LETTER RE: SURFACE WATER, FLOW AND WATER LEVEL … · 2020. 11. 28. · ©CBS 20 STANWIX STREET, 10TH FLOOR PITTSBURGH, PENNSYLVANIA 15222 March 18, 2011 To: DISTRIBUTION Dorothy

©CBS20 STANWIX STREET, 10TH FLOORPITTSBURGH, PENNSYLVANIA 15222

March 18, 2011

To: DISTRIBUTION

Dorothy M. AlkeVice President, Environmental Projects

412.642.2562 Telephone412.642.3014 Fax

dottie.alke @ cbs.com

Re; Surface Water, Flow and Water Level MonitoringSecond Quarter 2010Neal’s Landfill, Bloomington, Monroe County, Indiana

1.0 BACKGROUND

This report summarizes the results of surface water, flow and water level monitoring workcompleted by CBS Corporation during the second quarter of 2010 at the Neal’s Landfill site.

Surface water monitoring was performed at a total of three locations (springs and streams) inaccordance with the April 2002 Long Term Groundwater Monitoring Plan (LTGMP) for this site.The LTGMP was modified by agreement with the CD parties in December 2009. The modificationdiscontinues storm sampling as well as semi-annual sampling at Taylor and Branam Springs untilthe next revision of the LTGMP. Continuous monitoring of flow and water levels was alsoperformed at two locations.

2.0 SURFACE WATER MONITORING

The monitoring work described in this report was performed on March 31, April 21 and May 25,2010. The March-May time period constituted the second reporting quarter for Neal’s Landfill for2010.

Scope of Work

The scope of water sampling for this monitoring period comprised monthly sampling at SouthSpring and North Spring, as stipulated in the modified LTGMP and summarized in Table 1. SinceDecember 2004, surface water samples also have been collected from a small pool in Conard’sBranch near Vernal Pike. The approximate locations of these stations are shown on Figure 1,Monitoring and Sampling Locations.

March 18, 2011Page 2

Sample Collection and Handling

Samples at the spring and stream locations were collected by carefully filling a new disposablebeaker. The water was transferred from the beaker into pre-cleaned amber glass l-liter bottlessupplied by the analytical laboratory. Routine sampling parameters including temperature andconductivity were measured and recorded.

Samples were analyzed by Heritage Lab of Indianapolis, Indiana. All the samples except theConard’s Branch Pool samples were analyzed to a detection limit of 0.1 parts per billion (ppb) forall PCB parameters (except Aroclor 1221, detection limit 0.2 ppb) by EPA SW-846 method 8082.The Conard’s Branch Pool samples were analyzed to a detection limit of 0.01 ppb for all PCBparameters (except Aroclor 1221, detection limit 0.02 ppb). Samples were also analyzed for totalsuspended solids (TSS) by EPA method 160.2.

Quality Assurance

For quality assurance purposes a duplicate sample and a field blank were collected during eachsampling event. All environmental and blank samples were labeled and logged onto a chain ofcustody form. The samples were stored and transported on ice in insulated coolers. Custody of thewater samples was maintained by CBS until shipment to the analytical laboratory.

Field blank samples for these sampling events were NL5756, NL5761 and NL5766. No PCBs weredetected in any of these samples.

Analytical Results for Surface Water Samples

Field parameter measurements, PCB analytical results, and QA/QC results for samples collectedfrom South Spring and North Spring during this reporting period are reported in Tables 2 and 3.Historical groundwater monitoring data collected since the completion of the remedy in November1999 for these two sampling stations are also reported in Tables 2 and 3. Results of water samplingat the Conard’s Branch Pool station since December 2004 are reported in Table 4. Copies of thechain of custody forms are provided in Appendix A. Copies of the certificates of analysis areprovided in Appendix B. A validation summary for these samples appears in Appendix C. Copiesof the field sampling data sheets are on file at PSARA Technologies, Inc.’s Bloomington BranchOffice.

3.0 CONTINUOUS FLOW AND WATER LEVEL MONITORING

The purpose of flow and water level monitoring is to evaluate site-specific data characterizing sitehydrologic response under storm and non-storm conditions, and to evaluate correlations betweenPCB concentrations, spring flow and groundwater elevations.


Scope of Work

The scope of groundwater level and flow monitoring during this reporting period involved the useof dedicated instrumentation to record water level and other parameters as summarized in Table 5.Water lever transducers and data logging equipment and piezometer crest gauges were operatedduring all or part of the period from March through May 2010. The approximate locations of thestations in which these instruments were used are shown on Figure 1, Monitoring and SamplingLocations.

Flow and Water Level Plots

The following plots of the monitored stations for this reporting period are attached:

Flow data and monthly cumulative rainfall at Conard’s Branch weirater elevation at MW EPA-5A

The plots are annotated with dates of instrument installation or removal and other field activities ofinterest.

Quality Assurance

As a quality assurance check in documenting rain events and changes in flow and groundwaterlevel, rainfall records were obtained from the Neal’s Landfill recording rain gage and, if necessary,from those at Monroe County Airport, Indiana University, the PSARA Bloomington office and theIllinois Central Spring Treatment Facility. Rain events of approximately 0.25 inches or more areindicated on the flow and water level plots.

As a further data quality check, manual water level measurements were made after significant stormevents. The purpose of the manual checks was to verify instrument readings. Manual field checkdata collected during this reporting quarter are shown on the data plots.

An instrument maintenance log for all of the Neal’s Landfill installations is provided inAppendix D. This log details the installation, re-indexing, and maintenance history of thetransducers and data loggers present at Neal’s Landfill during the reporting quarter.

Crest Gauges

The purpose of these gauges is to provide an indication of maximum water level in the piezometersthat do not contain level logging transducers. Crest gauge measurements appear in Table 6.Piezometer-01 has neither a transducer nor a crest gauge, but the water level at this station ismeasured manually. Those observations appear in Table 7.


Potentiometric Data

On May 28, 2010, water levels were measured by hand at eleven monitor wells at the site plus threeadditional monitoring points. The added water level monitoring points are two boreholes in thesoutheast area of the site, BH-A2 and BH-B2, and a standpipe installed in the buried SW SeepSinkhole. The specific measurement locations are listed in the table insert on Figure 1, which alsodepicts the resulting potentiometric surface across the site on this date.

Scope of Non-Routine Activities

Pumping operations at the Conard’s Branch Pump (CBP) station continued during the secondreporting quarter of 2010. The system operated in automatic mode throughout the quarter.Maintenance of the system during this quarter involved the removal of storm debris and thecleaning of accumulated sediment and algae from the intake screens as needed. Operation duringthe third reporting quarter for 2010 is expected to be in automatic mode.

If you have questions regarding the sampling and flow/water level monitoring activities or findingsfor this reporting quarter, please call Mike McCann at (812) 335-0424.

S inc~j~ly,

Dorothy M. Alke

BP: 11-0020

Attachments

DISTRIBUTIONTom Alcamo, USEPA Region 5Jessica Fliss, IDEMDennis Williamson, Monroe County Health Department

CC~

John Langley, CBUJeff Lifka, Tetra Tech EM, Inc.John Bassett, AECOMMike McCann, CBSRuss Cepko, CBSMike Hessling, PSARAPatrick Kneip, PSARABP Files

TABLES

Table 1. Groundwater and Surface Water Monitoring RequirementsDuring the Monitoring Period

CBS CorporationNeal’s Landfill, Bloomington, Monroe County, Indiana

Monitoring StationLTGWMP Other Requirements/

Parameter a Frequency Comment

South Spring PCB, SS, C Monthly Qualitative or quantitativeflow estimate, if possible

North Spring PCB, SS, C Monthly Qualitative or quantitativeflow estimate, if possible

Spring Treatment Facility PCB Semimonthly Influent, Effluent andMid Carbon LocationsSampled

aparameters to be monitored: PCB=polychlorinated biphenyl; SS=total suspended solids; W=water level;C=conductivity; F=flow.

Table 3. Post-Remediation PCB ResultsNorth Spring

Neal’s Landfill, Bloomington, Indiana

Sample ID

NL5765

NL5760

NL5755

NL5750

NL5745

NL5740

NL5735

NL5730

NL5725

NL5720

NL5715

NL5708

NL5703

NL5698

NL5693

NL5688

NL5683

NL5678

NL5671

NL5666

NL5658

NL5653

NL5646

NL5641

NL5636

NL5631

NL5626

NL5621

NL5616

NL5609

NL5605

NL5607c

NL5600

NL5595

NL5590

NL5584

continued

SamplingDate

5125110

4/21/10

3/31/10

2/11/10

1/19/10

12/17/09

11/10/09

10/22/09

9/30/09

8/10/09

7/9/09

6/21/09

5/19/09

4/27/09

4/9/09

2/17/09

1/23/09

12/15/08

11/19/08

10/15/08

9/11/08

8/12/08

7/17/08

6/18/08

5/28/08

4/9/08

3/12/08

2/28/08

1/15/08

12/19/07

11/20/07

11/20/07

10/12/07

9/20/07

8/22/07

7/10/07

PCBa,

ppb

0.13 J

0.34

0.12 J

0.22 K

0.37

0.19J

0.42 K

0.52

0.72

0.41

0.32

0.31

0.18J

0.27

0.14J

0.41

0.76

1.0

1.1

0.98

0.75

0.71

0.51

0.37

0.48

0.17J

0.30

0.35

0.66

0.80

1.7

1.6

1.2

1.3

1.1

0.55

DataValidated?

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

TSS,mg/L

1

2

1

1

1

2

1

<1

4

<1

1

1

<1

2

<1

<1

4

<1

4

1

<1

2

3

1

2

<1

1

1

1

1

3

<1

6

2

2

5

Conductivity,uS/cm

426

444

400

453

471

432

498

513

628

498

462

452

391

399

393

408

527

586

617

629

608

567

551

506

446

383

410

432

50O

5O7

654

654

645

637

612

519

Temperature,deg C

12.2

11.4

11.2

10.7

10.8

11.7

12.8

13.4

14.3

13.8

13.6

12.6

11.7

11.3

11.0

10.5

10.3

11.4

12.7

14.2

14.4

13.9

13.1

12.1

11.6

11.0

10.7

10.7

11.2

11.5

13.3

13.3

14.5

14.6

14.4

13.5

Flowb,

gal/min

50

40

120

20

40

60

20

18

10

30

25

30

50

30

60

50

15

40

20

15

20

20

30

150

40

50

50

100

40

40

10

10

10

12

12

15



Sample ID

NL5579

NL5572

NL5567

NL5562

NL5557

NL5551

NL5527

NL5522

NL5433

NL5428

NL5423

NL5418

NL5406

NL5395

NL5390

NL5385

NL5380

NL5375

NL5370

NL5363

NL5357

NL5252

NL5233

NL5219

NL5214

NL5207

NL5196

NL5191

NL5179

NL5174

NL5154

NL4812

NL4808

NL4580

NL4572

NL4571

continued

SamplingDate

6/13/07

5/14/07

4/9/07

3/13/07

2/23/07

1/11/07

12/15/06

11/27/06

10/10/06

9/27/06

9/8/06

8/22/06

7/18/06

6/14/06

5/22/06

4/5/06

3/6/06

2/8/06

1/16/06

12/6/05

11/18/05

10/30/05

9/30/05

8/3/05

7/21/05

6/7/05

5/3/05

4/11/05

3/8/05

2/11/05

1 / 19/05

12/16/04

11/17/04

10/6/04

9/9/04

816104

PCBa,

ppb

0.66

0.40

0.17J

0.28

<0.10

0.20

0.15J

0.40

1.0

0.81

1.1

0.55

0.45

0.51

0.27

0.12J

0.40 K

0.27

0.17J

0.74

0.68

0.83

0.78

0.78

0.92

0.46 J

0.24

0.26

0.41

0.32

0.16J

0.45

0.82

1.4

0.88

0.56

DataValidated?

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

TSS,mg/L

11

<1

<1

3

<1

1

<1

4

5

3

2

5

7

2

2

<1

2

1

<1

3

<1

3

4

<1

<1

3

<1

<1

<1

<1

<1

4

2

4

<1

3

Conductivity,uS/cm

527

481

404

425

336

403

394

499

566

555

558

533

545

512

446

371

471

471

398

508

477

565

540

525

527

476

412

395

432

402

411

479

513

591

600

530

Temperature,deg C

12.6

11.8

11.0

10.8

10.7

11.4

11.7

12.2

14.0

14.1

14.5

14.5

13.5

12.4

11.7

11.3

10.9

10.1

11.4

12.1

12.9

13.8

14.4

14.4

13.9

12.4

11.6

11.4

10.8

10.9

11.2

11.8

12.8

14.1

14.2

13.8

Flowb,

gal/min

20

60

120

75

225

150

120

50

30

20

10

12

15

40

60

70

35

60

120

90

30

10

40

25

15

50

60

80

80

70

120

30

35

15

15

15



Sample ID

NL4556

NL4518

NL4500

NL4356

NL4347

NL4335

NL4223

NL4219

NL4215

NL4211

NL4207

NL4203

NL 1995

NL1985

NL1914

NL1910

NL 1906

NL 1902

NL1898

NL1888

NL1874

NL1870

NL1866

NL1861

NL1847

NL 1774

NL 1766

NL1760

NL 1702

NL 1696

NL1688

NL1683

NL 1633

NL1623

NL1617

NL1609

continued

SamplingDate

7/16/04

5/5/04

4/19/04

3/9/04

2/13/04

1/14/04

12/8/o3

11/5/03

1 o/8/03

9/9/03

8/5/03

7/9/03

6/2/03

5/14/03

4/10/03

3/17/03

2/7/o3

1/10/03

12/3/o2

11/12/02

10/lO/O2

9/4/02

8/8/02

7/17/02

6/11/02

5/21/02

4/11/02

3/14/02

2/13/02

1/22/02

1/3/02

11/15/01

10/19/01

9/14/01

8/16/01

7/27/01

PCBa,

ppb

0.43

0.26

0.35

0.2

0.34

0.42

0.35

0.86

1.2

0.67

0.75

0.68

0.66

0.18J

0.36

0.24

0.63

0.58

1.3

0.82

1.6

1.1

1.2

0.71

0.54

0.3

0.2

0.22

0.42

0.39

0.56

0.78

0.57

1.1

0.79

0.89

DataValidated?

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

TSS,mg/L

6

<1

<1

<1

<1

3

<1

<1

<1

<1

<1

8

5

<1

2

2

<1

<1

<1

2

3

3

8

<1

2

2

<1

8

3

4

2

<1

6

<1

4

7

Conductivity,uS/cm

465

420

450

400

393

438

449

570

580

524

515

532

496

392

396

388

473

453

564

441

592

564

570

543

466

410

379

357

387

472

465

512

463

521

504

531

Temperature,deg C

13.2

11.3

11.2

10.8

10.7

11.2

11.9

13.0

13.7

14.0

13.3

13.1

11.9

11.4

11.0

10.7

10.3

11.2

12.1

13.1

14.7

14.8

14.5

13.8

12.4

11.7

11.3

11.1

11.0

10.9

11.1

12.7

13.1

14.3

14.8

13.7

Flow~,

gal/min

20

40

30

lOO

lOO

50

30

lO

lO

lO

20

15

15

70

50

40

15

20

lO

15

15

lO

15

50

40

60

40

80

40

15

20

15

25

15

lO

20



Sample ID

NL1601

NL1536

NL1528

NL 1522

NL1514

NL1399

NL1393

NL1333

NL1259

NL1212

NL1112

NL 1098

NL1085

aSamples were anal’

SamplingDate

6/14/01

5/15/01

4/11/01

3/21/01

2/27/01

12/21/00

10/19/00

8/15/00

6/13/00

4/14/00

2/22/00

12/18/99

11/1/99

,zed

PCBa,

ppb

<0.1 R

1.1

0.63

0.31

0.23

0.33

0.36

1.5

1.6J

0.29

0.68

2.1

1.2

DataValidated?

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

TSS,mg/L

9

15

2

<1

2

NR

5

3

3

<1

4

10

2

Conductivity,uS/cm

432

517

398

435

377

419

473

623

521

409

491

599

4O0

Temperature,deg C

12.7

12.5

11.2

10.8

10.9

11.4

13.0

14.7

13.0

11.4

10.5

12.1

14.1

Flow~,

gal/min

12

12

60

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

to a detection limit of 0.1 ppb for all PCB parameters except Aroclor 1221 (detection limit 0.2 ppbor 0.5 ppb). Other detection limits may occasionally result from non-normal sample volumes, dilutions, etc.

bF1ow estimated visually.~Duplicate sample.NA = Not applicable.NR = Not reported. ’J = Estimated value. The QA/QC data indicated an analytical bias.K = Estimated value due to QA blank contaminationR=Unusable data. QA/QC data indicated significant deficiencies in the analytical data.

Table 4. Post-remediation PCB ResultsConard’s Branch Pool by Vernal PikeNeal’s Landfill, Bloomington, Indiana

Sample ID

NL5764

NL5759

NL5754

NL5749

NL5744

NL5739

NL5734

NL5729

NL5724

NL5719

NL5714

NL5707

NL5702

NL5697

NL5692

NL5687

NL5682

NL5677

NL5670

NL5665

NL5657

NL5652

NL5645

NL5640

NL5635

NL5630

NL5625

NL5620

NL5615

NL5608

NL5604

NL5599

NL5594

NL5589

NL5583

NL5578

NL5571

NL5566

NL5561

continued

Sampling PCBa, Data TSS, Conductivity,Date ppb Validated? mg/L uS/cm

5/25110 0.089 Y 13 445

4/21/10 0.076 Y 4 483

3/31/10 0.10 Y 7 423

2/11/10 0.090 K Y 7 527

1/19/10 0.048 Y 2 519

12/17/09 0.11 ¥ 4 448

11/10/09 0.086 K Y 6 493

10/22/09 0.056 Y 2 519

9/30/09 0.046 Y 5 583

8/10/09 0.10 Y 4 487

7/9/09 0.11 Y 3 471

6/21/09 0.11 Y 9 501

5/19/09 0.14 Y 6 401

4/27/09 0.073 Y 3 424

4/9/09 0.11 Y 8 413

2/17/09 0.14 Y 7 428

1/23/09 0.077 Y 4 500

12/15/08 0.05 Y 3 537

11/19/08 0.023 Y 2 612

10/15/08 0.09 Y 1 609

9/11/08 0.076 Y 3 548

8/12/08 0.084 Y 4 548

7/17/08 0.11 Y 5 501

6/18/08 0.13 Y 4 438

5/28/08 0.11 Y 3 451

4/9/08 0.12 Y 3 420

3/12/08 0.075 Y 2 501

2/28/08 0.16 J Y 4 546

1/15/08 0.096 Y 3 521

12/19/07 0.055 Y 2 672

11/20/07 0.04 Y 2 612

10/12/07 0.051 Y 3 614

9/20/07 0.068 Y 2 539

8/22/07 0.068 Y 7 564

7/10/07 0.10 Y 17 430

6/13/07 0.077 Y 6 519

5/14/07 0.093 Y < 1 447

4/9/07 0.076 Y 4 443

3/13/07 0.087 Y 3 417

Temperature,deg C

18.4

10.6

11.6

9.1

6.4

9.2

14.7

14.5

15.7

22.7

18.5

18.8

15,8

18.2

11.6

9.9

5.3

4.7

5.1

18.9

19.7

17.7

17.9

15.6

14.4

16.8

8.5

8.4

4.1

6.7

12.4

13.1

24

24.0

27.7

19.5

22.7

12.0

17.1

gal/min

250

125

500

220

90

450

100

70

25

90

150

200

500

200

600

400

80

100

30

12

25

60

150

200

180

480

500

45O

180

160

14

10

12

25

40

50

180

280

150

Table 4. Post-remediation PCB ResultsConard’s Branch Pool by Vernal PikeNeal’s Landfill, Bloomington, Indiana

Sample ID

NL5556

NL5550

NL5526

NL5521

NL5432

NL5427

NL5422

NL5417

NL5405

NL5394

NL5389

NL5384

NL5379

NL5374

NL5369

NL5362

NL5361

NL5356

NL5251b

NL523~

NL5224

NL5223

NL5218

NL521~

NL520~

NL5200

NLS19~

NL519~

NLS18~

NL517~

NL4816

Sampling PCBa, Data TSS, Conductivity,Date ppb Validated? mg/L uS/cm

2/23/07 0.11 Y 6 403

1/I 1/07 0.10 Y 1 445

12/15/06 0.13 Y 7 446

11/27/06 0.097 Y 6 510

10/10/06 0.094 K Y 3 563

9/27/06 0.11 Y 6 559

9/8/06 0.14 K Y 6 526

8/22/06 0.070 Y 9 503

7/18/06 0.081 Y 8 547

6/14/06 0.074 Y 2 516

5/22/06 0.079 Y 4 468

4/5/06 0.10 K Y 8 418

3/6/06 0.087 K Y 1 486

2/8/06 0.15 J Y 4 471

1/16/06 0.33 Y 15 459

12/6/05 0.071 J Y 11 532

12/1/05 0.071 Y 5 506

11/18/05 0.16 J Y 8 493

10/30/05 <0.10 Y 3 554

9/30/05 0.16 J Y 5 545

8/17/05 0.083 Y < 1 525

8/10/05 0.11 J Y 5 535

8/3/05 < 0.01 Y 3 525

7/21/05 0.17 J Y 3 493

6/7/05 < 0.10 Y 4 472

5/4/05 0.037 Y < 1 467

5/3/05 < 0.10 Y < 1 454

4/11/05 0.12 J Y 2 433

3/10/05 <0.10 Y 4 480

3/8/05 0.11 J Y 4 472

12/16/04 0.12 Y 13 513

Temperature,deg C

8.0

lO.8

10.3

12.8

14.2

14.0

16.7

23.0

21.5

16.8

13.7

14.8

7.9

10.1

11.8

3.4

7.7

10.7

11.7

17.7

24.5

21.6

25.1

22.7

20.1

12.6

12.8

17.9

7.2

8.7

8.3

Flowc,

gal/min

4O0

700

350

150

50

120

45

40

40

100

400

60O

150

415a

400

90

200

350

40

80

60

40

30

50

70

245d

150

120

180

180

150

aSamples were analyzed to a detection limit of 0.01 ppb for all PCB parameters except Aroclor 1221 (detection limitof 0.02 ppb).

bAnalyzed at a detection limit of 0.1 ppb.CFlow estimated visually.dFlow calculated from readings obtained with a manual flow velocity meter.J = Estimated value. The QA/QC data indicated an analytical bias.K = Estimated value due to QA blank contamination

Table 5.Continuous Flow and Water Level MonitoringNeal’s Landfill

Monroe County, Indiana

Monitoring Station Parameter Reported Monitoring Period Instrument

Conard’s Branch Weir Water level / flow All Quarter

NL Rain Gauge Rainfall All Quarter

MW EPA-5A Water level All Quarter

In-Situ LeveITroll

EZ-Logger/tippingbucket rain gauge

In-Situ Mini-Troll

PZ-02, -03, -04, -05 Water level All Quarter Crest gauge

Date2/11/2010

10/22/2009

8/25/2009

5/31/2009

2/18/2009

11/13/200810/22/2008

9/10/2008

8/1/2008

7/18/20086/25/2008

6/6/2008

5/20/2008

4/30/2008

4/9/2008

2/13/20088/27/2007

8/3/2007

7/5/2007

6/25/2007

6/11/20075/31/2007

5/8/2007

4/20/2007

3/23/2007

3/10/20072/19/2007

2/8/2007

1 / 18/2007

1/2/2007

11/8/2006

9/28/20069/13/2006

8/22/2006

8/3/2006

7/25/2006

7/11/2006

6/12/2006

5/18/20065/2/2006

continued

Table 6. Crest Gauge DataNeal’s Landfill


PZ-02o

o

2.6

2.6

2.6o

0

0

o

0o

0

o

02

o

o

o

o

oo

0

o

0

o

0o

0

o

0

0o

o

0

o

o

0

0o5

Apparent Movement (in)PZ-03

0

0

0

0

0

00

0

0

00

0

0

00

00

0

0

00

0

0

00

00

0

0

0

0

00

0

0

0

0

0

00

PZ-04

0

0

o

0

0

o

0o

0

o

0o

0

o

0

o

0o

0

o

0o

0

o

0

o

0o

o

0

o

o

0o

o

0

0

o

0o

PZ-05

0

0

0

0

0

00

0

0

00

00

0

0

00

0

0

00

00

0

0

0

00

0

0

0

0

00

0

0

0

0

00

Date4/3/2006

3/10/2006

2/28/20062/15/2006

2/1/2006

1/16/2006

1/5/2006

12/20/2005

11/2/200510/11/2005

9/19/2005

8/31/2005

8/8/20057/19/2005

6/22/2005

5/12/20055/3/2005

4/13/2005

3/25/2005

2/18/2005

2/3/200512/7/2004

11/22/2004

10/26/2004

10/7/20049/23/2004

9/10/2004

8/31/2004

8/11/2004

8/3/2004

7/13/2004

6/25/2004

6/15/20045/25/2004

5/10/2004

4/22/2004

4/13/2004

3/25/2004

3/11/20042/26/2004

continued

Table 6. Crest Gauge DataNeal’ s Landfill


PZ-02

00

o

0

o

0

0o

0

2.4

0o

00o

0

o

0

-Note0

0

00

00

0

0

00

0

0

0

0

0

00

0

0

0

0


0

0

00

0

0

0

00

00

0

00

0

0

00

0

0

00

0

0

0

0

00

0

0

0

0

00

0

0

0

0

0

0

PZ-04o

0o

o

0

o

0

oo

0

o

o

oo

0

o0

o

4.4

0o

0

o

0

o

00

0

0

o

0

0o

o

0

o

o

0

0o

PZ-05

00

o

0

o

0

0o

0

o

0o

00o

0

o

4.3

NR4

0

10

0

00

0

0

0

00

0

0

0

0

00

0

0

0

0

Date2/12/2oo4

1/29/2oo4

1/15/2oo4

12/31/2oo3

12/8/2oo3

11/2o12oo311/5/2oo3

1 o/2312oo3

lO/912oo3

9/29/2oo3

9/11/2oo38/29/2oo3

8/1512oo3

8/1/2oo3

7/1712oo3

7/3/2oo3

6/19/2oo36/6/2oo3

5/19/2oo3

518/2oo3

4/23/2oo341712oo3

3/19/2oo3

3/612oo3

2/2o/2oo3

2111/2oo3112812oo3

1113/2oo3

1213o/2oo2

12/13/2oo2

1212/2oo2

11114/2oo21 o131/2oo2

lO/17/2oo2

lO13/2oo2

9/19/2oo2

9/912oo2

8/2212oo28/9/2oo2

7/2612oo2

continued

Table 6. Crest Gauge DataNeal’ s Landfill


PZ-020

0

0

0

00

0

0

00

0

0

0

0

0

00

0

00

0

0

0

0

0

00

0

0

0

00

0

0

0

0

0

00

0


o

o

0

o

o

0o

0

o

0

oo

o

0

o

oo

o

o

0

o0

o

0

o

0

0o

0

o

0

-Note

-Note

-Note

-Note

-Note

-Note-Note

0.60.4

PZ-04

00

0

0

00

00

0

0

0

00

0

00

00

0

0

00

0

0

00

0

00

0

00

0

00

0

0

00

0

PZ-05oo

0

0

0

0

o

0o

0

o

0o

0

o

o

o

0o

0

o

0o

0

0

o

0

o0

0

o

0

0

oo

0

0

o

0

0

Table6. Crest Gauge DataNeal’ s Landfill


Date7/11/2002

6/27/2002

6/14/2002

5/31/2002

5/16/20025/3/2002

4/18/2002

4/4/2002

3/21/2002

3/8/2002

2/8/20021/25/2002

1/9/2002

10/25/2001

10/9/2001

9/21/20019/7/2001

8/28/2001

6/14/2001

PZ-020

0

0

0

00

0

0

0

00

0

0

0

0

00

0

0

Apparent Movement (in)PZ-03 PZ-04

oo

-Note 20

0

00

00

0

00

0

0

0

0

0

PZ-05

00

00

0

0

0

2

0.25

0.6

0.5

0.751.752.5

0

3.25

2

1.754.25

4.75

4.9

2.6

2.63.25

00.75

Reinstalled

0

0o

0

o

0

o

oo

0

0

Reinstalled0

Crest gauge removed from piezometer; miniTroll instrument installed.2 No measurement possible due to jammed lock on piezometer.

3 Gauge became damp, then dried prior to inspection in such a manner as to produce an inconclusive chalk

line. Dampness most likely caused by condensation of well humidity, not an actual piezometric rise.4 No record.

Table 7. Piezometer-01 Water ElevationsNeal’s Landfill


Date9/29/200310/9/200311/5/200311/20/200312/8/20031/15/20041/29/20042/12/20042/26/20043/11/20043/25/20044/13/20044/22/20045110120045/25/20046/15/20046/25/20047/13/20048/3/20048/11/20048/31/20049/10/20049/23/200410/7/200410/26/200411/22/200412/7/20042/3/2005

2/18/20054/13/20055/3/20055/12/20057/19/20058/8/20058/31/2005

9/19/2005

10/11/200511/2/2005

12/20/2005

WaterElevation

(~)772.53772.55772.58772.64772.61772.55772.52772.5772.53772.55772.47772.55772.50772.38772.41772.39772.38772.42772.42772.39772.34772.30772.25772.22772.28772.27772.40772.21772.27772.35772.19771.58772.03772.03772.09

772.06

772.03772.04

772.05

Date1/5/2006

1/16/20062/15/20062/28/20063/10/20063/29/20065/2/2006

5/18/20066/12/20067/11/20067/25/20068/3/20068/22/20069/13/200611/8/20061/2/2007

1/18/20072/8/2007

2/19/20073/10/20073/23/20074/20/20075/8/20075/31/20076/12/20076/26/20078/4/20078/27/20072/13/20086/12/20076/26/20078/4/2007

8/27/20072/13/2008

4/9/20084/30/2008

5/20/20086/6/2008

7/18/2008

WaterElevation

(~)772.22772.17772.14772.12772.14772.08772.10772.14772.07771.99771.69771.97771.94771.92771.92771.90771.90771.84771.90772.00771.98771.99772.00771.96771.96771.94771.86771.84771.82771.96771.94771.86771.84771.82

771.75771.83

771.77

771.78772.01

Date8/1/2008

9/10/2008101221200811/13/20082/18/20095/31/20098/25/200910/22/20092/11/2010

WaterElevation

(if)771.96771.95771.93771.54771.54771.36771.28771.21771.25

FIGURES

/ \/ \/

CONTINUOUS MONITORING PLOTS

(u!) Ile=tu!e~ aA!~,elnmno

G:) 0 0 0 0 0 0

(uJd6) ~o1_-I

(u!) Ileju!e~l eAp, elnu~no

(~ud6) ~Ol.-I

(Lud6) MoI-I

~ 0

(u!) Ileju!e~l aAp, elntuno

(u!) Ilej.u!eEI aA!:l.elnmno

(u!) Ile.~u!e~l eAp, elnuJnD

(~,J) uo!~,eAel:l Je~,eM

APPENDIX A

Chain-of-Custody Records

E

= i

APPENDIX B

Certificates of Analysis

CERTIFICATE OF ANALYSISService Location

]ERITAGE ENVIRONMENTAL SERVICES, LLC;OMMERCIAL LABORATORY OPERATIONS’901 W. MORRIS ST.~IDIANAPOLIS, IN 46231317)243-8304

Received

02-APR-10

Completed

08-APR-10

Printed

12-APR-10

Project Lab ID

4602 A877447

PO Number

BL0177 ..............

Sampled

31-MAR-10 10:29

Report To

NEILL VAUGHNCBS CORP2002 WEST VERNAL PIKEBLOOMINGTON, IN 47404

CLIENT ID: NL5754MATRIX TYPE: NON-SPECIFIC WATERSUBMITTER CODE: 2226MATRIX: WSLOCATION: NEAL’S LANDFILLBLANKET ORDER RELEASE: BL0177

Bill To

BETH STEIGERWALDCBS CORPORATION20 STANWIX STREET 10TH FLOORPITTSBURGH, PA 15222

Sample Description

PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION SW846i3510C

AnalySt~ B. WOOD Analysis Date: 06~APR:10 instrument: PREP Test: P230.1.0

Parameter Result Det. Limit UnitsINITIAL WEIGHT OR VOLUME 2000 mL

FINAL VOLUME 1.0 mL

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846.8082

...... Analysis Date : 06-APR, t0 17:15 Instrument: GCtECDAnalyst: K. VEST ......PCB SEPARATORY FUNNEL LiQUID-LIQUID EXT~CTION SW846-35~0C P230.t;0Prep:

Det. LimitParameterPCB AROCLOR 1016

PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY

DECACHLOROBIPHENYL (DCB)

SUMMATION OF AROCLORS

ResultBDL

BDL

BDL

0.10

BDL

BDL

BDL

BDL

82.0

0.10

Test: O301:7.0

Units0.01 ug/L

0.02 ug/L

0.01 ug/L

0.01 ug/L

0.01 ug/L

0.01 ug/L

0.01 ug/L

0.01 ug/L

% Rec

0.02 ug/L

Page 1 of 2

HERITAGE ENVIRONMENTAL SERVICES, LLC Sample ID: A877447 NL5754

Arochlor exhibits degradation.

TOTAL SUSPENDED SOLIDS DRIED AT 103-105 DEGREES CSM 2540 D; 19THi

Ana!yst: R. YOUNG Analysis Date: 06’APR,10 1;2:00

Parameter ResultSUSPENDED SOLIDS 7

Det. Limit UnitsI I mglL

Sample Comments

BDL Below Detection Limit

Sample was received on ice at temperature 4.2 C.Sample chain of custody number 68474.

This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample resultsrelate only to the analytes of interest tested or to the sample as received by the lab. Heritage Environmental Services,

LLC certifies that the test results indicated as NELAC (National Environmental Laboratory Accreditation Conference)accredited (Yes for NELAC) meet all requirements of NELAC and Illinois EPA Part 186 unless otherwise explained orjustified as to the the exact nature of the deviations.

IL ELAP / NELAP Accreditation # 100401 Indiana SDWA Lab Accred. No. C-49-01

Additional copies of this report sent to:

RUSS CEPKO, CBS CORP - NATIONAL CITY CENTER20 STANWiX STREET 10TH FLOOR, PITTSBURG, PA 15222-1384

Approved by: SCOTT BRYAN 08-APR-10

Page 2 of 2


HERITAGE ENVIRONMENTAL SERVICES, LLCCOMMERCIAL LABORATORY OPERATIONS7901 W. MORRIS ST.INDIANAPOLIS, IN 46231(317)243-8304

Received

02-APR-10

Completed

08-APR-10

Printed12-APR-10

Project

4602

Lab ID

A877448

PO Number

B L0177 ..............

Report To



Sampled

31-MAR-10 10:55

Bill To


Sample Description

PCB SEPARATORY FUNNEL MQUID-MQUID EXTRACTION SW846-3510C

Analyst: B. WOOD Analysis Date: 06,APR-10 Instrument:PREP Test: P230.1.0

Parameter Result Det. Limit Units

INITIAL WEIGHT OR VOLUME 1000 mL

FINAL VOLUME 5.0 mL

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846,8082

Analyst: K. VEST Analysis Date: 06~APR40 17:15 instrument: GC/ECDPrepi PCB SEPARATORY FUNN EL LIQUID-LiQUI D EXT~CTION SW846-35t0C P23011.0

Parameter Result Det. LimitPCB AROCLOR 1016 BDL

PCB AROCLOR 1221 BDL


PCB AROCLOR 1242 0.12





SURROGATE RECOVERY

DECACH LOROBI PH ENYL (DCB) 104.0

SUMMATION OF AROCLORS J 0.12

0.10

0.20

0.10

0.10

0.10

&10

0.10

0.10

0.20

NELAC:Y

Test; O301:.7:0

Unitsug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Rec

ug/L

Page 1 of 2



Parameter Result Def. Limit UnitsSUSPENDED SOLIDS I I I mglL

Sample Comments


J Estimated, below calibration range.


This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample resultsrelate only to the analytes of interest tested or to the sample as received by the lab. Heritage Environmental Services,

LLC certifies that the test results indicated as NELAC (National Environmental Laboratory Accreditation Conference)accredited (Yes for NELAC) meet all requirements of NELAC and Illinois EPA Part 186 unless otherwise explained orjustified as to the the exact nature of the deviations.



RUSS CEPKO, CBS CORP - NATIONAL CITY CENTER20 STANWIX STREET 10TH FLOOR, PITTSBURG, PA 15222-1384


Page 2 of 2



Received

02-APR-10

Completed

08-APR-10

Printed

12-APR-10

Project Lab ID

4602 A877449

PO Number

B L0177 ..............

Sampled

31-MAR-10 11:00

Report To



Bill To


Sample Description

PCB SEPARATORY FUNNEL LIQUID’LIQUID EXTRACTION SW846-3510C

Analyst: B. WOOD AnalYsis Date: 06~APR~10

Parameter Result

INITIAL WEIGHT OR VOLUME 1000

FINAL VOLUME 5.0

Instrument: PREP

Det. Limit

Test: P230.1.0

Units

mL

mL


Analyst: K. VEST Analysis Date: 06-APR-t0 1:7:15Prep PCB SEPARATORY FUNNEL LIQUID,LiQUID EXTRACTION SW846-3510C P230/I.0

ParameterPCB AROCLOR 1016

PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY



ResultBDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

72.0

BDL

Instrument: GC/ECD

Det. Limit

0.10

0.20

0.10

0.10

0.10

&10

0.10

0.10

0.20

NELAC:Y

Test: O301.7.0

Unitsug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Rec

ug/L

Page 1 of 2

HERITAGE ENVIRONMENTAL SERVICES, LLC

TOTAL SUSPENDED SOLIDS DRIED AT 103’105 DEGREES C SM 2540: D, 19TH ED;

Analyst: R. YOUNG Analysis Date: 06,APR~10 1:2:00

Parameter ResultSUSPENDED SOLIDS BDL

Det. Limit

Sample ID: A877449 NL5756

NELAC:Y

Units1 mg/L |

Sample Comments



This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results

relate only to the analytes of interest tested or to the sample as received by the lab. Heritage Environmental Services,LLC certifies that the test results indicated as NELAC (National Environmental Laboratory Accreditation Conference)

accredited (Yes for NELAC) meet all requirements of NELAC and Illinois EPA Part 186 unless otherwise explained orjustified as to the the exact nature of the deviations.IL ELAP / NELAP Accreditation # 100401 Indiana SDWA Lab Accred. No. C-49-01




Page 2 of 2



Received

02-APR-10

Completed

08-APR-10

Printed

2-AP R- 10

Project Lab ID

4602 A877450

PO Number

B L0177 ..............

Sampled

31-MAR-10 11:26

Report To


Bill To


Sample DescriptionCLIENT ID: NL5757MATRIX TYPE: NON-SPECIFIC WATERSUBMITTER CODE: 2226MATRIX: WSLOCATION: NEAL’S LANDFILLBLANKET ORDER RELEASE: BL0177

PCBSEPA TO FUNNELLIQUID’LIQUI x’r CTIONS 46-5t0C

Analyst: B. WOOD Analysis Date: 06-APR-10 instrument: PREP Test.: P230.1.0:



FINAL VOLUME 5.0 mL

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846,8082 NELAC:Y

Analyst: K. VEST Analysis Date: 06-APR-10 17:15 ~strument: GC/ECD Test: O301.7.0i i

Prep: PCB SEPARATORY FUNNEE LIQUID-LIQUID EXTRACTION SW846:3510C P230:.I.0


PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY



ResultBDL

BDL

BDL

0.61

BDL

BDL

BDL

BDL

102.0

0.61;

Det. Limit

0.10

&20

0.10

0.10

0.10

0.1;0

0.10

0.10

0.20

Unitsug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Rec

ug/L

Page 1 of 2




Analyst: R. YOUNG ASaiysis Date: 06"APR,10 12:00

Parameter Result

SUSPENDED SOLIDS 7

Det. Limit Units

1 I mg/LSample Comments



This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results

relate only to the analytes of interest tested or to the sample as received by the lab. Heritage Environmental Services,LLC certifies that the test results indicated as NELAC (National Environmental Laboratory Accreditation Conference)accredited (Yes for NELAC) meet all requirements of NELAC and Illinois EPA Part 186 unless otherwise explained orjustified as to the the exact nature of the deviations.





Page 2 of 2



Received

02-APR-10

Completed

08-APR-10

Printed

12-APR-10

Project Lab ID

4602 A877451

PO NumberB L0177 ..............

Sampled

31-MAR-10 11:26

Report To


Bill To


Sample DescriptionCLIENT ID: NL5758MATRIX TYPE: NON-SPECIFIC WATERSUBMITTER CODE: 2226MATRIX: WSLOCATION: NEAL’S LANDFILLBLANKET ORDER RELEASE: BL0177

PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION SW846:3510C

Analyst! B. WOOD Analysis Date: 06-APR~10 Instrument: PREP Test: P230.1.0


FINAL VOLUME 5.0 mL

PCB AROCLORS BY GAS CHROMA’rOGRAPHY/ECD SW846-8082

Analyst: ..... Analysis Date: 06-APR~10 17:15 Instrument: GC/ECDK.VESTPrep: PCB SEPA~TORY FUNNEL LIQUID-LIQUID EXTRACTION SW846,3510C P23011~0


PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY

DECACHLOROBIPHENYL(DCB)

SUMMATION OFAROCLORS

ResultBDL

BDL

BDL

0.67

BDL

BDL

BDL

BDL

98.0

0.67

Det. Limit

0.10

0.20

0.10

0.10

0.10

0.10

0.10

0.10

0.20

NELAC:Y

Test: O301.7:0

Unitsug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Rec

ug/L

Page 1 of 2


TOTAL SUSPENDED SOLIDS DRIED AT 103~105 DEGREES C SM 2540 D, 19TH ED~ NELAO:Y

Analyst:R, YOUNG AnalySis Date: 06-APR~10 12:00 Test: G403.8.0


SUSPENDED SOLIDS 8 1 mg/L

Sample Comments



This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample resultsrelate only to the analytes of interest tested or to the sample as received by the lab. Heritage Environmental Services,LLC certifies that the test results indicated as NELAC (National Environmental Laboratory Accreditation Conference)

accredited (Yes for NELAC) meet all requirements of NELAC and Illinois EPA Part 186 unless otherwise explained orjustified as to the the exact nature of the deviations.IL ELAP / NELAP Accreditation # 100401 Indiana SDWA Lab Accred. No. C-49-01



Approved by: SCOTT BRYAN 08-APR-J0

Page 2 of 2



Report To

NEILL VAUGHNCBS CORP

Received

22-APR-10

Completed

04- MAY- 10

Printed

20-MAY- 10

Lab ID

A879115

PO Number

BL-0396

Sampled

21-APR-10 09:34

2002 WEST VERNAL PIKEBLOOMINGTON, IN 47404

CLIENT ID: NL5759MATRIX TYPE: NON-SPECIFIC WATERSUBMITTER: 2226 - CBS CORPORATIONPROJECT NAME: CBS CORPDATA PACKAGE #: 59870MATRIX: WSLOCATION: NEAL’S LANDFILLBLANKET ORDER RELEASE: BL0177

Bill To


Sample Description

PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION SW846-3510C

Analyst: T. WATSON Analysis Date: 26-APR,10

Parameter ResultINITIAL WEIGHT OR VOLUME 1950

FINAL VOLUME 1.0

Instrument: PREP Test: P230.1.0

Det. Limit UnitsmL

mL


Analysis Date: 2ZiAPRil0 19:15Aaa!Ysti K. VEST ....PrepiPCB SEPARATORY FUNNEL ~iQUID-LIQUIDEXTRAOTION SW846-35!0C P230;:1:0


PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY


ResultBDL

BDL

BDL

0,076

BDL

E~DL

BDL

BDL

92.0

instrument: GC/ECD Test:: O301i17.0

Det. Limit

0.01

&02

0.01

0:01

0.01

0:01

0.01

0:01

Unitsug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Rec

Page 1 of 2



Aroclor exhibits degradation.

.076


0.02 ug/L

NELAC:YTOTAL SUSPENDED SOLIDS DRIED AT 103’105 DEGREES CSM 2540: D~ 19TH ED: .....

Analysis Date: 22-APR’10 09:30 Test: G403i8i0Analyst: R. YOUNG ...........



Sample Comments



This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample resultsrelate only to the analytes of interest tested or to the sample as received by the lab. Heritage Environmental Services,LLC certifies that the test results indicated as NELAC (National Environmental Laboratory Accreditation Conference)accredited (Yes for NELAC) meet all requirements of NELAC and Illinois EPA Part 186 unless otherwise explained orjustified as to the the exact nature of the deviations.IL ELAP / NELAP Accreditation # 100401 Indiana SDWA Lab Accred. No. C-49-01




Page 2 of 2



Received

22-APR-10

Completed

04-MAY-10

Printed

20-MAY-10

Lab ID

A879116

PO NumberBL-0396

Sampled

21-APR-10 09:55

Report To



Bill To


Sample Description

PCB SEPARATORY FUNNEL LIQUID,LIQUID EXTRACTION SW846~3510C

Analyst: TI WATSON Analysis Date: 26-APR.10 instrument: PREP Test: P230.1:0



FINAL VOLUME 5 mL

PCB AROCLORS BYGAS CHROMATOGRAPHY/ECD SW846’8082

Analyst: K~ VEST Analysis Date: 27-APR-1019:15 instrument:GC/ECD

Prep: PCB SEPARATORY FUNNEL LIQUID-LIQU D EXTRACT ON SW846-35IOC P230.1:0 ....


PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY


ResultBDL

BDL

BDL

0.34

BDL

BDL

BDL

BDL

106.0

0.10

0.20

0.10

0.10

0.10

0:1;0;

0.10

0.10

NELAC:Y

Test: O301.7:0

Unitsug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Rec

Page 1 of 2




I0.34


0.20 ug/L

TOTAL SUSPENDED SOLIDS DRIED AT 103’105 DEGREES C SM 2540 D, 19TH ED;

AnalYst: R: YOUNG AnalYsis Date: 22-APR~10 09i30

Parameter

I ResultSUSPENDED SOLIDS 2

Test: G403 &0~

Det. Limit Units/

1 mg/L J

Sample Comments







Page 2 of 2



Report To


Received

22-APR-10

Completed

04-MAY-10

Printed

20-MAY-10

Lab ID

A879117

PO Number

BL-0396

Sampled

21-APR-10 10:03



Bill To


Sample Description

PCB SEPARATORY FUNNEL LIQUID.LIQUID EXTRACTION SW846,3510C

Analyst: T. WATSON Analysis Date: 26-APR-10 Instrument: PREP Test: P230.1.0



FINAL VOLUME 5 mL

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846-8082 .... NELAC:Y

Analyst: K. VEST Analysis Date: 27-APR~10 19:15 Instrument: GC/ECD Test: O301.7.0

Prep: PCB SEPARATORY FUNNEL LIQUiD~LIQUID EXTRACTION SW846-3510C 9230:’1,0


PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY


ResultBDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

92.0

Units0.10 ug/L

0.20 ug/L

0.10 ug/L

0.10 ug/L

0.10 ug/L

0.10 ug/L

0.10 ug/L

0.10 ug/L

% Rec

Page 1 of 2


SUMMATION OFAROCLORS BDL 0:20 ug/L

TOTAL SUSPENDED SOLIDS DRIED AT 103i105 DEGREES C SM 2540 O, 19TH NELACI¥

Analyst! R~ YOUNG Analysis Date: 22~APR~10 09:30 Test:


SUSPENDED SOLIDS BDL 1 mg/L

Sample Comments







Page 2 of 2



Received

22-APR- 10

Completed

04-MAY-10

Printed

20-MAY- 10

Lab ID

A879118

PO Number

BL-0396

Sampled

21-APR-10 10:10

Report To


Bill To


Sample DescriptionCLIENT ID: NL5762MATRIX TYPE: NON-SPECIFIC WATERSUBMITTER: 2226 - CBS CORPORATIONPROJECT NAME: CBS CORPDATA PACKAGE #: 59870MATRIX: WSLOCATION: NEAL’S LANDFILLBLANKET ORDER RELEASE: BL0396

PCB SEPARATORY FUNNEL LIQUID~LIQUID EXTRACTION SW846-3510C

Analyst: T. WA’rSON Analysis Date: 26-APR~10 Instrument: PREP Test: P230.!I0


FINAL VOLUME 5 mL

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846,8082

Analyst: K. VES,r Analysis Date: 27~APR-10 1:9:15Prep: PCB SEPARATORY FUNNEL LIQUID,LIQUID E~RACTION SW846-3510C P230.1.0


PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY


ResultBDL

BDL

BDL

0.75

BDL

BDL

BDL

BDL

NELAC:Y

instrument: GC/ECD Test:: O301.7~0

Det. Limit Units0.10 ug/L

0.20 ug/L

0.10 ug/L

0.10 ug/L

0.10 ug/L

0.10 ug/L

0.10 ug/L

0.10 ug/L

86.0 % Rec

Page 1 of 2




0.75


0.20 ug/L

TOTAL SUSPENDED SOLIDS DRIED AT 103.105 DEGREES C SM 2540 Di 19TH ED. NELAC:¥

Analyst: R. YOUNG Ahalysis Date: 26iAPR~10 13:30 ...... Test: G403.8.0



Sample Comments







Page 2 of 2

CERTIFICATE OF ANALYSISReceived

22-APR-10

Lab ID

A879119Service Location


Completed PO Number

04-MAY-10 BL-0396

Sampled

21-APR-10 10:10

Report To



Printed20-MAY-10

Bill To


Sample Description

PCB SEPA~TORY FUNNEL LIQUID-LIQUID EXTRACTION SW846-3510C

Analyst: .T. WATSON Analysis Date: 26~APR~10 Instrument: PREP "Test: P230.1~0


FINAL VOLUME 5 mL

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846.8082 NELAC:Y

Analyst: K. VEST .... Analysis Date: 27,APR-10 19:15 Insti’ument: GC!ECD Test: O30t.7.0

Prep: PCB SEPARATORY FUNNEL EiQuID-LIQUiD EXTRACTION SW846-35!0C P230.1.0

Det. Limit UnitsParameterPCB AROCLOR 1016

PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY


ResultBDL

BDL

BDL

0.71

BDL

BDL

BDL

BDL

102.0

0.10

0.20

0.10

0.10

0.10

0.10

0.10

0.10

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Rec

Page 1 of 2




0.71

Sample lD: A879119 NL5763

0.20 ug/L

TOTAL SUSPENDED SOLIDS DRIED AT 103;’!05 DEGREES C SM2540 O, 19TH EO. NELAC:¥

Parameter Result Det. Limit UnitsSUSPENDED SOLIDS 6 1 I mg/L

Sample Comments







Page 2 of 2



Report To


Received

27-MAY- 10

Completed

09-JUN-10

Printed

07-JUL-10

Lab ID

A883083

PO Number

BL-0396

Sampled

25-MAY-10 13:59



Bill To

BETH STEIGERWALDCBS CORPORATION20 8TANWlX STREET 10TH FLOORPITTSBURGH, PA 15222

Sample Description

PCB SEPA~TORY FUN NEL LIQUID-LIQUID EXT~CTION SW846-3510C

Analyst: T. PINCKERT Analysis Date: 01-JUN~I:0 Instrument: PREP Test: P230.1~0



FINAL VOLUME 1.0 mL

PCB AROCLORS BYGAS CHROMATOGRAPHY/ECD SW846-8082

Analyst: B. WOOD A~alysis Date: 0t-JUN210 15:48 Instrument: GC/ECDPrepi PCB SEPARATORY FUNNEL LIQUID, LIQUID EXTRACTION SW846-35t0C P230.1.0


PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY


ResultBDL

BDL

BDL

0:089

BDL

BDL

BDL

BDL

104.0

Test:

Units0.01 ug/L

0.02 ug/L

0.01 ug/L

0.01 ug/L

0.01 ug/L

0.01 ug/L

0.01 ug/L

0.01 ug/L

% Rec

Page 1 of 2



0’02 I ug/L

TOTAL SUSPENDED SOLIDS DRIED AT 103~’105 DEGREES C SM 2540: D, 19TH ED, NELAC:Y

Analyst~ & BOXUM Analysis Date: 01;JUN-10 13:00 Test: G403.&0

Parameter Result Det. Limit UnitsSUSPENDED SOLIDS 13 1 mg/L

Sample Comments


Sample was received on ice at temperature 3 C.Sample chain of custody number 64147.



RUSS CEPKO, CBS CORP - NATIONAL CITY CENTER20 STANWlX STREET 10TH FLOOR, PITTSBURG, PA 15222-1384

Approved by: SCOTT BRYAN 04-JUN-10

Page 2 of 2



Received

27-MAY- 10

Completed

09-JUN-10

Printed

07-JUL-10

Lab ID

A883084

PO Number

BL-0396

Sampled

25-MA¥-10 14:03

Report To


Bill To

BETH STEIGERWALDCBS CORPORATION20 STANWIX STREET 10TH FLOORPITTSBURGH PA 15222

Sample DescriptionCLIENT ID: NL5765MATRIX TYPE: NON-SPECIFIC WATERSUBMITTER: 2226 - CBS CORPORATIONPROJECT NAME: CBS CORPDATA PACKAGE #: 60038MATRIX: WSLOCATION: NEAL’S LANDFILLBLANKET ORDER RELEASE: BL0177

PCB SEPARATORY FUNNEL LIQUID’LIQUID EXTRACTION SW846-3510C

Analyst: T. PINOKERT Analysis Date: 01-JUN.10 Instrumenti PREP Test: P230.1~0

Parameter Result Det. Limit UnitsINITIAL WEIGHT OR VOLUME 1000 rnL

FINAL VOLUME 5 mL

PCB AROCLORS BY GAS CH ROMATOGRAPHY/EC D SW846;8082

Analyst: B. WOOD Anaiys[s Date: 01’JUN,10 15:48 Instrumenii GC/ECD

Prep: PCB SEPA~TORY FUNNEL LIQU!D’LIQUlD E×TRAGTION SWa4e;35~0C P230:].0


PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY


ResultBDL

BDL

BDL

0.13

BDL

BDL

BDL

BDL

124.0

0.10

0.20

0.10

0.10

0.10

0.10

0.10

0.10

NELAC:Y

Test: O30"117.0

Unitsug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Rec

Page 1 of 2


SUMMATION OFAROCLORS J 0.13 0.20 ug/L

TOTAL SUSPENDED SOLIDS DRIED AT 103’105 DEGREES C SM 2540 Di 19TH ED~ NELAC:¥

Analyst: S. BOXUM Anaiysis Date! 0t-JUN-10 13:00 Test: G403i8:0



Sample Comments

BDL Below Detection LimitJ Estimated, below calibration range.




RUSS CEPKO, CBS CORP - NATIONAL CITY CENTER20 STANWlX STREET 10TH FLOOR, PITTSBURG, PA 15222-1384


Page 2 of 2



Received

27-MAY-10

Completed

09-JUN-10

Printed07-JUL-10

Lab ID

A883085

PO NumberBL-0396

Sampled

25-MAY-10 14:07

Report To



Bill To


Sample Description

RACTION SW846’PCB SEPARATORY FUNNEL LIQUID-LIQUID EXT 3510C

Analyst: T~ PINCKERT Analysis Date: 01-JUN~10 Instrument: PREP Test: P230,ii0

Parameter Result Det. Limit I UnitsINITIAL WEIGHT OR VOLUME 1000

t mLFINAL VOLUME 5 mL

PCB AROCLORS BY GAS CHROMA’rOG~PHY/ECD SW846,8082

Analyst: B. WOOD AnalysisDate: 01-JUN,10 15:48 Instrument: GC/ECD

Prep: PCB SEPARATORY FUNNEL LtQUtD~LIQUID EXTRACTIQN SW846.351OC P230.1~0


PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY


ResultBDL

BDL

BDL

BDL

BDL

BDL

BDL

BDL

116.0

0.10

0.20:

0.10

0.10

0.10

0.10

0.10

0.10

NELAC:Y

Test: O30r1.7.0

Unitsug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ugtL

% Rec

Page 1 of 2

SUMMATION OF AROCLORS BDL


0.20 ug/L

TOTAL SUSPENDED SOLIDS DRIED AT

ParameterSUSPENDED SOLIDS

103-105 DEGREES C SM 2540 D, 19TH ED., NE~C:¥

Result Det. Limit UnitsBDL I 1 mg/L

Sample Comments







Page 2 of 2

ENV~R( :~N Mi!! i’,J!)\i.. SE RVICt!!!S



Received

27-MAY-10

Completed

09-JUN-10

Printed07-JUL-10

Lab ID

A883086

PO NumberBL-0396

Sampled

25-MAY-10 14:10

Report To



Bill To


Sample Description

PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION SW846-3510C

Analyst: T; PINCKERT

ParameterINITIAL WEIGHT OR VOLUME

FINAL VOLUME

Analysis Date: 01-JUN-I:0

Result1000

5

Instrument: :PREP

Det. Limit

Test: P230:1:0

mLmLUnits

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846-8082 NELAC:¥

Analyst: B; WOOD Analysis Date: 01-JUN-10 15:48 InstrUment: GC/ECDTest:: O301:710Prep: PCB SEPARATORY FUNNEL LIQUID~LIQUID EXTRACTION SW846-3510C P230.1.0


PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR1242

PCB AROCLOR1248

PCB AROCLOR 1254

PCB AROCLOR1260

PCB AROCLOR 1262

ResultBDL

BDL

BDL

0:56

BDL

BDL

BDL

BDL

130.0

0.10

0.20

0.10

0:1;0

0.10

0~10

0.10

O: 10

SURROGATE RECOVERY


Unitsug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

% Rec

Page 1 of 2

~*" ~ r.:]NV RONM{ZN-fT\L S{i!RV!< }ES

SUMMATION OF AROCLORS 0.56

TOTAL SUSPENDED SOLIDS DRIED AT 103"105 DEGREES C SM 2540 D; 19TH ED.

Analyst! S~ BOXUM Analysis Date! 0%JUN,10

Parameter Result Det. LimitSUSPENDED SOLIDS 6


0.20 ug/L

Units/

mg/L J

Sample Comments







Page 2 of 2



Report To


Received

27-MAY-10

Completed

09-JUN-10

Printed

07-JUL-10

Lab ID

A883087

PO NumberBL-0396

Sampled

25-MAY-10 14:10



Bill To


Sample Description

PCB SEPARATORY FUNNEL LIQUIDiLIQUID EXTRACTION SW846~3510C

Analyst: T. PINCKERT Analysis DateI Ol-JUN-10 Instrument!PREP Test: P23&1:0



FINAL VOLUME 5 mL

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846-8082

Analyst: B. WOOD Analysis Date: 0t-JUN-t0 i5:48 Instrument: GC/ECD Test:: 030117.0

PieP: PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION SW846-35i0C P230.1.0


PCB AROCLOR 1221

PCB AROCLOR 1232

PCB AROCLOR 1242

PCB AROCLOR 1248

PCB AROCLOR 1254

PCB AROCLOR 1260

PCB AROCLOR 1262

SURROGATE RECOVERY


ResultBDL

BDL

BDL

0.55

BDL

BDL

BDL

BDL

120.0

Units0.10 ug/L

0.20 ug/L

0.10 ug/L

0:10 ug/L

0.10 ug/L

0.10 ug/L

0.10 ug/L

0.10 ug/L

% Rec

Page 1 of 2



0.20 ug/L

TOTAL SUSPENDED SOLIDS DRIED AT 103:105 DEGREES C SM 2540 D, 19TH EDi NELAC!YAnalyst: S~ BOXUM Analysis Date: 01-JUN~10 13:00 Test: G403.8i01



Sample Comments







Page 2 of 2

APPENDIX C

Data Validation

Validation ResultsMarch 2010

Neal’s Landfill GWM Samples

1. Validation of the following samples has been completed:

NL 5754-NL5758

2. Validation was performed per the requirements for level 4 data in the project QAPjP. This includes acheck for; Holding Time, Calibration, Blank Contamination, Precision, Accuracy, and Accuracy ofNominal Reporting Limits against method requirements.

3. Based on this review, no data qualifications are recommended.

4. The QAPjP requires an assessment of the overall data quality with respect to Precision, Accuracy,Representativeness, Completeness and Comparability (PARCC).

Precision and accuracy: Precision and accuracy were accessed by reviewing the labperformance on lab spiked samples, lab spike duplicates and field duplicates. Allrequirements were met.

Representativeness: The representativeness requirement involves an assessment of thefield sampling and lab analytical techniques. The fields sampling locations andtechniques as well as lab procedures were in accordance with the approved samplingplan and QAPjP. Therefore the representativeness requirements were met.

Completeness: The completeness goal for the project was for all project data to be 90%accepted. Completeness is calculated by dividing the total number of acceptableanalyses by the total performed. An acceptable analysis is defined as one that conformedto QC protocols and is not rejected. All these analyses were accepted. The projectcompleteness goal has been met to date.

Comparability: All the samples taken, analyzed and validated by CBS were taken byCBS or it’s contractors sampling crews using the same procedures as previous samples atthis location. These samples were analyzed by Heritage Labs. Care should be takenwhen attempting to trend Heritage sample results with other labs using slightly differentprocedures. Overall these results should be directly comparable to other Heritage labresults from these locations.

Overall, the main objective of the sampling event was to determine if PCBs are present at a concentrationof 0.1 ppb or more (0.01 ppb for CB Pool VP). This data is of sufficient quality to satisfy this goal asestimates.

O:LLEA\EnvironmentalkBloomington\SHAREDIR\BP validation reports\validation-gwm qtrly report-NL Mar 10.doc 12/6/2010

Validation ResultsApril 2010



NL 5759-NL5763



4. The QAPjP requires an assessment of the overall data quality with respect to Precision, Accuracy,Representativeness, Completeness and Comparability (PARCC).





Overall, the main objective of the sampling event was to determine if PCBs are present at a concentrationof 0.1 ppb or more (0.01 ppb for CB Pool VP). This data is of sufficient quality to satisfy this goal asestimates.

OALEA~Environmental\Bloomington\SHAREDIRkl3P validation reports\validation-gwm qtrly report-NL Apr 10.doc 12/6/2010

Validation ResultsMay 2010



NL 5764-NL5768



4. The QAPjP requires an assessment of the overall data quality with respect to Precision, Accuracy,Representativeness, ComPleteness and Comparability (PARCC).





Overall, the main objective of the sampling event was to determine if PCBs are present at a concentrationof 0.1 ppb or more (0.01 ppb for CB Pool YP). This data is of sufficient quality to satisfy this goal asestimates.

OALEA\Environmental~Bloomington\SHAREDIR’d3P validation reports\validation-gwm qtrly report-NL May 10.doc12/6/2010

APPENDIX D

Instrument Maintenance Log

Neal’s Landfill Q2 2010 Instrument Maintenance Log

Conard’s Branch Weir:Instrument

Level Troll #113729

CBR RaM Gauge:InstrumentEZLogger

MW-5a:Instrument

mini-Troll #7785

Date3/24/20105/10/20105/26/2010

DateAll quarter

Date3/16/20105/10/20105/26/2010

No re-index needed.No re-index needed.No re-index needed.

Action

ActionEZLogger operated properly during the Fourth Quarter.

Re-indexed by 0.105’Re-indexed by 0.03’Re-indexed by 0.01’

Action

Documents

LETTER RE: SURFACE WATER, FLOW AND WATER LEVEL … · 2020. 11. 28. · ©CBS 20 STANWIX STREET, 10TH FLOOR PITTSBURGH, PENNSYLVANIA 15222 March 18, 2011 To: DISTRIBUTION Dorothy