in some C !ima5-t#pe sto0s ma#

    4e, in part, a epositiona! ontro! to their

    "rae.

    C!ima5-t#pe eposits ma# a!so 4e

    hi"h-"rae &e to eposition rom a p&re!#

    ma"mati a?&eo&s phase that 4e"ins

    eposition at the ma"ma-6a!!ro0 interae.

    The ore-!&i or :-eiient eposits ma# 4e

    a mi5t&re o ma"mati an meteori 6ater

    an, at eposits s&h as Tro&t Ba0e, m&st

    ha(e oo!e at !east a e6 h&nre e"reesprior to minera!i>ation 7Binnen an

    i!!iams-Jones, =11;. This amo&nt o

    oo!in" an mi5in" ma# res&!t in eposition

    o(er a !ar"er (o!&me o ro0 res&!tin" in

    !o6er "raes. Deposition o mo!#4enite rom

    the ore !&i in 4oth C!ima5- an

    :-eiient-t#pe eposits is re!ate to

    ereasin" temperat&re anorpH 7Binnen an

    i!!iams-Jones, =11;.

    Proesses that ontro! the !oation an

    &ration o mo!#4enite eposition rom thea?&eo&s phase 6o&! a!so o4(io&s!# ontro!

    the "rae. These 6o&! in!&e m&!tip!e

    sto0s ormin" o(er!appin" ore 4oies an

    hi"h hemia! an therma! "raients aro&n

    the sto0 or p!&ton.

    S'//AR% /ODEB AND

    EPBORATION CRITERIA

    :rom the ore"oin" is&ssion it is

    apparent that the most si"niiant proess 7orpro4!em; in the ormation o C!ima5-t#pe

    eposits is sa(en"in" a e6 ppm

    mo!#4en&m rom a !ar"e ham4er e(ent&a!!#

    to #ie! an ore !&i 6ith tho&sans o ppm

    mo!#4en&m. A /o-rih ma"ma 6o&! 4e

    orme in the &po!a &rin" this proess &e

    to e?&i!i4ration 6ith the !&i ater its arri(a!

    an prior to re!ease &rin" minera!i>ation.

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    SEG SP-2 GIANT ORE DEPOSITS 8181 SEG SP-2 GIANT ORE DEPOSITS

    The o!!o6in" proesses appear to ha(e ate

    to"ether to pro&e a mo!#4en&m-rih

    &po!a o ma"ma@

    =. Cr#sta!!i>ation a!on" the 6a!!s or

    !oor o the ma"ma ham4er 6o&!

    ao&nt or the "ra&a!!# re&e RE$

    ontent o the ma"ma 4et6een

    s&essi(e intr&sions. The s&essi(e!#

    eeper '-shape REE patterns are not

    &ni?&e to C!ima5-t#pe s#stems, 4&t

    ha(e 4een note in oma"mati

    intr&sions rom other non-minera!i>e

    "ranitois 7Johnson et a! . , =1)1; .

    Gra&a! a&m&!ation o 6ater an

    !&orine a!on" the ham4er roo ma#

    !o6er the so ! i&s , pre(entr# s t a! !i >ation , an pe rmi t

    assimi!ation.

    2. 'nerp!ate or inete mai

    ma"mas ma# p!a# se(era! ro!es. The#

    ma# me!t the !o6er r&st an mi5 6ith

    !o6er r&sta! me!ts to pro(ie an

    o5ii>e m a "m a i n 6hih

    mo!#4en&m 6o&! 4e ha(e

    inompati4!# &rin" rationation.

    The# ma# pro(ie heat or@ a;on(eti(e transport o isso!(e an

    &nisso!(e (o!ati!es to the &po!a,4;

    assimi!ation o roo ro0s an the

    ores o o!er sto0s, ; e5tension o

    the !ie o the ham4er to a!!o6

    "eneration o a !ar"e (o!&me o

    rh#o!iti ma"ma an emp!aement o

    m&!tip!e intr&sions. The# ma# a!so

    s&pp!# some !&5 o !ess so!&4!e,

    espeia!!# s&!&ro&s , "ases .

    E5amination o the histories o most

    (o!anoes re(ea!s that the# ten to 4e

    omp!e5 rather than simp!e , 6ith the

    ommon o&rrene o repeate inetions

    o ma"ma, stora"e o ma"ma at ierent

    !e(e!s, an ma"mati e"assin" o&rrin"

    &rin" perios o re!ati(e ?&iesene or

    ati(it# . Ore eposits 6o&! 4e ar more

    ommon i simp!epassi(e

    r#sta!!i>ation o moest!# 6ater-rih ma"ma

    near the s&rae pro&e an ore eposit. In

    terms o inrease omp!e5it# 4e#on simp!e

    r#sta!!i>ation o &po!a ma"ma, this moe!

    on!# s&""ests that on(etion ais the

    transport o (o!ati!es pro&e 4#

    r#sta!!i>ation a!on" the 6a!!s an !oor an

    rom &nerp!ate mai ma"ma. The

    proesses o on(etion an (o!ati!e !&5in"

    ma# ha(e he!pe transorm /o-poor ma"ma

    78 ppm; into /o-rih ma"ma 7 < =ppm;,

    an enrihment that other6ise 6o&! 4e

    impossi4!e 4# r#sta! rationation a!one

    . Simi!ar proesses ma# ha(e operate in the

    parent ma"ma ham4ers o man# porph#r#

    /o s#stems, a!tho&"h the e(iene or

    theseproesses oten annot 4e o&n inminera!i>e &po!as a!one. Geohemia! ata

    re(ie6e here s&""est that initia!!# hi"h

    inompati4!e trae e!ement a4&nanes ma#4e

    m&h !ess a a&se o minera!i>ation than

    the a4o(e proesses. Ho6e(er, !&orine an

    6ater ma# 4e important positi(e ee4a0

    parameters as their onentrations inrease,

    the# re&e the (isosit# o the ma"ma an

    a!!o6 more rapi on(etion an a&m&!ation

    o ore !&i omponents in the &po!a.

    E5p!oration riteria or a "iant,hi"h-"rae eposit in!&e@

    = . a tetoni settin" that iniates a

    han"eo(er rom ompressiona! to

    e5tensiona! tetonis,

    2. thi0 ontinenta! r&st at the time

    o eposit ormation ma# eno&ra"e

    e5treme ierentiation an r&sta!

    ontamination,

    8. an isotopia!!# >one ma"ma

    ham4er iniati(e o a !on"-!i(e

    heat so&re,

    *. a !ar"e, s&4-(o!ani, entra!-(ent

    ash !o6ome s#stem that er&pte !ess

    than = 0m8 o rh#o!ite, an

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    . hi"h nio4i&m onentrations 7 < 3

    p p m ; i n a s & 4 a ! 0 a ! i n e ,

    ma"netite-4earin" rh#o!ite.

    ACKNOBEDGE/ENTS

    Re(ie6s o this paper 4# J. :. H.Thompson an A. H. C!ar0 are "rate&!!#

    a0no6!e"e . e appreiate the patiene

    an he!p&!ness o the eitors - espeia!!#

    $en hitin" . This 6or0 6as s&pporte 4#

    NS: "rant EAR-)1*33* to JDK.

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    SEG SP-2 GIANT ORE DEPOSITS 8==SEG SP-2 GIANT ORE DEPOSITS8==

    transer a!&!ations . o meta!

    onentrations. in hitne# , J.A. ,

    an Na!rett, A.J . , es . , Ore

    eposition assoiate 6ith ma"mas.

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    28-22= .

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    , es. , Ore eposition assoiate

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    re!etion o their so&re re"ionsM.

    Contri4 . /inera! . Petro! . , (o!.

    =+, p.

    =21-=* = .

    Carten,R. $. , Gera"ht#, E.P. , a!0er,$./. ,

    an Shannon, J.R. , =1))a, C#!i

    e(e!opment o i"neo&s eat&res an

    their re!ationship to hi"h-temperat&re

    h#rotherma! eat&res in the

    Henerson porph#r# mo!#4en&meposit Co!orao. Eon. Geo!. , (o!.

    )8, p. 2++-21+.

    Carten ,R.$ . , Gera"ht#, E. P. , a!0er,$./. ,

    an Shannon, J.R. , =1))a, C#!i

    "eneration o 6ea0!# an ston"!#

    minera!i>in" intr&sions in

    the Henerson porph#r#

    mo!#4en&m eposit, Co!orao @

    Corre!ation o i"neo&s eat&res 6ith

    hi"h-temperat&re h#rotherma!

    a!teration. Eon . Geo!. , (o!.

    2++-21+.

    Carten,R.$. , a!0er,$. /. , Gera"ht#,

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    SEG SP-2 GIANT ORE DEPOSITS 8=2SEG SP-2 GIANT ORE DEPOSITS8=2

    an G&no6, A. J., =1))4,

    Comparison o ie! 4ase st&ies o

    the Henerson porph#r#

    mo!#4en&m eposit, Co!orao ,

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    moe!s o porph#r# s#stems. in

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    , Reent a(anes in the "eo!o"#

    o "ranite-re!ate minera! eposits .

    Canaian Inst. /in . /eta!! . , Speia!

    o!&me 81, p. 8=-8++.

    en , R.$. , hite, . H., an Stein, H.!. ,

    in press, Hi"h-"rae "ranite-re!ate

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    D epos i t /oe!in" Pro"ram.

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    The !assiiation an "enesis

    o sto06or0 mo!#4en&m

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    o topa> rh#o!ites rom the

    6estern 'nite States . Geo! . So.

    Ameria, Speia! Paper2, )2p.

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    "ranites rom ep!ete r&sta!

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    Ceno>oi o 6estern 'tah, 'SA. in

    Ta#!or, R.P, an Stron", D.:., es . ,

    Reent a(anes in the "eo!o"#

    o "ranite-re!ate minera!

    eposits. Canaian !nst. /in. /eta!!

    . , Speia! o!&me 81,p. 83-82= .

    Con"on, R.D. , an Nash, .P. , =11= ,

    Er&pti(e pe"matite ma"ma@ Rh#o!ite

    o the Hone#om4 Hi!!s, 'tah .

    Amerian /inera!. , (o!. 3+, p.

    =2+=-=23).

    C#"an, G.B. , an Cho& , I-/in",

    =1)3, Ca!i4ration o the 2-8

    4&er. EOS, (o!. +),p. *= .

    DePao!o, D.J. , =1) =, N in the Co!orao

    :ront Ran"e an imp!iations orr&st

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    ormation an mant!e e(o!&tion inthe

    Protero>oi . Nat&re , (o! . 21= ,p.

    =18- =1+.

    :armer, G.B. , an DePao!o , D. J . ,

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    'nite States an imp!iations or

    pre-/eso>oi r&sta! str&t&re 2. N

    an Sr isotopi st&ies o

    &nminera!i>e an C&- an /o-

    minera!i>e "ranite in the

    Pream4rian raton. Jo&r. Geoph#s.

    Res . , (o!. )1,p. =,=*=-=,=+.

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    Emmons eposit Va4s .W . Amerian

    Inst. /in. /eta!! . Pet. En" . ,

    Ann&a! /eetin" Pro"ram, p . 2= .

    Ge#ti , A. , an Shon6ant, H.K. , =131,

    $or(i0a--a possi4!e porph#r#

    mo!#4en&m o&rrene 6ith the Os!o

    rit,Nor6a# . Eon. Geo! . , (o!. 3*,

    p.

    =2= =-=22.

    Ge#ti, A., an Thomasson, $., =1)*,

    /o!#4en&m an preio&s meta!

    minera!i>aiton at :!amme e!,

    So&th East Green!an. Eon. Geo!. ,

    (o!. 31 ,

    p . =12=-=121

    .

    Gi!es , D.B. , an Thompson, T. $.,

    =132, Petro!o"# an

    minera!i>aion o a mo!#4en&m-

    4earin" a!0a!i sto0, Sierra $!ana,

    Ne6 /e5io . Geo! . So . Ameria

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    2 =*).

    Go(inara&, K. , =1)1, =1)1 ompi!ation

    o 6or0in" (a!&es an samp!e

    esription or 232 "eostanars.

    Geostanars Ne6s!etter, (o!. = 8,

    Speia! Iss&e,p.

    =-= =8.

    Ha!!, .E. , :rieman, 1 . : anNash, J.T.,

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    sierophi!e an ha!ophi!e trae

    e!ements amon" mant!e-eri(e

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    s&!phies etete 4# in- sit&

    miro-PIE ana!#sis. EOS, (o!. 83 , '.

    8** .

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    "eohemistr# o the

    p or ph #r# sto 06or0

    mo!#4en&m eposit at Tam4oras, Ba

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    (o!.

    ), p. 2 =1-223.

    Hi!reth, ., =1)=, Graients in si!ii

    ma"ma ham4ers @ Imp!iations

    or !ithospheri ma"mati sm .

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    =, =8-

    =, =

    12.Ho!!ister , .: . , = 1 3)4 ,

    Porph#r# mo!#4en&m eposits . in

    S&t&!o(, A . , e . , Internationa!

    mo!#4en&m en#!opaeia =33)-

    =13) , o!&me = . Santia"o, Chi!e,

    Intermet P&4!iations,p. 23-2)).

    H&son, T., Ar!;: J. G. , an /&th, K.G. ,

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    ro0s assoiate 6ith mo!#4enite

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    so&theastern A!as0a . Eon. Geo!. ,

    (o!. 3+, p.

    =22- =282.

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    =1)2, /inera!i>ation, 6a!! ro0

    a!teration an >onation o ore epositsassoiate 6ith the Drammen Granite

    in the Os!o Re"ion , Nor6a# .

    in E(ans, A. /. , e. ,

    /eta!!i>ation assoiate 6ith ai

    ma"matism. Chihester, John i!e# ,

    p. = ==-=8+.

    I(ano(a, G.:. , =1+8 , Content o tin,

    t&n"sten, mo!#4en&m, in "ranites

    en!osin" tin-t&n"sten eposits.

    Geohemistr#, (o!. ), p. *12-.

    Johnson, C./. , an :ririh, C.J. , =11,Non-monotoni hemia! an -: Sr,N, an P4 isotope >onations an

    hetro"eniet# in the mai- to

    si!ii-omposition ma"ma ham4er o

    the Gri>>!# Pea0 T&, Co!orao.

    Contri4 . /inera! . Petro! . , (o!. = ,

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    +33-+1.

    Johnson, C. /. , an Bipman, P.. , =1)),

    Ori"in o meta!&mino&s an a!0a!ine

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    SEG SP-2 GIANT ORE DEPOSITS 8=88=8 SEG SP-2 GIANT ORE DEPOSITS

    (o!ani ro0s o the Bati (o!ani

    ie!, northern Rio Grane ri+!: Ne6

    /e5io. Contri4. /inera!. Petro!.,

    (o!. =, p. =3-=2).

    Johnson, C./., C>amans0e, G.K., an

    Bipman P. ., =1)1, Geohemistr#

    o intr&si(e ro0s assoiate 6ith

    the Batir (o!ani ie!, Ne6 /e5io,

    an ontrasts 4et6een e(o!&tion o

    p!&toni an (o!ani ro0s. Contri4.

    /inera!. Petro!., (o!. =8, p. 1- =1.

    Johnson , C. /., Bipman, P..,

    an C>amans0e, =11, H, , Sr, N,

    an P4 isotope "eohemistr# o the

    Bati (o!ani ie! an o"eneti

    intr&sions, Ne6 /e5io, an re!ations

    4et6een e(o!&tion o a ontinenta!

    ma"mati enter an

    moiiations o the !ithosphere.

    Contri4. /inera!. Petro!. , (o!. = *,

    p. 11- =2*.

    Keith, J.D., =1)2, /a"mati e(o!&tion o the

    Pine Gro(e porph#r# mo!#4en&ms#stem, so&th6estern U!*;. &np&4!.Ph.D. thesis, Dni(.

    isonsin, /aison, isonsin,

    2*+ p.

    Keith, J.D., Shan0s, D.e., III,

    Arhi4a!, D. A., an :arrar, E.,=

    1)+, o!ani an intr&si(e histor# o

    the Pine Gro(e porph#r#

    mo!#4en&m s#stem,

    so&th6estern U!*;. Eon. Geo!., (o!.

    )=, p. 8-33.

    Keith, J.D. , an Shan0s, .C., III,

    =1)), Chemia!e(o!&tion an

    (o!ati!e &"aities o the Pine Gro(e

    porph#r# mo!#4en&m an ash-!o6

    t& s#stem,

    so&th6estern U!*;. in Ta#!or, R.P,an Stron", D. :., es., Reent

    a(anes in the "eo!o"# o

    "ranite-re!ate minera! eposits.

    Canaian Inst. /in. /eta!!., Speia!

    o!&me 81, p. *2-*28.

    Keith, I.D., (an /i!e!aar, ., C!ar0,

    A. H. , an Ho"son, C.I., =1)1,

    Granitoi te5t&res, ompositions, an

    (o!ati!e &"aities assoiate 6ith the

    ormation o t&n"sten-ominate s0arn

    eposits. in hitne#, I. A.,an

    Na!rett, A. J. , es., Ore eposition

    assoiate 6ith ma"mas. Re(ie6s in

    Eon. Geo!., (o!. *, p. 28-2.

    Kepp!er, H., an #!!ie, P. I., =11=, Partitionin" o C&, Sn, /o,D, U:an Th 4et6een me!t an a?&eo&s

    !&i in the s#stem hap!o"ranite-H2-

    HC! an hap!o"ranite-H2-H:.

    Contri4. /inera!. Petro!., (o!. =1, p.

    =81- =

    .

    Kir0ham, R. ., /Carn, C., Prasa, N.,

    Sore"aro!i, A. E., o0es, :./., an

    ine, G ., =1)2, /o!#4en&m in

    Canaa, Part 2@ /OB%:IBE--An

    ine5-!e(e! omp&ter i!e o

    mo!#4en&m eposits an o&rrenes

    in Canaa. Geo!. S&r(. Canaa, Eon.

    Geo!. Report 88, 2)p.

    Knitte!, D. , an $&rton, C.K., =1), Po!o!Io

    Is!an 7Phi!ippines;@ /o!#4en&m

    minera!i>ation in an is!an ar. Eon.

    Geo!., (o!. ), p. 2 =8-2 =).

    Kooiman, G.J.A., /Beo, /.J., an

    Sin!air, .D. , = 1)+,

    Porph#r# t&n"sten-mo!#4en&m

    ore4oies, po!#meta!!i (eins an

    rep!aement 4oies, an tin-4earin"

    "reisen >ones in the :ire

    To6er one, /o&nt P!easant,

    Ne6 $r&ns6i0. Eon. Geo!., (o!.

    )=,p. =8+-=838.

    Ko(a!en0o, . I., Antipin, .S., Kon&so(a,

    . ., Smirno(a, %e.., Petro(, B.B.,

    !a#0in, N. . , K&>netso(a, A.I.,

    Kost#&0o(a, %e.S., an Pisars0a#a,

    .A., =13), Partition oeiients o

    !&orine, nio4i&m, tan ta!&m,

    !anthan&m, #tter4i&m, #ttri&m, tin an

    t&n"sten in on"onite. Geohemistr#

    Inti., (o!. =, p. 28-2.

    Ko(a!en0o, . I., Samo#!o(, . S. , an

    Gore"!#a, A.., =1)=, o!ani

    on"onites enrihe in rare e!ements.

    Do0!a# A0aemia Na&0 SSSR, (o!.

    2*+,p. )-+=.

    K&roa, P.K. , an Sane!!, E.$., =1*,

    Geohemistr# o mo!#4en&m.

    Geohim. Cosmohim. Ata, (o!. +,

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    8=* SEG SP-2 GIANT ORE DEPOSITS

    p. 8-+8.

    Beonarson, R.., D&n!ap, G., Star?&ist,

    .B. , $ratton, G.P., /e#er, J.. ,

    Os4orn, B .., At0in, S.A., /o!!in",

    P.A., /oore, R.:., !more, S.D.,

    =1)8, Pre!iminar# "eo!o"# an

    mo!#4en&m eposits at 9&esta, Ne6