Laxmi Agro Industrial Consultants & Exporters Ltd.environmentclearance.nic.in/writereaddata/FormB/TOR/Additional...Laxmi Agro Industrial Consultants & Exporters Ltd. ... Manufacturing

Laxmi Agro Industrial Consultants & Exporters Ltd. S. NO. 153/3, AT – Padana, TA– Gandhidham, Dist - Kutch -370240, GUJARAT

Email – [email protected], (M) 098100-25410

INDEX FOR ADDITIONAL ATTACHMENTS

Sr. No. Name of Enclosure

1. Name of Product with its quantity.

2. Packing and Final use of Product.

3. Name of Raw Material with its quantity.

4. MSDS of Raw Material and Product

5. Chemical name & Physical form of Raw Material with its storage facility

6. Details of Hazardous chemicals

7. Manufacturing Process with Chemical Reactions & Mass Balance

8. Details of water consumption and waste water generation

9. Details of Flue gas emission and process gas emission with APCD system

10. Details of hazardous waste generation with its management.

11. Land Supporting documents

12. Existing Consent Order copy

13. Layout Plan of Unit.

14. Name and Address of Partners

15. CA Certficate

16. DIC Certificate

17. Water Permission Letter



Enclosure: 01

Name of Product with its Qty.

Sr.

No. Name of Proposed Products

Quantity in MT /M

Existing Proposed Total After

Expansion

1. Acid Slurry / Linear Alkyl

Benzene Sulphonic Acid

(LASBSA)

1750 1750 3500

2. Sulphuric Acid – By Product

(70 – 75 %)

1500 1500 3000

Enclosure: 02



Packing & Final Use of Products

Sr. No. Name Of Products Type of

Packing

Storage

Facility

Final Application of

Product

1. Acid Slurry / Linear Alkyl

Benzene Sulphonic Acid

(LASBSA)

Tank MS storage

Tank

As a surfactant in

detergent Industries.

2. Spent Sulphuric Acid – By

Product

(70 – 75 %)

Tank MS storage

Tank

Use in fertilizer

industries, mineral

Benification

industries etc.

Tank details of LABSA:

Tank No. Capacity in KL No. of Tank Sp.Gr. Capacity in MT

1 212 01 1.07 226

2 72 x 02 02 1.07 154

3 42 01 1.07 45

4 25 01 1.07 26

5 16 01 1.07 16

Total 439 06 1.07 467


Email – [email protected], (M) 098100-25410 Tank details of Spent Sulphuric Acid(70 - 75 %):


1 94 x 02 02 1.63 306

2 42 01 1.63 68

3 16 01 1.63 26

Total 246 04 1.63 400



Enclosure: 03

Name of Raw Material with its Quantity

No. Name of Product Name of Raw Material Qty. in

MT/MT

Qty. in MT /M

1.

Acid Slurry / Linear

Alkyl Benzene

Sulphonic Acid

(LASBSA)

[Spent Sulphuric Acid – By Product]

Linear Alkyl Benzene 0.680 1190

Sulphuric Acid 1.057 1850

Water 0.12 210



Enclosure: 04

Material Safety data Sheet of Raw Material and product

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Fire

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Material Safety Data SheetSulfuric acid MSDS

Section 1: Chemical Product and Company Identification

Product Name: Sulfuric acid

Catalog Codes: SLS2539, SLS1741, SLS3166, SLS2371,SLS3793

CAS#: 7664-93-9

RTECS: WS5600000

TSCA: TSCA 8(b) inventory: Sulfuric acid

CI#: Not applicable.

Synonym: Oil of Vitriol; Sulfuric Acid

Chemical Name: Hydrogen sulfate

Chemical Formula: H2-SO4

Contact Information:

Sciencelab.com, Inc.14025 Smith Rd.Houston, Texas 77396

US Sales: 1-800-901-7247International Sales: 1-281-441-4400

Order Online: ScienceLab.com

CHEMTREC (24HR Emergency Telephone), call:1-800-424-9300

International CHEMTREC, call: 1-703-527-3887

For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Sulfuric acid 7664-93-9 95 - 98

Toxicological Data on Ingredients: Sulfuric acid: ORAL (LD50): Acute: 2140 mg/kg [Rat.]. VAPOR (LC50): Acute: 510 mg/m2 hours [Rat]. 320 mg/m 2 hours [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects:Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion,of inhalation. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth andrespiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratorytract, characterized by coughing, choking, or shortness of breath. Severe over-exposure can result in death. Inflammation ofthe eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening,or, occasionally, blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC, + (Proven.) by OSHA. Classified A2 (Suspected forhuman.) by ACGIH. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTALTOXICITY: Not available. The substance may be toxic to kidneys, lungs, heart, cardiovascular system, upper respiratory tract,eyes, teeth. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged

http://www.sciencelab.com/

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contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spraymist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to a highlytoxic material may produce general deterioration of health by an accumulation in one or many human organs.

Section 4: First Aid Measures

Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention immediately.

Skin Contact:In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothingand shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly cleanshoes before reuse. Get medical attention immediately.

Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medicalattention.

Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention immediately.

Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Ifbreathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It maybe hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious orcorrosive. Seek immediate medical attention.

Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.

Flash Points: Not applicable.

Flammable Limits: Not applicable.

Products of Combustion:Products of combustion are not available since material is non-flammable. However, products of decompostion include fumesof oxides of sulfur. Will react with water or steam to produce toxic and corrosive fumes. Reacts with carbonates to generatecarbon dioxide gas. Reacts with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.

Fire Hazards in Presence of Various Substances: Combustible materials

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Slightly explosive in presence of oxidizing materials.

Fire Fighting Media and Instructions: Not applicable.

Special Remarks on Fire Hazards:Metal acetylides (Monocesium and Monorubidium), and carbides ignite with concentrated sulfuric acid. White Phosphorous +boiling Sulfuric acid or its vapor ignites on contact. May ignite other combustible materials. May cause fire when sulfuric acidis mixed with Cyclopentadiene, cyclopentanone oxime, nitroaryl amines, hexalithium disilicide, phorphorous (III) oxide, andoxidizing agents such as chlorates, halogens, permanganates.

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Special Remarks on Explosion Hazards:M i x t u r e s o f s u l f u r i c a c i d a n d a n y o f t h e f o l l o w i n g c a n e x p l o d e : p - n i t r o t o l u e n e , p e n t a s il v e r trihydroxydiaminophosphate, perchlorates, alcohols with strong hydrogen peroxide, ammonium tetraperoxychromate,mercuric nitrite, potassium chlorate, potassium permanganate with potassium chloride, carbides, nitro compounds, nitrates,carbides, phosphorous, iodides, picratres, fulminats, dienes, alcohols (when heated) Nitramide decomposes explosivelyon contact with concentrated sulfuric acid. 1,3,5-Trinitrosohexahydro-1,3,5-triazine + sulfuric acid causes explosivedecompositon.

Section 6: Accidental Release Measures

Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Ifnecessary: Neutralize the residue with a dilute solution of sodium carbonate.

Large Spill:Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water sprayto reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentrationlevel above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:Keep locked up.. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and showthe container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, reducingagents, combustible materials, organic materials, metals, acids, alkalis, moisture. May corrode metallic surfaces. Store in ametallic or coated fiberboard drum using a strong polyethylene inner package.

Storage:Hygroscopic. Reacts. violently with water. Keep container tightly closed. Keep container in a cool, well-ventilated area. Do notstore above 23°C (73.4°F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respectivethreshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Personal Protection:Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.

Exposure Limits:TWA: 1 STEL: 3 (mg/m3) [Australia] Inhalation TWA: 1 (mg/m3) from OSHA (PEL) [United States] Inhalation TWA: 1 STEL: 3(mg/m3) from ACGIH (TLV) [United States] [1999] Inhalation TWA: 1 (mg/m3) from NIOSH [United States] Inhalation TWA: 1(mg/m3) [United Kingdom (UK)]Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

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Physical state and appearance: Liquid. (Thick oily liquid.)

Odor: Odorless, but has a choking odor when hot.

Taste: Marked acid taste. (Strong.)

Molecular Weight: 98.08 g/mole

Color: Colorless.

pH (1% soln/water): Acidic.

Boiling Point:270°C (518°F) - 340 deg. C Decomposes at 340 deg. C

Melting Point: -35°C (-31°F) to 10.36 deg. C (93% to 100% purity)

Critical Temperature: Not available.

Specific Gravity: 1.84 (Water = 1)

Vapor Pressure: Not available.

Vapor Density: 3.4 (Air = 1)

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: See solubility in water.

Solubility:Easily soluble in cold water. Sulfuric is soluble in water with liberation of much heat. Soluble in ethyl alcohol.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability:Conditions to Avoid: Incompatible materials, excess heat, combustible material materials, organic materials, exposure to moistair or water, oxidizers, amines, bases. Always add the acid to water, never the reverse.

Incompatibility with various substances:Reactive with oxidizing agents, reducing agents, combustible materials, organic materials, metals, acids, alkalis, moisture.

Corrosivity:Extremely corrosive in presence of aluminum, of copper, of stainless steel(316). Highly corrosive in presence of stainlesssteel(304). Non-corrosive in presence of glass.

Special Remarks on Reactivity:Hygroscopic. Strong oxidizer. Reacts violently with water and alcohol especially when water is added to the product.Incompatible (can react explosively or dangerously) with the following: ACETIC ACID, ACRYLIC ACID, AMMONIUMHYDROXIDE, CRESOL, CUMENE, DICHLOROETHYL ETHER, ETHYLENE CYANOHYDRIN, ETHYLENEIMINE, NITRICACID, 2-NITROPROPANE, PROPYLENE OXIDE, SULFOLANE, VINYLIDENE CHLORIDE, DIETHYLENE GLYCOLMONOMETHYL ETHER, ETHYL ACETATE, ETHYLENE CYANOHYDRIN, ETHYLENE GLYCOL MONOETHYL ETHERACETATE, GLYOXAL, METHYL ETHYL KETONE, dehydrating agents, organic materials, moisture (water), Acetic anhydride,Acetone, cyanohydrin, Acetone+nitric acid, Acetone + potassium dichromate, Acetonitrile, Acrolein, Acrylonitrile, Acrylonitrile+water, Alcohols + hydrogen peroxide, ally compounds such as Allyl alcohol, and Allyl Chloride, 2-Aminoethanol, Ammoniumhydroxide, Ammonium triperchromate, Aniline, Bromate + metals, Bromine pentafluoride, n-Butyraldehyde, Carbides, Cesiumacetylene carbide, Chlorates, Cyclopentanone oxime, chlorinates, Chlorates + metals, Chlorine trifluoride, Chlorosulfonicacid, 2-cyano-4-nitrobenzenediazonium hydrogen sulfate, Cuprous nitride, p-chloronitrobenzene, 1,5-Dinitronaphthlene +

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sulfur, Diisobutylene, p-dimethylaminobenzaldehyde, 1,3-Diazidobenzene, Dimethylbenzylcarbinol + hydrogen peroxide,Epichlorohydrin, Ethyl alcohol + hydrogen peroxide, Ethylene diamine, Ethylene glycol and other glycols, , Ethylenimine,Fulminates, hydrogen peroxide, Hydrochloric acid, Hydrofluoric acid, Iodine heptafluoride, Indane + nitric acid, Iron, Isoprene,Lithium silicide, Mercuric nitride, Mesityl oxide, Mercury nitride, Metals (powdered), Nitromethane, Nitric acid + glycerides,p-Nitrotoluene, Pentasilver trihydroxydiaminophosphate, Perchlorates, Perchloric acid, Permanganates + benzene, 1-Phenyl-2-methylpropyl alcohol + hydrogen peroxide, Phosphorus, Phosphorus isocyanate, Picrates, Potassium tert-butoxide,Potassium chlorate, Potassium Permanganate and other permanganates, halogens, amines, Potassium Permanganate +Potassium chloride, Potassium Permanganate + water, Propiolactone (beta)-, Pyridine, Rubidium aceteylene carbide, Silverpermanganate, Sodium, Sodium carbonate, sodium hydroxide, Steel, styrene monomer, toluene + nitric acid, Vinyl acetate,Thalium (I) azidodithiocarbonate, Zinc chlorate, Zinc Iodide, azides, carbonates, cyanides, sulfides, sulfites, alkali hydrides,carboxylic acid anhydrides, nitriles, olefinic organics, aqueous acids, cyclopentadiene, cyano-alcohols, metal acetylides,Hydrogen gas is generated by the action of the acid on most metals (i.e. lead, copper, tin, zinc, aluminum, etc.). Concentratedsulfuric acid oxidizes, dehydrates, or sulfonates most organic compounds.

Special Remarks on Corrosivity:Non-corrosive to lead and mild steel, but dillute acid attacks most metals. Attacks many metals releasing hydrogen. Minorcorrosive effect on bronze. No corrosion data on brass or zinc.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 2140 mg/kg [Rat.]. Acute toxicity of the vapor (LC50): 320 mg/m3 2 hours [Mouse].

Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC, + (Proven.) by OSHA. Classified A2 (Suspectedfor human.) by ACGIH. May cause damage to the following organs: kidneys, lungs, heart, cardiovascular system, upperrespiratory tract, eyes, teeth.

Other Toxic Effects on Humans:Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (corrosive, irritant,permeator), of eye contact (corrosive), of ingestion, .

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans:Mutagenicity: Cytogenetic Analysis: Hamster, ovary = 4mmol/L Reproductive effects: May cause adverse reproductive effectsbased on animal data. Developmental abnormalities (musculoskeletal) in rabbits at a dose of 20 mg/m3 for 7 hrs.(RTECS)Teratogenecity: neither embryotoxic, fetoxic, nor teratogenetic in mice or rabbits at inhaled doses producing some maternaltoxicity

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes severe skin irritation and burns. Continued contact can cause tissue necrosis.Eye: Causes severe eye irritation and burns. May cause irreversible eye injury. Ingestion: Harmful if swallowed. May causepermanent damage to the digestive tract. Causes gastrointestial tract burns. May cause perforation of the stomach, GIbleeding, edema of the glottis, necrosis and scarring, and sudden circulatory collapse(similar to acute inhalation). It mayalso cause systemic toxicity with acidosis. Inhalation: May cause severe irritation of the respiratory tract and mucousmembranes with sore throat, coughing, shortness of breath, and delayed lung edema. Causes chemical burns to the repiratorytract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis,and pulmonary edema. Cause corrosive action on mucous membranes. May affect cardiovascular system (hypotension,depressed cardiac output, bradycardia). Circulatory collapse with clammy skin, weak and rapid pulse, shallow respiration, andscanty urine may follow. Circulatory shock is often the immediate cause of death. May also affect teeth(changes in teeth andsupporting structures - erosion, discoloration). Chronic Potential Health Effects: Inhalation: Prolonged or repeated inhalationmay affect behavior (muscle contraction or spasticity), urinary system (kidney damage), and cardiovascular system, heart(ischemic heart leisons), and respiratory system/lungs(pulmonary edema, lung damage), teeth (dental discoloration, erosion).Skin: Prolonged or repeated skin contact may cause dermatitis, an allergic skin reaction.

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Section 12: Ecological Information

Ecotoxicity: Ecotoxicity in water (LC50): 49 mg/l 48 hours [bluegill/sunfish].

BOD5 and COD: Not available.

Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:Sulfuric acid may be placed in sealed container or absorbed in vermiculite, dry sand, earth, or a similar material. It may alsobe diluted and neutralized. Be sure to consult with local or regional authorities (waste regulators) prior to any disposal. Wastemust be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Class 8: Corrosive material

Identification: : Sulfuric acid UNNA: 1830 PG: II

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:Illinois toxic substances disclosure to employee act: Sulfuric acid New York release reporting list: Sulfuric acid RhodeIsland RTK hazardous substances: Sulfuric acid Pennsylvania RTK: Sulfuric acid Minnesota: Sulfuric acid MassachusettsRTK: Sulfuric acid New Jersey: Sulfuric acid California Director's List of Hazardous Substances (8 CCR 339): Sulfuric acidTennessee RTK: Sulfuric acid TSCA 8(b) inventory: Sulfuric acid SARA 302/304/311/312 extremely hazardous substances:Sulfuric acid SARA 313 toxic chemical notification and release reporting: Sulfuric acid CERCLA: Hazardous substances.:Sulfuric acid: 1000 lbs. (453.6 kg)

Other Regulations:OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on theEuropean Inventory of Existing Commercial Chemical Substances.

Other Classifications:

WHMIS (Canada):CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS E: Corrosive liquid.

DSCL (EEC):R35- Causes severe burns. S2- Keep out of the reach of children. S26- In case of contact with eyes, rinse immediately withplenty of water and seek medical advice. S30- Never add water to this product. S45- In case of accident or if you feel unwell,seek medical advice immediately (show the label where possible).

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 2

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Personal Protection:

National Fire Protection Association (U.S.A.):

Health: 3

Flammability: 0

Reactivity: 2

Specific hazard:

Protective Equipment:Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Face shield.

Section 16: Other Information

References:-Material safety data sheet emitted by: la Commission de la Santé et de la Sécurité du Travail du Québec. -The Sigma-AldrichLibrary of Chemical Safety Data, Edition II. -Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., VanNostrand Reinold, 1987.

Other Special Considerations: Not available.

Created: 10/09/2005 11:58 PM

Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assumeno liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.

Material Safety Data SheetLinear Alkylbenzene Sulfonate, 1 mL = 1mg

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Section 1 - Chemical Product and Company Identification

MSDS Name:Linear Alkylbenzene Sulfonate Standard, 1 mL = 1 mg

Catalog Numbers:LC16150

Synonyms:

Company Identification:LabChem, Inc.200 William Pitt WayPittsburgh, PA 15238

Company Phone Number:(412) 826-5230

Emergency Phone Number:(800) 424-9300

CHEMTREC Phone Number:(800) 424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name: Percent25155-30-0 Sodium dodecylbenzene sulfonate 0.107

7664-93-9 Sulfuric acid <1

7732-18-5 Water Balance

Section 3 - Hazards Identification

Emergency OverviewAppearance: clear, colorless solution

Caution! Corrosive. Causes irritation or burns to eyes, skin, digestive andrespiratory tracts. Risk of serious eye damage. Toxic. Harmful if swallowed.

Target Organs: Eyes, skin, respiratory system, teeth

Potential Health EffectsEye:

Causes eye irritation and burns. Eye contact can result in blindness; exposure to mist leads towatering, irritation.

Skin:Skin contact may result in severe burns, blistering and pain.

Ingestion:May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.Vomiting and diarrhea of dark blood may occur; asphyxia from throat swelling. Stomach andesophagus may become perforated.

ISO9001:2000 Certified


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Inhalation:May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath,and delayed lung edema. Causes chemical burns to the respiratory tract. At 5 mg/m3concentrations, nose and throat irritation occurs, with headache, cough, increased respiratory rate,impairment of lung to ventilate.

Chronic:Delayed symptoms include tight chest, fluid in lungs, cyanosis (blue color), hypotension, bronchitisor emphysema, tracheobronchitis, dental erosion/discoloration, pneumonia, gastrointestinaldisturbances may occur. Skin irritation/dermatitis, conjunctivitis, and lacrimation of the eye mayoccur.

Section 4 - First Aid Measures

Eyes:Immediately flush eyes with copious amounts of water for at least 15 minutes, lifting the upper andlower lids until chemical is gone. Get medical aid immediately.

Skin:Flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing andshoes. Get medical aid.

Ingestion:Do NOT induce vomiting. Give conscious victim 30 mL (1 ounce) milk of magnesia and largequantities of water to dilute acid. Get medical aid at once. Never give anything by mouth to anunconscious person.

Inhalation:Remove to fresh air immediately. If not breathing, give artificial respiration. If breathing isdifficult, give oxygen. Get medical aid at once.

Notes to Physician:Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information:As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH(approved or equivalent), and full protective gear. Contact with metals may evolve flammablehydrogen gas. Avoid breathing toxic and corrosive vapors. Emits toxic fumes under fireconditions.

Extinguishing Media:Use extinguishing media most appropriate for the surrounding fire.

Autoignition Temperature:No information found.

Flash Point:No information found.

NFPA Rating:CAS# 7732-18-5: Not published.CAS# 7664-93-9: Health- 3, Flammability- 0, Reactivity- 2CAS# 25155-30-0: Health- 2, Flammability- 0, Reactivity-0

Explosion Limits:Lower: N/A Upper: N/A


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Section 6 - Accidental Release Measures

General Information:Use proper personal protective equipment as indicated in Section 8.

Spills/Leaks:May be neutralized with slaked lime, limestone, or sodium bicarbonate to pH 7. Place in labeled plasticcontainers for disposal; wash down area with water.

Section 7 - Handling and Storage

Handling:Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Use withadequate ventilation. Avoid prolonged or repeated exposure.

Storage:Do not store near alkaline substances. Store in tightly closed, labeled, non-reactive containers (glass, plastic)protected from heat and incompatible substances.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls:Use adequate general or local exhaust ventilation to keep airborne concentrations below thepermissible exposure limits.

Exposure Limits:Chemical Name: ACGIH NIOSH OSHA

Water Not included on this list Not included on this list Not included on this listSulfuric acid 1 mg/m3 TWA; 3 mg/mL

STEL1 mg/m3 TWA 1 mg/m3 TWA

Sodium dodecylbenzenesulfonate

Not included on this list Not included on this list Not included on this list

OSHA Vacated PELs:Sulfuric acid: 1 mg/m3 TWA

Personal Protective EquipmentEyes:

Wear appropriate protective eyeglasses or chemical safety goggles as descibed by OSHA’s eye and faceprotection regulations in 29 CFR 1910.133. Provide an eye-wash fountain in the immediate work area. Do notwear contact lenses when working with chemicals.

Skin:Wear appropriate protective gloves to prevent skin exposure.

Clothing:Wear acid-protective clothing and gloves.

Respirators:50 mg/m3 – GMAGHiEP/HiEPF/SAF/SCBAF100 mg/m3 – SAF: PD, PP, CFEscape- GMAGHiEP/SCBA. Firefighting- SCBAF: PD, PP


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(Respirator Codes: (NIOSH) Publication No. 78-210)

Section 9 - Physical and Chemical PropertiesPhysical State: Liquid

Color: ColorlessOdor: Odorless

pH: AcidicVapor Pressure: No information found.Vapor Density: No information found.

Evaporation Rate: < etherViscosity: No information found.

Boiling Point: No information found.Freezing/Melting Point: No information found.

Decomposition Temperature: No information found.Solubility in water: Soluble

Specific Gravity/Density: 1.0 – 1.1Molecular Formula: No information found.

Molecular Weight: No information found.

Section 10 - Stability and Reactivity

Chemical Stability:Stable under normal temperatures and pressures.

Conditions to Avoid:Excess heat, combustible materials, organic materials, oxidizers, amines, bases.

Incompatibilities with Other Materials:Explosive or violent reactions with acetone cyanohydrin, acetone and nitric acid or potassiumdichromate, acrylonitrile, alcohols, hydrogen peroxide, allyl chloride, bromates and metals, brominepentafluoride, carbides, all chlorates, chlorine trifluoride, cuprous nitride, ethylene cyanohydrin,fulminates, indane and nitric acid, iron, mercuric nitride, nitric acid and glycerides, p-nitrotoluene,penta-silver trihydroxydiaminophosphate, perchlorates, phosphorus isocyanate picrates, silverpermanganate, sodium, sodium carbonate, toluene and nitric acid. Dangerous temperatures andpressures occur with other substances, especially organic combinations. Explosive hydrogen gas isevolved from contact with steel, other metals.

Hazardous Decomposition Products:Oxides of sulfur, hydrogen gas, hydrogen sulfide gas, carbon monoxide, carbon dioxide.

Hazardous Polymerization:Has not been reported.

Section 11 - Toxicological Information

RTECS:CAS# 25155-30-0: DB6825000.CAS# 7664-93-9: WS5600000.CAS# 7732-18-5: ZC0110000.


- 5 -

LD50/LC50:CAS# 25155-30-0: Oral:Rat – 438mg/kg – Remarks: gastrointestinal: Hypermotility, diarrhea.

Behavioral:Somnolence (general depressed activity). Sense organs and special senses ( Nose,Eye, Ear, and Taste):Eye:Lacrimatior.Oral:Mouse – 1330mg/kg – Remark:Convulsions or effect or seizure threshold. Peripheral nerveand sensation:Spastic paralysis with or without sensory change. Gastrointestinal:Hypermotility,diarrhea.Intravenous:Mouse – 105mg/kg

CAS# 7664-93-9: Inhalation, Mouse:LC50=320 mg/m3 /2HInhalation, rat:LC50=510 mg/m3 /2HOral, rat:LD50=2140mg/kg

CAS# 7732-18-5:Oral, rat:LD50=>90ml/kg

Carcinogenicity:CAS# 25155-30-0: Not availableCalifornia:CAS# 7664-93-9: ACGIH-A2 Suspected Human Carcinogen (contained in strong inorganic acid

mists)CAS# 7732-18-5: Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP, OSHA, or CA

prop.65California: Not listed.

NIOSH: Not listed.NTP: Not listed.OSHA: Select carcinogen.IARC: Group 1 carcinogen.

Epidemiology: No information available

Teratogenicity:No information available

Reproductive:No information available

Mutagenicity:No information available

Neurotoxicity:No information available

Section 12 - Ecological Information

No information found.

Section 13 - Disposal Considerations

Dispose of in accordance with Federal, State, and local regulations.

Section 14 - Transport Information

US DOTShipping Name: Not regulated.


- 6 -

Hazard Class: UN Number:Packing Group:

Section 15 - Regulatory Information

US Federal

TSCA:CAS# 25155-30-0: is listed on the TSCA Inventory.CAS# 7664-93-9: is listed on the TSCA Inventory.CAS# 7732-18-5: is listed on the TSCA Inventory.

SARA Reportable Quantities (RQ):CAS# 7664-93-9: Final RQ=1000Pounds (454kg).

CERCLA/SARA Section 313:This material contains Suifuric acid (Cas# 7664-93-9-<1%), which is subject to the reportingrequirements of section 313 of SARA Title III and 40 CFR part 373.

OSHA - Highly Hazardous:None of the components are on this list.

US StateState Right to Know:

Sulfuric acid can be found on the following state lists: California, New Jersey, Florida,Pennsylvania, Minnesota, and Massachusetts.Sodium dodecylbenzene sulfonate can be found on the following state lists: Delaware,Massachusetts, New York, and Pennsylvania.

California Regulations:

European/International RegulationsCanadian DSL/NDSL:

CAS# 25155-30-0: is listed on Canada’s DSL List.CAS# 7664-93-9: is listed on Canada’s DSL List.CAS# 7732-18-5: is listed on Canada’s DSL List.

Canada Ingredient Disclosure List:CAS# 25155-30-0: is listed on Canada’s Ingredient Disclosure List.CAS# 7664-93-9: is listed on Canada’s Ingredient Disclosure List.CAS# 7732-18-5: is not listed on Canada’s Ingredient Disclosure List.

Section 16 - Other Information

MSDS Creation Date: June 5, 2006.Revision Date: June 5, 2006.

Information in this MSDS is from available published sources and is believed to be accurate. No warranty, express or implied,is made and LabChem Inc. assumes no liability resulting from the use of this MSDS. The user must determine suitability of thisinformation for his application.

P a g e | 1

Material Safety Data Sheet

Linear Alkyl Benzene

1. Chemical Product and Company Information :

Trade name: Linear Alkyl Benzene.

Synonyms: Benzene C10-C13 alkyl Derivatives / LAB

CAS Number : 67774-74-7

Manufacture : SEEF LIMITED QATAR

P.O.Box# 50077 - Mesaieed , Qatar

Tel.: +974-44223562 - Fax: +974-40139525

www.seef.com.qa 2. Hazard Identification:

Health Hazard:

NFPA Rating: 1 HMIS Rating: 1

Flammability Hazard:


Reactivity Hazard:


Environmental Hazard:

Not applicable.

3. First Aid:

Eye: Flush eyes with water for at least 15 minutes.

Skin: Wash the skin with soap and water, If irritation persists get medical

attention.

Inhalation: Remove to fresh air and train people give CPR, get Medical attention

if required.

Ingestion: Do not induce vomiting, Get Medical attention.

4. Fire fighting measures:

Extinguishing Media: CO2, dry Chemical powder and foam.

Fire Data: Flash point 130 oC

Combustible products: CO and CO2

5. Accidental release measures:

Person-related safety precautions Wear protective clothing and equipment.

Isolate hazard area. Evacuate all unauthorized personnel not participating in

rescue operations from the area. Avoid entry into danger area. Remove all

possible sources of ignition. Stop traffic and switch off the motors of the engines.

Do not smoke and do not handle with naked flame. Use explosion-proof lamps

and non-sparking tools. Avoid contact with the substance.

Precautions for protection of the environment: Prevent from further leaks of

substance. Dike flow of spilled material using soil or sandbags to minimize

http://www.seef.com.qa/

P a g e | 2

contamination of drains, surface and ground waters. If Linear Alkyl Benzene has

flowed into drains, ponds or sewage systems, inform appropriate authority.

Recommended methods for cleaning and disposal: Soak up residues with non-

combustible absorbent material (e.g. sand, earth, vermiculite) and forward for

disposal in closed containers. Dispose off under valid legal waste regulations.

6. Handling and storage:

Handling in accordance with good hygiene and safety procedures, since

empty containers contain residue, follow all hazard warning and

precautions.

Store in a cool, dry and well ventilated area. Store separately from

combustible, organic and oxidizable materials.

7. Exposure control:

Personal protective equipment (PPE) for the protection of eyes, hands and skin

corresponding with the performed labor has to be kept at disposition for the

employees. All PPE have to be kept in disposable state and the damaged or

contaminated equipment has to be replaced immediately.

Eye: Use chemical safety goggles.

Skin: Wear impervious protective clothing, including boots, gloves and coveralls.

Respiratory protection: If the exposure limit is exceeded and engineering controls are not

feasible, wear a supplied air, full-face piece respirator, airline hood, or full face piece

self-contained breathing apparatus.

Environmental exposure controls: Proceed in accordance with valid air and water

legislative regulations.

8. Physical and chemical properties:

Physical State: Liquid Appearance: Colorless

Odor: Odorless pH: Not Applicable

Boiling Range: 270 – 320 oC Flash Pint: 130

oC

Flammability: Not Available Explosive properties: Not Applicable

Oxidizing properties: Not Available Freezing Point: 4 oC

Vapor pressure mm Hg @ 20 oC: <0.1 Water Solubility: Negligible

Viscosity: 5- 10 cps @ 20 oC Vapor Density: 8.4

Specific Gravity: 0.86

9. Stability and reactivity:

Stable. Incompatible with strong oxidizers and No dangerous polymerization.

10. Disposal:

Waste can be incinerated under controlled conditions or land filled according to official

regulations.

This information contained herein has been compiled from sources considered by SEEF Limited to be

dependable and is accurate to the best of the company’s knowledge. The information relates to the specific

products designated herein, and doses not relate to use in combination with any other material of any other

process. SEEF Limited disclaims any liability for injury to the recipient or third persons or for any damage

to any property resulting on misuses of the controlled product.



Enclosure: 05

Chemical Name & Physical Form of Raw Materials with its storage facility

No. Name of Raw

Material

Chemical Name Physical

Form

Container

Type

MOC of

container

01 Linear Alkyl

benzene

Linear Alkyl benzene Liquid Tank MS

02 Sulphuric Acid Sulphuric Acid Liquid Tank MS

Tank details of LAB:


1 147 x 04 = 588 04 0.85 125 x 04 = 500

2 42 01 0.85 36

3 212 01 0.85 178

Total 842 06 0.85 714

Tank details of Sulphuric Acid - :


1 94 01 1.82 172

2 42 01 1.82 76

Total 136 02 1.63 248



Enclosure: 06

Details of Hazardous Chemicals

The Raw Materials, which are termed as Hazardous Chemicals as per the

"Manufacturing, Storage and Import of Hazardous Chemicals Rules, 1989", are as

listed in below Table

Hazardous Chemicals

Reference

The Manufacturer,

storage & Import of

Hazardous chemical Rules

1989

Threshold

Quantity in MT

Maximum

quantity that can

be stored at a

time (MT)

Sulphuric Acid Sr. No. 591, Part II, Sch 1 of

MSIHCR, 1989

---- 248



Enclosure: 07

Manufacturing Process

L.A.B is allowed to react with Sulphuric acid. The reaction leads to formation of Linear Alkyl Benzene

Sulphonic acid(LABSA/Acid Slurry). The reacted mass consists of LABSA & Un-reacted Sulphuric Acid. Lab

Sulphonic acid is the desired end product. To have LABSA of standard specification the un-reacted

Sulphuric Acid is to be removed from the mass. Un-reacted Sulphuric Acid is removed out in two stages:

Stage -1 Without Adding Water & Stage-2 by adding water . In Stage 1 – about 60% of unreacted

Sulphuric Acid is taken out in S 0 ( as shown in Process Flow Chart) is separated out which does not

require any cooling. .The balance unreacted Sulphuric Acid is removed out by adding water in Dilution

Vessel and subsequently separated out in stage 2 separation (as show in Process FLOW Chart Separators

S1 to S3).

By incorporating 2 stages of separation there is a saving of 50% of water in cooling.

Lab Sulphonic Acid is the economical name Linear Alkyl Benzene Sulphonic Acid [LABSA] which is produced by sulphonating Linear Alkyl Benzene with Sulphuric Acid. The equipment used is MS/SS Reactor Vessels. The required amount of LAB is transferred into the reactor vessel and Sulphuric Acid is added gradually. The mixture is continuously stirred to ensure complete mixing and completion of reaction between LAB & Sulphuric Acid after digestion. Since the reaction is exothermic, temperature is controlled by circulating water in jackets of the Sulphonator.The mixture now contains LAB Sulphonate [ LABS] and Spent Sulphuric Acid. To facilitate the separation of LABS and Spent Acid. Required quantity of Cold water is added to the total mass gradually controlling the temperature. The mixture is then stirred till completion and then transferred to the separator vessel and allowed to settle. The Spent Acid forms the bottom layer due to higher density and is transferred to intermediate tank and then to suitable storage tank. LSA forms the upper layer and is also transferred intermediate tank and later to suitable storage tanks.



Chemical Reaction

O O O II II II

H – O – S – O – H+ + -( CH2)11-CH3 + H2O H-O-S- -CH2)11--CH3 + H–O–S–O–H II II II

O O O (SULPHURIC ACID) + ( LINEAR ALKYL BENZENE) (LINEAR ALKYL BENZENE + (SPENT SULPHURIC ) (CONC) SULPHONIC ACID ) (DILUTE)

O O



Process Flow Diagram:

Laxmi Agro Industrial Consultants & Exporters Ltd.S. NO. 153/3, AT – Padana

Email – [email protected]

L.A.B.

( 0.680MT)

LINEAR ALKYL BENZENE

SULPHONIC ACID

( 1.000 MT)

Laxmi Agro Industrial Consultants & Exporters Ltd.Padana, TA– Gandhidham, Dist - Kutch -370240, GUJARAT

[email protected], (M) 098100-25410

Mass Balance:

SULPHUIRIC ACID H20 (WATER)

(1.057 MT)

(0.120MT)

SULPHONATION REACTOR

(1.857 MT)

SEPERATOR

(1.857 MT)

LINEAR ALKYL BENZENE

SULPHONIC ACID

SPENT SULHURIC

ACID

( 0.857MT)

Laxmi Agro Industrial Consultants & Exporters Ltd. , GUJARAT

H20 (WATER)



Enclosure: 08

Details of Water Consumption & Wastewater generation.

Water Consumption in

Liter /Day

Wastewater Generation in

Liter /Day

Existing Proposed Total

After

Expansion

Existing Proposed Total

After

Expansion

Domestic 1000 0 1000 Domestic 500 0 500

Industrial Industrial

Process 7000 7000 14000 Process 0 0 0

Cooling 7000 0 7000 Cooling 0 0 0

Gardening 0 1000 1000 Gardening

Other 500 0 500 Other 0 0 0

Total 15500 8000 23500 Total 0 0 0

• Domestic effluent @ 500 Liter /day will be disposed to Existing Soak Pit / Septic

Tank system.

• There will no industrial effluent generation from manufacturing process or other

activity.



Enclosure: 09

Details of Flue Gas Emission & process Gas Emission with APC system

Type of Flue Gas Emission:-

Stack No Stack

Attached To

Stack Height

(meter)

Parameter Permissible Limit

1 D.G. Set -1

62.5 KVA

(Existing)

5 SO2

100 ppm

2 D.G. Set -2

125 KVA

(Proposed )

5 SO2

100 ppm

Type of Process Gas Emission:-

There is no process emission from Existing as well as proposed manufacturing activity.

Fuel Details:

Sr. no. Fuel used Fuel Consumption

1 Diesel in DG Set 1

(Stand By)

12 Liter /Hr

2 Diesel in DG Set 2 15 Liter /Hr



Enclosure: 10

Details of Hazardous Waste generation with its Management

DETAILS OF HAZARDOUS WASTES

Sr. No. Type of Waste with

Category No.

Quantity

Existing Proposed Total After

Expansion

1. Used Oil

(Cat. No.5.1)

0.012

MT/Yr

0.012

MT/Yr

0.024

MT/Yr



MANAGEMENT OF HAZARDOUS WASTES

Sr.

No.

Type of

Waste

Source of

Generation

Collection Treatment Storage Disposal

1. Used /Spent

Oil

Lubrication of

plant

machineries

H.D.P.E.

Carboys

---

S.W.S.A.

Use for lubrication

of plant

machineries or Sell

to the registered

recycler



Enclosure: 11

Land Supporting Document



Enclosure: 12

Existing Consent Order



Enclosure: 13

Layout Plan



Enclosure: 14

Name and Address of Directors

Sr. No. Name of Director Address

1. Vidhula Gupta Rahul Apartment,24/24 Ansari Road,

Daryaganj, New Delhi - 110002

2. Gigi Gupta Rahul Apartment,24/24 Ansari Road,


3. Shushilkumar Gupta Rahul Apartment,24/24 Ansari Road,


4. N.K.Bagla 8 –A, Ansal garden Enclave, Hapur

Road, Ghaziabad.

5. Shiv Gupta Rahul Apartment,24/24 Ansari Road,


6. Lila Dhar Chopra W-10, Sector 12, Noida, Gautambudh

Nagar.

7. Vijaykumar Walia MS-3/602, Kendriya Vihar, Sector 56,

Gurgaon.

8. Lalitkumar Sharma 2167, 3rd

sector –D, Pocket -2, Vasant

Kunj, New Delhi.



Enclosure: 15

CA Certficate



Enclosure: 16

DIC Certficate



Enclosure: 17

Water permission

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