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MERSEY GATEWAY BRIDGE PROJECT MERSEYLINK SECTION 3: NORTH APPROACH VIADUCT PIER 1(P1) CONCEPTUAL SITE MODEL MARCH 2016 MER-DJV-REP-ENV-03-333030

MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

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Page 1: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

MERSEY GATEWAY

BRIDGE PROJECT

MERSEYLINK

SECTION 3: NORTH APPROACH VIADUCT PIER 1(P1) CONCEPTUAL SITE MODEL MARCH 2016 MER-DJV-REP-ENV-03-333030

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MERSEY GATEWAY BRIDGE

MER-DJV-REP-ENV-03-333030 I 17 MARCH 2016

Document Control Sheet

Rev. Status Date By Check Approved

0 Preliminary for CJV / Regulator

Review 09/06/2015 JM DT DC

1 Final Issue following CJV / Informal Regulator Review

18/09/2015 JM SNN LIB

2 Final issue following formal

board review (Ref DWP00-60-07 4_Board_01)

04/12/15 JM LE LB

3 Final issue following formal

board review (Ref DWP00-60-07 4_Board_01)

17/03/16 RE SB LB

URS Infrastructure & Environment UK Limited Royal Court Basil Close Chesterfield Derbyshire S41 7SL Tel: +44 (0) 1246 209221 Fax: +44 (0) 1246 209229 Web: www.ursglobal.com

This submission is prepared on behalf of and submitted by the Merseylink Consortium in accordance with the provisions of the Design Development Agreement for the Mersey

Gateway Bridge Project executed between Halton Borough Council and FCC Construccion, Samsung C&T Corporation and Kier Infrastructure and Overseas Limited.

Prior to the entry into a Project Agreement (between Halton Borough Council, a "Board" created by Halton Borough Council and a project company created by the Merseylink

consortium) this report may not be relied upon by any other party (save for Halton Borough Council) without the prior written agreement of one or all of FCC Construccion,

Samsung C&T Corporation and Kier Infrastructure and Overseas Limited, save to the extent that (i) disclosure and/or reliance of this report is permitted in accordance with any

purpose and intention of or related to the Design Development Agreement and (ii) disclosure is permitted by Halton Borough Council to the Board, to its advisors and otherwise in

accordance or as contemplated by the terms of the draft project agreement circulated by Halton Borough Council to the Merseylink Consortium dated 31 July 2013.

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MERSEY GATEWAY BRIDGE

MER-DJV-REP-ENV-03-333030 II 17 MARCH 2016

CONTENTS

1 INTRODUCTION ...................................................................................................... 1

1.1 GENERAL INTRODUCTION .................................................................................... 1

1.2 BACKGROUND ........................................................................................................ 2

2 GEOLOGY ................................................................................................................ 4

2.1 INTRODUCTION ...................................................................................................... 4

2.2 MADE GROUND....................................................................................................... 4

2.3 ALLUVIAL DEPOSITS .............................................................................................. 4

2.4 GLACIAL DEPOSITS ................................................................................................ 4

2.5 SANDSTONE ........................................................................................................... 5

3 HYDROGEOLOGY ................................................................................................... 6

3.1 INTRODUCTION ...................................................................................................... 6

3.2 GROUNDWATER STRIKES ..................................................................................... 6

3.3 GROUNDWATER ELEVATIONS.............................................................................. 6

3.4 GROUNDWATER FLOW DIRECTION ..................................................................... 8

4 HYDROLOGY ......................................................................................................... 10

5 ASSESSMENT OF CONTAMINATION .................................................................. 11

5.1 FIELD OBSERVATIONS ........................................................................................ 11

5.2 ASSESSMENT OF SOIL CHEMICAL DATA .......................................................... 11

5.3 ASSESSMENT OF GROUNDWATER CHEMICAL DATA ...................................... 13

5.4 SUMMARY OF COMPOUNDS OF POTENTIAL CONCERN ................................. 17

5.5 EVIDENCE OF DENSE NON-AQUEOUS PHASE LIQUIDS (DNAPL)................... 17

6 CONCEPTUAL SITE MODEL ................................................................................ 19

6.1 INTRODUCTION .................................................................................................... 19

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MERSEY GATEWAY BRIDGE

MER-DJV-REP-ENV-03-333030 III 17 MARCH 2016

6.2 SOURCE ................................................................................................................ 19

6.3 PATHWAY .............................................................................................................. 19

6.4 RECEPTORS ......................................................................................................... 20

7 CONCLUSIONS ..................................................................................................... 21

8 REFERENCES ....................................................................................................... 24

FIGURES .......................................................................................................................... A

TABLES ............................................................................................................................ B

APPENDIX A – PHOTOS OF PIER 1 ............................................................................... A

APPENDIX B – BOREHOLE LOGS (BHXX1 – BHXX5) .................................................. B

APPENDIX C – LAB REPORTS (SOIL) ........................................................................... C

APPENDIX D – LABORATORY REPORTS (GROUNDWATER)..................................... D

APPENDIX E – DEVELOPMENT TIMELINE .................................................................... E

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MERSEY GATEWAY BRIDGE

MER-DJV-REP-ENV-03-333030 IV 17 MARCH 2016

FIGURES

Figure 1 – Borehole Location Plan for Pier 1 and Lines of Cross Section

Figure 2 – Pier 1 Geological Cross Sections

TABLES

Table 1 – Groundwater Level Monitoring Data for BHXX1-BHXX5

Table 2 – Soil Analytical Data for BHXX1-BHXX5

Table 3 – Groundwater Analytical Data for BHXX1-BHXX5

Table 4 – Pier 1 Solubility Assessment for Volatile Organic Compounds (VOCs)

APPENDICES

Appendix A – Photos of Pier 1

Appendix B – Borehole Logs (BHXX1-BHXX5)

Appendix C – Lab Reports (Soil)

Appendix D – Lab Reports (Groundwater)

Appendix E – Development Timeline

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1 Introduction

1.1 General Introduction

Following the measurement of elevated concentrations of chlorinated solvents in

borehole location BHXX3 which is very close to the secant wall which encloses the

long piles at Pier 1 (P1) it was decided that additional investigation to investigate the

potential for chlorinated solvents (at concentrations approaching saturation (i.e.

presence of DNAPL) was required within the secant wall.

This document presents a conceptual site model (CSM) that specifically relates only to

Pier P1 on the North Approach Viaduct (NAV)of the Mersey Gateway Bridge Project.

The CSM will characterise the chemical concentrations within the P1 secant wall and if

significant risks are identified (i.e. the potential presence of DNAPL which may migrate

down the shaft of the long piles) will be used to inform a remedial options appraisal

(ROA).

The objective of the P1 CSM report is not to assess if the construction works have had

an impact on concentrations of contaminants in groundwater in the area of the P1

structure. This type of assessment and discussion would be undertaken outwith the

CSM and PRA documents and in accordance with the mechanisms set out in the

WQMP. However, to allow comparison of the data to that of the works being

undertaken at P1, a time scale of the works including the installation of the secant wall

piling is provided within Appendix E. A brief summary of the piling activity is included

below for reference:

Piling at P1 time scale summary:

• 22nd January 2015 – 3rd February 2015: Installation of Cofferdams (CFA

Piling);

• 20th February 2015 – 10th March 2015: Bored Piling (Piles 1-6);

• 9th September 2015 - 27th September 2015: MSS Support (Cofferdam CFA

piling); and

• 17th September 2015 - 27th September 2015: MSS Support (Bored piling).

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The ROA will assess the options and the best overall approach to remediate the soil

and groundwater contained within the secant pile cut-off wall surrounding the existing

P1 piles, where elevated levels of chemicals of potential concern (COPC) have been

identified, to minimise potential risks to the underlying principal aquifer (Sandstone

bedrock). The COPC are predominantly chlorinated solvents including carbon

tetrachloride and chloroform.

1.2 Background

The secant wall was constructed (as recommended in the Piling Risk Assessment

(PRA) report (MER-DJV-REP-ENV-03-333007_REV9, October 2015) at P1 prior to

the commencement of the piling activities and its design was two-fold:

1. To form a barrier and prevent the migration of elevated concentrations of

COPC inflowing to the P1 structure via groundwater within the granular alluvial

deposits from sources of contamination identified during earlier phases of the

project to the north and west. This barrier extended into the top of the

underlying low permeability glacial clay deposits; and

2. To facilitate the planned construction of the pile cap for which a ‘dry’ dewatered

excavation is required.

Four boreholes BHXX1, BHXX2, BHXX4 and BHXX5 were drilled and installed with

monitoring wells within the secant pile cut-off wall at the P1 structure between

September 2014 and April 2015. Borehole BHXX3, which is located just a few metres

immediately to the north of the secant pile cut-off wall, is also assessed in order to

make a direct comparison between COPC concentrations inside the wall with those

immediately outside of the wall. BHXX3 is the closest borehole to P1 beyond the

secant wall boundary. As this report focuses on ground conditions specifically in the

area inside the secant wall, only BHXX1-BHXX5 have been assessed in this CSM.

Information concerning the CSM of the wider area surrounding P1, is presented in

North Abutment (N1) to Pier P10 Conceptual Site Model Report (Ref. MER-DJV-REP-

ENV-03-333032 Rev 0, August 2015)

It was not possible to undertake ground investigations directly within the P1 footprint in

the early phases of the project due to this area being under water (previously the area

was part of the St Helens Canal). During later phases of groundwater investigation

works (after this section of the St Helens Canal was infilled to form a temporary road /

reclaimed land), BHXX1, BHXX2 and BHXX3 were completed in October 2014, and

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BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred

on the P1 structure is shown on Figure 1. Photographs showing the Pier 1 site area

are presented in Appendix A.

Soil and groundwater sampling were undertaken at each of the locations between the

end of September 2014 and early May 2015. Elevated concentrations of COPC,

specifically carbon tetrachloride, have intermittently exceeded 15,000µg/l in

groundwater from BHXX3 relating to the shallow alluvial deposits. This led to a more

focussed CSM in the area of P1 being developed to better understand the distribution

of elevated concentrations of COPC, in particular chlorinated solvents, which have

also been detected in groundwater samples taken from some of the monitoring wells

(BHXX1, BHXX4 and BHXX5) located within the secant pile cut-off wall surrounding

the P1 structure. The development of the CSM takes account of and makes reference

to the PRA.

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2 Geology

2.1 Introduction

The geology is shown on schematic cross sections which bisect P1 from North to

South and from East to West and are presented as Figure 2. The “BHXX” series

borehole logs are presented in Appendix B.

In summary, the geological sequence within the P1 structure comprises Made Ground,

Alluvial Deposits, Glacial Deposits and Sherwood Sandstone bedrock, as outlined

below.

2.2 Made Ground

Made Ground was encountered ranging in thickness from 3.5 to 4.6m. Made Ground

was described as ‘road stone’ in BHXX1 and predominantly comprised limestone

gravel (temporary fill material). The composition of Made Ground was similar at the

other borehole locations.

2.3 Alluvial Deposits

The alluvial deposits ranged in thickness from 5.7 to 6.5m and extended to a generally

uniform depth of 10.2m bgl corresponding to an elevation of -2.2m AOD. Note that the

secant wall extends approximately 0.3m below the base of the alluvium into the top of

the glacial clays at a depth of approximately 10.5m bgl (-2.5m AOD) in order to form

an effective barrier to groundwater flow within the permeable alluvial deposits.

The alluvium can be divided into an upper cohesive layer and lower granular layer.

The relatively thin upper cohesive layer is represented by predominantly firm sandy

clay between 0.2 and 2.0m in thickness, and is underlain by a granular layer

consisting of fine to coarse sands of greater thickness (4.5 and 5.6m).

Boreholes BHXX3, BHXX4 and BHXX5 terminated at the base of the alluvium.

2.4 Glacial Deposits

Within the deeper boreholes (BHXX1 and BHXX2), glacial deposits comprising inter-

bedded layers of gravelly clays and sands were encountered as shown on the

geological cross sections. The glacial deposits extended to a depth of 43.9m bgl in

BHXX2.

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The glacial deposits can be divided into an upper cohesive layer of gravelly clay

(approximately 2.5m to 3.0m in thickness), overlying a predominantly granular layer of

sand with gravelly clay lenses (approximately 5.0m to 6.0m in thickness), which in turn

overlies cohesive gravelly clay.

2.5 Sandstone

Depth to bedrock (Sherwood Sandstone) was proven in BHXX2 and was encountered

at 43.9m bgl. The borehole log described the solid geology as thin to thick laminations

of reddish brown fine to medium-grained sandstone. BHXX2 extended to a maximum

depth of 53.8m bgl.

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3 Hydrogeology

3.1 Introduction

Each of the four boreholes within the P1 structure was installed as monitoring wells

which screen the encountered strata (alluvial deposits, glacial sands and sandstone)

as follows:

• BHXX4 and BHXX5 both screen the shallow groundwater body associated with

the sandy alluvial deposits (7.5 to 10.7m bgl) with a screen length of 3.2m.

• BHXX1 has a 1m screen interval against the glacial sand deposits (17.7 to

18.7m bgl)

• BHXX2 has a 10.0m screened section against the deep sandstone bedrock

aquifer (43.8 to 53.8m bgl).

Outside of the P1 structure, BHXX3 was screened across the shallow groundwater

body associated with the sandy alluvial deposits (8.5 to 11.5m bgl) with a screen

length of approximately 3.0m.

3.2 Groundwater Strikes

Within the P1 structure a groundwater strike was encountered in just one of the

boreholes, BHXX4, at 3.2m bgl in the made ground, with groundwater rising to 3.0m

bgl over a 20 minute period.

A groundwater strike was also recorded in the BHXX3 (beyond the secant wall) at

5.7m bgl at the interface between the upper cohesive alluvial clays and the underlying

alluvial sands, rising to 4.7m bgl after a period of 20 minutes.

3.3 Groundwater Elevations

The depth to groundwater measurements and corresponding groundwater elevations

are presented in Table 1 for BHXX1 to BHXX5 and summarised below. BHXX3 was

originally part of the wider groundwater monitoring network (decommissioned/ grouted

in August 2015), while the four monitoring wells within the P1 structure were destroyed

within one month of their installation as a result of construction activities. As such, a

more comprehensive dataset of groundwater levels is available for BHXX3 from

November 2014 to May 2015, while limited datasets are available for BHXX1 and

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BHXX2 (relating to November 2014), and groundwater levels were recorded on two

occasions (29th April 2015 and 5th May 2015) at BHXX4 and BHXX5.

A review of groundwater elevations relating to the different strata are presented in the

sections below.

3.3.1 Alluvial Deposits

Three monitoring wells, BHXX3, BHXX4 and BHXX5 screen the alluvial deposits.

BHXX3 is located outside of the secant wall and inferred up hydraulic gradient of

BHXX4 and BHXX5, located inside the secant wall structure.

The depth to groundwater was measured at all three locations on the 29th April 2015

(prior to the well development of BHXX4 and BHXX5) and levels ranged from 3.70 to

3.95 m below top of casing (btoc). The corresponding groundwater elevations fit the

general trend in groundwater flow with groundwater elevation of 4.55m AOD at

BHXX3 decreasing to 4.30m AOD and 4.07m AOD at BHXX4 and BHXX5,

respectively.

On the following monitoring event (5th May 2015), this trend was not observed. The

groundwater elevation at BHXX3 rose very slightly by 0.17m to 4.72m AOD, while

within the secant wall groundwater levels rose by between 1.0 and 1.3m in BHXX4

and BHXX5 to 5.25m AOD and 5.35m AOD, respectively. It is notable that the

groundwater level within the secant wall is much higher than externally and therefore

is considered to be hydraulically isolated.

Given that the purpose of the secant wall is to act as a barrier and prevent the

movement of groundwater into and from the area within the structure, it is likely to act

as a ‘sealed bucket’ resulting in the input of waters within the secant wall artificially

raising groundwater elevations within P1. The downward infiltration of groundwater

into the underlying strata will be limited by the low permeability layer of glacial clay

deposits at the base of the alluvium.

Unfortunately, BHXX4 and BHXX5 are no longer in the groundwater monitoring

network, having been destroyed by construction activities (notably their installation

was never intended to be permanent) so it is not possible to assess this further.

However, this groundwater elevation data does suggest that the secant wall is working

as an effective groundwater flow barrier.

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It is proposed that the greater rise in groundwater levels within the secant wall to that

outside on the 5th May 2015 and the potential for a linkage between the wider groundwater

outside of the secant wall and that within, be explored, including the potential for construction

activities at the site having had an effect on groundwater levels. This investigation

should be undertaken as part of the remediation works, verification of the remediation works,

or in the verification of the construction activities at P1 in line with the mechanisms set out

within the WQMP.

3.3.2 Glacial Sands

Groundwater level monitoring data for BHXX1 representing the deeper glacial sands

unit were collected in November 2014 and groundwater elevations (potentiometric

surface) of between 2.04 and 2.09 m AOD were measured on three occasions.

Measured groundwater levels in the glacial sands are approximately 2m lower than

those measured in the overlying Alluvium (on 30 April 2015) and indicate that the

intervening Glacial Clay layer acts as a good hydraulic barrier to groundwater flow.

The Glacial Sands are also known to be tidally influenced (refer to REP-ENV-03-

333032 Rev 0, August 2015) which could explain the lower heads measured within

this unit and highlight that they have a good permeability (compared to other horizons)

and a good connection to groundwater discharge zones (ultimately the River Mersey).

3.3.3 Sandstone

Within P1, only one monitoring well, BHXX2, was advanced to the deep sandstone

bedrock that was encountered at 43.9m bgl. Three rounds of groundwater level

monitoring were undertaken in November 2014 and the potentiometric surface was

between 4.05 to 4.19m AOD.

The groundwater elevation (potentiometric surface) associated with the sandstone

bedrock is approximately 2m higher than those measured in the overlying glacial sand

deposits. This is expected due to the depth of the sandstone and it being confined by

substantial thickness of low permeable glacial clay deposits. .

3.4 Groundwater Flow Direction

Based on data collected from previous ground investigations (see PRA), the regional

groundwater flow direction within the sandstone bedrock is inferred towards the south

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east. The groundwater flow direction within the glacial sands and alluvial deposits in

the vicinity of the P1 structure is less well understood (due to the lack of monitoring

wells in the area which screen the same groundwater unit). The groundwater body

within the alluvial deposits (with potentiometric surface at approximately 5m bgl) could

be influenced by shallow groundwater migration from within the made ground where

cohesive alluvium between the two strata is limited or not present. In addition there is

known to be some tidal influence on groundwater flow (MER-DJV-REP-ENV-03-

333007_REV9, October 2015).

The construction of the secant wall structure also is anticipated to have an impact on

the groundwater flow behaviour within the alluvial deposits. First of all, groundwater

level monitoring data suggests that rainfall-recharge could be causing an artificial rise

in groundwater within the secant wall. Secondly, there is unlikely to be any change in

hydraulic gradient (i.e. will remain flat) inside the confines of the secant wall, as the

groundwater flow path has been severed. The piezometric head should be

maintained at a level below the blinding concrete which crates the formation level for

the pile cap since the excavation will be dewatered to facilitate construction.

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4 Hydrology

Following the infilling of St Helens Canal, P1 is currently in an area of reclaimed land

while the construction phase of the Mersey Gateway Project is carried out.

Bowers Brook, a tributary of the River Mersey, and St Helens Canal are in close

proximity to the structure, with the brook running parallel with, and north of St Helens

Canal. The brook in this area is culverted with an open overflow channel above with a

number of interception trenches to allow flood water within the culvert to rise into the

channel / recede from the channel. Additional detail is contained within the Ramboll

reports: Bowers Brook Research Report (Ref: B4027E/AW/RE/R/027, Rev -, dated

February 2014); and Bowers Brook Interpretative Report (Ref: B4027E/AW/RE/R/028,

Rev -, dated September 2014).

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5 Assessment of Contamination

5.1 Field Observations

The following observations indicating visual or olfactory evidence of contamination

were noted on the borehole log for BHXX1 (Glacial Sands):

• Mild organic odour (not known if from a natural or anthropogenic origin) was

noted in BHXX1 between 3.5 and 3.8m bgl within the gravelly clay alluvial

deposits (potentially the base of the Made Ground).

• An organic odour (potentially relating to a natural source) was noted between

8.5 and 9.5m bgl within the sandy alluvial deposits containing traces of organic

matter.

• A strong sulphurous odour was noted from 17.6 to 18.7m bgl within the glacial

sand deposits.

There was no visual or olfactory evidence of contamination noted on the other

borehole logs within the secant wall structure (BHXX2 (sandstone), BHXX4 and

BHXX5).

5.2 Assessment of Soil Chemical Data

Soil samples relating to BHXX1-BHXX5 were submitted to Scientific Analysis

Laboratories Ltd (SAL) for analysis between October 2014 and April 2015. A selection

of soil samples were taken from different depths. The depths ranged from 3.8m to

40.0m and were mostly from the superficial deposits below the Made Ground with a

few deeper samples representing the glacial deposits taken from BHXX2. As the

source of the Made Ground was clean, natural quarried stone (used in the reclamation

of the canal to construct a temporary haul road) this zone was not targeted.

The soil samples were tested for a number of analytical suites, namely phenols, total

petroleum hydrocarbons (TPH), polycyclic aromatic hydrocarbons (PAH), volatile

organic compounds (VOC), semi-volatile organic compounds (SVOC), metals and

inorganics. The analytical suites were selected based on findings during previous

phases of ground investigations works (refer to the PRA for more details).

The soils data are presented in Table 2. The lab reports are presented in Appendix C

for reference.

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5.2.1 VOC in Soils

Chloroform was detected in soils samples from all five borehole locations. The soil

samples which exhibited the chloroform were from towards the base of the alluvial

deposits and top of the glacial deposits (sample depths from 8.0 to 13.5m). The

highest concentration of chloroform was 0.43 mg/kg in BHXX2 at 10.1m depth. Similar

concentrations were also reported in BHXX3 (0.35mg/kg at 10.5m), BHXX4

(0.16mg/kg at 10.3m) and BHXX5 (0.22 mg/kg at 10.0m).

At two borehole locations, BHXX1 and BHXX3, carbon tetrachloride was reported at

the base of the alluvial deposits at concentrations of 0.068 and 0.058 mg/kg,

marginally above the method detection limit (0.05mg/kg).

Tetrachloroethene was reported in two soil samples from one borehole location,

BHXX4, at concentrations of 0.073 and 0.077 mg/kg (sample depths of 10.0m and

5.2m, respectively.

These VOCs (chloroform, carbon tetrachloride and tetrachloroethene) were detected

from the alluvial deposits (and on occasions the top of the underlying glacial clay

deposits). The analytical data indicates that these VOC were not identified within soil

samples taken from the deeper glacial deposits.

Carbon disulphide was tested in soils samples from just two of the boreholes, BHXX4

and BHXX5. Concentrations ranged from 0.5 to 260mg/kg in BHXX4 with highest

concentration reported in the soil sample at 10.0m at the base of the alluvial deposits.

Concentrations ranged from 8.4 to 56mg/kg in BHXX5 and, similarly, the highest

concentration was from a soil sample at 10.0m. Carbon disulphide concentrations

decreased significantly in samples below 10m in the underlying glacial clay deposits.

5.2.2 Metals in Soils

Some elevated metal concentrations were detected at the base of the Made Ground in

BHXX2 at 3.8m, namely arsenic (380mg/kg), copper (380mg/kg), lead (390mg/kg) and

zinc (2,300 mg/kg).

Low to non-detect concentrations of metals were detected in deeper samples

collected from the underlying Alluvium, Glacial deposits and Sandstone bedrock.

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5.2.3 Other analytical suites

Though some aliphatic and aromatic TPH fractions (carbon banding C16-C21 and

C21-C35) and PAH compounds were reported at low concentrations near to the limit

of detection in the shallowest soil sample (BHXX2 at 3.8m), TPH and PAH were not

detected in any of the other soil samples analysed by the laboratory. Phenols and

SVOC were not detected in any of the soil samples above the limit of detection.

5.3 Assessment of Groundwater Chemical Data

The groundwater sampling rounds undertaken at BHXX1-BHXX5 are as follows:

• BHXX1 and BHXX2: Three rounds on the 7th, 17th and 24th November 2014.

• BHXX3: Four rounds on 18th and 24th November 2014, 1st December 2014

and 29th April 2015.

• BHXX4 and BHXX5: Two rounds of groundwater monitoring on 29th April 2015

and 5th May 2015.

Note that additional chemical data are available for BHXX3 as this monitoring well was

part of the wider groundwater monitoring network until it was decommissioned in

August 2015. However, data from only four monitoring rounds from coincident

sampling events have been assessed in order to make direct comparisons with limited

dataset available which represents conditions inside the secant wall.

Since some monitoring wells have been destroyed it is not possible to understand how

concentrations vary spatially at any one given time at all five monitoring locations.

With this current dataset an assessment of the impact of the secant wall on

contaminant concentrations in groundwater is somewhat limited.

All groundwater samples were submitted to Envirolab for chemical analysis and tested

for the same analytical suites as for the soil samples. The results for the monitoring

rounds listed above are presented in Table 3 and summarised below. The lab reports

are presented in Appendix D for reference.

5.3.1 VOC in Groundwater

The highest concentrations of VOC in groundwater were reported on the 29th April

2015 in BHXX3, BHXX4 and BHXX5 associated with the alluvial deposits. Similar

carbon tetrachloride concentrations of 53,525µg/l and 54,234µg/l were reported in

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BHXX4 and BHXX3, respectively (i.e. both inside and outside the bounds of the

secant wall). This is a significant increase in carbon tetrachloride concentration at

BHXX3 for the sample from 29th April 2015, as sampling and testing from the initial

three monitoring rounds in November and December 2014 gave concentrations of

between 509 and 1,316µg/l. A groundwater sample from BHXX5 reported

concentrations of 107 and 413µg/l indicating a wide variation in concentrations within

the Alluvial Sands. It is possible that the spikes in VOC concentrations (see Section

5.5 for more details) are related to the presence of globules of DNAPL within the

groundwater samples. These concentrations significantly exceed the Water

Framework Directive (WFD) Environmental Quality Standard (EQS) for fresh water

(2010) which is set at 12µg/l for carbon tetrachloride.

The next highest VOC concentrations were reported for chloroform with 14,723µg/l

reported in the sample from BHXX4 on 29th April 2014. On the same date 670µg/l and

2,330µg/l of chloroform were reported in samples from BHXX3 and BHXX5. These

concentrations exceed the EQS of 2.5µg/l.

Elevated carbon disulphide concentrations were reported in samples from BHXX4 at

1,547 and 1,486µg/l on 29th April 2015 and 5th May 2015. These concentrations are at

least an order of magnitude greater that those recorded in samples from BHXX3 and

BHXX5.

Relatively low concentrations of tetrachloroethene (between 2 and 59µg/l) were

reported in samples from BHXX3, BHXX4 and BHXX5.

Dichloromethane was reported in samples from BHXX4 at 54 and 58µg/l. Lower

concentrations were reported in samples from BHXX5 (21µg/l) on 29th April 2015 but

were not detected on the following monitoring round. This VOC was not detected in

any of the groundwater samples from BHXX3. Dichloromethane is a biodegradation

product of chloroform, so its presence could suggest that conditions are favourable for

natural attenuation processes within the alluvial deposits. Between 29th April and 5th

May 2015 there was a reduction in chlorinated solvent concentrations in BHXX4 and

BHXX5 within the bounds of the secant wall, however, it is not possible to discern

trends from two monitoring rounds over a very short period of time.

A number of other VOCs, namely chloromethane, cis-1,2-dichloroethene,

trichloroethene, 1,1-dichloropropene and 1,1,2,2-tetrachloroethene, were reported

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only in groundwater samples from BHXX4 although concentrations just marginally

exceeded detection limits.

A large variation in COPC concentrations was reported in BHXX4 and BHXX5,

although these boreholes are located 9m apart and occupy a small volume of

groundwater which is confined by the secant wall. The predominant groundwater flow

direction in the area of P1 is assumed to be towards the south-east and so BHXX4

and BHXX5 were likely to be positioned cross gradient with respect to direction of any

plume of COPC in groundwater. It is possible that BHXX4 was located within the

COPC plume whereas BHXX5 was located on the edge of it. Since groundwater flow

is prevented by the secant wall structure, the mixing of COPC in groundwater within

the secant wall is assumed to be minimal and will occur mainly by diffusion processes,

which are very slow.

The concentrations of VOCs in groundwater from the underlying glacial sands

(BHXX1) were generally less than those reported in the alluvial deposits. However,

concentrations of two VOCs, chloroform (270 to 838µg/l) and carbon tetrachloride (71

to 215µg/l), were above their respective EQS of 2.5µg/l and 12µg/l, respectively.

VOCs were not detected in groundwater samples from the sandstone strata (BHXX2).

In summary, the data provides evidence that a migration pathway for COPC, such as

chloroform and carbon tetrachloride in groundwater, exists from the alluvium to the

underlying glacial sand deposits. Given the consistent approximate 2.5m thickness of

glacial clay measured at the P1 location, it is considered that this migration pathway

may be present at a different location up-hydraulic gradient of this area.

5.3.2 Metals in Groundwater

Within the alluvial deposits, concentrations of dissolved arsenic in groundwater

samples were particularly high, at between 7,480 and 9,780µg/l, in BHXX3. Inside the

secant wall arsenic was reported at 1,370 and 2,400µg/l at BHXX4, and between 14

and 73µg/l in BHXX5. With the exception of one sample, these results exceed the

EQS of 50µg/l for arsenic.

Elevated arsenic concentrations were also detected within the glacial sands (BHXX1)

ranging from 99 to 421µg/l, These data may also indicate that a migration pathway

from the alluvial deposits across the glacial clays to the glacial sands may be present.

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Very low levels of arsenic (3µg/l) were reported in groundwater from the sandstone

bedrock (BHXX2). This is likely to be indicative of natural conditions given that

regional groundwater quality databases indicated mean concentrations for arsenic of

11.5µg/l and a maximum of 355µg/l recorded within the Triassic Sandstone aquifer of

the Liverpool area (BGS 2005).

A few other metals were detected within groundwater samples but they only

marginally exceeded the EQS and were not considered to be of significance:

• Alluvial Sands:

o Maximum mercury concentration of 0.4µg/l in BHXX5 compared to EQS of

0.05µg/l; and

o Maximum zinc concentrations at 21µg/l in BHXX4 compared to EQS of

8µg/l.

• Sandstone Bedrock:

o Maximum chromium concentration of 14µg/l in BHXX2 compared to EQS

of 3.4µg/) Regional sandstone quality data indicates mean concentrations

of 1.7µg/l and a maximum of 42.8µg/l (BGS 2005);

5.3.3 SVOC in Groundwater

Di-n-octyl phthalate in groundwater samples from BHXX4 and BHXX5 at 47 and

56µg/l respectively on 29th April 2015 exceeded the EQS (20µg/l). This compound was

detected once in BHXX1 on 7th November 2015 at 17µg/l and has not been detected

in the other groundwater samples. No other SVOCs were detected in the groundwater

samples.

5.3.4 Other analytical suites

PAH compounds were not detected in any of the groundwater samples, nor were

phenols. Relatively low concentrations of heavy-end aliphatic and aromatic TPH

fractions (predominantly carbon banding C21-C35) in groundwater have been

reported in samples from BHXX3 and BHXX4 (Alluvial Sands).

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5.4 Summary of Compounds of Potential Concern

The compounds of potential concern (COPC) are found in groundwater associated

with the alluvial deposits (and to a significantly lesser degree the glacial sands) and

relate to the following VOC, SVOC and metals:

• Chloroform;

• Carbon tetrachloride;

• Tetrachloroethene;

• Carbon Disulphide;

• Dichloromethane;

• Di-n-octyl phthalate; and

• Arsenic

5.5 Evidence of Dense Non-Aqueous Phase Liquids (DNAPL)

Chlorinated solvents are typically used as neat liquids which have a density greater

than that of water. As a result chlorinated solvents are commonly known as dense

non-aqueous phase liquids, or ‘DNAPL’. When they are released into the ground,

they do not form floating layers but rather have the ability to migrate to depths below

the groundwater table. They can form pools of discrete DNAPL within geologic media

before slowly dissolving into flowing groundwater to produce dissolved-phase plumes

of COPC. More typically, DNAPL form ganglia or strings and are difficult to detect

using traditional techniques. AECOM are not aware of any discrete DNAPL layers

being detected, e.g. by using an oil-water interface probe during groundwater

monitoring events completed in the vicinity of P1 to date.

Although it is rarely possible to observe DNAPL (as free phase droplets in samples), it

is possible to infer the potential presence of DNAPL at the site using other lines of

evidence. The reported chlorinated solvent concentrations in groundwater have been

compared against their respective solubility data using guidance in Section 7.7 of the

EA’s R&D Publication 1331. The chlorinated VOC concentrations data for four

groundwater samples (two samples each from BHXX4 and BHXX5 on 29th April 2015

and 5th May 2015) are presented in Table 4.

1 An illustrated handbook of DNAPL transport and fate in the subsurface, R&D Publication 133, Environment Agency, June 2003

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The concentration reported for carbon tetrachloride in groundwater from BHXX4 on

29th April 2015 (53,525µg/l) was 6.3% of its aqueous solubility. The percentages are

greater when taking into consideration the additive effect of all of the chlorinated

solvents that were reported in groundwater (6.6% for this particular sample).

In general, groundwater concentrations of chlorinated solvents that exceed 1% of their

aqueous solubility are indicative of the potential presence of a residual DNAPL in the

vicinity of the sample location, which could therefore be present within the water-

bearing alluvial deposits at P1.

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6 Conceptual Site Model

6.1 Introduction

The CSM is based on current ground conditions based on the latest information

available at the time of writing.

6.2 Source

The Made Ground local to P1 is imported road stone as part of the land reclamation

works that were undertaken to facilitate the construction phases of the Mersey

Gateway Bridge. COPC were not identified in the soil samples taken from the

underlying natural deposits. However, elevated concentrations of COPC were

reported in the groundwater samples, in particular those from the alluvial deposits

(BHXX4 and BHXX5). The review of the data available suggests that the source (or

potentially multiple sources) of the COPC is located up hydraulic gradient (i.e. to the

northwest) of P1. Refer to Sections 6.3 and 7.3 of the PRA document for more details

on potential source areas.

Details about the source (including its origin, age, size, volume of COPC released to

the ground and timescales) remain unknown. As such the spatial extent (both laterally

and vertically) and flow path of the plume of COPC migrating in groundwater primarily

through the alluvial deposits in the area surrounding P1 also remains unknown.

6.3 Pathway

Based on the limited data available, the main pathway for the COPC is via

groundwater within the alluvial deposits. The construction of the secant wall (a series

of overlapping piles) has trapped chlorinated solvents within the P1 structure by virtue

of severing the pathway of contaminant movement via groundwater flow within the

alluvial deposits.

Concentrations of COPC within the glacial sand deposits (BHXX2) were generally

lower than those reported in the alluvial deposits. However, concentrations of

chloroform and carbon tetrachloride were in excess of the EQS in the glacial sands

indicating that a migration pathway for COPC in groundwater through the alluvial

deposits to the underlying glacial clay and sand deposits is already present (again

probably in areas up-hydraulic gradient of the P1 structure). These COPC, however,

were not detected in groundwater samples collected from the sandstone bedrock

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strata (principal aquifer) indicating that the thick layers of glacial clays (of relatively low

permeability) currently affording protection to the underlying sandstone bedrock by

means of attenuation. It is likely that the main component of groundwater flow will be

laterally within the alluvial deposits. However, the secant wall barrier is locally

preventing migration via this flow path.

6.4 Receptors

In terms of controlled waters receptors, groundwater within the secant wall is laterally

cut off from surrounding surface water features. As outlined in the report section

above, a viable pollutant linkage to the underlying bedrock (principal aquifer) is

considered unlikely.

In this specific instance the COPC (i.e. chlorinated solvents) within the P1 structure

are not considered to pose potential risks to surface waters or human health

receptors.

However, the purpose of the secant wall was to prevent chlorinated solvents from

migrating into the P1 foundations and thence to the underlying strata penetrated by

the proposed piling. It is therefore apparent that a plume of groundwater impacted with

chlorinated solvents was already in situ when the secant wall was constructed.

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7 Conclusions

The conclusions drawn from this CSM concerning the P1 structure are as follows:

• A number of COPC are trapped within the water bearing alluvial deposits

within the area bounded by the secant wall (a series of overlapping piles) at

P1. The COPC that have been identified in groundwater samples taken from

monitoring wells BHXX4 and BHXX5 are:

o Chloroform;

o Carbon tetrachloride;

o Tetrachloroethene;

o Carbon Disulphide;

o Dichloromethane;

o Di-n-octyl phthalate; and

o Arsenic

• The data provides evidence that a migration pathway for COPC, such as

chloroform and carbon tetrachloride in groundwater, exists from the Made

Ground through the alluvium to the underlying glacial till deposits. This

pathway is likely to be located in areas up-hydraulic gradient of the P1

structure.

• A large variation in concentrations was reported in BHXX4 and BHXX5,

although these boreholes are located 9m apart and occupy a small volume of

groundwater which is confined by the secant wall. The predominant

groundwater flow direction in the area of P1 is assumed to be towards the

south-east and so BHXX4 and BHXX5 were likely to be positioned cross

gradient with respect to direction of any plume of COPC in groundwater. It is

possible that BHXX4 was located within the COPC plume whereas BHXX5

was located on the edge of it. Since groundwater flow is prevented by the

secant wall structure, the mixing of COPC in groundwater within the secant

wall is assumed to be minimal and will occur mainly by diffusion processes,

which are very slow.

• The concentration reported for carbon tetrachloride in groundwater sampled

from BHXX4 on 29th April 2015 (53,525µg/l) was 6.3% of its aqueous

solubility. The percentages are greater when taking into consideration the

additive effect of all of the chlorinated solvents that were reported in

groundwater (6.6% for this particular sample). These concentrations are

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greater than the 1% threshold and could be indicative of the possible

presence of a DNAPL within the alluvial deposits in the vicinity of this well.

• The groundwater level within the secant wall rose by between 1.0 and 1.3m in

BHXX4 and BHXX5, but this was not observed in BHXX3 outside the secant

wall. It is considered possible that rainfall-recharge could artificially raise

groundwater elevations within P1, as this additional water is trapped by the

secant wall barrier. The downward infiltration of groundwater into underlying

strata will be attenuated by the low permeability layer of glacial clay deposits

at the base of the alluvium. In addition, construction activities at the site could

also have a local impact on groundwater levels within the P1 structure.

• The exact origin of the COPC within the P1 structure remains unknown. The

groundwater flow direction within the alluvial deposits is not well understood

and therefore the presence or otherwise of a flow path for COPC migrating in

groundwater remains unclear. The findings indicate that layers of glacial clays

(of relatively low permeability) below the alluvial deposits will inhibit the

downward migration of COPC and afford protection to the underlying

sandstone bedrock. It is likely that the main component of groundwater flow

will be laterally within the alluvial deposits. However, the secant wall barrier is

locally preventing groundwater movement via this flow path.

• The COPC within the P1 structure are not currently considered to pose a

potential risks to surface waters or human health receptors.

It is apparent that a plume of groundwater impacted with chlorinated solvents was

already in situ when the secant wall was constructed. The purpose of the secant wall

was to prevent chlorinated solvents from migrating into the P1 foundations and thence

to underlying strata via the piling. However, this is not to say that the construction

works associated with the secant wall have not exacerbated the impact of existing

contaminants in the P1 area.

Assessment of the potential that construction works have had an impact on

concentrations of contaminants in groundwater in the area of the P1 structure would

be undertaken outwith the CSM and PRA documents and in accordance with the

mechanisms set out in the WQMP.

This CSM will be used to inform the remedial options appraisal and remedial strategy

which will follow in a separate document. The remedial strategy will provide details of

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the measures required to mitigate and minimise the potential risks to controlled waters

from the P1 piling installation works.

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8 References

• British Geological Survey (2005) Baseline Report Series: 19. The Permo-Triassic

Sandstones of Liverpool and Rufford. Authors: Griffiths K.J., Shand P and

Ingram, J. BGS Commissioned Report CR/05/131N: Environment Agency

Science Group: Air, Land & Water Technical Report NC/99/74/19.

• Mersey Gateway Bridge Project, Merseylink North Abutment (N1) and North

Approach Viaduct Piers (P0 and P1) Piling Risk Assessment. 21 January 2015,

Reference MER-DJV-REP-ENV-03-333007 Rev 7 (PRA).

• Mersey Gateway Bridge Project, Merseylink, North Abutment (N1) to Pier P10

Conceptual Site Model Report, 21 August 2015, DJV-REP-ENV-03-333032 Rev 0

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FIGURES

Figure 1 – Borehole Location Plan for Pier 1 and Lines of Geological Cross Section

Figure 2 – Geological Cross Section

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0 1 2m

SCALE (1:50)

LINE OF GEOLOGICAL CROSS SECTIONX’X’XX

X’X’

XX

YY Y’Y’

BOREHOLE LOCATIONS

KEY:

BHXX1BHXX1

BHXX5BHXX5

BHXX2BHXX2

BHXX3BHXX3

BHXX4BHXX4

BHXX1BHXX1

BOREHOLE LOCATION PLAN FORPIER 1 AND LINES OF CROSS SECTION

Title

Location

Client MERSEY GATEWAY

PIER 1

Job No:

Ref:

Date:

Drg. Size:

Scale:

App’d:

A3

as shown

Drawn:

FIGURE 1

JUNE 2015RH

JM/RH/MCH

JM

47067604

N

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5/5/1524/4/15 Nov 2014

Nov 2014 Nov 2014

WaterStrike

5/5/15

WaterStrike

29/4/1529/4/15

5/5/15

BH

XX3

BH

XX4

BH

XX5

BH

XX1

BH

XX1

BH

XX2

?

9

8

7

6

5

4

3

2

1

0

-1

-2

-3

-4

-5

-6

-7

-8

-9

-10

-11

-12

-13

-14

-15

-16

Ele

vatio

n (m

AO

D)

9

8

7

6

5

4

3

2

1

0

-1

-2

-3

-4

-5

-6

-7

-8

-9

-10

-11

-12

-13

-14

-15

-16

Elevation (m

AO

D)

North South West East

X X’ Y Y’

SecantWall

SecantWall

SecantWall

SecantWall

MadeGround

MadeGround

MadeGroundMade

Ground

MadeGround

Firm CLAYCohesive AlluviumConfining layer?

Water bearingALLUVIUM(granular)

GLACIALCLAY

GLACIALCLAY

End of Borehole@25m bgl

GLACIALSAND

MadeGround

Soft possibleMade Ground

MadeGround

Soft CLAY

Firm sandyCLAY Firm sandy

CLAY

Firm siltyCLAY

Firm silty &sandy CLAY

Firm sandyCLAY

SANDSAND

SAND

SAND

SAND

SAND

SAND

SAND

Sandy CLAy

SAND

SAND

SANDSAND

SAND

SAND

GravellyCLAY

GravellyCLAY

GravellyCLAY

GravellyCLAY

GravellyCLAY

GravellyCLAY

GravellyCLAY

GravellyCLAY

GravellyCLAY

GravellyCLAY

GravellyCLAY

BHXX2 - Slotted sectionbetween 43.8 & 53.8m bgl

with response zone inSandstone bedrock.

Piles advanced intocompetent bedrockapproximately 45mbgl

Piles advanced intocompetent bedrock

approximately 45mbgl

GravellyCLAY

GravellyCLAY

GravellyCLAY

MadeGround

GLACIALCLAY

ALLUVIUM

GLACIALSAND

0 1 2m

SCALEX’

X

Y Y’BHXX5

BHXX2

BHXX3

BHXX4

BHXX1

N

GEOLOGICAL CROSS SECTION

KEY:

MADE GROUND

Title

Location

Client MERSEY GATEWAY

PIER 1

Job No:

Ref:

Date:

Drg. Size:

Scale:

App’d:

A3

as shown

Drawn:

FIGURE 2

AUG 2015RH

JM/RH/MCH

JM

47067604

MADE GROUND

COHESIVE ALLUVIUMSOFT CLAY

COHESIVE ALLUVIUMFIRM SANDY CLAY

ALLUVIUM (GRANULAR)

GLACIAL CLAY

GLACIAL SAND

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TABLES

Table 1 – Groundwater Level Monitoring Data for BHXX1-BHXX5

Table 2 – Soil Analytical Data for BHXX1-BHXX5

Table 3 – Groundwater Analytical Data for BHXX1-BHXX5

Table 4 – Pier 1 Solubility Assessment for Volatile Organic Compounds (VOCs)

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Table 1

Groundwater Elevation Data for Monitoring Wells BHXX1 - BHXX5

Monitoring Well Date

Depth to Water

(Corrected to

Ground Level)

Depth to Base

(Corrected to

Ground Level)

Ground Level

Elevation (m AOD)

Groundwater

Elevation (m AOD)

BHXX1 07/11/2014 5.58 19.85 7.62 2.04

17/11/2014 5.53 18.41 7.62 2.09

24/11/2014 5.53 18.41 7.62 2.09

BHXX2 07/11/2014 3.77 54.25 7.91 4.14

17/11/2014 3.86 54.23 7.91 4.05

24/11/2014 3.83 54.25 7.91 4.09

BHXX3 18/11/2014 4.10 11.23 8.50 4.40

24/11/2014 3.99 11.22 8.50 4.51

01/12/2014 4.05 11.11 8.50 4.45

04/02/2015 3.55 11.19 8.50 4.95

03/03/2015 3.67 11.19 8.50 4.83

10/04/2015 3.68 11.12 8.50 4.82

15/04/2015 3.84 11.13 8.50 4.66

21/04/2015 3.73 11.11 8.50 4.77

29/04/2015 3.95 11.10 8.50 4.55

05/05/2015 3.78 11.11 8.50 4.72

15/05/2015 4.00 11.11 8.50 4.50

BHXX4

29/04/2015 (Initial

level prior to well

development) 3.70 10.73 8.0 4.30

05/05/2015 2.73 10.74 8.0 5.27

BHXX5

29/04/2015 (Initial

Level prior to well

development) 3.94 10.79 8.00 4.07

05/05/2015 2.66 10.81 8.00 5.35

Notes:

Monitoring wells BHXX4 and BHXX5 were not surveyed and therefore ground level datum elevation has been

estimated relative to BHXX1 and BHXX2.

Monitoring wells BHXX1, BHXX2, BHXX4 and BHXX5 have been destroyed. BHXX3 remains in wider site monitoring

network.

Pier 1 CSM

Mersey Gateway Bridge Project August 2015

Page 35: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

Table 2

Soil Analytical Results for Pier 1

Mersey Gateway Bridge Project

Location

Average Depth (m) 4.3 5.2 10 10.2 10.3 4.7 6 8 10 10.4

Date 21/04/2015 21/04/2015 22/04/2015 22/04/2015 22/04/2015 23/04/2015 24/04/2015 24/04/2015 24/04/2015 27/04/2015Lab Report Number 754221 754221 754221 754221 754221 754221 754221 754221 754221 754221 754221 754235 754235 478734 478734 478734 478734 475292 478734 478734 478734 478734 475292

PHENOL

2-chlorophenol mg/kg 0.1 0.0000801#3

0.04#4 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

2-methylphenol mg/kg 0.1 0.339#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

2-nitrophenol mg/kg 0.1 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

2,4-dichlorophenol mg/kg 0.1 0.0000969#3

0.00646#4 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

2,4-dimethylphenol mg/kg 0.1 0.204#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

2,4,6-trichlorophenol mg/kg 0.1 0.129#3 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

4-nitrophenol mg/kg 0.1 <0.5 - - - - <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - - - - - - <0.5 - - - - <0.5

Pentachlorophenol mg/kg 0.1 0.00981#3

0.000436#4 <0.5 - - - - <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - - - - - - <0.5 - - - - <0.5

Phenol mg/kg 0.1 0.569#5

0.000755#4 <0.2 - - - - <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 - - - - - - <0.1 - - - - <0.1

TPH

>C10-C35 mg/kg 1 <1 - - - - 52 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1

>C5-C6 Aliphatics mg/kg 0.1 63.2#2 <0.2 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

>C6-C8 Aliphatics mg/kg 0.1 164#2 <0.2 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

>C8-C10 Aliphatics mg/kg 0.1 19.6#2 <0.2 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

>C10-C12 Aliphatics mg/kg 1 146#2 <1 - - - - <1 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1

>C12-C16 Aliphatics mg/kg 2 3,230#2 <2 - - - - <2 <2 <2 <2 <2 <2 - - - - - - <2 - - - - <2

>C16-C21 Aliphatics mg/kg 1 379,000#2 <1 - - - - 2 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1

>C16-C35 Aliphatics mg/kg <5 - - - - 4 <5 <5 <5 <5 <5 - - - - - - <5 - - - - <5

>C21-C35 Aliphatics mg/kg 4 4,550,000#2 <4 - - - - <4 <4 <4 <4 <4 <4 - - - - - - <4 - - - - <4

>EC6-EC7 Aromatics mg/kg 0.1 0.00207#1

0.0207#4 <0.2 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

>EC7-EC8 Aromatics mg/kg 0.1 0.324#2

0.0231#4 <0.2 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

>EC8-EC10 Aromatics mg/kg 0.1 0.972#2 <0.2 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

>EC10-EC12 Aromatics mg/kg 1 0.457#2 <1 - - - - <1 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1

>EC12-EC16 Aromatics mg/kg 1 0.906#2 <1 - - - - <1 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1

>EC16-EC21 Aromatics mg/kg 1 2.55#2 <1 - - - - 5 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1

>EC21-EC35 Aromatics mg/kg 1 22.7#2 <1 - - - - 16 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1

VOC

Naphthalene mg/kg 0.1 0.008#11

0.0032#4 <0.1 - - - - 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Dichlorodifluoromethane mg/kg 0.05 0.365#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

MTBE mg/kg 0.01 0.0991#11

0.562#8 <0.02 - - - - <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - - - - - - <0.01 - - - - <0.01

Chloromethane mg/kg 0.05 0.00174#3 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Vinyl chloride mg/kg 0.05 0.0000821#1 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Bromomethane mg/kg 0.05 0.000693#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Chloroethane mg/kg 0.05 2.76#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Trichlorofluoromethane mg/kg 0.05 0.439#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

1,1-dichloroethene mg/kg 0.05 0.00743#3 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 - <0.05 <0.05 <0.05 <0.05 -

Dichloromethane mg/kg 0.05 0.0015#3

0.0015#4 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

trans-1,2-dichloroethene mg/kg 0.05 0.0657#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

1,1-dichloroethane mg/kg 0.05 0.000343#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

cis-1,2-dichloroethene mg/kg 0.05 0.00471#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

2,2-dichloropropane mg/kg 0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Bromochloromethane mg/kg 0.05 0.00884#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Chloroform mg/kg 0.059e99 see trihalomethanes

#10.000375

#4 <0.1 0.094 <0.05 <0.05 <0.05 <0.05 0.43 0.062 <0.05 <0.05 <0.05 0.35 0.059 <0.05 <0.05 <0.05 <0.05 0.16 <0.05 <0.05 0.078 0.22 <0.05

1,1,1-trichloroethane mg/kg 0.05 0.695#3

0.0348#4 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

1,1-dichloropropene mg/kg 0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Carbon tetrachloride mg/kg 0.05 0.00243#1

0.0097#4 <0.1 0.068 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 0.058 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

1,2-dichloroethane mg/kg 0.05 0.00025#1

0.000832#4 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Benzene mg/kg 0.01 0.00019#1

0.0019#4 <0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Trichloroethene mg/kg 0.05 see sum of PCE and TCE 0.00346#4 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

1,2-dichloropropane mg/kg 0.05 0.0000152#1 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Dibromomethane mg/kg 0.05 0.00101#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Bromodichloromethane mg/kg 0.05 0.00002#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

cis-1,3-dichloropropene mg/kg 0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Toluene mg/kg 0.01 0.324#3

0.0231#4 <0.02 <0.01 <0.01 0.071 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

trans-1,3-dichloropropene mg/kg 0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

1,1,2-trichloroethane mg/kg 0.05 0.0000719#5

0.103#4 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Tetrachloroethene mg/kg 0.05 see sum of PCE and TCE 0.00617#4 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 0.077 0.073 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

1,3-dichloropropane mg/kg 0.05 0.0000149#1 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Chlorodibromomethane mg/kg 0.059e99 see trihalomethanes

#1 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

1,2-dibromoethane mg/kg 0.05 0.0000132#1 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Chlorobenzene mg/kg 0.05 0.166#3 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

1,1,1,2-tetrachloroethane mg/kg 0.05 0.000431#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Ethylbenzene mg/kg 0.01 0.285#3

0.019#7 <0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Xylene (m & p) mg/kg 0.01 <0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Xylene Total mg/kg 0.48#3

0.0288#4 <0.04 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02

Xylene (o) mg/kg 0.019e99 see Xylene Total

#1 <0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Styrene mg/kg 0.05 0.0139#3

0.0347#7 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Bromoform mg/kg 0.059e99 see trihalomethanes

#1 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Isopropylbenzene mg/kg 0.05 1.06#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

1,1,2,2-tetrachloroethane mg/kg 0.05 0.0000198#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Bromobenzene mg/kg 0.05 0.0438#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

1,2,3-trichloropropane mg/kg 0.05 1.78E-7#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

n-propylbenzene mg/kg 0.05 1.66#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

2-chlorotoluene mg/kg 0.05 0.367#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

1,3,5-trimethylbenzene mg/kg 0.05 0.184#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

4-chlorotoluene mg/kg 0.05 0.496#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

tert-butylbenzene mg/kg 0.05 3.76#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

1,2,4-trimethylbenzene mg/kg 0.05 0.0431#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

sec-butylbenzene mg/kg 0.05 25.4#5 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

p-isopropyltoluene mg/kg 0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

1,3-dichlorobenzene mg/kg 0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05

1,4-dichlorobenzene mg/kg 0.05 0.439#3 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05

1,2-dichlorobenzene mg/kg 0.05 1.43#3 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.1 <0.05 <0.05 <0.05 <0.05 <0.05

1,2,4-trichlorobenzene mg/kg 0.1 0.00509#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Hexachlorobutadiene mg/kg 0.1 0.0132#3

0.0022#4 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

1,2-Dichloroethene mg/kg 0.00658#3 <0.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Trihalomethanes mg/kg 0.0112#1 <0.4 0.169 <0.2 <0.2 <0.2 <0.2 0.505 0.137 <0.2 <0.2 <0.2 0.425 0.134 <0.2 <0.2 <0.2 <0.2 0.235 <0.2 <0.2 0.153 0.295 <0.2

Carbon disulfide mg/kg 0.1 0.259#5 - - - - - - - - - - - - - 160 73 260 65 0.5 8.4 9.7 10 56 <0.1

PAH

Acenaphthylene mg/kg 0.1 0.0662#11 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Acenaphthene mg/kg 0.1 0.0851#11 <0.1 - - - - 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Fluorene mg/kg 0.1 0.0681#11 <0.1 - - - - 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Phenanthrene mg/kg 0.1 0.0441#11 <0.1 - - - - 1.2 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Anthracene mg/kg 0.1 1.02#11

0.00113#4 <0.1 - - - - 0.4 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Fluoranthene mg/kg 0.1 0.146#11

0.00364#4 <0.1 - - - - 2 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Pyrene mg/kg 0.1 0.292#11 <0.1 - - - - 1.6 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Benzo(a)anthracene mg/kg 0.1 0.0155#11 <0.1 - - - - 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Chrysene mg/kg 0.1 0.11#11 <0.1 - - - - 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Benzo(a)pyrene mg/kg 0.1 0.00258#1

0.0129#4 <0.1 - - - - 0.5 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Indeno(1,2,3-c,d)pyrene mg/kg 0.19e99 see sum of 4 PAHs

#1 <0.1 - - - - 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Dibenzo(a,h)anthracene mg/kg 0.1 0.00372#11 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Benzo(g,h,i)perylene mg/kg 0.19e99 see sum of 4 PAHs

#1 <0.1 - - - - 0.3 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Benzo(b)fluoranthene mg/kg 0.19e99 see sum of 4 PAHs

#1 <0.1 - - - - 0.6 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Benzo(k)fluoranthene mg/kg 0.19e99 see sum of 4 PAHs

#1 <0.1 - - - - 0.3 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

5 9.5 10 18.7 25

BHXX1 BHXX2 BHXX3 BHXX4 BHXX5

10.5 11.5

###### ###### ###### ###### ###### ###### ###### ######

3.8 10.1 13.5 18.5 24 40

######

Units Me

tho

d D

ete

ctio

n

Lim

it

GA

C_

WT

V_

EN

/W

A_

DW

S_

[EN

_b

/g]

_S

AN

D0

.2%

TO

C

GA

C_

WT

V_

EN

/W

A_

EQ

S-

Fre

sh

_[E

N_

b/g

]_S

AN

D0

.2%

TO

C

###### ###### ###### ######

Pier 1 CSM

Mersey Gateway Bridge Project

AECOM

Page 1 of 2 August 2015

Page 36: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

Table 2

Soil Analytical Results for Pier 1

Mersey Gateway Bridge Project

Location

Average Depth (m) 4.3 5.2 10 10.2 10.3 4.7 6 8 10 10.4

Date 21/04/2015 21/04/2015 22/04/2015 22/04/2015 22/04/2015 23/04/2015 24/04/2015 24/04/2015 24/04/2015 27/04/2015Lab Report Number 754221 754221 754221 754221 754221 754221 754221 754221 754221 754221 754221 754235 754235 478734 478734 478734 478734 475292 478734 478734 478734 478734 475292

5 9.5 10 18.7 25

BHXX1 BHXX2 BHXX3 BHXX4 BHXX5

10.5 11.5

###### ###### ###### ###### ###### ###### ###### ######

3.8 10.1 13.5 18.5 24 40

######

Units Me

tho

d D

ete

ctio

n

Lim

it

GA

C_

WT

V_

EN

/W

A_

DW

S_

[EN

_b

/g]

_S

AN

D0

.2%

TO

C

GA

C_

WT

V_

EN

/W

A_

EQ

S-

Fre

sh

_[E

N_

b/g

]_S

AN

D0

.2%

TO

C

###### ###### ###### ######

Benzo(b)&(k)fluoranthene mg/kg 0.00628#4 <0.2 - - - - 0.9 <0.2 <0.2 <0.2 <0.2 <0.2 - - - - - - <0.2 - - - - <0.2

PAHs (sum of 4) mg/kg 0.0174#1 <0.4 - - - - 1.4 <0.4 <0.4 <0.4 <0.4 <0.4 - - - - - - <0.4 - - - - <0.4

PAH 17 Total mg/kg 1.6 <1.6 - - - - 9.1 <1.6 <1.6 <1.6 <1.6 <1.6 - - - - - - <1.6 - - - - <1.6

Coal Tar (Bap as surrogate marker) mg/kg <0.1 - - - - 0.5 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

SVOC

Coronene mg/kg 0.1 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

2,4,5-trichlorophenol mg/kg 0.1 0.0324#3 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

4-chloro-3-methylphenol mg/kg 0.1 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

2-chloronaphthalene mg/kg 0.1 3.16#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

2-methylnaphthalene mg/kg 0.1 0.106#3 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Bis(2-ethylhexyl) phthalate mg/kg 0.1 0.0883#3

0.0143#4 <0.1 - - - - <0.1 <0.1 0.4 0.2 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Butyl benzyl phthalate mg/kg 0.1 0.0616#5

0.077#7 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Di-n-butyl phthalate mg/kg 0.1 3.16#5

0.0281#7 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Di-n-octyl phthalate mg/kg 0.1 29.7#5

2.97#7 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Diethylphthalate mg/kg 0.1 4.84#5

0.0646#7 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Dimethyl phthalate mg/kg 0.1 0.146#7 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

2-nitroaniline mg/kg 0.1 0.0413#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

2,4-Dinitrotoluene mg/kg 0.1 0.0000775#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

2,6-dinitrotoluene mg/kg 0.1 0.0000179#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

3-nitroaniline mg/kg 0.1 <0.5 - - - - <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - - - - - - <0.1 - - - - <0.1

4-bromophenyl phenyl ether mg/kg 0.1 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

4-chloroaniline mg/kg 0.1 0.0000866#5 <0.5 - - - - <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - - - - - - <0.5 - - - - <0.5

4-chlorophenyl phenyl ether mg/kg 0.1 <0.5 - - - - <0.1 <0.5 <0.5 <0.5 <0.5 <0.5 - - - - - - <0.1 - - - - <0.1

4-nitroaniline mg/kg 0.1 0.00154#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.5 - - - - <0.5

Azobenzene mg/kg 0.1 0.000485#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Bis(2-chloroethoxy) methane mg/kg 0.1 0.003#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Bis(2-chloroethyl)ether mg/kg 0.1 0.0000027#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Carbazole mg/kg 0.1 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Dibenzofuran mg/kg 0.1 0.0817#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.5 - - - - <0.1

Hexachlorobenzene mg/kg 0.1 0.0678#3

0.000678#4 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Hexachlorocyclopentadiene mg/kg 0.1 12.4#5 <0.5 - - - - <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - - - - - - <0.5 - - - - <0.5

Hexachloroethane mg/kg 0.1 0.00399#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Isophorone mg/kg 0.1 0.0105#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Nitrobenzene mg/kg 0.1 0.0000301#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Bis(2-chloroisopropyl) ether mg/kg 0.1 0.0000673#5 <0.1 - - - - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - <0.1 - - - - <0.1

Phenolics

2,4-dinitrophenol mg/kg 0.1 0.0237#5 <0.5 - - - - <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - - - - - - <0.1 - - - - <0.5

3-&4-methylphenol mg/kg 0.1 <0.1 - - - - 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 - - - - - - - - - - - -

3,4-Dimethylphenol mg/kg 0.1 0.00836#5 - - - - - - - - - - - - - - - - - <0.1 - - - - <0.1

Phenols (Mono) mg/kg 1 <1 - - - - <1 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1

Metals

Arsenic mg/kg 2 32#12

32#12 49 - - - - 380 24 7 8 8 6 - - - - - - 8 - - - - 10

Barium mg/kg 1 28.7#3 42 - - - - 370 92 47 110 140 88 - - - - - - 110 - - - - 100

Beryllium mg/kg 2 42.5#5 <2 - - - - <2 <2 <2 <2 <2 <2 - - - - - - <2 - - - - <2

Boron mg/kg 1 10#1

20.1#7 <1 - - - - <1 <1 <1 <1 <1 <1 - - - - - - - - - - - -

Cadmium mg/kg 1 1#12

1#12 <1 - - - - 6 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1

Chromium (III+VI) mg/kg 1 59.5#12

59.5#12 10 - - - - 38 27 6 27 33 24 - - - - - - 26 - - - - 23

Copper mg/kg 1 62#12

62#12 19 - - - - 380 23 5 19 23 13 - - - - - - 27 - - - - 14

Lead mg/kg 1 180#12

180#12 38 - - - - 390 18 4 11 13 7 - - - - - - 16 - - - - 8

Mercury mg/kg 1 0.5#12

0.5#12 <1 - - - - 5 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1

Nickel mg/kg 1 42#12

42#12 10 - - - - 39 30 8 30 37 26 - - - - - - 31 - - - - 27

Selenium mg/kg 3 0.5#1 <3 - - - - <3 <3 <3 <3 <3 <3 - - - - - - <3 - - - - <3

Vanadium mg/kg 1 1.09#5

0.253#7 11 - - - - 23 27 7 26 31 25 - - - - - - 25 - - - - 22

Zinc mg/kg 1 224#12

224#12 130 - - - - 2,300 120 28 53 63 41 - - - - - - 110 - - - - 42

Boron (Water Soluble) mg/kg 1 - - - - - - - - - - - - - - - - - <1 - - - - <1

Chromium (hexavalent) mg/kg 1 0.902#1

0.0613#4 <1 - - - - <1 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1

Organics

Fraction Organic Carbon None - - - - - - - - - - - - - - - - - 0.0064 - - - - 0.0031

Inorganics

Water_Soluble_Sulphate g/L 0.01 - - - - - - - - - - - - - - - - - 0.31 - - - - 0.91

Sulphur % 0.01 - - - - - - - - - - - - - - - - - 0.06 - - - - 0.09

Total Sulphur - 0.01 0.13 - - - - 1.1 0.13 0.03 0.05 0.06 0.03 - - - - - - - - - - - -

Cyanide (Free) mg/kg 1 0.497#1

0.00994#4 <1 - - - - <1 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1

Sulphate mg/l 10 120 - - - - 1,100 510 220 180 160 50 - - - - - - - - - - - -

Sulphide mg/kg 1 1 - - - - 20 <1 <1 <1 <1 <1 - - - - - - - - - - - -

Moisture Content 105C % 0.1 - - - - - - - - - - - - - 31 23 27 8.5 15 36 23 21 17 -

Cyanide Total mg/kg 1 <1 - - - - 3 <1 <1 <1 <1 <1 - - - - - - <1 - - - - <1

Moisture Content (dried @ 40°C) % 0.1 24 20 11 22 23 44 15 18 20 22 14 19 14 - - - - - - - - - -

Easily Liberated Sulphide mg/kg 1 - - - - - - - - - - - - - - - - - <1 - - - - <1

pH pH_Units 7.8 - - - - 7.4 8 8.1 8.3 8.2 8.5 - - - - - - 8.3 - - - - 8.1

Asbestos

Asbestos Containing Material None ND - - - - ND ND ND ND ND ND - - - - - - ND - - - - -

Comments

#1 WS Regs 2010 (Eng/Wal)

#2 WHO Petroleum In DW 2008

#3 WHO DWG 2011

#4 WFD EQS 2010 Fresh (Eng/Wal)

#5 USEPA RSL (tapwater)

#6 SEPA WAT-SG-53 Fresh EQS - MAC - 2013

#7 SEPA WAT-SG-53 Fresh EQS - AA - 2013

#8 PNEC (EU REACH) - Freshwater

#9 New Hampshire DES (2009)

#10 California Draft health protective concentration

#11 Calc WHO

#12 AECOM Pragmatic CW/WE Soil Criteria - Eng

GAC: Generic Assessment Criteria

(blank): No assessment criteria available

Sol: Unacceptable risk not achieved due to calculated target above solubility limit

- : Not analysed

ND: Not Detected

DWS: Drinking Water Standard

EQS: Environmental Quality Standard

Key

XXX Exceedance of GAC_WTV_EN/WA_DWS_[EN_b/g]_SAND0.2%TOC

XXX Exceedance of GAC_WTV_EN/WA_EQS-Fresh_[EN_b/g]_SAND0.2%TOC

Pier 1 CSM

Mersey Gateway Bridge Project

AECOM

Page 2 of 2 August 2015

Page 37: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

Table 3

Groundwater Analytical Results for Pier 1

Mersey Gateway Bridge Project

Location

WellDate 07/11/2014 17/11/2014 24/11/2014 07/11/2014 17/11/2014 24/11/2014 18/11/2014 24/11/2014 01/12/2014 29/04/2015 29/04/2015 05/05/2015 29/04/2015 05/05/2015

PHENOL

2-chlorophenol µg/L 0.1#3

50#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

2-methylphenol µg/L 930#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

2-nitrophenol µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

2,4-dichlorophenol µg/L 0.3#3

20#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

2,4-dimethylphenol µg/L 360#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

2,4,6-trichlorophenol µg/L 200#3 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

4-nitrophenol µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Pentachlorophenol µg/L 9#3

0.4#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Phenol µg/L 5,800#5

7.7#4 <1 - - <1 - - - - - - <1 1 <1 1

TPH

>C5-C6 Aliphatics µg/L 15,000#2 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

>C6-C8 Aliphatics µg/L 15,000#2 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

>C8-C10 Aliphatics µg/L 300#2 <1 <1 <1 <1 <1 <1 <1 <1 <1 - 1 <1 1 <1

>C10-C12 Aliphatics µg/L 300#2 <5 <5 <5 <5 <5 <5 <5 <5 <5 - 8 <5 <5 <5

>C12-C16 Aliphatics µg/L 300#2 <5 <5 <5 <5 <5 <5 <5 <5 <5 - <5 <5 <5 <5

>C16-C21 Aliphatics µg/L 300#2 <5 <5 <5 <5 <5 <5 <5 10 <5 - <5 15 <5 <5

>C21-C35 Aliphatics µg/L 300#2 <5 <5 <5 <5 <5 <5 <5 208 <5 - <5 14 <5 <5

>C5-C35 Aliphatics µg/L <5 <5 <5 <5 <5 <5 <5 218 <5 - 9 28 <5 <5

>EC5-EC7 Aromatics µg/L 1#1

10#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

>EC7-EC8 Aromatics µg/L 700#2

50#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 1 <1 <1

>EC10-EC12 Aromatics µg/L 90#2 <5 <5 <5 <5 <5 <5 <5 <5 <5 - <5 <5 <5 <5

>EC12-EC16 Aromatics µg/L 90#2 <5 <5 <5 <5 <5 <5 <5 <5 <5 - <5 <5 <5 <5

>EC16-EC21 Aromatics µg/L 90#2 <5 <5 <5 <5 <5 <5 <5 <5 <5 - <5 <5 <5 <5

>EC21-EC35 Aromatics µg/L 90#2 <5 <5 <5 <5 <5 <5 <5 51 <5 - <5 <5 <5 <5

>EC5-EC35 Aromatics µg/L <5 <5 <5 <5 <5 <5 <5 51 <5 - <5 - <5 -

VOC

Naphthalene µg/L 6#11

2.4#4 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 0.03 0.02 0.02 - <1 - 0.06 <1 - 0.06 <1 - 0.02 <0.01

Dichlorodifluoromethane µg/L 200#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

MTBE µg/L 900#11

5,100#8 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Chloromethane µg/L 20#3 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 22 27 7 <1

Vinyl chloride µg/L 0.5#1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

Bromomethane µg/L 7.5#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

Chloroethane µg/L 21,000#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

Trichlorofluoromethane µg/L 1,100#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

1,1-dichloroethene µg/L 30#3 <1 <1 <1 <1 <1 <1 3 <1 <1 <1 2 2 <1 <1

Dichloromethane µg/L 20#3

20#4 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 58 54 21 <5

trans-1,2-dichloroethene µg/L 360#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

1,1-dichloroethane µg/L 2.7#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

cis-1,2-dichloroethene µg/L 36#5 <1 <1 <1 <1 <1 <1 3 3 3 3 3 2 <1 <1

2,2-dichloropropane µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

Bromochloromethane µg/L 83#5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5

Chloroform µg/L9e99 see trihalomethanes

#12.5

#4 838 423 270 <25 <25 <25 867 188 206 670 14,723 >3,303 2,330 587

1,1,1-trichloroethane µg/L 2,000#3

100#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 2 <1 <1

1,1-dichloropropene µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 14 <1 <1 <1

Carbon tetrachloride µg/L 3#1

12#4 71 55 215 <1 <1 <1 1,316 748 509 54,234 53,525 >6,542 413 107

1,2-dichloroethane µg/L 3#1

10#4 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 3 <2

Benzene µg/L 1#1

10#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 - 1 <1 <1 <1

Trichloroethene µg/L9e99 see sum of PCE and TCE

#110

#4 <1 <1 <1 <1 <1 <1 2 2 2 2 6 6 <1 <1

1,2-dichloropropane µg/L 0.1#1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

Dibromomethane µg/L 8#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

Bromodichloromethane µg/L 0.13#5 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10

cis-1,3-dichloropropene µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

Toluene µg/L 700#3

50#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 - 1 1 <1 <1

trans-1,3-dichloropropene µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

1,1,2-trichloroethane µg/L 0.28#5

400#4 <1 <1 <1 <1 <1 <1 6 <1 <1 <1 <1 <1 <1 <1

Tetrachloroethene µg/L9e99 see sum of PCE and TCE

#110

#4 <1 <1 <1 <1 <1 <1 14 14 19 39 59 53 7 2

1,3-dichloropropane µg/L 0.1#1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

Chlorodibromomethane µg/L9e99 see trihalomethanes

#1 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3

1,2-dibromoethane µg/L 0.1#1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

Chlorobenzene µg/L 300#3 <1 <1 <1 <1 <1 <1 <1 <1 <1 5 <1 <1 <1 <1

1,1,1,2-tetrachloroethane µg/L 0.57#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

Ethylbenzene µg/L 300#3

20#7 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

Xylene (m & p) µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

Xylene Total µg/L 500#3

30#4 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2

Xylene (o) µg/L9e99 see Xylene Total

#1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

Styrene µg/L 20#3

50#7 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

Bromoform µg/L9e99 see trihalomethanes

#1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

Isopropylbenzene µg/L 450#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

1,1,2,2-tetrachloroethane µg/L 0.076#5 <1 <1 <1 <1 <1 <1 6 <1 <1 1 6 5 <1 <1

Bromobenzene µg/L 62#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

1,2,3-trichloropropane µg/L 0.00075#5 <1 <1 <1 <1 <1 <1 1 <1 <1 <1 <1 <1 <1 <1

n-propylbenzene µg/L 660#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

2-chlorotoluene µg/L 240#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

1,3,5-trimethylbenzene µg/L 120#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

4-chlorotoluene µg/L 250#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

tert-butylbenzene µg/L 690#5 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2

1,2,4-trimethylbenzene µg/L 15#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

sec-butylbenzene µg/L 2,000#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

p-isopropyltoluene µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

1,3-dichlorobenzene µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

1,4-dichlorobenzene µg/L 300#3 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

n-butylbenzene µg/L 1,000#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

1,2-dichlorobenzene µg/L 1,000#3 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

1,2-dibromo-3-chloropropane µg/L 0.1#1 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2

1,2,4-trichlorobenzene µg/L 1.1#5 <1 <3 <3 <1 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3

Hexachlorobutadiene µg/L 0.6#3

0.1#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

1,2,3-trichlorobenzene µg/L 7#5 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3

1,2-Dichloroethene µg/L 50#3 <2 <2 <2 <2 <2 <2 3.5 3.5 3.5 3.5 3.5 2.5 <2 <2

Trihalomethanes µg/L 100#1 845 430 277 <39 <39 <39 874 195 213 677 14,730 3,310 2,337 594

Carbon disulfide µg/L 810#5 6 1 <1 <1 <1 <1 793 48 24 171 1,547 1,486 13 <1

BHXX3* BHXX4 BHXX5

- - - - -

BHXX1 BHXX2

Units Meth

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GA

C_W

TV

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N

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Pier 1 CSM

Mersey Gateway Bridge Project

AECOM

Page 1 of 3 August 2015

Page 38: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

Table 3

Groundwater Analytical Results for Pier 1

Mersey Gateway Bridge Project

Location

WellDate 07/11/2014 17/11/2014 24/11/2014 07/11/2014 17/11/2014 24/11/2014 18/11/2014 24/11/2014 01/12/2014 29/04/2015 29/04/2015 05/05/2015 29/04/2015 05/05/2015

BHXX3* BHXX4 BHXX5

- - - - -

BHXX1 BHXX2

Units Meth

od

Dete

ction L

imit

GA

C_W

TV

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N

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GA

C_W

TV

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N

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PAH

Acenaphthylene µg/L 18#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01

Acenaphthene µg/L 18#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <1 - 0.09 <1 - 0.08 <1 - 0.01 <1 - 0.05

Fluorene µg/L 12#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01

Phenanthrene µg/L 4#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 0.01 - <1 - 0.01 <1 - 0.01 <0.01 <0.01

Anthracene µg/L 90#11

0.1#4 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01

Fluoranthene µg/L 4#11

0.1#4 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01

Pyrene µg/L 9#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01

Benzo(a)anthracene µg/L 0.1#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01

Chrysene µg/L 1#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01

Benzo(a)pyrene µg/L 0.01#1

0.05#4 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01

Indeno(1,2,3-c,d)pyrene µg/L9e99 see sum of 4 PAHs

#1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01

Dibenzo(a,h)anthracene µg/L 0.01#11 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01

Benzo(g,h,i)perylene µg/L9e99 see sum of 4 PAHs

#1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01

Benzo(b)fluoranthene µg/L9e99 see sum of 4 PAHs

#1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01

Benzo(k)fluoranthene µg/L9e99 see sum of 4 PAHs

#1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01

Benzo(b)&(k)fluoranthene µg/L 0.03#4 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 - <0.02 <0.02 <0.02 <0.02

PAHs (sum of 4) µg/L 0.1#1 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 <0.04 - <0.04 <0.04 <0.04 <0.04

PAH 16 Total µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 0.03 0.02 0.03 - 0.16 0.15 0.03 0.05

benzo(g,h,i)perylene + indeno(1,2,3-cd)pyrene µg/L 0.002#4 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 - <0.02 <0.02 <0.02 <0.02

Coal Tar (Bap as surrogate marker) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 - <0.01 <0.01 <0.01 <0.01

SVOC

2,4,5-trichlorophenol µg/L 9#3 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

4-chloro-3-methylphenol µg/L 1,400#5

40#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

4-methylphenol µg/L 1,900#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

2-chloronaphthalene µg/L 750#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

2-methylnaphthalene µg/L 24#3 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Bis(2-ethylhexyl) phthalate µg/L 8#3

1.3#4 <2 <2 <2 <2 <2 <2 <2 <2 <2 - <2 <2 <2 <2

Butyl benzyl phthalate µg/L 16#5

20#7 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Di-n-butyl phthalate µg/L 900#5

8#7 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Di-n-octyl phthalate µg/L 200#5

20#7 17 <5 <5 <5 <5 <5 <5 <5 <5 - 47 - 56 -

Diethylphthalate µg/L 15,000#5

200#7 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Dimethyl phthalate µg/L 800#7 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

2,4-Dinitrotoluene µg/L 0.24#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

2,6-dinitrotoluene µg/L 0.048#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

4-bromophenyl phenyl ether µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Bis(2-chloroethoxy) methane µg/L 59#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Bis(2-chloroethyl)ether µg/L 0.014#5 <1 <1 <1 <1 <1 1 <1 <1 <1 - <1 <1 <1 <1

Carbazole µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Dibenzofuran µg/L 7.9#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Hexachlorobenzene µg/L 1#3

0.01#4 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Hexachlorocyclopentadiene µg/L 31#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Hexachloroethane µg/L 0.9#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Isophorone µg/L 78#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

N-nitrosodi-n-propylamine µg/L 0.011#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Nitrobenzene µg/L 0.14#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Bis(2-chloroisopropyl) ether µg/L 0.36#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Perylene µg/L <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Phenolics

2,4-dinitrophenol µg/L 39#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

4,6-Dinitro-2-methylphenol µg/L 1.5#5 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 <1 <1 <1

Phenols Total of 5 Speciated by HPLC (W) µg/L 50 <10 500 170 380 390 <10 <10 <10 - 110 30 30 <10

Pier 1 CSM

Mersey Gateway Bridge Project

AECOM

Page 2 of 3 August 2015

Page 39: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

Table 3

Groundwater Analytical Results for Pier 1

Mersey Gateway Bridge Project

Location

WellDate 07/11/2014 17/11/2014 24/11/2014 07/11/2014 17/11/2014 24/11/2014 18/11/2014 24/11/2014 01/12/2014 29/04/2015 29/04/2015 05/05/2015 29/04/2015 05/05/2015

BHXX3* BHXX4 BHXX5

- - - - -

BHXX1 BHXX2

Units Meth

od

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GA

C_W

TV

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Metals

Aluminium µg/L 200#1

15#7 <10 13 23 <10 12 21 32 35 17 - <10 <10 <10 <10

Arsenic µg/L 10#1

50#4 421 332 99 3 3 3 7,480 9,780 8,500 - 2,400 1,370 14 73

Barium µg/L 700#3 108 97 94 119 73 62 <50 47 46 - 96 106 141 66

Beryllium µg/L 25#5 <1 <2 <1 <1 <2 <1 <50 <1 <1 - <1 <1 <1 <1

Boron µg/L 1,000#1

2,000#7 683 668 501 67 52 56 1,650 444 1,090 - 1,180 1,230 959 138

Cadmium µg/L 5#1

0.08#4 <1 <2 <1 <1 <2 <1 <50 <1 <1 - <1 <1 <1 <1

Calcium µg/L 724,000 600,000 668,000 1,510,000 1,430,000 1,700,000 552,000 576,000 478,000 - 666,000 653,000 545,000 222,000

Chromium (III+VI) µg/L 50#1

3.4#4 3 10 10 2 11 14 <50 7 5 - 2 7 <1 1

Copper µg/L 2,000#1

1#4 <1 <2 <1 <1 <2 <1 <50 <1 <1 - <1 <1 <1 <1

Iron µg/L 200#1

1,000#4 11,060 8,530 3,124 108 165 178 14,700 17,730 17,200 - 12,370 7,007 8,114 299

Lead µg/L 25#1

7.2#4 <1 <2 <1 <1 <2 <1 <50 <1 <1 - <1 <1 <1 <1

Magnesium µg/L 293,000 302,000 304,000 709,000 674,000 827,000 104,000 57,000 81,000 - 142,000 114,000 83,000 32,000

Manganese µg/L 50#1

30#7 2,806 2,230 1,925 942 613 556 3,760 4,454 4,079 - 7,412 8,926 6,537 503

Mercury µg/L 1#1

0.05#4 <0.1 <0.2 <0.1 <0.1 <0.2 <0.1 <5 <0.1 <0.1 - 0.3 <0.1 0.4 <0.1

Nickel µg/L 20#1

20#4 4 3 4 9 8 7 <50 10 8 - 8 8 14 6

Selenium µg/L 10#1 1 <2 <1 <1 <2 <1 <50 2 2 - 6 8 8 12

Strontium µg/L 12,000#5 6,490 4,800 6,780 4,130 3,460 3,700 1,290 1,120 1,150 - 1,860 1,680 1,630 2,160

Vanadium µg/L 86#5

20#7 1 5 4 1 5 2 <50 11 10 - 1 3 <1 <1

Zinc µg/L 6,000#5

8#4 3 4 16 13 12 10 <50 9 8 - 21 15 14 3

Potassium µg/L 72,000 61,000 58,000 19,000 20,000 19,000 134,000 94,000 128,000 - 105,000 84,000 61,000 13,000

Chromium (hexavalent) µg/L 50#1

3.4#4 <50 <50 <50 <50 <5,000 <50 <50 <50 <50 - <50 <50 <50 <50

Organics

Dissolved Organic Carbon mg/l 4.3 10.7 3.8 2.1 1.6 1.7 13.7 13.8 14.3 - 13 19.1 10.7 7.6

Inorganics

BOD settled mg/l <1 2 <1 <1 2 <1 5 <1 <1 - <1 <1 <1 <1

Sodium mg/L 200#1 1,900 2,040 2,170 1,040 984 1,280 888 892 799 - 681 660 473 158

Electrical conductivity *(lab) µS/cm 11,900 12,900 12,800 14,200 14,300 14,400 11,000 8,250 9,630 - 9,050 8,640 6,300 1,913

Sulphate mg/L 250#1

400#7 1,998 1,785 1,848 588 634 614 5,820 3,548 3,947 - 3,475 3,546 2,168 801

Chloride mg/L 250#1

250#7 3,530 4,860 4,330 5,930 6,740 6,180 869 787 721 - 662.62 698 521.51 170.03

Sulphide mg/L - - - - - - - - - - 0.2 0.1 <0.1 <0.1

Cyanide Total mg/L 0.0015#5 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 - <0.005 <0.005 <0.005 <0.005

Nitrate (as N) mg/L <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - 0.68 <0.5 <0.5 0.8

Nitrite (as N) mg/L <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 - <0.1 0.13 <0.1 0.73

Easily Liberated Sulphide (Moisture Corrected) mg/l <0.1 0.5 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 <0.1 - - - - -

COD (Settled) µg/L 220,000 220,000 190,000 140,000 150,000 120,000 150,000 120,000 130,000 - 140,000 130,000 87,000 27,000

pH (Lab) pH_Units 7.16 7.89 7.55 7.07 7.61 7.24 7.66 7.51 7.25 - 7.11 7.22 7.38 7.68

Comments

*Additional 13 rounds of monitoring data for BHXX3 between 26/01/15 and 21/04/15 have not been included in this assessment. Refer to the wider CSM for more information.

#1 WS Regs 2010 (Eng/Wal)

#2 WHO Petroleum In DW 2008

#3 WHO DWG 2011

#4 WFD EQS 2010 Fresh (Eng/Wal)

#5 USEPA RSL (tapwater)

#6 SEPA WAT-SG-53 Fresh EQS - MAC - 2013

#7 SEPA WAT-SG-53 Fresh EQS - AA - 2013

#8 PNEC (EU REACH) - Freshwater

#9 New Hampshire DES (2009)

#10 California Draft health protective concentration

#11 Calc WHO

GAC: Generic Assessment Criteria

(blank): No assessment criteria available

- : Not analysed

DWS: Drinking Water Standard

EQS: Environmental Quality Standard

Key

XXX Exceedance of CW/WE Water. DWS - England/Wales

XXX Exceedance of CW/WE Water. Aquatic Toxicity - England/Wales - Freshwater

Pier 1 CSM

Mersey Gateway Bridge Project

AECOM

Page 3 of 3 August 2015

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Table 4

Pier 1 Soubililty Assessment for Volatile Organic Compounds (VOCs) in Groundwater

Location Solubility (µg/L)

Date 29/04/2015 05/05/2015 29/04/2015 05/05/2015 29/04/2015 05/05/2015 29/04/2015 05/05/2015

VOC

Chloromethane µg/L 22 27 7 <1 5.35E+06 4.11E-04 5.05E-04 1.31E-04 -

Dichloromethane µg/L 58 54 21 <5 2.01E+07 2.89E-04 2.69E-04 1.04E-04 -

Chloroform µg/L 14,723 >3,303 2,330 587 8.95E+06 1.65E-01 >3.69E-04 2.60E-02 1.10E-02

Carbon tetrachloride (Tetrachloromethane) µg/L 53,525 >6,542 413 107 8.46E+05 6.33E+00 >7.73E-03 4.88E-02 5.32E-04

Tetrachloroethene (PCE) µg/L 59 53 7 2 2.25E+05 2.62E-02 2.36E-02 3.11E-03 2.23E-05

1,1,2,2-tetrachloroethane µg/L 6 5 <1 <1 2.93E+06 2.05E-04 1.71E-04 -

Carbon disulfide µg/L 1,547 1,486 13 <1 2.10E+06 7.37E-02 7.08E-02 6.19E-04 -

Percentage of Total Solubility (%)

BHXX4 (Alluvial Deposits) BHXX5 (Alluvial Deposits)BHXX4 (Alluvial Deposits) BHXX5 (Alluvial Deposits)

Units

Pier 1 CSM

Mersey Gateway Bridge Project August 2015

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MERSEY GATEWAY BRIDGE

MER-DJV-REP-ENV-03-333030 A 17 MARCH 2016

APPENDIX A – PHOTOS OF PIER 1

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BHXX3

Haul Road

Thermphos

BHXX3 Haul Road

Thermphos

Canal

NORTH

Mersey River

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MERSEY GATEWAY BRIDGE

MER-DJV-REP-ENV-03-333030 B 17 MARCH 2016

APPENDIX B – BOREHOLE LOGS (BHXX1 – BHXX5)

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Page 49: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

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Page 54: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

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Page 55: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

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Page 56: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

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Page 57: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

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Page 58: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

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Page 59: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

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Page 67: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

5M[KZQX\QWV WN C\ZI\I <MOMVL 5MX\P<M^MT5I\]U CIUXTQVO

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Page 68: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

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Page 69: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

MERSEY GATEWAY BRIDGE

MER-DJV-REP-ENV-03-333030 C 17 MARCH 2016

APPENDIX C – LAB REPORTS (SOIL)

Page 70: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

Scientific Analysis Laboratories Ltd

Certificate of Analysis

Hadfield HouseHadfield Street

CornbrookManchester

M16 9FETel : 0161 874 2400Fax : 0161 874 2468

Report Number: 428221-2

Date of Report: 16-Oct-2014

Customer: Soil Engineering Geoservices LimitedParkside LaneDewsbury RoadLeedsWest Yorkshire.LS11 5SX

Customer Contact: Mr Peter Stoddart

Customer Job Reference: TA7437Customer Site Reference: Mersey Gateway Bridge Additional Phase

GI (Phase 2)Date Job Received at SAL: 30-Sep-2014

Date Analysis Started: 10-Oct-2014Date Analysis Completed: 16-Oct-2014

The results reported relate to samples received in the laboratoryOpinions and interpretations expressed herein are outside the scope of UKAS accreditationThis report should not be reproduced except in full without the written approval of the laboratoryTests covered by this certificate were conducted in accordance with SAL SOPsAll results have been reviewed in accordance with QP22

This document has been printed from a digitally signed master copy

Scientific Analysis Laboratories is a

limited company registered in England and

Wales (No 2514788) whose address is at

Hadfield House, Hadfield Street, Manchester M16 9FE

1549

Report checkedand authorised by :Mr Ross WalkerCustomer Services Manager(Land)

Issued by :Mr Ross WalkerCustomer Services Manager(Land)

Page 1 of 12

428221-2

Page 71: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

SAL Reference: 428221

Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Metals

SAL Reference 428221002

428221012

428221015

428221016

428221017

428221018

428221021

Customer Sample Reference BHXX1 ES007

BHXX2 ES001

BHXX2 ES018

BHXX2 ES025

BHXX2 ES038

BHXX2 ES051

BHXX2 ES085

Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Date Sampled 26-SEP-2014

25-SEP-2014

29-SEP-2014

29-SEP-2014

29-SEP-2014

30-SEP-2014

02-OCT-2014

Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Type Sandy Soil Clay Clay Sandy Soil Clay Clay Clay

Determinand Method TestSample LOD Units

Arsenic T6 M40 2 mg/kg 49 380 24 7 8 8 6

Barium T6 M40 1 mg/kg 42 370 92 47 110 140 88

Chromium VI T6 AR 1 mg/kg <1 <1 <1 <1 <1 <1 <1

Beryllium T6 M40 2 mg/kg <2 <2 <2 <2 <2 <2 <2

Boron (water-soluble) T6 AR 1 mg/kg <1 <1 <1 <1 <1 <1 <1

Cadmium T6 M40 1 mg/kg <1 6 <1 <1 <1 <1 <1

Chromium T6 M40 1 mg/kg 10 38 27 6 27 33 24

Copper T6 M40 1 mg/kg 19 380 23 5 19 23 13

Lead T6 M40 1 mg/kg 38 390 18 4 11 13 7

Mercury T6 M40 1 mg/kg <1 5 <1 <1 <1 <1 <1

Nickel T6 M40 1 mg/kg 10 39 30 8 30 37 26

Selenium T6 M40 3 mg/kg <3 <3 <3 <3 <3 <3 <3

Vanadium T6 M40 1 mg/kg 11 23 27 7 26 31 25

Zinc T6 M40 1 mg/kg 130 2300 120 28 53 63 41

SAL Reference: 428221

Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Miscellaneous

SAL Reference 428221002

428221012

428221015

428221016

428221017

428221018

428221021

Customer Sample Reference BHXX1ES 007

BHXX2ES 001

BHXX2ES 018

BHXX2ES 025

BHXX2ES 038

BHXX2ES 051

BHXX2ES 085

Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Date Sampled 26-SEP-2014

25-SEP-2014

29-SEP-2014

29-SEP-2014

29-SEP-2014

30-SEP-2014

02-OCT-2014

Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Type SandySoil

Clay Clay SandySoil

Clay Clay Clay

Determinand Method TestSample LOD Units

Mass Fraction of organic carbon T286 M40 0.0030 0.033 0.0053 0.0012 0.0047 0.0062 0.0019

Cyanide(Total) T546 AR 1 mg/kg <1 3 <1 <1 <1 <1 <1

Cyanide(free) T546 AR 1 mg/kg <1 <1 <1 <1 <1 <1 <1

pH T7 AR 7.8 7.4 8.0 8.1 8.3 8.2 8.5

Phenols(Mono) T546 AR 1 mg/kg <1 <1 <1 <1 <1 <1 <1

(Water Soluble) SO4 expressed as SO4 T242 M40 0.01 g/l 0.12 1.1 0.51 0.22 0.18 0.16 0.05

Sulphide T546 AR 1 mg/kg 1 20 <1 <1 <1 <1 <1

Sulphur (total) T6 M40 0.01 % 0.13 1.1 0.13 0.03 0.05 0.06 0.03

TPH (C10-C35) T8 M105 1 mg/kg <1 52 <1 <1 <1 <1 <1

This document has been printed from a digitally signed master copy

Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 2 of 12

428221-2

Page 72: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

SAL Reference: 428221

Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Moisture

SAL Reference 428221002

428221004

428221005

428221010

428221011

428221012

428221015

428221016

428221017

428221018

428221021

Customer Sample Reference BHXX1ES 007

BHXX1ES 023

BHXX1ES 025

BHXX1ES 048

BHXX1ES 061

BHXX2ES 001

BHXX2ES 018

BHXX2ES 025

BHXX2ES 038

BHXX2ES 051

BHXX2ES 085

Depth 5.00 9.50 10.00 18.70 25.00 3.80 10.10 13.50 18.50 24.00 40.00

Date Sampled 26-SEP-2014

29-SEP-2014

29-SEP-2014

30-SEP-2014

01-OCT-2014

25-SEP-2014

29-SEP-2014

29-SEP-2014

29-SEP-2014

30-SEP-2014

02-OCT-2014

Bottom Depth 5.00 9.50 10.00 18.70 25.00 3.80 10.10 13.50 18.50 24.00 40.00

Type SandySoil

SandySoil

Clay Clay Clay Clay Clay SandySoil

Clay Clay Clay

Determinand Method TestSample LOD Units

Moisture @ 105 C T162 AR 0.1 % 24 20 11 22 23 44 15 18 20 22 14

SAL Reference: 428221

Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Asbestos

SAL Reference 428221002

428221012

428221015

428221016

428221017

428221018

428221021

Customer Sample Reference BHXX1 ES007

BHXX2 ES001

BHXX2 ES018

BHXX2 ES025

BHXX2 ES038

BHXX2 ES051

BHXX2 ES085

Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Date Sampled 26-SEP-2014

25-SEP-2014

29-SEP-2014

29-SEP-2014

29-SEP-2014

30-SEP-2014

02-OCT-2014

Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Type Sandy Soil Clay Clay Sandy Soil Clay Clay Clay

Determinand Method TestSample LOD Units

Asbestos ID T27 AR N.D. N.D. N.D. N.D. N.D. N.D. N.D.

This document has been printed from a digitally signed master copy

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428221-2

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SAL Reference: 428221

Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

PAH EPA 16, Coronene

SAL Reference 428221002

428221012

428221015

428221016

428221017

428221018

428221021

Customer Sample Reference BHXX1 ES007

BHXX2 ES001

BHXX2 ES018

BHXX2 ES025

BHXX2 ES038

BHXX2 ES051

BHXX2 ES085

Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Date Sampled 26-SEP-2014

25-SEP-2014

29-SEP-2014

29-SEP-2014

29-SEP-2014

30-SEP-2014

02-OCT-2014

Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Type Sandy Soil Clay Clay Sandy Soil Clay Clay Clay

Determinand Method TestSample LOD Units

Naphthalene T207 M105 0.1 mg/kg <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1

Acenaphthylene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Acenaphthene T207 M105 0.1 mg/kg <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1

Fluorene T207 M105 0.1 mg/kg <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1

Phenanthrene T207 M105 0.1 mg/kg <0.1 1.2 <0.1 <0.1 <0.1 <0.1 <0.1

Anthracene T207 M105 0.1 mg/kg <0.1 0.4 <0.1 <0.1 <0.1 <0.1 <0.1

Fluoranthene T207 M105 0.1 mg/kg <0.1 2.0 <0.1 <0.1 <0.1 <0.1 <0.1

Pyrene T207 M105 0.1 mg/kg <0.1 1.6 <0.1 <0.1 <0.1 <0.1 <0.1

Benzo(a)Anthracene T207 M105 0.1 mg/kg <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1

Chrysene T207 M105 0.1 mg/kg <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1

Benzo(b)fluoranthene T207 M105 0.1 mg/kg <0.1 0.6 <0.1 <0.1 <0.1 <0.1 <0.1

Benzo(k)fluoranthene T207 M105 0.1 mg/kg <0.1 0.3 <0.1 <0.1 <0.1 <0.1 <0.1

Benzo(a)Pyrene T207 M105 0.1 mg/kg <0.1 0.5 <0.1 <0.1 <0.1 <0.1 <0.1

Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1

Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Benzo(ghi)Perylene T207 M105 0.1 mg/kg <0.1 0.3 <0.1 <0.1 <0.1 <0.1 <0.1

Coronene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

PAH (Sum) T85 M105 1.6 mg/kg (36) <1.6 9.1 (110) <1.6 <1.6 <1.6 (110) <1.6 (110) <1.6

SAL Reference: 428221

Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

TPH (CWG)

SAL Reference 428221002

428221012

428221015

428221016

428221017

428221018

428221021

Customer Sample Reference BHXX1 ES007

BHXX2 ES001

BHXX2 ES018

BHXX2 ES025

BHXX2 ES038

BHXX2 ES051

BHXX2 ES085

Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Date Sampled 26-SEP-2014

25-SEP-2014

29-SEP-2014

29-SEP-2014

29-SEP-2014

30-SEP-2014

02-OCT-2014

Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Type Sandy Soil Clay Clay Sandy Soil Clay Clay Clay

Determinand Method TestSample LOD Units

TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg (100)

<0.200<0.100 <0.100 <0.100 <0.100 <0.100 <0.100

TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg (100) <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10

TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg (100) <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10

TPH (C10-C12 aliphatic) T206 M105 1 mg/kg <1 <1 <1 <1 <1 <1 <1

TPH (C12-C16 aliphatic) T206 M105 2 mg/kg <2 <2 <2 <2 <2 <2 <2

TPH (C16-C21 aliphatic) T206 M105 1 mg/kg <1 2 <1 <1 <1 <1 <1

TPH (C21-C35 aliphatic) T206 M105 4 mg/kg <4 <4 <4 <4 <4 <4 <4

TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg (100) <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10

TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg (100) <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10

TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg (100) <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10

TPH (C10-C12 aromatic) T206 M105 1 mg/kg <1 <1 <1 <1 <1 <1 <1

TPH (C12-C16 aromatic) T206 M105 1 mg/kg <1 <1 <1 <1 <1 <1 <1

TPH (C16-C21 aromatic) T206 M105 1 mg/kg <1 5 <1 <1 <1 <1 <1

TPH (C21-C35 aromatic) T206 M105 1 mg/kg <1 16 <1 <1 <1 <1 <1

This document has been printed from a digitally signed master copy

Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 4 of 12

428221-2

Page 74: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

SAL Reference: 428221

Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Semi-Volatile Organic Compounds (Reduced)

SAL Reference 428221002

428221012

428221015

428221016

428221017

428221018

428221021

Customer Sample Reference BHXX1ES 007

BHXX2ES 001

BHXX2ES 018

BHXX2ES 025

BHXX2ES 038

BHXX2ES 051

BHXX2ES 085

Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Date Sampled 26-SEP-2014

25-SEP-2014

29-SEP-2014

29-SEP-2014

29-SEP-2014

30-SEP-2014

02-OCT-2014

Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Type SandySoil

Clay Clay SandySoil

Clay Clay Clay

Determinand Method TestSample LOD Units

1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

1,2-Dichlorobenzene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

1,3-Dichlorobenzene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

1,4-Dichlorobenzene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

2,4,5-Trichlorophenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

2,4,6-Trichlorophenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

2,4-Dichlorophenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

2,4-Dimethylphenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

2,4-Dinitrophenol T207 M105 0.1 mg/kg (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (110) <0.5

2,4-Dinitrotoluene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

2,6-Dinitrotoluene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

2-Chloronaphthalene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

2-Chlorophenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

2-methyl phenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

2-Methylnaphthalene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

2-Nitroaniline T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

2-Nitrophenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

3-Nitroaniline T207 M105 0.1 mg/kg (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (110) <0.5

3/4-Methylphenol T207 M105 0.1 mg/kg <0.1 0.2 <0.1 <0.1 <0.1 <0.1 <0.1

4-Bromophenyl phenylether T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

4-Chloro-3-methylphenol T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

4-Chloroaniline T207 M105 0.1 mg/kg (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (110) <0.5

4-Chlorophenyl phenylether T207 M105 0.1 mg/kg (36) <0.5 <0.1 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (110) <0.5

4-Nitroaniline T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

4-Nitrophenol T207 M105 0.1 mg/kg (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (110) <0.5

Azobenzene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 0.4 0.2 <0.1 <0.1

Butyl benzylphthalate T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Carbazole T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Di-n-butylphthalate T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Di-n-octylphthalate T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Dibenzofuran T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Diethyl phthalate T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Dimethyl phthalate T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Hexachlorobenzene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Hexachlorobutadiene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Hexachlorocyclopentadiene T207 M105 0.1 mg/kg (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (110) <0.5

Hexachloroethane T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Isophorone T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Nitrobenzene T207 M105 0.1 mg/kg <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Pentachlorophenol T207 M105 0.1 mg/kg (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (36) <0.5 (110) <0.5

Phenol T207 M105 0.1 mg/kg (107) <0.2 (107) <0.2 (36) <0.2 (110) <0.2 (110) <0.2 (110) <0.2 (110) <0.2

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428221-2

Page 75: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

SAL Reference: 428221

Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Volatile Organic Compounds (USEPA 624) (MCERTS)

SAL Reference 428221002

428221004

428221005

428221010

428221011

428221012

428221015

428221016

428221017

428221018

428221021

Customer Sample Reference BHXX1ES 007

BHXX1ES 023

BHXX1ES 025

BHXX1ES 048

BHXX1ES 061

BHXX2ES 001

BHXX2ES 018

BHXX2ES 025

BHXX2ES 038

BHXX2ES 051

BHXX2ES 085

Depth 5.00 9.50 10.00 18.70 25.00 3.80 10.10 13.50 18.50 24.00 40.00

Date Sampled 26-SEP-2014

29-SEP-2014

29-SEP-2014

30-SEP-2014

01-OCT-2014

25-SEP-2014

29-SEP-2014

29-SEP-2014

29-SEP-2014

30-SEP-2014

02-OCT-2014

Bottom Depth 5.00 9.50 10.00 18.70 25.00 3.80 10.10 13.50 18.50 24.00 40.00

Type SandySoil

SandySoil

Clay Clay Clay Clay Clay SandySoil

Clay Clay Clay

Determinand Method TestSample LOD Units

1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,1,1-Trichloroethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,1,2-Trichloroethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,1-Dichloroethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,1-Dichloroethylene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,1-Dichloropropene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,2,3-Trichloropropane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,2,4-Trimethylbenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,2-dibromoethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,2-Dichlorobenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,2-Dichloroethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,2-Dichloropropane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,3,5-Trimethylbenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,3-Dichlorobenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,3-Dichloropropane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

1,4-Dichlorobenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

2,2-Dichloropropane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

2-Chlorotoluene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

4-Chlorotoluene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Benzene T209 M105 10 µg/kg (100,13)

<20(13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10

Bromobenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Bromochloromethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Bromodichloromethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Bromoform T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Bromomethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Carbon tetrachloride T209 M105 50 µg/kg (100) <100 68 <50 <50 <50 <50 <50 <50 <50 <50 <50

Chlorobenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Chlorodibromomethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Chloroethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Chloroform T209 M105 50 µg/kg (100) <100 94 <50 <50 <50 <50 430 62 <50 <50 <50

Chloromethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Cis-1,2-Dichloroethylene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Cis-1,3-Dichloropropene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Dibromomethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Dichlorodifluoromethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Dichloromethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

EthylBenzene T209 M105 10 µg/kg (100) <20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10

Isopropyl benzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

M/P Xylene T209 M105 10 µg/kg (100) <20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10

n-Propylbenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

O Xylene T209 M105 10 µg/kg (100) <20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10

p-Isopropyltoluene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

S-Butylbenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Styrene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

T-Butylbenzene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Tetrachloroethene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Toluene T209 M105 10 µg/kg (100) <20 <10 <10 71 <10 <10 <10 <10 <10 <10 <10

Trans-1,2-Dichloroethene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Trans-1,3-Dichloropropene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Trichloroethene T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Trichlorofluoromethane T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Vinyl chloride T209 M105 50 µg/kg (100) <100 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50

Methyl tert-Butyl Ether T209 M105 10 µg/kg (100) <20 - - - - <10 <10 <10 <10 <10 <10

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428221-2

Page 76: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

SAL Reference: 428221

Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)

Customer Reference: TA7437

Leachate to BS EN 12457-2 (10:1) Analysed as Water

Metals

SAL Reference 428221002

428221012

428221015

428221016

428221017

428221018

428221021

Customer Sample Reference BHXX1 ES007

BHXX2 ES001

BHXX2 ES018

BHXX2 ES025

BHXX2 ES038

BHXX2 ES051

BHXX2 ES085

Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Date Sampled 26-SEP-2014

25-SEP-2014

29-SEP-2014

29-SEP-2014

29-SEP-2014

30-SEP-2014

02-OCT-2014

Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Type Sandy Soil Clay Clay Sandy Soil Clay Clay Clay

Determinand Method TestSample LOD Units

As (Dissolved) T281 10:1 0.2 µg/l 460 1500 2.2 16 1.7 1.9 5.6

Ba (Dissolved) T281 10:1 1 µg/l 12 44 37 15 32 40 46

Be (Dissolved) T281 10:1 0.05 µg/l <0.05 0.07 <0.05 <0.05 <0.05 <0.05 <0.05

Chromium VI T686 10:1 3 µg/l <3 <3 <3 <3 <3 <3 <3

Boron T6 10:1 10 µg/l 28 220 35 <10 76 41 <10

Cd (Dissolved) T281 10:1 0.02 µg/l 0.03 0.06 <0.02 <0.02 0.02 <0.02 <0.02

Cr (Dissolved) T281 10:1 1 µg/l 2 2 3 1 2 2 <1

Cu (Dissolved) T281 10:1 0.5 µg/l 1.0 1.2 1.3 2.0 3.0 2.9 1.4

Pb (Dissolved) T281 10:1 0.3 µg/l 1.1 0.4 <0.3 <0.3 <0.3 0.3 <0.3

Hg (Dissolved) T281 10:1 0.05 µg/l <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Ni (Dissolved) T281 10:1 1 µg/l 1 9 <1 <1 <1 <1 <1

Se (Dissolved) T281 10:1 0.5 µg/l 0.7 2.7 1.0 1.1 4.0 4.6 1.7

V (Dissolved) T281 10:1 2 µg/l 3 <2 <2 <2 <2 2 7

Zn (Dissolved) T281 10:1 2 µg/l 7 10 3 3 6 6 3

SAL Reference: 428221

Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)

Customer Reference: TA7437

Leachate to BS EN 12457-2 (10:1) Analysed as Water

Miscellaneous

SAL Reference 428221002

428221012

428221015

428221016

428221017

428221018

428221021

Customer Sample Reference BHXX1 ES007

BHXX2 ES001

BHXX2 ES018

BHXX2 ES025

BHXX2 ES038

BHXX2 ES051

BHXX2 ES085

Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Date Sampled 26-SEP-2014

25-SEP-2014

29-SEP-2014

29-SEP-2014

29-SEP-2014

30-SEP-2014

02-OCT-2014

Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Type Sandy Soil Clay Clay Sandy Soil Clay Clay Clay

Determinand Method TestSample LOD Units

Ammoniacal nitrogen T686 10:1 0.05 mg/l 5.7 5.1 16 4.0 0.33 0.33 0.53

Chloride T686 10:1 1 mg/l 9 97 37 25 160 180 20

Cyanide(Total) T4 10:1 0.05 mg/l <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Cyanide(free) T4 10:1 0.05 mg/l <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Electrical Conductivity T7 10:1 10 µS/cm 240 2600 610 260 870 850 150

Nitrate T686 10:1 0.5 mg/l <0.5 <0.5 <0.5 <0.5 3.1 1.6 <0.5

pH T7 10:1 7.7 6.9 8.1 7.9 7.9 7.6 7.7

Phenol T149 10:1 0.5 µg/l <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5

Sulphate T686 10:1 0.5 mg/l 49 1400 120 45 71 64 15

Sulphide T4 10:1 0.05 mg/l <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05

Sulphur (total) T65 10:1 0.01 mg/l 16 500 48 16 24 22 5.5

TPH (C10-C35) T8 10:1 0.1 mg/l <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

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Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 7 of 12

428221-2

Page 77: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

Index to symbols used in 428221-2

Notes

Method Index

SAL Reference: 428221

Project Site: Mersey Gateway Bridge Additional Phase GI (Phase 2)

Customer Reference: TA7437

Leachate to BS EN 12457-2 (10:1) Analysed as Water

PAH EPA 16, Coronene

SAL Reference 428221002

428221012

428221015

428221016

428221017

428221018

428221021

Customer Sample Reference BHXX1 ES007

BHXX2 ES001

BHXX2 ES018

BHXX2 ES025

BHXX2 ES038

BHXX2 ES051

BHXX2 ES085

Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Date Sampled 26-SEP-2014

25-SEP-2014

29-SEP-2014

29-SEP-2014

29-SEP-2014

30-SEP-2014

02-OCT-2014

Bottom Depth 5.00 3.80 10.10 13.50 18.50 24.00 40.00

Type Sandy Soil Clay Clay Sandy Soil Clay Clay Clay

Determinand Method TestSample LOD Units

Naphthalene T149 10:1 0.01 µg/l 0.18 0.04 0.04 <0.01 0.05 0.04 0.03

Acenaphthylene T149 10:1 0.01 µg/l 0.05 <0.01 0.02 <0.01 <0.01 <0.01 <0.01

Acenaphthene T149 10:1 0.01 µg/l 0.04 0.03 0.02 <0.01 <0.01 <0.01 0.02

Fluorene T149 10:1 0.01 µg/l 0.06 0.03 0.03 <0.01 0.02 <0.01 0.03

Phenanthrene T149 10:1 0.01 µg/l 0.10 <0.01 0.03 <0.01 0.05 <0.01 0.04

Anthracene T149 10:1 0.01 µg/l 0.05 <0.01 <0.01 <0.01 0.01 <0.01 <0.01

Fluoranthene T149 10:1 0.01 µg/l 0.21 0.03 <0.01 <0.01 0.04 <0.01 0.03

Pyrene T149 10:1 0.01 µg/l 0.17 0.02 <0.01 <0.01 0.04 <0.01 0.02

Benzo(a)Anthracene T149 10:1 0.01 µg/l 0.09 <0.01 <0.01 <0.01 0.02 <0.01 <0.01

Chrysene T149 10:1 0.01 µg/l 0.11 <0.01 <0.01 <0.01 0.04 <0.01 0.03

Benzo(b)fluoranthene T149 10:1 0.01 µg/l 0.16 <0.01 <0.01 <0.01 0.03 <0.01 0.02

Benzo(k)fluoranthene T149 10:1 0.01 µg/l 0.09 <0.01 <0.01 <0.01 0.02 <0.01 0.01

Benzo(a)Pyrene T149 10:1 0.01 µg/l 0.07 <0.01 <0.01 <0.01 0.01 <0.01 <0.01

Indeno(123-cd)Pyrene T149 10:1 0.01 µg/l 0.06 <0.01 <0.01 <0.01 0.02 <0.01 <0.01

Dibenzo(ah)Anthracene T149 10:1 0.01 µg/l 0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Benzo(ghi)Perylene T149 10:1 0.01 µg/l 0.04 <0.01 <0.01 <0.01 0.02 <0.01 <0.01

Coronene T149 10:1 0.01 µg/l <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

PAH (Sum) T85 10:1 0.01 µg/l 1.5 0.15 0.14 <0.01 0.37 0.04 0.23

Value Description

AR As Received

10:1 Leachate to BS EN 12457-2 (10:1)

M40 Analysis conducted on sample assisted dried at no morethan 40C. Results are reported on a dry weight basis.

M105 Analysis conducted on an "as received" aliquot. Results arereported on a dry weight basis where moisture content wasdetermined by assisted drying of sample at 105C

N.D. Not Detected

110 LOD raised due to low internal standard recovery.

107 1,1,2-trichloroethylene is the same as trichloroethylene

13 Results have been blank corrected.

36 LOD Raised due to low Matrix spike recovery

100 LOD determined by sample aliquot used for analysis

S Analysis was subcontracted

M Analysis is MCERTS accredited

U Analysis is UKAS accredited

N Analysis is not UKAS accredited

Samples 1-3 and 12-14 have exceeded our recommended holding time of 14 days from sampling and are classed as deviating. It is possible therefore that the results provided may becompromised.

Asbestos is subcontracted to REC Asbestos.

Value Description

T286 Calc TOC/100

T65 ICP/OES (Preconc.)

T4 Colorimetry

T7 Probe

T85 Calc

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Accreditation Summary

T206 GC/FID (MCERTS)

T209 GC/MS(Head Space)(MCERTS)

T242 2:1 Extraction/ICP/OES (TRL 447 T1)

T149 GC/MS (SIR)

T546 Colorimetry (CF)

T686 Discrete Analyser

T6 ICP/OES

T8 GC/FID

T27 PLM

T162 Grav (1 Dec) (105 C)

T281 ICP/MS (Filtered)

T207 GC/MS (MCERTS)

Determinand Method TestSample LOD Units Symbol SAL References

Mass Fraction of organic carbon T286 M40 N 002,012,015-018,021

Cyanide(Total) T546 AR 1 mg/kg M 002,012,015-018,021

Cyanide(free) T546 AR 1 mg/kg M 002,012,015-018,021

pH T7 AR M 002,012,015-018,021

Phenols(Mono) T546 AR 1 mg/kg M 002,012,015-018,021

(Water Soluble) SO4 expressed as SO4 T242 M40 0.01 g/l N 002,012,015-018,021

Sulphide T546 AR 1 mg/kg N 002,012,015-018,021

Sulphur (total) T6 M40 0.01 % N 002,012,015-018,021

TPH (C10-C35) T8 M105 1 mg/kg M 002,012,015-018,021

Arsenic T6 M40 2 mg/kg M 002,012,015-018,021

Barium T6 M40 1 mg/kg U 002,012,015-018,021

Chromium VI T6 AR 1 mg/kg N 002,012,015-018,021

Beryllium T6 M40 2 mg/kg M 002,012,015-018,021

Boron (water-soluble) T6 AR 1 mg/kg N 002,012,015-018,021

Cadmium T6 M40 1 mg/kg M 002,012,015-018,021

Chromium T6 M40 1 mg/kg M 002,012,015-018,021

Copper T6 M40 1 mg/kg M 002,012,015-018,021

Lead T6 M40 1 mg/kg M 002,012,015-018,021

Mercury T6 M40 1 mg/kg M 002,012,015-018,021

Nickel T6 M40 1 mg/kg M 002,012,015-018,021

Selenium T6 M40 3 mg/kg M 002,012,015-018,021

Vanadium T6 M40 1 mg/kg M 002,012,015-018,021

Zinc T6 M40 1 mg/kg M 002,012,015-018,021

Naphthalene T207 M105 0.1 mg/kg M 002,012,015-018,021

Acenaphthylene T207 M105 0.1 mg/kg U 002,012,015-018,021

Acenaphthene T207 M105 0.1 mg/kg M 002,012,015-018,021

Fluorene T207 M105 0.1 mg/kg M 002,012,015-018,021

Phenanthrene T207 M105 0.1 mg/kg M 002,012,015-018,021

Anthracene T207 M105 0.1 mg/kg U 002,012,015-018,021

Fluoranthene T207 M105 0.1 mg/kg M 002,012,015-018,021

Pyrene T207 M105 0.1 mg/kg M 002,012,015-018,021

Benzo(a)Anthracene T207 M105 0.1 mg/kg M 002,012,015-018,021

Chrysene T207 M105 0.1 mg/kg M 002,012,015-018,021

Benzo(b)fluoranthene T207 M105 0.1 mg/kg M 002,012,015-018,021

Benzo(k)fluoranthene T207 M105 0.1 mg/kg M 002,012,015-018,021

Benzo(a)Pyrene T207 M105 0.1 mg/kg M 002,012,015-018,021

Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg M 002,012,015-018,021

Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg M 002,012,015-018,021

Benzo(ghi)Perylene T207 M105 0.1 mg/kg M 002,012,015-018,021

Coronene T207 M105 0.1 mg/kg N 002,012,015-018,021

PAH (Sum) T85 M105 1.6 mg/kg N 002,012,015-018,021

Moisture @ 105 C T162 AR 0.1 % N 002,004-005,010-012,015-018,021

1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg M 002,012,015-018,021

1,2-Dichlorobenzene T207 M105 0.1 mg/kg M 002,012,015-018,021

1,3-Dichlorobenzene T207 M105 0.1 mg/kg M 002,012,015-018,021

1,4-Dichlorobenzene T207 M105 0.1 mg/kg M 002,012,015-018,021

2,4,5-Trichlorophenol T207 M105 0.1 mg/kg U 002,012,015-018,021

2,4,6-Trichlorophenol T207 M105 0.1 mg/kg U 002,012,015-018,021

2,4-Dichlorophenol T207 M105 0.1 mg/kg U 002,012,015-018,021

2,4-Dimethylphenol T207 M105 0.1 mg/kg U 002,012,015-018,021

2,4-Dinitrophenol T207 M105 0.1 mg/kg U 002,012,015-018,021

2,4-Dinitrotoluene T207 M105 0.1 mg/kg M 002,012,015-018,021

2,6-Dinitrotoluene T207 M105 0.1 mg/kg U 002,012,015-018,021

2-Chloronaphthalene T207 M105 0.1 mg/kg M 002,012,015-018,021

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Determinand Method TestSample LOD Units Symbol SAL References

2-Chlorophenol T207 M105 0.1 mg/kg M 002,012,015-018,021

2-methyl phenol T207 M105 0.1 mg/kg M 002,012,015-018,021

2-Methylnaphthalene T207 M105 0.1 mg/kg M 002,012,015-018,021

2-Nitroaniline T207 M105 0.1 mg/kg M 002,012,015-018,021

2-Nitrophenol T207 M105 0.1 mg/kg U 002,012,015-018,021

3-Nitroaniline T207 M105 0.1 mg/kg U 002,012,015-018,021

3/4-Methylphenol T207 M105 0.1 mg/kg M 002,012,015-018,021

4-Bromophenyl phenylether T207 M105 0.1 mg/kg M 002,012,015-018,021

4-Chloro-3-methylphenol T207 M105 0.1 mg/kg M 002,012,015-018,021

4-Chloroaniline T207 M105 0.1 mg/kg U 002,012,015-018,021

4-Chlorophenyl phenylether T207 M105 0.1 mg/kg M 002,012,015-018,021

4-Nitroaniline T207 M105 0.1 mg/kg U 002,012,015-018,021

4-Nitrophenol T207 M105 0.1 mg/kg U 002,012,015-018,021

Azobenzene T207 M105 0.1 mg/kg M 002,012,015-018,021

Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg M 002,012,015-018,021

Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg M 002,012,015-018,021

Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg M 002,012,015-018,021

Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg M 002,012,015-018,021

Butyl benzylphthalate T207 M105 0.1 mg/kg U 002,012,015-018,021

Carbazole T207 M105 0.1 mg/kg U 002,012,015-018,021

Di-n-butylphthalate T207 M105 0.1 mg/kg M 002,012,015-018,021

Di-n-octylphthalate T207 M105 0.1 mg/kg M 002,012,015-018,021

Dibenzofuran T207 M105 0.1 mg/kg M 002,012,015-018,021

Diethyl phthalate T207 M105 0.1 mg/kg U 002,012,015-018,021

Dimethyl phthalate T207 M105 0.1 mg/kg U 002,012,015-018,021

Hexachlorobenzene T207 M105 0.1 mg/kg M 002,012,015-018,021

Hexachlorobutadiene T207 M105 0.1 mg/kg M 002,012,015-018,021

Hexachlorocyclopentadiene T207 M105 0.1 mg/kg U 002,012,015-018,021

Hexachloroethane T207 M105 0.1 mg/kg U 002,012,015-018,021

Isophorone T207 M105 0.1 mg/kg U 002,012,015-018,021

Nitrobenzene T207 M105 0.1 mg/kg M 002,012,015-018,021

Pentachlorophenol T207 M105 0.1 mg/kg U 002,012,015-018,021

Phenol T207 M105 0.1 mg/kg M 002,012,015-018,021

TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg N 002,012,015-018,021

TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg N 002,012,015-018,021

TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg N 002,012,015-018,021

TPH (C10-C12 aliphatic) T206 M105 1 mg/kg M 002,012,015-018,021

TPH (C12-C16 aliphatic) T206 M105 2 mg/kg M 002,012,015-018,021

TPH (C16-C21 aliphatic) T206 M105 1 mg/kg M 002,012,015-018,021

TPH (C21-C35 aliphatic) T206 M105 4 mg/kg M 002,012,015-018,021

TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg N 002,012,015-018,021

TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg N 002,012,015-018,021

TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg N 002,012,015-018,021

TPH (C10-C12 aromatic) T206 M105 1 mg/kg N 002,012,015-018,021

TPH (C12-C16 aromatic) T206 M105 1 mg/kg M 002,012,015-018,021

TPH (C16-C21 aromatic) T206 M105 1 mg/kg M 002,012,015-018,021

TPH (C21-C35 aromatic) T206 M105 1 mg/kg M 002,012,015-018,021

1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

1,1,1-Trichloroethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021

1,1,2-Trichloroethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

1,1-Dichloroethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

1,1-Dichloroethylene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

1,1-Dichloropropene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

1,2,3-Trichloropropane T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021

1,2,4-Trimethylbenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

1,2-dibromoethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

1,2-Dichlorobenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

1,2-Dichloroethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

1,2-Dichloropropane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

1,3,5-Trimethylbenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

1,3-Dichlorobenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

1,3-Dichloropropane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

1,4-Dichlorobenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

2,2-Dichloropropane T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021

2-Chlorotoluene T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021

4-Chlorotoluene T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021

Benzene T209 M105 10 µg/kg M 002,004-005,010-012,015-018,021

Bromobenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Bromochloromethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

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Determinand Method TestSample LOD Units Symbol SAL References

Bromodichloromethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Bromoform T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Bromomethane T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021

Carbon tetrachloride T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Chlorobenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Chlorodibromomethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Chloroethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Chloroform T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Chloromethane T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021

Cis-1,2-Dichloroethylene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Cis-1,3-Dichloropropene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Dibromomethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Dichlorodifluoromethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Dichloromethane T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021

EthylBenzene T209 M105 10 µg/kg M 002,004-005,010-012,015-018,021

Isopropyl benzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

M/P Xylene T209 M105 10 µg/kg M 002,004-005,010-012,015-018,021

n-Propylbenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

O Xylene T209 M105 10 µg/kg M 002,004-005,010-012,015-018,021

p-Isopropyltoluene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

S-Butylbenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Styrene T209 M105 50 µg/kg U 002,004-005,010-012,015-018,021

T-Butylbenzene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Tetrachloroethene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Toluene T209 M105 10 µg/kg M 002,004-005,010-012,015-018,021

Trans-1,2-Dichloroethene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Trans-1,3-Dichloropropene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Trichloroethene T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Trichlorofluoromethane T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Vinyl chloride T209 M105 50 µg/kg M 002,004-005,010-012,015-018,021

Methyl tert-Butyl Ether T209 M105 10 µg/kg M 002,012,015-018,021

Ammoniacal nitrogen T686 10:1 0.05 mg/l U 002,012,015-018,021

Chloride T686 10:1 1 mg/l U 002,012,015-018,021

Cyanide(Total) T4 10:1 0.05 mg/l U 002,012,015-018,021

Cyanide(free) T4 10:1 0.05 mg/l U 002,012,015-018,021

Electrical Conductivity T7 10:1 10 µS/cm N 002,012,015-018,021

Nitrate T686 10:1 0.5 mg/l U 002,012,015-018,021

pH T7 10:1 U 002,012,015-018,021

Phenol T149 10:1 0.5 µg/l U 002,012,015-018,021

Sulphate T686 10:1 0.5 mg/l U 002,012,015-018,021

Sulphide T4 10:1 0.05 mg/l N 002,012,015-018,021

Sulphur (total) T65 10:1 0.01 mg/l N 002,012,015-018,021

TPH (C10-C35) T8 10:1 0.1 mg/l U 002,012,015-018,021

As (Dissolved) T281 10:1 0.2 µg/l U 002,012,015-018,021

Ba (Dissolved) T281 10:1 1 µg/l U 002,012,015-018,021

Be (Dissolved) T281 10:1 0.05 µg/l U 002,012,015-018,021

Chromium VI T686 10:1 3 µg/l U 002,012,015-018,021

Boron T6 10:1 10 µg/l N 002,012,015-018,021

Cd (Dissolved) T281 10:1 0.02 µg/l U 002,012,015-018,021

Cr (Dissolved) T281 10:1 1 µg/l U 002,012,015-018,021

Cu (Dissolved) T281 10:1 0.5 µg/l U 002,012,015-018,021

Pb (Dissolved) T281 10:1 0.3 µg/l U 002,012,015-018,021

Hg (Dissolved) T281 10:1 0.05 µg/l U 002,012,015-018,021

Ni (Dissolved) T281 10:1 1 µg/l U 002,012,015-018,021

Se (Dissolved) T281 10:1 0.5 µg/l U 002,012,015-018,021

V (Dissolved) T281 10:1 2 µg/l U 002,012,015-018,021

Zn (Dissolved) T281 10:1 2 µg/l U 002,012,015-018,021

Naphthalene T149 10:1 0.01 µg/l U 002,012,015-018,021

Acenaphthylene T149 10:1 0.01 µg/l U 002,012,015-018,021

Acenaphthene T149 10:1 0.01 µg/l U 002,012,015-018,021

Fluorene T149 10:1 0.01 µg/l U 002,012,015-018,021

Phenanthrene T149 10:1 0.01 µg/l U 002,012,015-018,021

Anthracene T149 10:1 0.01 µg/l U 002,012,015-018,021

Fluoranthene T149 10:1 0.01 µg/l U 002,012,015-018,021

Pyrene T149 10:1 0.01 µg/l U 002,012,015-018,021

Benzo(a)Anthracene T149 10:1 0.01 µg/l U 002,012,015-018,021

Chrysene T149 10:1 0.01 µg/l U 002,012,015-018,021

Benzo(b)fluoranthene T149 10:1 0.01 µg/l U 002,012,015-018,021

Benzo(k)fluoranthene T149 10:1 0.01 µg/l U 002,012,015-018,021

Benzo(a)Pyrene T149 10:1 0.01 µg/l U 002,012,015-018,021

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Determinand Method TestSample LOD Units Symbol SAL References

Indeno(123-cd)Pyrene T149 10:1 0.01 µg/l U 002,012,015-018,021

Dibenzo(ah)Anthracene T149 10:1 0.01 µg/l U 002,012,015-018,021

Benzo(ghi)Perylene T149 10:1 0.01 µg/l U 002,012,015-018,021

Coronene T149 10:1 0.01 µg/l N 002,012,015-018,021

PAH (Sum) T85 10:1 0.01 µg/l N 002,012,015-018,021

Asbestos ID T27 AR SU 002,012,015-018,021

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Scientific Analysis Laboratories Ltd

Certificate of Analysis

Hadfield HouseHadfield Street

CornbrookManchester

M16 9FETel : 0161 874 2400Fax : 0161 874 2468

Report Number: 435930-1

Date of Report: 21-Nov-2014

Customer: Soil Engineering Geoservices LimitedParkside LaneDewsbury RoadLeedsWest Yorkshire.LS11 5SX

Customer Contact: Mr Peter Stoddart

Customer Job Reference: TA7437Customer Site Reference: Mersey Gateway Bridge, Additional GI

(Phase 2)Date Job Received at SAL: 03-Nov-2014

Date Analysis Started: 13-Nov-2014Date Analysis Completed: 21-Nov-2014

The results reported relate to samples received in the laboratoryOpinions and interpretations expressed herein are outside the scope of UKAS accreditationThis report should not be reproduced except in full without the written approval of the laboratoryTests covered by this certificate were conducted in accordance with SAL SOPsAll results have been reviewed in accordance with QP22

This document has been printed from a digitally signed master copy

Scientific Analysis Laboratories is a

limited company registered in England and

Wales (No 2514788) whose address is at

Hadfield House, Hadfield Street, Manchester M16 9FE

1549

Report checkedand authorised by :Mr Ross WalkerCustomer Services Manager(Land)

Issued by :Mr Ross WalkerCustomer Services Manager(Land)

Page 1 of 9

435930-1

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SAL Reference: 435930

Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

MCERTS Preparation

SAL Reference 435930 005 435930 006 435930 009 435930 015

Customer Sample Reference BHXX3 ES 005 BHXX3 ES 006 BH323 ES 003 BH323 ES 009

Date Sampled 05-NOV-2014 05-NOV-2014 29-OCT-2014 31-OCT-2014

Depth 10.50 11.50 1.95 14.60

Type Sandy Soil Clay Sandy Soil Sandy Soil

Determinand Method TestSample LOD Units

Moisture @ 105 C T162 AR 0.1 % 19 14 37 24

SAL Reference: 435930

Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

CLEA Metals

SAL Reference 435930 009

Customer Sample Reference BH323 ES 003

Date Sampled 29-OCT-2014

Depth 1.95

Type Sandy Soil

Determinand Method TestSample LOD Units

Arsenic T6 M40 2 mg/kg 110

Barium T6 M40 1 mg/kg 44

Beryllium T6 M40 2 mg/kg <2

Boron (water-soluble) T6 AR 1 mg/kg <1

Cadmium T6 M40 1 mg/kg <1

Chromium T6 M40 1 mg/kg 9

Copper T6 M40 1 mg/kg 65

Lead T6 M40 1 mg/kg 120

Mercury T6 M40 1 mg/kg <1

Nickel T6 M40 1 mg/kg 9

Selenium T6 M40 3 mg/kg <3

Vanadium T6 M40 1 mg/kg 9

Zinc T6 M40 1 mg/kg 300

SAL Reference: 435930

Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Suite E

SAL Reference 435930 009

Customer Sample Reference BH323 ES 003

Date Sampled 29-OCT-2014

Depth 1.95

Type Sandy Soil

Determinand Method TestSample LOD Units

Asbestos ID T27 AR N.D.

Chromium VI T6 AR 1 mg/kg <1

Cyanide(Total) T546 AR 1 mg/kg <1

Cyanide(free) T546 AR 1 mg/kg <1

pH T7 AR 8.5

Phenols(Mono) T546 AR 1 mg/kg <1

(Water Soluble) SO4 expressed as SO4 T242 AR 0.01 g/l 1.3

Sulphide T546 AR 1 mg/kg <1

Sulphur (total) T6 M40 0.01 % 1.0

TPH (C10-C35) T8 M105 1 mg/kg <1

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435930-1

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SAL Reference: 435930

Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

PAH EPA 16, Coronene

SAL Reference 435930 009

Customer Sample Reference BH323 ES 003

Date Sampled 29-OCT-2014

Depth 1.95

Type Sandy Soil

Determinand Method TestSample LOD Units

Naphthalene T207 M105 0.1 mg/kg <0.1

Acenaphthylene T207 M105 0.1 mg/kg <0.1

Acenaphthene T207 M105 0.1 mg/kg <0.1

Fluorene T207 M105 0.1 mg/kg <0.1

Phenanthrene T207 M105 0.1 mg/kg 0.3

Anthracene T207 M105 0.1 mg/kg <0.1

Fluoranthene T207 M105 0.1 mg/kg 0.6

Pyrene T207 M105 0.1 mg/kg 0.6

Benzo(a)Anthracene T207 M105 0.1 mg/kg 0.4

Chrysene T207 M105 0.1 mg/kg 0.3

Benzo(b)fluoranthene T207 M105 0.1 mg/kg 0.4

Benzo(k)fluoranthene T207 M105 0.1 mg/kg 0.2

Benzo(a)Pyrene T207 M105 0.1 mg/kg 0.2

Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg <0.1

Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg <0.1

Benzo(ghi)Perylene T207 M105 0.1 mg/kg <0.1

Coronene T207 M105 0.1 mg/kg <0.1

PAH (Sum) T85 M105 1.6 mg/kg 3.0

SAL Reference: 435930

Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Suite K

SAL Reference 435930 009

Customer Sample Reference BH323 ES 003

Date Sampled 29-OCT-2014

Depth 1.95

Type Sandy Soil

Determinand Method TestSample LOD Units

Mass Fraction of organic carbon T286 M40 0.0077

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SAL Reference: 435930

Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

TPH (CWG)

SAL Reference 435930 009

Customer Sample Reference BH323 ES 003

Date Sampled 29-OCT-2014

Depth 1.95

Type Sandy Soil

Determinand Method TestSample LOD Units

TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg <0.100

TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg <0.10

TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg <0.10

TPH (C10-C12 aliphatic) T206 M105 1 mg/kg <1

TPH (C12-C16 aliphatic) T206 M105 2 mg/kg <2

TPH (C16-C21 aliphatic) T206 M105 1 mg/kg 1

TPH (C21-C35 aliphatic) T206 M105 4 mg/kg 10

TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg <0.10

TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg <0.10

TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg <0.10

TPH (C10-C12 aromatic) T206 M105 1 mg/kg <1

TPH (C12-C16 aromatic) T206 M105 1 mg/kg <1

TPH (C16-C21 aromatic) T206 M105 1 mg/kg <1

TPH (C21-C35 aromatic) T206 M105 1 mg/kg <1

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435930-1

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SAL Reference: 435930

Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Semi-Volatile Organic Compounds (Reduced)

SAL Reference 435930 009

Customer Sample Reference BH323 ES 003

Date Sampled 29-OCT-2014

Depth 1.95

Type Sandy Soil

Determinand Method TestSample LOD Units

1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg <0.1

1,2-Dichlorobenzene T207 M105 0.1 mg/kg <0.1

1,3-Dichlorobenzene T207 M105 0.1 mg/kg <0.1

1,4-Dichlorobenzene T207 M105 0.1 mg/kg <0.1

2,4,5-Trichlorophenol T207 M105 0.1 mg/kg <0.1

2,4,6-Trichlorophenol T207 M105 0.1 mg/kg <0.1

2,4-Dichlorophenol T207 M105 0.1 mg/kg <0.1

2,4-Dimethylphenol T207 M105 0.1 mg/kg <0.1

2,4-Dinitrophenol T207 M105 0.1 mg/kg (36) <0.5

2,4-Dinitrotoluene T207 M105 0.1 mg/kg <0.1

2,6-Dinitrotoluene T207 M105 0.1 mg/kg <0.1

2-Chloronaphthalene T207 M105 0.1 mg/kg <0.1

2-Chlorophenol T207 M105 0.1 mg/kg <0.1

2-methyl phenol T207 M105 0.1 mg/kg <0.1

2-Methylnaphthalene T207 M105 0.1 mg/kg <0.1

2-Nitroaniline T207 M105 0.1 mg/kg <0.1

2-Nitrophenol T207 M105 0.1 mg/kg <0.1

3-Nitroaniline T207 M105 0.1 mg/kg <0.1

3/4-Methylphenol T207 M105 0.1 mg/kg <0.1

4-Bromophenyl phenylether T207 M105 0.1 mg/kg <0.1

4-Chloro-3-methylphenol T207 M105 0.1 mg/kg <0.1

4-Chloroaniline T207 M105 0.1 mg/kg (36) <0.5

4-Chlorophenyl phenylether T207 M105 0.1 mg/kg <0.1

4-Nitroaniline T207 M105 0.1 mg/kg (36) <0.5

4-Nitrophenol T207 M105 0.1 mg/kg <0.1

Azobenzene T207 M105 0.1 mg/kg <0.1

Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg <0.1

Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg <0.1

Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg <0.1

Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg <0.1

Butyl benzylphthalate T207 M105 0.1 mg/kg <0.1

Carbazole T207 M105 0.1 mg/kg <0.1

Di-n-butylphthalate T207 M105 0.1 mg/kg <0.1

Di-n-octylphthalate T207 M105 0.1 mg/kg <0.1

Dibenzofuran T207 M105 0.1 mg/kg <0.1

Diethyl phthalate T207 M105 0.1 mg/kg <0.1

Dimethyl phthalate T207 M105 0.1 mg/kg <0.1

Hexachlorobenzene T207 M105 0.1 mg/kg <0.1

Hexachlorobutadiene T207 M105 0.1 mg/kg <0.1

Hexachlorocyclopentadiene T207 M105 0.1 mg/kg (36) <0.5

Hexachloroethane T207 M105 0.1 mg/kg <0.1

Isophorone T207 M105 0.1 mg/kg <0.1

Nitrobenzene T207 M105 0.1 mg/kg <0.1

Pentachlorophenol T207 M105 0.1 mg/kg (36) <0.5

Phenol T207 M105 0.1 mg/kg <0.1

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SAL Reference: 435930

Project Site: Mersey Gateway Bridge, Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Volatile Organic Compounds (USEPA 624) (MCERTS)

SAL Reference 435930 005 435930 006 435930 009 435930 015

Customer Sample Reference BHXX3 ES 005 BHXX3 ES 006 BH323 ES 003 BH323 ES 009

Date Sampled 05-NOV-2014 05-NOV-2014 29-OCT-2014 31-OCT-2014

Depth 10.50 11.50 1.95 14.60

Type Sandy Soil Clay Sandy Soil Sandy Soil

Determinand Method TestSample LOD Units

1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg <50 <50 <50 <50

1,1,1-Trichloroethane T209 M105 50 µg/kg <50 <50 <50 <50

1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg <50 <50 <50 <50

1,1,2-Trichloroethane T209 M105 50 µg/kg <50 <50 210 1500

1,1-Dichloroethane T209 M105 50 µg/kg <50 <50 <50 310

1,1-Dichloroethylene T209 M105 50 µg/kg <50 <50 95 300

1,1-Dichloropropene T209 M105 50 µg/kg <50 <50 <50 <50

1,2,3-Trichloropropane T209 M105 50 µg/kg <50 <50 <50 <50

1,2,4-Trimethylbenzene T209 M105 50 µg/kg <50 <50 <50 <50

1,2-dibromoethane T209 M105 50 µg/kg <50 <50 <50 <50

1,2-Dichlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50

1,2-Dichloroethane T209 M105 50 µg/kg <50 <50 <50 <50

1,2-Dichloropropane T209 M105 50 µg/kg <50 <50 <50 <50

1,3,5-Trimethylbenzene T209 M105 50 µg/kg <50 <50 <50 <50

1,3-Dichlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50

1,3-Dichloropropane T209 M105 50 µg/kg <50 <50 <50 <50

1,4-Dichlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50

2,2-Dichloropropane T209 M105 50 µg/kg <50 <50 <50 <50

2-Chlorotoluene T209 M105 50 µg/kg <50 <50 <50 <50

4-Chlorotoluene T209 M105 50 µg/kg <50 <50 <50 <50

Benzene T209 M105 10 µg/kg (13) <10 (13) <10 (13) <10 (13) <10

Bromobenzene T209 M105 50 µg/kg <50 <50 <50 <50

Bromochloromethane T209 M105 50 µg/kg <50 <50 <50 <50

Bromodichloromethane T209 M105 50 µg/kg <50 <50 <50 <50

Bromoform T209 M105 50 µg/kg <50 <50 <50 <50

Bromomethane T209 M105 50 µg/kg <50 <50 <50 <50

Carbon tetrachloride T209 M105 50 µg/kg 58 <50 <50 <50

Chlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50

Chlorodibromomethane T209 M105 50 µg/kg <50 <50 <50 <50

Chloroethane T209 M105 50 µg/kg <50 <50 <50 <50

Chloroform T209 M105 50 µg/kg 350 59 <50 <50

Chloromethane T209 M105 50 µg/kg <50 <50 <50 <50

Cis-1,2-Dichloroethylene T209 M105 50 µg/kg <50 <50 <50 <50

Cis-1,3-Dichloropropene T209 M105 50 µg/kg <50 <50 <50 <50

Dibromomethane T209 M105 50 µg/kg <50 <50 <50 <50

Dichlorodifluoromethane T209 M105 50 µg/kg <50 <50 <50 <50

Dichloromethane T209 M105 50 µg/kg <50 <50 <50 <50

EthylBenzene T209 M105 10 µg/kg <10 <10 <10 <10

Isopropyl benzene T209 M105 50 µg/kg <50 <50 <50 <50

M/P Xylene T209 M105 10 µg/kg <10 <10 <10 <10

n-Propylbenzene T209 M105 50 µg/kg <50 <50 <50 <50

O Xylene T209 M105 10 µg/kg <10 <10 <10 <10

p-Isopropyltoluene T209 M105 50 µg/kg <50 <50 <50 <50

S-Butylbenzene T209 M105 50 µg/kg <50 <50 <50 <50

Styrene T209 M105 50 µg/kg <50 <50 <50 <50

T-Butylbenzene T209 M105 50 µg/kg <50 <50 <50 <50

Tetrachloroethene T209 M105 50 µg/kg <50 <50 <50 <50

Toluene T209 M105 10 µg/kg <10 <10 <10 <10

Trans-1,2-Dichloroethene T209 M105 50 µg/kg <50 <50 <50 <50

Trans-1,3-Dichloropropene T209 M105 50 µg/kg <50 <50 <50 <50

Trichloroethene T209 M105 50 µg/kg <50 <50 150 170

Trichlorofluoromethane T209 M105 50 µg/kg <50 <50 <50 <50

Vinyl chloride T209 M105 50 µg/kg <50 <50 <50 <50

Methyl tert-Butyl Ether T209 M105 10 µg/kg - - <10 -

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Index to symbols used in 435930-1

Notes

Method Index

Accreditation Summary

Value Description

AR As Received

M105 Analysis conducted on an "as received" aliquot.Results are reported on a dry weight basis wheremoisture content was determined by assisteddrying of sample at 105C

M40 Analysis conducted on sample assisted dried at nomore than 40C. Results are reported on a dryweight basis.

N.D. Not Detected

13 Results have been blank corrected.

36 LOD Raised due to low Matrix spike recovery

S Analysis was subcontracted

M Analysis is MCERTS accredited

U Analysis is UKAS accredited

N Analysis is not UKAS accredited

Asbestos was subcontracted to REC Asbestos

Value Description

T242 2:1 Extraction/ICP/OES (TRL 447 T1)

T8 GC/FID

T206 GC/FID (MCERTS)

T209 GC/MS(Head Space)(MCERTS)

T7 Probe

T162 Grav (1 Dec) (105 C)

T27 PLM

T6 ICP/OES

T286 Calc TOC/100

T85 Calc

T207 GC/MS (MCERTS)

T546 Colorimetry (CF)

Determinand Method TestSample LOD Units Symbol SAL References

Moisture @ 105 C T162 AR 0.1 % N 005-006,009,015

Asbestos ID T27 AR SU 009

Chromium VI T6 AR 1 mg/kg N 009

Cyanide(Total) T546 AR 1 mg/kg M 009

Cyanide(free) T546 AR 1 mg/kg M 009

pH T7 AR M 009

Phenols(Mono) T546 AR 1 mg/kg M 009

(Water Soluble) SO4 expressed as SO4 T242 AR 0.01 g/l N 009

Sulphide T546 AR 1 mg/kg N 009

Sulphur (total) T6 M40 0.01 % N 009

TPH (C10-C35) T8 M105 1 mg/kg M 009

Arsenic T6 M40 2 mg/kg M 009

Barium T6 M40 1 mg/kg U 009

Beryllium T6 M40 2 mg/kg M 009

Boron (water-soluble) T6 AR 1 mg/kg N 009

Cadmium T6 M40 1 mg/kg M 009

Chromium T6 M40 1 mg/kg M 009

Copper T6 M40 1 mg/kg M 009

Lead T6 M40 1 mg/kg M 009

Mercury T6 M40 1 mg/kg M 009

Nickel T6 M40 1 mg/kg M 009

Selenium T6 M40 3 mg/kg M 009

Vanadium T6 M40 1 mg/kg M 009

Zinc T6 M40 1 mg/kg M 009

Naphthalene T207 M105 0.1 mg/kg M 009

Acenaphthylene T207 M105 0.1 mg/kg U 009

Acenaphthene T207 M105 0.1 mg/kg M 009

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435930-1

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Determinand Method TestSample LOD Units Symbol SAL References

Fluorene T207 M105 0.1 mg/kg M 009

Phenanthrene T207 M105 0.1 mg/kg M 009

Anthracene T207 M105 0.1 mg/kg U 009

Fluoranthene T207 M105 0.1 mg/kg M 009

Pyrene T207 M105 0.1 mg/kg M 009

Benzo(a)Anthracene T207 M105 0.1 mg/kg M 009

Chrysene T207 M105 0.1 mg/kg M 009

Benzo(b)fluoranthene T207 M105 0.1 mg/kg M 009

Benzo(k)fluoranthene T207 M105 0.1 mg/kg M 009

Benzo(a)Pyrene T207 M105 0.1 mg/kg M 009

Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg M 009

Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg M 009

Benzo(ghi)Perylene T207 M105 0.1 mg/kg M 009

Coronene T207 M105 0.1 mg/kg N 009

PAH (Sum) T85 M105 1.6 mg/kg N 009

Mass Fraction of organic carbon T286 M40 N 009

1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg M 009

1,2-Dichlorobenzene T207 M105 0.1 mg/kg M 009

1,3-Dichlorobenzene T207 M105 0.1 mg/kg M 009

1,4-Dichlorobenzene T207 M105 0.1 mg/kg M 009

2,4,5-Trichlorophenol T207 M105 0.1 mg/kg U 009

2,4,6-Trichlorophenol T207 M105 0.1 mg/kg U 009

2,4-Dichlorophenol T207 M105 0.1 mg/kg U 009

2,4-Dimethylphenol T207 M105 0.1 mg/kg U 009

2,4-Dinitrophenol T207 M105 0.1 mg/kg U 009

2,4-Dinitrotoluene T207 M105 0.1 mg/kg M 009

2,6-Dinitrotoluene T207 M105 0.1 mg/kg U 009

2-Chloronaphthalene T207 M105 0.1 mg/kg M 009

2-Chlorophenol T207 M105 0.1 mg/kg M 009

2-methyl phenol T207 M105 0.1 mg/kg M 009

2-Methylnaphthalene T207 M105 0.1 mg/kg M 009

2-Nitroaniline T207 M105 0.1 mg/kg M 009

2-Nitrophenol T207 M105 0.1 mg/kg U 009

3-Nitroaniline T207 M105 0.1 mg/kg U 009

3/4-Methylphenol T207 M105 0.1 mg/kg M 009

4-Bromophenyl phenylether T207 M105 0.1 mg/kg M 009

4-Chloro-3-methylphenol T207 M105 0.1 mg/kg M 009

4-Chloroaniline T207 M105 0.1 mg/kg U 009

4-Chlorophenyl phenylether T207 M105 0.1 mg/kg M 009

4-Nitroaniline T207 M105 0.1 mg/kg U 009

4-Nitrophenol T207 M105 0.1 mg/kg U 009

Azobenzene T207 M105 0.1 mg/kg M 009

Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg M 009

Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg M 009

Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg M 009

Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg M 009

Butyl benzylphthalate T207 M105 0.1 mg/kg U 009

Carbazole T207 M105 0.1 mg/kg U 009

Di-n-butylphthalate T207 M105 0.1 mg/kg M 009

Di-n-octylphthalate T207 M105 0.1 mg/kg M 009

Dibenzofuran T207 M105 0.1 mg/kg M 009

Diethyl phthalate T207 M105 0.1 mg/kg U 009

Dimethyl phthalate T207 M105 0.1 mg/kg U 009

Hexachlorobenzene T207 M105 0.1 mg/kg M 009

Hexachlorobutadiene T207 M105 0.1 mg/kg M 009

Hexachlorocyclopentadiene T207 M105 0.1 mg/kg U 009

Hexachloroethane T207 M105 0.1 mg/kg U 009

Isophorone T207 M105 0.1 mg/kg U 009

Nitrobenzene T207 M105 0.1 mg/kg M 009

Pentachlorophenol T207 M105 0.1 mg/kg U 009

Phenol T207 M105 0.1 mg/kg M 009

TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg N 009

TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg N 009

TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg N 009

TPH (C10-C12 aliphatic) T206 M105 1 mg/kg M 009

TPH (C12-C16 aliphatic) T206 M105 2 mg/kg M 009

TPH (C16-C21 aliphatic) T206 M105 1 mg/kg M 009

TPH (C21-C35 aliphatic) T206 M105 4 mg/kg M 009

TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg N 009

TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg N 009

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435930-1

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Determinand Method TestSample LOD Units Symbol SAL References

TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg N 009

TPH (C10-C12 aromatic) T206 M105 1 mg/kg N 009

TPH (C12-C16 aromatic) T206 M105 1 mg/kg M 009

TPH (C16-C21 aromatic) T206 M105 1 mg/kg M 009

TPH (C21-C35 aromatic) T206 M105 1 mg/kg M 009

1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg M 005-006,009,015

1,1,1-Trichloroethane T209 M105 50 µg/kg M 005-006,009,015

1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg U 005-006,009,015

1,1,2-Trichloroethane T209 M105 50 µg/kg M 005-006,009,015

1,1-Dichloroethane T209 M105 50 µg/kg M 005-006,009,015

1,1-Dichloroethylene T209 M105 50 µg/kg M 005-006,009,015

1,1-Dichloropropene T209 M105 50 µg/kg M 005-006,009,015

1,2,3-Trichloropropane T209 M105 50 µg/kg U 005-006,009,015

1,2,4-Trimethylbenzene T209 M105 50 µg/kg M 005-006,009,015

1,2-dibromoethane T209 M105 50 µg/kg M 005-006,009,015

1,2-Dichlorobenzene T209 M105 50 µg/kg M 005-006,009,015

1,2-Dichloroethane T209 M105 50 µg/kg M 005-006,009,015

1,2-Dichloropropane T209 M105 50 µg/kg M 005-006,009,015

1,3,5-Trimethylbenzene T209 M105 50 µg/kg M 005-006,009,015

1,3-Dichlorobenzene T209 M105 50 µg/kg M 005-006,009,015

1,3-Dichloropropane T209 M105 50 µg/kg M 005-006,009,015

1,4-Dichlorobenzene T209 M105 50 µg/kg M 005-006,009,015

2,2-Dichloropropane T209 M105 50 µg/kg U 005-006,009,015

2-Chlorotoluene T209 M105 50 µg/kg U 005-006,009,015

4-Chlorotoluene T209 M105 50 µg/kg U 005-006,009,015

Benzene T209 M105 10 µg/kg M 005-006,009,015

Bromobenzene T209 M105 50 µg/kg M 005-006,009,015

Bromochloromethane T209 M105 50 µg/kg M 005-006,009,015

Bromodichloromethane T209 M105 50 µg/kg M 005-006,009,015

Bromoform T209 M105 50 µg/kg M 005-006,009,015

Bromomethane T209 M105 50 µg/kg U 005-006,009,015

Carbon tetrachloride T209 M105 50 µg/kg M 005-006,009,015

Chlorobenzene T209 M105 50 µg/kg M 005-006,009,015

Chlorodibromomethane T209 M105 50 µg/kg M 005-006,009,015

Chloroethane T209 M105 50 µg/kg M 005-006,009,015

Chloroform T209 M105 50 µg/kg M 005-006,009,015

Chloromethane T209 M105 50 µg/kg U 005-006,009,015

Cis-1,2-Dichloroethylene T209 M105 50 µg/kg M 005-006,009,015

Cis-1,3-Dichloropropene T209 M105 50 µg/kg M 005-006,009,015

Dibromomethane T209 M105 50 µg/kg M 005-006,009,015

Dichlorodifluoromethane T209 M105 50 µg/kg M 005-006,009,015

Dichloromethane T209 M105 50 µg/kg U 005-006,009,015

EthylBenzene T209 M105 10 µg/kg M 005-006,009,015

Isopropyl benzene T209 M105 50 µg/kg M 005-006,009,015

M/P Xylene T209 M105 10 µg/kg M 005-006,009,015

n-Propylbenzene T209 M105 50 µg/kg M 005-006,009,015

O Xylene T209 M105 10 µg/kg M 005-006,009,015

p-Isopropyltoluene T209 M105 50 µg/kg M 005-006,009,015

S-Butylbenzene T209 M105 50 µg/kg M 005-006,009,015

Styrene T209 M105 50 µg/kg U 005-006,009,015

T-Butylbenzene T209 M105 50 µg/kg M 005-006,009,015

Tetrachloroethene T209 M105 50 µg/kg M 005-006,009,015

Toluene T209 M105 10 µg/kg M 005-006,009,015

Trans-1,2-Dichloroethene T209 M105 50 µg/kg M 005-006,009,015

Trans-1,3-Dichloropropene T209 M105 50 µg/kg M 005-006,009,015

Trichloroethene T209 M105 50 µg/kg M 005-006,009,015

Trichlorofluoromethane T209 M105 50 µg/kg M 005-006,009,015

Vinyl chloride T209 M105 50 µg/kg M 005-006,009,015

Methyl tert-Butyl Ether T209 M105 10 µg/kg M 009

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435930-1

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Scientific Analysis Laboratories Ltd

Certificate of Analysis

Hadfield HouseHadfield Street

CornbrookManchester

M16 9FETel : 0161 874 2400Fax : 0161 874 2468

Report Number: 473147-1

Date of Report: 06-May-2015

Customer: Soil Engineering Geoservices LimitedParkside LaneDewsbury RoadLeedsWest Yorkshire.LS11 5SX

Customer Contact: Mr Ian Swain

Customer Job Reference: TA7437Customer Site Reference: Mersey Gateway Bridge. Additional GI

(Phase 2)Date Job Received at SAL: 22-Apr-2015

Date Analysis Started: 29-Apr-2015Date Analysis Completed: 06-May-2015

The results reported relate to samples received in the laboratoryOpinions and interpretations expressed herein are outside the scope of UKAS accreditationThis report should not be reproduced except in full without the written approval of the laboratoryTests covered by this certificate were conducted in accordance with SAL SOPsAll results have been reviewed in accordance with QP22

This document has been printed from a digitally signed master copy

Scientific Analysis Laboratories is a

limited company registered in England and

Wales (No 2514788) whose address is at

Hadfield House, Hadfield Street, Manchester M16 9FE

1549

Report checkedand authorised by :Natasha WildProject Manager

Issued by :Natasha WildProject Manager

Page 1 of 9

473147-1

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SAL Reference: 473147

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Moisture

SAL Reference 473147 013

Customer Sample Reference BHXX4 ES 013

Top Depth 10.30

Date Sampled 22-APR-2015

Bottom Depth 10.30

Type Clay

Determinand Method TestSample LOD Units

Moisture @ 105 C T162 AR 0.1 % 15

SAL Reference: 473147

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

CLEA Metals

SAL Reference 473147 013

Customer Sample Reference BHXX4 ES 013

Top Depth 10.30

Date Sampled 22-APR-2015

Bottom Depth 10.30

Type Clay

Determinand Method TestSample LOD Units

Arsenic T6 M40 2 mg/kg 8

Barium T6 M40 1 mg/kg 110

Beryllium T6 M40 2 mg/kg <2

Boron (water-soluble) T6 AR 1 mg/kg <1

Cadmium T6 M40 1 mg/kg <1

Chromium T6 M40 1 mg/kg 26

Copper T6 M40 1 mg/kg 27

Lead T6 M40 1 mg/kg 16

Mercury T6 M40 1 mg/kg <1

Nickel T6 M40 1 mg/kg 31

Selenium T6 M40 3 mg/kg <3

Vanadium T6 M40 1 mg/kg 25

Zinc T6 M40 1 mg/kg 110

SAL Reference: 473147

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Suite E

SAL Reference 473147 013

Customer Sample Reference BHXX4 ES 013

Top Depth 10.30

Date Sampled 22-APR-2015

Bottom Depth 10.30

Type Clay

Determinand Method TestSample LOD Units

Asbestos ID T27 AR N.D.

Chromium VI T6 AR 1 mg/kg <1

Cyanide(Total) T546 AR 1 mg/kg <1

Cyanide(free) T546 AR 1 mg/kg <1

pH T7 AR 8.3

Phenols(Mono) T546 AR 1 mg/kg <1

(Water Soluble) SO4 expressed as SO4 T242 AR 0.01 g/l 0.31

Sulphide T546 AR 1 mg/kg <1

Sulphur (total) T6 M40 0.01 % 0.06

TPH (C10-C35) T8 M105 1 mg/kg <1

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SAL Reference: 473147

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Carbon disulphide

SAL Reference 473147 013

Customer Sample Reference BHXX4 ES 013

Top Depth 10.30

Date Sampled 22-APR-2015

Bottom Depth 10.30

Type Clay

Determinand Method TestSample LOD Units

Carbon disulphide T54 M105 0.1 mg/kg 0.5

SAL Reference: 473147

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Suite K

SAL Reference 473147 013

Customer Sample Reference BHXX4 ES 013

Top Depth 10.30

Date Sampled 22-APR-2015

Bottom Depth 10.30

Type Clay

Determinand Method TestSample LOD Units

Mass Fraction of organic carbon T286 M40 0.0064

Methyl tert-Butyl Ether T209 M105 10 µg/kg <10

SAL Reference: 473147

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

TPH (CWG)

SAL Reference 473147 013

Customer Sample Reference BHXX4 ES 013

Top Depth 10.30

Date Sampled 22-APR-2015

Bottom Depth 10.30

Type Clay

Determinand Method TestSample LOD Units

TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg <0.100

TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg <0.10

TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg <0.10

TPH (C10-C12 aliphatic) T206 M105 1 mg/kg <1

TPH (C12-C16 aliphatic) T206 M105 2 mg/kg <2

TPH (C16-C21 aliphatic) T206 M105 1 mg/kg <1

TPH (C21-C35 aliphatic) T206 M105 4 mg/kg <4

TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg <0.10

TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg <0.10

TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg <0.10

TPH (C10-C12 aromatic) T206 M105 1 mg/kg <1

TPH (C12-C16 aromatic) T206 M105 1 mg/kg <1

TPH (C16-C21 aromatic) T206 M105 1 mg/kg <1

TPH (C21-C35 aromatic) T206 M105 1 mg/kg <1

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473147-1

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SAL Reference: 473147

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

PAH EPA 16, Coronene

SAL Reference 473147 013

Customer Sample Reference BHXX4 ES 013

Top Depth 10.30

Date Sampled 22-APR-2015

Bottom Depth 10.30

Type Clay

Determinand Method TestSample LOD Units

Naphthalene T207 M105 0.1 mg/kg <0.1

Acenaphthylene T207 M105 0.1 mg/kg <0.1

Acenaphthene T207 M105 0.1 mg/kg <0.1

Fluorene T207 M105 0.1 mg/kg <0.1

Phenanthrene T207 M105 0.1 mg/kg <0.1

Anthracene T207 M105 0.1 mg/kg <0.1

Fluoranthene T207 M105 0.1 mg/kg <0.1

Pyrene T207 M105 0.1 mg/kg <0.1

Benzo(a)Anthracene T207 M105 0.1 mg/kg <0.1

Chrysene T207 M105 0.1 mg/kg <0.1

Benzo(b)fluoranthene T207 M105 0.1 mg/kg <0.1

Benzo(k)fluoranthene T207 M105 0.1 mg/kg <0.1

Benzo(a)Pyrene T207 M105 0.1 mg/kg <0.1

Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg <0.1

Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg <0.1

Benzo(ghi)Perylene T207 M105 0.1 mg/kg <0.1

Coronene T207 M105 0.1 mg/kg <0.1

PAH (Sum) T85 M105 1.6 mg/kg <1.6

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473147-1

Page 95: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

SAL Reference: 473147

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Semi-Volatile Organic Compounds (Reduced)

SAL Reference 473147 013

Customer Sample Reference BHXX4 ES 013

Top Depth 10.30

Date Sampled 22-APR-2015

Bottom Depth 10.30

Type Clay

Determinand Method TestSample LOD Units

1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg <0.1

1,2-Dichlorobenzene T207 M105 0.1 mg/kg <0.1

1,3-Dichlorobenzene T207 M105 0.1 mg/kg <0.1

1,4-Dichlorobenzene T207 M105 0.1 mg/kg <0.1

2,4,5-Trichlorophenol T207 M105 0.1 mg/kg <0.1

2,4,6-Trichlorophenol T207 M105 0.1 mg/kg <0.1

2,4-Dichlorophenol T207 M105 0.1 mg/kg <0.1

2,4-Dimethylphenol T207 M105 0.1 mg/kg <0.1

2,4-Dinitrophenol T207 M105 0.1 mg/kg <0.1

2,4-Dinitrotoluene T207 M105 0.1 mg/kg <0.1

2,6-Dinitrotoluene T207 M105 0.1 mg/kg <0.1

2-Chloronaphthalene T207 M105 0.1 mg/kg <0.1

2-Chlorophenol T207 M105 0.1 mg/kg <0.1

2-methyl phenol T207 M105 0.1 mg/kg <0.1

2-Methylnaphthalene T207 M105 0.1 mg/kg <0.1

2-Nitroaniline T207 M105 0.1 mg/kg <0.1

2-Nitrophenol T207 M105 0.1 mg/kg <0.1

3-Nitroaniline T207 M105 0.1 mg/kg <0.1

3/4-Methylphenol T207 M105 0.1 mg/kg <0.1

4-Bromophenyl phenylether T207 M105 0.1 mg/kg <0.1

4-Chloro-3-methylphenol T207 M105 0.1 mg/kg <0.1

4-Chloroaniline T207 M105 0.1 mg/kg (36) <0.5

4-Chlorophenyl phenylether T207 M105 0.1 mg/kg <0.1

4-Nitroaniline T207 M105 0.1 mg/kg (36) <0.5

4-Nitrophenol T207 M105 0.1 mg/kg (36) <0.5

Azobenzene T207 M105 0.1 mg/kg <0.1

Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg <0.1

Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg <0.1

Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg <0.1

Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg <0.1

Butyl benzylphthalate T207 M105 0.1 mg/kg <0.1

Carbazole T207 M105 0.1 mg/kg <0.1

Di-n-butylphthalate T207 M105 0.1 mg/kg <0.1

Di-n-octylphthalate T207 M105 0.1 mg/kg <0.1

Dibenzofuran T207 M105 0.1 mg/kg (36) <0.5

Diethyl phthalate T207 M105 0.1 mg/kg <0.1

Dimethyl phthalate T207 M105 0.1 mg/kg <0.1

Hexachlorobenzene T207 M105 0.1 mg/kg <0.1

Hexachlorobutadiene T207 M105 0.1 mg/kg <0.1

Hexachlorocyclopentadiene T207 M105 0.1 mg/kg (36) <0.5

Hexachloroethane T207 M105 0.1 mg/kg <0.1

Isophorone T207 M105 0.1 mg/kg <0.1

Nitrobenzene T207 M105 0.1 mg/kg <0.1

Pentachlorophenol T207 M105 0.1 mg/kg (36) <0.5

Phenol T207 M105 0.1 mg/kg <0.1

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473147-1

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SAL Reference: 473147

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Volatile Organic Compounds (USEPA 624) (MCERTS)

SAL Reference 473147 013

Customer Sample Reference BHXX4 ES 013

Top Depth 10.30

Date Sampled 22-APR-2015

Bottom Depth 10.30

Type Clay

Determinand Method TestSample LOD Units

1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg <50

1,1,1-Trichloroethane T209 M105 50 µg/kg <50

1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg <50

1,1,2-Trichloroethane T209 M105 50 µg/kg <50

1,1-Dichloroethane T209 M105 50 µg/kg <50

1,1-Dichloroethylene T209 M105 50 µg/kg <50

1,1-Dichloropropene T209 M105 50 µg/kg <50

1,2,3-Trichloropropane T209 M105 50 µg/kg <50

1,2,4-Trimethylbenzene T209 M105 50 µg/kg <50

1,2-dibromoethane T209 M105 50 µg/kg <50

1,2-Dichlorobenzene T209 M105 50 µg/kg <50

1,2-Dichloroethane T209 M105 50 µg/kg <50

1,2-Dichloropropane T209 M105 50 µg/kg <50

1,3,5-Trimethylbenzene T209 M105 50 µg/kg <50

1,3-Dichlorobenzene T209 M105 50 µg/kg <50

1,3-Dichloropropane T209 M105 50 µg/kg <50

1,4-Dichlorobenzene T209 M105 50 µg/kg <50

2,2-Dichloropropane T209 M105 50 µg/kg <50

2-Chlorotoluene T209 M105 50 µg/kg <50

4-Chlorotoluene T209 M105 50 µg/kg <50

Benzene T209 M105 10 µg/kg <10

Bromobenzene T209 M105 50 µg/kg <50

Bromochloromethane T209 M105 50 µg/kg <50

Bromodichloromethane T209 M105 50 µg/kg <50

Bromoform T209 M105 50 µg/kg <50

Bromomethane T209 M105 50 µg/kg <50

Carbon tetrachloride T209 M105 50 µg/kg <50

Chlorobenzene T209 M105 50 µg/kg <50

Chlorodibromomethane T209 M105 50 µg/kg <50

Chloroethane T209 M105 50 µg/kg <50

Chloroform T209 M105 50 µg/kg 160

Chloromethane T209 M105 50 µg/kg <50

Cis-1,2-Dichloroethylene T209 M105 50 µg/kg <50

Cis-1,3-Dichloropropene T209 M105 50 µg/kg <50

Dibromomethane T209 M105 50 µg/kg <50

Dichlorodifluoromethane T209 M105 50 µg/kg <50

Dichloromethane T209 M105 50 µg/kg <50

EthylBenzene T209 M105 10 µg/kg <10

Isopropyl benzene T209 M105 50 µg/kg <50

M/P Xylene T209 M105 10 µg/kg <10

n-Propylbenzene T209 M105 50 µg/kg <50

O Xylene T209 M105 10 µg/kg <10

p-Isopropyltoluene T209 M105 50 µg/kg <50

S-Butylbenzene T209 M105 50 µg/kg <50

Styrene T209 M105 50 µg/kg <50

T-Butylbenzene T209 M105 50 µg/kg <50

Tetrachloroethene T209 M105 50 µg/kg <50

Toluene T209 M105 10 µg/kg <10

Trans-1,2-Dichloroethene T209 M105 50 µg/kg <50

Trans-1,3-Dichloropropene T209 M105 50 µg/kg <50

Trichloroethene T209 M105 50 µg/kg <50

Trichlorofluoromethane T209 M105 50 µg/kg <50

Vinyl chloride T209 M105 50 µg/kg <50

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473147-1

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Index to symbols used in 473147-1

Notes

Method Index

Accreditation Summary

Value Description

AR As Received

M105 Analysis conducted on an "as received" aliquot.Results are reported on a dry weight basis wheremoisture content was determined by assisteddrying of sample at 105C

M40 Analysis conducted on sample assisted dried at nomore than 40C. Results are reported on a dryweight basis.

N.D. Not Detected

36 LOD Raised due to low Matrix spike recovery

S Analysis was subcontracted

M Analysis is MCERTS accredited

U Analysis is UKAS accredited

N Analysis is not UKAS accredited

Asbestos was subcontracted to REC Asbestos

Value Description

T85 Calc

T162 Grav (1 Dec) (105 C)

T209 GC/MS(Head Space)(MCERTS)

T546 Colorimetry (CF)

T6 ICP/OES

T286 Calc TOC/100

T54 GC/MS (Headspace)

T207 GC/MS (MCERTS)

T27 PLM

T242 2:1 Extraction/ICP/OES (TRL 447 T1)

T8 GC/FID

T7 Probe

T206 GC/FID (MCERTS)

Determinand Method TestSample LOD Units Symbol SAL References

Carbon disulphide T54 M105 0.1 mg/kg N 013

Asbestos ID T27 AR SU 013

Chromium VI T6 AR 1 mg/kg N 013

Cyanide(Total) T546 AR 1 mg/kg M 013

Cyanide(free) T546 AR 1 mg/kg M 013

pH T7 AR M 013

Phenols(Mono) T546 AR 1 mg/kg M 013

(Water Soluble) SO4 expressed as SO4 T242 AR 0.01 g/l N 013

Sulphide T546 AR 1 mg/kg N 013

Sulphur (total) T6 M40 0.01 % N 013

TPH (C10-C35) T8 M105 1 mg/kg M 013

Arsenic T6 M40 2 mg/kg M 013

Barium T6 M40 1 mg/kg U 013

Beryllium T6 M40 2 mg/kg M 013

Boron (water-soluble) T6 AR 1 mg/kg N 013

Cadmium T6 M40 1 mg/kg M 013

Chromium T6 M40 1 mg/kg M 013

Copper T6 M40 1 mg/kg M 013

Lead T6 M40 1 mg/kg M 013

Mercury T6 M40 1 mg/kg M 013

Nickel T6 M40 1 mg/kg M 013

Selenium T6 M40 3 mg/kg M 013

Vanadium T6 M40 1 mg/kg M 013

Zinc T6 M40 1 mg/kg M 013

Naphthalene T207 M105 0.1 mg/kg M 013

Acenaphthylene T207 M105 0.1 mg/kg U 013

Acenaphthene T207 M105 0.1 mg/kg M 013

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473147-1

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Determinand Method TestSample LOD Units Symbol SAL References

Fluorene T207 M105 0.1 mg/kg M 013

Phenanthrene T207 M105 0.1 mg/kg M 013

Anthracene T207 M105 0.1 mg/kg U 013

Fluoranthene T207 M105 0.1 mg/kg M 013

Pyrene T207 M105 0.1 mg/kg M 013

Benzo(a)Anthracene T207 M105 0.1 mg/kg M 013

Chrysene T207 M105 0.1 mg/kg M 013

Benzo(b)fluoranthene T207 M105 0.1 mg/kg M 013

Benzo(k)fluoranthene T207 M105 0.1 mg/kg M 013

Benzo(a)Pyrene T207 M105 0.1 mg/kg M 013

Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg M 013

Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg M 013

Benzo(ghi)Perylene T207 M105 0.1 mg/kg M 013

Coronene T207 M105 0.1 mg/kg N 013

PAH (Sum) T85 M105 1.6 mg/kg N 013

Mass Fraction of organic carbon T286 M40 N 013

Methyl tert-Butyl Ether T209 M105 10 µg/kg M 013

1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg M 013

1,2-Dichlorobenzene T207 M105 0.1 mg/kg M 013

1,3-Dichlorobenzene T207 M105 0.1 mg/kg M 013

1,4-Dichlorobenzene T207 M105 0.1 mg/kg M 013

2,4,5-Trichlorophenol T207 M105 0.1 mg/kg U 013

2,4,6-Trichlorophenol T207 M105 0.1 mg/kg U 013

2,4-Dichlorophenol T207 M105 0.1 mg/kg U 013

2,4-Dimethylphenol T207 M105 0.1 mg/kg U 013

2,4-Dinitrophenol T207 M105 0.1 mg/kg U 013

2,4-Dinitrotoluene T207 M105 0.1 mg/kg M 013

2,6-Dinitrotoluene T207 M105 0.1 mg/kg U 013

2-Chloronaphthalene T207 M105 0.1 mg/kg M 013

2-Chlorophenol T207 M105 0.1 mg/kg M 013

2-methyl phenol T207 M105 0.1 mg/kg M 013

2-Methylnaphthalene T207 M105 0.1 mg/kg M 013

2-Nitroaniline T207 M105 0.1 mg/kg M 013

2-Nitrophenol T207 M105 0.1 mg/kg U 013

3-Nitroaniline T207 M105 0.1 mg/kg U 013

3/4-Methylphenol T207 M105 0.1 mg/kg M 013

4-Bromophenyl phenylether T207 M105 0.1 mg/kg M 013

4-Chloro-3-methylphenol T207 M105 0.1 mg/kg M 013

4-Chloroaniline T207 M105 0.1 mg/kg U 013

4-Chlorophenyl phenylether T207 M105 0.1 mg/kg M 013

4-Nitroaniline T207 M105 0.1 mg/kg U 013

4-Nitrophenol T207 M105 0.1 mg/kg U 013

Azobenzene T207 M105 0.1 mg/kg M 013

Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg M 013

Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg M 013

Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg M 013

Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg M 013

Butyl benzylphthalate T207 M105 0.1 mg/kg U 013

Carbazole T207 M105 0.1 mg/kg U 013

Di-n-butylphthalate T207 M105 0.1 mg/kg M 013

Di-n-octylphthalate T207 M105 0.1 mg/kg M 013

Dibenzofuran T207 M105 0.1 mg/kg M 013

Diethyl phthalate T207 M105 0.1 mg/kg U 013

Dimethyl phthalate T207 M105 0.1 mg/kg U 013

Hexachlorobenzene T207 M105 0.1 mg/kg M 013

Hexachlorobutadiene T207 M105 0.1 mg/kg M 013

Hexachlorocyclopentadiene T207 M105 0.1 mg/kg U 013

Hexachloroethane T207 M105 0.1 mg/kg U 013

Isophorone T207 M105 0.1 mg/kg U 013

Nitrobenzene T207 M105 0.1 mg/kg M 013

Pentachlorophenol T207 M105 0.1 mg/kg U 013

Phenol T207 M105 0.1 mg/kg M 013

TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg N 013

TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg N 013

TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg N 013

TPH (C10-C12 aliphatic) T206 M105 1 mg/kg M 013

TPH (C12-C16 aliphatic) T206 M105 2 mg/kg M 013

TPH (C16-C21 aliphatic) T206 M105 1 mg/kg M 013

TPH (C21-C35 aliphatic) T206 M105 4 mg/kg M 013

TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg N 013

This document has been printed from a digitally signed master copy

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Determinand Method TestSample LOD Units Symbol SAL References

TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg N 013

TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg N 013

TPH (C10-C12 aromatic) T206 M105 1 mg/kg N 013

TPH (C12-C16 aromatic) T206 M105 1 mg/kg M 013

TPH (C16-C21 aromatic) T206 M105 1 mg/kg M 013

TPH (C21-C35 aromatic) T206 M105 1 mg/kg M 013

1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg M 013

1,1,1-Trichloroethane T209 M105 50 µg/kg M 013

1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg U 013

1,1,2-Trichloroethane T209 M105 50 µg/kg M 013

1,1-Dichloroethane T209 M105 50 µg/kg M 013

1,1-Dichloroethylene T209 M105 50 µg/kg M 013

1,1-Dichloropropene T209 M105 50 µg/kg M 013

1,2,3-Trichloropropane T209 M105 50 µg/kg U 013

1,2,4-Trimethylbenzene T209 M105 50 µg/kg M 013

1,2-dibromoethane T209 M105 50 µg/kg M 013

1,2-Dichlorobenzene T209 M105 50 µg/kg M 013

1,2-Dichloroethane T209 M105 50 µg/kg M 013

1,2-Dichloropropane T209 M105 50 µg/kg M 013

1,3,5-Trimethylbenzene T209 M105 50 µg/kg M 013

1,3-Dichlorobenzene T209 M105 50 µg/kg M 013

1,3-Dichloropropane T209 M105 50 µg/kg M 013

1,4-Dichlorobenzene T209 M105 50 µg/kg M 013

2,2-Dichloropropane T209 M105 50 µg/kg U 013

2-Chlorotoluene T209 M105 50 µg/kg U 013

4-Chlorotoluene T209 M105 50 µg/kg U 013

Benzene T209 M105 10 µg/kg M 013

Bromobenzene T209 M105 50 µg/kg M 013

Bromochloromethane T209 M105 50 µg/kg M 013

Bromodichloromethane T209 M105 50 µg/kg M 013

Bromoform T209 M105 50 µg/kg M 013

Bromomethane T209 M105 50 µg/kg U 013

Carbon tetrachloride T209 M105 50 µg/kg M 013

Chlorobenzene T209 M105 50 µg/kg M 013

Chlorodibromomethane T209 M105 50 µg/kg M 013

Chloroethane T209 M105 50 µg/kg M 013

Chloroform T209 M105 50 µg/kg M 013

Chloromethane T209 M105 50 µg/kg U 013

Cis-1,2-Dichloroethylene T209 M105 50 µg/kg M 013

Cis-1,3-Dichloropropene T209 M105 50 µg/kg M 013

Dibromomethane T209 M105 50 µg/kg M 013

Dichlorodifluoromethane T209 M105 50 µg/kg M 013

Dichloromethane T209 M105 50 µg/kg U 013

EthylBenzene T209 M105 10 µg/kg M 013

Isopropyl benzene T209 M105 50 µg/kg M 013

M/P Xylene T209 M105 10 µg/kg M 013

n-Propylbenzene T209 M105 50 µg/kg M 013

O Xylene T209 M105 10 µg/kg M 013

p-Isopropyltoluene T209 M105 50 µg/kg M 013

S-Butylbenzene T209 M105 50 µg/kg M 013

Styrene T209 M105 50 µg/kg U 013

T-Butylbenzene T209 M105 50 µg/kg M 013

Tetrachloroethene T209 M105 50 µg/kg M 013

Toluene T209 M105 10 µg/kg M 013

Trans-1,2-Dichloroethene T209 M105 50 µg/kg M 013

Trans-1,3-Dichloropropene T209 M105 50 µg/kg M 013

Trichloroethene T209 M105 50 µg/kg M 013

Trichlorofluoromethane T209 M105 50 µg/kg M 013

Vinyl chloride T209 M105 50 µg/kg M 013

Moisture @ 105 C T162 AR 0.1 % N 013

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Scientific Analysis Laboratories Ltd

Certificate of Analysis

Hadfield HouseHadfield Street

CornbrookManchester

M16 9FETel : 0161 874 2400Fax : 0161 874 2468

Report Number: 478734-1

Date of Report: 26-May-2015

Customer: Soil Engineering Geoservices LimitedParkside LaneDewsbury RoadLeedsWest Yorkshire.LS11 5SX

Customer Contact: Mr Andrew De Joux

Customer Job Reference: TA7437Customer Site Reference: Mersey Gateway Bridge. Additional GI

(Phase 2)Date Job Received at SAL: 22-Apr-2015

Date Analysis Started: 20-May-2015Date Analysis Completed: 22-May-2015

The results reported relate to samples received in the laboratoryOpinions and interpretations expressed herein are outside the scope of UKAS accreditationThis report should not be reproduced except in full without the written approval of the laboratoryTests covered by this certificate were conducted in accordance with SAL SOPsAll results have been reviewed in accordance with Section 25 of the SAL Quality Manual

This document has been printed from a digitally signed master copy

Scientific Analysis Laboratories is a

limited company registered in England and

Wales (No 2514788) whose address is at

Hadfield House, Hadfield Street, Manchester M16 9FE

1549

Report checkedand authorised by :Natasha WildProject Manager

Issued by :Natasha WildProject Manager

Page 1 of 5

478734-1

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SAL Reference: 478734

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Moisture

SAL Reference 478734005

478734006

478734011

478734012

478734019

478734021

478734023

478734025

Customer Sample Reference BHXX4 ES005

(473147/005)

BHXX4 ES006

(473147/006)

BHXX4 ES011

(473147/011)

BHXX4 ES012

(473147/012)

BHXX5 ES006

(475292/006)

BHXX5 ES008

(475292/008)

BHXX5 ES010

(475292/010)

BHXX5 ES012

(475292/012)

Date Sampled 21-APR-2015

21-APR-2015

22-APR-2015

22-APR-2015

23-APR-2015

24-APR-2015

24-APR-2015

24-APR-2015

Bottom Depth 4.30 5.20 10.00 10.20 4.70 6.00 8.00 10.00

Top Depth 4.30 5.20 10.00 10.20 4.70 6.00 8.00 10.00

Type Clay Clay Clay Sandy Soil Clay Sandy Soil Sandy Soil Sandy Soil

Determinand Method TestSample LOD Units

Moisture @ 105 C T162 AR 0.1 % 31 23 27 8.5 36 23 21 17

SAL Reference: 478734

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Carbon disulphide

SAL Reference 478734005

478734006

478734011

478734012

478734019

478734021

478734023

478734025

Customer Sample Reference BHXX4 ES005

(473147/005)

BHXX4 ES006

(473147/006)

BHXX4 ES011

(473147/011)

BHXX4 ES012

(473147/012)

BHXX5 ES006

(475292/006)

BHXX5 ES008

(475292/008)

BHXX5 ES010

(475292/010)

BHXX5 ES012

(475292/012)

Date Sampled 21-APR-2015

21-APR-2015

22-APR-2015

22-APR-2015

23-APR-2015

24-APR-2015

24-APR-2015

24-APR-2015

Bottom Depth 4.30 5.20 10.00 10.20 4.70 6.00 8.00 10.00

Top Depth 4.30 5.20 10.00 10.20 4.70 6.00 8.00 10.00

Type Clay Clay Clay Sandy Soil Clay Sandy Soil Sandy Soil Sandy Soil

Determinand Method TestSample LOD Units

Carbon disulphide T54 AR 0.1 mg/kg 160 73 260 65 8.4 9.7 10 56

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SAL Reference: 478734

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Volatile Organic Compounds (USEPA 624) (MCERTS)

SAL Reference 478734005

478734006

478734011

478734012

478734019

478734021

478734023

478734025

Customer Sample Reference BHXX4 ES005

(473147/005)

BHXX4 ES006

(473147/006)

BHXX4 ES011

(473147/011)

BHXX4 ES012

(473147/012)

BHXX5 ES006

(475292/006)

BHXX5 ES008

(475292/008)

BHXX5 ES010

(475292/010)

BHXX5 ES012

(475292/012)

Date Sampled 21-APR-2015

21-APR-2015

22-APR-2015

22-APR-2015

23-APR-2015

24-APR-2015

24-APR-2015

24-APR-2015

Bottom Depth 4.30 5.20 10.00 10.20 4.70 6.00 8.00 10.00

Top Depth 4.30 5.20 10.00 10.20 4.70 6.00 8.00 10.00

Type Clay Clay Clay SandySoil

Clay SandySoil

SandySoil

SandySoil

Determinand Method TestSample LOD Units

Dichlorodifluoromethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Chloromethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Vinyl chloride T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Bromomethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Chloroethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Trichlorofluoromethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,1-Dichloroethylene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Dichloromethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Trans-1,2-Dichloroethene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,1-Dichloroethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Cis-1,2-Dichloroethylene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

2,2-Dichloropropane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Chloroform T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 78 220

Bromochloromethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,1,1-Trichloroethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,1-Dichloropropene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Carbon tetrachloride T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,2-Dichloroethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Benzene T209 M105 10 µg/kg (13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10 (13) <10

1,2-Dichloropropane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Trichloroethene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Bromodichloromethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Dibromomethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Cis-1,3-Dichloropropene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Toluene T209 M105 10 µg/kg <10 <10 <10 <10 <10 <10 <10 <10

Trans-1,3-Dichloropropene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,1,2-Trichloroethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,3-Dichloropropane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Tetrachloroethene T209 M105 50 µg/kg <50 77 73 <50 <50 <50 <50 <50

Chlorodibromomethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,2-dibromoethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Chlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

EthylBenzene T209 M105 10 µg/kg <10 <10 <10 <10 <10 <10 <10 <10

M/P Xylene T209 M105 10 µg/kg <10 <10 <10 <10 <10 <10 <10 <10

O Xylene T209 M105 10 µg/kg <10 <10 <10 <10 <10 <10 <10 <10

Styrene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Bromoform T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Isopropyl benzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,2,3-Trichloropropane T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

n-Propylbenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

Bromobenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,3,5-Trimethylbenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

T-Butylbenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,2,4-Trimethylbenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

S-Butylbenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

p-Isopropyltoluene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

2-Chlorotoluene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

4-Chlorotoluene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,3-Dichlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,4-Dichlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

1,2-Dichlorobenzene T209 M105 50 µg/kg <50 <50 <50 <50 <50 <50 <50 <50

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478734-1

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Index to symbols used in 478734-1

Notes

Method Index

Accreditation Summary

Value Description

AR As Received

M105 Analysis conducted on an "as received"aliquot. Results are reported on a dryweight basis where moisture content wasdetermined by assisted drying of sampleat 105C

13 Results have been blank corrected.

M Analysis is MCERTS accredited

U Analysis is UKAS accredited

N Analysis is not UKAS accredited

These samples have been analysed exceeding recommended holding times. It is possible therefore that the results provided may be compromised.

Value Description

T54 GC/MS (Headspace)

T209 GC/MS(Head Space)(MCERTS)

T162 Grav (1 Dec) (105 C)

Determinand Method TestSample LOD Units Symbol SAL References

Carbon disulphide T54 AR 0.1 mg/kg N 005-006,011-012,019,021,023,025

Dichlorodifluoromethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Chloromethane T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025

Vinyl chloride T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Bromomethane T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025

Chloroethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Trichlorofluoromethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

1,1-Dichloroethylene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Dichloromethane T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025

Trans-1,2-Dichloroethene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

1,1-Dichloroethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Cis-1,2-Dichloroethylene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

2,2-Dichloropropane T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025

Chloroform T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Bromochloromethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

1,1,1-Trichloroethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

1,1-Dichloropropene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Carbon tetrachloride T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

1,2-Dichloroethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Benzene T209 M105 10 µg/kg M 005-006,011-012,019,021,023,025

1,2-Dichloropropane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Trichloroethene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Bromodichloromethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Dibromomethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Cis-1,3-Dichloropropene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Toluene T209 M105 10 µg/kg M 005-006,011-012,019,021,023,025

Trans-1,3-Dichloropropene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

1,1,2-Trichloroethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

1,3-Dichloropropane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Tetrachloroethene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Chlorodibromomethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

1,2-dibromoethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Chlorobenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

EthylBenzene T209 M105 10 µg/kg M 005-006,011-012,019,021,023,025

M/P Xylene T209 M105 10 µg/kg M 005-006,011-012,019,021,023,025

O Xylene T209 M105 10 µg/kg M 005-006,011-012,019,021,023,025

Styrene T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025

Bromoform T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Isopropyl benzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025

This document has been printed from a digitally signed master copy

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478734-1

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Determinand Method TestSample LOD Units Symbol SAL References

1,2,3-Trichloropropane T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025

n-Propylbenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Bromobenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

1,3,5-Trimethylbenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

T-Butylbenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

1,2,4-Trimethylbenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

S-Butylbenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

p-Isopropyltoluene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

2-Chlorotoluene T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025

4-Chlorotoluene T209 M105 50 µg/kg U 005-006,011-012,019,021,023,025

1,3-Dichlorobenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

1,4-Dichlorobenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

1,2-Dichlorobenzene T209 M105 50 µg/kg M 005-006,011-012,019,021,023,025

Moisture @ 105 C T162 AR 0.1 % N 005-006,011-012,019,021,023,025

This document has been printed from a digitally signed master copy

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478734-1

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Scientific Analysis Laboratories Ltd

Certificate of Analysis

Hadfield HouseHadfield Street

CornbrookManchester

M16 9FETel : 0161 874 2400Fax : 0161 874 2468

Report Number: 475292-1

Date of Report: 18-May-2015

Customer: Soil Engineering Geoservices LimitedParkside LaneDewsbury RoadLeedsWest Yorkshire.LS11 5SX

Customer Contact: Mr Andrew De Joux

Customer Job Reference: TA7437Customer Site Reference: Mersey Gateway Bridge. Additional GI

(Phase 2)Date Job Received at SAL: 24-Apr-2015

Date Analysis Started: 07-May-2015Date Analysis Completed: 14-May-2015

The results reported relate to samples received in the laboratoryOpinions and interpretations expressed herein are outside the scope of UKAS accreditationThis report should not be reproduced except in full without the written approval of the laboratoryTests covered by this certificate were conducted in accordance with SAL SOPsAll results have been reviewed in accordance with Section 25 of the SAL Quality Manual

This document has been printed from a digitally signed master copy

Scientific Analysis Laboratories is a

limited company registered in England and

Wales (No 2514788) whose address is at

Hadfield House, Hadfield Street, Manchester M16 9FE

1549

Report checkedand authorised by :Natasha WildProject Manager

Issued by :Natasha WildProject Manager

Page 1 of 9

475292-1

Page 106: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

SAL Reference: 475292

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Moisture

SAL Reference 475292 013

Customer Sample Reference BHXX5 ES 013

Bottom Depth 10.40

Date Sampled 27-APR-2015

Top Depth 10.40

Type Clay

Determinand Method TestSample LOD Units

Moisture @ 105 C T162 AR 0.1 % 16

SAL Reference: 475292

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Asbestos

SAL Reference 475292 013

Customer Sample Reference BHXX5 ES 013

Bottom Depth 10.40

Date Sampled 27-APR-2015

Top Depth 10.40

Type Clay

Determinand Method TestSample LOD Units

Asbestos ID T27 AR N.D.

SAL Reference: 475292

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Carbon disulphide

SAL Reference 475292 013

Customer Sample Reference BHXX5 ES 013

Bottom Depth 10.40

Date Sampled 27-APR-2015

Top Depth 10.40

Type Clay

Determinand Method TestSample LOD Units

Carbon disulphide T54 M105 0.1 mg/kg <0.1

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SAL Reference: 475292

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

CLEA Metals

SAL Reference 475292 013

Customer Sample Reference BHXX5 ES 013

Bottom Depth 10.40

Date Sampled 27-APR-2015

Top Depth 10.40

Type Clay

Determinand Method TestSample LOD Units

Arsenic T6 M40 2 mg/kg 10

Beryllium T6 M40 2 mg/kg <2

Cadmium T6 M40 1 mg/kg <1

Chromium T6 M40 1 mg/kg 23

Copper T6 M40 1 mg/kg 14

Lead T6 M40 1 mg/kg 8

Mercury T6 M40 1 mg/kg <1

Nickel T6 M40 1 mg/kg 27

Selenium T6 M40 3 mg/kg <3

Vanadium T6 M40 1 mg/kg 22

Zinc T6 M40 1 mg/kg 42

Barium T6 M40 1 mg/kg 100

Boron (water-soluble) T6 AR 1 mg/kg <1

SAL Reference: 475292

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Suite E

SAL Reference 475292 013

Customer Sample Reference BHXX5 ES 013

Bottom Depth 10.40

Date Sampled 27-APR-2015

Top Depth 10.40

Type Clay

Determinand Method TestSample LOD Units

Chromium VI T6 AR 1 mg/kg <1

Cyanide(Total) T546 AR 1 mg/kg <1

Cyanide(free) T546 AR 1 mg/kg <1

pH T7 AR 8.1

Phenols(Mono) T546 AR 1 mg/kg <1

(Water Soluble) SO4 expressed as SO4 T242 AR 0.01 g/l 0.91

Sulphide T546 AR 1 mg/kg <1

Sulphur (total) T6 M40 0.01 % 0.09

TPH (C10-C35) T8 M105 1 mg/kg <1

SAL Reference: 475292

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Suite K

SAL Reference 475292 013

Customer Sample Reference BHXX5 ES 013

Bottom Depth 10.40

Date Sampled 27-APR-2015

Top Depth 10.40

Type Clay

Determinand Method TestSample LOD Units

Mass Fraction of organic carbon T286 M40 0.0031

Methyl tert-Butyl Ether T209 M105 10 µg/kg <10

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SAL Reference: 475292

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

PAH EPA 16, Coronene

SAL Reference 475292 013

Customer Sample Reference BHXX5 ES 013

Bottom Depth 10.40

Date Sampled 27-APR-2015

Top Depth 10.40

Type Clay

Determinand Method TestSample LOD Units

Naphthalene T207 M105 0.1 mg/kg <0.1

Acenaphthylene T207 M105 0.1 mg/kg <0.1

Acenaphthene T207 M105 0.1 mg/kg <0.1

Fluorene T207 M105 0.1 mg/kg <0.1

Phenanthrene T207 M105 0.1 mg/kg <0.1

Anthracene T207 M105 0.1 mg/kg <0.1

Fluoranthene T207 M105 0.1 mg/kg <0.1

Pyrene T207 M105 0.1 mg/kg <0.1

Benzo(a)Anthracene T207 M105 0.1 mg/kg <0.1

Chrysene T207 M105 0.1 mg/kg <0.1

Benzo(b)fluoranthene T207 M105 0.1 mg/kg <0.1

Benzo(k)fluoranthene T207 M105 0.1 mg/kg <0.1

Benzo(a)Pyrene T207 M105 0.1 mg/kg <0.1

Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg <0.1

Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg <0.1

Benzo(ghi)Perylene T207 M105 0.1 mg/kg <0.1

Coronene T207 M105 0.1 mg/kg <0.1

PAH (Sum) T85 M105 1.6 mg/kg <1.6

SAL Reference: 475292

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

TPH (CWG)

SAL Reference 475292 013

Customer Sample Reference BHXX5 ES 013

Bottom Depth 10.40

Date Sampled 27-APR-2015

Top Depth 10.40

Type Clay

Determinand Method TestSample LOD Units

TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg <0.100

TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg <0.10

TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg <0.10

TPH (C10-C12 aliphatic) T206 M105 1 mg/kg <1

TPH (C12-C16 aliphatic) T206 M105 2 mg/kg <2

TPH (C16-C21 aliphatic) T206 M105 1 mg/kg <1

TPH (C21-C35 aliphatic) T206 M105 4 mg/kg <4

TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg <0.10

TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg <0.10

TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg <0.10

TPH (C10-C12 aromatic) T206 M105 1 mg/kg <1

TPH (C12-C16 aromatic) T206 M105 1 mg/kg <1

TPH (C16-C21 aromatic) T206 M105 1 mg/kg <1

TPH (C21-C35 aromatic) T206 M105 1 mg/kg <1

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475292-1

Page 109: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

SAL Reference: 475292

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Semi-Volatile Organic Compounds (Reduced)

SAL Reference 475292 013

Customer Sample Reference BHXX5 ES 013

Bottom Depth 10.40

Date Sampled 27-APR-2015

Top Depth 10.40

Type Clay

Determinand Method TestSample LOD Units

1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg <0.1

1,2-Dichlorobenzene T207 M105 0.1 mg/kg <0.1

1,3-Dichlorobenzene T207 M105 0.1 mg/kg <0.1

1,4-Dichlorobenzene T207 M105 0.1 mg/kg <0.1

2,4,5-Trichlorophenol T207 M105 0.1 mg/kg <0.1

2,4,6-Trichlorophenol T207 M105 0.1 mg/kg <0.1

2,4-Dichlorophenol T207 M105 0.1 mg/kg <0.1

2,4-Dimethylphenol T207 M105 0.1 mg/kg <0.1

2,4-Dinitrophenol T207 M105 0.1 mg/kg (36) <0.5

2,4-Dinitrotoluene T207 M105 0.1 mg/kg <0.1

2,6-Dinitrotoluene T207 M105 0.1 mg/kg <0.1

2-Chloronaphthalene T207 M105 0.1 mg/kg <0.1

2-Chlorophenol T207 M105 0.1 mg/kg <0.1

2-methyl phenol T207 M105 0.1 mg/kg <0.1

2-Methylnaphthalene T207 M105 0.1 mg/kg <0.1

2-Nitroaniline T207 M105 0.1 mg/kg <0.1

2-Nitrophenol T207 M105 0.1 mg/kg <0.1

3-Nitroaniline T207 M105 0.1 mg/kg <0.1

3/4-Methylphenol T207 M105 0.1 mg/kg <0.1

4-Bromophenyl phenylether T207 M105 0.1 mg/kg <0.1

4-Chloro-3-methylphenol T207 M105 0.1 mg/kg <0.1

4-Chloroaniline T207 M105 0.1 mg/kg (36) <0.5

4-Chlorophenyl phenylether T207 M105 0.1 mg/kg <0.1

4-Nitroaniline T207 M105 0.1 mg/kg (36) <0.5

4-Nitrophenol T207 M105 0.1 mg/kg (36) <0.5

Azobenzene T207 M105 0.1 mg/kg <0.1

Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg <0.1

Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg <0.1

Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg <0.1

Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg <0.1

Butyl benzylphthalate T207 M105 0.1 mg/kg <0.1

Carbazole T207 M105 0.1 mg/kg <0.1

Di-n-butylphthalate T207 M105 0.1 mg/kg <0.1

Di-n-octylphthalate T207 M105 0.1 mg/kg <0.1

Dibenzofuran T207 M105 0.1 mg/kg <0.1

Diethyl phthalate T207 M105 0.1 mg/kg <0.1

Dimethyl phthalate T207 M105 0.1 mg/kg <0.1

Hexachlorobenzene T207 M105 0.1 mg/kg <0.1

Hexachlorobutadiene T207 M105 0.1 mg/kg <0.1

Hexachlorocyclopentadiene T207 M105 0.1 mg/kg (36) <0.5

Hexachloroethane T207 M105 0.1 mg/kg <0.1

Isophorone T207 M105 0.1 mg/kg <0.1

Nitrobenzene T207 M105 0.1 mg/kg <0.1

Pentachlorophenol T207 M105 0.1 mg/kg (36) <0.5

Phenol T207 M105 0.1 mg/kg <0.1

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475292-1

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SAL Reference: 475292

Project Site: Mersey Gateway Bridge. Additional GI (Phase 2)

Customer Reference: TA7437

Soil Analysed as Soil

Volatile Organic Compounds (USEPA 624) (MCERTS)

SAL Reference 475292 013

Customer Sample Reference BHXX5 ES 013

Bottom Depth 10.40

Date Sampled 27-APR-2015

Top Depth 10.40

Type Clay

Determinand Method TestSample LOD Units

1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg <50

1,1,1-Trichloroethane T209 M105 50 µg/kg <50

1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg <50

1,1,2-Trichloroethane T209 M105 50 µg/kg <50

1,1-Dichloroethane T209 M105 50 µg/kg <50

1,1-Dichloroethylene T209 M105 50 µg/kg <50

1,1-Dichloropropene T209 M105 50 µg/kg <50

1,2,3-Trichloropropane T209 M105 50 µg/kg <50

1,2,4-Trimethylbenzene T209 M105 50 µg/kg <50

1,2-dibromoethane T209 M105 50 µg/kg <50

1,2-Dichlorobenzene T209 M105 50 µg/kg <50

1,2-Dichloroethane T209 M105 50 µg/kg <50

1,2-Dichloropropane T209 M105 50 µg/kg <50

1,3,5-Trimethylbenzene T209 M105 50 µg/kg <50

1,3-Dichlorobenzene T209 M105 50 µg/kg <50

1,3-Dichloropropane T209 M105 50 µg/kg <50

1,4-Dichlorobenzene T209 M105 50 µg/kg <50

2,2-Dichloropropane T209 M105 50 µg/kg <50

2-Chlorotoluene T209 M105 50 µg/kg <50

4-Chlorotoluene T209 M105 50 µg/kg <50

Benzene T209 M105 10 µg/kg (13) <10

Bromobenzene T209 M105 50 µg/kg <50

Bromochloromethane T209 M105 50 µg/kg <50

Bromodichloromethane T209 M105 50 µg/kg <50

Bromoform T209 M105 50 µg/kg <50

Bromomethane T209 M105 50 µg/kg <50

Carbon tetrachloride T209 M105 50 µg/kg <50

Chlorobenzene T209 M105 50 µg/kg <50

Chlorodibromomethane T209 M105 50 µg/kg <50

Chloroethane T209 M105 50 µg/kg <50

Chloroform T209 M105 50 µg/kg <50

Chloromethane T209 M105 50 µg/kg <50

Cis-1,2-Dichloroethylene T209 M105 50 µg/kg <50

Cis-1,3-Dichloropropene T209 M105 50 µg/kg <50

Dibromomethane T209 M105 50 µg/kg <50

Dichlorodifluoromethane T209 M105 50 µg/kg <50

Dichloromethane T209 M105 50 µg/kg <50

EthylBenzene T209 M105 10 µg/kg <10

Isopropyl benzene T209 M105 50 µg/kg <50

M/P Xylene T209 M105 10 µg/kg <10

n-Propylbenzene T209 M105 50 µg/kg <50

O Xylene T209 M105 10 µg/kg <10

p-Isopropyltoluene T209 M105 50 µg/kg <50

S-Butylbenzene T209 M105 50 µg/kg <50

Styrene T209 M105 50 µg/kg <50

T-Butylbenzene T209 M105 50 µg/kg <50

Tetrachloroethene T209 M105 50 µg/kg <50

Toluene T209 M105 10 µg/kg <10

Trans-1,2-Dichloroethene T209 M105 50 µg/kg <50

Trans-1,3-Dichloropropene T209 M105 50 µg/kg <50

Trichloroethene T209 M105 50 µg/kg <50

Trichlorofluoromethane T209 M105 50 µg/kg <50

Vinyl chloride T209 M105 50 µg/kg <50

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475292-1

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Index to symbols used in 475292-1

Notes

Method Index

Accreditation Summary

Value Description

M105 Analysis conducted on an "as received" aliquot.Results are reported on a dry weight basis wheremoisture content was determined by assisteddrying of sample at 105C

M40 Analysis conducted on sample assisted dried at nomore than 40C. Results are reported on a dryweight basis.

AR As Received

N.D. Not Detected

36 LOD Raised due to low Matrix spike recovery

13 Results have been blank corrected.

S Analysis was subcontracted

M Analysis is MCERTS accredited

U Analysis is UKAS accredited

N Analysis is not UKAS accredited

These samples have been analysed exceeding recommended holding times. It is possible therefore that the results provided may be compromised.

Asbestos was subcontracted to REC Asbestos.

Value Description

T8 GC/FID

T546 Colorimetry (CF)

T6 ICP/OES

T27 PLM

T206 GC/FID (MCERTS)

T85 Calc

T7 Probe

T162 Grav (1 Dec) (105 C)

T242 2:1 Extraction/ICP/OES (TRL 447 T1)

T286 Calc TOC/100

T54 GC/MS (Headspace)

T209 GC/MS(Head Space)(MCERTS)

T207 GC/MS (MCERTS)

Determinand Method TestSample LOD Units Symbol SAL References

Carbon disulphide T54 M105 0.1 mg/kg N 013

Chromium VI T6 AR 1 mg/kg N 013

Cyanide(Total) T546 AR 1 mg/kg M 013

Cyanide(free) T546 AR 1 mg/kg M 013

pH T7 AR M 013

Phenols(Mono) T546 AR 1 mg/kg M 013

(Water Soluble) SO4 expressed as SO4 T242 AR 0.01 g/l N 013

Sulphide T546 AR 1 mg/kg N 013

Sulphur (total) T6 M40 0.01 % N 013

TPH (C10-C35) T8 M105 1 mg/kg M 013

Arsenic T6 M40 2 mg/kg M 013

Beryllium T6 M40 2 mg/kg M 013

Cadmium T6 M40 1 mg/kg M 013

Chromium T6 M40 1 mg/kg M 013

Copper T6 M40 1 mg/kg M 013

Lead T6 M40 1 mg/kg M 013

Mercury T6 M40 1 mg/kg M 013

Nickel T6 M40 1 mg/kg M 013

Selenium T6 M40 3 mg/kg M 013

Vanadium T6 M40 1 mg/kg M 013

Zinc T6 M40 1 mg/kg M 013

Barium T6 M40 1 mg/kg U 013

Boron (water-soluble) T6 AR 1 mg/kg N 013

Naphthalene T207 M105 0.1 mg/kg M 013

Acenaphthylene T207 M105 0.1 mg/kg U 013

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475292-1

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Determinand Method TestSample LOD Units Symbol SAL References

Acenaphthene T207 M105 0.1 mg/kg M 013

Fluorene T207 M105 0.1 mg/kg M 013

Phenanthrene T207 M105 0.1 mg/kg M 013

Anthracene T207 M105 0.1 mg/kg U 013

Fluoranthene T207 M105 0.1 mg/kg M 013

Pyrene T207 M105 0.1 mg/kg M 013

Benzo(a)Anthracene T207 M105 0.1 mg/kg M 013

Chrysene T207 M105 0.1 mg/kg M 013

Benzo(b)fluoranthene T207 M105 0.1 mg/kg M 013

Benzo(k)fluoranthene T207 M105 0.1 mg/kg M 013

Benzo(a)Pyrene T207 M105 0.1 mg/kg M 013

Indeno(123-cd)Pyrene T207 M105 0.1 mg/kg M 013

Dibenzo(ah)Anthracene T207 M105 0.1 mg/kg M 013

Benzo(ghi)Perylene T207 M105 0.1 mg/kg M 013

Coronene T207 M105 0.1 mg/kg N 013

PAH (Sum) T85 M105 1.6 mg/kg N 013

Mass Fraction of organic carbon T286 M40 N 013

Methyl tert-Butyl Ether T209 M105 10 µg/kg M 013

1,2,4-Trichlorobenzene T207 M105 0.1 mg/kg M 013

1,2-Dichlorobenzene T207 M105 0.1 mg/kg M 013

1,3-Dichlorobenzene T207 M105 0.1 mg/kg M 013

1,4-Dichlorobenzene T207 M105 0.1 mg/kg M 013

2,4,5-Trichlorophenol T207 M105 0.1 mg/kg U 013

2,4,6-Trichlorophenol T207 M105 0.1 mg/kg U 013

2,4-Dichlorophenol T207 M105 0.1 mg/kg U 013

2,4-Dimethylphenol T207 M105 0.1 mg/kg U 013

2,4-Dinitrophenol T207 M105 0.1 mg/kg U 013

2,4-Dinitrotoluene T207 M105 0.1 mg/kg M 013

2,6-Dinitrotoluene T207 M105 0.1 mg/kg U 013

2-Chloronaphthalene T207 M105 0.1 mg/kg M 013

2-Chlorophenol T207 M105 0.1 mg/kg M 013

2-methyl phenol T207 M105 0.1 mg/kg M 013

2-Methylnaphthalene T207 M105 0.1 mg/kg M 013

2-Nitroaniline T207 M105 0.1 mg/kg M 013

2-Nitrophenol T207 M105 0.1 mg/kg U 013

3-Nitroaniline T207 M105 0.1 mg/kg U 013

3/4-Methylphenol T207 M105 0.1 mg/kg M 013

4-Bromophenyl phenylether T207 M105 0.1 mg/kg M 013

4-Chloro-3-methylphenol T207 M105 0.1 mg/kg M 013

4-Chloroaniline T207 M105 0.1 mg/kg U 013

4-Chlorophenyl phenylether T207 M105 0.1 mg/kg M 013

4-Nitroaniline T207 M105 0.1 mg/kg U 013

4-Nitrophenol T207 M105 0.1 mg/kg U 013

Azobenzene T207 M105 0.1 mg/kg M 013

Bis (2-chloroethoxy) methane T207 M105 0.1 mg/kg M 013

Bis (2-chloroethyl) ether T207 M105 0.1 mg/kg M 013

Bis (2-chloroisopropyl) ether T207 M105 0.1 mg/kg M 013

Bis (2-ethylhexyl)phthalate T207 M105 0.1 mg/kg M 013

Butyl benzylphthalate T207 M105 0.1 mg/kg U 013

Carbazole T207 M105 0.1 mg/kg U 013

Di-n-butylphthalate T207 M105 0.1 mg/kg M 013

Di-n-octylphthalate T207 M105 0.1 mg/kg M 013

Dibenzofuran T207 M105 0.1 mg/kg M 013

Diethyl phthalate T207 M105 0.1 mg/kg U 013

Dimethyl phthalate T207 M105 0.1 mg/kg U 013

Hexachlorobenzene T207 M105 0.1 mg/kg M 013

Hexachlorobutadiene T207 M105 0.1 mg/kg M 013

Hexachlorocyclopentadiene T207 M105 0.1 mg/kg U 013

Hexachloroethane T207 M105 0.1 mg/kg U 013

Isophorone T207 M105 0.1 mg/kg U 013

Nitrobenzene T207 M105 0.1 mg/kg M 013

Pentachlorophenol T207 M105 0.1 mg/kg U 013

Phenol T207 M105 0.1 mg/kg M 013

TPH (C5-C6 aliphatic) T209 M105 0.100 mg/kg N 013

TPH (C6-C8 aliphatic) T209 M105 0.10 mg/kg N 013

TPH (C8-C10 aliphatic) T209 M105 0.10 mg/kg N 013

TPH (C10-C12 aliphatic) T206 M105 1 mg/kg M 013

TPH (C12-C16 aliphatic) T206 M105 2 mg/kg M 013

TPH (C16-C21 aliphatic) T206 M105 1 mg/kg M 013

TPH (C21-C35 aliphatic) T206 M105 4 mg/kg M 013

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475292-1

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Determinand Method TestSample LOD Units Symbol SAL References

TPH (C6-C7 aromatic) T209 M105 0.10 mg/kg N 013

TPH (C7-C8 aromatic) T209 M105 0.10 mg/kg N 013

TPH (C8-C10 aromatic) T209 M105 0.10 mg/kg N 013

TPH (C10-C12 aromatic) T206 M105 1 mg/kg N 013

TPH (C12-C16 aromatic) T206 M105 1 mg/kg M 013

TPH (C16-C21 aromatic) T206 M105 1 mg/kg M 013

TPH (C21-C35 aromatic) T206 M105 1 mg/kg M 013

1,1,1,2-Tetrachloroethane T209 M105 50 µg/kg M 013

1,1,1-Trichloroethane T209 M105 50 µg/kg M 013

1,1,2,2-Tetrachloroethane T209 M105 50 µg/kg U 013

1,1,2-Trichloroethane T209 M105 50 µg/kg M 013

1,1-Dichloroethane T209 M105 50 µg/kg M 013

1,1-Dichloroethylene T209 M105 50 µg/kg M 013

1,1-Dichloropropene T209 M105 50 µg/kg M 013

1,2,3-Trichloropropane T209 M105 50 µg/kg U 013

1,2,4-Trimethylbenzene T209 M105 50 µg/kg M 013

1,2-dibromoethane T209 M105 50 µg/kg M 013

1,2-Dichlorobenzene T209 M105 50 µg/kg M 013

1,2-Dichloroethane T209 M105 50 µg/kg M 013

1,2-Dichloropropane T209 M105 50 µg/kg M 013

1,3,5-Trimethylbenzene T209 M105 50 µg/kg M 013

1,3-Dichlorobenzene T209 M105 50 µg/kg M 013

1,3-Dichloropropane T209 M105 50 µg/kg M 013

1,4-Dichlorobenzene T209 M105 50 µg/kg M 013

2,2-Dichloropropane T209 M105 50 µg/kg U 013

2-Chlorotoluene T209 M105 50 µg/kg U 013

4-Chlorotoluene T209 M105 50 µg/kg U 013

Benzene T209 M105 10 µg/kg M 013

Bromobenzene T209 M105 50 µg/kg M 013

Bromochloromethane T209 M105 50 µg/kg M 013

Bromodichloromethane T209 M105 50 µg/kg M 013

Bromoform T209 M105 50 µg/kg M 013

Bromomethane T209 M105 50 µg/kg U 013

Carbon tetrachloride T209 M105 50 µg/kg M 013

Chlorobenzene T209 M105 50 µg/kg M 013

Chlorodibromomethane T209 M105 50 µg/kg M 013

Chloroethane T209 M105 50 µg/kg M 013

Chloroform T209 M105 50 µg/kg M 013

Chloromethane T209 M105 50 µg/kg U 013

Cis-1,2-Dichloroethylene T209 M105 50 µg/kg M 013

Cis-1,3-Dichloropropene T209 M105 50 µg/kg M 013

Dibromomethane T209 M105 50 µg/kg M 013

Dichlorodifluoromethane T209 M105 50 µg/kg M 013

Dichloromethane T209 M105 50 µg/kg U 013

EthylBenzene T209 M105 10 µg/kg M 013

Isopropyl benzene T209 M105 50 µg/kg M 013

M/P Xylene T209 M105 10 µg/kg M 013

n-Propylbenzene T209 M105 50 µg/kg M 013

O Xylene T209 M105 10 µg/kg M 013

p-Isopropyltoluene T209 M105 50 µg/kg M 013

S-Butylbenzene T209 M105 50 µg/kg M 013

Styrene T209 M105 50 µg/kg U 013

T-Butylbenzene T209 M105 50 µg/kg M 013

Tetrachloroethene T209 M105 50 µg/kg M 013

Toluene T209 M105 10 µg/kg M 013

Trans-1,2-Dichloroethene T209 M105 50 µg/kg M 013

Trans-1,3-Dichloropropene T209 M105 50 µg/kg M 013

Trichloroethene T209 M105 50 µg/kg M 013

Trichlorofluoromethane T209 M105 50 µg/kg M 013

Vinyl chloride T209 M105 50 µg/kg M 013

Moisture @ 105 C T162 AR 0.1 % N 013

Asbestos ID T27 AR SU 013

This document has been printed from a digitally signed master copy

Produced by Scientific Analysis Laboratories Ltd, Hadfield House, Hadfield Street, Cornbrook, Manchester, M16 9FE Page 9 of 9

475292-1

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MERSEY GATEWAY BRIDGE

MER-DJV-REP-ENV-03-333030 D 17 MARCH 2016

APPENDIX D – LABORATORY REPORTS

(GROUNDWATER)

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Units 7 & 8 Sandpits Business Park Mottram Road, Hyde, Cheshire, SK14 3AR

FINAL ANALYTICAL TEST REPORT

Envirolab Job Number: 15/02829 Issue Number: 1 Date: 20 May, 2015 Client: RSK Environment Helsby Spring Lodge 172 Chester Road Helsby Cheshire UK WA6 0AR Project Manager: Rachel Hagan Project Name: Mersey Gateway Project Ref: 321315 Order No: N/A Date Samples Received: 06/05/15 Date Instructions Received: 07/05/15 Date Analysis Completed: 20/05/15 Prepared by: Approved by:

Melanie Marshall Carolyn Field Laboratory Coordinator Sales Executive

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Envirolab Job Number: 15/02829 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02829/1 15/02829/2 15/02829/3

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Client Sample No

Client Sample ID BHXX3 BH427A BH427B

Depth to Top 8.00 22.00 47.25

Depth To Bottom

Date Sampled 05-May-15 05-May-15 05-May-15

Sample Type Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A

pH (w)A# 7.24 7.52 7.27 pH A-T-031w

Electrical conductivity @ 20degC (w)A# 9570 17880 8350 µs/cm A-T-037w

COD (settled)A# 140 160 57 mg/l A-T-034w

BOD (settled, 5 day)A 5 12 7 mg/l A-T-048

Hardness TotalA# 1690 3710 2090 mg/l Ca

CO3

A-T-049w

Chloride (w)A# 727 5540 2040 mg/l A-T-026w

Nitrite (w)A# <0.10 <0.10 <0.10 mg/l A-T-026w

Nitrate (w) A# <0.50 <0.50 <0.50 mg/l A-T-026w

Sulphate (w)A# 3632 2008 997 mg/l A-T-026w

Cyanide (total) (w)A# 0.006 <0.005 0.112 mg/l A-T-042wTCN

Phenols - Total by HPLC (w)A <0.01 0.12 <0.01 mg/l A-T-050w

Sulphide (w)A <0.1 0.1 <0.1 mg/l A-T-S2-w

DOC (w)A# 15.5 10.1 3.3 mg/l A-T-032w

Aluminium (dissolved)A 19 <10 <10 µg/l A-T-049w

Arsenic (dissolved)A# 9870 <10 <10 µg/l A-T-025w

Boron (dissolved)A# 546 690 405 µg/l A-T-025w

Barium (dissolved)A# 68 68 339 µg/l A-T-025w

Beryllium (dissolved)A# <10 <10 <10 µg/l A-T-025w

Cadmium (dissolved)A# <10 <10 <10 µg/l A-T-025w

Calcium (dissolved)A# 573 739 678 mg/l A-T-049w

Copper (dissolved)A# <10 <10 <10 µg/l A-T-025w

Chromium (dissolved)A# <10 14 <10 µg/l A-T-025w

Chromium (hexavalent) (w)A# <0.05 <0.05 <0.05 mg/l A-T-040w

Chromium (trivalent) (w) <0.05 <0.05 <0.05 mg/l Calc

Iron (dissolved)A# 17700 4360 205 µg/l A-T-025w

Lead (dissolved)A# <10 <10 <10 µg/l A-T-025w

Manganese (dissolved)A# 3940 1880 241 µg/l A-T-025w

Magnesium (dissolved)A# 63 453 97 mg/l A-T-049w

Mercury (dissolved)A# <1.0 <1.0 <2 µg/l A-T-025w

Nickel (dissolved)A# 10 <10 <10 µg/l A-T-025w

Potassium (dissolved)A# 81 77 44 mg/l A-T-049w

Selenium (dissolved)A# <10 <10 <10 µg/l A-T-025w

Sodium (dissolved)A# 943 2610 83 mg/l A-T-049w

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Envirolab Job Number: 15/02829 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02829/1 15/02829/2 15/02829/3

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Client Sample No

Client Sample ID BHXX3 BH427A BH427B

Depth to Top 8.00 22.00 47.25

Depth To Bottom

Date Sampled 05-May-15 05-May-15 05-May-15

Sample Type Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A

Strontium (dissolved)A 1060 6250 2860 µg/l A-T-025w

Vanadium (dissolved)A# 14 <10 <10 µg/l A-T-025w

Zinc (dissolved)A# <10 <10 66 µg/l A-T-025w

TPH CWG

Ali >C5-C6 (w)A# <1 3 <1 µg/l A-T-022w

Ali >C6-C8 (w)A# <1 <1 <1 µg/l A-T-022w

Ali >C8-C10 (w)A# <1 <1 <1 µg/l A-T-022w

Ali >C10-C12 (w)A# <5 <5 <5 µg/l A-T-023w

Ali >C12-C16 (w)A# <5 <5 <5 µg/l A-T-023w

Ali >C16-C21 (w)A# <5 <5 <5 µg/l A-T-023w

Ali >C21-C35 (w)A# <5 <5 <5 µg/l A-T-023w

Total Aliphatics (w)A <5 <5 <5 µg/l A-T-022+23w

Aro >C5-C7 (w)A# <1 <1 <1 µg/l A-T-022w

Aro >C7-C8 (w)A# <1 <1 <1 µg/l A-T-022w

Aro >C8-C9 (w)A# <1 <1 <1 µg/l A-T-022w

Aro >C9-C10 (w)A# <1 <1 <1 µg/l A-T-022w

Aro >C10-C12 (w)A# <5 <5 <5 µg/l A-T-023w

Aro >C12-C16 (w)A# <5 <5 <5 µg/l A-T-023w

Aro >C16-C21 (w)A# <5 <5 <5 µg/l A-T-023w

Aro >C21-C35 (w)A# <5 <5 <5 µg/l A-T-023w

Total Aromatics (w)A <5 <5 <5 µg/l A-T-022+23w

TPH (Ali & Aro) (w)A <5 <5 <5 µg/l A-T-022+23w

BTEX - Benzene (w)A# <1 <1 <1 µg/l A-T-022w

BTEX - Toluene (w)A# <1 <1 <1 µg/l A-T-022w

BTEX - Ethyl Benzene (w)A# <1 <1 <1 µg/l A-T-022w

BTEX - m & p Xylene (w)A# <1 <1 <1 µg/l A-T-022w

BTEX - o Xylene (w)A# <1 <1 <1 µg/l A-T-022w

MTBE (w)A# <1 <1 <1 µg/l A-T-022w

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Envirolab Job Number: 15/02829 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02829/1 15/02829/2 15/02829/3

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Client Sample No

Client Sample ID BHXX3 BH427A BH427B

Depth to Top 8.00 22.00 47.25

Depth To Bottom

Date Sampled 05-May-15 05-May-15 05-May-15

Sample Type Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A

PAH 16MS (w)

Acenaphthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Acenaphthylene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Anthracene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(a)anthracene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(a)pyrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(b)fluoranthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(ghi)perylene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(k)fluoranthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Chrysene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Dibenzo(ah)anthracene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Fluoranthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Fluorene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Indeno(123-cd)pyrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Naphthalene (w)A# 0.13 <0.01 <0.01 µg/l A-T-019w

Phenanthrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Pyrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

PAH (total 16) (w)A# 0.13 <0.01 <0.01 µg/l A-T-019w

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Envirolab Job Number: 15/02829 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02829/1 15/02829/2 15/02829/3

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Client Sample No

Client Sample ID BHXX3 BH427A BH427B

Depth to Top 8.00 22.00 47.25

Depth To Bottom

Date Sampled 05-May-15 05-May-15 05-May-15

Sample Type Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A

SVOC (w)

2,4,5-TrichlorophenolA <1 <1 <1 µg/l A-T-052w

2,4,6-TrichlorophenolA <1 <1 <1 µg/l A-T-052w

2,4-DichlorophenolA <1 <1 <1 µg/l A-T-052w

2,4-DimethylphenolA <1 <1 <1 µg/l A-T-052w

2,4-DinitrotolueneA <1 <1 <1 µg/l A-T-052w

2,6-DinitrotolueneA <1 <1 <1 µg/l A-T-052w

2-ChloronaphthaleneA <1 <1 <1 µg/l A-T-052w

2-ChlorophenolA <1 <1 <1 µg/l A-T-052w

2-MethylnaphthaleneA <1 <1 <1 µg/l A-T-052w

2-MethylphenolA <1 <1 <1 µg/l A-T-052w

2-NitrophenolA <1 <1 <1 µg/l A-T-052w

4-Bromophenyl phenyl etherA <1 <1 <1 µg/l A-T-052w

4-Chloro-3-methylphenolA <1 <1 <1 µg/l A-T-052w

Bis(2-chloroisopropyl)etherA <1 <1 <1 µg/l A-T-052w

2,4-DinitrophenolA <1 <1 <1 µg/l A-T-052w

4,6-Dinitro-2-methylphenolA <1 <1 <1 µg/l A-T-052w

4-MethylphenolA <1 <1 <1 µg/l A-T-052w

4-NitrophenolA <1 <1 <1 µg/l A-T-052w

Acenaphthene A <1 <1 <1 µg/l A-T-052w

AcenaphthyleneA <1 <1 <1 µg/l A-T-052w

Anthracene A <1 <1 <1 µg/l A-T-052w

Bis(2-chloroethyl)etherA <1 <1 <1 µg/l A-T-052w

Bis(2-chloroethoxy)methaneA <1 <1 <1 µg/l A-T-052w

Bis(2-ethylhexyl)phthalateA <2 <2 <2 µg/l A-T-052w

Benzo(a)anthraceneA <1 <1 <1 µg/l A-T-052w

Butylbenzyl phthalate A <1 <1 <1 µg/l A-T-052w

Benzo(b)fluorantheneA <1 <1 <1 µg/l A-T-052w

Benzo(k)fluorantheneA <1 <1 <1 µg/l A-T-052w

Benzo(a)pyrene A <1 <1 <1 µg/l A-T-052w

Benzo(ghi)peryleneA <1 <1 <1 µg/l A-T-052w

CarbazoleA <1 <1 <1 µg/l A-T-052w

ChryseneA <1 <1 <1 µg/l A-T-052w

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Envirolab Job Number: 15/02829 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02829/1 15/02829/2 15/02829/3

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Client Sample No

Client Sample ID BHXX3 BH427A BH427B

Depth to Top 8.00 22.00 47.25

Depth To Bottom

Date Sampled 05-May-15 05-May-15 05-May-15

Sample Type Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A

DibenzofuranA <1 <1 <1 µg/l A-T-052w

n-DibutylphthalateA <1 <1 <1 µg/l A-T-052w

n-DioctylphthalateA <5 <5 <5 µg/l A-T-052w

n-Nitroso-n-dipropylamineA <1 <1 <1 µg/l A-T-052w

Diethyl phthalateA <1 <1 <1 µg/l A-T-052w

Dimethyl phthalateA <1 <1 <1 µg/l A-T-052w

Dibenzo(ah)anthraceneA <1 <1 <1 µg/l A-T-052w

Fluorene A <1 <1 <1 µg/l A-T-052w

FluorantheneA <1 <1 <1 µg/l A-T-052w

HexachlorobenzeneA <1 <1 <1 µg/l A-T-052w

PentachlorophenolA <1 <1 <1 µg/l A-T-052w

Phenol A <1 7 <1 µg/l A-T-052w

HexachloroethaneA 21 <1 <1 µg/l A-T-052w

NitrobenzeneA <1 <1 <1 µg/l A-T-052w

Naphthalene A <1 <1 <1 µg/l A-T-052w

IsophoroneA <1 <1 <1 µg/l A-T-052w

HexachlorocyclopentadieneA <1 <1 <1 µg/l A-T-052w

Phenanthrene A <1 <1 <1 µg/l A-T-052w

Pyrene A <1 <1 <1 µg/l A-T-052w

Indeno(1,2,3-cd)pyreneA <1 <1 <1 µg/l A-T-052w

PeryleneA <1 <1 <1 µg/l A-T-052w

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Envirolab Job Number: 15/02829 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02829/1 15/02829/2 15/02829/3

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Client Sample No

Client Sample ID BHXX3 BH427A BH427B

Depth to Top 8.00 22.00 47.25

Depth To Bottom

Date Sampled 05-May-15 05-May-15 05-May-15

Sample Type Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A

VOC (w)

DichlorodifluoromethaneA# <1 <1 <1 µg/l A-T-006w

ChloromethaneA# <1 <1 <1 µg/l A-T-006w

Vinyl ChlorideA# <1 <1 <1 µg/l A-T-006w

BromomethaneA# <1 <1 <1 µg/l A-T-006w

ChloroethaneA# <1 <1 <1 µg/l A-T-006w

TrichlorofluoromethaneA# <1 <1 <1 µg/l A-T-006w

trans 1,2-DichloroetheneA# <1 <1 <1 µg/l A-T-006w

DichloromethaneA <5 <5 39 µg/l A-T-006w

Carbon DisulphideA# 134 <1 <1 µg/l A-T-006w

1,1-DichloroetheneA# <1 1 <1 µg/l A-T-006w

1,1-DichloroethaneA# <1 <1 <1 µg/l A-T-006w

cis 1,2-DichloroetheneA# 3 1 <1 µg/l A-T-006w

BromochloromethaneA# <5 <5 <5 µg/l A-T-006w

ChloroformA# 555 <25 <25 µg/l A-T-006w

2,2-DichloropropaneA# <1 <1 <1 µg/l A-T-006w

1,2-DichloroethaneA# <2 <2 4 µg/l A-T-006w

1,1,1-TrichloroethaneA# <1 <1 <1 µg/l A-T-006w

1,1-DichloropropeneA# 16 <1 <1 µg/l A-T-006w

Benzene A# <1 <1 <1 µg/l A-T-006w

Carbon TetrachlorideA# 2410 <1 8 µg/l A-T-006w

DibromomethaneA# <1 <1 <1 µg/l A-T-006w

1,2-DichloropropaneA# <1 <1 <1 µg/l A-T-006w

BromodichloromethaneA# <10 <10 <10 µg/l A-T-006w

TrichloroetheneA# 3 <1 1 µg/l A-T-006w

cis 1,3-DichloropropeneA# <1 <1 <1 µg/l A-T-006w

trans 1,3-DichloropropeneA# <1 <1 <1 µg/l A-T-006w

1,1,2-TrichloroethaneA# <1 <1 15 µg/l A-T-006w

Toluene A# <1 1 <1 µg/l A-T-006w

1,3-DichloropropaneA# <1 <1 <1 µg/l A-T-006w

DibromochloromethaneA# <3 <3 <3 µg/l A-T-006w

1,2-DibromoethaneA# <1 <1 <1 µg/l A-T-006w

TetrachloroetheneA# 42 <1 <1 µg/l A-T-006w

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Envirolab Job Number: 15/02829 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02829/1 15/02829/2 15/02829/3

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Client Sample No

Client Sample ID BHXX3 BH427A BH427B

Depth to Top 8.00 22.00 47.25

Depth To Bottom

Date Sampled 05-May-15 05-May-15 05-May-15

Sample Type Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A

1,1,1,2-TetrachloroethaneA <1 <1 <1 µg/l A-T-006w

ChlorobenzeneA# 5 <1 <1 µg/l A-T-006w

EthylbenzeneA# <1 <1 <1 µg/l A-T-006w

m & p XyleneA# <1 <1 <1 µg/l A-T-006w

BromoformA# <1 <1 <1 µg/l A-T-006w

StyreneA# <1 <1 <1 µg/l A-T-006w

1,1,2,2-TetrachloroethaneA <1 <1 <1 µg/l A-T-006w

o-XyleneA# <1 <1 <1 µg/l A-T-006w

1,2,3-TrichloropropaneA# <1 <1 <1 µg/l A-T-006w

IsopropylbenzeneA# <1 <1 <1 µg/l A-T-006w

BromobenzeneA# <1 <1 <1 µg/l A-T-006w

2-ChlorotolueneA# <1 <1 <1 µg/l A-T-006w

n-propylbenzeneA# <1 <1 <1 µg/l A-T-006w

4-ChlorotolueneA# <1 <1 <1 µg/l A-T-006w

1,2,4-TrimethylbenzeneA# <1 <1 <1 µg/l A-T-006w

4-IsopropyltolueneA# <1 <1 <1 µg/l A-T-006w

1,3,5-TrimethylbenzeneA# <1 <1 <1 µg/l A-T-006w

1,2-DichlorobenzeneA# <1 <1 <1 µg/l A-T-006w

1,4-DichlorobenzeneA# <1 <1 <1 µg/l A-T-006w

sec-ButylbenzeneA# <1 <1 <1 µg/l A-T-006w

tert-ButylbenzeneA# <2 <2 <2 µg/l A-T-006w

1,3-DichlorobenzeneA# <1 <1 <1 µg/l A-T-006w

n-butylbenzeneA# <1 <1 <1 µg/l A-T-006w

1,2-Dibromo-3-chloropropaneA# <2 <2 <2 µg/l A-T-006w

1,2,4-TrichlorobenzeneA# <3 <3 <3 µg/l A-T-006w

1,2,3-TrichlorobenzeneA# <3 <3 <3 µg/l A-T-006w

HexachlorobutadieneA# <1 <1 <1 µg/l A-T-006w

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REPORT NOTES

Notes - Soil chemical analysis All results are reported as dry weight (<40°C). For samples with Matrix Codes 1 - 6 natural stones >10mm are removed or excluded from the sample prior to analysis and reported results corrected to a whole sample basis. For samples with Matrix Code 7 the whole sample is dried and crushed prior to analysis. Notes - General

This report shall not be reproduced, except in full, without written approval from Envirolab. Subscript "A" indicates analysis performed on the sample as received. "D" indicates analysis performed on the dried sample, crushed to pass a 2mm sieve, unless asbestos is found to be present in which case all analysis is performed on the sample as received. All analysis is performed on the dried and crushed sample for samples with Matrix Code 7 and this supercedes any "A" subscripts. All analysis is performed on the sample as received for soil samples from outside the European Union and this supercedes any "D" subscripts. Superscript "M" indicates method accredited to MCERTS. If results are in italic font they are associated with an AQC failure. These are not accredited and are unreliable. A deviating samples report is appended and will indicate if samples or tests have been found to be deviating. Any test results affected may not be an accurate record of the concentration at the time of sampling and, as a result, may be invalid. TPH analysis of water by method A-T-007 Free and visible oils are excluded from the sample used for analysis so that the reported result represents the dissolved phase only. Asbestos in soil Asbestos in soil analysis is performed on a dried aliquot of the submitted sample and cannot guarantee to identify asbestos if present as discrete fibres/fragments. Stones etc. are not removed from the sample prior to analysis. Quantification of asbestos is a 3 stage process including visual identification, hand picking and weighing and fibre counting by sedimentation/phase contrast optical microscopy if required. If asbestos is identified a being present but is not in a form that is suitable for analysis by hand picking and weighing (normally if the asbestos is present as free fibres) quantification by sedimentation is performed. Where ACMs are found a percentage asbestos is assigned to each with reference to 'HSG264, Asbestos: The survey guide' and the calculated asbestos content is expressed as a percentage of the dried soil sample aliquot used. Predominant Matrix Codes: 1 = SAND, 2 = LOAM, 3 = CLAY, 4 = LOAM/SAND, 5 = SAND/CLAY, 6 = CLAY/LOAM, 7 = OTHER. Samples with Matrix Code 7 are not predominantly a SAND/LOAM/CLAY mix and are not covered by our BSEN 17025 or MCERTS accreditations. Secondary Matrix Codes: A = contains stones, B = contains construction rubble, C = contains visible hydrocarbons, D = contains glass/metal, E = contains roots/twigs. IS indicates Insufficient sample for analysis. NDP indicates No Determination Possible. NAD indicates No Asbestos Detected. N/A indicates Not Applicable. Superscript # indicates method accredited to ISO 17025. Analytical results reflect the quality of the sample at the time of analysis only. Opinions and interpretations expressed are outside the scope of our accreditation. Please contact us if you need any further information.

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Units 7 & 8 Sandpits Business Park Mottram Road, Hyde, Cheshire, SK14 3AR

FINAL ANALYTICAL TEST REPORT

Envirolab Job Number: 15/02804 Issue Number: 1 Date: 12 May, 2015 Client: RSK Environment Helsby Spring Lodge 172 Chester Road Helsby Cheshire UK WA6 0AR Project Manager: Rachel Hagan Project Name: Mersey Gateway Project Ref: 321315 Order No: N/A Date Samples Received: 05/05/15 Date Instructions Received: 06/05/15 Date Analysis Completed: 11/05/15 Prepared by: Approved by:

Melanie Marshall Carolyn Field Laboratory Coordinator Sales Executive

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Envirolab Job Number: 15/02804 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02804/1 15/02804/2

Un

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Client Sample No

Client Sample ID BHXX4 BHXX5

Depth to Top 9.00 9.00

Depth To Bottom

Date Sampled 05-May-15 05-May-15

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

pH (w)A# 7.22 7.68 pH A-T-031w

Electrical conductivity @ 20degC (w)A# 8640 1913 µs/cm A-T-037w

COD (settled)A# 130 27 mg/l A-T-034w

BOD (settled, 5 day)A <1 <1 mg/l A-T-048

Hardness TotalA# 2100 686 mg/l Ca

CO3

A-T-049w

Chloride (w)A# 698 170.03 mg/l A-T-026w

Nitrite (w)A# 0.13 0.73 mg/l A-T-026w

Nitrate (w) A# <0.50 0.80 mg/l A-T-026w

Sulphate (w)A# 3546 801 mg/l A-T-026w

Cyanide (total) (w)A# <0.005 <0.005 mg/l A-T-042wTCN

Phenols - Total by HPLC (w)A 0.03 <0.01 mg/l A-T-050w

Sulphide (w)A 0.1 <0.1 mg/l A-T-S2-w

DOC (w)A# 19.1 7.6 mg/l A-T-032w

Aluminium (dissolved)A <10 <10 µg/l A-T-049w

Arsenic (dissolved)A# 1370 73 µg/l A-T-025w

Boron (dissolved)A# 1230 138 µg/l A-T-025w

Barium (dissolved)A# 106 66 µg/l A-T-025w

Beryllium (dissolved)A# <1 <1 µg/l A-T-025w

Cadmium (dissolved)A# <1 <1 µg/l A-T-025w

Calcium (dissolved)A# 653 222 mg/l A-T-049w

Copper (dissolved)A# <1 <1 µg/l A-T-025w

Chromium (dissolved)A# 7 1 µg/l A-T-025w

Chromium (hexavalent) (w)A# <0.05 <0.05 mg/l A-T-040w

Chromium (trivalent) (w) <0.05 <0.05 mg/l Calc

Iron (dissolved)A# 7007 299 µg/l A-T-025w

Lead (dissolved)A# <1 <1 µg/l A-T-025w

Manganese (dissolved)A# 8926 503 µg/l A-T-025w

Magnesium (dissolved)A# 114 32 mg/l A-T-049w

Mercury (dissolved)A# <0.1 <0.1 µg/l A-T-025w

Nickel (dissolved)A# 8 6 µg/l A-T-025w

Potassium (dissolved)A# 84 13 mg/l A-T-049w

Selenium (dissolved)A# 8 12 µg/l A-T-025w

Sodium (dissolved)A# 660 158 mg/l A-T-049w

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Envirolab Job Number: 15/02804 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02804/1 15/02804/2

Un

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Client Sample No

Client Sample ID BHXX4 BHXX5

Depth to Top 9.00 9.00

Depth To Bottom

Date Sampled 05-May-15 05-May-15

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

Strontium (dissolved)A 1680 2160 µg/l A-T-025w

Vanadium (dissolved)A# 3 <1 µg/l A-T-025w

Zinc (dissolved)A# 15 3 µg/l A-T-025w

TPH CWG

Ali >C5-C6 (w)A# <1 <1 µg/l A-T-022w

Ali >C6-C8 (w)A# <1 <1 µg/l A-T-022w

Ali >C8-C10 (w)A# <1 <1 µg/l A-T-022w

Ali >C10-C12 (w)A# <5 <5 µg/l A-T-023w

Ali >C12-C16 (w)A# <5 <5 µg/l A-T-023w

Ali >C16-C21 (w)A# 15 <5 µg/l A-T-023w

Ali >C21-C35 (w)A# 14 <5 µg/l A-T-023w

Total Aliphatics (w)A 28 <5 µg/l A-T-022+23w

Aro >C5-C7 (w)A# <1 <1 µg/l A-T-022w

Aro >C7-C8 (w)A# 1 <1 µg/l A-T-022w

Aro >C8-C9 (w)A# <1 <1 µg/l A-T-022w

Aro >C9-C10 (w)A# <1 <1 µg/l A-T-022w

Aro >C10-C12 (w)A# <5 <5 µg/l A-T-023w

Aro >C12-C16 (w)A# <5 <5 µg/l A-T-023w

Aro >C16-C21 (w)A# <5 <5 µg/l A-T-023w

Aro >C21-C35 (w)A# <5 <5 µg/l A-T-023w

Total Aromatics (w)A <5 <5 µg/l A-T-022+23w

TPH (Ali & Aro) (w)A 29 <5 µg/l A-T-022+23w

BTEX - Benzene (w)A# <1 <1 µg/l A-T-022w

BTEX - Toluene (w)A# 1 <1 µg/l A-T-022w

BTEX - Ethyl Benzene (w)A# <1 <1 µg/l A-T-022w

BTEX - m & p Xylene (w)A# <1 <1 µg/l A-T-022w

BTEX - o Xylene (w)A# <1 <1 µg/l A-T-022w

MTBE (w)A# <1 <1 µg/l A-T-022w

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Envirolab Job Number: 15/02804 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02804/1 15/02804/2

Un

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Client Sample No

Client Sample ID BHXX4 BHXX5

Depth to Top 9.00 9.00

Depth To Bottom

Date Sampled 05-May-15 05-May-15

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

PAH 16MS (w)

Acenaphthene (w)A# 0.08 0.05 µg/l A-T-019w

Acenaphthylene (w)A# <0.01 <0.01 µg/l A-T-019w

Anthracene (w)A# <0.01 <0.01 µg/l A-T-019w

Benzo(a)anthracene (w)A# <0.01 <0.01 µg/l A-T-019w

Benzo(a)pyrene (w)A# <0.01 <0.01 µg/l A-T-019w

Benzo(b)fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w

Benzo(ghi)perylene (w)A# <0.01 <0.01 µg/l A-T-019w

Benzo(k)fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w

Chrysene (w)A# <0.01 <0.01 µg/l A-T-019w

Dibenzo(ah)anthracene (w)A# <0.01 <0.01 µg/l A-T-019w

Fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w

Fluorene (w)A# <0.01 <0.01 µg/l A-T-019w

Indeno(123-cd)pyrene (w)A# <0.01 <0.01 µg/l A-T-019w

Naphthalene (w)A# 0.06 <0.01 µg/l A-T-019w

Phenanthrene (w)A# 0.01 <0.01 µg/l A-T-019w

Pyrene (w)A# <0.01 <0.01 µg/l A-T-019w

PAH (total 16) (w)A# 0.15 0.05 µg/l A-T-019w

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Envirolab Job Number: 15/02804 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02804/1 15/02804/2

Un

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Client Sample No

Client Sample ID BHXX4 BHXX5

Depth to Top 9.00 9.00

Depth To Bottom

Date Sampled 05-May-15 05-May-15

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

SVOC (w)

2,4,5-TrichlorophenolA <1 <1 µg/l A-T-052w

2,4,6-TrichlorophenolA <1 <1 µg/l A-T-052w

2,4-DichlorophenolA <1 <1 µg/l A-T-052w

2,4-DimethylphenolA <1 <1 µg/l A-T-052w

2,4-DinitrotolueneA <1 <1 µg/l A-T-052w

2,6-DinitrotolueneA <1 <1 µg/l A-T-052w

2-ChloronaphthaleneA <1 <1 µg/l A-T-052w

2-ChlorophenolA <1 <1 µg/l A-T-052w

2-MethylnaphthaleneA <1 <1 µg/l A-T-052w

2-MethylphenolA <1 <1 µg/l A-T-052w

2-NitrophenolA <1 <1 µg/l A-T-052w

4-Bromophenyl phenyl etherA <1 <1 µg/l A-T-052w

4-Chloro-3-methylphenolA <1 <1 µg/l A-T-052w

Bis(2-chloroisopropyl)etherA <1 <1 µg/l A-T-052w

2,4-DinitrophenolA <1 <1 µg/l A-T-052w

4,6-Dinitro-2-methylphenolA <1 <1 µg/l A-T-052w

4-MethylphenolA <1 <1 µg/l A-T-052w

4-NitrophenolA <1 <1 µg/l A-T-052w

Acenaphthene A <1 <1 µg/l A-T-052w

AcenaphthyleneA <1 <1 µg/l A-T-052w

Anthracene A <1 <1 µg/l A-T-052w

Bis(2-chloroethyl)etherA <1 <1 µg/l A-T-052w

Bis(2-chloroethoxy)methaneA <1 <1 µg/l A-T-052w

Bis(2-ethylhexyl)phthalateA <2 <2 µg/l A-T-052w

Benzo(a)anthraceneA <1 <1 µg/l A-T-052w

Butylbenzyl phthalate A <1 <1 µg/l A-T-052w

Benzo(b)fluorantheneA <1 <1 µg/l A-T-052w

Benzo(k)fluorantheneA <1 <1 µg/l A-T-052w

Benzo(a)pyrene A <1 <1 µg/l A-T-052w

Benzo(ghi)peryleneA <1 <1 µg/l A-T-052w

CarbazoleA <1 <1 µg/l A-T-052w

ChryseneA <1 <1 µg/l A-T-052w

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Envirolab Job Number: 15/02804 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02804/1 15/02804/2

Un

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Client Sample No

Client Sample ID BHXX4 BHXX5

Depth to Top 9.00 9.00

Depth To Bottom

Date Sampled 05-May-15 05-May-15

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

DibenzofuranA <1 <1 µg/l A-T-052w

n-DibutylphthalateA <1 <1 µg/l A-T-052w

n-DioctylphthalateA <5 <5 µg/l A-T-052w

n-Nitroso-n-dipropylamineA <1 <1 µg/l A-T-052w

Diethyl phthalateA <1 <1 µg/l A-T-052w

Dimethyl phthalateA <1 <1 µg/l A-T-052w

Dibenzo(ah)anthraceneA <1 <1 µg/l A-T-052w

Fluorene A <1 <1 µg/l A-T-052w

FluorantheneA <1 <1 µg/l A-T-052w

HexachlorobenzeneA <1 <1 µg/l A-T-052w

PentachlorophenolA <1 <1 µg/l A-T-052w

Phenol A 1 1 µg/l A-T-052w

HexachloroethaneA <1 <1 µg/l A-T-052w

NitrobenzeneA <1 <1 µg/l A-T-052w

Naphthalene A <1 <1 µg/l A-T-052w

IsophoroneA <1 <1 µg/l A-T-052w

HexachlorocyclopentadieneA <1 <1 µg/l A-T-052w

Phenanthrene A <1 <1 µg/l A-T-052w

Pyrene A <1 <1 µg/l A-T-052w

Indeno(1,2,3-cd)pyreneA <1 <1 µg/l A-T-052w

PeryleneA <1 <1 µg/l A-T-052w

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Envirolab Job Number: 15/02804 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02804/1 15/02804/2

Un

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Client Sample No

Client Sample ID BHXX4 BHXX5

Depth to Top 9.00 9.00

Depth To Bottom

Date Sampled 05-May-15 05-May-15

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

VOC (w)

DichlorodifluoromethaneA# <1 <1 µg/l A-T-006w

ChloromethaneA# 27 <1 µg/l A-T-006w

Vinyl ChlorideA# <1 <1 µg/l A-T-006w

BromomethaneA# <1 <1 µg/l A-T-006w

ChloroethaneA# <1 <1 µg/l A-T-006w

TrichlorofluoromethaneA# <1 <1 µg/l A-T-006w

trans 1,2-DichloroetheneA# <1 <1 µg/l A-T-006w

DichloromethaneA 54 <5 µg/l A-T-006w

Carbon DisulphideA# 1486 <1 µg/l A-T-006w

1,1-DichloroetheneA# 2 <1 µg/l A-T-006w

1,1-DichloroethaneA# <1 <1 µg/l A-T-006w

cis 1,2-DichloroetheneA# 2 <1 µg/l A-T-006w

BromochloromethaneA# <5 <5 µg/l A-T-006w

ChloroformA# >3303 587 µg/l A-T-006w

2,2-DichloropropaneA# <1 <1 µg/l A-T-006w

1,2-DichloroethaneA# <2 <2 µg/l A-T-006w

1,1,1-TrichloroethaneA# 2 <1 µg/l A-T-006w

1,1-DichloropropeneA# <1 <1 µg/l A-T-006w

Benzene A# <1 <1 µg/l A-T-006w

Carbon TetrachlorideA# >6542 107 µg/l A-T-006w

DibromomethaneA# <1 <1 µg/l A-T-006w

1,2-DichloropropaneA# <1 <1 µg/l A-T-006w

BromodichloromethaneA# <10 <10 µg/l A-T-006w

TrichloroetheneA# 6 <1 µg/l A-T-006w

cis 1,3-DichloropropeneA# <1 <1 µg/l A-T-006w

trans 1,3-DichloropropeneA# <1 <1 µg/l A-T-006w

1,1,2-TrichloroethaneA# <1 <1 µg/l A-T-006w

Toluene A# 1 <1 µg/l A-T-006w

1,3-DichloropropaneA# <1 <1 µg/l A-T-006w

DibromochloromethaneA# <3 <3 µg/l A-T-006w

1,2-DibromoethaneA# <1 <1 µg/l A-T-006w

TetrachloroetheneA# 53 2 µg/l A-T-006w

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Envirolab Job Number: 15/02804 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02804/1 15/02804/2

Un

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Client Sample No

Client Sample ID BHXX4 BHXX5

Depth to Top 9.00 9.00

Depth To Bottom

Date Sampled 05-May-15 05-May-15

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

1,1,1,2-TetrachloroethaneA <1 <1 µg/l A-T-006w

ChlorobenzeneA# <1 <1 µg/l A-T-006w

EthylbenzeneA# <1 <1 µg/l A-T-006w

m & p XyleneA# <1 <1 µg/l A-T-006w

BromoformA# <1 <1 µg/l A-T-006w

StyreneA# <1 <1 µg/l A-T-006w

1,1,2,2-TetrachloroethaneA 5 <1 µg/l A-T-006w

o-XyleneA# <1 <1 µg/l A-T-006w

1,2,3-TrichloropropaneA# <1 <1 µg/l A-T-006w

IsopropylbenzeneA# <1 <1 µg/l A-T-006w

BromobenzeneA# <1 <1 µg/l A-T-006w

2-ChlorotolueneA# <1 <1 µg/l A-T-006w

n-propylbenzeneA# <1 <1 µg/l A-T-006w

4-ChlorotolueneA# <1 <1 µg/l A-T-006w

1,2,4-TrimethylbenzeneA# <1 <1 µg/l A-T-006w

4-IsopropyltolueneA# <1 <1 µg/l A-T-006w

1,3,5-TrimethylbenzeneA# <1 <1 µg/l A-T-006w

1,2-DichlorobenzeneA# <1 <1 µg/l A-T-006w

1,4-DichlorobenzeneA# <1 <1 µg/l A-T-006w

sec-ButylbenzeneA# <1 <1 µg/l A-T-006w

tert-ButylbenzeneA# <2 <2 µg/l A-T-006w

1,3-DichlorobenzeneA# <1 <1 µg/l A-T-006w

n-butylbenzeneA# <1 <1 µg/l A-T-006w

1,2-Dibromo-3-chloropropaneA# <2 <2 µg/l A-T-006w

1,2,4-TrichlorobenzeneA# <3 <3 µg/l A-T-006w

1,2,3-TrichlorobenzeneA# <3 <3 µg/l A-T-006w

HexachlorobutadieneA# <1 <1 µg/l A-T-006w

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Page 9 of 9

REPORT NOTES

Notes - Soil chemical analysis All results are reported as dry weight (<40°C). For samples with Matrix Codes 1 - 6 natural stones >10mm are removed or excluded from the sample prior to analysis and reported results corrected to a whole sample basis. For samples with Matrix Code 7 the whole sample is dried and crushed prior to analysis. Notes - General

This report shall not be reproduced, except in full, without written approval from Envirolab. Subscript "A" indicates analysis performed on the sample as received. "D" indicates analysis performed on the dried sample, crushed to pass a 2mm sieve, unless asbestos is found to be present in which case all analysis is performed on the sample as received. All analysis is performed on the dried and crushed sample for samples with Matrix Code 7 and this supercedes any "A" subscripts. All analysis is performed on the sample as received for soil samples from outside the European Union and this supercedes any "D" subscripts. Superscript "M" indicates method accredited to MCERTS. If results are in italic font they are associated with an AQC failure. These are not accredited and are unreliable. A deviating samples report is appended and will indicate if samples or tests have been found to be deviating. Any test results affected may not be an accurate record of the concentration at the time of sampling and, as a result, may be invalid. TPH analysis of water by method A-T-007 Free and visible oils are excluded from the sample used for analysis so that the reported result represents the dissolved phase only. Asbestos in soil Asbestos in soil analysis is performed on a dried aliquot of the submitted sample and cannot guarantee to identify asbestos if present as discrete fibres/fragments. Stones etc. are not removed from the sample prior to analysis. Quantification of asbestos is a 3 stage process including visual identification, hand picking and weighing and fibre counting by sedimentation/phase contrast optical microscopy if required. If asbestos is identified a being present but is not in a form that is suitable for analysis by hand picking and weighing (normally if the asbestos is present as free fibres) quantification by sedimentation is performed. Where ACMs are found a percentage asbestos is assigned to each with reference to 'HSG264, Asbestos: The survey guide' and the calculated asbestos content is expressed as a percentage of the dried soil sample aliquot used. Predominant Matrix Codes: 1 = SAND, 2 = LOAM, 3 = CLAY, 4 = LOAM/SAND, 5 = SAND/CLAY, 6 = CLAY/LOAM, 7 = OTHER. Samples with Matrix Code 7 are not predominantly a SAND/LOAM/CLAY mix and are not covered by our BSEN 17025 or MCERTS accreditations. Secondary Matrix Codes: A = contains stones, B = contains construction rubble, C = contains visible hydrocarbons, D = contains glass/metal, E = contains roots/twigs. IS indicates Insufficient sample for analysis. NDP indicates No Determination Possible. NAD indicates No Asbestos Detected. N/A indicates Not Applicable. Superscript # indicates method accredited to ISO 17025. Analytical results reflect the quality of the sample at the time of analysis only. Opinions and interpretations expressed are outside the scope of our accreditation. Please contact us if you need any further information.

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Page 1 of 10

Units 7 & 8 Sandpits Business Park Mottram Road, Hyde, Cheshire, SK14 3AR

FINAL ANALYTICAL TEST REPORT

Envirolab Job Number: 15/02720 Issue Number: 1 Date: 14 May, 2015 Client: RSK Environment Helsby Spring Lodge 172 Chester Road Helsby Cheshire UK WA6 0AR Project Manager: Rachel Hagan Project Name: Mersey Gateway Project Ref: 321315 Order No: N/A Date Samples Received: 30/04/15 Date Instructions Received: 01/05/15 Date Analysis Completed: 13/05/15 Prepared by: Approved by:

Gill Scott Iain Haslock Laboratory Manager Analytical Consultant

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Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4

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Client Sample No

Client Sample ID BHXX5 BHXX4 BH410 BHXX3

Depth to Top 9.00 9.00 13.20 8.00

Depth To Bottom

Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15

Sample Type Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A

pH (w)A# 7.38 7.11 8.49 - pH A-T-031w

Electrical conductivity @ 20degC (w)A# 6300 9050 20200 - µs/cm A-T-037w

COD (settled)A# 87 140 230 - mg/l A-T-034w

BOD (settled, 5 day)A <1 <1 31 - mg/l A-T-048

Hardness TotalA# 1703 2247 2080 - mg/l Ca

CO3

A-T-049w

Chloride (w)A# 521.51 662.62 6445.05 - mg/l A-T-026w

Nitrite (w)A# <0.10 <0.10 <0.10 - mg/l A-T-026w

Nitrate (w) A# <0.50 0.68 <0.50 - mg/l A-T-026w

Sulphate (w)A# 2168 3475 1611 - mg/l A-T-026w

Cyanide (total) (w)A# <0.005 <0.005 1.209 - mg/l A-T-042wTCN

Phenols - Total by HPLC (w)A 0.03 0.11 0.03 - mg/l A-T-050w

Sulphide (w)A <0.1 0.2 10.6 - mg/l A-T-S2-w

DOC (w)A# 10.7 13.0 10.1 - mg/l A-T-032w

Aluminium (dissolved)A <10 <10 24 - µg/l A-T-049w

Arsenic (dissolved)A# 14 2400 1730 - µg/l A-T-025w

Boron (dissolved)A# 959 1180 1730 - µg/l A-T-025w

Barium (dissolved)A# 141 96 63 - µg/l A-T-025w

Beryllium (dissolved)A# <1 <1 <1 - µg/l A-T-025w

Cadmium (dissolved)A# <1 <1 <1 - µg/l A-T-025w

Calcium (dissolved)A# 545 666 278 - mg/l A-T-049w

Copper (dissolved)A# <1 <1 1 - µg/l A-T-025w

Chromium (dissolved)A# <1 2 6 - µg/l A-T-025w

Chromium (hexavalent) (w)A# <0.05 <0.05 <0.05 - mg/l A-T-040w

Chromium (trivalent) (w) <0.05 <0.05 <0.05 - mg/l Calc

Iron (dissolved)A# 8114 12370 623 - µg/l A-T-025w

Lead (dissolved)A# <1 <1 <1 - µg/l A-T-025w

Manganese (dissolved)A# 6537 7412 834 - µg/l A-T-025w

Magnesium (dissolved)A# 83 142 336 - mg/l A-T-049w

Mercury (dissolved)A# 0.4 0.3 <0.1 - µg/l A-T-025w

Nickel (dissolved)A# 14 8 4 - µg/l A-T-025w

Potassium (dissolved)A# 61 105 123 - mg/l A-T-049w

Selenium (dissolved)A# 8 6 4 - µg/l A-T-025w

Sodium (dissolved)A# 473 681 3900 - mg/l A-T-049w

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Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4

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Client Sample No

Client Sample ID BHXX5 BHXX4 BH410 BHXX3

Depth to Top 9.00 9.00 13.20 8.00

Depth To Bottom

Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15

Sample Type Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A

Strontium (dissolved)A 1630 1860 2270 - µg/l A-T-025w

Vanadium (dissolved)A# <1 1 25 - µg/l A-T-025w

Zinc (dissolved)A# 14 21 4 - µg/l A-T-025w

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Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4

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Client Sample No

Client Sample ID BHXX5 BHXX4 BH410 BHXX3

Depth to Top 9.00 9.00 13.20 8.00

Depth To Bottom

Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15

Sample Type Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A

TPH CWG

Ali >C5-C6 (w)A# <1 <1 <1 - µg/l A-T-022w

Ali >C6-C8 (w)A# <1 <1 <1 - µg/l A-T-022w

Ali >C8-C10 (w)A# 1 1 <1 - µg/l A-T-022w

Ali >C10-C12 (w)A# <5 8 <5 - µg/l A-T-023w

Ali >C12-C16 (w)A# <5 <5 <5 - µg/l A-T-023w

Ali >C16-C21 (w)A# <5 <5 <5 - µg/l A-T-023w

Ali >C21-C35 (w)A# <5 <5 <5 - µg/l A-T-023w

Total Aliphatics (w)A <5 9 <5 - µg/l A-T-022+23w

Aro >C5-C7 (w)A# <1 <1 <1 - µg/l A-T-022w

Aro >C7-C8 (w)A# <1 <1 <1 - µg/l A-T-022w

Aro >C8-C9 (w)A# <1 <1 <1 - µg/l A-T-022w

Aro >C9-C10 (w)A# <1 <1 <1 - µg/l A-T-022w

Aro >C10-C12 (w)A# <5 <5 <5 - µg/l A-T-023w

Aro >C12-C16 (w)A# <5 <5 <5 - µg/l A-T-023w

Aro >C16-C21 (w)A# <5 <5 <5 - µg/l A-T-023w

Aro >C21-C35 (w)A# <5 <5 <5 - µg/l A-T-023w

Total Aromatics (w)A <5 <5 <5 - µg/l A-T-022+23w

TPH (Ali & Aro) (w)A <5 9 <5 - µg/l A-T-022+23w

BTEX - Benzene (w)A# <1 <1 <1 - µg/l A-T-022w

BTEX - Toluene (w)A# <1 <1 <1 - µg/l A-T-022w

BTEX - Ethyl Benzene (w)A# <1 <1 <1 - µg/l A-T-022w

BTEX - m & p Xylene (w)A# <1 <1 <1 - µg/l A-T-022w

BTEX - o Xylene (w)A# <1 <1 <1 - µg/l A-T-022w

MTBE (w)A# <1 <1 <1 - µg/l A-T-022w

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Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4

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Client Sample No

Client Sample ID BHXX5 BHXX4 BH410 BHXX3

Depth to Top 9.00 9.00 13.20 8.00

Depth To Bottom

Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15

Sample Type Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A

PAH 16MS (w)

Acenaphthene (w)A# 0.01 0.09 <0.01 - µg/l A-T-019w

Acenaphthylene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w

Anthracene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w

Benzo(a)anthracene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w

Benzo(a)pyrene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w

Benzo(b)fluoranthene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w

Benzo(ghi)perylene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w

Benzo(k)fluoranthene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w

Chrysene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w

Dibenzo(ah)anthracene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w

Fluoranthene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w

Fluorene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w

Indeno(123-cd)pyrene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w

Naphthalene (w)A# 0.02 0.06 <0.01 - µg/l A-T-019w

Phenanthrene (w)A# <0.01 0.01 <0.01 - µg/l A-T-019w

Pyrene (w)A# <0.01 <0.01 <0.01 - µg/l A-T-019w

PAH (total 16) (w)A# 0.03 0.16 <0.01 - µg/l A-T-019w

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Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4

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Client Sample No

Client Sample ID BHXX5 BHXX4 BH410 BHXX3

Depth to Top 9.00 9.00 13.20 8.00

Depth To Bottom

Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15

Sample Type Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A

SVOC (w)

2,4,5-TrichlorophenolA <1 <1 <1 - µg/l A-T-052w

2,4,6-TrichlorophenolA <1 <1 <1 - µg/l A-T-052w

2,4-DichlorophenolA <1 <1 <1 - µg/l A-T-052w

2,4-DimethylphenolA <1 <1 <1 - µg/l A-T-052w

2,4-DinitrotolueneA <1 <1 <1 - µg/l A-T-052w

2,6-DinitrotolueneA <1 <1 <1 - µg/l A-T-052w

2-ChloronaphthaleneA <1 <1 <1 - µg/l A-T-052w

2-ChlorophenolA <1 <1 <1 - µg/l A-T-052w

2-MethylnaphthaleneA <1 <1 <1 - µg/l A-T-052w

2-MethylphenolA <1 <1 <1 - µg/l A-T-052w

2-NitrophenolA <1 <1 <1 - µg/l A-T-052w

4-Bromophenyl phenyl etherA <1 <1 <1 - µg/l A-T-052w

4-Chloro-3-methylphenolA <1 <1 <1 - µg/l A-T-052w

Bis(2-chloroisopropyl)etherA <1 <1 <1 - µg/l A-T-052w

2,4-DinitrophenolA <1 <1 <1 - µg/l A-T-052w

4,6-Dinitro-2-methylphenolA <1 <1 <1 - µg/l A-T-052w

4-MethylphenolA <1 <1 <1 - µg/l A-T-052w

4-NitrophenolA <1 <1 <1 - µg/l A-T-052w

Acenaphthene A <1 <1 <1 - µg/l A-T-052w

AcenaphthyleneA <1 <1 <1 - µg/l A-T-052w

Anthracene A <1 <1 <1 - µg/l A-T-052w

Bis(2-chloroethyl)etherA <1 <1 <1 - µg/l A-T-052w

Bis(2-chloroethoxy)methaneA <1 <1 <1 - µg/l A-T-052w

Bis(2-ethylhexyl)phthalateA <2 <2 <2 - µg/l A-T-052w

Benzo(a)anthraceneA <1 <1 <1 - µg/l A-T-052w

Butylbenzyl phthalate A <1 <1 <1 - µg/l A-T-052w

Benzo(b)fluorantheneA <1 <1 <1 - µg/l A-T-052w

Benzo(k)fluorantheneA <1 <1 <1 - µg/l A-T-052w

Benzo(a)pyrene A <1 <1 <1 - µg/l A-T-052w

Benzo(ghi)peryleneA <1 <1 <1 - µg/l A-T-052w

CarbazoleA <1 <1 <1 - µg/l A-T-052w

ChryseneA <1 <1 <1 - µg/l A-T-052w

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Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4

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Client Sample No

Client Sample ID BHXX5 BHXX4 BH410 BHXX3

Depth to Top 9.00 9.00 13.20 8.00

Depth To Bottom

Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15

Sample Type Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A

DibenzofuranA <1 <1 <1 - µg/l A-T-052w

n-DibutylphthalateA <1 <1 <1 - µg/l A-T-052w

n-DioctylphthalateA 56 47 166 - µg/l A-T-052w

n-Nitroso-n-dipropylamineA <1 <1 <1 - µg/l A-T-052w

Diethyl phthalateA <1 <1 <1 - µg/l A-T-052w

Dimethyl phthalateA <1 <1 <1 - µg/l A-T-052w

Dibenzo(ah)anthraceneA <1 <1 <1 - µg/l A-T-052w

Fluorene A <1 <1 <1 - µg/l A-T-052w

FluorantheneA <1 <1 <1 - µg/l A-T-052w

HexachlorobenzeneA <1 <1 <1 - µg/l A-T-052w

PentachlorophenolA <1 <1 <1 - µg/l A-T-052w

Phenol A <1 <1 <1 - µg/l A-T-052w

HexachloroethaneA <1 <1 <1 - µg/l A-T-052w

NitrobenzeneA <1 <1 <1 - µg/l A-T-052w

Naphthalene A <1 <1 <1 - µg/l A-T-052w

IsophoroneA <1 <1 <1 - µg/l A-T-052w

HexachlorocyclopentadieneA <1 <1 <1 - µg/l A-T-052w

Phenanthrene A <1 <1 <1 - µg/l A-T-052w

Pyrene A <1 <1 <1 - µg/l A-T-052w

Indeno(1,2,3-cd)pyreneA <1 <1 <1 - µg/l A-T-052w

PeryleneA <1 <1 <1 - µg/l A-T-052w

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Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4

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Client Sample No

Client Sample ID BHXX5 BHXX4 BH410 BHXX3

Depth to Top 9.00 9.00 13.20 8.00

Depth To Bottom

Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15

Sample Type Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A

VOC (w)

DichlorodifluoromethaneA# <1 <1 <1 <1 µg/l A-T-006w

ChloromethaneA# 7 22 <1 <1 µg/l A-T-006w

Vinyl ChlorideA# <1 <1 <1 <1 µg/l A-T-006w

BromomethaneA# <1 <1 <1 <1 µg/l A-T-006w

ChloroethaneA# <1 <1 <1 <1 µg/l A-T-006w

TrichlorofluoromethaneA# <1 <1 <1 <1 µg/l A-T-006w

trans 1,2-DichloroetheneA# <1 <1 <1 <1 µg/l A-T-006w

DichloromethaneA 21 58 <5 <5 µg/l A-T-006w

Carbon DisulphideA# 13 1547 1 171 µg/l A-T-006w

1,1-DichloroetheneA# <1 2 <1 <1 µg/l A-T-006w

1,1-DichloroethaneA# <1 <1 <1 <1 µg/l A-T-006w

cis 1,2-DichloroetheneA# <1 3 <1 3 µg/l A-T-006w

BromochloromethaneA# <5 <5 <5 <5 µg/l A-T-006w

ChloroformA# 2330 14723 <25 670 µg/l A-T-006w

2,2-DichloropropaneA# <1 <1 <1 <1 µg/l A-T-006w

1,2-DichloroethaneA# 3 <2 <2 <2 µg/l A-T-006w

1,1,1-TrichloroethaneA# <1 <1 <1 <1 µg/l A-T-006w

1,1-DichloropropeneA# <1 14 <1 <1 µg/l A-T-006w

Benzene A# <1 1 <1 <1 µg/l A-T-006w

Carbon TetrachlorideA# 413 53525 2 54234 µg/l A-T-006w

DibromomethaneA# <1 <1 <1 <1 µg/l A-T-006w

1,2-DichloropropaneA# <1 <1 <1 <1 µg/l A-T-006w

BromodichloromethaneA# <10 <10 <10 <10 µg/l A-T-006w

TrichloroetheneA# <1 6 <1 2 µg/l A-T-006w

cis 1,3-DichloropropeneA# <1 <1 <1 <1 µg/l A-T-006w

trans 1,3-DichloropropeneA# <1 <1 <1 <1 µg/l A-T-006w

1,1,2-TrichloroethaneA# <1 <1 <1 <1 µg/l A-T-006w

Toluene A# <1 1 <1 <1 µg/l A-T-006w

1,3-DichloropropaneA# <1 <1 <1 <1 µg/l A-T-006w

DibromochloromethaneA# <3 <3 <3 <3 µg/l A-T-006w

1,2-DibromoethaneA# <1 <1 <1 <1 µg/l A-T-006w

TetrachloroetheneA# 7 59 <1 39 µg/l A-T-006w

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Envirolab Job Number: 15/02720 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 15/02720/1 15/02720/2 15/02720/3 15/02720/4

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Client Sample No

Client Sample ID BHXX5 BHXX4 BH410 BHXX3

Depth to Top 9.00 9.00 13.20 8.00

Depth To Bottom

Date Sampled 29-Apr-15 29-Apr-15 29-Apr-15 29-Apr-15

Sample Type Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A

1,1,1,2-TetrachloroethaneA <1 <1 <1 <1 µg/l A-T-006w

ChlorobenzeneA# <1 <1 <1 5 µg/l A-T-006w

EthylbenzeneA# <1 <1 <1 <1 µg/l A-T-006w

m & p XyleneA# <1 <1 <1 <1 µg/l A-T-006w

BromoformA# <1 <1 <1 <1 µg/l A-T-006w

StyreneA# <1 <1 <1 <1 µg/l A-T-006w

1,1,2,2-TetrachloroethaneA <1 6 <1 1 µg/l A-T-006w

o-XyleneA# <1 <1 <1 <1 µg/l A-T-006w

1,2,3-TrichloropropaneA# <1 <1 <1 <1 µg/l A-T-006w

IsopropylbenzeneA# <1 <1 <1 <1 µg/l A-T-006w

BromobenzeneA# <1 <1 <1 <1 µg/l A-T-006w

2-ChlorotolueneA# <1 <1 <1 <1 µg/l A-T-006w

n-propylbenzeneA# <1 <1 <1 <1 µg/l A-T-006w

4-ChlorotolueneA# <1 <1 <1 <1 µg/l A-T-006w

1,2,4-TrimethylbenzeneA# <1 <1 <1 <1 µg/l A-T-006w

4-IsopropyltolueneA# <1 <1 <1 <1 µg/l A-T-006w

1,3,5-TrimethylbenzeneA# <1 <1 <1 <1 µg/l A-T-006w

1,2-DichlorobenzeneA# <1 <1 <1 <1 µg/l A-T-006w

1,4-DichlorobenzeneA# <1 <1 <1 <1 µg/l A-T-006w

sec-ButylbenzeneA# <1 <1 <1 <1 µg/l A-T-006w

tert-ButylbenzeneA# <2 <2 <2 <2 µg/l A-T-006w

1,3-DichlorobenzeneA# <1 <1 <1 <1 µg/l A-T-006w

n-butylbenzeneA# <1 <1 <1 <1 µg/l A-T-006w

1,2-Dibromo-3-chloropropaneA# <2 <2 <2 <2 µg/l A-T-006w

1,2,4-TrichlorobenzeneA# <3 <3 <3 <3 µg/l A-T-006w

1,2,3-TrichlorobenzeneA# <3 <3 <3 <3 µg/l A-T-006w

HexachlorobutadieneA# <1 <1 <1 <1 µg/l A-T-006w

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REPORT NOTES

Notes - Soil chemical analysis All results are reported as dry weight (<40°C). For samples with Matrix Codes 1 - 6 natural stones >10mm are removed or excluded from the sample prior to analysis and reported results corrected to a whole sample basis. For samples with Matrix Code 7 the whole sample is dried and crushed prior to analysis. Notes - General

This report shall not be reproduced, except in full, without written approval from Envirolab. Subscript "A" indicates analysis performed on the sample as received. "D" indicates analysis performed on the dried sample, crushed to pass a 2mm sieve, unless asbestos is found to be present in which case all analysis is performed on the sample as received. All analysis is performed on the dried and crushed sample for samples with Matrix Code 7 and this supercedes any "A" subscripts. All analysis is performed on the sample as received for soil samples from outside the European Union and this supercedes any "D" subscripts. Superscript "M" indicates method accredited to MCERTS. If results are in italic font they are associated with an AQC failure. These are not accredited and are unreliable. A deviating samples report is appended and will indicate if samples or tests have been found to be deviating. Any test results affected may not be an accurate record of the concentration at the time of sampling and, as a result, may be invalid. TPH analysis of water by method A-T-007 Free and visible oils are excluded from the sample used for analysis so that the reported result represents the dissolved phase only. Asbestos in soil Asbestos in soil analysis is performed on a dried aliquot of the submitted sample and cannot guarantee to identify asbestos if present as discrete fibres/fragments. Stones etc. are not removed from the sample prior to analysis. Quantification of asbestos is a 3 stage process including visual identification, hand picking and weighing and fibre counting by sedimentation/phase contrast optical microscopy if required. If asbestos is identified a being present but is not in a form that is suitable for analysis by hand picking and weighing (normally if the asbestos is present as free fibres) quantification by sedimentation is performed. Where ACMs are found a percentage asbestos is assigned to each with reference to 'HSG264, Asbestos: The survey guide' and the calculated asbestos content is expressed as a percentage of the dried soil sample aliquot used. Predominant Matrix Codes: 1 = SAND, 2 = LOAM, 3 = CLAY, 4 = LOAM/SAND, 5 = SAND/CLAY, 6 = CLAY/LOAM, 7 = OTHER. Samples with Matrix Code 7 are not predominantly a SAND/LOAM/CLAY mix and are not covered by our BSEN 17025 or MCERTS accreditations. Secondary Matrix Codes: A = contains stones, B = contains construction rubble, C = contains visible hydrocarbons, D = contains glass/metal, E = contains roots/twigs. IS indicates Insufficient sample for analysis. NDP indicates No Determination Possible. NAD indicates No Asbestos Detected. N/A indicates Not Applicable. Superscript # indicates method accredited to ISO 17025. Analytical results reflect the quality of the sample at the time of analysis only. Opinions and interpretations expressed are outside the scope of our accreditation. Please contact us if you need any further information.

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Units 7 & 8 Sandpits Business Park Mottram Road, Hyde, Cheshire, SK14 3AR

FINAL ANALYTICAL TEST REPORT

Envirolab Job Number: 14/06758 Issue Number: 1 Date: 16 December, 2014 Client: RSK Environment Helsby Spring Lodge 172 Chester Road Helsby Cheshire UK WA6 0AR Project Manager: Rachel Hagan/Steven Pettitt Project Name: Mersey Gateway Project Ref: 321315 Order No: N/A Date Samples Received: 02/12/14 Date Instructions Received: 04/12/14 Date Analysis Completed: 15/12/14 Prepared by: Approved by:

Melanie Marshall Carolyn Field Laboratory Coordinator Sales Executive

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Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06758/1 14/06758/2

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Client Sample No

Client Sample ID BHXX3 WS64

Depth to Top 10.50 2.70

Depth To Bottom

Date Sampled 01-Dec-14 01-Dec-14

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

pH (w)A# 7.25 12.12 pH A-T-031w

Electrical conductivity @ 20degC (w)A# 9630 4370 µs/cm A-T-037w

COD (settled)A# 130 130 mg/l A-T-034w

BOD (settled, 5 day)A <1 16 mg/l A-T-048

Hardness TotalA# 1530 1444 mg/l Ca

CO3

A-T-049w

Chloride (w)A# 721 415.93 mg/l A-T-026w

Nitrite (w)A# <0.10 0.35 mg/l A-T-026w

Nitrate (w) A# <0.50 <0.50 mg/l A-T-026w

Sulphate (w)A# 3947 824 mg/l A-T-026w

Cyanide (total) (w)A# <0.005 0.034 mg/l A-T-042wTCN

Phenols - Total by HPLC (w)A <0.01 0.43 mg/l A-T-050w

Sulphide (w)A <0.1 105.0 mg/l A-T-S2-w

DOC (w)A# 14.3 21.9 mg/l A-T-032w

Aluminium (dissolved)A 17 138 µg/l A-T-049w

Arsenic (dissolved)A# 8500 7 µg/l A-T-025w

Boron (dissolved)A# 1090 89 µg/l A-T-025w

Barium (dissolved)A# 46 37 µg/l A-T-025w

Beryllium (dissolved)A# <1 <1 µg/l A-T-025w

Cadmium (dissolved)A# <1 <1 µg/l A-T-025w

Calcium (dissolved)A# 478 578 mg/l A-T-049w

Copper (dissolved)A# <1 <1 µg/l A-T-025w

Chromium (dissolved)A# 5 2 µg/l A-T-025w

Chromium (hexavalent) (w)A# <0.05 <0.05 mg/l A-T-040w

Chromium (trivalent) (w) <0.05 <0.05 mg/l Calc

Iron (dissolved)A# 17200 65 µg/l A-T-025w

Lead (dissolved)A# <1 <1 µg/l A-T-025w

Manganese (dissolved)A# 4079 2 µg/l A-T-025w

Magnesium (dissolved)A# 81 <1 mg/l A-T-049w

Mercury (dissolved)A# <0.1 0.1 µg/l A-T-025w

Nickel (dissolved)A# 8 4 µg/l A-T-025w

Potassium (dissolved)A# 128 20 mg/l A-T-049w

Selenium (dissolved)A# 2 6 µg/l A-T-025w

Sodium (dissolved)A# 799 240 mg/l A-T-049w

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Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06758/1 14/06758/2

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Client Sample No

Client Sample ID BHXX3 WS64

Depth to Top 10.50 2.70

Depth To Bottom

Date Sampled 01-Dec-14 01-Dec-14

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

Strontium (dissolved)A 1150 866 µg/l A-T-025w

Vanadium (dissolved)A# 10 5 µg/l A-T-025w

Zinc (dissolved)A# 8 <1 µg/l A-T-025w

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Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06758/1 14/06758/2

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Client Sample No

Client Sample ID BHXX3 WS64

Depth to Top 10.50 2.70

Depth To Bottom

Date Sampled 01-Dec-14 01-Dec-14

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

TPH CWG

Ali >C5-C6 (w)A# <1 <1 µg/l A-T-022w

Ali >C6-C8 (w)A# <1 <1 µg/l A-T-022w

Ali >C8-C10 (w)A# <1 <1 µg/l A-T-022w

Ali >C10-C12 (w)A# <5 <5 µg/l A-T-023w

Ali >C12-C16 (w)A# <5 <5 µg/l A-T-023w

Ali >C16-C21 (w)A# <5 <5 µg/l A-T-023w

Ali >C21-C35 (w)A# <5 <5 µg/l A-T-023w

Total Aliphatics (w)A <5 <5 µg/l A-T-022+23w

Aro >C5-C7 (w)A# <1 <1 µg/l A-T-022w

Aro >C7-C8 (w)A# <1 1 µg/l A-T-022w

Aro >C8-C9 (w)A# <1 3 µg/l A-T-022w

Aro >C9-C10 (w)A# <1 2 µg/l A-T-022w

Aro >C10-C12 (w)A# <5 8 µg/l A-T-023w

Aro >C12-C16 (w)A# <5 7 µg/l A-T-023w

Aro >C16-C21 (w)A# <5 <5 µg/l A-T-023w

Aro >C21-C35 (w)A# <5 <5 µg/l A-T-023w

Total Aromatics (w)A <5 21 µg/l A-T-022+23w

TPH (Ali & Aro) (w)A <5 21 µg/l A-T-022+23w

BTEX - Benzene (w)A# <1 <1 µg/l A-T-022w

BTEX - Toluene (w)A# <1 1 µg/l A-T-022w

BTEX - Ethyl Benzene (w)A# <1 <1 µg/l A-T-022w

BTEX - m & p Xylene (w)A# <1 1 µg/l A-T-022w

BTEX - o Xylene (w)A# <1 1 µg/l A-T-022w

MTBE (w)A# <1 <1 µg/l A-T-022w

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Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06758/1 14/06758/2

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Client Sample No

Client Sample ID BHXX3 WS64

Depth to Top 10.50 2.70

Depth To Bottom

Date Sampled 01-Dec-14 01-Dec-14

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

PAH 16MS (w)

Acenaphthene (w)A# <0.01 <0.01 µg/l A-T-019w

Acenaphthylene (w)A# <0.01 <0.01 µg/l A-T-019w

Anthracene (w)A# <0.01 <0.01 µg/l A-T-019w

Benzo(a)anthracene (w)A# <0.01 <0.01 µg/l A-T-019w

Benzo(a)pyrene (w)A# <0.01 <0.01 µg/l A-T-019w

Benzo(b)fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w

Benzo(ghi)perylene (w)A# <0.01 <0.01 µg/l A-T-019w

Benzo(k)fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w

Chrysene (w)A# <0.01 <0.01 µg/l A-T-019w

Dibenzo(ah)anthracene (w)A# <0.01 <0.01 µg/l A-T-019w

Fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w

Fluorene (w)A# <0.01 <0.01 µg/l A-T-019w

Indeno(123-cd)pyrene (w)A# <0.01 <0.01 µg/l A-T-019w

Naphthalene (w)A# 0.02 3.59 µg/l A-T-019w

Phenanthrene (w)A# 0.01 <0.01 µg/l A-T-019w

Pyrene (w)A# <0.01 <0.01 µg/l A-T-019w

PAH (total 16) (w)A# 0.03 3.59 µg/l A-T-019w

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Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06758/1 14/06758/2

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Client Sample No

Client Sample ID BHXX3 WS64

Depth to Top 10.50 2.70

Depth To Bottom

Date Sampled 01-Dec-14 01-Dec-14

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

SVOC (w)

2,4,5-TrichlorophenolA <1 <1 µg/l A-T-052w

2,4,6-TrichlorophenolA <1 <1 µg/l A-T-052w

2,4-DichlorophenolA <1 <1 µg/l A-T-052w

2,4-DimethylphenolA <1 7 µg/l A-T-052w

2,4-DinitrotolueneA <1 <1 µg/l A-T-052w

2,6-DinitrotolueneA <1 <1 µg/l A-T-052w

2-ChloronaphthaleneA <1 <1 µg/l A-T-052w

2-ChlorophenolA <1 <1 µg/l A-T-052w

2-MethylnaphthaleneA <1 <1 µg/l A-T-052w

2-MethylphenolA <1 12 µg/l A-T-052w

2-NitrophenolA <1 <1 µg/l A-T-052w

4-Bromophenyl phenyl etherA <1 <1 µg/l A-T-052w

4-Chloro-3-methylphenolA <1 <1 µg/l A-T-052w

Bis(2-chloroisopropyl)etherA <1 <1 µg/l A-T-052w

2,4-DinitrophenolA <1 <1 µg/l A-T-052w

4,6-Dinitro-2-methylphenolA <1 <1 µg/l A-T-052w

4-MethylphenolA <1 13 µg/l A-T-052w

4-NitrophenolA <1 <1 µg/l A-T-052w

Acenaphthene A <1 <1 µg/l A-T-052w

AcenaphthyleneA <1 <1 µg/l A-T-052w

Anthracene A <1 <1 µg/l A-T-052w

Bis(2-chloroethyl)etherA <1 <1 µg/l A-T-052w

Bis(2-chloroethoxy)methaneA <1 <1 µg/l A-T-052w

Bis(2-ethylhexyl)phthalateA <2 <2 µg/l A-T-052w

Benzo(a)anthraceneA <1 <1 µg/l A-T-052w

Butylbenzyl phthalate A <1 <1 µg/l A-T-052w

Benzo(b)fluorantheneA <1 <1 µg/l A-T-052w

Benzo(k)fluorantheneA <1 <1 µg/l A-T-052w

Benzo(a)pyrene A <1 <1 µg/l A-T-052w

Benzo(ghi)peryleneA <1 <1 µg/l A-T-052w

CarbazoleA <1 <1 µg/l A-T-052w

ChryseneA <1 <1 µg/l A-T-052w

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Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06758/1 14/06758/2

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Client Sample No

Client Sample ID BHXX3 WS64

Depth to Top 10.50 2.70

Depth To Bottom

Date Sampled 01-Dec-14 01-Dec-14

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

DibenzofuranA <1 <1 µg/l A-T-052w

n-DibutylphthalateA <1 <1 µg/l A-T-052w

n-DioctylphthalateA <5 <5 µg/l A-T-052w

n-Nitroso-n-dipropylamineA <1 <1 µg/l A-T-052w

Diethyl phthalateA <1 <1 µg/l A-T-052w

Dimethyl phthalateA <1 <1 µg/l A-T-052w

Dibenzo(ah)anthraceneA <1 <1 µg/l A-T-052w

Fluorene A <1 <1 µg/l A-T-052w

FluorantheneA <1 <1 µg/l A-T-052w

HexachlorobenzeneA <1 <1 µg/l A-T-052w

PentachlorophenolA <1 <1 µg/l A-T-052w

Phenol A 2 54 µg/l A-T-052w

HexachloroethaneA <1 <1 µg/l A-T-052w

NitrobenzeneA <1 <1 µg/l A-T-052w

Naphthalene A <1 4 µg/l A-T-052w

IsophoroneA <1 <1 µg/l A-T-052w

HexachlorocyclopentadieneA <1 <1 µg/l A-T-052w

Phenanthrene A <1 <1 µg/l A-T-052w

Pyrene A <1 <1 µg/l A-T-052w

Indeno(1,2,3-cd)pyreneA <1 <1 µg/l A-T-052w

PeryleneA <1 <1 µg/l A-T-052w

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Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06758/1 14/06758/2

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Client Sample No

Client Sample ID BHXX3 WS64

Depth to Top 10.50 2.70

Depth To Bottom

Date Sampled 01-Dec-14 01-Dec-14

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

VOC (w)

DichlorodifluoromethaneA# <1 <1 µg/l A-T-006w

ChloromethaneA# <1 <1 µg/l A-T-006w

Vinyl ChlorideA# <1 <1 µg/l A-T-006w

BromomethaneA# <1 <1 µg/l A-T-006w

ChloroethaneA# <1 <1 µg/l A-T-006w

TrichlorofluoromethaneA# <1 <1 µg/l A-T-006w

trans 1,2-DichloroetheneA# <1 <1 µg/l A-T-006w

DichloromethaneA <5 <5 µg/l A-T-006w

Carbon DisulphideA# 24 <1 µg/l A-T-006w

1,1-DichloroetheneA# <1 <1 µg/l A-T-006w

1,1-DichloroethaneA# <1 <1 µg/l A-T-006w

cis 1,2-DichloroetheneA# 3 <1 µg/l A-T-006w

BromochloromethaneA# <5 <5 µg/l A-T-006w

ChloroformA# 206 <25 µg/l A-T-006w

2,2-DichloropropaneA# <1 <1 µg/l A-T-006w

1,2-DichloroethaneA# <2 <2 µg/l A-T-006w

1,1,1-TrichloroethaneA# <1 <1 µg/l A-T-006w

1,1-DichloropropeneA# <1 <1 µg/l A-T-006w

Benzene A# <1 <1 µg/l A-T-006w

Carbon TetrachlorideA# 509 <1 µg/l A-T-006w

DibromomethaneA# <1 <1 µg/l A-T-006w

1,2-DichloropropaneA# <1 <1 µg/l A-T-006w

BromodichloromethaneA# <10 <10 µg/l A-T-006w

TrichloroetheneA# 2 <1 µg/l A-T-006w

cis 1,3-DichloropropeneA# <1 <1 µg/l A-T-006w

trans 1,3-DichloropropeneA# <1 <1 µg/l A-T-006w

1,1,2-TrichloroethaneA# <1 <1 µg/l A-T-006w

Toluene A# <1 1 µg/l A-T-006w

1,3-DichloropropaneA# <1 <1 µg/l A-T-006w

DibromochloromethaneA# <3 <3 µg/l A-T-006w

1,2-DibromoethaneA# <1 <1 µg/l A-T-006w

TetrachloroetheneA# 19 <1 µg/l A-T-006w

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Envirolab Job Number: 14/06758 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06758/1 14/06758/2

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Client Sample No

Client Sample ID BHXX3 WS64

Depth to Top 10.50 2.70

Depth To Bottom

Date Sampled 01-Dec-14 01-Dec-14

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

1,1,1,2-TetrachloroethaneA <1 <1 µg/l A-T-006w

ChlorobenzeneA# <1 <1 µg/l A-T-006w

EthylbenzeneA# <1 <1 µg/l A-T-006w

m & p XyleneA# <1 <1 µg/l A-T-006w

BromoformA# <1 <1 µg/l A-T-006w

StyreneA# <1 <1 µg/l A-T-006w

1,1,2,2-TetrachloroethaneA <1 <1 µg/l A-T-006w

o-XyleneA# <1 <1 µg/l A-T-006w

1,2,3-TrichloropropaneA# <1 <1 µg/l A-T-006w

IsopropylbenzeneA# <1 <1 µg/l A-T-006w

BromobenzeneA# <1 <1 µg/l A-T-006w

2-ChlorotolueneA# <1 <1 µg/l A-T-006w

n-propylbenzeneA# <1 <1 µg/l A-T-006w

4-ChlorotolueneA# <1 <1 µg/l A-T-006w

1,2,4-TrimethylbenzeneA# <1 <1 µg/l A-T-006w

4-IsopropyltolueneA# <1 <1 µg/l A-T-006w

1,3,5-TrimethylbenzeneA# <1 <1 µg/l A-T-006w

1,2-DichlorobenzeneA# <1 <1 µg/l A-T-006w

1,4-DichlorobenzeneA# <1 <1 µg/l A-T-006w

sec-ButylbenzeneA# <1 <1 µg/l A-T-006w

tert-ButylbenzeneA# <2 <2 µg/l A-T-006w

1,3-DichlorobenzeneA# <1 <1 µg/l A-T-006w

n-butylbenzeneA# <1 <1 µg/l A-T-006w

1,2-Dibromo-3-chloropropaneA# <2 <2 µg/l A-T-006w

1,2,4-TrichlorobenzeneA# <3 <3 µg/l A-T-006w

1,2,3-TrichlorobenzeneA# <3 <3 µg/l A-T-006w

HexachlorobutadieneA# <1 <1 µg/l A-T-006w

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REPORT NOTES

Notes - Soil chemical analysis All results are reported as dry weight (<40°C). For samples with Matrix Codes 1 - 6 natural stones >10mm are removed or excluded from the sample prior to analysis and reported results corrected to a whole sample basis. For samples with Matrix Code 7 the whole sample is dried and crushed prior to analysis. Notes - General

This report shall not be reproduced, except in full, without written approval from Envirolab. Subscript "A" indicates analysis performed on the sample as received. "D" indicates analysis performed on the dried sample, crushed to pass a 2mm sieve, unless asbestos is found to be present in which case all analysis is performed on the sample as received. All analysis is performed on the dried and crushed sample for samples with Matrix Code 7 and this supercedes any "A" subscripts. All analysis is performed on the sample as received for soil samples from outside the European Union and this supercedes any "D" subscripts. Superscript "M" indicates method accredited to MCERTS. If results are in italic font they are associated with an AQC failure. These are not accredited and are unreliable. A deviating samples report is appended and will indicate if samples or tests have been found to be deviating. Any test results affected may not be an accurate record of the concentration at the time of sampling and, as a result, may be invalid. TPH analysis of water by method A-T-007 Free and visible oils are excluded from the sample used for analysis so that the reported result represents the dissolved phase only. Asbestos in soil Asbestos in soil analysis is performed on a dried aliquot of the submitted sample and cannot guarantee to identify asbestos if present as discrete fibres/fragments. Stones etc. are not removed from the sample prior to analysis. Quantification of asbestos is a 3 stage process including visual identification, hand picking and weighing and fibre counting by sedimentation/phase contrast optical microscopy if required. If asbestos is identified a being present but is not in a form that is suitable for analysis by hand picking and weighing (normally if the asbestos is present as free fibres) quantification by sedimentation is performed. Where ACMs are found a percentage asbestos is assigned to each with reference to 'HSG264, Asbestos: The survey guide' and the calculated asbestos content is expressed as a percentage of the dried soil sample aliquot used. Predominant Matrix Codes: 1 = SAND, 2 = LOAM, 3 = CLAY, 4 = LOAM/SAND, 5 = SAND/CLAY, 6 = CLAY/LOAM, 7 = OTHER. Samples with Matrix Code 7 are not predominantly a SAND/LOAM/CLAY mix and are not covered by our BSEN 17025 or MCERTS accreditations. Secondary Matrix Codes: A = contains stones, B = contains construction rubble, C = contains visible hydrocarbons, D = contains glass/metal, E = contains roots/twigs. IS indicates Insufficient sample for analysis. NDP indicates No Determination Possible. NAD indicates No Asbestos Detected. N/A indicates Not Applicable. Superscript # indicates method accredited to ISO 17025. Analytical results reflect the quality of the sample at the time of analysis only. Opinions and interpretations expressed are outside the scope of our accreditation. Please contact us if you need any further information.

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Units 7 & 8 Sandpits Business Park Mottram Road, Hyde, Cheshire, SK14 3AR

FINAL ANALYTICAL TEST REPORT

Envirolab Job Number: 14/06552 Issue Number: 1 Date: 01 December, 2014 Client: RSK Environment Helsby Spring Lodge 172 Chester Road Helsby Cheshire UK WA6 0AR Project Manager: Rachel Hagan/Steven Pettitt Project Name: Mersey Gateway Project Ref: 321315 Order No: N/A Date Samples Received: 24/11/14 Date Instructions Received: 25/11/14 Date Analysis Completed: 01/12/14 Prepared by: Approved by:

Melanie Marshall Iain Haslock Laboratory Coordinator Analytical Consultant

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Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06552/1 14/06552/2 14/06552/3

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Client Sample No

Client Sample ID BHXX1 BHXX2 BHXX3

Depth to Top 19.00 52.8 10.50

Depth To Bottom

Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14

Sample Type Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A

pH (w)A# 7.55 7.24 7.51 pH A-T-031w

Electrical conductivity @ 20degC (w)A# 12800 14400 8250 µs/cm A-T-037w

COD (settled)A# 190 120 120 mg/l A-T-034w

BOD (settled, 5 day)A <1 <1 <1 mg/l A-T-048

Hardness TotalA# 2920 7660 1675 mg/l Ca

CO3

A-T-049w

Chloride (w)A# 4330 6180 787 mg/l A-T-026w

Nitrite (w)A# <0.10 <0.10 <0.10 mg/l A-T-026w

Nitrate (w) A# <0.50 <0.50 <0.50 mg/l A-T-026w

Sulphate (w)A# 1848 614 3548 mg/l A-T-026w

Cyanide (total) (w)A# <0.005 <0.005 <0.005 mg/l A-T-042wTCN

Phenols - Total by HPLC (w)A 0.50 0.39 <0.01 mg/l A-T-050w

Sulphide (w)A <0.1 <0.1 0.1 mg/l A-T-S2-w

DOC (w)A# 3.8 1.7 13.8 mg/l A-T-032w

Aluminium (dissolved)A 23 21 35 µg/l A-T-049w

Arsenic (dissolved)A# 99 3 9780 µg/l A-T-025w

Boron (dissolved)A# 501 56 444 µg/l A-T-025w

Barium (dissolved)A# 94 62 47 µg/l A-T-025w

Beryllium (dissolved)A# <1 <1 <1 µg/l A-T-025w

Cadmium (dissolved)A# <1 <1 <1 µg/l A-T-025w

Calcium (dissolved)A# 668 1700 576 mg/l A-T-049w

Copper (dissolved)A# <1 <1 <1 µg/l A-T-025w

Chromium (dissolved)A# 10 14 7 µg/l A-T-025w

Chromium (hexavalent) (w)A# <0.05 <0.05 <0.05 mg/l A-T-040w

Chromium (trivalent) (w) <0.05 <0.05 <0.05 mg/l Calc

Iron (dissolved)A# 3124 178 17730 µg/l A-T-025w

Lead (dissolved)A# <1 <1 <1 µg/l A-T-025w

Manganese (dissolved)A# 1925 556 4454 µg/l A-T-025w

Magnesium (dissolved)A# 304 827 57 mg/l A-T-049w

Mercury (dissolved)A# <0.1 <0.1 <0.1 µg/l A-T-025w

Nickel (dissolved)A# 4 7 10 µg/l A-T-025w

Potassium (dissolved)A# 58 19 94 mg/l A-T-049w

Selenium (dissolved)A# <1 <1 2 µg/l A-T-025w

Sodium (dissolved)A# 2170 1280 892 mg/l A-T-049w

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Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06552/1 14/06552/2 14/06552/3

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Client Sample No

Client Sample ID BHXX1 BHXX2 BHXX3

Depth to Top 19.00 52.8 10.50

Depth To Bottom

Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14

Sample Type Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A

Strontium (dissolved)A 6780 3700 1120 µg/l A-T-025w

Vanadium (dissolved)A# 4 2 11 µg/l A-T-025w

Zinc (dissolved)A# 16 10 9 µg/l A-T-025w

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Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06552/1 14/06552/2 14/06552/3

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Client Sample No

Client Sample ID BHXX1 BHXX2 BHXX3

Depth to Top 19.00 52.8 10.50

Depth To Bottom

Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14

Sample Type Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A

TPH CWG

Ali >C5-C6 (w)A# <1 <1 <1 µg/l A-T-022w

Ali >C6-C8 (w)A# <1 <1 <1 µg/l A-T-022w

Ali >C8-C10 (w)A# <1 <1 <1 µg/l A-T-022w

Ali >C10-C12 (w)A# <5 <5 <5 µg/l A-T-023w

Ali >C12-C16 (w)A# <5 <5 <5 µg/l A-T-023w

Ali >C16-C21 (w)A# <5 <5 10 µg/l A-T-023w

Ali >C21-C35 (w)A# <5 <5 208 µg/l A-T-023w

Total Aliphatics (w)A <5 <5 218 µg/l A-T-022+23w

Aro >C5-C7 (w)A# <1 <1 <1 µg/l A-T-022w

Aro >C7-C8 (w)A# <1 <1 <1 µg/l A-T-022w

Aro >C8-C9 (w)A# <1 <1 <1 µg/l A-T-022w

Aro >C9-C10 (w)A# <1 <1 <1 µg/l A-T-022w

Aro >C10-C12 (w)A# <5 <5 <5 µg/l A-T-023w

Aro >C12-C16 (w)A# <5 <5 <5 µg/l A-T-023w

Aro >C16-C21 (w)A# <5 <5 <5 µg/l A-T-023w

Aro >C21-C35 (w)A# <5 <5 51 µg/l A-T-023w

Total Aromatics (w)A <5 <5 51 µg/l A-T-022+23w

TPH (Ali & Aro) (w)A <5 <5 269 µg/l A-T-022+23w

BTEX - Benzene (w)A# <1 <1 <1 µg/l A-T-022w

BTEX - Toluene (w)A# <1 <1 <1 µg/l A-T-022w

BTEX - Ethyl Benzene (w)A# <1 <1 <1 µg/l A-T-022w

BTEX - m & p Xylene (w)A# <1 <1 <1 µg/l A-T-022w

BTEX - o Xylene (w)A# <1 <1 <1 µg/l A-T-022w

MTBE (w)A# <1 <1 <1 µg/l A-T-022w

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Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06552/1 14/06552/2 14/06552/3

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Client Sample No

Client Sample ID BHXX1 BHXX2 BHXX3

Depth to Top 19.00 52.8 10.50

Depth To Bottom

Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14

Sample Type Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A

PAH 16MS (w)

Acenaphthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Acenaphthylene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Anthracene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(a)anthracene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(a)pyrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(b)fluoranthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(ghi)perylene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(k)fluoranthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Chrysene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Dibenzo(ah)anthracene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Fluoranthene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Fluorene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Indeno(123-cd)pyrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Naphthalene (w)A# <0.01 <0.01 0.02 µg/l A-T-019w

Phenanthrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

Pyrene (w)A# <0.01 <0.01 <0.01 µg/l A-T-019w

PAH (total 16) (w)A# <0.01 <0.01 0.02 µg/l A-T-019w

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Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06552/1 14/06552/2 14/06552/3

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Client Sample No

Client Sample ID BHXX1 BHXX2 BHXX3

Depth to Top 19.00 52.8 10.50

Depth To Bottom

Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14

Sample Type Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A

SVOC (w)

2,4,5-TrichlorophenolA <1 <1 <1 µg/l A-T-052w

2,4,6-TrichlorophenolA <1 <1 <1 µg/l A-T-052w

2,4-DichlorophenolA <1 <1 <1 µg/l A-T-052w

2,4-DimethylphenolA <1 <1 <1 µg/l A-T-052w

2,4-DinitrotolueneA <1 <1 <1 µg/l A-T-052w

2,6-DinitrotolueneA <1 <1 <1 µg/l A-T-052w

2-ChloronaphthaleneA <1 <1 <1 µg/l A-T-052w

2-ChlorophenolA <1 <1 <1 µg/l A-T-052w

2-MethylnaphthaleneA <1 <1 <1 µg/l A-T-052w

2-MethylphenolA <1 <1 <1 µg/l A-T-052w

2-NitrophenolA <1 <1 <1 µg/l A-T-052w

4-Bromophenyl phenyl etherA <1 <1 <1 µg/l A-T-052w

4-Chloro-3-methylphenolA <1 <1 <1 µg/l A-T-052w

Bis(2-chloroisopropyl)etherA <1 <1 <1 µg/l A-T-052w

2,4-DinitrophenolA <1 <1 <1 µg/l A-T-052w

4,6-Dinitro-2-methylphenolA <1 <1 <1 µg/l A-T-052w

4-MethylphenolA <1 <1 <1 µg/l A-T-052w

4-NitrophenolA <1 <1 <1 µg/l A-T-052w

Acenaphthene A <1 <1 <1 µg/l A-T-052w

AcenaphthyleneA <1 <1 <1 µg/l A-T-052w

Anthracene A <1 <1 <1 µg/l A-T-052w

Bis(2-chloroethyl)etherA <1 1 <1 µg/l A-T-052w

Bis(2-chloroethoxy)methaneA <1 <1 <1 µg/l A-T-052w

Bis(2-ethylhexyl)phthalateA <2 <2 <2 µg/l A-T-052w

Benzo(a)anthraceneA <1 <1 <1 µg/l A-T-052w

Butylbenzyl phthalate A <1 <1 <1 µg/l A-T-052w

Benzo(b)fluorantheneA <1 <1 <1 µg/l A-T-052w

Benzo(k)fluorantheneA <1 <1 <1 µg/l A-T-052w

Benzo(a)pyrene A <1 <1 <1 µg/l A-T-052w

Benzo(ghi)peryleneA <1 <1 <1 µg/l A-T-052w

CarbazoleA <1 <1 <1 µg/l A-T-052w

ChryseneA <1 <1 <1 µg/l A-T-052w

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Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06552/1 14/06552/2 14/06552/3

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Client Sample No

Client Sample ID BHXX1 BHXX2 BHXX3

Depth to Top 19.00 52.8 10.50

Depth To Bottom

Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14

Sample Type Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A

DibenzofuranA <1 <1 <1 µg/l A-T-052w

n-DibutylphthalateA <1 <1 <1 µg/l A-T-052w

n-DioctylphthalateA <5 <5 <5 µg/l A-T-052w

n-Nitroso-n-dipropylamineA <1 <1 <1 µg/l A-T-052w

Diethyl phthalateA <1 <1 <1 µg/l A-T-052w

Dimethyl phthalateA <1 <1 <1 µg/l A-T-052w

Dibenzo(ah)anthraceneA <1 <1 <1 µg/l A-T-052w

Fluorene A <1 <1 <1 µg/l A-T-052w

FluorantheneA <1 <1 <1 µg/l A-T-052w

HexachlorobenzeneA <1 <1 <1 µg/l A-T-052w

PentachlorophenolA <1 <1 <1 µg/l A-T-052w

Phenol A <1 <1 <1 µg/l A-T-052w

HexachloroethaneA <1 <1 <1 µg/l A-T-052w

NitrobenzeneA <1 <1 <1 µg/l A-T-052w

Naphthalene A <1 <1 <1 µg/l A-T-052w

IsophoroneA <1 <1 <1 µg/l A-T-052w

HexachlorocyclopentadieneA <1 <1 <1 µg/l A-T-052w

Phenanthrene A <1 <1 <1 µg/l A-T-052w

Pyrene A <1 <1 <1 µg/l A-T-052w

Indeno(1,2,3-cd)pyreneA <1 <1 <1 µg/l A-T-052w

PeryleneA <1 <1 <1 µg/l A-T-052w

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Page 8 of 10

Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06552/1 14/06552/2 14/06552/3

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Client Sample No

Client Sample ID BHXX1 BHXX2 BHXX3

Depth to Top 19.00 52.8 10.50

Depth To Bottom

Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14

Sample Type Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A

VOC (w)

DichlorodifluoromethaneA# <1 <1 <1 µg/l A-T-006w

ChloromethaneA# <1 <1 <1 µg/l A-T-006w

Vinyl ChlorideA# <1 <1 <1 µg/l A-T-006w

BromomethaneA# <1 <1 <1 µg/l A-T-006w

ChloroethaneA# <1 <1 <1 µg/l A-T-006w

TrichlorofluoromethaneA# <1 <1 <1 µg/l A-T-006w

trans 1,2-DichloroetheneA# <1 <1 <1 µg/l A-T-006w

DichloromethaneA <5 <5 <5 µg/l A-T-006w

Carbon DisulphideA# <1 <1 48 µg/l A-T-006w

1,1-DichloroetheneA# <1 <1 <1 µg/l A-T-006w

1,1-DichloroethaneA# <1 <1 <1 µg/l A-T-006w

cis 1,2-DichloroetheneA# <1 <1 3 µg/l A-T-006w

BromochloromethaneA# <5 <5 <5 µg/l A-T-006w

ChloroformA# 270 <25 188 µg/l A-T-006w

2,2-DichloropropaneA# <1 <1 <1 µg/l A-T-006w

1,2-DichloroethaneA# <2 <2 <2 µg/l A-T-006w

1,1,1-TrichloroethaneA# <1 <1 <1 µg/l A-T-006w

1,1-DichloropropeneA# <1 <1 <1 µg/l A-T-006w

Benzene A# <1 <1 <1 µg/l A-T-006w

Carbon TetrachlorideA# 215 <1 748 µg/l A-T-006w

DibromomethaneA# <1 <1 <1 µg/l A-T-006w

1,2-DichloropropaneA# <1 <1 <1 µg/l A-T-006w

BromodichloromethaneA# <10 <10 <10 µg/l A-T-006w

TrichloroetheneA# <1 <1 2 µg/l A-T-006w

cis 1,3-DichloropropeneA# <1 <1 <1 µg/l A-T-006w

trans 1,3-DichloropropeneA# <1 <1 <1 µg/l A-T-006w

1,1,2-TrichloroethaneA# <1 <1 <1 µg/l A-T-006w

Toluene A# <1 <1 <1 µg/l A-T-006w

1,3-DichloropropaneA# <1 <1 <1 µg/l A-T-006w

DibromochloromethaneA# <3 <3 <3 µg/l A-T-006w

1,2-DibromoethaneA# <1 <1 <1 µg/l A-T-006w

TetrachloroetheneA# <1 <1 14 µg/l A-T-006w

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Envirolab Job Number: 14/06552 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06552/1 14/06552/2 14/06552/3

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Client Sample No

Client Sample ID BHXX1 BHXX2 BHXX3

Depth to Top 19.00 52.8 10.50

Depth To Bottom

Date Sampled 24-Nov-14 24-Nov-14 24-Nov-14

Sample Type Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A

1,1,1,2-TetrachloroethaneA <1 <1 <1 µg/l A-T-006w

ChlorobenzeneA# <1 <1 <1 µg/l A-T-006w

EthylbenzeneA# <1 <1 <1 µg/l A-T-006w

m & p XyleneA# <1 <1 <1 µg/l A-T-006w

BromoformA# <1 <1 <1 µg/l A-T-006w

StyreneA# <1 <1 <1 µg/l A-T-006w

1,1,2,2-TetrachloroethaneA <1 <1 <1 µg/l A-T-006w

o-XyleneA# <1 <1 <1 µg/l A-T-006w

1,2,3-TrichloropropaneA# <1 <1 <1 µg/l A-T-006w

IsopropylbenzeneA# <1 <1 <1 µg/l A-T-006w

BromobenzeneA# <1 <1 <1 µg/l A-T-006w

2-ChlorotolueneA# <1 <1 <1 µg/l A-T-006w

n-propylbenzeneA# <1 <1 <1 µg/l A-T-006w

4-ChlorotolueneA# <1 <1 <1 µg/l A-T-006w

1,2,4-TrimethylbenzeneA# <1 <1 <1 µg/l A-T-006w

4-IsopropyltolueneA# <1 <1 <1 µg/l A-T-006w

1,3,5-TrimethylbenzeneA# <1 <1 <1 µg/l A-T-006w

1,2-DichlorobenzeneA# <1 <1 <1 µg/l A-T-006w

1,4-DichlorobenzeneA# <1 <1 <1 µg/l A-T-006w

sec-ButylbenzeneA# <1 <1 <1 µg/l A-T-006w

tert-ButylbenzeneA# <2 <2 <2 µg/l A-T-006w

1,3-DichlorobenzeneA# <1 <1 <1 µg/l A-T-006w

n-butylbenzeneA# <1 <1 <1 µg/l A-T-006w

1,2-Dibromo-3-chloropropaneA# <2 <2 <2 µg/l A-T-006w

1,2,4-TrichlorobenzeneA# <3 <3 <3 µg/l A-T-006w

1,2,3-TrichlorobenzeneA# <3 <3 <3 µg/l A-T-006w

HexachlorobutadieneA# <1 <1 <1 µg/l A-T-006w

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Page 10 of 10

REPORT NOTES

Notes - Soil chemical analysis All results are reported as dry weight (<40°C). For samples with Matrix Codes 1 - 6 natural stones >10mm are removed or excluded from the sample prior to analysis and reported results corrected to a whole sample basis. For samples with Matrix Code 7 the whole sample is dried and crushed prior to analysis. Notes - General

This report shall not be reproduced, except in full, without written approval from Envirolab. Subscript "A" indicates analysis performed on the sample as received. "D" indicates analysis performed on the dried sample, crushed to pass a 2mm sieve, unless asbestos is found to be present in which case all analysis is performed on the sample as received. All analysis is performed on the dried and crushed sample for samples with Matrix Code 7 and this supercedes any "A" subscripts. All analysis is performed on the sample as received for soil samples from outside the European Union and this supercedes any "D" subscripts. Superscript "M" indicates method accredited to MCERTS. If results are in italic font they are associated with an AQC failure. These are not accredited and are unreliable. A deviating samples report is appended and will indicate if samples or tests have been found to be deviating. Any test results affected may not be an accurate record of the concentration at the time of sampling and, as a result, may be invalid. TPH analysis of water by method A-T-007 Free and visible oils are excluded from the sample used for analysis so that the reported result represents the dissolved phase only. Asbestos in soil Asbestos in soil analysis is performed on a dried aliquot of the submitted sample and cannot guarantee to identify asbestos if present as discrete fibres/fragments. Stones etc. are not removed from the sample prior to analysis. Quantification of asbestos is a 3 stage process including visual identification, hand picking and weighing and fibre counting by sedimentation/phase contrast optical microscopy if required. If asbestos is identified a being present but is not in a form that is suitable for analysis by hand picking and weighing (normally if the asbestos is present as free fibres) quantification by sedimentation is performed. Where ACMs are found a percentage asbestos is assigned to each with reference to 'HSG264, Asbestos: The survey guide' and the calculated asbestos content is expressed as a percentage of the dried soil sample aliquot used. Predominant Matrix Codes: 1 = SAND, 2 = LOAM, 3 = CLAY, 4 = LOAM/SAND, 5 = SAND/CLAY, 6 = CLAY/LOAM, 7 = OTHER. Samples with Matrix Code 7 are not predominantly a SAND/LOAM/CLAY mix and are not covered by our BSEN 17025 or MCERTS accreditations. Secondary Matrix Codes: A = contains stones, B = contains construction rubble, C = contains visible hydrocarbons, D = contains glass/metal, E = contains roots/twigs. IS indicates Insufficient sample for analysis. NDP indicates No Determination Possible. NAD indicates No Asbestos Detected. N/A indicates Not Applicable. Superscript # indicates method accredited to ISO 17025. Analytical results reflect the quality of the sample at the time of analysis only. Opinions and interpretations expressed are outside the scope of our accreditation. Please contact us if you need any further information.

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Page 1 of 18

Units 7 & 8 Sandpits Business Park Mottram Road, Hyde, Cheshire, SK14 3AR

FINAL ANALYTICAL TEST REPORT

Envirolab Job Number: 14/06461 Issue Number: 1 Date: 01 December, 2014 Client: RSK Environment Helsby Spring Lodge 172 Chester Road Helsby Cheshire UK WA6 0AR Project Manager: Rachel Hagan/Steven Pettitt Project Name: Mersey Gateway Project Ref: 321315 Order No: N/A Date Samples Received: 20/11/14 Date Instructions Received: 20/11/14 Date Analysis Completed: 01/12/14 Prepared by: Approved by:

Melanie Marshall Iain Haslock Laboratory Coordinator Analytical Consultant

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Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8

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Client Sample No

Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256

Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80

Depth To Bottom

Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A

pH (w)A# 8.14 6.57 11.70 12.40 7.89 7.61 8.01 6.63 pH A-T-031w

Electrical conductivity @ 20degC (w)A# 1090 2740 26100 4190 12900 14300 959 2830 µs/cm A-T-037w

COD (settled)A# 20 7 19000 66 220 150 13 53 mg/l A-T-034w

BOD (settled, 5 day)A 3 3 170 23 2 2 4 8 mg/l A-T-048

Hardness TotalA# 796 1630 17500 1710 2740 6340 469 1690 mg/l Ca

CO3

A-T-049w

Chloride (w)A# 33.59 120.77 33400 151.78 4860 6740 231.77 135.45 mg/l A-T-026w

Nitrite (w)A# 0.26 0.11 19.44 1.04 <0.10 <0.10 <0.10 <0.10 mg/l A-T-026w

Nitrate (w) A# 13.25 5.67 <0.50 4.69 <0.50 <0.50 <0.50 <0.50 mg/l A-T-026w

Sulphate (w)A# 379 1736 1499 713 1785 634 49 1752 mg/l A-T-026w

Cyanide (total) (w)A# <0.005 <0.005 1.139 0.018 <0.005 <0.005 <0.005 0.070 mg/l A-T-042wTCN

Phenols - Total by HPLC (w)A <0.01 <0.01 30.1 0.06 <0.01 0.38 <0.01 <0.01 mg/l A-T-050w

Sulphide (w)A 0.3 1.5 16800 71.2 0.5 <0.1 0.4 0.5 mg/l A-T-S2-w

DOC (w)A# 5.4 3.6 146.3 6.1 10.7 1.6 2.8 8.1 mg/l A-T-032w

Aluminium (dissolved)A 24 3240 162 13 13 12 32 50 µg/l A-T-049w

Arsenic (dissolved)A# 6 6 10400 <2 332 3 11 9800 µg/l A-T-025w

Boron (dissolved)A# 144 1520 <500 <20 668 52 72 <500 µg/l A-T-025w

Barium (dissolved)A# 163 489 1580 75 97 73 336 <50 µg/l A-T-025w

Beryllium (dissolved)A# <2 <5 <50 <2 <2 <2 <2 <50 µg/l A-T-025w

Cadmium (dissolved)A# <2 <5 <50 <2 <2 <2 <2 <50 µg/l A-T-025w

Calcium (dissolved)A# 267 600 6980 684 600 1430 105 637 mg/l A-T-049w

Copper (dissolved)A# 3 11 <50 <2 <2 <2 <2 <50 µg/l A-T-025w

Chromium (dissolved)A# 6 10 <50 10 10 11 3 <50 µg/l A-T-025w

Chromium (hexavalent) (w)A# <0.05 <1.00 <0.05 <0.05 <0.05 <5.00 <0.05 <1.00 mg/l A-T-040w

Chromium (trivalent) (w) <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 mg/l Calc

Iron (dissolved)A# 2600 317 <500 28 8530 165 591 56800 µg/l A-T-025w

Lead (dissolved)A# <2 <5 <50 <2 <2 <2 <2 <50 µg/l A-T-025w

Manganese (dissolved)A# 1660 1500 <50 <2 2230 613 115 2170 µg/l A-T-025w

Magnesium (dissolved)A# 31 32 13 1 302 674 50 24 mg/l A-T-049w

Mercury (dissolved)A# <0.2 <0.5 <5.0 <0.2 <0.2 <0.2 <0.2 <5.0 µg/l A-T-025w

Nickel (dissolved)A# 16 142 167 2 3 8 <2 <50 µg/l A-T-025w

Potassium (dissolved)A# 22 23 44 18 61 20 4 10 mg/l A-T-049w

Selenium (dissolved)A# 2 <5 65 <2 <2 <2 <2 <50 µg/l A-T-025w

Sodium (dissolved)A# 96 124 484 91 2040 984 49 82 mg/l A-T-049w

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Page 3 of 18

Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8

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Client Sample No

Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256

Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80

Depth To Bottom

Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A

Strontium (dissolved)A 676 1490 7580 1170 4800 3460 475 527 µg/l A-T-025w

Vanadium (dissolved)A# <2 102 <50 3 5 5 <2 <50 µg/l A-T-025w

Zinc (dissolved)A# 12 489 <50 <2 4 12 <2 740 µg/l A-T-025w

Page 166: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

Page 4 of 18

Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8

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Client Sample No

Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256

Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80

Depth To Bottom

Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A

TPH CWG

Ali >C5-C6 (w)A# <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-022w

Ali >C6-C8 (w)A# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-022w

Ali >C8-C10 (w)A# <1 <1 <15 <1 <1 <1 <1 164 µg/l A-T-022w

Ali >C10-C12 (w)A# <5 <5 <5 <5 <5 <5 <5 22 µg/l A-T-023w

Ali >C12-C16 (w)A# <5 <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w

Ali >C16-C21 (w)A# <5 <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w

Ali >C21-C35 (w)A# <5 <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w

Total Aliphatics (w)A <5 <5 23 <5 <5 <5 <5 186 µg/l A-T-022+23w

Aro >C5-C7 (w)A# <1 <1 <1 <1 <1 <1 <1 11 µg/l A-T-022w

Aro >C7-C8 (w)A# <1 <1 <1 <1 <1 <1 <1 116 µg/l A-T-022w

Aro >C8-C9 (w)A# <1 <1 <5 <1 <1 <1 <1 30 µg/l A-T-022w

Aro >C9-C10 (w)A# <1 <1 <5 <1 <1 <1 <1 4 µg/l A-T-022w

Aro >C10-C12 (w)A# <5 <5 <5 <5 <5 <5 <5 360 µg/l A-T-023w

Aro >C12-C16 (w)A# <5 <5 <5 <5 <5 <5 <5 26 µg/l A-T-023w

Aro >C16-C21 (w)A# <5 <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w

Aro >C21-C35 (w)A# <5 <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w

Total Aromatics (w)A <5 <5 8 <5 <5 <5 <5 546 µg/l A-T-022+23w

TPH (Ali & Aro) (w)A <5 <5 31 <5 <5 <5 <5 732 µg/l A-T-022+23w

BTEX - Benzene (w)A# <1 <1 <1 <1 <1 <1 <1 11 µg/l A-T-022w

BTEX - Toluene (w)A# <1 <1 <1 <1 <1 <1 <1 116 µg/l A-T-022w

BTEX - Ethyl Benzene (w)A# <1 <1 <1 <1 <1 <1 <1 3 µg/l A-T-022w

BTEX - m & p Xylene (w)A# <1 <1 <5 <1 <1 <1 <1 7 µg/l A-T-022w

BTEX - o Xylene (w)A# <1 <1 <1 <1 <1 <1 <1 13 µg/l A-T-022w

MTBE (w)A# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-022w

Page 167: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

Page 5 of 18

Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8

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Client Sample No

Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256

Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80

Depth To Bottom

Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A

PAH 16MS (w)

Acenaphthene (w)A# <0.01 <0.01 0.02 0.02 <0.01 <0.01 <0.01 0.06 µg/l A-T-019w

Acenaphthylene (w)A# <0.01 <0.01 <0.01 0.02 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Anthracene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(a)anthracene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(a)pyrene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(b)fluoranthene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(ghi)perylene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(k)fluoranthene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Chrysene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Dibenzo(ah)anthracene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Fluoranthene (w)A# <0.01 <0.01 0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Fluorene (w)A# <0.01 <0.01 0.02 0.03 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Indeno(123-cd)pyrene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Naphthalene (w)A# <0.01 <0.01 0.01 0.38 <0.01 <0.01 <0.01 32.90 µg/l A-T-019w

Phenanthrene (w)A# <0.01 <0.01 0.04 0.02 <0.01 <0.01 <0.01 0.01 µg/l A-T-019w

Pyrene (w)A# <0.01 <0.01 0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

PAH (total 16) (w)A# <0.01 <0.01 0.11 0.47 <0.01 <0.01 <0.01 32.97 µg/l A-T-019w

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Page 6 of 18

Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8

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Client Sample No

Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256

Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80

Depth To Bottom

Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A

SVOC (w)

2,4,5-TrichlorophenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

2,4,6-TrichlorophenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

2,4-DichlorophenolA <1 <1 <10 <1 <1 <1 <1 3 µg/l A-T-052w

2,4-DimethylphenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

2,4-DinitrotolueneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

2,6-DinitrotolueneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

2-ChloronaphthaleneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

2-ChlorophenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

2-MethylnaphthaleneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

2-MethylphenolA <1 <1 <10 7 <1 <1 <1 2 µg/l A-T-052w

2-NitrophenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

4-Bromophenyl phenyl etherA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

4-Chloro-3-methylphenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Bis(2-chloroisopropyl)etherA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

2,4-DinitrophenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

4,6-Dinitro-2-methylphenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

4-MethylphenolA <1 <1 <10 1 <1 <1 <1 4 µg/l A-T-052w

4-NitrophenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Acenaphthene A <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

AcenaphthyleneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Anthracene A <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Bis(2-chloroethyl)etherA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Bis(2-chloroethoxy)methaneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Bis(2-ethylhexyl)phthalateA <2 <2 <20 <2 <2 <2 <2 <2 µg/l A-T-052w

Benzo(a)anthraceneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Butylbenzyl phthalate A <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Benzo(b)fluorantheneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Benzo(k)fluorantheneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Benzo(a)pyrene A <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Benzo(ghi)peryleneA <1 <1 <10 <1 <1 <1 4 <1 µg/l A-T-052w

CarbazoleA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

ChryseneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Page 169: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

Page 7 of 18

Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8

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Client Sample No

Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256

Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80

Depth To Bottom

Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A

DibenzofuranA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

n-DibutylphthalateA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

n-DioctylphthalateA <5 <5 <50 <5 <5 <5 <5 <5 µg/l A-T-052w

n-Nitroso-n-dipropylamineA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Diethyl phthalateA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Dimethyl phthalateA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Dibenzo(ah)anthraceneA <1 <1 <10 <1 <1 <1 1 <1 µg/l A-T-052w

Fluorene A <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

FluorantheneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

HexachlorobenzeneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

PentachlorophenolA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Phenol A <1 <1 222 3 <1 <1 <1 5 µg/l A-T-052w

HexachloroethaneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

NitrobenzeneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Naphthalene A <1 <1 <10 <1 <1 <1 <1 21 µg/l A-T-052w

IsophoroneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

HexachlorocyclopentadieneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Phenanthrene A <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Pyrene A <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

Indeno(1,2,3-cd)pyreneA <1 <1 <10 <1 <1 <1 3 <1 µg/l A-T-052w

PeryleneA <1 <1 <10 <1 <1 <1 <1 <1 µg/l A-T-052w

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Page 8 of 18

Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8

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Client Sample No

Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256

Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80

Depth To Bottom

Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A

VOC (w)

DichlorodifluoromethaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

ChloromethaneA# <1 <1 <1 <1 <1 <1 <1 3 µg/l A-T-006w

Vinyl ChlorideA# <1 <1 <1 <1 <1 <1 <1 111 µg/l A-T-006w

BromomethaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

ChloroethaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

TrichlorofluoromethaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

trans 1,2-DichloroetheneA# <1 <1 <1 <1 <1 <1 <1 56 µg/l A-T-006w

DichloromethaneA <5 <5 <5 <5 <5 <5 <5 <5 µg/l A-T-006w

Carbon DisulphideA# <1 <1 <1 <1 1 <1 <1 4 µg/l A-T-006w

1,1-DichloroetheneA# 2 <1 <1 <1 <1 <1 <1 2373 µg/l A-T-006w

1,1-DichloroethaneA# <1 <1 <1 <1 <1 <1 <1 434 µg/l A-T-006w

cis 1,2-DichloroetheneA# <1 <1 <1 <1 <1 <1 <1 176 µg/l A-T-006w

BromochloromethaneA# <5 <5 <5 <5 <5 <5 <5 <5 µg/l A-T-006w

ChloroformA# <25 <25 <25 <25 423 <25 <25 53 µg/l A-T-006w

2,2-DichloropropaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

1,2-DichloroethaneA# <2 <2 <2 <2 <2 <2 <2 142 µg/l A-T-006w

1,1,1-TrichloroethaneA# <1 <1 <1 <1 <1 <1 <1 156 µg/l A-T-006w

1,1-DichloropropeneA# <1 <1 <1 <1 <1 <1 <1 28 µg/l A-T-006w

Benzene A# <1 <1 <1 <1 <1 <1 <1 13 µg/l A-T-006w

Carbon TetrachlorideA# <1 <1 <1 <1 55 <1 <1 <1 µg/l A-T-006w

DibromomethaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

1,2-DichloropropaneA# <1 <1 <1 <1 <1 <1 <1 5 µg/l A-T-006w

BromodichloromethaneA# <10 <10 <10 <10 <10 <10 <10 <10 µg/l A-T-006w

TrichloroetheneA# <1 <1 <1 <1 <1 <1 <1 1455 µg/l A-T-006w

cis 1,3-DichloropropeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

trans 1,3-DichloropropeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

1,1,2-TrichloroethaneA# <1 <1 <1 <1 <1 <1 <1 3671 µg/l A-T-006w

Toluene A# <1 <1 <1 <1 <1 <1 <1 132 µg/l A-T-006w

1,3-DichloropropaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

DibromochloromethaneA# <3 <3 <3 <3 <3 <3 <3 <3 µg/l A-T-006w

1,2-DibromoethaneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

TetrachloroetheneA# <1 <1 <1 <1 <1 <1 <1 176 µg/l A-T-006w

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Page 9 of 18

Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/1 14/06461/2 14/06461/3 14/06461/4 14/06461/5 14/06461/6 14/06461/7 14/06461/8

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Client Sample No

Client Sample ID BH159A BH59 BH60 BH501 BHXX1 BHXX2 BH152 BH256

Depth to Top 1.70 2.20 2.50 17.00 19.00 52.80 49.70 6.80

Depth To Bottom

Date Sampled 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14 17-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A N/A

1,1,1,2-TetrachloroethaneA <1 <1 <1 <1 <1 <1 <1 89 µg/l A-T-006w

ChlorobenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

EthylbenzeneA# <1 <1 <1 <1 <1 <1 <1 3 µg/l A-T-006w

m & p XyleneA# <1 <1 <1 <1 <1 <1 <1 7 µg/l A-T-006w

BromoformA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

StyreneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

1,1,2,2-TetrachloroethaneA <1 <1 <1 <1 <1 <1 <1 2932 µg/l A-T-006w

o-XyleneA# <1 <1 <1 <1 <1 <1 <1 11 µg/l A-T-006w

1,2,3-TrichloropropaneA# <1 <1 <1 <1 <1 <1 <1 415 µg/l A-T-006w

IsopropylbenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

BromobenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

2-ChlorotolueneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

n-propylbenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

4-ChlorotolueneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

1,2,4-TrimethylbenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

4-IsopropyltolueneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

1,3,5-TrimethylbenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

1,2-DichlorobenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

1,4-DichlorobenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

sec-ButylbenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

tert-ButylbenzeneA# <2 <2 <2 <2 <2 <2 <2 9 µg/l A-T-006w

1,3-DichlorobenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

n-butylbenzeneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

1,2-Dibromo-3-chloropropaneA# <2 <2 <2 <2 <2 <2 <2 <2 µg/l A-T-006w

1,2,4-TrichlorobenzeneA# <3 <3 <3 <3 <3 <3 <3 <3 µg/l A-T-006w

1,2,3-TrichlorobenzeneA# <3 <3 <3 <3 <3 <3 <3 <3 µg/l A-T-006w

HexachlorobutadieneA# <1 <1 <1 <1 <1 <1 <1 <1 µg/l A-T-006w

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Page 10 of 18

Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15

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Client Sample No

Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23

Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00

Depth To Bottom

Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A

pH (w)A# 7.66 7.98 7.47 9.11 7.74 7.67 - pH A-T-031w

Electrical conductivity @ 20degC (w)A# 11000 7100 15700 24600 17500 12600 - µs/cm A-T-037w

COD (settled)A# 150 55 170 210 220 110 - mg/l A-T-034w

BOD (settled, 5 day)A 5 1 2 14 4 <1 - mg/l A-T-048

Hardness TotalA# 1807 1680 3120 772 4930 3720 - mg/l Ca

CO3

A-T-049w

Chloride (w)A# 869 2640 6590 3870 7880 4930 - mg/l A-T-026w

Nitrite (w)A# <0.10 <0.10 <0.10 0.11 0.12 <0.10 - mg/l A-T-026w

Nitrate (w) A# <0.50 19.00 <0.50 <0.50 <0.50 <0.50 - mg/l A-T-026w

Sulphate (w)A# 5820 392 981 10600 1073 1456 - mg/l A-T-026w

Cyanide (total) (w)A# <0.005 <0.005 <0.005 0.307 <0.005 <0.005 - mg/l A-T-042wTCN

Phenols - Total by HPLC (w)A <0.01 0.11 0.47 0.74 0.36 0.44 - mg/l A-T-050w

Sulphide (w)A <0.1 0.3 0.1 <0.1 <0.1 <0.1 - mg/l A-T-S2-w

DOC (w)A# 13.7 2.2 5.3 35.5 4.5 3.4 - mg/l A-T-032w

Aluminium (dissolved)A 32 21 18 155 21 29 - µg/l A-T-049w

Arsenic (dissolved)A# 7480 3 9 57 4 3 - µg/l A-T-025w

Boron (dissolved)A# 1650 185 934 11700 <20 22 - µg/l A-T-025w

Barium (dissolved)A# <50 95 111 <50 104 46 - µg/l A-T-025w

Beryllium (dissolved)A# <50 <2 <2 <50 <2 <2 - µg/l A-T-025w

Cadmium (dissolved)A# <50 <2 <2 <50 <2 <2 - µg/l A-T-025w

Calcium (dissolved)A# 552 395 652 284 1230 867 - mg/l A-T-049w

Copper (dissolved)A# <50 <2 <2 <50 <2 <2 - µg/l A-T-025w

Chromium (dissolved)A# <50 5 9 <50 7 4 - µg/l A-T-025w

Chromium (hexavalent) (w)A# <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 - mg/l A-T-040w

Chromium (trivalent) (w) <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 - mg/l Calc

Iron (dissolved)A# 14700 204 799 <500 63 1310 - µg/l A-T-025w

Lead (dissolved)A# <50 <2 <2 <50 <2 <2 - µg/l A-T-025w

Manganese (dissolved)A# 3760 1150 1390 <50 220 801 - µg/l A-T-025w

Magnesium (dissolved)A# 104 168 361 15 451 377 - mg/l A-T-049w

Mercury (dissolved)A# <5.0 <0.2 <0.2 <5.0 <0.2 <0.2 - µg/l A-T-025w

Nickel (dissolved)A# <50 16 13 <50 10 20 - µg/l A-T-025w

Potassium (dissolved)A# 134 25 29 31 21 20 - mg/l A-T-049w

Selenium (dissolved)A# <50 <2 <2 <50 <2 <2 - µg/l A-T-025w

Sodium (dissolved)A# 888 1010 2800 6050 2920 2070 - mg/l A-T-049w

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Page 11 of 18

Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15

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Client Sample No

Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23

Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00

Depth To Bottom

Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A

Strontium (dissolved)A 1290 1590 3170 1170 2500 2450 - µg/l A-T-025w

Vanadium (dissolved)A# <50 3 5 <50 5 2 - µg/l A-T-025w

Zinc (dissolved)A# <50 15 3 <50 5 7 - µg/l A-T-025w

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Page 12 of 18

Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15

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Client Sample No

Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23

Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00

Depth To Bottom

Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A

TPH CWG

Ali >C5-C6 (w)A# <1 <1 <1 <1 <1 <1 - µg/l A-T-022w

Ali >C6-C8 (w)A# <1 <1 <1 <1 <1 <1 - µg/l A-T-022w

Ali >C8-C10 (w)A# <1 <1 <1 <1 <1 <1 - µg/l A-T-022w

Ali >C10-C12 (w)A# <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w

Ali >C12-C16 (w)A# <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w

Ali >C16-C21 (w)A# <5 <5 <5 <5 <5 <5 19 µg/l A-T-023w

Ali >C21-C35 (w)A# <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w

Total Aliphatics (w)A <5 <5 <5 <5 <5 <5 19 µg/l A-T-022+23w

Aro >C5-C7 (w)A# <1 <1 <1 5 <1 <1 - µg/l A-T-022w

Aro >C7-C8 (w)A# <1 <1 <1 1 <1 <1 - µg/l A-T-022w

Aro >C8-C9 (w)A# <1 <1 <1 4 <1 <1 - µg/l A-T-022w

Aro >C9-C10 (w)A# <1 <1 <1 4 <1 <1 - µg/l A-T-022w

Aro >C10-C12 (w)A# <5 <5 <5 26 <5 <5 <5 µg/l A-T-023w

Aro >C12-C16 (w)A# <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w

Aro >C16-C21 (w)A# <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w

Aro >C21-C35 (w)A# <5 <5 <5 <5 <5 <5 <5 µg/l A-T-023w

Total Aromatics (w)A <5 <5 <5 40 <5 <5 <5 µg/l A-T-022+23w

TPH (Ali & Aro) (w)A <5 <5 <5 40 <5 <5 19 µg/l A-T-022+23w

BTEX - Benzene (w)A# <1 <1 <1 5 <1 <1 - µg/l A-T-022w

BTEX - Toluene (w)A# <1 <1 <1 1 <1 <1 - µg/l A-T-022w

BTEX - Ethyl Benzene (w)A# <1 <1 <1 <1 <1 <1 - µg/l A-T-022w

BTEX - m & p Xylene (w)A# <1 <1 <1 2 <1 <1 - µg/l A-T-022w

BTEX - o Xylene (w)A# <1 <1 <1 1 <1 <1 - µg/l A-T-022w

MTBE (w)A# <1 <1 <1 <1 <1 <1 - µg/l A-T-022w

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Page 13 of 18

Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15

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Client Sample No

Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23

Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00

Depth To Bottom

Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A

PAH 16MS (w)

Acenaphthene (w)A# <0.01 <0.01 <0.01 0.21 <0.01 <0.01 <0.01 µg/l A-T-019w

Acenaphthylene (w)A# <0.01 <0.01 <0.01 0.02 <0.01 <0.01 <0.01 µg/l A-T-019w

Anthracene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(a)anthracene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(a)pyrene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(b)fluoranthene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(ghi)perylene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Benzo(k)fluoranthene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Chrysene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Dibenzo(ah)anthracene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Fluoranthene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Fluorene (w)A# <0.01 <0.01 <0.01 0.07 <0.01 <0.01 <0.01 µg/l A-T-019w

Indeno(123-cd)pyrene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

Naphthalene (w)A# 0.03 <0.01 <0.01 33.73 0.01 <0.01 <0.01 µg/l A-T-019w

Phenanthrene (w)A# <0.01 <0.01 <0.01 0.07 <0.01 <0.01 <0.01 µg/l A-T-019w

Pyrene (w)A# <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 µg/l A-T-019w

PAH (total 16) (w)A# 0.03 <0.01 <0.01 34.10 0.01 <0.01 <0.01 µg/l A-T-019w

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Page 14 of 18

Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15

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Client Sample No

Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23

Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00

Depth To Bottom

Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A

SVOC (w)

2,4,5-TrichlorophenolA <1 <1 <1 5 <1 <1 - µg/l A-T-052w

2,4,6-TrichlorophenolA <1 <1 <1 1 <1 <1 - µg/l A-T-052w

2,4-DichlorophenolA <1 <1 <1 1 <1 <1 - µg/l A-T-052w

2,4-DimethylphenolA <1 <1 <1 7 <1 <1 - µg/l A-T-052w

2,4-DinitrotolueneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

2,6-DinitrotolueneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

2-ChloronaphthaleneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

2-ChlorophenolA <1 <1 <1 3 <1 <1 - µg/l A-T-052w

2-MethylnaphthaleneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

2-MethylphenolA <1 <1 <1 5 <1 <1 - µg/l A-T-052w

2-NitrophenolA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

4-Bromophenyl phenyl etherA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

4-Chloro-3-methylphenolA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Bis(2-chloroisopropyl)etherA <1 5 <1 <1 <1 <1 - µg/l A-T-052w

2,4-DinitrophenolA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

4,6-Dinitro-2-methylphenolA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

4-MethylphenolA <1 <1 <1 43 <1 <1 - µg/l A-T-052w

4-NitrophenolA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Acenaphthene A <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

AcenaphthyleneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Anthracene A <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Bis(2-chloroethyl)etherA <1 8 <1 <1 <1 <1 - µg/l A-T-052w

Bis(2-chloroethoxy)methaneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Bis(2-ethylhexyl)phthalateA <2 <2 <2 <2 <2 <2 - µg/l A-T-052w

Benzo(a)anthraceneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Butylbenzyl phthalate A <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Benzo(b)fluorantheneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Benzo(k)fluorantheneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Benzo(a)pyrene A <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Benzo(ghi)peryleneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

CarbazoleA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

ChryseneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

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Page 15 of 18

Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15

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Client Sample No

Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23

Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00

Depth To Bottom

Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A

DibenzofuranA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

n-DibutylphthalateA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

n-DioctylphthalateA <5 <5 <5 <5 <5 <5 - µg/l A-T-052w

n-Nitroso-n-dipropylamineA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Diethyl phthalateA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Dimethyl phthalateA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Dibenzo(ah)anthraceneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Fluorene A <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

FluorantheneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

HexachlorobenzeneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

PentachlorophenolA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Phenol A <1 <1 <1 87 <1 <1 - µg/l A-T-052w

HexachloroethaneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

NitrobenzeneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Naphthalene A <1 <1 <1 23 <1 <1 - µg/l A-T-052w

IsophoroneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

HexachlorocyclopentadieneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Phenanthrene A <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Pyrene A <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

Indeno(1,2,3-cd)pyreneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

PeryleneA <1 <1 <1 <1 <1 <1 - µg/l A-T-052w

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Page 16 of 18

Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15

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Client Sample No

Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23

Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00

Depth To Bottom

Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A

VOC (w)

DichlorodifluoromethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

ChloromethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

Vinyl ChlorideA# <1 <1 <1 3 <1 <1 - µg/l A-T-006w

BromomethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

ChloroethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

TrichlorofluoromethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

trans 1,2-DichloroetheneA# <1 4 <1 <1 <1 <1 - µg/l A-T-006w

DichloromethaneA <5 <5 <5 <5 <5 <5 - µg/l A-T-006w

Carbon DisulphideA# 793 <1 <1 <1 <1 <1 - µg/l A-T-006w

1,1-DichloroetheneA# 3 1 <1 2 <1 <1 - µg/l A-T-006w

1,1-DichloroethaneA# <1 4 <1 2 <1 <1 - µg/l A-T-006w

cis 1,2-DichloroetheneA# 3 9 <1 9 <1 <1 - µg/l A-T-006w

BromochloromethaneA# <5 <5 <5 <5 <5 <5 - µg/l A-T-006w

ChloroformA# 867 <25 <25 <25 <25 <25 - µg/l A-T-006w

2,2-DichloropropaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

1,2-DichloroethaneA# <2 12 <2 <2 <2 <2 - µg/l A-T-006w

1,1,1-TrichloroethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

1,1-DichloropropeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

Benzene A# <1 <1 <1 7 <1 <1 - µg/l A-T-006w

Carbon TetrachlorideA# 1316 <1 <1 <1 <1 <1 - µg/l A-T-006w

DibromomethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

1,2-DichloropropaneA# <1 4 <1 <1 <1 <1 - µg/l A-T-006w

BromodichloromethaneA# <10 <10 <10 <10 <10 <10 - µg/l A-T-006w

TrichloroetheneA# 2 4 <1 2 <1 <1 - µg/l A-T-006w

cis 1,3-DichloropropeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

trans 1,3-DichloropropeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

1,1,2-TrichloroethaneA# 6 3 <1 <1 <1 <1 - µg/l A-T-006w

Toluene A# <1 <1 <1 2 <1 <1 - µg/l A-T-006w

1,3-DichloropropaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

DibromochloromethaneA# <3 <3 <3 <3 <3 <3 - µg/l A-T-006w

1,2-DibromoethaneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

TetrachloroetheneA# 14 <1 <1 3 <1 <1 - µg/l A-T-006w

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Page 17 of 18

Envirolab Job Number: 14/06461 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06461/9 14/06461/10 14/06461/11 14/06461/12 14/06461/13 14/06461/14 14/06461/15

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Client Sample No

Client Sample ID BHXX3 BH526 BH524 BH529 BH523 BH527 WS23

Depth to Top 10.50 34.50 7.50 12.50 24.00 33.00 2.00

Depth To Bottom

Date Sampled 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14 18-Nov-14

Sample Type Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A N/A N/A N/A N/A N/A

1,1,1,2-TetrachloroethaneA <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

ChlorobenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

EthylbenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

m & p XyleneA# <1 <1 <1 1 <1 <1 - µg/l A-T-006w

BromoformA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

StyreneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

1,1,2,2-TetrachloroethaneA 6 <1 <1 <1 <1 <1 - µg/l A-T-006w

o-XyleneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

1,2,3-TrichloropropaneA# 1 <1 <1 <1 <1 <1 - µg/l A-T-006w

IsopropylbenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

BromobenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

2-ChlorotolueneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

n-propylbenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

4-ChlorotolueneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

1,2,4-TrimethylbenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

4-IsopropyltolueneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

1,3,5-TrimethylbenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

1,2-DichlorobenzeneA# <1 <1 <1 5 <1 <1 - µg/l A-T-006w

1,4-DichlorobenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

sec-ButylbenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

tert-ButylbenzeneA# <2 <2 <2 <2 <2 <2 - µg/l A-T-006w

1,3-DichlorobenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

n-butylbenzeneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

1,2-Dibromo-3-chloropropaneA# <2 <2 <2 <2 <2 <2 - µg/l A-T-006w

1,2,4-TrichlorobenzeneA# <3 <3 <3 9 <3 <3 - µg/l A-T-006w

1,2,3-TrichlorobenzeneA# <3 <3 <3 <3 <3 <3 - µg/l A-T-006w

HexachlorobutadieneA# <1 <1 <1 <1 <1 <1 - µg/l A-T-006w

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REPORT NOTES

Notes - Soil chemical analysis All results are reported as dry weight (<40°C). For samples with Matrix Codes 1 - 6 natural stones >10mm are removed or excluded from the sample prior to analysis and reported results corrected to a whole sample basis. For samples with Matrix Code 7 the whole sample is dried and crushed prior to analysis. Notes - General

This report shall not be reproduced, except in full, without written approval from Envirolab. Subscript "A" indicates analysis performed on the sample as received. "D" indicates analysis performed on the dried sample, crushed to pass a 2mm sieve, unless asbestos is found to be present in which case all analysis is performed on the sample as received. All analysis is performed on the dried and crushed sample for samples with Matrix Code 7 and this supercedes any "A" subscripts. All analysis is performed on the sample as received for soil samples from outside the European Union and this supercedes any "D" subscripts. Superscript "M" indicates method accredited to MCERTS. If results are in italic font they are associated with an AQC failure. These are not accredited and are unreliable. A deviating samples report is appended and will indicate if samples or tests have been found to be deviating. Any test results affected may not be an accurate record of the concentration at the time of sampling and, as a result, may be invalid. TPH analysis of water by method A-T-007 Free and visible oils are excluded from the sample used for analysis so that the reported result represents the dissolved phase only. Asbestos in soil Asbestos in soil analysis is performed on a dried aliquot of the submitted sample and cannot guarantee to identify asbestos if present as discrete fibres/fragments. Stones etc. are not removed from the sample prior to analysis. Quantification of asbestos is a 3 stage process including visual identification, hand picking and weighing and fibre counting by sedimentation/phase contrast optical microscopy if required. If asbestos is identified a being present but is not in a form that is suitable for analysis by hand picking and weighing (normally if the asbestos is present as free fibres) quantification by sedimentation is performed. Where ACMs are found a percentage asbestos is assigned to each with reference to 'HSG264, Asbestos: The survey guide' and the calculated asbestos content is expressed as a percentage of the dried soil sample aliquot used. Predominant Matrix Codes: 1 = SAND, 2 = LOAM, 3 = CLAY, 4 = LOAM/SAND, 5 = SAND/CLAY, 6 = CLAY/LOAM, 7 = OTHER. Samples with Matrix Code 7 are not predominantly a SAND/LOAM/CLAY mix and are not covered by our BSEN 17025 or MCERTS accreditations. Secondary Matrix Codes: A = contains stones, B = contains construction rubble, C = contains visible hydrocarbons, D = contains glass/metal, E = contains roots/twigs. IS indicates Insufficient sample for analysis. NDP indicates No Determination Possible. NAD indicates No Asbestos Detected. N/A indicates Not Applicable. Superscript # indicates method accredited to ISO 17025. Analytical results reflect the quality of the sample at the time of analysis only. Opinions and interpretations expressed are outside the scope of our accreditation. Please contact us if you need any further information.

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Units 7 & 8 Sandpits Business Park Mottram Road, Hyde, Cheshire, SK14 3AR

FINAL ANALYTICAL TEST REPORT

Envirolab Job Number: 14/06203 Issue Number: 1 Date: 17 November, 2014 Client: RSK Environment Helsby Spring Lodge 172 Chester Road Helsby Cheshire UK WA6 0AR Project Manager: Rachel Hagan/Steven Pettitt Project Name: Mersey Gateway Project Ref: 321315 Order No: N/A Date Samples Received: 07/11/14 Date Instructions Received: 10/11/14 Date Analysis Completed: 16/11/14 Prepared by: Approved by:

Melanie Marshall Lianne Bromiley Laboratory Coordinator Senior Client Manager

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Envirolab Job Number: 14/06203 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06203/1 14/06203/2

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Client Sample No

Client Sample ID BHXX1 BHXX2

Depth to Top 19.00 53.00

Depth To Bottom

Date Sampled 07-Nov-14 07-Nov-14

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

pH (w)A# 7.16 7.07 pH A-T-031w

Electrical conductivity @ 20degC (w) A# 11900 14200 µs/cm A-T-037w

COD (settled)A# 220 140 mg/l A-T-034w

BOD (settled, 5 day)A <1 <1 mg/l A-T-048

Hardness TotalA# 3020 6690 mg/l Ca

CO3

A-T-049w

Chloride (w)A# 3530 5930 mg/l A-T-026w

Nitrite (w) A# <0.10 <0.10 mg/l A-T-026w

Nitrate (w) A# <0.50 <0.50 mg/l A-T-026w

Sulphate (w)A# 1998 588 mg/l A-T-026w

Cyanide (total) (w)A# <0.005 <0.005 mg/l A-T-042wTCN

Phenols - Total by HPLC (w)A 0.05 0.17 mg/l A-T-050w

Sulphide (w)A <0.1 <0.1 mg/l A-T-S2-w

DOC (w)A# 4.3 2.1 mg/l A-T-032w

Aluminium (dissolved)A <10 <10 µg/l A-T-049w

Arsenic (dissolved)A# 421 3 µg/l A-T-025w

Boron (dissolved)A# 683 67 µg/l A-T-025w

Barium (dissolved)A# 108 119 µg/l A-T-025w

Beryllium (dissolved)A# <1 <1 µg/l A-T-025w

Cadmium (dissolved)A# <1 <1 µg/l A-T-025w

Calcium (dissolved)A# 724 1510 mg/l A-T-049w

Copper (dissolved)A# <1 <1 µg/l A-T-025w

Chromium (dissolved)A# 3 2 µg/l A-T-025w

Chromium (hexavalent) (w)A# <0.05 <0.05 mg/l A-T-040w

Chromium (trivalent) (w) <0.05 <0.05 mg/l Calc

Iron (dissolved)A# 11060 108 µg/l A-T-025w

Lead (dissolved)A# <1 <1 µg/l A-T-025w

Manganese (dissolved)A# 2806 942 µg/l A-T-025w

Magnesium (dissolved)A# 293 709 mg/l A-T-049w

Mercury (dissolved)A# <0.1 <0.1 µg/l A-T-025w

Nickel (dissolved)A# 4 9 µg/l A-T-025w

Potassium (dissolved)A# 72 19 mg/l A-T-049w

Selenium (dissolved)A# 1 <1 µg/l A-T-025w

Sodium (dissolved)A# 1900 1040 mg/l A-T-049w

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Envirolab Job Number: 14/06203 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06203/1 14/06203/2

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Client Sample No

Client Sample ID BHXX1 BHXX2

Depth to Top 19.00 53.00

Depth To Bottom

Date Sampled 07-Nov-14 07-Nov-14

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

Strontium (dissolved)A 6490 4130 µg/l A-T-025w

Vanadium (dissolved)A# 1 1 µg/l A-T-025w

Zinc (dissolved)A# 3 13 µg/l A-T-025w

TPH CWG

Ali >C5-C6 (w)A# <1 <1 µg/l A-T-022w

Ali >C6-C8 (w)A# <1 <1 µg/l A-T-022w

Ali >C8-C10 (w)A# <1 <1 µg/l A-T-022w

Ali >C10-C12 (w)A# <5 <5 µg/l A-T-023w

Ali >C12-C16 (w)A# <5 <5 µg/l A-T-023w

Ali >C16-C21 (w)A# <5 <5 µg/l A-T-023w

Ali >C21-C35 (w)A# <5 <5 µg/l A-T-023w

Total Aliphatics (w)A <5 <5 µg/l A-T-022+23w

Aro >C5-C7 (w)A# <1 <1 µg/l A-T-022w

Aro >C7-C8 (w)A# <1 <1 µg/l A-T-022w

Aro >C8-C9 (w)A# <1 <1 µg/l A-T-022w

Aro >C9-C10 (w)A# <1 <1 µg/l A-T-022w

Aro >C10-C12 (w)A# <5 <5 µg/l A-T-023w

Aro >C12-C16 (w)A# <5 <5 µg/l A-T-023w

Aro >C16-C21 (w)A# <5 <5 µg/l A-T-023w

Aro >C21-C35 (w)A# <5 <5 µg/l A-T-023w

Total Aromatics (w)A <5 <5 µg/l A-T-022+23w

TPH (Ali & Aro) (w)A <5 <5 µg/l A-T-022+23w

BTEX - Benzene (w)A# <1 <1 µg/l A-T-022w

BTEX - Toluene (w)A# <1 <1 µg/l A-T-022w

BTEX - Ethyl Benzene (w)A# <1 <1 µg/l A-T-022w

BTEX - m & p Xylene (w)A# <1 <1 µg/l A-T-022w

BTEX - o Xylene (w)A# <1 <1 µg/l A-T-022w

MTBE (w)A# <1 <1 µg/l A-T-022w

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Envirolab Job Number: 14/06203 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06203/1 14/06203/2

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Client Sample No

Client Sample ID BHXX1 BHXX2

Depth to Top 19.00 53.00

Depth To Bottom

Date Sampled 07-Nov-14 07-Nov-14

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

PAH 16MS (w)

Acenaphthene (w)A# <0.01 <0.01 µg/l A-T-019w

Acenaphthylene (w)A# <0.01 <0.01 µg/l A-T-019w

Anthracene (w)A# <0.01 <0.01 µg/l A-T-019w

Benzo(a)anthracene (w)A# <0.01 <0.01 µg/l A-T-019w

Benzo(a)pyrene (w)A# <0.01 <0.01 µg/l A-T-019w

Benzo(b)fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w

Benzo(ghi)perylene (w)A# <0.01 <0.01 µg/l A-T-019w

Benzo(k)fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w

Chrysene (w)A# <0.01 <0.01 µg/l A-T-019w

Dibenzo(ah)anthracene (w)A# <0.01 <0.01 µg/l A-T-019w

Fluoranthene (w)A# <0.01 <0.01 µg/l A-T-019w

Fluorene (w)A# <0.01 <0.01 µg/l A-T-019w

Indeno(123-cd)pyrene (w)A# <0.01 <0.01 µg/l A-T-019w

Naphthalene (w)A# <0.01 <0.01 µg/l A-T-019w

Phenanthrene (w)A# <0.01 <0.01 µg/l A-T-019w

Pyrene (w)A# <0.01 <0.01 µg/l A-T-019w

PAH (total 16) (w)A# <0.01 <0.01 µg/l A-T-019w

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Envirolab Job Number: 14/06203 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06203/1 14/06203/2

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Client Sample No

Client Sample ID BHXX1 BHXX2

Depth to Top 19.00 53.00

Depth To Bottom

Date Sampled 07-Nov-14 07-Nov-14

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

SVOC (w)

1,2,4-Trichlorobenzene SVOCA <1 <1 µg/l A-T-052w

1,2-Dichlorobenzene SVOCA <1 <1 µg/l A-T-052w

1,3-Dichlorobenzene SVOCA <1 <1 µg/l A-T-052w

1,4-Dichlorobenzene SVOCA <1 <1 µg/l A-T-052w

2,4,5-TrichlorophenolA <1 <1 µg/l A-T-052w

2,4,6-TrichlorophenolA <1 <1 µg/l A-T-052w

2,4-DichlorophenolA <1 <1 µg/l A-T-052w

2,4-DimethylphenolA <1 <1 µg/l A-T-052w

2,4-DinitrotolueneA <1 <1 µg/l A-T-052w

2,6-DinitrotolueneA <1 <1 µg/l A-T-052w

2-ChloronaphthaleneA <1 <1 µg/l A-T-052w

2-ChlorophenolA <1 <1 µg/l A-T-052w

2-MethylnaphthaleneA <1 <1 µg/l A-T-052w

2-MethylphenolA <1 <1 µg/l A-T-052w

2-NitrophenolA <1 <1 µg/l A-T-052w

4-Bromophenyl phenyl etherA <1 <1 µg/l A-T-052w

4-Chloro-3-methylphenolA <1 <1 µg/l A-T-052w

Bis(2-chloroisopropyl)etherA <1 <1 µg/l A-T-052w

2,4-DinitrophenolA <1 <1 µg/l A-T-052w

4,6-Dinitro-2-methylphenolA <1 <1 µg/l A-T-052w

4-MethylphenolA <1 <1 µg/l A-T-052w

4-NitrophenolA <1 <1 µg/l A-T-052w

Acenaphthene SVOCA <1 <1 µg/l A-T-052w

Acenaphthylene SVOCA <1 <1 µg/l A-T-052w

Anthracene SVOCA <1 <1 µg/l A-T-052w

Bis(2-chloroethyl)etherA <1 <1 µg/l A-T-052w

Bis(2-chloroethoxy)methaneA <1 <1 µg/l A-T-052w

Bis(2-ethylhexyl)phthalateA <2 <2 µg/l A-T-052w

Benzo(a)anthracene SVOCA <1 <1 µg/l A-T-052w

Butylbenzyl phthalate SVOCA <1 <1 µg/l A-T-052w

Benzo(b)fluoranthene SVOCA <1 <1 µg/l A-T-052w

Benzo(k)fluoranthene SVOCA <1 <1 µg/l A-T-052w

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Envirolab Job Number: 14/06203 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06203/1 14/06203/2

U

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Client Sample No

Client Sample ID BHXX1 BHXX2

Depth to Top 19.00 53.00

Depth To Bottom

Date Sampled 07-Nov-14 07-Nov-14

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

Benzo(a)pyrene SVOCA <1 <1 µg/l A-T-052w

Benzo(ghi)perylene SVOCA <1 <1 µg/l A-T-052w

CarbazoleA <1 <1 µg/l A-T-052w

Chrysene SVOCA <1 <1 µg/l A-T-052w

DibenzofuranA <1 <1 µg/l A-T-052w

n-DibutylphthalateA <1 <1 µg/l A-T-052w

n-DioctylphthalateA 17 <5 µg/l A-T-052w

n-Nitroso-n-dipropylamineA <1 <1 µg/l A-T-052w

Diethyl phthalateA <1 <1 µg/l A-T-052w

Dimethyl phthalateA <1 <1 µg/l A-T-052w

Dibenzo(ah)anthracene SVOCA <1 <1 µg/l A-T-052w

Fluorene SVOCA <1 <1 µg/l A-T-052w

Fluoranthene SVOCA <1 <1 µg/l A-T-052w

Hexachlorobutadiene SVOCA <1 <1 µg/l A-T-052w

HexachlorobenzeneA <1 <1 µg/l A-T-052w

PentachlorophenolA <1 <1 µg/l A-T-052w

Phenol SVOCA <1 <1 µg/l A-T-052w

HexachloroethaneA <1 <1 µg/l A-T-052w

NitrobenzeneA <1 <1 µg/l A-T-052w

Naphthalene SVOCA <1 <1 µg/l A-T-052w

IsophoroneA <1 <1 µg/l A-T-052w

HexachlorocyclopentadieneA <1 <1 µg/l A-T-052w

Phenanthrene SVOCA <1 <1 µg/l A-T-052w

Pyrene SVOCA <1 <1 µg/l A-T-052w

Indeno(1,2,3-cd)pyrene SVOCA <1 <1 µg/l A-T-052w

PeryleneA <1 <1 µg/l A-T-052w

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Envirolab Job Number: 14/06203 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06203/1 14/06203/2

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Client Sample No

Client Sample ID BHXX1 BHXX2

Depth to Top 19.00 53.00

Depth To Bottom

Date Sampled 07-Nov-14 07-Nov-14

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

VOC (w)

DichlorodifluoromethaneA# <1 <1 µg/l A-T-006w

ChloromethaneA# <1 <1 µg/l A-T-006w

Vinyl ChlorideA# <1 <1 µg/l A-T-006w

BromomethaneA# <1 <1 µg/l A-T-006w

ChloroethaneA# <1 <1 µg/l A-T-006w

TrichlorofluoromethaneA# <1 <1 µg/l A-T-006w

trans 1,2-DichloroetheneA# <1 <1 µg/l A-T-006w

Dichloromethane VOCA <5 <5 µg/l A-T-006w

Carbon DisulphideA# 6 <1 µg/l A-T-006w

1,1-DichloroetheneA# <1 <1 µg/l A-T-006w

1,1-DichloroethaneA# <1 <1 µg/l A-T-006w

cis 1,2-DichloroetheneA# <1 <1 µg/l A-T-006w

BromochloromethaneA# <5 <5 µg/l A-T-006w

ChloroformA# 838 <25 µg/l A-T-006w

2,2-DichloropropaneA# <1 <1 µg/l A-T-006w

1,2-DichloroethaneA# <2 <2 µg/l A-T-006w

1,1,1-TrichloroethaneA# <1 <1 µg/l A-T-006w

1,1-DichloropropeneA# <1 <1 µg/l A-T-006w

Benzene VOCA# <1 <1 µg/l A-T-006w

Carbon TetrachlorideA# 71 <1 µg/l A-T-006w

DibromomethaneA# <1 <1 µg/l A-T-006w

1,2-DichloropropaneA# <1 <1 µg/l A-T-006w

BromodichloromethaneA# <10 <10 µg/l A-T-006w

TrichloroetheneA# <1 <1 µg/l A-T-006w

cis 1,3-DichloropropeneA# <1 <1 µg/l A-T-006w

trans 1,3-DichloropropeneA# <1 <1 µg/l A-T-006w

1,1,2-TrichloroethaneA# <1 <1 µg/l A-T-006w

Toluene VOCA# <1 <1 µg/l A-T-006w

1,3-DichloropropaneA# <1 <1 µg/l A-T-006w

DibromochloromethaneA# <3 <3 µg/l A-T-006w

1,2-DibromoethaneA# <1 <1 µg/l A-T-006w

TetrachloroetheneA# <1 <1 µg/l A-T-006w

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Page 8 of 9

Envirolab Job Number: 14/06203 Client Project Name: Mersey Gateway

Client Project Ref: 321315

Lab Sample ID 14/06203/1 14/06203/2

U

nit

s

M

eth

od

ref

Client Sample No

Client Sample ID BHXX1 BHXX2

Depth to Top 19.00 53.00

Depth To Bottom

Date Sampled 07-Nov-14 07-Nov-14

Sample Type Water - EW Water - EW

MCERTS Sample Matrix Code N/A N/A

1,1,1,2-TetrachloroethaneA <1 <1 µg/l A-T-006w

ChlorobenzeneA# <1 <1 µg/l A-T-006w

EthylbenzeneA# <1 <1 µg/l A-T-006w

m & p XyleneA# <1 <1 µg/l A-T-006w

BromoformA# <1 <1 µg/l A-T-006w

StyreneA# <1 <1 µg/l A-T-006w

1,1,2,2-TetrachloroethaneA <1 <1 µg/l A-T-006w

o-XyleneA# <1 <1 µg/l A-T-006w

1,2,3-TrichloropropaneA# <1 <1 µg/l A-T-006w

IsopropylbenzeneA# <1 <1 µg/l A-T-006w

BromobenzeneA# <1 <1 µg/l A-T-006w

2-ChlorotolueneA# <1 <1 µg/l A-T-006w

n-propylbenzeneA# <1 <1 µg/l A-T-006w

4-ChlorotolueneA# <1 <1 µg/l A-T-006w

1,2,4-TrimethylbenzeneA# <1 <1 µg/l A-T-006w

4-IsopropyltolueneA# <1 <1 µg/l A-T-006w

1,3,5-TrimethylbenzeneA# <1 <1 µg/l A-T-006w

1,2-DichlorobenzeneA# <1 <1 µg/l A-T-006w

1,4-DichlorobenzeneA# <1 <1 µg/l A-T-006w

sec-ButylbenzeneA# <1 <1 µg/l A-T-006w

tert-ButylbenzeneA# <2 <2 µg/l A-T-006w

1,3-DichlorobenzeneA# <1 <1 µg/l A-T-006w

n-butylbenzeneA# <1 <1 µg/l A-T-006w

1,2-Dibromo-3-chloropropaneA# <2 <2 µg/l A-T-006w

1,2,4-TrichlorobenzeneA# <3 <3 µg/l A-T-006w

1,2,3-TrichlorobenzeneA# <3 <3 µg/l A-T-006w

HexachlorobutadieneA# <1 <1 µg/l A-T-006w

Page 189: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

Page 9 of 9

REPORT NOTES

Notes - Soil chemical analysis All results are reported as dry weight (<40°C). For samples with Matrix Codes 1 - 6 natural stones >10mm are removed or excluded from the sample prior to analysis and reported results corrected to a whole sample basis. For samples with Matrix Code 7 the whole sample is dried and crushed prior to analysis. Notes - General

This report shall not be reproduced, except in full, without written approval from Envirolab. Subscript "A" indicates analysis performed on the sample as received. "D" indicates analysis performed on the dried sample, crushed to pass a 2mm sieve, unless asbestos is found to be present in which case all analysis is performed on the sample as received. All analysis is performed on the dried and crushed sample for samples with Matrix Code 7 and this supercedes any "A" subscripts. All analysis is performed on the sample as received for soil samples from outside the European Union and this supercedes any "D" subscripts. Superscript "M" indicates method accredited to MCERTS. If results are in italic font they are associated with an AQC failure. These are not accredited and are unreliable. A deviating samples report is appended and will indicate if samples or tests have been found to be deviating. Any test results affected may not be an accurate record of the concentration at the time of sampling and, as a result, may be invalid. TPH analysis of water by method A-T-007 Free and visible oils are excluded from the sample used for analysis so that the reported result represents the dissolved phase only. Asbestos in soil Asbestos in soil analysis is performed on a dried aliquot of the submitted sample and cannot guarantee to identify asbestos if present as discrete fibres/fragments. Stones etc. are not removed from the sample prior to analysis. Quantification of asbestos is a 3 stage process including visual identification, hand picking and weighing and fibre counting by sedimentation/phase contrast optical microscopy if required. If asbestos is identified a being present but is not in a form that is suitable for analysis by hand picking and weighing (normally if the asbestos is present as free fibres) quantification by sedimentation is performed. Where ACMs are found a percentage asbestos is assigned to each with reference to 'HSG264, Asbestos: The survey guide' and the calculated asbestos content is expressed as a percentage of the dried soil sample aliquot used. Predominant Matrix Codes: 1 = SAND, 2 = LOAM, 3 = CLAY, 4 = LOAM/SAND, 5 = SAND/CLAY, 6 = CLAY/LOAM, 7 = OTHER. Samples with Matrix Code 7 are not predominantly a SAND/LOAM/CLAY mix and are not covered by our BSEN 17025 or MCERTS accreditations. Secondary Matrix Codes: A = contains stones, B = contains construction rubble, C = contains visible hydrocarbons, D = contains glass/metal, E = contains roots/twigs. IS indicates Insufficient sample for analysis. NDP indicates No Determination Possible. NAD indicates No Asbestos Detected. N/A indicates Not Applicable. Superscript # indicates method accredited to ISO 17025. Analytical results reflect the quality of the sample at the time of analysis only. Opinions and interpretations expressed are outside the scope of our accreditation. Please contact us if you need any further information.

Page 190: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

MERSEY GATEWAY BRIDGE

MER-DJV-REP-ENV-03-333030 E 17 MARCH 2016

APPENDIX E – DEVELOPMENT TIMELINE

Page 191: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

Time Line of development events at P1

Start Finish Event/Activity

24.06.2014 17.10.2014 Temporary Crossing of St Helens Canal

26.11.2014 01.12.2014 Guide wall for CFA

21.02.2015 21.02.2015 Intersite Moving from P0 to P1 (CFA)

22.01.2015 03.02.2015 Install Cofferdams (CFA Piling) (See Separate Sheet)

20.02.2015 10.03.2015 Bored Piling:

2015.02.21 2015.02.21 Pile 4

2015.02.23 2015.02.23 Pile 2

2015.02.26 2015.02.26 Pile 6

2015.03.03 2015.03.03 Pile 1

2015.03.05 2015.03.05 Pile 3

2015.03.10 2015.03.10 Pile 5

05.05.2015 30.06.2015 Excavation / Bracing / Pile Cropping

16.07.2015 16.07.2015 BHXX3 destroyed

27.07.2015 28.07.2015 Sonic Testing

29.07.2015 04.09.2015 Pile Cap

05.09.2015 09.09.2015 Pier shaft 1st Phase

09.09.2015 27.09.2015 MSS Support - Cofferdam (CFA)

15.09.2015 19.09.2015 Pier Head 1st

17.09.2015 27.09.2015 MSS Support - Bored Piling

20.09.2015 10.12.2015 Pier Head 2nd and Bearings

12.10.2015 23.10.2015 Waterproofing & Backfilling

02.02.2016 21.02.2016 MSS Construction: Span P0 to P1

22.02.2016 09.03.2016 MSS Construction: Span P1 to P2

Page 192: MERSEY GATEWAY BRIDGE PROJECT€¦ · MER-DJV-REP-ENV-03-333030 17 MARCH 2016 BHXX4 and BHXX5 were completed in April 2015. The borehole location plan centred on the P1 structure

MERSEY GATEWAY

BACHY SOLETANCHE

P1 Records

Move and SetupReinforcement for

cast-in-place piles Percentage Complete Comments

Toe Level Cut Off Level Length (m)

1 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

2 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

3 02/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

4 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

5 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

6 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

7 02/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

8 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

9 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

10 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

11 03/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

12 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

13 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

14 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

15 03/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

16 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

17 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

18 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

19 03/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

20 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

21 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

22 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

23 03/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

24 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

25 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

26 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

27 03/02/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

28 30/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

29 29/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

30 27/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

31 03/02/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

32 30/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

33 29/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

34 27/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

35 03/02/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

36 30/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

37 27/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

38 26/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

39 03/02/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

40 29/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

41 27/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

42 26/01/2015 1 -2.7 8.45 11.15 1053.000 100% TYPE B

43 30/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

44 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

45 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

46 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

47 02/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

48 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

49 27/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

50 26/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

51 02/02/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

52 29/01/2015 1 -2.7 8.45 11.15 1064.000 100% TYPE A

52 312.2 29616.000 5200% 0

Move and SetupReinforcement for

cast-in-place piles Percentage Complete Comments

Toe Level Cut Off Level Length (m)

1 24/01/2015 1 -2.7 8.45 11.15 100%

2 23/01/2015 1 -2.7 8.45 11.15 100%

3 22/01/2015 1 -2.7 8.45 11.15 100%

4 25/01/2015 1 -2.7 8.45 11.15 100%

5 24/01/2015 1 -2.7 8.45 11.15 100%

6 23/01/2015 1 -2.7 8.45 11.15 100%

7 22/01/2015 1 -2.7 8.45 11.15 100%

8 25/01/2015 1 -2.7 8.45 11.15 100%

9 24/01/2015 1 -2.7 8.45 11.15 100%

10 23/01/2015 1 -2.7 8.45 11.15 100%

11 22/01/2015 1 -2.7 8.45 11.15 100%

12 25/01/2015 1 -2.7 8.45 11.15 100%

13 24/01/2015 1 -2.7 8.45 11.15 100%

14 23/01/2015 1 -2.7 8.45 11.15 100%

15 22/01/2015 1 -2.7 8.45 11.15 100%

16 25/01/2015 1 -2.7 8.45 11.15 100%

17 24/01/2015 1 -2.7 8.45 11.15 100%

18 23/01/2015 1 -2.7 8.45 11.15 100%

19 22/01/2015 1 -2.7 8.45 11.15 100%

20 25/01/2015 1 -2.7 8.45 11.15 100%

21 24/01/2015 1 -2.7 8.45 11.15 100%

22 23/01/2015 1 -2.7 8.45 11.15 100%

23 22/01/2015 1 -2.7 8.45 11.15 100%

24 25/01/2015 1 -2.7 8.45 11.15 100%

25 24/01/2015 1 -2.7 8.45 11.15 100%

26 23/01/2015 1 -2.7 8.45 11.15 100%

27 22/01/2015 1 -2.7 8.45 11.15 100%

28 25/01/2015 1 -2.7 8.45 11.15 100%

29 24/01/2015 1 -2.7 8.45 11.15 100%

30 23/01/2015 1 -2.7 8.45 11.15 100%

31 22/01/2015 1 -2.7 8.45 11.15 100%

32 25/01/2015 1 -2.7 8.45 11.15 100%

33 24/01/2015 1 -2.7 8.45 11.15 100%

34 23/01/2015 1 -2.7 8.45 11.15 100%

35 22/01/2015 1 -2.7 8.45 11.15 100%

36 25/01/2015 1 -2.7 8.45 11.15 100%

37 24/01/2015 1 -2.7 8.45 11.15 100%

38 23/01/2015 1 -2.7 8.45 11.15 100%

39 22/01/2015 1 -2.7 8.45 11.15 100%

40 25/01/2015 1 -2.7 8.45 11.15 100%

41 24/01/2015 1 -2.7 8.45 11.15 100%

42 23/01/2015 1 -2.7 8.45 11.15 100%

43 22/01/2015 1 -2.7 8.45 11.15 100%

44 25/01/2015 1 -2.7 8.45 11.15 100%

45 24/01/2015 1 -2.7 8.45 11.15 100%

46 23/01/2015 1 -2.7 8.45 11.15 100%

47 22/01/2015 1 -2.7 8.45 11.15 100%

48 25/01/2015 1 -2.7 8.45 11.15 100%

49 24/01/2015 1 -2.7 8.45 11.15 100%

50 23/01/2015 1 -2.7 8.45 11.15 100%

51 22/01/2015 1 -2.7 8.45 11.15 100%

52 25/01/2015 1 -2.7 8.45 11.15 100%

52 312.2 0 5200% 0

Actual (Tonne)

Totals

Pile I.DDate

CompletedActual

Actual

Actual (Tonne)

Totals

P1 - Female Piles

Activity Bored cast-in-place piles

Pile I.DDate

CompletedActual

Actual

P1 - Male Piles

Activity Bored cast-in-place piles