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Materials 286K [email protected] Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition dependence at 10 K of (a) the in-plane copper-oxygen, Cu-O(1), bond lengths; (b) the orthorhombic strain; (c) the Cu- O(1)-Cu bond angles; (d ) the superconducting T c ’s for La 2–x Sr x CuO 4 and La 2–x Ca x CuO 4 systems. Tetragonal La 2– x Sr x CuO 4 systems under applied pressure are marked by solid squares. Dabrowski, Wang, Rogacki, Jorgensen, Hitterman, Wagner, Hunter, Radaelli, Hinks, Phys. Rev. Lett. 76 (1996) 1348–1351.

Materials 286K [email protected] Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

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Page 1: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in cuprates

Right: (La,M)2CuO4 superconducting Tc: Composition dependence at 10 K of (a) the in-planecopper-oxygen, Cu-O(1), bond lengths; (b) the orthorhombic strain; (c) the Cu-O(1)-Cu bond angles; (d ) the superconducting Tc’s for La2–

xSrxCuO4 and La2–xCaxCuO4 systems. Tetragonal La2–xSrxCuO4 systems under applied pressure are marked by solid squares.

Dabrowski, Wang, Rogacki, Jorgensen, Hitterman, Wagner, Hunter, Radaelli, Hinks, Phys. Rev. Lett. 76 (1996) 1348–1351.

Page 2: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in cuprates

Cu–O bond distances in La1.85Sr0.15CuO4 appear to suggest two phases at low temperature, associated with stripes.

Bianconi, Saini, Lanzara, Missori, Rossetti, Moro, Oyanagi, Yamaguchi, Oka, Ito, Phys. Rev. Lett. 76 (1996) 3412–3415.

Page 3: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in cuprates

MBE-grown LSCO: Highest TC recorded, potentially due to interface effects.

Bozovic, Logvenov, Belca, Narimbetov, Sveklo, Phys. Rev. Lett. 89 (2002) 107001(1–4).

Page 4: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in cuprates

Average compositions versus bilayers: Tc is enhanced

Yuli, Asulin, Millo, Orgad, Iomin, Koren, Phys. Rev. Lett. 101 (2008) 057005(1–4).

Page 5: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in cuprates

Highly optimized “123”. Tc reaches 94.3 K.

Liang, Bonn, Hardy, Phys. Rev. B. 73 (2006) 180505R(1–4).

Page 6: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in cuprates

Highly optimized “123”. Tc reaches 94.3 K.

Tc is slightly suppressed near p = 1/8 holes. Stripe formation?

Liang, Bonn, Hardy, Phys. Rev. B. 73 (2006) 180505R(1–4).

Page 7: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in cuprates

McAllister, Attfield, Phys. Rev. Lett. 83 (1999) 3289–3292.

Cation disorder in 214 cuprates: All doped at x = 0.15

Page 8: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in cuprates

Cation disorder in 214 cuprates: All doped at x = 0.15

McAllister, Attfield, Phys. Rev. Lett. 83 (1999) 3289–3292.

Page 9: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in cobaltates

Polarons in La1–xSrxCoO3 (x = 0.3): Behavior attributed to phase separation.

Caciuffo, Mira, Rivas, Senaris-Rodrguez, Radaelli, Carsughi, Fiorani, Goodenough, Europhys. Lett. 45 (1999) 399–405.

Page 10: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in cobaltates

Polarons in La1–xSrxCoO3 (x = 0.3): Magnetic clusters seen in small-angle scattering grow and then shrink.

Caciuffo, Mira, Rivas, Senaris-Rodrguez, Radaelli, Carsughi, Fiorani, Goodenough, Europhys. Lett. 45 (1999) 399–405.

Page 11: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in manganites

Pr0.7Ca0.3MnO3:

Radaelli, Ibberson, Argyriou, Casalta, Andersen, Cheong, Mitchell, Phys. Rev. B 63 (2001) 172419(1–4).

Page 12: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in manganites

Pr0.7Ca0.3MnO3:

Radaelli, Ibberson, Argyriou, Casalta, Andersen, Cheong, Mitchell, Phys. Rev. B 63 (2001) 172419(1–4).

Page 13: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in manganites

La1–xCaxMnO3: PDF peak corresponding to O–O correlations.(a) x = 0.25, (b) x = 0.21, and(c) x = 0.12.

Billinge, DiFrancesco, Kwei, Neumeier, Thompson, Phys. Rev. Lett 77 (1996) 715–718.

Page 14: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in manganites

La1–xCaxMnO3 in the ferromagnetic regime

Bozin, Schmidt, DeConinck, Paglia, Mitchell, Chatterji, Radaelli,Proffen, Billinge, Phys. Rev. Lett. 98 (2007) 137203(1–4).

Page 15: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in manganites

La1–xCaxMnO3 in the ferromagnetic regime

Bozin, Schmidt, DeConinck, Paglia, Mitchell, Chatterji, Radaelli,Proffen, Billinge, Phys. Rev. Lett. 98 (2007) 137203(1–4).

Page 16: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in thiospinels

CuIr2S4: M–I transition at 230 K.

Radaelli, Horibe, Gutmann, Ishibashi, Chen, Ibberson, Koyama, Hor, Kiryukhin, Cheong, Nature 416 (2002) 155–158.

Page 17: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in thiospinels

CuIr2S4: M–I transition at 230 K. Temperature, Cr3+ doping, and X-ray fluence effects.

Bozin, Masadeh, Hor, Mitchell, Billinge, Phys. Rev. Lett. 106 (2011) 045501(1–4).

Page 18: Materials 286K seshadri@mrl.ucsb.edu Class 13, Local structure and structural effects in cuprates Right: (La,M) 2 CuO 4 superconducting T c : Composition

Materials 286K [email protected]

Class 13, Local structure and structural effects in thiospinels

CuIr2S4: M–I transition at 230 K. Temperature, Cr3+ doping, and X-ray fluence effects.

Bozin, Masadeh, Hor, Mitchell, Billinge, Phys. Rev. Lett. 106 (2011) 045501(1–4).