MATERIAL SAFETY DATA SHEET RODEX RAT & … All.pdfWash contaminated skin with plenty of soap and water. Launder contaminated clothing before re –use. Eyes: First, rinse with plenty

MATERIAL SAFETY DATA SHEET

RODEX RAT & MOUSE PELLETS

DATE ISSUED: 23 October 2002 PAGE 1 OF 4 PREPARED BY: M.C. SAAIMAN

UPDATED: 23 October 2002

COMPANY DETAILS:

Name: Small Pack Solutions (PTY)LTD Address: No. 18 Aschenberg Street Chamdor Krugersdorp Tel. Nr.: (011) 769 1300 Fax Nr.: (011) 762 5712 Emergency Tel Nr.: 083 326 3581 / 082 823 4473 OR 0800172743

1. PRODUCT IDENTIFICATION:

Trade Name: Rodex Rat & Mouse Pellets. Chemical Family: Coumarin anticoagulant Chemical Name: 3-[3-(4’-bromobiphenyl-4-yl)-1,2,3,4-tetrahydro-1-naphthyl]-4-hydroxycoumarin

(Active Ingredient) Molecular Formula: C31 H23 BrNO3 (Active ingredient) UN Nr.: 3027 C.A.S. Nr.: [56073-10-0] (Active Ingredient) Description of product: A HIGHLY ACTIVE anticoagulant grain bait for the control of the Norway rat, Roof

rat, the House mouse and Gerbilles

2. COMPOSITION:

Hazardous Components: Brodifacoum (Anticoagulant) 0.05 g /kg

3. PHYSICAL AND CHEMICAL CHARACTERISTICS:

Appearance: Blue pellets Odour: Vanillin odour



4. FIRE AND EXPLOSION HAZARD:

Flash Point: N/A Flammability: N/A Auto ignition Temperature: N/A Decomposition Temperature: Not available Acute Hazards: Unlikely in normal use. Special fire fighting procedures: If a leak or spill has not ignited, use water spray to disperse the

vapours and to protect personnel attempting to stop leak. Water spray may be used to flush spills away from exposures. Prevent run –off from fire control or dilution from entering streams, sewers, or drinking water supply.

Special protective equipment: Do not breathe fumes. For fires in enclosed areas, fire fighters must use self –contained breathing apparatus, as well as full protective gear.

__________________________________________________________________________________________

5. REACTIVITY DATA:

Stability: Stable Conditions to avoid: Heat, sparks, flame and build up of static electricity, spillage onto

roadways, etc.

6. WARNINGS:

Handle with care. Prevent access to bait by children, uninformed persons and domestic animals. Store under lock and key, away from food and feedstuffs. Poisonous if swallowed and upon prolonged contact with the skin. Toxic to fish and wildlife.

7. HEALTH HAZARD DATA: (Acute Hazards & Symptoms)

Ingestion: Bleeding from the gums and nose, bleeding under the skin, pallor, haemorrhage into and around elbow and knee joints. Blood in urine and faeces.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Inhalation: Avoid inhalation of dust. Use only in well –ventilated areas, in case of insufficient ventilation, wear suitable respiratory equipment.

Skin: Wear protective clothing, as well as protective gloves. Launder contaminated clothing before re –use. Avoid skin contact. Keep working clothes separately and do not take home.

Good personal hygiene practices should always be followed. Eyes: Avoid contact with eyes. Wear eye /face protection. Ingestion: Keep away from food and

feedstuffs. Do not eat, drink or smoke whilst handling this product. Wash hands and face before eating and drinking.



9. FIRST AID MEASURES:

Inhalation: Remove patient from further exposure to fresh air. Skin: Remove contaminated clothing and shoes. Wash contaminated skin with plenty of soap and water. Launder contaminated clothing before re –use. Eyes: First, rinse with plenty of water for at least 15 minutes. Seek medical attention if irritation persists. Ingestion: If swallowed induce vomiting by tickling the back part of the throat. Repeat until vomit is

clear. Take patient IMMEDIATELY to nearest physician. NOTE TO PHYSICIAN: Intravenous Vitamin K1, 10 – 20 mg depending on prothrombin time. In sever cases small

transfusions of fresh blood.

10. ACCIDENTAL RELEASE MEASURES:

Notification procedures: Report spills as required to appropriate authorities. Procedures if material is released or spilled: Absorb on fire retardant treated sawdust, diatomaceous

earth, sand, peat sorb, etc. Shovel in and dispose of at an appropriate waste disposal facility, in accordance with current applicable laws and regulations, and product characteristics at time of disposal.

Environmental Precautions: Prevent spills from entering storm sewers or drains and contact with soil.

11. HANDLING AND STORAGE:

Suitable Material: 200 l Steel drums, Plastic drums and bottles. Handling /storage precaution: Avoid prolonged repeated skin contact. Do not contaminate water,

food or feed by storage or disposal. Store in a secure, dry, well –ventilated separate room, building or covered area. Keep away from sources of ignition and protect from exposure to fire and heat separate from incompatible materials. Do not allow entering public sewers and water sources. If contamination of drainage systems or water sources is unavoidable, inform the appropriate authorities immediately.

12. DISPOSAL CONSIDERATION:

Waste disposal: Destroy empty container by perforation or flattening, and do not use for any other purpose. Product should be utilized completely to avoid disposal. If not possible, dispose of at an appropriate waste disposal facility, in accordance with current applicable laws and regulations.



13. TRANSPORTATION DATA:

Hazardous Description Label: Coumarin anticoagulant, toxic. Keep away from foodstuff. Do not transport with food and feedstuffs. UN Hazard Class: 6.1 UN Packing Group: IV IMO: Label(s): Poison

ICAO/IATA: Label(s): Poison

14. ENVIRONMENTAL DATA:

The product is toxic to bees and aquatic organisms. Avoid release into environment in circumstances different to normal use. __________________________________________________________________________________

15. OTHER INFORMATION:

HARMFUL OR FATAL IF SWALLOWED. HARMFUL IF INHALED. MAY CAUSE SKIN IRRITATION ON PROLONGED, REPEATED SKIN CONTACT. AVOID BREATHING OF DUST. KEEP AWAY FROM HEAT OR FLAME. KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. AVOID WEARING OF CONTAMINATED CLOTHING. FIRST AID: IF SWALLOWED CALL A DOCTOR IMMEDIATELY. NEVER GIVE ANYTHING BY NOUTH TO AN UNCONSCIOUS PERSON. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION AND CALL A DOCTOR. IN CASE OF SKIN CONTACT, WASH CONTAMINATED AREAS WITH SOAP AND WATER. REMOVE CONTAMINAED CLOTHING. WASH BEFORE RE –USE. ATTENTION: EMPTY CONTAINERS MAY CONTAIN PRODUCT RESIDUE. ALL LABEL WARNINGS AND PRECAUTIONS MUST BE OBSERVED UNTIL THE CONTAINER HAS BEEN THOROUGHLY CLEANED OR DESTROYED. REFER TO PRODUCT MATERIAL SAFETY DATA SHEET FOR FURTHER SAFETY AND HANDLING INFORMATION.

DATE ISSUED: 30 June 2005 PAGE 1 of 4 PREPARED BY: SM Peters

UPDATED: 30 June 2005


RODEX BOOST

COMPANY DETAILS:

Name: Avima (Pty) Ltd Address: No. 18 Aschenberg Street Chamdor Krugersdorp Tel. Nr.: (011) 769 1300 Fax Nr.: (011) 762 5712 Emergency Tel Nr.: 083 326 3581 / 082 823 4473 OR 0800 172 743


Trade Name: Rodex Boost Common Name (ISO): Propylene glycol Chemical Name: 1,2-Propanediol Simplified formula: CH3CH(OH)CH2OH Molecular weight: Cas number: 57-55-6 Chemical Class: Glycols

2. COMPOSITION:

Hazardous Components Propylene Glycol < 99.5 %


Appearance: Liquid Colour: Colourless Odour: Little or no odour Flash Point: 109 oC Boiling point: 188 oC Specific gravity: 1,04 @ 25 oC pH: 7,0 Solubility in Water: Completely soluble Autoignition: 371 oC




Flashpoint ~ 109 deg C Slightly combustable. Heat can generate flammable vapor. SMALL FIRES: Dry chemical, CO2, Halon, water spray or alcohol foam. LARGE FIRES: Water spray, fog or alcohol foam is recommended. Move container from fire area if you can do it without risk. Cool containers that are exposed to flames with water from the side until well after the fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety device or any discolouration of tank due to fire. Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Self-contained breathing apparatus (SCBA) and structural firefighter's protective clothing will provide limited protection. IF TANK, RAIL CAR OR TANK TRUCK IS INVOLVED IN FIRE, ISOLATE FOR 1 KILOMETRE IN ALL DIRECTIONS.

5. REACTIVITY DATA:

Chemical Stability: This material is stable under normal handling and storage conditions described in Section 11. Decomposition product – carbon monoxide and other toxic vapours.

Incompatibility: Strong oxidizing agents Conditions to avoid: High temperatures, oxidizing conditions

6. WARNINGS:

Store away from food and feedstuffs. Keep under lock and key. Keep out of reach of children, uninformed persons and animals. Harmful if swallowed, by contact or inhalation. Flammable liquid.


Emergency Overview: Caution. Hazard to humans and domestic animals. Keep out of the each of children.

Immediate Effects: Eye: Avoid contact with eyes. Skin: Harmful if absorbed through skin. Avoid contact with skin or

clothing. Inhalation: Harmful if inhaled. Avoid breathing vapors and spray mist.


First Aid Skin

Promptly remove contaminated clothing. Wash affected area with plenty of soap and water minutes. In case of burns, immediately cool skin as long as possible with cold water. Seek medical treatment.

First Aid Eyes

Flush eyes with water for 15 minutes. Hold eyelids open while washing. Seek medical treatment.


UPDATED: 30 June 2005 First Aid Ingested Seek medical treatment.

First Aid Inhalation Remove from contaminated area. Seek medical treatment.

9. EXPOSURE CONTROLS /PERSONAL PROTECTION:

Occupation Exposure Limits: N/A Controls: The control measures appropriate for a particular worksite depend on how this material is used and on the extent of exposure. The best protection is to enclose operations and/or provide local exhaust ventilation at the site of chemical release. Use a non-sparking, grounded ventilation system separate from other exhaust ventilation systems. Exhaust directly to the outside. Supply sufficient replacement air to make up for air removed. Have a safety shower/eye wash fountain readily available in the immediate work area Personal Protection: If engineering controls and work practices are not effective in controlling this material, then wear suitable personal protection equipment, including chemical safety goggles & face shield, boots, imperious gloves, coveralls, & respiratory protection. Have appropriate equipment available for use in emergencies.


Breathing apparatus for fire only Dilute (substance may be washed to drain with a lot of water) PRECAUTIONS: Restrict access to area. Provide adequate protective equipment and ventilation. Remove sources of heat and flame. Notify occupational and environmental authorities. SPILL OR LEAK: Shut off ignition sources; no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. SMALL SPILLS: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. LARGE SPILLS: Dike far ahead of liquid spill for later disposal.


HANDLING Hygroscopic, handle with care. Wear protective cloves. STORAGE Store in tightly closed mild steel drums.


Disposal Method Product There are no uniform EC regulations for the disposal of chemicals or residues. Chemical residues generally count as special waste. The disposal of the latter is regulated in the EC member countries through corresponding laws and regulations. We recommend that you contact the authorities in charge or approved waste disposal companies which will advise you on how to dispose of special waste. Disposal Method Packaging


UPDATED: 30 June 2005 Disposal in accordance with local legal provisions.

13. ECOLOGICAL INFORMATION:

No ecological problems are expected when the product is handled and used with due care.

14. TOXICOLOGICAL INFORMATION:

LD50 (oral) Rat: 20 mg/kg LD50 (skin) Rabbit: 20,8 mg/kg Hazardous Identification: Not regulated, may cause minor irritation to eyes.

15. TRANSPORT INFORMATION:

Marine pollutant: No Class: Not regulated Subsidiary risks: None

16. REGULATORY INFORMATION:

EEC Hazard Classification: 3 Risk Phrases: N/A


RODEX BAIT BLOCKS

DATE ISSUED: 13 May 2003 PAGE 1 OF 4 PREPARED BY: M.C. SAAIMAN

UPDATED: 13 May 2003

COMPANY DETAILS:

Name: Innovative Pest Management (PTY)LTD Address: No. 18 Aschenberg Street Chamdor Krugersdorp Tel. Nr.: (011) 769 1300 Fax Nr.: (011) 762 5712 Emergency Tel Nr.: 083 326 3581 / 082 823 4473 OR 0800172743


Trade Name: Rodex Bait Blocks Chemical Family: Coumarin anticoagulant Chemical Name: 3-[3-(4’-bromobiphenyl-4-yl)-1,2,3,4-tetrahydro-1-naphthyl]-4-hydroxycoumarin


rat, the House mouse and Gerbille.

2. COMPOSITION:



Appearance: Blue wax blocks Odour: Vanillin odour







__________________________________________________________________________________________

5. REACTIVITY DATA:


roadways, etc.

6. WARNINGS:





Inhalation: Use only in well –ventilated areas, in case of insufficient ventilation, wear suitable respiratory equipment.


Good personal hygiene practices should always be followed. Eyes: Avoid contact with eyes. Wear eye /face protection. Ingestion: Keep away from food and feedstuffs. Do not eat, drink or smoke whilst handling this product.

Wash hands and face before eating and drinking.


























RODEX GRAIN BAIT



COMPANY DETAILS:



Trade Name: Rodex Grain Bait. Chemical Family: Coumarin anticoagulant Chemical Name: 3-[3-(4’-bromobiphenyl-4-yl)-1,2,3,4-tetrahydro-1-naphthyl]-4-hydroxycoumarin


rat, the House mouse and Gerbilles

2. COMPOSITION:



Appearance: Blue grain mixture. Odour: Vanillin odour







__________________________________________________________________________________________

5. REACTIVITY DATA:


roadways, etc.

6. WARNINGS:





Inhalation: Avoid inhalation of dust. Use only in well –ventilated areas, in case of insufficient ventilation, wear suitable respiratory equipment.


Good personal hygiene practices should always be followed. Eyes: Avoid contact with eyes. Wear eye /face protection. Ingestion: Keep away from food and

feedstuffs. Do not eat, drink or smoke whilst handling this product. Wash hands and face before eating and drinking.


























RODEX LIQUID BAIT



COMPANY DETAILS:



Trade Name: Rodex Liquid Bait. Chemical Family: Coumarin anticoagulant Chemical Name: 3-[3-(4’-bromobiphenyl-4-yl)-1,2,3,4-tetrahydro-1-naphthyl]-4-hydroxycoumarin

(Active Ingredient) Molecular Formula: C31 H23 BrNO3 (Active ingredient) UN Nr.: 3026 C.A.S. Nr.: [56073-10-0] (Active Ingredient) Description of product: A HIGHLY ACTIVE anticoagulant liquid bait for the control of the Norway Rat,

Roof Rat, the House Mouse.

2. COMPOSITION:



Appearance: Blue Liquid. Odour: Vanillin odour







__________________________________________________________________________________________

5. REACTIVITY DATA:


roadways, etc.

6. WARNINGS:

Handle with EXTREME care. Avoid all contact by mouth. Avoid contamination of any edible commodity, feeds, food utensils and drinking water. Prevent access to bait by children, uninformed persons and domestic animals. Store under lock and key, away from food and feedstuffs. Poisonous if swallowed and upon prolonged contact with the skin. Toxic to fish and wildlife.




Inhalation: Avoid inhalation of spray mist. Use only in well –ventilated areas, in case of insufficient ventilation, wear suitable respiratory equipment.








clear. Take patient IMMEDIATELY to nearest physician. NOTE TO PHYSICIAN: Intravenous Vitamin K1, 50 – 150 mg on first day, in divided doses, depending on

prothrombin time. Keep under medical supervision until prothrombin times return to normal. In sever cases small transfusions of fresh blood.






Suitable Material: Plastic bottles. Handling /storage precaution: Avoid all contact by mouth. Avoid contamination of any edible

commodity, feeds, food utensils and drinking water. Set bait stations where it will be inaccessible to children and domestic animals. Wear rubber gloves and wash hands after handling. Avoid prolonged repeated skin contact. Do not eat, drink or smoke while handling the concentrate. Do not contaminate water, food or feed by storage or disposal. Store in a secure, dry, well –ventilated separate room, building or covered area. Keep away from sources of ignition and protect from exposure to fire and heat separate from incompatible materials. Do not allow entering public sewers and water sources. If contamination of drainage systems or water sources is unavoidable, inform the appropriate authorities immediately.


Waste disposal: Rinse empty container three time with a volume of water equal to a minimum of 10% of that of the container. Add rinsing to the tank before destroying the container. Destroy empty container by perforation or flattening, and do not use for any other purpose. Product should be utilized completely to avoid disposal. If not possible, dispose of at an appropriate waste disposal facility, in accordance with current applicable laws and regulations.











RODEX PROFESSIONAL

LIQUID CONCENTRATE

DATE ISSUED: 18 June 2003 PAGE 1 OF 4 PREPARED BY: M.C. SAAIMAN


COMPANY DETAILS:

Name: Small Pack Solutions (PTY)LTD Address: No. 18 Aschenberg Street Chamdor Krugersdorp Tel. Nr.: (011) 769 1300 Fax Nr.: (011) 762 5712 Emergency Tel Nr.: 083 326 3581 / 082 823 4473 OR 0800 172 743


Trade Name: Rodex Liquid Concentrate Chemical Family: Coumarin anticoagulant Chemical Name: 3-[3-(4’-bromobiphenyl-4-yl)-1,2,3,4-tetrahydro-1-naphthyl]-4-hydroxycoumarin

(Active Ingredient) Molecular Formula: C31 H23 BrNO3 (Active ingredient) UN Nr.: 3026 C.A.S. Nr.: [56073-10-0] (Active Ingredient) Description of product: A HIGHLY ACTIVE anticoagulant liquid bait concentrate for the control of the

Norway Rat, Roof Rat, the House Mouse and Gerbilles.

2. COMPOSITION:

Hazardous Components: Brodifacoum (Anticoagulant) 2.5 g /l


Appearance: Blue Liquid.







__________________________________________________________________________________________

5. REACTIVITY DATA:


roadways, etc.

6. WARNINGS:

Handle with EXTREME care. Avoid all contact by mouth. Avoid contamination of any edible commodity, animal feed, food utensils and drinking water. Prevent access to bait stations by children, uninformed persons and domestic animals. Store under lock and key, away from food and feedstuffs. Poisonous if swallowed and upon prolonged contact with the skin. Toxic to fish and wildlife.




Inhalation: Avoid inhalation of spray mist. Use only in well –ventilated areas, in case of insufficient ventilation, wear suitable respiratory equipment.








clear. Take patient IMMEDIATELY to nearest physician. NOTE TO PHYSICIAN: Intravenous Vitamin K1, 50 – 150 mg on first day, in divided doses, depending on

prothrombin time. Keep under medical supervision until prothrombin times return to normal. In sever cases small transfusions of fresh blood.






Suitable Material: Plastic bottles. Handling /storage precaution: Avoid all contact by mouth. Avoid contamination of any edible

commodity, feeds, food utensils and drinking water. Set bait stations where it will be inaccessible to children and domestic animals. Wear rubber gloves and wash hands after handling. Avoid prolonged repeated skin contact. Do not eat, drink or smoke while handling the concentrate. Do not contaminate water, food or feed by storage or disposal. Store in a secure, dry, well –ventilated separate room, building or covered area. Keep away from sources of ignition and protect from exposure to fire and heat separate from incompatible materials. Do not allow entering public sewers and water sources. If contamination of drainage systems or water sources is unavoidable, inform the appropriate authorities immediately.


Waste disposal: Rinse empty container three time with a volume of water equal to a minimum of 10% of that of the container. Add rinsing to the tank before destroying the container. Destroy empty container by perforation or flattening, and do not use for any other purpose. Product should be utilized completely to avoid disposal. If not possible, dispose of at an appropriate waste disposal facility, in accordance with current applicable laws and regulations.










Documents

MATERIAL SAFETY DATA SHEET RODEX RAT & … All.pdfWash contaminated skin with plenty of soap and water. Launder contaminated clothing before re –use. Eyes: First, rinse with plenty