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Early Postulates
What is everything (Matter)made of?Greek Mythology –Fire, Air, Water, Earth
Aristotle in “Metaphysics”----- The shape and existence of all things are determined by void and atoms through the differences in shape, position and arrangement of the atoms and the proportion of void in the substance.
Leucippius (Born-50BCE) Democritus (Born –460 BCE)
Postulated an indivisible form of matter
THE ATOM
1897 J.J. Thompson
1899 Charge of the Electron Measured
Crookes Tube
Vacuum Tube
Discovery of the Electron
Electrons Hitting
Target
Electrons Missing
Target
Electrons, Electricity???Electricity was
thought of as a stream, (analogous to water flowing as a pipe)Now thought of as a the motion of
Discrete ParticlesDiscrete Particles having mass mass (Electrons)
Carrying the smallest possible unit of charge
The Plum Pudding Model
Electrons
(Negativly Charged)
J.J. Thompson- 1904
Field
(Positively Charged)
In Today's Vernacular- The Chocolate Chip Model
Earnest Rutherford-1911
Discovery of the Nucleus
Rutherford called it a“Central Charge
(1920 called it a Proton)
Bohr,s Model
Nucleus
1913 – Atomic Model with Fixed Orbits proposed – Modeled after the Solar System
Electrons
Protons
Inner Orbit
Outer Orbit
Nucleus
The Atom has No Charge
Number of Protons =
Number of Electrons
What Did Bohr’s Model Accomplish ?
StabilityElectrical Forces balanced by Centrifugal Forces
IdentityChange in number of Protons/Electrons Changes the Element
Regeneration
Once Pulled Apart, the Atom Reforms as before
How Big is It, (Are They)?
1 Proton ( or Neutron)----1.67 x10-24 Grams
=0.000000000000000000000001.67 Grams
1 electron-----9.1x10-28 Grams
=0.0000000000000000000000000009.1Grams
The Proton weighs 1800 x the Electron
The Atom is about 5 X 10-8 Cm
Lets Try AnalogiesIf the Nucleus were the size of a Garbage Can
The Atom would be the size of LA
If an electrons weighed as much as a watermelon
The proton would weigh as much as an elephant
Conclusion; It’s mostly nothing
Strange Things were Happening
Rutherford – 1920 Postulated a Neutron Doublet
Sometimes the nucleus of an element weighed differently than another nucleus of the same element
Irene and Fredrick Joliot- Curie 1932 found radiation they thought was protons
James Chadwick Didn’t Believe It
James Chadwick - 1935
A Unique Particle, (not an electron or a proton )
Essentially the same mass as an Proton
Has no Charge
With the Proton, Makes up the Nucleus
Discovery of the Neutron
Bohr Model of Potassium(K) and Uranium (U)
39P19
19 Protons
20 Neutrons
Atomic Mass=39
92 Protons
143 Neutrons
Atomic Mass = 235
92 Protons
146 Neutrons
Atomic Mass=238
235U92 238U92
So Little From So Much• Marie Curie purified 10,000,000
grams of Pitchblende to get 0.1 Grams of Uranium
• Natural uranium is • 99. 3% U238 • 0. 7% U235 (The Bomb Type)
Problem – Not Enough 235U How to increase the Concentration?.
Combine the Uranium(s) with Fluorine to get a gas
(Uranium Hexafluoride)
Pass the gas through a porous filter –
More 235U based gas than 238U gas gets through.
Collect it and do it again,& again & again, & again, & again------
Centrifuge the Gasses-
Heavier 238U based gas separates from lighter 235 U based gas
Collect it and do it again,& again 7 again, & again, & again--------- Thermal Diffusion- Used Heated, Pressurized Uranium
Hexafluoride
So Much from So LittleNew Term—Electron Volt (ev)A Measure of Energy
Chemical Reaction-Dynamite Releases 1 ev per Atom
Nuclear Reaction – ( The Bomb) Releases 1,000,000 ev per atom
They like Things Orderly How we organize these different
Elements???
Are there Common
Characteristics ???
Ti=50 Zr=90 ?=180 V=51 Nb=94 Ta=182 Cr=52 Mo=96 W=186 Mn=55 Rh=104,4 Pt=197,4 Fe=56 Ru=104,4 Ir=198 Ni=Co=59 Pd=106,6 Os=199 H=1 Cu=63,4 Ag=108 Hg=200 Be=9,4 Mg=24 Zn=65,2 Cd=112 B=11 Al=27,4 ?=68 Ur=116 Au=197? C=12 Si=28 ?=70 Sn=118 N=14 P=31 As=75 Sb=122 Bi=210? O=16 S=32 Se=79,4 Te=128? F=19 Cl=35,5 Br=80 J=127 Li=7 Na=23 K=39 Rb=85,4 Cs=133 Tl=204 Ca=40 Sr=87,6 Ba=137 Pb=207 ?=45 Ce=92 ?Er=56 La=94 ?Yt=60 Di=95 ?In=75,6 Th=118?
Mendeleev 1869
Original Table – 63 Elements