MATERIAL SAFETY DATA SHEETcontent.oppictures.com/Master_Images/Master_PDF_Files/rac98576_sds.pdf · This SDS is designed for workplace employees, emergency personnel and for other

MATERIAL SAFETY DATA SHEET NAME: NANFU(EXCELL) ALKALINE BATTERIES

--LR20(D);LR14(C);LR6(AA);LR03(AAA);6LR61(9V) CAS No.: Not applicable

1. IDENTIFICATIONManganese Dioxide (CAS No.:1313-13-9) 36%-43% Zinc (CAS No.:7440-66-6) 13%-18% Potassium Hydroxide (40%) (CAS No.:1310-58-3) 4%-9% Graphite, natural (CAS No.:7782-42-5) 1%-4% Zinc Oxide (CAS No.:1314-13-2) <1

2. PHYSICAL/CHEMICAL CHARACTERISTICSAppearance And Odor: N/R Boiling Point: N/R Melting Point:

N/RVapor Pressure (MM Hg/70 F): N/R Vapor Density (Air=1): N/R Specific Gravity:

N/RDecomposition Temperature: UNKNOWN

Evaporation Rate And Ref: N/R Solubility In Water: N/R

Percent Volatiles By Volume: N/R Viscosity: N/R pH: N/RCorrosion Rate (IPY): UNKNOWN Autoignition Temperature: N/R

3. REACTIVITYStability: YES Polymerization:Will not occurCondition to avoid: Avoid electrical shorting Materials to avoid: Not applicableHazardous Decomposition Products: Thermal degradation may produce hazardous fumes of zinc and manganese;Hydrogen gas;caustic vapors of potassium hydroxide and other toxic by-products.

4. HEALTH HAZARD DATALD50-LC50 Mixture: LD 50 oral rat is unknownRoute of entry - Inhalation: NORoute of entry - Skin: YESRoute of entry - Ingestion: NOHealth Haz Acute And Chronic: No health hazard unless battery ruptures. In that event, It may cause burns and irritation. Carcinogenicity - NTP: NOCarcinogenicity - IARC: NOCarcinogenicity - OSHA: NO

FuJian NanPing NanFu Batteries Co.,Ltd

5. EXPOSURE CONTROL METHODSEngineering Controls General ventilation under normal use conditions. Eye Protection None under normal use conditions. Wear safety glasses when handling leaking batteries. Skin Protection None under normal use conditions. Use neoprene, rubber or latex gloves when handling leaking batteries. Respiratory Protection None under normal use conditions.Other Keep batteries away from small children.

6. HANDLING AND STORAGEStore at room temperature. Avoid mechanical or electrical abuse. Do not short or install incorrectly.Batteries may explode, pyrolize or vent if disassembled, crushed, recharged or exposed to high temperatures.Install batteries in accordance with equipment instructions. Do not mix battery systems, such as alkaline and zinc carbon, in the same equipment. Replace all batteries in equipment at the same time. Do not carry batteries loose in pocket or bag. Do not remove battery label.

7. WASTE DISPOSAL METHODSIndividual consumers may dispose of spent (used) batteries with household trash. Nanfu does not recommend that spent batteries be accumulated (quantities of five gallons or more should be disposed of in a secure landfill), in accordance with appropriate federal, state and local regulations. Do not incinerate, since batteries may explode at excessive temperatures.

8. EMERGENCY PROCEDURESSteps to be taken if material is released to the environment or spilled in the work area Notify safety personnel of large spills. Caustic potassium hydroxide may be released from leaking or ruptured batteries. Avoid eye or skin contact and inhalation of vapors. Increase ventilation. Clean-up personnel should wear appropriate protective gear. Fire and Explosion Hazard Batteries may burst and release hazardous decomposition products when exposed to a fire situation. See Sec. 3. Extinguishing Media As appropriate for surrounding area. Firefighting Procedures Use self-contained breathing apparatus and full protective gear.


9. FIRST AID AND MEDICAL EMERGENCY PROCEDURESEyes Not anticipated. If battery is leaking and material contacts eyes, flush with copious amounts of clear, tepid water for 30 minutes. Contact physician at once. Skin Not anticipated. If battery is leaking, irrigate exposed skin with copious amounts of clear, tepid water for at least 15 minutes. If irritation, injury or pain persists, consult a physician.Inhalation Not anticipated. If battery is leaking, contents may be irritating to respiratory passages. Remove to fresh air. Contact physician if irritation persists.Ingestion Not anticipated. Rinse the mouth and surrounding area with clear, tepid water for at least 15 minutes. Consult a physician immediately for treatment and to rule out involvement of the esophagus and other tissues.Notes to Physician 1) The primary acutely toxic ingredient is concentrated (40%) potassiumhydroxide. 2) Anticipated potential leakage of potassium hydroxide is 1-3 ml,

depending on battery size.3) This MSDS does not include or address the small button cell batteries,

which can be ingested.


MATERIAL SAFETY DATA SHEET In Accordance with Directive 2001/58/CE Date: 01/01/2011

SICHUAN CHANGHONG NEWENERGY TECHNOLOGY CO., LTD. Tel: +86-816-2418674 Fax: +86-816-2410586 www.changhongnewenergy.com

Page 1 of 4

1. Chemical ProductMSDS Name: Alkaline Battery

Manufacturer: SICHUAN CHANGHONG NEWENERGY TECHNOLOGY CO., LTD.

Address: No.35, East Mianxing Road, High-Tech Park, 621000, Mianyang, Sichuan, China.

Tel: +86-816-2418674

Fax: +86-816-2410586

2. Composition /Information on Ingredients:Chemical Nature: Chemical power source

CAS-No/EINECS NO.: Not applicable.

INCI CTFA-Description: Alkaline Zinc-Manganese Dry Battery

Tariff No.: “W” 85.06

IMPORTANT NOTE: The battery shall not be opened or burned. Exposure to the ingredients contained

within or their combustion products could be harmful.

Chemical Name Molecular

Formula CAS No. Weight (%)

Zinc Zn 7440-66-6 17~25

Manganese Dioxide MnO2 1313-13-9 35~43

Graphite C 7782-42-5 3~4

Potassium hydroxide (liquid)

KOH 1310-58-3 9~12.5

Copper Cu 7440-50-8 1

Iron Fe 7439-89-6 15~18

Water H2O 7732-18-5 10~12

Nylon --- 24937-16-4 2~3

* PNOR: Particulates not otherwise regulated ** PNOC: Particulates not otherwise classified

3. Hazards identificationsGeneral: Alkaline battery --- The Common known rules for handing of chemical power

source should be obeyed. Do not heat, recharge, disassemble the product or

dispose of in fire.

Physical-Chemical Hazards: The chemical materials concluded in the Product is sealed up, thus being

stable, safe and eco-friendly under common conditions, may not cause

physical-chemical hazards.

Hazards to Human being: Disassemble the product without a professional basis, may cause leakage of

the electrolyte and irritation to skin; or cause Hg/ Cd/ Pb (micro trace)

poisoning.

Hazards to environment: Dispose the product without separate collection, may lead to pollution

caused by Hg/ Cd/ Pb (micro trace), or the electrolyte of alkali solution.



Page 2 of 4

4. First-aid measuresInhalation: Not applicable.

Skin Contact: Wash with clear water immediately once leakage happens and the inner liquid splashes onto

skin.

Eye contact: Rinse eyes immediately with running water for at least ten minutes. Consult an

ophthalmologist.

Ingestion: Rinse mouth with water; Give plenty of water to drink. Obtain medical advice.

5. Fire-fighting measuresSuitable extinguishing media: Carbon dioxide (CO2), foam, dry chemical powder.

Extinguishing media not to be used: Never use a direct water jet, may pollute the water

system.

Exposure hazards from combustion products: In case of fire, carbon monoxide or other toxic

organic substances may be generated.

Do not inhale fumes and smoke.

Personal protective equipments: Wear full protective clothing. Use self contained

breathing apparatus.

＊ Remark: It can be extinguished by car extinguisher as well.

6. Accidental release measuresPersonal precautions: Wear protective clothing. Keep unprotected persons away.

Environmental precautions: Avoid discharge and penetration into sewerage systems, waterways, pits, and

cellars.

Methods for cleaning up: Collect spilled material with an insert standard absorbent like sand or silica.

Care for well-Ventilated conditions. Recycle or dispose of the materials in an

appropriate way.

7. Handling and storageGeneral: Obey the common known rules and precautions for handling with chemical

power sources.

Fire/Explosion protections: Explosion may happen if short-circuit; collect spilled material with an insert standard absorbent like sand or silica.

Storage: Store product in clean, cool and ventilated place with a temperature between 10℃ and 30℃ (no higher than 40℃ in the ordinary course of events) and a relative humidity no higher than 65%; the storage time should not be too long; the batteries should be well-arranged, and do avoid sort-circuit caused by the contact of the positive and negative electrodes.

8. Exposure controls/Personal protectionExposition/ Technical measures: Not applicable.

Protection of hands, eyes and skin: To protect hands, eyes and skin, do not disassemble the

product without professional basis.



Page 3 of 4

9. Physical and chemical propertiedPhysical state Solid Solubility in water not applicable

Color not applicable Vapor pressure not applicable

Odor not applicable Explosion limit not applicable

pH value not applicable Oxidizing properties not applicable

Specific gravity not applicable Flashpoint not applicable

Refractive index not applicable Auto flammability not applicable

Solubility in ethanol not applicable Partition coefficient not applicable

Melting Point not applicable Boiling Point not applicable

Freezing Point not applicable

10. Stability and ReactivityThe chemical materials concluded in the Product are sealed up, thus being stable, safe and eco-friendly under

common conditions.

11. Toxicological informationThe product is multi component mixture for which no toxicological data exists.

Precautions avoid disassembling the product without a professional basis.

12. Ecological informationIn general, no ecological data is available for preparations.

Precautions avoid disposing into drainage systems and into the environment.

13. Disposable considerationsPrecautions avoid disposing waste products into environment, sewerage, landfills or by incineration.

Obey the rules and precautions for separate collection and recycling of the waste products.

14. Transport InformationRoad (ADR/RID) : not regulated

Air (ICAO/IATA) : not regulated

Sea (IMDG) : not regulated

＊ Remark: Avoid high-temperature, high-humidity condition.

15. Regulatory InformationSymbol: for transportation, collection, or environment protection (stipulated respectively

by each contract).

Contains: transportation marks;

“separate collection” symbol;

“RoHS” symbol (maybe), etc.



Page 4 of 4

16. Other informationThe information on this Material Safety Date Sheet (MSDS) was obtained from current and reputable sources.

For any other question, please contact the manufacturer for further information.

AIR WICK® Essential Mist - Lavender & Almond Blossom

Air care, continuous action (solid and liquid)

SAFETY DATA SHEET

Product name

Distributed by

Product use

1. Product and company identification:

:

:

D8308258 v3.0:SDS #

Formulation #: : 8300059 v1.0

UPC Code / Sizes : Liquid autospray/battery operated

AIR WICK® Essential Mist - Lavender & Almond Blossom

:Website: http://www.rbnainfo.com

Emergency telephone number (Medical)

Emergency telephone number (Transport)

:

1-800-338-6167

1-800-424-9300 (U.S. & Canada) CHEMTREC Outside U.S. and Canada (North America), call Chemtrec:703-527-3887

:

This SDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is greater potential for large-scale or prolonged exposure, in accordance with the requirements of USDOL Occupational Safety and Health Administration.

This SDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulations, and shown in Section 15 of this SDS.

Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM

Reckitt Benckiser LLC.Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225)Parsippany, New Jersey 07054-0225 +1 973 404 2600

Reckitt Benckiser (Canada) Inc.1680 Tech Avenue, Unit #2 Mississauga, Ontario L4W 5S9 CANADA Telephone: +1 905 283 7000

2. Hazards identification

Classification of the substance or mixture

FLAMMABLE LIQUIDS - Category 4EYE IRRITATION - Category 2A

:

Hazard pictograms :

GHS label elements

1/1304/10/2017Date of issue :SDS #D8308258 (NA):Code # D8308258 v3.0:

D8308258 v3.0


2. Hazards identificationSignal word : CAUTION

Hazard statements : Combustible liquid.Causes serious eye irritation.

Supplemental label elements

: None known.

Hazards not otherwise classified

: None known.

General

Prevention : Wash hands thoroughly after handling.

Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs, seek medical advice/attention. IF SWALLOWED: Immediately call a POISON CENTER or doctor.

Storage : Store in a well-ventilated place. Keep cool.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

: Keep out of reach of children and pets. If medical advice is needed, have product container or label at hand.

Precautionary statements

3. Composition/information on ingredientsMixture:Substance/mixture

Benzyl acetate 1 - 2.5 140-11-4Linalool 0.1 - 1 78-70-6Coumarin 0.1 - 1 91-64-5alpha-Hexylcinnamaldehyde 0.1 - 1 101-86-04-tert-Butylcyclohexyl acetate 0.1 - 1 32210-23-4

Ingredient name CAS number%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

4. First aid measures

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,tie, belt or waistband.

Eye contact

Skin contact

Inhalation

:

:

:

Description of necessary first aid measures


D8308258 v3.0


4. First aid measuresWash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person.If unconscious, place in recovery position and get medical attention immediately.Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Ingestion :

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion

Skin contact : No known significant effects or critical hazards.

Causes serious eye irritation.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation No specific data.

No specific data.

No specific data.

:

:

:

Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

Potential acute health effects

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

5. Fire-fighting measures

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:carbon dioxidecarbon monoxide

Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.

Use dry chemical, CO₂, water spray (fog) or foam.

Extinguishing media

:

:

Do not use water jet.

Suitable extinguishing media

:

Unsuitable extinguishing media

:


D8308258 v3.0


5. Fire-fighting measuresPromptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

:

Special protective actions for fire-fighters

:

6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

:

: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

7. Handling and storage

Protective measures Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Do not reuse container.

:

Precautions for safe handling


D8308258 v3.0


7. Handling and storageConditions for safe storage,including any incompatibilities

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination.

:

Benzyl acetate ACGIH TLV (United States, 4/2014). TWA: 10 ppm 8 hours. TWA: 61 mg/m³ 8 hours.

8. Exposure controls/personal protection

Ingredient name Exposure limits

Hand protection

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Eye/face protection

Respiratory protection :

:

:

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

:

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas,vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Control

Individual protection measures

Occupational exposure limits

Skin protection

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.


D8308258 v3.0


9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid.

Not available.

Not available.

Not available.

Not available.

Not available.

Characteristic.Odor

pH

Colorless to light yellow.Color

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

Closed cup: 72°C (161.6°F)

Not available.

Not available.

Not available.Odor threshold

Partition coefficient: n-octanol/water

:

:

:

:

:

:

:

:

:

:

:

:

:

:

Appearance

Boiling point : Not available.

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits

: Not available.

Decomposition temperature : Not available.

Viscosity Not available.:

Flow time (ISO 2431) : Not available.

10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Reactive or incompatible with the following materials:oxidizing materials

:

:

:

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

11. Toxicological information

Acute toxicity

Information on toxicological effects


D8308258 v3.0


11. Toxicological informationProduct/ingredient name Result Species Dose Exposure

Conclusion/Summary : Based on available data, the classification criteria are not met.

Irritation/Corrosion

Benzyl acetate Skin - Moderate irritant Rabbit - 24 hours 100 milligrams

-

Linalool Eyes - Moderate irritant Rabbit - 1 hours 0.1 Mililiters

-

Eyes - Moderate irritant Rabbit - 100 microliters

-

Skin - Moderate irritant Guinea pig - 24 hours 100 milligrams

-

Skin - Mild irritant Human - 72 hours 32 Percent

-

Skin - Mild irritant Man - 48 hours 16 milligrams

-

Skin - Mild irritant Rabbit - 24 hours 500 milligrams

-

Skin - Severe irritant Rabbit - 24 hours 100 milligrams

-

alpha-Hexylcinnamaldehyde Skin - Severe irritant Guinea pig - 24 hours 100 milligrams

-

Skin - Moderate irritant Rabbit - 24 hours 500 milligrams

-

Skin - Severe irritant Rabbit - 24 hours 100 milligrams

-

4-tert-Butylcyclohexyl acetate Skin - Mild irritant Guinea pig - 4 hours 3 Percent

-

Skin - Moderate irritant Rabbit - 4 hours 100 Percent

-

Skin - Moderate irritant Rabbit - 24 hours 500 milligrams

-

Product/ingredient name Result Score Exposure Observation

Conclusion/Summary

Skin : Based on available data, the classification criteria are not met.

Eyes : Based on Calculation method: Causes serious eye irritation.

Respiratory : Based on available data, the classification criteria are not met.

Species

Sensitization

Not available.

Conclusion/Summary

Skin : Based on available data, the classification criteria are not met.

Respiratory : Based on available data, the classification criteria are not met.

Benzyl acetate LD50 Dermal Rabbit >5 g/kg -LD50 Oral Rat 2490 mg/kg -

Linalool LD50 Dermal Rabbit 5610 mg/kg -LD50 Dermal Rat 5610 mg/kg -LD50 Oral Rat 2790 mg/kg -

Coumarin LD50 Oral Rat 293 mg/kg -alpha-Hexylcinnamaldehyde LD50 Oral Rat 3100 mg/kg -4-tert-Butylcyclohexyl acetate LD50 Dermal Rabbit >5000 mg/kg -

LD50 Oral Rat 3550 mg/kg -


D8308258 v3.0



Carcinogenicity

Not available.


Mutagenicity

Not available.


Teratogenicity

Not available.


Reproductive toxicity


Not available.

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Not available.

Not available.

Aspiration hazard

Not available.

Classification

Benzyl acetate - 3 -Coumarin - 3 -

Product/ingredient name NTPIARCOSHA

Information on the likely routes of exposure

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion

Skin contact : No known significant effects or critical hazards.

Causes serious eye irritation.:Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation No specific data.

No specific data.

No specific data.

:

:

:

Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

Delayed and immediate effects and also chronic effects from short and long term exposure

: Not available.

Potential acute health effects

Short term exposure


D8308258 v3.0



Not available.


No known significant effects or critical hazards.General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Potential chronic health effects

Numerical measures of toxicity

Oral 29699.4 mg/kg

Route ATE value

Acute toxicity estimates

Potential immediate effects

: Not available.

Potential delayed effects : Not available.

Potential immediate effects

: Not available.

Long term exposure

Potential delayed effects : Not available.

12. Ecological informationToxicity

Benzyl acetate Acute LC50 4000 µg/l Fresh water Fish - Oryzias latipes - Juvenile (Fledgling, Hatchling, Weanling)

96 hours

Chronic NOEC 920 µg/l Fresh water Fish - Oryzias latipes - Larvae 28 daysLinalool Acute EC50 36.7 ppm Fresh water Daphnia - Daphnia magna 48 hours

Acute LC50 28.8 ppm Fresh water Fish - Oncorhynchus mykiss 96 hoursCoumarin Acute LC50 13500 µg/l Fresh water Daphnia - Daphnia magna 48 hours

Acute LC50 56000 µg/l Fresh water Fish - Poecilia reticulata 96 hours

Product/ingredient name SpeciesResult Exposure

Bioaccumulative potential

Product/ingredient name Aquatic half-life Photolysis Biodegradability

Linalool - - Readily

Persistence and degradability

Linalool - 62.4 % - Readily - 28 days - -

Product/ingredient name Test DoseResult Inoculum


D8308258 v3.0


12. Ecological informationLogPow BCF Potential

Other adverse effects : No known significant effects or critical hazards.

Product/ingredient name

Benzyl acetate 1.96 8 lowLinalool 2.84 - lowCoumarin 1.39 - low4-tert-Butylcyclohexyl acetate 4.8 - high

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

13. Disposal considerations

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

:Disposal methods

14. Transport information

Not applicable. -DOT Classification

TDG Classification Not available.

Not applicable. -

Not Regulated

Not applicable. -

IMDG Class Not applicable. Not available. -

Not applicable.Not Regulated

IATA-DGR Class Not available.

Regulatory information

UN number Proper shipping name

Classes PG* Label Additional information

-

Not Regulated

-

-

Not Regulated

-

Mexico Classification

Not Regulated

Not applicable. Not available. - -


D8308258 v3.0


14. Transport information

PG* : Packing group

Special precautions for user Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

:

15. Regulatory information

U.S. Federal regulations : TSCA 8(a) PAIR: (2-methoxymethylethoxy)propanol; 3-ethoxy-4-hydroxybenzaldehyde;anisaldehyde; 3-p-cumenyl-2-methylpropionaldehyde; 4-(4-hydroxy-4-methylpentyl)cyclohex-3-enecarbaldehyde; α-hexylcinnamaldehyde; cinnamaldehyde; benzaldehyde;2-benzylideneheptanal

TSCA 8(a) CDR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): Not determined.

Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)

: Not listed

Clean Air Act Section 602 Class I Substances

: Not listed

Clean Air Act Section 602 Class II Substances

: Not listed

DEA List I Chemicals (Precursor Chemicals)

: Not listed

DEA List II Chemicals (Essential Chemicals)

: Not listed

The following components are listed: DIPROPYLENE GLYCOL METHYL ETHERMassachusetts :

New York : None of the components are listed.

State regulations

SARA 302/304

SARA 304 RQ : Not applicable.

No products were found.

Composition/information on ingredients

SARA 311/312

Classification : Fire hazardImmediate (acute) health hazard

Benzyl acetate 1 - 2.5 No. No. No. Yes. No.Linalool 0.1 - 1 Yes. No. No. Yes. No.Coumarin 0.1 - 1 No. No. No. Yes. No.alpha-Hexylcinnamaldehyde 0.1 - 1 No. No. No. Yes. No.4-tert-Butylcyclohexyl acetate 0.1 - 1 No. No. No. Yes. No.

Name % Fire hazard

Sudden release of pressure

Reactive Immediate (acute)health hazard

Delayed (chronic)health hazard

Composition/information on ingredients


D8308258 v3.0


15. Regulatory information

CAUTION

Combustible liquid. CAUSES EYE IRRITATION.

Keep out of reach of children and pets. Avoid contact with eyes.

Signal word :

Hazard statements :

Precautionary measures :

Label elements

Additional information IF SWALLOWED: Do NOT induce vomiting. Immediately call a POISON CENTER or doctor. If in eyes, immediately rinse eyes with water. Remove any contact lenses if present and continue rinsing for 15 minutes. If irritation persists, get medical attention. If on skin, rinse well with water.

:

Recommendations : People suffering from perfume sensitivity should be cautious when using this product.Air Fresheners do not replace good hygiene practices.

New Jersey : The following components are listed: DIPROPYLENE GLYCOL METHYL ETHER;(2-METHOXYMETHYLETHOXY) PROPANOL; BENZYL ACETATE; ACETIC ACID,PHENYLMETHYL ESTER

Pennsylvania : The following components are listed: PROPANOL, (2-METHOXYMETHYLETHOXY)-

None of the components are listed.

WHMIS (Canada) Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F).Class D-2B: Material causing other toxic effects (Toxic).

:

Canada

Canadian NPRI :

Canada inventory : Not determined.

CEPA Toxic substances : None of the components are listed.

Canadian lists

16. Other informationHazardous Material Information System (U.S.A.)

2

2

0

02

2

*

National Fire Protection Association (U.S.A.)

Health

Special

Instability/Reactivity

Flammability

Health

Flammability

Physical hazards

:

:

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

Personal protection B


D8308258 v3.0


16. Other information

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Date of issue

Date of previous issue

Version :

:

:

Indicates information that has changed from previously issued version.

04/10/2017

29/09/2017

3

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not,anyone using the 704 systems to classify chemicals does so at their own risk.

Prepared by : Reckitt Benckiser India LtdPlot No 48Sector - 32Institutional AreaGurgaon, HaryanaIndia - 122001

RB is a member of the CSPA Product Care Product Stewardship Program.

Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations


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