Upload
others
View
2
Download
0
Embed Size (px)
Citation preview
MERSEY GATEWAY
BRIDGE PROJECT
MERSEYLINK
SECTION 3: NORTH APPROACH VIADUCT PIER 1(P1) CONCEPTUAL SITE MODEL MARCH 2016 MER-DJV-REP-ENV-03-333030
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 I 17 MARCH 2016
Document Control Sheet
Rev. Status Date By Check Approved
0 Preliminary for CJV / Regulator
Review 09/06/2015 JM DT DC
1 Final Issue following CJV / Informal Regulator Review
18/09/2015 JM SNN LIB
2 Final issue following formal
board review (Ref DWP00-60-07 4_Board_01)
04/12/15 JM LE LB
3 Final issue following formal
board review (Ref DWP00-60-07 4_Board_01)
17/03/16 RE SB LB
URS Infrastructure & Environment UK Limited Royal Court Basil Close Chesterfield Derbyshire S41 7SL Tel: +44 (0) 1246 209221 Fax: +44 (0) 1246 209229 Web: www.ursglobal.com
This submission is prepared on behalf of and submitted by the Merseylink Consortium in accordance with the provisions of the Design Development Agreement for the Mersey
Gateway Bridge Project executed between Halton Borough Council and FCC Construccion, Samsung C&T Corporation and Kier Infrastructure and Overseas Limited.
Prior to the entry into a Project Agreement (between Halton Borough Council, a "Board" created by Halton Borough Council and a project company created by the Merseylink
consortium) this report may not be relied upon by any other party (save for Halton Borough Council) without the prior written agreement of one or all of FCC Construccion,
Samsung C&T Corporation and Kier Infrastructure and Overseas Limited, save to the extent that (i) disclosure and/or reliance of this report is permitted in accordance with any
purpose and intention of or related to the Design Development Agreement and (ii) disclosure is permitted by Halton Borough Council to the Board, to its advisors and otherwise in
accordance or as contemplated by the terms of the draft project agreement circulated by Halton Borough Council to the Merseylink Consortium dated 31 July 2013.
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 II 17 MARCH 2016
CONTENTS
1 INTRODUCTION ...................................................................................................... 1
1.1 GENERAL INTRODUCTION .................................................................................... 1
1.2 BACKGROUND ........................................................................................................ 2
2 GEOLOGY ................................................................................................................ 4
2.1 INTRODUCTION ...................................................................................................... 4
2.2 MADE GROUND....................................................................................................... 4
2.3 ALLUVIAL DEPOSITS .............................................................................................. 4
2.4 GLACIAL DEPOSITS ................................................................................................ 4
2.5 SANDSTONE ........................................................................................................... 5
3 HYDROGEOLOGY ................................................................................................... 6
3.1 INTRODUCTION ...................................................................................................... 6
3.2 GROUNDWATER STRIKES ..................................................................................... 6
3.3 GROUNDWATER ELEVATIONS.............................................................................. 6
3.4 GROUNDWATER FLOW DIRECTION ..................................................................... 8
4 HYDROLOGY ......................................................................................................... 10
5 ASSESSMENT OF CONTAMINATION .................................................................. 11
5.1 FIELD OBSERVATIONS ........................................................................................ 11
5.2 ASSESSMENT OF SOIL CHEMICAL DATA .......................................................... 11
5.3 ASSESSMENT OF GROUNDWATER CHEMICAL DATA ...................................... 13
5.4 SUMMARY OF COMPOUNDS OF POTENTIAL CONCERN ................................. 17
5.5 EVIDENCE OF DENSE NON-AQUEOUS PHASE LIQUIDS (DNAPL)................... 17
6 CONCEPTUAL SITE MODEL ................................................................................ 19
6.1 INTRODUCTION .................................................................................................... 19
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 III 17 MARCH 2016
6.2 SOURCE ................................................................................................................ 19
6.3 PATHWAY .............................................................................................................. 19
6.4 RECEPTORS ......................................................................................................... 20
7 CONCLUSIONS ..................................................................................................... 21
8 REFERENCES ....................................................................................................... 24
FIGURES .......................................................................................................................... A
TABLES ............................................................................................................................ B
APPENDIX A – PHOTOS OF PIER 1 ............................................................................... A
APPENDIX B – BOREHOLE LOGS (BHXX1 – BHXX5) .................................................. B
APPENDIX C – LAB REPORTS (SOIL) ........................................................................... C
APPENDIX D – LABORATORY REPORTS (GROUNDWATER)..................................... D
APPENDIX E – DEVELOPMENT TIMELINE .................................................................... E
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 IV 17 MARCH 2016
FIGURES
Figure 1 – Borehole Location Plan for Pier 1 and Lines of Cross Section
Figure 2 – Pier 1 Geological Cross Sections
TABLES
Table 1 – Groundwater Level Monitoring Data for BHXX1-BHXX5
Table 2 – Soil Analytical Data for BHXX1-BHXX5
Table 3 – Groundwater Analytical Data for BHXX1-BHXX5
Table 4 – Pier 1 Solubility Assessment for Volatile Organic Compounds (VOCs)
APPENDICES
Appendix A – Photos of Pier 1
Appendix B – Borehole Logs (BHXX1-BHXX5)
Appendix C – Lab Reports (Soil)
Appendix D – Lab Reports (Groundwater)
Appendix E – Development Timeline
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
1 Introduction
1.1 General Introduction
Following the measurement of elevated concentrations of chlorinated solvents in
borehole location BHXX3 which is very close to the secant wall which encloses the
long piles at Pier 1 (P1) it was decided that additional investigation to investigate the
potential for chlorinated solvents (at concentrations approaching saturation (i.e.
presence of DNAPL) was required within the secant wall.
This document presents a conceptual site model (CSM) that specifically relates only to
Pier P1 on the North Approach Viaduct (NAV)of the Mersey Gateway Bridge Project.
The CSM will characterise the chemical concentrations within the P1 secant wall and if
significant risks are identified (i.e. the potential presence of DNAPL which may migrate
down the shaft of the long piles) will be used to inform a remedial options appraisal
(ROA).
The objective of the P1 CSM report is not to assess if the construction works have had
an impact on concentrations of contaminants in groundwater in the area of the P1
structure. This type of assessment and discussion would be undertaken outwith the
CSM and PRA documents and in accordance with the mechanisms set out in the
WQMP. However, to allow comparison of the data to that of the works being
undertaken at P1, a time scale of the works including the installation of the secant wall
piling is provided within Appendix E. A brief summary of the piling activity is included
below for reference:
Piling at P1 time scale summary:
• 22nd January 2015 – 3rd February 2015: Installation of Cofferdams (CFA
Piling);
• 20th February 2015 – 10th March 2015: Bored Piling (Piles 1-6);
• 9th September 2015 - 27th September 2015: MSS Support (Cofferdam CFA
piling); and
• 17th September 2015 - 27th September 2015: MSS Support (Bored piling).
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
The ROA will assess the options and the best overall approach to remediate the soil
and groundwater contained within the secant pile cut-off wall surrounding the existing
P1 piles, where elevated levels of chemicals of potential concern (COPC) have been
identified, to minimise potential risks to the underlying principal aquifer (Sandstone
bedrock). The COPC are predominantly chlorinated solvents including carbon
tetrachloride and chloroform.
1.2 Background
The secant wall was constructed (as recommended in the Piling Risk Assessment
(PRA) report (MER-DJV-REP-ENV-03-333007_REV9, October 2015) at P1 prior to
the commencement of the piling activities and its design was two-fold:
1. To form a barrier and prevent the migration of elevated concentrations of
COPC inflowing to the P1 structure via groundwater within the granular alluvial
deposits from sources of contamination identified during earlier phases of the
project to the north and west. This barrier extended into the top of the
underlying low permeability glacial clay deposits; and
2. To facilitate the planned construction of the pile cap for which a ‘dry’ dewatered
excavation is required.
Four boreholes BHXX1, BHXX2, BHXX4 and BHXX5 were drilled and installed with
monitoring wells within the secant pile cut-off wall at the P1 structure between
September 2014 and April 2015. Borehole BHXX3, which is located just a few metres
immediately to the north of the secant pile cut-off wall, is also assessed in order to
make a direct comparison between COPC concentrations inside the wall with those
immediately outside of the wall. BHXX3 is the closest borehole to P1 beyond the
secant wall boundary. As this report focuses on ground conditions specifically in the
area inside the secant wall, only BHXX1-BHXX5 have been assessed in this CSM.
Information concerning the CSM of the wider area surrounding P1, is presented in
North Abutment (N1) to Pier P10 Conceptual Site Model Report (Ref. MER-DJV-REP-
ENV-03-333032 Rev 0, August 2015)
It was not possible to undertake ground investigations directly within the P1 footprint in
the early phases of the project due to this area being under water (previously the area
was part of the St Helens Canal). During later phases of groundwater investigation
works (after this section of the St Helens Canal was infilled to form a temporary road /
reclaimed land), BHXX1, BHXX2 and BHXX3 were completed in October 2014, and
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred
on the P1 structure is shown on Figure 1. Photographs showing the Pier 1 site area
are presented in Appendix A.
Soil and groundwater sampling were undertaken at each of the locations between the
end of September 2014 and early May 2015. Elevated concentrations of COPC,
specifically carbon tetrachloride, have intermittently exceeded 15,000µg/l in
groundwater from BHXX3 relating to the shallow alluvial deposits. This led to a more
focussed CSM in the area of P1 being developed to better understand the distribution
of elevated concentrations of COPC, in particular chlorinated solvents, which have
also been detected in groundwater samples taken from some of the monitoring wells
(BHXX1, BHXX4 and BHXX5) located within the secant pile cut-off wall surrounding
the P1 structure. The development of the CSM takes account of and makes reference
to the PRA.
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
2 Geology
2.1 Introduction
The geology is shown on schematic cross sections which bisect P1 from North to
South and from East to West and are presented as Figure 2. The “BHXX” series
borehole logs are presented in Appendix B.
In summary, the geological sequence within the P1 structure comprises Made Ground,
Alluvial Deposits, Glacial Deposits and Sherwood Sandstone bedrock, as outlined
below.
2.2 Made Ground
Made Ground was encountered ranging in thickness from 3.5 to 4.6m. Made Ground
was described as ‘road stone’ in BHXX1 and predominantly comprised limestone
gravel (temporary fill material). The composition of Made Ground was similar at the
other borehole locations.
2.3 Alluvial Deposits
The alluvial deposits ranged in thickness from 5.7 to 6.5m and extended to a generally
uniform depth of 10.2m bgl corresponding to an elevation of -2.2m AOD. Note that the
secant wall extends approximately 0.3m below the base of the alluvium into the top of
the glacial clays at a depth of approximately 10.5m bgl (-2.5m AOD) in order to form
an effective barrier to groundwater flow within the permeable alluvial deposits.
The alluvium can be divided into an upper cohesive layer and lower granular layer.
The relatively thin upper cohesive layer is represented by predominantly firm sandy
clay between 0.2 and 2.0m in thickness, and is underlain by a granular layer
consisting of fine to coarse sands of greater thickness (4.5 and 5.6m).
Boreholes BHXX3, BHXX4 and BHXX5 terminated at the base of the alluvium.
2.4 Glacial Deposits
Within the deeper boreholes (BHXX1 and BHXX2), glacial deposits comprising inter-
bedded layers of gravelly clays and sands were encountered as shown on the
geological cross sections. The glacial deposits extended to a depth of 43.9m bgl in
BHXX2.
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
The glacial deposits can be divided into an upper cohesive layer of gravelly clay
(approximately 2.5m to 3.0m in thickness), overlying a predominantly granular layer of
sand with gravelly clay lenses (approximately 5.0m to 6.0m in thickness), which in turn
overlies cohesive gravelly clay.
2.5 Sandstone
Depth to bedrock (Sherwood Sandstone) was proven in BHXX2 and was encountered
at 43.9m bgl. The borehole log described the solid geology as thin to thick laminations
of reddish brown fine to medium-grained sandstone. BHXX2 extended to a maximum
depth of 53.8m bgl.
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
3 Hydrogeology
3.1 Introduction
Each of the four boreholes within the P1 structure was installed as monitoring wells
which screen the encountered strata (alluvial deposits, glacial sands and sandstone)
as follows:
• BHXX4 and BHXX5 both screen the shallow groundwater body associated with
the sandy alluvial deposits (7.5 to 10.7m bgl) with a screen length of 3.2m.
• BHXX1 has a 1m screen interval against the glacial sand deposits (17.7 to
18.7m bgl)
• BHXX2 has a 10.0m screened section against the deep sandstone bedrock
aquifer (43.8 to 53.8m bgl).
Outside of the P1 structure, BHXX3 was screened across the shallow groundwater
body associated with the sandy alluvial deposits (8.5 to 11.5m bgl) with a screen
length of approximately 3.0m.
3.2 Groundwater Strikes
Within the P1 structure a groundwater strike was encountered in just one of the
boreholes, BHXX4, at 3.2m bgl in the made ground, with groundwater rising to 3.0m
bgl over a 20 minute period.
A groundwater strike was also recorded in the BHXX3 (beyond the secant wall) at
5.7m bgl at the interface between the upper cohesive alluvial clays and the underlying
alluvial sands, rising to 4.7m bgl after a period of 20 minutes.
3.3 Groundwater Elevations
The depth to groundwater measurements and corresponding groundwater elevations
are presented in Table 1 for BHXX1 to BHXX5 and summarised below. BHXX3 was
originally part of the wider groundwater monitoring network (decommissioned/ grouted
in August 2015), while the four monitoring wells within the P1 structure were destroyed
within one month of their installation as a result of construction activities. As such, a
more comprehensive dataset of groundwater levels is available for BHXX3 from
November 2014 to May 2015, while limited datasets are available for BHXX1 and
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
BHXX2 (relating to November 2014), and groundwater levels were recorded on two
occasions (29th April 2015 and 5th May 2015) at BHXX4 and BHXX5.
A review of groundwater elevations relating to the different strata are presented in the
sections below.
3.3.1 Alluvial Deposits
Three monitoring wells, BHXX3, BHXX4 and BHXX5 screen the alluvial deposits.
BHXX3 is located outside of the secant wall and inferred up hydraulic gradient of
BHXX4 and BHXX5, located inside the secant wall structure.
The depth to groundwater was measured at all three locations on the 29th April 2015
(prior to the well development of BHXX4 and BHXX5) and levels ranged from 3.70 to
3.95 m below top of casing (btoc). The corresponding groundwater elevations fit the
general trend in groundwater flow with groundwater elevation of 4.55m AOD at
BHXX3 decreasing to 4.30m AOD and 4.07m AOD at BHXX4 and BHXX5,
respectively.
On the following monitoring event (5th May 2015), this trend was not observed. The
groundwater elevation at BHXX3 rose very slightly by 0.17m to 4.72m AOD, while
within the secant wall groundwater levels rose by between 1.0 and 1.3m in BHXX4
and BHXX5 to 5.25m AOD and 5.35m AOD, respectively. It is notable that the
groundwater level within the secant wall is much higher than externally and therefore
is considered to be hydraulically isolated.
Given that the purpose of the secant wall is to act as a barrier and prevent the
movement of groundwater into and from the area within the structure, it is likely to act
as a ‘sealed bucket’ resulting in the input of waters within the secant wall artificially
raising groundwater elevations within P1. The downward infiltration of groundwater
into the underlying strata will be limited by the low permeability layer of glacial clay
deposits at the base of the alluvium.
Unfortunately, BHXX4 and BHXX5 are no longer in the groundwater monitoring
network, having been destroyed by construction activities (notably their installation
was never intended to be permanent) so it is not possible to assess this further.
However, this groundwater elevation data does suggest that the secant wall is working
as an effective groundwater flow barrier.
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
It is proposed that the greater rise in groundwater levels within the secant wall to that
outside on the 5th May 2015 and the potential for a linkage between the wider groundwater
outside of the secant wall and that within, be explored, including the potential for construction
activities at the site having had an effect on groundwater levels. This investigation
should be undertaken as part of the remediation works, verification of the remediation works,
or in the verification of the construction activities at P1 in line with the mechanisms set out
within the WQMP.
3.3.2 Glacial Sands
Groundwater level monitoring data for BHXX1 representing the deeper glacial sands
unit were collected in November 2014 and groundwater elevations (potentiometric
surface) of between 2.04 and 2.09 m AOD were measured on three occasions.
Measured groundwater levels in the glacial sands are approximately 2m lower than
those measured in the overlying Alluvium (on 30 April 2015) and indicate that the
intervening Glacial Clay layer acts as a good hydraulic barrier to groundwater flow.
The Glacial Sands are also known to be tidally influenced (refer to REP-ENV-03-
333032 Rev 0, August 2015) which could explain the lower heads measured within
this unit and highlight that they have a good permeability (compared to other horizons)
and a good connection to groundwater discharge zones (ultimately the River Mersey).
3.3.3 Sandstone
Within P1, only one monitoring well, BHXX2, was advanced to the deep sandstone
bedrock that was encountered at 43.9m bgl. Three rounds of groundwater level
monitoring were undertaken in November 2014 and the potentiometric surface was
between 4.05 to 4.19m AOD.
The groundwater elevation (potentiometric surface) associated with the sandstone
bedrock is approximately 2m higher than those measured in the overlying glacial sand
deposits. This is expected due to the depth of the sandstone and it being confined by
substantial thickness of low permeable glacial clay deposits. .
3.4 Groundwater Flow Direction
Based on data collected from previous ground investigations (see PRA), the regional
groundwater flow direction within the sandstone bedrock is inferred towards the south
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
east. The groundwater flow direction within the glacial sands and alluvial deposits in
the vicinity of the P1 structure is less well understood (due to the lack of monitoring
wells in the area which screen the same groundwater unit). The groundwater body
within the alluvial deposits (with potentiometric surface at approximately 5m bgl) could
be influenced by shallow groundwater migration from within the made ground where
cohesive alluvium between the two strata is limited or not present. In addition there is
known to be some tidal influence on groundwater flow (MER-DJV-REP-ENV-03-
333007_REV9, October 2015).
The construction of the secant wall structure also is anticipated to have an impact on
the groundwater flow behaviour within the alluvial deposits. First of all, groundwater
level monitoring data suggests that rainfall-recharge could be causing an artificial rise
in groundwater within the secant wall. Secondly, there is unlikely to be any change in
hydraulic gradient (i.e. will remain flat) inside the confines of the secant wall, as the
groundwater flow path has been severed. The piezometric head should be
maintained at a level below the blinding concrete which crates the formation level for
the pile cap since the excavation will be dewatered to facilitate construction.
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
4 Hydrology
Following the infilling of St Helens Canal, P1 is currently in an area of reclaimed land
while the construction phase of the Mersey Gateway Project is carried out.
Bowers Brook, a tributary of the River Mersey, and St Helens Canal are in close
proximity to the structure, with the brook running parallel with, and north of St Helens
Canal. The brook in this area is culverted with an open overflow channel above with a
number of interception trenches to allow flood water within the culvert to rise into the
channel / recede from the channel. Additional detail is contained within the Ramboll
reports: Bowers Brook Research Report (Ref: B4027E/AW/RE/R/027, Rev -, dated
February 2014); and Bowers Brook Interpretative Report (Ref: B4027E/AW/RE/R/028,
Rev -, dated September 2014).
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
5 Assessment of Contamination
5.1 Field Observations
The following observations indicating visual or olfactory evidence of contamination
were noted on the borehole log for BHXX1 (Glacial Sands):
• Mild organic odour (not known if from a natural or anthropogenic origin) was
noted in BHXX1 between 3.5 and 3.8m bgl within the gravelly clay alluvial
deposits (potentially the base of the Made Ground).
• An organic odour (potentially relating to a natural source) was noted between
8.5 and 9.5m bgl within the sandy alluvial deposits containing traces of organic
matter.
• A strong sulphurous odour was noted from 17.6 to 18.7m bgl within the glacial
sand deposits.
There was no visual or olfactory evidence of contamination noted on the other
borehole logs within the secant wall structure (BHXX2 (sandstone), BHXX4 and
BHXX5).
5.2 Assessment of Soil Chemical Data
Soil samples relating to BHXX1-BHXX5 were submitted to Scientific Analysis
Laboratories Ltd (SAL) for analysis between October 2014 and April 2015. A selection
of soil samples were taken from different depths. The depths ranged from 3.8m to
40.0m and were mostly from the superficial deposits below the Made Ground with a
few deeper samples representing the glacial deposits taken from BHXX2. As the
source of the Made Ground was clean, natural quarried stone (used in the reclamation
of the canal to construct a temporary haul road) this zone was not targeted.
The soil samples were tested for a number of analytical suites, namely phenols, total
petroleum hydrocarbons (TPH), polycyclic aromatic hydrocarbons (PAH), volatile
organic compounds (VOC), semi-volatile organic compounds (SVOC), metals and
inorganics. The analytical suites were selected based on findings during previous
phases of ground investigations works (refer to the PRA for more details).
The soils data are presented in Table 2. The lab reports are presented in Appendix C
for reference.
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
5.2.1 VOC in Soils
Chloroform was detected in soils samples from all five borehole locations. The soil
samples which exhibited the chloroform were from towards the base of the alluvial
deposits and top of the glacial deposits (sample depths from 8.0 to 13.5m). The
highest concentration of chloroform was 0.43 mg/kg in BHXX2 at 10.1m depth. Similar
concentrations were also reported in BHXX3 (0.35mg/kg at 10.5m), BHXX4
(0.16mg/kg at 10.3m) and BHXX5 (0.22 mg/kg at 10.0m).
At two borehole locations, BHXX1 and BHXX3, carbon tetrachloride was reported at
the base of the alluvial deposits at concentrations of 0.068 and 0.058 mg/kg,
marginally above the method detection limit (0.05mg/kg).
Tetrachloroethene was reported in two soil samples from one borehole location,
BHXX4, at concentrations of 0.073 and 0.077 mg/kg (sample depths of 10.0m and
5.2m, respectively.
These VOCs (chloroform, carbon tetrachloride and tetrachloroethene) were detected
from the alluvial deposits (and on occasions the top of the underlying glacial clay
deposits). The analytical data indicates that these VOC were not identified within soil
samples taken from the deeper glacial deposits.
Carbon disulphide was tested in soils samples from just two of the boreholes, BHXX4
and BHXX5. Concentrations ranged from 0.5 to 260mg/kg in BHXX4 with highest
concentration reported in the soil sample at 10.0m at the base of the alluvial deposits.
Concentrations ranged from 8.4 to 56mg/kg in BHXX5 and, similarly, the highest
concentration was from a soil sample at 10.0m. Carbon disulphide concentrations
decreased significantly in samples below 10m in the underlying glacial clay deposits.
5.2.2 Metals in Soils
Some elevated metal concentrations were detected at the base of the Made Ground in
BHXX2 at 3.8m, namely arsenic (380mg/kg), copper (380mg/kg), lead (390mg/kg) and
zinc (2,300 mg/kg).
Low to non-detect concentrations of metals were detected in deeper samples
collected from the underlying Alluvium, Glacial deposits and Sandstone bedrock.
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
5.2.3 Other analytical suites
Though some aliphatic and aromatic TPH fractions (carbon banding C16-C21 and
C21-C35) and PAH compounds were reported at low concentrations near to the limit
of detection in the shallowest soil sample (BHXX2 at 3.8m), TPH and PAH were not
detected in any of the other soil samples analysed by the laboratory. Phenols and
SVOC were not detected in any of the soil samples above the limit of detection.
5.3 Assessment of Groundwater Chemical Data
The groundwater sampling rounds undertaken at BHXX1-BHXX5 are as follows:
• BHXX1 and BHXX2: Three rounds on the 7th, 17th and 24th November 2014.
• BHXX3: Four rounds on 18th and 24th November 2014, 1st December 2014
and 29th April 2015.
• BHXX4 and BHXX5: Two rounds of groundwater monitoring on 29th April 2015
and 5th May 2015.
Note that additional chemical data are available for BHXX3 as this monitoring well was
part of the wider groundwater monitoring network until it was decommissioned in
August 2015. However, data from only four monitoring rounds from coincident
sampling events have been assessed in order to make direct comparisons with limited
dataset available which represents conditions inside the secant wall.
Since some monitoring wells have been destroyed it is not possible to understand how
concentrations vary spatially at any one given time at all five monitoring locations.
With this current dataset an assessment of the impact of the secant wall on
contaminant concentrations in groundwater is somewhat limited.
All groundwater samples were submitted to Envirolab for chemical analysis and tested
for the same analytical suites as for the soil samples. The results for the monitoring
rounds listed above are presented in Table 3 and summarised below. The lab reports
are presented in Appendix D for reference.
5.3.1 VOC in Groundwater
The highest concentrations of VOC in groundwater were reported on the 29th April
2015 in BHXX3, BHXX4 and BHXX5 associated with the alluvial deposits. Similar
carbon tetrachloride concentrations of 53,525µg/l and 54,234µg/l were reported in
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
BHXX4 and BHXX3, respectively (i.e. both inside and outside the bounds of the
secant wall). This is a significant increase in carbon tetrachloride concentration at
BHXX3 for the sample from 29th April 2015, as sampling and testing from the initial
three monitoring rounds in November and December 2014 gave concentrations of
between 509 and 1,316µg/l. A groundwater sample from BHXX5 reported
concentrations of 107 and 413µg/l indicating a wide variation in concentrations within
the Alluvial Sands. It is possible that the spikes in VOC concentrations (see Section
5.5 for more details) are related to the presence of globules of DNAPL within the
groundwater samples. These concentrations significantly exceed the Water
Framework Directive (WFD) Environmental Quality Standard (EQS) for fresh water
(2010) which is set at 12µg/l for carbon tetrachloride.
The next highest VOC concentrations were reported for chloroform with 14,723µg/l
reported in the sample from BHXX4 on 29th April 2014. On the same date 670µg/l and
2,330µg/l of chloroform were reported in samples from BHXX3 and BHXX5. These
concentrations exceed the EQS of 2.5µg/l.
Elevated carbon disulphide concentrations were reported in samples from BHXX4 at
1,547 and 1,486µg/l on 29th April 2015 and 5th May 2015. These concentrations are at
least an order of magnitude greater that those recorded in samples from BHXX3 and
BHXX5.
Relatively low concentrations of tetrachloroethene (between 2 and 59µg/l) were
reported in samples from BHXX3, BHXX4 and BHXX5.
Dichloromethane was reported in samples from BHXX4 at 54 and 58µg/l. Lower
concentrations were reported in samples from BHXX5 (21µg/l) on 29th April 2015 but
were not detected on the following monitoring round. This VOC was not detected in
any of the groundwater samples from BHXX3. Dichloromethane is a biodegradation
product of chloroform, so its presence could suggest that conditions are favourable for
natural attenuation processes within the alluvial deposits. Between 29th April and 5th
May 2015 there was a reduction in chlorinated solvent concentrations in BHXX4 and
BHXX5 within the bounds of the secant wall, however, it is not possible to discern
trends from two monitoring rounds over a very short period of time.
A number of other VOCs, namely chloromethane, cis-1,2-dichloroethene,
trichloroethene, 1,1-dichloropropene and 1,1,2,2-tetrachloroethene, were reported
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
only in groundwater samples from BHXX4 although concentrations just marginally
exceeded detection limits.
A large variation in COPC concentrations was reported in BHXX4 and BHXX5,
although these boreholes are located 9m apart and occupy a small volume of
groundwater which is confined by the secant wall. The predominant groundwater flow
direction in the area of P1 is assumed to be towards the south-east and so BHXX4
and BHXX5 were likely to be positioned cross gradient with respect to direction of any
plume of COPC in groundwater. It is possible that BHXX4 was located within the
COPC plume whereas BHXX5 was located on the edge of it. Since groundwater flow
is prevented by the secant wall structure, the mixing of COPC in groundwater within
the secant wall is assumed to be minimal and will occur mainly by diffusion processes,
which are very slow.
The concentrations of VOCs in groundwater from the underlying glacial sands
(BHXX1) were generally less than those reported in the alluvial deposits. However,
concentrations of two VOCs, chloroform (270 to 838µg/l) and carbon tetrachloride (71
to 215µg/l), were above their respective EQS of 2.5µg/l and 12µg/l, respectively.
VOCs were not detected in groundwater samples from the sandstone strata (BHXX2).
In summary, the data provides evidence that a migration pathway for COPC, such as
chloroform and carbon tetrachloride in groundwater, exists from the alluvium to the
underlying glacial sand deposits. Given the consistent approximate 2.5m thickness of
glacial clay measured at the P1 location, it is considered that this migration pathway
may be present at a different location up-hydraulic gradient of this area.
5.3.2 Metals in Groundwater
Within the alluvial deposits, concentrations of dissolved arsenic in groundwater
samples were particularly high, at between 7,480 and 9,780µg/l, in BHXX3. Inside the
secant wall arsenic was reported at 1,370 and 2,400µg/l at BHXX4, and between 14
and 73µg/l in BHXX5. With the exception of one sample, these results exceed the
EQS of 50µg/l for arsenic.
Elevated arsenic concentrations were also detected within the glacial sands (BHXX1)
ranging from 99 to 421µg/l, These data may also indicate that a migration pathway
from the alluvial deposits across the glacial clays to the glacial sands may be present.
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
Very low levels of arsenic (3µg/l) were reported in groundwater from the sandstone
bedrock (BHXX2). This is likely to be indicative of natural conditions given that
regional groundwater quality databases indicated mean concentrations for arsenic of
11.5µg/l and a maximum of 355µg/l recorded within the Triassic Sandstone aquifer of
the Liverpool area (BGS 2005).
A few other metals were detected within groundwater samples but they only
marginally exceeded the EQS and were not considered to be of significance:
• Alluvial Sands:
o Maximum mercury concentration of 0.4µg/l in BHXX5 compared to EQS of
0.05µg/l; and
o Maximum zinc concentrations at 21µg/l in BHXX4 compared to EQS of
8µg/l.
• Sandstone Bedrock:
o Maximum chromium concentration of 14µg/l in BHXX2 compared to EQS
of 3.4µg/) Regional sandstone quality data indicates mean concentrations
of 1.7µg/l and a maximum of 42.8µg/l (BGS 2005);
5.3.3 SVOC in Groundwater
Di-n-octyl phthalate in groundwater samples from BHXX4 and BHXX5 at 47 and
56µg/l respectively on 29th April 2015 exceeded the EQS (20µg/l). This compound was
detected once in BHXX1 on 7th November 2015 at 17µg/l and has not been detected
in the other groundwater samples. No other SVOCs were detected in the groundwater
samples.
5.3.4 Other analytical suites
PAH compounds were not detected in any of the groundwater samples, nor were
phenols. Relatively low concentrations of heavy-end aliphatic and aromatic TPH
fractions (predominantly carbon banding C21-C35) in groundwater have been
reported in samples from BHXX3 and BHXX4 (Alluvial Sands).
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
5.4 Summary of Compounds of Potential Concern
The compounds of potential concern (COPC) are found in groundwater associated
with the alluvial deposits (and to a significantly lesser degree the glacial sands) and
relate to the following VOC, SVOC and metals:
• Chloroform;
• Carbon tetrachloride;
• Tetrachloroethene;
• Carbon Disulphide;
• Dichloromethane;
• Di-n-octyl phthalate; and
• Arsenic
5.5 Evidence of Dense Non-Aqueous Phase Liquids (DNAPL)
Chlorinated solvents are typically used as neat liquids which have a density greater
than that of water. As a result chlorinated solvents are commonly known as dense
non-aqueous phase liquids, or ‘DNAPL’. When they are released into the ground,
they do not form floating layers but rather have the ability to migrate to depths below
the groundwater table. They can form pools of discrete DNAPL within geologic media
before slowly dissolving into flowing groundwater to produce dissolved-phase plumes
of COPC. More typically, DNAPL form ganglia or strings and are difficult to detect
using traditional techniques. AECOM are not aware of any discrete DNAPL layers
being detected, e.g. by using an oil-water interface probe during groundwater
monitoring events completed in the vicinity of P1 to date.
Although it is rarely possible to observe DNAPL (as free phase droplets in samples), it
is possible to infer the potential presence of DNAPL at the site using other lines of
evidence. The reported chlorinated solvent concentrations in groundwater have been
compared against their respective solubility data using guidance in Section 7.7 of the
EA’s R&D Publication 1331. The chlorinated VOC concentrations data for four
groundwater samples (two samples each from BHXX4 and BHXX5 on 29th April 2015
and 5th May 2015) are presented in Table 4.
1 An illustrated handbook of DNAPL transport and fate in the subsurface, R&D Publication 133, Environment Agency, June 2003
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
The concentration reported for carbon tetrachloride in groundwater from BHXX4 on
29th April 2015 (53,525µg/l) was 6.3% of its aqueous solubility. The percentages are
greater when taking into consideration the additive effect of all of the chlorinated
solvents that were reported in groundwater (6.6% for this particular sample).
In general, groundwater concentrations of chlorinated solvents that exceed 1% of their
aqueous solubility are indicative of the potential presence of a residual DNAPL in the
vicinity of the sample location, which could therefore be present within the water-
bearing alluvial deposits at P1.
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
6 Conceptual Site Model
6.1 Introduction
The CSM is based on current ground conditions based on the latest information
available at the time of writing.
6.2 Source
The Made Ground local to P1 is imported road stone as part of the land reclamation
works that were undertaken to facilitate the construction phases of the Mersey
Gateway Bridge. COPC were not identified in the soil samples taken from the
underlying natural deposits. However, elevated concentrations of COPC were
reported in the groundwater samples, in particular those from the alluvial deposits
(BHXX4 and BHXX5). The review of the data available suggests that the source (or
potentially multiple sources) of the COPC is located up hydraulic gradient (i.e. to the
northwest) of P1. Refer to Sections 6.3 and 7.3 of the PRA document for more details
on potential source areas.
Details about the source (including its origin, age, size, volume of COPC released to
the ground and timescales) remain unknown. As such the spatial extent (both laterally
and vertically) and flow path of the plume of COPC migrating in groundwater primarily
through the alluvial deposits in the area surrounding P1 also remains unknown.
6.3 Pathway
Based on the limited data available, the main pathway for the COPC is via
groundwater within the alluvial deposits. The construction of the secant wall (a series
of overlapping piles) has trapped chlorinated solvents within the P1 structure by virtue
of severing the pathway of contaminant movement via groundwater flow within the
alluvial deposits.
Concentrations of COPC within the glacial sand deposits (BHXX2) were generally
lower than those reported in the alluvial deposits. However, concentrations of
chloroform and carbon tetrachloride were in excess of the EQS in the glacial sands
indicating that a migration pathway for COPC in groundwater through the alluvial
deposits to the underlying glacial clay and sand deposits is already present (again
probably in areas up-hydraulic gradient of the P1 structure). These COPC, however,
were not detected in groundwater samples collected from the sandstone bedrock
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
strata (principal aquifer) indicating that the thick layers of glacial clays (of relatively low
permeability) currently affording protection to the underlying sandstone bedrock by
means of attenuation. It is likely that the main component of groundwater flow will be
laterally within the alluvial deposits. However, the secant wall barrier is locally
preventing migration via this flow path.
6.4 Receptors
In terms of controlled waters receptors, groundwater within the secant wall is laterally
cut off from surrounding surface water features. As outlined in the report section
above, a viable pollutant linkage to the underlying bedrock (principal aquifer) is
considered unlikely.
In this specific instance the COPC (i.e. chlorinated solvents) within the P1 structure
are not considered to pose potential risks to surface waters or human health
receptors.
However, the purpose of the secant wall was to prevent chlorinated solvents from
migrating into the P1 foundations and thence to the underlying strata penetrated by
the proposed piling. It is therefore apparent that a plume of groundwater impacted with
chlorinated solvents was already in situ when the secant wall was constructed.
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
7 Conclusions
The conclusions drawn from this CSM concerning the P1 structure are as follows:
• A number of COPC are trapped within the water bearing alluvial deposits
within the area bounded by the secant wall (a series of overlapping piles) at
P1. The COPC that have been identified in groundwater samples taken from
monitoring wells BHXX4 and BHXX5 are:
o Chloroform;
o Carbon tetrachloride;
o Tetrachloroethene;
o Carbon Disulphide;
o Dichloromethane;
o Di-n-octyl phthalate; and
o Arsenic
• The data provides evidence that a migration pathway for COPC, such as
chloroform and carbon tetrachloride in groundwater, exists from the Made
Ground through the alluvium to the underlying glacial till deposits. This
pathway is likely to be located in areas up-hydraulic gradient of the P1
structure.
• A large variation in concentrations was reported in BHXX4 and BHXX5,
although these boreholes are located 9m apart and occupy a small volume of
groundwater which is confined by the secant wall. The predominant
groundwater flow direction in the area of P1 is assumed to be towards the
south-east and so BHXX4 and BHXX5 were likely to be positioned cross
gradient with respect to direction of any plume of COPC in groundwater. It is
possible that BHXX4 was located within the COPC plume whereas BHXX5
was located on the edge of it. Since groundwater flow is prevented by the
secant wall structure, the mixing of COPC in groundwater within the secant
wall is assumed to be minimal and will occur mainly by diffusion processes,
which are very slow.
• The concentration reported for carbon tetrachloride in groundwater sampled
from BHXX4 on 29th April 2015 (53,525µg/l) was 6.3% of its aqueous
solubility. The percentages are greater when taking into consideration the
additive effect of all of the chlorinated solvents that were reported in
groundwater (6.6% for this particular sample). These concentrations are
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
greater than the 1% threshold and could be indicative of the possible
presence of a DNAPL within the alluvial deposits in the vicinity of this well.
• The groundwater level within the secant wall rose by between 1.0 and 1.3m in
BHXX4 and BHXX5, but this was not observed in BHXX3 outside the secant
wall. It is considered possible that rainfall-recharge could artificially raise
groundwater elevations within P1, as this additional water is trapped by the
secant wall barrier. The downward infiltration of groundwater into underlying
strata will be attenuated by the low permeability layer of glacial clay deposits
at the base of the alluvium. In addition, construction activities at the site could
also have a local impact on groundwater levels within the P1 structure.
• The exact origin of the COPC within the P1 structure remains unknown. The
groundwater flow direction within the alluvial deposits is not well understood
and therefore the presence or otherwise of a flow path for COPC migrating in
groundwater remains unclear. The findings indicate that layers of glacial clays
(of relatively low permeability) below the alluvial deposits will inhibit the
downward migration of COPC and afford protection to the underlying
sandstone bedrock. It is likely that the main component of groundwater flow
will be laterally within the alluvial deposits. However, the secant wall barrier is
locally preventing groundwater movement via this flow path.
• The COPC within the P1 structure are not currently considered to pose a
potential risks to surface waters or human health receptors.
It is apparent that a plume of groundwater impacted with chlorinated solvents was
already in situ when the secant wall was constructed. The purpose of the secant wall
was to prevent chlorinated solvents from migrating into the P1 foundations and thence
to underlying strata via the piling. However, this is not to say that the construction
works associated with the secant wall have not exacerbated the impact of existing
contaminants in the P1 area.
Assessment of the potential that construction works have had an impact on
concentrations of contaminants in groundwater in the area of the P1 structure would
be undertaken outwith the CSM and PRA documents and in accordance with the
mechanisms set out in the WQMP.
This CSM will be used to inform the remedial options appraisal and remedial strategy
which will follow in a separate document. The remedial strategy will provide details of
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
the measures required to mitigate and minimise the potential risks to controlled waters
from the P1 piling installation works.
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
8 References
• British Geological Survey (2005) Baseline Report Series: 19. The Permo-Triassic
Sandstones of Liverpool and Rufford. Authors: Griffiths K.J., Shand P and
Ingram, J. BGS Commissioned Report CR/05/131N: Environment Agency
Science Group: Air, Land & Water Technical Report NC/99/74/19.
• Mersey Gateway Bridge Project, Merseylink North Abutment (N1) and North
Approach Viaduct Piers (P0 and P1) Piling Risk Assessment. 21 January 2015,
Reference MER-DJV-REP-ENV-03-333007 Rev 7 (PRA).
• Mersey Gateway Bridge Project, Merseylink, North Abutment (N1) to Pier P10
Conceptual Site Model Report, 21 August 2015, DJV-REP-ENV-03-333032 Rev 0
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
FIGURES
Figure 1 – Borehole Location Plan for Pier 1 and Lines of Geological Cross Section
Figure 2 – Geological Cross Section
0 1 2m
SCALE (1:50)
LINE OF GEOLOGICAL CROSS SECTIONX’X’XX
X’X’
XX
YY Y’Y’
BOREHOLE LOCATIONS
KEY:
BHXX1BHXX1
BHXX5BHXX5
BHXX2BHXX2
BHXX3BHXX3
BHXX4BHXX4
BHXX1BHXX1
BOREHOLE LOCATION PLAN FORPIER 1 AND LINES OF CROSS SECTION
Title
Location
Client MERSEY GATEWAY
PIER 1
Job No:
Ref:
Date:
Drg. Size:
Scale:
App’d:
A3
as shown
Drawn:
FIGURE 1
JUNE 2015RH
JM/RH/MCH
JM
47067604
N
5/5/1524/4/15 Nov 2014
Nov 2014 Nov 2014
WaterStrike
5/5/15
WaterStrike
29/4/1529/4/15
5/5/15
BH
XX3
BH
XX4
BH
XX5
BH
XX1
BH
XX1
BH
XX2
?
9
8
7
6
5
4
3
2
1
0
-1
-2
-3
-4
-5
-6
-7
-8
-9
-10
-11
-12
-13
-14
-15
-16
Ele
vatio
n (m
AO
D)
9
8
7
6
5
4
3
2
1
0
-1
-2
-3
-4
-5
-6
-7
-8
-9
-10
-11
-12
-13
-14
-15
-16
Elevation (m
AO
D)
North South West East
X X’ Y Y’
SecantWall
SecantWall
SecantWall
SecantWall
MadeGround
MadeGround
MadeGroundMade
Ground
MadeGround
Firm CLAYCohesive AlluviumConfining layer?
Water bearingALLUVIUM(granular)
GLACIALCLAY
GLACIALCLAY
End of Borehole@25m bgl
GLACIALSAND
MadeGround
Soft possibleMade Ground
MadeGround
Soft CLAY
Firm sandyCLAY Firm sandy
CLAY
Firm siltyCLAY
Firm silty &sandy CLAY
Firm sandyCLAY
SANDSAND
SAND
SAND
SAND
SAND
SAND
SAND
Sandy CLAy
SAND
SAND
SANDSAND
SAND
SAND
GravellyCLAY
GravellyCLAY
GravellyCLAY
GravellyCLAY
GravellyCLAY
GravellyCLAY
GravellyCLAY
GravellyCLAY
GravellyCLAY
GravellyCLAY
GravellyCLAY
BHXX2 - Slotted sectionbetween 43.8 & 53.8m bgl
with response zone inSandstone bedrock.
Piles advanced intocompetent bedrockapproximately 45mbgl
Piles advanced intocompetent bedrock
approximately 45mbgl
GravellyCLAY
GravellyCLAY
GravellyCLAY
MadeGround
GLACIALCLAY
ALLUVIUM
GLACIALSAND
0 1 2m
SCALEX’
X
Y Y’BHXX5
BHXX2
BHXX3
BHXX4
BHXX1
N
GEOLOGICAL CROSS SECTION
KEY:
MADE GROUND
Title
Location
Client MERSEY GATEWAY
PIER 1
Job No:
Ref:
Date:
Drg. Size:
Scale:
App’d:
A3
as shown
Drawn:
FIGURE 2
AUG 2015RH
JM/RH/MCH
JM
47067604
MADE GROUND
COHESIVE ALLUVIUMSOFT CLAY
COHESIVE ALLUVIUMFIRM SANDY CLAY
ALLUVIUM (GRANULAR)
GLACIAL CLAY
GLACIAL SAND
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 17 MARCH 2016
TABLES
Table 1 – Groundwater Level Monitoring Data for BHXX1-BHXX5
Table 2 – Soil Analytical Data for BHXX1-BHXX5
Table 3 – Groundwater Analytical Data for BHXX1-BHXX5
Table 4 – Pier 1 Solubility Assessment for Volatile Organic Compounds (VOCs)
Table 1
Groundwater Elevation Data for Monitoring Wells BHXX1 - BHXX5
Monitoring Well Date
Depth to Water
(Corrected to
Ground Level)
Depth to Base
(Corrected to
Ground Level)
Ground Level
Elevation (m AOD)
Groundwater
Elevation (m AOD)
BHXX1 07/11/2014 5.58 19.85 7.62 2.04
17/11/2014 5.53 18.41 7.62 2.09
24/11/2014 5.53 18.41 7.62 2.09
BHXX2 07/11/2014 3.77 54.25 7.91 4.14
17/11/2014 3.86 54.23 7.91 4.05
24/11/2014 3.83 54.25 7.91 4.09
BHXX3 18/11/2014 4.10 11.23 8.50 4.40
24/11/2014 3.99 11.22 8.50 4.51
01/12/2014 4.05 11.11 8.50 4.45
04/02/2015 3.55 11.19 8.50 4.95
03/03/2015 3.67 11.19 8.50 4.83
10/04/2015 3.68 11.12 8.50 4.82
15/04/2015 3.84 11.13 8.50 4.66
21/04/2015 3.73 11.11 8.50 4.77
29/04/2015 3.95 11.10 8.50 4.55
05/05/2015 3.78 11.11 8.50 4.72
15/05/2015 4.00 11.11 8.50 4.50
BHXX4
29/04/2015 (Initial
level prior to well
development) 3.70 10.73 8.0 4.30
05/05/2015 2.73 10.74 8.0 5.27
BHXX5
29/04/2015 (Initial
Level prior to well
development) 3.94 10.79 8.00 4.07
05/05/2015 2.66 10.81 8.00 5.35
Notes:
Monitoring wells BHXX4 and BHXX5 were not surveyed and therefore ground level datum elevation has been
estimated relative to BHXX1 and BHXX2.
Monitoring wells BHXX1, BHXX2, BHXX4 and BHXX5 have been destroyed. BHXX3 remains in wider site monitoring
network.
Pier 1 CSM
Mersey Gateway Bridge Project August 2015
Table 2
Soil Analytical Results for Pier 1
Mersey Gateway Bridge Project
Location
Average Depth (m) 4.3 5.2 10 10.2 10.3 4.7 6 8 10 10.4
Date 21/04/2015 21/04/2015 22/04/2015 22/04/2015 22/04/2015 23/04/2015 24/04/2015 24/04/2015 24/04/2015 27/04/2015Lab Report Number 754221 754221 754221 754221 754221 754221 754221 754221 754221 754221 754221 754235 754235 478734 478734 478734 478734 475292 478734 478734 478734 478734 475292
PHENOL
2-chlorophenol mg/kg 0.1 0.0000801#3
0.04#4 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
2-methylphenol mg/kg 0.1 0.339#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
2-nitrophenol mg/kg 0.1 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
2,4-dichlorophenol mg/kg 0.1 0.0000969#3
0.00646#4 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
2,4-dimethylphenol mg/kg 0.1 0.204#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
2,4,6-trichlorophenol mg/kg 0.1 0.129#3 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
4-nitrophenol mg/kg 0.1 <0.5 - - - - <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - - - - - - <0.5 - - - - <0.5
Pentachlorophenol mg/kg 0.1 0.00981#3
0.000436#4 <0.5 - - - - <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - - - - - - <0.5 - - - - <0.5
Phenol mg/kg 0.1 0.569#5
0.000755#4 <0.2 - - - - <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 - - - - - - <0.1 - - - - <0.1
TPH
>C10-C35 mg/kg 1 <1 - - - - 52 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1
>C5-C6 Aliphatics mg/kg 0.1 63.2#2 <0.2 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
>C6-C8 Aliphatics mg/kg 0.1 164#2 <0.2 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
>C8-C10 Aliphatics mg/kg 0.1 19.6#2 <0.2 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
>C10-C12 Aliphatics mg/kg 1 146#2 <1 - - - - <1 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1
>C12-C16 Aliphatics mg/kg 2 3,230#2 <2 - - - - <2 <2 <2 <2 <2 <2 - - - - - - <2 - - - - <2
>C16-C21 Aliphatics mg/kg 1 379,000#2 <1 - - - - 2 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1
>C16-C35 Aliphatics mg/kg <5 - - - - 4 <5 <5 <5 <5 <5 - - - - - - <5 - - - - <5
>C21-C35 Aliphatics mg/kg 4 4,550,000#2 <4 - - - - <4 <4 <4 <4 <4 <4 - - - - - - <4 - - - - <4
>EC6-EC7 Aromatics mg/kg 0.1 0.00207#1
0.0207#4 <0.2 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
>EC7-EC8 Aromatics mg/kg 0.1 0.324#2
0.0231#4 <0.2 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
>EC8-EC10 Aromatics mg/kg 0.1 0.972#2 <0.2 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
>EC10-EC12 Aromatics mg/kg 1 0.457#2 <1 - - - - <1 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1
>EC12-EC16 Aromatics mg/kg 1 0.906#2 <1 - - - - <1 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1
>EC16-EC21 Aromatics mg/kg 1 2.55#2 <1 - - - - 5 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1
>EC21-EC35 Aromatics mg/kg 1 22.7#2 <1 - - - - 16 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1
VOC
Naphthalene mg/kg 0.1 0.008#11
0.0032#4 <0.1 - - - - 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Dichlorodifluoromethane mg/kg 0.05 0.365#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
MTBE mg/kg 0.01 0.0991#11
0.562#8 <0.02 - - - - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - - - - - - <0.01 - - - - <0.01
Chloromethane mg/kg 0.05 0.00174#3 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Vinyl chloride mg/kg 0.05 0.0000821#1 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Bromomethane mg/kg 0.05 0.000693#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Chloroethane mg/kg 0.05 2.76#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Trichlorofluoromethane mg/kg 0.05 0.439#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
1,1-dichloroethene mg/kg 0.05 0.00743#3 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 - <0.05 <0.05 <0.05 <0.05 -
Dichloromethane mg/kg 0.05 0.0015#3
0.0015#4 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
trans-1,2-dichloroethene mg/kg 0.05 0.0657#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
1,1-dichloroethane mg/kg 0.05 0.000343#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
cis-1,2-dichloroethene mg/kg 0.05 0.00471#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
2,2-dichloropropane mg/kg 0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Bromochloromethane mg/kg 0.05 0.00884#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Chloroform mg/kg 0.059e99 see trihalomethanes
#10.000375
#4 <0.1 0.094 <0.05 <0.05 <0.05 <0.05 0.43 0.062 <0.05 <0.05 <0.05 0.35 0.059 <0.05 <0.05 <0.05 <0.05 0.16 <0.05 <0.05 0.078 0.22 <0.05
1,1,1-trichloroethane mg/kg 0.05 0.695#3
0.0348#4 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
1,1-dichloropropene mg/kg 0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Carbon tetrachloride mg/kg 0.05 0.00243#1
0.0097#4 <0.1 0.068 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 0.058 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
1,2-dichloroethane mg/kg 0.05 0.00025#1
0.000832#4 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Benzene mg/kg 0.01 0.00019#1
0.0019#4 <0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Trichloroethene mg/kg 0.05 see sum of PCE and TCE 0.00346#4 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
1,2-dichloropropane mg/kg 0.05 0.0000152#1 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Dibromomethane mg/kg 0.05 0.00101#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Bromodichloromethane mg/kg 0.05 0.00002#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
cis-1,3-dichloropropene mg/kg 0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Toluene mg/kg 0.01 0.324#3
0.0231#4 <0.02 <0.01 <0.01 0.071 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
trans-1,3-dichloropropene mg/kg 0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
1,1,2-trichloroethane mg/kg 0.05 0.0000719#5
0.103#4 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Tetrachloroethene mg/kg 0.05 see sum of PCE and TCE 0.00617#4 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 0.077 0.073 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
1,3-dichloropropane mg/kg 0.05 0.0000149#1 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Chlorodibromomethane mg/kg 0.059e99 see trihalomethanes
#1 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
1,2-dibromoethane mg/kg 0.05 0.0000132#1 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Chlorobenzene mg/kg 0.05 0.166#3 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
1,1,1,2-tetrachloroethane mg/kg 0.05 0.000431#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Ethylbenzene mg/kg 0.01 0.285#3
0.019#7 <0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Xylene (m & p) mg/kg 0.01 <0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Xylene Total mg/kg 0.48#3
0.0288#4 <0.04 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02
Xylene (o) mg/kg 0.019e99 see Xylene Total
#1 <0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Styrene mg/kg 0.05 0.0139#3
0.0347#7 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Bromoform mg/kg 0.059e99 see trihalomethanes
#1 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Isopropylbenzene mg/kg 0.05 1.06#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
1,1,2,2-tetrachloroethane mg/kg 0.05 0.0000198#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Bromobenzene mg/kg 0.05 0.0438#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
1,2,3-trichloropropane mg/kg 0.05 1.78E-7#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
n-propylbenzene mg/kg 0.05 1.66#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
2-chlorotoluene mg/kg 0.05 0.367#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
1,3,5-trimethylbenzene mg/kg 0.05 0.184#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
4-chlorotoluene mg/kg 0.05 0.496#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
tert-butylbenzene mg/kg 0.05 3.76#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
1,2,4-trimethylbenzene mg/kg 0.05 0.0431#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
sec-butylbenzene mg/kg 0.05 25.4#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
p-isopropyltoluene mg/kg 0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
1,3-dichlorobenzene mg/kg 0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05
1,4-dichlorobenzene mg/kg 0.05 0.439#3 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05
1,2-dichlorobenzene mg/kg 0.05 1.43#3 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05
1,2,4-trichlorobenzene mg/kg 0.1 0.00509#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Hexachlorobutadiene mg/kg 0.1 0.0132#3
0.0022#4 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
1,2-Dichloroethene mg/kg 0.00658#3 <0.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Trihalomethanes mg/kg 0.0112#1 <0.4 0.169 <0.2 <0.2 <0.2 <0.2 0.505 0.137 <0.2 <0.2 <0.2 0.425 0.134 <0.2 <0.2 <0.2 <0.2 0.235 <0.2 <0.2 0.153 0.295 <0.2
Carbon disulfide mg/kg 0.1 0.259#5 - - - - - - - - - - - - - 160 73 260 65 0.5 8.4 9.7 10 56 <0.1
PAH
Acenaphthylene mg/kg 0.1 0.0662#11 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Acenaphthene mg/kg 0.1 0.0851#11 <0.1 - - - - 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Fluorene mg/kg 0.1 0.0681#11 <0.1 - - - - 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Phenanthrene mg/kg 0.1 0.0441#11 <0.1 - - - - 1.2 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Anthracene mg/kg 0.1 1.02#11
0.00113#4 <0.1 - - - - 0.4 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Fluoranthene mg/kg 0.1 0.146#11
0.00364#4 <0.1 - - - - 2 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Pyrene mg/kg 0.1 0.292#11 <0.1 - - - - 1.6 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Benzo(a)anthracene mg/kg 0.1 0.0155#11 <0.1 - - - - 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Chrysene mg/kg 0.1 0.11#11 <0.1 - - - - 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Benzo(a)pyrene mg/kg 0.1 0.00258#1
0.0129#4 <0.1 - - - - 0.5 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Indeno(1,2,3-c,d)pyrene mg/kg 0.19e99 see sum of 4 PAHs
#1 <0.1 - - - - 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Dibenzo(a,h)anthracene mg/kg 0.1 0.00372#11 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Benzo(g,h,i)perylene mg/kg 0.19e99 see sum of 4 PAHs
#1 <0.1 - - - - 0.3 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Benzo(b)fluoranthene mg/kg 0.19e99 see sum of 4 PAHs
#1 <0.1 - - - - 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Benzo(k)fluoranthene mg/kg 0.19e99 see sum of 4 PAHs
#1 <0.1 - - - - 0.3 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
5 9.5 10 18.7 25
BHXX1 BHXX2 BHXX3 BHXX4 BHXX5
10.5 11.5
###### ###### ###### ###### ###### ###### ###### ######
3.8 10.1 13.5 18.5 24 40
######
Units Me
tho
d D
ete
ctio
n
Lim
it
GA
C_
WT
V_
EN
/W
A_
DW
S_
[EN
_b
/g]
_S
AN
D0
.2%
TO
C
GA
C_
WT
V_
EN
/W
A_
EQ
S-
Fre
sh
_[E
N_
b/g
]_S
AN
D0
.2%
TO
C
###### ###### ###### ######
Pier 1 CSM
Mersey Gateway Bridge Project
AECOM
Page 1 of 2 August 2015
Table 2
Soil Analytical Results for Pier 1
Mersey Gateway Bridge Project
Location
Average Depth (m) 4.3 5.2 10 10.2 10.3 4.7 6 8 10 10.4
Date 21/04/2015 21/04/2015 22/04/2015 22/04/2015 22/04/2015 23/04/2015 24/04/2015 24/04/2015 24/04/2015 27/04/2015Lab Report Number 754221 754221 754221 754221 754221 754221 754221 754221 754221 754221 754221 754235 754235 478734 478734 478734 478734 475292 478734 478734 478734 478734 475292
5 9.5 10 18.7 25
BHXX1 BHXX2 BHXX3 BHXX4 BHXX5
10.5 11.5
###### ###### ###### ###### ###### ###### ###### ######
3.8 10.1 13.5 18.5 24 40
######
Units Me
tho
d D
ete
ctio
n
Lim
it
GA
C_
WT
V_
EN
/W
A_
DW
S_
[EN
_b
/g]
_S
AN
D0
.2%
TO
C
GA
C_
WT
V_
EN
/W
A_
EQ
S-
Fre
sh
_[E
N_
b/g
]_S
AN
D0
.2%
TO
C
###### ###### ###### ######
Benzo(b)&(k)fluoranthene mg/kg 0.00628#4 <0.2 - - - - 0.9 <0.2 <0.2 <0.2 <0.2 <0.2 - - - - - - <0.2 - - - - <0.2
PAHs (sum of 4) mg/kg 0.0174#1 <0.4 - - - - 1.4 <0.4 <0.4 <0.4 <0.4 <0.4 - - - - - - <0.4 - - - - <0.4
PAH 17 Total mg/kg 1.6 <1.6 - - - - 9.1 <1.6 <1.6 <1.6 <1.6 <1.6 - - - - - - <1.6 - - - - <1.6
Coal Tar (Bap as surrogate marker) mg/kg <0.1 - - - - 0.5 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
SVOC
Coronene mg/kg 0.1 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
2,4,5-trichlorophenol mg/kg 0.1 0.0324#3 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
4-chloro-3-methylphenol mg/kg 0.1 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
2-chloronaphthalene mg/kg 0.1 3.16#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
2-methylnaphthalene mg/kg 0.1 0.106#3 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Bis(2-ethylhexyl) phthalate mg/kg 0.1 0.0883#3
0.0143#4 <0.1 - - - - <0.1 <0.1 0.4 0.2 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Butyl benzyl phthalate mg/kg 0.1 0.0616#5
0.077#7 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Di-n-butyl phthalate mg/kg 0.1 3.16#5
0.0281#7 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Di-n-octyl phthalate mg/kg 0.1 29.7#5
2.97#7 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Diethylphthalate mg/kg 0.1 4.84#5
0.0646#7 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Dimethyl phthalate mg/kg 0.1 0.146#7 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
2-nitroaniline mg/kg 0.1 0.0413#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
2,4-Dinitrotoluene mg/kg 0.1 0.0000775#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
2,6-dinitrotoluene mg/kg 0.1 0.0000179#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
3-nitroaniline mg/kg 0.1 <0.5 - - - - <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - - - - - - <0.1 - - - - <0.1
4-bromophenyl phenyl ether mg/kg 0.1 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
4-chloroaniline mg/kg 0.1 0.0000866#5 <0.5 - - - - <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - - - - - - <0.5 - - - - <0.5
4-chlorophenyl phenyl ether mg/kg 0.1 <0.5 - - - - <0.1 <0.5 <0.5 <0.5 <0.5 <0.5 - - - - - - <0.1 - - - - <0.1
4-nitroaniline mg/kg 0.1 0.00154#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.5 - - - - <0.5
Azobenzene mg/kg 0.1 0.000485#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Bis(2-chloroethoxy) methane mg/kg 0.1 0.003#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Bis(2-chloroethyl)ether mg/kg 0.1 0.0000027#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Carbazole mg/kg 0.1 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Dibenzofuran mg/kg 0.1 0.0817#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.5 - - - - <0.1
Hexachlorobenzene mg/kg 0.1 0.0678#3
0.000678#4 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Hexachlorocyclopentadiene mg/kg 0.1 12.4#5 <0.5 - - - - <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - - - - - - <0.5 - - - - <0.5
Hexachloroethane mg/kg 0.1 0.00399#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Isophorone mg/kg 0.1 0.0105#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Nitrobenzene mg/kg 0.1 0.0000301#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Bis(2-chloroisopropyl) ether mg/kg 0.1 0.0000673#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1
Phenolics
2,4-dinitrophenol mg/kg 0.1 0.0237#5 <0.5 - - - - <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - - - - - - <0.1 - - - - <0.5
3-&4-methylphenol mg/kg 0.1 <0.1 - - - - 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - - - - - - -
3,4-Dimethylphenol mg/kg 0.1 0.00836#5 - - - - - - - - - - - - - - - - - <0.1 - - - - <0.1
Phenols (Mono) mg/kg 1 <1 - - - - <1 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1
Metals
Arsenic mg/kg 2 32#12
32#12 49 - - - - 380 24 7 8 8 6 - - - - - - 8 - - - - 10
Barium mg/kg 1 28.7#3 42 - - - - 370 92 47 110 140 88 - - - - - - 110 - - - - 100
Beryllium mg/kg 2 42.5#5 <2 - - - - <2 <2 <2 <2 <2 <2 - - - - - - <2 - - - - <2
Boron mg/kg 1 10#1
20.1#7 <1 - - - - <1 <1 <1 <1 <1 <1 - - - - - - - - - - - -
Cadmium mg/kg 1 1#12
1#12 <1 - - - - 6 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1
Chromium (III+VI) mg/kg 1 59.5#12
59.5#12 10 - - - - 38 27 6 27 33 24 - - - - - - 26 - - - - 23
Copper mg/kg 1 62#12
62#12 19 - - - - 380 23 5 19 23 13 - - - - - - 27 - - - - 14
Lead mg/kg 1 180#12
180#12 38 - - - - 390 18 4 11 13 7 - - - - - - 16 - - - - 8
Mercury mg/kg 1 0.5#12
0.5#12 <1 - - - - 5 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1
Nickel mg/kg 1 42#12
42#12 10 - - - - 39 30 8 30 37 26 - - - - - - 31 - - - - 27
Selenium mg/kg 3 0.5#1 <3 - - - - <3 <3 <3 <3 <3 <3 - - - - - - <3 - - - - <3
Vanadium mg/kg 1 1.09#5
0.253#7 11 - - - - 23 27 7 26 31 25 - - - - - - 25 - - - - 22
Zinc mg/kg 1 224#12
224#12 130 - - - - 2,300 120 28 53 63 41 - - - - - - 110 - - - - 42
Boron (Water Soluble) mg/kg 1 - - - - - - - - - - - - - - - - - <1 - - - - <1
Chromium (hexavalent) mg/kg 1 0.902#1
0.0613#4 <1 - - - - <1 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1
Organics
Fraction Organic Carbon None - - - - - - - - - - - - - - - - - 0.0064 - - - - 0.0031
Inorganics
Water_Soluble_Sulphate g/L 0.01 - - - - - - - - - - - - - - - - - 0.31 - - - - 0.91
Sulphur % 0.01 - - - - - - - - - - - - - - - - - 0.06 - - - - 0.09
Total Sulphur - 0.01 0.13 - - - - 1.1 0.13 0.03 0.05 0.06 0.03 - - - - - - - - - - - -
Cyanide (Free) mg/kg 1 0.497#1
0.00994#4 <1 - - - - <1 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1
Sulphate mg/l 10 120 - - - - 1,100 510 220 180 160 50 - - - - - - - - - - - -
Sulphide mg/kg 1 1 - - - - 20 <1 <1 <1 <1 <1 - - - - - - - - - - - -
Moisture Content 105C % 0.1 - - - - - - - - - - - - - 31 23 27 8.5 15 36 23 21 17 -
Cyanide Total mg/kg 1 <1 - - - - 3 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1
Moisture Content (dried @ 40°C) % 0.1 24 20 11 22 23 44 15 18 20 22 14 19 14 - - - - - - - - - -
Easily Liberated Sulphide mg/kg 1 - - - - - - - - - - - - - - - - - <1 - - - - <1
pH pH_Units 7.8 - - - - 7.4 8 8.1 8.3 8.2 8.5 - - - - - - 8.3 - - - - 8.1
Asbestos
Asbestos Containing Material None ND - - - - ND ND ND ND ND ND - - - - - - ND - - - - -
Comments
#1 WS Regs 2010 (Eng/Wal)
#2 WHO Petroleum In DW 2008
#3 WHO DWG 2011
#4 WFD EQS 2010 Fresh (Eng/Wal)
#5 USEPA RSL (tapwater)
#6 SEPA WAT-SG-53 Fresh EQS - MAC - 2013
#7 SEPA WAT-SG-53 Fresh EQS - AA - 2013
#8 PNEC (EU REACH) - Freshwater
#9 New Hampshire DES (2009)
#10 California Draft health protective concentration
#11 Calc WHO
#12 AECOM Pragmatic CW/WE Soil Criteria - Eng
GAC: Generic Assessment Criteria
(blank): No assessment criteria available
Sol: Unacceptable risk not achieved due to calculated target above solubility limit
- : Not analysed
ND: Not Detected
DWS: Drinking Water Standard
EQS: Environmental Quality Standard
Key
XXX Exceedance of GAC_WTV_EN/WA_DWS_[EN_b/g]_SAND0.2%TOC
XXX Exceedance of GAC_WTV_EN/WA_EQS-Fresh_[EN_b/g]_SAND0.2%TOC
Pier 1 CSM
Mersey Gateway Bridge Project
AECOM
Page 2 of 2 August 2015
Table 3
Groundwater Analytical Results for Pier 1
Mersey Gateway Bridge Project
Location
WellDate 07/11/2014 17/11/2014 24/11/2014 07/11/2014 17/11/2014 24/11/2014 18/11/2014 24/11/2014 01/12/2014 29/04/2015 29/04/2015 05/05/2015 29/04/2015 05/05/2015
PHENOL
2-chlorophenol µg/L 0.1#3
50#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
2-methylphenol µg/L 930#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
2-nitrophenol µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
2,4-dichlorophenol µg/L 0.3#3
20#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
2,4-dimethylphenol µg/L 360#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
2,4,6-trichlorophenol µg/L 200#3 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
4-nitrophenol µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Pentachlorophenol µg/L 9#3
0.4#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Phenol µg/L 5,800#5
7.7#4 <1 - - <1 - - - - - - <1 1 <1 1
TPH
>C5-C6 Aliphatics µg/L 15,000#2 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
>C6-C8 Aliphatics µg/L 15,000#2 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
>C8-C10 Aliphatics µg/L 300#2 <1 <1 <1 <1 <1 <1 <1 <1 <1 - 1 <1 1 <1
>C10-C12 Aliphatics µg/L 300#2 <5 <5 <5 <5 <5 <5 <5 <5 <5 - 8 <5 <5 <5
>C12-C16 Aliphatics µg/L 300#2 <5 <5 <5 <5 <5 <5 <5 <5 <5 - <5 <5 <5 <5
>C16-C21 Aliphatics µg/L 300#2 <5 <5 <5 <5 <5 <5 <5 10 <5 - <5 15 <5 <5
>C21-C35 Aliphatics µg/L 300#2 <5 <5 <5 <5 <5 <5 <5 208 <5 - <5 14 <5 <5
>C5-C35 Aliphatics µg/L <5 <5 <5 <5 <5 <5 <5 218 <5 - 9 28 <5 <5
>EC5-EC7 Aromatics µg/L 1#1
10#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
>EC7-EC8 Aromatics µg/L 700#2
50#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 1 <1 <1
>EC10-EC12 Aromatics µg/L 90#2 <5 <5 <5 <5 <5 <5 <5 <5 <5 - <5 <5 <5 <5
>EC12-EC16 Aromatics µg/L 90#2 <5 <5 <5 <5 <5 <5 <5 <5 <5 - <5 <5 <5 <5
>EC16-EC21 Aromatics µg/L 90#2 <5 <5 <5 <5 <5 <5 <5 <5 <5 - <5 <5 <5 <5
>EC21-EC35 Aromatics µg/L 90#2 <5 <5 <5 <5 <5 <5 <5 51 <5 - <5 <5 <5 <5
>EC5-EC35 Aromatics µg/L <5 <5 <5 <5 <5 <5 <5 51 <5 - <5 - <5 -
VOC
Naphthalene µg/L 6#11
2.4#4 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 0.03 0.02 0.02 - <1 - 0.06 <1 - 0.06 <1 - 0.02 <0.01
Dichlorodifluoromethane µg/L 200#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
MTBE µg/L 900#11
5,100#8 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Chloromethane µg/L 20#3 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 22 27 7 <1
Vinyl chloride µg/L 0.5#1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Bromomethane µg/L 7.5#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Chloroethane µg/L 21,000#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Trichlorofluoromethane µg/L 1,100#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,1-dichloroethene µg/L 30#3 <1 <1 <1 <1 <1 <1 3 <1 <1 <1 2 2 <1 <1
Dichloromethane µg/L 20#3
20#4 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 58 54 21 <5
trans-1,2-dichloroethene µg/L 360#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,1-dichloroethane µg/L 2.7#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
cis-1,2-dichloroethene µg/L 36#5 <1 <1 <1 <1 <1 <1 3 3 3 3 3 2 <1 <1
2,2-dichloropropane µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Bromochloromethane µg/L 83#5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
Chloroform µg/L9e99 see trihalomethanes
#12.5
#4 838 423 270 <25 <25 <25 867 188 206 670 14,723 >3,303 2,330 587
1,1,1-trichloroethane µg/L 2,000#3
100#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 2 <1 <1
1,1-dichloropropene µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 14 <1 <1 <1
Carbon tetrachloride µg/L 3#1
12#4 71 55 215 <1 <1 <1 1,316 748 509 54,234 53,525 >6,542 413 107
1,2-dichloroethane µg/L 3#1
10#4 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 3 <2
Benzene µg/L 1#1
10#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 - 1 <1 <1 <1
Trichloroethene µg/L9e99 see sum of PCE and TCE
#110
#4 <1 <1 <1 <1 <1 <1 2 2 2 2 6 6 <1 <1
1,2-dichloropropane µg/L 0.1#1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Dibromomethane µg/L 8#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Bromodichloromethane µg/L 0.13#5 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
cis-1,3-dichloropropene µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Toluene µg/L 700#3
50#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 - 1 1 <1 <1
trans-1,3-dichloropropene µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,1,2-trichloroethane µg/L 0.28#5
400#4 <1 <1 <1 <1 <1 <1 6 <1 <1 <1 <1 <1 <1 <1
Tetrachloroethene µg/L9e99 see sum of PCE and TCE
#110
#4 <1 <1 <1 <1 <1 <1 14 14 19 39 59 53 7 2
1,3-dichloropropane µg/L 0.1#1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Chlorodibromomethane µg/L9e99 see trihalomethanes
#1 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3
1,2-dibromoethane µg/L 0.1#1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Chlorobenzene µg/L 300#3 <1 <1 <1 <1 <1 <1 <1 <1 <1 5 <1 <1 <1 <1
1,1,1,2-tetrachloroethane µg/L 0.57#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Ethylbenzene µg/L 300#3
20#7 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Xylene (m & p) µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Xylene Total µg/L 500#3
30#4 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
Xylene (o) µg/L9e99 see Xylene Total
#1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Styrene µg/L 20#3
50#7 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Bromoform µg/L9e99 see trihalomethanes
#1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Isopropylbenzene µg/L 450#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,1,2,2-tetrachloroethane µg/L 0.076#5 <1 <1 <1 <1 <1 <1 6 <1 <1 1 6 5 <1 <1
Bromobenzene µg/L 62#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,2,3-trichloropropane µg/L 0.00075#5 <1 <1 <1 <1 <1 <1 1 <1 <1 <1 <1 <1 <1 <1
n-propylbenzene µg/L 660#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
2-chlorotoluene µg/L 240#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,3,5-trimethylbenzene µg/L 120#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
4-chlorotoluene µg/L 250#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
tert-butylbenzene µg/L 690#5 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
1,2,4-trimethylbenzene µg/L 15#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
sec-butylbenzene µg/L 2,000#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
p-isopropyltoluene µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,3-dichlorobenzene µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,4-dichlorobenzene µg/L 300#3 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
n-butylbenzene µg/L 1,000#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,2-dichlorobenzene µg/L 1,000#3 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,2-dibromo-3-chloropropane µg/L 0.1#1 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
1,2,4-trichlorobenzene µg/L 1.1#5 <1 <3 <3 <1 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3
Hexachlorobutadiene µg/L 0.6#3
0.1#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,2,3-trichlorobenzene µg/L 7#5 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3
1,2-Dichloroethene µg/L 50#3 <2 <2 <2 <2 <2 <2 3.5 3.5 3.5 3.5 3.5 2.5 <2 <2
Trihalomethanes µg/L 100#1 845 430 277 <39 <39 <39 874 195 213 677 14,730 3,310 2,337 594
Carbon disulfide µg/L 810#5 6 1 <1 <1 <1 <1 793 48 24 171 1,547 1,486 13 <1
BHXX3* BHXX4 BHXX5
- - - - -
BHXX1 BHXX2
Units Meth
od
Dete
ction L
imit
GA
C_W
TV
_E
N
/WA
_D
WS
GA
C_W
TV
_E
N
/WA
_E
QS
-
Fre
sh
Pier 1 CSM
Mersey Gateway Bridge Project
AECOM
Page 1 of 3 August 2015
Table 3
Groundwater Analytical Results for Pier 1
Mersey Gateway Bridge Project
Location
WellDate 07/11/2014 17/11/2014 24/11/2014 07/11/2014 17/11/2014 24/11/2014 18/11/2014 24/11/2014 01/12/2014 29/04/2015 29/04/2015 05/05/2015 29/04/2015 05/05/2015
BHXX3* BHXX4 BHXX5
- - - - -
BHXX1 BHXX2
Units Meth
od
Dete
ction L
imit
GA
C_W
TV
_E
N
/WA
_D
WS
GA
C_W
TV
_E
N
/WA
_E
QS
-
Fre
sh
PAH
Acenaphthylene µg/L 18#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01
Acenaphthene µg/L 18#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <1 - 0.09 <1 - 0.08 <1 - 0.01 <1 - 0.05
Fluorene µg/L 12#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01
Phenanthrene µg/L 4#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 0.01 - <1 - 0.01 <1 - 0.01 <0.01 <0.01
Anthracene µg/L 90#11
0.1#4 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01
Fluoranthene µg/L 4#11
0.1#4 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01
Pyrene µg/L 9#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01
Benzo(a)anthracene µg/L 0.1#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01
Chrysene µg/L 1#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01
Benzo(a)pyrene µg/L 0.01#1
0.05#4 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01
Indeno(1,2,3-c,d)pyrene µg/L9e99 see sum of 4 PAHs
#1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01
Dibenzo(a,h)anthracene µg/L 0.01#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01
Benzo(g,h,i)perylene µg/L9e99 see sum of 4 PAHs
#1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01
Benzo(b)fluoranthene µg/L9e99 see sum of 4 PAHs
#1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01
Benzo(k)fluoranthene µg/L9e99 see sum of 4 PAHs
#1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01
Benzo(b)&(k)fluoranthene µg/L 0.03#4 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 - <0.02 <0.02 <0.02 <0.02
PAHs (sum of 4) µg/L 0.1#1 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 - <0.04 <0.04 <0.04 <0.04
PAH 16 Total µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 0.03 0.02 0.03 - 0.16 0.15 0.03 0.05
benzo(g,h,i)perylene + indeno(1,2,3-cd)pyrene µg/L 0.002#4 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 - <0.02 <0.02 <0.02 <0.02
Coal Tar (Bap as surrogate marker) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01
SVOC
2,4,5-trichlorophenol µg/L 9#3 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
4-chloro-3-methylphenol µg/L 1,400#5
40#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
4-methylphenol µg/L 1,900#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
2-chloronaphthalene µg/L 750#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
2-methylnaphthalene µg/L 24#3 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Bis(2-ethylhexyl) phthalate µg/L 8#3
1.3#4 <2 <2 <2 <2 <2 <2 <2 <2 <2 - <2 <2 <2 <2
Butyl benzyl phthalate µg/L 16#5
20#7 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Di-n-butyl phthalate µg/L 900#5
8#7 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Di-n-octyl phthalate µg/L 200#5
20#7 17 <5 <5 <5 <5 <5 <5 <5 <5 - 47 - 56 -
Diethylphthalate µg/L 15,000#5
200#7 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Dimethyl phthalate µg/L 800#7 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
2,4-Dinitrotoluene µg/L 0.24#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
2,6-dinitrotoluene µg/L 0.048#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
4-bromophenyl phenyl ether µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Bis(2-chloroethoxy) methane µg/L 59#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Bis(2-chloroethyl)ether µg/L 0.014#5 <1 <1 <1 <1 <1 1 <1 <1 <1 - <1 <1 <1 <1
Carbazole µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Dibenzofuran µg/L 7.9#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Hexachlorobenzene µg/L 1#3
0.01#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Hexachlorocyclopentadiene µg/L 31#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Hexachloroethane µg/L 0.9#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Isophorone µg/L 78#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
N-nitrosodi-n-propylamine µg/L 0.011#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Nitrobenzene µg/L 0.14#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Bis(2-chloroisopropyl) ether µg/L 0.36#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Perylene µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Phenolics
2,4-dinitrophenol µg/L 39#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
4,6-Dinitro-2-methylphenol µg/L 1.5#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1
Phenols Total of 5 Speciated by HPLC (W) µg/L 50 <10 500 170 380 390 <10 <10 <10 - 110 30 30 <10
Pier 1 CSM
Mersey Gateway Bridge Project
AECOM
Page 2 of 3 August 2015
Table 3
Groundwater Analytical Results for Pier 1
Mersey Gateway Bridge Project
Location
WellDate 07/11/2014 17/11/2014 24/11/2014 07/11/2014 17/11/2014 24/11/2014 18/11/2014 24/11/2014 01/12/2014 29/04/2015 29/04/2015 05/05/2015 29/04/2015 05/05/2015
BHXX3* BHXX4 BHXX5
- - - - -
BHXX1 BHXX2
Units Meth
od
Dete
ction L
imit
GA
C_W
TV
_E
N
/WA
_D
WS
GA
C_W
TV
_E
N
/WA
_E
QS
-
Fre
sh
Metals
Aluminium µg/L 200#1
15#7 <10 13 23 <10 12 21 32 35 17 - <10 <10 <10 <10
Arsenic µg/L 10#1
50#4 421 332 99 3 3 3 7,480 9,780 8,500 - 2,400 1,370 14 73
Barium µg/L 700#3 108 97 94 119 73 62 <50 47 46 - 96 106 141 66
Beryllium µg/L 25#5 <1 <2 <1 <1 <2 <1 <50 <1 <1 - <1 <1 <1 <1
Boron µg/L 1,000#1
2,000#7 683 668 501 67 52 56 1,650 444 1,090 - 1,180 1,230 959 138
Cadmium µg/L 5#1
0.08#4 <1 <2 <1 <1 <2 <1 <50 <1 <1 - <1 <1 <1 <1
Calcium µg/L 724,000 600,000 668,000 1,510,000 1,430,000 1,700,000 552,000 576,000 478,000 - 666,000 653,000 545,000 222,000
Chromium (III+VI) µg/L 50#1
3.4#4 3 10 10 2 11 14 <50 7 5 - 2 7 <1 1
Copper µg/L 2,000#1
1#4 <1 <2 <1 <1 <2 <1 <50 <1 <1 - <1 <1 <1 <1
Iron µg/L 200#1
1,000#4 11,060 8,530 3,124 108 165 178 14,700 17,730 17,200 - 12,370 7,007 8,114 299
Lead µg/L 25#1
7.2#4 <1 <2 <1 <1 <2 <1 <50 <1 <1 - <1 <1 <1 <1
Magnesium µg/L 293,000 302,000 304,000 709,000 674,000 827,000 104,000 57,000 81,000 - 142,000 114,000 83,000 32,000
Manganese µg/L 50#1
30#7 2,806 2,230 1,925 942 613 556 3,760 4,454 4,079 - 7,412 8,926 6,537 503
Mercury µg/L 1#1
0.05#4 <0.1 <0.2 <0.1 <0.1 <0.2 <0.1 <5 <0.1 <0.1 - 0.3 <0.1 0.4 <0.1
Nickel µg/L 20#1
20#4 4 3 4 9 8 7 <50 10 8 - 8 8 14 6
Selenium µg/L 10#1 1 <2 <1 <1 <2 <1 <50 2 2 - 6 8 8 12
Strontium µg/L 12,000#5 6,490 4,800 6,780 4,130 3,460 3,700 1,290 1,120 1,150 - 1,860 1,680 1,630 2,160
Vanadium µg/L 86#5
20#7 1 5 4 1 5 2 <50 11 10 - 1 3 <1 <1
Zinc µg/L 6,000#5
8#4 3 4 16 13 12 10 <50 9 8 - 21 15 14 3
Potassium µg/L 72,000 61,000 58,000 19,000 20,000 19,000 134,000 94,000 128,000 - 105,000 84,000 61,000 13,000
Chromium (hexavalent) µg/L 50#1
3.4#4 <50 <50 <50 <50 <5,000 <50 <50 <50 <50 - <50 <50 <50 <50
Organics
Dissolved Organic Carbon mg/l 4.3 10.7 3.8 2.1 1.6 1.7 13.7 13.8 14.3 - 13 19.1 10.7 7.6
Inorganics
BOD settled mg/l <1 2 <1 <1 2 <1 5 <1 <1 - <1 <1 <1 <1
Sodium mg/L 200#1 1,900 2,040 2,170 1,040 984 1,280 888 892 799 - 681 660 473 158
Electrical conductivity *(lab) µS/cm 11,900 12,900 12,800 14,200 14,300 14,400 11,000 8,250 9,630 - 9,050 8,640 6,300 1,913
Sulphate mg/L 250#1
400#7 1,998 1,785 1,848 588 634 614 5,820 3,548 3,947 - 3,475 3,546 2,168 801
Chloride mg/L 250#1
250#7 3,530 4,860 4,330 5,930 6,740 6,180 869 787 721 - 662.62 698 521.51 170.03
Sulphide mg/L - - - - - - - - - - 0.2 0.1 <0.1 <0.1
Cyanide Total mg/L 0.0015#5 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 - <0.005 <0.005 <0.005 <0.005
Nitrate (as N) mg/L <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - 0.68 <0.5 <0.5 0.8
Nitrite (as N) mg/L <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - <0.1 0.13 <0.1 0.73
Easily Liberated Sulphide (Moisture Corrected) mg/l <0.1 0.5 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 <0.1 - - - - -
COD (Settled) µg/L 220,000 220,000 190,000 140,000 150,000 120,000 150,000 120,000 130,000 - 140,000 130,000 87,000 27,000
pH (Lab) pH_Units 7.16 7.89 7.55 7.07 7.61 7.24 7.66 7.51 7.25 - 7.11 7.22 7.38 7.68
Comments
*Additional 13 rounds of monitoring data for BHXX3 between 26/01/15 and 21/04/15 have not been included in this assessment. Refer to the wider CSM for more information.
#1 WS Regs 2010 (Eng/Wal)
#2 WHO Petroleum In DW 2008
#3 WHO DWG 2011
#4 WFD EQS 2010 Fresh (Eng/Wal)
#5 USEPA RSL (tapwater)
#6 SEPA WAT-SG-53 Fresh EQS - MAC - 2013
#7 SEPA WAT-SG-53 Fresh EQS - AA - 2013
#8 PNEC (EU REACH) - Freshwater
#9 New Hampshire DES (2009)
#10 California Draft health protective concentration
#11 Calc WHO
GAC: Generic Assessment Criteria
(blank): No assessment criteria available
- : Not analysed
DWS: Drinking Water Standard
EQS: Environmental Quality Standard
Key
XXX Exceedance of CW/WE Water. DWS - England/Wales
XXX Exceedance of CW/WE Water. Aquatic Toxicity - England/Wales - Freshwater
Pier 1 CSM
Mersey Gateway Bridge Project
AECOM
Page 3 of 3 August 2015
Table 4
Pier 1 Soubililty Assessment for Volatile Organic Compounds (VOCs) in Groundwater
Location Solubility (µg/L)
Date 29/04/2015 05/05/2015 29/04/2015 05/05/2015 29/04/2015 05/05/2015 29/04/2015 05/05/2015
VOC
Chloromethane µg/L 22 27 7 <1 5.35E+06 4.11E-04 5.05E-04 1.31E-04 -
Dichloromethane µg/L 58 54 21 <5 2.01E+07 2.89E-04 2.69E-04 1.04E-04 -
Chloroform µg/L 14,723 >3,303 2,330 587 8.95E+06 1.65E-01 >3.69E-04 2.60E-02 1.10E-02
Carbon tetrachloride (Tetrachloromethane) µg/L 53,525 >6,542 413 107 8.46E+05 6.33E+00 >7.73E-03 4.88E-02 5.32E-04
Tetrachloroethene (PCE) µg/L 59 53 7 2 2.25E+05 2.62E-02 2.36E-02 3.11E-03 2.23E-05
1,1,2,2-tetrachloroethane µg/L 6 5 <1 <1 2.93E+06 2.05E-04 1.71E-04 -
Carbon disulfide µg/L 1,547 1,486 13 <1 2.10E+06 7.37E-02 7.08E-02 6.19E-04 -
Percentage of Total Solubility (%)
BHXX4 (Alluvial Deposits) BHXX5 (Alluvial Deposits)BHXX4 (Alluvial Deposits) BHXX5 (Alluvial Deposits)
Units
Pier 1 CSM
Mersey Gateway Bridge Project August 2015
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 A 17 MARCH 2016
APPENDIX A – PHOTOS OF PIER 1
BHXX3
Haul Road
Thermphos
BHXX3 Haul Road
Thermphos
Canal
NORTH
Mersey River
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 B 17 MARCH 2016
APPENDIX B – BOREHOLE LOGS (BHXX1 – BHXX5)
DT^P _Z FTXP_Z ]T^P
6L^TYR OP[_SL_ ^_]TVP
_TXP_Z ^PLW
7P[_S Fd[P <YN]PXPY_LW MWZb NZ‘Y_ (
;PLOP]
ABF8E3 4WW OP[_S^ TY XP_]P^%IL_P] ^_]TVP ]T^P _TXP TY XTY‘_P^%
:8A8D4? ABF8E
9]ZXOP[_S
FZOP[_S
9W‘^S_d[P
9W‘^S]P_‘]Y
$ EPL_TYR MWZb^ ZYWd’
DPXL]V^ 6L^TYR IL_P]OP[_S
6ST^PWWTYR
9Z]X AZ’ E<8JC;B?8;7D <^^‘P’DPaT^TZY AZ’ *’)/ <^^‘P 7L_P *)(),(+)*-
8\‘T[XPY_FZ[ 5L^P Fd[P 7L_P E_L]_PO 7L_P 8YOPO 6]Pb EPN_TZY ESZ]TYR ( DPXL]V^
LWW OTLXP_P]^ TY XTWWTXP_]P^’SL]O ^_]L_L _TXP TY SSXX
8YP]Rd]L_TZ
FZ[ 5L^P 7TLXP_P] FTXP DPNZaP]d!
7KA4@<6 E4@C?<A:
[PYP_]L_TZY TY XX;LXXP]
AZ’
CL]_ ZQ _SP 5LNSd EZWP_LYNSP :]Z‘[
Fd[P DP^[ZY^P eZYPFZ[ 5L^P
CT[P
?ZR E_L_‘^3 C]PWTXTYL]d
F40-,0
)-(**(+)*-1’.)X B7
@P]^Pd :L_PbLd 5]TORP’ 4OOT_TZYLW :< "CSL^P +#
@P]^Pd ?TYV 6=H@P]^Pd ?TYV 6=H
?ZR C]TY_ 7L_P 4YO FTXP3 +)().(+)*. )23)+3++
,.*0,1’-1 8% ,1-001’+, A AL_TZYLW :]TO).(**(+)*-
&
HP]_TNLW
5;JJ,
)’)) **’.) 6C )-(**(+)*- ).(**(+)*- =6 7? A4 A4 7LYOZ *.)
+))*.)
**’.)
)’)) )’.) 6ZYN]P_P)’.) 1’.) 5PY_ZYT_P1’.) **’.) :]LaPW MLNVQTWW
)-(**(+)*- *0,) *)’)) *)’)) 8YO ZQ ESTQ_).(**(+)*- )0,) *)’)) *)’)) E_L]_ ZQ ESTQ_).(**(+)*- **,) **’.) **’)) 8YO ZQ ;ZWP
)’)) )’2) )2)) )+)) 6ST^PWWTYR
)*
,’))**’.)
+))*.)
EC
,’))**’))
1’.) **’.)
*’))+’))1’+)
)* )’)) 1’.) .) CWLTY)* 1’.) **’.) .) EWZ__PO
)-(**(+)*- *-)) .’0) -’0) +) -’.) AE
FZ[OP[_S
5L^POP[_S
DPXL]V^78CF; D8?4F87 D8@4D>E
C<C8 6BAEFDG6F<BA
<7
OP[_S
SSXX^^
5T_6Z]P 6Z]P
5L]]PW E‘[[Z]_?ZRRPO 5d
7TL’ZQ [T[P
!
DPXL]V^@L_P]TLW^PN_TZY
5L^P ZQ^PN_TZY
FZ[ ZQ546>9<?? 78F4<?E
!7‘]L_TZY
SSXXE_L]_ _TXP
9W‘^SNZWZ‘]
_LVPYQWZb
FZ[ 5L^PFd[P ZQ
[T[P7T^_LYNP
<AEF4??4F<BA 78F4<?E
Q]ZX :’?’<7
C]ZUPN_ AZ’
C]ZUPN_ ALXP
8X[WZdP]8YRTYPP]
6ZZ]OTYL_P^:]Z‘YO ?PaPW<YNWTYL_TZY7L_P E_L]_PO 7L_P 6ZX[WP_PO
;ZWP <7’8c[WZ]L_Z]d ;ZWP ?ZR
645?8 C8D6GEE<BA 78F4<?E
;B?8 7<4@8F8D ( 64E<A:
I4F8D EFD<>8E
DBF4DK 9?GE; 78F4<?E
ECF 78F4<?E
CDB:D8EEDPXL]V^7L_P FTXP ;ZWP
OP[_S OP[_S6L^TYR IL_P]
OP[_S
;L]O E_]L_L 7P[_SQ]ZX _Z
SSXX
;ZWPOTLXP_P]
7P[_S ZQSZWP
6L^TYROTLXP_P]
7P[_S ZQNL^TYR
7L_P FTXP E_]TVP L_OP[_S OP[_S
5M[KZQX\QWV WN C\ZI\I <MOMVL 5MX\P<M^MT5I\]U CIUXTQVO
5M\IQT[:V CQ\] DM[\ :V[\ITT$
I\QWV
>?D6C1 2TT LMX\P[ QV UM\ZM[# ITT LQIUM\MZ[ QV UQTTQUM\ZM[%CMM PMILMZ [PMM\ NWZ LM\IQT[ WN JWZQVO#
9WTM :5%
5M\IQT[
3TW_ 4W]V\ 2VL
@ZWRMK\ >W%
D4B C4B BA5
6UXTWaMZ6VOQVMMZ
4WWZLQVI\M[8ZW]VL <M^MT
6‘XTWZI\WZa 9WTM <WO@ZWRMK\ >IUM
9WTM DaXM :VKTQVI\QWV
7WZU >W% C:6G@9?<6<?8 :[[]M%BM^Q[QWV >W% (%’- :[[]M 5I\M )’&’0&)’(* @IZ\ WN \PM 3IKPa CWTM\IVKPM 8ZW]X
CIUXTM BMKW^MZa
7WZ LM\IQT[ WN IJJZM^QI\QWV[# [MM SMaXZWOZM[[ IVL _I\MZ%
5QI%!DPQKSVM[["
<WO C\I\][1 @ZMTQUQVIZa
4@
D2.+*.
/%,’U ?5
=MZ[Ma 8I\M_Ia 3ZQLOM% 2LLQ\QWVIT 8: !@PI[M )"
=MZ[Ma <QVS 4;F=MZ[Ma <QVS 4;F
<WO @ZQV\ 5I\M 2VL DQUM1 )’&’,&)’(, ’01’)1)-
*,(.*/%+/ 6# */+../%)* > >I\QWVIT 8ZQLFMZ\QKIT
$
39GG*
(%.,
)%,’
+%’’
,%.’
!(%.,"
!’%.,"
!(%,’"
!(%.’"
!+%-’"
-%.,
-%’’
+%,’
)%/’
6C (
6C )
6C *
6C +
)%’’
*%’’
+%,’
-%’’
=256 8B?E>51 <QOP\ OZMaQ[P JZW_V [TQOP\Ta KTIaMa [IVLa IVO]TIZ \W[]JIVO]TIZ NQVM \W KWIZ[M OZI^MT [QbML NZIOUMV\[ WN TQUM[\WVM_Q\P TW_ KWJJTM KWV\MV\% CIVL Q[ NQVM \W KWIZ[M% 4WJJTM [QbMLNZIOUMV\[ IZM IVO]TIZ WN TQUM[\WVM%
=256 8B?E>51 8ZMaQ[P JZW_V [IVLa IVO]TIZ \W []JZW]VLML OZI^MT[QbML NZIOUMV\[ WN JZQKS# KWVKZM\M# [IVL[\WVM# OTI[[# _WWL#XTI[\QK IVL UM\IT _Q\P TW_ KWJJTM KWV\MV\% CIVL Q[ NQVM \WKWIZ[M% 4WJJTM [QbML NZIOUMV\[ IZM []JIVO]TIZ \W []JZW]VLML WNJZQKS IVL KWVKZM\M%
CWN\ \W NQZU TQOP\ OZMaQ[P JZW_V [TQOP\Ta [QT\a [IVLa 4<2H _Q\PWKKI[QWVIT XWKSM\[ WN WZIVOQ[P JZW_V [TQOP\Ta [QT\a NQVM \WUMLQ]U [IVL !]X \W .’UU"% !@W[[QJTM =ILM 8ZW]VL"
7QZU JZW_V [TQOP\Ta [IVLa ^MZa [QT\a 4<2H _Q\P WKKI[QWVIT OZMaOTMaML ZWW\TM\ \ZIKM[% CIVL Q[ NQVM%
8ZMaQ[P JZW_V \W JZW_V [QT\a TWKITTa ^MZa [QT\a NQVM C2>5 _Q\PWKKI[QWVIT KWIT NTMKS[%
CPMM\ ( WN )
5M[KZQX\QWV WN C\ZI\I <MOMVL 5MX\P<M^MT5I\]U CIUXTQVO
5M\IQT[:V CQ\] DM[\ :V[\ITT$
I\QWV
>?D6C1 2TT LMX\P[ QV UM\ZM[# ITT LQIUM\MZ[ QV UQTTQUM\ZM[%CMM PMILMZ [PMM\ NWZ LM\IQT[ WN JWZQVO#
9WTM :5%
5M\IQT[
3TW_ 4W]V\ 2VL
@ZWRMK\ >W%
D4B C4B BA5
6UXTWaMZ6VOQVMMZ
4WWZLQVI\M[8ZW]VL <M^MT
6‘XTWZI\WZa 9WTM <WO@ZWRMK\ >IUM
9WTM DaXM :VKTQVI\QWV
7WZU >W% C:6G@9?<6<?8 :[[]M%BM^Q[QWV >W% (%’- :[[]M 5I\M )’&’0&)’(* @IZ\ WN \PM 3IKPa CWTM\IVKPM 8ZW]X
CIUXTM BMKW^MZa
7WZ LM\IQT[ WN IJJZM^QI\QWV[# [MM SMaXZWOZM[[ IVL _I\MZ%
5QI%!DPQKSVM[["
<WO C\I\][1 @ZMTQUQVIZa
4@
D2.+*.
/%,’U ?5
=MZ[Ma 8I\M_Ia 3ZQLOM% 2LLQ\QWVIT 8: !@PI[M )"
=MZ[Ma <QVS 4;F=MZ[Ma <QVS 4;F
<WO @ZQV\ 5I\M 2VL DQUM1 )’&’,&)’(, ’01’)1).
*,(.*/%+/ 6# */+../%)* > >I\QWVIT 8ZQLFMZ\QKIT
$
39GG*
(’%*’
((%’’
((%,’
!’%.’"
!’%,’"
$(%/’
$)%,’
$*%’’
6C ,
6C -
(’%,’
((%,’
8ZMaQ[P JZW_V \W JZW_V [QT\a TWKITTa ^MZa [QT\a NQVM C2>5 _Q\PWKKI[QWVIT KWIT NTMKS[%
8ZMaQ[P JZW_V \W LIZS OZMa OZI^MTTa NQVM \W KWIZ[M C2>5 _Q\PWKKI[QWVIT KWIT NTMKS[% 8ZI^MT Q[ []JIVO]TIZ \W ZW]VLML NQVM \WKWIZ[M WN [IVL[\WVM# U]L[\WVM# Y]IZ\bQ\M# OZIVQ\M%
7QZU OZMaQ[P JZW_V \W JZW_V [TQOP\Ta [IVLa [TQOP\Ta OZI^MTTa4<2H% CIVL Q[ NQVM \W KWIZ[M% 8ZI^MT Q[ IVO]TIZ \W ZW]VLML NQVM\W KWIZ[M WN [IVL[\WVM# U]L[\WVM# OZIVQ\M IVL Y]IZ\bQ\M%
6‘XTWZI\WZa PWTM KWUXTM\M I\ ((%,’ U%
CPMM\ ) WN )
EU_Q ‘[ GUYQ‘[ ^U_Q
7M_UZS PQ\‘TM‘ _‘^UWQ
‘UYQ‘[ _QMX
8Q\‘T Ge\Q =ZO^QYQZ‘MX NX[c O[aZ‘ (
<QMPQ^
BCG9F3 5XX PQ\‘T_ UZ YQ‘^Q_%JM‘Q^ _‘^UWQ ^U_Q ‘UYQ UZ YUZa‘Q_%
;9B9E5@ BCG9F
:^[YPQ\‘T
G[PQ\‘T
:Xa_T‘e\Q
:Xa_T^Q‘a^Z
$ FQM‘UZS NX[c_ [ZXe’
EQYM^W_ 7M_UZS JM‘Q^PQ\‘T
7TU_QXXUZS
:[^Y B[’ F=9KD<C@9<8E =__aQ’EQbU_U[Z B[’ *’)/ =__aQ 8M‘Q *)(),(+)*-
9]aU\YQZ‘G[\ 6M_Q Ge\Q 8M‘Q F‘M^‘QP 8M‘Q 9ZPQP 7^Qc FQO‘U[Z FT[^UZS ( EQYM^W_
MXX PUMYQ‘Q^_ UZ YUXXUYQ‘^Q_’TM^P _‘^M‘M ‘UYQ UZ TTYY
9ZQ^Se^M‘U[
G[\ 6M_Q 8UMYQ‘Q^ GUYQ EQO[bQ^e!
8LB5A=7 F5AD@=B;
\QZQ‘^M‘U[Z UZ YY<MYYQ^
B[’
DM^‘ [R ‘TQ 6MOTe F[XQ‘MZOTQ ;^[a\
Ge\Q EQ_\[Z_Q f[ZQG[\ 6M_Q
DU\Q
:[^ PQ‘MUX_ [R MNN^QbUM‘U[Z_% _QQ WQe
G50-,0
+.()2(+)*-0’/+Y C8
AQ^_Qe ;M‘QcMe 6^UPSQ’ 5PPU‘U[ZMX ;= "DTM_Q +#
AQ^_Qe @UZW 7>IAQ^_Qe @UZW 7>I
@[S D^UZ‘ 8M‘Q 5ZP GUYQ3 +)().(+)*. )23)+3,-
,.*0-/’)) 9% ,1-0//’22 B BM‘U[ZMX ;^UP)*(*)(+)*-
&
IQ^‘UOMX
6<KK*
)’)) *’+) =D +.()2(+)*- +.()2(+)*- >A 79 B5 B5 <MZP G[[X_*’+) +.’)) 7D +.()2(+)*- )*(*)(+)*- >A 79 B5 B5 8MZP[ *.)
+.)+))
*2’+)
)’)) )’.) 7[ZO^Q‘Q)’.) *0’0) 6QZ‘[ZU‘Q
*0’0) *1’0) ;^MbQX NMOWRUXX*1’0) +.’)) 6QZ‘[ZU‘Q
+.()2(+)*- *0,) -’)) -’)) 9ZP [R FTUR‘+/()2(+)*- )0,) -’)) -’)) F‘M^‘ [R FTUR‘+/()2(+)*- *0,) 2’)) 2’)) 9ZP [R FTUR‘+2()2(+)*- *0,) *+’.) *+’.) 9ZP [R FTUR‘,)()2(+)*- )0,) *+’.) *+’.) F‘M^‘ [R FTUR‘,)()2(+)*- *0,) +,’)) ++’)) 9ZP [R FTUR‘)*(*)(+)*- )0,) +,’)) ++’)) F‘M^‘ [R FTUR‘)*(*)(+)*- *0,) +.’)) +.’)) 9ZP [R <[UQ
+’)) +’0) BE )+)) 7TU_QXXUZS
)*
-’))+.’))
+.)+))
FD
-’))+.’))
*0’0) *1’0)
8EL,’.).’))1’+)-’))-’.),’,)-’,)
)* )’)) *0’0) .) DXMUZ)* *0’0) *1’0) .) FX[‘‘QP)* *1’0) *2’+) .) DXMUZ
-’)) FDG B4- "*%)%)%*%*%+# 8;)* 0+ -’)) 8EL.’)) FDG B4. "*%*%*%*%*%+# 8;)* 0+ .’)) -’))/’)) FDG B4/ "*%+%+%*%*%+# 8;)* 0+ -’2) /’))0’.) FDG B4*. "+%,%,%-%-%-# 8;)* 0+ 0’.) .’0)2’)) FDG B4*. "+%+%,%-%-%-# 8;)* 0+ 2’)) .’/)
*)’.) FDG B4*+ "+%+%,%,%,%,# 8;)* 0+ *)’.) ,’0)*+’)) FDG B4,/ ",%.%1%1%*)%*)# 8;)* 0+ *+’)) -’,)*,’.) FDG B4,2 "-%1%2%*)%*)%*)# 8;)* 0+ *,’.) .’*)*.’)) FDG .)(+0.YY "2%*)%**%*+%*-%*,(.)# 8;)* 0+ *.’)) -’+)*/’.) FDG .)(+/.YY ".%**%*+%*-%*-%*)(-)# 8;)* 0+ */’.) -’2)*1’)) FDG .)(+0)YY "/%2%**%*,%*,%*,(-.# 8;)* 0+ *1’)) -’+)+*’)) FDG B4,. "-%.%/%1%*)%**# 8;)* 0+ +*’)) -’2)+-’)) FDG B4-) ".%0%1%*)%*)%*+# 8;)* 0+ +-’)) -’,)
G[\PQ\‘T
6M_QPQ\‘T
EQYM^W_89DG< E9@5G98 E9A5E?F
D=D9 7CBFGEH7G=CB
=8
PQ\‘T
TTYY__
6U‘7[^Q 7[^Q
6M^^QX Fa\\[^‘@[SSQP 6e
8UM’[R \U\Q
!
EQYM^W_AM‘Q^UMX_QO‘U[Z
6M_Q [R_QO‘U[Z
G[\ [R657?:=@@ 89G5=@F
!8a^M‘U[Z
TTYYF‘M^‘ ‘UYQ
:Xa_TO[X[a^
‘MWQZRX[c
G[\ 6M_QGe\Q [R
\U\Q8U_‘MZOQ
=BFG5@@5G=CB 89G5=@F
R^[Y ;’@’=8
D^[VQO‘ B[’
D^[VQO‘ BMYQ
9Y\X[eQ^9ZSUZQQ^
7[[^PUZM‘Q_;^[aZP @QbQX=ZOXUZM‘U[Z8M‘Q F‘M^‘QP 8M‘Q 7[Y\XQ‘QP
<[XQ =8’9d\X[^M‘[^e <[XQ @[S
756@9 D9E7HFF=CB 89G5=@F
<C@9 8=5A9G9E ( 75F=B;
J5G9E FGE=?9F
ECG5EL :@HF< 89G5=@F
FDG 89G5=@F
DEC;E9FFEQYM^W_8M‘Q GUYQ <[XQ
PQ\‘T PQ\‘T7M_UZS JM‘Q^
PQ\‘T
<M^P F‘^M‘M 8Q\‘TR^[Y ‘[
TTYY
<[XQPUMYQ‘Q^
8Q\‘T [RT[XQ
7M_UZSPUMYQ‘Q^
8Q\‘T [ROM_UZS
8M‘Q GUYQ F‘^UWQ M‘PQ\‘T PQ\‘T
8P^N]T[_TZY ZQ F_]L_L ?PRPYO 8P[_S?PaPW8L_‘X FLX[WTYR
8P_LTW^=Y FT_‘ GP^_ =Y^_LWW&
L_TZY
ABG9F3 5WW OP[_S^ TY XP_]P^% LWW OTLXP_P]^ TY XTWWTXP_]P^’FPP SPLOP] ^SPP_ QZ] OP_LTW^ ZQ MZ]TYR%
<ZWP =8’
8P_LTW^
6WZb 7Z‘Y_ 5YO
C]ZUPN_ AZ’
G7E F7E ED8
9X[WZdP]9YRTYPP]
7ZZ]OTYL_P^;]Z‘YO ?PaPW
9c[WZ]L_Z]d <ZWP ?ZRC]ZUPN_ ALXP
<ZWP Gd[P =YNWTYL_TZY
:Z]X AZ’ F=9JC<B?9?B; =^^‘P’EPaT^TZY AZ’ *’)/ =^^‘P 8L_P +)()2(+)*, CL]_ ZQ _SP 6LNSd FZWP_LYNSP ;]Z‘[
FLX[WP EPNZaP]d
:Z] OP_LTW^ ZQ LMM]PaTL_TZY^% ^PP VPd[]ZR]P^^ LYO bL_P]’
8TL’"GSTNVYP^^#
=C$7C
G50-,0
0’/+X B8
@P]^Pd ;L_PbLd 6]TORP’ 5OOT_TZYLW ;= "CSL^P +#
@P]^Pd ?TYV 7>I@P]^Pd ?TYV 7>I
?ZR C]TY_ 8L_P 5YO GTXP3 +)().(+)*. )23)+3,1
,.*0-/’)) 9% ,1-0//’22 A AL_TZYLW ;]TOIP]_TNLW
&
6<JJ*
,’.)
,’1)
.’.)
0’.)
1’.)
2’.)
",’.)#
")’,)#
"*’0)#
"+’))#
"*’))#
"*’))#
")’.)#
-’*+
,’1+
+’*+
)’*+
&)’12
&*’12
9F *6 +8 ,6 -
8 .8 /
9F 08 16 2
8 *)
8 **6 *+
8 *,
9F */8 *-
8 *.
8 *0
6 *1
8 *28 +)
8 +*9F +,6 ++
,’.),’.),’.),’1)
-’))-’))&-’-.
.’))
.’))&.’-.
.’))&.’-.
.’.)
/’))&/’-./’))&/’-.
/’.)
/’2)0’))
0’.)&0’2.
1’))
1’.)
2’))2’))&2’-.
2’.)2’.)2’0)
FCG A4--’))
FCG A4..’))
FCG A4//’))
FCG A4*.0’.)
FCG A4*.2’))
-’-.
.’-.
/’-.
0’2.
2’-.
@589 ;EBHA83 ;]Pd _Z OL]V R]Pd ^LYOd LYR‘WL] _Z ^‘MLYR‘WL] QTYP_Z NZL]^P R]LaPW ^TePO Q]LRXPY_^ ZQ WTXP^_ZYP bT_S XPOT‘X NZMMWPNZY_PY_’ FLYO T^ QTYP _Z NZL]^P’ 7ZMMWP ^TePO Q]LRXPY_^ L]P^‘MLYR‘WL] ZQ WTXP^_ZYP’
@589 ;EBHA83 8L]V R]Pd _Z MWLNV ^WTRS_Wd R]LaPWWd ^LYOd NWLd bT_SZNNL^TZYLW [ZNVP_^ ZQ Z]RLYTN XL_P]TLW "‘[ _Z +)XX#’ FLYO T^QTYP _Z NZL]^P’ ;]LaPW ̂ TePO Q]LRXPY_^ L]P LYR‘WL] _Z ^‘M]Z‘YOPOQTYP _Z NZL]^P ZQ ^LYO^_ZYP% WTXP^_ZYP% X‘O^_ZYP% ̂ WLR LYO XTcPOWT_SZWZRTP^’ "@TWO Z]RLYTN ZOZ‘] YZ_PO#’
:T]X M]ZbYT^S R]Pd ^WTRS_Wd ^LYOd 7?5K’ FLYO T^ QTYP _Z NZL]^P’
?ZZ^P OL]V R]Pd _Z MWLNV ^TW_d R]LaPWWd QTYP _Z NZL]^P F5A8’;]LaPW T^ LYR‘WL] _Z ]Z‘YOPO QTYP _Z NZL]^P ZQ ^LYO^_ZYP% QWTY_LYO XTcPO WT_SZWZRTP^’
@POT‘X OPY^P OL]V R]Pd aP]d ^TW_d QTYP _Z NZL]^P F5A8’ "FWTRS_^‘W[S‘]Z‘^ ZOZ‘] YZ_PO#’
@POT‘X OPY^P M]ZbYT^S R]Pd aP]d ^TW_d QTYP _Z NZL]^P F5A8 bT_SZNNL^TZYLW _]LNP^ ZQ Z]RLYTN XL__P]’ "B]RLYTN ZOZ‘] YZ_PO#’
@POT‘X OPY^P M]ZbYT^S R]Pd LYO MWLNV ^TW_d R]LaPWWd QTYP _ZNZL]^P F5A8 LYO LYR‘LW] _Z ^‘M]Z‘YOPO QTYP _Z NZL]^P ;E5I9? ZQ
FSPP_ * ZQ ,
8P^N]T[_TZY ZQ F_]L_L ?PRPYO 8P[_S?PaPW8L_‘X FLX[WTYR
8P_LTW^=Y FT_‘ GP^_ =Y^_LWW&
L_TZY
ABG9F3 5WW OP[_S^ TY XP_]P^% LWW OTLXP_P]^ TY XTWWTXP_]P^’FPP SPLOP] ^SPP_ QZ] OP_LTW^ ZQ MZ]TYR%
<ZWP =8’
8P_LTW^
6WZb 7Z‘Y_ 5YO
C]ZUPN_ AZ’
G7E F7E ED8
9X[WZdP]9YRTYPP]
7ZZ]OTYL_P^;]Z‘YO ?PaPW
9c[WZ]L_Z]d <ZWP ?ZRC]ZUPN_ ALXP
<ZWP Gd[P =YNWTYL_TZY
:Z]X AZ’ F=9JC<B?9?B; =^^‘P’EPaT^TZY AZ’ *’)/ =^^‘P 8L_P +)()2(+)*, CL]_ ZQ _SP 6LNSd FZWP_LYNSP ;]Z‘[
FLX[WP EPNZaP]d
:Z] OP_LTW^ ZQ LMM]PaTL_TZY^% ^PP VPd[]ZR]P^^ LYO bL_P]’
8TL’"GSTNVYP^^#
=C$7C
G50-,0
0’/+X B8
@P]^Pd ;L_PbLd 6]TORP’ 5OOT_TZYLW ;= "CSL^P +#
@P]^Pd ?TYV 7>I@P]^Pd ?TYV 7>I
?ZR C]TY_ 8L_P 5YO GTXP3 +)().(+)*. )23)+3-)
,.*0-/’)) 9% ,1-0//’22 A AL_TZYLW ;]TOIP]_TNLW
&
6<JJ*
*)’))
*+’.)
*-’+)
*0’*)
*0’/)
*1’0)
"+’.)#
"*’0)#
"+’2)#
")’.)#
"*’*)#
&+’,2
&-’12
&/’.2
&2’-2
&2’22
&**’)2
8 +-9F +.6 +0
8 +/
8 +1
8 +2
6 ,)
9F ,*
8 ,+8 ,,6 ,-
8 ,.
9F ,/
6 ,0
8 ,1
8 ,2
8 -)
6 -*9F -+
8 -,6 --9F -.
8 -/8 -0
9F -16 -2
8 .)
H .*
*)’))*)’))*)’))
*)’.)&*)’2.
**’))
*+’))&*+’-.
*+’.)
*,’))
*,’.)*,’.)&*,’2.*,’.)&*,’2.
*-’))
*-’+)
*-’.)
*.’))&*.’-.
*/’))
*/’.)&*/’2.
*0’*)*0’*)
*0’.)*0’/)*0’/)
*1’))*1’))&*1’-.
*1’0)*1’0)
*2’))
*2’.)&*2’2. *)) .) 6WZb^% 1)! EPNZaP]d
FCG A4*+*)’.)
FCG A4,/*+’))
FCG A4,2*,’.)
FCG .)(+0.XX*.’))
FCG .)(+/.XX*/’.)
FCG .)(+0)XX*1’))
*)’2.
*+’-.
*,’2.
*.’-,
*/’2+
*1’-+
^LYO^_ZYP LYO XTcPO WT_SZWZRTP^ bT_S WZb NZMMWP NZY_PY_’ 7ZMMWP^L]P ^‘MLYR‘WL] ZQ ^LYO^_ZYP’
F_TQQ M]ZbY XZ__WPO MWLNV ^WTRS_Wd ^LYOd ^WTRS_Wd R]LaPWWd 7?5K’FLYO T^ QTYP _Z NZL]^P’ ;]LaPW T^ LYR‘WL] _Z ^‘M]Z‘YOPO QTYP _ZNZL]^P ZQ ^LYO^_ZYP% X‘O^_ZYP% QWTY_ LYO XTcPO WT_SZWZRTP^’
8PY^P OL]V R]PdT^S M]ZbY aP]d ^TW_d aP]d R]LaPWWd QTYP _Z NZL]^PF5A8 bT_S _]LNP^ ZQ Z]RLYTN XL__P]’ ;]LaPW T^ LYR‘WL] _Z ]Z‘YOPOQTYP _Z NZL]^P ^LYO^_ZYP% X‘O^_ZYP% WTXP^_ZYP% QWTY_% NZLW LYOXTcPO WT_SZWZRTP^’
IP]d OPY^P OL]V R]PdT^S M]ZbY ^WTRS_Wd R]LaPWWd ^TW_d QTYP _ZNZL]^P F5A8’ ;]LaPW T^ LYR‘WL] _Z ]Z‘YOPO QTYP _Z NZL]^P ZQ^LYO^_ZYP% QWTY_ LYO XTcPO WT_SZWZRTP^’
:T]X M]ZbY ^WTRS_Wd ^LYOd ^WTRS_Wd R]LaPWWd 7?5K’ FLYO T^ QTYP _ZNZL]^P’ ;]LaPW T^ LYR‘WL] _Z ]Z‘YOPO QTYP _Z NZL]^P ZQ^LYO^_ZYP% X‘O^_ZYP% QWTY_ LYO XTcPO WT_SZWZRTP^’
IP]d OPY^P R]PdT^S M]ZbY ^TW_d R]LaPWWd QTYP _Z NZL]^P F5A8’;]LaPW T^ LYR‘WL] _Z ]Z‘YOPO QTYP _Z NZL]^P ZQ ^LYO^_ZYP% QWTY_%NZLW XTcPO WT_SZWZRTP^’ "F_]ZYR ^‘W[S‘]Z‘^ ZOZ‘] YZ_PO#’
:T]X _Z ^_TQQ XPOT‘X ^_]PYR_S R]PdT^S M]ZbY ^WTRS_Wd ^LYOd^WTRS_Wd R]LaPWWd 7?5K bT_S Q]P\‘PY_ aP]d _STY MPO^ ZQ QTYP _ZNZL]^P ^LYO’ FLYO T^ QTYP _Z NZL]^P’ ;]LaPW T^ LYR‘WL] _Z ]Z‘YOPOQTYP _Z NZL]^P ZQ ^LYO^_ZYP% X‘O^_ZYP LYO XTcPO WT_SZWZRTP^’
FSPP_ + ZQ ,
8P^N]T[_TZY ZQ F_]L_L ?PRPYO 8P[_S?PaPW8L_‘X FLX[WTYR
8P_LTW^=Y FT_‘ GP^_ =Y^_LWW&
L_TZY
ABG9F3 5WW OP[_S^ TY XP_]P^% LWW OTLXP_P]^ TY XTWWTXP_]P^’FPP SPLOP] ^SPP_ QZ] OP_LTW^ ZQ MZ]TYR%
<ZWP =8’
8P_LTW^
6WZb 7Z‘Y_ 5YO
C]ZUPN_ AZ’
G7E F7E ED8
9X[WZdP]9YRTYPP]
7ZZ]OTYL_P^;]Z‘YO ?PaPW
9c[WZ]L_Z]d <ZWP ?ZRC]ZUPN_ ALXP
<ZWP Gd[P =YNWTYL_TZY
:Z]X AZ’ F=9JC<B?9?B; =^^‘P’EPaT^TZY AZ’ *’)/ =^^‘P 8L_P +)()2(+)*, CL]_ ZQ _SP 6LNSd FZWP_LYNSP ;]Z‘[
FLX[WP EPNZaP]d
:Z] OP_LTW^ ZQ LMM]PaTL_TZY^% ^PP VPd[]ZR]P^^ LYO bL_P]’
8TL’"GSTNVYP^^#
=C$7C
G50-,0
0’/+X B8
@P]^Pd ;L_PbLd 6]TORP’ 5OOT_TZYLW ;= "CSL^P +#
@P]^Pd ?TYV 7>I@P]^Pd ?TYV 7>I
?ZR C]TY_ 8L_P 5YO GTXP3 +)().(+)*. )23)+3-,
,.*0-/’)) 9% ,1-0//’22 A AL_TZYLW ;]TOIP]_TNLW
&
6<JJ*
+.’))
"/’,)#
&*0’,2
8 .+
8 .,
8 .-
8 ..
H ./
8 .0
8 .1
8 .2
6 /)9F /*
+)’))
+)’.)
+*’))&+*’-.
++’))
++’.)&++’2.
+,’))
+,’.)
+-’))&+-’-.
+.’))+.’))
*)) .) 6WZb^% *))! EPNZaP]d
FCG A4,.+*’))
FCG A4-)+-’))
+*’-.
+-’-.
:T]X _Z ^_TQQ XPOT‘X ^_]PYR_S R]PdT^S M]ZbY ^WTRS_Wd ^LYOd^WTRS_Wd R]LaPWWd 7?5K bT_S Q]P\‘PY_ aP]d _STY MPO^ ZQ QTYP _ZNZL]^P ^LYO’ FLYO T^ QTYP _Z NZL]^P’ ;]LaPW T^ LYR‘WL] _Z ]Z‘YOPOQTYP _Z NZL]^P ZQ ^LYO^_ZYP% X‘O^_ZYP LYO XTcPO WT_SZWZRTP^’
Q]ZX ++’.)X _Z +.’))X STRS ^_]PYR_S
9c[WZ]L_Z]d SZWP NZX[WP_P L_ +.’)) X’
FSPP_ , ZQ ,
EU_Q ‘[ GUYQ‘[ ^U_Q
7M_UZS PQ\‘TM‘ _‘^UWQ
‘UYQ‘[ _QMX
8Q\‘T Ge\Q =ZO^QYQZ‘MX NX[c O[aZ‘ (
<QMPQ^
BCG9F3 5XX PQ\‘T_ UZ YQ‘^Q_%JM‘Q^ _‘^UWQ ^U_Q ‘UYQ UZ YUZa‘Q_%
;9B9E5@ BCG9F
:^[YPQ\‘T
G[PQ\‘T
:Xa_T‘e\Q
:Xa_T^Q‘a^Z
$ FQM‘UZS NX[c_ [ZXe’
EQYM^W_ 7M_UZS JM‘Q^PQ\‘T
7TU_QXXUZS
:[^Y B[’ F=9KD<C@9<8E =__aQ’EQbU_U[Z B[’ *’)/ =__aQ 8M‘Q *)(),(+)*-
9]aU\YQZ‘G[\ 6M_Q Ge\Q 8M‘Q F‘M^‘QP 8M‘Q 9ZPQP 7^Qc FQO‘U[Z FT[^UZS ( EQYM^W_
MXX PUMYQ‘Q^_ UZ YUXXUYQ‘^Q_’TM^P _‘^M‘M ‘UYQ UZ TTYY
9ZQ^Se^M‘U[
G[\ 6M_Q 8UMYQ‘Q^ GUYQ EQO[bQ^e!
8LB5A=7 F5AD@=B;
\QZQ‘^M‘U[Z UZ YY<MYYQ^
B[’
DM^‘ [R ‘TQ 6MOTe F[XQ‘MZOTQ ;^[a\
Ge\Q EQ_\[Z_Q f[ZQG[\ 6M_Q
DU\Q
@[S F‘M‘a_3 D^QXUYUZM^e
:[^ PQ‘MUX_ [R MNN^QbUM‘U[Z_% _QQ WQe
G50-,0
+.()2(+)*-0’2*Y C8
AQ^_Qe ;M‘QcMe 6^UPSQ’ 5PPU‘U[ZMX ;= "DTM_Q +#
AQ^_Qe @UZW 7>IAQ^_Qe @UZW 7>I
@[S D^UZ‘ 8M‘Q 5ZP GUYQ3 +)().(+)*. )23)+3-2
,.*0-/’*. 9% ,1-00*’+* B BM‘U[ZMX ;^UP)0(*)(+)*-
&
IQ^‘UOMX
6<KK+
)’)) *’+) =D +.()2(+)*- +.()2(+)*- A: 79 B5 B5 <MZP G[[X_*’+) -*’)) 7D +.()2(+)*- )+(*)(+)*- A: 79 B5 B5 8MZP[ ,)))
-*’)) .,’1) E7 )/(*)(+)*- )0(*)(+)*- FE 8@ ;Q[N[^Q D78 86.+)
+.)+))*.)*-/
.,’1)
)’)) )’.) 7[ZO^Q‘Q)’.) -,’1) 6QZ‘[ZU‘Q
-,’1) .,’1) ;^MbQX NMOWRUXX
+.()2(+)*- *0,) -’)) -’)) 9ZP [R FTUR‘+/()2(+)*- )0,) -’)) -’)) F‘M^‘ [R FTUR‘+/()2(+)*- *0,) *)’)) *)’)) 9ZP [R FTUR‘+2()2(+)*- )0,) *)’)) *)’)) F‘M^‘ [R FTUR‘+2()2(+)*- *0,) *2’)) *2’)) 9ZP [R FTUR‘,)()2(+)*- )0,) *2’)) *2’)) F‘M^‘ [R FTUR‘,)()2(+)*- *0,) +2’)) +2’)) 9ZP [R FTUR‘)*(*)(+)*- )0,) +2’)) +2’)) F‘M^‘ [R FTUR‘)*(*)(+)*- *0,) ,/’)) ,/’)) 9ZP [R FTUR‘)+(*)(+)*- )0,) ,/’)) ,/’)) F‘M^‘ [R FTUR‘)+(*)(+)*- *0,) -*’)) ,2’/) 9ZP [R 7D)/(*)(+)*- )0,) -*’)) ,2’/) F‘M^‘ [R E[‘M^e)/(*)(+)*- *0,) --’0) --’0) 9ZP [R FTUR‘)0(*)(+)*- )0,) --’0) --’0) F‘M^‘ [R FTUR‘)0(*)(+)*- *0,) .,’1) .,’1) 9ZP [R <[XQ
-*’)) -,’+) JM‘Q^ *)) 6^[cZ-,’+) --’0) JM‘Q^ 1) 6^[cZ--’0) .,’1) JM‘Q^ 1) EQP
)*
-’))+.’))-*’)).,’1)
+.)+))*.)*-/
FD
-’))+.’)),2’/).,’1)
-,’1) .,’1)
8EL8EL.’)),’-)0’2).’/)
*+’)).’2)
*)’))-’/).’))-’*),’0)-’)),’-)
)* )’)) -,’1) .) DXMUZ)* -,’1) .,’1) .) FX[‘‘QP
-’)) FDG B4/ "*%)%*%*%+%+# D6, 0* -’)) 8EL.’)) FDG B4, "*%)%*%)%*%*# D6, 0* .’)) 85AD/’)) FDG B4*0 "-%+%,%-%-%/# D6, 0* /’)) .’))0’.) FDG B4*2 ",%,%-%-%.%/# D6, 0* 0’.) .’))2’)) FDG B4*. ",%,%,%-%-%-# D6, 0* 2’)) .’))
*+’)) FDG B4,) "-%-%.%/%1%**# D6, 0* *+’)) .’))*,’.) FDG B4*+ "+%+%,%,%,%,# D6, 0* *,’.) /’))*.’)) FDG .)(+1)YY "/%.%1%**%*.%*/(..# D6, 0* *.’)) 0’))*/’.) FDG B4.) ".%/%0%*)%*.%*1(0.# D6, 0* */’.) 1’))*1’)) FDG B4,) ",%-%0%0%1%1# D6, 0* *1’)) 1’))+*’)) FDG B4,2 ".%/%1%2%*)%*+# D6, 0* +*’)) 0’))+-’)) FDG B4,2 ".%/%1%2%*)%*+# D6, 0* +-’)) 2’))+0’)) FDG B4+- ",%.%.%/%0%/# D6, 0* +0’)) **’)),)’)) FDG B4+* ",%-%.%.%/%.# D6, 0* ,)’)) /’)),,’)) FDG B4*2 ",%-%.%.%.%-# D6, 0* ,,’)) 1’)),/’)) FDG B4-+ "-%0%2%*)%**%*+# D6, 0* ,/’)) -’/),2’)) FDG B4,) "-%.%/%1%1%1# D6, 0* ,2’)) 0’))
G[\PQ\‘T
6M_QPQ\‘T
EQYM^W_89DG< E9@5G98 E9A5E?F
D=D9 7CBFGEH7G=CB
=8
PQ\‘T
TTYY__
6U‘7[^Q 7[^Q
6M^^QX Fa\\[^‘@[SSQP 6e
8UM’[R \U\Q
!
EQYM^W_AM‘Q^UMX_QO‘U[Z
6M_Q [R_QO‘U[Z
G[\ [R657?:=@@ 89G5=@F
!8a^M‘U[Z
TTYYF‘M^‘ ‘UYQ
:Xa_TO[X[a^
‘MWQZRX[c
G[\ 6M_QGe\Q [R
\U\Q8U_‘MZOQ
=BFG5@@5G=CB 89G5=@F
R^[Y ;’@’=8
D^[VQO‘ B[’
D^[VQO‘ BMYQ
9Y\X[eQ^9ZSUZQQ^
7[[^PUZM‘Q_;^[aZP @QbQX=ZOXUZM‘U[Z8M‘Q F‘M^‘QP 8M‘Q 7[Y\XQ‘QP
<[XQ =8’9d\X[^M‘[^e <[XQ @[S
756@9 D9E7HFF=CB 89G5=@F
<C@9 8=5A9G9E ( 75F=B;
J5G9E FGE=?9F
ECG5EL :@HF< 89G5=@F
FDG 89G5=@F
DEC;E9FFEQYM^W_8M‘Q GUYQ <[XQ
PQ\‘T PQ\‘T7M_UZS JM‘Q^
PQ\‘T
<M^P F‘^M‘M 8Q\‘TR^[Y ‘[
TTYY
<[XQPUMYQ‘Q^
8Q\‘T [RT[XQ
7M_UZSPUMYQ‘Q^
8Q\‘T [ROM_UZS
8M‘Q GUYQ F‘^UWQ M‘PQ\‘T PQ\‘T
8R‘P_V]aV\[ \S Fa_NaN ?RTR[Q 8R]aU?RcRY8NabZ FNZ]YV[T
8RaNVY‘=[ FVab GR‘a =[‘aNYY&
NaV\[
ABG9F3 5YY QR]aU‘ V[ ZRa_R‘% NYY QVNZRaR_‘ V[ ZVYYVZRa_R‘’FRR URNQR_ ‘URRa S\_ QRaNVY‘ \S O\_V[T%
<\YR =8’
8RaNVY‘
6Y\d 7\b[a 5[Q
C_\WRPa A\’
G7E F7E ED8
9Z]Y\fR_9[TV[RR_
7\\_QV[NaR‘;_\b[Q ?RcRY
9e]Y\_Na\_f <\YR ?\TC_\WRPa ANZR
<\YR Gf]R =[PYV[NaV\[
:\_Z A\’ F=9KC<B?9?B; =‘‘bR’ERcV‘V\[ A\’ *’)/ =‘‘bR 8NaR +)()2(+)*, CN_a \S aUR 6NPUf F\YRaN[PUR ;_\b]
FNZ]YR ERP\cR_f
:\_ QRaNVY‘ \S NOO_RcVNaV\[‘% ‘RR XRf]_\T_R‘‘ N[Q dNaR_’
8VN’"GUVPX[R‘‘#
?\T FaNab‘3 C_RYVZV[N_f
=C$7C$E7
G50-,0
0’2*Z B8
@R_‘Rf ;NaRdNf 6_VQTR’ 5QQVaV\[NY ;= "CUN‘R +#
@R_‘Rf ?V[X 7>I@R_‘Rf ?V[X 7>I
?\T C_V[a 8NaR 5[Q GVZR3 +)().(+)*. )23)+3..
,.*0-/’*. 9% ,1-00*’+* A ANaV\[NY ;_VQIR_aVPNY
&
=:
6<KK+
,’1)
-’))
-’1)
",’1)#
")’+)#
")’1)#
")’+)#
-’**
,’2*
,’**
9F *8 +
8 ,6 -
9F .
,’1),’1)
-’))-’))&-’-.
-’1)
FCG A4/-’))
-’-.
@589 ;EBHA83 ;_Rf ‘N[Qf N[TbYN_ a\ ‘bON[TbYN_ SV[R a\ P\N_‘RT_NcRY ‘VgRQ S_NTZR[a‘ \S YVZR‘a\[R dVaU UVTU P\OOYR P\[aR[a’FN[Q V‘ SV[R a\ P\N_‘R’ 7\OOYR ‘VgRQ S_NTZR[a‘ N_R N[TbYN_ a\‘bON[TbYN_ \S YVZR‘a\[R’
F\Sa QN_X T_Rf a\ OYNPX ‘YVTUaYf T_NcRYYf ‘N[Qf F=?G’ FN[Q V‘SV[R a\ P\N_‘R’ ;_NcRY V‘ N[TbYN_ a\ _\b[QRQ SV[R a\ P\N_‘R \S‘N[Q‘a\[R% ZbQ‘a\[R N[Q ^bN_agVaR’
:=_Z O_\d[V‘U T_Rf ‘YVTUaYf ‘N[Qf 7?5L’ FN[Q V‘ SV[R a\ P\N_‘R’
:V_Z QN_X T_Rf ‘]RPXYRQ OYNPX ‘YVTUaYf ‘N[Qf 7?5L’ FN[Q V‘ SV[R
FURRa * \S **
8R‘P_V]aV\[ \S Fa_NaN ?RTR[Q 8R]aU?RcRY8NabZ FNZ]YV[T
8RaNVY‘=[ FVab GR‘a =[‘aNYY&
NaV\[
ABG9F3 5YY QR]aU‘ V[ ZRa_R‘% NYY QVNZRaR_‘ V[ ZVYYVZRa_R‘’FRR URNQR_ ‘URRa S\_ QRaNVY‘ \S O\_V[T%
<\YR =8’
8RaNVY‘
6Y\d 7\b[a 5[Q
C_\WRPa A\’
G7E F7E ED8
9Z]Y\fR_9[TV[RR_
7\\_QV[NaR‘;_\b[Q ?RcRY
9e]Y\_Na\_f <\YR ?\TC_\WRPa ANZR
<\YR Gf]R =[PYV[NaV\[
:\_Z A\’ F=9KC<B?9?B; =‘‘bR’ERcV‘V\[ A\’ *’)/ =‘‘bR 8NaR +)()2(+)*, CN_a \S aUR 6NPUf F\YRaN[PUR ;_\b]
FNZ]YR ERP\cR_f
:\_ QRaNVY‘ \S NOO_RcVNaV\[‘% ‘RR XRf]_\T_R‘‘ N[Q dNaR_’
8VN’"GUVPX[R‘‘#
?\T FaNab‘3 C_RYVZV[N_f
=C$7C$E7
G50-,0
0’2*Z B8
@R_‘Rf ;NaRdNf 6_VQTR’ 5QQVaV\[NY ;= "CUN‘R +#
@R_‘Rf ?V[X 7>I@R_‘Rf ?V[X 7>I
?\T C_V[a 8NaR 5[Q GVZR3 +)().(+)*. )23)+3./
,.*0-/’*. 9% ,1-00*’+* A ANaV\[NY ;_VQIR_aVPNY
&
=:
6<KK+
.’))
/’))
2’))
2’1)
"*’))#
",’))#
")’1)#
")’,)#
+’2*
*’2*
&*’)2
&*’12
8 /6 0
8 16 2
8 *)6 **
8 *+
8 *,6 *-
8 *.9F */
.’))
.’))&.’-.
/’))/’))&/’-.
0’.)&0’2.0’.)&0’2.
1’.)
2’))&2’-.2’))&2’-.
2’1)2’1)
FCG A4,.’))
FCG A4*0/’))
FCG A4*20’.)
FCG A4*.2’))
.’-.
/’-.
0’2.
2’-.
a\ P\N_‘R’
?\\‘R \_N[TV‘U T_Rf ‘VYaf SV[R a\ P\N_‘R F5A8 dVaU \PPN‘V\[NYYNZV[NaV\[‘ \S QN_X T_Rf ‘VYa’
@RQVbZ QR[‘R T_RfV‘U O_\d[ ‘YVTUaYf ‘VYaf SV[R a\ P\N_‘R F5A8’
@RQVbZ QR[‘R O_\d[V‘U T_Rf ‘VYaf SV[R a\ P\N_‘R F5A8 dVaU\PPN‘‘V\[NY OYNPX \_TN[VP ZNaaR_’
6_\d[V‘U T_Rf ‘VYaf T_NcRYYf SV[R a\ P\N_‘R F5A8 dVaU Y\d P\OOYR
FURRa + \S **
8R‘P_V]aV\[ \S Fa_NaN ?RTR[Q 8R]aU?RcRY8NabZ FNZ]YV[T
8RaNVY‘=[ FVab GR‘a =[‘aNYY&
NaV\[
ABG9F3 5YY QR]aU‘ V[ ZRa_R‘% NYY QVNZRaR_‘ V[ ZVYYVZRa_R‘’FRR URNQR_ ‘URRa S\_ QRaNVY‘ \S O\_V[T%
<\YR =8’
8RaNVY‘
6Y\d 7\b[a 5[Q
C_\WRPa A\’
G7E F7E ED8
9Z]Y\fR_9[TV[RR_
7\\_QV[NaR‘;_\b[Q ?RcRY
9e]Y\_Na\_f <\YR ?\TC_\WRPa ANZR
<\YR Gf]R =[PYV[NaV\[
:\_Z A\’ F=9KC<B?9?B; =‘‘bR’ERcV‘V\[ A\’ *’)/ =‘‘bR 8NaR +)()2(+)*, CN_a \S aUR 6NPUf F\YRaN[PUR ;_\b]
FNZ]YR ERP\cR_f
:\_ QRaNVY‘ \S NOO_RcVNaV\[‘% ‘RR XRf]_\T_R‘‘ N[Q dNaR_’
8VN’"GUVPX[R‘‘#
?\T FaNab‘3 C_RYVZV[N_f
=C$7C$E7
G50-,0
0’2*Z B8
@R_‘Rf ;NaRdNf 6_VQTR’ 5QQVaV\[NY ;= "CUN‘R +#
@R_‘Rf ?V[X 7>I@R_‘Rf ?V[X 7>I
?\T C_V[a 8NaR 5[Q GVZR3 +)().(+)*. )23)+3.1
,.*0-/’*. 9% ,1-00*’+* A ANaV\[NY ;_VQIR_aVPNY
&
=:
6<KK+
*)’*)
*,’.)
",’-)#
"*’.)#
&+’*2
&.’.2
8 *09F *1
H *2
8 +)
8 +*
8 ++6 +,
8 +-
9F +.8 +/6 +0
8 +1
*)’*)*)’*)
*)’.)&*)’2.
**’))
**’.)
*+’))*+’))&*+’-.
*,’))
*,’.)*,’.)*,’.)&*,’2.
*-’.)
*)) **. 6Y\d‘% 1)! ERP\cR_f
FCG A4,)*+’))
FCG A4*+*,’.)
*+’-.
*,’2.
P\[aR[a’ ;_NcRY V‘ N[TbYN_ a\ _\b[QRQ SV[R a\ P\N_‘R \S‘N[Q‘a\[R% ̂ bN_agVaR N[Q ZVeRQ YVaU\Y\TVR‘’ 7\OOYR‘ N_R‘bON[TbYN_ \S ‘N[Q‘a\[R N[Q ^bN_agVaR’
:V_Z a\ ‘aVSS _RQQV‘U O_\d[ Z\aaYRQ OYNPX ‘YVTUaYf ‘N[Qf ‘YVTUaYfT_NcRYYf 7?5L’ FN[Q V‘ SV[R a\ P\N_‘R’ ;_NcRY V‘ N[TbYN_ a\_\b[QRQ SV[R a\ P\N_‘R \S ‘N[Q‘a\[R% ZbQ‘a\[R’ ̂ bN_agVaR%‘VYa‘a\[R N[Q ZVeRQ YVaU\Y\TVR‘’
@RQVbZ QR[‘R QN_X O_\d[ ‘VYaf ‘YVTUaYf T_NcRYYf SV[R a\ P\N_‘RF5A8 dVaU ‘\ZR \_TN[VP ZNaaR_’ ;_NcRY V‘ N[TbYN_ a\ ‘bO_\b[QRQSV[R a\ P\N_‘R \S ‘N[Q‘a\[R% ̂ bN_agVaR% P\NY N[Q ZVeRQYVaU\Y\TVR‘’
FURRa , \S **
8R‘P_V]aV\[ \S Fa_NaN ?RTR[Q 8R]aU?RcRY8NabZ FNZ]YV[T
8RaNVY‘=[ FVab GR‘a =[‘aNYY&
NaV\[
ABG9F3 5YY QR]aU‘ V[ ZRa_R‘% NYY QVNZRaR_‘ V[ ZVYYVZRa_R‘’FRR URNQR_ ‘URRa S\_ QRaNVY‘ \S O\_V[T%
<\YR =8’
8RaNVY‘
6Y\d 7\b[a 5[Q
C_\WRPa A\’
G7E F7E ED8
9Z]Y\fR_9[TV[RR_
7\\_QV[NaR‘;_\b[Q ?RcRY
9e]Y\_Na\_f <\YR ?\TC_\WRPa ANZR
<\YR Gf]R =[PYV[NaV\[
:\_Z A\’ F=9KC<B?9?B; =‘‘bR’ERcV‘V\[ A\’ *’)/ =‘‘bR 8NaR +)()2(+)*, CN_a \S aUR 6NPUf F\YRaN[PUR ;_\b]
FNZ]YR ERP\cR_f
:\_ QRaNVY‘ \S NOO_RcVNaV\[‘% ‘RR XRf]_\T_R‘‘ N[Q dNaR_’
8VN’"GUVPX[R‘‘#
?\T FaNab‘3 C_RYVZV[N_f
=C$7C$E7
G50-,0
0’2*Z B8
@R_‘Rf ;NaRdNf 6_VQTR’ 5QQVaV\[NY ;= "CUN‘R +#
@R_‘Rf ?V[X 7>I@R_‘Rf ?V[X 7>I
?\T C_V[a 8NaR 5[Q GVZR3 +)().(+)*. )23)+3.2
,.*0-/’*. 9% ,1-00*’+* A ANaV\[NY ;_VQIR_aVPNY
&
=:
6<KK+
*.’))
*.’.)
*1’.)
*2’))
")’.)#
",’))#
")’.)#
&0’)2
&0’.2
&*)’.2
&**’)2
8 +26 ,)
8 ,*
8 ,+6 ,,
8 ,-
8 ,.6 ,/
8 ,09F ,1
8 ,2
H -)
*.’))*.’))&*.’-.
*/’))
*/’.)*/’.)&*/’2.
*0’.)
*1’))&*1’-.*1’))&*1’-.
*1’.)*1’.)
*2’))
*2’.)&*2’2. *)) *,) 6Y\d‘% 0.! ERP\cR_f
FCG .)(+1)ZZ*.’))
FCG A4.)*/’.)
FCG A4,)*1’))
*.’-,
*/’2.
*1’-.
FaVSS _RQQV‘U O_\d[ Z\aaYRQ OYNPX ‘N[Qf T_NcRYYf 7?5L dVaU Y\dP\OOYR P\[aR[a’ FN[Q V‘ SV[R a\ P\N_‘R’ ;_NcRY V‘ N[TbYN_ a\_\b[QRQ SV[R a\ P\N_‘R \S ‘N[Q‘a\[R% ZbQ‘a\[R% ̂ bN_agVaR N[QZVeRQ YVaU\Y\TVR‘’ 7\OOYR‘ N_R ‘bON[TbYN_ \S ‘N[Q‘a\[R’
8R[‘R QN_X O_\d[ ‘YVTUaYf T_NcRYYf ‘VYaf SV[R a\ P\N_‘R F5A8 dVaU\PPN‘V\[NY ]\PXRa‘ \S \_TN[VP ZNaaR_’ ;_NcRY V‘ N[TbYN_ a\_\b[QRQ SV[R a\ P\N_‘R \S ‘N[Q‘a\[R% ̂ bN_agVaR% P\NY N[Q ZVeRQYVaU\Y\TVR‘’
:V_Z a\ ‘aVSS T_RfV‘U O_\d[ ‘N[Qf T_NcRYYf 7?5L’ FN[Q V‘ SV[R a\P\N_‘R’ ;_NcRY V‘ N[TbYN_ a\ _\b[QRQ SV[R a\ P\N_‘R \S ‘N[Q‘a\[R%ZbQ‘a\[R N[Q ZVeRQ YVaU\Y\TVR‘’
:V_Z a\ ‘aVSS ZRQVbZ ‘a_R[TaU T_RfV‘U O_\d[ ‘YVTUaYf ‘N[Qf‘YVTUaYf T_NcRYYf 7?5L dVaU S_R^bR[a ZRQVbZ a\ P\N_‘R T_NcRY‘VgRQ ]\PXRa‘ \S SV[R a\ P\N_‘R ‘N[Q’ ;_NcRY V‘ N[TbYN_ a\_\b[QRQ SV[R a\ P\N_‘R \S ‘N[Q‘a\[R% ZbQ‘a\[R% ̂ bN_agVaR N[QZVeRQ YVaU\Y\TVR‘’
FURRa - \S **
8R‘P_V]aV\[ \S Fa_NaN ?RTR[Q 8R]aU?RcRY8NabZ FNZ]YV[T
8RaNVY‘=[ FVab GR‘a =[‘aNYY&
NaV\[
ABG9F3 5YY QR]aU‘ V[ ZRa_R‘% NYY QVNZRaR_‘ V[ ZVYYVZRa_R‘’FRR URNQR_ ‘URRa S\_ QRaNVY‘ \S O\_V[T%
<\YR =8’
8RaNVY‘
6Y\d 7\b[a 5[Q
C_\WRPa A\’
G7E F7E ED8
9Z]Y\fR_9[TV[RR_
7\\_QV[NaR‘;_\b[Q ?RcRY
9e]Y\_Na\_f <\YR ?\TC_\WRPa ANZR
<\YR Gf]R =[PYV[NaV\[
:\_Z A\’ F=9KC<B?9?B; =‘‘bR’ERcV‘V\[ A\’ *’)/ =‘‘bR 8NaR +)()2(+)*, CN_a \S aUR 6NPUf F\YRaN[PUR ;_\b]
FNZ]YR ERP\cR_f
:\_ QRaNVY‘ \S NOO_RcVNaV\[‘% ‘RR XRf]_\T_R‘‘ N[Q dNaR_’
8VN’"GUVPX[R‘‘#
?\T FaNab‘3 C_RYVZV[N_f
=C$7C$E7
G50-,0
0’2*Z B8
@R_‘Rf ;NaRdNf 6_VQTR’ 5QQVaV\[NY ;= "CUN‘R +#
@R_‘Rf ?V[X 7>I@R_‘Rf ?V[X 7>I
?\T C_V[a 8NaR 5[Q GVZR3 +)().(+)*. )23),3)*
,.*0-/’*. 9% ,1-00*’+* A ANaV\[NY ;_VQIR_aVPNY
&
=:
6<KK+
"1’))#
8 -*
8 -+
8 -,6 --
8 -.
H -/
8 -0
8 -1
8 -26 .)9F .*
+)’))
+)’.)
+*’))+*’))&+*’-.
++’))
++’.)&++’2.
+,’))
+,’.)
+-’))+-’))&+-’-.+-’))
*)) *,) 6Y\d‘% 2)! ERP\cR_f
FCG A4,2+*’))
FCG A4,2+-’))
+*’-.
+-’-.
:V_Z a\ ‘aVSS ZRQVbZ ‘a_R[TaU T_RfV‘U O_\d[ ‘YVTUaYf ‘N[Qf‘YVTUaYf T_NcRYYf 7?5L dVaU S_R^bR[a ZRQVbZ a\ P\N_‘R T_NcRY‘VgRQ ]\PXRa‘ \S SV[R a\ P\N_‘R ‘N[Q’ ;_NcRY V‘ N[TbYN_ a\_\b[QRQ SV[R a\ P\N_‘R \S ‘N[Q‘a\[R% ZbQ‘a\[R% ̂ bN_agVaR N[QZVeRQ YVaU\Y\TVR‘’
FURRa . \S **
8R‘P_V]aV\[ \S Fa_NaN ?RTR[Q 8R]aU?RcRY8NabZ FNZ]YV[T
8RaNVY‘=[ FVab GR‘a =[‘aNYY&
NaV\[
ABG9F3 5YY QR]aU‘ V[ ZRa_R‘% NYY QVNZRaR_‘ V[ ZVYYVZRa_R‘’FRR URNQR_ ‘URRa S\_ QRaNVY‘ \S O\_V[T%
<\YR =8’
8RaNVY‘
6Y\d 7\b[a 5[Q
C_\WRPa A\’
G7E F7E ED8
9Z]Y\fR_9[TV[RR_
7\\_QV[NaR‘;_\b[Q ?RcRY
9e]Y\_Na\_f <\YR ?\TC_\WRPa ANZR
<\YR Gf]R =[PYV[NaV\[
:\_Z A\’ F=9KC<B?9?B; =‘‘bR’ERcV‘V\[ A\’ *’)/ =‘‘bR 8NaR +)()2(+)*, CN_a \S aUR 6NPUf F\YRaN[PUR ;_\b]
FNZ]YR ERP\cR_f
:\_ QRaNVY‘ \S NOO_RcVNaV\[‘% ‘RR XRf]_\T_R‘‘ N[Q dNaR_’
8VN’"GUVPX[R‘‘#
?\T FaNab‘3 C_RYVZV[N_f
=C$7C$E7
G50-,0
0’2*Z B8
@R_‘Rf ;NaRdNf 6_VQTR’ 5QQVaV\[NY ;= "CUN‘R +#
@R_‘Rf ?V[X 7>I@R_‘Rf ?V[X 7>I
?\T C_V[a 8NaR 5[Q GVZR3 +)().(+)*. )23),3)+
,.*0-/’*. 9% ,1-00*’+* A ANaV\[NY ;_VQIR_aVPNY
&
=:
6<KK+
+0’)) &*2’)2
8 .+
H .,
8 .-
8 ..
8 ./6 .0
8 .1
H .2
8 /)9F /+8 /,
+.’))
+.’.)&+.’2.
+/’))
+/’.)
+0’))&+0’-.+0’))&+0’-.
+1’))
+1’.)&+1’2.
+2’))+2’))+2’))
*))
*))
*+) 6Y\d‘% 2)! ERP\cR_f
0) 6Y\d‘% 1)! ERP\cR_f
FCG A4+-+0’))
+0’-.
:V_Z a\ ‘aVSS ZRQVbZ ‘a_R[TaU T_RfV‘U O_\d[ ‘YVTUaYf ‘N[Qf‘YVTUaYf T_NcRYYf 7?5L dVaU S_R^bR[a ZRQVbZ a\ P\N_‘R T_NcRY‘VgRQ ]\PXRa‘ \S SV[R a\ P\N_‘R ‘N[Q’ ;_NcRY V‘ N[TbYN_ a\_\b[QRQ SV[R a\ P\N_‘R \S ‘N[Q‘a\[R% ZbQ‘a\[R% ̂ bN_agVaR N[QZVeRQ YVaU\Y\TVR‘’
:V_Z a\ ‘aVSS ZRQVbZ ‘a_R[TaU _RQQV‘U O_\d[ ‘YVTUaYf ‘N[Qf‘YVTUaYf T_NcRYYf 7?5L dVaU \PPN‘V\[NY aUVPX YNZV[NaV\[‘ \S SV[Ra\ P\N_‘R ‘N[Q’ ;_NcRY V‘ N[TbYN_ a\ _\b[QRQ SV[R a\ P\N_‘R \S‘N[Q‘a\[R% ZbQ‘a\[R% ̂ bN_agVaR N[Q ZVeRQ YVaU\Y\TVR‘’
FURRa / \S **
8R‘P_V]aV\[ \S Fa_NaN ?RTR[Q 8R]aU?RcRY8NabZ FNZ]YV[T
8RaNVY‘=[ FVab GR‘a =[‘aNYY&
NaV\[
ABG9F3 5YY QR]aU‘ V[ ZRa_R‘% NYY QVNZRaR_‘ V[ ZVYYVZRa_R‘’FRR URNQR_ ‘URRa S\_ QRaNVY‘ \S O\_V[T%
<\YR =8’
8RaNVY‘
6Y\d 7\b[a 5[Q
C_\WRPa A\’
G7E F7E ED8
9Z]Y\fR_9[TV[RR_
7\\_QV[NaR‘;_\b[Q ?RcRY
9e]Y\_Na\_f <\YR ?\TC_\WRPa ANZR
<\YR Gf]R =[PYV[NaV\[
:\_Z A\’ F=9KC<B?9?B; =‘‘bR’ERcV‘V\[ A\’ *’)/ =‘‘bR 8NaR +)()2(+)*, CN_a \S aUR 6NPUf F\YRaN[PUR ;_\b]
FNZ]YR ERP\cR_f
:\_ QRaNVY‘ \S NOO_RcVNaV\[‘% ‘RR XRf]_\T_R‘‘ N[Q dNaR_’
8VN’"GUVPX[R‘‘#
?\T FaNab‘3 C_RYVZV[N_f
=C$7C$E7
G50-,0
0’2*Z B8
@R_‘Rf ;NaRdNf 6_VQTR’ 5QQVaV\[NY ;= "CUN‘R +#
@R_‘Rf ?V[X 7>I@R_‘Rf ?V[X 7>I
?\T C_V[a 8NaR 5[Q GVZR3 +)().(+)*. )23),3)-
,.*0-/’*. 9% ,1-00*’+* A ANaV\[NY ;_VQIR_aVPNY
&
=:
6<KK+
,,’))
,-’))
"/’))#
"*’))#
&+.’)2
&+/’)2
8 /-6 /.
8 //
H /0
8 /1
8 /2
8 0)6 0*
8 0+
H 0,
,)’)),)’))&,)’-.
,*’))
,*’.)&,*’2.
,+’))
,+’.)
,,’)),,’))&,,’-.
,-’))
,-’.)&,-’2.
*))
*))
*,) 6Y\d‘% *))! ERP\cR_f
*,) 6Y\d‘% fR‘! ERP\cR_f
FCG A4+*,)’))
FCG A4*2,,’))
,)’-.
,,’-.
:V_Z a\ ‘aVSS ZRQVbZ ‘a_R[TaU _RQQV‘U O_\d[ ‘YVTUaYf ‘N[Qf‘YVTUaYf T_NcRYYf 7?5L dVaU \PPN‘V\[NY aUVPX YNZV[NaV\[‘ \S SV[Ra\ P\N_‘R ‘N[Q’ ;_NcRY V‘ N[TbYN_ a\ _\b[QRQ SV[R a\ P\N_‘R \S‘N[Q‘a\[R% ZbQ‘a\[R% ̂ bN_agVaR N[Q ZVeRQ YVaU\Y\TVR‘’
S_\Z ,*’.)Z a\ ,,’))Z cR_f ‘aVSS
:V_Z _RQQV‘U O_\d[ ‘YVTUaYf ‘N[Qf ‘YVTUaYf T_NcRYYf 7?5L’ FN[Q V‘SV[R a\ P\N_‘R’ ;_NcRY V‘ N[TbYN_ a\ _\b[QRQ SV[R a\ P\N_‘R \S‘N[Q‘a\[R% ZbQ‘a\[R% ̂ bN_agVaR N[Q ZVeRQ YVaU\Y\TVR‘’
FaVSS a\ cR_f ‘aVSS ZRQVbZ ‘a_R[TaU O_\d[ ‘YVTUaYf T_NcRYYf ‘N[Qf7?5L dVaU Y\d P\OOYR P\[aR[a’ FN[Q V‘ SV[R a\ P\N_‘R’ ;_NcRY V‘N[TbYN_ a\ ‘bO_\b[QRQ SV[R a\ P\N_‘R \S ‘N[Q‘a\[R% ZbQ‘a\[R%^bN_agVaR N[Q ZVeRQ YaVU\Y\TVR‘’ 7\OOYR‘ N_R ‘bON[TbYN_ \S‘N[Q‘a\[R’
FURRa 0 \S **
8R‘P_V]aV\[ \S Fa_NaN ?RTR[Q 8R]aU?RcRY8NabZ FNZ]YV[T
8RaNVY‘=[ FVab GR‘a =[‘aNYY&
NaV\[
ABG9F3 5YY QR]aU‘ V[ ZRa_R‘% NYY QVNZRaR_‘ V[ ZVYYVZRa_R‘’FRR URNQR_ ‘URRa S\_ QRaNVY‘ \S O\_V[T%
<\YR =8’
8RaNVY‘
6Y\d 7\b[a 5[Q
C_\WRPa A\’
G7E F7E ED8
9Z]Y\fR_9[TV[RR_
7\\_QV[NaR‘;_\b[Q ?RcRY
9e]Y\_Na\_f <\YR ?\TC_\WRPa ANZR
<\YR Gf]R =[PYV[NaV\[
:\_Z A\’ F=9KC<B?9?B; =‘‘bR’ERcV‘V\[ A\’ *’)/ =‘‘bR 8NaR +)()2(+)*, CN_a \S aUR 6NPUf F\YRaN[PUR ;_\b]
FNZ]YR ERP\cR_f
:\_ QRaNVY‘ \S NOO_RcVNaV\[‘% ‘RR XRf]_\T_R‘‘ N[Q dNaR_’
8VN’"GUVPX[R‘‘#
?\T FaNab‘3 C_RYVZV[N_f
=C$7C$E7
G50-,0
0’2*Z B8
@R_‘Rf ;NaRdNf 6_VQTR’ 5QQVaV\[NY ;= "CUN‘R +#
@R_‘Rf ?V[X 7>I@R_‘Rf ?V[X 7>I
?\T C_V[a 8NaR 5[Q GVZR3 +)().(+)*. )23),3).
,.*0-/’*. 9% ,1-00*’+* A ANaV\[NY ;_VQIR_aVPNY
&
=:
6<KK+
"0’))#
8 0-9F 0.
8 0/
8 006 01
8 02
H 1)
8 1*
8 1+
8 1,6 1-
,.’)),.’))
,.’.)
,/’)),/’))&,/’-.
,0’))
,0’.)&,0’2.
,1’))
,1’.)
,2’))&,2’-.,2’))&,2’-.
*)) *,) 6Y\d‘% 1)! ERP\cR_f
FCG A4-+,/’))
FCG A4,),2’))
,/’-.
,2’-.
FaVSS a\ cR_f ‘aVSS ZRQVbZ ‘a_R[TaU O_\d[ ‘YVTUaYf T_NcRYYf ‘N[Qf7?5L dVaU Y\d P\OOYR P\[aR[a’ FN[Q V‘ SV[R a\ P\N_‘R’ ;_NcRY V‘N[TbYN_ a\ ‘bO_\b[QRQ SV[R a\ P\N_‘R \S ‘N[Q‘a\[R% ZbQ‘a\[R%^bN_agVaR N[Q ZVeRQ YaVU\Y\TVR‘’ 7\OOYR‘ N_R ‘bON[TbYN_ \S‘N[Q‘a\[R’
FURRa 1 \S **
8R‘P_V]aV\[ \S Fa_NaN ?RTR[Q 8R]aU?RcRY8NabZ FNZ]YV[T
8RaNVY‘=[ FVab GR‘a =[‘aNYY&
NaV\[
ABG9F3 5YY QR]aU‘ V[ ZRa_R‘% NYY QVNZRaR_‘ V[ ZVYYVZRa_R‘’FRR URNQR_ ‘URRa S\_ QRaNVY‘ \S O\_V[T%
<\YR =8’
8RaNVY‘
6Y\d 7\b[a 5[Q
C_\WRPa A\’
G7E F7E ED8
9Z]Y\fR_9[TV[RR_
7\\_QV[NaR‘;_\b[Q ?RcRY
9e]Y\_Na\_f <\YR ?\TC_\WRPa ANZR
<\YR Gf]R =[PYV[NaV\[
:\_Z A\’ F=9KC<B?9?B; =‘‘bR’ERcV‘V\[ A\’ *’)/ =‘‘bR 8NaR +)()2(+)*, CN_a \S aUR 6NPUf F\YRaN[PUR ;_\b]
FNZ]YR ERP\cR_f
:\_ QRaNVY‘ \S NOO_RcVNaV\[‘% ‘RR XRf]_\T_R‘‘ N[Q dNaR_’
8VN’"GUVPX[R‘‘#
?\T FaNab‘3 C_RYVZV[N_f
=C$7C$E7
G50-,0
0’2*Z B8
@R_‘Rf ;NaRdNf 6_VQTR’ 5QQVaV\[NY ;= "CUN‘R +#
@R_‘Rf ?V[X 7>I@R_‘Rf ?V[X 7>I
?\T C_V[a 8NaR 5[Q GVZR3 +)().(+)*. )23),3)/
,.*0-/’*. 9% ,1-00*’+* A ANaV\[NY ;_VQIR_aVPNY
&
=:
6<KK+
-*’))
-+’0)
-,’,1
-,’1/
"*’0)#
")’/1#
")’-1#
"*’..#
&,,’)2
&,-’02
&,.’-0
&,.’2.
9F 1.
H:6 10
-*’))
-+’))
-,’+)
-)’))
-)’.)&-)’2.-)’.)&-)’2.
-+’))
-,’+)
--’0)
*))
*)+
*)+
*)+
*))
/,
11
A5
A5
.-
*,) 6Y\d‘% )! ERP\cR_f
A5
A5
*1
A5
A=
1)
*,)
FaVSS a\ cR_f ‘aVSS ZRQVbZ ‘a_R[TaU O_\d[ ‘YVTUaYf T_NcRYYf ‘N[Qf7?5L dVaU Y\d P\OOYR P\[aR[a’ FN[Q V‘ SV[R a\ P\N_‘R’ ;_NcRY V‘N[TbYN_ a\ ‘bO_\b[QRQ SV[R a\ P\N_‘R \S ‘N[Q‘a\[R% ZbQ‘a\[R%^bN_agVaR N[Q ZVeRQ YaVU\Y\TVR‘’ 7\OOYR‘ N_R ‘bON[TbYN_ \S‘N[Q‘a\[R’
:V_Z a\ ‘aVSS O_\d[ ‘YVTUaYf ‘N[Qf ‘YVTUaYf T_NcRYYf 7?5L’ FN[QV‘ SV[R a\ P\N_‘R’ ;_NcRY V‘ ‘bON[TbYN_ a\ ‘bO_\b[QRQ \S‘N[Q‘a\[R% ZbQ‘a\[R% ̂ bN_agVaR N[Q ZVeRQ YVaU\Y\TVR‘’
S_\Z -+’))Z a\ -+’-.Z N‘‘bZRQ g\[R \S P\_R Y\‘‘
FaVSS O_\d[ ‘N[Qf 7?5L’
S_\Z -,’++Z a\ -,’,1Z N‘‘bZRQ g\[R \S P\_R Y\‘‘
6_\d[ a\ _RQQV‘U O_\d[ ‘YVTUaYf T_NcRYYf ‘N[Qf 7?5L’ FN[Q V‘ SV[Ra\ P\N_‘R’ ;_NcRY V‘ N[TbYN_ a\ ‘bO_\b[QRQ \S ‘N[Q‘a\[R%ZbQ‘a\[R N[Q ZVeRQ YVaU\Y\TVR‘’
9ea_RZRYf dRNX a\ Y\PNYYf cR_f dRNX V[QV‘aV[PaYf aUV[Yf YNZV[NaRQa\ cR_f aUV[Yf ORQQRQ _RQQV‘U O_\d[ ‘VYaf SV[R a\ ZRQVbZ T_NV[RQF5A8FGBA9’ 8V‘P\[aV[bVaVR‘ *# )&. QRT_RR‘ Rea_RZRYf PY\‘RYf a\PY\‘RYf ‘]NPRQ ]YN[N_ ‘Z\\aU’ +# 1)&2) QRT_RR‘ PY\‘RYf ‘]NPRQ]YN[N_ Y\PNYYf V__RTbYN_ _\bTU’
S_\Z --’0)Z a\ -.’-*Z dVaU cR_f PY\‘RYf ‘]NPRQ aUVPXYNZV[NaV\[‘ \S T_RR[ ‘N[Q‘a\[R
FURRa 2 \S **
8R‘P_V]aV\[ \S Fa_NaN ?RTR[Q 8R]aU?RcRY8NabZ FNZ]YV[T
8RaNVY‘=[ FVab GR‘a =[‘aNYY&
NaV\[
ABG9F3 5YY QR]aU‘ V[ ZRa_R‘% NYY QVNZRaR_‘ V[ ZVYYVZRa_R‘’FRR URNQR_ ‘URRa S\_ QRaNVY‘ \S O\_V[T%
<\YR =8’
8RaNVY‘
6Y\d 7\b[a 5[Q
C_\WRPa A\’
G7E F7E ED8
9Z]Y\fR_9[TV[RR_
7\\_QV[NaR‘;_\b[Q ?RcRY
9e]Y\_Na\_f <\YR ?\TC_\WRPa ANZR
<\YR Gf]R =[PYV[NaV\[
:\_Z A\’ F=9KC<B?9?B; =‘‘bR’ERcV‘V\[ A\’ *’)/ =‘‘bR 8NaR +)()2(+)*, CN_a \S aUR 6NPUf F\YRaN[PUR ;_\b]
FNZ]YR ERP\cR_f
:\_ QRaNVY‘ \S NOO_RcVNaV\[‘% ‘RR XRf]_\T_R‘‘ N[Q dNaR_’
8VN’"GUVPX[R‘‘#
?\T FaNab‘3 C_RYVZV[N_f
=C$7C$E7
G50-,0
0’2*Z B8
@R_‘Rf ;NaRdNf 6_VQTR’ 5QQVaV\[NY ;= "CUN‘R +#
@R_‘Rf ?V[X 7>I@R_‘Rf ?V[X 7>I
?\T C_V[a 8NaR 5[Q GVZR3 +)().(+)*. )23),3)2
,.*0-/’*. 9% ,1-00*’+* A ANaV\[NY ;_VQIR_aVPNY
&
=:
6<KK+
-.’-*
-0’*/
-2’22
"*’0.#
"+’1,#
&,0’.)
&,2’+.
&-+’)1
--’0)
-/’,)
-0’,)
-1’,)
-/’,)
-0’,)
-1’,)
-2’,)
*)+
*)+
*)+
*)+
02
2/
20
*))
./
1.
20
*))
-/
+,
1,
1/
A=
0)
,)
*0)
*,)
,/)
ERZNV[V[T 8RaNVY 3 --’2)Z & -.’+)Z 3 S_\Z --’2)Z a\ -.’+)Z ZRQVbZORQ \S T_RR[V‘U T_Rf ‘N[Q‘a\[R
8RaNVY --’2)Z & .)’)0Z 3 S_\Z --’2)Z a\ .)’)0Z dVaU aUV[YNZV[NaV\[‘ \S YVTUa T_RR[V‘U T_Rf ‘N[Q‘a\[R’
JRNX Y\PNYYf Rea_RZRYf dRNX V[QV‘aV[PaYf aUV[Yf a\ aUVPXYfYNZV[NaRQ _RQQV‘U O_\d[ ‘VYaf SV[R a\ ZRQVbZ T_NV[RQ F5A8FGBA9’8V‘P\[aV[bVaVR‘ *# )&*) QRT_RR‘ Rea_RZRYf PY\‘RYf a\ PY\‘RYf‘]NPRQ ]YN[N_ ‘Z\\aU Y\PNYYf V__RTbYN_ _\bTU
S_\Z -.’2/Z a\ -/’,)Z N‘‘bZRQ g\[R \S P\_R Y\‘‘
S_\Z -/’/-Z a\ -/’/1Z _RP\cR_RQ N‘ [\[ V[aNPa "‘N[Qf‘bON[TbYN_ SV[R a\ P\N_‘R T_NcRY ‘VgRQ S_NTZR[a‘#
JRNX \PPN‘V\[NYYf cR_f dRNX V[QV‘aV[PaYf aUV[Yf a\ aUVPXYfYNZV[NaRQ _RQQV‘U O_\d[ ‘VYaf SV[R Y\PNYYf ZRQVbZ T_NV[RQF5A8FGBA9’ 8V‘P\[aV[bVaVR‘ *# )&*) QRT_RR‘ PY\‘RYf a\ ZRQVbZY\PNYYf cR_f PY\‘RYf ‘]NPRQ ]YN[N_ ‘Z\\aU Y\PNYYf V__RTbYN__\bTU’ +# 1)&2) QRT_RR‘ PY\‘RYf a\ ZRQVbZ ‘]NPRQ V__RTbYN_ _\bTU’
FURRa *) \S **
8R‘P_V]aV\[ \S Fa_NaN ?RTR[Q 8R]aU?RcRY8NabZ FNZ]YV[T
8RaNVY‘=[ FVab GR‘a =[‘aNYY&
NaV\[
ABG9F3 5YY QR]aU‘ V[ ZRa_R‘% NYY QVNZRaR_‘ V[ ZVYYVZRa_R‘’FRR URNQR_ ‘URRa S\_ QRaNVY‘ \S O\_V[T%
<\YR =8’
8RaNVY‘
6Y\d 7\b[a 5[Q
C_\WRPa A\’
G7E F7E ED8
9Z]Y\fR_9[TV[RR_
7\\_QV[NaR‘;_\b[Q ?RcRY
9e]Y\_Na\_f <\YR ?\TC_\WRPa ANZR
<\YR Gf]R =[PYV[NaV\[
:\_Z A\’ F=9KC<B?9?B; =‘‘bR’ERcV‘V\[ A\’ *’)/ =‘‘bR 8NaR +)()2(+)*, CN_a \S aUR 6NPUf F\YRaN[PUR ;_\b]
FNZ]YR ERP\cR_f
:\_ QRaNVY‘ \S NOO_RcVNaV\[‘% ‘RR XRf]_\T_R‘‘ N[Q dNaR_’
8VN’"GUVPX[R‘‘#
?\T FaNab‘3 C_RYVZV[N_f
=C$7C$E7
G50-,0
0’2*Z B8
@R_‘Rf ;NaRdNf 6_VQTR’ 5QQVaV\[NY ;= "CUN‘R +#
@R_‘Rf ?V[X 7>I@R_‘Rf ?V[X 7>I
?\T C_V[a 8NaR 5[Q GVZR3 +)().(+)*. )23),3*+
,.*0-/’*. 9% ,1-00*’+* A ANaV\[NY ;_VQIR_aVPNY
&
=:
6<KK+
.,’1)
",’1*#
&-.’12
-2’,)
.)’1)
.+’,)
.)’1)
.+’,)
.,’1)
*)+
*)+
*)+
*))
2,
2.
2/
2*
2.
0+
12
1*
-)
+))
.+)
MMMMMMMMMMMM-0’*/Z & -2’22Z 3 ERZNV[V[T 8RaNVY 3 -2’10Z & -2’22Z 3 S_\Z-2’10Z a\ -2’22Z dVaU aUV[X a\ aUV[ YNZV[NaV\[‘ YVTUa T_RR[V‘UT_Rf N[Q O_\d[ ‘N[Q‘a\[RMMMMMMMMMMMM-2’22Z & .,’1)Z 3 JRNX a\ ZRQVbZ ‘a_\[T V[QV‘aV[PaYf aUV[Yf a\aUVPXYf YNZV[NaRQ _RQQV‘U O_\d[ ‘VYaf SV[R a\ ZRQVbZ T_NV[RQF5A8FGBA9’ 8V‘P\[aV[bVaVR‘ *# )&*) QRT_RR‘ PY\‘RYf a\ ZRQVbZ‘]NPRQ ]YN[N_ ‘Z\\aU’
8RaNVY .)’1)Z & .)’2*Z 3 S_\Z .)’1)Z a\ .)’2*Z N‘‘bZRQ g\[R\S P\_R Y\‘‘8RaNVY .+’)-Z & .+’,)Z 3 S_\Z .+’)-Z a\ .+’,)Z ZRQVbZ ORQ\S YVTUa T_RR[V‘U T_Rf ‘N[Q‘a\[R’S_\Z .)’1)Z a\ .)’2*Z N‘‘bZRQ g\[R \S P\_R Y\‘‘
S_\Z .+’)-Z a\ .+’,)Z ZRQVbZ ORQ \S YVTUa T_RR[V‘U T_Rf‘N[Q‘a\[R’
9e]Y\_Na\_f U\YR P\Z]YRaR Na .,’1) Z’
FURRa ** \S **
DT^P _Z FTXP_Z ]T^P
6L^TYR OP[_SL_ ^_]TVP
_TXP_Z ^PLW
7P[_S Fd[P <YN]PXPY_LW MWZb NZ‘Y_ (
;PLOP]
ABF8E3 4WW OP[_S^ TY XP_]P^%IL_P] ^_]TVP ]T^P _TXP TY XTY‘_P^%
:8A8D4? ABF8E
9]ZXOP[_S
FZOP[_S
9W‘^S_d[P
9W‘^S]P_‘]Y
$ EPL_TYR MWZb^ ZYWd’
DPXL]V^ 6L^TYR IL_P]OP[_S
6ST^PWWTYR
9Z]X AZ’ E<8JC;B?8;7D <^^‘P’DPaT^TZY AZ’ *’)/ <^^‘P 7L_P *)(),(+)*-
8\‘T[XPY_FZ[ 5L^P Fd[P 7L_P E_L]_PO 7L_P 8YOPO 6]Pb EPN_TZY ESZ]TYR ( DPXL]V^
LWW OTLXP_P]^ TY XTWWTXP_]P^’SL]O ^_]L_L _TXP TY SSXX
8YP]Rd]L_TZ
FZ[ 5L^P 7TLXP_P] FTXP DPNZaP]d!
7KA4@<6 E4@C?<A:
[PYP_]L_TZY TY XX;LXXP]
AZ’
CL]_ ZQ _SP 5LNSd EZWP_LYNSP :]Z‘[
Fd[P DP^[ZY^P eZYPFZ[ 5L^P
CT[P
F40-,0
+*()-(+)*.&
@P]^Pd :L_PbLd 5]TORP’ 4OOT_TZYLW :< "CSL^P +#
@P]^Pd ?TYV 6=H@P]^Pd ?TYV 6=H
?ZR C]TY_ 7L_P 4YO FTXP3 *.().(+)*. )13-23,2
&++()-(+)*.
&
HP]_TNLW
5;JJ-
)’)) *)’0) 6C +*()-(+)*. ++()-(+)*. 66 47= A4 A4 7LYOZ ,)))
+))
*)’0)
)’)) )’.) 6ZYN]P_P)’.) 0’.) 5PY_ZYT_P0’.) *)’0) :]LaPW MLNVQTWW
+*()-(+)*. *0,) /’+) /’+) 8YO ZQ ESTQ_++()-(+)*. )0,) /’+) /’+) E_L]_ ZQ ESTQ_++()-(+)*. *0,) *)’0) *)’-) 8YO ZQ ;ZWP
)*
*)’0) +))
EC
*)’-)
0’.) *)’0)
-’2)-’*).’0)
)* )’)) 0’.) .) CWLTY)* 0’.) *)’0) .) EWZ__PO
+*()-(+)*. ,’+) ,’)) +) ,’+) AD
FZ[OP[_S
5L^POP[_S
DPXL]V^78CF; D8?4F87 D8@4D>E
C<C8 6BAEFDG6F<BA
<7
OP[_S
SSXX^^
5T_6Z]P 6Z]P
5L]]PW E‘[[Z]_?ZRRPO 5d
7TL’ZQ [T[P
!
DPXL]V^@L_P]TLW^PN_TZY
5L^P ZQ^PN_TZY
FZ[ ZQ546>9<?? 78F4<?E
!7‘]L_TZY
SSXXE_L]_ _TXP
9W‘^SNZWZ‘]
_LVPYQWZb
FZ[ 5L^PFd[P ZQ
[T[P7T^_LYNP
<AEF4??4F<BA 78F4<?E
Q]ZX :’?’<7
C]ZUPN_ AZ’
C]ZUPN_ ALXP
8X[WZdP]8YRTYPP]
6ZZ]OTYL_P^:]Z‘YO ?PaPW<YNWTYL_TZY7L_P E_L]_PO 7L_P 6ZX[WP_PO
;ZWP <7’8c[WZ]L_Z]d ;ZWP ?ZR
645?8 C8D6GEE<BA 78F4<?E
;B?8 7<4@8F8D ( 64E<A:
I4F8D EFD<>8E
DBF4DK 9?GE; 78F4<?E
ECF 78F4<?E
CDB:D8EEDPXL]V^7L_P FTXP ;ZWP
OP[_S OP[_S6L^TYR IL_P]
OP[_S
;L]O E_]L_L 7P[_SQ]ZX _Z
SSXX
;ZWPOTLXP_P]
7P[_S ZQSZWP
6L^TYROTLXP_P]
7P[_S ZQNL^TYR
7L_P FTXP E_]TVP L_OP[_S OP[_S
5M[KZQX\QWV WN C\ZI\I <MOMVL 5MX\P<M^MT5I\]U CIUXTQVO
5M\IQT[:V CQ\] DM[\ :V[\ITT$
I\QWV
>?D6C1 2TT LMX\P[ QV UM\ZM[# ITT LQIUM\MZ[ QV UQTTQUM\ZM[%CMM PMILMZ [PMM\ NWZ LM\IQT[ WN JWZQVO#
9WTM :5%
5M\IQT[
3TW_ 4W]V\ 2VL
@ZWRMK\ >W%
D4B C4B BA5
6UXTWaMZ6VOQVMMZ
4WWZLQVI\M[8ZW]VL <M^MT
6‘XTWZI\WZa 9WTM <WO@ZWRMK\ >IUM
9WTM DaXM :VKTQVI\QWV
7WZU >W% C:6G@9?<6<?8 :[[]M%BM^Q[QWV >W% (%’- :[[]M 5I\M )’&’0&)’(* @IZ\ WN \PM 3IKPa CWTM\IVKPM 8ZW]X
CIUXTM BMKW^MZa
7WZ LM\IQT[ WN IJJZM^QI\QWV[# [MM SMaXZWOZM[[ IVL _I\MZ%
5QI%!DPQKSVM[["
4@
D2.+*.
$
=MZ[Ma 8I\M_Ia 3ZQLOM% 2LLQ\QWVIT 8: !@PI[M )"
=MZ[Ma <QVS 4;F=MZ[Ma <QVS 4;F
<WO @ZQV\ 5I\M 2VL DQUM1 (,&’,&)’(, ’/1+01+)
$FMZ\QKIT
$
39GG+
+%*’
,%)’
!+%*’"
!’%0’"
!+%/’"
6C (
6C )
6C *
6C +
6C ,
6C -
6C .
6C /
6C 0
6C (’
’%,’
(%,’
)%,’
*%,’
+%*’
,%)’
-%)’
.%)’
/%)’
0%)’
=256 8B?E>51 <QOP\ OZMaQ[P JZW_V [TQOP\Ta KTIaMa [IVLa IVO]TIZ \W[]JIVO]TIZ NQVM \W KWIZ[M OZI^MT [QbML NZIOUMV\[ WN TQUM[\WVM_Q\P TW_ KWJJTM KWV\MV\% CIVL Q[ NQVM \W KWIZ[M% 4WJJTM [QbMLNZIOUMV\[ IZM IVO]TIZ \W []JIVO]TIZ WN TQUM[\WVM%
7QZU LIZS OZMa [TQOP\Ta [QT\a 4<2H%
8ZMa \W JZW_V [QT\a NQVM \W KWIZ[M C2>5 _Q\P WKKI[QWVIT KWITNTMKS[%
CPMM\ ( WN )
5M[KZQX\QWV WN C\ZI\I <MOMVL 5MX\P<M^MT5I\]U CIUXTQVO
5M\IQT[:V CQ\] DM[\ :V[\ITT$
I\QWV
>?D6C1 2TT LMX\P[ QV UM\ZM[# ITT LQIUM\MZ[ QV UQTTQUM\ZM[%CMM PMILMZ [PMM\ NWZ LM\IQT[ WN JWZQVO#
9WTM :5%
5M\IQT[
3TW_ 4W]V\ 2VL
@ZWRMK\ >W%
D4B C4B BA5
6UXTWaMZ6VOQVMMZ
4WWZLQVI\M[8ZW]VL <M^MT
6‘XTWZI\WZa 9WTM <WO@ZWRMK\ >IUM
9WTM DaXM :VKTQVI\QWV
7WZU >W% C:6G@9?<6<?8 :[[]M%BM^Q[QWV >W% (%’- :[[]M 5I\M )’&’0&)’(* @IZ\ WN \PM 3IKPa CWTM\IVKPM 8ZW]X
CIUXTM BMKW^MZa
7WZ LM\IQT[ WN IJJZM^QI\QWV[# [MM SMaXZWOZM[[ IVL _I\MZ%
5QI%!DPQKSVM[["
4@
D2.+*.
$
=MZ[Ma 8I\M_Ia 3ZQLOM% 2LLQ\QWVIT 8: !@PI[M )"
=MZ[Ma <QVS 4;F=MZ[Ma <QVS 4;F
<WO @ZQV\ 5I\M 2VL DQUM1 (,&’,&)’(, ’/1+01++
$FMZ\QKIT
$
39GG+
(’%’’(’%)’(’%*’
(’%.’
!’%)’"
!’%+’"
6C ((6C ()6C (*
(’%’’(’%)’(’%*’
7QZU OZMa [TQOP\Ta [IVLa 4<2H% CIVL Q[ NQVM \W KWIZ[M%
8ZMa ^MZa OZI^MTTa C2>5% 8ZI^MT Q[ []JIVO]TIZ \W ZW]VLML NQVM \WKWIZ[M WN [IVL[\WVM IVL U]L[\WVM%
7QZU \W [WN\ JZW_V [TQOP\Ta [IVLa OZI^MTTa 4<2H% CIVL Q[ NQVM \WKWIZ[M% 8ZI^MT Q[ IVO]TIZ \W ZW]VLML NQVM \W KWIZ[M WN [IVL[\WVM#U]L[\WVM# OZIVQ\M IVL Y]IZ\bQ\M%6‘XTWZI\WZa PWTM KWUXTM\M I\ (’%.’ U%
CPMM\ ) WN )
DT^P _Z FTXP_Z ]T^P
6L^TYR OP[_SL_ ^_]TVP
_TXP_Z ^PLW
7P[_S Fd[P <YN]PXPY_LW MWZb NZ‘Y_ (
;PLOP]
ABF8E3 4WW OP[_S^ TY XP_]P^%IL_P] ^_]TVP ]T^P _TXP TY XTY‘_P^%
:8A8D4? ABF8E
9]ZXOP[_S
FZOP[_S
9W‘^S_d[P
9W‘^S]P_‘]Y
$ EPL_TYR MWZb^ ZYWd’
DPXL]V^ 6L^TYR IL_P]OP[_S
6ST^PWWTYR
9Z]X AZ’ E<8JC;B?8;7D <^^‘P’DPaT^TZY AZ’ *’)/ <^^‘P 7L_P *)(),(+)*-
8\‘T[XPY_FZ[ 5L^P Fd[P 7L_P E_L]_PO 7L_P 8YOPO 6]Pb EPN_TZY ESZ]TYR ( DPXL]V^
LWW OTLXP_P]^ TY XTWWTXP_]P^’SL]O ^_]L_L _TXP TY SSXX
8YP]Rd]L_TZ
FZ[ 5L^P 7TLXP_P] FTXP DPNZaP]d!
7KA4@<6 E4@C?<A:
[PYP_]L_TZY TY XX;LXXP]
AZ’
CL]_ ZQ _SP 5LNSd EZWP_LYNSP :]Z‘[
Fd[P DP^[ZY^P eZYPFZ[ 5L^P
CT[P
F40-,0
+,()-(+)*.&
@P]^Pd :L_PbLd 5]TORP’ 4OOT_TZYLW :< "CSL^P +#
@P]^Pd ?TYV 6=H@P]^Pd ?TYV 6=H
?ZR C]TY_ 7L_P 4YO FTXP3 *1().(+)*. )23,03-.
&+,()-(+)*.
&
HP]_TNLW
5;JJ.
)’)) *)’0) 6C +,()-(+)*. +0()-(+)*. 66 47= A4 A4 7LYOZ ,)))
+))
*)’0)
)’)) )’.) 6ZYN]P_P)’.) 0’.) 5PY_ZYT_P0’.) *)’0) :]LaPW MLNVQTWW
+,()-(+)*. *0,) -’1) -’1) 8YO ZQ ESTQ_+-()-(+)*. )0,) -’1) -’1) E_L]_ ZQ ESTQ_+-()-(+)*. *0,) *)’*) *)’)) 8YO ZQ ESTQ_+0()-(+)*. )0,) *)’*) *)’)) E_L]_ ZQ ESTQ_+0()-(+)*. *0,) *)’0) *)’-) 8YO ZQ ;ZWP
)*
*)’0) +))
EC
*)’-)
0’.) *)’0)
-’0),’..-’2),’0).’0)
)* )’)) 0’.) .) CWLTY)* 0’.) *)’0) .) EWZ__PO
FZ[OP[_S
5L^POP[_S
DPXL]V^78CF; D8?4F87 D8@4D>E
C<C8 6BAEFDG6F<BA
<7
OP[_S
SSXX^^
5T_6Z]P 6Z]P
5L]]PW E‘[[Z]_?ZRRPO 5d
7TL’ZQ [T[P
!
DPXL]V^@L_P]TLW^PN_TZY
5L^P ZQ^PN_TZY
FZ[ ZQ546>9<?? 78F4<?E
!7‘]L_TZY
SSXXE_L]_ _TXP
9W‘^SNZWZ‘]
_LVPYQWZb
FZ[ 5L^PFd[P ZQ
[T[P7T^_LYNP
<AEF4??4F<BA 78F4<?E
Q]ZX :’?’<7
C]ZUPN_ AZ’
C]ZUPN_ ALXP
8X[WZdP]8YRTYPP]
6ZZ]OTYL_P^:]Z‘YO ?PaPW<YNWTYL_TZY7L_P E_L]_PO 7L_P 6ZX[WP_PO
;ZWP <7’8c[WZ]L_Z]d ;ZWP ?ZR
645?8 C8D6GEE<BA 78F4<?E
;B?8 7<4@8F8D ( 64E<A:
I4F8D EFD<>8E
DBF4DK 9?GE; 78F4<?E
ECF 78F4<?E
CDB:D8EEDPXL]V^7L_P FTXP ;ZWP
OP[_S OP[_S6L^TYR IL_P]
OP[_S
;L]O E_]L_L 7P[_SQ]ZX _Z
SSXX
;ZWPOTLXP_P]
7P[_S ZQSZWP
6L^TYROTLXP_P]
7P[_S ZQNL^TYR
7L_P FTXP E_]TVP L_OP[_S OP[_S
5M[KZQX\QWV WN C\ZI\I <MOMVL 5MX\P<M^MT5I\]U CIUXTQVO
5M\IQT[:V CQ\] DM[\ :V[\ITT$
I\QWV
>?D6C1 2TT LMX\P[ QV UM\ZM[# ITT LQIUM\MZ[ QV UQTTQUM\ZM[%CMM PMILMZ [PMM\ NWZ LM\IQT[ WN JWZQVO#
9WTM :5%
5M\IQT[
3TW_ 4W]V\ 2VL
@ZWRMK\ >W%
D4B C4B BA5
6UXTWaMZ6VOQVMMZ
4WWZLQVI\M[8ZW]VL <M^MT
6‘XTWZI\WZa 9WTM <WO@ZWRMK\ >IUM
9WTM DaXM :VKTQVI\QWV
7WZU >W% C:6G@9?<6<?8 :[[]M%BM^Q[QWV >W% (%’- :[[]M 5I\M )’&’0&)’(* @IZ\ WN \PM 3IKPa CWTM\IVKPM 8ZW]X
CIUXTM BMKW^MZa
7WZ LM\IQT[ WN IJJZM^QI\QWV[# [MM SMaXZWOZM[[ IVL _I\MZ%
5QI%!DPQKSVM[["
4@
D2.+*.
$
=MZ[Ma 8I\M_Ia 3ZQLOM% 2LLQ\QWVIT 8: !@PI[M )"
=MZ[Ma <QVS 4;F=MZ[Ma <QVS 4;F
<WO @ZQV\ 5I\M 2VL DQUM1 (/&’,&)’(, ’01*.1+/
$FMZ\QKIT
$
39GG,
+%-’
+%/’
!+%-’"
!’%)’"
!,%)’"
6C (
6C )
6C *
6C +
6C ,
6C -
6C .
6C /
6C 0
6C (’
6C ((
’%,’
(%,’
)%,’
*%,’
+%,’
+%.’
,%’’
-%’’
.%’’
/%’’
0%’’
=256 8B?E>51 <QOP\ OZMaQ[P JZW_V [TQOP\Ta KTIaMa [IVLa IVO]TIZ \W[]JIVO]TIZ NQVM \W KWIZ[M OZI^MT [QbML NZIOUMV\[ WN TQUM[\WVM_Q\P TW_ KWJJTM KWV\MV\% CIVL Q[ NQVM \W KWIZ[M% 4WJJTM [QbMLNZIOUMV\[ IZM IVO]TIZ \W []JIVO]TIZ WN TQUM[\WVM%
7QZU OZMa [TQOP\Ta [QT\a 4<2H%
8ZMa \W JZW_V [QT\a NQVM \W KWIZ[M C2>5 _Q\P WKKI[QWVIT KWITNTMKS[%
CPMM\ ( WN )
5M[KZQX\QWV WN C\ZI\I <MOMVL 5MX\P<M^MT5I\]U CIUXTQVO
5M\IQT[:V CQ\] DM[\ :V[\ITT$
I\QWV
>?D6C1 2TT LMX\P[ QV UM\ZM[# ITT LQIUM\MZ[ QV UQTTQUM\ZM[%CMM PMILMZ [PMM\ NWZ LM\IQT[ WN JWZQVO#
9WTM :5%
5M\IQT[
3TW_ 4W]V\ 2VL
@ZWRMK\ >W%
D4B C4B BA5
6UXTWaMZ6VOQVMMZ
4WWZLQVI\M[8ZW]VL <M^MT
6‘XTWZI\WZa 9WTM <WO@ZWRMK\ >IUM
9WTM DaXM :VKTQVI\QWV
7WZU >W% C:6G@9?<6<?8 :[[]M%BM^Q[QWV >W% (%’- :[[]M 5I\M )’&’0&)’(* @IZ\ WN \PM 3IKPa CWTM\IVKPM 8ZW]X
CIUXTM BMKW^MZa
7WZ LM\IQT[ WN IJJZM^QI\QWV[# [MM SMaXZWOZM[[ IVL _I\MZ%
5QI%!DPQKSVM[["
4@
D2.+*.
$
=MZ[Ma 8I\M_Ia 3ZQLOM% 2LLQ\QWVIT 8: !@PI[M )"
=MZ[Ma <QVS 4;F=MZ[Ma <QVS 4;F
<WO @ZQV\ 5I\M 2VL DQUM1 (/&’,&)’(, ’01*.1,’
$FMZ\QKIT
$
39GG,
(’%’’
(’%+’
(’%.’
!’%+’"
!’%*’"
6C ()
6C (*
(’%’’
(’%+’
8ZMa ^MZa OZI^MTTa C2>5% 8ZI^MT Q[ []JIVO]TIZ \W []JZW]VLML NQVM\W KWIZ[M WN [IVL[\WVM IVL U]L[\WVM%
7QZU \W [\QNN JZW_V [TQOP\Ta [IVLa [TQOP\Ta OZI^MTTa 4<2H% CIVLQ[ NQVM \W KWIZ[M% 8ZI^MT Q[ []JIVO]TIZ \W []JZW]VLML NQVM \WKWIZ[M WN [IVL[\WVM# U]L[\WVM# OZIVQ\M IVL Y]IZ\bQ\M%6‘XTWZI\WZa PWTM KWUXTM\M I\ (’%.’ U%
CPMM\ ) WN )
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 C 17 MARCH 2016
APPENDIX C – LAB REPORTS (SOIL)
Scientific Analysis Laboratories Ltd
Certificate of Analysis
Hadfield HouseHadfield Street
CornbrookManchester
M16 9FETel : 0161 874 2400Fax : 0161 874 2468
Report Number: 428221-2
Date of Report: 16-Oct-2014
Customer: Soil Engineering Geoservices LimitedParkside LaneDewsbury RoadLeedsWest Yorkshire.LS11 5SX
Customer Contact: Mr Peter Stoddart
Customer Job Reference: TA7437Customer Site Reference: Mersey Gateway Bridge Additional Phase
GI (Phase 2)Date Job Received at SAL: 30-Sep-2014
Date Analysis Started: 10-Oct-2014Date Analysis Completed: 16-Oct-2014
The results reported relate to samples received in the laboratoryOpinions and interpretations expressed herein are outside the scope of UKAS accreditationThis report should not be reproduced except in full without the written approval of the laboratoryTests covered by this certificate were conducted in accordance with SAL SOPsAll results have been reviewed in accordance with QP22
This document has been printed from a digitally signed master copy
Scientific Analysis Laboratories is a
limited company registered in England and
Wales (No 2514788) whose address is at
Hadfield House, Hadfield Street, Manchester M16 9FE
1549
Report checkedand authorised by :Mr Ross WalkerCustomer Services Manager(Land)
Issued by :Mr Ross WalkerCustomer Services Manager(Land)
Page 1 of 12
428221-2
SAL Reference: 428221
Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Metals
SAL Reference 428221002
428221012
428221015
428221016
428221017
428221018
428221021
Customer Sample Reference BHXX1 ES007
BHXX2 ES001
BHXX2 ES018
BHXX2 ES025
BHXX2 ES038
BHXX2 ES051
BHXX2 ES085
Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Date Sampled 26-SEP-2014
25-SEP-2014
29-SEP-2014
29-SEP-2014
29-SEP-2014
30-SEP-2014
02-OCT-2014
Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Type Sandy Soil Clay Clay Sandy Soil Clay Clay Clay
Determinand Method TestSample LOD Units
Arsenic T6 M40 2 mg/kg 49 380 24 7 8 8 6
Barium T6 M40 1 mg/kg 42 370 92 47 110 140 88
Chromium VI T6 AR 1 mg/kg <1 <1 <1 <1 <1 <1 <1
Beryllium T6 M40 2 mg/kg <2 <2 <2 <2 <2 <2 <2
Boron (water-soluble) T6 AR 1 mg/kg <1 <1 <1 <1 <1 <1 <1
Cadmium T6 M40 1 mg/kg <1 6 <1 <1 <1 <1 <1
Chromium T6 M40 1 mg/kg 10 38 27 6 27 33 24
Copper T6 M40 1 mg/kg 19 380 23 5 19 23 13
Lead T6 M40 1 mg/kg 38 390 18 4 11 13 7
Mercury T6 M40 1 mg/kg <1 5 <1 <1 <1 <1 <1
Nickel T6 M40 1 mg/kg 10 39 30 8 30 37 26
Selenium T6 M40 3 mg/kg <3 <3 <3 <3 <3 <3 <3
Vanadium T6 M40 1 mg/kg 11 23 27 7 26 31 25
Zinc T6 M40 1 mg/kg 130 2300 120 28 53 63 41
SAL Reference: 428221
Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Miscellaneous
SAL Reference 428221002
428221012
428221015
428221016
428221017
428221018
428221021
Customer Sample Reference BHXX1ES 007
BHXX2ES 001
BHXX2ES 018
BHXX2ES 025
BHXX2ES 038
BHXX2ES 051
BHXX2ES 085
Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Date Sampled 26-SEP-2014
25-SEP-2014
29-SEP-2014
29-SEP-2014
29-SEP-2014
30-SEP-2014
02-OCT-2014
Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Type SandySoil
Clay Clay SandySoil
Clay Clay Clay
Determinand Method TestSample LOD Units
Mass Fraction of organic carbon T286 M40 0.0030 0.033 0.0053 0.0012 0.0047 0.0062 0.0019
Cyanide(Total) T546 AR 1 mg/kg <1 3 <1 <1 <1 <1 <1
Cyanide(free) T546 AR 1 mg/kg <1 <1 <1 <1 <1 <1 <1
pH T7 AR 7.8 7.4 8.0 8.1 8.3 8.2 8.5
Phenols(Mono) T546 AR 1 mg/kg <1 <1 <1 <1 <1 <1 <1
(Water Soluble) SO4 expressed as SO4 T242 M40 0.01 g/l 0.12 1.1 0.51 0.22 0.18 0.16 0.05
Sulphide T546 AR 1 mg/kg 1 20 <1 <1 <1 <1 <1
Sulphur (total) T6 M40 0.01 % 0.13 1.1 0.13 0.03 0.05 0.06 0.03
TPH (C10-C35) T8 M105 1 mg/kg <1 52 <1 <1 <1 <1 <1
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 2 of 12
428221-2
SAL Reference: 428221
Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Moisture
SAL Reference 428221002
428221004
428221005
428221010
428221011
428221012
428221015
428221016
428221017
428221018
428221021
Customer Sample Reference BHXX1ES 007
BHXX1ES 023
BHXX1ES 025
BHXX1ES 048
BHXX1ES 061
BHXX2ES 001
BHXX2ES 018
BHXX2ES 025
BHXX2ES 038
BHXX2ES 051
BHXX2ES 085
Depth 5.00 9.50 10.00 18.70 25.00 3.80 10.10 13.50 18.50 24.00 40.00
Date Sampled 26-SEP-2014
29-SEP-2014
29-SEP-2014
30-SEP-2014
01-OCT-2014
25-SEP-2014
29-SEP-2014
29-SEP-2014
29-SEP-2014
30-SEP-2014
02-OCT-2014
Bottom Depth 5.00 9.50 10.00 18.70 25.00 3.80 10.10 13.50 18.50 24.00 40.00
Type SandySoil
SandySoil
Clay Clay Clay Clay Clay SandySoil
Clay Clay Clay
Determinand Method TestSample LOD Units
Moisture @ 105 C T162 AR 0.1 % 24 20 11 22 23 44 15 18 20 22 14
SAL Reference: 428221
Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Asbestos
SAL Reference 428221002
428221012
428221015
428221016
428221017
428221018
428221021
Customer Sample Reference BHXX1 ES007
BHXX2 ES001
BHXX2 ES018
BHXX2 ES025
BHXX2 ES038
BHXX2 ES051
BHXX2 ES085
Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Date Sampled 26-SEP-2014
25-SEP-2014
29-SEP-2014
29-SEP-2014
29-SEP-2014
30-SEP-2014
02-OCT-2014
Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Type Sandy Soil Clay Clay Sandy Soil Clay Clay Clay
Determinand Method TestSample LOD Units
Asbestos ID T27 AR N.D. N.D. N.D. N.D. N.D. N.D. N.D.
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 3 of 12
428221-2
SAL Reference: 428221
Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
PAH EPA 16, Coronene
SAL Reference 428221002
428221012
428221015
428221016
428221017
428221018
428221021
Customer Sample Reference BHXX1 ES007
BHXX2 ES001
BHXX2 ES018
BHXX2 ES025
BHXX2 ES038
BHXX2 ES051
BHXX2 ES085
Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Date Sampled 26-SEP-2014
25-SEP-2014
29-SEP-2014
29-SEP-2014
29-SEP-2014
30-SEP-2014
02-OCT-2014
Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Type Sandy Soil Clay Clay Sandy Soil Clay Clay Clay
Determinand Method TestSample LOD Units
Naphthalene T207 M105 0.1 mg/kg <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1
Acenaphthylene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Acenaphthene T207 M105 0.1 mg/kg <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1
Fluorene T207 M105 0.1 mg/kg <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1
Phenanthrene T207 M105 0.1 mg/kg <0.1 1.2 <0.1 <0.1 <0.1 <0.1 <0.1
Anthracene T207 M105 0.1 mg/kg <0.1 0.4 <0.1 <0.1 <0.1 <0.1 <0.1
Fluoranthene T207 M105 0.1 mg/kg <0.1 2.0 <0.1 <0.1 <0.1 <0.1 <0.1
Pyrene T207 M105 0.1 mg/kg <0.1 1.6 <0.1 <0.1 <0.1 <0.1 <0.1
Benzo(a)Anthracene T207 M105 0.1 mg/kg <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1
Chrysene T207 M105 0.1 mg/kg <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1
Benzo(b)fluoranthene T207 M105 0.1 mg/kg <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1
Benzo(k)fluoranthene T207 M105 0.1 mg/kg <0.1 0.3 <0.1 <0.1 <0.1 <0.1 <0.1
Benzo(a)Pyrene T207 M105 0.1 mg/kg <0.1 0.5 <0.1 <0.1 <0.1 <0.1 <0.1
Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1
Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Benzo(ghi)Perylene T207 M105 0.1 mg/kg <0.1 0.3 <0.1 <0.1 <0.1 <0.1 <0.1
Coronene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
PAH (Sum) T85 M105 1.6 mg/kg (36) <1.6 9.1 (110) <1.6 <1.6 <1.6 (110) <1.6 (110) <1.6
SAL Reference: 428221
Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
TPH (CWG)
SAL Reference 428221002
428221012
428221015
428221016
428221017
428221018
428221021
Customer Sample Reference BHXX1 ES007
BHXX2 ES001
BHXX2 ES018
BHXX2 ES025
BHXX2 ES038
BHXX2 ES051
BHXX2 ES085
Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Date Sampled 26-SEP-2014
25-SEP-2014
29-SEP-2014
29-SEP-2014
29-SEP-2014
30-SEP-2014
02-OCT-2014
Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Type Sandy Soil Clay Clay Sandy Soil Clay Clay Clay
Determinand Method TestSample LOD Units
TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg (100)
<0.200<0.100 <0.100 <0.100 <0.100 <0.100 <0.100
TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg (100) <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg (100) <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
TPH (C10-C12 aliphatic) T206 M105 1 mg/kg <1 <1 <1 <1 <1 <1 <1
TPH (C12-C16 aliphatic) T206 M105 2 mg/kg <2 <2 <2 <2 <2 <2 <2
TPH (C16-C21 aliphatic) T206 M105 1 mg/kg <1 2 <1 <1 <1 <1 <1
TPH (C21-C35 aliphatic) T206 M105 4 mg/kg <4 <4 <4 <4 <4 <4 <4
TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg (100) <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg (100) <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg (100) <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10
TPH (C10-C12 aromatic) T206 M105 1 mg/kg <1 <1 <1 <1 <1 <1 <1
TPH (C12-C16 aromatic) T206 M105 1 mg/kg <1 <1 <1 <1 <1 <1 <1
TPH (C16-C21 aromatic) T206 M105 1 mg/kg <1 5 <1 <1 <1 <1 <1
TPH (C21-C35 aromatic) T206 M105 1 mg/kg <1 16 <1 <1 <1 <1 <1
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 4 of 12
428221-2
SAL Reference: 428221
Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Semi-Volatile Organic Compounds (Reduced)
SAL Reference 428221002
428221012
428221015
428221016
428221017
428221018
428221021
Customer Sample Reference BHXX1ES 007
BHXX2ES 001
BHXX2ES 018
BHXX2ES 025
BHXX2ES 038
BHXX2ES 051
BHXX2ES 085
Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Date Sampled 26-SEP-2014
25-SEP-2014
29-SEP-2014
29-SEP-2014
29-SEP-2014
30-SEP-2014
02-OCT-2014
Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Type SandySoil
Clay Clay SandySoil
Clay Clay Clay
Determinand Method TestSample LOD Units
1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
1,2-Dichlorobenzene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
1,3-Dichlorobenzene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
1,4-Dichlorobenzene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
2,4,5-Trichlorophenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
2,4,6-Trichlorophenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
2,4-Dichlorophenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
2,4-Dimethylphenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
2,4-Dinitrophenol T207 M105 0.1 mg/kg (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (110) <0.5
2,4-Dinitrotoluene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
2,6-Dinitrotoluene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
2-Chloronaphthalene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
2-Chlorophenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
2-methyl phenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
2-Methylnaphthalene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
2-Nitroaniline T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
2-Nitrophenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
3-Nitroaniline T207 M105 0.1 mg/kg (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (110) <0.5
3/4-Methylphenol T207 M105 0.1 mg/kg <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1
4-Bromophenyl phenylether T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
4-Chloro-3-methylphenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
4-Chloroaniline T207 M105 0.1 mg/kg (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (110) <0.5
4-Chlorophenyl phenylether T207 M105 0.1 mg/kg (36) <0.5 <0.1 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (110) <0.5
4-Nitroaniline T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
4-Nitrophenol T207 M105 0.1 mg/kg (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (110) <0.5
Azobenzene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 0.4 0.2 <0.1 <0.1
Butyl benzylphthalate T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Carbazole T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Di-n-butylphthalate T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Di-n-octylphthalate T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Dibenzofuran T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Diethyl phthalate T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Dimethyl phthalate T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Hexachlorobenzene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Hexachlorobutadiene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Hexachlorocyclopentadiene T207 M105 0.1 mg/kg (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (110) <0.5
Hexachloroethane T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Isophorone T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Nitrobenzene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Pentachlorophenol T207 M105 0.1 mg/kg (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (110) <0.5
Phenol T207 M105 0.1 mg/kg (107) <0.2 (107) <0.2 (36) <0.2 (110) <0.2 (110) <0.2 (110) <0.2 (110) <0.2
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 5 of 12
428221-2
SAL Reference: 428221
Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Volatile Organic Compounds (USEPA 624) (MCERTS)
SAL Reference 428221002
428221004
428221005
428221010
428221011
428221012
428221015
428221016
428221017
428221018
428221021
Customer Sample Reference BHXX1ES 007
BHXX1ES 023
BHXX1ES 025
BHXX1ES 048
BHXX1ES 061
BHXX2ES 001
BHXX2ES 018
BHXX2ES 025
BHXX2ES 038
BHXX2ES 051
BHXX2ES 085
Depth 5.00 9.50 10.00 18.70 25.00 3.80 10.10 13.50 18.50 24.00 40.00
Date Sampled 26-SEP-2014
29-SEP-2014
29-SEP-2014
30-SEP-2014
01-OCT-2014
25-SEP-2014
29-SEP-2014
29-SEP-2014
29-SEP-2014
30-SEP-2014
02-OCT-2014
Bottom Depth 5.00 9.50 10.00 18.70 25.00 3.80 10.10 13.50 18.50 24.00 40.00
Type SandySoil
SandySoil
Clay Clay Clay Clay Clay SandySoil
Clay Clay Clay
Determinand Method TestSample LOD Units
1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,1,1-Trichloroethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,1,2-Trichloroethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,1-Dichloroethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,1-Dichloroethylene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,1-Dichloropropene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,2,3-Trichloropropane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,2,4-Trimethylbenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,2-dibromoethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,2-Dichlorobenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,2-Dichloroethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,2-Dichloropropane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,3,5-Trimethylbenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,3-Dichlorobenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,3-Dichloropropane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
1,4-Dichlorobenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
2,2-Dichloropropane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
2-Chlorotoluene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
4-Chlorotoluene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Benzene T209 M105 10 µg/kg (100,13)
<20(13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10
Bromobenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Bromochloromethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Bromodichloromethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Bromoform T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Bromomethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Carbon tetrachloride T209 M105 50 µg/kg (100) <100 68 <50 <50 <50 <50 <50 <50 <50 <50 <50
Chlorobenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Chlorodibromomethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Chloroethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Chloroform T209 M105 50 µg/kg (100) <100 94 <50 <50 <50 <50 430 62 <50 <50 <50
Chloromethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Cis-1,2-Dichloroethylene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Cis-1,3-Dichloropropene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Dibromomethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Dichlorodifluoromethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Dichloromethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
EthylBenzene T209 M105 10 µg/kg (100) <20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
Isopropyl benzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
M/P Xylene T209 M105 10 µg/kg (100) <20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
n-Propylbenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
O Xylene T209 M105 10 µg/kg (100) <20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
p-Isopropyltoluene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
S-Butylbenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Styrene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
T-Butylbenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Tetrachloroethene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Toluene T209 M105 10 µg/kg (100) <20 <10 <10 71 <10 <10 <10 <10 <10 <10 <10
Trans-1,2-Dichloroethene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Trans-1,3-Dichloropropene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Trichloroethene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Trichlorofluoromethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Vinyl chloride T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50
Methyl tert-Butyl Ether T209 M105 10 µg/kg (100) <20 - - - - <10 <10 <10 <10 <10 <10
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 6 of 12
428221-2
SAL Reference: 428221
Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)
Customer Reference: TA7437
Leachate to BS EN 12457-2 (10:1) Analysed as Water
Metals
SAL Reference 428221002
428221012
428221015
428221016
428221017
428221018
428221021
Customer Sample Reference BHXX1 ES007
BHXX2 ES001
BHXX2 ES018
BHXX2 ES025
BHXX2 ES038
BHXX2 ES051
BHXX2 ES085
Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Date Sampled 26-SEP-2014
25-SEP-2014
29-SEP-2014
29-SEP-2014
29-SEP-2014
30-SEP-2014
02-OCT-2014
Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Type Sandy Soil Clay Clay Sandy Soil Clay Clay Clay
Determinand Method TestSample LOD Units
As (Dissolved) T281 10:1 0.2 µg/l 460 1500 2.2 16 1.7 1.9 5.6
Ba (Dissolved) T281 10:1 1 µg/l 12 44 37 15 32 40 46
Be (Dissolved) T281 10:1 0.05 µg/l <0.05 0.07 <0.05 <0.05 <0.05 <0.05 <0.05
Chromium VI T686 10:1 3 µg/l <3 <3 <3 <3 <3 <3 <3
Boron T6 10:1 10 µg/l 28 220 35 <10 76 41 <10
Cd (Dissolved) T281 10:1 0.02 µg/l 0.03 0.06 <0.02 <0.02 0.02 <0.02 <0.02
Cr (Dissolved) T281 10:1 1 µg/l 2 2 3 1 2 2 <1
Cu (Dissolved) T281 10:1 0.5 µg/l 1.0 1.2 1.3 2.0 3.0 2.9 1.4
Pb (Dissolved) T281 10:1 0.3 µg/l 1.1 0.4 <0.3 <0.3 <0.3 0.3 <0.3
Hg (Dissolved) T281 10:1 0.05 µg/l <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Ni (Dissolved) T281 10:1 1 µg/l 1 9 <1 <1 <1 <1 <1
Se (Dissolved) T281 10:1 0.5 µg/l 0.7 2.7 1.0 1.1 4.0 4.6 1.7
V (Dissolved) T281 10:1 2 µg/l 3 <2 <2 <2 <2 2 7
Zn (Dissolved) T281 10:1 2 µg/l 7 10 3 3 6 6 3
SAL Reference: 428221
Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)
Customer Reference: TA7437
Leachate to BS EN 12457-2 (10:1) Analysed as Water
Miscellaneous
SAL Reference 428221002
428221012
428221015
428221016
428221017
428221018
428221021
Customer Sample Reference BHXX1 ES007
BHXX2 ES001
BHXX2 ES018
BHXX2 ES025
BHXX2 ES038
BHXX2 ES051
BHXX2 ES085
Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Date Sampled 26-SEP-2014
25-SEP-2014
29-SEP-2014
29-SEP-2014
29-SEP-2014
30-SEP-2014
02-OCT-2014
Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Type Sandy Soil Clay Clay Sandy Soil Clay Clay Clay
Determinand Method TestSample LOD Units
Ammoniacal nitrogen T686 10:1 0.05 mg/l 5.7 5.1 16 4.0 0.33 0.33 0.53
Chloride T686 10:1 1 mg/l 9 97 37 25 160 180 20
Cyanide(Total) T4 10:1 0.05 mg/l <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Cyanide(free) T4 10:1 0.05 mg/l <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Electrical Conductivity T7 10:1 10 µS/cm 240 2600 610 260 870 850 150
Nitrate T686 10:1 0.5 mg/l <0.5 <0.5 <0.5 <0.5 3.1 1.6 <0.5
pH T7 10:1 7.7 6.9 8.1 7.9 7.9 7.6 7.7
Phenol T149 10:1 0.5 µg/l <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Sulphate T686 10:1 0.5 mg/l 49 1400 120 45 71 64 15
Sulphide T4 10:1 0.05 mg/l <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Sulphur (total) T65 10:1 0.01 mg/l 16 500 48 16 24 22 5.5
TPH (C10-C35) T8 10:1 0.1 mg/l <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 7 of 12
428221-2
Index to symbols used in 428221-2
Notes
Method Index
SAL Reference: 428221
Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)
Customer Reference: TA7437
Leachate to BS EN 12457-2 (10:1) Analysed as Water
PAH EPA 16, Coronene
SAL Reference 428221002
428221012
428221015
428221016
428221017
428221018
428221021
Customer Sample Reference BHXX1 ES007
BHXX2 ES001
BHXX2 ES018
BHXX2 ES025
BHXX2 ES038
BHXX2 ES051
BHXX2 ES085
Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Date Sampled 26-SEP-2014
25-SEP-2014
29-SEP-2014
29-SEP-2014
29-SEP-2014
30-SEP-2014
02-OCT-2014
Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00
Type Sandy Soil Clay Clay Sandy Soil Clay Clay Clay
Determinand Method TestSample LOD Units
Naphthalene T149 10:1 0.01 µg/l 0.18 0.04 0.04 <0.01 0.05 0.04 0.03
Acenaphthylene T149 10:1 0.01 µg/l 0.05 <0.01 0.02 <0.01 <0.01 <0.01 <0.01
Acenaphthene T149 10:1 0.01 µg/l 0.04 0.03 0.02 <0.01 <0.01 <0.01 0.02
Fluorene T149 10:1 0.01 µg/l 0.06 0.03 0.03 <0.01 0.02 <0.01 0.03
Phenanthrene T149 10:1 0.01 µg/l 0.10 <0.01 0.03 <0.01 0.05 <0.01 0.04
Anthracene T149 10:1 0.01 µg/l 0.05 <0.01 <0.01 <0.01 0.01 <0.01 <0.01
Fluoranthene T149 10:1 0.01 µg/l 0.21 0.03 <0.01 <0.01 0.04 <0.01 0.03
Pyrene T149 10:1 0.01 µg/l 0.17 0.02 <0.01 <0.01 0.04 <0.01 0.02
Benzo(a)Anthracene T149 10:1 0.01 µg/l 0.09 <0.01 <0.01 <0.01 0.02 <0.01 <0.01
Chrysene T149 10:1 0.01 µg/l 0.11 <0.01 <0.01 <0.01 0.04 <0.01 0.03
Benzo(b)fluoranthene T149 10:1 0.01 µg/l 0.16 <0.01 <0.01 <0.01 0.03 <0.01 0.02
Benzo(k)fluoranthene T149 10:1 0.01 µg/l 0.09 <0.01 <0.01 <0.01 0.02 <0.01 0.01
Benzo(a)Pyrene T149 10:1 0.01 µg/l 0.07 <0.01 <0.01 <0.01 0.01 <0.01 <0.01
Indeno(123-cd)Pyrene T149 10:1 0.01 µg/l 0.06 <0.01 <0.01 <0.01 0.02 <0.01 <0.01
Dibenzo(ah)Anthracene T149 10:1 0.01 µg/l 0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Benzo(ghi)Perylene T149 10:1 0.01 µg/l 0.04 <0.01 <0.01 <0.01 0.02 <0.01 <0.01
Coronene T149 10:1 0.01 µg/l <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
PAH (Sum) T85 10:1 0.01 µg/l 1.5 0.15 0.14 <0.01 0.37 0.04 0.23
Value Description
AR As Received
10:1 Leachate to BS EN 12457-2 (10:1)
M40 Analysis conducted on sample assisted dried at no morethan 40C. Results are reported on a dry weight basis.
M105 Analysis conducted on an "as received" aliquot. Results arereported on a dry weight basis where moisture content wasdetermined by assisted drying of sample at 105C
N.D. Not Detected
110 LOD raised due to low internal standard recovery.
107 1,1,2-trichloroethylene is the same as trichloroethylene
13 Results have been blank corrected.
36 LOD Raised due to low Matrix spike recovery
100 LOD determined by sample aliquot used for analysis
S Analysis was subcontracted
M Analysis is MCERTS accredited
U Analysis is UKAS accredited
N Analysis is not UKAS accredited
Samples 1-3 and 12-14 have exceeded our recommended holding time of 14 days from sampling and are classed as deviating. It is possible therefore that the results provided may becompromised.
Asbestos is subcontracted to REC Asbestos.
Value Description
T286 Calc TOC/100
T65 ICP/OES (Preconc.)
T4 Colorimetry
T7 Probe
T85 Calc
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 8 of 12
428221-2
Accreditation Summary
T206 GC/FID (MCERTS)
T209 GC/MS(Head Space)(MCERTS)
T242 2:1 Extraction/ICP/OES (TRL 447 T1)
T149 GC/MS (SIR)
T546 Colorimetry (CF)
T686 Discrete Analyser
T6 ICP/OES
T8 GC/FID
T27 PLM
T162 Grav (1 Dec) (105 C)
T281 ICP/MS (Filtered)
T207 GC/MS (MCERTS)
Determinand Method TestSample LOD Units Symbol SAL References
Mass Fraction of organic carbon T286 M40 N 002,012,015-018,021
Cyanide(Total) T546 AR 1 mg/kg M 002,012,015-018,021
Cyanide(free) T546 AR 1 mg/kg M 002,012,015-018,021
pH T7 AR M 002,012,015-018,021
Phenols(Mono) T546 AR 1 mg/kg M 002,012,015-018,021
(Water Soluble) SO4 expressed as SO4 T242 M40 0.01 g/l N 002,012,015-018,021
Sulphide T546 AR 1 mg/kg N 002,012,015-018,021
Sulphur (total) T6 M40 0.01 % N 002,012,015-018,021
TPH (C10-C35) T8 M105 1 mg/kg M 002,012,015-018,021
Arsenic T6 M40 2 mg/kg M 002,012,015-018,021
Barium T6 M40 1 mg/kg U 002,012,015-018,021
Chromium VI T6 AR 1 mg/kg N 002,012,015-018,021
Beryllium T6 M40 2 mg/kg M 002,012,015-018,021
Boron (water-soluble) T6 AR 1 mg/kg N 002,012,015-018,021
Cadmium T6 M40 1 mg/kg M 002,012,015-018,021
Chromium T6 M40 1 mg/kg M 002,012,015-018,021
Copper T6 M40 1 mg/kg M 002,012,015-018,021
Lead T6 M40 1 mg/kg M 002,012,015-018,021
Mercury T6 M40 1 mg/kg M 002,012,015-018,021
Nickel T6 M40 1 mg/kg M 002,012,015-018,021
Selenium T6 M40 3 mg/kg M 002,012,015-018,021
Vanadium T6 M40 1 mg/kg M 002,012,015-018,021
Zinc T6 M40 1 mg/kg M 002,012,015-018,021
Naphthalene T207 M105 0.1 mg/kg M 002,012,015-018,021
Acenaphthylene T207 M105 0.1 mg/kg U 002,012,015-018,021
Acenaphthene T207 M105 0.1 mg/kg M 002,012,015-018,021
Fluorene T207 M105 0.1 mg/kg M 002,012,015-018,021
Phenanthrene T207 M105 0.1 mg/kg M 002,012,015-018,021
Anthracene T207 M105 0.1 mg/kg U 002,012,015-018,021
Fluoranthene T207 M105 0.1 mg/kg M 002,012,015-018,021
Pyrene T207 M105 0.1 mg/kg M 002,012,015-018,021
Benzo(a)Anthracene T207 M105 0.1 mg/kg M 002,012,015-018,021
Chrysene T207 M105 0.1 mg/kg M 002,012,015-018,021
Benzo(b)fluoranthene T207 M105 0.1 mg/kg M 002,012,015-018,021
Benzo(k)fluoranthene T207 M105 0.1 mg/kg M 002,012,015-018,021
Benzo(a)Pyrene T207 M105 0.1 mg/kg M 002,012,015-018,021
Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg M 002,012,015-018,021
Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg M 002,012,015-018,021
Benzo(ghi)Perylene T207 M105 0.1 mg/kg M 002,012,015-018,021
Coronene T207 M105 0.1 mg/kg N 002,012,015-018,021
PAH (Sum) T85 M105 1.6 mg/kg N 002,012,015-018,021
Moisture @ 105 C T162 AR 0.1 % N 002,004-005,010-012,015-018,021
1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg M 002,012,015-018,021
1,2-Dichlorobenzene T207 M105 0.1 mg/kg M 002,012,015-018,021
1,3-Dichlorobenzene T207 M105 0.1 mg/kg M 002,012,015-018,021
1,4-Dichlorobenzene T207 M105 0.1 mg/kg M 002,012,015-018,021
2,4,5-Trichlorophenol T207 M105 0.1 mg/kg U 002,012,015-018,021
2,4,6-Trichlorophenol T207 M105 0.1 mg/kg U 002,012,015-018,021
2,4-Dichlorophenol T207 M105 0.1 mg/kg U 002,012,015-018,021
2,4-Dimethylphenol T207 M105 0.1 mg/kg U 002,012,015-018,021
2,4-Dinitrophenol T207 M105 0.1 mg/kg U 002,012,015-018,021
2,4-Dinitrotoluene T207 M105 0.1 mg/kg M 002,012,015-018,021
2,6-Dinitrotoluene T207 M105 0.1 mg/kg U 002,012,015-018,021
2-Chloronaphthalene T207 M105 0.1 mg/kg M 002,012,015-018,021
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 9 of 12
428221-2
Determinand Method TestSample LOD Units Symbol SAL References
2-Chlorophenol T207 M105 0.1 mg/kg M 002,012,015-018,021
2-methyl phenol T207 M105 0.1 mg/kg M 002,012,015-018,021
2-Methylnaphthalene T207 M105 0.1 mg/kg M 002,012,015-018,021
2-Nitroaniline T207 M105 0.1 mg/kg M 002,012,015-018,021
2-Nitrophenol T207 M105 0.1 mg/kg U 002,012,015-018,021
3-Nitroaniline T207 M105 0.1 mg/kg U 002,012,015-018,021
3/4-Methylphenol T207 M105 0.1 mg/kg M 002,012,015-018,021
4-Bromophenyl phenylether T207 M105 0.1 mg/kg M 002,012,015-018,021
4-Chloro-3-methylphenol T207 M105 0.1 mg/kg M 002,012,015-018,021
4-Chloroaniline T207 M105 0.1 mg/kg U 002,012,015-018,021
4-Chlorophenyl phenylether T207 M105 0.1 mg/kg M 002,012,015-018,021
4-Nitroaniline T207 M105 0.1 mg/kg U 002,012,015-018,021
4-Nitrophenol T207 M105 0.1 mg/kg U 002,012,015-018,021
Azobenzene T207 M105 0.1 mg/kg M 002,012,015-018,021
Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg M 002,012,015-018,021
Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg M 002,012,015-018,021
Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg M 002,012,015-018,021
Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg M 002,012,015-018,021
Butyl benzylphthalate T207 M105 0.1 mg/kg U 002,012,015-018,021
Carbazole T207 M105 0.1 mg/kg U 002,012,015-018,021
Di-n-butylphthalate T207 M105 0.1 mg/kg M 002,012,015-018,021
Di-n-octylphthalate T207 M105 0.1 mg/kg M 002,012,015-018,021
Dibenzofuran T207 M105 0.1 mg/kg M 002,012,015-018,021
Diethyl phthalate T207 M105 0.1 mg/kg U 002,012,015-018,021
Dimethyl phthalate T207 M105 0.1 mg/kg U 002,012,015-018,021
Hexachlorobenzene T207 M105 0.1 mg/kg M 002,012,015-018,021
Hexachlorobutadiene T207 M105 0.1 mg/kg M 002,012,015-018,021
Hexachlorocyclopentadiene T207 M105 0.1 mg/kg U 002,012,015-018,021
Hexachloroethane T207 M105 0.1 mg/kg U 002,012,015-018,021
Isophorone T207 M105 0.1 mg/kg U 002,012,015-018,021
Nitrobenzene T207 M105 0.1 mg/kg M 002,012,015-018,021
Pentachlorophenol T207 M105 0.1 mg/kg U 002,012,015-018,021
Phenol T207 M105 0.1 mg/kg M 002,012,015-018,021
TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg N 002,012,015-018,021
TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg N 002,012,015-018,021
TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg N 002,012,015-018,021
TPH (C10-C12 aliphatic) T206 M105 1 mg/kg M 002,012,015-018,021
TPH (C12-C16 aliphatic) T206 M105 2 mg/kg M 002,012,015-018,021
TPH (C16-C21 aliphatic) T206 M105 1 mg/kg M 002,012,015-018,021
TPH (C21-C35 aliphatic) T206 M105 4 mg/kg M 002,012,015-018,021
TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg N 002,012,015-018,021
TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg N 002,012,015-018,021
TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg N 002,012,015-018,021
TPH (C10-C12 aromatic) T206 M105 1 mg/kg N 002,012,015-018,021
TPH (C12-C16 aromatic) T206 M105 1 mg/kg M 002,012,015-018,021
TPH (C16-C21 aromatic) T206 M105 1 mg/kg M 002,012,015-018,021
TPH (C21-C35 aromatic) T206 M105 1 mg/kg M 002,012,015-018,021
1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
1,1,1-Trichloroethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021
1,1,2-Trichloroethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
1,1-Dichloroethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
1,1-Dichloroethylene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
1,1-Dichloropropene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
1,2,3-Trichloropropane T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021
1,2,4-Trimethylbenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
1,2-dibromoethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
1,2-Dichlorobenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
1,2-Dichloroethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
1,2-Dichloropropane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
1,3,5-Trimethylbenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
1,3-Dichlorobenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
1,3-Dichloropropane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
1,4-Dichlorobenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
2,2-Dichloropropane T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021
2-Chlorotoluene T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021
4-Chlorotoluene T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021
Benzene T209 M105 10 µg/kg M 002,004-005,010-012,015-018,021
Bromobenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Bromochloromethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 10 of 12
428221-2
Determinand Method TestSample LOD Units Symbol SAL References
Bromodichloromethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Bromoform T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Bromomethane T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021
Carbon tetrachloride T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Chlorobenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Chlorodibromomethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Chloroethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Chloroform T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Chloromethane T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021
Cis-1,2-Dichloroethylene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Cis-1,3-Dichloropropene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Dibromomethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Dichlorodifluoromethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Dichloromethane T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021
EthylBenzene T209 M105 10 µg/kg M 002,004-005,010-012,015-018,021
Isopropyl benzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
M/P Xylene T209 M105 10 µg/kg M 002,004-005,010-012,015-018,021
n-Propylbenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
O Xylene T209 M105 10 µg/kg M 002,004-005,010-012,015-018,021
p-Isopropyltoluene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
S-Butylbenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Styrene T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021
T-Butylbenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Tetrachloroethene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Toluene T209 M105 10 µg/kg M 002,004-005,010-012,015-018,021
Trans-1,2-Dichloroethene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Trans-1,3-Dichloropropene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Trichloroethene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Trichlorofluoromethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Vinyl chloride T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021
Methyl tert-Butyl Ether T209 M105 10 µg/kg M 002,012,015-018,021
Ammoniacal nitrogen T686 10:1 0.05 mg/l U 002,012,015-018,021
Chloride T686 10:1 1 mg/l U 002,012,015-018,021
Cyanide(Total) T4 10:1 0.05 mg/l U 002,012,015-018,021
Cyanide(free) T4 10:1 0.05 mg/l U 002,012,015-018,021
Electrical Conductivity T7 10:1 10 µS/cm N 002,012,015-018,021
Nitrate T686 10:1 0.5 mg/l U 002,012,015-018,021
pH T7 10:1 U 002,012,015-018,021
Phenol T149 10:1 0.5 µg/l U 002,012,015-018,021
Sulphate T686 10:1 0.5 mg/l U 002,012,015-018,021
Sulphide T4 10:1 0.05 mg/l N 002,012,015-018,021
Sulphur (total) T65 10:1 0.01 mg/l N 002,012,015-018,021
TPH (C10-C35) T8 10:1 0.1 mg/l U 002,012,015-018,021
As (Dissolved) T281 10:1 0.2 µg/l U 002,012,015-018,021
Ba (Dissolved) T281 10:1 1 µg/l U 002,012,015-018,021
Be (Dissolved) T281 10:1 0.05 µg/l U 002,012,015-018,021
Chromium VI T686 10:1 3 µg/l U 002,012,015-018,021
Boron T6 10:1 10 µg/l N 002,012,015-018,021
Cd (Dissolved) T281 10:1 0.02 µg/l U 002,012,015-018,021
Cr (Dissolved) T281 10:1 1 µg/l U 002,012,015-018,021
Cu (Dissolved) T281 10:1 0.5 µg/l U 002,012,015-018,021
Pb (Dissolved) T281 10:1 0.3 µg/l U 002,012,015-018,021
Hg (Dissolved) T281 10:1 0.05 µg/l U 002,012,015-018,021
Ni (Dissolved) T281 10:1 1 µg/l U 002,012,015-018,021
Se (Dissolved) T281 10:1 0.5 µg/l U 002,012,015-018,021
V (Dissolved) T281 10:1 2 µg/l U 002,012,015-018,021
Zn (Dissolved) T281 10:1 2 µg/l U 002,012,015-018,021
Naphthalene T149 10:1 0.01 µg/l U 002,012,015-018,021
Acenaphthylene T149 10:1 0.01 µg/l U 002,012,015-018,021
Acenaphthene T149 10:1 0.01 µg/l U 002,012,015-018,021
Fluorene T149 10:1 0.01 µg/l U 002,012,015-018,021
Phenanthrene T149 10:1 0.01 µg/l U 002,012,015-018,021
Anthracene T149 10:1 0.01 µg/l U 002,012,015-018,021
Fluoranthene T149 10:1 0.01 µg/l U 002,012,015-018,021
Pyrene T149 10:1 0.01 µg/l U 002,012,015-018,021
Benzo(a)Anthracene T149 10:1 0.01 µg/l U 002,012,015-018,021
Chrysene T149 10:1 0.01 µg/l U 002,012,015-018,021
Benzo(b)fluoranthene T149 10:1 0.01 µg/l U 002,012,015-018,021
Benzo(k)fluoranthene T149 10:1 0.01 µg/l U 002,012,015-018,021
Benzo(a)Pyrene T149 10:1 0.01 µg/l U 002,012,015-018,021
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 11 of 12
428221-2
Determinand Method TestSample LOD Units Symbol SAL References
Indeno(123-cd)Pyrene T149 10:1 0.01 µg/l U 002,012,015-018,021
Dibenzo(ah)Anthracene T149 10:1 0.01 µg/l U 002,012,015-018,021
Benzo(ghi)Perylene T149 10:1 0.01 µg/l U 002,012,015-018,021
Coronene T149 10:1 0.01 µg/l N 002,012,015-018,021
PAH (Sum) T85 10:1 0.01 µg/l N 002,012,015-018,021
Asbestos ID T27 AR SU 002,012,015-018,021
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 12 of 12
428221-2
Scientific Analysis Laboratories Ltd
Certificate of Analysis
Hadfield HouseHadfield Street
CornbrookManchester
M16 9FETel : 0161 874 2400Fax : 0161 874 2468
Report Number: 435930-1
Date of Report: 21-Nov-2014
Customer: Soil Engineering Geoservices LimitedParkside LaneDewsbury RoadLeedsWest Yorkshire.LS11 5SX
Customer Contact: Mr Peter Stoddart
Customer Job Reference: TA7437Customer Site Reference: Mersey Gateway Bridge, Additional GI
(Phase 2)Date Job Received at SAL: 03-Nov-2014
Date Analysis Started: 13-Nov-2014Date Analysis Completed: 21-Nov-2014
The results reported relate to samples received in the laboratoryOpinions and interpretations expressed herein are outside the scope of UKAS accreditationThis report should not be reproduced except in full without the written approval of the laboratoryTests covered by this certificate were conducted in accordance with SAL SOPsAll results have been reviewed in accordance with QP22
This document has been printed from a digitally signed master copy
Scientific Analysis Laboratories is a
limited company registered in England and
Wales (No 2514788) whose address is at
Hadfield House, Hadfield Street, Manchester M16 9FE
1549
Report checkedand authorised by :Mr Ross WalkerCustomer Services Manager(Land)
Issued by :Mr Ross WalkerCustomer Services Manager(Land)
Page 1 of 9
435930-1
SAL Reference: 435930
Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
MCERTS Preparation
SAL Reference 435930 005 435930 006 435930 009 435930 015
Customer Sample Reference BHXX3 ES 005 BHXX3 ES 006 BH323 ES 003 BH323 ES 009
Date Sampled 05-NOV-2014 05-NOV-2014 29-OCT-2014 31-OCT-2014
Depth 10.50 11.50 1.95 14.60
Type Sandy Soil Clay Sandy Soil Sandy Soil
Determinand Method TestSample LOD Units
Moisture @ 105 C T162 AR 0.1 % 19 14 37 24
SAL Reference: 435930
Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
CLEA Metals
SAL Reference 435930 009
Customer Sample Reference BH323 ES 003
Date Sampled 29-OCT-2014
Depth 1.95
Type Sandy Soil
Determinand Method TestSample LOD Units
Arsenic T6 M40 2 mg/kg 110
Barium T6 M40 1 mg/kg 44
Beryllium T6 M40 2 mg/kg <2
Boron (water-soluble) T6 AR 1 mg/kg <1
Cadmium T6 M40 1 mg/kg <1
Chromium T6 M40 1 mg/kg 9
Copper T6 M40 1 mg/kg 65
Lead T6 M40 1 mg/kg 120
Mercury T6 M40 1 mg/kg <1
Nickel T6 M40 1 mg/kg 9
Selenium T6 M40 3 mg/kg <3
Vanadium T6 M40 1 mg/kg 9
Zinc T6 M40 1 mg/kg 300
SAL Reference: 435930
Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Suite E
SAL Reference 435930 009
Customer Sample Reference BH323 ES 003
Date Sampled 29-OCT-2014
Depth 1.95
Type Sandy Soil
Determinand Method TestSample LOD Units
Asbestos ID T27 AR N.D.
Chromium VI T6 AR 1 mg/kg <1
Cyanide(Total) T546 AR 1 mg/kg <1
Cyanide(free) T546 AR 1 mg/kg <1
pH T7 AR 8.5
Phenols(Mono) T546 AR 1 mg/kg <1
(Water Soluble) SO4 expressed as SO4 T242 AR 0.01 g/l 1.3
Sulphide T546 AR 1 mg/kg <1
Sulphur (total) T6 M40 0.01 % 1.0
TPH (C10-C35) T8 M105 1 mg/kg <1
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 2 of 9
435930-1
SAL Reference: 435930
Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
PAH EPA 16, Coronene
SAL Reference 435930 009
Customer Sample Reference BH323 ES 003
Date Sampled 29-OCT-2014
Depth 1.95
Type Sandy Soil
Determinand Method TestSample LOD Units
Naphthalene T207 M105 0.1 mg/kg <0.1
Acenaphthylene T207 M105 0.1 mg/kg <0.1
Acenaphthene T207 M105 0.1 mg/kg <0.1
Fluorene T207 M105 0.1 mg/kg <0.1
Phenanthrene T207 M105 0.1 mg/kg 0.3
Anthracene T207 M105 0.1 mg/kg <0.1
Fluoranthene T207 M105 0.1 mg/kg 0.6
Pyrene T207 M105 0.1 mg/kg 0.6
Benzo(a)Anthracene T207 M105 0.1 mg/kg 0.4
Chrysene T207 M105 0.1 mg/kg 0.3
Benzo(b)fluoranthene T207 M105 0.1 mg/kg 0.4
Benzo(k)fluoranthene T207 M105 0.1 mg/kg 0.2
Benzo(a)Pyrene T207 M105 0.1 mg/kg 0.2
Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg <0.1
Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg <0.1
Benzo(ghi)Perylene T207 M105 0.1 mg/kg <0.1
Coronene T207 M105 0.1 mg/kg <0.1
PAH (Sum) T85 M105 1.6 mg/kg 3.0
SAL Reference: 435930
Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Suite K
SAL Reference 435930 009
Customer Sample Reference BH323 ES 003
Date Sampled 29-OCT-2014
Depth 1.95
Type Sandy Soil
Determinand Method TestSample LOD Units
Mass Fraction of organic carbon T286 M40 0.0077
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 3 of 9
435930-1
SAL Reference: 435930
Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
TPH (CWG)
SAL Reference 435930 009
Customer Sample Reference BH323 ES 003
Date Sampled 29-OCT-2014
Depth 1.95
Type Sandy Soil
Determinand Method TestSample LOD Units
TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg <0.100
TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg <0.10
TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg <0.10
TPH (C10-C12 aliphatic) T206 M105 1 mg/kg <1
TPH (C12-C16 aliphatic) T206 M105 2 mg/kg <2
TPH (C16-C21 aliphatic) T206 M105 1 mg/kg 1
TPH (C21-C35 aliphatic) T206 M105 4 mg/kg 10
TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg <0.10
TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg <0.10
TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg <0.10
TPH (C10-C12 aromatic) T206 M105 1 mg/kg <1
TPH (C12-C16 aromatic) T206 M105 1 mg/kg <1
TPH (C16-C21 aromatic) T206 M105 1 mg/kg <1
TPH (C21-C35 aromatic) T206 M105 1 mg/kg <1
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 4 of 9
435930-1
SAL Reference: 435930
Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Semi-Volatile Organic Compounds (Reduced)
SAL Reference 435930 009
Customer Sample Reference BH323 ES 003
Date Sampled 29-OCT-2014
Depth 1.95
Type Sandy Soil
Determinand Method TestSample LOD Units
1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg <0.1
1,2-Dichlorobenzene T207 M105 0.1 mg/kg <0.1
1,3-Dichlorobenzene T207 M105 0.1 mg/kg <0.1
1,4-Dichlorobenzene T207 M105 0.1 mg/kg <0.1
2,4,5-Trichlorophenol T207 M105 0.1 mg/kg <0.1
2,4,6-Trichlorophenol T207 M105 0.1 mg/kg <0.1
2,4-Dichlorophenol T207 M105 0.1 mg/kg <0.1
2,4-Dimethylphenol T207 M105 0.1 mg/kg <0.1
2,4-Dinitrophenol T207 M105 0.1 mg/kg (36) <0.5
2,4-Dinitrotoluene T207 M105 0.1 mg/kg <0.1
2,6-Dinitrotoluene T207 M105 0.1 mg/kg <0.1
2-Chloronaphthalene T207 M105 0.1 mg/kg <0.1
2-Chlorophenol T207 M105 0.1 mg/kg <0.1
2-methyl phenol T207 M105 0.1 mg/kg <0.1
2-Methylnaphthalene T207 M105 0.1 mg/kg <0.1
2-Nitroaniline T207 M105 0.1 mg/kg <0.1
2-Nitrophenol T207 M105 0.1 mg/kg <0.1
3-Nitroaniline T207 M105 0.1 mg/kg <0.1
3/4-Methylphenol T207 M105 0.1 mg/kg <0.1
4-Bromophenyl phenylether T207 M105 0.1 mg/kg <0.1
4-Chloro-3-methylphenol T207 M105 0.1 mg/kg <0.1
4-Chloroaniline T207 M105 0.1 mg/kg (36) <0.5
4-Chlorophenyl phenylether T207 M105 0.1 mg/kg <0.1
4-Nitroaniline T207 M105 0.1 mg/kg (36) <0.5
4-Nitrophenol T207 M105 0.1 mg/kg <0.1
Azobenzene T207 M105 0.1 mg/kg <0.1
Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg <0.1
Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg <0.1
Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg <0.1
Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg <0.1
Butyl benzylphthalate T207 M105 0.1 mg/kg <0.1
Carbazole T207 M105 0.1 mg/kg <0.1
Di-n-butylphthalate T207 M105 0.1 mg/kg <0.1
Di-n-octylphthalate T207 M105 0.1 mg/kg <0.1
Dibenzofuran T207 M105 0.1 mg/kg <0.1
Diethyl phthalate T207 M105 0.1 mg/kg <0.1
Dimethyl phthalate T207 M105 0.1 mg/kg <0.1
Hexachlorobenzene T207 M105 0.1 mg/kg <0.1
Hexachlorobutadiene T207 M105 0.1 mg/kg <0.1
Hexachlorocyclopentadiene T207 M105 0.1 mg/kg (36) <0.5
Hexachloroethane T207 M105 0.1 mg/kg <0.1
Isophorone T207 M105 0.1 mg/kg <0.1
Nitrobenzene T207 M105 0.1 mg/kg <0.1
Pentachlorophenol T207 M105 0.1 mg/kg (36) <0.5
Phenol T207 M105 0.1 mg/kg <0.1
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 5 of 9
435930-1
SAL Reference: 435930
Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Volatile Organic Compounds (USEPA 624) (MCERTS)
SAL Reference 435930 005 435930 006 435930 009 435930 015
Customer Sample Reference BHXX3 ES 005 BHXX3 ES 006 BH323 ES 003 BH323 ES 009
Date Sampled 05-NOV-2014 05-NOV-2014 29-OCT-2014 31-OCT-2014
Depth 10.50 11.50 1.95 14.60
Type Sandy Soil Clay Sandy Soil Sandy Soil
Determinand Method TestSample LOD Units
1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg <50 <50 <50 <50
1,1,1-Trichloroethane T209 M105 50 µg/kg <50 <50 <50 <50
1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg <50 <50 <50 <50
1,1,2-Trichloroethane T209 M105 50 µg/kg <50 <50 210 1500
1,1-Dichloroethane T209 M105 50 µg/kg <50 <50 <50 310
1,1-Dichloroethylene T209 M105 50 µg/kg <50 <50 95 300
1,1-Dichloropropene T209 M105 50 µg/kg <50 <50 <50 <50
1,2,3-Trichloropropane T209 M105 50 µg/kg <50 <50 <50 <50
1,2,4-Trimethylbenzene T209 M105 50 µg/kg <50 <50 <50 <50
1,2-dibromoethane T209 M105 50 µg/kg <50 <50 <50 <50
1,2-Dichlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50
1,2-Dichloroethane T209 M105 50 µg/kg <50 <50 <50 <50
1,2-Dichloropropane T209 M105 50 µg/kg <50 <50 <50 <50
1,3,5-Trimethylbenzene T209 M105 50 µg/kg <50 <50 <50 <50
1,3-Dichlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50
1,3-Dichloropropane T209 M105 50 µg/kg <50 <50 <50 <50
1,4-Dichlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50
2,2-Dichloropropane T209 M105 50 µg/kg <50 <50 <50 <50
2-Chlorotoluene T209 M105 50 µg/kg <50 <50 <50 <50
4-Chlorotoluene T209 M105 50 µg/kg <50 <50 <50 <50
Benzene T209 M105 10 µg/kg (13) <10 (13) <10 (13) <10 (13) <10
Bromobenzene T209 M105 50 µg/kg <50 <50 <50 <50
Bromochloromethane T209 M105 50 µg/kg <50 <50 <50 <50
Bromodichloromethane T209 M105 50 µg/kg <50 <50 <50 <50
Bromoform T209 M105 50 µg/kg <50 <50 <50 <50
Bromomethane T209 M105 50 µg/kg <50 <50 <50 <50
Carbon tetrachloride T209 M105 50 µg/kg 58 <50 <50 <50
Chlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50
Chlorodibromomethane T209 M105 50 µg/kg <50 <50 <50 <50
Chloroethane T209 M105 50 µg/kg <50 <50 <50 <50
Chloroform T209 M105 50 µg/kg 350 59 <50 <50
Chloromethane T209 M105 50 µg/kg <50 <50 <50 <50
Cis-1,2-Dichloroethylene T209 M105 50 µg/kg <50 <50 <50 <50
Cis-1,3-Dichloropropene T209 M105 50 µg/kg <50 <50 <50 <50
Dibromomethane T209 M105 50 µg/kg <50 <50 <50 <50
Dichlorodifluoromethane T209 M105 50 µg/kg <50 <50 <50 <50
Dichloromethane T209 M105 50 µg/kg <50 <50 <50 <50
EthylBenzene T209 M105 10 µg/kg <10 <10 <10 <10
Isopropyl benzene T209 M105 50 µg/kg <50 <50 <50 <50
M/P Xylene T209 M105 10 µg/kg <10 <10 <10 <10
n-Propylbenzene T209 M105 50 µg/kg <50 <50 <50 <50
O Xylene T209 M105 10 µg/kg <10 <10 <10 <10
p-Isopropyltoluene T209 M105 50 µg/kg <50 <50 <50 <50
S-Butylbenzene T209 M105 50 µg/kg <50 <50 <50 <50
Styrene T209 M105 50 µg/kg <50 <50 <50 <50
T-Butylbenzene T209 M105 50 µg/kg <50 <50 <50 <50
Tetrachloroethene T209 M105 50 µg/kg <50 <50 <50 <50
Toluene T209 M105 10 µg/kg <10 <10 <10 <10
Trans-1,2-Dichloroethene T209 M105 50 µg/kg <50 <50 <50 <50
Trans-1,3-Dichloropropene T209 M105 50 µg/kg <50 <50 <50 <50
Trichloroethene T209 M105 50 µg/kg <50 <50 150 170
Trichlorofluoromethane T209 M105 50 µg/kg <50 <50 <50 <50
Vinyl chloride T209 M105 50 µg/kg <50 <50 <50 <50
Methyl tert-Butyl Ether T209 M105 10 µg/kg - - <10 -
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 6 of 9
435930-1
Index to symbols used in 435930-1
Notes
Method Index
Accreditation Summary
Value Description
AR As Received
M105 Analysis conducted on an "as received" aliquot.Results are reported on a dry weight basis wheremoisture content was determined by assisteddrying of sample at 105C
M40 Analysis conducted on sample assisted dried at nomore than 40C. Results are reported on a dryweight basis.
N.D. Not Detected
13 Results have been blank corrected.
36 LOD Raised due to low Matrix spike recovery
S Analysis was subcontracted
M Analysis is MCERTS accredited
U Analysis is UKAS accredited
N Analysis is not UKAS accredited
Asbestos was subcontracted to REC Asbestos
Value Description
T242 2:1 Extraction/ICP/OES (TRL 447 T1)
T8 GC/FID
T206 GC/FID (MCERTS)
T209 GC/MS(Head Space)(MCERTS)
T7 Probe
T162 Grav (1 Dec) (105 C)
T27 PLM
T6 ICP/OES
T286 Calc TOC/100
T85 Calc
T207 GC/MS (MCERTS)
T546 Colorimetry (CF)
Determinand Method TestSample LOD Units Symbol SAL References
Moisture @ 105 C T162 AR 0.1 % N 005-006,009,015
Asbestos ID T27 AR SU 009
Chromium VI T6 AR 1 mg/kg N 009
Cyanide(Total) T546 AR 1 mg/kg M 009
Cyanide(free) T546 AR 1 mg/kg M 009
pH T7 AR M 009
Phenols(Mono) T546 AR 1 mg/kg M 009
(Water Soluble) SO4 expressed as SO4 T242 AR 0.01 g/l N 009
Sulphide T546 AR 1 mg/kg N 009
Sulphur (total) T6 M40 0.01 % N 009
TPH (C10-C35) T8 M105 1 mg/kg M 009
Arsenic T6 M40 2 mg/kg M 009
Barium T6 M40 1 mg/kg U 009
Beryllium T6 M40 2 mg/kg M 009
Boron (water-soluble) T6 AR 1 mg/kg N 009
Cadmium T6 M40 1 mg/kg M 009
Chromium T6 M40 1 mg/kg M 009
Copper T6 M40 1 mg/kg M 009
Lead T6 M40 1 mg/kg M 009
Mercury T6 M40 1 mg/kg M 009
Nickel T6 M40 1 mg/kg M 009
Selenium T6 M40 3 mg/kg M 009
Vanadium T6 M40 1 mg/kg M 009
Zinc T6 M40 1 mg/kg M 009
Naphthalene T207 M105 0.1 mg/kg M 009
Acenaphthylene T207 M105 0.1 mg/kg U 009
Acenaphthene T207 M105 0.1 mg/kg M 009
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 7 of 9
435930-1
Determinand Method TestSample LOD Units Symbol SAL References
Fluorene T207 M105 0.1 mg/kg M 009
Phenanthrene T207 M105 0.1 mg/kg M 009
Anthracene T207 M105 0.1 mg/kg U 009
Fluoranthene T207 M105 0.1 mg/kg M 009
Pyrene T207 M105 0.1 mg/kg M 009
Benzo(a)Anthracene T207 M105 0.1 mg/kg M 009
Chrysene T207 M105 0.1 mg/kg M 009
Benzo(b)fluoranthene T207 M105 0.1 mg/kg M 009
Benzo(k)fluoranthene T207 M105 0.1 mg/kg M 009
Benzo(a)Pyrene T207 M105 0.1 mg/kg M 009
Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg M 009
Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg M 009
Benzo(ghi)Perylene T207 M105 0.1 mg/kg M 009
Coronene T207 M105 0.1 mg/kg N 009
PAH (Sum) T85 M105 1.6 mg/kg N 009
Mass Fraction of organic carbon T286 M40 N 009
1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg M 009
1,2-Dichlorobenzene T207 M105 0.1 mg/kg M 009
1,3-Dichlorobenzene T207 M105 0.1 mg/kg M 009
1,4-Dichlorobenzene T207 M105 0.1 mg/kg M 009
2,4,5-Trichlorophenol T207 M105 0.1 mg/kg U 009
2,4,6-Trichlorophenol T207 M105 0.1 mg/kg U 009
2,4-Dichlorophenol T207 M105 0.1 mg/kg U 009
2,4-Dimethylphenol T207 M105 0.1 mg/kg U 009
2,4-Dinitrophenol T207 M105 0.1 mg/kg U 009
2,4-Dinitrotoluene T207 M105 0.1 mg/kg M 009
2,6-Dinitrotoluene T207 M105 0.1 mg/kg U 009
2-Chloronaphthalene T207 M105 0.1 mg/kg M 009
2-Chlorophenol T207 M105 0.1 mg/kg M 009
2-methyl phenol T207 M105 0.1 mg/kg M 009
2-Methylnaphthalene T207 M105 0.1 mg/kg M 009
2-Nitroaniline T207 M105 0.1 mg/kg M 009
2-Nitrophenol T207 M105 0.1 mg/kg U 009
3-Nitroaniline T207 M105 0.1 mg/kg U 009
3/4-Methylphenol T207 M105 0.1 mg/kg M 009
4-Bromophenyl phenylether T207 M105 0.1 mg/kg M 009
4-Chloro-3-methylphenol T207 M105 0.1 mg/kg M 009
4-Chloroaniline T207 M105 0.1 mg/kg U 009
4-Chlorophenyl phenylether T207 M105 0.1 mg/kg M 009
4-Nitroaniline T207 M105 0.1 mg/kg U 009
4-Nitrophenol T207 M105 0.1 mg/kg U 009
Azobenzene T207 M105 0.1 mg/kg M 009
Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg M 009
Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg M 009
Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg M 009
Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg M 009
Butyl benzylphthalate T207 M105 0.1 mg/kg U 009
Carbazole T207 M105 0.1 mg/kg U 009
Di-n-butylphthalate T207 M105 0.1 mg/kg M 009
Di-n-octylphthalate T207 M105 0.1 mg/kg M 009
Dibenzofuran T207 M105 0.1 mg/kg M 009
Diethyl phthalate T207 M105 0.1 mg/kg U 009
Dimethyl phthalate T207 M105 0.1 mg/kg U 009
Hexachlorobenzene T207 M105 0.1 mg/kg M 009
Hexachlorobutadiene T207 M105 0.1 mg/kg M 009
Hexachlorocyclopentadiene T207 M105 0.1 mg/kg U 009
Hexachloroethane T207 M105 0.1 mg/kg U 009
Isophorone T207 M105 0.1 mg/kg U 009
Nitrobenzene T207 M105 0.1 mg/kg M 009
Pentachlorophenol T207 M105 0.1 mg/kg U 009
Phenol T207 M105 0.1 mg/kg M 009
TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg N 009
TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg N 009
TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg N 009
TPH (C10-C12 aliphatic) T206 M105 1 mg/kg M 009
TPH (C12-C16 aliphatic) T206 M105 2 mg/kg M 009
TPH (C16-C21 aliphatic) T206 M105 1 mg/kg M 009
TPH (C21-C35 aliphatic) T206 M105 4 mg/kg M 009
TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg N 009
TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg N 009
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 8 of 9
435930-1
Determinand Method TestSample LOD Units Symbol SAL References
TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg N 009
TPH (C10-C12 aromatic) T206 M105 1 mg/kg N 009
TPH (C12-C16 aromatic) T206 M105 1 mg/kg M 009
TPH (C16-C21 aromatic) T206 M105 1 mg/kg M 009
TPH (C21-C35 aromatic) T206 M105 1 mg/kg M 009
1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg M 005-006,009,015
1,1,1-Trichloroethane T209 M105 50 µg/kg M 005-006,009,015
1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg U 005-006,009,015
1,1,2-Trichloroethane T209 M105 50 µg/kg M 005-006,009,015
1,1-Dichloroethane T209 M105 50 µg/kg M 005-006,009,015
1,1-Dichloroethylene T209 M105 50 µg/kg M 005-006,009,015
1,1-Dichloropropene T209 M105 50 µg/kg M 005-006,009,015
1,2,3-Trichloropropane T209 M105 50 µg/kg U 005-006,009,015
1,2,4-Trimethylbenzene T209 M105 50 µg/kg M 005-006,009,015
1,2-dibromoethane T209 M105 50 µg/kg M 005-006,009,015
1,2-Dichlorobenzene T209 M105 50 µg/kg M 005-006,009,015
1,2-Dichloroethane T209 M105 50 µg/kg M 005-006,009,015
1,2-Dichloropropane T209 M105 50 µg/kg M 005-006,009,015
1,3,5-Trimethylbenzene T209 M105 50 µg/kg M 005-006,009,015
1,3-Dichlorobenzene T209 M105 50 µg/kg M 005-006,009,015
1,3-Dichloropropane T209 M105 50 µg/kg M 005-006,009,015
1,4-Dichlorobenzene T209 M105 50 µg/kg M 005-006,009,015
2,2-Dichloropropane T209 M105 50 µg/kg U 005-006,009,015
2-Chlorotoluene T209 M105 50 µg/kg U 005-006,009,015
4-Chlorotoluene T209 M105 50 µg/kg U 005-006,009,015
Benzene T209 M105 10 µg/kg M 005-006,009,015
Bromobenzene T209 M105 50 µg/kg M 005-006,009,015
Bromochloromethane T209 M105 50 µg/kg M 005-006,009,015
Bromodichloromethane T209 M105 50 µg/kg M 005-006,009,015
Bromoform T209 M105 50 µg/kg M 005-006,009,015
Bromomethane T209 M105 50 µg/kg U 005-006,009,015
Carbon tetrachloride T209 M105 50 µg/kg M 005-006,009,015
Chlorobenzene T209 M105 50 µg/kg M 005-006,009,015
Chlorodibromomethane T209 M105 50 µg/kg M 005-006,009,015
Chloroethane T209 M105 50 µg/kg M 005-006,009,015
Chloroform T209 M105 50 µg/kg M 005-006,009,015
Chloromethane T209 M105 50 µg/kg U 005-006,009,015
Cis-1,2-Dichloroethylene T209 M105 50 µg/kg M 005-006,009,015
Cis-1,3-Dichloropropene T209 M105 50 µg/kg M 005-006,009,015
Dibromomethane T209 M105 50 µg/kg M 005-006,009,015
Dichlorodifluoromethane T209 M105 50 µg/kg M 005-006,009,015
Dichloromethane T209 M105 50 µg/kg U 005-006,009,015
EthylBenzene T209 M105 10 µg/kg M 005-006,009,015
Isopropyl benzene T209 M105 50 µg/kg M 005-006,009,015
M/P Xylene T209 M105 10 µg/kg M 005-006,009,015
n-Propylbenzene T209 M105 50 µg/kg M 005-006,009,015
O Xylene T209 M105 10 µg/kg M 005-006,009,015
p-Isopropyltoluene T209 M105 50 µg/kg M 005-006,009,015
S-Butylbenzene T209 M105 50 µg/kg M 005-006,009,015
Styrene T209 M105 50 µg/kg U 005-006,009,015
T-Butylbenzene T209 M105 50 µg/kg M 005-006,009,015
Tetrachloroethene T209 M105 50 µg/kg M 005-006,009,015
Toluene T209 M105 10 µg/kg M 005-006,009,015
Trans-1,2-Dichloroethene T209 M105 50 µg/kg M 005-006,009,015
Trans-1,3-Dichloropropene T209 M105 50 µg/kg M 005-006,009,015
Trichloroethene T209 M105 50 µg/kg M 005-006,009,015
Trichlorofluoromethane T209 M105 50 µg/kg M 005-006,009,015
Vinyl chloride T209 M105 50 µg/kg M 005-006,009,015
Methyl tert-Butyl Ether T209 M105 10 µg/kg M 009
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 9 of 9
435930-1
Scientific Analysis Laboratories Ltd
Certificate of Analysis
Hadfield HouseHadfield Street
CornbrookManchester
M16 9FETel : 0161 874 2400Fax : 0161 874 2468
Report Number: 473147-1
Date of Report: 06-May-2015
Customer: Soil Engineering Geoservices LimitedParkside LaneDewsbury RoadLeedsWest Yorkshire.LS11 5SX
Customer Contact: Mr Ian Swain
Customer Job Reference: TA7437Customer Site Reference: Mersey Gateway Bridge. Additional GI
(Phase 2)Date Job Received at SAL: 22-Apr-2015
Date Analysis Started: 29-Apr-2015Date Analysis Completed: 06-May-2015
The results reported relate to samples received in the laboratoryOpinions and interpretations expressed herein are outside the scope of UKAS accreditationThis report should not be reproduced except in full without the written approval of the laboratoryTests covered by this certificate were conducted in accordance with SAL SOPsAll results have been reviewed in accordance with QP22
This document has been printed from a digitally signed master copy
Scientific Analysis Laboratories is a
limited company registered in England and
Wales (No 2514788) whose address is at
Hadfield House, Hadfield Street, Manchester M16 9FE
1549
Report checkedand authorised by :Natasha WildProject Manager
Issued by :Natasha WildProject Manager
Page 1 of 9
473147-1
SAL Reference: 473147
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Moisture
SAL Reference 473147 013
Customer Sample Reference BHXX4 ES 013
Top Depth 10.30
Date Sampled 22-APR-2015
Bottom Depth 10.30
Type Clay
Determinand Method TestSample LOD Units
Moisture @ 105 C T162 AR 0.1 % 15
SAL Reference: 473147
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
CLEA Metals
SAL Reference 473147 013
Customer Sample Reference BHXX4 ES 013
Top Depth 10.30
Date Sampled 22-APR-2015
Bottom Depth 10.30
Type Clay
Determinand Method TestSample LOD Units
Arsenic T6 M40 2 mg/kg 8
Barium T6 M40 1 mg/kg 110
Beryllium T6 M40 2 mg/kg <2
Boron (water-soluble) T6 AR 1 mg/kg <1
Cadmium T6 M40 1 mg/kg <1
Chromium T6 M40 1 mg/kg 26
Copper T6 M40 1 mg/kg 27
Lead T6 M40 1 mg/kg 16
Mercury T6 M40 1 mg/kg <1
Nickel T6 M40 1 mg/kg 31
Selenium T6 M40 3 mg/kg <3
Vanadium T6 M40 1 mg/kg 25
Zinc T6 M40 1 mg/kg 110
SAL Reference: 473147
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Suite E
SAL Reference 473147 013
Customer Sample Reference BHXX4 ES 013
Top Depth 10.30
Date Sampled 22-APR-2015
Bottom Depth 10.30
Type Clay
Determinand Method TestSample LOD Units
Asbestos ID T27 AR N.D.
Chromium VI T6 AR 1 mg/kg <1
Cyanide(Total) T546 AR 1 mg/kg <1
Cyanide(free) T546 AR 1 mg/kg <1
pH T7 AR 8.3
Phenols(Mono) T546 AR 1 mg/kg <1
(Water Soluble) SO4 expressed as SO4 T242 AR 0.01 g/l 0.31
Sulphide T546 AR 1 mg/kg <1
Sulphur (total) T6 M40 0.01 % 0.06
TPH (C10-C35) T8 M105 1 mg/kg <1
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 2 of 9
473147-1
SAL Reference: 473147
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Carbon disulphide
SAL Reference 473147 013
Customer Sample Reference BHXX4 ES 013
Top Depth 10.30
Date Sampled 22-APR-2015
Bottom Depth 10.30
Type Clay
Determinand Method TestSample LOD Units
Carbon disulphide T54 M105 0.1 mg/kg 0.5
SAL Reference: 473147
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Suite K
SAL Reference 473147 013
Customer Sample Reference BHXX4 ES 013
Top Depth 10.30
Date Sampled 22-APR-2015
Bottom Depth 10.30
Type Clay
Determinand Method TestSample LOD Units
Mass Fraction of organic carbon T286 M40 0.0064
Methyl tert-Butyl Ether T209 M105 10 µg/kg <10
SAL Reference: 473147
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
TPH (CWG)
SAL Reference 473147 013
Customer Sample Reference BHXX4 ES 013
Top Depth 10.30
Date Sampled 22-APR-2015
Bottom Depth 10.30
Type Clay
Determinand Method TestSample LOD Units
TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg <0.100
TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg <0.10
TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg <0.10
TPH (C10-C12 aliphatic) T206 M105 1 mg/kg <1
TPH (C12-C16 aliphatic) T206 M105 2 mg/kg <2
TPH (C16-C21 aliphatic) T206 M105 1 mg/kg <1
TPH (C21-C35 aliphatic) T206 M105 4 mg/kg <4
TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg <0.10
TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg <0.10
TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg <0.10
TPH (C10-C12 aromatic) T206 M105 1 mg/kg <1
TPH (C12-C16 aromatic) T206 M105 1 mg/kg <1
TPH (C16-C21 aromatic) T206 M105 1 mg/kg <1
TPH (C21-C35 aromatic) T206 M105 1 mg/kg <1
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 3 of 9
473147-1
SAL Reference: 473147
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
PAH EPA 16, Coronene
SAL Reference 473147 013
Customer Sample Reference BHXX4 ES 013
Top Depth 10.30
Date Sampled 22-APR-2015
Bottom Depth 10.30
Type Clay
Determinand Method TestSample LOD Units
Naphthalene T207 M105 0.1 mg/kg <0.1
Acenaphthylene T207 M105 0.1 mg/kg <0.1
Acenaphthene T207 M105 0.1 mg/kg <0.1
Fluorene T207 M105 0.1 mg/kg <0.1
Phenanthrene T207 M105 0.1 mg/kg <0.1
Anthracene T207 M105 0.1 mg/kg <0.1
Fluoranthene T207 M105 0.1 mg/kg <0.1
Pyrene T207 M105 0.1 mg/kg <0.1
Benzo(a)Anthracene T207 M105 0.1 mg/kg <0.1
Chrysene T207 M105 0.1 mg/kg <0.1
Benzo(b)fluoranthene T207 M105 0.1 mg/kg <0.1
Benzo(k)fluoranthene T207 M105 0.1 mg/kg <0.1
Benzo(a)Pyrene T207 M105 0.1 mg/kg <0.1
Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg <0.1
Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg <0.1
Benzo(ghi)Perylene T207 M105 0.1 mg/kg <0.1
Coronene T207 M105 0.1 mg/kg <0.1
PAH (Sum) T85 M105 1.6 mg/kg <1.6
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 4 of 9
473147-1
SAL Reference: 473147
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Semi-Volatile Organic Compounds (Reduced)
SAL Reference 473147 013
Customer Sample Reference BHXX4 ES 013
Top Depth 10.30
Date Sampled 22-APR-2015
Bottom Depth 10.30
Type Clay
Determinand Method TestSample LOD Units
1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg <0.1
1,2-Dichlorobenzene T207 M105 0.1 mg/kg <0.1
1,3-Dichlorobenzene T207 M105 0.1 mg/kg <0.1
1,4-Dichlorobenzene T207 M105 0.1 mg/kg <0.1
2,4,5-Trichlorophenol T207 M105 0.1 mg/kg <0.1
2,4,6-Trichlorophenol T207 M105 0.1 mg/kg <0.1
2,4-Dichlorophenol T207 M105 0.1 mg/kg <0.1
2,4-Dimethylphenol T207 M105 0.1 mg/kg <0.1
2,4-Dinitrophenol T207 M105 0.1 mg/kg <0.1
2,4-Dinitrotoluene T207 M105 0.1 mg/kg <0.1
2,6-Dinitrotoluene T207 M105 0.1 mg/kg <0.1
2-Chloronaphthalene T207 M105 0.1 mg/kg <0.1
2-Chlorophenol T207 M105 0.1 mg/kg <0.1
2-methyl phenol T207 M105 0.1 mg/kg <0.1
2-Methylnaphthalene T207 M105 0.1 mg/kg <0.1
2-Nitroaniline T207 M105 0.1 mg/kg <0.1
2-Nitrophenol T207 M105 0.1 mg/kg <0.1
3-Nitroaniline T207 M105 0.1 mg/kg <0.1
3/4-Methylphenol T207 M105 0.1 mg/kg <0.1
4-Bromophenyl phenylether T207 M105 0.1 mg/kg <0.1
4-Chloro-3-methylphenol T207 M105 0.1 mg/kg <0.1
4-Chloroaniline T207 M105 0.1 mg/kg (36) <0.5
4-Chlorophenyl phenylether T207 M105 0.1 mg/kg <0.1
4-Nitroaniline T207 M105 0.1 mg/kg (36) <0.5
4-Nitrophenol T207 M105 0.1 mg/kg (36) <0.5
Azobenzene T207 M105 0.1 mg/kg <0.1
Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg <0.1
Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg <0.1
Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg <0.1
Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg <0.1
Butyl benzylphthalate T207 M105 0.1 mg/kg <0.1
Carbazole T207 M105 0.1 mg/kg <0.1
Di-n-butylphthalate T207 M105 0.1 mg/kg <0.1
Di-n-octylphthalate T207 M105 0.1 mg/kg <0.1
Dibenzofuran T207 M105 0.1 mg/kg (36) <0.5
Diethyl phthalate T207 M105 0.1 mg/kg <0.1
Dimethyl phthalate T207 M105 0.1 mg/kg <0.1
Hexachlorobenzene T207 M105 0.1 mg/kg <0.1
Hexachlorobutadiene T207 M105 0.1 mg/kg <0.1
Hexachlorocyclopentadiene T207 M105 0.1 mg/kg (36) <0.5
Hexachloroethane T207 M105 0.1 mg/kg <0.1
Isophorone T207 M105 0.1 mg/kg <0.1
Nitrobenzene T207 M105 0.1 mg/kg <0.1
Pentachlorophenol T207 M105 0.1 mg/kg (36) <0.5
Phenol T207 M105 0.1 mg/kg <0.1
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 5 of 9
473147-1
SAL Reference: 473147
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Volatile Organic Compounds (USEPA 624) (MCERTS)
SAL Reference 473147 013
Customer Sample Reference BHXX4 ES 013
Top Depth 10.30
Date Sampled 22-APR-2015
Bottom Depth 10.30
Type Clay
Determinand Method TestSample LOD Units
1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg <50
1,1,1-Trichloroethane T209 M105 50 µg/kg <50
1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg <50
1,1,2-Trichloroethane T209 M105 50 µg/kg <50
1,1-Dichloroethane T209 M105 50 µg/kg <50
1,1-Dichloroethylene T209 M105 50 µg/kg <50
1,1-Dichloropropene T209 M105 50 µg/kg <50
1,2,3-Trichloropropane T209 M105 50 µg/kg <50
1,2,4-Trimethylbenzene T209 M105 50 µg/kg <50
1,2-dibromoethane T209 M105 50 µg/kg <50
1,2-Dichlorobenzene T209 M105 50 µg/kg <50
1,2-Dichloroethane T209 M105 50 µg/kg <50
1,2-Dichloropropane T209 M105 50 µg/kg <50
1,3,5-Trimethylbenzene T209 M105 50 µg/kg <50
1,3-Dichlorobenzene T209 M105 50 µg/kg <50
1,3-Dichloropropane T209 M105 50 µg/kg <50
1,4-Dichlorobenzene T209 M105 50 µg/kg <50
2,2-Dichloropropane T209 M105 50 µg/kg <50
2-Chlorotoluene T209 M105 50 µg/kg <50
4-Chlorotoluene T209 M105 50 µg/kg <50
Benzene T209 M105 10 µg/kg <10
Bromobenzene T209 M105 50 µg/kg <50
Bromochloromethane T209 M105 50 µg/kg <50
Bromodichloromethane T209 M105 50 µg/kg <50
Bromoform T209 M105 50 µg/kg <50
Bromomethane T209 M105 50 µg/kg <50
Carbon tetrachloride T209 M105 50 µg/kg <50
Chlorobenzene T209 M105 50 µg/kg <50
Chlorodibromomethane T209 M105 50 µg/kg <50
Chloroethane T209 M105 50 µg/kg <50
Chloroform T209 M105 50 µg/kg 160
Chloromethane T209 M105 50 µg/kg <50
Cis-1,2-Dichloroethylene T209 M105 50 µg/kg <50
Cis-1,3-Dichloropropene T209 M105 50 µg/kg <50
Dibromomethane T209 M105 50 µg/kg <50
Dichlorodifluoromethane T209 M105 50 µg/kg <50
Dichloromethane T209 M105 50 µg/kg <50
EthylBenzene T209 M105 10 µg/kg <10
Isopropyl benzene T209 M105 50 µg/kg <50
M/P Xylene T209 M105 10 µg/kg <10
n-Propylbenzene T209 M105 50 µg/kg <50
O Xylene T209 M105 10 µg/kg <10
p-Isopropyltoluene T209 M105 50 µg/kg <50
S-Butylbenzene T209 M105 50 µg/kg <50
Styrene T209 M105 50 µg/kg <50
T-Butylbenzene T209 M105 50 µg/kg <50
Tetrachloroethene T209 M105 50 µg/kg <50
Toluene T209 M105 10 µg/kg <10
Trans-1,2-Dichloroethene T209 M105 50 µg/kg <50
Trans-1,3-Dichloropropene T209 M105 50 µg/kg <50
Trichloroethene T209 M105 50 µg/kg <50
Trichlorofluoromethane T209 M105 50 µg/kg <50
Vinyl chloride T209 M105 50 µg/kg <50
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 6 of 9
473147-1
Index to symbols used in 473147-1
Notes
Method Index
Accreditation Summary
Value Description
AR As Received
M105 Analysis conducted on an "as received" aliquot.Results are reported on a dry weight basis wheremoisture content was determined by assisteddrying of sample at 105C
M40 Analysis conducted on sample assisted dried at nomore than 40C. Results are reported on a dryweight basis.
N.D. Not Detected
36 LOD Raised due to low Matrix spike recovery
S Analysis was subcontracted
M Analysis is MCERTS accredited
U Analysis is UKAS accredited
N Analysis is not UKAS accredited
Asbestos was subcontracted to REC Asbestos
Value Description
T85 Calc
T162 Grav (1 Dec) (105 C)
T209 GC/MS(Head Space)(MCERTS)
T546 Colorimetry (CF)
T6 ICP/OES
T286 Calc TOC/100
T54 GC/MS (Headspace)
T207 GC/MS (MCERTS)
T27 PLM
T242 2:1 Extraction/ICP/OES (TRL 447 T1)
T8 GC/FID
T7 Probe
T206 GC/FID (MCERTS)
Determinand Method TestSample LOD Units Symbol SAL References
Carbon disulphide T54 M105 0.1 mg/kg N 013
Asbestos ID T27 AR SU 013
Chromium VI T6 AR 1 mg/kg N 013
Cyanide(Total) T546 AR 1 mg/kg M 013
Cyanide(free) T546 AR 1 mg/kg M 013
pH T7 AR M 013
Phenols(Mono) T546 AR 1 mg/kg M 013
(Water Soluble) SO4 expressed as SO4 T242 AR 0.01 g/l N 013
Sulphide T546 AR 1 mg/kg N 013
Sulphur (total) T6 M40 0.01 % N 013
TPH (C10-C35) T8 M105 1 mg/kg M 013
Arsenic T6 M40 2 mg/kg M 013
Barium T6 M40 1 mg/kg U 013
Beryllium T6 M40 2 mg/kg M 013
Boron (water-soluble) T6 AR 1 mg/kg N 013
Cadmium T6 M40 1 mg/kg M 013
Chromium T6 M40 1 mg/kg M 013
Copper T6 M40 1 mg/kg M 013
Lead T6 M40 1 mg/kg M 013
Mercury T6 M40 1 mg/kg M 013
Nickel T6 M40 1 mg/kg M 013
Selenium T6 M40 3 mg/kg M 013
Vanadium T6 M40 1 mg/kg M 013
Zinc T6 M40 1 mg/kg M 013
Naphthalene T207 M105 0.1 mg/kg M 013
Acenaphthylene T207 M105 0.1 mg/kg U 013
Acenaphthene T207 M105 0.1 mg/kg M 013
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 7 of 9
473147-1
Determinand Method TestSample LOD Units Symbol SAL References
Fluorene T207 M105 0.1 mg/kg M 013
Phenanthrene T207 M105 0.1 mg/kg M 013
Anthracene T207 M105 0.1 mg/kg U 013
Fluoranthene T207 M105 0.1 mg/kg M 013
Pyrene T207 M105 0.1 mg/kg M 013
Benzo(a)Anthracene T207 M105 0.1 mg/kg M 013
Chrysene T207 M105 0.1 mg/kg M 013
Benzo(b)fluoranthene T207 M105 0.1 mg/kg M 013
Benzo(k)fluoranthene T207 M105 0.1 mg/kg M 013
Benzo(a)Pyrene T207 M105 0.1 mg/kg M 013
Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg M 013
Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg M 013
Benzo(ghi)Perylene T207 M105 0.1 mg/kg M 013
Coronene T207 M105 0.1 mg/kg N 013
PAH (Sum) T85 M105 1.6 mg/kg N 013
Mass Fraction of organic carbon T286 M40 N 013
Methyl tert-Butyl Ether T209 M105 10 µg/kg M 013
1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg M 013
1,2-Dichlorobenzene T207 M105 0.1 mg/kg M 013
1,3-Dichlorobenzene T207 M105 0.1 mg/kg M 013
1,4-Dichlorobenzene T207 M105 0.1 mg/kg M 013
2,4,5-Trichlorophenol T207 M105 0.1 mg/kg U 013
2,4,6-Trichlorophenol T207 M105 0.1 mg/kg U 013
2,4-Dichlorophenol T207 M105 0.1 mg/kg U 013
2,4-Dimethylphenol T207 M105 0.1 mg/kg U 013
2,4-Dinitrophenol T207 M105 0.1 mg/kg U 013
2,4-Dinitrotoluene T207 M105 0.1 mg/kg M 013
2,6-Dinitrotoluene T207 M105 0.1 mg/kg U 013
2-Chloronaphthalene T207 M105 0.1 mg/kg M 013
2-Chlorophenol T207 M105 0.1 mg/kg M 013
2-methyl phenol T207 M105 0.1 mg/kg M 013
2-Methylnaphthalene T207 M105 0.1 mg/kg M 013
2-Nitroaniline T207 M105 0.1 mg/kg M 013
2-Nitrophenol T207 M105 0.1 mg/kg U 013
3-Nitroaniline T207 M105 0.1 mg/kg U 013
3/4-Methylphenol T207 M105 0.1 mg/kg M 013
4-Bromophenyl phenylether T207 M105 0.1 mg/kg M 013
4-Chloro-3-methylphenol T207 M105 0.1 mg/kg M 013
4-Chloroaniline T207 M105 0.1 mg/kg U 013
4-Chlorophenyl phenylether T207 M105 0.1 mg/kg M 013
4-Nitroaniline T207 M105 0.1 mg/kg U 013
4-Nitrophenol T207 M105 0.1 mg/kg U 013
Azobenzene T207 M105 0.1 mg/kg M 013
Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg M 013
Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg M 013
Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg M 013
Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg M 013
Butyl benzylphthalate T207 M105 0.1 mg/kg U 013
Carbazole T207 M105 0.1 mg/kg U 013
Di-n-butylphthalate T207 M105 0.1 mg/kg M 013
Di-n-octylphthalate T207 M105 0.1 mg/kg M 013
Dibenzofuran T207 M105 0.1 mg/kg M 013
Diethyl phthalate T207 M105 0.1 mg/kg U 013
Dimethyl phthalate T207 M105 0.1 mg/kg U 013
Hexachlorobenzene T207 M105 0.1 mg/kg M 013
Hexachlorobutadiene T207 M105 0.1 mg/kg M 013
Hexachlorocyclopentadiene T207 M105 0.1 mg/kg U 013
Hexachloroethane T207 M105 0.1 mg/kg U 013
Isophorone T207 M105 0.1 mg/kg U 013
Nitrobenzene T207 M105 0.1 mg/kg M 013
Pentachlorophenol T207 M105 0.1 mg/kg U 013
Phenol T207 M105 0.1 mg/kg M 013
TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg N 013
TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg N 013
TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg N 013
TPH (C10-C12 aliphatic) T206 M105 1 mg/kg M 013
TPH (C12-C16 aliphatic) T206 M105 2 mg/kg M 013
TPH (C16-C21 aliphatic) T206 M105 1 mg/kg M 013
TPH (C21-C35 aliphatic) T206 M105 4 mg/kg M 013
TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg N 013
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 8 of 9
473147-1
Determinand Method TestSample LOD Units Symbol SAL References
TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg N 013
TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg N 013
TPH (C10-C12 aromatic) T206 M105 1 mg/kg N 013
TPH (C12-C16 aromatic) T206 M105 1 mg/kg M 013
TPH (C16-C21 aromatic) T206 M105 1 mg/kg M 013
TPH (C21-C35 aromatic) T206 M105 1 mg/kg M 013
1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg M 013
1,1,1-Trichloroethane T209 M105 50 µg/kg M 013
1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg U 013
1,1,2-Trichloroethane T209 M105 50 µg/kg M 013
1,1-Dichloroethane T209 M105 50 µg/kg M 013
1,1-Dichloroethylene T209 M105 50 µg/kg M 013
1,1-Dichloropropene T209 M105 50 µg/kg M 013
1,2,3-Trichloropropane T209 M105 50 µg/kg U 013
1,2,4-Trimethylbenzene T209 M105 50 µg/kg M 013
1,2-dibromoethane T209 M105 50 µg/kg M 013
1,2-Dichlorobenzene T209 M105 50 µg/kg M 013
1,2-Dichloroethane T209 M105 50 µg/kg M 013
1,2-Dichloropropane T209 M105 50 µg/kg M 013
1,3,5-Trimethylbenzene T209 M105 50 µg/kg M 013
1,3-Dichlorobenzene T209 M105 50 µg/kg M 013
1,3-Dichloropropane T209 M105 50 µg/kg M 013
1,4-Dichlorobenzene T209 M105 50 µg/kg M 013
2,2-Dichloropropane T209 M105 50 µg/kg U 013
2-Chlorotoluene T209 M105 50 µg/kg U 013
4-Chlorotoluene T209 M105 50 µg/kg U 013
Benzene T209 M105 10 µg/kg M 013
Bromobenzene T209 M105 50 µg/kg M 013
Bromochloromethane T209 M105 50 µg/kg M 013
Bromodichloromethane T209 M105 50 µg/kg M 013
Bromoform T209 M105 50 µg/kg M 013
Bromomethane T209 M105 50 µg/kg U 013
Carbon tetrachloride T209 M105 50 µg/kg M 013
Chlorobenzene T209 M105 50 µg/kg M 013
Chlorodibromomethane T209 M105 50 µg/kg M 013
Chloroethane T209 M105 50 µg/kg M 013
Chloroform T209 M105 50 µg/kg M 013
Chloromethane T209 M105 50 µg/kg U 013
Cis-1,2-Dichloroethylene T209 M105 50 µg/kg M 013
Cis-1,3-Dichloropropene T209 M105 50 µg/kg M 013
Dibromomethane T209 M105 50 µg/kg M 013
Dichlorodifluoromethane T209 M105 50 µg/kg M 013
Dichloromethane T209 M105 50 µg/kg U 013
EthylBenzene T209 M105 10 µg/kg M 013
Isopropyl benzene T209 M105 50 µg/kg M 013
M/P Xylene T209 M105 10 µg/kg M 013
n-Propylbenzene T209 M105 50 µg/kg M 013
O Xylene T209 M105 10 µg/kg M 013
p-Isopropyltoluene T209 M105 50 µg/kg M 013
S-Butylbenzene T209 M105 50 µg/kg M 013
Styrene T209 M105 50 µg/kg U 013
T-Butylbenzene T209 M105 50 µg/kg M 013
Tetrachloroethene T209 M105 50 µg/kg M 013
Toluene T209 M105 10 µg/kg M 013
Trans-1,2-Dichloroethene T209 M105 50 µg/kg M 013
Trans-1,3-Dichloropropene T209 M105 50 µg/kg M 013
Trichloroethene T209 M105 50 µg/kg M 013
Trichlorofluoromethane T209 M105 50 µg/kg M 013
Vinyl chloride T209 M105 50 µg/kg M 013
Moisture @ 105 C T162 AR 0.1 % N 013
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 9 of 9
473147-1
Scientific Analysis Laboratories Ltd
Certificate of Analysis
Hadfield HouseHadfield Street
CornbrookManchester
M16 9FETel : 0161 874 2400Fax : 0161 874 2468
Report Number: 478734-1
Date of Report: 26-May-2015
Customer: Soil Engineering Geoservices LimitedParkside LaneDewsbury RoadLeedsWest Yorkshire.LS11 5SX
Customer Contact: Mr Andrew De Joux
Customer Job Reference: TA7437Customer Site Reference: Mersey Gateway Bridge. Additional GI
(Phase 2)Date Job Received at SAL: 22-Apr-2015
Date Analysis Started: 20-May-2015Date Analysis Completed: 22-May-2015
The results reported relate to samples received in the laboratoryOpinions and interpretations expressed herein are outside the scope of UKAS accreditationThis report should not be reproduced except in full without the written approval of the laboratoryTests covered by this certificate were conducted in accordance with SAL SOPsAll results have been reviewed in accordance with Section 25 of the SAL Quality Manual
This document has been printed from a digitally signed master copy
Scientific Analysis Laboratories is a
limited company registered in England and
Wales (No 2514788) whose address is at
Hadfield House, Hadfield Street, Manchester M16 9FE
1549
Report checkedand authorised by :Natasha WildProject Manager
Issued by :Natasha WildProject Manager
Page 1 of 5
478734-1
SAL Reference: 478734
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Moisture
SAL Reference 478734005
478734006
478734011
478734012
478734019
478734021
478734023
478734025
Customer Sample Reference BHXX4 ES005
(473147/005)
BHXX4 ES006
(473147/006)
BHXX4 ES011
(473147/011)
BHXX4 ES012
(473147/012)
BHXX5 ES006
(475292/006)
BHXX5 ES008
(475292/008)
BHXX5 ES010
(475292/010)
BHXX5 ES012
(475292/012)
Date Sampled 21-APR-2015
21-APR-2015
22-APR-2015
22-APR-2015
23-APR-2015
24-APR-2015
24-APR-2015
24-APR-2015
Bottom Depth 4.30 5.20 10.00 10.20 4.70 6.00 8.00 10.00
Top Depth 4.30 5.20 10.00 10.20 4.70 6.00 8.00 10.00
Type Clay Clay Clay Sandy Soil Clay Sandy Soil Sandy Soil Sandy Soil
Determinand Method TestSample LOD Units
Moisture @ 105 C T162 AR 0.1 % 31 23 27 8.5 36 23 21 17
SAL Reference: 478734
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Carbon disulphide
SAL Reference 478734005
478734006
478734011
478734012
478734019
478734021
478734023
478734025
Customer Sample Reference BHXX4 ES005
(473147/005)
BHXX4 ES006
(473147/006)
BHXX4 ES011
(473147/011)
BHXX4 ES012
(473147/012)
BHXX5 ES006
(475292/006)
BHXX5 ES008
(475292/008)
BHXX5 ES010
(475292/010)
BHXX5 ES012
(475292/012)
Date Sampled 21-APR-2015
21-APR-2015
22-APR-2015
22-APR-2015
23-APR-2015
24-APR-2015
24-APR-2015
24-APR-2015
Bottom Depth 4.30 5.20 10.00 10.20 4.70 6.00 8.00 10.00
Top Depth 4.30 5.20 10.00 10.20 4.70 6.00 8.00 10.00
Type Clay Clay Clay Sandy Soil Clay Sandy Soil Sandy Soil Sandy Soil
Determinand Method TestSample LOD Units
Carbon disulphide T54 AR 0.1 mg/kg 160 73 260 65 8.4 9.7 10 56
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 2 of 5
478734-1
SAL Reference: 478734
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Volatile Organic Compounds (USEPA 624) (MCERTS)
SAL Reference 478734005
478734006
478734011
478734012
478734019
478734021
478734023
478734025
Customer Sample Reference BHXX4 ES005
(473147/005)
BHXX4 ES006
(473147/006)
BHXX4 ES011
(473147/011)
BHXX4 ES012
(473147/012)
BHXX5 ES006
(475292/006)
BHXX5 ES008
(475292/008)
BHXX5 ES010
(475292/010)
BHXX5 ES012
(475292/012)
Date Sampled 21-APR-2015
21-APR-2015
22-APR-2015
22-APR-2015
23-APR-2015
24-APR-2015
24-APR-2015
24-APR-2015
Bottom Depth 4.30 5.20 10.00 10.20 4.70 6.00 8.00 10.00
Top Depth 4.30 5.20 10.00 10.20 4.70 6.00 8.00 10.00
Type Clay Clay Clay SandySoil
Clay SandySoil
SandySoil
SandySoil
Determinand Method TestSample LOD Units
Dichlorodifluoromethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Chloromethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Vinyl chloride T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Bromomethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Chloroethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Trichlorofluoromethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,1-Dichloroethylene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Dichloromethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Trans-1,2-Dichloroethene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,1-Dichloroethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Cis-1,2-Dichloroethylene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
2,2-Dichloropropane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Chloroform T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 78 220
Bromochloromethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,1,1-Trichloroethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,1-Dichloropropene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Carbon tetrachloride T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,2-Dichloroethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Benzene T209 M105 10 µg/kg (13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10
1,2-Dichloropropane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Trichloroethene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Bromodichloromethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Dibromomethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Cis-1,3-Dichloropropene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Toluene T209 M105 10 µg/kg <10 <10 <10 <10 <10 <10 <10 <10
Trans-1,3-Dichloropropene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,1,2-Trichloroethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,3-Dichloropropane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Tetrachloroethene T209 M105 50 µg/kg <50 77 73 <50 <50 <50 <50 <50
Chlorodibromomethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,2-dibromoethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Chlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
EthylBenzene T209 M105 10 µg/kg <10 <10 <10 <10 <10 <10 <10 <10
M/P Xylene T209 M105 10 µg/kg <10 <10 <10 <10 <10 <10 <10 <10
O Xylene T209 M105 10 µg/kg <10 <10 <10 <10 <10 <10 <10 <10
Styrene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Bromoform T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Isopropyl benzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,2,3-Trichloropropane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
n-Propylbenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
Bromobenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,3,5-Trimethylbenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
T-Butylbenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,2,4-Trimethylbenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
S-Butylbenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
p-Isopropyltoluene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
2-Chlorotoluene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
4-Chlorotoluene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,3-Dichlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,4-Dichlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
1,2-Dichlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 3 of 5
478734-1
Index to symbols used in 478734-1
Notes
Method Index
Accreditation Summary
Value Description
AR As Received
M105 Analysis conducted on an "as received"aliquot. Results are reported on a dryweight basis where moisture content wasdetermined by assisted drying of sampleat 105C
13 Results have been blank corrected.
M Analysis is MCERTS accredited
U Analysis is UKAS accredited
N Analysis is not UKAS accredited
These samples have been analysed exceeding recommended holding times. It is possible therefore that the results provided may be compromised.
Value Description
T54 GC/MS (Headspace)
T209 GC/MS(Head Space)(MCERTS)
T162 Grav (1 Dec) (105 C)
Determinand Method TestSample LOD Units Symbol SAL References
Carbon disulphide T54 AR 0.1 mg/kg N 005-006,011-012,019,021,023,025
Dichlorodifluoromethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Chloromethane T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025
Vinyl chloride T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Bromomethane T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025
Chloroethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Trichlorofluoromethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
1,1-Dichloroethylene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Dichloromethane T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025
Trans-1,2-Dichloroethene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
1,1-Dichloroethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Cis-1,2-Dichloroethylene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
2,2-Dichloropropane T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025
Chloroform T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Bromochloromethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
1,1,1-Trichloroethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
1,1-Dichloropropene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Carbon tetrachloride T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
1,2-Dichloroethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Benzene T209 M105 10 µg/kg M 005-006,011-012,019,021,023,025
1,2-Dichloropropane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Trichloroethene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Bromodichloromethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Dibromomethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Cis-1,3-Dichloropropene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Toluene T209 M105 10 µg/kg M 005-006,011-012,019,021,023,025
Trans-1,3-Dichloropropene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
1,1,2-Trichloroethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
1,3-Dichloropropane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Tetrachloroethene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Chlorodibromomethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
1,2-dibromoethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Chlorobenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
EthylBenzene T209 M105 10 µg/kg M 005-006,011-012,019,021,023,025
M/P Xylene T209 M105 10 µg/kg M 005-006,011-012,019,021,023,025
O Xylene T209 M105 10 µg/kg M 005-006,011-012,019,021,023,025
Styrene T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025
Bromoform T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Isopropyl benzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 4 of 5
478734-1
Determinand Method TestSample LOD Units Symbol SAL References
1,2,3-Trichloropropane T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025
n-Propylbenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Bromobenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
1,3,5-Trimethylbenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
T-Butylbenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
1,2,4-Trimethylbenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
S-Butylbenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
p-Isopropyltoluene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
2-Chlorotoluene T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025
4-Chlorotoluene T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025
1,3-Dichlorobenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
1,4-Dichlorobenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
1,2-Dichlorobenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025
Moisture @ 105 C T162 AR 0.1 % N 005-006,011-012,019,021,023,025
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 5 of 5
478734-1
Scientific Analysis Laboratories Ltd
Certificate of Analysis
Hadfield HouseHadfield Street
CornbrookManchester
M16 9FETel : 0161 874 2400Fax : 0161 874 2468
Report Number: 475292-1
Date of Report: 18-May-2015
Customer: Soil Engineering Geoservices LimitedParkside LaneDewsbury RoadLeedsWest Yorkshire.LS11 5SX
Customer Contact: Mr Andrew De Joux
Customer Job Reference: TA7437Customer Site Reference: Mersey Gateway Bridge. Additional GI
(Phase 2)Date Job Received at SAL: 24-Apr-2015
Date Analysis Started: 07-May-2015Date Analysis Completed: 14-May-2015
The results reported relate to samples received in the laboratoryOpinions and interpretations expressed herein are outside the scope of UKAS accreditationThis report should not be reproduced except in full without the written approval of the laboratoryTests covered by this certificate were conducted in accordance with SAL SOPsAll results have been reviewed in accordance with Section 25 of the SAL Quality Manual
This document has been printed from a digitally signed master copy
Scientific Analysis Laboratories is a
limited company registered in England and
Wales (No 2514788) whose address is at
Hadfield House, Hadfield Street, Manchester M16 9FE
1549
Report checkedand authorised by :Natasha WildProject Manager
Issued by :Natasha WildProject Manager
Page 1 of 9
475292-1
SAL Reference: 475292
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Moisture
SAL Reference 475292 013
Customer Sample Reference BHXX5 ES 013
Bottom Depth 10.40
Date Sampled 27-APR-2015
Top Depth 10.40
Type Clay
Determinand Method TestSample LOD Units
Moisture @ 105 C T162 AR 0.1 % 16
SAL Reference: 475292
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Asbestos
SAL Reference 475292 013
Customer Sample Reference BHXX5 ES 013
Bottom Depth 10.40
Date Sampled 27-APR-2015
Top Depth 10.40
Type Clay
Determinand Method TestSample LOD Units
Asbestos ID T27 AR N.D.
SAL Reference: 475292
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Carbon disulphide
SAL Reference 475292 013
Customer Sample Reference BHXX5 ES 013
Bottom Depth 10.40
Date Sampled 27-APR-2015
Top Depth 10.40
Type Clay
Determinand Method TestSample LOD Units
Carbon disulphide T54 M105 0.1 mg/kg <0.1
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 2 of 9
475292-1
SAL Reference: 475292
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
CLEA Metals
SAL Reference 475292 013
Customer Sample Reference BHXX5 ES 013
Bottom Depth 10.40
Date Sampled 27-APR-2015
Top Depth 10.40
Type Clay
Determinand Method TestSample LOD Units
Arsenic T6 M40 2 mg/kg 10
Beryllium T6 M40 2 mg/kg <2
Cadmium T6 M40 1 mg/kg <1
Chromium T6 M40 1 mg/kg 23
Copper T6 M40 1 mg/kg 14
Lead T6 M40 1 mg/kg 8
Mercury T6 M40 1 mg/kg <1
Nickel T6 M40 1 mg/kg 27
Selenium T6 M40 3 mg/kg <3
Vanadium T6 M40 1 mg/kg 22
Zinc T6 M40 1 mg/kg 42
Barium T6 M40 1 mg/kg 100
Boron (water-soluble) T6 AR 1 mg/kg <1
SAL Reference: 475292
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Suite E
SAL Reference 475292 013
Customer Sample Reference BHXX5 ES 013
Bottom Depth 10.40
Date Sampled 27-APR-2015
Top Depth 10.40
Type Clay
Determinand Method TestSample LOD Units
Chromium VI T6 AR 1 mg/kg <1
Cyanide(Total) T546 AR 1 mg/kg <1
Cyanide(free) T546 AR 1 mg/kg <1
pH T7 AR 8.1
Phenols(Mono) T546 AR 1 mg/kg <1
(Water Soluble) SO4 expressed as SO4 T242 AR 0.01 g/l 0.91
Sulphide T546 AR 1 mg/kg <1
Sulphur (total) T6 M40 0.01 % 0.09
TPH (C10-C35) T8 M105 1 mg/kg <1
SAL Reference: 475292
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Suite K
SAL Reference 475292 013
Customer Sample Reference BHXX5 ES 013
Bottom Depth 10.40
Date Sampled 27-APR-2015
Top Depth 10.40
Type Clay
Determinand Method TestSample LOD Units
Mass Fraction of organic carbon T286 M40 0.0031
Methyl tert-Butyl Ether T209 M105 10 µg/kg <10
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 3 of 9
475292-1
SAL Reference: 475292
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
PAH EPA 16, Coronene
SAL Reference 475292 013
Customer Sample Reference BHXX5 ES 013
Bottom Depth 10.40
Date Sampled 27-APR-2015
Top Depth 10.40
Type Clay
Determinand Method TestSample LOD Units
Naphthalene T207 M105 0.1 mg/kg <0.1
Acenaphthylene T207 M105 0.1 mg/kg <0.1
Acenaphthene T207 M105 0.1 mg/kg <0.1
Fluorene T207 M105 0.1 mg/kg <0.1
Phenanthrene T207 M105 0.1 mg/kg <0.1
Anthracene T207 M105 0.1 mg/kg <0.1
Fluoranthene T207 M105 0.1 mg/kg <0.1
Pyrene T207 M105 0.1 mg/kg <0.1
Benzo(a)Anthracene T207 M105 0.1 mg/kg <0.1
Chrysene T207 M105 0.1 mg/kg <0.1
Benzo(b)fluoranthene T207 M105 0.1 mg/kg <0.1
Benzo(k)fluoranthene T207 M105 0.1 mg/kg <0.1
Benzo(a)Pyrene T207 M105 0.1 mg/kg <0.1
Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg <0.1
Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg <0.1
Benzo(ghi)Perylene T207 M105 0.1 mg/kg <0.1
Coronene T207 M105 0.1 mg/kg <0.1
PAH (Sum) T85 M105 1.6 mg/kg <1.6
SAL Reference: 475292
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
TPH (CWG)
SAL Reference 475292 013
Customer Sample Reference BHXX5 ES 013
Bottom Depth 10.40
Date Sampled 27-APR-2015
Top Depth 10.40
Type Clay
Determinand Method TestSample LOD Units
TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg <0.100
TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg <0.10
TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg <0.10
TPH (C10-C12 aliphatic) T206 M105 1 mg/kg <1
TPH (C12-C16 aliphatic) T206 M105 2 mg/kg <2
TPH (C16-C21 aliphatic) T206 M105 1 mg/kg <1
TPH (C21-C35 aliphatic) T206 M105 4 mg/kg <4
TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg <0.10
TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg <0.10
TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg <0.10
TPH (C10-C12 aromatic) T206 M105 1 mg/kg <1
TPH (C12-C16 aromatic) T206 M105 1 mg/kg <1
TPH (C16-C21 aromatic) T206 M105 1 mg/kg <1
TPH (C21-C35 aromatic) T206 M105 1 mg/kg <1
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 4 of 9
475292-1
SAL Reference: 475292
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Semi-Volatile Organic Compounds (Reduced)
SAL Reference 475292 013
Customer Sample Reference BHXX5 ES 013
Bottom Depth 10.40
Date Sampled 27-APR-2015
Top Depth 10.40
Type Clay
Determinand Method TestSample LOD Units
1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg <0.1
1,2-Dichlorobenzene T207 M105 0.1 mg/kg <0.1
1,3-Dichlorobenzene T207 M105 0.1 mg/kg <0.1
1,4-Dichlorobenzene T207 M105 0.1 mg/kg <0.1
2,4,5-Trichlorophenol T207 M105 0.1 mg/kg <0.1
2,4,6-Trichlorophenol T207 M105 0.1 mg/kg <0.1
2,4-Dichlorophenol T207 M105 0.1 mg/kg <0.1
2,4-Dimethylphenol T207 M105 0.1 mg/kg <0.1
2,4-Dinitrophenol T207 M105 0.1 mg/kg (36) <0.5
2,4-Dinitrotoluene T207 M105 0.1 mg/kg <0.1
2,6-Dinitrotoluene T207 M105 0.1 mg/kg <0.1
2-Chloronaphthalene T207 M105 0.1 mg/kg <0.1
2-Chlorophenol T207 M105 0.1 mg/kg <0.1
2-methyl phenol T207 M105 0.1 mg/kg <0.1
2-Methylnaphthalene T207 M105 0.1 mg/kg <0.1
2-Nitroaniline T207 M105 0.1 mg/kg <0.1
2-Nitrophenol T207 M105 0.1 mg/kg <0.1
3-Nitroaniline T207 M105 0.1 mg/kg <0.1
3/4-Methylphenol T207 M105 0.1 mg/kg <0.1
4-Bromophenyl phenylether T207 M105 0.1 mg/kg <0.1
4-Chloro-3-methylphenol T207 M105 0.1 mg/kg <0.1
4-Chloroaniline T207 M105 0.1 mg/kg (36) <0.5
4-Chlorophenyl phenylether T207 M105 0.1 mg/kg <0.1
4-Nitroaniline T207 M105 0.1 mg/kg (36) <0.5
4-Nitrophenol T207 M105 0.1 mg/kg (36) <0.5
Azobenzene T207 M105 0.1 mg/kg <0.1
Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg <0.1
Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg <0.1
Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg <0.1
Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg <0.1
Butyl benzylphthalate T207 M105 0.1 mg/kg <0.1
Carbazole T207 M105 0.1 mg/kg <0.1
Di-n-butylphthalate T207 M105 0.1 mg/kg <0.1
Di-n-octylphthalate T207 M105 0.1 mg/kg <0.1
Dibenzofuran T207 M105 0.1 mg/kg <0.1
Diethyl phthalate T207 M105 0.1 mg/kg <0.1
Dimethyl phthalate T207 M105 0.1 mg/kg <0.1
Hexachlorobenzene T207 M105 0.1 mg/kg <0.1
Hexachlorobutadiene T207 M105 0.1 mg/kg <0.1
Hexachlorocyclopentadiene T207 M105 0.1 mg/kg (36) <0.5
Hexachloroethane T207 M105 0.1 mg/kg <0.1
Isophorone T207 M105 0.1 mg/kg <0.1
Nitrobenzene T207 M105 0.1 mg/kg <0.1
Pentachlorophenol T207 M105 0.1 mg/kg (36) <0.5
Phenol T207 M105 0.1 mg/kg <0.1
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 5 of 9
475292-1
SAL Reference: 475292
Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)
Customer Reference: TA7437
Soil Analysed as Soil
Volatile Organic Compounds (USEPA 624) (MCERTS)
SAL Reference 475292 013
Customer Sample Reference BHXX5 ES 013
Bottom Depth 10.40
Date Sampled 27-APR-2015
Top Depth 10.40
Type Clay
Determinand Method TestSample LOD Units
1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg <50
1,1,1-Trichloroethane T209 M105 50 µg/kg <50
1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg <50
1,1,2-Trichloroethane T209 M105 50 µg/kg <50
1,1-Dichloroethane T209 M105 50 µg/kg <50
1,1-Dichloroethylene T209 M105 50 µg/kg <50
1,1-Dichloropropene T209 M105 50 µg/kg <50
1,2,3-Trichloropropane T209 M105 50 µg/kg <50
1,2,4-Trimethylbenzene T209 M105 50 µg/kg <50
1,2-dibromoethane T209 M105 50 µg/kg <50
1,2-Dichlorobenzene T209 M105 50 µg/kg <50
1,2-Dichloroethane T209 M105 50 µg/kg <50
1,2-Dichloropropane T209 M105 50 µg/kg <50
1,3,5-Trimethylbenzene T209 M105 50 µg/kg <50
1,3-Dichlorobenzene T209 M105 50 µg/kg <50
1,3-Dichloropropane T209 M105 50 µg/kg <50
1,4-Dichlorobenzene T209 M105 50 µg/kg <50
2,2-Dichloropropane T209 M105 50 µg/kg <50
2-Chlorotoluene T209 M105 50 µg/kg <50
4-Chlorotoluene T209 M105 50 µg/kg <50
Benzene T209 M105 10 µg/kg (13) <10
Bromobenzene T209 M105 50 µg/kg <50
Bromochloromethane T209 M105 50 µg/kg <50
Bromodichloromethane T209 M105 50 µg/kg <50
Bromoform T209 M105 50 µg/kg <50
Bromomethane T209 M105 50 µg/kg <50
Carbon tetrachloride T209 M105 50 µg/kg <50
Chlorobenzene T209 M105 50 µg/kg <50
Chlorodibromomethane T209 M105 50 µg/kg <50
Chloroethane T209 M105 50 µg/kg <50
Chloroform T209 M105 50 µg/kg <50
Chloromethane T209 M105 50 µg/kg <50
Cis-1,2-Dichloroethylene T209 M105 50 µg/kg <50
Cis-1,3-Dichloropropene T209 M105 50 µg/kg <50
Dibromomethane T209 M105 50 µg/kg <50
Dichlorodifluoromethane T209 M105 50 µg/kg <50
Dichloromethane T209 M105 50 µg/kg <50
EthylBenzene T209 M105 10 µg/kg <10
Isopropyl benzene T209 M105 50 µg/kg <50
M/P Xylene T209 M105 10 µg/kg <10
n-Propylbenzene T209 M105 50 µg/kg <50
O Xylene T209 M105 10 µg/kg <10
p-Isopropyltoluene T209 M105 50 µg/kg <50
S-Butylbenzene T209 M105 50 µg/kg <50
Styrene T209 M105 50 µg/kg <50
T-Butylbenzene T209 M105 50 µg/kg <50
Tetrachloroethene T209 M105 50 µg/kg <50
Toluene T209 M105 10 µg/kg <10
Trans-1,2-Dichloroethene T209 M105 50 µg/kg <50
Trans-1,3-Dichloropropene T209 M105 50 µg/kg <50
Trichloroethene T209 M105 50 µg/kg <50
Trichlorofluoromethane T209 M105 50 µg/kg <50
Vinyl chloride T209 M105 50 µg/kg <50
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 6 of 9
475292-1
Index to symbols used in 475292-1
Notes
Method Index
Accreditation Summary
Value Description
M105 Analysis conducted on an "as received" aliquot.Results are reported on a dry weight basis wheremoisture content was determined by assisteddrying of sample at 105C
M40 Analysis conducted on sample assisted dried at nomore than 40C. Results are reported on a dryweight basis.
AR As Received
N.D. Not Detected
36 LOD Raised due to low Matrix spike recovery
13 Results have been blank corrected.
S Analysis was subcontracted
M Analysis is MCERTS accredited
U Analysis is UKAS accredited
N Analysis is not UKAS accredited
These samples have been analysed exceeding recommended holding times. It is possible therefore that the results provided may be compromised.
Asbestos was subcontracted to REC Asbestos.
Value Description
T8 GC/FID
T546 Colorimetry (CF)
T6 ICP/OES
T27 PLM
T206 GC/FID (MCERTS)
T85 Calc
T7 Probe
T162 Grav (1 Dec) (105 C)
T242 2:1 Extraction/ICP/OES (TRL 447 T1)
T286 Calc TOC/100
T54 GC/MS (Headspace)
T209 GC/MS(Head Space)(MCERTS)
T207 GC/MS (MCERTS)
Determinand Method TestSample LOD Units Symbol SAL References
Carbon disulphide T54 M105 0.1 mg/kg N 013
Chromium VI T6 AR 1 mg/kg N 013
Cyanide(Total) T546 AR 1 mg/kg M 013
Cyanide(free) T546 AR 1 mg/kg M 013
pH T7 AR M 013
Phenols(Mono) T546 AR 1 mg/kg M 013
(Water Soluble) SO4 expressed as SO4 T242 AR 0.01 g/l N 013
Sulphide T546 AR 1 mg/kg N 013
Sulphur (total) T6 M40 0.01 % N 013
TPH (C10-C35) T8 M105 1 mg/kg M 013
Arsenic T6 M40 2 mg/kg M 013
Beryllium T6 M40 2 mg/kg M 013
Cadmium T6 M40 1 mg/kg M 013
Chromium T6 M40 1 mg/kg M 013
Copper T6 M40 1 mg/kg M 013
Lead T6 M40 1 mg/kg M 013
Mercury T6 M40 1 mg/kg M 013
Nickel T6 M40 1 mg/kg M 013
Selenium T6 M40 3 mg/kg M 013
Vanadium T6 M40 1 mg/kg M 013
Zinc T6 M40 1 mg/kg M 013
Barium T6 M40 1 mg/kg U 013
Boron (water-soluble) T6 AR 1 mg/kg N 013
Naphthalene T207 M105 0.1 mg/kg M 013
Acenaphthylene T207 M105 0.1 mg/kg U 013
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 7 of 9
475292-1
Determinand Method TestSample LOD Units Symbol SAL References
Acenaphthene T207 M105 0.1 mg/kg M 013
Fluorene T207 M105 0.1 mg/kg M 013
Phenanthrene T207 M105 0.1 mg/kg M 013
Anthracene T207 M105 0.1 mg/kg U 013
Fluoranthene T207 M105 0.1 mg/kg M 013
Pyrene T207 M105 0.1 mg/kg M 013
Benzo(a)Anthracene T207 M105 0.1 mg/kg M 013
Chrysene T207 M105 0.1 mg/kg M 013
Benzo(b)fluoranthene T207 M105 0.1 mg/kg M 013
Benzo(k)fluoranthene T207 M105 0.1 mg/kg M 013
Benzo(a)Pyrene T207 M105 0.1 mg/kg M 013
Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg M 013
Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg M 013
Benzo(ghi)Perylene T207 M105 0.1 mg/kg M 013
Coronene T207 M105 0.1 mg/kg N 013
PAH (Sum) T85 M105 1.6 mg/kg N 013
Mass Fraction of organic carbon T286 M40 N 013
Methyl tert-Butyl Ether T209 M105 10 µg/kg M 013
1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg M 013
1,2-Dichlorobenzene T207 M105 0.1 mg/kg M 013
1,3-Dichlorobenzene T207 M105 0.1 mg/kg M 013
1,4-Dichlorobenzene T207 M105 0.1 mg/kg M 013
2,4,5-Trichlorophenol T207 M105 0.1 mg/kg U 013
2,4,6-Trichlorophenol T207 M105 0.1 mg/kg U 013
2,4-Dichlorophenol T207 M105 0.1 mg/kg U 013
2,4-Dimethylphenol T207 M105 0.1 mg/kg U 013
2,4-Dinitrophenol T207 M105 0.1 mg/kg U 013
2,4-Dinitrotoluene T207 M105 0.1 mg/kg M 013
2,6-Dinitrotoluene T207 M105 0.1 mg/kg U 013
2-Chloronaphthalene T207 M105 0.1 mg/kg M 013
2-Chlorophenol T207 M105 0.1 mg/kg M 013
2-methyl phenol T207 M105 0.1 mg/kg M 013
2-Methylnaphthalene T207 M105 0.1 mg/kg M 013
2-Nitroaniline T207 M105 0.1 mg/kg M 013
2-Nitrophenol T207 M105 0.1 mg/kg U 013
3-Nitroaniline T207 M105 0.1 mg/kg U 013
3/4-Methylphenol T207 M105 0.1 mg/kg M 013
4-Bromophenyl phenylether T207 M105 0.1 mg/kg M 013
4-Chloro-3-methylphenol T207 M105 0.1 mg/kg M 013
4-Chloroaniline T207 M105 0.1 mg/kg U 013
4-Chlorophenyl phenylether T207 M105 0.1 mg/kg M 013
4-Nitroaniline T207 M105 0.1 mg/kg U 013
4-Nitrophenol T207 M105 0.1 mg/kg U 013
Azobenzene T207 M105 0.1 mg/kg M 013
Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg M 013
Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg M 013
Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg M 013
Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg M 013
Butyl benzylphthalate T207 M105 0.1 mg/kg U 013
Carbazole T207 M105 0.1 mg/kg U 013
Di-n-butylphthalate T207 M105 0.1 mg/kg M 013
Di-n-octylphthalate T207 M105 0.1 mg/kg M 013
Dibenzofuran T207 M105 0.1 mg/kg M 013
Diethyl phthalate T207 M105 0.1 mg/kg U 013
Dimethyl phthalate T207 M105 0.1 mg/kg U 013
Hexachlorobenzene T207 M105 0.1 mg/kg M 013
Hexachlorobutadiene T207 M105 0.1 mg/kg M 013
Hexachlorocyclopentadiene T207 M105 0.1 mg/kg U 013
Hexachloroethane T207 M105 0.1 mg/kg U 013
Isophorone T207 M105 0.1 mg/kg U 013
Nitrobenzene T207 M105 0.1 mg/kg M 013
Pentachlorophenol T207 M105 0.1 mg/kg U 013
Phenol T207 M105 0.1 mg/kg M 013
TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg N 013
TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg N 013
TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg N 013
TPH (C10-C12 aliphatic) T206 M105 1 mg/kg M 013
TPH (C12-C16 aliphatic) T206 M105 2 mg/kg M 013
TPH (C16-C21 aliphatic) T206 M105 1 mg/kg M 013
TPH (C21-C35 aliphatic) T206 M105 4 mg/kg M 013
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 8 of 9
475292-1
Determinand Method TestSample LOD Units Symbol SAL References
TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg N 013
TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg N 013
TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg N 013
TPH (C10-C12 aromatic) T206 M105 1 mg/kg N 013
TPH (C12-C16 aromatic) T206 M105 1 mg/kg M 013
TPH (C16-C21 aromatic) T206 M105 1 mg/kg M 013
TPH (C21-C35 aromatic) T206 M105 1 mg/kg M 013
1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg M 013
1,1,1-Trichloroethane T209 M105 50 µg/kg M 013
1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg U 013
1,1,2-Trichloroethane T209 M105 50 µg/kg M 013
1,1-Dichloroethane T209 M105 50 µg/kg M 013
1,1-Dichloroethylene T209 M105 50 µg/kg M 013
1,1-Dichloropropene T209 M105 50 µg/kg M 013
1,2,3-Trichloropropane T209 M105 50 µg/kg U 013
1,2,4-Trimethylbenzene T209 M105 50 µg/kg M 013
1,2-dibromoethane T209 M105 50 µg/kg M 013
1,2-Dichlorobenzene T209 M105 50 µg/kg M 013
1,2-Dichloroethane T209 M105 50 µg/kg M 013
1,2-Dichloropropane T209 M105 50 µg/kg M 013
1,3,5-Trimethylbenzene T209 M105 50 µg/kg M 013
1,3-Dichlorobenzene T209 M105 50 µg/kg M 013
1,3-Dichloropropane T209 M105 50 µg/kg M 013
1,4-Dichlorobenzene T209 M105 50 µg/kg M 013
2,2-Dichloropropane T209 M105 50 µg/kg U 013
2-Chlorotoluene T209 M105 50 µg/kg U 013
4-Chlorotoluene T209 M105 50 µg/kg U 013
Benzene T209 M105 10 µg/kg M 013
Bromobenzene T209 M105 50 µg/kg M 013
Bromochloromethane T209 M105 50 µg/kg M 013
Bromodichloromethane T209 M105 50 µg/kg M 013
Bromoform T209 M105 50 µg/kg M 013
Bromomethane T209 M105 50 µg/kg U 013
Carbon tetrachloride T209 M105 50 µg/kg M 013
Chlorobenzene T209 M105 50 µg/kg M 013
Chlorodibromomethane T209 M105 50 µg/kg M 013
Chloroethane T209 M105 50 µg/kg M 013
Chloroform T209 M105 50 µg/kg M 013
Chloromethane T209 M105 50 µg/kg U 013
Cis-1,2-Dichloroethylene T209 M105 50 µg/kg M 013
Cis-1,3-Dichloropropene T209 M105 50 µg/kg M 013
Dibromomethane T209 M105 50 µg/kg M 013
Dichlorodifluoromethane T209 M105 50 µg/kg M 013
Dichloromethane T209 M105 50 µg/kg U 013
EthylBenzene T209 M105 10 µg/kg M 013
Isopropyl benzene T209 M105 50 µg/kg M 013
M/P Xylene T209 M105 10 µg/kg M 013
n-Propylbenzene T209 M105 50 µg/kg M 013
O Xylene T209 M105 10 µg/kg M 013
p-Isopropyltoluene T209 M105 50 µg/kg M 013
S-Butylbenzene T209 M105 50 µg/kg M 013
Styrene T209 M105 50 µg/kg U 013
T-Butylbenzene T209 M105 50 µg/kg M 013
Tetrachloroethene T209 M105 50 µg/kg M 013
Toluene T209 M105 10 µg/kg M 013
Trans-1,2-Dichloroethene T209 M105 50 µg/kg M 013
Trans-1,3-Dichloropropene T209 M105 50 µg/kg M 013
Trichloroethene T209 M105 50 µg/kg M 013
Trichlorofluoromethane T209 M105 50 µg/kg M 013
Vinyl chloride T209 M105 50 µg/kg M 013
Moisture @ 105 C T162 AR 0.1 % N 013
Asbestos ID T27 AR SU 013
This document has been printed from a digitally signed master copy
Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 9 of 9
475292-1
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 D 17 MARCH 2016
APPENDIX D – LABORATORY REPORTS
(GROUNDWATER)
Page 1 of 9
Units 7 & 8 Sandpits Business Park Mottram Road, Hyde, Cheshire, SK14 3AR
FINAL ANALYTICAL TEST REPORT
Envirolab Job Number: 15/02829 Issue Number: 1 Date: 20 May, 2015 Client: RSK Environment Helsby Spring Lodge 172 Chester Road Helsby Cheshire UK WA6 0AR Project Manager: Rachel Hagan Project Name: Mersey Gateway Project Ref: 321315 Order No: N/A Date Samples Received: 06/05/15 Date Instructions Received: 07/05/15 Date Analysis Completed: 20/05/15 Prepared by: Approved by:
Melanie Marshall Carolyn Field Laboratory Coordinator Sales Executive
Page 2 of 9
Envirolab Job Number: 15/02829 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02829/1 15/02829/2 15/02829/3
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX3 BH427A BH427B
Depth to Top 8.00 22.00 47.25
Depth To Bottom
Date Sampled 05-May-15 05-May-15 05-May-15
Sample Type Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A
pH (w)A# 7.24 7.52 7.27 pH A-T-031w
Electrical conductivity @ 20degC (w)A# 9570 17880 8350 µs/cm A-T-037w
COD (settled)A# 140 160 57 mg/l A-T-034w
BOD (settled, 5 day)A 5 12 7 mg/l A-T-048
Hardness TotalA# 1690 3710 2090 mg/l Ca
CO3
A-T-049w
Chloride (w)A# 727 5540 2040 mg/l A-T-026w
Nitrite (w)A# <0.10 <0.10 <0.10 mg/l A-T-026w
Nitrate (w) A# <0.50 <0.50 <0.50 mg/l A-T-026w
Sulphate (w)A# 3632 2008 997 mg/l A-T-026w
Cyanide (total) (w)A# 0.006 <0.005 0.112 mg/l A-T-042wTCN
Phenols - Total by HPLC (w)A <0.01 0.12 <0.01 mg/l A-T-050w
Sulphide (w)A <0.1 0.1 <0.1 mg/l A-T-S2-w
DOC (w)A# 15.5 10.1 3.3 mg/l A-T-032w
Aluminium (dissolved)A 19 <10 <10 µg/l A-T-049w
Arsenic (dissolved)A# 9870 <10 <10 µg/l A-T-025w
Boron (dissolved)A# 546 690 405 µg/l A-T-025w
Barium (dissolved)A# 68 68 339 µg/l A-T-025w
Beryllium (dissolved)A# <10 <10 <10 µg/l A-T-025w
Cadmium (dissolved)A# <10 <10 <10 µg/l A-T-025w
Calcium (dissolved)A# 573 739 678 mg/l A-T-049w
Copper (dissolved)A# <10 <10 <10 µg/l A-T-025w
Chromium (dissolved)A# <10 14 <10 µg/l A-T-025w
Chromium (hexavalent) (w)A# <0.05 <0.05 <0.05 mg/l A-T-040w
Chromium (trivalent) (w) <0.05 <0.05 <0.05 mg/l Calc
Iron (dissolved)A# 17700 4360 205 µg/l A-T-025w
Lead (dissolved)A# <10 <10 <10 µg/l A-T-025w
Manganese (dissolved)A# 3940 1880 241 µg/l A-T-025w
Magnesium (dissolved)A# 63 453 97 mg/l A-T-049w
Mercury (dissolved)A# <1.0 <1.0 <2 µg/l A-T-025w
Nickel (dissolved)A# 10 <10 <10 µg/l A-T-025w
Potassium (dissolved)A# 81 77 44 mg/l A-T-049w
Selenium (dissolved)A# <10 <10 <10 µg/l A-T-025w
Sodium (dissolved)A# 943 2610 83 mg/l A-T-049w
Page 3 of 9
Envirolab Job Number: 15/02829 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02829/1 15/02829/2 15/02829/3
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX3 BH427A BH427B
Depth to Top 8.00 22.00 47.25
Depth To Bottom
Date Sampled 05-May-15 05-May-15 05-May-15
Sample Type Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A
Strontium (dissolved)A 1060 6250 2860 µg/l A-T-025w
Vanadium (dissolved)A# 14 <10 <10 µg/l A-T-025w
Zinc (dissolved)A# <10 <10 66 µg/l A-T-025w
TPH CWG
Ali >C5-C6 (w)A# <1 3 <1 µg/l A-T-022w
Ali >C6-C8 (w)A# <1 <1 <1 µg/l A-T-022w
Ali >C8-C10 (w)A# <1 <1 <1 µg/l A-T-022w
Ali >C10-C12 (w)A# <5 <5 <5 µg/l A-T-023w
Ali >C12-C16 (w)A# <5 <5 <5 µg/l A-T-023w
Ali >C16-C21 (w)A# <5 <5 <5 µg/l A-T-023w
Ali >C21-C35 (w)A# <5 <5 <5 µg/l A-T-023w
Total Aliphatics (w)A <5 <5 <5 µg/l A-T-022+23w
Aro >C5-C7 (w)A# <1 <1 <1 µg/l A-T-022w
Aro >C7-C8 (w)A# <1 <1 <1 µg/l A-T-022w
Aro >C8-C9 (w)A# <1 <1 <1 µg/l A-T-022w
Aro >C9-C10 (w)A# <1 <1 <1 µg/l A-T-022w
Aro >C10-C12 (w)A# <5 <5 <5 µg/l A-T-023w
Aro >C12-C16 (w)A# <5 <5 <5 µg/l A-T-023w
Aro >C16-C21 (w)A# <5 <5 <5 µg/l A-T-023w
Aro >C21-C35 (w)A# <5 <5 <5 µg/l A-T-023w
Total Aromatics (w)A <5 <5 <5 µg/l A-T-022+23w
TPH (Ali & Aro) (w)A <5 <5 <5 µg/l A-T-022+23w
BTEX - Benzene (w)A# <1 <1 <1 µg/l A-T-022w
BTEX - Toluene (w)A# <1 <1 <1 µg/l A-T-022w
BTEX - Ethyl Benzene (w)A# <1 <1 <1 µg/l A-T-022w
BTEX - m & p Xylene (w)A# <1 <1 <1 µg/l A-T-022w
BTEX - o Xylene (w)A# <1 <1 <1 µg/l A-T-022w
MTBE (w)A# <1 <1 <1 µg/l A-T-022w
Page 4 of 9
Envirolab Job Number: 15/02829 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02829/1 15/02829/2 15/02829/3
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX3 BH427A BH427B
Depth to Top 8.00 22.00 47.25
Depth To Bottom
Date Sampled 05-May-15 05-May-15 05-May-15
Sample Type Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A
PAH 16MS (w)
Acenaphthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Acenaphthylene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Anthracene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(a)anthracene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(a)pyrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(b)fluoranthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(ghi)perylene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(k)fluoranthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Chrysene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Dibenzo(ah)anthracene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Fluoranthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Fluorene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Indeno(123-cd)pyrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Naphthalene (w)A# 0.13 <0.01 <0.01 µg/l A-T-019w
Phenanthrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Pyrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
PAH (total 16) (w)A# 0.13 <0.01 <0.01 µg/l A-T-019w
Page 5 of 9
Envirolab Job Number: 15/02829 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02829/1 15/02829/2 15/02829/3
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX3 BH427A BH427B
Depth to Top 8.00 22.00 47.25
Depth To Bottom
Date Sampled 05-May-15 05-May-15 05-May-15
Sample Type Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A
SVOC (w)
2,4,5-TrichlorophenolA <1 <1 <1 µg/l A-T-052w
2,4,6-TrichlorophenolA <1 <1 <1 µg/l A-T-052w
2,4-DichlorophenolA <1 <1 <1 µg/l A-T-052w
2,4-DimethylphenolA <1 <1 <1 µg/l A-T-052w
2,4-DinitrotolueneA <1 <1 <1 µg/l A-T-052w
2,6-DinitrotolueneA <1 <1 <1 µg/l A-T-052w
2-ChloronaphthaleneA <1 <1 <1 µg/l A-T-052w
2-ChlorophenolA <1 <1 <1 µg/l A-T-052w
2-MethylnaphthaleneA <1 <1 <1 µg/l A-T-052w
2-MethylphenolA <1 <1 <1 µg/l A-T-052w
2-NitrophenolA <1 <1 <1 µg/l A-T-052w
4-Bromophenyl phenyl etherA <1 <1 <1 µg/l A-T-052w
4-Chloro-3-methylphenolA <1 <1 <1 µg/l A-T-052w
Bis(2-chloroisopropyl)etherA <1 <1 <1 µg/l A-T-052w
2,4-DinitrophenolA <1 <1 <1 µg/l A-T-052w
4,6-Dinitro-2-methylphenolA <1 <1 <1 µg/l A-T-052w
4-MethylphenolA <1 <1 <1 µg/l A-T-052w
4-NitrophenolA <1 <1 <1 µg/l A-T-052w
Acenaphthene A <1 <1 <1 µg/l A-T-052w
AcenaphthyleneA <1 <1 <1 µg/l A-T-052w
Anthracene A <1 <1 <1 µg/l A-T-052w
Bis(2-chloroethyl)etherA <1 <1 <1 µg/l A-T-052w
Bis(2-chloroethoxy)methaneA <1 <1 <1 µg/l A-T-052w
Bis(2-ethylhexyl)phthalateA <2 <2 <2 µg/l A-T-052w
Benzo(a)anthraceneA <1 <1 <1 µg/l A-T-052w
Butylbenzyl phthalate A <1 <1 <1 µg/l A-T-052w
Benzo(b)fluorantheneA <1 <1 <1 µg/l A-T-052w
Benzo(k)fluorantheneA <1 <1 <1 µg/l A-T-052w
Benzo(a)pyrene A <1 <1 <1 µg/l A-T-052w
Benzo(ghi)peryleneA <1 <1 <1 µg/l A-T-052w
CarbazoleA <1 <1 <1 µg/l A-T-052w
ChryseneA <1 <1 <1 µg/l A-T-052w
Page 6 of 9
Envirolab Job Number: 15/02829 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02829/1 15/02829/2 15/02829/3
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX3 BH427A BH427B
Depth to Top 8.00 22.00 47.25
Depth To Bottom
Date Sampled 05-May-15 05-May-15 05-May-15
Sample Type Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A
DibenzofuranA <1 <1 <1 µg/l A-T-052w
n-DibutylphthalateA <1 <1 <1 µg/l A-T-052w
n-DioctylphthalateA <5 <5 <5 µg/l A-T-052w
n-Nitroso-n-dipropylamineA <1 <1 <1 µg/l A-T-052w
Diethyl phthalateA <1 <1 <1 µg/l A-T-052w
Dimethyl phthalateA <1 <1 <1 µg/l A-T-052w
Dibenzo(ah)anthraceneA <1 <1 <1 µg/l A-T-052w
Fluorene A <1 <1 <1 µg/l A-T-052w
FluorantheneA <1 <1 <1 µg/l A-T-052w
HexachlorobenzeneA <1 <1 <1 µg/l A-T-052w
PentachlorophenolA <1 <1 <1 µg/l A-T-052w
Phenol A <1 7 <1 µg/l A-T-052w
HexachloroethaneA 21 <1 <1 µg/l A-T-052w
NitrobenzeneA <1 <1 <1 µg/l A-T-052w
Naphthalene A <1 <1 <1 µg/l A-T-052w
IsophoroneA <1 <1 <1 µg/l A-T-052w
HexachlorocyclopentadieneA <1 <1 <1 µg/l A-T-052w
Phenanthrene A <1 <1 <1 µg/l A-T-052w
Pyrene A <1 <1 <1 µg/l A-T-052w
Indeno(1,2,3-cd)pyreneA <1 <1 <1 µg/l A-T-052w
PeryleneA <1 <1 <1 µg/l A-T-052w
Page 7 of 9
Envirolab Job Number: 15/02829 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02829/1 15/02829/2 15/02829/3
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX3 BH427A BH427B
Depth to Top 8.00 22.00 47.25
Depth To Bottom
Date Sampled 05-May-15 05-May-15 05-May-15
Sample Type Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A
VOC (w)
DichlorodifluoromethaneA# <1 <1 <1 µg/l A-T-006w
ChloromethaneA# <1 <1 <1 µg/l A-T-006w
Vinyl ChlorideA# <1 <1 <1 µg/l A-T-006w
BromomethaneA# <1 <1 <1 µg/l A-T-006w
ChloroethaneA# <1 <1 <1 µg/l A-T-006w
TrichlorofluoromethaneA# <1 <1 <1 µg/l A-T-006w
trans 1,2-DichloroetheneA# <1 <1 <1 µg/l A-T-006w
DichloromethaneA <5 <5 39 µg/l A-T-006w
Carbon DisulphideA# 134 <1 <1 µg/l A-T-006w
1,1-DichloroetheneA# <1 1 <1 µg/l A-T-006w
1,1-DichloroethaneA# <1 <1 <1 µg/l A-T-006w
cis 1,2-DichloroetheneA# 3 1 <1 µg/l A-T-006w
BromochloromethaneA# <5 <5 <5 µg/l A-T-006w
ChloroformA# 555 <25 <25 µg/l A-T-006w
2,2-DichloropropaneA# <1 <1 <1 µg/l A-T-006w
1,2-DichloroethaneA# <2 <2 4 µg/l A-T-006w
1,1,1-TrichloroethaneA# <1 <1 <1 µg/l A-T-006w
1,1-DichloropropeneA# 16 <1 <1 µg/l A-T-006w
Benzene A# <1 <1 <1 µg/l A-T-006w
Carbon TetrachlorideA# 2410 <1 8 µg/l A-T-006w
DibromomethaneA# <1 <1 <1 µg/l A-T-006w
1,2-DichloropropaneA# <1 <1 <1 µg/l A-T-006w
BromodichloromethaneA# <10 <10 <10 µg/l A-T-006w
TrichloroetheneA# 3 <1 1 µg/l A-T-006w
cis 1,3-DichloropropeneA# <1 <1 <1 µg/l A-T-006w
trans 1,3-DichloropropeneA# <1 <1 <1 µg/l A-T-006w
1,1,2-TrichloroethaneA# <1 <1 15 µg/l A-T-006w
Toluene A# <1 1 <1 µg/l A-T-006w
1,3-DichloropropaneA# <1 <1 <1 µg/l A-T-006w
DibromochloromethaneA# <3 <3 <3 µg/l A-T-006w
1,2-DibromoethaneA# <1 <1 <1 µg/l A-T-006w
TetrachloroetheneA# 42 <1 <1 µg/l A-T-006w
Page 8 of 9
Envirolab Job Number: 15/02829 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02829/1 15/02829/2 15/02829/3
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX3 BH427A BH427B
Depth to Top 8.00 22.00 47.25
Depth To Bottom
Date Sampled 05-May-15 05-May-15 05-May-15
Sample Type Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A
1,1,1,2-TetrachloroethaneA <1 <1 <1 µg/l A-T-006w
ChlorobenzeneA# 5 <1 <1 µg/l A-T-006w
EthylbenzeneA# <1 <1 <1 µg/l A-T-006w
m & p XyleneA# <1 <1 <1 µg/l A-T-006w
BromoformA# <1 <1 <1 µg/l A-T-006w
StyreneA# <1 <1 <1 µg/l A-T-006w
1,1,2,2-TetrachloroethaneA <1 <1 <1 µg/l A-T-006w
o-XyleneA# <1 <1 <1 µg/l A-T-006w
1,2,3-TrichloropropaneA# <1 <1 <1 µg/l A-T-006w
IsopropylbenzeneA# <1 <1 <1 µg/l A-T-006w
BromobenzeneA# <1 <1 <1 µg/l A-T-006w
2-ChlorotolueneA# <1 <1 <1 µg/l A-T-006w
n-propylbenzeneA# <1 <1 <1 µg/l A-T-006w
4-ChlorotolueneA# <1 <1 <1 µg/l A-T-006w
1,2,4-TrimethylbenzeneA# <1 <1 <1 µg/l A-T-006w
4-IsopropyltolueneA# <1 <1 <1 µg/l A-T-006w
1,3,5-TrimethylbenzeneA# <1 <1 <1 µg/l A-T-006w
1,2-DichlorobenzeneA# <1 <1 <1 µg/l A-T-006w
1,4-DichlorobenzeneA# <1 <1 <1 µg/l A-T-006w
sec-ButylbenzeneA# <1 <1 <1 µg/l A-T-006w
tert-ButylbenzeneA# <2 <2 <2 µg/l A-T-006w
1,3-DichlorobenzeneA# <1 <1 <1 µg/l A-T-006w
n-butylbenzeneA# <1 <1 <1 µg/l A-T-006w
1,2-Dibromo-3-chloropropaneA# <2 <2 <2 µg/l A-T-006w
1,2,4-TrichlorobenzeneA# <3 <3 <3 µg/l A-T-006w
1,2,3-TrichlorobenzeneA# <3 <3 <3 µg/l A-T-006w
HexachlorobutadieneA# <1 <1 <1 µg/l A-T-006w
Page 9 of 9
REPORT NOTES
Notes - Soil chemical analysis All results are reported as dry weight (<40°C). For samples with Matrix Codes 1 - 6 natural stones >10mm are removed or excluded from the sample prior to analysis and reported results corrected to a whole sample basis. For samples with Matrix Code 7 the whole sample is dried and crushed prior to analysis. Notes - General
This report shall not be reproduced, except in full, without written approval from Envirolab. Subscript "A" indicates analysis performed on the sample as received. "D" indicates analysis performed on the dried sample, crushed to pass a 2mm sieve, unless asbestos is found to be present in which case all analysis is performed on the sample as received. All analysis is performed on the dried and crushed sample for samples with Matrix Code 7 and this supercedes any "A" subscripts. All analysis is performed on the sample as received for soil samples from outside the European Union and this supercedes any "D" subscripts. Superscript "M" indicates method accredited to MCERTS. If results are in italic font they are associated with an AQC failure. These are not accredited and are unreliable. A deviating samples report is appended and will indicate if samples or tests have been found to be deviating. Any test results affected may not be an accurate record of the concentration at the time of sampling and, as a result, may be invalid. TPH analysis of water by method A-T-007 Free and visible oils are excluded from the sample used for analysis so that the reported result represents the dissolved phase only. Asbestos in soil Asbestos in soil analysis is performed on a dried aliquot of the submitted sample and cannot guarantee to identify asbestos if present as discrete fibres/fragments. Stones etc. are not removed from the sample prior to analysis. Quantification of asbestos is a 3 stage process including visual identification, hand picking and weighing and fibre counting by sedimentation/phase contrast optical microscopy if required. If asbestos is identified a being present but is not in a form that is suitable for analysis by hand picking and weighing (normally if the asbestos is present as free fibres) quantification by sedimentation is performed. Where ACMs are found a percentage asbestos is assigned to each with reference to 'HSG264, Asbestos: The survey guide' and the calculated asbestos content is expressed as a percentage of the dried soil sample aliquot used. Predominant Matrix Codes: 1 = SAND, 2 = LOAM, 3 = CLAY, 4 = LOAM/SAND, 5 = SAND/CLAY, 6 = CLAY/LOAM, 7 = OTHER. Samples with Matrix Code 7 are not predominantly a SAND/LOAM/CLAY mix and are not covered by our BSEN 17025 or MCERTS accreditations. Secondary Matrix Codes: A = contains stones, B = contains construction rubble, C = contains visible hydrocarbons, D = contains glass/metal, E = contains roots/twigs. IS indicates Insufficient sample for analysis. NDP indicates No Determination Possible. NAD indicates No Asbestos Detected. N/A indicates Not Applicable. Superscript # indicates method accredited to ISO 17025. Analytical results reflect the quality of the sample at the time of analysis only. Opinions and interpretations expressed are outside the scope of our accreditation. Please contact us if you need any further information.
Page 1 of 9
Units 7 & 8 Sandpits Business Park Mottram Road, Hyde, Cheshire, SK14 3AR
FINAL ANALYTICAL TEST REPORT
Envirolab Job Number: 15/02804 Issue Number: 1 Date: 12 May, 2015 Client: RSK Environment Helsby Spring Lodge 172 Chester Road Helsby Cheshire UK WA6 0AR Project Manager: Rachel Hagan Project Name: Mersey Gateway Project Ref: 321315 Order No: N/A Date Samples Received: 05/05/15 Date Instructions Received: 06/05/15 Date Analysis Completed: 11/05/15 Prepared by: Approved by:
Melanie Marshall Carolyn Field Laboratory Coordinator Sales Executive
Page 2 of 9
Envirolab Job Number: 15/02804 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02804/1 15/02804/2
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX4 BHXX5
Depth to Top 9.00 9.00
Depth To Bottom
Date Sampled 05-May-15 05-May-15
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
pH (w)A# 7.22 7.68 pH A-T-031w
Electrical conductivity @ 20degC (w)A# 8640 1913 µs/cm A-T-037w
COD (settled)A# 130 27 mg/l A-T-034w
BOD (settled, 5 day)A <1 <1 mg/l A-T-048
Hardness TotalA# 2100 686 mg/l Ca
CO3
A-T-049w
Chloride (w)A# 698 170.03 mg/l A-T-026w
Nitrite (w)A# 0.13 0.73 mg/l A-T-026w
Nitrate (w) A# <0.50 0.80 mg/l A-T-026w
Sulphate (w)A# 3546 801 mg/l A-T-026w
Cyanide (total) (w)A# <0.005 <0.005 mg/l A-T-042wTCN
Phenols - Total by HPLC (w)A 0.03 <0.01 mg/l A-T-050w
Sulphide (w)A 0.1 <0.1 mg/l A-T-S2-w
DOC (w)A# 19.1 7.6 mg/l A-T-032w
Aluminium (dissolved)A <10 <10 µg/l A-T-049w
Arsenic (dissolved)A# 1370 73 µg/l A-T-025w
Boron (dissolved)A# 1230 138 µg/l A-T-025w
Barium (dissolved)A# 106 66 µg/l A-T-025w
Beryllium (dissolved)A# <1 <1 µg/l A-T-025w
Cadmium (dissolved)A# <1 <1 µg/l A-T-025w
Calcium (dissolved)A# 653 222 mg/l A-T-049w
Copper (dissolved)A# <1 <1 µg/l A-T-025w
Chromium (dissolved)A# 7 1 µg/l A-T-025w
Chromium (hexavalent) (w)A# <0.05 <0.05 mg/l A-T-040w
Chromium (trivalent) (w) <0.05 <0.05 mg/l Calc
Iron (dissolved)A# 7007 299 µg/l A-T-025w
Lead (dissolved)A# <1 <1 µg/l A-T-025w
Manganese (dissolved)A# 8926 503 µg/l A-T-025w
Magnesium (dissolved)A# 114 32 mg/l A-T-049w
Mercury (dissolved)A# <0.1 <0.1 µg/l A-T-025w
Nickel (dissolved)A# 8 6 µg/l A-T-025w
Potassium (dissolved)A# 84 13 mg/l A-T-049w
Selenium (dissolved)A# 8 12 µg/l A-T-025w
Sodium (dissolved)A# 660 158 mg/l A-T-049w
Page 3 of 9
Envirolab Job Number: 15/02804 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02804/1 15/02804/2
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX4 BHXX5
Depth to Top 9.00 9.00
Depth To Bottom
Date Sampled 05-May-15 05-May-15
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
Strontium (dissolved)A 1680 2160 µg/l A-T-025w
Vanadium (dissolved)A# 3 <1 µg/l A-T-025w
Zinc (dissolved)A# 15 3 µg/l A-T-025w
TPH CWG
Ali >C5-C6 (w)A# <1 <1 µg/l A-T-022w
Ali >C6-C8 (w)A# <1 <1 µg/l A-T-022w
Ali >C8-C10 (w)A# <1 <1 µg/l A-T-022w
Ali >C10-C12 (w)A# <5 <5 µg/l A-T-023w
Ali >C12-C16 (w)A# <5 <5 µg/l A-T-023w
Ali >C16-C21 (w)A# 15 <5 µg/l A-T-023w
Ali >C21-C35 (w)A# 14 <5 µg/l A-T-023w
Total Aliphatics (w)A 28 <5 µg/l A-T-022+23w
Aro >C5-C7 (w)A# <1 <1 µg/l A-T-022w
Aro >C7-C8 (w)A# 1 <1 µg/l A-T-022w
Aro >C8-C9 (w)A# <1 <1 µg/l A-T-022w
Aro >C9-C10 (w)A# <1 <1 µg/l A-T-022w
Aro >C10-C12 (w)A# <5 <5 µg/l A-T-023w
Aro >C12-C16 (w)A# <5 <5 µg/l A-T-023w
Aro >C16-C21 (w)A# <5 <5 µg/l A-T-023w
Aro >C21-C35 (w)A# <5 <5 µg/l A-T-023w
Total Aromatics (w)A <5 <5 µg/l A-T-022+23w
TPH (Ali & Aro) (w)A 29 <5 µg/l A-T-022+23w
BTEX - Benzene (w)A# <1 <1 µg/l A-T-022w
BTEX - Toluene (w)A# 1 <1 µg/l A-T-022w
BTEX - Ethyl Benzene (w)A# <1 <1 µg/l A-T-022w
BTEX - m & p Xylene (w)A# <1 <1 µg/l A-T-022w
BTEX - o Xylene (w)A# <1 <1 µg/l A-T-022w
MTBE (w)A# <1 <1 µg/l A-T-022w
Page 4 of 9
Envirolab Job Number: 15/02804 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02804/1 15/02804/2
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX4 BHXX5
Depth to Top 9.00 9.00
Depth To Bottom
Date Sampled 05-May-15 05-May-15
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
PAH 16MS (w)
Acenaphthene (w)A# 0.08 0.05 µg/l A-T-019w
Acenaphthylene (w)A# <0.01 <0.01 µg/l A-T-019w
Anthracene (w)A# <0.01 <0.01 µg/l A-T-019w
Benzo(a)anthracene (w)A# <0.01 <0.01 µg/l A-T-019w
Benzo(a)pyrene (w)A# <0.01 <0.01 µg/l A-T-019w
Benzo(b)fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w
Benzo(ghi)perylene (w)A# <0.01 <0.01 µg/l A-T-019w
Benzo(k)fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w
Chrysene (w)A# <0.01 <0.01 µg/l A-T-019w
Dibenzo(ah)anthracene (w)A# <0.01 <0.01 µg/l A-T-019w
Fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w
Fluorene (w)A# <0.01 <0.01 µg/l A-T-019w
Indeno(123-cd)pyrene (w)A# <0.01 <0.01 µg/l A-T-019w
Naphthalene (w)A# 0.06 <0.01 µg/l A-T-019w
Phenanthrene (w)A# 0.01 <0.01 µg/l A-T-019w
Pyrene (w)A# <0.01 <0.01 µg/l A-T-019w
PAH (total 16) (w)A# 0.15 0.05 µg/l A-T-019w
Page 5 of 9
Envirolab Job Number: 15/02804 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02804/1 15/02804/2
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX4 BHXX5
Depth to Top 9.00 9.00
Depth To Bottom
Date Sampled 05-May-15 05-May-15
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
SVOC (w)
2,4,5-TrichlorophenolA <1 <1 µg/l A-T-052w
2,4,6-TrichlorophenolA <1 <1 µg/l A-T-052w
2,4-DichlorophenolA <1 <1 µg/l A-T-052w
2,4-DimethylphenolA <1 <1 µg/l A-T-052w
2,4-DinitrotolueneA <1 <1 µg/l A-T-052w
2,6-DinitrotolueneA <1 <1 µg/l A-T-052w
2-ChloronaphthaleneA <1 <1 µg/l A-T-052w
2-ChlorophenolA <1 <1 µg/l A-T-052w
2-MethylnaphthaleneA <1 <1 µg/l A-T-052w
2-MethylphenolA <1 <1 µg/l A-T-052w
2-NitrophenolA <1 <1 µg/l A-T-052w
4-Bromophenyl phenyl etherA <1 <1 µg/l A-T-052w
4-Chloro-3-methylphenolA <1 <1 µg/l A-T-052w
Bis(2-chloroisopropyl)etherA <1 <1 µg/l A-T-052w
2,4-DinitrophenolA <1 <1 µg/l A-T-052w
4,6-Dinitro-2-methylphenolA <1 <1 µg/l A-T-052w
4-MethylphenolA <1 <1 µg/l A-T-052w
4-NitrophenolA <1 <1 µg/l A-T-052w
Acenaphthene A <1 <1 µg/l A-T-052w
AcenaphthyleneA <1 <1 µg/l A-T-052w
Anthracene A <1 <1 µg/l A-T-052w
Bis(2-chloroethyl)etherA <1 <1 µg/l A-T-052w
Bis(2-chloroethoxy)methaneA <1 <1 µg/l A-T-052w
Bis(2-ethylhexyl)phthalateA <2 <2 µg/l A-T-052w
Benzo(a)anthraceneA <1 <1 µg/l A-T-052w
Butylbenzyl phthalate A <1 <1 µg/l A-T-052w
Benzo(b)fluorantheneA <1 <1 µg/l A-T-052w
Benzo(k)fluorantheneA <1 <1 µg/l A-T-052w
Benzo(a)pyrene A <1 <1 µg/l A-T-052w
Benzo(ghi)peryleneA <1 <1 µg/l A-T-052w
CarbazoleA <1 <1 µg/l A-T-052w
ChryseneA <1 <1 µg/l A-T-052w
Page 6 of 9
Envirolab Job Number: 15/02804 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02804/1 15/02804/2
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX4 BHXX5
Depth to Top 9.00 9.00
Depth To Bottom
Date Sampled 05-May-15 05-May-15
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
DibenzofuranA <1 <1 µg/l A-T-052w
n-DibutylphthalateA <1 <1 µg/l A-T-052w
n-DioctylphthalateA <5 <5 µg/l A-T-052w
n-Nitroso-n-dipropylamineA <1 <1 µg/l A-T-052w
Diethyl phthalateA <1 <1 µg/l A-T-052w
Dimethyl phthalateA <1 <1 µg/l A-T-052w
Dibenzo(ah)anthraceneA <1 <1 µg/l A-T-052w
Fluorene A <1 <1 µg/l A-T-052w
FluorantheneA <1 <1 µg/l A-T-052w
HexachlorobenzeneA <1 <1 µg/l A-T-052w
PentachlorophenolA <1 <1 µg/l A-T-052w
Phenol A 1 1 µg/l A-T-052w
HexachloroethaneA <1 <1 µg/l A-T-052w
NitrobenzeneA <1 <1 µg/l A-T-052w
Naphthalene A <1 <1 µg/l A-T-052w
IsophoroneA <1 <1 µg/l A-T-052w
HexachlorocyclopentadieneA <1 <1 µg/l A-T-052w
Phenanthrene A <1 <1 µg/l A-T-052w
Pyrene A <1 <1 µg/l A-T-052w
Indeno(1,2,3-cd)pyreneA <1 <1 µg/l A-T-052w
PeryleneA <1 <1 µg/l A-T-052w
Page 7 of 9
Envirolab Job Number: 15/02804 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02804/1 15/02804/2
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX4 BHXX5
Depth to Top 9.00 9.00
Depth To Bottom
Date Sampled 05-May-15 05-May-15
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
VOC (w)
DichlorodifluoromethaneA# <1 <1 µg/l A-T-006w
ChloromethaneA# 27 <1 µg/l A-T-006w
Vinyl ChlorideA# <1 <1 µg/l A-T-006w
BromomethaneA# <1 <1 µg/l A-T-006w
ChloroethaneA# <1 <1 µg/l A-T-006w
TrichlorofluoromethaneA# <1 <1 µg/l A-T-006w
trans 1,2-DichloroetheneA# <1 <1 µg/l A-T-006w
DichloromethaneA 54 <5 µg/l A-T-006w
Carbon DisulphideA# 1486 <1 µg/l A-T-006w
1,1-DichloroetheneA# 2 <1 µg/l A-T-006w
1,1-DichloroethaneA# <1 <1 µg/l A-T-006w
cis 1,2-DichloroetheneA# 2 <1 µg/l A-T-006w
BromochloromethaneA# <5 <5 µg/l A-T-006w
ChloroformA# >3303 587 µg/l A-T-006w
2,2-DichloropropaneA# <1 <1 µg/l A-T-006w
1,2-DichloroethaneA# <2 <2 µg/l A-T-006w
1,1,1-TrichloroethaneA# 2 <1 µg/l A-T-006w
1,1-DichloropropeneA# <1 <1 µg/l A-T-006w
Benzene A# <1 <1 µg/l A-T-006w
Carbon TetrachlorideA# >6542 107 µg/l A-T-006w
DibromomethaneA# <1 <1 µg/l A-T-006w
1,2-DichloropropaneA# <1 <1 µg/l A-T-006w
BromodichloromethaneA# <10 <10 µg/l A-T-006w
TrichloroetheneA# 6 <1 µg/l A-T-006w
cis 1,3-DichloropropeneA# <1 <1 µg/l A-T-006w
trans 1,3-DichloropropeneA# <1 <1 µg/l A-T-006w
1,1,2-TrichloroethaneA# <1 <1 µg/l A-T-006w
Toluene A# 1 <1 µg/l A-T-006w
1,3-DichloropropaneA# <1 <1 µg/l A-T-006w
DibromochloromethaneA# <3 <3 µg/l A-T-006w
1,2-DibromoethaneA# <1 <1 µg/l A-T-006w
TetrachloroetheneA# 53 2 µg/l A-T-006w
Page 8 of 9
Envirolab Job Number: 15/02804 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02804/1 15/02804/2
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX4 BHXX5
Depth to Top 9.00 9.00
Depth To Bottom
Date Sampled 05-May-15 05-May-15
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
1,1,1,2-TetrachloroethaneA <1 <1 µg/l A-T-006w
ChlorobenzeneA# <1 <1 µg/l A-T-006w
EthylbenzeneA# <1 <1 µg/l A-T-006w
m & p XyleneA# <1 <1 µg/l A-T-006w
BromoformA# <1 <1 µg/l A-T-006w
StyreneA# <1 <1 µg/l A-T-006w
1,1,2,2-TetrachloroethaneA 5 <1 µg/l A-T-006w
o-XyleneA# <1 <1 µg/l A-T-006w
1,2,3-TrichloropropaneA# <1 <1 µg/l A-T-006w
IsopropylbenzeneA# <1 <1 µg/l A-T-006w
BromobenzeneA# <1 <1 µg/l A-T-006w
2-ChlorotolueneA# <1 <1 µg/l A-T-006w
n-propylbenzeneA# <1 <1 µg/l A-T-006w
4-ChlorotolueneA# <1 <1 µg/l A-T-006w
1,2,4-TrimethylbenzeneA# <1 <1 µg/l A-T-006w
4-IsopropyltolueneA# <1 <1 µg/l A-T-006w
1,3,5-TrimethylbenzeneA# <1 <1 µg/l A-T-006w
1,2-DichlorobenzeneA# <1 <1 µg/l A-T-006w
1,4-DichlorobenzeneA# <1 <1 µg/l A-T-006w
sec-ButylbenzeneA# <1 <1 µg/l A-T-006w
tert-ButylbenzeneA# <2 <2 µg/l A-T-006w
1,3-DichlorobenzeneA# <1 <1 µg/l A-T-006w
n-butylbenzeneA# <1 <1 µg/l A-T-006w
1,2-Dibromo-3-chloropropaneA# <2 <2 µg/l A-T-006w
1,2,4-TrichlorobenzeneA# <3 <3 µg/l A-T-006w
1,2,3-TrichlorobenzeneA# <3 <3 µg/l A-T-006w
HexachlorobutadieneA# <1 <1 µg/l A-T-006w
Page 9 of 9
REPORT NOTES
Notes - Soil chemical analysis All results are reported as dry weight (<40°C). For samples with Matrix Codes 1 - 6 natural stones >10mm are removed or excluded from the sample prior to analysis and reported results corrected to a whole sample basis. For samples with Matrix Code 7 the whole sample is dried and crushed prior to analysis. Notes - General
This report shall not be reproduced, except in full, without written approval from Envirolab. Subscript "A" indicates analysis performed on the sample as received. "D" indicates analysis performed on the dried sample, crushed to pass a 2mm sieve, unless asbestos is found to be present in which case all analysis is performed on the sample as received. All analysis is performed on the dried and crushed sample for samples with Matrix Code 7 and this supercedes any "A" subscripts. All analysis is performed on the sample as received for soil samples from outside the European Union and this supercedes any "D" subscripts. Superscript "M" indicates method accredited to MCERTS. If results are in italic font they are associated with an AQC failure. These are not accredited and are unreliable. A deviating samples report is appended and will indicate if samples or tests have been found to be deviating. Any test results affected may not be an accurate record of the concentration at the time of sampling and, as a result, may be invalid. TPH analysis of water by method A-T-007 Free and visible oils are excluded from the sample used for analysis so that the reported result represents the dissolved phase only. Asbestos in soil Asbestos in soil analysis is performed on a dried aliquot of the submitted sample and cannot guarantee to identify asbestos if present as discrete fibres/fragments. Stones etc. are not removed from the sample prior to analysis. Quantification of asbestos is a 3 stage process including visual identification, hand picking and weighing and fibre counting by sedimentation/phase contrast optical microscopy if required. If asbestos is identified a being present but is not in a form that is suitable for analysis by hand picking and weighing (normally if the asbestos is present as free fibres) quantification by sedimentation is performed. Where ACMs are found a percentage asbestos is assigned to each with reference to 'HSG264, Asbestos: The survey guide' and the calculated asbestos content is expressed as a percentage of the dried soil sample aliquot used. Predominant Matrix Codes: 1 = SAND, 2 = LOAM, 3 = CLAY, 4 = LOAM/SAND, 5 = SAND/CLAY, 6 = CLAY/LOAM, 7 = OTHER. Samples with Matrix Code 7 are not predominantly a SAND/LOAM/CLAY mix and are not covered by our BSEN 17025 or MCERTS accreditations. Secondary Matrix Codes: A = contains stones, B = contains construction rubble, C = contains visible hydrocarbons, D = contains glass/metal, E = contains roots/twigs. IS indicates Insufficient sample for analysis. NDP indicates No Determination Possible. NAD indicates No Asbestos Detected. N/A indicates Not Applicable. Superscript # indicates method accredited to ISO 17025. Analytical results reflect the quality of the sample at the time of analysis only. Opinions and interpretations expressed are outside the scope of our accreditation. Please contact us if you need any further information.
Page 1 of 10
Units 7 & 8 Sandpits Business Park Mottram Road, Hyde, Cheshire, SK14 3AR
FINAL ANALYTICAL TEST REPORT
Envirolab Job Number: 15/02720 Issue Number: 1 Date: 14 May, 2015 Client: RSK Environment Helsby Spring Lodge 172 Chester Road Helsby Cheshire UK WA6 0AR Project Manager: Rachel Hagan Project Name: Mersey Gateway Project Ref: 321315 Order No: N/A Date Samples Received: 30/04/15 Date Instructions Received: 01/05/15 Date Analysis Completed: 13/05/15 Prepared by: Approved by:
Gill Scott Iain Haslock Laboratory Manager Analytical Consultant
Page 2 of 10
Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX5 BHXX4 BH410 BHXX3
Depth to Top 9.00 9.00 13.20 8.00
Depth To Bottom
Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15
Sample Type Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A
pH (w)A# 7.38 7.11 8.49 - pH A-T-031w
Electrical conductivity @ 20degC (w)A# 6300 9050 20200 - µs/cm A-T-037w
COD (settled)A# 87 140 230 - mg/l A-T-034w
BOD (settled, 5 day)A <1 <1 31 - mg/l A-T-048
Hardness TotalA# 1703 2247 2080 - mg/l Ca
CO3
A-T-049w
Chloride (w)A# 521.51 662.62 6445.05 - mg/l A-T-026w
Nitrite (w)A# <0.10 <0.10 <0.10 - mg/l A-T-026w
Nitrate (w) A# <0.50 0.68 <0.50 - mg/l A-T-026w
Sulphate (w)A# 2168 3475 1611 - mg/l A-T-026w
Cyanide (total) (w)A# <0.005 <0.005 1.209 - mg/l A-T-042wTCN
Phenols - Total by HPLC (w)A 0.03 0.11 0.03 - mg/l A-T-050w
Sulphide (w)A <0.1 0.2 10.6 - mg/l A-T-S2-w
DOC (w)A# 10.7 13.0 10.1 - mg/l A-T-032w
Aluminium (dissolved)A <10 <10 24 - µg/l A-T-049w
Arsenic (dissolved)A# 14 2400 1730 - µg/l A-T-025w
Boron (dissolved)A# 959 1180 1730 - µg/l A-T-025w
Barium (dissolved)A# 141 96 63 - µg/l A-T-025w
Beryllium (dissolved)A# <1 <1 <1 - µg/l A-T-025w
Cadmium (dissolved)A# <1 <1 <1 - µg/l A-T-025w
Calcium (dissolved)A# 545 666 278 - mg/l A-T-049w
Copper (dissolved)A# <1 <1 1 - µg/l A-T-025w
Chromium (dissolved)A# <1 2 6 - µg/l A-T-025w
Chromium (hexavalent) (w)A# <0.05 <0.05 <0.05 - mg/l A-T-040w
Chromium (trivalent) (w) <0.05 <0.05 <0.05 - mg/l Calc
Iron (dissolved)A# 8114 12370 623 - µg/l A-T-025w
Lead (dissolved)A# <1 <1 <1 - µg/l A-T-025w
Manganese (dissolved)A# 6537 7412 834 - µg/l A-T-025w
Magnesium (dissolved)A# 83 142 336 - mg/l A-T-049w
Mercury (dissolved)A# 0.4 0.3 <0.1 - µg/l A-T-025w
Nickel (dissolved)A# 14 8 4 - µg/l A-T-025w
Potassium (dissolved)A# 61 105 123 - mg/l A-T-049w
Selenium (dissolved)A# 8 6 4 - µg/l A-T-025w
Sodium (dissolved)A# 473 681 3900 - mg/l A-T-049w
Page 3 of 10
Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX5 BHXX4 BH410 BHXX3
Depth to Top 9.00 9.00 13.20 8.00
Depth To Bottom
Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15
Sample Type Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A
Strontium (dissolved)A 1630 1860 2270 - µg/l A-T-025w
Vanadium (dissolved)A# <1 1 25 - µg/l A-T-025w
Zinc (dissolved)A# 14 21 4 - µg/l A-T-025w
Page 4 of 10
Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX5 BHXX4 BH410 BHXX3
Depth to Top 9.00 9.00 13.20 8.00
Depth To Bottom
Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15
Sample Type Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A
TPH CWG
Ali >C5-C6 (w)A# <1 <1 <1 - µg/l A-T-022w
Ali >C6-C8 (w)A# <1 <1 <1 - µg/l A-T-022w
Ali >C8-C10 (w)A# 1 1 <1 - µg/l A-T-022w
Ali >C10-C12 (w)A# <5 8 <5 - µg/l A-T-023w
Ali >C12-C16 (w)A# <5 <5 <5 - µg/l A-T-023w
Ali >C16-C21 (w)A# <5 <5 <5 - µg/l A-T-023w
Ali >C21-C35 (w)A# <5 <5 <5 - µg/l A-T-023w
Total Aliphatics (w)A <5 9 <5 - µg/l A-T-022+23w
Aro >C5-C7 (w)A# <1 <1 <1 - µg/l A-T-022w
Aro >C7-C8 (w)A# <1 <1 <1 - µg/l A-T-022w
Aro >C8-C9 (w)A# <1 <1 <1 - µg/l A-T-022w
Aro >C9-C10 (w)A# <1 <1 <1 - µg/l A-T-022w
Aro >C10-C12 (w)A# <5 <5 <5 - µg/l A-T-023w
Aro >C12-C16 (w)A# <5 <5 <5 - µg/l A-T-023w
Aro >C16-C21 (w)A# <5 <5 <5 - µg/l A-T-023w
Aro >C21-C35 (w)A# <5 <5 <5 - µg/l A-T-023w
Total Aromatics (w)A <5 <5 <5 - µg/l A-T-022+23w
TPH (Ali & Aro) (w)A <5 9 <5 - µg/l A-T-022+23w
BTEX - Benzene (w)A# <1 <1 <1 - µg/l A-T-022w
BTEX - Toluene (w)A# <1 <1 <1 - µg/l A-T-022w
BTEX - Ethyl Benzene (w)A# <1 <1 <1 - µg/l A-T-022w
BTEX - m & p Xylene (w)A# <1 <1 <1 - µg/l A-T-022w
BTEX - o Xylene (w)A# <1 <1 <1 - µg/l A-T-022w
MTBE (w)A# <1 <1 <1 - µg/l A-T-022w
Page 5 of 10
Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX5 BHXX4 BH410 BHXX3
Depth to Top 9.00 9.00 13.20 8.00
Depth To Bottom
Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15
Sample Type Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A
PAH 16MS (w)
Acenaphthene (w)A# 0.01 0.09 <0.01 - µg/l A-T-019w
Acenaphthylene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w
Anthracene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w
Benzo(a)anthracene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w
Benzo(a)pyrene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w
Benzo(b)fluoranthene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w
Benzo(ghi)perylene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w
Benzo(k)fluoranthene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w
Chrysene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w
Dibenzo(ah)anthracene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w
Fluoranthene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w
Fluorene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w
Indeno(123-cd)pyrene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w
Naphthalene (w)A# 0.02 0.06 <0.01 - µg/l A-T-019w
Phenanthrene (w)A# <0.01 0.01 <0.01 - µg/l A-T-019w
Pyrene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w
PAH (total 16) (w)A# 0.03 0.16 <0.01 - µg/l A-T-019w
Page 6 of 10
Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX5 BHXX4 BH410 BHXX3
Depth to Top 9.00 9.00 13.20 8.00
Depth To Bottom
Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15
Sample Type Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A
SVOC (w)
2,4,5-TrichlorophenolA <1 <1 <1 - µg/l A-T-052w
2,4,6-TrichlorophenolA <1 <1 <1 - µg/l A-T-052w
2,4-DichlorophenolA <1 <1 <1 - µg/l A-T-052w
2,4-DimethylphenolA <1 <1 <1 - µg/l A-T-052w
2,4-DinitrotolueneA <1 <1 <1 - µg/l A-T-052w
2,6-DinitrotolueneA <1 <1 <1 - µg/l A-T-052w
2-ChloronaphthaleneA <1 <1 <1 - µg/l A-T-052w
2-ChlorophenolA <1 <1 <1 - µg/l A-T-052w
2-MethylnaphthaleneA <1 <1 <1 - µg/l A-T-052w
2-MethylphenolA <1 <1 <1 - µg/l A-T-052w
2-NitrophenolA <1 <1 <1 - µg/l A-T-052w
4-Bromophenyl phenyl etherA <1 <1 <1 - µg/l A-T-052w
4-Chloro-3-methylphenolA <1 <1 <1 - µg/l A-T-052w
Bis(2-chloroisopropyl)etherA <1 <1 <1 - µg/l A-T-052w
2,4-DinitrophenolA <1 <1 <1 - µg/l A-T-052w
4,6-Dinitro-2-methylphenolA <1 <1 <1 - µg/l A-T-052w
4-MethylphenolA <1 <1 <1 - µg/l A-T-052w
4-NitrophenolA <1 <1 <1 - µg/l A-T-052w
Acenaphthene A <1 <1 <1 - µg/l A-T-052w
AcenaphthyleneA <1 <1 <1 - µg/l A-T-052w
Anthracene A <1 <1 <1 - µg/l A-T-052w
Bis(2-chloroethyl)etherA <1 <1 <1 - µg/l A-T-052w
Bis(2-chloroethoxy)methaneA <1 <1 <1 - µg/l A-T-052w
Bis(2-ethylhexyl)phthalateA <2 <2 <2 - µg/l A-T-052w
Benzo(a)anthraceneA <1 <1 <1 - µg/l A-T-052w
Butylbenzyl phthalate A <1 <1 <1 - µg/l A-T-052w
Benzo(b)fluorantheneA <1 <1 <1 - µg/l A-T-052w
Benzo(k)fluorantheneA <1 <1 <1 - µg/l A-T-052w
Benzo(a)pyrene A <1 <1 <1 - µg/l A-T-052w
Benzo(ghi)peryleneA <1 <1 <1 - µg/l A-T-052w
CarbazoleA <1 <1 <1 - µg/l A-T-052w
ChryseneA <1 <1 <1 - µg/l A-T-052w
Page 7 of 10
Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX5 BHXX4 BH410 BHXX3
Depth to Top 9.00 9.00 13.20 8.00
Depth To Bottom
Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15
Sample Type Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A
DibenzofuranA <1 <1 <1 - µg/l A-T-052w
n-DibutylphthalateA <1 <1 <1 - µg/l A-T-052w
n-DioctylphthalateA 56 47 166 - µg/l A-T-052w
n-Nitroso-n-dipropylamineA <1 <1 <1 - µg/l A-T-052w
Diethyl phthalateA <1 <1 <1 - µg/l A-T-052w
Dimethyl phthalateA <1 <1 <1 - µg/l A-T-052w
Dibenzo(ah)anthraceneA <1 <1 <1 - µg/l A-T-052w
Fluorene A <1 <1 <1 - µg/l A-T-052w
FluorantheneA <1 <1 <1 - µg/l A-T-052w
HexachlorobenzeneA <1 <1 <1 - µg/l A-T-052w
PentachlorophenolA <1 <1 <1 - µg/l A-T-052w
Phenol A <1 <1 <1 - µg/l A-T-052w
HexachloroethaneA <1 <1 <1 - µg/l A-T-052w
NitrobenzeneA <1 <1 <1 - µg/l A-T-052w
Naphthalene A <1 <1 <1 - µg/l A-T-052w
IsophoroneA <1 <1 <1 - µg/l A-T-052w
HexachlorocyclopentadieneA <1 <1 <1 - µg/l A-T-052w
Phenanthrene A <1 <1 <1 - µg/l A-T-052w
Pyrene A <1 <1 <1 - µg/l A-T-052w
Indeno(1,2,3-cd)pyreneA <1 <1 <1 - µg/l A-T-052w
PeryleneA <1 <1 <1 - µg/l A-T-052w
Page 8 of 10
Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX5 BHXX4 BH410 BHXX3
Depth to Top 9.00 9.00 13.20 8.00
Depth To Bottom
Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15
Sample Type Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A
VOC (w)
DichlorodifluoromethaneA# <1 <1 <1 <1 µg/l A-T-006w
ChloromethaneA# 7 22 <1 <1 µg/l A-T-006w
Vinyl ChlorideA# <1 <1 <1 <1 µg/l A-T-006w
BromomethaneA# <1 <1 <1 <1 µg/l A-T-006w
ChloroethaneA# <1 <1 <1 <1 µg/l A-T-006w
TrichlorofluoromethaneA# <1 <1 <1 <1 µg/l A-T-006w
trans 1,2-DichloroetheneA# <1 <1 <1 <1 µg/l A-T-006w
DichloromethaneA 21 58 <5 <5 µg/l A-T-006w
Carbon DisulphideA# 13 1547 1 171 µg/l A-T-006w
1,1-DichloroetheneA# <1 2 <1 <1 µg/l A-T-006w
1,1-DichloroethaneA# <1 <1 <1 <1 µg/l A-T-006w
cis 1,2-DichloroetheneA# <1 3 <1 3 µg/l A-T-006w
BromochloromethaneA# <5 <5 <5 <5 µg/l A-T-006w
ChloroformA# 2330 14723 <25 670 µg/l A-T-006w
2,2-DichloropropaneA# <1 <1 <1 <1 µg/l A-T-006w
1,2-DichloroethaneA# 3 <2 <2 <2 µg/l A-T-006w
1,1,1-TrichloroethaneA# <1 <1 <1 <1 µg/l A-T-006w
1,1-DichloropropeneA# <1 14 <1 <1 µg/l A-T-006w
Benzene A# <1 1 <1 <1 µg/l A-T-006w
Carbon TetrachlorideA# 413 53525 2 54234 µg/l A-T-006w
DibromomethaneA# <1 <1 <1 <1 µg/l A-T-006w
1,2-DichloropropaneA# <1 <1 <1 <1 µg/l A-T-006w
BromodichloromethaneA# <10 <10 <10 <10 µg/l A-T-006w
TrichloroetheneA# <1 6 <1 2 µg/l A-T-006w
cis 1,3-DichloropropeneA# <1 <1 <1 <1 µg/l A-T-006w
trans 1,3-DichloropropeneA# <1 <1 <1 <1 µg/l A-T-006w
1,1,2-TrichloroethaneA# <1 <1 <1 <1 µg/l A-T-006w
Toluene A# <1 1 <1 <1 µg/l A-T-006w
1,3-DichloropropaneA# <1 <1 <1 <1 µg/l A-T-006w
DibromochloromethaneA# <3 <3 <3 <3 µg/l A-T-006w
1,2-DibromoethaneA# <1 <1 <1 <1 µg/l A-T-006w
TetrachloroetheneA# 7 59 <1 39 µg/l A-T-006w
Page 9 of 10
Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4
Un
its
Me
tho
d r
ef
Client Sample No
Client Sample ID BHXX5 BHXX4 BH410 BHXX3
Depth to Top 9.00 9.00 13.20 8.00
Depth To Bottom
Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15
Sample Type Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A
1,1,1,2-TetrachloroethaneA <1 <1 <1 <1 µg/l A-T-006w
ChlorobenzeneA# <1 <1 <1 5 µg/l A-T-006w
EthylbenzeneA# <1 <1 <1 <1 µg/l A-T-006w
m & p XyleneA# <1 <1 <1 <1 µg/l A-T-006w
BromoformA# <1 <1 <1 <1 µg/l A-T-006w
StyreneA# <1 <1 <1 <1 µg/l A-T-006w
1,1,2,2-TetrachloroethaneA <1 6 <1 1 µg/l A-T-006w
o-XyleneA# <1 <1 <1 <1 µg/l A-T-006w
1,2,3-TrichloropropaneA# <1 <1 <1 <1 µg/l A-T-006w
IsopropylbenzeneA# <1 <1 <1 <1 µg/l A-T-006w
BromobenzeneA# <1 <1 <1 <1 µg/l A-T-006w
2-ChlorotolueneA# <1 <1 <1 <1 µg/l A-T-006w
n-propylbenzeneA# <1 <1 <1 <1 µg/l A-T-006w
4-ChlorotolueneA# <1 <1 <1 <1 µg/l A-T-006w
1,2,4-TrimethylbenzeneA# <1 <1 <1 <1 µg/l A-T-006w
4-IsopropyltolueneA# <1 <1 <1 <1 µg/l A-T-006w
1,3,5-TrimethylbenzeneA# <1 <1 <1 <1 µg/l A-T-006w
1,2-DichlorobenzeneA# <1 <1 <1 <1 µg/l A-T-006w
1,4-DichlorobenzeneA# <1 <1 <1 <1 µg/l A-T-006w
sec-ButylbenzeneA# <1 <1 <1 <1 µg/l A-T-006w
tert-ButylbenzeneA# <2 <2 <2 <2 µg/l A-T-006w
1,3-DichlorobenzeneA# <1 <1 <1 <1 µg/l A-T-006w
n-butylbenzeneA# <1 <1 <1 <1 µg/l A-T-006w
1,2-Dibromo-3-chloropropaneA# <2 <2 <2 <2 µg/l A-T-006w
1,2,4-TrichlorobenzeneA# <3 <3 <3 <3 µg/l A-T-006w
1,2,3-TrichlorobenzeneA# <3 <3 <3 <3 µg/l A-T-006w
HexachlorobutadieneA# <1 <1 <1 <1 µg/l A-T-006w
Page 10 of 10
REPORT NOTES
Notes - Soil chemical analysis All results are reported as dry weight (<40°C). For samples with Matrix Codes 1 - 6 natural stones >10mm are removed or excluded from the sample prior to analysis and reported results corrected to a whole sample basis. For samples with Matrix Code 7 the whole sample is dried and crushed prior to analysis. Notes - General
This report shall not be reproduced, except in full, without written approval from Envirolab. Subscript "A" indicates analysis performed on the sample as received. "D" indicates analysis performed on the dried sample, crushed to pass a 2mm sieve, unless asbestos is found to be present in which case all analysis is performed on the sample as received. All analysis is performed on the dried and crushed sample for samples with Matrix Code 7 and this supercedes any "A" subscripts. All analysis is performed on the sample as received for soil samples from outside the European Union and this supercedes any "D" subscripts. Superscript "M" indicates method accredited to MCERTS. If results are in italic font they are associated with an AQC failure. These are not accredited and are unreliable. A deviating samples report is appended and will indicate if samples or tests have been found to be deviating. Any test results affected may not be an accurate record of the concentration at the time of sampling and, as a result, may be invalid. TPH analysis of water by method A-T-007 Free and visible oils are excluded from the sample used for analysis so that the reported result represents the dissolved phase only. Asbestos in soil Asbestos in soil analysis is performed on a dried aliquot of the submitted sample and cannot guarantee to identify asbestos if present as discrete fibres/fragments. Stones etc. are not removed from the sample prior to analysis. Quantification of asbestos is a 3 stage process including visual identification, hand picking and weighing and fibre counting by sedimentation/phase contrast optical microscopy if required. If asbestos is identified a being present but is not in a form that is suitable for analysis by hand picking and weighing (normally if the asbestos is present as free fibres) quantification by sedimentation is performed. Where ACMs are found a percentage asbestos is assigned to each with reference to 'HSG264, Asbestos: The survey guide' and the calculated asbestos content is expressed as a percentage of the dried soil sample aliquot used. Predominant Matrix Codes: 1 = SAND, 2 = LOAM, 3 = CLAY, 4 = LOAM/SAND, 5 = SAND/CLAY, 6 = CLAY/LOAM, 7 = OTHER. Samples with Matrix Code 7 are not predominantly a SAND/LOAM/CLAY mix and are not covered by our BSEN 17025 or MCERTS accreditations. Secondary Matrix Codes: A = contains stones, B = contains construction rubble, C = contains visible hydrocarbons, D = contains glass/metal, E = contains roots/twigs. IS indicates Insufficient sample for analysis. NDP indicates No Determination Possible. NAD indicates No Asbestos Detected. N/A indicates Not Applicable. Superscript # indicates method accredited to ISO 17025. Analytical results reflect the quality of the sample at the time of analysis only. Opinions and interpretations expressed are outside the scope of our accreditation. Please contact us if you need any further information.
Page 1 of 10
Units 7 & 8 Sandpits Business Park Mottram Road, Hyde, Cheshire, SK14 3AR
FINAL ANALYTICAL TEST REPORT
Envirolab Job Number: 14/06758 Issue Number: 1 Date: 16 December, 2014 Client: RSK Environment Helsby Spring Lodge 172 Chester Road Helsby Cheshire UK WA6 0AR Project Manager: Rachel Hagan/Steven Pettitt Project Name: Mersey Gateway Project Ref: 321315 Order No: N/A Date Samples Received: 02/12/14 Date Instructions Received: 04/12/14 Date Analysis Completed: 15/12/14 Prepared by: Approved by:
Melanie Marshall Carolyn Field Laboratory Coordinator Sales Executive
Page 2 of 10
Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06758/1 14/06758/2
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 WS64
Depth to Top 10.50 2.70
Depth To Bottom
Date Sampled 01-Dec-14 01-Dec-14
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
pH (w)A# 7.25 12.12 pH A-T-031w
Electrical conductivity @ 20degC (w)A# 9630 4370 µs/cm A-T-037w
COD (settled)A# 130 130 mg/l A-T-034w
BOD (settled, 5 day)A <1 16 mg/l A-T-048
Hardness TotalA# 1530 1444 mg/l Ca
CO3
A-T-049w
Chloride (w)A# 721 415.93 mg/l A-T-026w
Nitrite (w)A# <0.10 0.35 mg/l A-T-026w
Nitrate (w) A# <0.50 <0.50 mg/l A-T-026w
Sulphate (w)A# 3947 824 mg/l A-T-026w
Cyanide (total) (w)A# <0.005 0.034 mg/l A-T-042wTCN
Phenols - Total by HPLC (w)A <0.01 0.43 mg/l A-T-050w
Sulphide (w)A <0.1 105.0 mg/l A-T-S2-w
DOC (w)A# 14.3 21.9 mg/l A-T-032w
Aluminium (dissolved)A 17 138 µg/l A-T-049w
Arsenic (dissolved)A# 8500 7 µg/l A-T-025w
Boron (dissolved)A# 1090 89 µg/l A-T-025w
Barium (dissolved)A# 46 37 µg/l A-T-025w
Beryllium (dissolved)A# <1 <1 µg/l A-T-025w
Cadmium (dissolved)A# <1 <1 µg/l A-T-025w
Calcium (dissolved)A# 478 578 mg/l A-T-049w
Copper (dissolved)A# <1 <1 µg/l A-T-025w
Chromium (dissolved)A# 5 2 µg/l A-T-025w
Chromium (hexavalent) (w)A# <0.05 <0.05 mg/l A-T-040w
Chromium (trivalent) (w) <0.05 <0.05 mg/l Calc
Iron (dissolved)A# 17200 65 µg/l A-T-025w
Lead (dissolved)A# <1 <1 µg/l A-T-025w
Manganese (dissolved)A# 4079 2 µg/l A-T-025w
Magnesium (dissolved)A# 81 <1 mg/l A-T-049w
Mercury (dissolved)A# <0.1 0.1 µg/l A-T-025w
Nickel (dissolved)A# 8 4 µg/l A-T-025w
Potassium (dissolved)A# 128 20 mg/l A-T-049w
Selenium (dissolved)A# 2 6 µg/l A-T-025w
Sodium (dissolved)A# 799 240 mg/l A-T-049w
Page 3 of 10
Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06758/1 14/06758/2
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 WS64
Depth to Top 10.50 2.70
Depth To Bottom
Date Sampled 01-Dec-14 01-Dec-14
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
Strontium (dissolved)A 1150 866 µg/l A-T-025w
Vanadium (dissolved)A# 10 5 µg/l A-T-025w
Zinc (dissolved)A# 8 <1 µg/l A-T-025w
Page 4 of 10
Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06758/1 14/06758/2
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 WS64
Depth to Top 10.50 2.70
Depth To Bottom
Date Sampled 01-Dec-14 01-Dec-14
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
TPH CWG
Ali >C5-C6 (w)A# <1 <1 µg/l A-T-022w
Ali >C6-C8 (w)A# <1 <1 µg/l A-T-022w
Ali >C8-C10 (w)A# <1 <1 µg/l A-T-022w
Ali >C10-C12 (w)A# <5 <5 µg/l A-T-023w
Ali >C12-C16 (w)A# <5 <5 µg/l A-T-023w
Ali >C16-C21 (w)A# <5 <5 µg/l A-T-023w
Ali >C21-C35 (w)A# <5 <5 µg/l A-T-023w
Total Aliphatics (w)A <5 <5 µg/l A-T-022+23w
Aro >C5-C7 (w)A# <1 <1 µg/l A-T-022w
Aro >C7-C8 (w)A# <1 1 µg/l A-T-022w
Aro >C8-C9 (w)A# <1 3 µg/l A-T-022w
Aro >C9-C10 (w)A# <1 2 µg/l A-T-022w
Aro >C10-C12 (w)A# <5 8 µg/l A-T-023w
Aro >C12-C16 (w)A# <5 7 µg/l A-T-023w
Aro >C16-C21 (w)A# <5 <5 µg/l A-T-023w
Aro >C21-C35 (w)A# <5 <5 µg/l A-T-023w
Total Aromatics (w)A <5 21 µg/l A-T-022+23w
TPH (Ali & Aro) (w)A <5 21 µg/l A-T-022+23w
BTEX - Benzene (w)A# <1 <1 µg/l A-T-022w
BTEX - Toluene (w)A# <1 1 µg/l A-T-022w
BTEX - Ethyl Benzene (w)A# <1 <1 µg/l A-T-022w
BTEX - m & p Xylene (w)A# <1 1 µg/l A-T-022w
BTEX - o Xylene (w)A# <1 1 µg/l A-T-022w
MTBE (w)A# <1 <1 µg/l A-T-022w
Page 5 of 10
Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06758/1 14/06758/2
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 WS64
Depth to Top 10.50 2.70
Depth To Bottom
Date Sampled 01-Dec-14 01-Dec-14
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
PAH 16MS (w)
Acenaphthene (w)A# <0.01 <0.01 µg/l A-T-019w
Acenaphthylene (w)A# <0.01 <0.01 µg/l A-T-019w
Anthracene (w)A# <0.01 <0.01 µg/l A-T-019w
Benzo(a)anthracene (w)A# <0.01 <0.01 µg/l A-T-019w
Benzo(a)pyrene (w)A# <0.01 <0.01 µg/l A-T-019w
Benzo(b)fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w
Benzo(ghi)perylene (w)A# <0.01 <0.01 µg/l A-T-019w
Benzo(k)fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w
Chrysene (w)A# <0.01 <0.01 µg/l A-T-019w
Dibenzo(ah)anthracene (w)A# <0.01 <0.01 µg/l A-T-019w
Fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w
Fluorene (w)A# <0.01 <0.01 µg/l A-T-019w
Indeno(123-cd)pyrene (w)A# <0.01 <0.01 µg/l A-T-019w
Naphthalene (w)A# 0.02 3.59 µg/l A-T-019w
Phenanthrene (w)A# 0.01 <0.01 µg/l A-T-019w
Pyrene (w)A# <0.01 <0.01 µg/l A-T-019w
PAH (total 16) (w)A# 0.03 3.59 µg/l A-T-019w
Page 6 of 10
Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06758/1 14/06758/2
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 WS64
Depth to Top 10.50 2.70
Depth To Bottom
Date Sampled 01-Dec-14 01-Dec-14
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
SVOC (w)
2,4,5-TrichlorophenolA <1 <1 µg/l A-T-052w
2,4,6-TrichlorophenolA <1 <1 µg/l A-T-052w
2,4-DichlorophenolA <1 <1 µg/l A-T-052w
2,4-DimethylphenolA <1 7 µg/l A-T-052w
2,4-DinitrotolueneA <1 <1 µg/l A-T-052w
2,6-DinitrotolueneA <1 <1 µg/l A-T-052w
2-ChloronaphthaleneA <1 <1 µg/l A-T-052w
2-ChlorophenolA <1 <1 µg/l A-T-052w
2-MethylnaphthaleneA <1 <1 µg/l A-T-052w
2-MethylphenolA <1 12 µg/l A-T-052w
2-NitrophenolA <1 <1 µg/l A-T-052w
4-Bromophenyl phenyl etherA <1 <1 µg/l A-T-052w
4-Chloro-3-methylphenolA <1 <1 µg/l A-T-052w
Bis(2-chloroisopropyl)etherA <1 <1 µg/l A-T-052w
2,4-DinitrophenolA <1 <1 µg/l A-T-052w
4,6-Dinitro-2-methylphenolA <1 <1 µg/l A-T-052w
4-MethylphenolA <1 13 µg/l A-T-052w
4-NitrophenolA <1 <1 µg/l A-T-052w
Acenaphthene A <1 <1 µg/l A-T-052w
AcenaphthyleneA <1 <1 µg/l A-T-052w
Anthracene A <1 <1 µg/l A-T-052w
Bis(2-chloroethyl)etherA <1 <1 µg/l A-T-052w
Bis(2-chloroethoxy)methaneA <1 <1 µg/l A-T-052w
Bis(2-ethylhexyl)phthalateA <2 <2 µg/l A-T-052w
Benzo(a)anthraceneA <1 <1 µg/l A-T-052w
Butylbenzyl phthalate A <1 <1 µg/l A-T-052w
Benzo(b)fluorantheneA <1 <1 µg/l A-T-052w
Benzo(k)fluorantheneA <1 <1 µg/l A-T-052w
Benzo(a)pyrene A <1 <1 µg/l A-T-052w
Benzo(ghi)peryleneA <1 <1 µg/l A-T-052w
CarbazoleA <1 <1 µg/l A-T-052w
ChryseneA <1 <1 µg/l A-T-052w
Page 7 of 10
Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06758/1 14/06758/2
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 WS64
Depth to Top 10.50 2.70
Depth To Bottom
Date Sampled 01-Dec-14 01-Dec-14
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
DibenzofuranA <1 <1 µg/l A-T-052w
n-DibutylphthalateA <1 <1 µg/l A-T-052w
n-DioctylphthalateA <5 <5 µg/l A-T-052w
n-Nitroso-n-dipropylamineA <1 <1 µg/l A-T-052w
Diethyl phthalateA <1 <1 µg/l A-T-052w
Dimethyl phthalateA <1 <1 µg/l A-T-052w
Dibenzo(ah)anthraceneA <1 <1 µg/l A-T-052w
Fluorene A <1 <1 µg/l A-T-052w
FluorantheneA <1 <1 µg/l A-T-052w
HexachlorobenzeneA <1 <1 µg/l A-T-052w
PentachlorophenolA <1 <1 µg/l A-T-052w
Phenol A 2 54 µg/l A-T-052w
HexachloroethaneA <1 <1 µg/l A-T-052w
NitrobenzeneA <1 <1 µg/l A-T-052w
Naphthalene A <1 4 µg/l A-T-052w
IsophoroneA <1 <1 µg/l A-T-052w
HexachlorocyclopentadieneA <1 <1 µg/l A-T-052w
Phenanthrene A <1 <1 µg/l A-T-052w
Pyrene A <1 <1 µg/l A-T-052w
Indeno(1,2,3-cd)pyreneA <1 <1 µg/l A-T-052w
PeryleneA <1 <1 µg/l A-T-052w
Page 8 of 10
Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06758/1 14/06758/2
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 WS64
Depth to Top 10.50 2.70
Depth To Bottom
Date Sampled 01-Dec-14 01-Dec-14
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
VOC (w)
DichlorodifluoromethaneA# <1 <1 µg/l A-T-006w
ChloromethaneA# <1 <1 µg/l A-T-006w
Vinyl ChlorideA# <1 <1 µg/l A-T-006w
BromomethaneA# <1 <1 µg/l A-T-006w
ChloroethaneA# <1 <1 µg/l A-T-006w
TrichlorofluoromethaneA# <1 <1 µg/l A-T-006w
trans 1,2-DichloroetheneA# <1 <1 µg/l A-T-006w
DichloromethaneA <5 <5 µg/l A-T-006w
Carbon DisulphideA# 24 <1 µg/l A-T-006w
1,1-DichloroetheneA# <1 <1 µg/l A-T-006w
1,1-DichloroethaneA# <1 <1 µg/l A-T-006w
cis 1,2-DichloroetheneA# 3 <1 µg/l A-T-006w
BromochloromethaneA# <5 <5 µg/l A-T-006w
ChloroformA# 206 <25 µg/l A-T-006w
2,2-DichloropropaneA# <1 <1 µg/l A-T-006w
1,2-DichloroethaneA# <2 <2 µg/l A-T-006w
1,1,1-TrichloroethaneA# <1 <1 µg/l A-T-006w
1,1-DichloropropeneA# <1 <1 µg/l A-T-006w
Benzene A# <1 <1 µg/l A-T-006w
Carbon TetrachlorideA# 509 <1 µg/l A-T-006w
DibromomethaneA# <1 <1 µg/l A-T-006w
1,2-DichloropropaneA# <1 <1 µg/l A-T-006w
BromodichloromethaneA# <10 <10 µg/l A-T-006w
TrichloroetheneA# 2 <1 µg/l A-T-006w
cis 1,3-DichloropropeneA# <1 <1 µg/l A-T-006w
trans 1,3-DichloropropeneA# <1 <1 µg/l A-T-006w
1,1,2-TrichloroethaneA# <1 <1 µg/l A-T-006w
Toluene A# <1 1 µg/l A-T-006w
1,3-DichloropropaneA# <1 <1 µg/l A-T-006w
DibromochloromethaneA# <3 <3 µg/l A-T-006w
1,2-DibromoethaneA# <1 <1 µg/l A-T-006w
TetrachloroetheneA# 19 <1 µg/l A-T-006w
Page 9 of 10
Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06758/1 14/06758/2
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 WS64
Depth to Top 10.50 2.70
Depth To Bottom
Date Sampled 01-Dec-14 01-Dec-14
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
1,1,1,2-TetrachloroethaneA <1 <1 µg/l A-T-006w
ChlorobenzeneA# <1 <1 µg/l A-T-006w
EthylbenzeneA# <1 <1 µg/l A-T-006w
m & p XyleneA# <1 <1 µg/l A-T-006w
BromoformA# <1 <1 µg/l A-T-006w
StyreneA# <1 <1 µg/l A-T-006w
1,1,2,2-TetrachloroethaneA <1 <1 µg/l A-T-006w
o-XyleneA# <1 <1 µg/l A-T-006w
1,2,3-TrichloropropaneA# <1 <1 µg/l A-T-006w
IsopropylbenzeneA# <1 <1 µg/l A-T-006w
BromobenzeneA# <1 <1 µg/l A-T-006w
2-ChlorotolueneA# <1 <1 µg/l A-T-006w
n-propylbenzeneA# <1 <1 µg/l A-T-006w
4-ChlorotolueneA# <1 <1 µg/l A-T-006w
1,2,4-TrimethylbenzeneA# <1 <1 µg/l A-T-006w
4-IsopropyltolueneA# <1 <1 µg/l A-T-006w
1,3,5-TrimethylbenzeneA# <1 <1 µg/l A-T-006w
1,2-DichlorobenzeneA# <1 <1 µg/l A-T-006w
1,4-DichlorobenzeneA# <1 <1 µg/l A-T-006w
sec-ButylbenzeneA# <1 <1 µg/l A-T-006w
tert-ButylbenzeneA# <2 <2 µg/l A-T-006w
1,3-DichlorobenzeneA# <1 <1 µg/l A-T-006w
n-butylbenzeneA# <1 <1 µg/l A-T-006w
1,2-Dibromo-3-chloropropaneA# <2 <2 µg/l A-T-006w
1,2,4-TrichlorobenzeneA# <3 <3 µg/l A-T-006w
1,2,3-TrichlorobenzeneA# <3 <3 µg/l A-T-006w
HexachlorobutadieneA# <1 <1 µg/l A-T-006w
Page 10 of 10
REPORT NOTES
Notes - Soil chemical analysis All results are reported as dry weight (<40°C). For samples with Matrix Codes 1 - 6 natural stones >10mm are removed or excluded from the sample prior to analysis and reported results corrected to a whole sample basis. For samples with Matrix Code 7 the whole sample is dried and crushed prior to analysis. Notes - General
This report shall not be reproduced, except in full, without written approval from Envirolab. Subscript "A" indicates analysis performed on the sample as received. "D" indicates analysis performed on the dried sample, crushed to pass a 2mm sieve, unless asbestos is found to be present in which case all analysis is performed on the sample as received. All analysis is performed on the dried and crushed sample for samples with Matrix Code 7 and this supercedes any "A" subscripts. All analysis is performed on the sample as received for soil samples from outside the European Union and this supercedes any "D" subscripts. Superscript "M" indicates method accredited to MCERTS. If results are in italic font they are associated with an AQC failure. These are not accredited and are unreliable. A deviating samples report is appended and will indicate if samples or tests have been found to be deviating. Any test results affected may not be an accurate record of the concentration at the time of sampling and, as a result, may be invalid. TPH analysis of water by method A-T-007 Free and visible oils are excluded from the sample used for analysis so that the reported result represents the dissolved phase only. Asbestos in soil Asbestos in soil analysis is performed on a dried aliquot of the submitted sample and cannot guarantee to identify asbestos if present as discrete fibres/fragments. Stones etc. are not removed from the sample prior to analysis. Quantification of asbestos is a 3 stage process including visual identification, hand picking and weighing and fibre counting by sedimentation/phase contrast optical microscopy if required. If asbestos is identified a being present but is not in a form that is suitable for analysis by hand picking and weighing (normally if the asbestos is present as free fibres) quantification by sedimentation is performed. Where ACMs are found a percentage asbestos is assigned to each with reference to 'HSG264, Asbestos: The survey guide' and the calculated asbestos content is expressed as a percentage of the dried soil sample aliquot used. Predominant Matrix Codes: 1 = SAND, 2 = LOAM, 3 = CLAY, 4 = LOAM/SAND, 5 = SAND/CLAY, 6 = CLAY/LOAM, 7 = OTHER. Samples with Matrix Code 7 are not predominantly a SAND/LOAM/CLAY mix and are not covered by our BSEN 17025 or MCERTS accreditations. Secondary Matrix Codes: A = contains stones, B = contains construction rubble, C = contains visible hydrocarbons, D = contains glass/metal, E = contains roots/twigs. IS indicates Insufficient sample for analysis. NDP indicates No Determination Possible. NAD indicates No Asbestos Detected. N/A indicates Not Applicable. Superscript # indicates method accredited to ISO 17025. Analytical results reflect the quality of the sample at the time of analysis only. Opinions and interpretations expressed are outside the scope of our accreditation. Please contact us if you need any further information.
Page 1 of 10
Units 7 & 8 Sandpits Business Park Mottram Road, Hyde, Cheshire, SK14 3AR
FINAL ANALYTICAL TEST REPORT
Envirolab Job Number: 14/06552 Issue Number: 1 Date: 01 December, 2014 Client: RSK Environment Helsby Spring Lodge 172 Chester Road Helsby Cheshire UK WA6 0AR Project Manager: Rachel Hagan/Steven Pettitt Project Name: Mersey Gateway Project Ref: 321315 Order No: N/A Date Samples Received: 24/11/14 Date Instructions Received: 25/11/14 Date Analysis Completed: 01/12/14 Prepared by: Approved by:
Melanie Marshall Iain Haslock Laboratory Coordinator Analytical Consultant
Page 2 of 10
Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06552/1 14/06552/2 14/06552/3
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX1 BHXX2 BHXX3
Depth to Top 19.00 52.8 10.50
Depth To Bottom
Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14
Sample Type Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A
pH (w)A# 7.55 7.24 7.51 pH A-T-031w
Electrical conductivity @ 20degC (w)A# 12800 14400 8250 µs/cm A-T-037w
COD (settled)A# 190 120 120 mg/l A-T-034w
BOD (settled, 5 day)A <1 <1 <1 mg/l A-T-048
Hardness TotalA# 2920 7660 1675 mg/l Ca
CO3
A-T-049w
Chloride (w)A# 4330 6180 787 mg/l A-T-026w
Nitrite (w)A# <0.10 <0.10 <0.10 mg/l A-T-026w
Nitrate (w) A# <0.50 <0.50 <0.50 mg/l A-T-026w
Sulphate (w)A# 1848 614 3548 mg/l A-T-026w
Cyanide (total) (w)A# <0.005 <0.005 <0.005 mg/l A-T-042wTCN
Phenols - Total by HPLC (w)A 0.50 0.39 <0.01 mg/l A-T-050w
Sulphide (w)A <0.1 <0.1 0.1 mg/l A-T-S2-w
DOC (w)A# 3.8 1.7 13.8 mg/l A-T-032w
Aluminium (dissolved)A 23 21 35 µg/l A-T-049w
Arsenic (dissolved)A# 99 3 9780 µg/l A-T-025w
Boron (dissolved)A# 501 56 444 µg/l A-T-025w
Barium (dissolved)A# 94 62 47 µg/l A-T-025w
Beryllium (dissolved)A# <1 <1 <1 µg/l A-T-025w
Cadmium (dissolved)A# <1 <1 <1 µg/l A-T-025w
Calcium (dissolved)A# 668 1700 576 mg/l A-T-049w
Copper (dissolved)A# <1 <1 <1 µg/l A-T-025w
Chromium (dissolved)A# 10 14 7 µg/l A-T-025w
Chromium (hexavalent) (w)A# <0.05 <0.05 <0.05 mg/l A-T-040w
Chromium (trivalent) (w) <0.05 <0.05 <0.05 mg/l Calc
Iron (dissolved)A# 3124 178 17730 µg/l A-T-025w
Lead (dissolved)A# <1 <1 <1 µg/l A-T-025w
Manganese (dissolved)A# 1925 556 4454 µg/l A-T-025w
Magnesium (dissolved)A# 304 827 57 mg/l A-T-049w
Mercury (dissolved)A# <0.1 <0.1 <0.1 µg/l A-T-025w
Nickel (dissolved)A# 4 7 10 µg/l A-T-025w
Potassium (dissolved)A# 58 19 94 mg/l A-T-049w
Selenium (dissolved)A# <1 <1 2 µg/l A-T-025w
Sodium (dissolved)A# 2170 1280 892 mg/l A-T-049w
Page 3 of 10
Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06552/1 14/06552/2 14/06552/3
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX1 BHXX2 BHXX3
Depth to Top 19.00 52.8 10.50
Depth To Bottom
Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14
Sample Type Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A
Strontium (dissolved)A 6780 3700 1120 µg/l A-T-025w
Vanadium (dissolved)A# 4 2 11 µg/l A-T-025w
Zinc (dissolved)A# 16 10 9 µg/l A-T-025w
Page 4 of 10
Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06552/1 14/06552/2 14/06552/3
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX1 BHXX2 BHXX3
Depth to Top 19.00 52.8 10.50
Depth To Bottom
Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14
Sample Type Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A
TPH CWG
Ali >C5-C6 (w)A# <1 <1 <1 µg/l A-T-022w
Ali >C6-C8 (w)A# <1 <1 <1 µg/l A-T-022w
Ali >C8-C10 (w)A# <1 <1 <1 µg/l A-T-022w
Ali >C10-C12 (w)A# <5 <5 <5 µg/l A-T-023w
Ali >C12-C16 (w)A# <5 <5 <5 µg/l A-T-023w
Ali >C16-C21 (w)A# <5 <5 10 µg/l A-T-023w
Ali >C21-C35 (w)A# <5 <5 208 µg/l A-T-023w
Total Aliphatics (w)A <5 <5 218 µg/l A-T-022+23w
Aro >C5-C7 (w)A# <1 <1 <1 µg/l A-T-022w
Aro >C7-C8 (w)A# <1 <1 <1 µg/l A-T-022w
Aro >C8-C9 (w)A# <1 <1 <1 µg/l A-T-022w
Aro >C9-C10 (w)A# <1 <1 <1 µg/l A-T-022w
Aro >C10-C12 (w)A# <5 <5 <5 µg/l A-T-023w
Aro >C12-C16 (w)A# <5 <5 <5 µg/l A-T-023w
Aro >C16-C21 (w)A# <5 <5 <5 µg/l A-T-023w
Aro >C21-C35 (w)A# <5 <5 51 µg/l A-T-023w
Total Aromatics (w)A <5 <5 51 µg/l A-T-022+23w
TPH (Ali & Aro) (w)A <5 <5 269 µg/l A-T-022+23w
BTEX - Benzene (w)A# <1 <1 <1 µg/l A-T-022w
BTEX - Toluene (w)A# <1 <1 <1 µg/l A-T-022w
BTEX - Ethyl Benzene (w)A# <1 <1 <1 µg/l A-T-022w
BTEX - m & p Xylene (w)A# <1 <1 <1 µg/l A-T-022w
BTEX - o Xylene (w)A# <1 <1 <1 µg/l A-T-022w
MTBE (w)A# <1 <1 <1 µg/l A-T-022w
Page 5 of 10
Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06552/1 14/06552/2 14/06552/3
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX1 BHXX2 BHXX3
Depth to Top 19.00 52.8 10.50
Depth To Bottom
Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14
Sample Type Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A
PAH 16MS (w)
Acenaphthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Acenaphthylene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Anthracene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(a)anthracene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(a)pyrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(b)fluoranthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(ghi)perylene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(k)fluoranthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Chrysene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Dibenzo(ah)anthracene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Fluoranthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Fluorene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Indeno(123-cd)pyrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Naphthalene (w)A# <0.01 <0.01 0.02 µg/l A-T-019w
Phenanthrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
Pyrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w
PAH (total 16) (w)A# <0.01 <0.01 0.02 µg/l A-T-019w
Page 6 of 10
Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06552/1 14/06552/2 14/06552/3
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX1 BHXX2 BHXX3
Depth to Top 19.00 52.8 10.50
Depth To Bottom
Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14
Sample Type Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A
SVOC (w)
2,4,5-TrichlorophenolA <1 <1 <1 µg/l A-T-052w
2,4,6-TrichlorophenolA <1 <1 <1 µg/l A-T-052w
2,4-DichlorophenolA <1 <1 <1 µg/l A-T-052w
2,4-DimethylphenolA <1 <1 <1 µg/l A-T-052w
2,4-DinitrotolueneA <1 <1 <1 µg/l A-T-052w
2,6-DinitrotolueneA <1 <1 <1 µg/l A-T-052w
2-ChloronaphthaleneA <1 <1 <1 µg/l A-T-052w
2-ChlorophenolA <1 <1 <1 µg/l A-T-052w
2-MethylnaphthaleneA <1 <1 <1 µg/l A-T-052w
2-MethylphenolA <1 <1 <1 µg/l A-T-052w
2-NitrophenolA <1 <1 <1 µg/l A-T-052w
4-Bromophenyl phenyl etherA <1 <1 <1 µg/l A-T-052w
4-Chloro-3-methylphenolA <1 <1 <1 µg/l A-T-052w
Bis(2-chloroisopropyl)etherA <1 <1 <1 µg/l A-T-052w
2,4-DinitrophenolA <1 <1 <1 µg/l A-T-052w
4,6-Dinitro-2-methylphenolA <1 <1 <1 µg/l A-T-052w
4-MethylphenolA <1 <1 <1 µg/l A-T-052w
4-NitrophenolA <1 <1 <1 µg/l A-T-052w
Acenaphthene A <1 <1 <1 µg/l A-T-052w
AcenaphthyleneA <1 <1 <1 µg/l A-T-052w
Anthracene A <1 <1 <1 µg/l A-T-052w
Bis(2-chloroethyl)etherA <1 1 <1 µg/l A-T-052w
Bis(2-chloroethoxy)methaneA <1 <1 <1 µg/l A-T-052w
Bis(2-ethylhexyl)phthalateA <2 <2 <2 µg/l A-T-052w
Benzo(a)anthraceneA <1 <1 <1 µg/l A-T-052w
Butylbenzyl phthalate A <1 <1 <1 µg/l A-T-052w
Benzo(b)fluorantheneA <1 <1 <1 µg/l A-T-052w
Benzo(k)fluorantheneA <1 <1 <1 µg/l A-T-052w
Benzo(a)pyrene A <1 <1 <1 µg/l A-T-052w
Benzo(ghi)peryleneA <1 <1 <1 µg/l A-T-052w
CarbazoleA <1 <1 <1 µg/l A-T-052w
ChryseneA <1 <1 <1 µg/l A-T-052w
Page 7 of 10
Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06552/1 14/06552/2 14/06552/3
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX1 BHXX2 BHXX3
Depth to Top 19.00 52.8 10.50
Depth To Bottom
Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14
Sample Type Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A
DibenzofuranA <1 <1 <1 µg/l A-T-052w
n-DibutylphthalateA <1 <1 <1 µg/l A-T-052w
n-DioctylphthalateA <5 <5 <5 µg/l A-T-052w
n-Nitroso-n-dipropylamineA <1 <1 <1 µg/l A-T-052w
Diethyl phthalateA <1 <1 <1 µg/l A-T-052w
Dimethyl phthalateA <1 <1 <1 µg/l A-T-052w
Dibenzo(ah)anthraceneA <1 <1 <1 µg/l A-T-052w
Fluorene A <1 <1 <1 µg/l A-T-052w
FluorantheneA <1 <1 <1 µg/l A-T-052w
HexachlorobenzeneA <1 <1 <1 µg/l A-T-052w
PentachlorophenolA <1 <1 <1 µg/l A-T-052w
Phenol A <1 <1 <1 µg/l A-T-052w
HexachloroethaneA <1 <1 <1 µg/l A-T-052w
NitrobenzeneA <1 <1 <1 µg/l A-T-052w
Naphthalene A <1 <1 <1 µg/l A-T-052w
IsophoroneA <1 <1 <1 µg/l A-T-052w
HexachlorocyclopentadieneA <1 <1 <1 µg/l A-T-052w
Phenanthrene A <1 <1 <1 µg/l A-T-052w
Pyrene A <1 <1 <1 µg/l A-T-052w
Indeno(1,2,3-cd)pyreneA <1 <1 <1 µg/l A-T-052w
PeryleneA <1 <1 <1 µg/l A-T-052w
Page 8 of 10
Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06552/1 14/06552/2 14/06552/3
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX1 BHXX2 BHXX3
Depth to Top 19.00 52.8 10.50
Depth To Bottom
Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14
Sample Type Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A
VOC (w)
DichlorodifluoromethaneA# <1 <1 <1 µg/l A-T-006w
ChloromethaneA# <1 <1 <1 µg/l A-T-006w
Vinyl ChlorideA# <1 <1 <1 µg/l A-T-006w
BromomethaneA# <1 <1 <1 µg/l A-T-006w
ChloroethaneA# <1 <1 <1 µg/l A-T-006w
TrichlorofluoromethaneA# <1 <1 <1 µg/l A-T-006w
trans 1,2-DichloroetheneA# <1 <1 <1 µg/l A-T-006w
DichloromethaneA <5 <5 <5 µg/l A-T-006w
Carbon DisulphideA# <1 <1 48 µg/l A-T-006w
1,1-DichloroetheneA# <1 <1 <1 µg/l A-T-006w
1,1-DichloroethaneA# <1 <1 <1 µg/l A-T-006w
cis 1,2-DichloroetheneA# <1 <1 3 µg/l A-T-006w
BromochloromethaneA# <5 <5 <5 µg/l A-T-006w
ChloroformA# 270 <25 188 µg/l A-T-006w
2,2-DichloropropaneA# <1 <1 <1 µg/l A-T-006w
1,2-DichloroethaneA# <2 <2 <2 µg/l A-T-006w
1,1,1-TrichloroethaneA# <1 <1 <1 µg/l A-T-006w
1,1-DichloropropeneA# <1 <1 <1 µg/l A-T-006w
Benzene A# <1 <1 <1 µg/l A-T-006w
Carbon TetrachlorideA# 215 <1 748 µg/l A-T-006w
DibromomethaneA# <1 <1 <1 µg/l A-T-006w
1,2-DichloropropaneA# <1 <1 <1 µg/l A-T-006w
BromodichloromethaneA# <10 <10 <10 µg/l A-T-006w
TrichloroetheneA# <1 <1 2 µg/l A-T-006w
cis 1,3-DichloropropeneA# <1 <1 <1 µg/l A-T-006w
trans 1,3-DichloropropeneA# <1 <1 <1 µg/l A-T-006w
1,1,2-TrichloroethaneA# <1 <1 <1 µg/l A-T-006w
Toluene A# <1 <1 <1 µg/l A-T-006w
1,3-DichloropropaneA# <1 <1 <1 µg/l A-T-006w
DibromochloromethaneA# <3 <3 <3 µg/l A-T-006w
1,2-DibromoethaneA# <1 <1 <1 µg/l A-T-006w
TetrachloroetheneA# <1 <1 14 µg/l A-T-006w
Page 9 of 10
Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06552/1 14/06552/2 14/06552/3
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX1 BHXX2 BHXX3
Depth to Top 19.00 52.8 10.50
Depth To Bottom
Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14
Sample Type Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A
1,1,1,2-TetrachloroethaneA <1 <1 <1 µg/l A-T-006w
ChlorobenzeneA# <1 <1 <1 µg/l A-T-006w
EthylbenzeneA# <1 <1 <1 µg/l A-T-006w
m & p XyleneA# <1 <1 <1 µg/l A-T-006w
BromoformA# <1 <1 <1 µg/l A-T-006w
StyreneA# <1 <1 <1 µg/l A-T-006w
1,1,2,2-TetrachloroethaneA <1 <1 <1 µg/l A-T-006w
o-XyleneA# <1 <1 <1 µg/l A-T-006w
1,2,3-TrichloropropaneA# <1 <1 <1 µg/l A-T-006w
IsopropylbenzeneA# <1 <1 <1 µg/l A-T-006w
BromobenzeneA# <1 <1 <1 µg/l A-T-006w
2-ChlorotolueneA# <1 <1 <1 µg/l A-T-006w
n-propylbenzeneA# <1 <1 <1 µg/l A-T-006w
4-ChlorotolueneA# <1 <1 <1 µg/l A-T-006w
1,2,4-TrimethylbenzeneA# <1 <1 <1 µg/l A-T-006w
4-IsopropyltolueneA# <1 <1 <1 µg/l A-T-006w
1,3,5-TrimethylbenzeneA# <1 <1 <1 µg/l A-T-006w
1,2-DichlorobenzeneA# <1 <1 <1 µg/l A-T-006w
1,4-DichlorobenzeneA# <1 <1 <1 µg/l A-T-006w
sec-ButylbenzeneA# <1 <1 <1 µg/l A-T-006w
tert-ButylbenzeneA# <2 <2 <2 µg/l A-T-006w
1,3-DichlorobenzeneA# <1 <1 <1 µg/l A-T-006w
n-butylbenzeneA# <1 <1 <1 µg/l A-T-006w
1,2-Dibromo-3-chloropropaneA# <2 <2 <2 µg/l A-T-006w
1,2,4-TrichlorobenzeneA# <3 <3 <3 µg/l A-T-006w
1,2,3-TrichlorobenzeneA# <3 <3 <3 µg/l A-T-006w
HexachlorobutadieneA# <1 <1 <1 µg/l A-T-006w
Page 10 of 10
REPORT NOTES
Notes - Soil chemical analysis All results are reported as dry weight (<40°C). For samples with Matrix Codes 1 - 6 natural stones >10mm are removed or excluded from the sample prior to analysis and reported results corrected to a whole sample basis. For samples with Matrix Code 7 the whole sample is dried and crushed prior to analysis. Notes - General
This report shall not be reproduced, except in full, without written approval from Envirolab. Subscript "A" indicates analysis performed on the sample as received. "D" indicates analysis performed on the dried sample, crushed to pass a 2mm sieve, unless asbestos is found to be present in which case all analysis is performed on the sample as received. All analysis is performed on the dried and crushed sample for samples with Matrix Code 7 and this supercedes any "A" subscripts. All analysis is performed on the sample as received for soil samples from outside the European Union and this supercedes any "D" subscripts. Superscript "M" indicates method accredited to MCERTS. If results are in italic font they are associated with an AQC failure. These are not accredited and are unreliable. A deviating samples report is appended and will indicate if samples or tests have been found to be deviating. Any test results affected may not be an accurate record of the concentration at the time of sampling and, as a result, may be invalid. TPH analysis of water by method A-T-007 Free and visible oils are excluded from the sample used for analysis so that the reported result represents the dissolved phase only. Asbestos in soil Asbestos in soil analysis is performed on a dried aliquot of the submitted sample and cannot guarantee to identify asbestos if present as discrete fibres/fragments. Stones etc. are not removed from the sample prior to analysis. Quantification of asbestos is a 3 stage process including visual identification, hand picking and weighing and fibre counting by sedimentation/phase contrast optical microscopy if required. If asbestos is identified a being present but is not in a form that is suitable for analysis by hand picking and weighing (normally if the asbestos is present as free fibres) quantification by sedimentation is performed. Where ACMs are found a percentage asbestos is assigned to each with reference to 'HSG264, Asbestos: The survey guide' and the calculated asbestos content is expressed as a percentage of the dried soil sample aliquot used. Predominant Matrix Codes: 1 = SAND, 2 = LOAM, 3 = CLAY, 4 = LOAM/SAND, 5 = SAND/CLAY, 6 = CLAY/LOAM, 7 = OTHER. Samples with Matrix Code 7 are not predominantly a SAND/LOAM/CLAY mix and are not covered by our BSEN 17025 or MCERTS accreditations. Secondary Matrix Codes: A = contains stones, B = contains construction rubble, C = contains visible hydrocarbons, D = contains glass/metal, E = contains roots/twigs. IS indicates Insufficient sample for analysis. NDP indicates No Determination Possible. NAD indicates No Asbestos Detected. N/A indicates Not Applicable. Superscript # indicates method accredited to ISO 17025. Analytical results reflect the quality of the sample at the time of analysis only. Opinions and interpretations expressed are outside the scope of our accreditation. Please contact us if you need any further information.
Page 1 of 18
Units 7 & 8 Sandpits Business Park Mottram Road, Hyde, Cheshire, SK14 3AR
FINAL ANALYTICAL TEST REPORT
Envirolab Job Number: 14/06461 Issue Number: 1 Date: 01 December, 2014 Client: RSK Environment Helsby Spring Lodge 172 Chester Road Helsby Cheshire UK WA6 0AR Project Manager: Rachel Hagan/Steven Pettitt Project Name: Mersey Gateway Project Ref: 321315 Order No: N/A Date Samples Received: 20/11/14 Date Instructions Received: 20/11/14 Date Analysis Completed: 01/12/14 Prepared by: Approved by:
Melanie Marshall Iain Haslock Laboratory Coordinator Analytical Consultant
Page 2 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256
Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80
Depth To Bottom
Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A
pH (w)A# 8.14 6.57 11.70 12.40 7.89 7.61 8.01 6.63 pH A-T-031w
Electrical conductivity @ 20degC (w)A# 1090 2740 26100 4190 12900 14300 959 2830 µs/cm A-T-037w
COD (settled)A# 20 7 19000 66 220 150 13 53 mg/l A-T-034w
BOD (settled, 5 day)A 3 3 170 23 2 2 4 8 mg/l A-T-048
Hardness TotalA# 796 1630 17500 1710 2740 6340 469 1690 mg/l Ca
CO3
A-T-049w
Chloride (w)A# 33.59 120.77 33400 151.78 4860 6740 231.77 135.45 mg/l A-T-026w
Nitrite (w)A# 0.26 0.11 19.44 1.04 <0.10 <0.10 <0.10 <0.10 mg/l A-T-026w
Nitrate (w) A# 13.25 5.67 <0.50 4.69 <0.50 <0.50 <0.50 <0.50 mg/l A-T-026w
Sulphate (w)A# 379 1736 1499 713 1785 634 49 1752 mg/l A-T-026w
Cyanide (total) (w)A# <0.005 <0.005 1.139 0.018 <0.005 <0.005 <0.005 0.070 mg/l A-T-042wTCN
Phenols - Total by HPLC (w)A <0.01 <0.01 30.1 0.06 <0.01 0.38 <0.01 <0.01 mg/l A-T-050w
Sulphide (w)A 0.3 1.5 16800 71.2 0.5 <0.1 0.4 0.5 mg/l A-T-S2-w
DOC (w)A# 5.4 3.6 146.3 6.1 10.7 1.6 2.8 8.1 mg/l A-T-032w
Aluminium (dissolved)A 24 3240 162 13 13 12 32 50 µg/l A-T-049w
Arsenic (dissolved)A# 6 6 10400 <2 332 3 11 9800 µg/l A-T-025w
Boron (dissolved)A# 144 1520 <500 <20 668 52 72 <500 µg/l A-T-025w
Barium (dissolved)A# 163 489 1580 75 97 73 336 <50 µg/l A-T-025w
Beryllium (dissolved)A# <2 <5 <50 <2 <2 <2 <2 <50 µg/l A-T-025w
Cadmium (dissolved)A# <2 <5 <50 <2 <2 <2 <2 <50 µg/l A-T-025w
Calcium (dissolved)A# 267 600 6980 684 600 1430 105 637 mg/l A-T-049w
Copper (dissolved)A# 3 11 <50 <2 <2 <2 <2 <50 µg/l A-T-025w
Chromium (dissolved)A# 6 10 <50 10 10 11 3 <50 µg/l A-T-025w
Chromium (hexavalent) (w)A# <0.05 <1.00 <0.05 <0.05 <0.05 <5.00 <0.05 <1.00 mg/l A-T-040w
Chromium (trivalent) (w) <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 mg/l Calc
Iron (dissolved)A# 2600 317 <500 28 8530 165 591 56800 µg/l A-T-025w
Lead (dissolved)A# <2 <5 <50 <2 <2 <2 <2 <50 µg/l A-T-025w
Manganese (dissolved)A# 1660 1500 <50 <2 2230 613 115 2170 µg/l A-T-025w
Magnesium (dissolved)A# 31 32 13 1 302 674 50 24 mg/l A-T-049w
Mercury (dissolved)A# <0.2 <0.5 <5.0 <0.2 <0.2 <0.2 <0.2 <5.0 µg/l A-T-025w
Nickel (dissolved)A# 16 142 167 2 3 8 <2 <50 µg/l A-T-025w
Potassium (dissolved)A# 22 23 44 18 61 20 4 10 mg/l A-T-049w
Selenium (dissolved)A# 2 <5 65 <2 <2 <2 <2 <50 µg/l A-T-025w
Sodium (dissolved)A# 96 124 484 91 2040 984 49 82 mg/l A-T-049w
Page 3 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256
Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80
Depth To Bottom
Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A
Strontium (dissolved)A 676 1490 7580 1170 4800 3460 475 527 µg/l A-T-025w
Vanadium (dissolved)A# <2 102 <50 3 5 5 <2 <50 µg/l A-T-025w
Zinc (dissolved)A# 12 489 <50 <2 4 12 <2 740 µg/l A-T-025w
Page 4 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256
Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80
Depth To Bottom
Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A
TPH CWG
Ali >C5-C6 (w)A# <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-022w
Ali >C6-C8 (w)A# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-022w
Ali >C8-C10 (w)A# <1 <1 <15 <1 <1 <1 <1 164 µg/l A-T-022w
Ali >C10-C12 (w)A# <5 <5 <5 <5 <5 <5 <5 22 µg/l A-T-023w
Ali >C12-C16 (w)A# <5 <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w
Ali >C16-C21 (w)A# <5 <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w
Ali >C21-C35 (w)A# <5 <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w
Total Aliphatics (w)A <5 <5 23 <5 <5 <5 <5 186 µg/l A-T-022+23w
Aro >C5-C7 (w)A# <1 <1 <1 <1 <1 <1 <1 11 µg/l A-T-022w
Aro >C7-C8 (w)A# <1 <1 <1 <1 <1 <1 <1 116 µg/l A-T-022w
Aro >C8-C9 (w)A# <1 <1 <5 <1 <1 <1 <1 30 µg/l A-T-022w
Aro >C9-C10 (w)A# <1 <1 <5 <1 <1 <1 <1 4 µg/l A-T-022w
Aro >C10-C12 (w)A# <5 <5 <5 <5 <5 <5 <5 360 µg/l A-T-023w
Aro >C12-C16 (w)A# <5 <5 <5 <5 <5 <5 <5 26 µg/l A-T-023w
Aro >C16-C21 (w)A# <5 <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w
Aro >C21-C35 (w)A# <5 <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w
Total Aromatics (w)A <5 <5 8 <5 <5 <5 <5 546 µg/l A-T-022+23w
TPH (Ali & Aro) (w)A <5 <5 31 <5 <5 <5 <5 732 µg/l A-T-022+23w
BTEX - Benzene (w)A# <1 <1 <1 <1 <1 <1 <1 11 µg/l A-T-022w
BTEX - Toluene (w)A# <1 <1 <1 <1 <1 <1 <1 116 µg/l A-T-022w
BTEX - Ethyl Benzene (w)A# <1 <1 <1 <1 <1 <1 <1 3 µg/l A-T-022w
BTEX - m & p Xylene (w)A# <1 <1 <5 <1 <1 <1 <1 7 µg/l A-T-022w
BTEX - o Xylene (w)A# <1 <1 <1 <1 <1 <1 <1 13 µg/l A-T-022w
MTBE (w)A# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-022w
Page 5 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256
Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80
Depth To Bottom
Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A
PAH 16MS (w)
Acenaphthene (w)A# <0.01 <0.01 0.02 0.02 <0.01 <0.01 <0.01 0.06 µg/l A-T-019w
Acenaphthylene (w)A# <0.01 <0.01 <0.01 0.02 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Anthracene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(a)anthracene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(a)pyrene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(b)fluoranthene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(ghi)perylene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(k)fluoranthene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Chrysene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Dibenzo(ah)anthracene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Fluoranthene (w)A# <0.01 <0.01 0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Fluorene (w)A# <0.01 <0.01 0.02 0.03 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Indeno(123-cd)pyrene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Naphthalene (w)A# <0.01 <0.01 0.01 0.38 <0.01 <0.01 <0.01 32.90 µg/l A-T-019w
Phenanthrene (w)A# <0.01 <0.01 0.04 0.02 <0.01 <0.01 <0.01 0.01 µg/l A-T-019w
Pyrene (w)A# <0.01 <0.01 0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
PAH (total 16) (w)A# <0.01 <0.01 0.11 0.47 <0.01 <0.01 <0.01 32.97 µg/l A-T-019w
Page 6 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256
Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80
Depth To Bottom
Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A
SVOC (w)
2,4,5-TrichlorophenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
2,4,6-TrichlorophenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
2,4-DichlorophenolA <1 <1 <10 <1 <1 <1 <1 3 µg/l A-T-052w
2,4-DimethylphenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
2,4-DinitrotolueneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
2,6-DinitrotolueneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
2-ChloronaphthaleneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
2-ChlorophenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
2-MethylnaphthaleneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
2-MethylphenolA <1 <1 <10 7 <1 <1 <1 2 µg/l A-T-052w
2-NitrophenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
4-Bromophenyl phenyl etherA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
4-Chloro-3-methylphenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Bis(2-chloroisopropyl)etherA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
2,4-DinitrophenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
4,6-Dinitro-2-methylphenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
4-MethylphenolA <1 <1 <10 1 <1 <1 <1 4 µg/l A-T-052w
4-NitrophenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Acenaphthene A <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
AcenaphthyleneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Anthracene A <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Bis(2-chloroethyl)etherA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Bis(2-chloroethoxy)methaneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Bis(2-ethylhexyl)phthalateA <2 <2 <20 <2 <2 <2 <2 <2 µg/l A-T-052w
Benzo(a)anthraceneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Butylbenzyl phthalate A <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Benzo(b)fluorantheneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Benzo(k)fluorantheneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Benzo(a)pyrene A <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Benzo(ghi)peryleneA <1 <1 <10 <1 <1 <1 4 <1 µg/l A-T-052w
CarbazoleA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
ChryseneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Page 7 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256
Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80
Depth To Bottom
Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A
DibenzofuranA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
n-DibutylphthalateA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
n-DioctylphthalateA <5 <5 <50 <5 <5 <5 <5 <5 µg/l A-T-052w
n-Nitroso-n-dipropylamineA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Diethyl phthalateA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Dimethyl phthalateA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Dibenzo(ah)anthraceneA <1 <1 <10 <1 <1 <1 1 <1 µg/l A-T-052w
Fluorene A <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
FluorantheneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
HexachlorobenzeneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
PentachlorophenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Phenol A <1 <1 222 3 <1 <1 <1 5 µg/l A-T-052w
HexachloroethaneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
NitrobenzeneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Naphthalene A <1 <1 <10 <1 <1 <1 <1 21 µg/l A-T-052w
IsophoroneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
HexachlorocyclopentadieneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Phenanthrene A <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Pyrene A <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Indeno(1,2,3-cd)pyreneA <1 <1 <10 <1 <1 <1 3 <1 µg/l A-T-052w
PeryleneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w
Page 8 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256
Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80
Depth To Bottom
Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A
VOC (w)
DichlorodifluoromethaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
ChloromethaneA# <1 <1 <1 <1 <1 <1 <1 3 µg/l A-T-006w
Vinyl ChlorideA# <1 <1 <1 <1 <1 <1 <1 111 µg/l A-T-006w
BromomethaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
ChloroethaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
TrichlorofluoromethaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
trans 1,2-DichloroetheneA# <1 <1 <1 <1 <1 <1 <1 56 µg/l A-T-006w
DichloromethaneA <5 <5 <5 <5 <5 <5 <5 <5 µg/l A-T-006w
Carbon DisulphideA# <1 <1 <1 <1 1 <1 <1 4 µg/l A-T-006w
1,1-DichloroetheneA# 2 <1 <1 <1 <1 <1 <1 2373 µg/l A-T-006w
1,1-DichloroethaneA# <1 <1 <1 <1 <1 <1 <1 434 µg/l A-T-006w
cis 1,2-DichloroetheneA# <1 <1 <1 <1 <1 <1 <1 176 µg/l A-T-006w
BromochloromethaneA# <5 <5 <5 <5 <5 <5 <5 <5 µg/l A-T-006w
ChloroformA# <25 <25 <25 <25 423 <25 <25 53 µg/l A-T-006w
2,2-DichloropropaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
1,2-DichloroethaneA# <2 <2 <2 <2 <2 <2 <2 142 µg/l A-T-006w
1,1,1-TrichloroethaneA# <1 <1 <1 <1 <1 <1 <1 156 µg/l A-T-006w
1,1-DichloropropeneA# <1 <1 <1 <1 <1 <1 <1 28 µg/l A-T-006w
Benzene A# <1 <1 <1 <1 <1 <1 <1 13 µg/l A-T-006w
Carbon TetrachlorideA# <1 <1 <1 <1 55 <1 <1 <1 µg/l A-T-006w
DibromomethaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
1,2-DichloropropaneA# <1 <1 <1 <1 <1 <1 <1 5 µg/l A-T-006w
BromodichloromethaneA# <10 <10 <10 <10 <10 <10 <10 <10 µg/l A-T-006w
TrichloroetheneA# <1 <1 <1 <1 <1 <1 <1 1455 µg/l A-T-006w
cis 1,3-DichloropropeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
trans 1,3-DichloropropeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
1,1,2-TrichloroethaneA# <1 <1 <1 <1 <1 <1 <1 3671 µg/l A-T-006w
Toluene A# <1 <1 <1 <1 <1 <1 <1 132 µg/l A-T-006w
1,3-DichloropropaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
DibromochloromethaneA# <3 <3 <3 <3 <3 <3 <3 <3 µg/l A-T-006w
1,2-DibromoethaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
TetrachloroetheneA# <1 <1 <1 <1 <1 <1 <1 176 µg/l A-T-006w
Page 9 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256
Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80
Depth To Bottom
Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A
1,1,1,2-TetrachloroethaneA <1 <1 <1 <1 <1 <1 <1 89 µg/l A-T-006w
ChlorobenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
EthylbenzeneA# <1 <1 <1 <1 <1 <1 <1 3 µg/l A-T-006w
m & p XyleneA# <1 <1 <1 <1 <1 <1 <1 7 µg/l A-T-006w
BromoformA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
StyreneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
1,1,2,2-TetrachloroethaneA <1 <1 <1 <1 <1 <1 <1 2932 µg/l A-T-006w
o-XyleneA# <1 <1 <1 <1 <1 <1 <1 11 µg/l A-T-006w
1,2,3-TrichloropropaneA# <1 <1 <1 <1 <1 <1 <1 415 µg/l A-T-006w
IsopropylbenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
BromobenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
2-ChlorotolueneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
n-propylbenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
4-ChlorotolueneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
1,2,4-TrimethylbenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
4-IsopropyltolueneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
1,3,5-TrimethylbenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
1,2-DichlorobenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
1,4-DichlorobenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
sec-ButylbenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
tert-ButylbenzeneA# <2 <2 <2 <2 <2 <2 <2 9 µg/l A-T-006w
1,3-DichlorobenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
n-butylbenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
1,2-Dibromo-3-chloropropaneA# <2 <2 <2 <2 <2 <2 <2 <2 µg/l A-T-006w
1,2,4-TrichlorobenzeneA# <3 <3 <3 <3 <3 <3 <3 <3 µg/l A-T-006w
1,2,3-TrichlorobenzeneA# <3 <3 <3 <3 <3 <3 <3 <3 µg/l A-T-006w
HexachlorobutadieneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w
Page 10 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23
Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00
Depth To Bottom
Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A
pH (w)A# 7.66 7.98 7.47 9.11 7.74 7.67 - pH A-T-031w
Electrical conductivity @ 20degC (w)A# 11000 7100 15700 24600 17500 12600 - µs/cm A-T-037w
COD (settled)A# 150 55 170 210 220 110 - mg/l A-T-034w
BOD (settled, 5 day)A 5 1 2 14 4 <1 - mg/l A-T-048
Hardness TotalA# 1807 1680 3120 772 4930 3720 - mg/l Ca
CO3
A-T-049w
Chloride (w)A# 869 2640 6590 3870 7880 4930 - mg/l A-T-026w
Nitrite (w)A# <0.10 <0.10 <0.10 0.11 0.12 <0.10 - mg/l A-T-026w
Nitrate (w) A# <0.50 19.00 <0.50 <0.50 <0.50 <0.50 - mg/l A-T-026w
Sulphate (w)A# 5820 392 981 10600 1073 1456 - mg/l A-T-026w
Cyanide (total) (w)A# <0.005 <0.005 <0.005 0.307 <0.005 <0.005 - mg/l A-T-042wTCN
Phenols - Total by HPLC (w)A <0.01 0.11 0.47 0.74 0.36 0.44 - mg/l A-T-050w
Sulphide (w)A <0.1 0.3 0.1 <0.1 <0.1 <0.1 - mg/l A-T-S2-w
DOC (w)A# 13.7 2.2 5.3 35.5 4.5 3.4 - mg/l A-T-032w
Aluminium (dissolved)A 32 21 18 155 21 29 - µg/l A-T-049w
Arsenic (dissolved)A# 7480 3 9 57 4 3 - µg/l A-T-025w
Boron (dissolved)A# 1650 185 934 11700 <20 22 - µg/l A-T-025w
Barium (dissolved)A# <50 95 111 <50 104 46 - µg/l A-T-025w
Beryllium (dissolved)A# <50 <2 <2 <50 <2 <2 - µg/l A-T-025w
Cadmium (dissolved)A# <50 <2 <2 <50 <2 <2 - µg/l A-T-025w
Calcium (dissolved)A# 552 395 652 284 1230 867 - mg/l A-T-049w
Copper (dissolved)A# <50 <2 <2 <50 <2 <2 - µg/l A-T-025w
Chromium (dissolved)A# <50 5 9 <50 7 4 - µg/l A-T-025w
Chromium (hexavalent) (w)A# <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 - mg/l A-T-040w
Chromium (trivalent) (w) <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 - mg/l Calc
Iron (dissolved)A# 14700 204 799 <500 63 1310 - µg/l A-T-025w
Lead (dissolved)A# <50 <2 <2 <50 <2 <2 - µg/l A-T-025w
Manganese (dissolved)A# 3760 1150 1390 <50 220 801 - µg/l A-T-025w
Magnesium (dissolved)A# 104 168 361 15 451 377 - mg/l A-T-049w
Mercury (dissolved)A# <5.0 <0.2 <0.2 <5.0 <0.2 <0.2 - µg/l A-T-025w
Nickel (dissolved)A# <50 16 13 <50 10 20 - µg/l A-T-025w
Potassium (dissolved)A# 134 25 29 31 21 20 - mg/l A-T-049w
Selenium (dissolved)A# <50 <2 <2 <50 <2 <2 - µg/l A-T-025w
Sodium (dissolved)A# 888 1010 2800 6050 2920 2070 - mg/l A-T-049w
Page 11 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23
Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00
Depth To Bottom
Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A
Strontium (dissolved)A 1290 1590 3170 1170 2500 2450 - µg/l A-T-025w
Vanadium (dissolved)A# <50 3 5 <50 5 2 - µg/l A-T-025w
Zinc (dissolved)A# <50 15 3 <50 5 7 - µg/l A-T-025w
Page 12 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23
Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00
Depth To Bottom
Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A
TPH CWG
Ali >C5-C6 (w)A# <1 <1 <1 <1 <1 <1 - µg/l A-T-022w
Ali >C6-C8 (w)A# <1 <1 <1 <1 <1 <1 - µg/l A-T-022w
Ali >C8-C10 (w)A# <1 <1 <1 <1 <1 <1 - µg/l A-T-022w
Ali >C10-C12 (w)A# <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w
Ali >C12-C16 (w)A# <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w
Ali >C16-C21 (w)A# <5 <5 <5 <5 <5 <5 19 µg/l A-T-023w
Ali >C21-C35 (w)A# <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w
Total Aliphatics (w)A <5 <5 <5 <5 <5 <5 19 µg/l A-T-022+23w
Aro >C5-C7 (w)A# <1 <1 <1 5 <1 <1 - µg/l A-T-022w
Aro >C7-C8 (w)A# <1 <1 <1 1 <1 <1 - µg/l A-T-022w
Aro >C8-C9 (w)A# <1 <1 <1 4 <1 <1 - µg/l A-T-022w
Aro >C9-C10 (w)A# <1 <1 <1 4 <1 <1 - µg/l A-T-022w
Aro >C10-C12 (w)A# <5 <5 <5 26 <5 <5 <5 µg/l A-T-023w
Aro >C12-C16 (w)A# <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w
Aro >C16-C21 (w)A# <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w
Aro >C21-C35 (w)A# <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w
Total Aromatics (w)A <5 <5 <5 40 <5 <5 <5 µg/l A-T-022+23w
TPH (Ali & Aro) (w)A <5 <5 <5 40 <5 <5 19 µg/l A-T-022+23w
BTEX - Benzene (w)A# <1 <1 <1 5 <1 <1 - µg/l A-T-022w
BTEX - Toluene (w)A# <1 <1 <1 1 <1 <1 - µg/l A-T-022w
BTEX - Ethyl Benzene (w)A# <1 <1 <1 <1 <1 <1 - µg/l A-T-022w
BTEX - m & p Xylene (w)A# <1 <1 <1 2 <1 <1 - µg/l A-T-022w
BTEX - o Xylene (w)A# <1 <1 <1 1 <1 <1 - µg/l A-T-022w
MTBE (w)A# <1 <1 <1 <1 <1 <1 - µg/l A-T-022w
Page 13 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23
Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00
Depth To Bottom
Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A
PAH 16MS (w)
Acenaphthene (w)A# <0.01 <0.01 <0.01 0.21 <0.01 <0.01 <0.01 µg/l A-T-019w
Acenaphthylene (w)A# <0.01 <0.01 <0.01 0.02 <0.01 <0.01 <0.01 µg/l A-T-019w
Anthracene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(a)anthracene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(a)pyrene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(b)fluoranthene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(ghi)perylene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Benzo(k)fluoranthene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Chrysene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Dibenzo(ah)anthracene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Fluoranthene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Fluorene (w)A# <0.01 <0.01 <0.01 0.07 <0.01 <0.01 <0.01 µg/l A-T-019w
Indeno(123-cd)pyrene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
Naphthalene (w)A# 0.03 <0.01 <0.01 33.73 0.01 <0.01 <0.01 µg/l A-T-019w
Phenanthrene (w)A# <0.01 <0.01 <0.01 0.07 <0.01 <0.01 <0.01 µg/l A-T-019w
Pyrene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w
PAH (total 16) (w)A# 0.03 <0.01 <0.01 34.10 0.01 <0.01 <0.01 µg/l A-T-019w
Page 14 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23
Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00
Depth To Bottom
Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A
SVOC (w)
2,4,5-TrichlorophenolA <1 <1 <1 5 <1 <1 - µg/l A-T-052w
2,4,6-TrichlorophenolA <1 <1 <1 1 <1 <1 - µg/l A-T-052w
2,4-DichlorophenolA <1 <1 <1 1 <1 <1 - µg/l A-T-052w
2,4-DimethylphenolA <1 <1 <1 7 <1 <1 - µg/l A-T-052w
2,4-DinitrotolueneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
2,6-DinitrotolueneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
2-ChloronaphthaleneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
2-ChlorophenolA <1 <1 <1 3 <1 <1 - µg/l A-T-052w
2-MethylnaphthaleneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
2-MethylphenolA <1 <1 <1 5 <1 <1 - µg/l A-T-052w
2-NitrophenolA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
4-Bromophenyl phenyl etherA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
4-Chloro-3-methylphenolA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Bis(2-chloroisopropyl)etherA <1 5 <1 <1 <1 <1 - µg/l A-T-052w
2,4-DinitrophenolA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
4,6-Dinitro-2-methylphenolA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
4-MethylphenolA <1 <1 <1 43 <1 <1 - µg/l A-T-052w
4-NitrophenolA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Acenaphthene A <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
AcenaphthyleneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Anthracene A <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Bis(2-chloroethyl)etherA <1 8 <1 <1 <1 <1 - µg/l A-T-052w
Bis(2-chloroethoxy)methaneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Bis(2-ethylhexyl)phthalateA <2 <2 <2 <2 <2 <2 - µg/l A-T-052w
Benzo(a)anthraceneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Butylbenzyl phthalate A <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Benzo(b)fluorantheneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Benzo(k)fluorantheneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Benzo(a)pyrene A <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Benzo(ghi)peryleneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
CarbazoleA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
ChryseneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Page 15 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23
Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00
Depth To Bottom
Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A
DibenzofuranA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
n-DibutylphthalateA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
n-DioctylphthalateA <5 <5 <5 <5 <5 <5 - µg/l A-T-052w
n-Nitroso-n-dipropylamineA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Diethyl phthalateA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Dimethyl phthalateA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Dibenzo(ah)anthraceneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Fluorene A <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
FluorantheneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
HexachlorobenzeneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
PentachlorophenolA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Phenol A <1 <1 <1 87 <1 <1 - µg/l A-T-052w
HexachloroethaneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
NitrobenzeneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Naphthalene A <1 <1 <1 23 <1 <1 - µg/l A-T-052w
IsophoroneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
HexachlorocyclopentadieneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Phenanthrene A <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Pyrene A <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Indeno(1,2,3-cd)pyreneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
PeryleneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w
Page 16 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23
Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00
Depth To Bottom
Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A
VOC (w)
DichlorodifluoromethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
ChloromethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
Vinyl ChlorideA# <1 <1 <1 3 <1 <1 - µg/l A-T-006w
BromomethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
ChloroethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
TrichlorofluoromethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
trans 1,2-DichloroetheneA# <1 4 <1 <1 <1 <1 - µg/l A-T-006w
DichloromethaneA <5 <5 <5 <5 <5 <5 - µg/l A-T-006w
Carbon DisulphideA# 793 <1 <1 <1 <1 <1 - µg/l A-T-006w
1,1-DichloroetheneA# 3 1 <1 2 <1 <1 - µg/l A-T-006w
1,1-DichloroethaneA# <1 4 <1 2 <1 <1 - µg/l A-T-006w
cis 1,2-DichloroetheneA# 3 9 <1 9 <1 <1 - µg/l A-T-006w
BromochloromethaneA# <5 <5 <5 <5 <5 <5 - µg/l A-T-006w
ChloroformA# 867 <25 <25 <25 <25 <25 - µg/l A-T-006w
2,2-DichloropropaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
1,2-DichloroethaneA# <2 12 <2 <2 <2 <2 - µg/l A-T-006w
1,1,1-TrichloroethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
1,1-DichloropropeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
Benzene A# <1 <1 <1 7 <1 <1 - µg/l A-T-006w
Carbon TetrachlorideA# 1316 <1 <1 <1 <1 <1 - µg/l A-T-006w
DibromomethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
1,2-DichloropropaneA# <1 4 <1 <1 <1 <1 - µg/l A-T-006w
BromodichloromethaneA# <10 <10 <10 <10 <10 <10 - µg/l A-T-006w
TrichloroetheneA# 2 4 <1 2 <1 <1 - µg/l A-T-006w
cis 1,3-DichloropropeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
trans 1,3-DichloropropeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
1,1,2-TrichloroethaneA# 6 3 <1 <1 <1 <1 - µg/l A-T-006w
Toluene A# <1 <1 <1 2 <1 <1 - µg/l A-T-006w
1,3-DichloropropaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
DibromochloromethaneA# <3 <3 <3 <3 <3 <3 - µg/l A-T-006w
1,2-DibromoethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
TetrachloroetheneA# 14 <1 <1 3 <1 <1 - µg/l A-T-006w
Page 17 of 18
Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23
Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00
Depth To Bottom
Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14
Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A
1,1,1,2-TetrachloroethaneA <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
ChlorobenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
EthylbenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
m & p XyleneA# <1 <1 <1 1 <1 <1 - µg/l A-T-006w
BromoformA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
StyreneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
1,1,2,2-TetrachloroethaneA 6 <1 <1 <1 <1 <1 - µg/l A-T-006w
o-XyleneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
1,2,3-TrichloropropaneA# 1 <1 <1 <1 <1 <1 - µg/l A-T-006w
IsopropylbenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
BromobenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
2-ChlorotolueneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
n-propylbenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
4-ChlorotolueneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
1,2,4-TrimethylbenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
4-IsopropyltolueneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
1,3,5-TrimethylbenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
1,2-DichlorobenzeneA# <1 <1 <1 5 <1 <1 - µg/l A-T-006w
1,4-DichlorobenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
sec-ButylbenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
tert-ButylbenzeneA# <2 <2 <2 <2 <2 <2 - µg/l A-T-006w
1,3-DichlorobenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
n-butylbenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
1,2-Dibromo-3-chloropropaneA# <2 <2 <2 <2 <2 <2 - µg/l A-T-006w
1,2,4-TrichlorobenzeneA# <3 <3 <3 9 <3 <3 - µg/l A-T-006w
1,2,3-TrichlorobenzeneA# <3 <3 <3 <3 <3 <3 - µg/l A-T-006w
HexachlorobutadieneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w
Page 18 of 18
REPORT NOTES
Notes - Soil chemical analysis All results are reported as dry weight (<40°C). For samples with Matrix Codes 1 - 6 natural stones >10mm are removed or excluded from the sample prior to analysis and reported results corrected to a whole sample basis. For samples with Matrix Code 7 the whole sample is dried and crushed prior to analysis. Notes - General
This report shall not be reproduced, except in full, without written approval from Envirolab. Subscript "A" indicates analysis performed on the sample as received. "D" indicates analysis performed on the dried sample, crushed to pass a 2mm sieve, unless asbestos is found to be present in which case all analysis is performed on the sample as received. All analysis is performed on the dried and crushed sample for samples with Matrix Code 7 and this supercedes any "A" subscripts. All analysis is performed on the sample as received for soil samples from outside the European Union and this supercedes any "D" subscripts. Superscript "M" indicates method accredited to MCERTS. If results are in italic font they are associated with an AQC failure. These are not accredited and are unreliable. A deviating samples report is appended and will indicate if samples or tests have been found to be deviating. Any test results affected may not be an accurate record of the concentration at the time of sampling and, as a result, may be invalid. TPH analysis of water by method A-T-007 Free and visible oils are excluded from the sample used for analysis so that the reported result represents the dissolved phase only. Asbestos in soil Asbestos in soil analysis is performed on a dried aliquot of the submitted sample and cannot guarantee to identify asbestos if present as discrete fibres/fragments. Stones etc. are not removed from the sample prior to analysis. Quantification of asbestos is a 3 stage process including visual identification, hand picking and weighing and fibre counting by sedimentation/phase contrast optical microscopy if required. If asbestos is identified a being present but is not in a form that is suitable for analysis by hand picking and weighing (normally if the asbestos is present as free fibres) quantification by sedimentation is performed. Where ACMs are found a percentage asbestos is assigned to each with reference to 'HSG264, Asbestos: The survey guide' and the calculated asbestos content is expressed as a percentage of the dried soil sample aliquot used. Predominant Matrix Codes: 1 = SAND, 2 = LOAM, 3 = CLAY, 4 = LOAM/SAND, 5 = SAND/CLAY, 6 = CLAY/LOAM, 7 = OTHER. Samples with Matrix Code 7 are not predominantly a SAND/LOAM/CLAY mix and are not covered by our BSEN 17025 or MCERTS accreditations. Secondary Matrix Codes: A = contains stones, B = contains construction rubble, C = contains visible hydrocarbons, D = contains glass/metal, E = contains roots/twigs. IS indicates Insufficient sample for analysis. NDP indicates No Determination Possible. NAD indicates No Asbestos Detected. N/A indicates Not Applicable. Superscript # indicates method accredited to ISO 17025. Analytical results reflect the quality of the sample at the time of analysis only. Opinions and interpretations expressed are outside the scope of our accreditation. Please contact us if you need any further information.
Page 1 of 9
Units 7 & 8 Sandpits Business Park Mottram Road, Hyde, Cheshire, SK14 3AR
FINAL ANALYTICAL TEST REPORT
Envirolab Job Number: 14/06203 Issue Number: 1 Date: 17 November, 2014 Client: RSK Environment Helsby Spring Lodge 172 Chester Road Helsby Cheshire UK WA6 0AR Project Manager: Rachel Hagan/Steven Pettitt Project Name: Mersey Gateway Project Ref: 321315 Order No: N/A Date Samples Received: 07/11/14 Date Instructions Received: 10/11/14 Date Analysis Completed: 16/11/14 Prepared by: Approved by:
Melanie Marshall Lianne Bromiley Laboratory Coordinator Senior Client Manager
Page 2 of 9
Envirolab Job Number: 14/06203 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06203/1 14/06203/2
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX1 BHXX2
Depth to Top 19.00 53.00
Depth To Bottom
Date Sampled 07-Nov-14 07-Nov-14
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
pH (w)A# 7.16 7.07 pH A-T-031w
Electrical conductivity @ 20degC (w) A# 11900 14200 µs/cm A-T-037w
COD (settled)A# 220 140 mg/l A-T-034w
BOD (settled, 5 day)A <1 <1 mg/l A-T-048
Hardness TotalA# 3020 6690 mg/l Ca
CO3
A-T-049w
Chloride (w)A# 3530 5930 mg/l A-T-026w
Nitrite (w) A# <0.10 <0.10 mg/l A-T-026w
Nitrate (w) A# <0.50 <0.50 mg/l A-T-026w
Sulphate (w)A# 1998 588 mg/l A-T-026w
Cyanide (total) (w)A# <0.005 <0.005 mg/l A-T-042wTCN
Phenols - Total by HPLC (w)A 0.05 0.17 mg/l A-T-050w
Sulphide (w)A <0.1 <0.1 mg/l A-T-S2-w
DOC (w)A# 4.3 2.1 mg/l A-T-032w
Aluminium (dissolved)A <10 <10 µg/l A-T-049w
Arsenic (dissolved)A# 421 3 µg/l A-T-025w
Boron (dissolved)A# 683 67 µg/l A-T-025w
Barium (dissolved)A# 108 119 µg/l A-T-025w
Beryllium (dissolved)A# <1 <1 µg/l A-T-025w
Cadmium (dissolved)A# <1 <1 µg/l A-T-025w
Calcium (dissolved)A# 724 1510 mg/l A-T-049w
Copper (dissolved)A# <1 <1 µg/l A-T-025w
Chromium (dissolved)A# 3 2 µg/l A-T-025w
Chromium (hexavalent) (w)A# <0.05 <0.05 mg/l A-T-040w
Chromium (trivalent) (w) <0.05 <0.05 mg/l Calc
Iron (dissolved)A# 11060 108 µg/l A-T-025w
Lead (dissolved)A# <1 <1 µg/l A-T-025w
Manganese (dissolved)A# 2806 942 µg/l A-T-025w
Magnesium (dissolved)A# 293 709 mg/l A-T-049w
Mercury (dissolved)A# <0.1 <0.1 µg/l A-T-025w
Nickel (dissolved)A# 4 9 µg/l A-T-025w
Potassium (dissolved)A# 72 19 mg/l A-T-049w
Selenium (dissolved)A# 1 <1 µg/l A-T-025w
Sodium (dissolved)A# 1900 1040 mg/l A-T-049w
Page 3 of 9
Envirolab Job Number: 14/06203 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06203/1 14/06203/2
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX1 BHXX2
Depth to Top 19.00 53.00
Depth To Bottom
Date Sampled 07-Nov-14 07-Nov-14
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
Strontium (dissolved)A 6490 4130 µg/l A-T-025w
Vanadium (dissolved)A# 1 1 µg/l A-T-025w
Zinc (dissolved)A# 3 13 µg/l A-T-025w
TPH CWG
Ali >C5-C6 (w)A# <1 <1 µg/l A-T-022w
Ali >C6-C8 (w)A# <1 <1 µg/l A-T-022w
Ali >C8-C10 (w)A# <1 <1 µg/l A-T-022w
Ali >C10-C12 (w)A# <5 <5 µg/l A-T-023w
Ali >C12-C16 (w)A# <5 <5 µg/l A-T-023w
Ali >C16-C21 (w)A# <5 <5 µg/l A-T-023w
Ali >C21-C35 (w)A# <5 <5 µg/l A-T-023w
Total Aliphatics (w)A <5 <5 µg/l A-T-022+23w
Aro >C5-C7 (w)A# <1 <1 µg/l A-T-022w
Aro >C7-C8 (w)A# <1 <1 µg/l A-T-022w
Aro >C8-C9 (w)A# <1 <1 µg/l A-T-022w
Aro >C9-C10 (w)A# <1 <1 µg/l A-T-022w
Aro >C10-C12 (w)A# <5 <5 µg/l A-T-023w
Aro >C12-C16 (w)A# <5 <5 µg/l A-T-023w
Aro >C16-C21 (w)A# <5 <5 µg/l A-T-023w
Aro >C21-C35 (w)A# <5 <5 µg/l A-T-023w
Total Aromatics (w)A <5 <5 µg/l A-T-022+23w
TPH (Ali & Aro) (w)A <5 <5 µg/l A-T-022+23w
BTEX - Benzene (w)A# <1 <1 µg/l A-T-022w
BTEX - Toluene (w)A# <1 <1 µg/l A-T-022w
BTEX - Ethyl Benzene (w)A# <1 <1 µg/l A-T-022w
BTEX - m & p Xylene (w)A# <1 <1 µg/l A-T-022w
BTEX - o Xylene (w)A# <1 <1 µg/l A-T-022w
MTBE (w)A# <1 <1 µg/l A-T-022w
Page 4 of 9
Envirolab Job Number: 14/06203 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06203/1 14/06203/2
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX1 BHXX2
Depth to Top 19.00 53.00
Depth To Bottom
Date Sampled 07-Nov-14 07-Nov-14
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
PAH 16MS (w)
Acenaphthene (w)A# <0.01 <0.01 µg/l A-T-019w
Acenaphthylene (w)A# <0.01 <0.01 µg/l A-T-019w
Anthracene (w)A# <0.01 <0.01 µg/l A-T-019w
Benzo(a)anthracene (w)A# <0.01 <0.01 µg/l A-T-019w
Benzo(a)pyrene (w)A# <0.01 <0.01 µg/l A-T-019w
Benzo(b)fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w
Benzo(ghi)perylene (w)A# <0.01 <0.01 µg/l A-T-019w
Benzo(k)fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w
Chrysene (w)A# <0.01 <0.01 µg/l A-T-019w
Dibenzo(ah)anthracene (w)A# <0.01 <0.01 µg/l A-T-019w
Fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w
Fluorene (w)A# <0.01 <0.01 µg/l A-T-019w
Indeno(123-cd)pyrene (w)A# <0.01 <0.01 µg/l A-T-019w
Naphthalene (w)A# <0.01 <0.01 µg/l A-T-019w
Phenanthrene (w)A# <0.01 <0.01 µg/l A-T-019w
Pyrene (w)A# <0.01 <0.01 µg/l A-T-019w
PAH (total 16) (w)A# <0.01 <0.01 µg/l A-T-019w
Page 5 of 9
Envirolab Job Number: 14/06203 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06203/1 14/06203/2
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX1 BHXX2
Depth to Top 19.00 53.00
Depth To Bottom
Date Sampled 07-Nov-14 07-Nov-14
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
SVOC (w)
1,2,4-Trichlorobenzene SVOCA <1 <1 µg/l A-T-052w
1,2-Dichlorobenzene SVOCA <1 <1 µg/l A-T-052w
1,3-Dichlorobenzene SVOCA <1 <1 µg/l A-T-052w
1,4-Dichlorobenzene SVOCA <1 <1 µg/l A-T-052w
2,4,5-TrichlorophenolA <1 <1 µg/l A-T-052w
2,4,6-TrichlorophenolA <1 <1 µg/l A-T-052w
2,4-DichlorophenolA <1 <1 µg/l A-T-052w
2,4-DimethylphenolA <1 <1 µg/l A-T-052w
2,4-DinitrotolueneA <1 <1 µg/l A-T-052w
2,6-DinitrotolueneA <1 <1 µg/l A-T-052w
2-ChloronaphthaleneA <1 <1 µg/l A-T-052w
2-ChlorophenolA <1 <1 µg/l A-T-052w
2-MethylnaphthaleneA <1 <1 µg/l A-T-052w
2-MethylphenolA <1 <1 µg/l A-T-052w
2-NitrophenolA <1 <1 µg/l A-T-052w
4-Bromophenyl phenyl etherA <1 <1 µg/l A-T-052w
4-Chloro-3-methylphenolA <1 <1 µg/l A-T-052w
Bis(2-chloroisopropyl)etherA <1 <1 µg/l A-T-052w
2,4-DinitrophenolA <1 <1 µg/l A-T-052w
4,6-Dinitro-2-methylphenolA <1 <1 µg/l A-T-052w
4-MethylphenolA <1 <1 µg/l A-T-052w
4-NitrophenolA <1 <1 µg/l A-T-052w
Acenaphthene SVOCA <1 <1 µg/l A-T-052w
Acenaphthylene SVOCA <1 <1 µg/l A-T-052w
Anthracene SVOCA <1 <1 µg/l A-T-052w
Bis(2-chloroethyl)etherA <1 <1 µg/l A-T-052w
Bis(2-chloroethoxy)methaneA <1 <1 µg/l A-T-052w
Bis(2-ethylhexyl)phthalateA <2 <2 µg/l A-T-052w
Benzo(a)anthracene SVOCA <1 <1 µg/l A-T-052w
Butylbenzyl phthalate SVOCA <1 <1 µg/l A-T-052w
Benzo(b)fluoranthene SVOCA <1 <1 µg/l A-T-052w
Benzo(k)fluoranthene SVOCA <1 <1 µg/l A-T-052w
Page 6 of 9
Envirolab Job Number: 14/06203 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06203/1 14/06203/2
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX1 BHXX2
Depth to Top 19.00 53.00
Depth To Bottom
Date Sampled 07-Nov-14 07-Nov-14
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
Benzo(a)pyrene SVOCA <1 <1 µg/l A-T-052w
Benzo(ghi)perylene SVOCA <1 <1 µg/l A-T-052w
CarbazoleA <1 <1 µg/l A-T-052w
Chrysene SVOCA <1 <1 µg/l A-T-052w
DibenzofuranA <1 <1 µg/l A-T-052w
n-DibutylphthalateA <1 <1 µg/l A-T-052w
n-DioctylphthalateA 17 <5 µg/l A-T-052w
n-Nitroso-n-dipropylamineA <1 <1 µg/l A-T-052w
Diethyl phthalateA <1 <1 µg/l A-T-052w
Dimethyl phthalateA <1 <1 µg/l A-T-052w
Dibenzo(ah)anthracene SVOCA <1 <1 µg/l A-T-052w
Fluorene SVOCA <1 <1 µg/l A-T-052w
Fluoranthene SVOCA <1 <1 µg/l A-T-052w
Hexachlorobutadiene SVOCA <1 <1 µg/l A-T-052w
HexachlorobenzeneA <1 <1 µg/l A-T-052w
PentachlorophenolA <1 <1 µg/l A-T-052w
Phenol SVOCA <1 <1 µg/l A-T-052w
HexachloroethaneA <1 <1 µg/l A-T-052w
NitrobenzeneA <1 <1 µg/l A-T-052w
Naphthalene SVOCA <1 <1 µg/l A-T-052w
IsophoroneA <1 <1 µg/l A-T-052w
HexachlorocyclopentadieneA <1 <1 µg/l A-T-052w
Phenanthrene SVOCA <1 <1 µg/l A-T-052w
Pyrene SVOCA <1 <1 µg/l A-T-052w
Indeno(1,2,3-cd)pyrene SVOCA <1 <1 µg/l A-T-052w
PeryleneA <1 <1 µg/l A-T-052w
Page 7 of 9
Envirolab Job Number: 14/06203 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06203/1 14/06203/2
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX1 BHXX2
Depth to Top 19.00 53.00
Depth To Bottom
Date Sampled 07-Nov-14 07-Nov-14
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
VOC (w)
DichlorodifluoromethaneA# <1 <1 µg/l A-T-006w
ChloromethaneA# <1 <1 µg/l A-T-006w
Vinyl ChlorideA# <1 <1 µg/l A-T-006w
BromomethaneA# <1 <1 µg/l A-T-006w
ChloroethaneA# <1 <1 µg/l A-T-006w
TrichlorofluoromethaneA# <1 <1 µg/l A-T-006w
trans 1,2-DichloroetheneA# <1 <1 µg/l A-T-006w
Dichloromethane VOCA <5 <5 µg/l A-T-006w
Carbon DisulphideA# 6 <1 µg/l A-T-006w
1,1-DichloroetheneA# <1 <1 µg/l A-T-006w
1,1-DichloroethaneA# <1 <1 µg/l A-T-006w
cis 1,2-DichloroetheneA# <1 <1 µg/l A-T-006w
BromochloromethaneA# <5 <5 µg/l A-T-006w
ChloroformA# 838 <25 µg/l A-T-006w
2,2-DichloropropaneA# <1 <1 µg/l A-T-006w
1,2-DichloroethaneA# <2 <2 µg/l A-T-006w
1,1,1-TrichloroethaneA# <1 <1 µg/l A-T-006w
1,1-DichloropropeneA# <1 <1 µg/l A-T-006w
Benzene VOCA# <1 <1 µg/l A-T-006w
Carbon TetrachlorideA# 71 <1 µg/l A-T-006w
DibromomethaneA# <1 <1 µg/l A-T-006w
1,2-DichloropropaneA# <1 <1 µg/l A-T-006w
BromodichloromethaneA# <10 <10 µg/l A-T-006w
TrichloroetheneA# <1 <1 µg/l A-T-006w
cis 1,3-DichloropropeneA# <1 <1 µg/l A-T-006w
trans 1,3-DichloropropeneA# <1 <1 µg/l A-T-006w
1,1,2-TrichloroethaneA# <1 <1 µg/l A-T-006w
Toluene VOCA# <1 <1 µg/l A-T-006w
1,3-DichloropropaneA# <1 <1 µg/l A-T-006w
DibromochloromethaneA# <3 <3 µg/l A-T-006w
1,2-DibromoethaneA# <1 <1 µg/l A-T-006w
TetrachloroetheneA# <1 <1 µg/l A-T-006w
Page 8 of 9
Envirolab Job Number: 14/06203 Client Project Name: Mersey Gateway
Client Project Ref: 321315
Lab Sample ID 14/06203/1 14/06203/2
U
nit
s
M
eth
od
ref
Client Sample No
Client Sample ID BHXX1 BHXX2
Depth to Top 19.00 53.00
Depth To Bottom
Date Sampled 07-Nov-14 07-Nov-14
Sample Type Water - EW Water - EW
MCERTS Sample Matrix Code N/A N/A
1,1,1,2-TetrachloroethaneA <1 <1 µg/l A-T-006w
ChlorobenzeneA# <1 <1 µg/l A-T-006w
EthylbenzeneA# <1 <1 µg/l A-T-006w
m & p XyleneA# <1 <1 µg/l A-T-006w
BromoformA# <1 <1 µg/l A-T-006w
StyreneA# <1 <1 µg/l A-T-006w
1,1,2,2-TetrachloroethaneA <1 <1 µg/l A-T-006w
o-XyleneA# <1 <1 µg/l A-T-006w
1,2,3-TrichloropropaneA# <1 <1 µg/l A-T-006w
IsopropylbenzeneA# <1 <1 µg/l A-T-006w
BromobenzeneA# <1 <1 µg/l A-T-006w
2-ChlorotolueneA# <1 <1 µg/l A-T-006w
n-propylbenzeneA# <1 <1 µg/l A-T-006w
4-ChlorotolueneA# <1 <1 µg/l A-T-006w
1,2,4-TrimethylbenzeneA# <1 <1 µg/l A-T-006w
4-IsopropyltolueneA# <1 <1 µg/l A-T-006w
1,3,5-TrimethylbenzeneA# <1 <1 µg/l A-T-006w
1,2-DichlorobenzeneA# <1 <1 µg/l A-T-006w
1,4-DichlorobenzeneA# <1 <1 µg/l A-T-006w
sec-ButylbenzeneA# <1 <1 µg/l A-T-006w
tert-ButylbenzeneA# <2 <2 µg/l A-T-006w
1,3-DichlorobenzeneA# <1 <1 µg/l A-T-006w
n-butylbenzeneA# <1 <1 µg/l A-T-006w
1,2-Dibromo-3-chloropropaneA# <2 <2 µg/l A-T-006w
1,2,4-TrichlorobenzeneA# <3 <3 µg/l A-T-006w
1,2,3-TrichlorobenzeneA# <3 <3 µg/l A-T-006w
HexachlorobutadieneA# <1 <1 µg/l A-T-006w
Page 9 of 9
REPORT NOTES
Notes - Soil chemical analysis All results are reported as dry weight (<40°C). For samples with Matrix Codes 1 - 6 natural stones >10mm are removed or excluded from the sample prior to analysis and reported results corrected to a whole sample basis. For samples with Matrix Code 7 the whole sample is dried and crushed prior to analysis. Notes - General
This report shall not be reproduced, except in full, without written approval from Envirolab. Subscript "A" indicates analysis performed on the sample as received. "D" indicates analysis performed on the dried sample, crushed to pass a 2mm sieve, unless asbestos is found to be present in which case all analysis is performed on the sample as received. All analysis is performed on the dried and crushed sample for samples with Matrix Code 7 and this supercedes any "A" subscripts. All analysis is performed on the sample as received for soil samples from outside the European Union and this supercedes any "D" subscripts. Superscript "M" indicates method accredited to MCERTS. If results are in italic font they are associated with an AQC failure. These are not accredited and are unreliable. A deviating samples report is appended and will indicate if samples or tests have been found to be deviating. Any test results affected may not be an accurate record of the concentration at the time of sampling and, as a result, may be invalid. TPH analysis of water by method A-T-007 Free and visible oils are excluded from the sample used for analysis so that the reported result represents the dissolved phase only. Asbestos in soil Asbestos in soil analysis is performed on a dried aliquot of the submitted sample and cannot guarantee to identify asbestos if present as discrete fibres/fragments. Stones etc. are not removed from the sample prior to analysis. Quantification of asbestos is a 3 stage process including visual identification, hand picking and weighing and fibre counting by sedimentation/phase contrast optical microscopy if required. If asbestos is identified a being present but is not in a form that is suitable for analysis by hand picking and weighing (normally if the asbestos is present as free fibres) quantification by sedimentation is performed. Where ACMs are found a percentage asbestos is assigned to each with reference to 'HSG264, Asbestos: The survey guide' and the calculated asbestos content is expressed as a percentage of the dried soil sample aliquot used. Predominant Matrix Codes: 1 = SAND, 2 = LOAM, 3 = CLAY, 4 = LOAM/SAND, 5 = SAND/CLAY, 6 = CLAY/LOAM, 7 = OTHER. Samples with Matrix Code 7 are not predominantly a SAND/LOAM/CLAY mix and are not covered by our BSEN 17025 or MCERTS accreditations. Secondary Matrix Codes: A = contains stones, B = contains construction rubble, C = contains visible hydrocarbons, D = contains glass/metal, E = contains roots/twigs. IS indicates Insufficient sample for analysis. NDP indicates No Determination Possible. NAD indicates No Asbestos Detected. N/A indicates Not Applicable. Superscript # indicates method accredited to ISO 17025. Analytical results reflect the quality of the sample at the time of analysis only. Opinions and interpretations expressed are outside the scope of our accreditation. Please contact us if you need any further information.
MERSEY GATEWAY BRIDGE
MER-DJV-REP-ENV-03-333030 E 17 MARCH 2016
APPENDIX E – DEVELOPMENT TIMELINE
Time Line of development events at P1
Start Finish Event/Activity
24.06.2014 17.10.2014 Temporary Crossing of St Helens Canal
26.11.2014 01.12.2014 Guide wall for CFA
21.02.2015 21.02.2015 Intersite Moving from P0 to P1 (CFA)
22.01.2015 03.02.2015 Install Cofferdams (CFA Piling) (See Separate Sheet)
20.02.2015 10.03.2015 Bored Piling:
2015.02.21 2015.02.21 Pile 4
2015.02.23 2015.02.23 Pile 2
2015.02.26 2015.02.26 Pile 6
2015.03.03 2015.03.03 Pile 1
2015.03.05 2015.03.05 Pile 3
2015.03.10 2015.03.10 Pile 5
05.05.2015 30.06.2015 Excavation / Bracing / Pile Cropping
16.07.2015 16.07.2015 BHXX3 destroyed
27.07.2015 28.07.2015 Sonic Testing
29.07.2015 04.09.2015 Pile Cap
05.09.2015 09.09.2015 Pier shaft 1st Phase
09.09.2015 27.09.2015 MSS Support - Cofferdam (CFA)
15.09.2015 19.09.2015 Pier Head 1st
17.09.2015 27.09.2015 MSS Support - Bored Piling
20.09.2015 10.12.2015 Pier Head 2nd and Bearings
12.10.2015 23.10.2015 Waterproofing & Backfilling
02.02.2016 21.02.2016 MSS Construction: Span P0 to P1
22.02.2016 09.03.2016 MSS Construction: Span P1 to P2
MERSEY GATEWAY
BACHY SOLETANCHE
P1 Records
Move and SetupReinforcement for
cast-in-place piles Percentage Complete Comments
Toe Level Cut Off Level Length (m)
1 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
2 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
3 02/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
4 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
5 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
6 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
7 02/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
8 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
9 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
10 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
11 03/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
12 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
13 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
14 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
15 03/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
16 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
17 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
18 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
19 03/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
20 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
21 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
22 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
23 03/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
24 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
25 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
26 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
27 03/02/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
28 30/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
29 29/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
30 27/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
31 03/02/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
32 30/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
33 29/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
34 27/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
35 03/02/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
36 30/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
37 27/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
38 26/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
39 03/02/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
40 29/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
41 27/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
42 26/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B
43 30/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
44 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
45 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
46 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
47 02/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
48 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
49 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
50 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
51 02/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
52 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A
52 312.2 29616.000 5200% 0
Move and SetupReinforcement for
cast-in-place piles Percentage Complete Comments
Toe Level Cut Off Level Length (m)
1 24/01/2015 1 -2.7 8.45 11.15 100%
2 23/01/2015 1 -2.7 8.45 11.15 100%
3 22/01/2015 1 -2.7 8.45 11.15 100%
4 25/01/2015 1 -2.7 8.45 11.15 100%
5 24/01/2015 1 -2.7 8.45 11.15 100%
6 23/01/2015 1 -2.7 8.45 11.15 100%
7 22/01/2015 1 -2.7 8.45 11.15 100%
8 25/01/2015 1 -2.7 8.45 11.15 100%
9 24/01/2015 1 -2.7 8.45 11.15 100%
10 23/01/2015 1 -2.7 8.45 11.15 100%
11 22/01/2015 1 -2.7 8.45 11.15 100%
12 25/01/2015 1 -2.7 8.45 11.15 100%
13 24/01/2015 1 -2.7 8.45 11.15 100%
14 23/01/2015 1 -2.7 8.45 11.15 100%
15 22/01/2015 1 -2.7 8.45 11.15 100%
16 25/01/2015 1 -2.7 8.45 11.15 100%
17 24/01/2015 1 -2.7 8.45 11.15 100%
18 23/01/2015 1 -2.7 8.45 11.15 100%
19 22/01/2015 1 -2.7 8.45 11.15 100%
20 25/01/2015 1 -2.7 8.45 11.15 100%
21 24/01/2015 1 -2.7 8.45 11.15 100%
22 23/01/2015 1 -2.7 8.45 11.15 100%
23 22/01/2015 1 -2.7 8.45 11.15 100%
24 25/01/2015 1 -2.7 8.45 11.15 100%
25 24/01/2015 1 -2.7 8.45 11.15 100%
26 23/01/2015 1 -2.7 8.45 11.15 100%
27 22/01/2015 1 -2.7 8.45 11.15 100%
28 25/01/2015 1 -2.7 8.45 11.15 100%
29 24/01/2015 1 -2.7 8.45 11.15 100%
30 23/01/2015 1 -2.7 8.45 11.15 100%
31 22/01/2015 1 -2.7 8.45 11.15 100%
32 25/01/2015 1 -2.7 8.45 11.15 100%
33 24/01/2015 1 -2.7 8.45 11.15 100%
34 23/01/2015 1 -2.7 8.45 11.15 100%
35 22/01/2015 1 -2.7 8.45 11.15 100%
36 25/01/2015 1 -2.7 8.45 11.15 100%
37 24/01/2015 1 -2.7 8.45 11.15 100%
38 23/01/2015 1 -2.7 8.45 11.15 100%
39 22/01/2015 1 -2.7 8.45 11.15 100%
40 25/01/2015 1 -2.7 8.45 11.15 100%
41 24/01/2015 1 -2.7 8.45 11.15 100%
42 23/01/2015 1 -2.7 8.45 11.15 100%
43 22/01/2015 1 -2.7 8.45 11.15 100%
44 25/01/2015 1 -2.7 8.45 11.15 100%
45 24/01/2015 1 -2.7 8.45 11.15 100%
46 23/01/2015 1 -2.7 8.45 11.15 100%
47 22/01/2015 1 -2.7 8.45 11.15 100%
48 25/01/2015 1 -2.7 8.45 11.15 100%
49 24/01/2015 1 -2.7 8.45 11.15 100%
50 23/01/2015 1 -2.7 8.45 11.15 100%
51 22/01/2015 1 -2.7 8.45 11.15 100%
52 25/01/2015 1 -2.7 8.45 11.15 100%
52 312.2 0 5200% 0
Actual (Tonne)
Totals
Pile I.DDate
CompletedActual
Actual
Actual (Tonne)
Totals
P1 - Female Piles
Activity Bored cast-in-place piles
Pile I.DDate
CompletedActual
Actual
P1 - Male Piles
Activity Bored cast-in-place piles