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Floor 11, 452 Flinders StreetMelbourne VIC 3000PO Box 312, Flinders LaneMelbourne VIC 8009 AustraliaT +61 3 8668 3000F +61 3 8668 3001www.jacobs.com
Jacobs Group (Australia) Pty Limited ABN 37 001 024 095IS157700-03-NP-LTR-0002
19 September 2017
Attention: Barry DungeyGeneral Manager EBAC and Major ProjectsBy email [email protected]
Project Name: Morwell Power Station and Briquetting FacilitiesProject Number: IS157700
Subject: Groundwater Monitoring Event February 2017
Dear Barry,
This letter outlines the results of the groundwater monitoring event (GME) conducted by JacobsGroup (Australia) Pty Limited (Jacobs) between 27 February and 2 March 2017 for Energy BrixAustralia Corporation (in Liquidation) Pty Ltd (EBAC) at Morwell Power Station (the site).
The work was conducted as part of the environmental site assessment (ESA) process for the siteinitiated by EBAC. It is the second GME to be conducted at the site, the first of which was completedby GHD in December 2016 as part of their Phase 2 ESA (GHD, 2016). We draw your attention toAttachment 3 “Important note about your report” for context.
1. Sampling and analysis
1.1 Field sampling
Of 20 wells comprising the groundwater monitoring network of the site, 19 in total were sampled byJacobs. One well (GW15) was unable to be sampled due to a damaged stand pipe. For well locations,refer to Figure 4 in GHD (2016).
All sampling was undertaken in accordance with Jacobs standard field procedures and relevantAustralian Standards (Standards Australia, 2005) and National Environment Protection (Assessmentof Site Contamination) Measure (NEPM) (NEPC, 2013) guidelines.
A total of 18 of the 19 wells were sampled by means of low-flow micro-purge technique, while one well(GW16) was sampled by use of a disposable bailer due to extremely low recharge conditions. Thewater level and water quality parameters of each well were monitored during sampling to confirm thatgroundwater was being recharged into the well and when a representative sample of groundwatercould be taken. Groundwater well GW16 however, was first purged with use of a disposable bailerand left for ~4 hours to allow for recharge before being sampled with the disposable bailer.
One set of blind replicates were collected from a randomly selected well for analysis by the primary(ALS) and secondary (Eurofins) laboratories for quality assurance/ quality control (QA/QC) purposes.
19 September 2017Subject: Groundwater Monitoring Event February 2017
IS157700-03-NP-LTR-0002 2
Between sampling at each well, all re-useable equipment in contact with groundwater wasdecontaminated with Decon90TM and tap water. Internal pump bladders and twin tubing were replacedbetween each well. At the end of each sampling day, a rinsate blank was collected from the samplingpump after decontamination and laboratory prepared trip blank samples were also stored in eachbatch submitted to ALS.
All samples were collected in laboratory provided bottles with relevant preservatives and immediatelyplaced on ice within an insulated cooler. Field filtered and unfiltered samples were collected for metalsanalysis. Coolers were replenished with ice prior to being couriered to the laboratories under chain ofcustody protocols.
1.2 Analytical testing
Analytes were scheduled for laboratory testing in accordance with the SAQP and in line with thoseselected by GHD for the first GME (GHD, 2016; Jacobs, 2016). An exception was radium-226/228,which was not analysed in this GME due to the protracted turnaround time required for this analysis.
2. Adopted guidelines
The following guidelines have been adopted for the purposes of screening against results:
· National Environment Protection (Assessment of Site Contamination) Measure Schedule B11999 (Vol. 2) (NEPC, 2013);
· Australian and New Zealand guidelines for fresh and marine water quality: Volume 1 andVolume 3 (ANZECC and ARMCANZ, 2000a, 2000b);
· Technical Report No. 38 - Assessment, management and remediation for PFOS and PFOAPart 3: ecological screening levels (CRC CARE, 2017); and
· Australian water quality guidelines for fresh and marine waters (ANZECC, 1992).
3. Results
Exceedances were reported for several analytes, primarily of adopted ecological freshwater criteria.Several analytes also reported technical exceedances of the adopted criteria (Table 3.1).
Table 3.1 : Summary of exceedances of adopted criteria
Analyte Criteria(mg/L)
Total orfiltered
No. ofexceedances
Average(mg/L) Range (mg/L)
EIL freshwater 95% (ANZECC and ARMCANZ, 2000a)
Boron 370T 1 153 <50 - 2,180
F 1 176 <50 - 2,520
Cadmium 0.2T 2 0.11 <0.1 - 0.9
F 1 0.097 <0.1 - 0.4
Copper 1.4T 19 34 4 - 215
F 15 3.4 <1 - 14
Lead 3.4 T 14 33 2 - 196
19 September 2017Subject: Groundwater Monitoring Event February 2017
IS157700-03-NP-LTR-0002 3
Analyte Criteria(mg/L)
Total orfiltered
No. ofexceedances
Average(mg/L) Range (mg/L)
Mercury 0.6 T 1 0.24 <0.1 - 3
Nickel 11T 15 42 6 - 209
F 12 21 3 - 70
Selenium 11 T 4 11 10 - 60
Zinc 8T 19 165 44 - 799
F 19 75 11 - 190
Stock watering (ANZECC and ARMCANZ, 2000b)
Lead 100 T 1 33 2 - 196
Mercury 2 T 1 0.24 <0.1 - 3
Selenium 20 T 1 11 10 - 60
Industrial water use (ANZECC, 1992)
pH1 6 – 8.3 - 5 6.2 4.31 - 7.26
PFAS freshwater 99% (CRC CARE, 2017)
PFOS2 0.00023 - 2 0.018 <0.01 – 0.11Notes:
1. pH units
2. PFOS reported as µg/L
3.1 PFAS results
Per- and polyfluoroalkyl substances (PFAS) are a significant and emerging group of environmentalcontaminants. These are typically derived from aqueous film forming foam (AFFF) compounds used infirefighting/training activities.
PFAS were detected in several groundwater samples during Jacobs’ GME but were not previouslydetected in GHD’s groundwater monitoring program (due in part to a lowering of the laboratory’sdetection limit between the analysis events). PFAS compounds were also detected in soil samplescollected by GHD at a number of areas. The attached Figures 1 and 2, respectively, indicate theseareas.
The distribution of PFAS detections around possible source locations (such as the fire training area –GHD’s APEC Area 7) and drainage lines suggests a possible site-based origin.
Given the emerging nature of PFAS as environmental contaminants of concern, regulations includingacceptable guideline levels in soil and groundwater are not comprehensive and are changing. Recentguidance published by CRC CARE (2017) has been referenced for this assessment.
One compound, perfluorooctanesulfonate (PFOS), exceeds the groundwater screening level for 99%species ecosystem protection at three locations. This is a high-conservation level (highly protective).The concentrations do not exceed the 95% species ecosystem protection level applicable for “slightlyto moderately disturbed” surface water systems – the GHD report identifies that SEPP Waters ofVictoria designates this level of protection to relevant potential surface water receptors; screeninglevels apply at the point of discharge of groundwater to a receiving surface water body.
19 September 2017Subject: Groundwater Monitoring Event February 2017
IS157700-03-NP-LTR-0002 4
3.2 Quality assurance/quality control
QA/QC procedures were implemented as per Jacobs standard work procedures.
An evaluation of the QA/QC procedures implemented in this assessment and the results of laboratoryanalysis of field and laboratory QA/QC samples suggests that the results from the assessment are ofadequate quality and provide a reliable basis for the conclusions presented in this report.
Further details of the QA/QC procedures and results are provided in Attachment 2 and results arepresented in Table 2 and Table 3.
3.3 Conclusions
In respect to the PFAS groundwater data, we note that:
· groundwater flow directions are unclear from GHD’s assessment, and therefore the location ofany such surface water interaction (near or far from the site) has not been established; and
· The regulatory (EPA Victoria) position on PFAS compounds, as emerging contaminants ofconcern, is not crystal clear; it is possible the regulator may see fit to find that the 99% protectionlevel applies and in which case concentrations would be exceeding assessment levels.
Broadly two issues arise from these results:
· Soil contamination around the source area (likely to be chiefly the fire training area) may nothave been fully delineated.
· It is unclear from the available data whether the observed groundwater PFOS concentrationswould adversely affect a nearby surface water body. The regulator (EPA) would likely want tosee this risk assessed.
We recommend that to more accurately assess the risk and ongoing liability to EBAC from legacyPFAS issues in soil and groundwater, a review of the conceptual site model be undertaken andfurther investigation of data gaps conducted where required to define linkages between source(s),pathways and receptors. This should include additional soil investigation in the possible source areas(e.g. fire training area).
Yours sincerely
Ben GrassoContaminated Land Consultant(03) 8868 [email protected]
19 September 2017Subject: Groundwater Monitoring Event February 2017
IS157700-03-NP-LTR-0002 5
Attachments
Figure 1 – Groundwater PFAS detections sketch
Figure 2 – Soil PFAS detections sketch
Table 1 – Analytical Data Summary
Table 2 – Quality Assurance/ Quality Control Relative Percentage Differences
Table 3 – Rinsate and Trip Blank Data Summary
Attachment 1 – Laboratory Certificates of Analysis
Attachment 2 – Quality assurance/ quality control overview
Attachment 3 – Important note about your report
DRAFT MAP OF DETECTED PFOS, PFOA, PFHxS AND PFPeA (05/04/2017)
The following table outlines available ecological screening levels for freshwater ecosystems at 95% and 99% levels of protection as per Table 18 of CRCCARE Technical Report 38 Part 3.
CRCCARE No.38 Freshwater 95%
ESL (interim, 2017) CRCCARE No.38 Freshwater 99%
ESL (interim, 2017)
Units EQL Perfluorooctanesulfonic acid (PFOS) µg/L 0.01 0.13 0.00023 Perfluorooctanoic acid (PFOA) µg/L 0.01 220 19
The following map summarises the locations of groundwater wells where perflurochemicals were detected above the laboratory limit of detection.
Table 1 - Analytical Summary Table, Groundwater Monitoring Event, February 2017 Energy Brix Australia Corporation, Morwell Power Station and Briquetting Facilities
Location Code GW01 GW02 GW03 GW04 GW05 GW06 GW07 GW08 GW09 GW10 GW11 GW12 GW13 GW14Field ID GW01 GW02 GW03 GW04 GW05 GW06 GW07 GW08 GW09 GW10 GW11 GW12 GW13 GW14
Sample Date 27/02/2017 27/02/2017 27/02/2017 27/02/2017 2/03/2017 2/03/2017 2/03/2017 1/03/2017 1/03/2017 28/02/2017 28/02/2017 28/02/2017 28/02/2017 2/03/2017Lab Report Number EM1702240 EM1702240 EM1702240 EM1702240 EM1702389 EM1702389 EM1702389 EM1702312 EM1702312 EM1702240 EM1702240 EM1702240 EM1702240 EM1702389
Sample_Type Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal
Chem name Units EQL 2-4m 4-8m >8mMajor ions
Alkalinity (Carbonate as CaCO3) mg/L 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1Bicarbonate as CaCO3 mg/L 1 106 166 378 1460 310 424 520 3 <1 472 16 100 883 657Alkalinity (Hydroxide) as CaCO3 mg/L 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1Alkalinity (total) as CaCO3 mg/L 1 106 166 378 1460 310 424 520 3 <1 472 16 100 883 657Anions Total meq/L 0.01 130 28 122 107 111 103 122 54 61.1 114 51 64.3 123 78.1Calcium mg/L 0.5 420 - - - - - - - - - - - - - - Calcium (Filtered) mg/L 1 420 86 48 237 91 36 201 402 39 26 229 191 151 211 96Cations Total meq/L 0.01 124 27.2 111 96.3 105 94.6 118 55 58.9 105 52.3 66.3 112 75.3Chloride mg/L 1 19000 4470 867 3980 2600 3550 3240 673 1890 2150 3550 505 1130 3690 1940Fluoride mg/L 0.1 2 0.4 0.3 0.3 0.7 0.3 0.3 0.2 0.3 0.2 0.5 <0.1 0.3 0.7 0.7Ionic Balance % 0.01 2.03 1.41 4.82 5.26 2.61 4.37 1.76 0.85 1.83 3.93 1.28 1.57 4.58 1.78Magnesium mg/L 0.5 - - - - - - - - - - - - - - Magnesium (Filtered) mg/L 1 217 74 344 180 165 270 470 94 174 313 203 216 268 136Potassium mg/L 0.5 - - - - - - - - - - - - - - Potassium (Filtered) mg/L 1 2 3 7 14 7 4 4 2 2 16 8 8 10 8Sodium mg/L 0.5 - - - - - - - - - - - - - - Sodium (Filtered) mg/L 1 2350 429 1620 1760 2060 1430 1360 1040 994 1550 595 938 1820 1360Sulphate mg/L 5 2700 - - - - - - - - - - - - - - Sulphate (Filtered) mg/L 1 2700 66 11 105 213 - - - - - 194 1750 1460 50 -
Nitrogen compoundsAmmonia as N mg/L 0.01 0.03 <0.01 0.04 0.26 0.12 0.31 0.12 0.07 0.03 0.02 0.02 0.02 0.1 0.12Nitrate (as N) mg/L 0.02 0.1581 - - - - - - - - - - - - - - Sulfate as SO4 - Turbidimetric (Filtered) mg/L 1 - - - - 214 160 4460 32 22 - - - - 491
MetalsArsenic µg/L 1 500 6 2 2 3 3 5 21 8 5 <1 9 17 2 18Arsenic (Filtered) µg/L 1 500 <1 <1 <1 2 2 1 1 <1 <1 <1 1 <1 <1 <1Barium µg/L 1 252 1270 288 349 108 335 1080 292 448 204 237 1170 1300 1180Barium (Filtered) µg/L 1 204 1010 239 314 86 287 25 215 394 177 11 41 1230 542Beryllium µg/L 1 6 1 <1 <1 <1 <1 4 6 9 <1 2 7 <1 4Beryllium (Filtered) µg/L 1 <1 <1 <1 <1 <1 <1 <1 3 10 <1 <1 <1 <1 <1Boron µg/L 50 370 370 5000 <50 <50 <50 <50 80 <50 2180 <50 <50 <50 <50 <50 <50 <50Boron (Filtered) µg/L 50 370 370 5000 <50 <50 <50 70 100 <50 2520 90 <50 <50 <50 <50 <50 <50Cadmium µg/L 0.1 0.2 0.2 10 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1Cadmium (Filtered) µg/L 0.1 0.2 0.2 10 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 <0.1 <0.1 <0.1 <0.1 <0.1Chromium (hexavalent) µg/L 1 1 1 - - - - - - - - - - - - - - Chromium (hexavalent) (Filtered) µg/L 10 1 1 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10Chromium (III+VI) µg/L 1 1000 15 16 6 4 3 17 86 37 32 3 27 46 10 53Chromium (III+VI) (Filtered) µg/L 1 1000 1 <1 <1 <1 <1 <1 <1 1 <1 <1 <1 <1 <1 <1Chromium (Trivalent) µg/L 1 - - - - - - - - - - - - - - Chromium (Trivalent) (Filtered) µg/L 1 - - - - - - - - - - - - - - Cobalt µg/L 1 1000 94 18 10 7 6 18 200 56 141 3 84 89 5 71Cobalt (Filtered) µg/L 1 1000 64 2 6 5 5 11 151 47 136 2 65 10 <1 6Copper µg/L 1 1.4 1.4 1000 24 11 6 9 5 14 34 53 72 7 18 33 6 55Copper (Filtered) µg/L 1 1.4 1.4 1000 2 1 2 4 6 1 2 8 14 7 2 2 3 <1Lead µg/L 1 3.4 3.4 100 22 18 4 2 2 13 71 35 23 2 17 61 6 77Lead (Filtered) µg/L 1 3.4 3.4 100 <1 <1 <1 <1 <1 <1 <1 <1 2 <1 <1 <1 <1 <1Manganese µg/L 1 1900 1900 123 129 194 479 122 1400 531 27 60 43 2990 548 77 1100Manganese (Filtered) µg/L 1 1900 1900 26 58 301 476 113 1420 492 24 56 38 2910 306 36 732Mercury µg/L 0.1 0.6 0.06 2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 3 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1Mercury (Filtered) µg/L 0.1 0.6 0.06 2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1Nickel µg/L 1 11 11 1000 34 14 14 9 13 24 58 41 72 7 34 47 9 38Nickel (Filtered) µg/L 1 11 11 1000 19 4 8 6 14 15 32 31 70 6 21 14 5 3Selenium µg/L 10 11 5 20 <10 <10 <10 <10 <10 <10 10 10 <10 <10 10 20 <10 10Selenium (Filtered) µg/L 10 11 5 20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10Vanadium µg/L 10 70 40 20 <10 <10 50 180 50 50 <10 80 210 20 230Vanadium (Filtered) µg/L 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10Zinc µg/L 5 8 8 20000 109 52 61 60 79 222 213 184 213 50 85 138 52 153Zinc (Filtered) µg/L 5 8 8 20000 41 47 40 49 80 158 96 159 190 50 42 29 35 11
InorganicspH (lab) pH Units 0.01 6.36 6.65 6.64 7.41 7.39 7.12 7.15 6.27 4.61 7.34 5.98 6.96 7.66 7.89Reactive Phosphorus as P mg/L 0.01 <0.01 <0.01 <0.01 <0.01 0.07 <0.01 0.02 0.02 <0.01 0.01 <0.01 <0.01 0.02 <0.01TDS mg/L 10 35000 - - - - - - - - - - - - - - TDS (Filtered) mg/L 10 35000 8470 2700 7710 5420 6450 6640 7850 4150 4040 7350 4000 4660 7540 4870TOC mg/L 1 4 2 3 16 4 8 29 18 7 5 3 4 6 5TSS mg/L 5 2210 1490 161 286 90 1670 8830 2580 2190 70 1400 6010 560 7990
TRH - NEPM 2013 FractionsTRH >C6 - C10 µg/L 20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20TRH >C10 - C16 µg/L 100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100TRH >C16 - C34 µg/L 100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100TRH >C34 - C40 µg/L 100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100TRH >C10 - C40 (Sum of total) µg/L 100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100TRH >C6 - C10 less BTEX (F1) mg/L 0.02 6 6 7 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02TRH >C10 - C16 less Naphthalene (F2) mg/L 0.1 NL NL NL <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
ANZECC 2000 Stock Watering
ANZECC 1992 Industrial Water
Use
NEPM 2013 Table 1C GILs, Fresh Waters
CRCCARE No.38 Freshwater 95%
ESL (interim, 2017)
CRCCARE No.38 Freshwater 99%
ESL (interim, 2017)
ANZECC 2000 FW 95%
NEPM 2013 Table 1A(4) HSL D GW, Sand for Vapour
Intrusion
Table 1Analytical Summary Table, Groundwater Monitoring Event, February 2017
Page 1 of 6
Table 1 - Analytical Summary Table, Groundwater Monitoring Event, February 2017 Energy Brix Australia Corporation, Morwell Power Station and Briquetting Facilities
Location Code GW01 GW02 GW03 GW04 GW05 GW06 GW07 GW08 GW09 GW10 GW11 GW12 GW13 GW14Field ID GW01 GW02 GW03 GW04 GW05 GW06 GW07 GW08 GW09 GW10 GW11 GW12 GW13 GW14
Sample Date 27/02/2017 27/02/2017 27/02/2017 27/02/2017 2/03/2017 2/03/2017 2/03/2017 1/03/2017 1/03/2017 28/02/2017 28/02/2017 28/02/2017 28/02/2017 2/03/2017Lab Report Number EM1702240 EM1702240 EM1702240 EM1702240 EM1702389 EM1702389 EM1702389 EM1702312 EM1702312 EM1702240 EM1702240 EM1702240 EM1702240 EM1702389
Sample_Type Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal
Chem name Units EQL 2-4m 4-8m >8m
ANZECC 2000 Stock Watering
ANZECC 1992 Industrial Water
Use
NEPM 2013 Table 1C GILs, Fresh Waters
CRCCARE No.38 Freshwater 95%
ESL (interim, 2017)
CRCCARE No.38 Freshwater 99%
ESL (interim, 2017)
ANZECC 2000 FW 95%
NEPM 2013 Table 1A(4) HSL D GW, Sand for Vapour
Intrusion
Table 1Analytical Summary Table, Groundwater Monitoring Event, February 2017
TPH - NEPM 1999 FractionsTPH C6 - C9 µg/L 20 <20 <20 <20 <20 <20 <20 <20 20 <20 <20 <20 <20 <20 <20TPH C10 - C14 µg/L 50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50TPH C15 - C28 µg/L 100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100TPH C29-C36 µg/L 50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50TPH C10 - C36 (Sum of total) µg/L 50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
BTEXBenzene µg/L 1 950 5000 5000 5000 950 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1Ethylbenzene µg/L 2 NL NL NL <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2Toluene µg/L 2 NL NL NL <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2Total BTEX mg/L 0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Xylene (m & p) µg/L 2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2Xylene (o) µg/L 2 350 350 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2Xylene Total µg/L 2 NL NL NL <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
PAHsPolycylic aromatic hydrocarbons EPA448 µg/L 0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Benzo[b+j]fluoranthene mg/L 0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Acenaphthene µg/L 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1Acenaphthylene µg/L 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1Anthracene µg/L 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1Benz(a)anthracene µg/L 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1Benzo(a) pyrene µg/L 0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Benzo(a)pyrene TEQ (zero) µg/L 0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Benzo(g,h,i)perylene µg/L 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1Benzo(k)fluoranthene µg/L 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1Chrysene µg/L 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1Dibenz(a,h)anthracene µg/L 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1Fluoranthene µg/L 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1Fluorene µg/L 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1Indeno(1,2,3-c,d)pyrene µg/L 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1Naphthalene µg/L 1 16 NL NL NL 16 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1PAHs (Sum of total) µg/L 1 - - - - - - - - - - - - - - Phenanthrene µg/L 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1Pyrene µg/L 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Chlorinated Hydrocarbons1,1,1,2-tetrachloroethane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51,1,1-trichloroethane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51,1,2,2-tetrachloroethane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51,1,2-trichloroethane µg/L 5 6500 6500 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51,1-dichloroethane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51,1-dichloroethene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51,2,3-trichloropropane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51,2-dibromo-3-chloropropane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51,2-dichloroethane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51,2-dichloropropane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51,3-dichloropropane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <52,2-dichloropropane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Bromochloromethane µg/L 1 - - - - - - - - - - - - - - Bromodichloromethane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Bromoform µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Carbon tetrachloride µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Chlorodibromomethane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Chloroethane µg/L 50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50Chloroform µg/L 5 12 <5 <5 <5 8 <5 <5 <5 9 <5 <5 <5 <5 <5Chloromethane µg/L 50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50cis-1,2-dichloroethene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5cis-1,3-dichloropropene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Dibromomethane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Dichloromethane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Hexachlorobutadiene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Trichloroethene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Tetrachloroethene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5trans-1,2-dichloroethene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5trans-1,3-dichloropropene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Vinyl chloride µg/L 50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Volatile Organics1,1-dichloropropene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
FieldTemp (Field) oC 19.2 18.7 17.9 17.7 22.4 20.1 20.3 20.3 19.8 18.5 19.5 17.5 19.6 16.6DO (Field) mg/L 1.78 1.47 0.46 1.02 5.25 0.2 0.16 6.07 11.98 2.02 0.12 4.19 5.13 5.73EC (field) uS/cm 10,591 2470 9455 8255 9978 8426 6948 5324 5647 8984 3808 5127 9757 6205pH (Field) pH_Units 6-8.3 5.78 6.39 6.26 6.82 6.33 6.19 6.25 4.8 4.31 6.67 5.4 6.63 7.26 7.24Redox mV 504.3 453 166.1 82.9 170.1 26.7 67.1 241 372.5 140.6 206.3 177.6 137.6 84.7
Page 2 of 6
Table 1 - Analytical Summary Table, Groundwater Monitoring Event, February 2017 Energy Brix Australia Corporation, Morwell Power Station and Briquetting Facilities
Location Code GW01 GW02 GW03 GW04 GW05 GW06 GW07 GW08 GW09 GW10 GW11 GW12 GW13 GW14Field ID GW01 GW02 GW03 GW04 GW05 GW06 GW07 GW08 GW09 GW10 GW11 GW12 GW13 GW14
Sample Date 27/02/2017 27/02/2017 27/02/2017 27/02/2017 2/03/2017 2/03/2017 2/03/2017 1/03/2017 1/03/2017 28/02/2017 28/02/2017 28/02/2017 28/02/2017 2/03/2017Lab Report Number EM1702240 EM1702240 EM1702240 EM1702240 EM1702389 EM1702389 EM1702389 EM1702312 EM1702312 EM1702240 EM1702240 EM1702240 EM1702240 EM1702389
Sample_Type Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal
Chem name Units EQL 2-4m 4-8m >8m
ANZECC 2000 Stock Watering
ANZECC 1992 Industrial Water
Use
NEPM 2013 Table 1C GILs, Fresh Waters
CRCCARE No.38 Freshwater 95%
ESL (interim, 2017)
CRCCARE No.38 Freshwater 99%
ESL (interim, 2017)
ANZECC 2000 FW 95%
NEPM 2013 Table 1A(4) HSL D GW, Sand for Vapour
Intrusion
Table 1Analytical Summary Table, Groundwater Monitoring Event, February 2017
Halogenated Benzenes1,2,3-trichlorobenzene µg/L 5 10 3 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51,2,4-trichlorobenzene µg/L 5 170 85 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51,2-dichlorobenzene µg/L 5 160 160 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51,3-dichlorobenzene µg/L 5 260 260 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51,4-dichlorobenzene µg/L 5 60 60 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <52-chlorotoluene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <54-chlorotoluene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Bromobenzene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Chlorobenzene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
Halogenated Hydrocarbons1,2-dibromoethane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Bromomethane µg/L 50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50Dichlorodifluoromethane µg/L 50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50Iodomethane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Trichlorofluoromethane µg/L 50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
MAH1,2,4-trimethylbenzene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51,3,5-trimethylbenzene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Isopropylbenzene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5n-butylbenzene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5n-propylbenzene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5p-isopropyltoluene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5sec-butylbenzene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Styrene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5tert-butylbenzene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
SolventsMethyl Ethyl Ketone µg/L 50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <502-hexanone (MBK) µg/L 50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <504-Methyl-2-pentanone µg/L 50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50Acetone mg/L 0.001 - - - - - - - - - - - - - - Allyl chloride mg/L 0.001 - - - - - - - - - - - - - - Carbon disulfide µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Vinyl acetate µg/L 50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
VOCscis-1,4-Dichloro-2-butene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Pentachloroethane µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5trans-1,4-Dichloro-2-butene µg/L 5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
PerfluorochemicalsPerfluorooctanesulfonic acid (PFOS) µg/L 0.01 0.13 0.00023 0.06 <0.01 <0.01 0.03 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 0.11 <0.01Perfluorooctanoic acid (PFOA) µg/L 0.01 220 19 <0.01 <0.01 <0.01 0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01Perfluorooctanesulfonamide (PFOSA) µg/L 0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02Perfluoropentane sulfonic acid (PFPeS) ng/L 20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20Perfluoro-n-pentanoic acid (PFPeA) µg/L 0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.0210:2 Fluorotelomer sulfonic acid (10:2 FTS) µg/L 0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05Perfluorononanoic acid (PFNA) µg/L 0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02Perfluorohexanoic acid (PFHxA) µg/L 0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02Perfluorohexanesulfonic acid (PFHxS) µg/L 0.02 0.03 <0.02 <0.02 0.04 <0.02 <0.02 0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02Perfluoroheptanoic acid (PFHpA) µg/L 0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02Perfluorododecanoic acid (PFDoA) µg/L 0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02Perfluorodecanoic acid (PFDA) µg/L 0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02Perfluoroheptane sulfonic acid (PFHpS) ng/L 20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20Perfluorobutanesulfonic acid (PFBS) µg/L 0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02Perfluorodecanesulfonic acid (PFDS) µg/L 0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02Perfluorotetradecanoic aicd (PFTeDA) µg/L 0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05Perfluorotridecanoic acid (PFTrDA) µg/L 0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02Perfluoroundecanoic acid (PFUnA) µg/L 0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.021H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/L 0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05Perfluorobutanoic acid (PFBA) µg/L 0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.11H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/L 0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.056:2 Fluorotelomer Sulfonate (6:2 FtS) µg/L 0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05NEtFOSAA µg/L 0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05N-Et-FOSE µg/L 0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05N-Ethyl perfluorooctane sulfonamidoacetic acid (Et ng/L 20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20NMeFOSAA µg/L 0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05N-Me-FOSE µg/L 0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05N-Methyl perfluorooctane sulfonamidoacetic acid (M ng/L 20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20Sum of PFAS ng/L 10 90 <10 <10 80 <10 <10 40 <10 <10 <10 <10 <10 110 <10Sum of PFAS (WA DER List) ng/L 10 90 <10 <10 80 <10 <10 40 <10 <10 <10 <10 <10 110 <10Sum of PFHxS and PFOS ng/L 10 90 <10 <10 70 <10 <10 20 <10 <10 <10 <10 <10 110 <10
Page 3 of 6
Table 1 - Analytical Summary Table, Groundwater Monitoring Event, February 2017 Energy Brix Australia Corporation, Morwell Power Station and Briquetting Facilities
Location CodeField ID
Sample DateLab Report Number
Sample_Type
Chem name Units EQL 2-4m 4-8m >8mMajor ions
Alkalinity (Carbonate as CaCO3) mg/L 1Bicarbonate as CaCO3 mg/L 1Alkalinity (Hydroxide) as CaCO3 mg/L 1Alkalinity (total) as CaCO3 mg/L 1Anions Total meq/L 0.01Calcium mg/L 0.5 420Calcium (Filtered) mg/L 1 420Cations Total meq/L 0.01Chloride mg/L 1 19000Fluoride mg/L 0.1 2Ionic Balance % 0.01Magnesium mg/L 0.5Magnesium (Filtered) mg/L 1Potassium mg/L 0.5Potassium (Filtered) mg/L 1Sodium mg/L 0.5Sodium (Filtered) mg/L 1Sulphate mg/L 5 2700Sulphate (Filtered) mg/L 1 2700
Nitrogen compoundsAmmonia as N mg/L 0.01Nitrate (as N) mg/L 0.02 0.1581Sulfate as SO4 - Turbidimetric (Filtered) mg/L 1
MetalsArsenic µg/L 1 500Arsenic (Filtered) µg/L 1 500Barium µg/L 1Barium (Filtered) µg/L 1Beryllium µg/L 1Beryllium (Filtered) µg/L 1Boron µg/L 50 370 370 5000Boron (Filtered) µg/L 50 370 370 5000Cadmium µg/L 0.1 0.2 0.2 10Cadmium (Filtered) µg/L 0.1 0.2 0.2 10Chromium (hexavalent) µg/L 1 1 1Chromium (hexavalent) (Filtered) µg/L 10 1 1Chromium (III+VI) µg/L 1 1000Chromium (III+VI) (Filtered) µg/L 1 1000Chromium (Trivalent) µg/L 1Chromium (Trivalent) (Filtered) µg/L 1Cobalt µg/L 1 1000Cobalt (Filtered) µg/L 1 1000Copper µg/L 1 1.4 1.4 1000Copper (Filtered) µg/L 1 1.4 1.4 1000Lead µg/L 1 3.4 3.4 100Lead (Filtered) µg/L 1 3.4 3.4 100Manganese µg/L 1 1900 1900Manganese (Filtered) µg/L 1 1900 1900Mercury µg/L 0.1 0.6 0.06 2Mercury (Filtered) µg/L 0.1 0.6 0.06 2Nickel µg/L 1 11 11 1000Nickel (Filtered) µg/L 1 11 11 1000Selenium µg/L 10 11 5 20Selenium (Filtered) µg/L 10 11 5 20Vanadium µg/L 10Vanadium (Filtered) µg/L 10Zinc µg/L 5 8 8 20000Zinc (Filtered) µg/L 5 8 8 20000
InorganicspH (lab) pH Units 0.01Reactive Phosphorus as P mg/L 0.01TDS mg/L 10 35000TDS (Filtered) mg/L 10 35000TOC mg/L 1TSS mg/L 5
TRH - NEPM 2013 FractionsTRH >C6 - C10 µg/L 20TRH >C10 - C16 µg/L 100TRH >C16 - C34 µg/L 100TRH >C34 - C40 µg/L 100TRH >C10 - C40 (Sum of total) µg/L 100TRH >C6 - C10 less BTEX (F1) mg/L 0.02 6 6 7TRH >C10 - C16 less Naphthalene (F2) mg/L 0.1 NL NL NL
ANZECC 2000 Stock Watering
ANZECC 1992 Industrial Water
Use
NEPM 2013 Table 1C GILs, Fresh Waters
CRCCARE No.38 Freshwater 95%
ESL (interim, 2017)
CRCCARE No.38 Freshwater 99%
ESL (interim, 2017)
ANZECC 2000 FW 95%
NEPM 2013 Table 1A(4) HSL D GW, Sand for Vapour
Intrusion
Table 1Analytical Summary Table, Groundwater Monitoring Event, February 2017
GW16 GW17 GW18 GW19 GW20 GW03 GW03GW16 GW17 GW18 GW19 GW20 QA_002 QA_01 RB_001 RB_002 RB_003 RB_004 TB_001 TB_002 TB_003 TB_0041/03/2017 1/03/2017 1/03/2017 28/02/2017 2/03/2017 27/02/2017 27/02/2017 27/02/2017 28/02/2017 1/03/2017 3/03/2017 27/02/2017 28/02/2017 1/03/2017 2/03/2017EM1702312 EM1702312 EM1702312 EM1702240 EM1702389 536142 EM1702240 EM1702240 EM1702312 EM1702312 EM1702389 EM1702240 EM1702240 EM1702312 EM1702389Normal Normal Normal Normal Normal Interlab_D Field_D Rinsate Rinsate Rinsate Rinsate Trip_B Trip_B Trip_B Trip_B
<1 <1 <1 <1 <1 <10 <1 - - - - - - - - 128 78 296 508 65 410 376 - - - - - - - - <1 <1 <1 <1 <1 - <1 - - - - - - - -
128 78 296 508 65 - 376 - - - - - - - - 110 92.5 35.2 80.6 100 - 117 - - - - - - - - - - - - - 230 - - - - - - - - - 40 40 15 131 40 - 243 - - - - - - - -
97.6 84.8 33.4 80.8 94.1 - 110 - - - - - - - - 3720 3060 652 1140 3350 3600 3790 - - - - - - - - 0.4 0.2 0.4 0.3 0.2 - 0.3 - - - - - - - - 5.9 4.35 2.63 0.12 3.3 - 3.06 - - - - - - - - - - - - - 320 - - - - - - - - -
281 265 39 337 172 - 343 - - - - - - - - - - - - - 9.1 - - - - - - - - - 12 20 2 <1 4 - 7 - - - - - - - - - - - - - 1400 - - - - - - - - -
1660 1390 676 1070 1790 - 1590 - - - - - - - - - - - - - 100 - - - - - - - - - - - - 1840 - - 105 - - - - - - - -
0.36 0.13 0.11 0.36 0.03 0.04 0.04 - - - - - - - - - - - - - 0.07 - - - - - - - - -
115 222 524 - 228 - - - - - - - - - -
44 12 2 15 2 1 2 <1 <1 <1 <1 - - - - <1 <1 <1 7 <1 <1 <1 - - - - - - - -
1310 262 68 169 123 290 296 - - - - - - - - 201 71 48 82 94 270 237 - - - - - - - - 21 3 <1 2 1 <1 <1 - - - - - - - - <1 <1 <1 <1 <1 <1 <1 - - - - - - - -
<250 <50 <50 150 <50 <50 <50 - - - - - - - - 50 <50 <50 180 <50 <50 <50 - - - - - - - - 0.9 0.4 <0.1 <0.1 <0.1 <0.2 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - 0.2 0.4 <0.1 <0.1 <0.1 <0.2 <0.1 - - - - - - - - - - - - - <1 - - - - - - - - -
<10 <10 <10 <10 <10 - <10 - - - - - - - - 156 45 5 28 6 3 8 <1 <1 <1 <1 - - - - <1 <1 <1 2 1 <1 <1 - - - - - - - - - - - - - 3 - - - - - - - - - - - - - - <1 - - - - - - - - -
452 181 8 84 81 8 11 - - - - - - - - 109 124 4 69 72 7 6 - - - - - - - - 215 58 4 14 6 4 7 <1 <1 <1 <1 - - - -
2 <1 2 2 4 2 3 - - - - - - - - 196 47 2 15 5 2 4 <1 <1 <1 <1 - - - - <1 <1 <1 <1 <1 <1 <1 - - - - - - - -
470 305 91 405 111 280 201 - - - - - - - - 169 284 86 395 100 280 232 - - - - - - - - 0.2 0.5 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - -
<0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - - - 209 105 6 37 23 11 13 <1 <1 <1 <1 - - - - 39 54 4 27 20 9 9 - - - - - - - - 60 20 <10 20 <10 - <10 - - - - - - - -
<10 <10 <10 10 <10 - <10 - - - - - - - - 540 110 <10 80 20 9 20 - - - - - - - - <10 <10 <10 <10 <10 <5 <10 - - - - - - - - 799 377 44 76 162 62 68 <5 <5 <5 <5 - - - - 54 106 32 50 156 43 43 - - - - - - - -
6.86 7.18 8.18 6.25 6.87 7.3 6.7 - - - - - - - - 0.03 <0.01 <0.01 <0.01 <0.01 <0.05 <0.01 - - - - - - - -
- - - - - 5700 - - - - - - - - - 5850 5960 2290 6030 6220 - 8140 - - - - - - - -
11 8 16 173 6 <5 9 - - - - - - - - 66,000 9620 86 1490 455 120 190 - - - - - - - -
<20 <20 <20 <20 <20 <20 <20 - - - - <20 <20 <20 <20<100 <100 <100 <100 <100 <50 <100 - - - - - - - - 150 <100 <100 <100 <100 <100 <100 - - - - - - - -
<100 <100 <100 <100 <100 <100 <100 - - - - - - - - 150 <100 <100 <100 <100 - <100 - - - - - - - -
<0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 - - - - <0.02 <0.02 <0.02 <0.02<0.1 <0.1 <0.1 <0.1 <0.1 <0.05 <0.1 - - - - - - - -
Page 4 of 6
Table 1 - Analytical Summary Table, Groundwater Monitoring Event, February 2017 Energy Brix Australia Corporation, Morwell Power Station and Briquetting Facilities
Location CodeField ID
Sample DateLab Report Number
Sample_Type
Chem name Units EQL 2-4m 4-8m >8mMajor ions
ANZECC 2000 Stock Watering
ANZECC 1992 Industrial Water
Use
NEPM 2013 Table 1C GILs, Fresh Waters
CRCCARE No.38 Freshwater 95%
ESL (interim, 2017)
CRCCARE No.38 Freshwater 99%
ESL (interim, 2017)
ANZECC 2000 FW 95%
NEPM 2013 Table 1A(4) HSL D GW, Sand for Vapour
Intrusion
Table 1Analytical Summary Table, Groundwater Monitoring Event, February 2017
TPH - NEPM 1999 FractionsTPH C6 - C9 µg/L 20TPH C10 - C14 µg/L 50TPH C15 - C28 µg/L 100TPH C29-C36 µg/L 50TPH C10 - C36 (Sum of total) µg/L 50
BTEXBenzene µg/L 1 950 5000 5000 5000 950Ethylbenzene µg/L 2 NL NL NLToluene µg/L 2 NL NL NLTotal BTEX mg/L 0.001Xylene (m & p) µg/L 2Xylene (o) µg/L 2 350 350Xylene Total µg/L 2 NL NL NL
PAHsPolycylic aromatic hydrocarbons EPA448 µg/L 0.5Benzo[b+j]fluoranthene mg/L 0.001Acenaphthene µg/L 1Acenaphthylene µg/L 1Anthracene µg/L 1Benz(a)anthracene µg/L 1Benzo(a) pyrene µg/L 0.5Benzo(a)pyrene TEQ (zero) µg/L 0.5Benzo(g,h,i)perylene µg/L 1Benzo(k)fluoranthene µg/L 1Chrysene µg/L 1Dibenz(a,h)anthracene µg/L 1Fluoranthene µg/L 1Fluorene µg/L 1Indeno(1,2,3-c,d)pyrene µg/L 1Naphthalene µg/L 1 16 NL NL NL 16PAHs (Sum of total) µg/L 1Phenanthrene µg/L 1Pyrene µg/L 1
Chlorinated Hydrocarbons1,1,1,2-tetrachloroethane µg/L 51,1,1-trichloroethane µg/L 51,1,2,2-tetrachloroethane µg/L 51,1,2-trichloroethane µg/L 5 6500 65001,1-dichloroethane µg/L 51,1-dichloroethene µg/L 51,2,3-trichloropropane µg/L 51,2-dibromo-3-chloropropane µg/L 51,2-dichloroethane µg/L 51,2-dichloropropane µg/L 51,3-dichloropropane µg/L 52,2-dichloropropane µg/L 5Bromochloromethane µg/L 1Bromodichloromethane µg/L 5Bromoform µg/L 5Carbon tetrachloride µg/L 5Chlorodibromomethane µg/L 5Chloroethane µg/L 50Chloroform µg/L 5Chloromethane µg/L 50cis-1,2-dichloroethene µg/L 5cis-1,3-dichloropropene µg/L 5Dibromomethane µg/L 5Dichloromethane µg/L 5Hexachlorobutadiene µg/L 5Trichloroethene µg/L 5Tetrachloroethene µg/L 5trans-1,2-dichloroethene µg/L 5trans-1,3-dichloropropene µg/L 5Vinyl chloride µg/L 50
Volatile Organics1,1-dichloropropene µg/L 5
FieldTemp (Field) oCDO (Field) mg/LEC (field) uS/cmpH (Field) pH_Units 6-8.3Redox mV
GW16 GW17 GW18 GW19 GW20 GW03 GW03GW16 GW17 GW18 GW19 GW20 QA_002 QA_01 RB_001 RB_002 RB_003 RB_004 TB_001 TB_002 TB_003 TB_0041/03/2017 1/03/2017 1/03/2017 28/02/2017 2/03/2017 27/02/2017 27/02/2017 27/02/2017 28/02/2017 1/03/2017 3/03/2017 27/02/2017 28/02/2017 1/03/2017 2/03/2017EM1702312 EM1702312 EM1702312 EM1702240 EM1702389 536142 EM1702240 EM1702240 EM1702312 EM1702312 EM1702389 EM1702240 EM1702240 EM1702312 EM1702389Normal Normal Normal Normal Normal Interlab_D Field_D Rinsate Rinsate Rinsate Rinsate Trip_B Trip_B Trip_B Trip_B
<20 <20 <20 <20 <20 <20 <20 - - - - <20 <20 <20 <20<50 <50 <50 <50 <50 <50 <50 - - - - - - - - 130 <100 <100 <100 <100 <100 <100 - - - - - - - - <50 <50 <50 <50 <50 <100 <50 - - - - - - - - 130 <50 <50 <50 <50 <100 <50 - - - - - - - -
<1 <1 <1 <1 <1 <1 <1 - - - - <1 <1 <1 <1<2 <2 <2 <2 <2 <1 <2 - - - - <2 <2 <2 <2<2 <2 <2 <2 <2 <1 <2 - - - - <2 <2 <2 <2
<0.001 <0.001 <0.001 <0.001 <0.001 - <0.001 - - - - <0.001 <0.001 <0.001 <0.001<2 <2 <2 <2 <2 <2 <2 - - - - <2 <2 <2 <2<2 <2 <2 <2 <2 <1 <2 - - - - <2 <2 <2 <2<2 <2 <2 <2 <2 <3 <2 - - - - <2 <2 <2 <2
<0.5 <0.5 <0.5 <0.5 <0.5 - <0.5 - - - - - - - - <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 - - - - - - - -
<1 <1 <1 <1 <1 <1 <1 - - - - - - - - <1 <1 <1 <1 <1 <1 <1 - - - - - - - - <1 <1 <1 <1 <1 <1 <1 - - - - - - - - <1 <1 <1 <1 <1 <1 <1 - - - - - - - -
<0.5 <0.5 <0.5 <0.5 <0.5 <1 <0.5 - - - - - - - - <0.5 <0.5 <0.5 <0.5 <0.5 - <0.5 - - - - - - - - <1 <1 <1 <1 <1 <1 <1 - - - - - - - - <1 <1 <1 <1 <1 <1 <1 - - - - - - - - <1 <1 <1 <1 <1 <1 <1 - - - - - - - - <1 <1 <1 <1 <1 <1 <1 - - - - - - - - <1 <1 <1 <1 <1 <1 <1 - - - - - - - - <1 <1 <1 <1 <1 <1 <1 - - - - - - - - <1 <1 <1 <1 <1 <1 <1 - - - - - - - - <1 <1 <1 <1 <1 <1 <1 - - - - <5 <5 <5 <5 - - - - - <1 - - - - - - - - - <1 <1 <1 <1 <1 <1 <1 - - - - - - - - <1 <1 <1 <1 <1 <1 <1 - - - - - - - -
<5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 - <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 - <5 - - - - - - - - - - - - - <1 - - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - -
<50 <50 <50 <50 <50 <1 <50 - - - - - - - - 10 9 <5 <5 <5 <5 <5 - - - - - - - -
<50 <50 <50 <50 <50 <1 <50 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 - <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - -
<50 <50 <50 <50 <50 <1 <50 - - - - - - - -
<5 <5 <5 <5 <5 - <5 - - - - - - - -
16.8 16.6 17.3 19.3 22.7 - - - - - - - - - - 4.62 7.65 1.07 0.91 5.02 - - - - - - - - - - 8392 7201 2874 6236 9730 - - - - - - - - - - 7.07 6.34 6.72 6.15 5.84 - - - - - - - - - -
173.9 164.9 136.7 14.6 203.4 - - - - - - - - - -
Page 5 of 6
Table 1 - Analytical Summary Table, Groundwater Monitoring Event, February 2017 Energy Brix Australia Corporation, Morwell Power Station and Briquetting Facilities
Location CodeField ID
Sample DateLab Report Number
Sample_Type
Chem name Units EQL 2-4m 4-8m >8mMajor ions
ANZECC 2000 Stock Watering
ANZECC 1992 Industrial Water
Use
NEPM 2013 Table 1C GILs, Fresh Waters
CRCCARE No.38 Freshwater 95%
ESL (interim, 2017)
CRCCARE No.38 Freshwater 99%
ESL (interim, 2017)
ANZECC 2000 FW 95%
NEPM 2013 Table 1A(4) HSL D GW, Sand for Vapour
Intrusion
Table 1Analytical Summary Table, Groundwater Monitoring Event, February 2017
Halogenated Benzenes1,2,3-trichlorobenzene µg/L 5 10 31,2,4-trichlorobenzene µg/L 5 170 851,2-dichlorobenzene µg/L 5 160 1601,3-dichlorobenzene µg/L 5 260 2601,4-dichlorobenzene µg/L 5 60 602-chlorotoluene µg/L 54-chlorotoluene µg/L 5Bromobenzene µg/L 5Chlorobenzene µg/L 5
Halogenated Hydrocarbons1,2-dibromoethane µg/L 5Bromomethane µg/L 50Dichlorodifluoromethane µg/L 50Iodomethane µg/L 5Trichlorofluoromethane µg/L 50
MAH1,2,4-trimethylbenzene µg/L 51,3,5-trimethylbenzene µg/L 5Isopropylbenzene µg/L 5n-butylbenzene µg/L 5n-propylbenzene µg/L 5p-isopropyltoluene µg/L 5sec-butylbenzene µg/L 5Styrene µg/L 5tert-butylbenzene µg/L 5
SolventsMethyl Ethyl Ketone µg/L 502-hexanone (MBK) µg/L 504-Methyl-2-pentanone µg/L 50Acetone mg/L 0.001Allyl chloride mg/L 0.001Carbon disulfide µg/L 5Vinyl acetate µg/L 50
VOCscis-1,4-Dichloro-2-butene µg/L 5Pentachloroethane µg/L 5trans-1,4-Dichloro-2-butene µg/L 5
PerfluorochemicalsPerfluorooctanesulfonic acid (PFOS) µg/L 0.01 0.13 0.00023Perfluorooctanoic acid (PFOA) µg/L 0.01 220 19Perfluorooctanesulfonamide (PFOSA) µg/L 0.02Perfluoropentane sulfonic acid (PFPeS) ng/L 20Perfluoro-n-pentanoic acid (PFPeA) µg/L 0.0210:2 Fluorotelomer sulfonic acid (10:2 FTS) µg/L 0.05Perfluorononanoic acid (PFNA) µg/L 0.02Perfluorohexanoic acid (PFHxA) µg/L 0.02Perfluorohexanesulfonic acid (PFHxS) µg/L 0.02Perfluoroheptanoic acid (PFHpA) µg/L 0.02Perfluorododecanoic acid (PFDoA) µg/L 0.02Perfluorodecanoic acid (PFDA) µg/L 0.02Perfluoroheptane sulfonic acid (PFHpS) ng/L 20Perfluorobutanesulfonic acid (PFBS) µg/L 0.02Perfluorodecanesulfonic acid (PFDS) µg/L 0.02Perfluorotetradecanoic aicd (PFTeDA) µg/L 0.05Perfluorotridecanoic acid (PFTrDA) µg/L 0.02Perfluoroundecanoic acid (PFUnA) µg/L 0.021H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/L 0.05Perfluorobutanoic acid (PFBA) µg/L 0.11H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/L 0.056:2 Fluorotelomer Sulfonate (6:2 FtS) µg/L 0.05NEtFOSAA µg/L 0.05N-Et-FOSE µg/L 0.05N-Ethyl perfluorooctane sulfonamidoacetic acid (Et ng/L 20NMeFOSAA µg/L 0.05N-Me-FOSE µg/L 0.05N-Methyl perfluorooctane sulfonamidoacetic acid (M ng/L 20Sum of PFAS ng/L 10Sum of PFAS (WA DER List) ng/L 10Sum of PFHxS and PFOS ng/L 10
GW16 GW17 GW18 GW19 GW20 GW03 GW03GW16 GW17 GW18 GW19 GW20 QA_002 QA_01 RB_001 RB_002 RB_003 RB_004 TB_001 TB_002 TB_003 TB_0041/03/2017 1/03/2017 1/03/2017 28/02/2017 2/03/2017 27/02/2017 27/02/2017 27/02/2017 28/02/2017 1/03/2017 3/03/2017 27/02/2017 28/02/2017 1/03/2017 2/03/2017EM1702312 EM1702312 EM1702312 EM1702240 EM1702389 536142 EM1702240 EM1702240 EM1702312 EM1702312 EM1702389 EM1702240 EM1702240 EM1702312 EM1702389Normal Normal Normal Normal Normal Interlab_D Field_D Rinsate Rinsate Rinsate Rinsate Trip_B Trip_B Trip_B Trip_B
<5 <5 <5 <5 <5 - <5 - - - - - - - - <5 <5 <5 <5 <5 - <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 - <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - -
<5 <5 <5 <5 <5 <1 <5 - - - - - - - - <50 <50 <50 <50 <50 <1 <50 - - - - - - - - <50 <50 <50 <50 <50 <1 <50 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - -
<50 <50 <50 <50 <50 <1 <50 - - - - - - - -
<5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 - <5 - - - - - - - - <5 <5 <5 <5 <5 - <5 - - - - - - - - <5 <5 <5 <5 <5 - <5 - - - - - - - - <5 <5 <5 <5 <5 - <5 - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - - <5 <5 <5 <5 <5 - <5 - - - - - - - -
<50 <50 <50 <50 <50 <1 <50 - - - - - - - - <50 <50 <50 <50 <50 - <50 - - - - - - - - <50 <50 <50 <50 <50 <1 <50 - - - - - - - - - - - - - <0.001 - - - - - - - - - - - - - - <0.001 - - - - - - - - - <5 <5 <5 <5 <5 <1 <5 - - - - - - - -
<50 <50 <50 <50 <50 - <50 - - - - - - - -
<5 <5 <5 <5 <5 - <5 - - - - - - - - <5 <5 <5 <5 <5 - <5 - - - - - - - - <5 <5 <5 <5 <5 - <5 - - - - - - - -
<0.05 <0.05 <0.05 <0.01 <0.01 <0.01 <0.01 - - - - - - - - <0.05 <0.05 <0.05 <0.01 <0.01 <0.01 <0.01 - - - - - - - - <0.05 <0.05 <0.05 <0.02 <0.02 <0.05 <0.02 - - - - - - - - <50 <50 <50 <20 <20 <10 <20 - - - - - - - -
<0.05 <0.05 <0.05 <0.02 <0.02 <0.01 <0.02 - - - - - - - - <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.05 - - - - - - - - <0.05 <0.05 <0.05 <0.02 <0.02 <0.01 <0.02 - - - - - - - - <0.05 <0.05 <0.05 <0.02 <0.02 <0.01 <0.02 - - - - - - - - <0.05 <0.05 <0.05 <0.02 <0.02 <0.01 <0.02 - - - - - - - - <0.05 <0.05 <0.05 <0.02 <0.02 <0.01 <0.02 - - - - - - - - <0.05 <0.05 <0.05 <0.02 <0.02 <0.01 <0.02 - - - - - - - - <0.05 <0.05 <0.05 <0.02 <0.02 <0.01 <0.02 - - - - - - - - <50 <50 <50 <20 <20 <10 <20 - - - - - - - -
<0.05 <0.05 <0.05 <0.02 <0.02 <0.01 <0.02 - - - - - - - - <0.05 <0.05 <0.05 <0.02 <0.02 <0.01 <0.02 - - - - - - - - <0.12 <0.12 <0.12 <0.05 <0.05 0.01 <0.05 - - - - - - - - <0.05 <0.05 <0.05 <0.02 <0.02 <0.01 <0.02 - - - - - - - - <0.05 <0.05 <0.05 <0.02 <0.02 <0.01 <0.02 - - - - - - - - <0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.05 - - - - - - - - <0.2 <0.2 <0.2 <0.1 <0.1 <0.05 <0.1 - - - - - - - -
<0.05 <0.05 <0.05 <0.05 <0.05 <0.01 <0.05 - - - - - - - - <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 - - - - - - - - <0.12 <0.12 <0.12 <0.05 <0.05 <0.05 <0.05 - - - - - - - - <0.12 <0.12 <0.12 <0.05 <0.05 <0.05 <0.05 - - - - - - - - <50 <50 <50 <20 <20 <50 <20 - - - - - - - -
<0.12 <0.12 <0.12 <0.05 <0.05 <0.05 <0.05 - - - - - - - - <0.12 <0.12 <0.12 <0.05 <0.05 <0.05 <0.05 - - - - - - - - <50 <50 <50 <20 <20 <50 <20 - - - - - - - - <50 <50 <50 <10 <10 - <10 - - - - - - - - <50 <50 <50 <10 <10 - <10 - - - - - - - - <50 <50 <50 <10 <10 - <10 - - - - - - - -
Page 6 of 6
Table 2 - Quality Assurance/ Quality Control Relative Percentage Differences,
Groundwater Monitoring Event, February 2017
Energy Brix Australia Corporation, Morwell Power Station and Briquetting Facilities
Laboratory ALS ALS ALS EurofinsSample type Primay Primary replicate Primary Split replicateField ID GW03 QA_01 RPD GW03 QA_02 RPDSampled Date/Time27/02/2017 27/02/2017 27/02/2017 27/02/2017
Chem name Units EQLAnions and Cations Calcium (Filtered) mg/l 1 237 243 3 237Physiochemical parameters pH (lab) pH Units 0.01 : 0.1 (Interlab) 6.64 6.7 1 6.64 7.3 9Metals Arsenic µg/l 1 2 2 0 2 1 67 Arsenic (Filtered) µg/l 1 <1 <1 0 <1 <1 0 Barium µg/l 1 : 20 (Interlab) 288 296 3 288 290 1 Barium (Filtered) µg/l 1 : 20 (Interlab) 239 237 1 239 270 12 Beryllium µg/l 1 <1 <1 0 <1 <1 0 Beryllium (Filtered) µg/l 1 <1 <1 0 <1 <1 0 Boron µg/l 50 <50 <50 0 <50 <50 0 Boron (Filtered) µg/l 50 <50 <50 0 <50 <50 0 Cadmium µg/l 0.1 : 0.2 (Interlab) <0.1 <0.1 0 <0.1 <0.2 0 Cadmium (Filtered) µg/l 0.1 : 0.2 (Interlab) <0.1 <0.1 0 <0.1 <0.2 0 Chromium (hexavalent) (Filtered) µg/l 10 <10 <10 0 <10 Chromium (III+VI) µg/l 1 6 8 29 6 3 67 Chromium (III+VI) (Filtered) µg/l 1 <1 <1 0 <1 <1 0 Cobalt µg/l 1 10 11 10 10 8 22 Cobalt (Filtered) µg/l 1 6 6 0 6 7 15 Copper µg/l 1 6 7 15 6 4 40 Copper (Filtered) µg/l 1 2 3 40 2 2 0 Lead µg/l 1 4 4 0 4 2 67 Lead (Filtered) µg/l 1 <1 <1 0 <1 <1 0 Magnesium (Filtered) mg/l 1 344 343 0 344 Manganese µg/l 1 : 5 (Interlab) 194 201 4 194 280 36 Manganese (Filtered) µg/l 1 : 5 (Interlab) 301 232 26 301 280 7 Mercury µg/l 0.1 <0.1 <0.1 0 <0.1 <0.1 0 Mercury (Filtered) µg/l 0.1 <0.1 <0.1 0 <0.1 <0.1 0 Nickel µg/l 1 14 13 7 14 11 24 Nickel (Filtered) µg/l 1 8 9 12 8 9 12 Potassium (Filtered) mg/l 1 7 7 0 7 Selenium µg/l 10 <10 <10 0 <10 Selenium (Filtered) µg/l 10 <10 <10 0 <10 Vanadium µg/l 10 : 5 (Interlab) 20 20 0 20 9 76 Vanadium (Filtered) µg/l 10 : 5 (Interlab) <10 <10 0 <10 <5 0 Zinc µg/l 5 61 68 11 61 62 2 Zinc (Filtered) µg/l 5 40 43 7 40 43 7Inorganics Alkalinity (Carbonate as CaCO3) mg/l 1 : 10 (Interlab) <1 <1 0 <1 <10 0 Bicarbonate as CaCO3 mg/l 1 : 20 (Interlab) 378 376 1 378 410 8 Alkalinity (Hydroxide) as CaCO3 mg/l 1 <1 <1 0 <1 Alkalinity (total) as CaCO3 mg/l 1 378 376 1 378 Ammonia as N mg/l 0.01 0.04 0.04 0 0.04 0.04 0 Anions Total meq/L 0.01 122 117 4 122 Cations Total meq/L 0.01 111 110 1 111 Chloride mg/l 1 3980 3790 5 3980 3600 10 Fluoride mg/l 0.1 0.3 0.3 0 0.3 Ionic Balance % 0.01 4.82 3.06 45 4.82 Reactive Phosphorus as P mg/l 0.01 : 0.05 (Interlab)<0.01 <0.01 0 <0.01 <0.05 0 Sodium (Filtered) mg/l 1 1620 1590 2 1620 Sulphate (Filtered) mg/l 1 105 105 0 105 TDS (Filtered) mg/l 10 7710 8140 5 7710 TOC mg/l 1 : 5 (Interlab) 3 9 76 3 <5 0 TSS mg/l 5 : 1 (Interlab) 161 190 17 161 120 29TRH - NEPM 2013 Fractions TRH >C6 - C10 µg/L 20 <20 <20 0 <20 <20 0 TRH >C10 - C16 µg/L 100 : 50 (Interlab) <100 <100 0 <100 <50 0 TRH >C16 - C34 µg/L 100 <100 <100 0 <100 <100 0 TRH >C34 - C40 µg/L 100 <100 <100 0 <100 <100 0 TRH >C10 - C40 (Sum of total) µg/L 100 <100 <100 0 <100 TRH >C6 - C10 less BTEX (F1) mg/l 0.02 <0.02 <0.02 0 <0.02 <0.02 0 TRH >C10 - C16 less Naphthalene (F2) mg/l 0.1 : 0.05 (Interlab) <0.1 <0.1 0 <0.1 <0.05 0TPH - NEPM 1999 Fractions TPH C6 - C9 µg/L 20 <20 <20 0 <20 <20 0 TPH C10 - C14 µg/L 50 <50 <50 0 <50 <50 0 TPH C15 - C28 µg/L 100 <100 <100 0 <100 <100 0 TPH C29-C36 µg/L 50 : 100 (Interlab) <50 <50 0 <50 <100 0 TPH C10 - C36 (Sum of total) µg/L 50 : 100 (Interlab) <50 <50 0 <50 <100 0BTEXN Benzene µg/L 1 <1 <1 0 <1 <1 0 Ethylbenzene µg/L 2 : 1 (Interlab) <2 <2 0 <2 <1 0 Toluene µg/L 2 : 1 (Interlab) <2 <2 0 <2 <1 0 Total BTEX mg/l 0.001 <0.001 <0.001 0 <0.001 Xylene (m & p) µg/L 2 <2 <2 0 <2 <2 0 Xylene (o) µg/L 2 : 1 (Interlab) <2 <2 0 <2 <1 0 Xylene Total µg/L 2 : 3 (Interlab) <2 <2 0 <2 <3 0PAHs Benzo[b+j]fluoranthene mg/l 0.001 <0.001 <0.001 0 <0.001 <0.001 0 Polycylic aromatic hydrocarbons EPA448 µg/L 0.5 <0.5 <0.5 0 <0.5 Benzo(a) pyrene µg/L 0.5 : 1 (Interlab) <0.5 <0.5 0 <0.5 <1 0 Benzo(a)pyrene TEQ (zero) µg/L 0.5 <0.5 <0.5 0 <0.5 Phenanthrene µg/L 1 <1 <1 0 <1 <1 0 Pyrene µg/L 1 <1 <1 0 <1 <1 0Chlorinated Hydrocarbons 1,1,1,2-tetrachloroethane µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 1,1,1-trichloroethane µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 1,1,2,2-tetrachloroethane µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 1,1,2-trichloroethane µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 1,1-dichloroethane µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 1,1-dichloroethene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 1,2,3-trichloropropane µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 1,2-dibromo-3-chloropropane µg/L 5 <5 <5 0 <5 1,2-dichloroethane µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 1,2-dichloropropane µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 1,3-dichloropropane µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 2,2-dichloropropane µg/L 5 <5 <5 0 <5 Bromodichloromethane µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 Bromoform µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 Carbon tetrachloride µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 Chlorodibromomethane µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0
Table 2Quality Assurance/ Quality Control Relative Percentage Differences, Groundwater Monitoring Event, February 2017
Page 1 of 4
Table 2 - Quality Assurance/ Quality Control Relative Percentage Differences,
Groundwater Monitoring Event, February 2017
Energy Brix Australia Corporation, Morwell Power Station and Briquetting Facilities
Laboratory ALS ALS ALS EurofinsSample type Primay Primary replicate Primary Split replicateField ID GW03 QA_01 RPD GW03 QA_02 RPDSampled Date/Time27/02/2017 27/02/2017 27/02/2017 27/02/2017
Chem name Units EQL
Table 2Quality Assurance/ Quality Control Relative Percentage Differences, Groundwater Monitoring Event, February 2017
Chloroethane µg/L 50 : 1 (Interlab) <50 <50 0 <50 <1 0 Chloroform µg/L 5 <5 <5 0 <5 <5 0 Chloromethane µg/L 50 : 1 (Interlab) <50 <50 0 <50 <1 0 cis-1,2-dichloroethene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 cis-1,3-dichloropropene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 Dibromomethane µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 Dichloromethane µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 Hexachlorobutadiene µg/L 5 <5 <5 0 <5 Trichloroethene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 Tetrachloroethene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 trans-1,2-dichloroethene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 trans-1,3-dichloropropene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 Vinyl chloride µg/L 50 : 1 (Interlab) <50 <50 0 <50 <1 0Volatile Organics 1,1-dichloropropene µg/L 5 <5 <5 0 <5Halogenated Benzenes 1,2,3-trichlorobenzene µg/L 5 <5 <5 0 <5 1,2,4-trichlorobenzene µg/L 5 <5 <5 0 <5 1,2-dichlorobenzene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 1,3-dichlorobenzene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 1,4-dichlorobenzene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 2-chlorotoluene µg/L 5 <5 <5 0 <5 4-chlorotoluene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 Bromobenzene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 Chlorobenzene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0Halogenated Hydrocarbons 1,2-dibromoethane µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 Bromomethane µg/L 50 : 1 (Interlab) <50 <50 0 <50 <1 0 Dichlorodifluoromethane µg/L 50 : 1 (Interlab) <50 <50 0 <50 <1 0 Iodomethane µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 Trichlorofluoromethane µg/L 50 : 1 (Interlab) <50 <50 0 <50 <1 0MAH 1,2,4-trimethylbenzene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 1,3,5-trimethylbenzene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 Isopropylbenzene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 n-butylbenzene µg/L 5 <5 <5 0 <5 n-propylbenzene µg/L 5 <5 <5 0 <5 p-isopropyltoluene µg/L 5 <5 <5 0 <5 sec-butylbenzene µg/L 5 <5 <5 0 <5 Styrene µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 tert-butylbenzene µg/L 5 <5 <5 0 <5PAH/Phenols Acenaphthene µg/L 1 <1 <1 0 <1 <1 0 Acenaphthylene µg/L 1 <1 <1 0 <1 <1 0 Anthracene µg/L 1 <1 <1 0 <1 <1 0 Benz(a)anthracene µg/L 1 <1 <1 0 <1 <1 0 Benzo(g,h,i)perylene µg/L 1 <1 <1 0 <1 <1 0 Benzo(k)fluoranthene µg/L 1 <1 <1 0 <1 <1 0 Chrysene µg/L 1 <1 <1 0 <1 <1 0 Dibenz(a,h)anthracene µg/L 1 <1 <1 0 <1 <1 0 Fluoranthene µg/L 1 <1 <1 0 <1 <1 0 Fluorene µg/L 1 <1 <1 0 <1 <1 0 Indeno(1,2,3-c,d)pyrene µg/L 1 <1 <1 0 <1 <1 0 Naphthalene µg/L 5 : 10 (Interlab) <5 <5 0 <5 <1 0 Naphthalene µg/L 1 : 10 (Interlab) <1 <1 0 <1 <1 0Solvents Methyl Ethyl Ketone µg/L 50 : 1 (Interlab) <50 <50 0 <50 <1 0 2-hexanone (MBK) µg/L 50 <50 <50 0 <50 4-Methyl-2-pentanone µg/L 50 : 1 (Interlab) <50 <50 0 <50 <1 0 Carbon disulfide µg/L 5 : 1 (Interlab) <5 <5 0 <5 <1 0 Vinyl acetate µg/L 50 <50 <50 0 <50VOCs cis-1,4-Dichloro-2-butene µg/L 5 <5 <5 0 <5 Pentachloroethane µg/L 5 <5 <5 0 <5 trans-1,4-Dichloro-2-butene µg/L 5 <5 <5 0 <5Perfluorochemicals Perfluorooctanesulfonic acid (PFOS) mg/l 1e-005 <0.00001 <0.00001 0 <0.00001 <0.00001 0 Perfluorooctanoic acid (PFOA) mg/l 1e-005 <0.00001 <0.00001 0 <0.00001 <0.00001 0 Perfluorooctanesulfonamide (PFOSA) mg/l 2e-005 : 5e-005 (Interlab)<0.00002 <0.00002 0 <0.00002 <0.00005 0 Perfluoropentane sulfonic acid (PFPeS) mg/kg 20 : 10 (Interlab) <20 <20 0 <20 <10 0 Perfluoro-n-pentanoic acid (PFPeA) mg/l 2e-005 : 1e-005 (Interlab)<0.00002 <0.00002 0 <0.00002 <0.00001 0 10:2 Fluorotelomer sulfonic acid (10:2 FTS) mg/l 5e-005 : 1e-005 (Interlab)<0.00005 <0.00005 0 <0.00005 <0.00001 0 Perfluorononanoic acid (PFNA) mg/l 2e-005 : 1e-005 (Interlab)<0.00002 <0.00002 0 <0.00002 <0.00001 0 Perfluorohexanoic acid (PFHxA) mg/l 2e-005 : 1e-005 (Interlab)<0.00002 <0.00002 0 <0.00002 <0.00001 0 Perfluorohexanesulfonic acid (PFHxS) µg/L 0.02 : 0.01 (Interlab)<0.02 <0.02 0 <0.02 <0.01 0 Perfluoroheptanoic acid (PFHpA) mg/l 2e-005 : 1e-005 (Interlab)<0.00002 <0.00002 0 <0.00002 <0.00001 0 Perfluorododecanoic acid (PFDoA) mg/l 2e-005 : 1e-005 (Interlab)<0.00002 <0.00002 0 <0.00002 <0.00001 0 Perfluorodecanoic acid (PFDA) mg/l 2e-005 : 1e-005 (Interlab)<0.00002 <0.00002 0 <0.00002 <0.00001 0 Perfluoroheptane sulfonic acid (PFHpS) mg/kg 20 : 10 (Interlab) <20 <20 0 <20 <10 0 Perfluorobutanesulfonic acid (PFBS) mg/l 2e-005 : 1e-005 (Interlab)<0.00002 <0.00002 0 <0.00002 <0.00001 0 Perfluorodecanesulfonic acid (PFDS) mg/l 2e-005 : 1e-005 (Interlab)<0.00002 <0.00002 0 <0.00002 <0.00001 0 Perfluorotetradecanoic aicd (PFTeDA) mg/l 5e-005 : 1e-005 (Interlab)<0.00005 <0.00005 0 <0.00005 0.00001 0 Perfluorotridecanoic acid (PFTrDA) mg/l 2e-005 : 1e-005 (Interlab)<0.00002 <0.00002 0 <0.00002 <0.00001 0 Perfluoroundecanoic acid (PFUnA) mg/l 2e-005 : 1e-005 (Interlab)<0.00002 <0.00002 0 <0.00002 <0.00001 0 1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) mg/l 5e-005 : 1e-005 (Interlab)<0.00005 <0.00005 0 <0.00005 <0.00001 0 Perfluorobutanoic acid (PFBA) mg/l 0.0001 : 5e-005 (Interlab)<0.0001 <0.0001 0 <0.0001 <0.00005 0 1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) mg/l 5e-005 : 1e-005 (Interlab)<0.00005 <0.00005 0 <0.00005 <0.00001 0 6:2 Fluorotelomer Sulfonate (6:2 FtS) mg/l 5e-005 <0.00005 <0.00005 0 <0.00005 <0.00005 0 NEtFOSAA µg/L 0.05 <0.05 <0.05 0 <0.05 <0.05 0 N-Et-FOSE µg/L 0.05 <0.05 <0.05 0 <0.05 <0.05 0 N-Ethyl perfluorooctane sulfonamidoacetic acid (Et mg/kg 20 : 50 (Interlab) <20 <20 0 <20 <50 0 NMeFOSAA mg/l 5e-005 <0.00005 <0.00005 0 <0.00005 <0.00005 0 N-Me-FOSE µg/L 0.05 <0.05 <0.05 0 <0.05 <0.05 0 N-Methyl perfluorooctane sulfonamidoacetic acid (M mg/kg 20 : 50 (Interlab) <20 <20 0 <20 <50 0 Sum of PFAS mg/kg 10 <10 <10 0 <10 Sum of PFAS (WA DER List) mg/kg 10 <10 <10 0 <10 Sum of PFHxS and PFOS mg/kg 10 <10 <10 0 <10*RPDs have only been considered where a concentration is greater than 1 times the EQL.**High RPDs are in bold (Acceptable RPDs for each EQL multiplier range are: 80 (1-10 x EQL); 50 (10-30 x EQL); 30 ( > 30 x EQL) )***Interlab Duplicates are matched on a per compound basis as methods vary between laboratories. Any methods in the row header relate to those used in the primary laboratory
Page 2 of 4
Table 3 - Rinsate and Trip Blank Data Summary TableGroundwater Monitoring Event, February 2017
Energy Brix Australia CorporationMorwell Power Station and Briquetting Facilities
Field ID RB_001 RB_002 RB_003 RB_004 TB_001 TB_002 TB_003 TB_004Sample Date 27/02/2017 28/02/2017 1/03/2017 3/03/2017 27/02/2017 28/02/2017 1/03/2017 2/03/2017
Lab Report Number EM1702240 EM1702312 EM1702312 EM1702389 EM1702240 EM1702240 EM1702312 EM1702389Sample Type Rinsate Rinsate Rinsate Rinsate Trip_B Trip_B Trip_B Trip_B
Chem name Units EQLMetals
Arsenic µg/L 1 <1 <1 <1 <1 - - - - Barium µg/L 1 - - - - - - - - Beryllium µg/L 1 - - - - - - - - Boron µg/L 50 - - - - - - - - Cadmium µg/L 0.1 <0.1 <0.1 <0.1 <0.1 - - - - Chromium (hexavalent) µg/L 1 - - - - - - - - Chromium (III+VI) µg/L 1 <1 <1 <1 <1 - - - - Chromium (Trivalent) µg/L 1 - - - - - - - - Cobalt µg/L 1 - - - - - - - - Copper µg/L 1 <1 <1 <1 <1 - - - - Lead µg/L 1 <1 <1 <1 <1 - - - - Manganese µg/L 1 - - - - - - - - Mercury µg/L 0.1 <0.1 <0.1 <0.1 <0.1 - - - - Nickel µg/L 1 <1 <1 <1 <1 - - - - Selenium µg/L 10 - - - - - - - - Vanadium µg/L 10 - - - - - - - - Zinc µg/L 5 <5 <5 <5 <5 - - - -
TRH - NEPM 2013 FractionsTRH >C6 - C10 µg/L 20 - - - - <20 <20 <20 <20TRH >C10 - C16 µg/L 100 - - - - - - - - TRH >C16 - C34 µg/L 100 - - - - - - - - TRH >C34 - C40 µg/L 100 - - - - - - - - TRH >C10 - C40 (Sum of total) µg/L 100 - - - - - - - - TRH >C6 - C10 less BTEX (F1) mg/L 0.02 - - - - <0.02 <0.02 <0.02 <0.02TRH >C10 - C16 less Naphthalene (F2) mg/L 0.1 - - - - - - - -
TPH - NEPM 1999 FractionsTPH C6 - C9 µg/L 20 - - - - <20 <20 <20 <20TPH C10 - C14 µg/L 50 - - - - - - - - TPH C15 - C28 µg/L 100 - - - - - - - - TPH C29-C36 µg/L 50 - - - - - - - - TPH C10 - C36 (Sum of total) µg/L 50 - - - - - - - -
BTEXBenzene µg/L 1 - - - - <1 <1 <1 <1Ethylbenzene µg/L 2 - - - - <2 <2 <2 <2Toluene µg/L 2 - - - - <2 <2 <2 <2Total BTEX mg/L 0.001 - - - - <0.001 <0.001 <0.001 <0.001Xylene (m & p) µg/L 2 - - - - <2 <2 <2 <2Xylene (o) µg/L 2 - - - - <2 <2 <2 <2Xylene Total µg/L 2 - - - - <2 <2 <2 <2
PAHsNaphthalene µg/L 1 - - - - <5 <5 <5 <5
Table 3Rinsate and Trip Blank Data Summary Table, Groundwater Monitoring Event, February 2017
Page 1 of 2
19 September 2017Subject: Groundwater Monitoring Event February 2017
IS157700-03-NP-LTR-0002 6
ReferencesANZECC, 1992. Australian water quality guidelines for fresh and marine waters. Australian and New
Zealand Environment and Conservation Council, Canberra.ANZECC, ARMCANZ, 2000a. Australian and New Zealand guidelines for fresh and marine water
quality: Volume 1, The Guidelines. Australian and New Zealand Environment andConservation Council and Agriculture and Resource Management Council of Australia andNew Zealand, Canberra.
ANZECC, ARMCANZ, 2000b. Australian and New Zealand guidelines for fresh and marine waterquality: Volume 3, Primary Industries- Rationale and background Information (Irrigation andgeneral water uses, stock drinking water, aquaculture and human consumers of aquaticfoods). Australian and New Zealand Environment and Conservation Council and Agricultureand Resource Management Council of Australia and New Zealand, Canberra.
CRC CARE, 2017. Technical Report No. 38: Assessment, management and remediation for PFOSand PFOA Part 3: ecological screening levels, Technical Report Series.
GHD, 2016. Former Morwell Power Station: Phase 2 Environmental Site Assessment (No. 3134501-NaN-0). GHD, Melbourne, Vic.
Jacobs, 2016. Morwell Power Station and Briquetting Facilities - Environmental Site Assessment:Phase 1 Environmental Site Assessment (ESA) and Sampling & Analysis Quality Plan(SAQP) Report (No. IS155700-NaN-NaN-0000). Jacobs Group (Australia) Pty Limited,Melbourne, Vic.
NEPC, 2013. National Environment Protection (Assessment of Site Contamination) MeasureSchedule B1 1999, 2013 Amended. National Environment Protection Council ServiceCorporation, Canberra, A.C.T.
Standards Australia, 2005. AS 4482.1-2005 Guide to the investigation and sampling of sites withpotentially contaminated soil Part 1: Non-volatile and semi-volatile compounds. StandardsAustralia, Sydney, N.S.W.
19 September 2017Subject: Groundwater Monitoring Event February 2017
IS157700-03-NP-LTR-0002 7
Attachment 1 – Laboratory certificates
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 20EM1702240
:: LaboratoryClient JACOBS GROUP (AUSTRALIA) PTY LTD Environmental Division Melbourne
: :ContactContact MR BENJAMIN GRASSO Carol Walsh
:: AddressAddress P O BOX 312 FLINDERS LANE
MELBOURNE VIC AUSTRALIA 8009
4 Westall Rd Springvale VIC Australia 3171
:Telephone +61 03 8668 3000 :Telephone +61-3-8549 9608
:Project IS157700 Date Samples Received : 01-Mar-2017 11:05
:Order number ---- Date Analysis Commenced : 01-Mar-2017
:C-O-C number ---- Issue Date : 08-Mar-2017 15:20
Sampler : BENJAMIN GRASSO
Site : ----
Quote number : ME/088/17
13:No. of samples received
13:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:
l General Comments
l Analytical Results
l Surrogate Control Limits
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with
Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Alex Rossi Organic Chemist Sydney Organics, Smithfield, NSW
Dilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VIC
Eric Chau Metals Team Leader Melbourne Inorganics, Springvale, VIC
Nikki Stepniewski Senior Inorganic Instrument Chemist Melbourne Inorganics, Springvale, VIC
Xing Lin Senior Organic Chemist Melbourne Organics, Springvale, VIC
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Work Order :
:Client
EM1702240
IS157700:Project
JACOBS GROUP (AUSTRALIA) PTY LTD
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When no sampling time is provided, the sampling time will default 00:00 on the date of sampling. If no sampling date is provided, the sampling date will be assumed by the laboratory and displayed in brackets without a
time component.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
^ = This result is computed from individual analyte detections at or above the level of reporting
ø = ALS is not NATA accredited for these tests.
~ = Indicates an estimated value.
Key :
It is recognised that total metals is less than dissolved metals for samples #4, #9 & #10. However, the difference is within experimental variation of the methods.l
EP005: Total organic carbon for EM1702240 #9 has been confirmed by re-preparation and re-analysis.l
It is recognised that total arsenic is less than dissolved arsenic for samples #3. However, the difference is within experimental variation of the methods.l
EG020F&T: Filtered and total manganese results for EM1702240-003 and 009 have been confirmed by re-preparation and re-analysis.l
TDS by method EA-015 may bias high for EM1702240 #1, 2, 3, 4, 5, 6, 7, 8, 9 and 10 due to the presence of fine particulate matter, which may pass through the prescribed GF/C paper.l
Ionic balances were calculated using: major anions - chloride, alkalinity and sulfate; and major cations - calcium, magnesium, potassium and sodium.l
ED045G: The presence of thiocyanate can positively contribute to the chloride result, thereby may bias results higher than expected. Results should be scrutinised accordingly.l
Benzo(a)pyrene Toxicity Equivalent Quotient (TEQ) is the sum total of the concentration of the eight carcinogenic PAHs multiplied by their Toxicity Equivalence Factor (TEF) relative to Benzo(a)pyrene. TEF values
are provided in brackets as follows: Benz(a)anthracene (0.1), Chrysene (0.01), Benzo(b+j) & Benzo(k)fluoranthene (0.1), Benzo(a)pyrene (1.0), Indeno(1.2.3.cd)pyrene (0.1), Dibenz(a.h)anthracene (1.0),
Benzo(g.h.i)perylene (0.01). Less than LOR results for 'TEQ Zero' are treated as zero.
l
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:Client
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IS157700:Project
JACOBS GROUP (AUSTRALIA) PTY LTD
Analytical Results
GW10GW04GW03GW02GW01Client sample IDSub-Matrix: WATER
(Matrix: WATER)
28-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:00Client sampling date / time
EM1702240-005EM1702240-004EM1702240-003EM1702240-002EM1702240-001UnitLORCAS NumberCompound
Result Result Result Result Result
EA005P: pH by PC Titrator
6.36 6.65 6.64 7.41 7.34pH Unit0.01----pH Value
EA015: Total Dissolved Solids dried at 180 ± 5 °C
8470 2700 7710 5420 7350mg/L10----Total Dissolved Solids @180°C
EA025: Total Suspended Solids dried at 104 ± 2°C
2210 1490 161 286 70mg/L5----Suspended Solids (SS)
ED037P: Alkalinity by PC Titrator
<1Hydroxide Alkalinity as CaCO3 <1 <1 <1 <1mg/L1DMO-210-001
<1Carbonate Alkalinity as CaCO3 <1 <1 <1 <1mg/L13812-32-6
106Bicarbonate Alkalinity as CaCO3 166 378 1460 472mg/L171-52-3
106 166 378 1460 472mg/L1----Total Alkalinity as CaCO3
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
66Sulfate as SO4 - Turbidimetric 11 105 213 194mg/L114808-79-8
ED045G: Chloride by Discrete Analyser
4470Chloride 867 3980 2600 3550mg/L116887-00-6
ED093F: Dissolved Major Cations
86Calcium 48 237 91 229mg/L17440-70-2
217Magnesium 74 344 180 313mg/L17439-95-4
2350Sodium 429 1620 1760 1550mg/L17440-23-5
2Potassium 3 7 14 16mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS
<0.001Arsenic <0.001 <0.001 0.002 <0.001mg/L0.0017440-38-2
<0.05Boron <0.05 <0.05 0.07 <0.05mg/L0.057440-42-8
0.204Barium 1.01 0.239 0.314 0.177mg/L0.0017440-39-3
<0.001Beryllium <0.001 <0.001 <0.001 <0.001mg/L0.0017440-41-7
<0.0001Cadmium <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017440-43-9
0.064Cobalt 0.002 0.006 0.005 0.002mg/L0.0017440-48-4
0.001Chromium <0.001 <0.001 <0.001 <0.001mg/L0.0017440-47-3
0.002Copper 0.001 0.002 0.004 0.007mg/L0.0017440-50-8
0.026Manganese 0.058 0.301 0.476 0.038mg/L0.0017439-96-5
0.019Nickel 0.004 0.008 0.006 0.006mg/L0.0017440-02-0
<0.001Lead <0.001 <0.001 <0.001 <0.001mg/L0.0017439-92-1
<0.01Selenium <0.01 <0.01 <0.01 <0.01mg/L0.017782-49-2
<0.01Vanadium <0.01 <0.01 <0.01 <0.01mg/L0.017440-62-2
0.041Zinc 0.047 0.040 0.049 0.050mg/L0.0057440-66-6
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Analytical Results
GW10GW04GW03GW02GW01Client sample IDSub-Matrix: WATER
(Matrix: WATER)
28-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:00Client sampling date / time
EM1702240-005EM1702240-004EM1702240-003EM1702240-002EM1702240-001UnitLORCAS NumberCompound
Result Result Result Result Result
EG020T: Total Metals by ICP-MS
0.006Arsenic 0.002 0.002 0.003 <0.001mg/L0.0017440-38-2
<0.05Boron <0.05 <0.05 <0.05 <0.05mg/L0.057440-42-8
0.252Barium 1.27 0.288 0.349 0.204mg/L0.0017440-39-3
0.006Beryllium 0.001 <0.001 <0.001 <0.001mg/L0.0017440-41-7
<0.0001Cadmium <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017440-43-9
0.094Cobalt 0.018 0.010 0.007 0.003mg/L0.0017440-48-4
0.015Chromium 0.016 0.006 0.004 0.003mg/L0.0017440-47-3
0.024Copper 0.011 0.006 0.009 0.007mg/L0.0017440-50-8
0.123Manganese 0.129 0.194 0.479 0.043mg/L0.0017439-96-5
0.034Nickel 0.014 0.014 0.009 0.007mg/L0.0017440-02-0
0.022Lead 0.018 0.004 0.002 0.002mg/L0.0017439-92-1
<0.01Selenium <0.01 <0.01 <0.01 <0.01mg/L0.017782-49-2
0.07Vanadium 0.04 0.02 <0.01 <0.01mg/L0.017440-62-2
0.109Zinc 0.052 0.061 0.060 0.050mg/L0.0057440-66-6
EG035F: Dissolved Mercury by FIMS
<0.0001Mercury <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017439-97-6
EG035T: Total Recoverable Mercury by FIMS
<0.0001Mercury <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017439-97-6
EG050F: Dissolved Hexavalent Chromium
<0.01Hexavalent Chromium <0.01 <0.01 <0.01 <0.01mg/L0.0118540-29-9
EK040P: Fluoride by PC Titrator
0.4Fluoride 0.3 0.3 0.7 0.5mg/L0.116984-48-8
EK055G: Ammonia as N by Discrete Analyser
0.03Ammonia as N <0.01 0.04 0.26 0.02mg/L0.017664-41-7
EK071G: Reactive Phosphorus as P by discrete analyser
<0.01Reactive Phosphorus as P <0.01 <0.01 <0.01 0.01mg/L0.0114265-44-2
EN055: Ionic Balance
130 28.0 122 107 114meq/L0.01----Total Anions
124 27.2 111 96.3 105meq/L0.01----Total Cations
2.03 1.41 4.82 5.26 3.93%0.01----Ionic Balance
EP005: Total Organic Carbon (TOC)
4 2 3 16 5mg/L1----Total Organic Carbon
EP074A: Monocyclic Aromatic Hydrocarbons
<5Styrene <5 <5 <5 <5µg/L5100-42-5
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Analytical Results
GW10GW04GW03GW02GW01Client sample IDSub-Matrix: WATER
(Matrix: WATER)
28-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:00Client sampling date / time
EM1702240-005EM1702240-004EM1702240-003EM1702240-002EM1702240-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP074A: Monocyclic Aromatic Hydrocarbons - Continued
<5Isopropylbenzene <5 <5 <5 <5µg/L598-82-8
<5n-Propylbenzene <5 <5 <5 <5µg/L5103-65-1
<51.3.5-Trimethylbenzene <5 <5 <5 <5µg/L5108-67-8
<5sec-Butylbenzene <5 <5 <5 <5µg/L5135-98-8
<51.2.4-Trimethylbenzene <5 <5 <5 <5µg/L595-63-6
<5tert-Butylbenzene <5 <5 <5 <5µg/L598-06-6
<5p-Isopropyltoluene <5 <5 <5 <5µg/L599-87-6
<5n-Butylbenzene <5 <5 <5 <5µg/L5104-51-8
EP074B: Oxygenated Compounds
<50Vinyl Acetate <50 <50 <50 <50µg/L50108-05-4
<502-Butanone (MEK) <50 <50 <50 <50µg/L5078-93-3
<504-Methyl-2-pentanone (MIBK) <50 <50 <50 <50µg/L50108-10-1
<502-Hexanone (MBK) <50 <50 <50 <50µg/L50591-78-6
EP074C: Sulfonated Compounds
<5Carbon disulfide <5 <5 <5 <5µg/L575-15-0
EP074D: Fumigants
<52.2-Dichloropropane <5 <5 <5 <5µg/L5594-20-7
<51.2-Dichloropropane <5 <5 <5 <5µg/L578-87-5
<5cis-1.3-Dichloropropylene <5 <5 <5 <5µg/L510061-01-5
<5trans-1.3-Dichloropropylene <5 <5 <5 <5µg/L510061-02-6
<51.2-Dibromoethane (EDB) <5 <5 <5 <5µg/L5106-93-4
EP074E: Halogenated Aliphatic Compounds
<50Dichlorodifluoromethane <50 <50 <50 <50µg/L5075-71-8
<50Chloromethane <50 <50 <50 <50µg/L5074-87-3
<50Vinyl chloride <50 <50 <50 <50µg/L5075-01-4
<50Bromomethane <50 <50 <50 <50µg/L5074-83-9
<50Chloroethane <50 <50 <50 <50µg/L5075-00-3
<50Trichlorofluoromethane <50 <50 <50 <50µg/L5075-69-4
<51.1-Dichloroethene <5 <5 <5 <5µg/L575-35-4
<5Iodomethane <5 <5 <5 <5µg/L574-88-4
<5Methylene chloride <5 <5 <5 <5µg/L575-09-2
<5trans-1.2-Dichloroethene <5 <5 <5 <5µg/L5156-60-5
<51.1-Dichloroethane <5 <5 <5 <5µg/L575-34-3
<5cis-1.2-Dichloroethene <5 <5 <5 <5µg/L5156-59-2
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Analytical Results
GW10GW04GW03GW02GW01Client sample IDSub-Matrix: WATER
(Matrix: WATER)
28-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:00Client sampling date / time
EM1702240-005EM1702240-004EM1702240-003EM1702240-002EM1702240-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP074E: Halogenated Aliphatic Compounds - Continued
<51.1.1-Trichloroethane <5 <5 <5 <5µg/L571-55-6
<51.1-Dichloropropylene <5 <5 <5 <5µg/L5563-58-6
<5Carbon Tetrachloride <5 <5 <5 <5µg/L556-23-5
<51.2-Dichloroethane <5 <5 <5 <5µg/L5107-06-2
<5Trichloroethene <5 <5 <5 <5µg/L579-01-6
<5Dibromomethane <5 <5 <5 <5µg/L574-95-3
<51.1.2-Trichloroethane <5 <5 <5 <5µg/L579-00-5
<51.3-Dichloropropane <5 <5 <5 <5µg/L5142-28-9
<5Tetrachloroethene <5 <5 <5 <5µg/L5127-18-4
<51.1.1.2-Tetrachloroethane <5 <5 <5 <5µg/L5630-20-6
<5trans-1.4-Dichloro-2-butene <5 <5 <5 <5µg/L5110-57-6
<5cis-1.4-Dichloro-2-butene <5 <5 <5 <5µg/L51476-11-5
<51.1.2.2-Tetrachloroethane <5 <5 <5 <5µg/L579-34-5
<51.2.3-Trichloropropane <5 <5 <5 <5µg/L596-18-4
<5Pentachloroethane <5 <5 <5 <5µg/L576-01-7
<51.2-Dibromo-3-chloropropane <5 <5 <5 <5µg/L596-12-8
<5Hexachlorobutadiene <5 <5 <5 <5µg/L587-68-3
EP074F: Halogenated Aromatic Compounds
<5Chlorobenzene <5 <5 <5 <5µg/L5108-90-7
<5Bromobenzene <5 <5 <5 <5µg/L5108-86-1
<52-Chlorotoluene <5 <5 <5 <5µg/L595-49-8
<54-Chlorotoluene <5 <5 <5 <5µg/L5106-43-4
<51.3-Dichlorobenzene <5 <5 <5 <5µg/L5541-73-1
<51.4-Dichlorobenzene <5 <5 <5 <5µg/L5106-46-7
<51.2-Dichlorobenzene <5 <5 <5 <5µg/L595-50-1
<51.2.4-Trichlorobenzene <5 <5 <5 <5µg/L5120-82-1
<51.2.3-Trichlorobenzene <5 <5 <5 <5µg/L587-61-6
EP074G: Trihalomethanes
12Chloroform <5 <5 <5 <5µg/L567-66-3
<5Bromodichloromethane <5 <5 <5 <5µg/L575-27-4
<5Dibromochloromethane <5 <5 <5 <5µg/L5124-48-1
<5Bromoform <5 <5 <5 <5µg/L575-25-2
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
<1.0Naphthalene <1.0 <1.0 <1.0 <1.0µg/L191-20-3
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Analytical Results
GW10GW04GW03GW02GW01Client sample IDSub-Matrix: WATER
(Matrix: WATER)
28-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:00Client sampling date / time
EM1702240-005EM1702240-004EM1702240-003EM1702240-002EM1702240-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued
<1.0Acenaphthylene <1.0 <1.0 <1.0 <1.0µg/L1208-96-8
<1.0Acenaphthene <1.0 <1.0 <1.0 <1.0µg/L183-32-9
<1.0Fluorene <1.0 <1.0 <1.0 <1.0µg/L186-73-7
<1.0Phenanthrene <1.0 <1.0 <1.0 <1.0µg/L185-01-8
<1.0Anthracene <1.0 <1.0 <1.0 <1.0µg/L1120-12-7
<1.0Fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1206-44-0
<1.0Pyrene <1.0 <1.0 <1.0 <1.0µg/L1129-00-0
<1.0Benz(a)anthracene <1.0 <1.0 <1.0 <1.0µg/L156-55-3
<1.0Chrysene <1.0 <1.0 <1.0 <1.0µg/L1218-01-9
<1.0Benzo(b+j)fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1205-99-2 205-82-3
<1.0Benzo(k)fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1207-08-9
<0.5Benzo(a)pyrene <0.5 <0.5 <0.5 <0.5µg/L0.550-32-8
<1.0Indeno(1.2.3.cd)pyrene <1.0 <1.0 <1.0 <1.0µg/L1193-39-5
<1.0Dibenz(a.h)anthracene <1.0 <1.0 <1.0 <1.0µg/L153-70-3
<1.0Benzo(g.h.i)perylene <1.0 <1.0 <1.0 <1.0µg/L1191-24-2
<0.5^ <0.5 <0.5 <0.5 <0.5µg/L0.5----Sum of polycyclic aromatic hydrocarbons
<0.5^ <0.5 <0.5 <0.5 <0.5µg/L0.5----Benzo(a)pyrene TEQ (zero)
EP080/071: Total Petroleum Hydrocarbons
<20 <20 <20 <20 <20µg/L20----C6 - C9 Fraction
<50 <50 <50 <50 <50µg/L50----C10 - C14 Fraction
<100 <100 <100 <100 <100µg/L100----C15 - C28 Fraction
<50 <50 <50 <50 <50µg/L50----C29 - C36 Fraction
<50^ <50 <50 <50 <50µg/L50----C10 - C36 Fraction (sum)
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
<20C6 - C10 Fraction <20 <20 <20 <20µg/L20C6_C10
<20^ C6 - C10 Fraction minus BTEX
(F1)
<20 <20 <20 <20µg/L20C6_C10-BTEX
<100 <100 <100 <100 <100µg/L100---->C10 - C16 Fraction
<100 <100 <100 <100 <100µg/L100---->C16 - C34 Fraction
<100 <100 <100 <100 <100µg/L100---->C34 - C40 Fraction
<100^ <100 <100 <100 <100µg/L100---->C10 - C40 Fraction (sum)
<100^ <100 <100 <100 <100µg/L100---->C10 - C16 Fraction minus Naphthalene
(F2)
EP080: BTEXN
<1Benzene <1 <1 <1 <1µg/L171-43-2
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GW10GW04GW03GW02GW01Client sample IDSub-Matrix: WATER
(Matrix: WATER)
28-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:00Client sampling date / time
EM1702240-005EM1702240-004EM1702240-003EM1702240-002EM1702240-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP080: BTEXN - Continued
<2Toluene <2 <2 <2 <2µg/L2108-88-3
<2Ethylbenzene <2 <2 <2 <2µg/L2100-41-4
<2meta- & para-Xylene <2 <2 <2 <2µg/L2108-38-3 106-42-3
<2ortho-Xylene <2 <2 <2 <2µg/L295-47-6
<2^ Total Xylenes <2 <2 <2 <2µg/L21330-20-7
<1^ <1 <1 <1 <1µg/L1----Sum of BTEX
<5Naphthalene <5 <5 <5 <5µg/L591-20-3
EP231A: Perfluoroalkyl Sulfonic Acids
<0.02Perfluorobutane sulfonic acid
(PFBS)
<0.02 <0.02 <0.02 <0.02µg/L0.02375-73-5
<0.02Perfluoropentane sulfonic acid
(PFPeS)
<0.02 <0.02 <0.02 <0.02µg/L0.022706-91-4
0.03Perfluorohexane sulfonic acid
(PFHxS)
<0.02 <0.02 0.04 <0.02µg/L0.02355-46-4
<0.02Perfluoroheptane sulfonic acid
(PFHpS)
<0.02 <0.02 <0.02 <0.02µg/L0.02375-92-8
0.06Perfluorooctane sulfonic acid
(PFOS)
<0.01 <0.01 0.03 <0.01µg/L0.011763-23-1
<0.02Perfluorodecane sulfonic acid
(PFDS)
<0.02 <0.02 <0.02 <0.02µg/L0.02335-77-3
EP231B: Perfluoroalkyl Carboxylic Acids
<0.1Perfluorobutanoic acid (PFBA) <0.1 <0.1 <0.1 <0.1µg/L0.1375-22-4
<0.02Perfluoropentanoic acid (PFPeA) <0.02 <0.02 <0.02 <0.02µg/L0.022706-90-3
<0.02Perfluorohexanoic acid (PFHxA) <0.02 <0.02 <0.02 <0.02µg/L0.02307-24-4
<0.02Perfluoroheptanoic acid (PFHpA) <0.02 <0.02 <0.02 <0.02µg/L0.02375-85-9
<0.01Perfluorooctanoic acid (PFOA) <0.01 <0.01 0.01 <0.01µg/L0.01335-67-1
<0.02Perfluorononanoic acid (PFNA) <0.02 <0.02 <0.02 <0.02µg/L0.02375-95-1
<0.02Perfluorodecanoic acid (PFDA) <0.02 <0.02 <0.02 <0.02µg/L0.02335-76-2
<0.02Perfluoroundecanoic acid
(PFUnDA)
<0.02 <0.02 <0.02 <0.02µg/L0.022058-94-8
<0.02Perfluorododecanoic acid
(PFDoDA)
<0.02 <0.02 <0.02 <0.02µg/L0.02307-55-1
<0.02Perfluorotridecanoic acid
(PFTrDA)
<0.02 <0.02 <0.02 <0.02µg/L0.0272629-94-8
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Analytical Results
GW10GW04GW03GW02GW01Client sample IDSub-Matrix: WATER
(Matrix: WATER)
28-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:00Client sampling date / time
EM1702240-005EM1702240-004EM1702240-003EM1702240-002EM1702240-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP231B: Perfluoroalkyl Carboxylic Acids - Continued
<0.05Perfluorotetradecanoic acid
(PFTeDA)
<0.05 <0.05 <0.05 <0.05µg/L0.05376-06-7
EP231C: Perfluoroalkyl Sulfonamides
<0.02Perfluorooctane sulfonamide
(FOSA)
<0.02 <0.02 <0.02 <0.02µg/L0.02754-91-6
<0.05N-Methyl perfluorooctane
sulfonamide (MeFOSA)
<0.05 <0.05 <0.05 <0.05µg/L0.0531506-32-8
<0.05N-Ethyl perfluorooctane
sulfonamide (EtFOSA)
<0.05 <0.05 <0.05 <0.05µg/L0.054151-50-2
<0.05N-Methyl perfluorooctane
sulfonamidoethanol (MeFOSE)
<0.05 <0.05 <0.05 <0.05µg/L0.052448-09-7
<0.05N-Ethyl perfluorooctane
sulfonamidoethanol (EtFOSE)
<0.05 <0.05 <0.05 <0.05µg/L0.051691-99-2
<0.02N-Methyl perfluorooctane
sulfonamidoacetic acid
(MeFOSAA)
<0.02 <0.02 <0.02 <0.02µg/L0.022355-31-9
<0.02N-Ethyl perfluorooctane
sulfonamidoacetic acid
(EtFOSAA)
<0.02 <0.02 <0.02 <0.02µg/L0.022991-50-6
EP231D: (n:2) Fluorotelomer Sulfonic Acids
<0.054:2 Fluorotelomer sulfonic acid
(4:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.05757124-72-4
<0.056:2 Fluorotelomer sulfonic acid
(6:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.0527619-97-2
<0.058:2 Fluorotelomer sulfonic acid
(8:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.0539108-34-4
<0.0510:2 Fluorotelomer sulfonic acid
(10:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.05120226-60-0
EP231P: PFAS Sums
0.09 <0.01 <0.01 0.08 <0.01µg/L0.01----Sum of PFAS
0.09Sum of PFHxS and PFOS <0.01 <0.01 0.07 <0.01µg/L0.01355-46-4/1763-23-
1
0.09 <0.01 <0.01 0.08 <0.01µg/L0.01----Sum of PFAS (WA DER List)
EP074S: VOC Surrogates
97.91.2-Dichloroethane-D4 101 102 95.6 102%517060-07-0
94.2Toluene-D8 103 102 91.8 97.0%52037-26-5
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Analytical Results
GW10GW04GW03GW02GW01Client sample IDSub-Matrix: WATER
(Matrix: WATER)
28-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:00Client sampling date / time
EM1702240-005EM1702240-004EM1702240-003EM1702240-002EM1702240-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP074S: VOC Surrogates - Continued
89.14-Bromofluorobenzene 92.3 93.2 88.5 89.6%5460-00-4
EP075(SIM)S: Phenolic Compound Surrogates
30.7Phenol-d6 28.0 32.4 30.1 29.7%113127-88-3
73.02-Chlorophenol-D4 62.4 72.4 68.5 67.2%193951-73-6
88.02.4.6-Tribromophenol 69.7 90.6 84.1 85.7%1118-79-6
EP075(SIM)T: PAH Surrogates
78.82-Fluorobiphenyl 84.1 85.6 87.2 80.5%1321-60-8
90.1Anthracene-d10 72.6 95.0 87.6 91.2%11719-06-8
97.24-Terphenyl-d14 76.0 103 92.9 91.0%11718-51-0
EP080S: TPH(V)/BTEX Surrogates
95.01.2-Dichloroethane-D4 99.0 99.2 93.1 100%217060-07-0
90.2Toluene-D8 98.5 98.4 88.0 92.9%22037-26-5
90.94-Bromofluorobenzene 94.4 95.1 90.6 88.2%2460-00-4
EP231S: PFAS Surrogate
97.1 98.9 105 100 97.8%0.02----13C4-PFOS
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Analytical Results
QA_01GW19GW13GW12GW11Client sample IDSub-Matrix: WATER
(Matrix: WATER)
27-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:00Client sampling date / time
EM1702240-010EM1702240-009EM1702240-008EM1702240-007EM1702240-006UnitLORCAS NumberCompound
Result Result Result Result Result
EA005P: pH by PC Titrator
5.98 6.96 7.66 6.25 6.70pH Unit0.01----pH Value
EA015: Total Dissolved Solids dried at 180 ± 5 °C
4000 4660 7540 6030 8140mg/L10----Total Dissolved Solids @180°C
EA025: Total Suspended Solids dried at 104 ± 2°C
1400 6010 560 1490 190mg/L5----Suspended Solids (SS)
ED037P: Alkalinity by PC Titrator
<1Hydroxide Alkalinity as CaCO3 <1 <1 <1 <1mg/L1DMO-210-001
<1Carbonate Alkalinity as CaCO3 <1 <1 <1 <1mg/L13812-32-6
16Bicarbonate Alkalinity as CaCO3 100 883 508 376mg/L171-52-3
16 100 883 508 376mg/L1----Total Alkalinity as CaCO3
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
1750Sulfate as SO4 - Turbidimetric 1460 50 1840 105mg/L114808-79-8
ED045G: Chloride by Discrete Analyser
505Chloride 1130 3690 1140 3790mg/L116887-00-6
ED093F: Dissolved Major Cations
191Calcium 151 211 131 243mg/L17440-70-2
203Magnesium 216 268 337 343mg/L17439-95-4
595Sodium 938 1820 1070 1590mg/L17440-23-5
8Potassium 8 10 <1 7mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS
0.001Arsenic <0.001 <0.001 0.007 <0.001mg/L0.0017440-38-2
<0.05Boron <0.05 <0.05 0.18 <0.05mg/L0.057440-42-8
0.011Barium 0.041 1.23 0.082 0.237mg/L0.0017440-39-3
<0.001Beryllium <0.001 <0.001 <0.001 <0.001mg/L0.0017440-41-7
<0.0001Cadmium <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017440-43-9
0.065Cobalt 0.010 <0.001 0.069 0.006mg/L0.0017440-48-4
<0.001Chromium <0.001 <0.001 0.002 <0.001mg/L0.0017440-47-3
0.002Copper 0.002 0.003 0.002 0.003mg/L0.0017440-50-8
2.91Manganese 0.306 0.036 0.395 0.232mg/L0.0017439-96-5
0.021Nickel 0.014 0.005 0.027 0.009mg/L0.0017440-02-0
<0.001Lead <0.001 <0.001 <0.001 <0.001mg/L0.0017439-92-1
<0.01Selenium <0.01 <0.01 0.01 <0.01mg/L0.017782-49-2
<0.01Vanadium <0.01 <0.01 <0.01 <0.01mg/L0.017440-62-2
0.042Zinc 0.029 0.035 0.050 0.043mg/L0.0057440-66-6
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Analytical Results
QA_01GW19GW13GW12GW11Client sample IDSub-Matrix: WATER
(Matrix: WATER)
27-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:00Client sampling date / time
EM1702240-010EM1702240-009EM1702240-008EM1702240-007EM1702240-006UnitLORCAS NumberCompound
Result Result Result Result Result
EG020T: Total Metals by ICP-MS
0.009Arsenic 0.017 0.002 0.015 0.002mg/L0.0017440-38-2
<0.05Boron <0.05 <0.05 0.15 <0.05mg/L0.057440-42-8
0.237Barium 1.17 1.30 0.169 0.296mg/L0.0017440-39-3
0.002Beryllium 0.007 <0.001 0.002 <0.001mg/L0.0017440-41-7
<0.0001Cadmium <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017440-43-9
0.084Cobalt 0.089 0.005 0.084 0.011mg/L0.0017440-48-4
0.027Chromium 0.046 0.010 0.028 0.008mg/L0.0017440-47-3
0.018Copper 0.033 0.006 0.014 0.007mg/L0.0017440-50-8
2.99Manganese 0.548 0.077 0.405 0.201mg/L0.0017439-96-5
0.034Nickel 0.047 0.009 0.037 0.013mg/L0.0017440-02-0
0.017Lead 0.061 0.006 0.015 0.004mg/L0.0017439-92-1
0.01Selenium 0.02 <0.01 0.02 <0.01mg/L0.017782-49-2
0.08Vanadium 0.21 0.02 0.08 0.02mg/L0.017440-62-2
0.085Zinc 0.138 0.052 0.076 0.068mg/L0.0057440-66-6
EG035F: Dissolved Mercury by FIMS
<0.0001Mercury <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017439-97-6
EG035T: Total Recoverable Mercury by FIMS
<0.0001Mercury <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017439-97-6
EG050F: Dissolved Hexavalent Chromium
<0.01Hexavalent Chromium <0.01 <0.01 <0.01 <0.01mg/L0.0118540-29-9
EK040P: Fluoride by PC Titrator
<0.1Fluoride 0.3 0.7 0.3 0.3mg/L0.116984-48-8
EK055G: Ammonia as N by Discrete Analyser
0.02Ammonia as N 0.02 0.10 0.36 0.04mg/L0.017664-41-7
EK071G: Reactive Phosphorus as P by discrete analyser
<0.01Reactive Phosphorus as P <0.01 0.02 <0.01 <0.01mg/L0.0114265-44-2
EN055: Ionic Balance
51.0 64.3 123 80.6 117meq/L0.01----Total Anions
52.3 66.3 112 80.8 110meq/L0.01----Total Cations
1.28 1.57 4.58 0.12 3.06%0.01----Ionic Balance
EP005: Total Organic Carbon (TOC)
3 4 6 173 9mg/L1----Total Organic Carbon
EP074A: Monocyclic Aromatic Hydrocarbons
<5Styrene <5 <5 <5 <5µg/L5100-42-5
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Analytical Results
QA_01GW19GW13GW12GW11Client sample IDSub-Matrix: WATER
(Matrix: WATER)
27-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:00Client sampling date / time
EM1702240-010EM1702240-009EM1702240-008EM1702240-007EM1702240-006UnitLORCAS NumberCompound
Result Result Result Result Result
EP074A: Monocyclic Aromatic Hydrocarbons - Continued
<5Isopropylbenzene <5 <5 <5 <5µg/L598-82-8
<5n-Propylbenzene <5 <5 <5 <5µg/L5103-65-1
<51.3.5-Trimethylbenzene <5 <5 <5 <5µg/L5108-67-8
<5sec-Butylbenzene <5 <5 <5 <5µg/L5135-98-8
<51.2.4-Trimethylbenzene <5 <5 <5 <5µg/L595-63-6
<5tert-Butylbenzene <5 <5 <5 <5µg/L598-06-6
<5p-Isopropyltoluene <5 <5 <5 <5µg/L599-87-6
<5n-Butylbenzene <5 <5 <5 <5µg/L5104-51-8
EP074B: Oxygenated Compounds
<50Vinyl Acetate <50 <50 <50 <50µg/L50108-05-4
<502-Butanone (MEK) <50 <50 <50 <50µg/L5078-93-3
<504-Methyl-2-pentanone (MIBK) <50 <50 <50 <50µg/L50108-10-1
<502-Hexanone (MBK) <50 <50 <50 <50µg/L50591-78-6
EP074C: Sulfonated Compounds
<5Carbon disulfide <5 <5 <5 <5µg/L575-15-0
EP074D: Fumigants
<52.2-Dichloropropane <5 <5 <5 <5µg/L5594-20-7
<51.2-Dichloropropane <5 <5 <5 <5µg/L578-87-5
<5cis-1.3-Dichloropropylene <5 <5 <5 <5µg/L510061-01-5
<5trans-1.3-Dichloropropylene <5 <5 <5 <5µg/L510061-02-6
<51.2-Dibromoethane (EDB) <5 <5 <5 <5µg/L5106-93-4
EP074E: Halogenated Aliphatic Compounds
<50Dichlorodifluoromethane <50 <50 <50 <50µg/L5075-71-8
<50Chloromethane <50 <50 <50 <50µg/L5074-87-3
<50Vinyl chloride <50 <50 <50 <50µg/L5075-01-4
<50Bromomethane <50 <50 <50 <50µg/L5074-83-9
<50Chloroethane <50 <50 <50 <50µg/L5075-00-3
<50Trichlorofluoromethane <50 <50 <50 <50µg/L5075-69-4
<51.1-Dichloroethene <5 <5 <5 <5µg/L575-35-4
<5Iodomethane <5 <5 <5 <5µg/L574-88-4
<5Methylene chloride <5 <5 <5 <5µg/L575-09-2
<5trans-1.2-Dichloroethene <5 <5 <5 <5µg/L5156-60-5
<51.1-Dichloroethane <5 <5 <5 <5µg/L575-34-3
<5cis-1.2-Dichloroethene <5 <5 <5 <5µg/L5156-59-2
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Analytical Results
QA_01GW19GW13GW12GW11Client sample IDSub-Matrix: WATER
(Matrix: WATER)
27-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:00Client sampling date / time
EM1702240-010EM1702240-009EM1702240-008EM1702240-007EM1702240-006UnitLORCAS NumberCompound
Result Result Result Result Result
EP074E: Halogenated Aliphatic Compounds - Continued
<51.1.1-Trichloroethane <5 <5 <5 <5µg/L571-55-6
<51.1-Dichloropropylene <5 <5 <5 <5µg/L5563-58-6
<5Carbon Tetrachloride <5 <5 <5 <5µg/L556-23-5
<51.2-Dichloroethane <5 <5 <5 <5µg/L5107-06-2
<5Trichloroethene <5 <5 <5 <5µg/L579-01-6
<5Dibromomethane <5 <5 <5 <5µg/L574-95-3
<51.1.2-Trichloroethane <5 <5 <5 <5µg/L579-00-5
<51.3-Dichloropropane <5 <5 <5 <5µg/L5142-28-9
<5Tetrachloroethene <5 <5 <5 <5µg/L5127-18-4
<51.1.1.2-Tetrachloroethane <5 <5 <5 <5µg/L5630-20-6
<5trans-1.4-Dichloro-2-butene <5 <5 <5 <5µg/L5110-57-6
<5cis-1.4-Dichloro-2-butene <5 <5 <5 <5µg/L51476-11-5
<51.1.2.2-Tetrachloroethane <5 <5 <5 <5µg/L579-34-5
<51.2.3-Trichloropropane <5 <5 <5 <5µg/L596-18-4
<5Pentachloroethane <5 <5 <5 <5µg/L576-01-7
<51.2-Dibromo-3-chloropropane <5 <5 <5 <5µg/L596-12-8
<5Hexachlorobutadiene <5 <5 <5 <5µg/L587-68-3
EP074F: Halogenated Aromatic Compounds
<5Chlorobenzene <5 <5 <5 <5µg/L5108-90-7
<5Bromobenzene <5 <5 <5 <5µg/L5108-86-1
<52-Chlorotoluene <5 <5 <5 <5µg/L595-49-8
<54-Chlorotoluene <5 <5 <5 <5µg/L5106-43-4
<51.3-Dichlorobenzene <5 <5 <5 <5µg/L5541-73-1
<51.4-Dichlorobenzene <5 <5 <5 <5µg/L5106-46-7
<51.2-Dichlorobenzene <5 <5 <5 <5µg/L595-50-1
<51.2.4-Trichlorobenzene <5 <5 <5 <5µg/L5120-82-1
<51.2.3-Trichlorobenzene <5 <5 <5 <5µg/L587-61-6
EP074G: Trihalomethanes
<5Chloroform <5 <5 <5 <5µg/L567-66-3
<5Bromodichloromethane <5 <5 <5 <5µg/L575-27-4
<5Dibromochloromethane <5 <5 <5 <5µg/L5124-48-1
<5Bromoform <5 <5 <5 <5µg/L575-25-2
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
<1.0Naphthalene <1.0 <1.0 <1.0 <1.0µg/L191-20-3
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Analytical Results
QA_01GW19GW13GW12GW11Client sample IDSub-Matrix: WATER
(Matrix: WATER)
27-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:00Client sampling date / time
EM1702240-010EM1702240-009EM1702240-008EM1702240-007EM1702240-006UnitLORCAS NumberCompound
Result Result Result Result Result
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued
<1.0Acenaphthylene <1.0 <1.0 <1.0 <1.0µg/L1208-96-8
<1.0Acenaphthene <1.0 <1.0 <1.0 <1.0µg/L183-32-9
<1.0Fluorene <1.0 <1.0 <1.0 <1.0µg/L186-73-7
<1.0Phenanthrene <1.0 <1.0 <1.0 <1.0µg/L185-01-8
<1.0Anthracene <1.0 <1.0 <1.0 <1.0µg/L1120-12-7
<1.0Fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1206-44-0
<1.0Pyrene <1.0 <1.0 <1.0 <1.0µg/L1129-00-0
<1.0Benz(a)anthracene <1.0 <1.0 <1.0 <1.0µg/L156-55-3
<1.0Chrysene <1.0 <1.0 <1.0 <1.0µg/L1218-01-9
<1.0Benzo(b+j)fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1205-99-2 205-82-3
<1.0Benzo(k)fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1207-08-9
<0.5Benzo(a)pyrene <0.5 <0.5 <0.5 <0.5µg/L0.550-32-8
<1.0Indeno(1.2.3.cd)pyrene <1.0 <1.0 <1.0 <1.0µg/L1193-39-5
<1.0Dibenz(a.h)anthracene <1.0 <1.0 <1.0 <1.0µg/L153-70-3
<1.0Benzo(g.h.i)perylene <1.0 <1.0 <1.0 <1.0µg/L1191-24-2
<0.5^ <0.5 <0.5 <0.5 <0.5µg/L0.5----Sum of polycyclic aromatic hydrocarbons
<0.5^ <0.5 <0.5 <0.5 <0.5µg/L0.5----Benzo(a)pyrene TEQ (zero)
EP080/071: Total Petroleum Hydrocarbons
<20 <20 <20 <20 <20µg/L20----C6 - C9 Fraction
<50 <50 <50 <50 <50µg/L50----C10 - C14 Fraction
<100 <100 <100 <100 <100µg/L100----C15 - C28 Fraction
<50 <50 <50 <50 <50µg/L50----C29 - C36 Fraction
<50^ <50 <50 <50 <50µg/L50----C10 - C36 Fraction (sum)
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
<20C6 - C10 Fraction <20 <20 <20 <20µg/L20C6_C10
<20^ C6 - C10 Fraction minus BTEX
(F1)
<20 <20 <20 <20µg/L20C6_C10-BTEX
<100 <100 <100 <100 <100µg/L100---->C10 - C16 Fraction
<100 <100 <100 <100 <100µg/L100---->C16 - C34 Fraction
<100 <100 <100 <100 <100µg/L100---->C34 - C40 Fraction
<100^ <100 <100 <100 <100µg/L100---->C10 - C40 Fraction (sum)
<100^ <100 <100 <100 <100µg/L100---->C10 - C16 Fraction minus Naphthalene
(F2)
EP080: BTEXN
<1Benzene <1 <1 <1 <1µg/L171-43-2
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Analytical Results
QA_01GW19GW13GW12GW11Client sample IDSub-Matrix: WATER
(Matrix: WATER)
27-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:00Client sampling date / time
EM1702240-010EM1702240-009EM1702240-008EM1702240-007EM1702240-006UnitLORCAS NumberCompound
Result Result Result Result Result
EP080: BTEXN - Continued
<2Toluene <2 <2 <2 <2µg/L2108-88-3
<2Ethylbenzene <2 <2 <2 <2µg/L2100-41-4
<2meta- & para-Xylene <2 <2 <2 <2µg/L2108-38-3 106-42-3
<2ortho-Xylene <2 <2 <2 <2µg/L295-47-6
<2^ Total Xylenes <2 <2 <2 <2µg/L21330-20-7
<1^ <1 <1 <1 <1µg/L1----Sum of BTEX
<5Naphthalene <5 <5 <5 <5µg/L591-20-3
EP231A: Perfluoroalkyl Sulfonic Acids
<0.02Perfluorobutane sulfonic acid
(PFBS)
<0.02 <0.02 <0.02 <0.02µg/L0.02375-73-5
<0.02Perfluoropentane sulfonic acid
(PFPeS)
<0.02 <0.02 <0.02 <0.02µg/L0.022706-91-4
<0.02Perfluorohexane sulfonic acid
(PFHxS)
<0.02 <0.02 <0.02 <0.02µg/L0.02355-46-4
<0.02Perfluoroheptane sulfonic acid
(PFHpS)
<0.02 <0.02 <0.02 <0.02µg/L0.02375-92-8
<0.01Perfluorooctane sulfonic acid
(PFOS)
<0.01 0.11 <0.01 <0.01µg/L0.011763-23-1
<0.02Perfluorodecane sulfonic acid
(PFDS)
<0.02 <0.02 <0.02 <0.02µg/L0.02335-77-3
EP231B: Perfluoroalkyl Carboxylic Acids
<0.1Perfluorobutanoic acid (PFBA) <0.1 <0.1 <0.1 <0.1µg/L0.1375-22-4
<0.02Perfluoropentanoic acid (PFPeA) <0.02 <0.02 <0.02 <0.02µg/L0.022706-90-3
<0.02Perfluorohexanoic acid (PFHxA) <0.02 <0.02 <0.02 <0.02µg/L0.02307-24-4
<0.02Perfluoroheptanoic acid (PFHpA) <0.02 <0.02 <0.02 <0.02µg/L0.02375-85-9
<0.01Perfluorooctanoic acid (PFOA) <0.01 <0.01 <0.01 <0.01µg/L0.01335-67-1
<0.02Perfluorononanoic acid (PFNA) <0.02 <0.02 <0.02 <0.02µg/L0.02375-95-1
<0.02Perfluorodecanoic acid (PFDA) <0.02 <0.02 <0.02 <0.02µg/L0.02335-76-2
<0.02Perfluoroundecanoic acid
(PFUnDA)
<0.02 <0.02 <0.02 <0.02µg/L0.022058-94-8
<0.02Perfluorododecanoic acid
(PFDoDA)
<0.02 <0.02 <0.02 <0.02µg/L0.02307-55-1
<0.02Perfluorotridecanoic acid
(PFTrDA)
<0.02 <0.02 <0.02 <0.02µg/L0.0272629-94-8
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Analytical Results
QA_01GW19GW13GW12GW11Client sample IDSub-Matrix: WATER
(Matrix: WATER)
27-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:00Client sampling date / time
EM1702240-010EM1702240-009EM1702240-008EM1702240-007EM1702240-006UnitLORCAS NumberCompound
Result Result Result Result Result
EP231B: Perfluoroalkyl Carboxylic Acids - Continued
<0.05Perfluorotetradecanoic acid
(PFTeDA)
<0.05 <0.05 <0.05 <0.05µg/L0.05376-06-7
EP231C: Perfluoroalkyl Sulfonamides
<0.02Perfluorooctane sulfonamide
(FOSA)
<0.02 <0.02 <0.02 <0.02µg/L0.02754-91-6
<0.05N-Methyl perfluorooctane
sulfonamide (MeFOSA)
<0.05 <0.05 <0.05 <0.05µg/L0.0531506-32-8
<0.05N-Ethyl perfluorooctane
sulfonamide (EtFOSA)
<0.05 <0.05 <0.05 <0.05µg/L0.054151-50-2
<0.05N-Methyl perfluorooctane
sulfonamidoethanol (MeFOSE)
<0.05 <0.05 <0.05 <0.05µg/L0.052448-09-7
<0.05N-Ethyl perfluorooctane
sulfonamidoethanol (EtFOSE)
<0.05 <0.05 <0.05 <0.05µg/L0.051691-99-2
<0.02N-Methyl perfluorooctane
sulfonamidoacetic acid
(MeFOSAA)
<0.02 <0.02 <0.02 <0.02µg/L0.022355-31-9
<0.02N-Ethyl perfluorooctane
sulfonamidoacetic acid
(EtFOSAA)
<0.02 <0.02 <0.02 <0.02µg/L0.022991-50-6
EP231D: (n:2) Fluorotelomer Sulfonic Acids
<0.054:2 Fluorotelomer sulfonic acid
(4:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.05757124-72-4
<0.056:2 Fluorotelomer sulfonic acid
(6:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.0527619-97-2
<0.058:2 Fluorotelomer sulfonic acid
(8:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.0539108-34-4
<0.0510:2 Fluorotelomer sulfonic acid
(10:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.05120226-60-0
EP231P: PFAS Sums
<0.01 <0.01 0.11 <0.01 <0.01µg/L0.01----Sum of PFAS
<0.01Sum of PFHxS and PFOS <0.01 0.11 <0.01 <0.01µg/L0.01355-46-4/1763-23-
1
<0.01 <0.01 0.11 <0.01 <0.01µg/L0.01----Sum of PFAS (WA DER List)
EP074S: VOC Surrogates
99.51.2-Dichloroethane-D4 102 95.1 111 104%517060-07-0
99.2Toluene-D8 100 93.0 112 100%52037-26-5
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Analytical Results
QA_01GW19GW13GW12GW11Client sample IDSub-Matrix: WATER
(Matrix: WATER)
27-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:0028-Feb-2017 00:00Client sampling date / time
EM1702240-010EM1702240-009EM1702240-008EM1702240-007EM1702240-006UnitLORCAS NumberCompound
Result Result Result Result Result
EP074S: VOC Surrogates - Continued
87.44-Bromofluorobenzene 83.7 84.9 98.9 92.2%5460-00-4
EP075(SIM)S: Phenolic Compound Surrogates
31.2Phenol-d6 28.0 28.0 27.8 30.2%113127-88-3
73.22-Chlorophenol-D4 63.3 64.4 66.6 68.6%193951-73-6
97.32.4.6-Tribromophenol 81.3 85.9 79.2 87.0%1118-79-6
EP075(SIM)T: PAH Surrogates
83.02-Fluorobiphenyl 73.2 87.1 91.3 88.4%1321-60-8
91.3Anthracene-d10 87.4 90.7 85.6 88.9%11719-06-8
92.24-Terphenyl-d14 89.1 100.0 89.7 91.4%11718-51-0
EP080S: TPH(V)/BTEX Surrogates
97.61.2-Dichloroethane-D4 100 93.1 109 101%217060-07-0
94.9Toluene-D8 96.4 89.5 106 94.8%22037-26-5
90.54-Bromofluorobenzene 94.3 88.2 98.6 92.9%2460-00-4
EP231S: PFAS Surrogate
100 99.7 100 106 98.8%0.02----13C4-PFOS
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Analytical Results
--------TB_002TB_001RB_001Client sample IDSub-Matrix: WATER
(Matrix: WATER)
--------28-Feb-2017 00:0027-Feb-2017 00:0027-Feb-2017 00:00Client sampling date / time
----------------EM1702240-013EM1702240-012EM1702240-011UnitLORCAS NumberCompound
Result Result Result ---- ----
EG020T: Total Metals by ICP-MS
<0.001Arsenic ---- ---- ---- ----mg/L0.0017440-38-2
<0.0001Cadmium ---- ---- ---- ----mg/L0.00017440-43-9
<0.001Chromium ---- ---- ---- ----mg/L0.0017440-47-3
<0.001Copper ---- ---- ---- ----mg/L0.0017440-50-8
<0.001Nickel ---- ---- ---- ----mg/L0.0017440-02-0
<0.001Lead ---- ---- ---- ----mg/L0.0017439-92-1
<0.005Zinc ---- ---- ---- ----mg/L0.0057440-66-6
EG035T: Total Recoverable Mercury by FIMS
<0.0001Mercury ---- ---- ---- ----mg/L0.00017439-97-6
EP080/071: Total Petroleum Hydrocarbons
---- <20 <20 ---- ----µg/L20----C6 - C9 Fraction
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
----C6 - C10 Fraction <20 <20 ---- ----µg/L20C6_C10
----^ C6 - C10 Fraction minus BTEX
(F1)
<20 <20 ---- ----µg/L20C6_C10-BTEX
EP080: BTEXN
----Benzene <1 <1 ---- ----µg/L171-43-2
----Toluene <2 <2 ---- ----µg/L2108-88-3
----Ethylbenzene <2 <2 ---- ----µg/L2100-41-4
----meta- & para-Xylene <2 <2 ---- ----µg/L2108-38-3 106-42-3
----ortho-Xylene <2 <2 ---- ----µg/L295-47-6
----^ Total Xylenes <2 <2 ---- ----µg/L21330-20-7
----^ <1 <1 ---- ----µg/L1----Sum of BTEX
----Naphthalene <5 <5 ---- ----µg/L591-20-3
EP080S: TPH(V)/BTEX Surrogates
----1.2-Dichloroethane-D4 88.3 97.1 ---- ----%217060-07-0
----Toluene-D8 82.6 89.0 ---- ----%22037-26-5
----4-Bromofluorobenzene 86.7 90.6 ---- ----%2460-00-4
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Surrogate Control Limits
Recovery Limits (%)Sub-Matrix: WATER
Compound CAS Number Low High
EP074S: VOC Surrogates
1.2-Dichloroethane-D4 17060-07-0 72 132
Toluene-D8 2037-26-5 77 132
4-Bromofluorobenzene 460-00-4 67 131
EP075(SIM)S: Phenolic Compound Surrogates
Phenol-d6 13127-88-3 10 46
2-Chlorophenol-D4 93951-73-6 23 104
2.4.6-Tribromophenol 118-79-6 28 130
EP075(SIM)T: PAH Surrogates
2-Fluorobiphenyl 321-60-8 36 114
Anthracene-d10 1719-06-8 51 119
4-Terphenyl-d14 1718-51-0 49 127
EP080S: TPH(V)/BTEX Surrogates
1.2-Dichloroethane-D4 17060-07-0 73 129
Toluene-D8 2037-26-5 70 125
4-Bromofluorobenzene 460-00-4 71 129
EP231S: PFAS Surrogate
13C4-PFOS ---- 60 130
False
5 5.00True
Environmental
QUALITY CONTROL REPORTWork Order : EM1702240 Page : 1 of 20
:: LaboratoryClient Environmental Division MelbourneJACOBS GROUP (AUSTRALIA) PTY LTD
:Contact MR BENJAMIN GRASSO :Contact Carol Walsh
:Address P O BOX 312 FLINDERS LANE
MELBOURNE VIC AUSTRALIA 8009
Address : 4 Westall Rd Springvale VIC Australia 3171
::Telephone +61 03 8668 3000 +61-3-8549 9608:Telephone
:Project IS157700 Date Samples Received : 01-Mar-2017
:Order number ---- Date Analysis Commenced : 01-Mar-2017
:C-O-C number ---- Issue Date : 08-Mar-2017
Sampler : BENJAMIN GRASSO
Site : ----
Quote number : ME/088/17
No. of samples received 13:
No. of samples analysed 13:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limits
l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits
l Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Alex Rossi Organic Chemist Sydney Organics, Smithfield, NSW
Dilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VIC
Eric Chau Metals Team Leader Melbourne Inorganics, Springvale, VIC
Nikki Stepniewski Senior Inorganic Instrument Chemist Melbourne Inorganics, Springvale, VIC
Xing Lin Senior Organic Chemist Melbourne Organics, Springvale, VIC
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
RPD = Relative Percentage Difference
# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) Report
The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges
for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:
No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EA005P: pH by PC Titrator (QC Lot: 774881)
EA005-P: pH Value ---- 0.01 pH Unit 7.82 7.83 0.128 0% - 20%Anonymous EM1702218-002
EA005-P: pH Value ---- 0.01 pH Unit 6.65 6.63 0.301 0% - 20%GW02 EM1702240-002
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QC Lot: 776587)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 8470 8650 2.12 0% - 20%GW01 EM1702240-001
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 1360 1420 4.60 0% - 20%Anonymous EM1702220-001
EA025: Total Suspended Solids dried at 104 ± 2°C (QC Lot: 776586)
EA025H: Suspended Solids (SS) ---- 5 mg/L 1490 1400 6.44 0% - 20%GW02 EM1702240-002
EA025H: Suspended Solids (SS) ---- 5 mg/L <5 <5 0.00 No LimitAnonymous EM1702220-001
ED037P: Alkalinity by PC Titrator (QC Lot: 774882)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitGW02 EM1702240-002
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 166 166 0.00 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 166 166 0.00 0% - 20%
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EM1702250-002
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 197 198 0.774 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 197 198 0.774 0% - 20%
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QC Lot: 773883)
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 194 194 0.00 0% - 20%GW10 EM1702240-005
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 2 2 0.00 No LimitAnonymous EM1702234-001
ED045G: Chloride by Discrete Analyser (QC Lot: 773884)
ED045G: Chloride 16887-00-6 1 mg/L 2600 2620 0.558 0% - 20%GW04 EM1702240-004
ED045G: Chloride 16887-00-6 1 mg/L 7 7 0.00 No LimitAnonymous EM1702234-001
ED093F: Dissolved Major Cations (QC Lot: 774038)
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
ED093F: Dissolved Major Cations (QC Lot: 774038) - continued
ED093F: Calcium 7440-70-2 1 mg/L 91 94 3.00 0% - 20%Anonymous EM1702217-002
ED093F: Magnesium 7439-95-4 1 mg/L 152 154 1.87 0% - 20%
ED093F: Sodium 7440-23-5 1 mg/L 2180 2210 1.19 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 70 70 0.00 0% - 20%
ED093F: Calcium 7440-70-2 1 mg/L 211 211 0.00 0% - 20%GW13 EM1702240-008
ED093F: Magnesium 7439-95-4 1 mg/L 268 272 1.86 0% - 20%
ED093F: Sodium 7440-23-5 1 mg/L 1820 1860 2.52 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 10 10 0.00 No Limit
EG020F: Dissolved Metals by ICP-MS (QC Lot: 774040)
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitGW01 EM1702240-001
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Beryllium 7440-41-7 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Barium 7440-39-3 0.001 mg/L 0.204 0.202 0.898 0% - 20%
EG020A-F: Chromium 7440-47-3 0.001 mg/L 0.001 0.001 0.00 No Limit
EG020A-F: Cobalt 7440-48-4 0.001 mg/L 0.064 0.063 0.00 0% - 20%
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.026 0.025 0.00 0% - 20%
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.019 0.017 8.27 0% - 50%
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.041 0.041 0.00 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Vanadium 7440-62-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Boron 7440-42-8 0.05 mg/L <0.05 <0.05 0.00 No Limit
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitGW13 EM1702240-008
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Beryllium 7440-41-7 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Barium 7440-39-3 0.001 mg/L 1.23 1.27 3.18 0% - 20%
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Cobalt 7440-48-4 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.003 0.004 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.036 0.037 0.00 0% - 20%
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.005 0.006 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.035 0.034 3.31 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Vanadium 7440-62-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Boron 7440-42-8 0.05 mg/L <0.05 <0.05 0.00 No Limit
EG020T: Total Metals by ICP-MS (QC Lot: 775079)
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702234-001
EG020A-T: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EG020T: Total Metals by ICP-MS (QC Lot: 775079) - continued
EG020A-T: Beryllium 7440-41-7 0.001 mg/L <0.001 <0.001 0.00 No LimitAnonymous EM1702234-001
EG020A-T: Barium 7440-39-3 0.001 mg/L 0.001 0.001 0.00 No Limit
EG020A-T: Chromium 7440-47-3 0.001 mg/L 0.002 0.001 0.00 No Limit
EG020A-T: Cobalt 7440-48-4 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Copper 7440-50-8 0.001 mg/L 0.005 0.005 0.00 No Limit
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Manganese 7439-96-5 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-T: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Zinc 7440-66-6 0.005 mg/L 0.184 0.177 3.95 0% - 20%
EG020A-T: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-T: Vanadium 7440-62-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-T: Boron 7440-42-8 0.05 mg/L <0.05 <0.05 0.00 No Limit
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitGW12 EM1702240-007
EG020A-T: Arsenic 7440-38-2 0.001 mg/L 0.017 0.019 13.4 0% - 50%
EG020A-T: Beryllium 7440-41-7 0.001 mg/L 0.007 0.007 0.00 No Limit
EG020A-T: Barium 7440-39-3 0.001 mg/L 1.17 1.24 5.86 0% - 20%
EG020A-T: Chromium 7440-47-3 0.001 mg/L 0.046 0.053 13.5 0% - 20%
EG020A-T: Cobalt 7440-48-4 0.001 mg/L 0.089 0.099 11.2 0% - 20%
EG020A-T: Copper 7440-50-8 0.001 mg/L 0.033 0.039 16.2 0% - 20%
EG020A-T: Lead 7439-92-1 0.001 mg/L 0.061 0.064 6.18 0% - 20%
EG020A-T: Manganese 7439-96-5 0.001 mg/L 0.548 0.567 3.44 0% - 20%
EG020A-T: Nickel 7440-02-0 0.001 mg/L 0.047 0.051 6.70 0% - 20%
EG020A-T: Zinc 7440-66-6 0.005 mg/L 0.138 0.155 11.9 0% - 20%
EG020A-T: Selenium 7782-49-2 0.01 mg/L 0.02 0.01 0.00 No Limit
EG020A-T: Vanadium 7440-62-2 0.01 mg/L 0.21 0.24 9.99 0% - 20%
EG020A-T: Boron 7440-42-8 0.05 mg/L <0.05 <0.05 0.00 No Limit
EG035F: Dissolved Mercury by FIMS (QC Lot: 774037)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702198-006
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702211-001
EG035F: Dissolved Mercury by FIMS (QC Lot: 774041)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitGW13 EM1702240-008
EG035T: Total Recoverable Mercury by FIMS (QC Lot: 774525)
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702211-007
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702235-001
EG035T: Total Recoverable Mercury by FIMS (QC Lot: 774526)
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitGW10 EM1702240-005
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702242-003
EG050F: Dissolved Hexavalent Chromium (QC Lot: 775560)
EG050F: Hexavalent Chromium 18540-29-9 0.01 mg/L <0.01 <0.01 0.00 No LimitGW01 EM1702240-001
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EG050F: Dissolved Hexavalent Chromium (QC Lot: 775560) - continued
EG050F: Hexavalent Chromium 18540-29-9 0.01 mg/L <0.01 <0.01 0.00 No LimitQA_01 EM1702240-010
EK040P: Fluoride by PC Titrator (QC Lot: 779005)
EK040P: Fluoride 16984-48-8 0.1 mg/L 0.3 0.3 0.00 No LimitGW02 EM1702240-002
EK040P: Fluoride 16984-48-8 0.1 mg/L 0.1 <0.1 0.00 No LimitAnonymous EM1702272-005
EK055G: Ammonia as N by Discrete Analyser (QC Lot: 773793)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.02 0.02 0.00 No LimitGW11 EM1702240-006
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.82 0.82 0.00 0% - 20%Anonymous EM1702220-001
EK071G: Reactive Phosphorus as P by discrete analyser (QC Lot: 773882)
EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L 214 206 3.92 0% - 20%Anonymous EM1702221-001
EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L 0.02 0.02 0.00 No LimitGW13 EM1702240-008
EP005: Total Organic Carbon (TOC) (QC Lot: 775333)
EP005: Total Organic Carbon ---- 1 mg/L 4 5 0.00 No LimitGW01 EM1702240-001
EP005: Total Organic Carbon ---- 1 mg/L 9 3 98.8 No LimitQA_01 EM1702240-010
EP074A: Monocyclic Aromatic Hydrocarbons (QC Lot: 774514)
EP074: Styrene 100-42-5 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702227-001
EP074: Isopropylbenzene 98-82-8 5 µg/L <5 <5 0.00 No Limit
EP074: n-Propylbenzene 103-65-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3.5-Trimethylbenzene 108-67-8 5 µg/L <5 <5 0.00 No Limit
EP074: sec-Butylbenzene 135-98-8 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trimethylbenzene 95-63-6 5 µg/L <5 <5 0.00 No Limit
EP074: tert-Butylbenzene 98-06-6 5 µg/L <5 <5 0.00 No Limit
EP074: p-Isopropyltoluene 99-87-6 5 µg/L <5 <5 0.00 No Limit
EP074: n-Butylbenzene 104-51-8 5 µg/L <5 <5 0.00 No Limit
EP074: Styrene 100-42-5 5 µg/L <5 <5 0.00 No LimitGW10 EM1702240-005
EP074: Isopropylbenzene 98-82-8 5 µg/L <5 <5 0.00 No Limit
EP074: n-Propylbenzene 103-65-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3.5-Trimethylbenzene 108-67-8 5 µg/L <5 <5 0.00 No Limit
EP074: sec-Butylbenzene 135-98-8 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trimethylbenzene 95-63-6 5 µg/L <5 <5 0.00 No Limit
EP074: tert-Butylbenzene 98-06-6 5 µg/L <5 <5 0.00 No Limit
EP074: p-Isopropyltoluene 99-87-6 5 µg/L <5 <5 0.00 No Limit
EP074: n-Butylbenzene 104-51-8 5 µg/L <5 <5 0.00 No Limit
EP074B: Oxygenated Compounds (QC Lot: 774514)
EP074: Vinyl Acetate 108-05-4 50 µg/L <50 <50 0.00 No LimitAnonymous EM1702227-001
EP074: 2-Butanone (MEK) 78-93-3 50 µg/L <50 <50 0.00 No Limit
EP074: 4-Methyl-2-pentanone (MIBK) 108-10-1 50 µg/L <50 <50 0.00 No Limit
EP074: 2-Hexanone (MBK) 591-78-6 50 µg/L <50 <50 0.00 No Limit
EP074: Vinyl Acetate 108-05-4 50 µg/L <50 <50 0.00 No LimitGW10 EM1702240-005
EP074: 2-Butanone (MEK) 78-93-3 50 µg/L <50 <50 0.00 No Limit
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP074B: Oxygenated Compounds (QC Lot: 774514) - continued
EP074: 4-Methyl-2-pentanone (MIBK) 108-10-1 50 µg/L <50 <50 0.00 No LimitGW10 EM1702240-005
EP074: 2-Hexanone (MBK) 591-78-6 50 µg/L <50 <50 0.00 No Limit
EP074C: Sulfonated Compounds (QC Lot: 774514)
EP074: Carbon disulfide 75-15-0 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702227-001
EP074: Carbon disulfide 75-15-0 5 µg/L <5 <5 0.00 No LimitGW10 EM1702240-005
EP074D: Fumigants (QC Lot: 774514)
EP074: 2.2-Dichloropropane 594-20-7 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702227-001
EP074: 1.2-Dichloropropane 78-87-5 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.3-Dichloropropylene 10061-01-5 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.3-Dichloropropylene 10061-02-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromoethane (EDB) 106-93-4 5 µg/L <5 <5 0.00 No Limit
EP074: 2.2-Dichloropropane 594-20-7 5 µg/L <5 <5 0.00 No LimitGW10 EM1702240-005
EP074: 1.2-Dichloropropane 78-87-5 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.3-Dichloropropylene 10061-01-5 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.3-Dichloropropylene 10061-02-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromoethane (EDB) 106-93-4 5 µg/L <5 <5 0.00 No Limit
EP074E: Halogenated Aliphatic Compounds (QC Lot: 774514)
EP074: 1.1-Dichloroethene 75-35-4 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702227-001
EP074: Iodomethane 74-88-4 5 µg/L <5 <5 0.00 No Limit
EP074: Methylene chloride 75-09-2 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.2-Dichloroethene 156-60-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloroethane 75-34-3 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.2-Dichloroethene 156-59-2 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1-Trichloroethane 71-55-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloropropylene 563-58-6 5 µg/L <5 <5 0.00 No Limit
EP074: Carbon Tetrachloride 56-23-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichloroethane 107-06-2 5 µg/L <5 <5 0.00 No Limit
EP074: Trichloroethene 79-01-6 5 µg/L 9 8 0.00 No Limit
EP074: Dibromomethane 74-95-3 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2-Trichloroethane 79-00-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichloropropane 142-28-9 5 µg/L <5 <5 0.00 No Limit
EP074: Tetrachloroethene 127-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1.2-Tetrachloroethane 630-20-6 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.4-Dichloro-2-butene 110-57-6 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.4-Dichloro-2-butene 1476-11-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2.2-Tetrachloroethane 79-34-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichloropropane 96-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: Pentachloroethane 76-01-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromo-3-chloropropane 96-12-8 5 µg/L <5 <5 0.00 No Limit
EP074: Hexachlorobutadiene 87-68-3 5 µg/L <5 <5 0.00 No Limit
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP074E: Halogenated Aliphatic Compounds (QC Lot: 774514) - continued
EP074: Dichlorodifluoromethane 75-71-8 50 µg/L <50 <50 0.00 No LimitAnonymous EM1702227-001
EP074: Chloromethane 74-87-3 50 µg/L <50 <50 0.00 No Limit
EP074: Vinyl chloride 75-01-4 50 µg/L <50 <50 0.00 No Limit
EP074: Bromomethane 74-83-9 50 µg/L <50 <50 0.00 No Limit
EP074: Chloroethane 75-00-3 50 µg/L <50 <50 0.00 No Limit
EP074: Trichlorofluoromethane 75-69-4 50 µg/L <50 <50 0.00 No Limit
EP074: 1.1-Dichloroethene 75-35-4 5 µg/L <5 <5 0.00 No LimitGW10 EM1702240-005
EP074: Iodomethane 74-88-4 5 µg/L <5 <5 0.00 No Limit
EP074: Methylene chloride 75-09-2 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.2-Dichloroethene 156-60-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloroethane 75-34-3 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.2-Dichloroethene 156-59-2 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1-Trichloroethane 71-55-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloropropylene 563-58-6 5 µg/L <5 <5 0.00 No Limit
EP074: Carbon Tetrachloride 56-23-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichloroethane 107-06-2 5 µg/L <5 <5 0.00 No Limit
EP074: Trichloroethene 79-01-6 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromomethane 74-95-3 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2-Trichloroethane 79-00-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichloropropane 142-28-9 5 µg/L <5 <5 0.00 No Limit
EP074: Tetrachloroethene 127-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1.2-Tetrachloroethane 630-20-6 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.4-Dichloro-2-butene 110-57-6 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.4-Dichloro-2-butene 1476-11-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2.2-Tetrachloroethane 79-34-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichloropropane 96-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: Pentachloroethane 76-01-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromo-3-chloropropane 96-12-8 5 µg/L <5 <5 0.00 No Limit
EP074: Hexachlorobutadiene 87-68-3 5 µg/L <5 <5 0.00 No Limit
EP074: Dichlorodifluoromethane 75-71-8 50 µg/L <50 <50 0.00 No Limit
EP074: Chloromethane 74-87-3 50 µg/L <50 <50 0.00 No Limit
EP074: Vinyl chloride 75-01-4 50 µg/L <50 <50 0.00 No Limit
EP074: Bromomethane 74-83-9 50 µg/L <50 <50 0.00 No Limit
EP074: Chloroethane 75-00-3 50 µg/L <50 <50 0.00 No Limit
EP074: Trichlorofluoromethane 75-69-4 50 µg/L <50 <50 0.00 No Limit
EP074F: Halogenated Aromatic Compounds (QC Lot: 774514)
EP074: Chlorobenzene 108-90-7 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702227-001
EP074: Bromobenzene 108-86-1 5 µg/L <5 <5 0.00 No Limit
EP074: 2-Chlorotoluene 95-49-8 5 µg/L <5 <5 0.00 No Limit
EP074: 4-Chlorotoluene 106-43-4 5 µg/L <5 <5 0.00 No Limit
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JACOBS GROUP (AUSTRALIA) PTY LTD
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP074F: Halogenated Aromatic Compounds (QC Lot: 774514) - continued
EP074: 1.3-Dichlorobenzene 541-73-1 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702227-001
EP074: 1.4-Dichlorobenzene 106-46-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichlorobenzene 95-50-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trichlorobenzene 120-82-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichlorobenzene 87-61-6 5 µg/L <5 <5 0.00 No Limit
EP074: Chlorobenzene 108-90-7 5 µg/L <5 <5 0.00 No LimitGW10 EM1702240-005
EP074: Bromobenzene 108-86-1 5 µg/L <5 <5 0.00 No Limit
EP074: 2-Chlorotoluene 95-49-8 5 µg/L <5 <5 0.00 No Limit
EP074: 4-Chlorotoluene 106-43-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichlorobenzene 541-73-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.4-Dichlorobenzene 106-46-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichlorobenzene 95-50-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trichlorobenzene 120-82-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichlorobenzene 87-61-6 5 µg/L <5 <5 0.00 No Limit
EP074G: Trihalomethanes (QC Lot: 774514)
EP074: Chloroform 67-66-3 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702227-001
EP074: Bromodichloromethane 75-27-4 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromochloromethane 124-48-1 5 µg/L <5 <5 0.00 No Limit
EP074: Bromoform 75-25-2 5 µg/L <5 <5 0.00 No Limit
EP074: Chloroform 67-66-3 5 µg/L <5 <5 0.00 No LimitGW10 EM1702240-005
EP074: Bromodichloromethane 75-27-4 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromochloromethane 124-48-1 5 µg/L <5 <5 0.00 No Limit
EP074: Bromoform 75-25-2 5 µg/L <5 <5 0.00 No Limit
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 774513)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitAnonymous EM1702227-001
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitGW10 EM1702240-005
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 774513)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitAnonymous EM1702227-001
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitGW10 EM1702240-005
EP080: BTEXN (QC Lot: 774513)
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitAnonymous EM1702227-001
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitGW10 EM1702240-005
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP080: BTEXN (QC Lot: 774513) - continued
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No LimitGW10 EM1702240-005
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
EP231A: Perfluoroalkyl Sulfonic Acids (QC Lot: 776460)
EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 32.2 33.1 2.65 0% - 20%Anonymous EB1703880-001
EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L 3.04 2.93 3.69 0% - 20%
EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L 3.36 3.18 5.41 0% - 20%
EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L 20.1 20.9 3.66 0% - 20%
EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L 1.17 1.12 4.53 0% - 20%
EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 0.11 0.12 0.00 0% - 50%GW13 EM1702240-008
EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231B: Perfluoroalkyl Carboxylic Acids (QC Lot: 776460)
EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L 1.97 1.92 2.83 0% - 20%Anonymous EB1703880-001
EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L 1.22 1.16 5.23 0% - 20%
EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L 3.51 3.04 14.3 0% - 20%
EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L 0.81 0.75 7.54 0% - 20%
EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L 0.12 0.12 0.00 No Limit
EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L 0.02 0.02 0.00 No Limit
EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L 0.6 0.5 0.00 No Limit
EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 <0.01 0.00 No LimitGW13 EM1702240-008
EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.05 µg/L <0.05 <0.05 0.00 No Limit
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP231B: Perfluoroalkyl Carboxylic Acids (QC Lot: 776460) - continued
EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L <0.1 <0.1 0.00 No LimitGW13 EM1702240-008
EP231C: Perfluoroalkyl Sulfonamides (QC Lot: 776460)
EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 <0.02 0.00 No LimitAnonymous EB1703880-001
EP231X: N-Methyl perfluorooctane
sulfonamidoacetic acid (MeFOSAA)
2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: N-Ethyl perfluorooctane
sulfonamidoacetic acid (EtFOSAA)
2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: N-Methyl perfluorooctane sulfonamide
(MeFOSA)
31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Ethyl perfluorooctane sulfonamide
(EtFOSA)
4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Methyl perfluorooctane
sulfonamidoethanol (MeFOSE)
2448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Ethyl perfluorooctane
sulfonamidoethanol (EtFOSE)
1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 <0.02 0.00 No LimitGW13 EM1702240-008
EP231X: N-Methyl perfluorooctane
sulfonamidoacetic acid (MeFOSAA)
2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: N-Ethyl perfluorooctane
sulfonamidoacetic acid (EtFOSAA)
2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: N-Methyl perfluorooctane sulfonamide
(MeFOSA)
31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Ethyl perfluorooctane sulfonamide
(EtFOSA)
4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Methyl perfluorooctane
sulfonamidoethanol (MeFOSE)
2448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Ethyl perfluorooctane
sulfonamidoethanol (EtFOSE)
1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QC Lot: 776460)
EP231X: 4:2 Fluorotelomer sulfonic acid (4:2
FTS)
757124-72-4 0.05 µg/L <0.05 <0.05 0.00 No LimitAnonymous EB1703880-001
EP231X: 6:2 Fluorotelomer sulfonic acid (6:2
FTS)
27619-97-2 0.05 µg/L 0.78 0.75 4.43 0% - 50%
EP231X: 8:2 Fluorotelomer sulfonic acid (8:2
FTS)
39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: 10:2 Fluorotelomer sulfonic acid (10:2
FTS)
120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: 4:2 Fluorotelomer sulfonic acid (4:2
FTS)
757124-72-4 0.05 µg/L <0.05 <0.05 0.00 No LimitGW13 EM1702240-008
EP231X: 6:2 Fluorotelomer sulfonic acid (6:2
FTS)
27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QC Lot: 776460) - continued
EP231X: 8:2 Fluorotelomer sulfonic acid (8:2
FTS)
39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No LimitGW13 EM1702240-008
EP231X: 10:2 Fluorotelomer sulfonic acid (10:2
FTS)
120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231P: PFAS Sums (QC Lot: 776460)
EP231X: Sum of PFAS ---- 0.01 µg/L 68.9 69.5 0.853 0% - 20%Anonymous EB1703880-001
EP231X: Sum of PFAS ---- 0.01 µg/L 0.11 0.12 8.70 0% - 50%GW13 EM1702240-008
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Method Blank (MB) and Laboratory Control Spike (LCS) Report
The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC
parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target
analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QCLot: 776587)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 1012000 mg/L 10696
<10 100293 mg/L 10696
EA025: Total Suspended Solids dried at 104 ± 2°C (QCLot: 776586)
EA025H: Suspended Solids (SS) ---- 5 mg/L <5 98.0150 mg/L 11190
ED037P: Alkalinity by PC Titrator (QCLot: 774882)
ED037-P: Total Alkalinity as CaCO3 ---- ---- mg/L ---- 99.9200 mg/L 11090
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 773883)
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L <1 10825 mg/L 11592
<1 100100 mg/L 11592
ED045G: Chloride by Discrete Analyser (QCLot: 773884)
ED045G: Chloride 16887-00-6 1 mg/L <1 98.210 mg/L 11789
<1 1071000 mg/L 11292
ED093F: Dissolved Major Cations (QCLot: 774038)
ED093F: Calcium 7440-70-2 1 mg/L <1 1015 mg/L 10892
ED093F: Magnesium 7439-95-4 1 mg/L <1 96.75 mg/L 10892
ED093F: Sodium 7440-23-5 1 mg/L <1 94.550 mg/L 10789
ED093F: Potassium 7440-09-7 1 mg/L <1 97.550 mg/L 10789
EG020F: Dissolved Metals by ICP-MS (QCLot: 774040)
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 99.60.1 mg/L 10894
EG020A-F: Beryllium 7440-41-7 0.001 mg/L <0.001 89.70.1 mg/L 11385
EG020A-F: Barium 7440-39-3 0.001 mg/L <0.001 89.20.1 mg/L 10787
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 95.90.1 mg/L 10886
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 89.20.1 mg/L 11086
EG020A-F: Cobalt 7440-48-4 0.001 mg/L <0.001 91.80.1 mg/L 10888
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 89.70.1 mg/L 10787
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 90.00.1 mg/L 10987
EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 90.30.1 mg/L 10987
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 91.50.1 mg/L 10987
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 89.40.1 mg/L 10987
EG020A-F: Vanadium 7440-62-2 0.01 mg/L <0.01 91.50.1 mg/L 11185
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 94.30.1 mg/L 10787
EG020A-F: Boron 7440-42-8 0.05 mg/L <0.05 98.30.5 mg/L 11684
EG020T: Total Metals by ICP-MS (QCLot: 775079)
EG020A-T: Arsenic 7440-38-2 0.001 mg/L <0.001 1000.1 mg/L 11394
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EG020T: Total Metals by ICP-MS (QCLot: 775079) - continued
EG020A-T: Beryllium 7440-41-7 0.001 mg/L <0.001 1030.1 mg/L 11189
EG020A-T: Barium 7440-39-3 0.001 mg/L <0.001 93.50.1 mg/L 11289
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 93.90.1 mg/L 11088
EG020A-T: Chromium 7440-47-3 0.001 mg/L <0.001 96.80.1 mg/L 11287
EG020A-T: Cobalt 7440-48-4 0.001 mg/L <0.001 97.40.1 mg/L 11388
EG020A-T: Copper 7440-50-8 0.001 mg/L <0.001 96.20.1 mg/L 11287
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 94.10.1 mg/L 11388
EG020A-T: Manganese 7439-96-5 0.001 mg/L <0.001 96.80.1 mg/L 11288
EG020A-T: Nickel 7440-02-0 0.001 mg/L <0.001 99.60.1 mg/L 11191
EG020A-T: Selenium 7782-49-2 0.01 mg/L <0.01 96.50.1 mg/L 11086
EG020A-T: Vanadium 7440-62-2 0.01 mg/L <0.01 99.90.1 mg/L 11288
EG020A-T: Zinc 7440-66-6 0.005 mg/L <0.005 98.10.1 mg/L 11288
EG020A-T: Boron 7440-42-8 0.05 mg/L <0.05 1020.5 mg/L 11888
EG035F: Dissolved Mercury by FIMS (QCLot: 774037)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 1030.01 mg/L 11788
EG035F: Dissolved Mercury by FIMS (QCLot: 774041)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 1040.01 mg/L 11788
EG035T: Total Recoverable Mercury by FIMS (QCLot: 774525)
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 1040.01 mg/L 11387
EG035T: Total Recoverable Mercury by FIMS (QCLot: 774526)
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 1080.01 mg/L 11387
EG050F: Dissolved Hexavalent Chromium (QCLot: 775560)
EG050F: Hexavalent Chromium 18540-29-9 0.01 mg/L <0.01 1090.5 mg/L 11392
EK040P: Fluoride by PC Titrator (QCLot: 779005)
EK040P: Fluoride 16984-48-8 0.1 mg/L <0.1 91.65 mg/L 11285
EK055G: Ammonia as N by Discrete Analyser (QCLot: 773793)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 1001 mg/L 11580
EK071G: Reactive Phosphorus as P by discrete analyser (QCLot: 773882)
EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L <0.01 1050.5 mg/L 10894
EP005: Total Organic Carbon (TOC) (QCLot: 775333)
EP005: Total Organic Carbon ---- 1 mg/L <1 95.6100 mg/L 10981
EP074A: Monocyclic Aromatic Hydrocarbons (QCLot: 774514)
EP074: Styrene 100-42-5 5 µg/L <5 90.720 µg/L 11981
EP074: Isopropylbenzene 98-82-8 5 µg/L <5 89.120 µg/L 12379
EP074: n-Propylbenzene 103-65-1 5 µg/L <5 81.320 µg/L 11571
EP074: 1.3.5-Trimethylbenzene 108-67-8 5 µg/L <5 83.120 µg/L 11472
EP074: sec-Butylbenzene 135-98-8 5 µg/L <5 84.220 µg/L 11472
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP074A: Monocyclic Aromatic Hydrocarbons (QCLot: 774514) - continued
EP074: 1.2.4-Trimethylbenzene 95-63-6 5 µg/L <5 84.320 µg/L 11274
EP074: tert-Butylbenzene 98-06-6 5 µg/L <5 86.820 µg/L 11473
EP074: p-Isopropyltoluene 99-87-6 5 µg/L <5 81.720 µg/L 11570
EP074: n-Butylbenzene 104-51-8 5 µg/L <5 74.220 µg/L 11662
EP074B: Oxygenated Compounds (QCLot: 774514)
EP074: Vinyl Acetate 108-05-4 50 µg/L <50 93.7200 µg/L 12673
EP074: 2-Butanone (MEK) 78-93-3 50 µg/L <50 104200 µg/L 13662
EP074: 4-Methyl-2-pentanone (MIBK) 108-10-1 50 µg/L <50 95.9200 µg/L 13273
EP074: 2-Hexanone (MBK) 591-78-6 50 µg/L <50 101200 µg/L 13668
EP074C: Sulfonated Compounds (QCLot: 774514)
EP074: Carbon disulfide 75-15-0 5 µg/L <5 78.720 µg/L 12355
EP074D: Fumigants (QCLot: 774514)
EP074: 2.2-Dichloropropane 594-20-7 5 µg/L <5 84.020 µg/L 12267
EP074: 1.2-Dichloropropane 78-87-5 5 µg/L <5 95.420 µg/L 12078
EP074: cis-1.3-Dichloropropylene 10061-01-5 5 µg/L <5 87.620 µg/L 11870
EP074: trans-1.3-Dichloropropylene 10061-02-6 5 µg/L <5 82.920 µg/L 11568
EP074: 1.2-Dibromoethane (EDB) 106-93-4 5 µg/L <5 98.020 µg/L 12078
EP074E: Halogenated Aliphatic Compounds (QCLot: 774514)
EP074: Dichlorodifluoromethane 75-71-8 50 µg/L <50 92.1200 µg/L 14062
EP074: Chloromethane 74-87-3 50 µg/L <50 96.6200 µg/L 13868
EP074: Vinyl chloride 75-01-4 50 µg/L <50 87.6200 µg/L 13964
EP074: Bromomethane 74-83-9 50 µg/L <50 67.0200 µg/L 13048
EP074: Chloroethane 75-00-3 50 µg/L <50 90.1200 µg/L 13071
EP074: Trichlorofluoromethane 75-69-4 50 µg/L <50 90.7200 µg/L 12671
EP074: 1.1-Dichloroethene 75-35-4 5 µg/L <5 89.220 µg/L 12568
EP074: Iodomethane 74-88-4 5 µg/L <5 74.820 µg/L 12027
EP074: Methylene chloride 75-09-2 5 µg/L <5 12420 µg/L 16574
EP074: trans-1.2-Dichloroethene 156-60-5 5 µg/L <5 88.920 µg/L 12173
EP074: 1.1-Dichloroethane 75-34-3 5 µg/L <5 94.820 µg/L 12077
EP074: cis-1.2-Dichloroethene 156-59-2 5 µg/L <5 95.620 µg/L 12079
EP074: 1.1.1-Trichloroethane 71-55-6 5 µg/L <5 87.920 µg/L 12070
EP074: 1.1-Dichloropropylene 563-58-6 5 µg/L <5 85.920 µg/L 12270
EP074: Carbon Tetrachloride 56-23-5 5 µg/L <5 83.420 µg/L 11966
EP074: 1.2-Dichloroethane 107-06-2 5 µg/L <5 99.320 µg/L 12079
EP074: Trichloroethene 79-01-6 5 µg/L <5 83.820 µg/L 12075
EP074: Dibromomethane 74-95-3 5 µg/L <5 98.620 µg/L 11877
EP074: 1.1.2-Trichloroethane 79-00-5 5 µg/L <5 10220 µg/L 12186
EP074: 1.3-Dichloropropane 142-28-9 5 µg/L <5 10120 µg/L 11984
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP074E: Halogenated Aliphatic Compounds (QCLot: 774514) - continued
EP074: Tetrachloroethene 127-18-4 5 µg/L <5 83.720 µg/L 11975
EP074: 1.1.1.2-Tetrachloroethane 630-20-6 5 µg/L <5 92.920 µg/L 11275
EP074: trans-1.4-Dichloro-2-butene 110-57-6 5 µg/L <5 86.520 µg/L 11963
EP074: cis-1.4-Dichloro-2-butene 1476-11-5 5 µg/L <5 74.120 µg/L 11954
EP074: 1.1.2.2-Tetrachloroethane 79-34-5 5 µg/L <5 10520 µg/L 12581
EP074: 1.2.3-Trichloropropane 96-18-4 5 µg/L <5 10320 µg/L 12581
EP074: Pentachloroethane 76-01-7 5 µg/L <5 99.520 µg/L 10963
EP074: 1.2-Dibromo-3-chloropropane 96-12-8 5 µg/L <5 92.920 µg/L 11659
EP074: Hexachlorobutadiene 87-68-3 5 µg/L <5 82.020 µg/L 12260
EP074F: Halogenated Aromatic Compounds (QCLot: 774514)
EP074: Chlorobenzene 108-90-7 5 µg/L <5 96.220 µg/L 11884
EP074: Bromobenzene 108-86-1 5 µg/L <5 92.020 µg/L 11974
EP074: 2-Chlorotoluene 95-49-8 5 µg/L <5 86.820 µg/L 11476
EP074: 4-Chlorotoluene 106-43-4 5 µg/L <5 84.220 µg/L 11373
EP074: 1.3-Dichlorobenzene 541-73-1 5 µg/L <5 89.420 µg/L 11476
EP074: 1.4-Dichlorobenzene 106-46-7 5 µg/L <5 88.720 µg/L 11876
EP074: 1.2-Dichlorobenzene 95-50-1 5 µg/L <5 94.020 µg/L 11381
EP074: 1.2.4-Trichlorobenzene 120-82-1 5 µg/L <5 79.520 µg/L 11864
EP074: 1.2.3-Trichlorobenzene 87-61-6 5 µg/L <5 91.220 µg/L 12072
EP074G: Trihalomethanes (QCLot: 774514)
EP074: Chloroform 67-66-3 5 µg/L <5 96.820 µg/L 11878
EP074: Bromodichloromethane 75-27-4 5 µg/L <5 91.620 µg/L 11569
EP074: Dibromochloromethane 124-48-1 5 µg/L <5 92.020 µg/L 10969
EP074: Bromoform 75-25-2 5 µg/L <5 91.820 µg/L 11162
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 774610)
EP075(SIM): Naphthalene 91-20-3 1 µg/L <1.0 88.35 µg/L 11039
EP075(SIM): Acenaphthylene 208-96-8 1 µg/L <1.0 96.65 µg/L 12440
EP075(SIM): Acenaphthene 83-32-9 1 µg/L <1.0 94.05 µg/L 11747
EP075(SIM): Fluorene 86-73-7 1 µg/L <1.0 1055 µg/L 11851
EP075(SIM): Phenanthrene 85-01-8 1 µg/L <1.0 97.85 µg/L 11953
EP075(SIM): Anthracene 120-12-7 1 µg/L <1.0 87.35 µg/L 11351
EP075(SIM): Fluoranthene 206-44-0 1 µg/L <1.0 1045 µg/L 12359
EP075(SIM): Pyrene 129-00-0 1 µg/L <1.0 1015 µg/L 12358
EP075(SIM): Benz(a)anthracene 56-55-3 1 µg/L <1.0 96.65 µg/L 12652
EP075(SIM): Chrysene 218-01-9 1 µg/L <1.0 1015 µg/L 12355
EP075(SIM): Benzo(b+j)fluoranthene 205-99-2
205-82-3
1 µg/L <1.0 94.95 µg/L 13152
EP075(SIM): Benzo(k)fluoranthene 207-08-9 1 µg/L <1.0 96.95 µg/L 12657
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 774610) - continued
EP075(SIM): Benzo(a)pyrene 50-32-8 0.5 µg/L <0.5 94.15 µg/L 12656
EP075(SIM): Indeno(1.2.3.cd)pyrene 193-39-5 1 µg/L <1.0 90.05 µg/L 12353
EP075(SIM): Dibenz(a.h)anthracene 53-70-3 1 µg/L <1.0 90.85 µg/L 12553
EP075(SIM): Benzo(g.h.i)perylene 191-24-2 1 µg/L <1.0 82.65 µg/L 12553
EP080/071: Total Petroleum Hydrocarbons (QCLot: 774513)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 79.7360 µg/L 12767
EP080/071: Total Petroleum Hydrocarbons (QCLot: 774611)
EP071: C10 - C14 Fraction ---- 50 µg/L <50 1113368 µg/L 12353
EP071: C15 - C28 Fraction ---- 100 µg/L <100 11114735 µg/L 13357
EP071: C29 - C36 Fraction ---- 50 µg/L <50 99.77856 µg/L 14155
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 774513)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 79.4450 µg/L 12565
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 774611)
EP071: >C10 - C16 Fraction ---- 100 µg/L <100 1045225 µg/L 12254
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 10419994 µg/L 13256
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 1081449 µg/L 13751
EP080: BTEXN (QCLot: 774513)
EP080: Benzene 71-43-2 1 µg/L <1 84.020 µg/L 12076
EP080: Toluene 108-88-3 2 µg/L <2 89.020 µg/L 12476
EP080: Ethylbenzene 100-41-4 2 µg/L <2 82.720 µg/L 12472
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 87.740 µg/L 13072
EP080: ortho-Xylene 95-47-6 2 µg/L <2 92.720 µg/L 12878
EP080: Naphthalene 91-20-3 5 µg/L <5 96.65 µg/L 12971
EP231A: Perfluoroalkyl Sulfonic Acids (QCLot: 776460)
EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L <0.02 93.20.5 µg/L 13070
EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L <0.02 95.60.5 µg/L 13070
EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L <0.02 1090.5 µg/L 13070
EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L <0.02 90.80.5 µg/L 13070
EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.01 1070.5 µg/L 13070
EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L <0.02 1150.5 µg/L 13070
EP231B: Perfluoroalkyl Carboxylic Acids (QCLot: 776460)
EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L <0.1 86.72.5 µg/L 13070
EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L <0.02 91.40.5 µg/L 13070
EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L <0.02 82.60.5 µg/L 13070
EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L <0.02 94.20.5 µg/L 13070
EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 99.00.5 µg/L 13070
EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L <0.02 1170.5 µg/L 13070
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP231B: Perfluoroalkyl Carboxylic Acids (QCLot: 776460) - continued
EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L <0.02 1160.5 µg/L 13070
EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L <0.02 1130.5 µg/L 13070
EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 1080.5 µg/L 13070
EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.02 µg/L <0.02 98.80.5 µg/L 13070
EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.05 µg/L <0.05 96.61.25 µg/L 12470
EP231C: Perfluoroalkyl Sulfonamides (QCLot: 776460)
EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 1010.5 µg/L 13070
EP231X: N-Methyl perfluorooctane sulfonamide (MeFOSA) 31506-32-8 0.05 µg/L <0.05 1171.25 µg/L 13070
EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 4151-50-2 0.05 µg/L <0.05 1021.25 µg/L 12970
EP231X: N-Methyl perfluorooctane sulfonamidoethanol
(MeFOSE)
2448-09-7 0.05 µg/L <0.05 1051.25 µg/L 12970
EP231X: N-Ethyl perfluorooctane sulfonamidoethanol
(EtFOSE)
1691-99-2 0.05 µg/L <0.05 1131.25 µg/L 12670
EP231X: N-Methyl perfluorooctane sulfonamidoacetic acid
(MeFOSAA)
2355-31-9 0.02 µg/L <0.02 83.20.5 µg/L 13070
EP231X: N-Ethyl perfluorooctane sulfonamidoacetic acid
(EtFOSAA)
2991-50-6 0.02 µg/L <0.02 82.40.5 µg/L 13070
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QCLot: 776460)
EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 757124-72-4 0.05 µg/L <0.05 89.20.5 µg/L 13070
EP231X: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) 27619-97-2 0.05 µg/L <0.05 96.00.5 µg/L 13070
EP231X: 8:2 Fluorotelomer sulfonic acid (8:2 FTS) 39108-34-4 0.05 µg/L <0.05 1110.5 µg/L 13070
EP231X: 10:2 Fluorotelomer sulfonic acid (10:2 FTS) 120226-60-0 0.05 µg/L <0.05 95.20.5 µg/L 13070
Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on
analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 773883)
Anonymous EM1702234-002 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric # Not
Determined
10 mg/L 13070
ED045G: Chloride by Discrete Analyser (QCLot: 773884)
Anonymous EM1702234-002 16887-00-6ED045G: Chloride 98.2400 mg/L 13070
EG020F: Dissolved Metals by ICP-MS (QCLot: 774040)
GW01 EM1702240-001 7440-38-2EG020A-F: Arsenic 96.50.2 mg/L 13185
7440-41-7EG020A-F: Beryllium 98.30.2 mg/L 14173
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EG020F: Dissolved Metals by ICP-MS (QCLot: 774040) - continued
GW01 EM1702240-001 7440-39-3EG020A-F: Barium 86.10.2 mg/L 12775
7440-43-9EG020A-F: Cadmium 99.00.05 mg/L 13381
7440-47-3EG020A-F: Chromium 95.70.2 mg/L 13571
7440-48-4EG020A-F: Cobalt 1020.2 mg/L 13278
7440-50-8EG020A-F: Copper 94.60.2 mg/L 13076
7439-92-1EG020A-F: Lead 90.60.2 mg/L 13375
7439-96-5EG020A-F: Manganese 98.40.2 mg/L 13464
7440-02-0EG020A-F: Nickel 99.20.2 mg/L 13173
7440-62-2EG020A-F: Vanadium 98.20.2 mg/L 13173
7440-66-6EG020A-F: Zinc 1030.2 mg/L 13175
EG020T: Total Metals by ICP-MS (QCLot: 775079)
Anonymous EM1702234-001 7440-38-2EG020A-T: Arsenic 1091 mg/L 11882
7440-41-7EG020A-T: Beryllium 1061 mg/L 12179
7440-39-3EG020A-T: Barium 1021 mg/L 11480
7440-43-9EG020A-T: Cadmium 1070.25 mg/L 12975
7440-47-3EG020A-T: Chromium 1101 mg/L 11880
7440-48-4EG020A-T: Cobalt 1081 mg/L 12082
7440-50-8EG020A-T: Copper 1051 mg/L 11581
7439-92-1EG020A-T: Lead 98.91 mg/L 12183
7439-96-5EG020A-T: Manganese 1081 mg/L 12373
7440-02-0EG020A-T: Nickel 1101 mg/L 11880
7440-62-2EG020A-T: Vanadium 1111 mg/L 11981
7440-66-6EG020A-T: Zinc 1081 mg/L 11674
EG035F: Dissolved Mercury by FIMS (QCLot: 774037)
Anonymous EM1702198-007 7439-97-6EG035F: Mercury 1080.01 mg/L 12070
EG035F: Dissolved Mercury by FIMS (QCLot: 774041)
GW19 EM1702240-009 7439-97-6EG035F: Mercury 91.80.01 mg/L 12070
EG035T: Total Recoverable Mercury by FIMS (QCLot: 774525)
Anonymous EM1702214-005 7439-97-6EG035T: Mercury 1060.01 mg/L 13070
EG035T: Total Recoverable Mercury by FIMS (QCLot: 774526)
GW11 EM1702240-006 7439-97-6EG035T: Mercury 98.50.01 mg/L 13070
EG050F: Dissolved Hexavalent Chromium (QCLot: 775560)
GW02 EM1702240-002 18540-29-9EG050F: Hexavalent Chromium 97.60.5 mg/L 12759
EK040P: Fluoride by PC Titrator (QCLot: 779005)
GW03 EM1702240-003 16984-48-8EK040P: Fluoride 89.05 mg/L 13070
EK055G: Ammonia as N by Discrete Analyser (QCLot: 773793)
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EK055G: Ammonia as N by Discrete Analyser (QCLot: 773793) - continued
Anonymous EM1702234-001 7664-41-7EK055G: Ammonia as N 1041 mg/L 13070
EK071G: Reactive Phosphorus as P by discrete analyser (QCLot: 773882)
Anonymous EM1702221-002 14265-44-2EK071G: Reactive Phosphorus as P 99.40.5 mg/L 12379
EP005: Total Organic Carbon (TOC) (QCLot: 775333)
GW02 EM1702240-002 ----EP005: Total Organic Carbon 88.3100 mg/L 11480
EP074E: Halogenated Aliphatic Compounds (QCLot: 774514)
Anonymous EM1702227-002 75-35-4EP074: 1.1-Dichloroethene 74.820 µg/L 12440
79-01-6EP074: Trichloroethene 87.020 µg/L 12654
EP074F: Halogenated Aromatic Compounds (QCLot: 774514)
Anonymous EM1702227-002 108-90-7EP074: Chlorobenzene 95.720 µg/L 13268
EP080/071: Total Petroleum Hydrocarbons (QCLot: 774513)
Anonymous EM1702227-002 ----EP080: C6 - C9 Fraction 64.7280 µg/L 12543
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 774513)
Anonymous EM1702227-002 C6_C10EP080: C6 - C10 Fraction 64.3330 µg/L 12244
EP080: BTEXN (QCLot: 774513)
Anonymous EM1702227-002 71-43-2EP080: Benzene 84.620 µg/L 13068
108-88-3EP080: Toluene 87.620 µg/L 13272
EP231A: Perfluoroalkyl Sulfonic Acids (QCLot: 776460)
Anonymous EB1703880-001 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) # Not
Determined
0.5 µg/L 13050
2706-91-4EP231X: Perfluoropentane sulfonic acid (PFPeS) # Not
Determined
0.5 µg/L 13050
355-46-4EP231X: Perfluorohexane sulfonic acid (PFHxS) # Not
Determined
0.5 µg/L 13050
375-92-8EP231X: Perfluoroheptane sulfonic acid (PFHpS) 1060.5 µg/L 13050
1763-23-1EP231X: Perfluorooctane sulfonic acid (PFOS) # Not
Determined
0.5 µg/L 13050
335-77-3EP231X: Perfluorodecane sulfonic acid (PFDS) 1140.5 µg/L 13050
EP231B: Perfluoroalkyl Carboxylic Acids (QCLot: 776460)
Anonymous EB1703880-001 375-22-4EP231X: Perfluorobutanoic acid (PFBA) 1172.5 µg/L 13050
2706-90-3EP231X: Perfluoropentanoic acid (PFPeA) 1020.5 µg/L 13050
307-24-4EP231X: Perfluorohexanoic acid (PFHxA) # Not
Determined
0.5 µg/L 13050
375-85-9EP231X: Perfluoroheptanoic acid (PFHpA) 79.80.5 µg/L 13050
335-67-1EP231X: Perfluorooctanoic acid (PFOA) 1190.5 µg/L 13050
375-95-1EP231X: Perfluorononanoic acid (PFNA) 1030.5 µg/L 13050
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EP231B: Perfluoroalkyl Carboxylic Acids (QCLot: 776460) - continued
Anonymous EB1703880-001 335-76-2EP231X: Perfluorodecanoic acid (PFDA) 79.00.5 µg/L 13050
2058-94-8EP231X: Perfluoroundecanoic acid (PFUnDA) 1110.5 µg/L 13050
307-55-1EP231X: Perfluorododecanoic acid (PFDoDA) 1220.5 µg/L 13050
72629-94-8EP231X: Perfluorotridecanoic acid (PFTrDA) 99.80.5 µg/L 13050
376-06-7EP231X: Perfluorotetradecanoic acid (PFTeDA) 82.01.25 µg/L 13050
EP231C: Perfluoroalkyl Sulfonamides (QCLot: 776460)
Anonymous EB1703880-001 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 1120.5 µg/L 13050
31506-32-8EP231X: N-Methyl perfluorooctane sulfonamide
(MeFOSA)
99.41.25 µg/L 13050
4151-50-2EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 77.21.25 µg/L 13050
2448-09-7EP231X: N-Methyl perfluorooctane sulfonamidoethanol
(MeFOSE)
1011.25 µg/L 13050
1691-99-2EP231X: N-Ethyl perfluorooctane sulfonamidoethanol
(EtFOSE)
72.31.25 µg/L 13050
2355-31-9EP231X: N-Methyl perfluorooctane sulfonamidoacetic
acid (MeFOSAA)
74.00.5 µg/L 13050
2991-50-6EP231X: N-Ethyl perfluorooctane sulfonamidoacetic
acid (EtFOSAA)
84.20.5 µg/L 13050
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QCLot: 776460)
Anonymous EB1703880-001 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 93.00.5 µg/L 13050
27619-97-2EP231X: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) 92.80.5 µg/L 13050
39108-34-4EP231X: 8:2 Fluorotelomer sulfonic acid (8:2 FTS) 80.60.5 µg/L 13050
120226-60-0EP231X: 10:2 Fluorotelomer sulfonic acid (10:2 FTS) 1050.5 µg/L 13050
True
Environmental
QA/QC Compliance Assessment to assist with Quality ReviewWork Order : EM1702240 Page : 1 of 17
:: LaboratoryClient Environmental Division MelbourneJACOBS GROUP (AUSTRALIA) PTY LTD
:Contact MR BENJAMIN GRASSO Telephone : +61-3-8549 9608
:Project IS157700 Date Samples Received : 01-Mar-2017
Site : ---- Issue Date : 08-Mar-2017
BENJAMIN GRASSO:Sampler No. of samples received : 13
:Order number ---- No. of samples analysed : 13
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated
reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this
report contribute to the overall DQO assessment and reporting for guideline compliance.
Brief method summaries and references are also provided to assist in traceability.
Summary of Outliers
Outliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.
l NO Duplicate outliers occur.
l NO Laboratory Control outliers occur.
l Matrix Spike outliers exist - please see following pages for full details.
l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliance
l Analysis Holding Time Outliers exist - please see following pages for full details.
Outliers : Frequency of Quality Control Samples
l Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Outliers : Quality Control Samples
Duplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes
Matrix: WATER
Compound Group Name CommentLimitsDataAnalyteClient Sample IDLaboratory Sample ID CAS Number
Matrix Spike (MS) Recoveries
EM1702234--002 14808-79-8Sulfate as SO4 -
Turbidimetric
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
EB1703880--001 375-73-5Perfluorobutane
sulfonic acid (PFBS)
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP231A: Perfluoroalkyl Sulfonic Acids
EB1703880--001 2706-91-4Perfluoropentane
sulfonic acid
(PFPeS)
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP231A: Perfluoroalkyl Sulfonic Acids
EB1703880--001 355-46-4Perfluorohexane
sulfonic acid
(PFHxS)
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP231A: Perfluoroalkyl Sulfonic Acids
EB1703880--001 1763-23-1Perfluorooctane
sulfonic acid (PFOS)
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP231A: Perfluoroalkyl Sulfonic Acids
EB1703880--001 307-24-4Perfluorohexanoic acid
(PFHxA)
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP231B: Perfluoroalkyl Carboxylic Acids
Outliers : Analysis Holding Time Compliance
Matrix: WATER
AnalysisExtraction / Preparation
Date analysedDate extractedContainer / Client Sample ID(s) Days
overdue
Days
overdue
Due for extraction Due for analysis
Method
EA005P: pH by PC Titrator
Clear Plastic Bottle - Natural
27-Feb-2017----GW01, GW02,
GW03, GW04,
QA_01
02-Mar-2017---- ---- 3
Clear Plastic Bottle - Natural
28-Feb-2017----GW10, GW11,
GW12, GW13,
GW19
02-Mar-2017---- ---- 2
Outliers : Frequency of Quality Control Samples
Matrix: WATER
Quality Control SpecificationQuality Control Sample Type
Method ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 10.000 17
NEPM 2013 B3 & ALS QC StandardTRH - Semivolatile Fraction 0.00 10.000 20
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Matrix: WATER
Quality Control SpecificationQuality Control Sample Type
Method ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 5.000 17
NEPM 2013 B3 & ALS QC StandardTRH - Semivolatile Fraction 0.00 5.000 20
Analysis Holding Time Compliance
Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and
should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.
Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics
14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.
If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.
This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container
provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EA005P: pH by PC Titrator
Clear Plastic Bottle - Natural (EA005-P)
GW01, GW02,
GW03, GW04,
QA_01
27-Feb-2017---- 02-Mar-2017----27-Feb-2017 ---- û
Clear Plastic Bottle - Natural (EA005-P)
GW10, GW11,
GW12, GW13,
GW19
28-Feb-2017---- 02-Mar-2017----28-Feb-2017 ---- û
EA015: Total Dissolved Solids dried at 180 ± 5 °C
Clear Plastic Bottle - Natural (EA015H)
GW01, GW02,
GW03, GW04,
QA_01
06-Mar-2017---- 03-Mar-2017----27-Feb-2017 ---- ü
Clear Plastic Bottle - Natural (EA015H)
GW10, GW11,
GW12, GW13,
GW19
07-Mar-2017---- 03-Mar-2017----28-Feb-2017 ---- ü
EA025: Total Suspended Solids dried at 104 ± 2°C
Clear Plastic Bottle - Natural (EA025H)
GW01, GW02,
GW03, GW04,
QA_01
06-Mar-2017---- 03-Mar-2017----27-Feb-2017 ---- ü
Clear Plastic Bottle - Natural (EA025H)
GW10, GW11,
GW12, GW13,
GW19
07-Mar-2017---- 03-Mar-2017----28-Feb-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
ED037P: Alkalinity by PC Titrator
Clear Plastic Bottle - Natural (ED037-P)
GW01, GW02,
GW03, GW04,
QA_01
13-Mar-2017---- 02-Mar-2017----27-Feb-2017 ---- ü
Clear Plastic Bottle - Natural (ED037-P)
GW10, GW11,
GW12, GW13,
GW19
14-Mar-2017---- 02-Mar-2017----28-Feb-2017 ---- ü
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
Clear Plastic Bottle - Natural (ED041G)
GW01, GW02,
GW03, GW04,
QA_01
27-Mar-2017---- 02-Mar-2017----27-Feb-2017 ---- ü
Clear Plastic Bottle - Natural (ED041G)
GW10, GW11,
GW12, GW13,
GW19
28-Mar-2017---- 02-Mar-2017----28-Feb-2017 ---- ü
ED045G: Chloride by Discrete Analyser
Clear Plastic Bottle - Natural (ED045G)
GW01, GW02,
GW03, GW04,
QA_01
27-Mar-2017---- 02-Mar-2017----27-Feb-2017 ---- ü
Clear Plastic Bottle - Natural (ED045G)
GW10, GW11,
GW12, GW13,
GW19
28-Mar-2017---- 02-Mar-2017----28-Feb-2017 ---- ü
ED093F: Dissolved Major Cations
Clear Plastic Bottle - Nitric Acid; Filtered (ED093F)
GW01, GW02,
GW03, GW04,
QA_01
27-Mar-2017---- 03-Mar-2017----27-Feb-2017 ---- ü
Clear Plastic Bottle - Nitric Acid; Filtered (ED093F)
GW10, GW11,
GW12, GW13,
GW19
28-Mar-2017---- 03-Mar-2017----28-Feb-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EG020F: Dissolved Metals by ICP-MS
Clear Plastic Bottle - Nitric Acid; Filtered (EG020A-F)
GW01, GW02,
GW03, GW04,
QA_01
26-Aug-2017---- 02-Mar-2017----27-Feb-2017 ---- ü
Clear Plastic Bottle - Nitric Acid; Filtered (EG020A-F)
GW10, GW11,
GW12, GW13,
GW19
27-Aug-2017---- 02-Mar-2017----28-Feb-2017 ---- ü
EG020T: Total Metals by ICP-MS
Clear Plastic Bottle - Natural (EG020A-T)
GW19 27-Aug-201727-Aug-2017 02-Mar-201702-Mar-201728-Feb-2017 ü üClear Plastic Bottle - Nitric Acid; Unfiltered (EG020A-T)
GW01, GW02,
GW03, GW04,
QA_01, RB_001
26-Aug-201726-Aug-2017 02-Mar-201702-Mar-201727-Feb-2017 ü ü
Clear Plastic Bottle - Nitric Acid; Unfiltered (EG020A-T)
GW10, GW11,
GW12, GW13
27-Aug-201727-Aug-2017 02-Mar-201702-Mar-201728-Feb-2017 ü ü
EG035F: Dissolved Mercury by FIMS
Clear Plastic Bottle - Nitric Acid; Filtered (EG035F)
GW01, GW02,
GW03, GW04,
QA_01
27-Mar-2017---- 02-Mar-2017----27-Feb-2017 ---- ü
Clear Plastic Bottle - Nitric Acid; Filtered (EG035F)
GW10, GW11,
GW12, GW13,
GW19
28-Mar-2017---- 02-Mar-2017----28-Feb-2017 ---- ü
EG035T: Total Recoverable Mercury by FIMS
Clear Plastic Bottle - Natural (EG035T)
GW19 28-Mar-2017---- 02-Mar-2017----28-Feb-2017 ---- üClear Plastic Bottle - Nitric Acid; Unfiltered (EG035T)
GW01, GW02,
GW03, GW04,
QA_01, RB_001
27-Mar-2017---- 02-Mar-2017----27-Feb-2017 ---- ü
Clear Plastic Bottle - Nitric Acid; Unfiltered (EG035T)
GW10, GW11,
GW12, GW13
28-Mar-2017---- 02-Mar-2017----28-Feb-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EG050F: Dissolved Hexavalent Chromium
Clear Plastic Bottle - NaOH Filtered (EG050F)
GW01, GW02,
GW03, GW04,
QA_01
27-Mar-2017---- 02-Mar-2017----27-Feb-2017 ---- ü
Clear Plastic Bottle - NaOH Filtered (EG050F)
GW10, GW11,
GW12, GW13,
GW19
28-Mar-2017---- 02-Mar-2017----28-Feb-2017 ---- ü
EK040P: Fluoride by PC Titrator
Clear Plastic Bottle - Natural (EK040P)
GW01, GW02,
GW03, GW04,
QA_01
27-Mar-2017---- 06-Mar-2017----27-Feb-2017 ---- ü
Clear Plastic Bottle - Natural (EK040P)
GW10, GW11,
GW12, GW13,
GW19
28-Mar-2017---- 06-Mar-2017----28-Feb-2017 ---- ü
EK055G: Ammonia as N by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK055G)
GW01, GW02,
GW03, GW04,
QA_01
27-Mar-2017---- 03-Mar-2017----27-Feb-2017 ---- ü
Clear Plastic Bottle - Sulfuric Acid (EK055G)
GW10, GW11,
GW12, GW13,
GW19
28-Mar-2017---- 03-Mar-2017----28-Feb-2017 ---- ü
EK071G: Reactive Phosphorus as P by discrete analyser
Clear Plastic Bottle - Natural (EK071G)
GW01, GW02,
GW03, GW04,
QA_01
01-Mar-2017---- 01-Mar-2017----27-Feb-2017 ---- ü
Clear Plastic Bottle - Natural (EK071G)
GW10, GW11,
GW12, GW13,
GW19
02-Mar-2017---- 01-Mar-2017----28-Feb-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP005: Total Organic Carbon (TOC)
Amber VOC Vial - Sulfuric Acid (EP005)
GW01, GW02,
GW03, GW04,
QA_01
27-Mar-2017---- 02-Mar-2017----27-Feb-2017 ---- ü
Amber VOC Vial - Sulfuric Acid (EP005)
GW10, GW11,
GW12, GW13,
GW19
28-Mar-2017---- 02-Mar-2017----28-Feb-2017 ---- ü
EP074A: Monocyclic Aromatic Hydrocarbons
Amber VOC Vial - Sulfuric Acid (EP074)
GW01, GW02,
GW03, GW04,
QA_01
13-Mar-201713-Mar-2017 03-Mar-201702-Mar-201727-Feb-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP074)
GW10, GW11,
GW12, GW13,
GW19
14-Mar-201714-Mar-2017 03-Mar-201702-Mar-201728-Feb-2017 ü ü
EP074B: Oxygenated Compounds
Amber VOC Vial - Sulfuric Acid (EP074)
GW01, GW02,
GW03, GW04,
QA_01
13-Mar-201713-Mar-2017 03-Mar-201702-Mar-201727-Feb-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP074)
GW10, GW11,
GW12, GW13,
GW19
14-Mar-201714-Mar-2017 03-Mar-201702-Mar-201728-Feb-2017 ü ü
EP074C: Sulfonated Compounds
Amber VOC Vial - Sulfuric Acid (EP074)
GW01, GW02,
GW03, GW04,
QA_01
13-Mar-201713-Mar-2017 03-Mar-201702-Mar-201727-Feb-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP074)
GW10, GW11,
GW12, GW13,
GW19
14-Mar-201714-Mar-2017 03-Mar-201702-Mar-201728-Feb-2017 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP074D: Fumigants
Amber VOC Vial - Sulfuric Acid (EP074)
GW01, GW02,
GW03, GW04,
QA_01
13-Mar-201713-Mar-2017 03-Mar-201702-Mar-201727-Feb-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP074)
GW10, GW11,
GW12, GW13,
GW19
14-Mar-201714-Mar-2017 03-Mar-201702-Mar-201728-Feb-2017 ü ü
EP074E: Halogenated Aliphatic Compounds
Amber VOC Vial - Sulfuric Acid (EP074)
GW01, GW02,
GW03, GW04,
QA_01
13-Mar-201713-Mar-2017 03-Mar-201702-Mar-201727-Feb-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP074)
GW10, GW11,
GW12, GW13,
GW19
14-Mar-201714-Mar-2017 03-Mar-201702-Mar-201728-Feb-2017 ü ü
EP074F: Halogenated Aromatic Compounds
Amber VOC Vial - Sulfuric Acid (EP074)
GW01, GW02,
GW03, GW04,
QA_01
13-Mar-201713-Mar-2017 03-Mar-201702-Mar-201727-Feb-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP074)
GW10, GW11,
GW12, GW13,
GW19
14-Mar-201714-Mar-2017 03-Mar-201702-Mar-201728-Feb-2017 ü ü
EP074G: Trihalomethanes
Amber VOC Vial - Sulfuric Acid (EP074)
GW01, GW02,
GW03, GW04,
QA_01
13-Mar-201713-Mar-2017 03-Mar-201702-Mar-201727-Feb-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP074)
GW10, GW11,
GW12, GW13,
GW19
14-Mar-201714-Mar-2017 03-Mar-201702-Mar-201728-Feb-2017 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
Amber Glass Bottle - Unpreserved (EP075(SIM))
GW01, GW02,
GW03, GW04,
QA_01
12-Apr-201706-Mar-2017 03-Mar-201703-Mar-201727-Feb-2017 ü ü
Amber Glass Bottle - Unpreserved (EP075(SIM))
GW10, GW11,
GW12, GW13,
GW19
12-Apr-201707-Mar-2017 03-Mar-201703-Mar-201728-Feb-2017 ü ü
EP080/071: Total Petroleum Hydrocarbons
Amber Glass Bottle - Unpreserved (EP071)
GW01, GW02,
GW03, GW04,
QA_01
12-Apr-201706-Mar-2017 03-Mar-201703-Mar-201727-Feb-2017 ü ü
Amber Glass Bottle - Unpreserved (EP071)
GW10, GW11,
GW12, GW13,
GW19
12-Apr-201707-Mar-2017 03-Mar-201703-Mar-201728-Feb-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
GW01, GW02,
GW03, GW04,
QA_01, TB_001
13-Mar-201713-Mar-2017 03-Mar-201702-Mar-201727-Feb-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
GW10, GW11,
GW12, GW13,
GW19, TB_002
14-Mar-201714-Mar-2017 03-Mar-201702-Mar-201728-Feb-2017 ü ü
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
Amber Glass Bottle - Unpreserved (EP071)
GW01, GW02,
GW03, GW04,
QA_01
12-Apr-201706-Mar-2017 03-Mar-201703-Mar-201727-Feb-2017 ü ü
Amber Glass Bottle - Unpreserved (EP071)
GW10, GW11,
GW12, GW13,
GW19
12-Apr-201707-Mar-2017 03-Mar-201703-Mar-201728-Feb-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
GW01, GW02,
GW03, GW04,
QA_01, TB_001
13-Mar-201713-Mar-2017 03-Mar-201702-Mar-201727-Feb-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
GW10, GW11,
GW12, GW13,
GW19, TB_002
14-Mar-201714-Mar-2017 03-Mar-201702-Mar-201728-Feb-2017 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP080: BTEXN
Amber VOC Vial - Sulfuric Acid (EP080)
GW01, GW02,
GW03, GW04,
QA_01, TB_001
13-Mar-201713-Mar-2017 03-Mar-201702-Mar-201727-Feb-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
GW10, GW11,
GW12, GW13,
GW19, TB_002
14-Mar-201714-Mar-2017 03-Mar-201702-Mar-201728-Feb-2017 ü ü
EP231A: Perfluoroalkyl Sulfonic Acids
HDPE (no PTFE) (EP231X)
GW01, GW02,
GW03, GW04,
QA_01
26-Aug-2017---- 06-Mar-2017----27-Feb-2017 ---- ü
HDPE (no PTFE) (EP231X)
GW10, GW11,
GW12, GW13,
GW19
27-Aug-2017---- 06-Mar-2017----28-Feb-2017 ---- ü
EP231B: Perfluoroalkyl Carboxylic Acids
HDPE (no PTFE) (EP231X)
GW01, GW02,
GW03, GW04,
QA_01
26-Aug-2017---- 06-Mar-2017----27-Feb-2017 ---- ü
HDPE (no PTFE) (EP231X)
GW10, GW11,
GW12, GW13,
GW19
27-Aug-2017---- 06-Mar-2017----28-Feb-2017 ---- ü
EP231C: Perfluoroalkyl Sulfonamides
HDPE (no PTFE) (EP231X)
GW01, GW02,
GW03, GW04,
QA_01
26-Aug-2017---- 06-Mar-2017----27-Feb-2017 ---- ü
HDPE (no PTFE) (EP231X)
GW10, GW11,
GW12, GW13,
GW19
27-Aug-2017---- 06-Mar-2017----28-Feb-2017 ---- ü
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IS157700:Project
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP231D: (n:2) Fluorotelomer Sulfonic Acids
HDPE (no PTFE) (EP231X)
GW01, GW02,
GW03, GW04,
QA_01
26-Aug-2017---- 06-Mar-2017----27-Feb-2017 ---- ü
HDPE (no PTFE) (EP231X)
GW10, GW11,
GW12, GW13,
GW19
27-Aug-2017---- 06-Mar-2017----28-Feb-2017 ---- ü
EP231P: PFAS Sums
HDPE (no PTFE) (EP231X)
GW01, GW02,
GW03, GW04,
QA_01
26-Aug-2017---- 06-Mar-2017----27-Feb-2017 ---- ü
HDPE (no PTFE) (EP231X)
GW10, GW11,
GW12, GW13,
GW19
27-Aug-2017---- 06-Mar-2017----28-Feb-2017 ---- ü
12 of 17:Page
Work Order :
:Client
EM1702240
JACOBS GROUP (AUSTRALIA) PTY LTD
IS157700:Project
Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to
the expected rate. A listing of breaches is provided in the Summary of Outliers.
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC Standard 10.53 10.002 19 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 11.11 10.002 18 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 13.04 10.003 23 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 15.38 10.002 13 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üFluoride by PC Titrator EK040P
NEPM 2013 B3 & ALS QC Standard 13.33 10.002 15 üHexavalent Chromium - Dissolved EG050F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 17 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üpH by PC Titrator EA005-P
NEPM 2013 B3 & ALS QC Standard 16.67 10.002 12 üReactive Phosphorus as P-By Discrete Analyser EK071G
NEPM 2013 B3 & ALS QC Standard 11.11 10.002 18 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üSuspended Solids (High Level) EA025H
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 10.81 10.004 37 üTotal Mercury by FIMS EG035T
NEPM 2013 B3 & ALS QC Standard 12.50 10.002 16 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 20.00 10.002 10 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 20 ûTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTRH Volatiles/BTEX EP080
NEPM 2013 B3 & ALS QC Standard 12.50 10.002 16 üVolatile Organic Compounds EP074
Laboratory Control Samples (LCS)
NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 11.11 10.002 18 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 8.70 5.002 23 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 7.69 5.001 13 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üFluoride by PC Titrator EK040P
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üHexavalent Chromium - Dissolved EG050F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üReactive Phosphorus as P-By Discrete Analyser EK071G
NEPM 2013 B3 & ALS QC Standard 11.11 10.002 18 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üSuspended Solids (High Level) EA025H
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Dissolved Solids (High Level) EA015H
13 of 17:Page
Work Order :
:Client
EM1702240
JACOBS GROUP (AUSTRALIA) PTY LTD
IS157700:Project
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Control Samples (LCS) - Continued
NEPM 2013 B3 & ALS QC Standard 5.41 5.002 37 üTotal Mercury by FIMS EG035T
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH Volatiles/BTEX EP080
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üVolatile Organic Compounds EP074
Method Blanks (MB)
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 8.70 5.002 23 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 7.69 5.001 13 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üFluoride by PC Titrator EK040P
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üHexavalent Chromium - Dissolved EG050F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üReactive Phosphorus as P-By Discrete Analyser EK071G
NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üSuspended Solids (High Level) EA025H
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 5.41 5.002 37 üTotal Mercury by FIMS EG035T
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH Volatiles/BTEX EP080
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üVolatile Organic Compounds EP074
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 8.70 5.002 23 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 7.69 5.001 13 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üFluoride by PC Titrator EK040P
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üHexavalent Chromium - Dissolved EG050F
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 17 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üReactive Phosphorus as P-By Discrete Analyser EK071G
NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 5.41 5.002 37 üTotal Mercury by FIMS EG035T
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 10.00 5.001 10 üTotal Organic Carbon EP005
14 of 17:Page
Work Order :
:Client
EM1702240
JACOBS GROUP (AUSTRALIA) PTY LTD
IS157700:Project
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Matrix Spikes (MS) - Continued
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 20 ûTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTRH Volatiles/BTEX EP080
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üVolatile Organic Compounds EP074
15 of 17:Page
Work Order :
:Client
EM1702240
JACOBS GROUP (AUSTRALIA) PTY LTD
IS157700:Project
Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the
Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 H+ B. This procedure determines pH of water samples by automated ISE.
This method is compliant with NEPM (2013) Schedule B(3)
pH by PC Titrator EA005-P WATER
In house: Referenced to APHA 2540C. A gravimetric procedure that determines the amount of `filterable` residue
in an aqueous sample. A well-mixed sample is filtered through a glass fibre filter (1.2um). The filtrate is
evaporated to dryness and dried to constant weight at 180+/-5C. This method is compliant with NEPM (2013)
Schedule B(3)
Total Dissolved Solids (High Level) EA015H WATER
In house: Referenced to APHA 2540D. A gravimetric procedure employed to determine the amount of
`non-filterable` residue in a aqueous sample. The prescribed GFC (1.2um) filter is rinsed with deionised water,
oven dried and weighed prior to analysis. A well-mixed sample is filtered through a glass fibre filter (1.2um).
The residue on the filter paper is dried at 104+/-2C . This method is compliant with NEPM (2013) Schedule B(3)
Suspended Solids (High Level) EA025H WATER
In house: Referenced to APHA 2320 B This procedure determines alkalinity by automated measurement (e.g. PC
Titrate) using pH 4.5 for indicating the total alkalinity end-point. This method is compliant with NEPM (2013)
Schedule B(3)
Alkalinity by PC Titrator ED037-P WATER
In house: Referenced to APHA 4500-SO4. Dissolved sulfate is determined in a 0.45um filtered sample. Sulfate
ions are converted to a barium sulfate suspension in an acetic acid medium with barium chloride. Light
absorbance of the BaSO4 suspension is measured by a photometer and the SO4-2 concentration is determined
by comparison of the reading with a standard curve. This method is compliant with NEPM (2013) Schedule B(3)
Sulfate (Turbidimetric) as SO4 2- by
Discrete Analyser
ED041G WATER
In house: Referenced to APHA 4500 Cl - G.The thiocyanate ion is liberated from mercuric thiocyanate through
sequestration of mercury by the chloride ion to form non-ionised mercuric chloride.in the presence of ferric ions
the librated thiocynate forms highly-coloured ferric thiocynate which is measured at 480 nm APHA 21st edition
seal method 2 017-1-L april 2003
Chloride by Discrete Analyser ED045G WATER
In house: Referenced to APHA 3120 and 3125; USEPA SW 846 - 6010 and 6020; Cations are determined by
either ICP-AES or ICP-MS techniques. This method is compliant with NEPM (2013) Schedule B(3)
Sodium Adsorption Ratio is calculated from Ca, Mg and Na which determined by ALS in house method
QWI-EN/ED093F. This method is compliant with NEPM (2013) Schedule B(3)
Hardness parameters are calculated based on APHA 2340 B. This method is compliant with NEPM (2013)
Schedule B(3)
Major Cations - Dissolved ED093F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. Samples are 0.45µm filtered
prior to analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions
are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct
mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Dissolved Metals by ICP-MS - Suite A EG020A-F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. The ICPMS technique utilizes
a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass
spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their
measurement by a discrete dynode ion detector.
Total Metals by ICP-MS - Suite A EG020A-T WATER
16 of 17:Page
Work Order :
:Client
EM1702240
JACOBS GROUP (AUSTRALIA) PTY LTD
IS157700:Project
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS)
Samples are 0.45µm filtered prior to analysis. FIM-AAS is an automated flameless atomic absorption technique.
A bromate/bromide reagent is used to oxidise any organic mercury compounds in the filtered sample. The ionic
mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell.
Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM
(2013) Schedule B(3)
Dissolved Mercury by FIMS EG035F WATER
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS)
FIM-AAS is an automated flameless atomic absorption technique. A bromate/bromide reagent is used to oxidise
any organic mercury compounds in the unfiltered sample. The ionic mercury is reduced online to atomic
mercury vapour by SnCl2 which is then purged into a heated quartz cell. Quantification is by comparing
absorbance against a calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Total Mercury by FIMS EG035T WATER
In house: Referenced to APHA 3500 Cr-B. Samples are 0.45µm filtered prior to analysis. Hexavalent chromium is
determined on filtered water sample as received by pH adjustment and colour development using
dephenylcarbazide. Each run of samples is measured against a five-point calibration curve. This method is
compliant with NEPM (2013) Schedule B(3)
Hexavalent Chromium - Dissolved EG050F WATER
In house: Referenced to APHA 4500-F C: CDTA is added to the sample to provide a uniform ionic strength
background, adjust pH, and break up complexes. Fluoride concentration is determined by either manual or
automatic ISE measurement. This method is compliant with NEPM (2013) Schedule B(3)
Fluoride by PC Titrator EK040P WATER
In house: Referenced to APHA 4500-NH3 G Ammonia is determined by direct colorimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Ammonia as N by Discrete analyser EK055G WATER
In house: Referenced to APHA 4500-P F Ammonium molybdate and potassium antimonyl tartrate reacts in acid
medium with othophosphate to form a heteropoly acid -phosphomolybdic acid - which is reduced to intensely
coloured molybdenum blue by ascorbic acid. Quantification is by Discrete Analyser. This method is compliant
with NEPM (2013) Schedule B(3)
Reactive Phosphorus as P-By Discrete
Analyser
EK071G WATER
In house: Referenced to APHA 1030F. This method is compliant with NEPM (2013) Schedule B(3)Ionic Balance by PCT DA and Turbi SO4
DA
EN055 - PG WATER
In house: Referenced to APHA 5310 B, The automated TOC analyzer determines Total and Inorganic Carbon by
IR cell. TOC is calculated as the difference. This method is compliant with NEPM (2013) Schedule B(3)
Total Organic Carbon EP005 WATER
In house: Referenced to USEPA SW 846 - 8015A The sample extract is analysed by Capillary GC/FID and
quantification is by comparison against an established 5 point calibration curve of n-Alkane standards. This
method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH - Semivolatile Fraction EP071 WATER
In house: Referenced to USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by
Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. This
method is compliant with NEPM (2013) Schedule B(3)
Volatile Organic Compounds EP074 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS in SIM Mode
and quantification is by comparison against an established 5 point calibration curve. This method is compliant
with NEPM (2013) Schedule B(3)
PAH/Phenols (GC/MS - SIM) EP075(SIM) WATER
In house: Referenced to USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by
Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve.
Alternatively, a sample is equilibrated in a headspace vial and a portion of the headspace determined by GCMS
analysis. This method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH Volatiles/BTEX EP080 WATER
17 of 17:Page
Work Order :
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EM1702240
JACOBS GROUP (AUSTRALIA) PTY LTD
IS157700:Project
Analytical Methods Method DescriptionsMatrixMethod
In house: Direct injection analysis of fresh waters after dilution (1:1) with methanol. Analysis by
LC-Electrospray-MS-MS, Negative Mode using MRM. PFOS is quantified using a certified, traceable standard
consisting of linear and branched PFOS isomers.
Per- and Polyfluoroalkyl Substances
(PFAS) by LCMSMS
EP231X WATER
Preparation Methods Method DescriptionsMatrixMethod
In house: Referenced to USEPA SW846-3005. Method 3005 is a Nitric/Hydrochloric acid digestion procedure
used to prepare surface and ground water samples for analysis by ICPAES or ICPMS. This method is compliant
with NEPM (2013) Schedule B(3)
Digestion for Total Recoverable Metals EN25 WATER
In house: Referenced to USEPA SW 846 - 3510B 100 mL to 1L of sample is transferred to a separatory funnel
and serially extracted three times using 60mL DCM for each extract. The resultant extracts are combined,
dehydrated and concentrated for analysis. This method is compliant with NEPM (2013) Schedule B(3) . ALS
default excludes sediment which may be resident in the container.
Separatory Funnel Extraction of Liquids ORG14 WATER
A 5 mL aliquot or 5 mL of a diluted sample is added to a 40 mL VOC vial for sparging.Volatiles Water Preparation ORG16-W WATER
Environmental
SAMPLE RECEIPT NOTIFICATION (SRN)Work Order : EM1702240
:: LaboratoryClient Environmental Division MelbourneJACOBS GROUP (AUSTRALIA) PTY
LTD
: :ContactContact MR BENJAMIN GRASSO Carol Walsh
:: AddressAddress P O BOX 312 FLINDERS LANE
MELBOURNE VIC AUSTRALIA 8009
4 Westall Rd Springvale VIC Australia
3171
:: E-mailE-mail [email protected] [email protected]
:: TelephoneTelephone +61 03 8668 3000 +61-3-8549 9608
:: FacsimileFacsimile +61 03 8668 3001 +61-3-8549 9601
::Project IS157700 Page 1 of 3
:Order number ---- :Quote number EM2016SINKNI0001 (EN/003/16 Pri
BQ)
:C-O-C number ---- :QC Level NEPM 2013 B3 & ALS QC Standard
Site : ----
Sampler : BENJAMIN GRASSO
DatesDate Samples Received : Issue Date : 01-Mar-201701-Mar-2017 11:05
Scheduled Reporting Date: 08-Mar-2017:Client Requested Due
Date
08-Mar-2017
Delivery DetailsMode of Delivery : :Carrier Intact.Security Seal
No. of coolers/boxes : :2 Temperature 8.1°C - Ice present
: : 13 / 13Receipt Detail No. of samples received / analysed
General Comments
This report contains the following information:l
- Sample Container(s)/Preservation Non-Compliances
- Summary of Sample(s) and Requested Analysis
- Proactive Holding Time Report
- Requested Deliverables
l Please direct any queries related to sample condition / numbering / breakages to Client Services.l Sample Disposal - Aqueous (14 days), Solid (60 days) from date of completion of work order.
l Analytical work for this work order will be conducted at ALS Springvale & ALS Sydney.l Please refer to the Proactive Holding Time Report table below which summarises breaches of
recommended holding times that have occurred prior to samples/instructions being received at
the laboratory. The absence of this summary table indicates that all samples have been received
within the recommended holding times for the analysis requested.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
:Client JACOBS GROUP (AUSTRALIA) PTY LTD
Work Order : EM1702240 Amendment 02 of 3:Page
01-Mar-2017:Issue Date
Sample Container(s)/Preservation Non-Compliances
All comparisons are made against pretreatment/preservation AS, APHA, USEPA standards.
MethodSample Container Received Preferred Sample Container for AnalysisClient sample ID
Total Mercury by FIMS : EG035T
GW19 - Clear Plastic Bottle - Natural - Clear Plastic Bottle - Nitric Acid;
Unfiltered
Total Metals by ICP-MS - Suite A : EG020A-T
GW19 - Clear Plastic Bottle - Natural - Clear Plastic Bottle - Nitric Acid;
Unfiltered
Summary of Sample(s) and Requested Analysis
Some items described below may be part of a laboratory
process necessary for the execution of client requested
tasks. Packages may contain additional analyses, such
as the determination of moisture content and preparation
tasks, that are included in the package.
If no sampling time is provided, the sampling time will
default 00:00 on the date of sampling. If no sampling date
is provided, the sampling date will be assumed by the
laboratory and displayed in brackets without a time
component
WA
TE
R -
EG
05
0F
Dis
solv
ed
He
xava
len
t C
hro
miu
m
WA
TE
R -
EK
05
5G
Am
mo
nia
as
N B
y D
iscr
ete
An
aly
ser
WA
TE
R -
EP
23
1X
PF
AS
- F
ull
Su
ite (
28
an
aly
tes)
WA
TE
R -
NT
-01
& 0
2
Ca
, M
g, N
a, K
, C
l, S
O4, A
lkalin
ity
WA
TE
R -
W-0
3
15
Me
tals
(N
EP
M S
uite
)
WA
TE
R -
W-0
3T
15
Me
tals
(T
ota
l) (
NE
PM
)
WA
TE
R -
W-1
0
TR
H/V
OC
/PA
H
EM1702240-001 27-Feb-2017 00:00 GW01 ü ü ü ü ü ü ü
EM1702240-002 27-Feb-2017 00:00 GW02 ü ü ü ü ü ü ü
EM1702240-003 27-Feb-2017 00:00 GW03 ü ü ü ü ü ü ü
EM1702240-004 27-Feb-2017 00:00 GW04 ü ü ü ü ü ü ü
EM1702240-005 28-Feb-2017 00:00 GW10 ü ü ü ü ü ü ü
EM1702240-006 28-Feb-2017 00:00 GW11 ü ü ü ü ü ü ü
EM1702240-007 28-Feb-2017 00:00 GW12 ü ü ü ü ü ü ü
EM1702240-008 28-Feb-2017 00:00 GW13 ü ü ü ü ü ü ü
EM1702240-009 28-Feb-2017 00:00 GW19 ü ü ü ü ü ü ü
EM1702240-010 27-Feb-2017 00:00 QA_01 ü ü ü ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
WA
TE
R -
EA
005P
pH
(P
C)
WA
TE
R -
EA
015H
Tota
l Dis
solv
ed S
olid
s -
Hig
h L
eve
l
WA
TE
R -
EA
025H
Susp
ended S
olid
s (H
igh L
eve
l)
WA
TE
R -
EK
071G
React
ive P
hosp
horu
s by
Dis
crete
analy
ser
WA
TE
R -
EP
005
Tota
l Org
anic
Carb
on (
TO
C)
WA
TE
R -
W-0
2T
8 m
eta
ls (
Tota
l)
WA
TE
R -
W-1
8
TR
H(C
6 -
C9)/
BT
EX
N
EM1702240-001 27-Feb-2017 00:00 GW01 ü ü ü ü ü
EM1702240-002 27-Feb-2017 00:00 GW02 ü ü ü ü ü
EM1702240-003 27-Feb-2017 00:00 GW03 ü ü ü ü ü
EM1702240-004 27-Feb-2017 00:00 GW04 ü ü ü ü ü
EM1702240-005 28-Feb-2017 00:00 GW10 ü ü ü ü ü
EM1702240-006 28-Feb-2017 00:00 GW11 ü ü ü ü ü
EM1702240-007 28-Feb-2017 00:00 GW12 ü ü ü ü ü
EM1702240-008 28-Feb-2017 00:00 GW13 ü ü ü ü ü
EM1702240-009 28-Feb-2017 00:00 GW19 ü ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
:Client JACOBS GROUP (AUSTRALIA) PTY LTD
Work Order : EM1702240 Amendment 03 of 3:Page
01-Mar-2017:Issue Date
WA
TE
R -
EA
00
5P
pH
(P
C)
WA
TE
R -
EA
01
5H
Tota
l Dis
solv
ed
Solid
s
- H
igh
Le
vel
WA
TE
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EM1702240-010 27-Feb-2017 00:00 QA_01 ü ü ü ü ü
EM1702240-011 27-Feb-2017 00:00 RB_001 ü
EM1702240-012 27-Feb-2017 00:00 TB_001 ü
EM1702240-013 28-Feb-2017 00:00 TB_002 ü
Proactive Holding Time Report
The following table summarises breaches of recommended holding times that have occurred prior to samples/instructions being
received at the laboratory.
Evaluation: û = Holding time breach ; ü = Within holding time. Matrix: WATER
EvaluationClient Sample ID(s)
Due for
extraction
Due for
analysis Evaluation
Samples Received Instructions Received
Date Date
Method
Container
EA005-P: pH by PC Titrator
GW01 û --------01-Mar-201727-Feb-2017----Clear Plastic Bottle - Natural
GW02 û --------01-Mar-201727-Feb-2017----Clear Plastic Bottle - Natural
GW03 û --------01-Mar-201727-Feb-2017----Clear Plastic Bottle - Natural
GW04 û --------01-Mar-201727-Feb-2017----Clear Plastic Bottle - Natural
GW10 û --------01-Mar-201728-Feb-2017----Clear Plastic Bottle - Natural
GW11 û --------01-Mar-201728-Feb-2017----Clear Plastic Bottle - Natural
GW12 û --------01-Mar-201728-Feb-2017----Clear Plastic Bottle - Natural
GW13 û --------01-Mar-201728-Feb-2017----Clear Plastic Bottle - Natural
GW19 û --------01-Mar-201728-Feb-2017----Clear Plastic Bottle - Natural
QA_01 û --------01-Mar-201727-Feb-2017----Clear Plastic Bottle - Natural
Requested Deliverables
BENJAMIN GRASSO
- *AU Certificate of Analysis - NATA (COA) Email [email protected]
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email [email protected]
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email [email protected]
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email [email protected]
- A4 - AU Tax Invoice (INV) Email [email protected]
- Chain of Custody (CoC) (COC) Email [email protected]
- Chromatogram (CHROM) Email [email protected]
- EDI Format - ESDAT (ESDAT) Email [email protected]
- EDI Format - XTab (XTAB) Email [email protected]
INVOICE ONLY (JACOBS)
- A4 - AU Tax Invoice (INV) Email [email protected]
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 12EM1702312
:: LaboratoryClient JACOBS GROUP (AUSTRALIA) PTY LTD Environmental Division Melbourne
: :ContactContact MR BENJAMIN GRASSO Carol Walsh
:: AddressAddress P O BOX 312 FLINDERS LANE
MELBOURNE VIC AUSTRALIA 8009
4 Westall Rd Springvale VIC Australia 3171
:Telephone +61 03 8668 3000 :Telephone +61-3-8549 9608
:Project IS157700 Date Samples Received : 02-Mar-2017 08:55
:Order number ---- Date Analysis Commenced : 02-Mar-2017
:C-O-C number ---- Issue Date : 09-Mar-2017 16:15
Sampler : BENJAMIN GRASSO
Site : ----
Quote number : ME/088/17
8:No. of samples received
8:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:
l General Comments
l Analytical Results
l Surrogate Control Limits
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with
Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Dilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VIC
Lana Nguyen Senior LCMS Chemist Sydney Organics, Smithfield, NSW
Nancy Wang Senior Semivolatile Instrument Chemist Melbourne Organics, Springvale, VIC
Nikki Stepniewski Senior Inorganic Instrument Chemist Melbourne Inorganics, Springvale, VIC
Xing Lin Senior Organic Chemist Melbourne Organics, Springvale, VIC
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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JACOBS GROUP (AUSTRALIA) PTY LTD
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When no sampling time is provided, the sampling time will default 00:00 on the date of sampling. If no sampling date is provided, the sampling date will be assumed by the laboratory and displayed in brackets without a
time component.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
^ = This result is computed from individual analyte detections at or above the level of reporting
ø = ALS is not NATA accredited for these tests.
~ = Indicates an estimated value.
Key :
EG035T: Mercury result for EM1702312 #1, #3 and #5 has been confirmed by re-preparation and re-analysis.l
It is recognised that total metals is less than dissolved metals for samples #1, #2 and #5. However, the difference is within experimental variation of the methods.l
EG020T: Sample EM1702312-005 has been diluted prior to analysis due to sample matrix and LORs have been raised accordingly.l
Sample GW16 was filtered through a 0.45um filter prior to the dissolved metals analysis.l
EP231X: Particular samples required dilution prior to extraction due to matrix interferences. LOR values have been adjusted accordingly.l
Ionic balances were calculated using: major anions - chloride, alkalinity and sulfate; and major cations - calcium, magnesium, potassium and sodium.l
ED045G: The presence of thiocyanate can positively contribute to the chloride result, thereby may bias results higher than expected. Results should be scrutinised accordingly.l
Benzo(a)pyrene Toxicity Equivalent Quotient (TEQ) is the sum total of the concentration of the eight carcinogenic PAHs multiplied by their Toxicity Equivalence Factor (TEF) relative to Benzo(a)pyrene. TEF values
are provided in brackets as follows: Benz(a)anthracene (0.1), Chrysene (0.01), Benzo(b+j) & Benzo(k)fluoranthene (0.1), Benzo(a)pyrene (1.0), Indeno(1.2.3.cd)pyrene (0.1), Dibenz(a.h)anthracene (1.0),
Benzo(g.h.i)perylene (0.01). Less than LOR results for 'TEQ Zero' are treated as zero.
l
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Analytical Results
GW16GW18GW17GW09GW08Client sample IDSub-Matrix: WATER
(Matrix: WATER)
01-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:00Client sampling date / time
EM1702312-005EM1702312-004EM1702312-003EM1702312-002EM1702312-001UnitLORCAS NumberCompound
Result Result Result Result Result
EA005P: pH by PC Titrator
6.27 4.61 7.18 8.18 6.86pH Unit0.01----pH Value
EA015: Total Dissolved Solids dried at 180 ± 5 °C
4150 4040 5960 2290 5850mg/L10----Total Dissolved Solids @180°C
EA025: Total Suspended Solids dried at 104 ± 2°C
2580 2190 9620 86 66000mg/L5----Suspended Solids (SS)
ED037P: Alkalinity by PC Titrator
<1Hydroxide Alkalinity as CaCO3 <1 <1 <1 <1mg/L1DMO-210-001
<1Carbonate Alkalinity as CaCO3 <1 <1 <1 <1mg/L13812-32-6
3Bicarbonate Alkalinity as CaCO3 <1 78 296 128mg/L171-52-3
3 <1 78 296 128mg/L1----Total Alkalinity as CaCO3
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
32Sulfate as SO4 - Turbidimetric 22 222 524 115mg/L114808-79-8
ED045G: Chloride by Discrete Analyser
1890Chloride 2150 3060 652 3720mg/L116887-00-6
ED093F: Dissolved Major Cations
39Calcium 26 40 15 40mg/L17440-70-2
94Magnesium 174 265 39 281mg/L17439-95-4
1040Sodium 994 1390 676 1660mg/L17440-23-5
2Potassium 2 20 2 12mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS
<0.001Arsenic <0.001 <0.001 <0.001 <0.001mg/L0.0017440-38-2
0.09Boron <0.05 <0.05 <0.05 0.05mg/L0.057440-42-8
0.215Barium 0.394 0.071 0.048 0.201mg/L0.0017440-39-3
0.003Beryllium 0.010 <0.001 <0.001 <0.001mg/L0.0017440-41-7
<0.0001Cadmium 0.0001 0.0004 <0.0001 0.0002mg/L0.00017440-43-9
0.047Cobalt 0.136 0.124 0.004 0.109mg/L0.0017440-48-4
0.001Chromium <0.001 <0.001 <0.001 <0.001mg/L0.0017440-47-3
0.008Copper 0.014 <0.001 0.002 0.002mg/L0.0017440-50-8
0.024Manganese 0.056 0.284 0.086 0.169mg/L0.0017439-96-5
0.031Nickel 0.070 0.054 0.004 0.039mg/L0.0017440-02-0
<0.001Lead 0.002 <0.001 <0.001 <0.001mg/L0.0017439-92-1
<0.01Selenium <0.01 <0.01 <0.01 <0.01mg/L0.017782-49-2
<0.01Vanadium <0.01 <0.01 <0.01 <0.01mg/L0.017440-62-2
0.159Zinc 0.190 0.106 0.032 0.054mg/L0.0057440-66-6
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Analytical Results
GW16GW18GW17GW09GW08Client sample IDSub-Matrix: WATER
(Matrix: WATER)
01-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:00Client sampling date / time
EM1702312-005EM1702312-004EM1702312-003EM1702312-002EM1702312-001UnitLORCAS NumberCompound
Result Result Result Result Result
EG020T: Total Metals by ICP-MS
0.008Arsenic 0.005 0.012 0.002 0.044mg/L0.0017440-38-2
<0.05Boron <0.05 <0.05 <0.05 <0.25mg/L0.057440-42-8
0.292Barium 0.448 0.262 0.068 1.31mg/L0.0017440-39-3
0.006Beryllium 0.009 0.003 <0.001 0.021mg/L0.0017440-41-7
<0.0001Cadmium <0.0001 0.0004 <0.0001 0.0009mg/L0.00017440-43-9
0.056Cobalt 0.141 0.181 0.008 0.452mg/L0.0017440-48-4
0.037Chromium 0.032 0.045 0.005 0.156mg/L0.0017440-47-3
0.053Copper 0.072 0.058 0.004 0.215mg/L0.0017440-50-8
0.027Manganese 0.060 0.305 0.091 0.470mg/L0.0017439-96-5
0.041Nickel 0.072 0.105 0.006 0.209mg/L0.0017440-02-0
0.035Lead 0.023 0.047 0.002 0.196mg/L0.0017439-92-1
0.01Selenium <0.01 0.02 <0.01 0.06mg/L0.017782-49-2
0.05Vanadium 0.05 0.11 <0.01 0.54mg/L0.017440-62-2
0.184Zinc 0.213 0.377 0.044 0.799mg/L0.0057440-66-6
EG035F: Dissolved Mercury by FIMS
<0.0001Mercury <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017439-97-6
EG035T: Total Recoverable Mercury by FIMS
0.0030Mercury <0.0001 0.0005 <0.0001 0.0002mg/L0.00017439-97-6
EG050F: Dissolved Hexavalent Chromium
<0.01Hexavalent Chromium <0.01 <0.01 <0.01 <0.01mg/L0.0118540-29-9
EK040P: Fluoride by PC Titrator
0.3Fluoride 0.2 0.2 0.4 0.4mg/L0.116984-48-8
EK055G: Ammonia as N by Discrete Analyser
0.07Ammonia as N 0.03 0.13 0.11 0.36mg/L0.017664-41-7
EK071G: Reactive Phosphorus as P by discrete analyser
0.02Reactive Phosphorus as P <0.01 <0.01 <0.01 0.03mg/L0.0114265-44-2
EN055: Ionic Balance
54.0 61.1 92.5 35.2 110meq/L0.01----Total Anions
55.0 58.9 84.8 33.4 97.6meq/L0.01----Total Cations
0.85 1.83 4.35 2.63 5.90%0.01----Ionic Balance
EP005: Total Organic Carbon (TOC)
18 7 8 16 11mg/L1----Total Organic Carbon
EP074A: Monocyclic Aromatic Hydrocarbons
<5Styrene <5 <5 <5 <5µg/L5100-42-5
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Analytical Results
GW16GW18GW17GW09GW08Client sample IDSub-Matrix: WATER
(Matrix: WATER)
01-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:00Client sampling date / time
EM1702312-005EM1702312-004EM1702312-003EM1702312-002EM1702312-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP074A: Monocyclic Aromatic Hydrocarbons - Continued
<5Isopropylbenzene <5 <5 <5 <5µg/L598-82-8
<5n-Propylbenzene <5 <5 <5 <5µg/L5103-65-1
<51.3.5-Trimethylbenzene <5 <5 <5 <5µg/L5108-67-8
<5sec-Butylbenzene <5 <5 <5 <5µg/L5135-98-8
<51.2.4-Trimethylbenzene <5 <5 <5 <5µg/L595-63-6
<5tert-Butylbenzene <5 <5 <5 <5µg/L598-06-6
<5p-Isopropyltoluene <5 <5 <5 <5µg/L599-87-6
<5n-Butylbenzene <5 <5 <5 <5µg/L5104-51-8
EP074B: Oxygenated Compounds
<50Vinyl Acetate <50 <50 <50 <50µg/L50108-05-4
<502-Butanone (MEK) <50 <50 <50 <50µg/L5078-93-3
<504-Methyl-2-pentanone (MIBK) <50 <50 <50 <50µg/L50108-10-1
<502-Hexanone (MBK) <50 <50 <50 <50µg/L50591-78-6
EP074C: Sulfonated Compounds
<5Carbon disulfide <5 <5 <5 <5µg/L575-15-0
EP074D: Fumigants
<52.2-Dichloropropane <5 <5 <5 <5µg/L5594-20-7
<51.2-Dichloropropane <5 <5 <5 <5µg/L578-87-5
<5cis-1.3-Dichloropropylene <5 <5 <5 <5µg/L510061-01-5
<5trans-1.3-Dichloropropylene <5 <5 <5 <5µg/L510061-02-6
<51.2-Dibromoethane (EDB) <5 <5 <5 <5µg/L5106-93-4
EP074E: Halogenated Aliphatic Compounds
<50Dichlorodifluoromethane <50 <50 <50 <50µg/L5075-71-8
<50Chloromethane <50 <50 <50 <50µg/L5074-87-3
<50Vinyl chloride <50 <50 <50 <50µg/L5075-01-4
<50Bromomethane <50 <50 <50 <50µg/L5074-83-9
<50Chloroethane <50 <50 <50 <50µg/L5075-00-3
<50Trichlorofluoromethane <50 <50 <50 <50µg/L5075-69-4
<51.1-Dichloroethene <5 <5 <5 <5µg/L575-35-4
<5Iodomethane <5 <5 <5 <5µg/L574-88-4
<5Methylene chloride <5 <5 <5 <5µg/L575-09-2
<5trans-1.2-Dichloroethene <5 <5 <5 <5µg/L5156-60-5
<51.1-Dichloroethane <5 <5 <5 <5µg/L575-34-3
<5cis-1.2-Dichloroethene <5 <5 <5 <5µg/L5156-59-2
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Analytical Results
GW16GW18GW17GW09GW08Client sample IDSub-Matrix: WATER
(Matrix: WATER)
01-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:00Client sampling date / time
EM1702312-005EM1702312-004EM1702312-003EM1702312-002EM1702312-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP074E: Halogenated Aliphatic Compounds - Continued
<51.1.1-Trichloroethane <5 <5 <5 <5µg/L571-55-6
<51.1-Dichloropropylene <5 <5 <5 <5µg/L5563-58-6
<5Carbon Tetrachloride <5 <5 <5 <5µg/L556-23-5
<51.2-Dichloroethane <5 <5 <5 <5µg/L5107-06-2
<5Trichloroethene <5 <5 <5 <5µg/L579-01-6
<5Dibromomethane <5 <5 <5 <5µg/L574-95-3
<51.1.2-Trichloroethane <5 <5 <5 <5µg/L579-00-5
<51.3-Dichloropropane <5 <5 <5 <5µg/L5142-28-9
<5Tetrachloroethene <5 <5 <5 <5µg/L5127-18-4
<51.1.1.2-Tetrachloroethane <5 <5 <5 <5µg/L5630-20-6
<5trans-1.4-Dichloro-2-butene <5 <5 <5 <5µg/L5110-57-6
<5cis-1.4-Dichloro-2-butene <5 <5 <5 <5µg/L51476-11-5
<51.1.2.2-Tetrachloroethane <5 <5 <5 <5µg/L579-34-5
<51.2.3-Trichloropropane <5 <5 <5 <5µg/L596-18-4
<5Pentachloroethane <5 <5 <5 <5µg/L576-01-7
<51.2-Dibromo-3-chloropropane <5 <5 <5 <5µg/L596-12-8
<5Hexachlorobutadiene <5 <5 <5 <5µg/L587-68-3
EP074F: Halogenated Aromatic Compounds
<5Chlorobenzene <5 <5 <5 <5µg/L5108-90-7
<5Bromobenzene <5 <5 <5 <5µg/L5108-86-1
<52-Chlorotoluene <5 <5 <5 <5µg/L595-49-8
<54-Chlorotoluene <5 <5 <5 <5µg/L5106-43-4
<51.3-Dichlorobenzene <5 <5 <5 <5µg/L5541-73-1
<51.4-Dichlorobenzene <5 <5 <5 <5µg/L5106-46-7
<51.2-Dichlorobenzene <5 <5 <5 <5µg/L595-50-1
<51.2.4-Trichlorobenzene <5 <5 <5 <5µg/L5120-82-1
<51.2.3-Trichlorobenzene <5 <5 <5 <5µg/L587-61-6
EP074G: Trihalomethanes
<5Chloroform 9 9 <5 10µg/L567-66-3
<5Bromodichloromethane <5 <5 <5 <5µg/L575-27-4
<5Dibromochloromethane <5 <5 <5 <5µg/L5124-48-1
<5Bromoform <5 <5 <5 <5µg/L575-25-2
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
<1.0Naphthalene <1.0 <1.0 <1.0 <1.0µg/L191-20-3
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GW16GW18GW17GW09GW08Client sample IDSub-Matrix: WATER
(Matrix: WATER)
01-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:00Client sampling date / time
EM1702312-005EM1702312-004EM1702312-003EM1702312-002EM1702312-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued
<1.0Acenaphthylene <1.0 <1.0 <1.0 <1.0µg/L1208-96-8
<1.0Acenaphthene <1.0 <1.0 <1.0 <1.0µg/L183-32-9
<1.0Fluorene <1.0 <1.0 <1.0 <1.0µg/L186-73-7
<1.0Phenanthrene <1.0 <1.0 <1.0 <1.0µg/L185-01-8
<1.0Anthracene <1.0 <1.0 <1.0 <1.0µg/L1120-12-7
<1.0Fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1206-44-0
<1.0Pyrene <1.0 <1.0 <1.0 <1.0µg/L1129-00-0
<1.0Benz(a)anthracene <1.0 <1.0 <1.0 <1.0µg/L156-55-3
<1.0Chrysene <1.0 <1.0 <1.0 <1.0µg/L1218-01-9
<1.0Benzo(b+j)fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1205-99-2 205-82-3
<1.0Benzo(k)fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1207-08-9
<0.5Benzo(a)pyrene <0.5 <0.5 <0.5 <0.5µg/L0.550-32-8
<1.0Indeno(1.2.3.cd)pyrene <1.0 <1.0 <1.0 <1.0µg/L1193-39-5
<1.0Dibenz(a.h)anthracene <1.0 <1.0 <1.0 <1.0µg/L153-70-3
<1.0Benzo(g.h.i)perylene <1.0 <1.0 <1.0 <1.0µg/L1191-24-2
<0.5^ <0.5 <0.5 <0.5 <0.5µg/L0.5----Sum of polycyclic aromatic hydrocarbons
<0.5^ <0.5 <0.5 <0.5 <0.5µg/L0.5----Benzo(a)pyrene TEQ (zero)
EP080/071: Total Petroleum Hydrocarbons
20 <20 <20 <20 <20µg/L20----C6 - C9 Fraction
<50 <50 <50 <50 <50µg/L50----C10 - C14 Fraction
<100 <100 <100 <100 130µg/L100----C15 - C28 Fraction
<50 <50 <50 <50 <50µg/L50----C29 - C36 Fraction
<50^ <50 <50 <50 130µg/L50----C10 - C36 Fraction (sum)
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
<20C6 - C10 Fraction <20 <20 <20 <20µg/L20C6_C10
<20^ C6 - C10 Fraction minus BTEX
(F1)
<20 <20 <20 <20µg/L20C6_C10-BTEX
<100 <100 <100 <100 <100µg/L100---->C10 - C16 Fraction
<100 <100 <100 <100 150µg/L100---->C16 - C34 Fraction
<100 <100 <100 <100 <100µg/L100---->C34 - C40 Fraction
<100^ <100 <100 <100 150µg/L100---->C10 - C40 Fraction (sum)
<100^ <100 <100 <100 <100µg/L100---->C10 - C16 Fraction minus Naphthalene
(F2)
EP080: BTEXN
<1Benzene <1 <1 <1 <1µg/L171-43-2
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Analytical Results
GW16GW18GW17GW09GW08Client sample IDSub-Matrix: WATER
(Matrix: WATER)
01-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:00Client sampling date / time
EM1702312-005EM1702312-004EM1702312-003EM1702312-002EM1702312-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP080: BTEXN - Continued
<2Toluene <2 <2 <2 <2µg/L2108-88-3
<2Ethylbenzene <2 <2 <2 <2µg/L2100-41-4
<2meta- & para-Xylene <2 <2 <2 <2µg/L2108-38-3 106-42-3
<2ortho-Xylene <2 <2 <2 <2µg/L295-47-6
<2^ Total Xylenes <2 <2 <2 <2µg/L21330-20-7
<1^ <1 <1 <1 <1µg/L1----Sum of BTEX
<5Naphthalene <5 <5 <5 <5µg/L591-20-3
EP231A: Perfluoroalkyl Sulfonic Acids
<0.02Perfluorobutane sulfonic acid
(PFBS)
<0.02 <0.05 <0.05 <0.05µg/L0.02375-73-5
<0.02Perfluoropentane sulfonic acid
(PFPeS)
<0.02 <0.05 <0.05 <0.05µg/L0.022706-91-4
<0.02Perfluorohexane sulfonic acid
(PFHxS)
<0.02 <0.05 <0.05 <0.05µg/L0.02355-46-4
<0.02Perfluoroheptane sulfonic acid
(PFHpS)
<0.02 <0.05 <0.05 <0.05µg/L0.02375-92-8
<0.01Perfluorooctane sulfonic acid
(PFOS)
<0.01 <0.05 <0.05 <0.05µg/L0.011763-23-1
<0.02Perfluorodecane sulfonic acid
(PFDS)
<0.02 <0.05 <0.05 <0.05µg/L0.02335-77-3
EP231B: Perfluoroalkyl Carboxylic Acids
<0.1Perfluorobutanoic acid (PFBA) <0.1 <0.2 <0.2 <0.2µg/L0.1375-22-4
<0.02Perfluoropentanoic acid (PFPeA) <0.02 <0.05 <0.05 <0.05µg/L0.022706-90-3
<0.02Perfluorohexanoic acid (PFHxA) <0.02 <0.05 <0.05 <0.05µg/L0.02307-24-4
<0.02Perfluoroheptanoic acid (PFHpA) <0.02 <0.05 <0.05 <0.05µg/L0.02375-85-9
<0.01Perfluorooctanoic acid (PFOA) <0.01 <0.05 <0.05 <0.05µg/L0.01335-67-1
<0.02Perfluorononanoic acid (PFNA) <0.02 <0.05 <0.05 <0.05µg/L0.02375-95-1
<0.02Perfluorodecanoic acid (PFDA) <0.02 <0.05 <0.05 <0.05µg/L0.02335-76-2
<0.02Perfluoroundecanoic acid
(PFUnDA)
<0.02 <0.05 <0.05 <0.05µg/L0.022058-94-8
<0.02Perfluorododecanoic acid
(PFDoDA)
<0.02 <0.05 <0.05 <0.05µg/L0.02307-55-1
<0.02Perfluorotridecanoic acid
(PFTrDA)
<0.02 <0.05 <0.05 <0.05µg/L0.0272629-94-8
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Analytical Results
GW16GW18GW17GW09GW08Client sample IDSub-Matrix: WATER
(Matrix: WATER)
01-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:00Client sampling date / time
EM1702312-005EM1702312-004EM1702312-003EM1702312-002EM1702312-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP231B: Perfluoroalkyl Carboxylic Acids - Continued
<0.05Perfluorotetradecanoic acid
(PFTeDA)
<0.05 <0.12 <0.12 <0.12µg/L0.05376-06-7
EP231C: Perfluoroalkyl Sulfonamides
<0.02Perfluorooctane sulfonamide
(FOSA)
<0.02 <0.05 <0.05 <0.05µg/L0.02754-91-6
<0.05N-Methyl perfluorooctane
sulfonamide (MeFOSA)
<0.05 <0.12 <0.12 <0.12µg/L0.0531506-32-8
<0.05N-Ethyl perfluorooctane
sulfonamide (EtFOSA)
<0.05 <0.12 <0.12 <0.12µg/L0.054151-50-2
<0.05N-Methyl perfluorooctane
sulfonamidoethanol (MeFOSE)
<0.05 <0.12 <0.12 <0.12µg/L0.052448-09-7
<0.05N-Ethyl perfluorooctane
sulfonamidoethanol (EtFOSE)
<0.05 <0.12 <0.12 <0.12µg/L0.051691-99-2
<0.02N-Methyl perfluorooctane
sulfonamidoacetic acid
(MeFOSAA)
<0.02 <0.05 <0.05 <0.05µg/L0.022355-31-9
<0.02N-Ethyl perfluorooctane
sulfonamidoacetic acid
(EtFOSAA)
<0.02 <0.05 <0.05 <0.05µg/L0.022991-50-6
EP231D: (n:2) Fluorotelomer Sulfonic Acids
<0.054:2 Fluorotelomer sulfonic acid
(4:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.05757124-72-4
<0.056:2 Fluorotelomer sulfonic acid
(6:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.0527619-97-2
<0.058:2 Fluorotelomer sulfonic acid
(8:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.0539108-34-4
<0.0510:2 Fluorotelomer sulfonic acid
(10:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.05120226-60-0
EP231P: PFAS Sums
<0.01 <0.01 <0.05 <0.05 <0.05µg/L0.01----Sum of PFAS
<0.01Sum of PFHxS and PFOS <0.01 <0.05 <0.05 <0.05µg/L0.01355-46-4/1763-23-
1
<0.01 <0.01 <0.05 <0.05 <0.05µg/L0.01----Sum of PFAS (WA DER List)
EP074S: VOC Surrogates
1021.2-Dichloroethane-D4 102 101 97.5 95.5%517060-07-0
96.2Toluene-D8 93.4 96.3 89.0 95.5%52037-26-5
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Analytical Results
GW16GW18GW17GW09GW08Client sample IDSub-Matrix: WATER
(Matrix: WATER)
01-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:0001-Mar-2017 00:00Client sampling date / time
EM1702312-005EM1702312-004EM1702312-003EM1702312-002EM1702312-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP074S: VOC Surrogates - Continued
1014-Bromofluorobenzene 101 99.0 94.7 99.3%5460-00-4
EP075(SIM)S: Phenolic Compound Surrogates
31.3Phenol-d6 29.8 27.6 26.9 30.1%113127-88-3
74.12-Chlorophenol-D4 68.3 67.0 66.7 73.5%193951-73-6
67.12.4.6-Tribromophenol 58.6 59.5 73.2 62.1%1118-79-6
EP075(SIM)T: PAH Surrogates
86.92-Fluorobiphenyl 63.9 57.9 78.5 59.0%1321-60-8
96.8Anthracene-d10 88.5 99.7 98.0 63.1%11719-06-8
76.74-Terphenyl-d14 73.4 66.4 76.4 79.0%11718-51-0
EP080S: TPH(V)/BTEX Surrogates
1011.2-Dichloroethane-D4 103 102 98.7 95.8%217060-07-0
94.4Toluene-D8 93.1 94.5 87.2 93.3%22037-26-5
97.24-Bromofluorobenzene 99.0 96.5 92.1 96.4%2460-00-4
EP231S: PFAS Surrogate
89.1 83.6 89.8 87.8 89.3%0.02----13C4-PFOS
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Analytical Results
--------RB_003RB_002TB_003Client sample IDSub-Matrix: WATER
(Matrix: WATER)
--------01-Mar-2017 00:0028-Feb-2017 00:0001-Mar-2017 00:00Client sampling date / time
----------------EM1702312-008EM1702312-007EM1702312-006UnitLORCAS NumberCompound
Result Result Result ---- ----
EG020T: Total Metals by ICP-MS
----Arsenic <0.001 <0.001 ---- ----mg/L0.0017440-38-2
----Cadmium <0.0001 <0.0001 ---- ----mg/L0.00017440-43-9
----Chromium <0.001 <0.001 ---- ----mg/L0.0017440-47-3
----Copper <0.001 <0.001 ---- ----mg/L0.0017440-50-8
----Nickel <0.001 <0.001 ---- ----mg/L0.0017440-02-0
----Lead <0.001 <0.001 ---- ----mg/L0.0017439-92-1
----Zinc <0.005 <0.005 ---- ----mg/L0.0057440-66-6
EG035T: Total Recoverable Mercury by FIMS
----Mercury <0.0001 <0.0001 ---- ----mg/L0.00017439-97-6
EP080/071: Total Petroleum Hydrocarbons
<20 ---- ---- ---- ----µg/L20----C6 - C9 Fraction
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
<20C6 - C10 Fraction ---- ---- ---- ----µg/L20C6_C10
<20^ C6 - C10 Fraction minus BTEX
(F1)
---- ---- ---- ----µg/L20C6_C10-BTEX
EP080: BTEXN
<1Benzene ---- ---- ---- ----µg/L171-43-2
<2Toluene ---- ---- ---- ----µg/L2108-88-3
<2Ethylbenzene ---- ---- ---- ----µg/L2100-41-4
<2meta- & para-Xylene ---- ---- ---- ----µg/L2108-38-3 106-42-3
<2ortho-Xylene ---- ---- ---- ----µg/L295-47-6
<2^ Total Xylenes ---- ---- ---- ----µg/L21330-20-7
<1^ ---- ---- ---- ----µg/L1----Sum of BTEX
<5Naphthalene ---- ---- ---- ----µg/L591-20-3
EP080S: TPH(V)/BTEX Surrogates
96.21.2-Dichloroethane-D4 ---- ---- ---- ----%217060-07-0
89.5Toluene-D8 ---- ---- ---- ----%22037-26-5
95.54-Bromofluorobenzene ---- ---- ---- ----%2460-00-4
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Surrogate Control Limits
Recovery Limits (%)Sub-Matrix: WATER
Compound CAS Number Low High
EP074S: VOC Surrogates
1.2-Dichloroethane-D4 17060-07-0 72 132
Toluene-D8 2037-26-5 77 132
4-Bromofluorobenzene 460-00-4 67 131
EP075(SIM)S: Phenolic Compound Surrogates
Phenol-d6 13127-88-3 10 46
2-Chlorophenol-D4 93951-73-6 23 104
2.4.6-Tribromophenol 118-79-6 28 130
EP075(SIM)T: PAH Surrogates
2-Fluorobiphenyl 321-60-8 36 114
Anthracene-d10 1719-06-8 51 119
4-Terphenyl-d14 1718-51-0 49 127
EP080S: TPH(V)/BTEX Surrogates
1.2-Dichloroethane-D4 17060-07-0 73 129
Toluene-D8 2037-26-5 70 125
4-Bromofluorobenzene 460-00-4 71 129
EP231S: PFAS Surrogate
13C4-PFOS ---- 60 130
False
5 5.00True
Environmental
QUALITY CONTROL REPORTWork Order : EM1702312 Page : 1 of 20
:: LaboratoryClient Environmental Division MelbourneJACOBS GROUP (AUSTRALIA) PTY LTD
:Contact MR BENJAMIN GRASSO :Contact Carol Walsh
:Address P O BOX 312 FLINDERS LANE
MELBOURNE VIC AUSTRALIA 8009
Address : 4 Westall Rd Springvale VIC Australia 3171
::Telephone +61 03 8668 3000 +61-3-8549 9608:Telephone
:Project IS157700 Date Samples Received : 02-Mar-2017
:Order number ---- Date Analysis Commenced : 02-Mar-2017
:C-O-C number ---- Issue Date : 09-Mar-2017
Sampler : BENJAMIN GRASSO
Site : ----
Quote number : ME/088/17
No. of samples received 8:
No. of samples analysed 8:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limits
l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits
l Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Dilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VIC
Lana Nguyen Senior LCMS Chemist Sydney Organics, Smithfield, NSW
Nancy Wang Senior Semivolatile Instrument Chemist Melbourne Organics, Springvale, VIC
Nikki Stepniewski Senior Inorganic Instrument Chemist Melbourne Inorganics, Springvale, VIC
Xing Lin Senior Organic Chemist Melbourne Organics, Springvale, VIC
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
RPD = Relative Percentage Difference
# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) Report
The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges
for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:
No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EA005P: pH by PC Titrator (QC Lot: 777106)
EA005-P: pH Value ---- 0.01 pH Unit 8.24 8.33 1.09 0% - 20%Anonymous EM1702306-003
EA005-P: pH Value ---- 0.01 pH Unit 4.61 4.43 3.98 0% - 20%GW09 EM1702312-002
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QC Lot: 778709)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 44 43 2.32 No LimitAnonymous EM1702281-001
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 5790 5680 1.80 0% - 20%Anonymous EM1702282-001
EA025: Total Suspended Solids dried at 104 ± 2°C (QC Lot: 778710)
EA025H: Suspended Solids (SS) ---- 5 mg/L 1720 1790 4.11 0% - 20%Anonymous EM1702306-001
EA025H: Suspended Solids (SS) ---- 5 mg/L 2190 2130 3.14 0% - 20%GW09 EM1702312-002
ED037P: Alkalinity by PC Titrator (QC Lot: 777107)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EM1702306-003
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 1230 1230 0.514 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 1230 1230 0.514 0% - 20%
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitGW09 EM1702312-002
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L <1 <1 0.00 No Limit
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L <1 <1 0.00 No Limit
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QC Lot: 777203)
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 12900 12700 1.40 0% - 20%Anonymous EM1702295-004
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 524 529 0.892 0% - 20%GW18 EM1702312-004
ED045G: Chloride by Discrete Analyser (QC Lot: 777204)
ED045G: Chloride 16887-00-6 1 mg/L 3950 3920 0.681 0% - 20%Anonymous EM1702295-004
ED045G: Chloride 16887-00-6 1 mg/L 652 657 0.838 0% - 20%GW18 EM1702312-004
ED093F: Dissolved Major Cations (QC Lot: 777822)
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
ED093F: Dissolved Major Cations (QC Lot: 777822) - continued
ED093F: Calcium 7440-70-2 1 mg/L 19 22 11.2 0% - 20%Anonymous EM1702296-001
ED093F: Magnesium 7439-95-4 1 mg/L 102 107 4.72 0% - 20%
ED093F: Sodium 7440-23-5 1 mg/L 1020 1030 0.687 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 31 31 0.00 0% - 20%
ED093F: Calcium 7440-70-2 1 mg/L 40 41 0.00 0% - 20%GW16 EM1702312-005
ED093F: Magnesium 7439-95-4 1 mg/L 281 284 1.07 0% - 20%
ED093F: Sodium 7440-23-5 1 mg/L 1660 1690 2.06 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 12 12 0.00 0% - 50%
EG020F: Dissolved Metals by ICP-MS (QC Lot: 777820)
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitGW18 EM1702312-004
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Beryllium 7440-41-7 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Barium 7440-39-3 0.001 mg/L 0.048 0.048 0.00 0% - 20%
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Cobalt 7440-48-4 0.001 mg/L 0.004 0.003 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.086 0.083 3.59 0% - 20%
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.004 0.003 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.032 0.029 9.02 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Vanadium 7440-62-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Boron 7440-42-8 0.05 mg/L <0.05 <0.05 0.00 No Limit
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702196-001
EG020A-F: Arsenic 7440-38-2 0.001 mg/L 0.003 0.003 0.00 No Limit
EG020A-F: Beryllium 7440-41-7 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Barium 7440-39-3 0.001 mg/L 0.028 0.027 0.00 0% - 20%
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Cobalt 7440-48-4 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 <0.005 0.00 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Vanadium 7440-62-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Boron 7440-42-8 0.05 mg/L 0.27 0.27 0.00 No Limit
EG020T: Total Metals by ICP-MS (QC Lot: 778607)
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702205-001
EG020A-T: Arsenic 7440-38-2 0.001 mg/L 0.002 0.001 0.00 No Limit
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EG020T: Total Metals by ICP-MS (QC Lot: 778607) - continued
EG020A-T: Beryllium 7440-41-7 0.001 mg/L <0.001 <0.001 0.00 No LimitAnonymous EM1702205-001
EG020A-T: Barium 7440-39-3 0.001 mg/L 0.108 0.099 8.25 0% - 20%
EG020A-T: Chromium 7440-47-3 0.001 mg/L 0.002 0.001 0.00 No Limit
EG020A-T: Cobalt 7440-48-4 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Copper 7440-50-8 0.001 mg/L 0.017 0.017 0.00 0% - 50%
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Manganese 7439-96-5 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-T: Nickel 7440-02-0 0.001 mg/L 0.017 0.017 0.00 0% - 50%
EG020A-T: Zinc 7440-66-6 0.005 mg/L 0.043 0.043 0.00 No Limit
EG020A-T: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-T: Vanadium 7440-62-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-T: Boron 7440-42-8 0.05 mg/L <0.05 <0.05 0.00 No Limit
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702285-005
EG020A-T: Arsenic 7440-38-2 0.001 mg/L 0.002 0.002 0.00 No Limit
EG020A-T: Beryllium 7440-41-7 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Barium 7440-39-3 0.001 mg/L 0.107 0.106 1.34 0% - 20%
EG020A-T: Chromium 7440-47-3 0.001 mg/L 0.001 0.001 0.00 No Limit
EG020A-T: Cobalt 7440-48-4 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Copper 7440-50-8 0.001 mg/L 0.001 0.001 0.00 No Limit
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Manganese 7439-96-5 0.001 mg/L 0.036 0.035 0.00 0% - 20%
EG020A-T: Nickel 7440-02-0 0.001 mg/L 0.003 0.003 0.00 No Limit
EG020A-T: Zinc 7440-66-6 0.005 mg/L 0.009 0.009 0.00 No Limit
EG020A-T: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-T: Vanadium 7440-62-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-T: Boron 7440-42-8 0.05 mg/L 0.08 0.08 0.00 No Limit
EG020T: Total Metals by ICP-MS (QC Lot: 778608)
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L 0.0009 0.0013 28.7 No LimitGW16 EM1702312-005
EG020A-T: Arsenic 7440-38-2 0.001 mg/L 0.044 0.040 9.59 No Limit
EG020A-T: Beryllium 7440-41-7 0.001 mg/L 0.021 0.018 12.7 No Limit
EG020A-T: Barium 7440-39-3 0.001 mg/L 1.31 1.21 8.33 0% - 20%
EG020A-T: Chromium 7440-47-3 0.001 mg/L 0.156 0.130 18.0 0% - 20%
EG020A-T: Cobalt 7440-48-4 0.001 mg/L 0.452 0.416 8.27 0% - 20%
EG020A-T: Copper 7440-50-8 0.001 mg/L 0.215 0.199 7.68 0% - 20%
EG020A-T: Lead 7439-92-1 0.001 mg/L 0.196 0.175 11.2 0% - 20%
EG020A-T: Manganese 7439-96-5 0.001 mg/L 0.470 0.436 7.42 0% - 20%
EG020A-T: Nickel 7440-02-0 0.001 mg/L 0.209 0.188 10.5 0% - 20%
EG020A-T: Zinc 7440-66-6 0.005 mg/L 0.799 0.686 15.2 0% - 20%
EG020A-T: Selenium 7782-49-2 0.01 mg/L 0.06 0.06 0.00 No Limit
EG020A-T: Vanadium 7440-62-2 0.01 mg/L 0.54 0.52 4.85 0% - 50%
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:Client
EM1702312
JACOBS GROUP (AUSTRALIA) PTY LTD
IS157700:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EG020T: Total Metals by ICP-MS (QC Lot: 778608) - continued
EG020A-T: Boron 7440-42-8 0.05 mg/L <0.25 <0.25 0.00 No LimitGW16 EM1702312-005
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L 0.0002 0.0003 57.0 No LimitAnonymous EM1702315-001
EG020A-T: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Beryllium 7440-41-7 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Barium 7440-39-3 0.001 mg/L 0.006 0.007 19.9 No Limit
EG020A-T: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Cobalt 7440-48-4 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Copper 7440-50-8 0.001 mg/L 0.011 0.012 0.00 0% - 50%
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Manganese 7439-96-5 0.001 mg/L 0.023 0.022 7.14 0% - 20%
EG020A-T: Nickel 7440-02-0 0.001 mg/L 0.007 0.007 0.00 No Limit
EG020A-T: Zinc 7440-66-6 0.005 mg/L 0.081 0.078 4.35 0% - 50%
EG020A-T: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-T: Vanadium 7440-62-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-T: Boron 7440-42-8 0.05 mg/L 0.44 0.46 3.24 No Limit
EG035F: Dissolved Mercury by FIMS (QC Lot: 777821)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702329-001
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702196-001
EG035T: Total Recoverable Mercury by FIMS (QC Lot: 776483)
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702289-020
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitGW09 EM1702312-002
EG050F: Dissolved Hexavalent Chromium (QC Lot: 775560)
EG050F: Hexavalent Chromium 18540-29-9 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EM1702240-001
EG050F: Hexavalent Chromium 18540-29-9 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EM1702240-010
EK040P: Fluoride by PC Titrator (QC Lot: 777102)
EK040P: Fluoride 16984-48-8 0.1 mg/L 1.1 1.1 0.00 0% - 50%Anonymous EM1702220-001
EK040P: Fluoride 16984-48-8 0.1 mg/L 0.2 0.3 0.00 No LimitGW09 EM1702312-002
EK055G: Ammonia as N by Discrete Analyser (QC Lot: 776619)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 250 283 12.0 0% - 20%Anonymous EM1702310-001
EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EM1702313-015
EK071G: Reactive Phosphorus as P by discrete analyser (QC Lot: 777205)
EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L <0.01 <0.01 0.00 No LimitGW18 EM1702312-004
EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EM1702335-003
EP005: Total Organic Carbon (TOC) (QC Lot: 779014)
EP005: Total Organic Carbon ---- 1 mg/L 3 3 0.00 No LimitAnonymous EM1702205-001
EP005: Total Organic Carbon ---- 1 mg/L 11 11 0.00 0% - 50%GW16 EM1702312-005
EP074A: Monocyclic Aromatic Hydrocarbons (QC Lot: 776481)
EP074: Styrene 100-42-5 5 µg/L <5 <5 0.00 No LimitGW08 EM1702312-001
EP074: Isopropylbenzene 98-82-8 5 µg/L <5 <5 0.00 No Limit
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:Client
EM1702312
JACOBS GROUP (AUSTRALIA) PTY LTD
IS157700:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP074A: Monocyclic Aromatic Hydrocarbons (QC Lot: 776481) - continued
EP074: n-Propylbenzene 103-65-1 5 µg/L <5 <5 0.00 No LimitGW08 EM1702312-001
EP074: 1.3.5-Trimethylbenzene 108-67-8 5 µg/L <5 <5 0.00 No Limit
EP074: sec-Butylbenzene 135-98-8 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trimethylbenzene 95-63-6 5 µg/L <5 <5 0.00 No Limit
EP074: tert-Butylbenzene 98-06-6 5 µg/L <5 <5 0.00 No Limit
EP074: p-Isopropyltoluene 99-87-6 5 µg/L <5 <5 0.00 No Limit
EP074: n-Butylbenzene 104-51-8 5 µg/L <5 <5 0.00 No Limit
EP074B: Oxygenated Compounds (QC Lot: 776481)
EP074: Vinyl Acetate 108-05-4 50 µg/L <50 <50 0.00 No LimitGW08 EM1702312-001
EP074: 2-Butanone (MEK) 78-93-3 50 µg/L <50 <50 0.00 No Limit
EP074: 4-Methyl-2-pentanone (MIBK) 108-10-1 50 µg/L <50 <50 0.00 No Limit
EP074: 2-Hexanone (MBK) 591-78-6 50 µg/L <50 <50 0.00 No Limit
EP074C: Sulfonated Compounds (QC Lot: 776481)
EP074: Carbon disulfide 75-15-0 5 µg/L <5 <5 0.00 No LimitGW08 EM1702312-001
EP074D: Fumigants (QC Lot: 776481)
EP074: 2.2-Dichloropropane 594-20-7 5 µg/L <5 <5 0.00 No LimitGW08 EM1702312-001
EP074: 1.2-Dichloropropane 78-87-5 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.3-Dichloropropylene 10061-01-5 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.3-Dichloropropylene 10061-02-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromoethane (EDB) 106-93-4 5 µg/L <5 <5 0.00 No Limit
EP074E: Halogenated Aliphatic Compounds (QC Lot: 776481)
EP074: 1.1-Dichloroethene 75-35-4 5 µg/L <5 <5 0.00 No LimitGW08 EM1702312-001
EP074: Iodomethane 74-88-4 5 µg/L <5 <5 0.00 No Limit
EP074: Methylene chloride 75-09-2 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.2-Dichloroethene 156-60-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloroethane 75-34-3 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.2-Dichloroethene 156-59-2 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1-Trichloroethane 71-55-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloropropylene 563-58-6 5 µg/L <5 <5 0.00 No Limit
EP074: Carbon Tetrachloride 56-23-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichloroethane 107-06-2 5 µg/L <5 <5 0.00 No Limit
EP074: Trichloroethene 79-01-6 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromomethane 74-95-3 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2-Trichloroethane 79-00-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichloropropane 142-28-9 5 µg/L <5 <5 0.00 No Limit
EP074: Tetrachloroethene 127-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1.2-Tetrachloroethane 630-20-6 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.4-Dichloro-2-butene 110-57-6 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.4-Dichloro-2-butene 1476-11-5 5 µg/L <5 <5 0.00 No Limit
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EM1702312
JACOBS GROUP (AUSTRALIA) PTY LTD
IS157700:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP074E: Halogenated Aliphatic Compounds (QC Lot: 776481) - continued
EP074: 1.1.2.2-Tetrachloroethane 79-34-5 5 µg/L <5 <5 0.00 No LimitGW08 EM1702312-001
EP074: 1.2.3-Trichloropropane 96-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: Pentachloroethane 76-01-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromo-3-chloropropane 96-12-8 5 µg/L <5 <5 0.00 No Limit
EP074: Hexachlorobutadiene 87-68-3 5 µg/L <5 <5 0.00 No Limit
EP074: Dichlorodifluoromethane 75-71-8 50 µg/L <50 <50 0.00 No Limit
EP074: Chloromethane 74-87-3 50 µg/L <50 <50 0.00 No Limit
EP074: Vinyl chloride 75-01-4 50 µg/L <50 <50 0.00 No Limit
EP074: Bromomethane 74-83-9 50 µg/L <50 <50 0.00 No Limit
EP074: Chloroethane 75-00-3 50 µg/L <50 <50 0.00 No Limit
EP074: Trichlorofluoromethane 75-69-4 50 µg/L <50 <50 0.00 No Limit
EP074F: Halogenated Aromatic Compounds (QC Lot: 776481)
EP074: Chlorobenzene 108-90-7 5 µg/L <5 <5 0.00 No LimitGW08 EM1702312-001
EP074: Bromobenzene 108-86-1 5 µg/L <5 <5 0.00 No Limit
EP074: 2-Chlorotoluene 95-49-8 5 µg/L <5 <5 0.00 No Limit
EP074: 4-Chlorotoluene 106-43-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichlorobenzene 541-73-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.4-Dichlorobenzene 106-46-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichlorobenzene 95-50-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trichlorobenzene 120-82-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichlorobenzene 87-61-6 5 µg/L <5 <5 0.00 No Limit
EP074G: Trihalomethanes (QC Lot: 776481)
EP074: Chloroform 67-66-3 5 µg/L <5 <5 0.00 No LimitGW08 EM1702312-001
EP074: Bromodichloromethane 75-27-4 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromochloromethane 124-48-1 5 µg/L <5 <5 0.00 No Limit
EP074: Bromoform 75-25-2 5 µg/L <5 <5 0.00 No Limit
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QC Lot: 776810)
EP075(SIM): Benzo(a)pyrene 50-32-8 0.5 µg/L <0.5 <0.5 0.00 No LimitGW16 EM1702312-005
EP075(SIM): Naphthalene 91-20-3 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Acenaphthylene 208-96-8 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Acenaphthene 83-32-9 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Fluorene 86-73-7 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Phenanthrene 85-01-8 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Anthracene 120-12-7 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Fluoranthene 206-44-0 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Pyrene 129-00-0 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Benz(a)anthracene 56-55-3 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Chrysene 218-01-9 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Benzo(b+j)fluoranthene 205-99-2
205-82-3
1 µg/L <1.0 <1.0 0.00 No Limit
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JACOBS GROUP (AUSTRALIA) PTY LTD
IS157700:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QC Lot: 776810) - continued
EP075(SIM): Benzo(k)fluoranthene 207-08-9 1 µg/L <1.0 <1.0 0.00 No LimitGW16 EM1702312-005
EP075(SIM): Indeno(1.2.3.cd)pyrene 193-39-5 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Dibenz(a.h)anthracene 53-70-3 1 µg/L <1.0 <1.0 0.00 No Limit
EP075(SIM): Benzo(g.h.i)perylene 191-24-2 1 µg/L <1.0 <1.0 0.00 No Limit
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 776480)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitAnonymous EM1702352-002
EP080: C6 - C9 Fraction ---- 20 µg/L 20 <20 0.00 No LimitGW08 EM1702312-001
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 776811)
EP071: C15 - C28 Fraction ---- 100 µg/L 130 <100 27.0 No LimitGW16 EM1702312-005
EP071: C10 - C14 Fraction ---- 50 µg/L <50 <50 0.00 No Limit
EP071: C29 - C36 Fraction ---- 50 µg/L <50 <50 0.00 No Limit
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 776480)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitAnonymous EM1702352-002
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitGW08 EM1702312-001
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 776811)
EP071: >C10 - C16 Fraction ---- 100 µg/L <100 <100 0.00 No LimitGW16 EM1702312-005
EP071: >C16 - C34 Fraction ---- 100 µg/L 150 110 31.0 No Limit
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 <100 0.00 No Limit
EP080: BTEXN (QC Lot: 776480)
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitAnonymous EM1702352-002
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitGW08 EM1702312-001
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
EP231A: Perfluoroalkyl Sulfonic Acids (QC Lot: 777260)
EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 158 170 7.32 0% - 20%Anonymous EM1702285-001
EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L 2.53 2.49 1.63 0% - 20%
EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L 1.89 1.96 3.59 0% - 20%
EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L 22.6 21.3 5.71 0% - 20%
EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L 2.21 2.26 1.88 0% - 20%
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EM1702312
JACOBS GROUP (AUSTRALIA) PTY LTD
IS157700:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP231A: Perfluoroalkyl Sulfonic Acids (QC Lot: 777260) - continued
EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L 0.52 0.57 10.8 0% - 20%Anonymous EM1702285-001
EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 0.26 0.26 0.00 0% - 20%Anonymous EM1702285-011
EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L 0.05 0.04 0.00 No Limit
EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L 0.04 0.04 0.00 No Limit
EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L 0.34 0.34 0.00 0% - 50%
EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231B: Perfluoroalkyl Carboxylic Acids (QC Lot: 777260)
EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L 5.43 5.33 1.84 0% - 20%Anonymous EM1702285-001
EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L 11.9 11.5 3.39 0% - 20%
EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L 25.9 24.7 4.74 0% - 20%
EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L 2.99 2.90 3.16 0% - 20%
EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L 0.18 0.18 0.00 No Limit
EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L 0.24 0.25 6.18 0% - 50%
EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L 0.04 0.05 0.00 No Limit
EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L 0.04 0.04 0.00 No Limit
EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L 2.8 2.8 0.00 0% - 20%
EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L 0.02 0.02 0.00 No LimitAnonymous EM1702285-011
EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L 0.19 0.19 0.00 No Limit
EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L 0.15 0.15 0.00 No Limit
EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L 0.08 0.08 0.00 No Limit
EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L 0.1 0.1 0.00 No Limit
EP231C: Perfluoroalkyl Sulfonamides (QC Lot: 777260)
EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L 0.36 0.40 11.5 0% - 20%Anonymous EM1702285-001
EP231X: N-Methyl perfluorooctane
sulfonamidoacetic acid (MeFOSAA)
2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: N-Ethyl perfluorooctane
sulfonamidoacetic acid (EtFOSAA)
2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: N-Methyl perfluorooctane sulfonamide
(MeFOSA)
31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Ethyl perfluorooctane sulfonamide
(EtFOSA)
4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit
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EM1702312
JACOBS GROUP (AUSTRALIA) PTY LTD
IS157700:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP231C: Perfluoroalkyl Sulfonamides (QC Lot: 777260) - continued
EP231X: N-Methyl perfluorooctane
sulfonamidoethanol (MeFOSE)
2448-09-7 0.05 µg/L <0.05 <0.05 0.00 No LimitAnonymous EM1702285-001
EP231X: N-Ethyl perfluorooctane
sulfonamidoethanol (EtFOSE)
1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 <0.02 0.00 No LimitAnonymous EM1702285-011
EP231X: N-Methyl perfluorooctane
sulfonamidoacetic acid (MeFOSAA)
2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: N-Ethyl perfluorooctane
sulfonamidoacetic acid (EtFOSAA)
2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: N-Methyl perfluorooctane sulfonamide
(MeFOSA)
31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Ethyl perfluorooctane sulfonamide
(EtFOSA)
4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Methyl perfluorooctane
sulfonamidoethanol (MeFOSE)
2448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Ethyl perfluorooctane
sulfonamidoethanol (EtFOSE)
1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QC Lot: 777260)
EP231X: 4:2 Fluorotelomer sulfonic acid (4:2
FTS)
757124-72-4 0.05 µg/L 0.07 0.07 0.00 No LimitAnonymous EM1702285-001
EP231X: 6:2 Fluorotelomer sulfonic acid (6:2
FTS)
27619-97-2 0.05 µg/L 115 130 12.2 0% - 20%
EP231X: 8:2 Fluorotelomer sulfonic acid (8:2
FTS)
39108-34-4 0.05 µg/L 41.0 39.0 5.00 0% - 20%
EP231X: 10:2 Fluorotelomer sulfonic acid (10:2
FTS)
120226-60-0 0.05 µg/L 1.00 1.09 7.75 0% - 20%
EP231X: 4:2 Fluorotelomer sulfonic acid (4:2
FTS)
757124-72-4 0.05 µg/L <0.05 <0.05 0.00 No LimitAnonymous EM1702285-011
EP231X: 6:2 Fluorotelomer sulfonic acid (6:2
FTS)
27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: 8:2 Fluorotelomer sulfonic acid (8:2
FTS)
39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: 10:2 Fluorotelomer sulfonic acid (10:2
FTS)
120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231P: PFAS Sums (QC Lot: 777260)
EP231X: Sum of PFAS ---- 0.01 µg/L 395 417 5.47 0% - 20%Anonymous EM1702285-001
EP231X: Sum of PFAS ---- 0.01 µg/L 1.23 1.22 0.816 0% - 20%Anonymous EM1702285-011
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Method Blank (MB) and Laboratory Control Spike (LCS) Report
The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC
parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target
analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QCLot: 778709)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 1022000 mg/L 10696
<10 102293 mg/L 10696
EA025: Total Suspended Solids dried at 104 ± 2°C (QCLot: 778710)
EA025H: Suspended Solids (SS) ---- 5 mg/L <5 106150 mg/L 11190
ED037P: Alkalinity by PC Titrator (QCLot: 777107)
ED037-P: Total Alkalinity as CaCO3 ---- ---- mg/L ---- 103200 mg/L 11090
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 777203)
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L <1 97.325 mg/L 11592
<1 99.9100 mg/L 11592
ED045G: Chloride by Discrete Analyser (QCLot: 777204)
ED045G: Chloride 16887-00-6 1 mg/L <1 10010 mg/L 11789
<1 99.01000 mg/L 11292
ED093F: Dissolved Major Cations (QCLot: 777822)
ED093F: Calcium 7440-70-2 1 mg/L <1 99.05 mg/L 10892
ED093F: Magnesium 7439-95-4 1 mg/L <1 96.15 mg/L 10892
ED093F: Sodium 7440-23-5 1 mg/L <1 99.850 mg/L 10789
ED093F: Potassium 7440-09-7 1 mg/L <1 10050 mg/L 10789
EG020F: Dissolved Metals by ICP-MS (QCLot: 777820)
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 1020.1 mg/L 10894
EG020A-F: Beryllium 7440-41-7 0.001 mg/L <0.001 1040.1 mg/L 11385
EG020A-F: Barium 7440-39-3 0.001 mg/L <0.001 97.60.1 mg/L 10787
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 97.30.1 mg/L 10886
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 99.00.1 mg/L 11086
EG020A-F: Cobalt 7440-48-4 0.001 mg/L <0.001 99.60.1 mg/L 10888
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 99.60.1 mg/L 10787
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 99.00.1 mg/L 10987
EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 1040.1 mg/L 10987
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 97.50.1 mg/L 10987
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 96.60.1 mg/L 10987
EG020A-F: Vanadium 7440-62-2 0.01 mg/L <0.01 99.40.1 mg/L 11185
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 1030.1 mg/L 10787
EG020A-F: Boron 7440-42-8 0.05 mg/L <0.05 1010.5 mg/L 11684
EG020T: Total Metals by ICP-MS (QCLot: 778607)
EG020A-T: Arsenic 7440-38-2 0.001 mg/L <0.001 1040.1 mg/L 11394
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EG020T: Total Metals by ICP-MS (QCLot: 778607) - continued
EG020A-T: Beryllium 7440-41-7 0.001 mg/L <0.001 1020.1 mg/L 11189
EG020A-T: Barium 7440-39-3 0.001 mg/L <0.001 97.80.1 mg/L 11289
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 99.20.1 mg/L 11088
EG020A-T: Chromium 7440-47-3 0.001 mg/L <0.001 95.50.1 mg/L 11287
EG020A-T: Cobalt 7440-48-4 0.001 mg/L <0.001 97.30.1 mg/L 11388
EG020A-T: Copper 7440-50-8 0.001 mg/L <0.001 94.80.1 mg/L 11287
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 96.60.1 mg/L 11388
EG020A-T: Manganese 7439-96-5 0.001 mg/L <0.001 96.80.1 mg/L 11288
EG020A-T: Nickel 7440-02-0 0.001 mg/L <0.001 98.80.1 mg/L 11191
EG020A-T: Selenium 7782-49-2 0.01 mg/L <0.01 98.80.1 mg/L 11086
EG020A-T: Vanadium 7440-62-2 0.01 mg/L <0.01 94.70.1 mg/L 11288
EG020A-T: Zinc 7440-66-6 0.005 mg/L <0.005 1010.1 mg/L 11288
EG020A-T: Boron 7440-42-8 0.05 mg/L <0.05 1040.5 mg/L 11888
EG020T: Total Metals by ICP-MS (QCLot: 778608)
EG020A-T: Arsenic 7440-38-2 0.001 mg/L <0.001 1040.1 mg/L 11394
EG020A-T: Beryllium 7440-41-7 0.001 mg/L <0.001 1010.1 mg/L 11189
EG020A-T: Barium 7440-39-3 0.001 mg/L <0.001 97.80.1 mg/L 11289
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 95.10.1 mg/L 11088
EG020A-T: Chromium 7440-47-3 0.001 mg/L <0.001 94.00.1 mg/L 11287
EG020A-T: Cobalt 7440-48-4 0.001 mg/L <0.001 94.50.1 mg/L 11388
EG020A-T: Copper 7440-50-8 0.001 mg/L <0.001 93.70.1 mg/L 11287
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 94.40.1 mg/L 11388
EG020A-T: Manganese 7439-96-5 0.001 mg/L <0.001 93.70.1 mg/L 11288
EG020A-T: Nickel 7440-02-0 0.001 mg/L <0.001 94.30.1 mg/L 11191
EG020A-T: Selenium 7782-49-2 0.01 mg/L <0.01 1010.1 mg/L 11086
EG020A-T: Vanadium 7440-62-2 0.01 mg/L <0.01 93.80.1 mg/L 11288
EG020A-T: Zinc 7440-66-6 0.005 mg/L <0.005 1000.1 mg/L 11288
EG020A-T: Boron 7440-42-8 0.05 mg/L <0.05 1040.5 mg/L 11888
EG035F: Dissolved Mercury by FIMS (QCLot: 777821)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 96.80.01 mg/L 11788
EG035T: Total Recoverable Mercury by FIMS (QCLot: 776483)
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 93.80.01 mg/L 11387
EG050F: Dissolved Hexavalent Chromium (QCLot: 775560)
EG050F: Hexavalent Chromium 18540-29-9 0.01 mg/L <0.01 1090.5 mg/L 11392
EK040P: Fluoride by PC Titrator (QCLot: 777102)
EK040P: Fluoride 16984-48-8 0.1 mg/L <0.1 1015 mg/L 11285
EK055G: Ammonia as N by Discrete Analyser (QCLot: 776619)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 1081 mg/L 11580
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EK071G: Reactive Phosphorus as P by discrete analyser (QCLot: 777205)
EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L <0.01 1040.5 mg/L 10894
EP005: Total Organic Carbon (TOC) (QCLot: 779014)
EP005: Total Organic Carbon ---- 1 mg/L <1 96.0100 mg/L 10981
EP074A: Monocyclic Aromatic Hydrocarbons (QCLot: 776481)
EP074: Styrene 100-42-5 5 µg/L <5 94.720 µg/L 11981
EP074: Isopropylbenzene 98-82-8 5 µg/L <5 99.020 µg/L 12379
EP074: n-Propylbenzene 103-65-1 5 µg/L <5 95.520 µg/L 11571
EP074: 1.3.5-Trimethylbenzene 108-67-8 5 µg/L <5 99.620 µg/L 11472
EP074: sec-Butylbenzene 135-98-8 5 µg/L <5 95.420 µg/L 11472
EP074: 1.2.4-Trimethylbenzene 95-63-6 5 µg/L <5 97.220 µg/L 11274
EP074: tert-Butylbenzene 98-06-6 5 µg/L <5 97.920 µg/L 11473
EP074: p-Isopropyltoluene 99-87-6 5 µg/L <5 93.920 µg/L 11570
EP074: n-Butylbenzene 104-51-8 5 µg/L <5 88.720 µg/L 11662
EP074B: Oxygenated Compounds (QCLot: 776481)
EP074: Vinyl Acetate 108-05-4 50 µg/L <50 98.6200 µg/L 12673
EP074: 2-Butanone (MEK) 78-93-3 50 µg/L <50 100200 µg/L 13662
EP074: 4-Methyl-2-pentanone (MIBK) 108-10-1 50 µg/L <50 98.0200 µg/L 13273
EP074: 2-Hexanone (MBK) 591-78-6 50 µg/L <50 97.2200 µg/L 13668
EP074C: Sulfonated Compounds (QCLot: 776481)
EP074: Carbon disulfide 75-15-0 5 µg/L <5 10920 µg/L 12355
EP074D: Fumigants (QCLot: 776481)
EP074: 2.2-Dichloropropane 594-20-7 5 µg/L <5 10720 µg/L 12267
EP074: 1.2-Dichloropropane 78-87-5 5 µg/L <5 10720 µg/L 12078
EP074: cis-1.3-Dichloropropylene 10061-01-5 5 µg/L <5 95.220 µg/L 11870
EP074: trans-1.3-Dichloropropylene 10061-02-6 5 µg/L <5 89.620 µg/L 11568
EP074: 1.2-Dibromoethane (EDB) 106-93-4 5 µg/L <5 98.820 µg/L 12078
EP074E: Halogenated Aliphatic Compounds (QCLot: 776481)
EP074: Dichlorodifluoromethane 75-71-8 50 µg/L <50 113200 µg/L 14062
EP074: Chloromethane 74-87-3 50 µg/L <50 99.4200 µg/L 13868
EP074: Vinyl chloride 75-01-4 50 µg/L <50 82.7200 µg/L 13964
EP074: Bromomethane 74-83-9 50 µg/L <50 51.4200 µg/L 13048
EP074: Chloroethane 75-00-3 50 µg/L <50 98.0200 µg/L 13071
EP074: Trichlorofluoromethane 75-69-4 50 µg/L <50 110200 µg/L 12671
EP074: 1.1-Dichloroethene 75-35-4 5 µg/L <5 10720 µg/L 12568
EP074: Iodomethane 74-88-4 5 µg/L <5 67.020 µg/L 12027
EP074: Methylene chloride 75-09-2 5 µg/L <5 13420 µg/L 16574
EP074: trans-1.2-Dichloroethene 156-60-5 5 µg/L <5 10520 µg/L 12173
EP074: 1.1-Dichloroethane 75-34-3 5 µg/L <5 10620 µg/L 12077
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP074E: Halogenated Aliphatic Compounds (QCLot: 776481) - continued
EP074: cis-1.2-Dichloroethene 156-59-2 5 µg/L <5 11820 µg/L 12079
EP074: 1.1.1-Trichloroethane 71-55-6 5 µg/L <5 10520 µg/L 12070
EP074: 1.1-Dichloropropylene 563-58-6 5 µg/L <5 10420 µg/L 12270
EP074: Carbon Tetrachloride 56-23-5 5 µg/L <5 10320 µg/L 11966
EP074: 1.2-Dichloroethane 107-06-2 5 µg/L <5 10920 µg/L 12079
EP074: Trichloroethene 79-01-6 5 µg/L <5 10520 µg/L 12075
EP074: Dibromomethane 74-95-3 5 µg/L <5 10820 µg/L 11877
EP074: 1.1.2-Trichloroethane 79-00-5 5 µg/L <5 10220 µg/L 12186
EP074: 1.3-Dichloropropane 142-28-9 5 µg/L <5 10220 µg/L 11984
EP074: Tetrachloroethene 127-18-4 5 µg/L <5 94.020 µg/L 11975
EP074: 1.1.1.2-Tetrachloroethane 630-20-6 5 µg/L <5 97.820 µg/L 11275
EP074: trans-1.4-Dichloro-2-butene 110-57-6 5 µg/L <5 90.320 µg/L 11963
EP074: cis-1.4-Dichloro-2-butene 1476-11-5 5 µg/L <5 79.220 µg/L 11954
EP074: 1.1.2.2-Tetrachloroethane 79-34-5 5 µg/L <5 10520 µg/L 12581
EP074: 1.2.3-Trichloropropane 96-18-4 5 µg/L <5 10420 µg/L 12581
EP074: Pentachloroethane 76-01-7 5 µg/L <5 97.620 µg/L 10963
EP074: 1.2-Dibromo-3-chloropropane 96-12-8 5 µg/L <5 10820 µg/L 11659
EP074: Hexachlorobutadiene 87-68-3 5 µg/L <5 96.020 µg/L 12260
EP074F: Halogenated Aromatic Compounds (QCLot: 776481)
EP074: Chlorobenzene 108-90-7 5 µg/L <5 10120 µg/L 11884
EP074: Bromobenzene 108-86-1 5 µg/L <5 10220 µg/L 11974
EP074: 2-Chlorotoluene 95-49-8 5 µg/L <5 99.220 µg/L 11476
EP074: 4-Chlorotoluene 106-43-4 5 µg/L <5 98.520 µg/L 11373
EP074: 1.3-Dichlorobenzene 541-73-1 5 µg/L <5 97.220 µg/L 11476
EP074: 1.4-Dichlorobenzene 106-46-7 5 µg/L <5 99.520 µg/L 11876
EP074: 1.2-Dichlorobenzene 95-50-1 5 µg/L <5 10020 µg/L 11381
EP074: 1.2.4-Trichlorobenzene 120-82-1 5 µg/L <5 94.620 µg/L 11864
EP074: 1.2.3-Trichlorobenzene 87-61-6 5 µg/L <5 99.220 µg/L 12072
EP074G: Trihalomethanes (QCLot: 776481)
EP074: Chloroform 67-66-3 5 µg/L <5 11720 µg/L 11878
EP074: Bromodichloromethane 75-27-4 5 µg/L <5 10820 µg/L 11569
EP074: Dibromochloromethane 124-48-1 5 µg/L <5 10020 µg/L 10969
EP074: Bromoform 75-25-2 5 µg/L <5 97.220 µg/L 11162
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 776810)
EP075(SIM): Naphthalene 91-20-3 1 µg/L <1.0 92.25 µg/L 11039
EP075(SIM): Acenaphthylene 208-96-8 1 µg/L <1.0 1025 µg/L 12440
EP075(SIM): Acenaphthene 83-32-9 1 µg/L <1.0 91.65 µg/L 11747
EP075(SIM): Fluorene 86-73-7 1 µg/L <1.0 91.45 µg/L 11851
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 776810) - continued
EP075(SIM): Phenanthrene 85-01-8 1 µg/L <1.0 1005 µg/L 11953
EP075(SIM): Anthracene 120-12-7 1 µg/L <1.0 1045 µg/L 11351
EP075(SIM): Fluoranthene 206-44-0 1 µg/L <1.0 94.65 µg/L 12359
EP075(SIM): Pyrene 129-00-0 1 µg/L <1.0 95.35 µg/L 12358
EP075(SIM): Benz(a)anthracene 56-55-3 1 µg/L <1.0 77.85 µg/L 12652
EP075(SIM): Chrysene 218-01-9 1 µg/L <1.0 91.25 µg/L 12355
EP075(SIM): Benzo(b+j)fluoranthene 205-99-2
205-82-3
1 µg/L <1.0 66.35 µg/L 13152
EP075(SIM): Benzo(k)fluoranthene 207-08-9 1 µg/L <1.0 1065 µg/L 12657
EP075(SIM): Benzo(a)pyrene 50-32-8 0.5 µg/L <0.5 96.85 µg/L 12656
EP075(SIM): Indeno(1.2.3.cd)pyrene 193-39-5 1 µg/L <1.0 92.25 µg/L 12353
EP075(SIM): Dibenz(a.h)anthracene 53-70-3 1 µg/L <1.0 99.45 µg/L 12553
EP075(SIM): Benzo(g.h.i)perylene 191-24-2 1 µg/L <1.0 1045 µg/L 12553
EP080/071: Total Petroleum Hydrocarbons (QCLot: 776480)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 102360 µg/L 12767
EP080/071: Total Petroleum Hydrocarbons (QCLot: 776811)
EP071: C10 - C14 Fraction ---- 50 µg/L <50 86.33368 µg/L 12353
EP071: C15 - C28 Fraction ---- 100 µg/L <100 86.614735 µg/L 13357
EP071: C29 - C36 Fraction ---- 50 µg/L <50 75.37856 µg/L 14155
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 776480)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 94.2450 µg/L 12565
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 776811)
EP071: >C10 - C16 Fraction ---- 100 µg/L <100 83.05225 µg/L 12254
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 78.819994 µg/L 13256
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 82.81449 µg/L 13751
EP080: BTEXN (QCLot: 776480)
EP080: Benzene 71-43-2 1 µg/L <1 93.220 µg/L 12076
EP080: Toluene 108-88-3 2 µg/L <2 95.520 µg/L 12476
EP080: Ethylbenzene 100-41-4 2 µg/L <2 95.220 µg/L 12472
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 94.240 µg/L 13072
EP080: ortho-Xylene 95-47-6 2 µg/L <2 99.320 µg/L 12878
EP080: Naphthalene 91-20-3 5 µg/L <5 94.25 µg/L 12971
EP231A: Perfluoroalkyl Sulfonic Acids (QCLot: 777260)
EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L <0.02 1070.5 µg/L 13070
EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L <0.02 84.60.5 µg/L 13070
EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L <0.02 86.00.5 µg/L 13070
EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L <0.02 81.80.5 µg/L 13070
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP231A: Perfluoroalkyl Sulfonic Acids (QCLot: 777260) - continued
EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.01 91.20.5 µg/L 13070
EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L <0.02 82.80.5 µg/L 13070
EP231B: Perfluoroalkyl Carboxylic Acids (QCLot: 777260)
EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L <0.1 92.02.5 µg/L 13070
EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L <0.02 89.40.5 µg/L 13070
EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L <0.02 90.60.5 µg/L 13070
EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L <0.02 93.20.5 µg/L 13070
EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 1080.5 µg/L 13070
EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L <0.02 86.60.5 µg/L 13070
EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L <0.02 80.80.5 µg/L 13070
EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L <0.02 94.40.5 µg/L 13070
EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 94.20.5 µg/L 13070
EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.02 µg/L <0.02 1030.5 µg/L 13070
EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.05 µg/L <0.05 97.41.25 µg/L 12470
EP231C: Perfluoroalkyl Sulfonamides (QCLot: 777260)
EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 89.80.5 µg/L 13070
EP231X: N-Methyl perfluorooctane sulfonamide (MeFOSA) 31506-32-8 0.05 µg/L <0.05 1021.25 µg/L 13070
EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 4151-50-2 0.05 µg/L <0.05 84.51.25 µg/L 12970
EP231X: N-Methyl perfluorooctane sulfonamidoethanol
(MeFOSE)
2448-09-7 0.05 µg/L <0.05 83.91.25 µg/L 12970
EP231X: N-Ethyl perfluorooctane sulfonamidoethanol
(EtFOSE)
1691-99-2 0.05 µg/L <0.05 93.01.25 µg/L 12670
EP231X: N-Methyl perfluorooctane sulfonamidoacetic acid
(MeFOSAA)
2355-31-9 0.02 µg/L <0.02 81.20.5 µg/L 13070
EP231X: N-Ethyl perfluorooctane sulfonamidoacetic acid
(EtFOSAA)
2991-50-6 0.02 µg/L <0.02 96.80.5 µg/L 13070
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QCLot: 777260)
EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 757124-72-4 0.05 µg/L <0.05 87.40.5 µg/L 13070
EP231X: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) 27619-97-2 0.05 µg/L <0.05 82.00.5 µg/L 13070
EP231X: 8:2 Fluorotelomer sulfonic acid (8:2 FTS) 39108-34-4 0.05 µg/L <0.05 93.40.5 µg/L 13070
EP231X: 10:2 Fluorotelomer sulfonic acid (10:2 FTS) 120226-60-0 0.05 µg/L <0.05 1080.5 µg/L 13070
Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on
analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 777203)
Anonymous EM1702301-001 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric 10410 mg/L 13070
ED045G: Chloride by Discrete Analyser (QCLot: 777204)
Anonymous EM1702301-001 16887-00-6ED045G: Chloride 94.9400 mg/L 13070
EG020F: Dissolved Metals by ICP-MS (QCLot: 777820)
Anonymous EM1702196-001 7440-38-2EG020A-F: Arsenic 99.90.2 mg/L 13185
7440-41-7EG020A-F: Beryllium 1120.2 mg/L 14173
7440-39-3EG020A-F: Barium 96.40.2 mg/L 12775
7440-43-9EG020A-F: Cadmium 99.90.05 mg/L 13381
7440-47-3EG020A-F: Chromium 95.80.2 mg/L 13571
7440-48-4EG020A-F: Cobalt 99.00.2 mg/L 13278
7440-50-8EG020A-F: Copper 96.40.2 mg/L 13076
7439-92-1EG020A-F: Lead 97.60.2 mg/L 13375
7439-96-5EG020A-F: Manganese 97.40.2 mg/L 13464
7440-02-0EG020A-F: Nickel 95.90.2 mg/L 13173
7440-62-2EG020A-F: Vanadium 94.50.2 mg/L 13173
7440-66-6EG020A-F: Zinc 98.50.2 mg/L 13175
EG020T: Total Metals by ICP-MS (QCLot: 778607)
Anonymous EM1702205-001 7440-38-2EG020A-T: Arsenic 1061 mg/L 11882
7440-41-7EG020A-T: Beryllium 93.71 mg/L 12179
7440-39-3EG020A-T: Barium 99.91 mg/L 11480
7440-43-9EG020A-T: Cadmium 1030.25 mg/L 12975
7440-47-3EG020A-T: Chromium 96.41 mg/L 11880
7440-48-4EG020A-T: Cobalt 1051 mg/L 12082
7440-50-8EG020A-T: Copper 97.81 mg/L 11581
7439-92-1EG020A-T: Lead 98.41 mg/L 12183
7439-96-5EG020A-T: Manganese 93.21 mg/L 12373
7440-02-0EG020A-T: Nickel 98.31 mg/L 11880
7440-62-2EG020A-T: Vanadium 97.81 mg/L 11981
7440-66-6EG020A-T: Zinc 97.31 mg/L 11674
EG020T: Total Metals by ICP-MS (QCLot: 778608)
GW16 EM1702312-005 7440-38-2EG020A-T: Arsenic 1061 mg/L 11882
7440-41-7EG020A-T: Beryllium 94.21 mg/L 12179
7440-39-3EG020A-T: Barium 1011 mg/L 11480
7440-43-9EG020A-T: Cadmium 95.80.25 mg/L 12975
7440-47-3EG020A-T: Chromium 97.81 mg/L 11880
7440-48-4EG020A-T: Cobalt 1001 mg/L 12082
7440-50-8EG020A-T: Copper 1061 mg/L 11581
7439-92-1EG020A-T: Lead 1041 mg/L 12183
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EG020T: Total Metals by ICP-MS (QCLot: 778608) - continued
GW16 EM1702312-005 7439-96-5EG020A-T: Manganese 94.71 mg/L 12373
7440-02-0EG020A-T: Nickel 1081 mg/L 11880
7440-62-2EG020A-T: Vanadium 99.11 mg/L 11981
7440-66-6EG020A-T: Zinc 95.11 mg/L 11674
EG035F: Dissolved Mercury by FIMS (QCLot: 777821)
Anonymous EM1702296-001 7439-97-6EG035F: Mercury 99.20.01 mg/L 12070
EG035T: Total Recoverable Mercury by FIMS (QCLot: 776483)
Anonymous EM1702289-021 7439-97-6EG035T: Mercury 91.50.01 mg/L 13070
EG050F: Dissolved Hexavalent Chromium (QCLot: 775560)
Anonymous EM1702240-002 18540-29-9EG050F: Hexavalent Chromium 97.60.5 mg/L 12759
EK040P: Fluoride by PC Titrator (QCLot: 777102)
Anonymous EM1702220-004 16984-48-8EK040P: Fluoride 95.65 mg/L 13070
EK055G: Ammonia as N by Discrete Analyser (QCLot: 776619)
Anonymous EM1702310-002 7664-41-7EK055G: Ammonia as N # Not
Determined
1 mg/L 13070
EK071G: Reactive Phosphorus as P by discrete analyser (QCLot: 777205)
GW09 EM1702312-002 14265-44-2EK071G: Reactive Phosphorus as P 91.00.5 mg/L 12379
EP005: Total Organic Carbon (TOC) (QCLot: 779014)
Anonymous EM1702205-002 ----EP005: Total Organic Carbon 96.0100 mg/L 11480
EP074E: Halogenated Aliphatic Compounds (QCLot: 776481)
GW09 EM1702312-002 75-35-4EP074: 1.1-Dichloroethene 67.420 µg/L 12440
79-01-6EP074: Trichloroethene 72.420 µg/L 12654
EP074F: Halogenated Aromatic Compounds (QCLot: 776481)
GW09 EM1702312-002 108-90-7EP074: Chlorobenzene 86.320 µg/L 13268
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 776810)
GW16 EM1702312-005 83-32-9EP075(SIM): Acenaphthene 57.25 µg/L 12242
129-00-0EP075(SIM): Pyrene 59.85 µg/L 13640
EP080/071: Total Petroleum Hydrocarbons (QCLot: 776480)
GW09 EM1702312-002 ----EP080: C6 - C9 Fraction 52.0280 µg/L 12543
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 776480)
GW09 EM1702312-002 C6_C10EP080: C6 - C10 Fraction 51.5330 µg/L 12244
EP080: BTEXN (QCLot: 776480)
GW09 EM1702312-002 71-43-2EP080: Benzene 80.020 µg/L 13068
108-88-3EP080: Toluene 84.120 µg/L 13272
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EP231A: Perfluoroalkyl Sulfonic Acids (QCLot: 777260)
Anonymous EM1702285-001 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) # Not
Determined
0.5 µg/L 13050
2706-91-4EP231X: Perfluoropentane sulfonic acid (PFPeS) 68.20.5 µg/L 13050
355-46-4EP231X: Perfluorohexane sulfonic acid (PFHxS) # Not
Determined
0.5 µg/L 13050
375-92-8EP231X: Perfluoroheptane sulfonic acid (PFHpS) # Not
Determined
0.5 µg/L 13050
1763-23-1EP231X: Perfluorooctane sulfonic acid (PFOS) # Not
Determined
0.5 µg/L 13050
335-77-3EP231X: Perfluorodecane sulfonic acid (PFDS) 95.00.5 µg/L 13050
EP231B: Perfluoroalkyl Carboxylic Acids (QCLot: 777260)
Anonymous EM1702285-001 375-22-4EP231X: Perfluorobutanoic acid (PFBA) 51.22.5 µg/L 13050
2706-90-3EP231X: Perfluoropentanoic acid (PFPeA) # Not
Determined
0.5 µg/L 13050
307-24-4EP231X: Perfluorohexanoic acid (PFHxA) # Not
Determined
0.5 µg/L 13050
375-85-9EP231X: Perfluoroheptanoic acid (PFHpA) # Not
Determined
0.5 µg/L 13050
335-67-1EP231X: Perfluorooctanoic acid (PFOA) # Not
Determined
0.5 µg/L 13050
375-95-1EP231X: Perfluorononanoic acid (PFNA) 81.40.5 µg/L 13050
335-76-2EP231X: Perfluorodecanoic acid (PFDA) 60.40.5 µg/L 13050
2058-94-8EP231X: Perfluoroundecanoic acid (PFUnDA) 63.20.5 µg/L 13050
307-55-1EP231X: Perfluorododecanoic acid (PFDoDA) 86.60.5 µg/L 13050
72629-94-8EP231X: Perfluorotridecanoic acid (PFTrDA) 70.20.5 µg/L 13050
376-06-7EP231X: Perfluorotetradecanoic acid (PFTeDA) 71.01.25 µg/L 13050
EP231C: Perfluoroalkyl Sulfonamides (QCLot: 777260)
Anonymous EM1702285-001 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 68.00.5 µg/L 13050
31506-32-8EP231X: N-Methyl perfluorooctane sulfonamide
(MeFOSA)
86.41.25 µg/L 13050
4151-50-2EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 70.91.25 µg/L 13050
2448-09-7EP231X: N-Methyl perfluorooctane sulfonamidoethanol
(MeFOSE)
67.91.25 µg/L 13050
1691-99-2EP231X: N-Ethyl perfluorooctane sulfonamidoethanol
(EtFOSE)
74.91.25 µg/L 13050
2355-31-9EP231X: N-Methyl perfluorooctane sulfonamidoacetic
acid (MeFOSAA)
68.00.5 µg/L 13050
2991-50-6EP231X: N-Ethyl perfluorooctane sulfonamidoacetic
acid (EtFOSAA)
89.80.5 µg/L 13050
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QCLot: 777260)
Anonymous EM1702285-001 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 97.20.5 µg/L 13050
27619-97-2EP231X: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) # Not
Determined
0.5 µg/L 13050
39108-34-4EP231X: 8:2 Fluorotelomer sulfonic acid (8:2 FTS) # Not
Determined
0.5 µg/L 13050
120226-60-0EP231X: 10:2 Fluorotelomer sulfonic acid (10:2 FTS) 77.40.5 µg/L 13050
True
Environmental
QA/QC Compliance Assessment to assist with Quality ReviewWork Order : EM1702312 Page : 1 of 14
:: LaboratoryClient Environmental Division MelbourneJACOBS GROUP (AUSTRALIA) PTY LTD
:Contact MR BENJAMIN GRASSO Telephone : +61-3-8549 9608
:Project IS157700 Date Samples Received : 02-Mar-2017
Site : ---- Issue Date : 09-Mar-2017
BENJAMIN GRASSO:Sampler No. of samples received : 8
:Order number ---- No. of samples analysed : 8
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated
reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this
report contribute to the overall DQO assessment and reporting for guideline compliance.
Brief method summaries and references are also provided to assist in traceability.
Summary of Outliers
Outliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.
l NO Duplicate outliers occur.
l NO Laboratory Control outliers occur.
l Matrix Spike outliers exist - please see following pages for full details.
l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliance
l Analysis Holding Time Outliers exist - please see following pages for full details.
Outliers : Frequency of Quality Control Samples
l Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Outliers : Quality Control Samples
Duplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes
Matrix: WATER
Compound Group Name CommentLimitsDataAnalyteClient Sample IDLaboratory Sample ID CAS Number
Matrix Spike (MS) Recoveries
EM1702310--002 7664-41-7Ammonia as NAnonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EK055G: Ammonia as N by Discrete Analyser
EM1702285--001 375-73-5Perfluorobutane
sulfonic acid (PFBS)
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP231A: Perfluoroalkyl Sulfonic Acids
EM1702285--001 355-46-4Perfluorohexane
sulfonic acid
(PFHxS)
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP231A: Perfluoroalkyl Sulfonic Acids
EM1702285--001 375-92-8Perfluoroheptane
sulfonic acid
(PFHpS)
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP231A: Perfluoroalkyl Sulfonic Acids
EM1702285--001 1763-23-1Perfluorooctane
sulfonic acid (PFOS)
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP231A: Perfluoroalkyl Sulfonic Acids
EM1702285--001 2706-90-3Perfluoropentanoic
acid (PFPeA)
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP231B: Perfluoroalkyl Carboxylic Acids
EM1702285--001 307-24-4Perfluorohexanoic acid
(PFHxA)
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP231B: Perfluoroalkyl Carboxylic Acids
EM1702285--001 375-85-9Perfluoroheptanoic
acid (PFHpA)
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP231B: Perfluoroalkyl Carboxylic Acids
EM1702285--001 335-67-1Perfluorooctanoic acid
(PFOA)
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP231B: Perfluoroalkyl Carboxylic Acids
EM1702285--001 27619-97-26:2 Fluorotelomer
sulfonic acid (6:2
FTS)
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP231D: (n:2) Fluorotelomer Sulfonic Acids
EM1702285--001 39108-34-48:2 Fluorotelomer
sulfonic acid (8:2
FTS)
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
EP231D: (n:2) Fluorotelomer Sulfonic Acids
Outliers : Analysis Holding Time Compliance
Matrix: WATER
AnalysisExtraction / Preparation
Date analysedDate extractedContainer / Client Sample ID(s) Days
overdue
Days
overdue
Due for extraction Due for analysis
Method
EA005P: pH by PC Titrator
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Matrix: WATER
AnalysisExtraction / Preparation
Date analysedDate extractedContainer / Client Sample ID(s) Days
overdue
Days
overdue
Due for extraction Due for analysis
Method
EA005P: pH by PC Titrator - Analysis Holding Time Compliance
Clear Plastic Bottle - Natural
01-Mar-2017----GW08, GW09,
GW17, GW18,
GW16
03-Mar-2017---- ---- 2
Outliers : Frequency of Quality Control Samples
Matrix: WATER
Quality Control SpecificationQuality Control Sample Type
Method ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC StandardTRH - Semivolatile Fraction 0.00 5.000 7
Analysis Holding Time Compliance
Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and
should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.
Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics
14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.
If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.
This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container
provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EA005P: pH by PC Titrator
Clear Plastic Bottle - Natural (EA005-P)
GW08, GW09,
GW17, GW18,
GW16
01-Mar-2017---- 03-Mar-2017----01-Mar-2017 ---- û
EA015: Total Dissolved Solids dried at 180 ± 5 °C
Clear Plastic Bottle - Natural (EA015H)
GW08, GW09,
GW17, GW18,
GW16
08-Mar-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
EA025: Total Suspended Solids dried at 104 ± 2°C
Clear Plastic Bottle - Natural (EA025H)
GW08, GW09,
GW17, GW18,
GW16
08-Mar-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
ED037P: Alkalinity by PC Titrator
Clear Plastic Bottle - Natural (ED037-P)
GW08, GW09,
GW17, GW18,
GW16
15-Mar-2017---- 03-Mar-2017----01-Mar-2017 ---- ü
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
Clear Plastic Bottle - Natural (ED041G)
GW08, GW09,
GW17, GW18,
GW16
29-Mar-2017---- 03-Mar-2017----01-Mar-2017 ---- ü
ED045G: Chloride by Discrete Analyser
Clear Plastic Bottle - Natural (ED045G)
GW08, GW09,
GW17, GW18,
GW16
29-Mar-2017---- 03-Mar-2017----01-Mar-2017 ---- ü
ED093F: Dissolved Major Cations
Clear Plastic Bottle - Natural (ED093F)
GW16 08-Mar-2017---- 07-Mar-2017----01-Mar-2017 ---- üClear Plastic Bottle - Nitric Acid; Filtered (ED093F)
GW08, GW09,
GW17, GW18
29-Mar-2017---- 07-Mar-2017----01-Mar-2017 ---- ü
EG020F: Dissolved Metals by ICP-MS
Clear Plastic Bottle - Natural (EG020A-F)
GW16 28-Aug-2017---- 06-Mar-2017----01-Mar-2017 ---- üClear Plastic Bottle - Nitric Acid; Filtered (EG020A-F)
GW08, GW09,
GW17, GW18
28-Aug-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
EG020T: Total Metals by ICP-MS
Clear Plastic Bottle - Nitric Acid; Unfiltered (EG020A-T)
GW08, GW09,
GW17, GW18,
GW16, RB_003
28-Aug-201728-Aug-2017 07-Mar-201707-Mar-201701-Mar-2017 ü ü
Clear Plastic Bottle - Nitric Acid; Unfiltered (EG020A-T)
RB_002 27-Aug-201727-Aug-2017 07-Mar-201707-Mar-201728-Feb-2017 ü üEG035F: Dissolved Mercury by FIMS
Clear Plastic Bottle - Natural (EG035F)
GW16 29-Mar-2017---- 07-Mar-2017----01-Mar-2017 ---- üClear Plastic Bottle - Nitric Acid; Filtered (EG035F)
GW08, GW09,
GW17, GW18
29-Mar-2017---- 07-Mar-2017----01-Mar-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EG035T: Total Recoverable Mercury by FIMS
Clear Plastic Bottle - Nitric Acid; Unfiltered (EG035T)
GW08, GW09,
GW17, GW18,
GW16, RB_003
29-Mar-2017---- 03-Mar-2017----01-Mar-2017 ---- ü
Clear Plastic Bottle - Nitric Acid; Unfiltered (EG035T)
RB_002 28-Mar-2017---- 03-Mar-2017----28-Feb-2017 ---- üEG050F: Dissolved Hexavalent Chromium
Clear Plastic Bottle - NaOH Filtered (EG050F)
GW08, GW09,
GW17, GW18
29-Mar-2017---- 02-Mar-2017----01-Mar-2017 ---- ü
Clear Plastic Bottle - Natural (EG050F)
GW16 02-Mar-2017---- 02-Mar-2017----01-Mar-2017 ---- üEK040P: Fluoride by PC Titrator
Clear Plastic Bottle - Natural (EK040P)
GW08, GW09,
GW17, GW18,
GW16
29-Mar-2017---- 03-Mar-2017----01-Mar-2017 ---- ü
EK055G: Ammonia as N by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK055G)
GW08, GW09,
GW17, GW18,
GW16
29-Mar-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
EK071G: Reactive Phosphorus as P by discrete analyser
Clear Plastic Bottle - Natural (EK071G)
GW08, GW09,
GW17, GW18,
GW16
03-Mar-2017---- 03-Mar-2017----01-Mar-2017 ---- ü
EP005: Total Organic Carbon (TOC)
Amber VOC Vial - Sulfuric Acid (EP005)
GW08, GW09,
GW17, GW18,
GW16
29-Mar-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
EP074A: Monocyclic Aromatic Hydrocarbons
Amber VOC Vial - Sulfuric Acid (EP074)
GW08, GW09,
GW17, GW18,
GW16
15-Mar-201715-Mar-2017 03-Mar-201703-Mar-201701-Mar-2017 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP074B: Oxygenated Compounds
Amber VOC Vial - Sulfuric Acid (EP074)
GW08, GW09,
GW17, GW18,
GW16
15-Mar-201715-Mar-2017 03-Mar-201703-Mar-201701-Mar-2017 ü ü
EP074C: Sulfonated Compounds
Amber VOC Vial - Sulfuric Acid (EP074)
GW08, GW09,
GW17, GW18,
GW16
15-Mar-201715-Mar-2017 03-Mar-201703-Mar-201701-Mar-2017 ü ü
EP074D: Fumigants
Amber VOC Vial - Sulfuric Acid (EP074)
GW08, GW09,
GW17, GW18,
GW16
15-Mar-201715-Mar-2017 03-Mar-201703-Mar-201701-Mar-2017 ü ü
EP074E: Halogenated Aliphatic Compounds
Amber VOC Vial - Sulfuric Acid (EP074)
GW08, GW09,
GW17, GW18,
GW16
15-Mar-201715-Mar-2017 03-Mar-201703-Mar-201701-Mar-2017 ü ü
EP074F: Halogenated Aromatic Compounds
Amber VOC Vial - Sulfuric Acid (EP074)
GW08, GW09,
GW17, GW18,
GW16
15-Mar-201715-Mar-2017 03-Mar-201703-Mar-201701-Mar-2017 ü ü
EP074G: Trihalomethanes
Amber VOC Vial - Sulfuric Acid (EP074)
GW08, GW09,
GW17, GW18,
GW16
15-Mar-201715-Mar-2017 03-Mar-201703-Mar-201701-Mar-2017 ü ü
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
Amber Glass Bottle - Unpreserved (EP075(SIM))
GW08, GW09,
GW17, GW18,
GW16
15-Apr-201708-Mar-2017 08-Mar-201706-Mar-201701-Mar-2017 ü ü
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JACOBS GROUP (AUSTRALIA) PTY LTD
IS157700:Project
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP080/071: Total Petroleum Hydrocarbons
Amber Glass Bottle - Unpreserved (EP071)
GW08, GW09,
GW17, GW18,
GW16
15-Apr-201708-Mar-2017 08-Mar-201706-Mar-201701-Mar-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
GW08, GW09,
GW17, GW18,
GW16, TB_003
15-Mar-201715-Mar-2017 03-Mar-201703-Mar-201701-Mar-2017 ü ü
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
Amber Glass Bottle - Unpreserved (EP071)
GW08, GW09,
GW17, GW18,
GW16
15-Apr-201708-Mar-2017 08-Mar-201706-Mar-201701-Mar-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
GW08, GW09,
GW17, GW18,
GW16, TB_003
15-Mar-201715-Mar-2017 03-Mar-201703-Mar-201701-Mar-2017 ü ü
EP080: BTEXN
Amber VOC Vial - Sulfuric Acid (EP080)
GW08, GW09,
GW17, GW18,
GW16, TB_003
15-Mar-201715-Mar-2017 03-Mar-201703-Mar-201701-Mar-2017 ü ü
EP231A: Perfluoroalkyl Sulfonic Acids
HDPE (no PTFE) (EP231X)
GW08, GW09,
GW17, GW18,
GW16
28-Aug-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
EP231B: Perfluoroalkyl Carboxylic Acids
HDPE (no PTFE) (EP231X)
GW08, GW09,
GW17, GW18,
GW16
28-Aug-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
EP231C: Perfluoroalkyl Sulfonamides
HDPE (no PTFE) (EP231X)
GW08, GW09,
GW17, GW18,
GW16
28-Aug-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
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JACOBS GROUP (AUSTRALIA) PTY LTD
IS157700:Project
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP231D: (n:2) Fluorotelomer Sulfonic Acids
HDPE (no PTFE) (EP231X)
GW08, GW09,
GW17, GW18,
GW16
28-Aug-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
EP231P: PFAS Sums
HDPE (no PTFE) (EP231X)
GW08, GW09,
GW17, GW18,
GW16
28-Aug-2017---- 06-Mar-2017----01-Mar-2017 ---- ü
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Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to
the expected rate. A listing of breaches is provided in the Summary of Outliers.
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üFluoride by PC Titrator EK040P
NEPM 2013 B3 & ALS QC Standard 13.33 10.002 15 üHexavalent Chromium - Dissolved EG050F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 14.29 10.001 7 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 11.11 10.002 18 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üpH by PC Titrator EA005-P
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üReactive Phosphorus as P-By Discrete Analyser EK071G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üSuspended Solids (High Level) EA025H
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 16.67 10.002 12 üTotal Mercury by FIMS EG035T
NEPM 2013 B3 & ALS QC Standard 16.67 10.004 24 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 14.29 10.001 7 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 12.50 10.002 16 üTRH Volatiles/BTEX EP080
NEPM 2013 B3 & ALS QC Standard 20.00 10.001 5 üVolatile Organic Compounds EP074
Laboratory Control Samples (LCS)
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üFluoride by PC Titrator EK040P
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üHexavalent Chromium - Dissolved EG050F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üReactive Phosphorus as P-By Discrete Analyser EK071G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üSuspended Solids (High Level) EA025H
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Dissolved Solids (High Level) EA015H
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Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Control Samples (LCS) - Continued
NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üTotal Mercury by FIMS EG035T
NEPM 2013 B3 & ALS QC Standard 8.33 5.002 24 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üTRH Volatiles/BTEX EP080
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üVolatile Organic Compounds EP074
Method Blanks (MB)
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üFluoride by PC Titrator EK040P
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üHexavalent Chromium - Dissolved EG050F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üReactive Phosphorus as P-By Discrete Analyser EK071G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üSuspended Solids (High Level) EA025H
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üTotal Mercury by FIMS EG035T
NEPM 2013 B3 & ALS QC Standard 8.33 5.002 24 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üTRH Volatiles/BTEX EP080
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üVolatile Organic Compounds EP074
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üFluoride by PC Titrator EK040P
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üHexavalent Chromium - Dissolved EG050F
NEPM 2013 B3 & ALS QC Standard 14.29 5.001 7 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 5.56 5.001 18 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üReactive Phosphorus as P-By Discrete Analyser EK071G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üTotal Mercury by FIMS EG035T
NEPM 2013 B3 & ALS QC Standard 8.33 5.002 24 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üTotal Organic Carbon EP005
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IS157700:Project
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Matrix Spikes (MS) - Continued
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 7 ûTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üTRH Volatiles/BTEX EP080
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üVolatile Organic Compounds EP074
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IS157700:Project
Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the
Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 H+ B. This procedure determines pH of water samples by automated ISE.
This method is compliant with NEPM (2013) Schedule B(3)
pH by PC Titrator EA005-P WATER
In house: Referenced to APHA 2540C. A gravimetric procedure that determines the amount of `filterable` residue
in an aqueous sample. A well-mixed sample is filtered through a glass fibre filter (1.2um). The filtrate is
evaporated to dryness and dried to constant weight at 180+/-5C. This method is compliant with NEPM (2013)
Schedule B(3)
Total Dissolved Solids (High Level) EA015H WATER
In house: Referenced to APHA 2540D. A gravimetric procedure employed to determine the amount of
`non-filterable` residue in a aqueous sample. The prescribed GFC (1.2um) filter is rinsed with deionised water,
oven dried and weighed prior to analysis. A well-mixed sample is filtered through a glass fibre filter (1.2um).
The residue on the filter paper is dried at 104+/-2C . This method is compliant with NEPM (2013) Schedule B(3)
Suspended Solids (High Level) EA025H WATER
In house: Referenced to APHA 2320 B This procedure determines alkalinity by automated measurement (e.g. PC
Titrate) using pH 4.5 for indicating the total alkalinity end-point. This method is compliant with NEPM (2013)
Schedule B(3)
Alkalinity by PC Titrator ED037-P WATER
In house: Referenced to APHA 4500-SO4. Dissolved sulfate is determined in a 0.45um filtered sample. Sulfate
ions are converted to a barium sulfate suspension in an acetic acid medium with barium chloride. Light
absorbance of the BaSO4 suspension is measured by a photometer and the SO4-2 concentration is determined
by comparison of the reading with a standard curve. This method is compliant with NEPM (2013) Schedule B(3)
Sulfate (Turbidimetric) as SO4 2- by
Discrete Analyser
ED041G WATER
In house: Referenced to APHA 4500 Cl - G.The thiocyanate ion is liberated from mercuric thiocyanate through
sequestration of mercury by the chloride ion to form non-ionised mercuric chloride.in the presence of ferric ions
the librated thiocynate forms highly-coloured ferric thiocynate which is measured at 480 nm APHA 21st edition
seal method 2 017-1-L april 2003
Chloride by Discrete Analyser ED045G WATER
In house: Referenced to APHA 3120 and 3125; USEPA SW 846 - 6010 and 6020; Cations are determined by
either ICP-AES or ICP-MS techniques. This method is compliant with NEPM (2013) Schedule B(3)
Sodium Adsorption Ratio is calculated from Ca, Mg and Na which determined by ALS in house method
QWI-EN/ED093F. This method is compliant with NEPM (2013) Schedule B(3)
Hardness parameters are calculated based on APHA 2340 B. This method is compliant with NEPM (2013)
Schedule B(3)
Major Cations - Dissolved ED093F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. Samples are 0.45µm filtered
prior to analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions
are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct
mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Dissolved Metals by ICP-MS - Suite A EG020A-F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. The ICPMS technique utilizes
a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass
spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their
measurement by a discrete dynode ion detector.
Total Metals by ICP-MS - Suite A EG020A-T WATER
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Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS)
Samples are 0.45µm filtered prior to analysis. FIM-AAS is an automated flameless atomic absorption technique.
A bromate/bromide reagent is used to oxidise any organic mercury compounds in the filtered sample. The ionic
mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell.
Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM
(2013) Schedule B(3)
Dissolved Mercury by FIMS EG035F WATER
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS)
FIM-AAS is an automated flameless atomic absorption technique. A bromate/bromide reagent is used to oxidise
any organic mercury compounds in the unfiltered sample. The ionic mercury is reduced online to atomic
mercury vapour by SnCl2 which is then purged into a heated quartz cell. Quantification is by comparing
absorbance against a calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Total Mercury by FIMS EG035T WATER
In house: Referenced to APHA 3500 Cr-B. Samples are 0.45µm filtered prior to analysis. Hexavalent chromium is
determined on filtered water sample as received by pH adjustment and colour development using
dephenylcarbazide. Each run of samples is measured against a five-point calibration curve. This method is
compliant with NEPM (2013) Schedule B(3)
Hexavalent Chromium - Dissolved EG050F WATER
In house: Referenced to APHA 4500-F C: CDTA is added to the sample to provide a uniform ionic strength
background, adjust pH, and break up complexes. Fluoride concentration is determined by either manual or
automatic ISE measurement. This method is compliant with NEPM (2013) Schedule B(3)
Fluoride by PC Titrator EK040P WATER
In house: Referenced to APHA 4500-NH3 G Ammonia is determined by direct colorimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Ammonia as N by Discrete analyser EK055G WATER
In house: Referenced to APHA 4500-P F Ammonium molybdate and potassium antimonyl tartrate reacts in acid
medium with othophosphate to form a heteropoly acid -phosphomolybdic acid - which is reduced to intensely
coloured molybdenum blue by ascorbic acid. Quantification is by Discrete Analyser. This method is compliant
with NEPM (2013) Schedule B(3)
Reactive Phosphorus as P-By Discrete
Analyser
EK071G WATER
In house: Referenced to APHA 1030F. This method is compliant with NEPM (2013) Schedule B(3)Ionic Balance by PCT DA and Turbi SO4
DA
EN055 - PG WATER
In house: Referenced to APHA 5310 B, The automated TOC analyzer determines Total and Inorganic Carbon by
IR cell. TOC is calculated as the difference. This method is compliant with NEPM (2013) Schedule B(3)
Total Organic Carbon EP005 WATER
In house: Referenced to USEPA SW 846 - 8015A The sample extract is analysed by Capillary GC/FID and
quantification is by comparison against an established 5 point calibration curve of n-Alkane standards. This
method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH - Semivolatile Fraction EP071 WATER
In house: Referenced to USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by
Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. This
method is compliant with NEPM (2013) Schedule B(3)
Volatile Organic Compounds EP074 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS in SIM Mode
and quantification is by comparison against an established 5 point calibration curve. This method is compliant
with NEPM (2013) Schedule B(3)
PAH/Phenols (GC/MS - SIM) EP075(SIM) WATER
In house: Referenced to USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by
Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve.
Alternatively, a sample is equilibrated in a headspace vial and a portion of the headspace determined by GCMS
analysis. This method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH Volatiles/BTEX EP080 WATER
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Analytical Methods Method DescriptionsMatrixMethod
In house: Direct injection analysis of fresh waters after dilution (1:1) with methanol. Analysis by
LC-Electrospray-MS-MS, Negative Mode using MRM. PFOS is quantified using a certified, traceable standard
consisting of linear and branched PFOS isomers.
Per- and Polyfluoroalkyl Substances
(PFAS) by LCMSMS
EP231X WATER
Preparation Methods Method DescriptionsMatrixMethod
In house: Referenced to USEPA SW846-3005. Method 3005 is a Nitric/Hydrochloric acid digestion procedure
used to prepare surface and ground water samples for analysis by ICPAES or ICPMS. This method is compliant
with NEPM (2013) Schedule B(3)
Digestion for Total Recoverable Metals EN25 WATER
In house: Referenced to USEPA SW 846 - 3510B 100 mL to 1L of sample is transferred to a separatory funnel
and serially extracted three times using 60mL DCM for each extract. The resultant extracts are combined,
dehydrated and concentrated for analysis. This method is compliant with NEPM (2013) Schedule B(3) . ALS
default excludes sediment which may be resident in the container.
Separatory Funnel Extraction of Liquids ORG14 WATER
A 5 mL aliquot or 5 mL of a diluted sample is added to a 40 mL VOC vial for sparging.Volatiles Water Preparation ORG16-W WATER
Environmental
SAMPLE RECEIPT NOTIFICATION (SRN)Work Order : EM1702312
:: LaboratoryClient Environmental Division MelbourneJACOBS GROUP (AUSTRALIA) PTY
LTD
: :ContactContact MR BENJAMIN GRASSO Carol Walsh
:: AddressAddress P O BOX 312 FLINDERS LANE
MELBOURNE VIC AUSTRALIA 8009
4 Westall Rd Springvale VIC Australia
3171
:: E-mailE-mail [email protected] [email protected]
:: TelephoneTelephone +61 03 8668 3000 +61-3-8549 9608
:: FacsimileFacsimile +61 03 8668 3001 +61-3-8549 9601
::Project IS157700 Page 1 of 3
:Order number ---- :Quote number EM2017SINKNI0002 (ME/088/17)
:C-O-C number ---- :QC Level NEPM 2013 B3 & ALS QC Standard
Site : ----
Sampler : BENJAMIN GRASSO
DatesDate Samples Received : Issue Date : 02-Mar-201702-Mar-2017 08:55
Scheduled Reporting Date: 10-Mar-2017:Client Requested Due
Date
10-Mar-2017
Delivery DetailsMode of Delivery : :Carrier Intact.Security Seal
No. of coolers/boxes : :1 Temperature 2.9°C - Ice present
: : 8 / 8Receipt Detail No. of samples received / analysed
General Comments
This report contains the following information:l
- Sample Container(s)/Preservation Non-Compliances
- Summary of Sample(s) and Requested Analysis
- Proactive Holding Time Report
- Requested Deliverables
l Sample GW16 to be filtered through a 0.45um filter prior to the dissolved metals analysis.l Please direct any queries related to sample condition / numbering / breakages to Client Services.l Sample Disposal - Aqueous (14 days), Solid (60 days) from date of completion of work order.
l Analytical work for this work order will be conducted at ALS Springvale & ALS Sydney.l Please refer to the Proactive Holding Time Report table below which summarises breaches of
recommended holding times that have occurred prior to samples/instructions being received at
the laboratory. The absence of this summary table indicates that all samples have been received
within the recommended holding times for the analysis requested.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
:Client JACOBS GROUP (AUSTRALIA) PTY LTD
Work Order : EM1702312 Amendment 02 of 3:Page
02-Mar-2017:Issue Date
Sample Container(s)/Preservation Non-Compliances
All comparisons are made against pretreatment/preservation AS, APHA, USEPA standards.
MethodSample Container Received Preferred Sample Container for AnalysisClient sample ID
Dissolved Mercury by FIMS : EG035F
GW16 - Clear Plastic Bottle - Natural - Clear Plastic Bottle - Nitric Acid; Filtered
Dissolved Metals by ICP-MS - Suite A : EG020A-F
GW16 - Clear Plastic Bottle - Natural - Clear Plastic Bottle - Nitric Acid; Filtered
Summary of Sample(s) and Requested Analysis
Some items described below may be part of a laboratory
process necessary for the execution of client requested
tasks. Packages may contain additional analyses, such
as the determination of moisture content and preparation
tasks, that are included in the package.
If no sampling time is provided, the sampling time will
default 00:00 on the date of sampling. If no sampling date
is provided, the sampling date will be assumed by the
laboratory and displayed in brackets without a time
component
WA
TE
R -
EG
05
0F
Dis
solv
ed
He
xava
lent C
hro
miu
m
WA
TE
R -
EK
05
5G
Am
mo
nia
as
N B
y D
iscr
ete
An
aly
ser
WA
TE
R -
EP
23
1X
PF
AS
- F
ull
Su
ite (
28
an
aly
tes)
WA
TE
R -
NT
-01
& 0
2
Ca
, M
g, N
a, K
, C
l, S
O4, A
lkalin
ity
WA
TE
R -
W-0
3
15
Me
tals
(N
EP
M S
uite
)
WA
TE
R -
W-0
3T
15
Me
tals
(T
ota
l) (
NE
PM
)
WA
TE
R -
W-1
0
TR
H/V
OC
/PA
H
EM1702312-001 01-Mar-2017 00:00 GW08 ü ü ü ü ü ü ü
EM1702312-002 01-Mar-2017 00:00 GW09 ü ü ü ü ü ü ü
EM1702312-003 01-Mar-2017 00:00 GW17 ü ü ü ü ü ü ü
EM1702312-004 01-Mar-2017 00:00 GW18 ü ü ü ü ü ü ü
EM1702312-005 01-Mar-2017 00:00 GW16 ü ü ü ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
WA
TE
R -
EA
005P
pH
(P
C)
WA
TE
R -
EA
015H
Tota
l Dis
solv
ed S
olid
s -
Hig
h L
eve
l
WA
TE
R -
EA
025H
Susp
ended S
olid
s (H
igh L
eve
l)
WA
TE
R -
EK
071G
React
ive P
hosp
horu
s by
Dis
cre
te a
na
lyse
r
WA
TE
R -
EP
005
Tota
l Org
anic
Carb
on (
TO
C)
WA
TE
R -
W-0
2T
8 m
eta
ls (
Tota
l)
WA
TE
R -
W-1
8
TR
H(C
6 -
C9)/
BT
EX
N
EM1702312-001 01-Mar-2017 00:00 GW08 ü ü ü ü ü
EM1702312-002 01-Mar-2017 00:00 GW09 ü ü ü ü ü
EM1702312-003 01-Mar-2017 00:00 GW17 ü ü ü ü ü
EM1702312-004 01-Mar-2017 00:00 GW18 ü ü ü ü ü
EM1702312-005 01-Mar-2017 00:00 GW16 ü ü ü ü ü
EM1702312-006 01-Mar-2017 00:00 TB_003 ü
EM1702312-007 28-Feb-2017 00:00 RB_002 ü
EM1702312-008 01-Mar-2017 00:00 RB_003 ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
Proactive Holding Time Report
The following table summarises breaches of recommended holding times that have occurred prior to samples/instructions being
received at the laboratory.
Evaluation: û = Holding time breach ; ü = Within holding time. Matrix: WATER
EvaluationClient Sample ID(s)
Due for
extraction
Due for
analysis Evaluation
Samples Received Instructions Received
Date Date
Method
Container
EA005-P: pH by PC Titrator
:Client JACOBS GROUP (AUSTRALIA) PTY LTD
Work Order : EM1702312 Amendment 03 of 3:Page
02-Mar-2017:Issue Date
GW08 û --------02-Mar-201701-Mar-2017----Clear Plastic Bottle - Natural
GW09 û --------02-Mar-201701-Mar-2017----Clear Plastic Bottle - Natural
GW16 û --------02-Mar-201701-Mar-2017----Clear Plastic Bottle - Natural
GW17 û --------02-Mar-201701-Mar-2017----Clear Plastic Bottle - Natural
GW18 û --------02-Mar-201701-Mar-2017----Clear Plastic Bottle - Natural
Requested Deliverables
ACCOUNTS PAYABLE
- A4 - AU Tax Invoice (INV) Email [email protected]
BENJAMIN GRASSO
- *AU Certificate of Analysis - NATA (COA) Email [email protected]
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email [email protected]
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email [email protected]
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email [email protected]
- A4 - AU Tax Invoice (INV) Email [email protected]
- Chain of Custody (CoC) (COC) Email [email protected]
- Chromatogram (CHROM) Email [email protected]
- EDI Format - ESDAT (ESDAT) Email [email protected]
- EDI Format - XTab (XTAB) Email [email protected]
Fraction Scheme : Legacy Fractions
Data File : 00601066.D
Laboratory Number: EM1702312-005
Sample ID : GW16
Date Acquired : 9 Mar 2017 3:15 am
0.50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50
160000
180000
200000
220000
240000
260000
280000
300000
320000
340000
360000
380000
400000
420000
440000
460000
480000
500000
520000
540000
560000
580000
600000
620000
640000
660000
680000
700000
720000
740000
760000
780000
800000
820000
840000
Time
Response_ Signal: 00601066.D\FID2B.ch
2.259
6.494
6.990
C29 - C36
C15 - C28
C10 - C14
Fraction Scheme : NEPM Fractions
Data File : 00601066.D
Laboratory Number: EM1702312-005
Sample ID : GW16
Date Acquired : 9 Mar 2017 3:15 am
0.50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50
160000
180000
200000
220000
240000
260000
280000
300000
320000
340000
360000
380000
400000
420000
440000
460000
480000
500000
520000
540000
560000
580000
600000
620000
640000
660000
680000
700000
720000
740000
760000
780000
800000
820000
840000
Time
Response_ Signal: 00601066.D\FID2B.ch
2.259
6.494
8.003
>C34 - C40
>C16 - C34
>C10 - C16
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 12EM1702389
:: LaboratoryClient JACOBS GROUP (AUSTRALIA) PTY LTD Environmental Division Melbourne
: :ContactContact MR BENJAMIN GRASSO Carol Walsh
:: AddressAddress P O BOX 312 FLINDERS LANE
MELBOURNE VIC AUSTRALIA 8009
4 Westall Rd Springvale VIC Australia 3171
:Telephone +61 03 8668 3000 :Telephone +61-3-8549 9608
:Project ISI57700 Date Samples Received : 03-Mar-2017 10:05
:Order number ---- Date Analysis Commenced : 03-Mar-2017
:C-O-C number ---- Issue Date : 09-Mar-2017 17:23
Sampler : BEN GRASSO
Site : EBAC GME
Quote number : ME/088/17
7:No. of samples received
7:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:
l General Comments
l Analytical Results
l Surrogate Control Limits
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with
Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Chris Lemaitre Non-Metals Team Leader Melbourne Inorganics, Springvale, VIC
Dilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VIC
Lana Nguyen Senior LCMS Chemist Sydney Organics, Smithfield, NSW
Nancy Wang Senior Semivolatile Instrument Chemist Melbourne Organics, Springvale, VIC
R I G H T S O L U T I O N S | R I G H T P A R T N E R
2 of 12:Page
Work Order :
:Client
EM1702389
ISI57700:Project
JACOBS GROUP (AUSTRALIA) PTY LTD
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When no sampling time is provided, the sampling time will default 00:00 on the date of sampling. If no sampling date is provided, the sampling date will be assumed by the laboratory and displayed in brackets without a
time component.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
^ = This result is computed from individual analyte detections at or above the level of reporting
ø = ALS is not NATA accredited for these tests.
~ = Indicates an estimated value.
Key :
EP074: Particular sample EM1702389_05 shows a positive hit for Chloroform. Confirmed by re-analysis.l
It is recognised that total metals is less than dissolved metals for samples #3, #4 and #5. However, the difference is within experimental variation of the methods.l
TDS by method EA-015 may bias high for EM1702389 #4 due to the presence of fine particulate matter, which may pass through the prescribed GF/C paper.l
Sample 004 was filtered through a 0.45um filter prior to the dissolved Hexachrome analysis.l
Ionic balances were calculated using: major anions - chloride, alkalinity and sulfate; and major cations - calcium, magnesium, potassium and sodium.l
ED045G: The presence of thiocyanate can positively contribute to the chloride result, thereby may bias results higher than expected. Results should be scrutinised accordingly.l
Benzo(a)pyrene Toxicity Equivalent Quotient (TEQ) is the sum total of the concentration of the eight carcinogenic PAHs multiplied by their Toxicity Equivalence Factor (TEF) relative to Benzo(a)pyrene. TEF values
are provided in brackets as follows: Benz(a)anthracene (0.1), Chrysene (0.01), Benzo(b+j) & Benzo(k)fluoranthene (0.1), Benzo(a)pyrene (1.0), Indeno(1.2.3.cd)pyrene (0.1), Dibenz(a.h)anthracene (1.0),
Benzo(g.h.i)perylene (0.01). Less than LOR results for 'TEQ Zero' are treated as zero.
l
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ISI57700:Project
JACOBS GROUP (AUSTRALIA) PTY LTD
Analytical Results
GW05GW07GW06GW20GW14Client sample IDSub-Matrix: WATER
(Matrix: WATER)
02-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:00Client sampling date / time
EM1702389-005EM1702389-004EM1702389-003EM1702389-002EM1702389-001UnitLORCAS NumberCompound
Result Result Result Result Result
EA005P: pH by PC Titrator
7.89 6.87 7.12 7.15 7.39pH Unit0.01----pH Value
EA015: Total Dissolved Solids dried at 180 ± 5 °C
4870 6220 6640 7850 6450mg/L10----Total Dissolved Solids @180°C
EA025: Total Suspended Solids dried at 104 ± 2°C
7990 455 1670 8830 90mg/L5----Suspended Solids (SS)
ED037P: Alkalinity by PC Titrator
<1Hydroxide Alkalinity as CaCO3 <1 <1 <1 <1mg/L1DMO-210-001
<1Carbonate Alkalinity as CaCO3 <1 <1 <1 <1mg/L13812-32-6
657Bicarbonate Alkalinity as CaCO3 65 424 520 310mg/L171-52-3
657 65 424 520 310mg/L1----Total Alkalinity as CaCO3
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
491Sulfate as SO4 - Turbidimetric 228 160 4460 214mg/L114808-79-8
ED045G: Chloride by Discrete Analyser
1940Chloride 3350 3240 673 3550mg/L116887-00-6
ED093F: Dissolved Major Cations
96Calcium 40 201 402 36mg/L17440-70-2
136Magnesium 172 270 470 165mg/L17439-95-4
1360Sodium 1790 1430 1360 2060mg/L17440-23-5
8Potassium 4 4 4 7mg/L17440-09-7
EG020F: Dissolved Metals by ICP-MS
<0.001Arsenic <0.001 0.001 0.001 0.002mg/L0.0017440-38-2
<0.05Boron <0.05 <0.05 2.52 0.10mg/L0.057440-42-8
0.542Barium 0.094 0.287 0.025 0.086mg/L0.0017440-39-3
<0.001Beryllium <0.001 <0.001 <0.001 <0.001mg/L0.0017440-41-7
<0.0001Cadmium <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017440-43-9
0.006Cobalt 0.072 0.011 0.151 0.005mg/L0.0017440-48-4
<0.001Chromium 0.001 <0.001 <0.001 <0.001mg/L0.0017440-47-3
<0.001Copper 0.004 0.001 0.002 0.006mg/L0.0017440-50-8
0.732Manganese 0.100 1.42 0.492 0.113mg/L0.0017439-96-5
0.003Nickel 0.020 0.015 0.032 0.014mg/L0.0017440-02-0
<0.001Lead <0.001 <0.001 <0.001 <0.001mg/L0.0017439-92-1
<0.01Selenium <0.01 <0.01 <0.01 <0.01mg/L0.017782-49-2
<0.01Vanadium <0.01 <0.01 <0.01 <0.01mg/L0.017440-62-2
0.011Zinc 0.156 0.158 0.096 0.080mg/L0.0057440-66-6
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ISI57700:Project
JACOBS GROUP (AUSTRALIA) PTY LTD
Analytical Results
GW05GW07GW06GW20GW14Client sample IDSub-Matrix: WATER
(Matrix: WATER)
02-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:00Client sampling date / time
EM1702389-005EM1702389-004EM1702389-003EM1702389-002EM1702389-001UnitLORCAS NumberCompound
Result Result Result Result Result
EG020T: Total Metals by ICP-MS
0.018Arsenic 0.002 0.005 0.021 0.003mg/L0.0017440-38-2
<0.05Boron <0.05 <0.05 2.18 0.08mg/L0.057440-42-8
1.18Barium 0.123 0.335 1.08 0.108mg/L0.0017440-39-3
0.004Beryllium 0.001 <0.001 0.004 <0.001mg/L0.0017440-41-7
<0.0001Cadmium <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017440-43-9
0.071Cobalt 0.081 0.018 0.200 0.006mg/L0.0017440-48-4
0.053Chromium 0.006 0.017 0.086 0.003mg/L0.0017440-47-3
0.055Copper 0.006 0.014 0.034 0.005mg/L0.0017440-50-8
1.10Manganese 0.111 1.40 0.531 0.122mg/L0.0017439-96-5
0.038Nickel 0.023 0.024 0.058 0.013mg/L0.0017440-02-0
0.077Lead 0.005 0.013 0.071 0.002mg/L0.0017439-92-1
0.01Selenium <0.01 <0.01 0.01 <0.01mg/L0.017782-49-2
0.23Vanadium 0.02 0.05 0.18 <0.01mg/L0.017440-62-2
0.153Zinc 0.162 0.222 0.213 0.079mg/L0.0057440-66-6
EG035F: Dissolved Mercury by FIMS
<0.0001Mercury <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017439-97-6
EG035T: Total Recoverable Mercury by FIMS
<0.0001Mercury <0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017439-97-6
EG050F: Dissolved Hexavalent Chromium
<0.01Hexavalent Chromium <0.01 <0.01 <0.01 <0.01mg/L0.0118540-29-9
EK040P: Fluoride by PC Titrator
0.7Fluoride 0.2 0.3 0.2 0.3mg/L0.116984-48-8
EK055G: Ammonia as N by Discrete Analyser
0.12Ammonia as N 0.03 0.31 0.12 0.12mg/L0.017664-41-7
EK071G: Reactive Phosphorus as P by discrete analyser
<0.01Reactive Phosphorus as P <0.01 <0.01 0.02 0.07mg/L0.0114265-44-2
EN055: Ionic Balance
78.1 100 103 122 111meq/L0.01----Total Anions
75.3 94.1 94.6 118 105meq/L0.01----Total Cations
1.78 3.30 4.37 1.76 2.61%0.01----Ionic Balance
EP005: Total Organic Carbon (TOC)
5 6 8 29 4mg/L1----Total Organic Carbon
EP074A: Monocyclic Aromatic Hydrocarbons
<5Styrene <5 <5 <5 <5µg/L5100-42-5
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ISI57700:Project
JACOBS GROUP (AUSTRALIA) PTY LTD
Analytical Results
GW05GW07GW06GW20GW14Client sample IDSub-Matrix: WATER
(Matrix: WATER)
02-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:00Client sampling date / time
EM1702389-005EM1702389-004EM1702389-003EM1702389-002EM1702389-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP074A: Monocyclic Aromatic Hydrocarbons - Continued
<5Isopropylbenzene <5 <5 <5 <5µg/L598-82-8
<5n-Propylbenzene <5 <5 <5 <5µg/L5103-65-1
<51.3.5-Trimethylbenzene <5 <5 <5 <5µg/L5108-67-8
<5sec-Butylbenzene <5 <5 <5 <5µg/L5135-98-8
<51.2.4-Trimethylbenzene <5 <5 <5 <5µg/L595-63-6
<5tert-Butylbenzene <5 <5 <5 <5µg/L598-06-6
<5p-Isopropyltoluene <5 <5 <5 <5µg/L599-87-6
<5n-Butylbenzene <5 <5 <5 <5µg/L5104-51-8
EP074B: Oxygenated Compounds
<50Vinyl Acetate <50 <50 <50 <50µg/L50108-05-4
<502-Butanone (MEK) <50 <50 <50 <50µg/L5078-93-3
<504-Methyl-2-pentanone (MIBK) <50 <50 <50 <50µg/L50108-10-1
<502-Hexanone (MBK) <50 <50 <50 <50µg/L50591-78-6
EP074C: Sulfonated Compounds
<5Carbon disulfide <5 <5 <5 <5µg/L575-15-0
EP074D: Fumigants
<52.2-Dichloropropane <5 <5 <5 <5µg/L5594-20-7
<51.2-Dichloropropane <5 <5 <5 <5µg/L578-87-5
<5cis-1.3-Dichloropropylene <5 <5 <5 <5µg/L510061-01-5
<5trans-1.3-Dichloropropylene <5 <5 <5 <5µg/L510061-02-6
<51.2-Dibromoethane (EDB) <5 <5 <5 <5µg/L5106-93-4
EP074E: Halogenated Aliphatic Compounds
<50Dichlorodifluoromethane <50 <50 <50 <50µg/L5075-71-8
<50Chloromethane <50 <50 <50 <50µg/L5074-87-3
<50Vinyl chloride <50 <50 <50 <50µg/L5075-01-4
<50Bromomethane <50 <50 <50 <50µg/L5074-83-9
<50Chloroethane <50 <50 <50 <50µg/L5075-00-3
<50Trichlorofluoromethane <50 <50 <50 <50µg/L5075-69-4
<51.1-Dichloroethene <5 <5 <5 <5µg/L575-35-4
<5Iodomethane <5 <5 <5 <5µg/L574-88-4
<5Methylene chloride <5 <5 <5 <5µg/L575-09-2
<5trans-1.2-Dichloroethene <5 <5 <5 <5µg/L5156-60-5
<51.1-Dichloroethane <5 <5 <5 <5µg/L575-34-3
<5cis-1.2-Dichloroethene <5 <5 <5 <5µg/L5156-59-2
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JACOBS GROUP (AUSTRALIA) PTY LTD
Analytical Results
GW05GW07GW06GW20GW14Client sample IDSub-Matrix: WATER
(Matrix: WATER)
02-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:00Client sampling date / time
EM1702389-005EM1702389-004EM1702389-003EM1702389-002EM1702389-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP074E: Halogenated Aliphatic Compounds - Continued
<51.1.1-Trichloroethane <5 <5 <5 <5µg/L571-55-6
<51.1-Dichloropropylene <5 <5 <5 <5µg/L5563-58-6
<5Carbon Tetrachloride <5 <5 <5 <5µg/L556-23-5
<51.2-Dichloroethane <5 <5 <5 <5µg/L5107-06-2
<5Trichloroethene <5 <5 <5 <5µg/L579-01-6
<5Dibromomethane <5 <5 <5 <5µg/L574-95-3
<51.1.2-Trichloroethane <5 <5 <5 <5µg/L579-00-5
<51.3-Dichloropropane <5 <5 <5 <5µg/L5142-28-9
<5Tetrachloroethene <5 <5 <5 <5µg/L5127-18-4
<51.1.1.2-Tetrachloroethane <5 <5 <5 <5µg/L5630-20-6
<5trans-1.4-Dichloro-2-butene <5 <5 <5 <5µg/L5110-57-6
<5cis-1.4-Dichloro-2-butene <5 <5 <5 <5µg/L51476-11-5
<51.1.2.2-Tetrachloroethane <5 <5 <5 <5µg/L579-34-5
<51.2.3-Trichloropropane <5 <5 <5 <5µg/L596-18-4
<5Pentachloroethane <5 <5 <5 <5µg/L576-01-7
<51.2-Dibromo-3-chloropropane <5 <5 <5 <5µg/L596-12-8
<5Hexachlorobutadiene <5 <5 <5 <5µg/L587-68-3
EP074F: Halogenated Aromatic Compounds
<5Chlorobenzene <5 <5 <5 <5µg/L5108-90-7
<5Bromobenzene <5 <5 <5 <5µg/L5108-86-1
<52-Chlorotoluene <5 <5 <5 <5µg/L595-49-8
<54-Chlorotoluene <5 <5 <5 <5µg/L5106-43-4
<51.3-Dichlorobenzene <5 <5 <5 <5µg/L5541-73-1
<51.4-Dichlorobenzene <5 <5 <5 <5µg/L5106-46-7
<51.2-Dichlorobenzene <5 <5 <5 <5µg/L595-50-1
<51.2.4-Trichlorobenzene <5 <5 <5 <5µg/L5120-82-1
<51.2.3-Trichlorobenzene <5 <5 <5 <5µg/L587-61-6
EP074G: Trihalomethanes
<5Chloroform <5 <5 <5 8µg/L567-66-3
<5Bromodichloromethane <5 <5 <5 <5µg/L575-27-4
<5Dibromochloromethane <5 <5 <5 <5µg/L5124-48-1
<5Bromoform <5 <5 <5 <5µg/L575-25-2
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
<1.0Naphthalene <1.0 <1.0 <1.0 <1.0µg/L191-20-3
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Analytical Results
GW05GW07GW06GW20GW14Client sample IDSub-Matrix: WATER
(Matrix: WATER)
02-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:00Client sampling date / time
EM1702389-005EM1702389-004EM1702389-003EM1702389-002EM1702389-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued
<1.0Acenaphthylene <1.0 <1.0 <1.0 <1.0µg/L1208-96-8
<1.0Acenaphthene <1.0 <1.0 <1.0 <1.0µg/L183-32-9
<1.0Fluorene <1.0 <1.0 <1.0 <1.0µg/L186-73-7
<1.0Phenanthrene <1.0 <1.0 <1.0 <1.0µg/L185-01-8
<1.0Anthracene <1.0 <1.0 <1.0 <1.0µg/L1120-12-7
<1.0Fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1206-44-0
<1.0Pyrene <1.0 <1.0 <1.0 <1.0µg/L1129-00-0
<1.0Benz(a)anthracene <1.0 <1.0 <1.0 <1.0µg/L156-55-3
<1.0Chrysene <1.0 <1.0 <1.0 <1.0µg/L1218-01-9
<1.0Benzo(b+j)fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1205-99-2 205-82-3
<1.0Benzo(k)fluoranthene <1.0 <1.0 <1.0 <1.0µg/L1207-08-9
<0.5Benzo(a)pyrene <0.5 <0.5 <0.5 <0.5µg/L0.550-32-8
<1.0Indeno(1.2.3.cd)pyrene <1.0 <1.0 <1.0 <1.0µg/L1193-39-5
<1.0Dibenz(a.h)anthracene <1.0 <1.0 <1.0 <1.0µg/L153-70-3
<1.0Benzo(g.h.i)perylene <1.0 <1.0 <1.0 <1.0µg/L1191-24-2
<0.5^ <0.5 <0.5 <0.5 <0.5µg/L0.5----Sum of polycyclic aromatic hydrocarbons
<0.5^ <0.5 <0.5 <0.5 <0.5µg/L0.5----Benzo(a)pyrene TEQ (zero)
EP080/071: Total Petroleum Hydrocarbons
<20 <20 <20 <20 <20µg/L20----C6 - C9 Fraction
<50 <50 <50 <50 <50µg/L50----C10 - C14 Fraction
<100 <100 <100 <100 <100µg/L100----C15 - C28 Fraction
<50 <50 <50 <50 <50µg/L50----C29 - C36 Fraction
<50^ <50 <50 <50 <50µg/L50----C10 - C36 Fraction (sum)
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
<20C6 - C10 Fraction <20 <20 <20 <20µg/L20C6_C10
<20^ C6 - C10 Fraction minus BTEX
(F1)
<20 <20 <20 <20µg/L20C6_C10-BTEX
<100 <100 <100 <100 <100µg/L100---->C10 - C16 Fraction
<100 <100 <100 <100 <100µg/L100---->C16 - C34 Fraction
<100 <100 <100 <100 <100µg/L100---->C34 - C40 Fraction
<100^ <100 <100 <100 <100µg/L100---->C10 - C40 Fraction (sum)
<100^ <100 <100 <100 <100µg/L100---->C10 - C16 Fraction minus Naphthalene
(F2)
EP080: BTEXN
<1Benzene <1 <1 <1 <1µg/L171-43-2
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Analytical Results
GW05GW07GW06GW20GW14Client sample IDSub-Matrix: WATER
(Matrix: WATER)
02-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:00Client sampling date / time
EM1702389-005EM1702389-004EM1702389-003EM1702389-002EM1702389-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP080: BTEXN - Continued
<2Toluene <2 <2 <2 <2µg/L2108-88-3
<2Ethylbenzene <2 <2 <2 <2µg/L2100-41-4
<2meta- & para-Xylene <2 <2 <2 <2µg/L2108-38-3 106-42-3
<2ortho-Xylene <2 <2 <2 <2µg/L295-47-6
<2^ Total Xylenes <2 <2 <2 <2µg/L21330-20-7
<1^ <1 <1 <1 <1µg/L1----Sum of BTEX
<5Naphthalene <5 <5 <5 <5µg/L591-20-3
EP231A: Perfluoroalkyl Sulfonic Acids
<0.02Perfluorobutane sulfonic acid
(PFBS)
<0.02 <0.02 <0.02 <0.02µg/L0.02375-73-5
<0.02Perfluoropentane sulfonic acid
(PFPeS)
<0.02 <0.02 <0.02 <0.02µg/L0.022706-91-4
<0.02Perfluorohexane sulfonic acid
(PFHxS)
<0.02 <0.02 0.02 <0.02µg/L0.02355-46-4
<0.02Perfluoroheptane sulfonic acid
(PFHpS)
<0.02 <0.02 <0.02 <0.02µg/L0.02375-92-8
<0.01Perfluorooctane sulfonic acid
(PFOS)
<0.01 <0.01 <0.01 <0.01µg/L0.011763-23-1
<0.02Perfluorodecane sulfonic acid
(PFDS)
<0.02 <0.02 <0.02 <0.02µg/L0.02335-77-3
EP231B: Perfluoroalkyl Carboxylic Acids
<0.1Perfluorobutanoic acid (PFBA) <0.1 <0.1 <0.1 <0.1µg/L0.1375-22-4
<0.02Perfluoropentanoic acid (PFPeA) <0.02 <0.02 0.02 <0.02µg/L0.022706-90-3
<0.02Perfluorohexanoic acid (PFHxA) <0.02 <0.02 <0.02 <0.02µg/L0.02307-24-4
<0.02Perfluoroheptanoic acid (PFHpA) <0.02 <0.02 <0.02 <0.02µg/L0.02375-85-9
<0.01Perfluorooctanoic acid (PFOA) <0.01 <0.01 <0.01 <0.01µg/L0.01335-67-1
<0.02Perfluorononanoic acid (PFNA) <0.02 <0.02 <0.02 <0.02µg/L0.02375-95-1
<0.02Perfluorodecanoic acid (PFDA) <0.02 <0.02 <0.02 <0.02µg/L0.02335-76-2
<0.02Perfluoroundecanoic acid
(PFUnDA)
<0.02 <0.02 <0.02 <0.02µg/L0.022058-94-8
<0.02Perfluorododecanoic acid
(PFDoDA)
<0.02 <0.02 <0.02 <0.02µg/L0.02307-55-1
<0.02Perfluorotridecanoic acid
(PFTrDA)
<0.02 <0.02 <0.02 <0.02µg/L0.0272629-94-8
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Analytical Results
GW05GW07GW06GW20GW14Client sample IDSub-Matrix: WATER
(Matrix: WATER)
02-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:00Client sampling date / time
EM1702389-005EM1702389-004EM1702389-003EM1702389-002EM1702389-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP231B: Perfluoroalkyl Carboxylic Acids - Continued
<0.05Perfluorotetradecanoic acid
(PFTeDA)
<0.05 <0.05 <0.05 <0.05µg/L0.05376-06-7
EP231C: Perfluoroalkyl Sulfonamides
<0.02Perfluorooctane sulfonamide
(FOSA)
<0.02 <0.02 <0.02 <0.02µg/L0.02754-91-6
<0.05N-Methyl perfluorooctane
sulfonamide (MeFOSA)
<0.05 <0.05 <0.05 <0.05µg/L0.0531506-32-8
<0.05N-Ethyl perfluorooctane
sulfonamide (EtFOSA)
<0.05 <0.05 <0.05 <0.05µg/L0.054151-50-2
<0.05N-Methyl perfluorooctane
sulfonamidoethanol (MeFOSE)
<0.05 <0.05 <0.05 <0.05µg/L0.052448-09-7
<0.05N-Ethyl perfluorooctane
sulfonamidoethanol (EtFOSE)
<0.05 <0.05 <0.05 <0.05µg/L0.051691-99-2
<0.02N-Methyl perfluorooctane
sulfonamidoacetic acid
(MeFOSAA)
<0.02 <0.02 <0.02 <0.02µg/L0.022355-31-9
<0.02N-Ethyl perfluorooctane
sulfonamidoacetic acid
(EtFOSAA)
<0.02 <0.02 <0.02 <0.02µg/L0.022991-50-6
EP231D: (n:2) Fluorotelomer Sulfonic Acids
<0.054:2 Fluorotelomer sulfonic acid
(4:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.05757124-72-4
<0.056:2 Fluorotelomer sulfonic acid
(6:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.0527619-97-2
<0.058:2 Fluorotelomer sulfonic acid
(8:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.0539108-34-4
<0.0510:2 Fluorotelomer sulfonic acid
(10:2 FTS)
<0.05 <0.05 <0.05 <0.05µg/L0.05120226-60-0
EP231P: PFAS Sums
<0.01 <0.01 <0.01 0.04 <0.01µg/L0.01----Sum of PFAS
<0.01Sum of PFHxS and PFOS <0.01 <0.01 0.02 <0.01µg/L0.01355-46-4/1763-23-
1
<0.01 <0.01 <0.01 0.04 <0.01µg/L0.01----Sum of PFAS (WA DER List)
EP074S: VOC Surrogates
1061.2-Dichloroethane-D4 116 113 118 98.1%517060-07-0
108Toluene-D8 117 118 117 100%52037-26-5
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Analytical Results
GW05GW07GW06GW20GW14Client sample IDSub-Matrix: WATER
(Matrix: WATER)
02-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:0002-Mar-2017 00:00Client sampling date / time
EM1702389-005EM1702389-004EM1702389-003EM1702389-002EM1702389-001UnitLORCAS NumberCompound
Result Result Result Result Result
EP074S: VOC Surrogates - Continued
1064-Bromofluorobenzene 116 114 119 104%5460-00-4
EP075(SIM)S: Phenolic Compound Surrogates
24.6Phenol-d6 25.3 23.6 26.0 26.6%113127-88-3
54.02-Chlorophenol-D4 55.6 52.9 60.1 60.4%193951-73-6
57.22.4.6-Tribromophenol 57.1 53.9 62.7 60.5%1118-79-6
EP075(SIM)T: PAH Surrogates
83.72-Fluorobiphenyl 74.8 68.1 80.6 85.5%1321-60-8
79.2Anthracene-d10 76.4 68.3 84.8 90.6%11719-06-8
74.24-Terphenyl-d14 71.4 62.9 80.6 90.2%11718-51-0
EP080S: TPH(V)/BTEX Surrogates
99.01.2-Dichloroethane-D4 107 106 112 107%217060-07-0
100Toluene-D8 106 108 116 109%22037-26-5
1104-Bromofluorobenzene 112 111 116 114%2460-00-4
EP231S: PFAS Surrogate
73.9 83.1 84.0 76.0 84.1%0.02----13C4-PFOS
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Analytical Results
------------RB_004TB_004Client sample IDSub-Matrix: WATER
(Matrix: WATER)
------------03-Mar-2017 00:0002-Mar-2017 00:00Client sampling date / time
------------------------EM1702389-007EM1702389-006UnitLORCAS NumberCompound
Result Result ---- ---- ----
EG020T: Total Metals by ICP-MS
----Arsenic <0.001 ---- ---- ----mg/L0.0017440-38-2
----Cadmium <0.0001 ---- ---- ----mg/L0.00017440-43-9
----Chromium <0.001 ---- ---- ----mg/L0.0017440-47-3
----Copper <0.001 ---- ---- ----mg/L0.0017440-50-8
----Nickel <0.001 ---- ---- ----mg/L0.0017440-02-0
----Lead <0.001 ---- ---- ----mg/L0.0017439-92-1
----Zinc <0.005 ---- ---- ----mg/L0.0057440-66-6
EG035T: Total Recoverable Mercury by FIMS
----Mercury <0.0001 ---- ---- ----mg/L0.00017439-97-6
EP080/071: Total Petroleum Hydrocarbons
<20 ---- ---- ---- ----µg/L20----C6 - C9 Fraction
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
<20C6 - C10 Fraction ---- ---- ---- ----µg/L20C6_C10
<20^ C6 - C10 Fraction minus BTEX
(F1)
---- ---- ---- ----µg/L20C6_C10-BTEX
EP080: BTEXN
<1Benzene ---- ---- ---- ----µg/L171-43-2
<2Toluene ---- ---- ---- ----µg/L2108-88-3
<2Ethylbenzene ---- ---- ---- ----µg/L2100-41-4
<2meta- & para-Xylene ---- ---- ---- ----µg/L2108-38-3 106-42-3
<2ortho-Xylene ---- ---- ---- ----µg/L295-47-6
<2^ Total Xylenes ---- ---- ---- ----µg/L21330-20-7
<1^ ---- ---- ---- ----µg/L1----Sum of BTEX
<5Naphthalene ---- ---- ---- ----µg/L591-20-3
EP080S: TPH(V)/BTEX Surrogates
96.51.2-Dichloroethane-D4 ---- ---- ---- ----%217060-07-0
100Toluene-D8 ---- ---- ---- ----%22037-26-5
1044-Bromofluorobenzene ---- ---- ---- ----%2460-00-4
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Surrogate Control Limits
Recovery Limits (%)Sub-Matrix: WATER
Compound CAS Number Low High
EP074S: VOC Surrogates
1.2-Dichloroethane-D4 17060-07-0 72 132
Toluene-D8 2037-26-5 77 132
4-Bromofluorobenzene 460-00-4 67 131
EP075(SIM)S: Phenolic Compound Surrogates
Phenol-d6 13127-88-3 10 46
2-Chlorophenol-D4 93951-73-6 23 104
2.4.6-Tribromophenol 118-79-6 28 130
EP075(SIM)T: PAH Surrogates
2-Fluorobiphenyl 321-60-8 36 114
Anthracene-d10 1719-06-8 51 119
4-Terphenyl-d14 1718-51-0 49 127
EP080S: TPH(V)/BTEX Surrogates
1.2-Dichloroethane-D4 17060-07-0 73 129
Toluene-D8 2037-26-5 70 125
4-Bromofluorobenzene 460-00-4 71 129
EP231S: PFAS Surrogate
13C4-PFOS ---- 60 130
False
4 4.00True
Environmental
QUALITY CONTROL REPORTWork Order : EM1702389 Page : 1 of 19
:: LaboratoryClient Environmental Division MelbourneJACOBS GROUP (AUSTRALIA) PTY LTD
:Contact MR BENJAMIN GRASSO :Contact Carol Walsh
:Address P O BOX 312 FLINDERS LANE
MELBOURNE VIC AUSTRALIA 8009
Address : 4 Westall Rd Springvale VIC Australia 3171
::Telephone +61 03 8668 3000 +61-3-8549 9608:Telephone
:Project ISI57700 Date Samples Received : 03-Mar-2017
:Order number ---- Date Analysis Commenced : 03-Mar-2017
:C-O-C number ---- Issue Date : 09-Mar-2017
Sampler : BEN GRASSO
Site : EBAC GME
Quote number : ME/088/17
No. of samples received 7:
No. of samples analysed 7:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limits
l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits
l Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Chris Lemaitre Non-Metals Team Leader Melbourne Inorganics, Springvale, VIC
Dilani Fernando Senior Inorganic Chemist Melbourne Inorganics, Springvale, VIC
Lana Nguyen Senior LCMS Chemist Sydney Organics, Smithfield, NSW
Nancy Wang Senior Semivolatile Instrument Chemist Melbourne Organics, Springvale, VIC
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
RPD = Relative Percentage Difference
# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) Report
The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges
for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:
No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EA005P: pH by PC Titrator (QC Lot: 779010)
EA005-P: pH Value ---- 0.01 pH Unit 6.73 6.60 1.95 0% - 20%Anonymous EM1702345-005
EA005-P: pH Value ---- 0.01 pH Unit 7.80 7.77 0.385 0% - 20%Anonymous EM1702381-002
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QC Lot: 778712)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 442 424 4.27 0% - 20%Anonymous EM1702345-005
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 574 564 1.93 0% - 20%Anonymous EM1702383-001
EA025: Total Suspended Solids dried at 104 ± 2°C (QC Lot: 778710)
EA025H: Suspended Solids (SS) ---- 5 mg/L 1720 1790 4.11 0% - 20%Anonymous EM1702306-001
EA025H: Suspended Solids (SS) ---- 5 mg/L 2190 2130 3.14 0% - 20%Anonymous EM1702312-002
EA025: Total Suspended Solids dried at 104 ± 2°C (QC Lot: 778713)
EA025H: Suspended Solids (SS) ---- 5 mg/L 455 438 3.70 0% - 20%GW20 EM1702389-002
ED037P: Alkalinity by PC Titrator (QC Lot: 779009)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EM1702342-011
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 971 971 0.00 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 971 971 0.00 0% - 20%
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous EM1702345-005
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 214 216 0.962 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 214 216 0.962 0% - 20%
ED037P: Alkalinity by PC Titrator (QC Lot: 779012)
ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitGW06 EM1702389-003
ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit
ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 424 424 0.00 0% - 20%
ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 424 424 0.00 0% - 20%
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QC Lot: 777656)
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 112 113 0.00 0% - 20%Anonymous EM1702375-007
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 745 741 0.566 0% - 20%Anonymous EM1702345-001
ED045G: Chloride by Discrete Analyser (QC Lot: 777655)
ED045G: Chloride 16887-00-6 1 mg/L 3350 3400 1.24 0% - 20%GW20 EM1702389-002
ED045G: Chloride 16887-00-6 1 mg/L 1000 1000 0.00 0% - 20%Anonymous EM1702345-001
ED093F: Dissolved Major Cations (QC Lot: 778640)
ED093F: Calcium 7440-70-2 1 mg/L 27 27 0.00 0% - 20%Anonymous EM1702345-002
ED093F: Magnesium 7439-95-4 1 mg/L 9 8 0.00 No Limit
ED093F: Sodium 7440-23-5 1 mg/L 58 57 0.00 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 6 6 0.00 No Limit
ED093F: Calcium 7440-70-2 1 mg/L 40 40 0.00 0% - 20%GW20 EM1702389-002
ED093F: Magnesium 7439-95-4 1 mg/L 172 174 1.23 0% - 20%
ED093F: Sodium 7440-23-5 1 mg/L 1790 1820 1.63 0% - 20%
ED093F: Potassium 7440-09-7 1 mg/L 4 4 0.00 No Limit
EG020F: Dissolved Metals by ICP-MS (QC Lot: 778638)
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702345-001
EG020A-F: Arsenic 7440-38-2 0.001 mg/L 0.095 0.093 2.08 0% - 20%
EG020A-F: Beryllium 7440-41-7 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Barium 7440-39-3 0.001 mg/L 0.121 0.117 3.01 0% - 20%
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Cobalt 7440-48-4 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.059 0.059 0.00 0% - 20%
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.019 0.019 0.00 0% - 50%
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 <0.005 0.00 No Limit
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Vanadium 7440-62-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-F: Boron 7440-42-8 0.05 mg/L 2.91 2.76 5.55 0% - 20%
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L 0.0002 0.0002 0.00 No LimitAnonymous EM1702362-003
EG020A-F: Arsenic 7440-38-2 0.001 mg/L 1.00 0.982 2.28 0% - 20%
EG020A-F: Beryllium 7440-41-7 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-F: Barium 7440-39-3 0.001 mg/L 0.490 0.476 2.79 0% - 20%
EG020A-F: Chromium 7440-47-3 0.001 mg/L 0.077 0.075 2.02 0% - 20%
EG020A-F: Cobalt 7440-48-4 0.001 mg/L 0.046 0.045 0.00 0% - 20%
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.073 0.071 2.70 0% - 20%
EG020A-F: Lead 7439-92-1 0.001 mg/L 0.020 0.020 0.00 0% - 20%
EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.772 0.758 1.78 0% - 20%
EG020A-F: Nickel 7440-02-0 0.001 mg/L 0.274 0.268 2.36 0% - 20%
EG020A-F: Zinc 7440-66-6 0.005 mg/L 0.517 0.500 3.29 0% - 20%
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EG020F: Dissolved Metals by ICP-MS (QC Lot: 778638) - continued
EG020A-F: Selenium 7782-49-2 0.01 mg/L 0.02 0.01 0.00 No LimitAnonymous EM1702362-003
EG020A-F: Vanadium 7440-62-2 0.01 mg/L 0.42 0.42 0.00 0% - 20%
EG020A-F: Boron 7440-42-8 0.05 mg/L 0.18 0.19 0.00 No Limit
EG020T: Total Metals by ICP-MS (QC Lot: 778609)
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L 0.0002 0.0002 0.00 No LimitAnonymous EM1702315-002
EG020A-T: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Beryllium 7440-41-7 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Barium 7440-39-3 0.001 mg/L 0.005 0.005 0.00 No Limit
EG020A-T: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Cobalt 7440-48-4 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Copper 7440-50-8 0.001 mg/L 0.009 0.009 0.00 No Limit
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Manganese 7439-96-5 0.001 mg/L 0.025 0.027 5.15 0% - 20%
EG020A-T: Nickel 7440-02-0 0.001 mg/L 0.005 0.006 24.7 No Limit
EG020A-T: Zinc 7440-66-6 0.005 mg/L 0.082 0.085 3.12 0% - 50%
EG020A-T: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-T: Vanadium 7440-62-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-T: Boron 7440-42-8 0.05 mg/L 0.20 0.22 8.51 No Limit
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L 0.0039 0.0040 2.62 0% - 20%Anonymous EM1702335-002
EG020A-T: Arsenic 7440-38-2 0.001 mg/L 0.004 0.004 0.00 No Limit
EG020A-T: Beryllium 7440-41-7 0.001 mg/L 0.009 0.012 24.3 0% - 50%
EG020A-T: Barium 7440-39-3 0.001 mg/L 0.266 0.264 0.536 0% - 20%
EG020A-T: Chromium 7440-47-3 0.001 mg/L 0.016 0.017 0.00 0% - 50%
EG020A-T: Cobalt 7440-48-4 0.001 mg/L 0.024 0.024 0.00 0% - 20%
EG020A-T: Copper 7440-50-8 0.001 mg/L 0.011 0.011 0.00 0% - 50%
EG020A-T: Lead 7439-92-1 0.001 mg/L 0.024 0.024 0.00 0% - 20%
EG020A-T: Manganese 7439-96-5 0.001 mg/L 2.34 2.41 2.63 0% - 20%
EG020A-T: Nickel 7440-02-0 0.001 mg/L 0.462 0.449 2.72 0% - 20%
EG020A-T: Zinc 7440-66-6 0.005 mg/L 1.03 1.05 1.66 0% - 20%
EG020A-T: Selenium 7782-49-2 0.01 mg/L 0.03 0.03 0.00 No Limit
EG020A-T: Vanadium 7440-62-2 0.01 mg/L 0.02 0.02 0.00 No Limit
EG020A-T: Boron 7440-42-8 0.05 mg/L <0.05 <0.05 0.00 No Limit
EG020T: Total Metals by ICP-MS (QC Lot: 778610)
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitGW05 EM1702389-005
EG020A-T: Arsenic 7440-38-2 0.001 mg/L 0.003 0.003 0.00 No Limit
EG020A-T: Beryllium 7440-41-7 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Barium 7440-39-3 0.001 mg/L 0.108 0.106 1.93 0% - 20%
EG020A-T: Chromium 7440-47-3 0.001 mg/L 0.003 0.003 0.00 No Limit
EG020A-T: Cobalt 7440-48-4 0.001 mg/L 0.006 0.006 0.00 No Limit
EG020A-T: Copper 7440-50-8 0.001 mg/L 0.005 0.005 0.00 No Limit
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Work Order :
:Client
EM1702389
JACOBS GROUP (AUSTRALIA) PTY LTD
ISI57700:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EG020T: Total Metals by ICP-MS (QC Lot: 778610) - continued
EG020A-T: Lead 7439-92-1 0.001 mg/L 0.002 0.002 0.00 No LimitGW05 EM1702389-005
EG020A-T: Manganese 7439-96-5 0.001 mg/L 0.122 0.121 0.921 0% - 20%
EG020A-T: Nickel 7440-02-0 0.001 mg/L 0.013 0.012 8.48 0% - 50%
EG020A-T: Zinc 7440-66-6 0.005 mg/L 0.079 0.078 0.00 0% - 50%
EG020A-T: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-T: Vanadium 7440-62-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-T: Boron 7440-42-8 0.05 mg/L 0.08 0.08 0.00 No Limit
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702424-002
EG020A-T: Arsenic 7440-38-2 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Beryllium 7440-41-7 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Barium 7440-39-3 0.001 mg/L 0.006 0.006 0.00 No Limit
EG020A-T: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Cobalt 7440-48-4 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Manganese 7439-96-5 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.00 No Limit
EG020A-T: Zinc 7440-66-6 0.005 mg/L <0.005 <0.005 0.00 No Limit
EG020A-T: Selenium 7782-49-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-T: Vanadium 7440-62-2 0.01 mg/L <0.01 <0.01 0.00 No Limit
EG020A-T: Boron 7440-42-8 0.05 mg/L <0.05 <0.05 0.00 No Limit
EG035F: Dissolved Mercury by FIMS (QC Lot: 778639)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702345-001
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702362-003
EG035T: Total Recoverable Mercury by FIMS (QC Lot: 778485)
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitAnonymous EM1702313-012
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 <0.0001 0.00 No LimitGW07 EM1702389-004
EG050F: Dissolved Hexavalent Chromium (QC Lot: 778879)
EG050F: Hexavalent Chromium 18540-29-9 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EM1702345-001
EG050F: Hexavalent Chromium 18540-29-9 0.01 mg/L <0.01 <0.01 0.00 No LimitGW14 EM1702389-001
EK040P: Fluoride by PC Titrator (QC Lot: 779007)
EK040P: Fluoride 16984-48-8 0.1 mg/L 0.1 0.1 0.00 No LimitAnonymous EM1702345-005
EK040P: Fluoride 16984-48-8 0.1 mg/L 0.9 0.9 0.00 No LimitAnonymous EM1702381-002
EK055G: Ammonia as N by Discrete Analyser (QC Lot: 777445)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 58.5 65.8 11.8 0% - 20%Anonymous EM1702313-012
EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.03 0.03 0.00 No LimitAnonymous EM1702381-004
EK071G: Reactive Phosphorus as P by discrete analyser (QC Lot: 777657)
EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L <0.01 <0.01 0.00 No LimitGW14 EM1702389-001
EP005: Total Organic Carbon (TOC) (QC Lot: 779015)
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:Client
EM1702389
JACOBS GROUP (AUSTRALIA) PTY LTD
ISI57700:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP005: Total Organic Carbon (TOC) (QC Lot: 779015) - continued
EP005: Total Organic Carbon ---- 1 mg/L 28 30 8.24 0% - 20%Anonymous EM1702342-006
EP005: Total Organic Carbon ---- 1 mg/L 7 7 0.00 No LimitAnonymous EM1702381-004
EP074A: Monocyclic Aromatic Hydrocarbons (QC Lot: 778468)
EP074: Styrene 100-42-5 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702345-001
EP074: Isopropylbenzene 98-82-8 5 µg/L <5 <5 0.00 No Limit
EP074: n-Propylbenzene 103-65-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3.5-Trimethylbenzene 108-67-8 5 µg/L <5 <5 0.00 No Limit
EP074: sec-Butylbenzene 135-98-8 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trimethylbenzene 95-63-6 5 µg/L <5 <5 0.00 No Limit
EP074: tert-Butylbenzene 98-06-6 5 µg/L <5 <5 0.00 No Limit
EP074: p-Isopropyltoluene 99-87-6 5 µg/L <5 <5 0.00 No Limit
EP074: n-Butylbenzene 104-51-8 5 µg/L <5 <5 0.00 No Limit
EP074: Styrene 100-42-5 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702383-001
EP074: Isopropylbenzene 98-82-8 5 µg/L <5 <5 0.00 No Limit
EP074: n-Propylbenzene 103-65-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3.5-Trimethylbenzene 108-67-8 5 µg/L <5 <5 0.00 No Limit
EP074: sec-Butylbenzene 135-98-8 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trimethylbenzene 95-63-6 5 µg/L <5 <5 0.00 No Limit
EP074: tert-Butylbenzene 98-06-6 5 µg/L <5 <5 0.00 No Limit
EP074: p-Isopropyltoluene 99-87-6 5 µg/L <5 <5 0.00 No Limit
EP074: n-Butylbenzene 104-51-8 5 µg/L <5 <5 0.00 No Limit
EP074B: Oxygenated Compounds (QC Lot: 778468)
EP074: Vinyl Acetate 108-05-4 50 µg/L <50 <50 0.00 No LimitAnonymous EM1702345-001
EP074: 2-Butanone (MEK) 78-93-3 50 µg/L <50 <50 0.00 No Limit
EP074: 4-Methyl-2-pentanone (MIBK) 108-10-1 50 µg/L <50 <50 0.00 No Limit
EP074: 2-Hexanone (MBK) 591-78-6 50 µg/L <50 <50 0.00 No Limit
EP074: Vinyl Acetate 108-05-4 50 µg/L <50 <50 0.00 No LimitAnonymous EM1702383-001
EP074: 2-Butanone (MEK) 78-93-3 50 µg/L <50 <50 0.00 No Limit
EP074: 4-Methyl-2-pentanone (MIBK) 108-10-1 50 µg/L <50 <50 0.00 No Limit
EP074: 2-Hexanone (MBK) 591-78-6 50 µg/L <50 <50 0.00 No Limit
EP074C: Sulfonated Compounds (QC Lot: 778468)
EP074: Carbon disulfide 75-15-0 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702345-001
EP074: Carbon disulfide 75-15-0 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702383-001
EP074D: Fumigants (QC Lot: 778468)
EP074: 2.2-Dichloropropane 594-20-7 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702345-001
EP074: 1.2-Dichloropropane 78-87-5 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.3-Dichloropropylene 10061-01-5 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.3-Dichloropropylene 10061-02-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromoethane (EDB) 106-93-4 5 µg/L <5 <5 0.00 No Limit
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:Client
EM1702389
JACOBS GROUP (AUSTRALIA) PTY LTD
ISI57700:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP074D: Fumigants (QC Lot: 778468) - continued
EP074: 2.2-Dichloropropane 594-20-7 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702383-001
EP074: 1.2-Dichloropropane 78-87-5 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.3-Dichloropropylene 10061-01-5 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.3-Dichloropropylene 10061-02-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromoethane (EDB) 106-93-4 5 µg/L <5 <5 0.00 No Limit
EP074E: Halogenated Aliphatic Compounds (QC Lot: 778468)
EP074: 1.1-Dichloroethene 75-35-4 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702345-001
EP074: Iodomethane 74-88-4 5 µg/L <5 <5 0.00 No Limit
EP074: Methylene chloride 75-09-2 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.2-Dichloroethene 156-60-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloroethane 75-34-3 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.2-Dichloroethene 156-59-2 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1-Trichloroethane 71-55-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloropropylene 563-58-6 5 µg/L <5 <5 0.00 No Limit
EP074: Carbon Tetrachloride 56-23-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichloroethane 107-06-2 5 µg/L <5 <5 0.00 No Limit
EP074: Trichloroethene 79-01-6 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromomethane 74-95-3 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2-Trichloroethane 79-00-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichloropropane 142-28-9 5 µg/L <5 <5 0.00 No Limit
EP074: Tetrachloroethene 127-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1.2-Tetrachloroethane 630-20-6 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.4-Dichloro-2-butene 110-57-6 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.4-Dichloro-2-butene 1476-11-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2.2-Tetrachloroethane 79-34-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichloropropane 96-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: Pentachloroethane 76-01-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromo-3-chloropropane 96-12-8 5 µg/L <5 <5 0.00 No Limit
EP074: Hexachlorobutadiene 87-68-3 5 µg/L <5 <5 0.00 No Limit
EP074: Dichlorodifluoromethane 75-71-8 50 µg/L <50 <50 0.00 No Limit
EP074: Chloromethane 74-87-3 50 µg/L <50 <50 0.00 No Limit
EP074: Vinyl chloride 75-01-4 50 µg/L <50 <50 0.00 No Limit
EP074: Bromomethane 74-83-9 50 µg/L <50 <50 0.00 No Limit
EP074: Chloroethane 75-00-3 50 µg/L <50 <50 0.00 No Limit
EP074: Trichlorofluoromethane 75-69-4 50 µg/L <50 <50 0.00 No Limit
EP074: 1.1-Dichloroethene 75-35-4 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702383-001
EP074: Iodomethane 74-88-4 5 µg/L <5 <5 0.00 No Limit
EP074: Methylene chloride 75-09-2 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.2-Dichloroethene 156-60-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloroethane 75-34-3 5 µg/L <5 <5 0.00 No Limit
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Work Order :
:Client
EM1702389
JACOBS GROUP (AUSTRALIA) PTY LTD
ISI57700:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP074E: Halogenated Aliphatic Compounds (QC Lot: 778468) - continued
EP074: cis-1.2-Dichloroethene 156-59-2 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702383-001
EP074: 1.1.1-Trichloroethane 71-55-6 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1-Dichloropropylene 563-58-6 5 µg/L <5 <5 0.00 No Limit
EP074: Carbon Tetrachloride 56-23-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichloroethane 107-06-2 5 µg/L <5 <5 0.00 No Limit
EP074: Trichloroethene 79-01-6 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromomethane 74-95-3 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2-Trichloroethane 79-00-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichloropropane 142-28-9 5 µg/L <5 <5 0.00 No Limit
EP074: Tetrachloroethene 127-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.1.2-Tetrachloroethane 630-20-6 5 µg/L <5 <5 0.00 No Limit
EP074: trans-1.4-Dichloro-2-butene 110-57-6 5 µg/L <5 <5 0.00 No Limit
EP074: cis-1.4-Dichloro-2-butene 1476-11-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.1.2.2-Tetrachloroethane 79-34-5 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichloropropane 96-18-4 5 µg/L <5 <5 0.00 No Limit
EP074: Pentachloroethane 76-01-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dibromo-3-chloropropane 96-12-8 5 µg/L <5 <5 0.00 No Limit
EP074: Hexachlorobutadiene 87-68-3 5 µg/L <5 <5 0.00 No Limit
EP074: Dichlorodifluoromethane 75-71-8 50 µg/L <50 <50 0.00 No Limit
EP074: Chloromethane 74-87-3 50 µg/L <50 <50 0.00 No Limit
EP074: Vinyl chloride 75-01-4 50 µg/L <50 <50 0.00 No Limit
EP074: Bromomethane 74-83-9 50 µg/L <50 <50 0.00 No Limit
EP074: Chloroethane 75-00-3 50 µg/L <50 <50 0.00 No Limit
EP074: Trichlorofluoromethane 75-69-4 50 µg/L <50 <50 0.00 No Limit
EP074F: Halogenated Aromatic Compounds (QC Lot: 778468)
EP074: Chlorobenzene 108-90-7 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702345-001
EP074: Bromobenzene 108-86-1 5 µg/L <5 <5 0.00 No Limit
EP074: 2-Chlorotoluene 95-49-8 5 µg/L <5 <5 0.00 No Limit
EP074: 4-Chlorotoluene 106-43-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichlorobenzene 541-73-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.4-Dichlorobenzene 106-46-7 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2-Dichlorobenzene 95-50-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.4-Trichlorobenzene 120-82-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichlorobenzene 87-61-6 5 µg/L <5 <5 0.00 No Limit
EP074: Chlorobenzene 108-90-7 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702383-001
EP074: Bromobenzene 108-86-1 5 µg/L <5 <5 0.00 No Limit
EP074: 2-Chlorotoluene 95-49-8 5 µg/L <5 <5 0.00 No Limit
EP074: 4-Chlorotoluene 106-43-4 5 µg/L <5 <5 0.00 No Limit
EP074: 1.3-Dichlorobenzene 541-73-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.4-Dichlorobenzene 106-46-7 5 µg/L <5 <5 0.00 No Limit
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Work Order :
:Client
EM1702389
JACOBS GROUP (AUSTRALIA) PTY LTD
ISI57700:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP074F: Halogenated Aromatic Compounds (QC Lot: 778468) - continued
EP074: 1.2-Dichlorobenzene 95-50-1 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702383-001
EP074: 1.2.4-Trichlorobenzene 120-82-1 5 µg/L <5 <5 0.00 No Limit
EP074: 1.2.3-Trichlorobenzene 87-61-6 5 µg/L <5 <5 0.00 No Limit
EP074G: Trihalomethanes (QC Lot: 778468)
EP074: Chloroform 67-66-3 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702345-001
EP074: Bromodichloromethane 75-27-4 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromochloromethane 124-48-1 5 µg/L <5 <5 0.00 No Limit
EP074: Bromoform 75-25-2 5 µg/L <5 <5 0.00 No Limit
EP074: Chloroform 67-66-3 5 µg/L <5 <5 0.00 No LimitAnonymous EM1702383-001
EP074: Bromodichloromethane 75-27-4 5 µg/L <5 <5 0.00 No Limit
EP074: Dibromochloromethane 124-48-1 5 µg/L <5 <5 0.00 No Limit
EP074: Bromoform 75-25-2 5 µg/L <5 <5 0.00 No Limit
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 778467)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitAnonymous EM1702345-001
EP080: C6 - C9 Fraction ---- 20 µg/L <20 <20 0.00 No LimitAnonymous EM1702383-001
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QC Lot: 778467)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitAnonymous EM1702345-001
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 <20 0.00 No LimitAnonymous EM1702383-001
EP080: BTEXN (QC Lot: 778467)
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitAnonymous EM1702345-001
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
EP080: Benzene 71-43-2 1 µg/L <1 <1 0.00 No LimitAnonymous EM1702383-001
EP080: Toluene 108-88-3 2 µg/L <2 <2 0.00 No Limit
EP080: Ethylbenzene 100-41-4 2 µg/L <2 <2 0.00 No Limit
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 <2 0.00 No Limit
EP080: ortho-Xylene 95-47-6 2 µg/L <2 <2 0.00 No Limit
EP080: Naphthalene 91-20-3 5 µg/L <5 <5 0.00 No Limit
EP231A: Perfluoroalkyl Sulfonic Acids (QC Lot: 780894)
EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.01 <0.01 0.00 No LimitGW14 EM1702389-001
EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L <0.02 <0.02 0.00 No Limit
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Work Order :
:Client
EM1702389
JACOBS GROUP (AUSTRALIA) PTY LTD
ISI57700:Project
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP231A: Perfluoroalkyl Sulfonic Acids (QC Lot: 780894) - continued
EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L <0.02 <0.02 0.00 No LimitGW14 EM1702389-001
EP231B: Perfluoroalkyl Carboxylic Acids (QC Lot: 780894)
EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 <0.01 0.00 No LimitGW14 EM1702389-001
EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L <0.1 <0.1 0.00 No Limit
EP231C: Perfluoroalkyl Sulfonamides (QC Lot: 780894)
EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 <0.02 0.00 No LimitGW14 EM1702389-001
EP231X: N-Methyl perfluorooctane
sulfonamidoacetic acid (MeFOSAA)
2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: N-Ethyl perfluorooctane
sulfonamidoacetic acid (EtFOSAA)
2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: N-Methyl perfluorooctane sulfonamide
(MeFOSA)
31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Ethyl perfluorooctane sulfonamide
(EtFOSA)
4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Methyl perfluorooctane
sulfonamidoethanol (MeFOSE)
2448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Ethyl perfluorooctane
sulfonamidoethanol (EtFOSE)
1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QC Lot: 780894)
EP231X: 4:2 Fluorotelomer sulfonic acid (4:2
FTS)
757124-72-4 0.05 µg/L <0.05 <0.05 0.00 No LimitGW14 EM1702389-001
EP231X: 6:2 Fluorotelomer sulfonic acid (6:2
FTS)
27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: 8:2 Fluorotelomer sulfonic acid (8:2
FTS)
39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: 10:2 Fluorotelomer sulfonic acid (10:2
FTS)
120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231P: PFAS Sums (QC Lot: 780894)
EP231X: Sum of PFAS ---- 0.01 µg/L <0.01 <0.01 0.00 No LimitGW14 EM1702389-001
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Method Blank (MB) and Laboratory Control Spike (LCS) Report
The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC
parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target
analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EA015: Total Dissolved Solids dried at 180 ± 5 °C (QCLot: 778712)
EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 99.62000 mg/L 10696
<10 102293 mg/L 10696
EA025: Total Suspended Solids dried at 104 ± 2°C (QCLot: 778710)
EA025H: Suspended Solids (SS) ---- 5 mg/L <5 106150 mg/L 11190
EA025: Total Suspended Solids dried at 104 ± 2°C (QCLot: 778713)
EA025H: Suspended Solids (SS) ---- 5 mg/L <5 95.3150 mg/L 11190
ED037P: Alkalinity by PC Titrator (QCLot: 779009)
ED037-P: Total Alkalinity as CaCO3 ---- ---- mg/L ---- 101200 mg/L 11090
ED037P: Alkalinity by PC Titrator (QCLot: 779012)
ED037-P: Total Alkalinity as CaCO3 ---- ---- mg/L ---- 103200 mg/L 11090
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 777656)
ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L <1 10525 mg/L 11592
<1 99.3100 mg/L 11592
ED045G: Chloride by Discrete Analyser (QCLot: 777655)
ED045G: Chloride 16887-00-6 1 mg/L <1 99.710 mg/L 11789
<1 1021000 mg/L 11292
ED093F: Dissolved Major Cations (QCLot: 778640)
ED093F: Calcium 7440-70-2 1 mg/L <1 1025 mg/L 10892
ED093F: Magnesium 7439-95-4 1 mg/L <1 97.25 mg/L 10892
ED093F: Sodium 7440-23-5 1 mg/L <1 10050 mg/L 10789
ED093F: Potassium 7440-09-7 1 mg/L <1 10050 mg/L 10789
EG020F: Dissolved Metals by ICP-MS (QCLot: 778638)
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 97.60.1 mg/L 10894
EG020A-F: Beryllium 7440-41-7 0.001 mg/L <0.001 1040.1 mg/L 11385
EG020A-F: Barium 7440-39-3 0.001 mg/L <0.001 98.30.1 mg/L 10787
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 95.30.1 mg/L 10886
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 96.50.1 mg/L 11086
EG020A-F: Cobalt 7440-48-4 0.001 mg/L <0.001 94.20.1 mg/L 10888
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 92.80.1 mg/L 10787
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 95.20.1 mg/L 10987
EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 1010.1 mg/L 10987
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 95.30.1 mg/L 10987
EG020A-F: Selenium 7782-49-2 0.01 mg/L <0.01 93.50.1 mg/L 10987
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EG020F: Dissolved Metals by ICP-MS (QCLot: 778638) - continued
EG020A-F: Vanadium 7440-62-2 0.01 mg/L <0.01 98.40.1 mg/L 11185
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 1010.1 mg/L 10787
EG020A-F: Boron 7440-42-8 0.05 mg/L <0.05 1030.5 mg/L 11684
EG020T: Total Metals by ICP-MS (QCLot: 778609)
EG020A-T: Arsenic 7440-38-2 0.001 mg/L <0.001 1080.1 mg/L 11394
EG020A-T: Beryllium 7440-41-7 0.001 mg/L <0.001 1040.1 mg/L 11189
EG020A-T: Barium 7440-39-3 0.001 mg/L <0.001 96.70.1 mg/L 11289
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 99.80.1 mg/L 11088
EG020A-T: Chromium 7440-47-3 0.001 mg/L <0.001 94.00.1 mg/L 11287
EG020A-T: Cobalt 7440-48-4 0.001 mg/L <0.001 96.70.1 mg/L 11388
EG020A-T: Copper 7440-50-8 0.001 mg/L <0.001 94.20.1 mg/L 11287
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 96.20.1 mg/L 11388
EG020A-T: Manganese 7439-96-5 0.001 mg/L <0.001 97.10.1 mg/L 11288
EG020A-T: Nickel 7440-02-0 0.001 mg/L <0.001 94.10.1 mg/L 11191
EG020A-T: Selenium 7782-49-2 0.01 mg/L <0.01 1040.1 mg/L 11086
EG020A-T: Vanadium 7440-62-2 0.01 mg/L <0.01 95.50.1 mg/L 11288
EG020A-T: Zinc 7440-66-6 0.005 mg/L <0.005 1080.1 mg/L 11288
EG020A-T: Boron 7440-42-8 0.05 mg/L <0.05 1050.5 mg/L 11888
EG020T: Total Metals by ICP-MS (QCLot: 778610)
EG020A-T: Arsenic 7440-38-2 0.001 mg/L <0.001 1010.1 mg/L 11394
EG020A-T: Beryllium 7440-41-7 0.001 mg/L <0.001 95.60.1 mg/L 11189
EG020A-T: Barium 7440-39-3 0.001 mg/L <0.001 99.90.1 mg/L 11289
EG020A-T: Cadmium 7440-43-9 0.0001 mg/L <0.0001 1030.1 mg/L 11088
EG020A-T: Chromium 7440-47-3 0.001 mg/L <0.001 97.20.1 mg/L 11287
EG020A-T: Cobalt 7440-48-4 0.001 mg/L <0.001 1010.1 mg/L 11388
EG020A-T: Copper 7440-50-8 0.001 mg/L <0.001 97.60.1 mg/L 11287
EG020A-T: Lead 7439-92-1 0.001 mg/L <0.001 98.00.1 mg/L 11388
EG020A-T: Manganese 7439-96-5 0.001 mg/L <0.001 98.90.1 mg/L 11288
EG020A-T: Nickel 7440-02-0 0.001 mg/L <0.001 97.20.1 mg/L 11191
EG020A-T: Selenium 7782-49-2 0.01 mg/L <0.01 1040.1 mg/L 11086
EG020A-T: Vanadium 7440-62-2 0.01 mg/L <0.01 99.00.1 mg/L 11288
EG020A-T: Zinc 7440-66-6 0.005 mg/L <0.005 1080.1 mg/L 11288
EG020A-T: Boron 7440-42-8 0.05 mg/L <0.05 1040.5 mg/L 11888
EG035F: Dissolved Mercury by FIMS (QCLot: 778639)
EG035F: Mercury 7439-97-6 0.0001 mg/L <0.0001 94.10.01 mg/L 11788
EG035T: Total Recoverable Mercury by FIMS (QCLot: 778485)
EG035T: Mercury 7439-97-6 0.0001 mg/L <0.0001 92.90.01 mg/L 11387
EG050F: Dissolved Hexavalent Chromium (QCLot: 778879)
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EG050F: Dissolved Hexavalent Chromium (QCLot: 778879) - continued
EG050F: Hexavalent Chromium 18540-29-9 0.01 mg/L <0.01 1000.5 mg/L 11392
EK040P: Fluoride by PC Titrator (QCLot: 779007)
EK040P: Fluoride 16984-48-8 0.1 mg/L <0.1 92.45 mg/L 11285
EK055G: Ammonia as N by Discrete Analyser (QCLot: 777445)
EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 98.01 mg/L 11580
EK071G: Reactive Phosphorus as P by discrete analyser (QCLot: 777657)
EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L <0.01 1040.5 mg/L 10894
EP005: Total Organic Carbon (TOC) (QCLot: 779015)
EP005: Total Organic Carbon ---- 1 mg/L <1 95.4100 mg/L 10981
EP074A: Monocyclic Aromatic Hydrocarbons (QCLot: 778468)
EP074: Styrene 100-42-5 5 µg/L <5 10320 µg/L 11981
EP074: Isopropylbenzene 98-82-8 5 µg/L <5 10720 µg/L 12379
EP074: n-Propylbenzene 103-65-1 5 µg/L <5 99.920 µg/L 11571
EP074: 1.3.5-Trimethylbenzene 108-67-8 5 µg/L <5 98.120 µg/L 11472
EP074: sec-Butylbenzene 135-98-8 5 µg/L <5 99.520 µg/L 11472
EP074: 1.2.4-Trimethylbenzene 95-63-6 5 µg/L <5 99.320 µg/L 11274
EP074: tert-Butylbenzene 98-06-6 5 µg/L <5 10020 µg/L 11473
EP074: p-Isopropyltoluene 99-87-6 5 µg/L <5 10320 µg/L 11570
EP074: n-Butylbenzene 104-51-8 5 µg/L <5 97.020 µg/L 11662
EP074B: Oxygenated Compounds (QCLot: 778468)
EP074: Vinyl Acetate 108-05-4 50 µg/L <50 101200 µg/L 12673
EP074: 2-Butanone (MEK) 78-93-3 50 µg/L <50 108200 µg/L 13662
EP074: 4-Methyl-2-pentanone (MIBK) 108-10-1 50 µg/L <50 97.3200 µg/L 13273
EP074: 2-Hexanone (MBK) 591-78-6 50 µg/L <50 102200 µg/L 13668
EP074C: Sulfonated Compounds (QCLot: 778468)
EP074: Carbon disulfide 75-15-0 5 µg/L <5 94.820 µg/L 12355
EP074D: Fumigants (QCLot: 778468)
EP074: 2.2-Dichloropropane 594-20-7 5 µg/L <5 10520 µg/L 12267
EP074: 1.2-Dichloropropane 78-87-5 5 µg/L <5 99.720 µg/L 12078
EP074: cis-1.3-Dichloropropylene 10061-01-5 5 µg/L <5 88.120 µg/L 11870
EP074: trans-1.3-Dichloropropylene 10061-02-6 5 µg/L <5 88.020 µg/L 11568
EP074: 1.2-Dibromoethane (EDB) 106-93-4 5 µg/L <5 10320 µg/L 12078
EP074E: Halogenated Aliphatic Compounds (QCLot: 778468)
EP074: Dichlorodifluoromethane 75-71-8 50 µg/L <50 99.4200 µg/L 14062
EP074: Chloromethane 74-87-3 50 µg/L <50 117200 µg/L 13868
EP074: Vinyl chloride 75-01-4 50 µg/L <50 108200 µg/L 13964
EP074: Bromomethane 74-83-9 50 µg/L <50 96.8200 µg/L 13048
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP074E: Halogenated Aliphatic Compounds (QCLot: 778468) - continued
EP074: Chloroethane 75-00-3 50 µg/L <50 110200 µg/L 13071
EP074: Trichlorofluoromethane 75-69-4 50 µg/L <50 102200 µg/L 12671
EP074: 1.1-Dichloroethene 75-35-4 5 µg/L <5 10120 µg/L 12568
EP074: Iodomethane 74-88-4 5 µg/L <5 10020 µg/L 12027
EP074: Methylene chloride 75-09-2 5 µg/L <6.8254307591 11820 µg/L 16574
EP074: trans-1.2-Dichloroethene 156-60-5 5 µg/L <5 98.120 µg/L 12173
EP074: 1.1-Dichloroethane 75-34-3 5 µg/L <5 10620 µg/L 12077
EP074: cis-1.2-Dichloroethene 156-59-2 5 µg/L <5 10820 µg/L 12079
EP074: 1.1.1-Trichloroethane 71-55-6 5 µg/L <5 85.620 µg/L 12070
EP074: 1.1-Dichloropropylene 563-58-6 5 µg/L <5 97.920 µg/L 12270
EP074: Carbon Tetrachloride 56-23-5 5 µg/L <5 87.920 µg/L 11966
EP074: 1.2-Dichloroethane 107-06-2 5 µg/L <5 99.820 µg/L 12079
EP074: Trichloroethene 79-01-6 5 µg/L <5 97.420 µg/L 12075
EP074: Dibromomethane 74-95-3 5 µg/L <5 98.420 µg/L 11877
EP074: 1.1.2-Trichloroethane 79-00-5 5 µg/L <5 10420 µg/L 12186
EP074: 1.3-Dichloropropane 142-28-9 5 µg/L <5 10720 µg/L 11984
EP074: Tetrachloroethene 127-18-4 5 µg/L <5 98.020 µg/L 11975
EP074: 1.1.1.2-Tetrachloroethane 630-20-6 5 µg/L <5 87.320 µg/L 11275
EP074: trans-1.4-Dichloro-2-butene 110-57-6 5 µg/L <5 96.720 µg/L 11963
EP074: cis-1.4-Dichloro-2-butene 1476-11-5 5 µg/L <5 74.620 µg/L 11954
EP074: 1.1.2.2-Tetrachloroethane 79-34-5 5 µg/L <5 10420 µg/L 12581
EP074: 1.2.3-Trichloropropane 96-18-4 5 µg/L <5 10420 µg/L 12581
EP074: Pentachloroethane 76-01-7 5 µg/L <5 78.520 µg/L 10963
EP074: 1.2-Dibromo-3-chloropropane 96-12-8 5 µg/L <5 79.920 µg/L 11659
EP074: Hexachlorobutadiene 87-68-3 5 µg/L <5 10120 µg/L 12260
EP074F: Halogenated Aromatic Compounds (QCLot: 778468)
EP074: Chlorobenzene 108-90-7 5 µg/L <5 10320 µg/L 11884
EP074: Bromobenzene 108-86-1 5 µg/L <5 10120 µg/L 11974
EP074: 2-Chlorotoluene 95-49-8 5 µg/L <5 99.920 µg/L 11476
EP074: 4-Chlorotoluene 106-43-4 5 µg/L <5 98.420 µg/L 11373
EP074: 1.3-Dichlorobenzene 541-73-1 5 µg/L <5 97.120 µg/L 11476
EP074: 1.4-Dichlorobenzene 106-46-7 5 µg/L <5 10220 µg/L 11876
EP074: 1.2-Dichlorobenzene 95-50-1 5 µg/L <5 10220 µg/L 11381
EP074: 1.2.4-Trichlorobenzene 120-82-1 5 µg/L <5 99.320 µg/L 11864
EP074: 1.2.3-Trichlorobenzene 87-61-6 5 µg/L <5 10620 µg/L 12072
EP074G: Trihalomethanes (QCLot: 778468)
EP074: Chloroform 67-66-3 5 µg/L <5 10820 µg/L 11878
EP074: Bromodichloromethane 75-27-4 5 µg/L <5 90.220 µg/L 11569
EP074: Dibromochloromethane 124-48-1 5 µg/L <5 87.220 µg/L 10969
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EM1702389
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP074G: Trihalomethanes (QCLot: 778468) - continued
EP074: Bromoform 75-25-2 5 µg/L <5 83.120 µg/L 11162
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 778701)
EP075(SIM): Naphthalene 91-20-3 1 µg/L <1.0 70.25 µg/L 11039
EP075(SIM): Acenaphthylene 208-96-8 1 µg/L <1.0 72.15 µg/L 12440
EP075(SIM): Acenaphthene 83-32-9 1 µg/L <1.0 73.35 µg/L 11747
EP075(SIM): Fluorene 86-73-7 1 µg/L <1.0 73.45 µg/L 11851
EP075(SIM): Phenanthrene 85-01-8 1 µg/L <1.0 77.65 µg/L 11953
EP075(SIM): Anthracene 120-12-7 1 µg/L <1.0 73.25 µg/L 11351
EP075(SIM): Fluoranthene 206-44-0 1 µg/L <1.0 74.75 µg/L 12359
EP075(SIM): Pyrene 129-00-0 1 µg/L <1.0 78.65 µg/L 12358
EP075(SIM): Benz(a)anthracene 56-55-3 1 µg/L <1.0 72.05 µg/L 12652
EP075(SIM): Chrysene 218-01-9 1 µg/L <1.0 82.35 µg/L 12355
EP075(SIM): Benzo(b+j)fluoranthene 205-99-2
205-82-3
1 µg/L <1.0 72.45 µg/L 13152
EP075(SIM): Benzo(k)fluoranthene 207-08-9 1 µg/L <1.0 79.55 µg/L 12657
EP075(SIM): Benzo(a)pyrene 50-32-8 0.5 µg/L <0.5 67.65 µg/L 12656
EP075(SIM): Indeno(1.2.3.cd)pyrene 193-39-5 1 µg/L <1.0 73.55 µg/L 12353
EP075(SIM): Dibenz(a.h)anthracene 53-70-3 1 µg/L <1.0 73.65 µg/L 12553
EP075(SIM): Benzo(g.h.i)perylene 191-24-2 1 µg/L <1.0 75.45 µg/L 12553
EP080/071: Total Petroleum Hydrocarbons (QCLot: 778467)
EP080: C6 - C9 Fraction ---- 20 µg/L <20 112360 µg/L 12767
EP080/071: Total Petroleum Hydrocarbons (QCLot: 778699)
EP071: C10 - C14 Fraction ---- 50 µg/L <50 96.53368 µg/L 12353
EP071: C15 - C28 Fraction ---- 100 µg/L <100 96.014735 µg/L 13357
EP071: C29 - C36 Fraction ---- 50 µg/L <50 84.27856 µg/L 14155
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 778467)
EP080: C6 - C10 Fraction C6_C10 20 µg/L <20 109450 µg/L 12565
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 778699)
EP071: >C10 - C16 Fraction ---- 100 µg/L <100 92.15225 µg/L 12254
EP071: >C16 - C34 Fraction ---- 100 µg/L <100 87.519994 µg/L 13256
EP071: >C34 - C40 Fraction ---- 100 µg/L <100 93.01449 µg/L 13751
EP080: BTEXN (QCLot: 778467)
EP080: Benzene 71-43-2 1 µg/L <1 87.520 µg/L 12076
EP080: Toluene 108-88-3 2 µg/L <2 10820 µg/L 12476
EP080: Ethylbenzene 100-41-4 2 µg/L <2 10720 µg/L 12472
EP080: meta- & para-Xylene 108-38-3
106-42-3
2 µg/L <2 10940 µg/L 13072
EP080: ortho-Xylene 95-47-6 2 µg/L <2 11720 µg/L 12878
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP080: BTEXN (QCLot: 778467) - continued
EP080: Naphthalene 91-20-3 5 µg/L <5 97.65 µg/L 12971
EP231A: Perfluoroalkyl Sulfonic Acids (QCLot: 780894)
EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L <0.02 1070.5 µg/L 13070
EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L <0.02 1060.5 µg/L 13070
EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L <0.02 1030.5 µg/L 13070
EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L <0.02 1110.5 µg/L 13070
EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.01 1070.5 µg/L 13070
EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L <0.02 1080.5 µg/L 13070
EP231B: Perfluoroalkyl Carboxylic Acids (QCLot: 780894)
EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L <0.1 87.82.5 µg/L 13070
EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L <0.02 1070.5 µg/L 13070
EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L <0.02 1120.5 µg/L 13070
EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L <0.02 1030.5 µg/L 13070
EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 1000.5 µg/L 13070
EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L <0.02 1200.5 µg/L 13070
EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L <0.02 1140.5 µg/L 13070
EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L <0.02 96.00.5 µg/L 13070
EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 98.00.5 µg/L 13070
EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.02 µg/L <0.02 1070.5 µg/L 13070
EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.05 µg/L <0.05 1021.25 µg/L 12470
EP231C: Perfluoroalkyl Sulfonamides (QCLot: 780894)
EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 1040.5 µg/L 13070
EP231X: N-Methyl perfluorooctane sulfonamide (MeFOSA) 31506-32-8 0.05 µg/L <0.05 1091.25 µg/L 13070
EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 4151-50-2 0.05 µg/L <0.05 97.91.25 µg/L 12970
EP231X: N-Methyl perfluorooctane sulfonamidoethanol
(MeFOSE)
2448-09-7 0.05 µg/L <0.05 1061.25 µg/L 12970
EP231X: N-Ethyl perfluorooctane sulfonamidoethanol
(EtFOSE)
1691-99-2 0.05 µg/L <0.05 1061.25 µg/L 12670
EP231X: N-Methyl perfluorooctane sulfonamidoacetic acid
(MeFOSAA)
2355-31-9 0.02 µg/L <0.02 1180.5 µg/L 13070
EP231X: N-Ethyl perfluorooctane sulfonamidoacetic acid
(EtFOSAA)
2991-50-6 0.02 µg/L <0.02 1180.5 µg/L 13070
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QCLot: 780894)
EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 757124-72-4 0.05 µg/L <0.05 83.20.5 µg/L 13070
EP231X: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) 27619-97-2 0.05 µg/L <0.05 98.40.5 µg/L 13070
EP231X: 8:2 Fluorotelomer sulfonic acid (8:2 FTS) 39108-34-4 0.05 µg/L <0.05 99.00.5 µg/L 13070
EP231X: 10:2 Fluorotelomer sulfonic acid (10:2 FTS) 120226-60-0 0.05 µg/L <0.05 1030.5 µg/L 13070
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Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on
analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 777656)
Anonymous EM1702345-002 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric # Not
Determined
10 mg/L 13070
ED045G: Chloride by Discrete Analyser (QCLot: 777655)
Anonymous EM1702345-002 16887-00-6ED045G: Chloride 113400 mg/L 13070
EG020F: Dissolved Metals by ICP-MS (QCLot: 778638)
Anonymous EM1702345-001 7440-38-2EG020A-F: Arsenic 99.00.2 mg/L 13185
7440-41-7EG020A-F: Beryllium 1100.2 mg/L 14173
7440-39-3EG020A-F: Barium 93.80.2 mg/L 12775
7440-43-9EG020A-F: Cadmium 99.20.05 mg/L 13381
7440-47-3EG020A-F: Chromium 1050.2 mg/L 13571
7440-48-4EG020A-F: Cobalt 92.90.2 mg/L 13278
7440-50-8EG020A-F: Copper 95.50.2 mg/L 13076
7439-92-1EG020A-F: Lead 96.80.2 mg/L 13375
7439-96-5EG020A-F: Manganese 97.00.2 mg/L 13464
7440-02-0EG020A-F: Nickel 91.00.2 mg/L 13173
7440-62-2EG020A-F: Vanadium 1130.2 mg/L 13173
7440-66-6EG020A-F: Zinc 94.70.2 mg/L 13175
EG020T: Total Metals by ICP-MS (QCLot: 778609)
Anonymous EM1702315-002 7440-38-2EG020A-T: Arsenic 1051 mg/L 11882
7440-41-7EG020A-T: Beryllium 90.51 mg/L 12179
7440-39-3EG020A-T: Barium 1031 mg/L 11480
7440-43-9EG020A-T: Cadmium 1050.25 mg/L 12975
7440-47-3EG020A-T: Chromium 98.91 mg/L 11880
7440-48-4EG020A-T: Cobalt 1081 mg/L 12082
7440-50-8EG020A-T: Copper 1011 mg/L 11581
7439-92-1EG020A-T: Lead 1011 mg/L 12183
7439-96-5EG020A-T: Manganese 95.31 mg/L 12373
7440-02-0EG020A-T: Nickel 1031 mg/L 11880
7440-62-2EG020A-T: Vanadium 1021 mg/L 11981
7440-66-6EG020A-T: Zinc 1031 mg/L 11674
EG020T: Total Metals by ICP-MS (QCLot: 778610)
GW05 EM1702389-005 7440-38-2EG020A-T: Arsenic 1041 mg/L 11882
7440-41-7EG020A-T: Beryllium 1001 mg/L 12179
7440-39-3EG020A-T: Barium 1011 mg/L 11480
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EG020T: Total Metals by ICP-MS (QCLot: 778610) - continued
GW05 EM1702389-005 7440-43-9EG020A-T: Cadmium 1020.25 mg/L 12975
7440-47-3EG020A-T: Chromium 99.21 mg/L 11880
7440-48-4EG020A-T: Cobalt 1071 mg/L 12082
7440-50-8EG020A-T: Copper 99.11 mg/L 11581
7439-92-1EG020A-T: Lead 1011 mg/L 12183
7439-96-5EG020A-T: Manganese 96.41 mg/L 12373
7440-02-0EG020A-T: Nickel 98.41 mg/L 11880
7440-62-2EG020A-T: Vanadium 1051 mg/L 11981
7440-66-6EG020A-T: Zinc 1001 mg/L 11674
EG035F: Dissolved Mercury by FIMS (QCLot: 778639)
Anonymous EM1702345-002 7439-97-6EG035F: Mercury 91.60.01 mg/L 12070
EG035T: Total Recoverable Mercury by FIMS (QCLot: 778485)
Anonymous EM1702313-013 7439-97-6EG035T: Mercury 89.70.01 mg/L 13070
EG050F: Dissolved Hexavalent Chromium (QCLot: 778879)
Anonymous EM1702345-002 18540-29-9EG050F: Hexavalent Chromium 1030.5 mg/L 12759
EK040P: Fluoride by PC Titrator (QCLot: 779007)
Anonymous EM1702345-002 16984-48-8EK040P: Fluoride 92.45 mg/L 13070
EK055G: Ammonia as N by Discrete Analyser (QCLot: 777445)
Anonymous EM1702313-013 7664-41-7EK055G: Ammonia as N 98.51 mg/L 13070
EK071G: Reactive Phosphorus as P by discrete analyser (QCLot: 777657)
GW20 EM1702389-002 14265-44-2EK071G: Reactive Phosphorus as P 97.40.5 mg/L 12379
EP005: Total Organic Carbon (TOC) (QCLot: 779015)
Anonymous EM1702342-007 ----EP005: Total Organic Carbon 100100 mg/L 11480
EP074E: Halogenated Aliphatic Compounds (QCLot: 778468)
Anonymous EM1702345-002 75-35-4EP074: 1.1-Dichloroethene 93.620 µg/L 12440
79-01-6EP074: Trichloroethene 79.720 µg/L 12654
EP074F: Halogenated Aromatic Compounds (QCLot: 778468)
Anonymous EM1702345-002 108-90-7EP074: Chlorobenzene 91.420 µg/L 13268
EP080/071: Total Petroleum Hydrocarbons (QCLot: 778467)
Anonymous EM1702345-002 ----EP080: C6 - C9 Fraction 75.1280 µg/L 12543
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions (QCLot: 778467)
Anonymous EM1702345-002 C6_C10EP080: C6 - C10 Fraction 78.5330 µg/L 12244
EP080: BTEXN (QCLot: 778467)
Anonymous EM1702345-002 71-43-2EP080: Benzene 82.220 µg/L 13068
108-88-3EP080: Toluene 91.820 µg/L 13272
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EP231A: Perfluoroalkyl Sulfonic Acids (QCLot: 780894)
GW14 EM1702389-001 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 1020.5 µg/L 13050
2706-91-4EP231X: Perfluoropentane sulfonic acid (PFPeS) 72.80.5 µg/L 13050
355-46-4EP231X: Perfluorohexane sulfonic acid (PFHxS) 74.00.5 µg/L 13050
375-92-8EP231X: Perfluoroheptane sulfonic acid (PFHpS) 84.60.5 µg/L 13050
1763-23-1EP231X: Perfluorooctane sulfonic acid (PFOS) 73.20.5 µg/L 13050
335-77-3EP231X: Perfluorodecane sulfonic acid (PFDS) 68.00.5 µg/L 13050
EP231B: Perfluoroalkyl Carboxylic Acids (QCLot: 780894)
GW14 EM1702389-001 375-22-4EP231X: Perfluorobutanoic acid (PFBA) 52.42.5 µg/L 13050
2706-90-3EP231X: Perfluoropentanoic acid (PFPeA) 87.60.5 µg/L 13050
307-24-4EP231X: Perfluorohexanoic acid (PFHxA) 74.60.5 µg/L 13050
375-85-9EP231X: Perfluoroheptanoic acid (PFHpA) 73.60.5 µg/L 13050
335-67-1EP231X: Perfluorooctanoic acid (PFOA) 66.80.5 µg/L 13050
375-95-1EP231X: Perfluorononanoic acid (PFNA) 73.20.5 µg/L 13050
335-76-2EP231X: Perfluorodecanoic acid (PFDA) 84.80.5 µg/L 13050
2058-94-8EP231X: Perfluoroundecanoic acid (PFUnDA) 75.20.5 µg/L 13050
307-55-1EP231X: Perfluorododecanoic acid (PFDoDA) 68.60.5 µg/L 13050
72629-94-8EP231X: Perfluorotridecanoic acid (PFTrDA) 63.40.5 µg/L 13050
376-06-7EP231X: Perfluorotetradecanoic acid (PFTeDA) 64.91.25 µg/L 13050
EP231C: Perfluoroalkyl Sulfonamides (QCLot: 780894)
GW14 EM1702389-001 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 82.80.5 µg/L 13050
31506-32-8EP231X: N-Methyl perfluorooctane sulfonamide
(MeFOSA)
76.31.25 µg/L 13050
4151-50-2EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 69.01.25 µg/L 13050
2448-09-7EP231X: N-Methyl perfluorooctane sulfonamidoethanol
(MeFOSE)
83.41.25 µg/L 13050
1691-99-2EP231X: N-Ethyl perfluorooctane sulfonamidoethanol
(EtFOSE)
81.41.25 µg/L 13050
2355-31-9EP231X: N-Methyl perfluorooctane sulfonamidoacetic
acid (MeFOSAA)
63.00.5 µg/L 13050
2991-50-6EP231X: N-Ethyl perfluorooctane sulfonamidoacetic
acid (EtFOSAA)
79.00.5 µg/L 13050
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QCLot: 780894)
GW14 EM1702389-001 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 83.00.5 µg/L 13050
27619-97-2EP231X: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) 98.40.5 µg/L 13050
39108-34-4EP231X: 8:2 Fluorotelomer sulfonic acid (8:2 FTS) 82.80.5 µg/L 13050
120226-60-0EP231X: 10:2 Fluorotelomer sulfonic acid (10:2 FTS) 67.40.5 µg/L 13050
True
Environmental
QA/QC Compliance Assessment to assist with Quality ReviewWork Order : EM1702389 Page : 1 of 13
:: LaboratoryClient Environmental Division MelbourneJACOBS GROUP (AUSTRALIA) PTY LTD
:Contact MR BENJAMIN GRASSO Telephone : +61-3-8549 9608
:Project ISI57700 Date Samples Received : 03-Mar-2017
Site : EBAC GME Issue Date : 09-Mar-2017
BEN GRASSO:Sampler No. of samples received : 7
:Order number ---- No. of samples analysed : 7
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated
reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this
report contribute to the overall DQO assessment and reporting for guideline compliance.
Brief method summaries and references are also provided to assist in traceability.
Summary of Outliers
Outliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.
l NO Duplicate outliers occur.
l NO Laboratory Control outliers occur.
l Matrix Spike outliers exist - please see following pages for full details.
l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliance
l Analysis Holding Time Outliers exist - please see following pages for full details.
Outliers : Frequency of Quality Control Samples
l Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Outliers : Quality Control Samples
Duplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes
Matrix: WATER
Compound Group Name CommentLimitsDataAnalyteClient Sample IDLaboratory Sample ID CAS Number
Matrix Spike (MS) Recoveries
EM1702345--002 14808-79-8Sulfate as SO4 -
Turbidimetric
Anonymous MS recovery not determined,
background level greater than or
equal to 4x spike level.
----Not
Determined
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
Outliers : Analysis Holding Time Compliance
Matrix: WATER
AnalysisExtraction / Preparation
Date analysedDate extractedContainer / Client Sample ID(s) Days
overdue
Days
overdue
Due for extraction Due for analysis
Method
EA005P: pH by PC Titrator
Clear Plastic Bottle - Natural
02-Mar-2017----GW14, GW20,
GW06, GW07,
GW05
06-Mar-2017---- ---- 4
Outliers : Frequency of Quality Control Samples
Matrix: WATER
Quality Control SpecificationQuality Control Sample Type
Method ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 10.000 13
NEPM 2013 B3 & ALS QC StandardTRH - Semivolatile Fraction 0.00 10.000 11
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC StandardPAH/Phenols (GC/MS - SIM) 0.00 5.000 13
NEPM 2013 B3 & ALS QC StandardTRH - Semivolatile Fraction 0.00 5.000 11
Analysis Holding Time Compliance
Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and
should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.
Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics
14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.
If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.
This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container
provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EA005P: pH by PC Titrator
Clear Plastic Bottle - Natural (EA005-P)
GW14, GW20,
GW06, GW07,
GW05
02-Mar-2017---- 06-Mar-2017----02-Mar-2017 ---- û
EA015: Total Dissolved Solids dried at 180 ± 5 °C
Clear Plastic Bottle - Natural (EA015H)
GW14, GW20,
GW06, GW07,
GW05
09-Mar-2017---- 06-Mar-2017----02-Mar-2017 ---- ü
EA025: Total Suspended Solids dried at 104 ± 2°C
Clear Plastic Bottle - Natural (EA025H)
GW14, GW20,
GW06, GW07,
GW05
09-Mar-2017---- 06-Mar-2017----02-Mar-2017 ---- ü
ED037P: Alkalinity by PC Titrator
Clear Plastic Bottle - Natural (ED037-P)
GW14, GW20,
GW06, GW07,
GW05
16-Mar-2017---- 06-Mar-2017----02-Mar-2017 ---- ü
ED041G: Sulfate (Turbidimetric) as SO4 2- by DA
Clear Plastic Bottle - Natural (ED041G)
GW14, GW20,
GW06, GW07,
GW05
30-Mar-2017---- 06-Mar-2017----02-Mar-2017 ---- ü
ED045G: Chloride by Discrete Analyser
Clear Plastic Bottle - Natural (ED045G)
GW14, GW20,
GW06, GW07,
GW05
30-Mar-2017---- 06-Mar-2017----02-Mar-2017 ---- ü
ED093F: Dissolved Major Cations
Clear Plastic Bottle - Nitric Acid; Filtered (ED093F)
GW14, GW20,
GW06, GW07,
GW05
30-Mar-2017---- 07-Mar-2017----02-Mar-2017 ---- ü
EG020F: Dissolved Metals by ICP-MS
Clear Plastic Bottle - Nitric Acid; Filtered (EG020A-F)
GW14, GW20,
GW06, GW07,
GW05
29-Aug-2017---- 07-Mar-2017----02-Mar-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EG020T: Total Metals by ICP-MS
Clear Plastic Bottle - Nitric Acid; Unfiltered (EG020A-T)
GW14, GW20,
GW06, GW07,
GW05
29-Aug-201729-Aug-2017 07-Mar-201707-Mar-201702-Mar-2017 ü ü
Clear Plastic Bottle - Nitric Acid; Unfiltered (EG020A-T)
RB_004 30-Aug-201730-Aug-2017 07-Mar-201707-Mar-201703-Mar-2017 ü üEG035F: Dissolved Mercury by FIMS
Clear Plastic Bottle - Nitric Acid; Filtered (EG035F)
GW14, GW20,
GW06, GW07,
GW05
30-Mar-2017---- 07-Mar-2017----02-Mar-2017 ---- ü
EG035T: Total Recoverable Mercury by FIMS
Clear Plastic Bottle - Nitric Acid; Unfiltered (EG035T)
GW14, GW20,
GW06, GW07,
GW05
30-Mar-2017---- 06-Mar-2017----02-Mar-2017 ---- ü
Clear Plastic Bottle - Nitric Acid; Unfiltered (EG035T)
RB_004 31-Mar-2017---- 06-Mar-2017----03-Mar-2017 ---- üEG050F: Dissolved Hexavalent Chromium
Clear Plastic Bottle - NaOH Filtered (EG050F)
GW14, GW20,
GW06, GW07,
GW05
30-Mar-2017---- 06-Mar-2017----02-Mar-2017 ---- ü
EK040P: Fluoride by PC Titrator
Clear Plastic Bottle - Natural (EK040P)
GW14, GW20,
GW06, GW07,
GW05
30-Mar-2017---- 06-Mar-2017----02-Mar-2017 ---- ü
EK055G: Ammonia as N by Discrete Analyser
Clear Plastic Bottle - Sulfuric Acid (EK055G)
GW14, GW20,
GW06, GW07,
GW05
30-Mar-2017---- 06-Mar-2017----02-Mar-2017 ---- ü
EK071G: Reactive Phosphorus as P by discrete analyser
Clear Plastic Bottle - Natural (EK071G)
GW14, GW20,
GW06, GW07,
GW05
04-Mar-2017---- 03-Mar-2017----02-Mar-2017 ---- ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP005: Total Organic Carbon (TOC)
Amber VOC Vial - Sulfuric Acid (EP005)
GW14, GW20,
GW06, GW07,
GW05
30-Mar-2017---- 06-Mar-2017----02-Mar-2017 ---- ü
EP074A: Monocyclic Aromatic Hydrocarbons
Amber VOC Vial - Sulfuric Acid (EP074)
GW14, GW20,
GW06, GW07,
GW05
16-Mar-201716-Mar-2017 06-Mar-201706-Mar-201702-Mar-2017 ü ü
EP074B: Oxygenated Compounds
Amber VOC Vial - Sulfuric Acid (EP074)
GW14, GW20,
GW06, GW07,
GW05
16-Mar-201716-Mar-2017 06-Mar-201706-Mar-201702-Mar-2017 ü ü
EP074C: Sulfonated Compounds
Amber VOC Vial - Sulfuric Acid (EP074)
GW14, GW20,
GW06, GW07,
GW05
16-Mar-201716-Mar-2017 06-Mar-201706-Mar-201702-Mar-2017 ü ü
EP074D: Fumigants
Amber VOC Vial - Sulfuric Acid (EP074)
GW14, GW20,
GW06, GW07,
GW05
16-Mar-201716-Mar-2017 06-Mar-201706-Mar-201702-Mar-2017 ü ü
EP074E: Halogenated Aliphatic Compounds
Amber VOC Vial - Sulfuric Acid (EP074)
GW14, GW20,
GW06, GW07,
GW05
16-Mar-201716-Mar-2017 06-Mar-201706-Mar-201702-Mar-2017 ü ü
EP074F: Halogenated Aromatic Compounds
Amber VOC Vial - Sulfuric Acid (EP074)
GW14, GW20,
GW06, GW07,
GW05
16-Mar-201716-Mar-2017 06-Mar-201706-Mar-201702-Mar-2017 ü ü
EP074G: Trihalomethanes
Amber VOC Vial - Sulfuric Acid (EP074)
GW14, GW20,
GW06, GW07,
GW05
16-Mar-201716-Mar-2017 06-Mar-201706-Mar-201702-Mar-2017 ü ü
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Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
Amber Glass Bottle - Unpreserved (EP075(SIM))
GW14, GW20,
GW06, GW07,
GW05
16-Apr-201709-Mar-2017 08-Mar-201707-Mar-201702-Mar-2017 ü ü
EP080/071: Total Petroleum Hydrocarbons
Amber Glass Bottle - Unpreserved (EP071)
GW14, GW20,
GW06, GW07,
GW05
16-Apr-201709-Mar-2017 08-Mar-201707-Mar-201702-Mar-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
GW14, GW20,
GW06, GW07,
GW05, TB_004
16-Mar-201716-Mar-2017 06-Mar-201706-Mar-201702-Mar-2017 ü ü
EP080/071: Total Recoverable Hydrocarbons - NEPM 2013 Fractions
Amber Glass Bottle - Unpreserved (EP071)
GW14, GW20,
GW06, GW07,
GW05
16-Apr-201709-Mar-2017 08-Mar-201707-Mar-201702-Mar-2017 ü ü
Amber VOC Vial - Sulfuric Acid (EP080)
GW14, GW20,
GW06, GW07,
GW05, TB_004
16-Mar-201716-Mar-2017 06-Mar-201706-Mar-201702-Mar-2017 ü ü
EP080: BTEXN
Amber VOC Vial - Sulfuric Acid (EP080)
GW14, GW20,
GW06, GW07,
GW05, TB_004
16-Mar-201716-Mar-2017 06-Mar-201706-Mar-201702-Mar-2017 ü ü
EP231A: Perfluoroalkyl Sulfonic Acids
HDPE (no PTFE) (EP231X)
GW14, GW20,
GW06, GW07,
GW05
29-Aug-2017---- 07-Mar-2017----02-Mar-2017 ---- ü
EP231B: Perfluoroalkyl Carboxylic Acids
HDPE (no PTFE) (EP231X)
GW14, GW20,
GW06, GW07,
GW05
29-Aug-2017---- 07-Mar-2017----02-Mar-2017 ---- ü
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ISI57700:Project
Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP231C: Perfluoroalkyl Sulfonamides
HDPE (no PTFE) (EP231X)
GW14, GW20,
GW06, GW07,
GW05
29-Aug-2017---- 07-Mar-2017----02-Mar-2017 ---- ü
EP231D: (n:2) Fluorotelomer Sulfonic Acids
HDPE (no PTFE) (EP231X)
GW14, GW20,
GW06, GW07,
GW05
29-Aug-2017---- 07-Mar-2017----02-Mar-2017 ---- ü
EP231P: PFAS Sums
HDPE (no PTFE) (EP231X)
GW14, GW20,
GW06, GW07,
GW05
29-Aug-2017---- 07-Mar-2017----02-Mar-2017 ---- ü
8 of 13:Page
Work Order :
:Client
EM1702389
JACOBS GROUP (AUSTRALIA) PTY LTD
ISI57700:Project
Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to
the expected rate. A listing of breaches is provided in the Summary of Outliers.
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC Standard 12.00 10.003 25 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 14.29 10.002 14 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 13.33 10.002 15 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 10.53 10.002 19 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üFluoride by PC Titrator EK040P
NEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üHexavalent Chromium - Dissolved EG050F
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 13 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 20.00 10.001 5 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
NEPM 2013 B3 & ALS QC Standard 11.11 10.002 18 üpH by PC Titrator EA005-P
NEPM 2013 B3 & ALS QC Standard 20.00 10.001 5 üReactive Phosphorus as P-By Discrete Analyser EK071G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 10.71 10.003 28 üSuspended Solids (High Level) EA025H
NEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üTotal Mercury by FIMS EG035T
NEPM 2013 B3 & ALS QC Standard 18.18 10.004 22 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 13.33 10.002 15 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 0.00 10.000 11 ûTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 10.53 10.002 19 üTRH Volatiles/BTEX EP080
NEPM 2013 B3 & ALS QC Standard 12.50 10.002 16 üVolatile Organic Compounds EP074
Laboratory Control Samples (LCS)
NEPM 2013 B3 & ALS QC Standard 8.00 5.002 25 üAlkalinity by PC Titrator ED037-P
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 13.33 10.002 15 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üFluoride by PC Titrator EK040P
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üHexavalent Chromium - Dissolved EG050F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 7.69 5.001 13 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üReactive Phosphorus as P-By Discrete Analyser EK071G
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 14.29 10.004 28 üSuspended Solids (High Level) EA025H
NEPM 2013 B3 & ALS QC Standard 11.76 10.002 17 üTotal Dissolved Solids (High Level) EA015H
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:Client
EM1702389
JACOBS GROUP (AUSTRALIA) PTY LTD
ISI57700:Project
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Control Samples (LCS) - Continued
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üTotal Mercury by FIMS EG035T
NEPM 2013 B3 & ALS QC Standard 9.09 5.002 22 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üTRH Volatiles/BTEX EP080
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üVolatile Organic Compounds EP074
Method Blanks (MB)
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üFluoride by PC Titrator EK040P
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üHexavalent Chromium - Dissolved EG050F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üMajor Cations - Dissolved ED093F
NEPM 2013 B3 & ALS QC Standard 7.69 5.001 13 üPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üReactive Phosphorus as P-By Discrete Analyser EK071G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 7.14 5.002 28 üSuspended Solids (High Level) EA025H
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üTotal Dissolved Solids (High Level) EA015H
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üTotal Mercury by FIMS EG035T
NEPM 2013 B3 & ALS QC Standard 9.09 5.002 22 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üTotal Organic Carbon EP005
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üTRH Volatiles/BTEX EP080
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üVolatile Organic Compounds EP074
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC Standard 7.14 5.001 14 üAmmonia as N by Discrete analyser EK055G
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üChloride by Discrete Analyser ED045G
NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üDissolved Mercury by FIMS EG035F
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üDissolved Metals by ICP-MS - Suite A EG020A-F
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üFluoride by PC Titrator EK040P
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üHexavalent Chromium - Dissolved EG050F
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 13 ûPAH/Phenols (GC/MS - SIM) EP075(SIM)
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
NEPM 2013 B3 & ALS QC Standard 20.00 5.001 5 üReactive Phosphorus as P-By Discrete Analyser EK071G
NEPM 2013 B3 & ALS QC Standard 5.00 5.001 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G
NEPM 2013 B3 & ALS QC Standard 5.88 5.001 17 üTotal Mercury by FIMS EG035T
NEPM 2013 B3 & ALS QC Standard 9.09 5.002 22 üTotal Metals by ICP-MS - Suite A EG020A-T
NEPM 2013 B3 & ALS QC Standard 6.67 5.001 15 üTotal Organic Carbon EP005
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Work Order :
:Client
EM1702389
JACOBS GROUP (AUSTRALIA) PTY LTD
ISI57700:Project
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Matrix Spikes (MS) - Continued
NEPM 2013 B3 & ALS QC Standard 0.00 5.000 11 ûTRH - Semivolatile Fraction EP071
NEPM 2013 B3 & ALS QC Standard 5.26 5.001 19 üTRH Volatiles/BTEX EP080
NEPM 2013 B3 & ALS QC Standard 6.25 5.001 16 üVolatile Organic Compounds EP074
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:Client
EM1702389
JACOBS GROUP (AUSTRALIA) PTY LTD
ISI57700:Project
Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the
Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to APHA 4500 H+ B. This procedure determines pH of water samples by automated ISE.
This method is compliant with NEPM (2013) Schedule B(3)
pH by PC Titrator EA005-P WATER
In house: Referenced to APHA 2540C. A gravimetric procedure that determines the amount of `filterable` residue
in an aqueous sample. A well-mixed sample is filtered through a glass fibre filter (1.2um). The filtrate is
evaporated to dryness and dried to constant weight at 180+/-5C. This method is compliant with NEPM (2013)
Schedule B(3)
Total Dissolved Solids (High Level) EA015H WATER
In house: Referenced to APHA 2540D. A gravimetric procedure employed to determine the amount of
`non-filterable` residue in a aqueous sample. The prescribed GFC (1.2um) filter is rinsed with deionised water,
oven dried and weighed prior to analysis. A well-mixed sample is filtered through a glass fibre filter (1.2um).
The residue on the filter paper is dried at 104+/-2C . This method is compliant with NEPM (2013) Schedule B(3)
Suspended Solids (High Level) EA025H WATER
In house: Referenced to APHA 2320 B This procedure determines alkalinity by automated measurement (e.g. PC
Titrate) using pH 4.5 for indicating the total alkalinity end-point. This method is compliant with NEPM (2013)
Schedule B(3)
Alkalinity by PC Titrator ED037-P WATER
In house: Referenced to APHA 4500-SO4. Dissolved sulfate is determined in a 0.45um filtered sample. Sulfate
ions are converted to a barium sulfate suspension in an acetic acid medium with barium chloride. Light
absorbance of the BaSO4 suspension is measured by a photometer and the SO4-2 concentration is determined
by comparison of the reading with a standard curve. This method is compliant with NEPM (2013) Schedule B(3)
Sulfate (Turbidimetric) as SO4 2- by
Discrete Analyser
ED041G WATER
In house: Referenced to APHA 4500 Cl - G.The thiocyanate ion is liberated from mercuric thiocyanate through
sequestration of mercury by the chloride ion to form non-ionised mercuric chloride.in the presence of ferric ions
the librated thiocynate forms highly-coloured ferric thiocynate which is measured at 480 nm APHA 21st edition
seal method 2 017-1-L april 2003
Chloride by Discrete Analyser ED045G WATER
In house: Referenced to APHA 3120 and 3125; USEPA SW 846 - 6010 and 6020; Cations are determined by
either ICP-AES or ICP-MS techniques. This method is compliant with NEPM (2013) Schedule B(3)
Sodium Adsorption Ratio is calculated from Ca, Mg and Na which determined by ALS in house method
QWI-EN/ED093F. This method is compliant with NEPM (2013) Schedule B(3)
Hardness parameters are calculated based on APHA 2340 B. This method is compliant with NEPM (2013)
Schedule B(3)
Major Cations - Dissolved ED093F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. Samples are 0.45µm filtered
prior to analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions
are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct
mass to charge ratios prior to their measurement by a discrete dynode ion detector.
Dissolved Metals by ICP-MS - Suite A EG020A-F WATER
In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. The ICPMS technique utilizes
a highly efficient argon plasma to ionize selected elements. Ions are then passed into a high vacuum mass
spectrometer, which separates the analytes based on their distinct mass to charge ratios prior to their
measurement by a discrete dynode ion detector.
Total Metals by ICP-MS - Suite A EG020A-T WATER
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EM1702389
JACOBS GROUP (AUSTRALIA) PTY LTD
ISI57700:Project
Analytical Methods Method DescriptionsMatrixMethod
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS)
Samples are 0.45µm filtered prior to analysis. FIM-AAS is an automated flameless atomic absorption technique.
A bromate/bromide reagent is used to oxidise any organic mercury compounds in the filtered sample. The ionic
mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell.
Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM
(2013) Schedule B(3)
Dissolved Mercury by FIMS EG035F WATER
In house: Referenced to AS 3550, APHA 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS)
FIM-AAS is an automated flameless atomic absorption technique. A bromate/bromide reagent is used to oxidise
any organic mercury compounds in the unfiltered sample. The ionic mercury is reduced online to atomic
mercury vapour by SnCl2 which is then purged into a heated quartz cell. Quantification is by comparing
absorbance against a calibration curve. This method is compliant with NEPM (2013) Schedule B(3)
Total Mercury by FIMS EG035T WATER
In house: Referenced to APHA 3500 Cr-B. Samples are 0.45µm filtered prior to analysis. Hexavalent chromium is
determined on filtered water sample as received by pH adjustment and colour development using
dephenylcarbazide. Each run of samples is measured against a five-point calibration curve. This method is
compliant with NEPM (2013) Schedule B(3)
Hexavalent Chromium - Dissolved EG050F WATER
In house: Referenced to APHA 4500-F C: CDTA is added to the sample to provide a uniform ionic strength
background, adjust pH, and break up complexes. Fluoride concentration is determined by either manual or
automatic ISE measurement. This method is compliant with NEPM (2013) Schedule B(3)
Fluoride by PC Titrator EK040P WATER
In house: Referenced to APHA 4500-NH3 G Ammonia is determined by direct colorimetry by Discrete Analyser.
This method is compliant with NEPM (2013) Schedule B(3)
Ammonia as N by Discrete analyser EK055G WATER
In house: Referenced to APHA 4500-P F Ammonium molybdate and potassium antimonyl tartrate reacts in acid
medium with othophosphate to form a heteropoly acid -phosphomolybdic acid - which is reduced to intensely
coloured molybdenum blue by ascorbic acid. Quantification is by Discrete Analyser. This method is compliant
with NEPM (2013) Schedule B(3)
Reactive Phosphorus as P-By Discrete
Analyser
EK071G WATER
In house: Referenced to APHA 1030F. This method is compliant with NEPM (2013) Schedule B(3)Ionic Balance by PCT DA and Turbi SO4
DA
EN055 - PG WATER
In house: Referenced to APHA 5310 B, The automated TOC analyzer determines Total and Inorganic Carbon by
IR cell. TOC is calculated as the difference. This method is compliant with NEPM (2013) Schedule B(3)
Total Organic Carbon EP005 WATER
In house: Referenced to USEPA SW 846 - 8015A The sample extract is analysed by Capillary GC/FID and
quantification is by comparison against an established 5 point calibration curve of n-Alkane standards. This
method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH - Semivolatile Fraction EP071 WATER
In house: Referenced to USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by
Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. This
method is compliant with NEPM (2013) Schedule B(3)
Volatile Organic Compounds EP074 WATER
In house: Referenced to USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS in SIM Mode
and quantification is by comparison against an established 5 point calibration curve. This method is compliant
with NEPM (2013) Schedule B(3)
PAH/Phenols (GC/MS - SIM) EP075(SIM) WATER
In house: Referenced to USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by
Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve.
Alternatively, a sample is equilibrated in a headspace vial and a portion of the headspace determined by GCMS
analysis. This method is compliant with the QC requirements of NEPM (2013) Schedule B(3)
TRH Volatiles/BTEX EP080 WATER
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EM1702389
JACOBS GROUP (AUSTRALIA) PTY LTD
ISI57700:Project
Analytical Methods Method DescriptionsMatrixMethod
In house: Direct injection analysis of fresh waters after dilution (1:1) with methanol. Analysis by
LC-Electrospray-MS-MS, Negative Mode using MRM. PFOS is quantified using a certified, traceable standard
consisting of linear and branched PFOS isomers.
Per- and Polyfluoroalkyl Substances
(PFAS) by LCMSMS
EP231X WATER
Preparation Methods Method DescriptionsMatrixMethod
In house: Referenced to USEPA SW846-3005. Method 3005 is a Nitric/Hydrochloric acid digestion procedure
used to prepare surface and ground water samples for analysis by ICPAES or ICPMS. This method is compliant
with NEPM (2013) Schedule B(3)
Digestion for Total Recoverable Metals EN25 WATER
In house: Referenced to USEPA SW 846 - 3510B 100 mL to 1L of sample is transferred to a separatory funnel
and serially extracted three times using 60mL DCM for each extract. The resultant extracts are combined,
dehydrated and concentrated for analysis. This method is compliant with NEPM (2013) Schedule B(3) . ALS
default excludes sediment which may be resident in the container.
Separatory Funnel Extraction of Liquids ORG14 WATER
A 5 mL aliquot or 5 mL of a diluted sample is added to a 40 mL VOC vial for sparging.Volatiles Water Preparation ORG16-W WATER
Environmental
SAMPLE RECEIPT NOTIFICATION (SRN)Work Order : EM1702389
:: LaboratoryClient Environmental Division MelbourneJACOBS GROUP (AUSTRALIA) PTY
LTD
: :ContactContact MR BENJAMIN GRASSO Carol Walsh
:: AddressAddress P O BOX 312 FLINDERS LANE
MELBOURNE VIC AUSTRALIA 8009
4 Westall Rd Springvale VIC Australia
3171
:: E-mailE-mail [email protected] [email protected]
:: TelephoneTelephone +61 03 8668 3000 +61-3-8549 9608
:: FacsimileFacsimile +61 03 8668 3001 +61-3-8549 9601
::Project ISI57700 Page 1 of 3
:Order number ---- :Quote number EM2017SINKNI0002 (ME/088/17)
:C-O-C number ---- :QC Level NEPM 2013 B3 & ALS QC Standard
Site : EBAC GME
Sampler : BEN GRASSO
DatesDate Samples Received : Issue Date : 03-Mar-201703-Mar-2017 10:05
Scheduled Reporting Date: 10-Mar-2017:Client Requested Due
Date
10-Mar-2017
Delivery DetailsMode of Delivery : :Undefined Not AvailableSecurity Seal
No. of coolers/boxes : :2 Temperature 6.4°C - Ice present
: : 7 / 7Receipt Detail No. of samples received / analysed
General Comments
This report contains the following information:l
- Sample Container(s)/Preservation Non-Compliances
- Summary of Sample(s) and Requested Analysis
- Proactive Holding Time Report
- Requested Deliverables
l Sample 004 to be filtered through a 0.45um filter prior to the dissolved Hexachrome analysis.l Please direct any queries related to sample condition / numbering / breakages to Client Services.l Sample Disposal - Aqueous (14 days), Solid (60 days) from date of completion of work order.
l Analytical work for this work order will be conducted at ALS Springvale.l Please refer to the Proactive Holding Time Report table below which summarises breaches of
recommended holding times that have occurred prior to samples/instructions being received at
the laboratory. The absence of this summary table indicates that all samples have been received
within the recommended holding times for the analysis requested.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
:Client JACOBS GROUP (AUSTRALIA) PTY LTD
Work Order : EM1702389 Amendment 02 of 3:Page
03-Mar-2017:Issue Date
Sample Container(s)/Preservation Non-Compliances
All comparisons are made against pretreatment/preservation AS, APHA, USEPA standards.
l No sample container / preservation non-compliance exists.
Summary of Sample(s) and Requested Analysis
Some items described below may be part of a laboratory
process necessary for the execution of client requested
tasks. Packages may contain additional analyses, such
as the determination of moisture content and preparation
tasks, that are included in the package.
If no sampling time is provided, the sampling time will
default 00:00 on the date of sampling. If no sampling date
is provided, the sampling date will be assumed by the
laboratory and displayed in brackets without a time
component
WA
TE
R -
EG
050F
Dis
solv
ed
Hexa
vale
nt C
hro
miu
m
WA
TE
R -
EK
055G
Am
mon
ia a
s N
By
Dis
cre
te A
na
lyse
r
WA
TE
R -
EP
231X
PF
AS
- F
ull
Su
ite (
28 a
na
lyte
s)
WA
TE
R -
NT
-01 &
02A
Ca, M
g, N
a, K
, C
l, S
O4
, A
lka
linity
& F
luo
rid
e
WA
TE
R -
W-0
3
15 M
eta
ls (
NE
PM
Su
ite)
WA
TE
R -
W-0
3T
15 M
eta
ls (
Tota
l) (
NE
PM
)
WA
TE
R -
W-1
0
TR
H/V
OC
/PA
H
EM1702389-001 02-Mar-2017 00:00 GW14 ü ü ü ü ü ü ü
EM1702389-002 02-Mar-2017 00:00 GW20 ü ü ü ü ü ü ü
EM1702389-003 02-Mar-2017 00:00 GW06 ü ü ü ü ü ü ü
EM1702389-004 02-Mar-2017 00:00 GW07 ü ü ü ü ü ü ü
EM1702389-005 02-Mar-2017 00:00 GW05 ü ü ü ü ü ü ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
WA
TE
R -
EA
00
5P
pH
(P
C)
WA
TE
R -
EA
01
5H
Tota
l Dis
solv
ed
So
lids
-
Hig
h L
eve
l
WA
TE
R -
EA
02
5H
Susp
ended S
olid
s (H
igh
Le
vel)
WA
TE
R -
EK
07
1G
React
ive P
ho
sph
oru
s b
y D
iscr
ete
an
aly
ser
WA
TE
R -
EP
00
5
Tota
l Org
anic
Ca
rbo
n (
TO
C)
WA
TE
R -
W-0
2T
8 m
eta
ls (
Tota
l)
WA
TE
R -
W-1
8
TR
H(C
6 -
C9)/
BT
EX
N
EM1702389-001 02-Mar-2017 00:00 GW14 ü ü ü ü ü
EM1702389-002 02-Mar-2017 00:00 GW20 ü ü ü ü ü
EM1702389-003 02-Mar-2017 00:00 GW06 ü ü ü ü ü
EM1702389-004 02-Mar-2017 00:00 GW07 ü ü ü ü ü
EM1702389-005 02-Mar-2017 00:00 GW05 ü ü ü ü ü
EM1702389-006 02-Mar-2017 00:00 TB_004 ü
EM1702389-007 03-Mar-2017 00:00 RB_004 ü
Matrix: WATER
Client sample IDLaboratory sample
ID
Client sampling
date / time
Proactive Holding Time Report
The following table summarises breaches of recommended holding times that have occurred prior to samples/instructions being
received at the laboratory.
Evaluation: û = Holding time breach ; ü = Within holding time. Matrix: WATER
EvaluationClient Sample ID(s)
Due for
extraction
Due for
analysis Evaluation
Samples Received Instructions Received
Date Date
Method
Container
EA005-P: pH by PC Titrator
GW05 û --------03-Mar-201702-Mar-2017----Clear Plastic Bottle - Natural
GW06 û --------03-Mar-201702-Mar-2017----Clear Plastic Bottle - Natural
GW07 û --------03-Mar-201702-Mar-2017----Clear Plastic Bottle - Natural
GW14 û --------03-Mar-201702-Mar-2017----Clear Plastic Bottle - Natural
GW20 û --------03-Mar-201702-Mar-2017----Clear Plastic Bottle - Natural
:Client JACOBS GROUP (AUSTRALIA) PTY LTD
Work Order : EM1702389 Amendment 03 of 3:Page
03-Mar-2017:Issue Date
Requested Deliverables
ACCOUNTS PAYABLE
- A4 - AU Tax Invoice (INV) Email [email protected]
BENJAMIN GRASSO
- *AU Certificate of Analysis - NATA (COA) Email [email protected]
- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email [email protected]
- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email [email protected]
- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email [email protected]
- A4 - AU Tax Invoice (INV) Email [email protected]
- Chain of Custody (CoC) (COC) Email [email protected]
- Chromatogram (CHROM) Email [email protected]
- EDI Format - ESDAT (ESDAT) Email [email protected]
- EDI Format - XTab (XTAB) Email [email protected]
.Company Name: Jacobs Group (Australia) P/L VIC Order No.: Received: Mar 1, 2017 2:52 PMAddress: PO Box 312 Flinders Lane Report #: 536142 Due: Mar 8, 2017
Melbourne Phone: 03 8668 3000 Priority: 5 DayVIC 8009 Fax: 03 8668 3001 Contact Name: Ben Grasso
Project Name: EBAC GMEProject ID: IS157700
Eurofins | mgt Analytical Services Manager : Onur Mehmet
Sample Detail
pH Phosphorus reactive (as P
)
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
Polycyclic A
romatic H
ydrocarbons
Eurofins | m
gt Suite B
11
NE
PM
1999 Metals : M
etals M15
BT
EX
and Naphthalene
Volatile O
rganics
Total R
ecoverable Hydrocarbons
NE
PM
1999 Metals : M
etals M15 (F
iltered)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 18217
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 QA_002 Feb 27, 2017 Water M17-Ma01315 X X X X X X X X X X X X X
Test Counts 1 1 1 1 1 1 1 1 1 1 1 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Certificate of Analysis
Jacobs Group (Australia) P/L VIC
PO Box 312 Flinders Lane
Melbourne
VIC 8009
Attention: Ben Grasso
Report 536142-W
Project name EBAC GME
Project ID IS157700
Received Date Mar 01, 2017
Client Sample ID QA_002
Sample Matrix Water
Eurofins | mgt Sample No. M17-Ma01315
Date Sampled Feb 27, 2017
Test/Reference LOR Unit
Total Recoverable Hydrocarbons - 1999 NEPM Fractions
TRH C6-C9 0.02 mg/L < 0.02
TRH C10-C14 0.05 mg/L < 0.05
TRH C15-C28 0.1 mg/L < 0.1
TRH C29-C36 0.1 mg/L < 0.1
TRH C10-36 (Total) 0.1 mg/L < 0.1
BTEX
Benzene 0.001 mg/L < 0.001
Toluene 0.001 mg/L < 0.001
Ethylbenzene 0.001 mg/L < 0.001
m&p-Xylenes 0.002 mg/L < 0.002
o-Xylene 0.001 mg/L < 0.001
Xylenes - Total 0.003 mg/L < 0.003
4-Bromofluorobenzene (surr.) 1 % 118
Volatile Organics
1.1-Dichloroethane 0.001 mg/L < 0.001
1.1-Dichloroethene 0.001 mg/L < 0.001
1.1.1-Trichloroethane 0.001 mg/L < 0.001
1.1.1.2-Tetrachloroethane 0.001 mg/L < 0.001
1.1.2-Trichloroethane 0.001 mg/L < 0.001
1.1.2.2-Tetrachloroethane 0.001 mg/L < 0.001
1.2-Dibromoethane 0.001 mg/L < 0.001
1.2-Dichlorobenzene 0.001 mg/L < 0.001
1.2-Dichloroethane 0.001 mg/L < 0.001
1.2-Dichloropropane 0.001 mg/L < 0.001
1.2.3-Trichloropropane 0.001 mg/L < 0.001
1.2.4-Trimethylbenzene 0.001 mg/L < 0.001
1.3-Dichlorobenzene 0.001 mg/L < 0.001
1.3-Dichloropropane 0.001 mg/L < 0.001
1.3.5-Trimethylbenzene 0.001 mg/L < 0.001
1.4-Dichlorobenzene 0.001 mg/L < 0.001
2-Butanone (MEK) 0.001 mg/L < 0.001
2-Propanone (Acetone) 0.001 mg/L < 0.001
4-Chlorotoluene 0.001 mg/L < 0.001
4-Methyl-2-pentanone (MIBK) 0.001 mg/L < 0.001
Allyl chloride 0.001 mg/L < 0.001
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 21
Report Number: 536142-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID QA_002
Sample Matrix Water
Eurofins | mgt Sample No. M17-Ma01315
Date Sampled Feb 27, 2017
Test/Reference LOR Unit
Volatile Organics
Benzene 0.001 mg/L < 0.001
Bromobenzene 0.001 mg/L < 0.001
Bromochloromethane 0.001 mg/L < 0.001
Bromodichloromethane 0.001 mg/L < 0.001
Bromoform 0.001 mg/L < 0.001
Bromomethane 0.001 mg/L < 0.001
Carbon disulfide 0.001 mg/L < 0.001
Carbon Tetrachloride 0.001 mg/L < 0.001
Chlorobenzene 0.001 mg/L < 0.001
Chloroethane 0.001 mg/L < 0.001
Chloroform 0.005 mg/L < 0.005
Chloromethane 0.001 mg/L < 0.001
cis-1.2-Dichloroethene 0.001 mg/L < 0.001
cis-1.3-Dichloropropene 0.001 mg/L < 0.001
Dibromochloromethane 0.001 mg/L < 0.001
Dibromomethane 0.001 mg/L < 0.001
Dichlorodifluoromethane 0.001 mg/L < 0.001
Ethylbenzene 0.001 mg/L < 0.001
Iodomethane 0.001 mg/L < 0.001
Isopropyl benzene (Cumene) 0.001 mg/L < 0.001
m&p-Xylenes 0.002 mg/L < 0.002
Methylene Chloride 0.001 mg/L < 0.001
o-Xylene 0.001 mg/L < 0.001
Styrene 0.001 mg/L < 0.001
Tetrachloroethene 0.001 mg/L < 0.001
Toluene 0.001 mg/L < 0.001
trans-1.2-Dichloroethene 0.001 mg/L < 0.001
trans-1.3-Dichloropropene 0.001 mg/L < 0.001
Trichloroethene 0.001 mg/L < 0.001
Trichlorofluoromethane 0.001 mg/L < 0.001
Vinyl chloride 0.001 mg/L < 0.001
Xylenes - Total 0.003 mg/L < 0.003
Fluorobenzene (surr.) 1 % 57
4-Bromofluorobenzene (surr.) 1 % 118
Total Recoverable Hydrocarbons - 2013 NEPM Fractions
NaphthaleneN02 0.01 mg/L < 0.01
TRH >C10-C16 less Naphthalene (F2)N01 0.05 mg/L < 0.05
TRH C6-C10 0.02 mg/L < 0.02
TRH C6-C10 less BTEX (F1)N04 0.02 mg/L < 0.02
Polycyclic Aromatic Hydrocarbons
Acenaphthene 0.001 mg/L < 0.001
Acenaphthylene 0.001 mg/L < 0.001
Anthracene 0.001 mg/L < 0.001
Benz(a)anthracene 0.001 mg/L < 0.001
Benzo(a)pyrene 0.001 mg/L < 0.001
Benzo(b&j)fluorantheneN07 0.001 mg/L < 0.001
Benzo(g.h.i)perylene 0.001 mg/L < 0.001
Benzo(k)fluoranthene 0.001 mg/L < 0.001
Chrysene 0.001 mg/L < 0.001
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 21
Report Number: 536142-W
Client Sample ID QA_002
Sample Matrix Water
Eurofins | mgt Sample No. M17-Ma01315
Date Sampled Feb 27, 2017
Test/Reference LOR Unit
Polycyclic Aromatic Hydrocarbons
Dibenz(a.h)anthracene 0.001 mg/L < 0.001
Fluoranthene 0.001 mg/L < 0.001
Fluorene 0.001 mg/L < 0.001
Indeno(1.2.3-cd)pyrene 0.001 mg/L < 0.001
Naphthalene 0.001 mg/L < 0.001
Phenanthrene 0.001 mg/L < 0.001
Pyrene 0.001 mg/L < 0.001
Total PAH* 0.001 mg/L < 0.001
2-Fluorobiphenyl (surr.) 1 % 50
p-Terphenyl-d14 (surr.) 1 % 60
Total Recoverable Hydrocarbons - 2013 NEPM Fractions
TRH >C10-C16 0.05 mg/L < 0.05
TRH >C16-C34 0.1 mg/L < 0.1
TRH >C34-C40 0.1 mg/L < 0.1
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05
13C4-PFBA (surr.) 1 % 71
Perfluoropentanoic acid (PFPeA) 0.01 ug/L < 0.01
13C5-PFPeA (surr.) 1 % 81
Perfluorohexanoic acid (PFHxA) 0.01 ug/L < 0.01
13C5-PFHxA (surr.) 1 % 89
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L < 0.01
13C4-PFHpA (surr.) 1 % 80
Perfluorooctanoic acid (PFOA) 0.01 ug/L < 0.01
13C8-PFOA (surr.) 1 % 107
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01
13C5-PFNA (surr.) 1 % 88
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01
13C6-PFDA (surr.) 1 % 63
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01
13C2-PFUnDA (surr.) 1 % 56
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01
13C2-PFDoDA (surr.) 1 % 49
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L 0.01
13C2-PFTeDA (surr.) 1 % 47
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 74
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05
D3-N-MeFOSA (surr.) 1 % 41
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05
D5-N-EtFOSA (surr.) 1 % 25
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05
D7-N-MeFOSE (surr.) 1 % 43
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05
D9-N-EtFOSE (surr.) 1 % 41
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 21
Report Number: 536142-W
Client Sample ID QA_002
Sample Matrix Water
Eurofins | mgt Sample No. M17-Ma01315
Date Sampled Feb 27, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05
D5-N-EtFOSAA (surr.) 1 % 52
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05
D3-N-MeFOSAA (surr.) 1 % 52
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 84
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L < 0.01
18O2-PFHxS (surr.) 1 % 82
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
13C8-PFOS (surr.) 1 % 73
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 93
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05
13C2-6:2 FTS (surr.) 1 % 93
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01
13C2-8:2 FTS (surr.) 1 % 61
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
Ammonia (as N) 0.01 mg/L 0.04
Chloride 1 mg/L 3600
Chromium (hexavalent) 0.001 mg/L < 0.001
Nitrate (as N) 0.02 mg/L 0.07
pH 0.1 pH Units 7.3
Phosphorus reactive (as P) 0.05 mg/L < 0.05
Sulphate (as SO4) 5 mg/L 100
Suspended Solids 1 mg/L 120
Total Dissolved Solids 10 mg/L 5700
Total Organic Carbon 5 mg/L < 5
Chromium (trivalent filtered) 0.001 mg/L < 0.001
Chromium (trivalent) 0.001 mg/L 0.003
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 410
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10
Heavy Metals
Arsenic 0.001 mg/L 0.001
Arsenic (filtered) 0.001 mg/L < 0.001
Barium 0.02 mg/L 0.29
Barium (filtered) 0.02 mg/L 0.27
Beryllium 0.001 mg/L < 0.001
Beryllium (filtered) 0.001 mg/L < 0.001
Boron 0.05 mg/L < 0.05
Boron (filtered) 0.05 mg/L < 0.05
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 21
Report Number: 536142-W
Client Sample ID QA_002
Sample Matrix Water
Eurofins | mgt Sample No. M17-Ma01315
Date Sampled Feb 27, 2017
Test/Reference LOR Unit
Heavy Metals
Cadmium 0.0002 mg/L < 0.0002
Cadmium (filtered) 0.0002 mg/L < 0.0002
Chromium 0.001 mg/L 0.003
Chromium (filtered) 0.001 mg/L < 0.001
Cobalt 0.001 mg/L 0.008
Cobalt (filtered) 0.001 mg/L 0.007
Copper 0.001 mg/L 0.004
Copper (filtered) 0.001 mg/L 0.002
Lead 0.001 mg/L 0.002
Lead (filtered) 0.001 mg/L < 0.001
Manganese 0.005 mg/L 0.28
Manganese (filtered) 0.005 mg/L 0.28
Mercury 0.0001 mg/L < 0.0001
Mercury (filtered) 0.0001 mg/L < 0.0001
Nickel 0.001 mg/L 0.011
Nickel (filtered) 0.001 mg/L 0.009
Vanadium 0.005 mg/L 0.009
Vanadium (filtered) 0.005 mg/L < 0.005
Zinc 0.005 mg/L 0.062
Zinc (filtered) 0.005 mg/L 0.043
Alkali Metals
Calcium 0.5 mg/L 230
Magnesium 0.5 mg/L 320
Potassium 0.5 mg/L 9.1
Sodium 0.5 mg/L 1400
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 21
Report Number: 536142-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Total Recoverable Hydrocarbons - 1999 NEPM Fractions Melbourne Mar 03, 2017 7 Day
- Method: TRH C6-C36 - LTM-ORG-2010
Total Recoverable Hydrocarbons - 2013 NEPM Fractions Melbourne Mar 02, 2017 7 Day
- Method: TRH C6-C40 - LTM-ORG-2010
Total Recoverable Hydrocarbons - 2013 NEPM Fractions Melbourne Mar 03, 2017 7 Day
- Method: TRH C6-C40 - LTM-ORG-2010
BTEX and Naphthalene
BTEX Melbourne Mar 02, 2017 14 Day
- Method: TRH C6-C40 - LTM-ORG-2010
Volatile Organics Melbourne Mar 02, 2017 7 Days
- Method: LTM-ORG-2150 VOCs in Soils Liquid and other Aqueous Matrices
Polycyclic Aromatic Hydrocarbons Melbourne Mar 03, 2017 7 Day
- Method: USEPA 8270 Polycyclic Aromatic Hydrocarbons
pH Melbourne Mar 02, 2017 0 Hours
- Method: LTM-GEN-7090 pH in water by ISE
Phosphorus reactive (as P) Melbourne Mar 02, 2017 2 Day
- Method: APHA4500-PO4
Suspended Solids Melbourne Mar 02, 2017 7 Day
- Method: LM-LTM-INO-4100 (Suspended Solids @ 103°C - 105°C)
Total Dissolved Solids Melbourne Mar 02, 2017 7 Day
- Method: LM-LTM-INO-4110 (Total Dissolved Solids @ 178°C - 182°C)
Total Organic Carbon Melbourne Mar 02, 2017 28 Day
- Method: APHA 5310B Total Organic Carbon
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Mar 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Mar 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Mar 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Mar 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Mar 02, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Chloride Melbourne Mar 02, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Mar 02, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Mar 02, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Mar 02, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Mar 02, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Chromium (hexavalent) Melbourne Mar 02, 2017 28 Day
- Method: Cr (VI) by MGT 1170A
Heavy Metals (filtered) Melbourne Mar 06, 2017 180 Day
- Method: LTM-MET-3040 Metals in Waters by ICP-MS
Mercury (filtered) Melbourne Mar 06, 2017 28 Day
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 21
Report Number: 536142-W
Description Testing Site Extracted Holding Time
- Method: USEPA 7470/1 Mercury
Heavy Metals Melbourne Mar 06, 2017 180 Day
- Method: LTM-MET-3040 Metals in Waters by ICP-MS
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 21
Report Number: 536142-W
.Company Name: Jacobs Group (Australia) P/L VIC Order No.: Received: Mar 1, 2017 2:52 PMAddress: PO Box 312 Flinders Lane Report #: 536142 Due: Mar 8, 2017
Melbourne Phone: 03 8668 3000 Priority: 5 DayVIC 8009 Fax: 03 8668 3001 Contact Name: Ben Grasso
Project Name: EBAC GMEProject ID: IS157700
Eurofins | mgt Analytical Services Manager : Onur Mehmet
Sample Detail
pH Phosphorus reactive (as P
)
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
Polycyclic A
romatic H
ydrocarbons
Eurofins | m
gt Suite B
11
NE
PM
1999 Metals : M
etals M15
BT
EX
and Naphthalene
Volatile O
rganics
Total R
ecoverable Hydrocarbons
NE
PM
1999 Metals : M
etals M15 (F
iltered)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 18217
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 QA_002 Feb 27, 2017 Water M17-Ma01315 X X X X X X X X X X X X X
Test Counts 1 1 1 1 1 1 1 1 1 1 1 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 21
Report Number: 536142-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
4. Results are uncorrected for matrix spikes or surrogate recoveries.
5. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
6. Samples were analysed on an 'as received' basis. 7. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per Kilogram mg/l: milligrams per litre
ug/l: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100ml: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery
CRM Certified Reference Material - reported as percent recovery
Method Blank In the case of solid samples these are performed on laboratory certified clean sands.
In the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
Batch Duplicate A second piece of analysis from a sample outside of the clients batch of samples but run within the laboratory batch of analysis.
Batch SPIKE Spike recovery reported on a sample from outside of the clients batch of samples but run within the laboratory batch of analysis.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs 20-130%
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 21
Report Number: 536142-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Total Recoverable Hydrocarbons - 1999 NEPM Fractions
TRH C6-C9 mg/L < 0.02 0.02 Pass
TRH C10-C14 mg/L < 0.05 0.05 Pass
TRH C15-C28 mg/L < 0.1 0.1 Pass
TRH C29-C36 mg/L < 0.1 0.1 Pass
Method Blank
BTEX
Benzene mg/L < 0.001 0.001 Pass
Toluene mg/L < 0.001 0.001 Pass
Ethylbenzene mg/L < 0.001 0.001 Pass
m&p-Xylenes mg/L < 0.002 0.002 Pass
o-Xylene mg/L < 0.001 0.001 Pass
Xylenes - Total mg/L < 0.003 0.003 Pass
Method Blank
Volatile Organics
1.1-Dichloroethane mg/L < 0.001 0.001 Pass
1.1-Dichloroethene mg/L < 0.001 0.001 Pass
1.1.1-Trichloroethane mg/L < 0.001 0.001 Pass
1.1.1.2-Tetrachloroethane mg/L < 0.001 0.001 Pass
1.1.2-Trichloroethane mg/L < 0.001 0.001 Pass
1.1.2.2-Tetrachloroethane mg/L < 0.001 0.001 Pass
1.2-Dibromoethane mg/L < 0.001 0.001 Pass
1.2-Dichlorobenzene mg/L < 0.001 0.001 Pass
1.2-Dichloroethane mg/L < 0.001 0.001 Pass
1.2-Dichloropropane mg/L < 0.001 0.001 Pass
1.2.3-Trichloropropane mg/L < 0.001 0.001 Pass
1.2.4-Trimethylbenzene mg/L < 0.001 0.001 Pass
1.3-Dichlorobenzene mg/L < 0.001 0.001 Pass
1.3-Dichloropropane mg/L < 0.001 0.001 Pass
1.3.5-Trimethylbenzene mg/L < 0.001 0.001 Pass
1.4-Dichlorobenzene mg/L < 0.001 0.001 Pass
2-Butanone (MEK) mg/L < 0.001 0.001 Pass
2-Propanone (Acetone) mg/L < 0.001 0.001 Pass
4-Chlorotoluene mg/L < 0.001 0.001 Pass
4-Methyl-2-pentanone (MIBK) mg/L < 0.001 0.001 Pass
Allyl chloride mg/L < 0.001 0.001 Pass
Bromobenzene mg/L < 0.001 0.001 Pass
Bromochloromethane mg/L < 0.001 0.001 Pass
Bromodichloromethane mg/L < 0.001 0.001 Pass
Bromoform mg/L < 0.001 0.001 Pass
Bromomethane mg/L < 0.001 0.001 Pass
Carbon disulfide mg/L < 0.001 0.001 Pass
Carbon Tetrachloride mg/L < 0.001 0.001 Pass
Chlorobenzene mg/L < 0.001 0.001 Pass
Chloroethane mg/L < 0.001 0.001 Pass
Chloroform mg/L < 0.005 0.005 Pass
Chloromethane mg/L < 0.001 0.001 Pass
cis-1.2-Dichloroethene mg/L < 0.001 0.001 Pass
cis-1.3-Dichloropropene mg/L < 0.001 0.001 Pass
Dibromochloromethane mg/L < 0.001 0.001 Pass
Dibromomethane mg/L < 0.001 0.001 Pass
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 21
Report Number: 536142-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Dichlorodifluoromethane mg/L < 0.001 0.001 Pass
Iodomethane mg/L < 0.001 0.001 Pass
Isopropyl benzene (Cumene) mg/L < 0.001 0.001 Pass
Methylene Chloride mg/L < 0.001 0.001 Pass
Styrene mg/L < 0.001 0.001 Pass
Tetrachloroethene mg/L < 0.001 0.001 Pass
trans-1.2-Dichloroethene mg/L < 0.001 0.001 Pass
trans-1.3-Dichloropropene mg/L < 0.001 0.001 Pass
Trichloroethene mg/L < 0.001 0.001 Pass
Trichlorofluoromethane mg/L < 0.001 0.001 Pass
Vinyl chloride mg/L < 0.001 0.001 Pass
Method Blank
Total Recoverable Hydrocarbons - 2013 NEPM Fractions
Naphthalene mg/L < 0.01 0.01 Pass
TRH C6-C10 mg/L < 0.02 0.02 Pass
Method Blank
Polycyclic Aromatic Hydrocarbons
Acenaphthene mg/L < 0.001 0.001 Pass
Acenaphthylene mg/L < 0.001 0.001 Pass
Anthracene mg/L < 0.001 0.001 Pass
Benz(a)anthracene mg/L < 0.001 0.001 Pass
Benzo(a)pyrene mg/L < 0.001 0.001 Pass
Benzo(b&j)fluoranthene mg/L < 0.001 0.001 Pass
Benzo(g.h.i)perylene mg/L < 0.001 0.001 Pass
Benzo(k)fluoranthene mg/L < 0.001 0.001 Pass
Chrysene mg/L < 0.001 0.001 Pass
Dibenz(a.h)anthracene mg/L < 0.001 0.001 Pass
Fluoranthene mg/L < 0.001 0.001 Pass
Fluorene mg/L < 0.001 0.001 Pass
Indeno(1.2.3-cd)pyrene mg/L < 0.001 0.001 Pass
Naphthalene mg/L < 0.001 0.001 Pass
Phenanthrene mg/L < 0.001 0.001 Pass
Pyrene mg/L < 0.001 0.001 Pass
Method Blank
Total Recoverable Hydrocarbons - 2013 NEPM Fractions
TRH >C10-C16 mg/L < 0.05 0.05 Pass
TRH >C16-C34 mg/L < 0.1 0.1 Pass
TRH >C34-C40 mg/L < 0.1 0.1 Pass
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 21
Report Number: 536142-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Chromium (hexavalent) mg/L < 0.001 0.001 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Phosphorus reactive (as P) mg/L < 0.05 0.05 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Total Dissolved Solids mg/L < 10 10 Pass
Total Organic Carbon mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Heavy Metals
Arsenic mg/L < 0.001 0.001 Pass
Arsenic (filtered) mg/L < 0.001 0.001 Pass
Barium mg/L < 0.02 0.02 Pass
Barium (filtered) mg/L < 0.02 0.02 Pass
Beryllium mg/L < 0.001 0.001 Pass
Beryllium (filtered) mg/L < 0.001 0.001 Pass
Boron mg/L < 0.05 0.05 Pass
Boron (filtered) mg/L < 0.05 0.05 Pass
Cadmium mg/L < 0.0002 0.0002 Pass
Cadmium (filtered) mg/L < 0.0002 0.0002 Pass
Chromium mg/L < 0.001 0.001 Pass
Chromium (filtered) mg/L < 0.001 0.001 Pass
Cobalt mg/L < 0.001 0.001 Pass
Cobalt (filtered) mg/L < 0.001 0.001 Pass
Copper mg/L < 0.001 0.001 Pass
Copper (filtered) mg/L < 0.001 0.001 Pass
Lead mg/L < 0.001 0.001 Pass
Lead (filtered) mg/L < 0.001 0.001 Pass
Manganese mg/L < 0.005 0.005 Pass
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 12 of 21
Report Number: 536142-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Manganese (filtered) mg/L < 0.005 0.005 Pass
Mercury mg/L < 0.0001 0.0001 Pass
Mercury (filtered) mg/L < 0.0001 0.0001 Pass
Nickel mg/L < 0.001 0.001 Pass
Nickel (filtered) mg/L < 0.001 0.001 Pass
Vanadium mg/L < 0.005 0.005 Pass
Vanadium (filtered) mg/L < 0.005 0.005 Pass
Zinc mg/L < 0.005 0.005 Pass
Zinc (filtered) mg/L < 0.005 0.005 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Total Recoverable Hydrocarbons - 1999 NEPM Fractions
TRH C6-C9 % 98 70-130 Pass
TRH C10-C14 % 97 70-130 Pass
LCS - % Recovery
BTEX
Benzene % 88 70-130 Pass
Toluene % 98 70-130 Pass
Ethylbenzene % 101 70-130 Pass
m&p-Xylenes % 100 70-130 Pass
Xylenes - Total % 99 70-130 Pass
LCS - % Recovery
Volatile Organics
1.1-Dichloroethene % 74 70-130 Pass
1.1.1-Trichloroethane % 98 70-130 Pass
1.2-Dichlorobenzene % 95 70-130 Pass
1.2-Dichloroethane % 106 70-130 Pass
Trichloroethene % 93 70-130 Pass
LCS - % Recovery
Total Recoverable Hydrocarbons - 2013 NEPM Fractions
Naphthalene % 75 70-130 Pass
TRH C6-C10 % 105 70-130 Pass
LCS - % Recovery
Polycyclic Aromatic Hydrocarbons
Acenaphthene % 79 70-130 Pass
Acenaphthylene % 85 70-130 Pass
Anthracene % 86 70-130 Pass
Benz(a)anthracene % 85 70-130 Pass
Benzo(a)pyrene % 82 70-130 Pass
Benzo(b&j)fluoranthene % 77 70-130 Pass
Benzo(g.h.i)perylene % 77 70-130 Pass
Benzo(k)fluoranthene % 87 70-130 Pass
Chrysene % 85 70-130 Pass
Dibenz(a.h)anthracene % 83 70-130 Pass
Fluoranthene % 89 70-130 Pass
Fluorene % 84 70-130 Pass
Indeno(1.2.3-cd)pyrene % 78 70-130 Pass
Naphthalene % 86 70-130 Pass
Phenanthrene % 84 70-130 Pass
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 13 of 21
Report Number: 536142-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Pyrene % 89 70-130 Pass
LCS - % Recovery
Total Recoverable Hydrocarbons - 2013 NEPM Fractions
TRH >C10-C16 % 101 70-130 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 113 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 78 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 67 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 80 50-150 Pass
Perfluorooctanoic acid (PFOA) % 58 50-150 Pass
Perfluorononanoic acid (PFNA) % 79 50-150 Pass
Perfluorodecanoic acid (PFDA) % 71 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 74 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 83 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 87 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 83 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 67 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 79 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 108 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 93 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 74 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 78 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 80 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 67 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 76 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 73 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 80 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 64 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 79 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 82 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 83 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 83 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 84 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 85 70-130 Pass
Chloride % 105 70-130 Pass
Chromium (hexavalent) % 108 70-130 Pass
Nitrate (as N) % 90 70-130 Pass
Phosphorus reactive (as P) % 117 70-130 Pass
Sulphate (as SO4) % 94 70-130 Pass
Suspended Solids % 122 70-130 Pass
Total Dissolved Solids % 99 70-130 Pass
Total Organic Carbon % 102 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 72 70-130 Pass
LCS - % Recovery
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 14 of 21
Report Number: 536142-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Heavy Metals
Arsenic % 103 80-120 Pass
Arsenic (filtered) % 103 80-120 Pass
Barium % 101 80-120 Pass
Beryllium % 97 80-120 Pass
Boron % 102 80-120 Pass
Boron (filtered) % 102 80-120 Pass
Cadmium % 102 80-120 Pass
Cadmium (filtered) % 102 80-120 Pass
Chromium % 96 80-120 Pass
Chromium (filtered) % 96 80-120 Pass
Cobalt % 104 80-120 Pass
Cobalt (filtered) % 104 80-120 Pass
Copper % 102 80-120 Pass
Copper (filtered) % 102 80-120 Pass
Lead % 98 80-120 Pass
Lead (filtered) % 98 80-120 Pass
Manganese % 106 80-120 Pass
Manganese (filtered) % 106 80-120 Pass
Mercury % 92 75-125 Pass
Mercury (filtered) % 92 70-130 Pass
Nickel % 104 80-120 Pass
Nickel (filtered) % 104 80-120 Pass
Vanadium % 100 80-120 Pass
Zinc % 103 80-120 Pass
Zinc (filtered) % 103 80-120 Pass
LCS - % Recovery
Alkali Metals
Calcium % 92 70-130 Pass
Magnesium % 99 70-130 Pass
Potassium % 90 70-130 Pass
Sodium % 89 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Total Recoverable Hydrocarbons - 1999 NEPM Fractions Result 1
TRH C10-C14 M17-Ma00355 NCP % 105 70-130 Pass
Spike - % Recovery
Polycyclic Aromatic Hydrocarbons Result 1
Acenaphthene B17-Ma02318 NCP % 83 70-130 Pass
Acenaphthylene B17-Ma02318 NCP % 93 70-130 Pass
Anthracene B17-Ma02318 NCP % 104 70-130 Pass
Benz(a)anthracene B17-Ma02318 NCP % 103 70-130 Pass
Benzo(a)pyrene B17-Ma02318 NCP % 103 70-130 Pass
Benzo(b&j)fluoranthene B17-Ma02318 NCP % 112 70-130 Pass
Benzo(g.h.i)perylene B17-Ma02318 NCP % 91 70-130 Pass
Benzo(k)fluoranthene B17-Ma02318 NCP % 107 70-130 Pass
Chrysene B17-Ma02318 NCP % 109 70-130 Pass
Dibenz(a.h)anthracene B17-Ma02318 NCP % 88 70-130 Pass
Fluoranthene B17-Ma02318 NCP % 92 70-130 Pass
Fluorene B17-Ma02318 NCP % 86 70-130 Pass
Indeno(1.2.3-cd)pyrene B17-Ma02318 NCP % 86 70-130 Pass
Naphthalene B17-Ma02318 NCP % 81 70-130 Pass
Phenanthrene B17-Ma02318 NCP % 94 70-130 Pass
Pyrene B17-Ma02318 NCP % 92 70-130 Pass
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 15 of 21
Report Number: 536142-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Total Recoverable Hydrocarbons - 2013 NEPM Fractions Result 1
TRH >C10-C16 M17-Ma00355 NCP % 107 70-130 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Ma01571 NCP % 106 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Ma01571 NCP % 129 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Ma01571 NCP % 110 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Ma01571 NCP % 133 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Ma01571 NCP % 96 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Ma01571 NCP % 132 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Ma01571 NCP % 117 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Ma01571 NCP % 115 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Ma01571 NCP % 131 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Ma01571 NCP % 125 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Ma01571 NCP % 137 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Ma01571 NCP % 113 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Ma01571 NCP % 130 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Ma01571 NCP % 143 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Ma01571 NCP % 139 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Ma01571 NCP % 130 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Ma01571 NCP % 131 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Ma01571 NCP % 133 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Ma01571 NCP % 113 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Ma01571 NCP % 122 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Ma01571 NCP % 125 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Ma01571 NCP % 128 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Ma01571 NCP % 110 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Ma01571 NCP % 121 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Ma01571 NCP % 135 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Ma01571 NCP % 137 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Ma01571 NCP % 132 50-150 Pass
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 16 of 21
Report Number: 536142-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Ma01571 NCP % 133 50-150 Pass
Spike - % Recovery
Result 1
Ammonia (as N) M17-Ma01081 NCP % 86 70-130 Pass
Chloride M17-Ma02235 NCP % 127 70-130 Pass
Chromium (hexavalent) M17-Fe28584 NCP % 83 70-130 Pass
Nitrate (as N) M17-Ma01081 NCP % 89 70-130 Pass
Phosphorus reactive (as P) B17-Ma01016 NCP % 87 70-130 Pass
Sulphate (as SO4) M17-Ma03159 NCP % 98 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Bicarbonate Alkalinity (as CaCO3) B17-Ma00853 NCP % 108 70-130 Pass
Spike - % Recovery
Heavy Metals Result 1
Arsenic P17-Ma01719 NCP % 102 75-125 Pass
Arsenic (filtered) M17-Ma02480 NCP % 98 70-130 Pass
Barium P17-Ma01719 NCP % 100 75-125 Pass
Barium (filtered) M17-Ma02480 NCP % 93 75-125 Pass
Beryllium P17-Ma01719 NCP % 100 75-125 Pass
Beryllium (filtered) M17-Ma02480 NCP % 112 75-125 Pass
Cadmium P17-Ma01719 NCP % 100 75-125 Pass
Cadmium (filtered) M17-Ma02480 NCP % 96 70-130 Pass
Chromium P17-Ma01719 NCP % 93 75-125 Pass
Chromium (filtered) M17-Ma02480 NCP % 90 70-130 Pass
Cobalt P17-Ma01719 NCP % 102 75-125 Pass
Cobalt (filtered) M17-Ma02480 NCP % 97 75-125 Pass
Copper P17-Ma01719 NCP % 102 75-125 Pass
Copper (filtered) M17-Ma02480 NCP % 96 70-130 Pass
Lead P17-Ma01719 NCP % 94 75-125 Pass
Lead (filtered) M17-Ma02480 NCP % 93 70-130 Pass
Manganese P17-Ma01719 NCP % 107 75-125 Pass
Manganese (filtered) M17-Ma02480 NCP % 97 70-130 Pass
Mercury P17-Ma01719 NCP % 91 70-130 Pass
Mercury (filtered) M17-Ma02480 NCP % 84 70-130 Pass
Nickel P17-Ma01719 NCP % 102 75-125 Pass
Nickel (filtered) M17-Ma02480 NCP % 96 70-130 Pass
Vanadium P17-Ma01719 NCP % 96 75-125 Pass
Vanadium (filtered) M17-Ma02480 NCP % 93 75-125 Pass
Zinc P17-Ma01719 NCP % 102 75-125 Pass
Zinc (filtered) M17-Ma02480 NCP % 98 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Ma02234 NCP % 105 70-130 Pass
Magnesium M17-Ma02234 NCP % 108 70-130 Pass
Potassium M17-Ma02234 NCP % 97 70-130 Pass
Sodium M17-Ma02234 NCP % 113 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Total Recoverable Hydrocarbons - 1999 NEPM Fractions Result 1 Result 2 RPD
TRH C10-C14 M17-Ma00826 NCP mg/L 3.4 3.3 4.0 30% Pass
TRH C15-C28 M17-Ma00826 NCP mg/L 23 22 5.5 30% Pass
TRH C29-C36 M17-Ma00826 NCP mg/L 27 25 7.6 30% Pass
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 17 of 21
Report Number: 536142-W
Duplicate
Polycyclic Aromatic Hydrocarbons Result 1 Result 2 RPD
Acenaphthene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Acenaphthylene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Anthracene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Benz(a)anthracene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Benzo(a)pyrene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Benzo(b&j)fluoranthene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Benzo(g.h.i)perylene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Benzo(k)fluoranthene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Chrysene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Dibenz(a.h)anthracene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Fluoranthene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Fluorene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Indeno(1.2.3-cd)pyrene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Naphthalene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Phenanthrene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Pyrene B17-Ma02317 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Duplicate
Total Recoverable Hydrocarbons - 2013 NEPM Fractions Result 1 Result 2 RPD
TRH >C10-C16 M17-Ma00826 NCP mg/L 3.8 3.6 3.8 30% Pass
TRH >C16-C34 M17-Ma00826 NCP mg/L 42 40 6.4 30% Pass
TRH >C34-C40 M17-Ma00826 NCP mg/L 8.3 7.9 4.5 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Ma01572 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Ma01572 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Ma01572 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Ma01572 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Ma01572 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Ma01572 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Ma01572 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Ma01572 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 18 of 21
Report Number: 536142-W
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Ma01572 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Ma01572 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) M17-Ma01081 NCP mg/L 0.22 0.22 <1 30% Pass
Chloride M17-Ma02235 NCP mg/L 1800 1900 2.7 30% Pass
Chromium (hexavalent) M17-Ma01329 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Nitrate (as N) M17-Ma01081 NCP mg/L 0.19 0.20 6.0 30% Pass
pH B17-Ma00855 NCP pH Units 7.4 7.5 pass 30% Pass
Phosphorus reactive (as P) M17-Ma01315 CP mg/L < 0.05 < 0.05 <1 30% Pass
Sulphate (as SO4) M17-Ma03159 NCP mg/L 41 40 1.3 30% Pass
Suspended Solids S17-Ma01021 NCP mg/L 120 100 18 30% Pass
Total Dissolved Solids M17-Ma01361 NCP mg/L 770 810 5.0 30% Pass
Total Organic Carbon S17-Ma05448 NCP mg/L 13 13 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) B17-Ma00855 NCP mg/L 940 970 3.0 30% Pass
Carbonate Alkalinity (as CaCO3) B17-Ma00855 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Heavy Metals Result 1 Result 2 RPD
Arsenic P17-Ma01719 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Arsenic (filtered) M17-Ma02480 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Barium P17-Ma01719 NCP mg/L < 0.02 < 0.02 <1 30% Pass
Barium (filtered) M17-Ma02480 NCP mg/L < 0.02 < 0.02 <1 30% Pass
Beryllium P17-Ma01719 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Beryllium (filtered) M17-Ma02480 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Cadmium P17-Ma01719 NCP mg/L < 0.0002 < 0.0002 <1 30% Pass
Cadmium (filtered) M17-Ma02480 NCP mg/L < 0.0002 < 0.0002 <1 30% Pass
Chromium P17-Ma01719 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Chromium (filtered) M17-Ma02480 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Cobalt P17-Ma01719 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Cobalt (filtered) M17-Ma02480 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Copper P17-Ma01719 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Copper (filtered) M17-Ma02480 NCP mg/L 0.002 0.002 6.0 30% Pass
Lead P17-Ma01719 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 19 of 21
Report Number: 536142-W
Duplicate
Heavy Metals Result 1 Result 2 RPD
Lead (filtered) M17-Ma02480 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Manganese P17-Ma01719 NCP mg/L < 0.005 < 0.005 <1 30% Pass
Manganese (filtered) M17-Ma02480 NCP mg/L 0.013 0.013 1.0 30% Pass
Mercury P17-Ma01719 NCP mg/L < 0.0001 < 0.0001 <1 30% Pass
Mercury (filtered) M17-Ma02480 NCP mg/L < 0.0001 < 0.0001 <1 30% Pass
Nickel P17-Ma01719 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Nickel (filtered) M17-Ma02480 NCP mg/L 0.003 0.003 11 30% Pass
Vanadium P17-Ma01719 NCP mg/L < 0.005 < 0.005 <1 30% Pass
Vanadium (filtered) M17-Ma02480 NCP mg/L < 0.005 < 0.005 <1 30% Pass
Zinc (filtered) M17-Ma02480 NCP mg/L 0.007 0.007 1.0 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Fe17262 NCP mg/L 53 51 4.0 30% Pass
Magnesium M17-Fe17262 NCP mg/L 160 160 4.0 30% Pass
Potassium M17-Fe17262 NCP mg/L 64 62 2.0 30% Pass
Sodium M17-Fe17262 NCP mg/L 1500 1400 2.0 30% Pass
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 20 of 21
Report Number: 536142-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved No
Appropriate sample containers have been used No
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N01F2 is determined by arithmetically subtracting the "naphthalene" value from the ">C10-C16" value. The naphthalene value used in this calculation is obtained from volatiles(Purge & Trap analysis).
N02
Where we have reported both volatile (P&T GCMS) and semivolatile (GCMS) naphthalene data, results may not be identical. Provided correct sample handling protocols havebeen followed, any observed differences in results are likely to be due to procedural differences within each methodology. Results determined by both techniques have passedall QAQC acceptance criteria, and are entirely technically valid.
N04F1 is determined by arithmetically subtracting the "Total BTEX" value from the "C6-C10" value. The "Total BTEX" value is obtained by summing the concentrations of BTEXanalytes. The "C6-C10" value is obtained by quantitating against a standard of mixed aromatic/aliphatic analytes.
N07Please note:- These two PAH isomers closely co-elute using the most contemporary analytical methods and both the reported concentration (and the TEQ) apply specifically tothe total of the two co-eluting PAHs
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Onur Mehmet Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Alex Petridis Senior Analyst-Organic (VIC)
Harry Bacalis Senior Analyst-Volatile (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Joseph Edouard Senior Analyst-Organic (VIC)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Mar 09, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 21 of 21
Report Number: 536142-W
19 September 2017Subject: Groundwater Monitoring Event February 2017
IS157700-03-NP-LTR-0002 8
Attachment 2 - Quality assurance/quality control
QA/QC procedures were implemented as per Jacobs standard work procedures and comprised:
· Calibration of water quality meters and groundwater level meters prior to use and retention ofrecords of calibration;
· Engagement of laboratories accredited by the National Association of Testing Authorities (NATA)for requested analyses;
· Preservation of samples in laboratory prepared sample containers and storage on ice in aninsulated container immediately after collection under chain of custody (CoC) protocols;
· Collection and analysis of blind replicate samples at a rate of one set of replicates per 20samples collected, with all duplicate samples scheduled for the same laboratory analysis as theparent sample;
· Collection and analysis of rinsate blank samples at the end of each sampling day and use oflaboratory prepared trip blank samples to accompany each batch of samples; and
· Replacement of disposable equipment between wells and use appropriate sterile laboratoryprovided bottles with relevant preservatives.
Evaluation of the relative percentage difference (RPD) results from a comparison of replicate samplesto parent samples identified the following exceedances of the 50% acceptance criterion:
· Primary blind replicate - Total organic carbon (100%);
· Split blind replicate – Arsenic, chromium and lead (67%); and
· Split blind replicate – Vanadium (76%).
Review of the results from analysis of rinsate and trip blank samples demonstrates no detection of theanalytes tested for.
Refer to Table 2 for a summary of RPDs and Table 3 for a summary of rinsate and trip blank results.
Review of laboratory QA/QC results suggested compliance with laboratory set QA/QC objectives withthe exception of the following:
· Matrix spike recoveries for PFAS compounds were not determined due to the backgroundlevel being equal to or greater than the spike level; and
· A single matrix spike recovery for sulfate was not determined due to the background levelbeing equal to or greater than the spike level.
All analytes were analysed within the respective acceptable holding times with exception of pH asmeasured in the laboratory in almost all samples.
19 September 2017Subject: Groundwater Monitoring Event February 2017
IS157700-03-NP-LTR-0002 9
Attachment 3 – Important note about your report
The sole purpose of this report and the associated services performed by Jacobs is to provide afactual letter report in accordance with the scope of services set out in the contract between Jacobsand EBAC. That scope of services, as described in this report, was developed with EBAC.
In preparing this report, Jacobs has relied upon, and presumed accurate, any information (orconfirmation of the absence thereof) provided by EBAC and/or from other sources. Except asotherwise stated in the report, Jacobs has not attempted to verify the accuracy or completeness ofany such information. If the information is subsequently determined to be false, inaccurate orincomplete then it is possible that our observations and conclusions as expressed in this report maychange.
The passage of time, manifestation of latent conditions, changes to the regulatory evaluation criteria /standards, or impacts of future events may require further examination of the project and subsequentdata analysis, and re-evaluation of the data, findings, observations and conclusions expressed in thisreport. Jacobs has prepared this report in accordance with the usual care and thoroughness of theconsulting profession, for the sole purpose described above and by reference to applicable standards,guidelines, procedures and practices at the date of issue of this report. For the reasons outlinedabove, however, no other warranty or guarantee, whether expressed or implied, is made as to thedata, observations and findings expressed in this report, to the extent permitted by law.
This report should be read in full and no excerpts are to be taken as representative of the findings.No responsibility is accepted by Jacobs for use of any part of this report in any other context.
This report has been prepared on behalf of, and for the exclusive use of, EBAC, and is subject to, andissued in accordance with, the provisions of the contract between Jacobs and EBAC. Jacobs acceptsno liability or responsibility whatsoever for, or in respect of, any use of, or reliance upon, this report byany third party.