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    Lecture XXIII 67

    Lecture XXIII: Field Theory of Superconductivity

    Following our discussion of the field theory of BEC and superfluidity in the weakly

    interacting Bose gas, we turn now to condensation phenomena in Fermi systems

    Starting point is BCS Hamiltonian for local pairing interaction: g V

    Ld

    H =

    ddr

    c(r)p2

    2mc(r) g c(r)c(r)c(r)c(r)

    Quantum partition function: Z= tr e(HN)

    Z=()=(0)

    D(, )exp

    x(,r)Rdx

    0

    d ddr

    [G(p)0 ]

    1 +

    p2

    2m

    g

    where (r, ) denote Grassmann (anticommuting) fields

    Analysis of interacting QFT?

    Perturbative expansion in g?Transition to condensate non-perturbative in g

    Mean-field analysis:condensation of pair wavefunction signalled by anomalous average cc

    Hubbard-Stratonovich decoupling: introducing complex commuting field (r, )

    egRdx =

    D(, ) exp

    dx

    1g

    (+g)(+g)g 1g|(r, )|2 + ( + )

    Z=

    D(, )

    D(, )e

    Rdx

    ||2

    g exp

    dx

    Nambu spinor ( )

    Gorkov Ham. G1 [G

    (p)0 ]

    1

    [G(h)0 ]

    1

    free particle/hole Hamiltonian: [G

    (p/h)0 ]

    1 = +/(

    p2

    2m

    )

    N.B. dx = dx () = dx Using Gaussian field integral:

    D(, ) exp[ A] = det A = exp[ln det A]

    Z=

    D(, ) exp

    dx1

    g||2 + ln det G1[]

    i.e. Zexpressed as functional field integral over single complex scalar field (x)

    To proceed, we must invoke some approximation:

    Lecture Notes October 2005

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    Lecture XXIII 68

    Mean-field theory: far below transition (T Tc, c) fluctuations small saddle-point approximation in constant Gap equation

    Ginzburg-Landau theory: since transition is continuous, close to Tc,we may develop perturbative expansion in (small)

    Noting : G1 = G10

    1 + G0

    0 0

    , G0 G( = 0)

    ln det G1 = trln G1 = trln G10 1

    2tr

    G0

    0 0

    2+

    N.B. ln(1 + z) = n=1(z)n/n

    Zeroth order term free particle contribution, viz.

    Z0 = det

    G10

    Using id. =

    kk,n

    |kk|, k = 1Ld

    dx

    einikreikx (x)

    Second order term

    tr G(p)0 G

    (h)0 =

    kk

    G(p)0 (k)

    kk/

    Ld k||k G(h)0 (k)k||k

    q=kk=

    q

    qq

    pairing susceptibility (q) 1

    Ld

    k

    G(p)0 (k)G

    (h)0 (k + q)

    Combined with bare term, one obtains

    Z=

    D[, ]eS[,], S =n,q

    1

    g+ (n, q)

    |n,q|2 + O(4)

    In principle, one can evaluate (q, n) explicitly;however we can proceed more simply by considering...

    Gradient expansion: (q, n) = (0, 0) +q2

    22|q|(0, 0) + O(in, q

    4)

    Ginzburg-Landau theory

    S[] =

    ddr

    t

    2||2 + K

    2||2 + u||4 +

    t2

    = 1g

    + (0, 0), K = 2|q|(0, 0) > 0 and u > 0

    Lecture Notes October 2005

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    Lecture XXIII 69

    Note structural similarity to weakly interacting Bose gas

    Landau Theory: If we assume that dominant contribution to Z= eF arises fromminumum action, i.e. spatially homogeneous that minimises

    S[]Ld = t2 ||2 + u||4

    i.e. || t + 4u||2 = 0, || = 0 t > 0t/4u t < 0i.e. for t < 0, spontaneous breaking of continuous U(1) symmetry associated

    with phase gapless fluctuations Goldstone modes

    Transition Temperature: Using identity 1Ld

    k =

    ddk

    (2)d=

    ()d

    (0, 0) = 1Ld

    n,k

    12n + (k

    2/2m )2 1

    n

    d(+ )2n +

    2 ()

    n

    1|n|

    Introducing energy cut-off at Debye frequency D = (2nmax + 1)/

    (0, 0) ()nmax

    n=nmax

    1

    2n + 1 2()

    nmax0

    dn

    2n + 1 () ln

    D

    Transition when t/2 1/g + (0, 0) = 0, i.e. kBT < kBTc = D exp 1

    ()g

    Near Tct

    2=

    g

    2 () ln

    D

    = 0 (g () ln

    cD

    )

    = ()ln(T /Tc) = () ln(1 + (T Tc)/Tc) ()

    T TcTc

    i.e. physically t is reduced temperature

    Lecture Notes October 2005