Material Safety Data Sheet - CHLOR RIDchlor-rid.com/sds/links/SDS_eCHLOR_TEST_Nov16.pdf · 7 IATA UN-No 3082 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

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Safety Data Sheet

Note: Read and understand Safety Data Sheet before handling or disposing of product.

1. CHEMICAL PRODUCT AND COMPANY INFORMATION Material Identity: Chloride Reagent (1 milliliter liquid in vials with caps) Synonym: UN No. 3082 Product Use: Laboratory/test kit reagent. Laboratory chemical. Industrial use only. Manufacturer: CHLOR RID International, Inc. 3356 N. San Marcos Place #107 Chandler AZ 85225 Emergency Number: 800-422-3217, 480-821-0039 Revised: 06/2016

2. HAZARD IDENTIFICATION Signal Word: WARNING

Hazard Statement: See also Section 4.

Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1 Respiratory sensitization Category 1 Skin sensitization Category 1 Carcinogenicity Category 1B

EMERGENCY OVERVIEW

Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling In case of inadequate ventilation wear respiratory protection Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Precautionary Statements - Response Immediately call a POISON CENTER or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse If skin irritation or rash occurs: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a POISON CENTER or doctor/physician

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IF SWALLOWED: Rinse mouth. DO NOT induce vomiting

Precautionary Statements - Storage Store locked up

Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant

x Very toxic to aquatic life with long lasting effects

x Very toxic to aquatic life

Read the entire SDS for more thorough evaluation of precautions required.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical name CAS-No Weight % Potassium persulfate 7727-21-1 1

Silver nitrate 7761-88-8 1 Water 7732-18-5 to 100%

4. FIRST AID MEASURES

FIRST AID MEASURES

Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Consult a physician.

Skin contact Wash off immediately with plenty of water for at least 15 minutes. If irritation

develops or persists, consult physician.

Inhalation Move to fresh air.

Ingestion Do NOT induce vomiting. Drink 1 or 2 glasses of water. Call a physician immediately. Clean mouth with water and afterwards drink plenty of water.

5. FIRE-FIGHTING MEASURES/ EXPLOSIVE HAZARDS

Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. CO 2, dry chemical, dry sand, alcohol-resistant foam.

Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

National Fire Protection Hazard Ratings- NFPA(R)

1 Health Hazard- 0 Flammability- 1 Reactivity -

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6. ACCIDENTAL RELEASE MEASURE

Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with skin, eyes, and clothing. Wear protective gloves/clothing and eye/face protection.

Environmental precautions See Section 12 for additional Ecological Information.

Methods and material for containment and cleaning up

Methods for containment Absorb/Cover spill with sodium bicarbonate or sodium carbonate to neutralize, then place

in a chemical waste container for later disposal.

Methods for cleaning up Sweep up and shovel into suitable containers for disposal. Procedure in case of accidental release, breakage or leakage: INFOTRAC 800-535-5053 Comply with local, state, and federal regulations for waste disposal.

7. HANDLING AND STORAGE

Precautions for safe handling

Handling Handle in accordance with good industrial hygiene and safety practice. Wear personal protective equipment. Avoid contact with skin, eyes and clothing.

Conditions for safe storage, including any incompatibilities

Storage Keep tightly closed in a dry and cool place.

Incompatible Products Strong bases.

8. EXPOSURE CONTROLS/ PERSONAL PROTECTION

Control parameters

Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Potassium persulfate

7727-21-1 TWA: 0.1 mg/m3 - None Established

Silver nitrate 7761-88-8

TWA: 0.01 mg/m3 TWA: 0.01 mg/m3 IDLH: 10 mg/m3 TWA: 0.01 mg/m3

Water 7732-18-5 - - None Established

Engineering Controls: Showers, eye wash stations, ventilation systems.

Individual protection measures, such as personal protective equipment

Eye/face Protection Safety glasses with side-shields. If splashes are likely to occur, wear:. Goggles.

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Skin and body protection Gloves & Lab Coat.

Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Hygiene Measures Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties Physical state liquid Appearance Clear, colorless Odor None Property Values Remarks • Method pH 1.5 Melting point/freezing point No information available Boiling Point/Range No information available Flash point No information available Evaporation rate Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density No information available Specific gravity No information available Water solubility No information available Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Explosive properties No information available Oxidizing properties No information available

Other information

Softening point No information available Molecular weight No information available VOC Content No information available Density No information available Bulk density No information available

10. STABILITY AND REACTIVITY: Stability Stable under recommended storage conditions.

Hazardous Reactions None under normal processing.

Hazardous polymerization Hazardous polymerization does not occur.

Conditions to avoid Exposure to air or moisture over prolonged periods. Extremes of temperature and direct sunlight.

Incompatible materials Strong bases.

Hazardous decomposition products Sulfur oxides (SOx). Do not use inconsistent with intended use. Keep out of reach of children and untrained users.

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11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Component Information Chemical name LD50 Oral LD50 Dermal LC50 Inhalation Potassium persulfate 7727-21-1

= 802 mg/kg ( Rat ) > 10000 mg/kg ( Rabbit ) None Established

Silver nitrate 7761-88-8 = 1173 mg/kg ( Rat ) None Established None Established

Water 7732-18-5 None Established None Established None Established

Information on toxicological effects Chemical name ACGIH IARC NTP OSHA Potassium persulfate 7727-21-1

- None Established None Established -


- Group 2A None Established X

Water 7732-18-5 - None Established None Established -

12. ECOLOGICAL INFORMATION

Ecotoxicity Unknown Aquatic Toxicity 0.7% of the mixture consists of components(s) of unknown hazards to the aquatic environment

Chemical name Toxicity to Algae Toxicity to Fish Daphnia Magna (Water Flea) Potassium persulfate

7727-21-1 None Established None Established None Established


None Established 0.001339 - 0.001637: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 0.00181 - 0.00214: 96 h Pimephales promelas mg/L LC50 static 0.00452 - 0.00638:

96 h Pimephales promelas mg/L LC50 flow-through 0.00512 -

0.00787: 96 h Poecilia reticulata mg/L LC50 semi-static 0.0064 -

0.0106: 96 h Pimephales promelas mg/L LC50 semi-static

0.00839 - 0.1802: 96 h Oncorhynchus mykiss mg/L LC50 static 0.009 - 0.02: 96 h Lepomis

macrochirus mg/L LC50 flow-through 0.0242 - 0.0484: 96

h Lepomis macrochirus mg/L LC50 semi-static 0.05 - 0.07: 96 h Lepomis macrochirus mg/L LC50

static 0.0027: 96 h Cyprinus carpio mg/L LC50 semi-static 0.0075: 96 h Oncorhynchus

mykiss mg/L LC50 semi-static 0.009: 96 h Pimephales promelas

mg/L LC50

0.0008 - 0.001: 48 h Daphnia magna mg/L EC50 Flow through 0.0008 - 0.0011: 48 h Daphnia

magna mg/L EC50 Static 0.0006: 48 h Daphnia magna mg/L EC50

Water 7732-18-5

None Established None Established None Established

Persistence and degradability No information available.

Bioaccumulation/Accumulation No information available.

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Chemical name Log Pow

Potassium persulfate 7727-21-1

None Established


None Established

Water 7732-18-5

None Established

13. DISPOSAL INFORMATION

Waste Disposal Method Should not be released into the environment. Dispose of in accordance with local regulations.

Contaminated packaging Do not re-use empty containers.

Chemical name RCRA RCRA - Basis for

Listing RCRA - D Series Wastes

RCRA - U Series Wastes


None Established - None Established None Established


(hazardous constituent - no waste number)

- None Established None Established

Water 7732-18-5 None Established - None Established None Established

Chemical name RCRA - Halogenated Organic Compounds

RCRA - P Series Wastes

RCRA - F Series Wastes

RCRA - K Series Wastes


None Established None Established None Established None Established



Water 7732-18-5 None Established None Established None Established None Established

Chemical name California Hazardous Waste Status


-


-

Water 7732-18-5

-

Comply with local, state and federal regulations. If permissible, flush to drain. Otherwise drain to effluent remediation facility. Neutralize with lime or soda ash, if required, then flush with water. Caution: Misuse of empty containers can be hazardous. Empty containers can be hazardous is used to store, toxic, flammable, or reactive materials. Cutting or welding of empty containers might cause fire, or toxic fumes from residues. Do not pressurize or expose to open flame or heat. Keep containers closed and drum bungs in place.

14. TRANSPORT INFORMATION

DOT UN-No 3082 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Silver

Nitrate solution) Hazard Class 9 Packing group III

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IATA UN-No 3082 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Silver


IMDG/IMO

UN-No 3082 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Silver


15. REGULATORY INFORMATION

International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies

Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

U.S. Federal Regulations

SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical name SARA 313 - Threshold Values %


None Established


1.0

Water 7732-18-5

None Established

SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard No Sudden release of pressure hazard No Reactive Hazard No

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Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

Chemical name CWA - Reportable

Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous

Substances Potassium persulfate

7727-21-1 None Established None Established None Established None Established


1 lb X None Established X

Water 7732-18-5


CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Chemical name Hazardous Substances RQs CERCLA/SARA RQ RQ


- None Established -


1 lb None Established RQ 1 lb final RQ RQ 0.454 kg final RQ

Water 7732-18-5

- None Established -

U.S. State Regulations

California Proposition 65 This product does not contain any Proposition 65 chemicals

Chemical name California Prop. 65


None Established


None Established

Water 7732-18-5

None Established

U.S. State Right-to-Know Regulations

Chemical name New Jersey Massachusetts Pennsylvania Potassium persulfate

7727-21-1 X X X


X X X

Water 7732-18-5

None Established None Established X

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16. OTHER INFORMATION

HMIS Health hazard 1 Flammability 0 Hazards N/A It is the responsibility of the buyer to maintain a safe workplace for the user. Personal protective rating to be supplied by user depending on use condition. The user should consider the health safety information contained herein as a guide and should take these precautions required in an individual operation to instruct employees and develop protective work procedures for a safe environment. The information contained herein is, to the best of our knowledge, accurate based on data available at the time of publication. The company accepts no liability for damages incurred. Nothing herein is to be construed as a warranty, expressed or implied. It is the responsibility of the user to determine the applicability of the information herein and suitability for its own particular purpose.

CHLOR RID International Inc

3356 N. San Marcos Place #107

Chandler, AZ 85225 USA

800-422-3217 480-821-0039 480-821-0364 fax

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Safety Data Sheet

Note: Read and understand Safety Data Sheet before handling or disposing of product.

1. CHEMICAL PRODUCT AND COMPANY INFORMATION Material Identity: CHLOR*EXTRACT™ Synonym: Surface Extraction Solution

Relevant Identified Uses: Surface test extraction solution. No other uses recommended for this product. Manufacturer: CHLOR RID International, Inc. 3356 N. San Marcos Place #107 Chandler, AZ USA 85225 Contact: [email protected] Emergency Number: 800-422-3217, +1-480-821-0039 Revised: 11/2016

2. HAZARD IDENTIFICATION Physical Hazards: None as defined by GHS Hazard Classification. GHS Label:

Signal Word: WARNING Product classification: Mixture

Hazard Classification: Effects of overexposure Eye Irritant 2: H319; Causes irritation. Skin Irritant 2: H315; May cause irritation. Ingestion: May cause gastrointestinal irritation. Inhalation: None currently known

Precautionary Statements: P102: Keep out of reach of children and untrained users. P103: Read directions before use.

P280: Wear protective gloves and eye/face protection. P264: Wash after handling the product.

P270: Do not eat or drink when using this product. Do not mix with other products. Environmental Hazards: None known. All components are readily biodegradable. (Section 12)

Other Hazards: Does not meet the criteria for PBT (Persistent, Bioaccumulative, & Toxic) or vPvB (very Persistent & very Bioaccumulative).

3. COMPOSITION / INFORMATION ON INGREDIENTS COMPOSITION: Ingredients: Range in % Proprietary Chemical Mixture: <2 Other Non-Hazardous Materials: >98 Specific chemical composition has been withheld as a trade secret. See 29 CFR 1910.1200 (i)(1)(iii)

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4. FIRST AID MEASURES

Eyes: P305+P351: Flush with plenty of water, occasionally lifting upper and lower eyelids. P338:

Remove contact lenses. P313: Contact physician if irritation persists.

Skin: P303+P353: Flush effected area with plenty of water. P362: wash contaminated clothing before reuse.

Ingestion: P301+P330+P331: If ingested, wash out mouth with plenty of water. Do not induce vomiting

unless directed by medical advice. P313: Get medical attention. Do not give anything by mouth to an unconscious person.

Inhalation: P304+P340: Remove victim to fresh air and keep at rest in position comfortable for breathing. P313: Get medical attention if symptoms occur.

5. FIRE-FIGHTING MEASURES

Flash Point: Does not flash

Extinguishing Media: Any appropriate media for local circumstances and surrounding media, generally water. Flammability Limits: N/A Explosive Hazards: None Known

Firefighting Instructions: Wear self-contained breathing apparatus (SCBA) and protective suit.

Unusual Fire & Explosive Hazards: Prolonged contact with certain metals may generate minor amounts of hydrogen

gas which can be diminished by quenching with large amounts of water. Hazardous By-Products: None Known National Fire Protection Hazard Ratings- NFPA(R)

1 Health Hazard- Slight 0 Flammability- None 0 Reactivity - Minimal

6. ACCIDENTAL RELEASE MEASURES

Procedure in case of accidental release, breakage or leakage: INFOTRAC 800-535-5053 Personal precautions: Wear appropriate protective clothing and/or equipment during cleanup. (Section 8)

Environmental precautions and cleanup methods: Dilute with water, or isolate material and neutralize with lime or soda ash, or a suitable non-combustible absorbent (sand, earth, vermiculite, diatomaceous earth). Remove contaminated absorbent. Flush spill area with water.

Reference to other sections: Section 8.

Comply with local, state, and federal and international regulations for waste disposal. If permissible, flush to industrial drain.

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7. HANDLING AND STORAGE

Precautions for safe handling: Minimize spillage. Use appropriate personal protective equipment (Section 8). Avoid contact with eyes, skin, and clothing. P264: Workers should wash hands before eating, drinking, or smoking.

Conditions for safe storage, including incompatibilities: P234: Keep in the original container or suitable alternative. P233: Keep containers sealed. Keep containers in a well-ventilated area. Keep container away from direct sunlight. Containers must be resealed after use and kept upright. Do not store in unlabeled containers.

Incompatible materials: Keep away from strong alkaline materials.

Storage temperatures: In accordance with local regulations. P233: Keep lids tightly closed and away from heat. Store above 32F (0°C).

Specific end uses: See relevant identified use in Section 1. Request Directions for use and technical data.

8. EXPOSURE CONTROLS/ PERSONAL PROTECTION

Exposure & engineering controls: S51: Use in ventilated areas.

Protective Equipment: Eye/Face Protection: P280: Wear safety glasses with side shields. Skin Protection: Personal protective equipment should be selected based on the task being

performed and risks involved and approved by a specialist before use. Respiratory Protection: Properly fitted air purifying or air fed respirator complying with an approved

standard if risk assessment indicates this is necessary. Respirator should be selected based on known or anticipated exposure level, the hazards of the product and the safe working limits of the respirator.

Hand Protection: Material: Rubber or latex gloves.

Protective Clothing Pictograms:

Exposure Limit for Total Product: 20 mg/m3 TWA.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Clear liquid Odor: Mildly of burnt sugar Odor Threshold: None detected Oxidizing Properties: Product is not oxidizing Boiling Point: 100 C (approximately as water) Specific Gravity: 1.01(+/- 0.1) pH: 3.5 (+/- 0.3) Vapor Pressure: Vapor is water Vapor Density: Vapor is water VOC Content: Non-detectable Flash Point: Non-flammable. Upper/Lower Flammability: Non-flammable

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Solubility: In water, complete miscible Partial coefficient: For n-octanol/water, no test data available. Auto-Ignition Temperature: Non-flammable Viscosity: 0.98 cP Explosive properties: None

10. STABILITY AND REACTIVITY Reactivity: Product is stable under normal conditions of use and storage. Chemical stability: Hazardous decomposition will not occur under normal conditions of use and storage at normal ambient temperatures. Conditions to avoid: Do not mix with other chemicals. Hazardous polymerization: Will not occur Hazardous decomposition products: Does not decompose when used as intended. Storage: Store out of direct contact with sunlight. Do not use inconsistent with relevant identified and intended use.

11. TOXICOLOGICAL INFORMATION No toxicology data is available for this product. Carcinogenicity: None of the components present in concentrations equal to or greater than 0.1% are listed as carcinogenic: OSHA IARC NTP OTHER NONE ------ ------ ----- --------- --X--

12. ECOLOGICAL INFORMATION

Toxicity: No information available. Persistence and Degradability: No data available. Environmental effects: Readily biodegradable. No phosphates. Low or non-detectable bioaccumulation. Ecotoxicological information: No information available. Bioaccumalative potential: No information available. Mobility in soil: No data available. Results of PBT and vPvB assessment: Does not meet the criteria for PBT (Persistent, Bioaccumulative, & Toxic) or vPvB (very Persistent and very Bioaccumulative)

Other adverse effects: None known.

13. DISPOSAL INFORMATION

P501: Comply with local, state, federal and international regulations. If permissible, flush to drain. Otherwise drain to effluent remediation facility. Neutralize with lime or soda ash, if required, then flush with water. Caution: Misuse of empty containers can be hazardous. Empty containers should not be reused. Do not expose to open flame or heat. Keep containers closed with caps available.

Page 5 of 5

14. TRANSPORT INFORMATION Shipping Classification: Specify as: Item No. 48580 – Sub 3 – Class 55 UN Number: Not listed, neither for this mixture nor for substances therein. UN Regulatory Information: DOT Classification: Not regulated. TDG Classification: Not regulated. IMDG Class: Not regulated. IATA-DGR Class: Not regulated

15. REGULATORY INFORMATION

Reportable Quantity (RQ): No calculable reportable quantity for this product. CERCLA (Superfund) reportable quantity: None TSCA Inventory Status: This product is not listed and is exempt from the TSCA Chemical Substances Inventory. SARA Title III (Section 302/304): Nonhazardous. SARA 313: No ingredients listed. Product does not contain nor is manufactured with ozone depleting substances. CA Prop 675: No known substances known to the State of California to cause cancer, birth defect, or reproductive harm. Canada: WHIMIS Classification D2B.

16. OTHER INFORMATION Supplemental classification information not included in Section 3, or other Sections: S 24 Avoid contact with skin S 25 Avoid contact with eyes In accordance with Regulation (EC) 1907/2006 (REACH), and with changes made to comply with Regulation (EU) 453/2010, Annex II. It is the responsibility of the buyer to maintain a safe workplace for the user. Personal protective rating to be supplied by user depending on use condition. The user should consider the health safety information contained herein as a guide and should take these precautions required in an individual operation to instruct employees and develop protective work procedures for a safe environment.

The information contained herein is, to the best of our knowledge, accurate based on data available at the time of publication. The company accepts no liability for damages incurred.

Nothing herein is to be construed as a warranty, expressed or implied. It is the responsibility of the user to determine the applicability of the information herein and suitability for its own particular purpose.

CHLOR RID International Inc

3356 N. San Marcos Place #107

Chandler, AZ 85225 USA

800-422-3217 480-821-0039 480-821-0364 fax

T x

Documents

Material Safety Data Sheet - CHLOR RIDchlor-rid.com/sds/links/SDS_eCHLOR_TEST_Nov16.pdf · 7 IATA UN-No 3082 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S