MG672 Oil and Gas Management Summary 1

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    MG672 Oil and Gas Management

    Week 1

    Global oil & gas industry

    Oil and Gas formation &reserves

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    What is petroleum?

    Petroleum: A general term for allnaturally occurring hydrocarbons

    (hydrogen + carbon)

    Solid Hydrocarbons: Asphalt

    Liquid Hydrocarbons: Crude oil

    Gas Hydrocarbons: Natural Gas:

    methane, butane, propane, etc.

    The simplest hydrocarbon

    is Methane (CH4)

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    1. Source RocksOrganic Matter

    Sedimentary rocks rich inorganic matter

    0.5 - 2% by weight

    Most commonlymicroscopic marinematerial, but it can beland based material

    Organic material cannotdecay too much

    It has to keep its carbon

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    Petroleum source rocks

    Petroleum source beds are fine grained, clay-

    rich rocks (mudstones, shales) or dark

    coloured carbonate rocks (limestones,

    marlstones), which have generated and

    effectively expelled hydrocarbons.

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    Kerogen

    The solid organic matter in source rocks which

    is insoluble in low-boiling organic solvents is

    called kerogen.

    Kerogen is partly formed by the accumulation

    of resistant macromolecular substances of

    biological origin such as cellular lipids, algae

    cell walls, membranes, cuticles, spores andpollen, etc.

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    Diagenesis

    Other parts of kerogen are formed in sedimentsduring a process called diagenesis:

    The geochemical and mineralogical processes that

    occur within the topmost interval of a sedimentarycolumn.

    Organic matter is synthesized by living organisms inthe form of biopolymers such as carbohydrates,proteins, lignin, etc.

    Kerogen is, however, not a polymer in a strictchemical sense, rather a complex mixture ofhigh molecular weight substances.

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    van Krevelen diagram

    Evolutionary pathways

    In this way, thegreat varietyof kerogensoccurring in

    nature can beclassified intothree broadcategoriesreferred to as

    type I-, type II-and type III-kerogens.

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    Fig. 4. Variation of elemental composition of naturallyoccurring kerogens in terms of their atomic H/C- and O/C-ratios

    Classification of kerogens into three broad categories.

    Elemental composition of organic matter in freshly

    deposited sediments is plotted towards the upper rightend of each field (diagenesis stage).

    With increasing burial, kerogen transformation proceedsduring the catagenesis and metagenesis stages.

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    Incipient Oil Generation

    Max. Oil Generated

    Oil Floor

    Wet Gas Floor

    Dry Gas Floor

    Max. Dry GasGenerated

    (modified from Foster and Beaumont, 1991, after Dow and OConner, 1982)

    VitriniteR

    eflectance(Ro

    )%

    Weight%CarboninKero

    gen

    SporeColo

    rationIndex(SCI)

    PyrolysisT

    (C)

    max

    0.2

    0.3

    0.4

    0.5

    4.0

    3.0

    2.0

    1.3

    1

    2

    3

    4

    56

    789

    10

    430

    450

    465

    65

    70

    75

    80

    85

    90

    95

    0.60.70.80.91.01.2

    OIL

    Wet

    Gas DryGas

    Comparison of Several Commonly Used Maturity

    Techniques and Their Correlation to Oil and Gas

    Generation Limits

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    Fig. 5. Diagram to

    illustrate the main

    conditions and

    processes for

    kerogen formation

    from biological

    precursor materialsand kerogen

    transformation into

    petroleum productswith increasing

    maturation

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    oil window

    The temperature interval where oil

    generation is in progress is referred to as the

    liquid window or oil window.

    It extends over the temperature interval of

    about 80-150C.

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    Origin (6): Cooking

    www.oilandgasgeology.com/oil_gas_window.jpg

    As Black Shale is buried, it is heated.

    Kerogen

    Gas

    Oil

    Organic matter is first changed by the

    increase in temperature into kerogen,

    which is a solidform of hydrocarbon

    Around 90C, it is changed into a liquid

    state, which we call oil

    Around 150C, it is changed into a gas

    A rock that has produced oil and gas in

    this way is known as a Source Rock

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    Origin (8): Ancient Earth Ron Blakey, Arizona FlagstaffDuring mid-Mesozoic times

    around 150 million years ago,

    conditions were just right

    to build up huge thicknesses

    of Black Shale source rocks

    Ancient Earth

    The worlds main oil deposits all formed in warm shallow seas

    where plankton bloomed but bottom waters were deoxygenated

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    Why is there oil in Texas?

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    Where is

    there oil in

    NorthAmerica?

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    II. A Strategic Natural Resource

    National Geographic, 2002

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    2. Transform organic matter

    Add heat and pressure by burying it (Maturation)

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    4. Traps If nothing stops oil from rising,

    it will reach surface

    Ex: The La Brea tar pits

    Trapscan be rocks that do notallow fluids to pass throughthem, or folds and faults in therock can trap petroleum

    Anticlinal Theory

    Petroleum Accumulates inStructural Closure

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    Migration of Petroleum (Traps)

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    Fig. 1. Main geological conditions and geochemical processes requiredfor the formation of petroleum accumulations in sedimentary basins:

    1) petroleum generation in source rocks;

    2) primary migration of petroleum;

    3) secondary migration of petroleum;4) accumulation of petroleum in a reservoir trap;

    5) seepage of petroleum at the Earths surface as a consequence of afractured cap rock.

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    Origin of petroleum

    As a general rule, the origin of petroleum is

    never in the reservoir accumulation from

    which it is produced.

    Instead, petroleums have experienced a long

    series of processes prior to accumulation in

    the reservoir.

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    Petroleum accumulation forms in sedimentary

    basins and can be discovered by exploration, if

    the following geological conditions are met: Occurrence of source rocks which generate

    petroleums under proper subsurface

    temperature conditions. Sediment compaction leading to expulsion of

    petroleum from the source and into the

    reservoir rocks (primary migration).

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    Occurrence of reservoir rocks of sufficient

    porosity and permeability allowing flow of

    petroleum through the pore system(secondary migration).

    Structural configurations of sedimentary

    strata whereby the reservoir rocks formtraps, i.e. closed containers in the subsurface

    for the accumulation of petroleum.

    Traps are sealed above by impermeable

    sediment layers (cap rocks) in order to keep

    petroleum accumulations in place.

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    Reservoirrock

    Seal

    Migration route

    Oil/watercontact (OWC)

    Hydrocarbon

    accumulationin thereservoir rock

    Top of maturity

    Source rock

    Fault(impermeable)

    Generation, Migration, and Trapping of

    Hydrocarbons

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    Cross Section Of A Petroleum System

    Overburden Rock

    Seal Rock

    Reservoir Rock

    Source Rock

    Underburden Rock

    Basement Rock

    Top Oil Window

    Top Gas Window

    Geographic Extent of Petroleum System

    Petroleum Reservoir (O)

    Fold-and-Thrust Belt

    (arrows indicate relative fault motion)

    Essential

    Elements

    of

    Petroleum

    System

    (Foreland Basin Example)

    (modified from Magoon and Dow, 1994)

    O O

    Sedimentary

    B

    asinFill

    O

    Stratigraphic

    Extent ofPetroleum

    System

    Pod of Active

    Source Rock

    Extent of Prospect/FieldExtent of Play

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    Review: Where does petroleum come from?

    1. Source rocksrich in organic matter

    2. Transform the organic material with heat andpressure to into petroleum (Maturation)

    3. Carrier bedsthat allow the generated petroleumto move

    4. Trapsthat keep the petroleum below ground

    5. Adequate reservoir bedsfrom which the

    petroleum can be extracted6. Propertimingof events 1-5

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    The First Pipeline

    Transporting the oil was also a problem.

    In 1865 Samuel Van Syckel, an oil buyer,began construction on a two-inch wide

    pipelinedesigned to span the distance to therailroad depot five miles away.

    Theteamsters, who had previously

    transported the oil, didn't take to kindly toSyckel's plan, and they used pickaxes to breakapart the line.

    http://en.wikipedia.org/wiki/File:George_Henry_Bissell_by_Gurney,_1860s.jpg
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    George Bissell

    Colonel Drake

    In 1856, after seeing pictures ofderrick drilling for salt, Bissellconceived of the idea of drilling for oil,rather than mining it.

    This was widely considered ludicrous

    at the time but on August 27, 1859,the company first succeeded in strikingoil, on a farm in Titusville,Pennsylvania.

    Bissell invested heavily in the

    surrounding region and ended upbecoming a wealthy business man.

    The company's agent, Edwin Drake, issometimes credited with the"discovery" of oil.

    http://en.wikipedia.org/wiki/File:George_Henry_Bissell_by_Gurney,_1860s.jpghttp://en.wikipedia.org/wiki/File:Edwindrake.jpg
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    Early Refining

    By 1860there were 15 refineriesin operation.

    Known as "tea kettle" stills, they consisted of a

    large iron drumand a long tubewhich acted as

    a condenser.

    Capacity of these stills ranged from 1 to 100

    barrels a day.

    A coal fireheated the drum, and three fractionswere obtained during the distillation process.

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    The first component to boil off was the highly

    volatile naphtha.

    Next came the kerosene, or "lamp oil", and

    lastly came the heavy oils and tar which were

    simply left in the bottom of the drum.

    These early refineries produced about 75%

    kerosene, which could be sold for high

    profits.

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    Kerosene was so valuablebecause of a whale shortagethat had began in 1845due

    to heavy hunting. Sperm oilhad been the main

    product of the whalingindustry and was used inlamps.

    Candleswere made withanother whale product called

    "spermaceti".

    http://www.google.com.cy/url?sa=i&rct=j&q=&esrc=s&frm=1&source=images&cd=&cad=rja&docid=0-sknav6A09ewM&tbnid=2zshEtLg5X_MtM:&ved=0CAUQjRw&url=http://theresaromain.com/2010/12/09/r-is-for-research-lamps-lighting-and-spermaceti/&ei=F0tOUsChHYjUtQaD24GABQ&bvm=bv.53537100,d.d2k&psig=AFQjCNGBa_TD1vhlvVRBD0oUpUfaXfX2AQ&ust=1380949082741887
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    In 1862John D. Rockefeller financed hisfirstrefineryas a side investment.

    Anyone could drill a well, and overproductionplagued the early industry. At times this

    overproduction meant that the crude oilwascheaper than water. Rockefeller saw early on,that refining and transportation, as opposed toproduction, were the keys to taking control of

    the industry. And control the industry he did!

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    In 1870he established Standard Oil, which

    then controlled 10% of the refining capacity

    in the country.

    Transportationoften encompassed 20% of

    the total production cost and Rockefeller

    made under-the-table dealswith railroadsto

    give him secret shipping rebates.

    http://www.google.com.cy/url?sa=i&rct=j&q=&esrc=s&frm=1&source=images&cd=&cad=rja&docid=bi7Cx1YF6XgSlM&tbnid=2KvvLEPao-DWvM:&ved=0CAUQjRw&url=http://thepublici.blogspot.com/2010/06/to-light-one-candle.html&ei=pEtOUp-zEcKNtQafkoHoAQ&bvm=bv.53537100,d.d2k&psig=AFQjCNGBa_TD1vhlvVRBD0oUpUfaXfX2AQ&ust=1380949082741887
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    This cheap transportation allowed Standard

    to undercut its competitorsand Rockefeller

    expanded aggressively, buying out

    competitors left and right.

    Soon Standard built a network of "iron

    arteries" which delivered oil across the

    Eastern U.S.

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    This pipeline systemrelieved Standard'sdependence upon the railroads and reduced itstransportation costs even more.

    By 1880Standard controlled 90% of the

    country's refining capacity. Because of its massive size, it brought security

    and stabilityto the oil business, guaranteeingcontinuous profits.

    With Standard Oil, John D. Rockefellerbecamethe richest person in the World

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    What do we get from oil?

    1 barrel = 42 gallonsof crude oil

    83% becomes fuel

    Gasoline, diesel, jetfuel, heating oil, andliquefied petroleumgas (propane andbutane)

    17% other Solvents, fertilizers,

    pesticides, plastics

    * These add up to 44.6 gallons

    because volume is increased during

    the refining process.

    US Energy Information Administration

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    How much oil do we use?

    US consumes20,680,000 barrels ofoil each day (2007)

    US motor gasolineconsumption9,286,000 b/d(390million gallons/day)(2007)

    World consumes83,607,000 b/d (2005)

    US Energy Information Administration

    US oil consumption 1980-2006

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    Where do we get our oil from?

    US Energy Information Administration

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    Oil exports by country

    Barrels per day

    US Energy Information Administration

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    Oil imports by country

    Barrels per day

    US Energy Information Administration

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    Are We Running Out of Oil?

    Marion King Hubbert (1903-1989)

    Shell geophysicist

    HubbertsPeak and Curve

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    Global Oil Flows

    BP Statistical Review, 2008

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