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“Lively Somerville” Promoting Green Building and Renovation Green Building elements and Somerville’s focus on toxic materials. What is toxics use reduction? Why are the hazardous substances in building materials a concern? What are the alternatives? What can you do?

Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

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Page 1: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

“Lively Somerville” Promoting Green Building and

Renovation

• Green Building elements and Somerville’s focus on toxic materials.

• What is toxics use reduction?• Why are the hazardous

substances in building materials a concern?

• What are the alternatives?• What can you do?

Page 2: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Building Materials with Hazardous Components

• Wood Products– Pressure Treated Wood– Composite Wood Products

• Flooring • Insulation• Concrete • Paints and Finishes• Caulk and Adhesives

Page 3: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Extraction and Production

Storage and transport

Product impacts through lifecycle

Disposal

UseUse

Page 4: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Building ImpactsUSGBC estimates U.S. commercial and

residential building create or consume:

65.2% of total energy consumption

30% of total greenhouse gas emissions

136 million tons of construction and demolition waste (approx, 2.8 lbs/person/day)

12% of potable water

40% (3 billion tons annually) of raw materials us globally

Page 5: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

When are the hazardous building materials a human health concern?

1.Production

2.Use• Installation• Occupant Use• Maintenance

3.Disposal

Workers Exposure

Occupant Exposure

Workers and Occupant Exposure

Page 6: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Why Are Building Materialsa Concern for the Builder?

• Some very common building products are known to cause: – reproductive disorders– cancer– nervous system disorders– asthma and allergies

• Builders receive both short-term and long-term exposures to these chemical hazards:– Off-gassing VOCs - solvent based products and

cleaners– Particulates - saw-dust and dusts from

construction materials.

Page 7: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Why Are Hazardous Building Materials a Concern for the

Homeowner?

The average person spends more than 90% of their time indoors.

10

100

0

50

100

Outdoor Pollution Indoor Pollution

Air in new homes can be 10 times more polluted than outdoor air. (EPA)

Outdoors 10%

Indoors 90%

Page 8: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Why Are Hazardous Building Materials a Concern for the

Homeowner?

• Over 500 pollutants have been identified in building materials.

• Focus on tighter house construction for energy efficiency, means less ventilation of harmful vapors.

• Exposure to chemicals in the indoor environment can cause short and long term health problems: – Short term - Lung irritation – Long-term – Asthma and allergies.

Page 9: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Why are children more affected by hazardous products than adults?

Children breathe more air in proportion to their body weight than do adults. Thus, they breathe in more of the chemicals.

Children’s immune systems are not fully developed. They can not detoxify the hazardous materials as well as adults.Children also play close to the ground and have more hand-to mouth activity.

Page 10: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Toxics in Building Products

•Formaldehyde– probable human carcinogen when

inhaled or ingested

•Volatile Organic Compounds (VOCs)–Petroleum –base solvents

Page 11: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

What is Formaldehyde?

•It is a major ingredient used in industrial products as an adhesive, antiseptic*, germicide*, fungicide* and preservative.

•It is a strong-smelling, colorless gas that is chemically unstable.

•It will off-gas for a long time.

Page 12: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

What is off-gasing?• When solid materials evaporate at room

temperature.

• Chemically unstable materials slowly release contaminants, including some additives such as dyes, solvents, and softeners.

• Time – some emissions decrease slowly over a long-period, while others cure immediately.

• Humidity can slow down the curing process and increase length of time material off-gases.

• VOCs are absorbed by some materials and re-released into the air. Materials that absorb VOCs include; plaster, rugs, and fabric.

Page 13: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Formaldehyde: Off-Gassing

• Formaldehyde is combined in the factory with other chemicals (urea or phenol) to form resins.

• When formaldehyde products are exposed to increased temperature and humidity, they start a chemical reaction which breaks apart the resin, and releases the formaldehyde.

• Urea formaldehyde is more reactive to moisture and off-gasses more than phenol formaldehyde.

Page 14: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Formaldehyde: Products

• FLAKE AND WAFER BOARD

• PARTICLEBOARD• PLYWOOD PANELING• INTERIOR & EXTERIOR

GRADE PLYWOOD• FIBERGLASS & MINERAL

WOOL INSULATION• BINDERS• FORMICA• PLUMBING FIXTURES• COUNTER & TABLE TOPS• RESINS & OIL-BASED

PAINTS• PAINT & WOOD FINISHES

• MILDEW • WATERPROOFING• ANTI-STATIC AGENTS• PRESERVATIVES• ACRYLIC MATERIALS• WOOL FIBERS• NYLON FIBERS• RAYON• CARPET BACKING• FIBERBOARD• GLUES

Page 15: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Formaldehyde: Off-Gassing

Does the Formaldehyde ever go away?

• The off-gassing process can continue as long as the material is exposed to sufficient moisture levels.

• Gradually, the "off-gassing" declines, but never goes to zero.

• It always returns when it is exposed to elevated temperature and humidity.

Page 16: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Urea Formaldehyde: Health Hazards

Symptoms:• Eye, skin, &

respiratory irritation

• Wheezing & coughing

• Fatigue• Skin rash

Health Effects:• Sensitization• Allergies• Cancer • Asthma - high

levels may trigger an attack

Page 17: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Formaldehyde: Exposure Rates

• Indoor air commonly measures 0.03 - 2.5 PPM (higher rates exist where off-gassing occurs)

• Most people will first react to formaldehyde when the levels are in the range of 0.1 to 1.1 parts per million.

Page 18: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Formaldehyde: Health Affects Exposure Levels

• No effects 0 - 0.05 PPM

• Odor threshold 0.05 - 1.0 PPM

• Neurophysiological effects 0.05 - 1.05 PPM

• Eye irritation 0.05 - 2.0 PPM

• Upper respiratory irritation 0.10 - 25 PPM

• Lower airway and pulmonary effects 5.0 - 30 PPM

• Pulmonary edema, pneumonia 50 - 100 PPM

• Death 100 PPM

Page 19: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Formaldehyde: Product Emission Rates

            Product Formaldehyde Emissions (µg/m²/hr)

Fiber Glass Insulation (R-19) 32

Permanent press shirt (unwashed)

107

Permanent press shirts (washed once)

45

Permanent press draperies 215

½” Hardwood plywood 103

¾” Industrial Particleboard 170

¼” Prefinished plywood wall paneling

181

20 mil Cabinet decorative laminate

51

Floor finish (base coat, after 22 hours)

10,800

Page 20: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Off-Gassing: Volatile Organic Compounds (VOC)

Definition of VOCs

• Organic solvents that form vapors at room temperatures and easily evaporate into the air.

• VOCs can be toxic, harmful to the environment, flammable.

Sources of VOCs• Oil Based Paints• Plastics• Adhesives and Glues• Solvents• Carpet backing• Asphalt compounds• Plastic foams• Vinyl flooring

Page 21: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Health Impacts of SolventsReproductive and Developmental Toxicity

• Reproductive:– Infertility– Early miscarriage– Sperm toxicity

• Developmental: Toluene - “Fetal Solvent Syndrome”– Birth defects– Growth and developmental

delays, IQ deficits, hyperactivity, attention deficits

Page 22: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Health Impacts of SolventsNervous System

• Peripheral Nervous System (arms, legs)– Motor: weakness,

uncoordinated, fatigue, tremor– Sensory: numbness, tingling,

visual or hearing problems

• Central Nervous System (brain)– Thought Processes: memory

loss, confusion– Emotional State: nervousness,

irritableness, depression, apathy, mood swings

Page 23: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Overview: Green Building Goals

People• Minimize exposure to workers• Create healthy spaces for occupants• Use low maintenance, durable

materials

Environment• Use resources, water and energy

efficiently• Avoid limited, nonrenewable resources• Minimize environmental impacts

Page 24: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Design and Construction Opportunities to Create Healthy

Homes• Building materials are only one aspect

of healthy building • Landscaping• Foundation• Radon control• Building envelope• Air tight construction• Ventilation and

filtration • Heating and air

conditioning • Moisture control

Page 25: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

What is Toxics Use Reduction (TUR)?

TUR examines the use of chemicals in a system, process or product, and asks:

Why is this chemical being used?

Is there another method or product that does not require the use of a hazardous chemical?

If the activity truly requires chemical use, is there a safer chemical alternative?

If no alternatives exist, is the chemical being used safely and efficiently?

Page 26: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Hazardous Building Materialsand

Alternative Products

Page 27: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Building Materials with Hazardous Components

• Wood Products– Composite Wood Products – Pressure Treated Wood

• Flooring • Insulation• Concrete • Paints and Finishes• Caulk and Adhesives

Page 28: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Composite Wood Products: Plywood

• Hardwood Plywood – interior grade

– Is used indoors for cabinetry and paneling

– Uses urea-formaldehyde (UF) glue as an adhesive to bind a core layer to a facing of higher quality woods.

• Softwood Plywood - exterior grade

– Is used for exterior and interior structural applications - walls, roofs, subfloors (resilient, wood and laminate flooring and ceramic tile)

– Uses phenol formaldehyde resin as an adhesive, which is a water-resistant glue. It off-gasses at a slower rate than urea formaldehyde glues.

Conventional plywood is made of thin veneers of wood, bonded together with formaldehyde resins.

Page 29: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Composite Wood Products: Particleboard

• Is used for substrates in counter tops, shelving, stair treads, cabinets, door cores and manufactured home decking.

• It is used for subflooring under carpet, and laminate and resilient flooring.

• It is not as structurally sound as plywood and is vulnerable to moisture. Particleboard is smooth, knot-free, and hard. It has great impact resistance.

• Is made from wood chips bonded with urea formaldehyde resins under heat and pressure.

Page 30: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Composite Wood Products:Medium Density Fiberboard (MDF)

• Is used indoors for underlayment of countertops, cabinet walls and shelves, millwork, molding, door parts, paneling, and laminate flooring.

• It is often painted, laminated or sealed.

• Is made from wood chips and sawdust bonded with urea formaldehyde resins under heat and pressure.

• EPA notes that Medium density fiberboard contains a higher resin-to-wood ratio than any other UF pressed wood product and is generally recognized as being the highest formaldehyde-emitting pressed wood product.

Page 31: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Composite Wood Products:Oriented Strand Board (OSB)

• Is used for sheathing.

• Is made from wood chips bonded with phenol formaldehyde resins.

• OSB was introduced as an attempt to compete with plywood as a structural material while using a low quality resource.*

• OSB is three times as strong as particle boards of the same density and resin content.

Page 32: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Alternatives to Formaldehyde Wood Composite:

Bio-Based Wood Composites for Sub-Flooring

• Bio-based building materials are produced from plant fibers including: agricultural and forestry by-products such as soy, wheat, corn, kenaf, jute, sunflower seeds, hemp, bamboo, wood and paper waste.

• They can be used for for interior walls, ceilings, flooring, movable partitions, cabinets, furniture, shelving, etc.

Page 33: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Alternatives to Formaldehyde Wood Composite:

Bio-Based Wood Composites for Sub-Flooring

• They are ground up or heat/moisture treated, mixed with PMDI – a non-formaldehyde binder, and molded into building products.

• Although they are comparable in price to plywood, they are not available locally and transportation costs are not economical.

• They PMDI is made from benzene and contains diisocyanate which is a known occupational asthmagen. We have not found any studies that data confirming that confirm that MDI does not off-gas after it has cured. Green industry people feel that it is less hazardous than formaldehyde.

Page 34: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Hierarchy of Alternatives: Nontoxic Subflooring

Formaldehyde Free Plywood or Particleboard with PMDI binder

• It is not cost effective when shipping is included for affordable housing.

Fiber/Cementboard• This is a thin, high-density underlayment used in

situations where floor height and moisture is a concern. • It can be used with carpeting, laminate flooring,

resilient flooring and ceramic tile.

Cementboard• Cementboard is used with ceramic tile installations. • It is completely stable, even when wet, as it has a

concrete core and is faced with fiberglass. • Cementboard is more expensive than a plywood

installation.

Page 35: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

http://www.greenguide.com

formaldehyde free particleboard made from recycled money

formaldehyde-free

sustainable yield veneer panels

Formaldehyde- free laminated sheathing

Page 36: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Hierarchy of Alternatives: Less Toxic Subflooring

Exterior Grade Plywood with Phenol

Formaldehyde

• Has a water-resistant glue

• Air well

• Off-gasses at a slower rate than urea formaldehyde

• Seal with sealer product

Page 37: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Cabinets and Countertops: Problems

Uses Urea Formaldehyde wood products:

• Interior grade plywood with Formica

• Melamine or Formica with particleboard core

Extent of Exposure• On average, 15 sheets of

wood products are used to build cabinets.*

• Gases can build-up in cabinet and be released when opened.

Page 38: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Cabinets: Hierarchy of Alternatives

Alternative Cabinets in order of preference -

• Solid Wood, Metal, or Glass

• Veneers with plywood or MDF substrates with phenol formaldehyde or PMDI (both hard to find)

Alternative Cabinet Materials

• Factory applied finishes

• Water-based glues

Page 39: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Cabinets: Hierarchy of Alternatives

There is no HUD label for MDF board.

• Sealed Masonite has fewer volatile organic chemicals than particle board

• Look for low-emission plywood and particleboard products with the following seals;

• European E1 (higher standard than U.S. HUD)• U.S. HUD Label

Page 40: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Pressure Treated Woods: Issues

• Hazardous Types– CCA – Chromated Copper Arsenate– ACA – Ammoniacal Copper Arsenate

• Hazards - contain heavy metals including arsenic salts and chromium compounds which can leach out of wood on-site:– Toxic to humans and can affect target organs (liver,

kidneys, etc.).– Toxic to the environment and can build up in the soil.

• By Jan. 2004, EPA will not allow CCA products for any of these residential uses: – Play-structures, decks, picnic tables, etc.– Landscaping timbers, residential fencing, patios and

walkways/boardwalks.

Page 41: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Pressure Treated Woods: Alternatives

• Recycled plastic or plastic composite lumber (structural issues)**

– 100% recycled plastic– Wood fiber and recycled HDPE plastic– Fiberglass reinforced HDPE plastic

• FSC-Certified untreated, naturally rot-resistant, heartwood – caution, these can be naturally toxic (check local codes)**– Cypress, Elm, Western Cedar, IPE and Black Locust– Redwood and teak are mentioned but have other

environmental issues

• Where sill plate is 18” above grade, a metal termite shield can be used instead of a treated sill plate, (check local codes).*

Page 42: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Pressure Treated Woods: Alternatives

ACQ – Alkaline Copper QuatAlthough, ACQ is considered less

toxic than CCA and ACA, it is not nontoxic.

• It can be used in any application that requires pressure treated lumber. 

• Quaternary compounds are an asthmagen.

• The copper may be toxic to insects and aquatic life.*

Page 43: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Pressure Treated Woods: Alternatives

• Boron based woods – limited to aboveground, covered use– Any wood - engineered, sheathing, dimensional - can

be treated by this method. –  Eliminates need for termite treatments and

maintenance calls. –  Penetrates heartwood (CCA does not). – Non-toxic for handling, cutting, and disposal. – Does not need to be site-treated on cut ends (CCA

does). – Borate pressure-treated material adds about $2,500

to the costs of an average sized frame house.

• Metal – steel coated with baked enamel

Page 44: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Cement: Additives & Alternatives

These products are mostly an issue for people who have chemical sensitivities

Hazardous Materials Alternatives

Diesel or motor oil form release

• Vegetable oil• Mineral oil• Bio-Form

Solvent based sealers • Water based acrylic• Sodium Silicate

Page 45: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Cement:Additives & Alternatives

Hazardous Materials Alternatives

Admixtures: super plasticizer, water reducing agents, accelerants, retardants, etc.

Work in warm weather to obtain strengths and finishes without additives.

Aniline Coloring Agents • Mineral pigments such as Chromix Admixture, Lithochrome Color Hardener, or Davis Colors.

• Verify that the product is free of chromium and other heavy metals.

Page 46: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Siding Alternative: Fiber Cement Siding

• Fiber-cement composites offer an extremely durable, attractive and fire-proof alternative to wood.

• Can be textured to exhibit a wood-grain appearance or smooth in a stucco-type finish.

• Is available in panel, plank and shake styles.

• Some fiber-cement siding requires painting before use and some comes primed.

• Cutting the siding produces a great deal of dust. Shears, rather than saws, are best used to cut the material.

Page 47: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Materials Selection: Setting Priorities

• Short and long term exposures for workers and homeowners.

• Quantity – how much of the material will be exposed in the house?– Carpet and floor tile large areas

• Location – how close is a the material to the occupant or air handling systems?– Duct materials are in contact with the ventilation

system– Vinyl tile maybe out in the unventilated mudroom

• Maintenance Requirements – what products are necessary to maintain a material?– Insecticides to prevent insect infestations in wool rugs– Biocides to stop mold in carpets– Solvent based finishes on vinyl tile floors

Page 48: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Materials Selection: Setting Priorities

• Emissions and Durability – what gases and particulates will be emitted during installation and use?– Fiberglass particulates are released during installation and use

if not properly encapsulated.

– Soft plastics, carpets, and formaldehyde in products will break down.

– Plastics and solvent based-finishes emit VOCs.

– Metals, glass, ceramics and some woods do not off-gas and break-down over time.

• Duration of off-gassing – how long will the material off-gas?– Paint finishes cure in a short time under the proper conditions.

– Formaldehyde products and plastics off-gas for long periods of time.

Page 49: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Summary of Alternative Products

• Minimize use of formaldehyde based wood composite products. Use phenol formaldehyde or PMDI instead of urea formaldehyde as the binder.

• Avoid products with Polyvinyl chloride (PVC).

• Use water-based finishes and adhesives.

• Eliminate wall to wall carpet, or use low or non-emission carpet and carpet components.

Page 50: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Off-Gassing - Sealing in the Gasses

What is a sealer?

It is a type of coating that is typically used to coat a porous surface to prevent stains and water damage.

How can a sealer affect the formaldehyde?

Sealers and finishes trap the formaldehyde gasses, slowing or preventing the product off-gassing.

Page 51: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Off-Gassing - Sealing in the Gasses

What products can be used to seal a product?

• Finishes - water resistant finishes such as oil paints, vapor resistant varnishes, polyurethane, oil-based alkyd resin paint, and thick vinyl film. Remember these oil-based products contain solvents, and need to be cured as completely as possible, outside or in a well ventilated area.

• Veneers - non-permeable veneers such as metal and plastic.

Page 52: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Off-Gassing - Sealing in the Gasses

How do I seal a product?

• Off-gas a material as long as possible before applying.

• Apply multiple or thick layers, covering all surfaces and edges of the product, and it should remain intact.

• Apply in a well-ventilated area.

• Air out the freshly-painted item for several weeks.

Page 53: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Finishes – Problem TypesSolvents and Solvent-Based Paints,

Stains, Varnish

• Polyurethane and Lacquer

• Paints – enamel, marine

• Stain and wood sealers– Polyurethane and Lacquer - Melamines, epoxies, and

acrylic lacquers– Paints – enamel, marine– Stain and wood sealers used prior to staining– Solvents

Page 54: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Finishes: Problems with Paints, Stains, Varnishes

• Formaldehyde – a preservative

• Heavy Metals – Color tinted with pigments of

lead, cadmium, chromium VI and their oxides

– Waterproofing using mercury or mercury compounds

• Pesticides (biocides, mildewcides, fungicides) – extend shelf life– prevent mold growth

Page 55: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Finishes – Problems

• Most finishes off-gas.

• They can cure in six weeks, depending on temperature and humidity, unless improperly applied.

• Sensitive people can be effected up to a year after.

Page 56: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Alternative Finishes:Water-Based Polyurethane, Paints,

Varnishes, & Stains

• Low VOC - not to exceed 380 g/l

• No Formaldehyde

• No Heavy Metals

• No Aromatic Hydrocarbons in

excess of 10% by weight

• No Halogenated solvents

Page 57: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Alternative Finishes:Water-Based Low Biocide

• Eliminate biocide (pesticide) where possible.

• Where necessary, pesticides and preservatives added to water based paints should be in very low levels.

• Levels as low as 0.01 to 0.025% can be effective in preventing spoilage and less likely be adverse to health.

• Low biocide paints can spoil if not used quickly, and can be a medium for mold growth on a finished surface. May not be appropriate for applications in wet areas.

Page 58: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Carpeting

All components of carpet can be hazardous:

1. Carpet Fiber2. Carpet Backing 3. Carpet Padding4. Carpet Adhesives

5. Seam Sealants6. Carpet Treatments

Carpet can trap pollutants

Sources of Pollutants:– Vapors and

particulates in air, e.g, VOCs.

– Anything carried onto a carpet on shoes or wheels, e.g., pesticides.

Page 59: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Carpet Components: Hazardous Materials

Carpet Fiber• All Types:

– Trap dust, moisture, and pollutants to varying degrees depending on the depth of the pile, the carpet density, and the type of carpet

– Harbor dust mites– May be treated

• Wool – although it is considered the least toxic fiber, it:– May have a greater capacity than synthetics for

trapping VOCs, especially formaldehyde and nitrogen oxides.

– Can be dyed with a toxic or a non toxic dye.– Can get infested by moths.

• Synthetic– Fibers are traditionally made from petroleum.

– Fibers can off-gas.

Page 60: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Carpet Components: Hazardous Materials

Seam Sealants• High initial emissions • Hazardous Ingredients

– Toluene, or– 1,1,1-trichlororoethane, or– Other solvents

Carpet Padding• Volatile Organic Compounds• BHT (butylated

hydroxytoluene)• Formaldehyde• 4-PC (4-phenylcyclohexene)

Page 61: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Carpet Components: Hazardous Treatments

Carpet Treatments

• Pesticides – Antimicrobial, Fungicides and Insecticides

• Stain Resistance

• Antistatic

• Fire Resistant

Page 62: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Carpet Components: Off-Gassing

After 72 hours to 4 or 5 weeks (estimates vary), Some pollutant levels will be reduced.

Off-gassing will decrease with time,

Page 63: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Hierarchy of Carpet Alternatives

Starting with the Preferred!

1. No carpet. Recommended by Asthma

organizations!

2. Natural Fiber Area Rug:1. Including Wool, Seagrass, Sisal,

Mountain Grass (hemp), and wool with no latex backing, carpet pad, or treatments.

2. These materials will trap dust, pollutants, allergens and potentially moisture. May not be appropriate for all applications.

3. Synthetic Area Rug• With no latex backing,

carpet pad, or treatments.

Page 64: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Hierarchy of Carpet Alternatives

4. Natural fiber wall-to-wall rug:

5. Acrylic wall-to-wall rug:Both should have:

• a natural backing• non-toxic pad, and no

treatments.

Can use:• peel and stick carpet tiles,

or • carpet that can be fastened

down with either:– double sided tape, – a hook and loop fastener,

or – tacks.

Page 65: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Carpet: Carpet and Rug InstituteTesting and Seal Program - Carpet

• CRI tests each carpet line four times a year for four categories of emissions. Criteria based on a maximum emission factor measured in mg/m² ∙hr as follows:

– Total VOC 0.5 – 4-Phenylcyclohexene) 0.05– 0.05 Styrene 0.4– Formaldehyde 0.05 (to prove that none

is used)– ---------------------------------------------------------------------------------

-----------• Criteria for the adhesive testing program are based on a

maximum emission factor as follows:– Total VOCs 10.00 – Formaldehyde .05 – Ethyl-1-Hexanol 3.00

Page 66: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?
Page 67: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Flooring and Flooring Components: Types of Hazardous Materials

• Flooring Materials– Vinyl and Vinyl Composition Tile (VCT)– Wood Laminates – adhesives which off-gas

• Flooring Components– Flooring Adhesives– Finishes

Page 68: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Greener Backing System

• 100% PVC-free recyclable backing system with recycled content, made from thermoplastic polyolefin compound with a fiberglass reinforcing layerwhere:High performance environments requiring modular flooring why:• thermoplastic alternative to PVC • Dimensional stability of PVC with 50% less weight• Superior de lamination and edge ravel strength to PVC• Lower BOC's and smoke density test results than PVC• 100% recyclable with recycled content and lower embodied energy than PVChow:• Full spread Shaw Sureset N5000 releasable adhesive• Ecoworx ES, Shaw's environmental self-adhesive system

Page 69: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Flooring: Vinyl TilesHealth Effects

• Organotins which can cause*:

– Immunotoxicity

– Reproductive and developmental damage in animals

– Nervous and respiratory problems in humans.

• VOCs result from both installation and use of tiles:– the petroleum base of the tiles, dyes, and

contaminates.

– the adhesives to install tiles. Less emissions from adhesive backed tiles.

Page 70: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Flooring: Vinyl Tiles

Health Effects• Plasticizers - several types of phthalates are

used in PVC tiles:

– Since the plasticizers do not bind to the PVC chemically, they evaporate into the air, attach to dust, and leach into wash water.

– Although it is not currently possible to test the amount of placticizer emissions into the air, they are suspected to contribute to sensitization in asthma, are known to affect the reproductive system, and are a possible carcinogen. *

– They are being removed from baby products.

Page 71: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Flooring: Vinyl Tiles Pollutants

When there is a fire,

the smoke could kill you

before the fire does

Page 72: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Flooring: Vinyl TilesMaintenance

• Vinyl is porous and requires a floor finish to fill pores.

• Can be coated with; melamine, water based acrylic or polyurethane as a finish to create a “no wax” finish.

• Otherwise, maintenance is high, and maintenance products made of petroleum based finish and solvent based stripper products are hazardous.

Page 73: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Flooring Alternatives: Linoleum

• Materials• Linoleum - Linseed oil from the flax

plant, rosin from pine trees, cork from tree bark, limestone, wood flour, pigment, and burlap/jute backing.

• Adhesive – styrene butadiene rubber (SBR), water based.

• Finish – comes in water and oil based finishes.

• Concerns• Occupant - may have an initial odor

that people cannot tolerate. Also, ongoing oxidation of materials releases aldehydes, which some people may be sensitive to.

• Worker – respiratory exposure from heat weldable seams which require thermal plastic melt glue.

Page 74: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Flooring Alternatives:

Linoleum Versus Vinyl

• Features and Durability• More durable than vinyl, not as brittle as vinyl.

As it continues to oxidize and form new chemical links, it becomes more durable.

• Higher compressive strength, 750 PSI versus Vinyl 75 PSI.

• Less maintenance, does not need waxing.• The oxidation process makes the material

inhospitable to mold.

• Pricing • $4 - $6 per sq ft versus Vinyl at $1.75 sq ft• Lower lifecycle cost, lasts 40 – 50 years

Page 75: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Flooring Alternatives: Tile

Materials• Tile• Adhesive• Grout• Grout Sealer

Features and Durability

Price• Pricing starts at $2 -$10 sq. ft• Increased costs for substructure to support

tile

Concerns• Additives in grout

Page 76: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Flooring: Cost Comparison Chart

Vinyl $ .50 – 4.50

Linoleum $ 4.00 – 6.00

Ceramic Tile $ 2.00 – 8.00

Pre-finished & Unfinished Solid Wood

$ 2.50 – 6.00

Pre-finished Engineered Wood $ 3.00 – 8.50

Laminate Flooring $ 2.00 – 5.00

Cork $ 6.80 – 9.75

Bamboo $ 3.00 – 7.00

Carpet $ .50 – 5.00

Material Cost Per Square Foot – Uninstalled

Should also consider lifecycle cost!

Page 77: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Solvent Based Adhesives: Issues and Alternatives

Hazardous Conditions• Exposure during application• Exposure in the home,

when adhesives that fail to cure (due to moisture) continue to off-gas

Alternative Products• Low VOCs• Water-based• No formaldehyde

Page 78: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Adhesives: Product Alternatives

• Epoxy adhesives are relatively nontoxic when fully cured.

• White glue (polyvinyl acetate) is safe when dry.

• Yellow carpenter’s glue (yellow aphilatic resin) is safe when dry.

• Cement mortar for tiles.

• Water-based contact cement.

• 100% Pure Silicone Caulk – aquarium grade without additives for subfloors

Page 79: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Caulk

• Problems*– Aromatic and Halogenated solvents– Fibrous talc and asbestos– Formaldehyde– Heavy metals – lead, mercury, cadmium,

barium– VOCs from petroleum base

• Alternative products– Less than 5% VOC by weight*– Reduce or eliminate ingredients listed above.

Page 80: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Purchasing Issues: Discussion

• Product Availability– Who carries it – stock item???– Special order issues – distribution time

• Cost– Shipping– Minimum orders

• Durability– Liability– Warranty

Page 81: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Cost Issues Related to Building Materials

Size of Initial Investment

•Additional structural work

•Design costs•Material costs•Shipping costs

Additional Labor Costs•Training• Installation time•Possible specialized

installer•Special equipment

Length of Payback•Less of an issue for

developer who is not also owner

• Issue for homeowner

Durability & Replacement Cycle

•How long lasting •How often replaced

Maintenance•Schedule•Labor involved•Costs and hazards of

products

Page 82: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Product Suppliers: Discussion

• Specifying Products in Bid Specs

• Local – standard products– Water-based finishes and adhesives– Copper plumbing– Linoleum– Hardwood flooring– Phenol formaldehyde plywood and OSB– Wool and some natural fiber carpeting

• Special order– Bio-based or PMDI wood composite products

for subfloors, cabinets, shelving, etc.– Natural material flooring – sisal, jute, etc.

Page 83: Lively Somerville Promoting Green Building and Renovation Green Building elements and Somervilles focus on toxic materials. What is toxics use reduction?

Some Resources

• Toxics Use Reduction Institute• Asthma Regional Council• EPA’s IAQ Website• Habitat for Humanity Green Building Initiative• Green Built Standards• Forest Stewardship Council• Healthy Building Network• Environmental Building News• Sustainable Building Sourcebook• BEES• LEEDS • INFORM• Environmental Preferable Products Listserv• Carpet and Rug Institute Certification Program