Lisa Sanzenbacher Illinois Institute of Technology [email protected] Please look at the notes sections in the presentation in “Normal View” if there

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Lisa Sanzenbacher Illinois Institute of Technology [email protected] Please look at the notes sections in the presentation in Normal View if there are technical difficulties with the audio. Slide 2 Outline Interest in Algae Converting Sunlight to Chemical Energy Resulting impacts of manufacturing algal fuel Comparing the impacts to other fuel sources Using Algae to Help Coal Algae as a Transportation Fuel Legal Considerations Part 2 Slide 3 Interest in Algae For over 50 years, algae was known to be a renewable source of energy Slide 4 Reliance on Fossil Energy for Transportation Fuel 95% of the united States transportation fuel comes from petroleum United States relies on foreign oil: imports 3 billion gallons per year Slide 5 Department of Energy funded ASP in 1970s and 1980s Funding died in 1990s because of cheap price of petroleum First oil shock facilitated Aquatic Species Program Fuel from algae first discovered in the 1950s EPA notes: Transportation sector 2 nd largest contributor to GHG emissions Climate change and energy security Issues revitalized algal research Slide 6 Energy Independence and Security Act of 2007 Renewable Portfolio Standards mandate an increase in non-corn based fuels Algae to provide biomass based diesel other advanced fuels 21 billion gallons by 2022 Slide 7 Research is booming Slide 8 Harnessing the Suns Energy Moving away form petroleum allows us to use a renewable source of energy, but it comes with its price Slide 9 what is algae? 2 nd Generation Renewable Biofuel characterized by Higher solar energy yield Year-round cultivation Ability to utilize gray waters and non-arable lands Produces biodegradable biofuels Multi-cellular plant Cholorphyll Occurs naturally in lake and streams with high amounts phosphorus and nitrogen Slide 10 converting sunlight into a fuel Growth Photobioreactor Open ponds Photosynthesis 10%solar energy conversion efficiency Carbohydrate, Oxygen Nutrient Restriction Less nutrient less growth, more lipids De-water Extraction Transesterification Slide 11 Algal Impacts Life Cycle Impact Assessment reveals high energy requirements for biodiesel production Electricity for pumping, sparging, dewatering Natural Gas for heating Slide 12 Energy, Economic & Environmental Comparison Energy Output, Price & GHG Contribution DieselSoybeanAlgae Net Energy Ratio* 0.191.640.93 strain to pump GHG # 17-71-75 Price per gallon $3.19$4.20$2.50- $25 Fuel Combustion Emissions * MJ consumed/MJ produced # gCO2e/MJ DieselSoybeanAlgae mpg10.93 CO10.57 PAH10.20 pm10.45 SO 2 100 NO x 11.13 * B100 blend Slide 13 Energy & Environmental Comparison Environmental Impacts of Making Fuels Algae Requirements: Sunlight CO2 Water (some) land Nutrients like Nitrogen & Phosphorus Slide 14 Using Algae to Help Coal One industrys trash is another industrys treasure Slide 15 From Waste to Resource Algal Requirements CO 2 Water Sunlight Land Nutrients Coal Plant Waste CO 2 Waste Water/ effluent Sulfur Ash & Slag NOx If algae promises to be the next source of transportation fuel Requires a lot of clean CO2- more than what atmosphere can provide 40 billion gallons algae fuel requires CO2 from 32% of all US coal power plant Slide 16 IGCC as Source of CO 2 GE's IGCC with CO 2 capture process Integrated Gas Combined Cycle gasifies coal to H 2 and CO (syngas) Removes impurities like sulfur Ability to use Illinois bituminous coal H 2 and CO fires first gas turbine to produce electricity Exhaust heat fires second steam turbine generator to produce electricity again CO combusted with controlled O 2 to produce CO 2 CO2 can be sequestered The General Electric Company. This material may not be copied or distributed in whole or in part, without the prior written permission of the copyright owner Slide 17 IGCC as Source of Additional Algal Inputs Eni Project, Monterotondo, Italy Sequestered carbon directed to nearby algae plant Convert NOx into ammonia, a fertilizer for algae React CO with H 2 to create methanol CO + 2H 2 CH 3 -OH Methanol is a necessary and expensive reactant to create biodiesel Future Gens IGCC Plant 1 2.5 MMT CO2 50,000 120,000 gallons biodiesel annual Slide 18 Algae as a Source of Biomass Algae can make 30% oil 70% dry biomass Midwest Generation Biomass Cofiring Test with 10% biomass blending Lower fuel costs 3.5 5% SO2 reduction No reduction in pm, NOx Slide 19 Siting Algae Plant adjacent to IGCC Plant Siting Algae plant near existing IGCC plants Legal Benefits No extensive energy to pump thousands of feet underground Potential SDWA issues averted, possibly CERCLA? Economic benefits $400,000 per MW to sequester Carbon Typical 500MW plant $200 million Global Energy Wabash River LP ASU and Steam Injection Algae + IGCC still not a cure all Mining coal causes Acid Mine Drainage Slide 20 Algae as a Transportation Fuel Slide 21 Biodiesel + Hybrid Vehicles Slide 22 First Car to run on algae biodiesel 2005 Algaeus 2009 Peugeot 3008 HYbrid 4 Spring 2011 Algae + Hybrid Vehicles still not a cure all NOx emissions contribute to upper respiratory tract infections Slide 23 Legal Implications Considerations for Algae Biodiesel Slide 24 Regulatory Questions Helping the Electricity Generation Sector CAA NSR? SDWA CWA CERCLA Helping the Transportation Sector CAFE standards EPA + NHTSA joint ruling 34.1 mpg 202 CAA RPS Slide 25 Conclusions Algae is a good start algal biodiesel will almost completely replace conventional biodiesel Slide 26 Conclusions But algae is not the answer But analytical results show that algal biodiesel will not be the major energy source in 2040