MSDS FOR 81-1071-06 - GE Analytical Instruments · PDF fileAs a standard precaution, ... procedures for taking care of liquid mercury under these and ... kidneys, and reproductive

PRODUCT HANDLING AND SAFETY DATA FOR LOW PRESSURE MERCURY LAMP

PART NUMBER 81-1071-06 INTACT MERCURY LAMPS The low pressure mercury vapor lamps manufactured by BHK, Inc., are exempted from the requirements of the OSHA Hazard Communication Standard (29 CFR 1910.1200) because they are articles. Intact (unbroken) low pressure mercury vapor lamps present no environmental hazard to the end user. As a courtesy to its customers, the hazards of materials used in the fabrication of low pressure mercury vapor lamps are identified in the appropriate MSDS that is provided by each of the material suppliers. A copy of each of these MSDS is included in the Appendix at the end of this document. NOTE: These materials become hazardous to the extent indicated by the specific material MSDS only in the event the lamp is broken, cut open or destroyed. PRODUCT IDENTIFICATION Trade Name(s) Low Pressure Mercury Lamp (Ultraviolet producing), Also known as: Analamp Manufacturer BHK, Inc. 760 E. Sunkist Street Ontario, CA, 91761 Tel: (909) 983-2973 Fax: (909) 986-3637 PRODUCT HANDLING As a standard precaution, all mercury lamps should be handled carefully because of the breakable nature of the quartz material from which it is made. BROKEN LAMPS In the event a lamp is broken, there is the possibility liquid mercury will escape from the lamp. The procedures for taking care of liquid mercury under these and other conditions are included in the appropriate MSDS for Mercury, in the Appendix. In the event a lamp is broken, there is the possibility powder and sharp pieces of quartz will be found in the vicinity of where the break occurred. The sharp pieces of quartz should be removed and placed in a safe container. The procedures for taking care of quartz under additional conditions are included in the appropriate MSDS for Quartz, in the Appendix. ALL OTHER CONDITIONS For all other conditions to which any of the materials used in the fabrication of the lamp may be exposed, refer to the appropriate MSDS in the Appendix.

APPENDIX CONTENTS: MSDS for Mercury MSDS for Quartz MSDS for Molybdenum MSDS for Aluminum MSDS for Epoxy Part A & B MSDS for Silicone Part A & B MSDS for Wire Cable** (Not available from Manufacturer) MSDS for Heat Shrink MSDS for RTV

MERCURY MSDS

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MATERIAL SAFETY DATA SHEET

Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards

PART I What is the material and what do I need to know in an emergency?

1. PRODUCT IDENTIFICATION

TRADE NAME (AS LABELED): MERCURY CHEMICAL NAME/CLASS: Mercury; Element SYNONYMS: Colloidal Mercury, Quick Silver; Liquid Silver;

NCI-C60399; Hydrargyrum PRODUCT USE: Variety of industrial, analytical, and research

applications. SUPPLIER/MANUFACTURER'S NAME: BETHLEHEM APPARATUS COMPANY ADDRESS: 890 Front Street Hellertown, PA 18055 EMERGENCY PHONE: 610-838-7034 BUSINESS PHONE: 610-838-7034 DATE OF PREPARATION: May 20, 1997 DATE OF REVISION: May 2, 2005

2. COMPOSITION and INFORMATION ON INGREDIENTS

CHEMICAL NAME CAS # %w/w EXPOSURE LIMITS IN AIR

ACGIH-TLV OSHA-PEL OTHER TWA STEL TWA STEL IDLH mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3

Mercury Exposure limits are for Mercury, Inorganic Compounds

7439-97-6 100 0.025, (skin) A4 (Not

Classifiable as a Human Carcinogen)

NE Mercury Vapor: 0.5,

Skin; (Vacated

1989 PEL)

0.1 (ceiling)

Non-alkyl Mercury Compounds: 0.1

Ceiling, skin (Vacated 1989

PEL)

10 NIOSH REL: STEL = 0.1 (ceiling,

skin) DFG MAKs: TWA = 0.1 PEAK = 10•MAK 30

min., momentary value

Carcinogen: EPA-D; IARC-3, TLV-A4

NE = Not Established. See Section 16 for Definitions of Terms Used. NOTE: ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in

accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.

MERCURY MSDS

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3. HAZARD IDENTIFICATION EMERGENCY OVERVIEW: Mercury is a silver-white, odorless, heavy liquid. Mercury is highly toxic, irritating, and causes sensitization and neurological symptoms. The primary health hazard associated with overexposure to this product is the potential for irritation of skin, eyes, or other contaminated tissues. Mercury causes severe, adverse health effects after chronic exposure to low vapor levels; emergency response efforts must be directed to removal of all traces of this product. Mercury is not flammable, and is relatively stable (though it can react with many metals to form amalgams). Emergency responders must wear the personal protective equipment suitable for the situation to which they are responding.

SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of occupational over-exposure are inhalation and contact with skin and eyes. The symptoms of over-exposure to Mercury, via route of exposure, are as follows: INHALATION: Long-term exposures to Mercury vapors present a severe health hazard. When inhaled, Mercury will be rapidly distributed throughout the body. During this time, Mercury will cross the blood-brain barrier, and become oxidized to the Hg(II) oxidation state. The oxidized species of Mercury cannot cross the blood-brain barrier and thus accumulates in the brain. Mercury in other organs is removed slowly from the body via the kidneys. The average half-time for clearance of Mercury for different parts of the human body is as follows: lung: 1.7 days; head: 21 days; kidney region: 64 days; chest: 43 days; whole body: 58 days. Long-term inhalation over-exposures can lead to the development of a wide variety of symptoms, including the following: excessive salivation, gingivitis, anorexia, chills, fever, cardiac abnormalities, anemia, digestive problems, abdominal pains, frequent urination, an inability to urinate, diarrhea, peripheral neuropathy (numbness, weakness, or burning sensations in the hands or feet), tremors (especially in the hands, fingers, eyelids, lips, cheeks, tongue, or legs), alteration of tendon reflexes, slurred speech, visual disturbances, and deafness. Allergic reactions (i.e. breathing difficulty) may also occur in sensitive individuals. The principal target organ associated with chronic Mercury exposures via inhalation is the central nervous system. Such exposures lead to the development of “Erethism”. This syndrome consists of subtle or dramatic changes in behavior and personality: depression, fearfulness, restlessness, irritability, timidity, and indecision. These psychic and behavioral characteristics are often accompanied by insomnia, drowsiness, headache, and fatigue. In advanced cases, memory loss, hallucinations, and mental deterioration may occur. Another, less common, syndrome associated with Mercury over-exposure is “Acrodynia”. Symptoms of this syndrome include a pink color to the extremities, apathy, fever, kidney problems, sensitivity to light, generalized edema, and a painful scaling of the skin of the hands and feet. Other symptoms of chronic over-exposure to Mercury can include loosening of the teeth, inflammation of the mucous membranes, a dark blue line appearing along gingival margins, abnormal blushing, excessive sweating, and rashes. Reproductive effects, sexual disorders, and impotence may also develop in the event of Mercury over-exposure. Short-term over-exposures to high concentrations of mercury vapors can lead to breathing difficulty, coughing, acute, chemical pneumonia, and pulmonary edema (a potentially fatal accumulation of fluid in the lungs). Depending on the concentration of over-exposure, cardiac abnormalities, damage to the kidney, liver or nerves and effects on the brain may occur. If this product is heated, and exposure to Mercury fumes occurs, “Metal Fume Fever” may develop. This syndrome is a flu-like illness which occurs when metal oxides below 1.5 microns in size are inhaled. Symptoms of this syndrome may develop 4-12 hours after exposure and begin with the onset of thirst, metallic taste in the mouth, and symptoms of Mercury poisoning as described above. All symptoms generally subside within 24-36 hours after the over-exposure ends. CONTACT WITH SKIN or EYES: Mercury can be irritating to contaminated skin and eyes. Symptoms of skin exposure can include redness, dry skin, and pain. Prolonged contact may lead to ulceration of the skin. Allergic reactions (i.e. rashes, welts) may occur in sensitive individuals. Dermatitis (redness and inflammation of the skin) may occur after repeated skin exposures. Symptoms of eye exposure can include redness, pain, and watery eyes. A symptom of Mercury exposure is discoloration of the lens of the eyes.

HEALTH

FLAMMABILITY

REACTIVITY

PROTECTIVE EQUIPMENT

3

0

0

EYES RESPIRATORY HANDS BODY

(BLUE)

(RED)

(YELLOW)

For a variety of applications involving elemental Mercury.

HAZARDOUS MATERIAL IDENTIFICATION SYSTEM

X

See Section 8

See Section 8

See Section 16 for Definition of Ratings

MERCURY MSDS

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3. HAZARD IDENTIFICATION (Continued) SKIN ABSORPTION: Skin absorption is a significant route of potential over-exposure to Mercury. Currently, no quantitative estimates of the rate of penetration are available. Symptoms of such over-exposure would include redness and irritation of the contaminated area, as well as the development of symptoms described for “Inhalation”. INGESTION: Ingestion is not anticipated to be a significant route of occupational over-exposure. If Mercury is swallowed, symptoms of such over-exposure can include metallic taste in mouth, nausea, vomiting, central nervous system effects, and damage to the kidneys. Metallic mercury is not usually absorbed sufficiently from the gastrointestinal tract to induce an acute, toxic response. Damage to the tissues of the mouth, throat, esophagus, and other tissues of the digestive system may occur. Ingestion may be fatal, due to effects on gastrointestinal system and kidneys. INJECTION: Injection is not anticipated to be a significant route of over-exposure for this product. If Mercury is injected (i.e. though abrasions and lacerations of the skin), local redness and pain will occur. Other symptoms of such exposure can include the development of embolisms (Mercury blocking a vein or artery), malaise, chest pain, and difficulty in breathing. HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. The most severe health effects associated with Mercury exposure are related to long-term exposures to vapors. In the event of over-exposure, the following symptoms may be observed: ACUTE: Mercury can be irritating to contaminated skin and eyes. Short-term over-exposures to high concentrations of mercury vapors can lead to breathing difficulty, coughing, acute, and potentially fatal lung disorders. Depending on the concentration of inhalation over-exposure, heart problems, damage to the kidney, liver or nerves and effects on the brain may occur. CHRONIC: Long-term over-exposure can lead to a wide range of adverse health effects. Anyone using Mercury must pay attention to personality changes, weight loss, skin or gum discolorations, stomach pains, and other signs of Mercury over-exposure. Gradually developing syndromes (“Erethism” and “Acrodynia”) are indicative of potentially severe health problems. Mercury can cause the development of allergic reactions (i.e. dermatitis, rashes, breathing difficulty) upon prolonged or repeated exposures. Refer to Section 11 (Toxicology Information) for additional data. TARGET ORGANS: ACUTE: Skin, eyes, respiratory system, central nervous system, brain. CHRONIC: Skin, respiratory system, central nervous system, brain, blood system, kidneys, and reproductive system.

PART II What should I do if a hazardous situation occurs?

4. FIRST-AID MEASURES Contaminated individuals must be taken for medical attention. Rescuers should be taken for medical attention, if necessary. Take a copy of label and MSDS to health professional with victim. SKIN EXPOSURE: If Mercury contaminates the skin, immediately begin decontamination with running water. Minimum flushing is for 15 minutes. Remove exposed or contaminated clothing, taking care not to contaminate eyes. The contaminated individual must seek immediate medical attention. EYE EXPOSURE: If Mercury contaminates the eyes, open the victim's eyes while under gently running water. Use sufficient force to open eyelids. Have the contaminated individual "roll" eyes. Minimum flushing is for 15 minutes. The contaminated individual must seek immediate medical attention. INHALATION: If Mercury vapors are inhaled, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers. The contaminated individual must seek immediate medical attention. INGESTION: If Mercury is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. If professional advice is not available, induce vomiting. Have victim rinse mouth with water, or drink several cupfuls of water, if conscious. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or unable to swallow. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Preexisting respiratory problems, dermatitis, central nervous system disorders, kidney problems, and liver dysfunctions can be aggravated by exposure to this product. RECOMMENDATIONS TO PHYSICIANS: Treatment for Mercury over-exposure must be given. The following treatment protocol for ingestion of Mercury is from Clinical Toxicology of Commercial Products (5th Edition, 1984).

1. As soon as possible, have patient drink milk or slurry of activated charcoal to help precipitate mercury in the stomach. 2. Gastric lavage with tap water, milk, or 2-5% solution of sodium bicarbonate, unless spontaneous vomiting is intense

and productive, 3. Administer through the lavage tube 0.5-1.0 oz. of sodium or magnesium sulfate in 6-8 oz. of water (unless spontaneous

purging has already begun) and a slurry of activated charcoal. 4. Administer BAL (Dimercaprol; 3 mg/kg or 0.3 mL/10 kg) intramuscularly as a 10% solution in oil. If given within three

hours after ingestion, severe renal damage may be prevented. Collect urine before and after BAL therapy for mercury analysis.

5. Demulcents (i.e. milk of magnesia, starch, bismuth subcarbonate) and analgesic drugs may be useful and necessary.

MERCURY MSDS

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4. FIRST-AID MEASURES (Continued) RECOMMENDATIONS TO PHYSICIANS (continued): 6. Because the BAL-Mercury Complex excreted in bile may be partly resorbed in the bowel, it is probably useful to

administer activated charcoal every few hours, starting as soon as vomiting subsides. 7. Treat shock by correcting dehydration and electrolyte imbalances. If renal insufficiency develops, treat for acute renal

failure. 8. The maintenance of an adequate nutritional status may be troublesome if gastrointestinal disorders becomes severe or

persistent. 9. If toxic signs or symptoms recur after an apparent recovery, another course of chelation therapy is warranted. BAL is

still appropriate, but a trial with D-Penicillamine or N-acetyl-D,L-penicillamine may be preferable. Either penicillamine compound is given by mouth, usually on an empty stomach, in a dose of 250 mg (4 times daily for adults; 3 times daily in children; 5-10 days). Penicillamine should be withheld until mercury is cleared out of the bowels. A chelating agent should be used until the urine-mercury level falls below 50µg/24 hours.

Laboratory Analysis: Determination of β2-Microglobulins has been recommended as a useful test for renal function. Electroencephalographic changes may be correlated closely with the clinical state. Analysis of the blood, hair, urine, or feces can be done to determine the level of Mercury exposure. Mercury deposits in the body can be observed in X-Rays.

5. FIRE-FIGHTING MEASURES FLASH POINT: Not flammable. AUTOIGNITION TEMPERATURE: Not applicable. FLAMMABLE LIMITS (in air by volume, %): Lower (LEL): Not applicable. Upper (UEL): Not applicable. FIRE EXTINGUISHING MATERIALS:

Water Spray: YES Carbon Dioxide: YES

Foam: YES Dry Chemical: YES

Halon: YES Other: Any "ABC" Class. UNUSUAL FIRE AND EXPLOSION HAZARDS: Mercury vapors and mercury oxides generated during fires involving this product are toxic; additionally, this element can be irritating to contaminated tissue. Therefore, this product presents a severe health hazard to firefighters. Mercury is not flammable, and is relatively stable (though it can react with many metals to form amalgams). Explosion Sensitivity to Mechanical Impact: Not sensitive. Explosion Sensitivity to Static Discharge: Not sensitive. SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment. Move fire-exposed containers if it can be done without risk to firefighters. Apply cooling water to sides of containers that are exposed to flame until well after fire is out. Decontaminate all equipment thoroughly after the conclusion of fire-fighting activities. If possible, prevent run-off water from entering storm drains, bodies of water, or other environmentally sensitive areas.

6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned procedures. Proper protective equipment should be used. In case of a Mercury release, clear the affected area, protect people, and respond with trained personnel. In the event of a release under 1 pound of Mercury, the minimum Personal Protective Equipment should be Level C: triple-gloves (rubber gloves and nitrile gloves over latex gloves), chemical resistant suit and boots, hard-hat, and Air-Purifying Respirator with cartridge appropriate for Mercury. Level B, which includes Self-Contained Breathing Apparatus, must be worn if the amount of Mercury released is over 1 pound or when the concentration of oxygen in atmospheres is less than 19.5% or unknown. If necessary, dike area of release with suitable absorbent materials. There are a variety of methods which can be used to clean-up Mercury spills. Use a commercially-available Mercury Spill Kit for small spills. A suction pump with aspirator can also be used during clean-up operations. For larger releases, a Mercury vacuum can be used. Calcium polysulfide or excess sulfur can also be used for clean-up. Mercury can migrate into cracks and other difficult-to-clean areas; calcium polysulfide and sulfur can be sprinkled effectively into these areas. Decontaminate the area thoroughly. The area should be inspected visually and with colorimetric tubes for Mercury to ensure all traces of Mercury have been removed prior to re-occupation by non-emergency personnel. Decontaminate all equipment used in response thoroughly. If such equipment cannot be adequately decontaminated, it must be discarded with other spill residue. Place all spill residue in an appropriate container, seal immediately, and label appropriately. Dispose of in accordance with U.S. Federal, State, and local hazardous waste disposal regulations and regulations of Canada and it’s Provinces. (see Section 13, Disposal Considerations).

3

0

0HEALTH

FLAMMABILITY

REACTIVITY

OTHER

NFPA RATING

See Section 16 for Definition of Ratings

MERCURY MSDS

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PART III How can I prevent hazardous situations from occurring?

7. HANDLING and STORAGE WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting Mercury ON YOU or IN YOU. Wash thoroughly after handling this product. Avoid breathing vapors or spays of this product. Do not eat or drink while handling this product. Remove contaminated clothing immediately. Report all Mercury releases promptly. Clean-up all releases of this product immediately. Supervisors and other responsible personnel must be aware of personality changes, weight loss, or other signs of Mercury over-exposure in employees using this product; these symptoms can develop gradually and are indicative of potentially severe health effects related to Mercury contamination. STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely. Use in a well-ventilated location. Open containers slowly on a stable surface. Drums, flask, and bottles of this product must be properly labeled. Empty containers may contain residual amounts of Mercury; therefore, empty containers should be handled with care. Store drums, flasks, and bottles in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials (see Section 10, Stability and Reactivity). Material should be stored in secondary containers or in a diked area, as appropriate. Keep drums, flasks, and bottles tightly closed when not in use. Storage areas should be made of fire-resistant materials. If appropriate, post warning signs in storage and use areas. Inspect all incoming containers before storage to ensure containers are properly labeled and not damaged. PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely. Always use this product in areas where adequate ventilation is provided. Decontaminate equipment thoroughly before maintenance begins.

8. EXPOSURE CONTROLS - PERSONAL PROTECTION VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided in Section 2 (Composition and Information on Ingredients), if applicable. Ensure eyewash/safety shower stations are available near areas where this product is used. RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below exposure limits listed in Section 2 (Composition and Information on Ingredients), if applicable. If necessary, use only respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134) or equivalent U.S. State standards, and Canadian CSA Standard Z94.4-93. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required under OSHA’s Respiratory Protection Standard (1910.134-1998).The following respirator selection guidelines from NIOSH are provided for additional information:

RECOMMENDATIONS FOR MERCURY COMPOUNDS [except (organo) alkyls] (as Hg) CONCENTRATIONS IN AIR:

Up to 0.5 mg/m3: Chemical cartridge respirator with cartridge(s) to protect against mercury compounds (an End-of-Service Life Indicator is required); or Supplied-Air Respirator (SAR).

Up to 1.25 mg/m3: SAR operated in a continuous-flow mode; or powered air- purifying respirator with cartridge(s) to protect against mercury compounds (canister) (an End-of-Service Life Indicator is required.)

Up to 2.5 mg/m3: Full-facepiece chemical cartridge respirator with cartridge(s) to protect against mercury compounds; or gas mask with canister to protect against mercury compounds; or SAR with a tight-fitting facepiece operated in a continuous-flow mode; or powered air-purifying respirator with a tight-fitting facepiece and cartridge(s) to protect against mercury compounds (canister) (an End-of-Service Life Indicator is required); or full-facepiece Self-Contained Breathing Apparatus (SCBA); or full-facepiece SAR.

Up to 10 mg/m3: Positive pressure SAR. Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Positive pressure, full-facepiece SCBA; or

positive pressure, full-facepiece SAR with an auxiliary positive pressure SCBA. Escape: Gas mask with canister to protect against mercury compounds; or escape-type SCBA. EYE PROTECTION: Splash goggles or safety glasses. For operations involving the use of more than 1 pound of Mercury, or if the operation may generate a spray of Mercury, the use of a faceshield is recommended. HAND PROTECTION: Wear neoprene gloves for routine industrial use. Use triple gloves for spill response, as stated in Section 6 (Accidental Release Measures) of this MSDS. BODY PROTECTION: Use body protection appropriate for task (i.e. lab coat, coveralls, Tyvek suit).

MERCURY MSDS

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9. PHYSICAL and CHEMICAL PROPERTIES RELATIVE VAPOR DENSITY (air = 1): 6.9 EVAPORATION RATE (n-BuAc = 1): Not determined. SPECIFIC GRAVITY (water = 1): 13.5939 MELTING/FREEZING POINT: -38.87°C (-37.97°F)

SOLUBILITY IN WATER: Insoluble. BOILING POINT: 356.72°C (674.1°F)

VAPOR PRESSURE, mm Hg @ 25°C: 0.002 pH: Not applicable. ODOR THRESHOLD: Not applicable. COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not available. APPEARANCE, ODOR AND COLOR: Mercury is a silver-white, heavy liquid which is odorless. HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance of this product is a distinguishing characteristic.

10. STABILITY and REACTIVITY STABILITY: Stable

DECOMPOSITION PRODUCTS: If this product is exposed to extremely high temperatures in the presence of oxygen or air, toxic vapors of mercury and mercury oxides will be generated. MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Mercury is incompatible with acetylene and acetylene derivatives, amines, ammonia, 3-bromopropyne, boron diiodophosphide, methyl azide, sodium carbide, heated sulfuric acid, methylsilane/oxygen mixtures; nitric acid/alcohol mixtures, tetracarbonylnickel/oxygen mixtures, alkyne/silver perchlorate mixtures, halogens (i.e. chlorine, bromine) and strong oxidizers (i.e. chlorine dioxide, perchlorates). Mercury can attack copper and copper alloys. Additionally, mercury can react with many metals (i.e. calcium, lithium, potassium, sodium, rubidium, aluminum) to form amalgams.

HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Avoid exposure or contact to extreme temperatures, incompatible chemicals

PART IV Is there any other useful information about this material?

11. TOXICOLOGICAL INFORMATION TOXICITY DATA: The specific toxicology data available for Mercury are as follows.

TDLo (Subcutaneous-Man) 254 mg/kg: Skin and Appendages: dermatitis, other (after systemic exposure)

TDLo (Oral-Man) 43 mg/kg: Behavioral: tremor; Liver: jaundice, other or unclassified, other changes

TDLo (Skin-Man) 129 mg/kg/5 hours-continuous: Sense Organs and Special Senses (Ear): tinnitus; Behavioral: headache; Skin and Appendages: dermatitis, allergic (after systemic exposure)

TDLo (Intravenous-Man) 571 µL/kg: Peripheral Nerve and Sensation: paresthesis; Lungs, Thorax, or Respiration: dyspnea; Skin and Appendages: sweating

TDLo (Intraperitoneal-Rat) 400 mg/kg/14 days-intermittent: Tumorigenic: equivocal tumorigenic agent by RTECS criteria, tumors at site of application

TCLo (Inhalation-Woman) 150 µg/m3/46 days: Behavioral: wakefulness, anorexia (human); Gastrointestinal: hypermotility, diarrhea

TCLo (Inhalation-Man) 44300 µg/m3/8 hours: Behavioral: muscle weakness; Liver: other changes; Nutritional and Gross Metabolic: body temperature increase

TCLo (Inhalation-Rat) 4 mg/m3/2 hours/11 days-intermittent: Brain and Coverings: other degenerative changes; Kidney, Ureter, Bladder: other changes; Biochemical: Enzyme inhibition, induction, or change in blood or tissue levels: other Enzymes

TCLo (Inhalation-Rat) 1 mg/m3/24 hours/5 weeks-continuous: Kidney, Ureter, Bladder: proteinuria

TCLo (Inhalation-Rat) 8 µg/m3/6.5 hours/41 weeks-intermittent: Behavioral: alteration of classical conditioning

TCLo (Inhalation-Rat) 17 mg/m3/2 hours/30 days-continuous: Brain and Coverings: other degenerative changes; Behavioral: alteration of classical conditioning, alteration of operant conditioning

TCLo (Inhalation-Rat) 890 ng/m3/24 hours: male 16 week(s) pre-mating: Reproductive: Paternal Effects: spermatogenesis (incl. genetic material, sperm morphology, motility, and count)

TCLo (Inhalation-Rat) 7440 ng/m3/24 hours: male 16 week(s) pre-mating: Reproductive: Fertility: post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)

TCLo (Inhalation-Rat) 1 mg/m3/24 hours: female 1-20 day(s) after conception: Reproductive: Effects on Embryo or Fetus: fetotoxicity (except death, e.g., stunted fetus)

TCLo (Inhalation-Rat) 300 µg/m3/4 hours: female 7-21 day(s) after conception: Reproductive: Specific Developmental Abnormalities: Central Nervous System

LCLo (Inhalation-Rabbit) 29 mg/m3/30 hours Cytogenetic Analysis (Unreported-Man) 150

µg/m3

SUSPECTED CANCER AGENT: Mercury is listed as follows by agencies tracking carcinogenic potential:

ACGIH TLV-A4 (Not Classifiable as a Human Carcinogen: Agents which cause concern that they could be carcinogenic for humans, but which cannot be assessed conclusively because of a lack of data); EPA- D (Not Classifiable as to Human Carcinogenicity-Inadequate human and animal evidence of carcinogenicity or no data are available); IARC-3 (Possibly Carcinogenic to Humans)

Mercury is not found on the following lists: FEDERAL OSHA Z LIST, NTP, or CAL/OSHA and therefore is not considered to be, nor suspected to be, a cancer-causing agent by these agencies.

MERCURY MSDS

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11. TOXICOLOGICAL INFORMATION (Continued) IRRITANCY OF PRODUCT: Mercury can be irritating to skin, eyes, or other contaminated tissue. SENSITIZATION TO THE PRODUCT: Mercury is a sensitizer capable of causing allergic reactions (i.e. breathing difficulty, dermatitis, rashes) after prolonged or repeated over-exposures. REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of Mercury on the human reproductive system.

Mutagenicity: Human mutation data are available for Mercury; these data were obtained during clinical studies on specific human tissues exposed to high doses of this element.

Embryotoxicity: This product may cause embryotoxic effects in humans. Refer to the paragraph on “Teratogenicity” for additional information.

Teratogenicity: This product may cause teratogenic effects in humans. Intrauterine exposure may result in tremors and involuntary movements in the fetus. Mercury has also been reported to produce teratogenic effects in test animals.

Reproductive Toxicity: This product is reported to cause reproductive effects in humans. Impotence has been reported in over-exposed males. Women occupationally exposed have reported menstrual disturbances, reduced ovulation, and spontaneous abortions. Mercury is excreted in breast milk. Mercury has also been reported to produce adverse reproductive effects in test animals.

A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate through generational lines. An embryotoxin is a chemical which causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical which causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance which interferes in any way with the reproductive process.

BIOLOGICAL EXPOSURE INDICES: The following Biological Exposure Indices (BEIs) have been determined for Mercury.

CHEMICAL DETERMINANT SAMPLING TIME BEI MERCURY • Total inorganic mercury in urine • Total inorganic mercury in blood

• Preshift • End of shift at end of workweek

• 35 µg/g creatinine • 15 µg/L

Note: Women of child-bearing potential, whose blood Pb exceeds 10 µg/dl, are at risk of delivering a child with a blood Pb over the current Center for Disease Control Quideline of 10 µg/dl. If the blood Pb of such children remains elevated, they may be at increased risk of cognitive deficits. The blood Pb of these children should be closely monitored and appropriate steps should be taken to minimize the child’s exposure to environmental lead.

12. ECOLOGICAL INFORMATION

ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. ENVIRONMENTAL STABILITY: Mercury is stable, and persists for long periods in ambient environmental conditions. The following environmental data are available for this element:

The biological half-life of mercury in fish is approximately 2 to 3 years. Mercury bioaccumulates and concentrates in the food chain. Concentration may be as much as 10,000 times that of water. Mercury is concentrated by animals, plants and fishes. Chinook salmon fed contaminated fingerlings concentrated Mercury in the liver and kidneys. Methyl mercury is formed naturally in aquatic and terrestrial environments from elemental mercury. Methylation is likely to occur in upper sedimentary layers of sea or lake bottoms.

EFFECT OF MATERIAL ON PLANTS or ANIMALS: Mercury can be harmful or fatal to contaminated plant or animal life. EFFECT OF CHEMICAL ON AQUATIC LIFE: Mercury can be harmful or fatal to contaminated aquatic plant or animal life in contaminated bodies of water. The following aquatic toxicity data are available for Mercury: MERCURY: LC50 (Catfish) = 0.35 mg/L/ 96 hours (conditions of bioassay not specified) LC50 (Modiolus carvalhoi) (mollusk) = 0.5 ppm / 48 hours; 0.19 ppm - 96 hours (conditions of bioassay not specified) LC50 (Rana hexadactyla) (tadpoles) = 0.051 ppm / 96 hours (conditions of bioassay not specified)

13. DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State, and local regulations. This product, if unaltered by use, should be recycled. If altered by use, recycling may be possible. Consult Bethlehem Apparatus Company for information. If Mercury must be disposed of as hazardous waste, it must be handled at a permitted facility or as advised by your local hazardous waste regulatory authority. EPA WASTE NUMBER: Depending on the nature of the waste, one of the following RCRA codes will be applicable: U151 (Toxic Commercial Chemical Products/Mercury); D009 (Characteristic; Toxicity Characteristic Leaching Procedure; Regulated Level: 0.2 mg/L).

MERCURY MSDS

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14. TRANSPORTATION INFORMATION THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION.

PROPER SHIPPING NAME: Mercury HAZARD CLASS NUMBER and DESCRIPTION: 8 (Corrosive Material) UN IDENTIFICATION NUMBER: UN 2809 PACKING GROUP: PG III DOT LABEL(S) REQUIRED: Corrosive NOTE: For transport by aircraft, Mercury must be packaged in packagings which meet the requirements of Packing Group

I Performance Level. For transportation by other modes, Mercury must be packaged in packagings which meet the requirements of Packing Group III Performance Level or in non-specification reusable metal packagings. Refer to 49 CFR 173.164 for specific packaging requirements.

NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER, 2000: 172 MARINE POLLUTANT: Mercury is not listed as a Marine Pollutant, per Appendix B to 49 CFR 172.101.

TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This material is considered as dangerous goods, per regulations of Transport Canada. Use the above U.S. DOT information for the preparation of Canadian Shipments.

15. REGULATORY INFORMATION ADDITIONAL U.S. REGULATIONS: U.S. SARA REPORTING REQUIREMENTS: Mercury is subject to the reporting requirements of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act, as follows:

CHEMICAL NAME SARA 302 (40 CFR 355, Appendix A)

SARA 304 (40 CFR Table 302.4)

SARA 313 (40 CFR 372.65)

Mercury No YES YES

U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for Mercury. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lbs. (4,540 kg) therefore applies, per 40 CFR 370.20. U.S. TSCA INVENTORY STATUS: Mercury is listed on the TSCA Inventory. U.S. CERCLA REPORTABLE QUANTITY (RQ): Mercury = 1 lb (0.454 kg) OTHER U.S. FEDERAL REGULATIONS: Mercury is regulated as follows (other regulations may be applicable): EPA: Mercury is listed as a Hazardous Air Pollutant (HAP) generally known or suspected to cause serious health problems.

The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Mercury is included on this list.

FDA: The action level of 1.0 ppm total mercury in fish has been revised on September 12, 1984 by FDA to apply only to methyl mercury.

FIFRA: All uses of mercury are cancelled except the following: 1) as a fungicide in the treatment of textiles and fabrics intended for continuous outdoor use; 2) as a fungicide to control brown mold on freshly sawn lumber; 3) as a fungicide treatment to control Dutch elm disease; 4) as an in-can preservative in water based paints and coatings; 5) as a fungicide in water-based paints and coatings used for exterior application; 6) as a fungicide to control "winter turf diseases" such as Sclerotinia boreales, and gray and pink snow mold subject to the following: a. the use of these products shall be prohibited within 25 feet of any water body where fish are taken for human consumption. b. these products can be applied only by or under the direct supervision of golf course superintendents. These types of Mercury-containing products will be classified as restricted use pesticides when they are reregistered and classified in accordance with Section 4(C) of FEPCA.

U.S. STATE REGULATORY INFORMATION: Mercury is covered under specific State regulations, as denoted below:

Alaska - Designated Toxic and Hazardous Substances: Mercury.

California - Permissible Exposure Limits for Chemical Contaminants: Mercury.

Florida - Substance List: Mercury. Illinois - Toxic Substance List: Mercury. Kansas - Section 302/313 List: Mercury. Massachusetts - Substance List: Mercury. Michigan – Critical Materials Register:

Mercury.

Minnesota - List of Hazardous Substances: Mercury.

Missouri - Employer Information/Toxic Substance List: Mercury.

New Jersey - Right to Know Hazardous Substance List: Mercury.

North Dakota - List of Hazardous Chemicals, Reportable Quantities: Mercury.

Pennsylvania - Hazardous Substance List: Mercury.

Rhode Island - Hazardous Substance List: Mercury.

Texas - Hazardous Substance List: Mercury. West Virginia - Hazardous Substance List:

Mercury. Wisconsin - Toxic and Hazardous

Substances: Mercury.

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15. REGULATORY INFORMATION (Continued) ADDITIONAL U.S. REGULATIONS (continued): CALIFORNIA PROPOSITION 65: Mercury is on the California Proposition 65 lists. WARNING: Contains a chemical known to the State of California to cause birth defects or other reproductive harm.

LABELING (Precautionary Statements) ANSI LABELING (Z129.1):: DANGER! HIGHLY TOXIC AFTER LONG-TERM EXPOSURE. DANGER OF CUMULATIVE EFFECTS. MAY CAUSE DAMAGE TO THE NERVOUS SYSTEM, BLOOD SYSTEM, KIDNEYS, LIVER. REPRODUCTIVE HAZARD. HARMFUL OR FATAL IF INHALED OR SWALLOWED. MAY CAUSE ALLERGIC SKIN AND RESPIRATORY REACTION. CAUSES SKIN AND EYE IRRITATION Do not get on skin, in eyes, or on clothing. Avoid prolonged contact with the skin. Avoid breathing vapors and fumes. Do not take internally. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Wear gloves, goggles, face-shield, body protection, and NIOSH-approved respiratory protection, as appropriate. FIRST-AID: In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. If inhaled, remove to fresh air. If ingested, induce vomiting. Get medical attention immediately. IN CASE OF FIRE: Use water fog, dry chemical, CO2, or “alcohol” foam. IN CASE OF SPILL: Vacuum released material, or use a Mercury Spill Kit. Containerize residue immediately, and label appropriately. Consult Material Safety Data Sheet for additional information. ADDITIONAL CANADIAN REGULATIONS: CANADIAN DSL/NDSL INVENTORY STATUS: Mercury is listed on the DSL Inventory. OTHER CANADIAN REGULATIONS: Not applicable. CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: Mercury is not on the CEPA Priorities Substances Lists. CANADIAN WHMIS SYMBOLS: D1B: Materials Causing Immediate and Serious Toxic Effects/Toxic Material D2A: Materials Causing Other Toxic Effects/Very Toxic Material D2B: Materials Causing Other Toxic Effects/Toxic Material E: Corrosive Material

16. OTHER INFORMATION PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc. 9163 Chesapeake Drive, San Diego, CA 92123-1002 (858) 565 - 0302

DATE OF PRINTING: May 1, 2000

The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. Bethlehem Apparatus Company responsibility for injury to the vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, Bethlehem Apparatus Company for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in his use of the material.

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DEFINITIONS OF TERMS A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the following: CAS #: This is the Chemical Abstract Service Number which uniquely identifies each constituent. EXPOSURE LIMITS IN AIR: ACGIH - American Conference of Governmental Industrial Hygienists, a professional association which establishes exposure limits. TLV - Threshold Limit Value - an airborne concentration of a substance which represents conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour Time Weighted Average (TWA), the 15-minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin absorption effects must also be considered. OSHA - U.S. Occupational Safety and Health Administration. PEL - Permissible Exposure Limit - This exposure value means exactly the same as a TLV, except that it is enforceable by OSHA. The OSHA Permissible Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated. The phrase, “Vacated 1989 PEL,” is placed next to the PEL which was vacated by Court Order. IDLH - Immediately Dangerous to Life and Health - This level represents a concentration from which one can escape within 30-minutes without suffering escape-preventing or permanent injury. The DFG - MAK is the Republic of Germany’s Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Safety and Health Administration (OSHA). NIOSH issues exposure guidelines called Recommended Exposure Levels (RELs). When no exposure guidelines are established, an entry of NE is made for reference. HAZARD RATINGS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: Health Hazard: 0 (minimal acute or chronic exposure hazard); 1 (slight acute or chronic exposure hazard); 2 (moderate acute or significant chronic exposure hazard); 3 (severe acute exposure hazard; onetime overexposure can result in permanent injury and may be fatal); 4 (extreme acute exposure hazard; onetime overexposure can be fatal). Flammability Hazard: 0 (minimal hazard); 1 (materials that require substantial pre-heating before burning); 2 (combustible liquid or solids; liquids with a flash point of 38-93°C [100-200°F]); 3 (Class IB and IC flammable liquids with flash points below 38°C [100°F]); 4 (Class IA flammable liquids with flash points below 23°C [73°F] and boiling points below 38°C [100°F]. Reactivity Hazard: 0 (normally stable); 1 (material that can become unstable at elevated temperatures or which can react slightly with water); 2 (materials that are unstable but do not detonate or which can react violently with water); 3 (materials that can detonate when initiated or which can react explosively with water); 4 (materials that can detonate at normal temperatures or pressures). NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0 (material that on exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials); 1 (materials that on exposure under fire conditions could cause irritation or minor residual injury); 2 (materials that on intense or continued exposure under fire conditions could cause temporary incapacitation or possible residual injury); 3 (materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short exposure causes death or major residual injury). Flammability Hazard and Reactivity Hazard: Refer to definitions for “Hazardous Materials Identification System”.

FLAMMABILITY LIMITS IN AIR: Much of the information related to fire and explosion is derived from the National Fire Protection Association (NFPA). Flash Point - Minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air. Autoignition Temperature: The minimum temperature required to initiate combustion in air with no other source of ignition. LEL - the lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL - the highest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. TOXICOLOGICAL INFORMATION: Human and Animal Toxicology: Possible health hazards as derived from human data, animal studies, or from the results of studies with similar compounds are presented. Definitions of some terms used in this section are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LC50 - Lethal Concentration (gases) which kills 50% of the exposed animals; ppm concentration expressed in parts of material per million parts of air or water; mg/m3 concentration expressed in weight of substance per volume of air; mg/kg quantity of material, by weight, administered to a test subject, based on their body weight in kg. Other measures of toxicity include TDLo, the lowest dose to cause a symptom and TCLo the lowest concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects. Cancer Information: The sources are: IARC - the International Agency for Research on Cancer; NTP - the National Toxicology Program, RTECS - the Registry of Toxic Effects of Chemical Substances, OSHA and CAL/OSHA. IARC and NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used. Other Information: BEI - ACGIH Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in specimens collected from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV. Ecological Information: EC is the effect concentration in water. BCF = Bioconcentration Factor, which is used to determine if a substance will concentrate in lifeforms which consume contaminated plant or animal matter. Coefficient of Oil/Water Distribution is represented by log Kow or log Koc and is used to assess a substance’s behavior in the environment. REGULATORY INFORMATION: This section explains the impact of various laws and regulations on the material. U.S.: EPA is the U.S. Environmental Protection Agency. DOT is the U.S. Department of Transportation. SARA is the Superfund Amendments and Reauthorization Act. TSCA is the U.S. Toxic Substance Control Act. CERCLA (or Superfund) refers to the Comprehensive Environmental Response, Compensation, and Liability Act. Labeling is per the American National Standards Institute (ANSI Z129.1). CANADA: CEPA is the Canadian Environmental Protection Act. WHMIS is the Canadian Workplace Hazardous Materials Information System. TC is Transport Canada. DSL/NDSL are the Canadian Domestic/Non-Domestic Substances Lists. The CPR is the Canadian Product Regulations. This section also includes information on the precautionary warnings which appear on the materials package label.


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021DB 6.5 MAX-RL Amorphous Fused Silica

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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Manufacturer Name: Momentive Performance Materials 22557 West Lunn Road STRONGSVILLE OH 44149

Revised: 05/29/2012 Prepared by Product Regulatory Compliance CHEMTREC 1-800-424-9300 MSDS Contact Information

1-888-443-9466 [email protected]

Formula: Inorganic HMIS Health: 1 Flammability: 0 Reactivity: 0 NFPA Health: 1 Flammability: 0 Reactivity: 0

2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW

CAUTION! Direct contact with product or dusts may cause mechanical irritation. Form: Solid Color: Colorless Odor: Odorless

POTENTIAL HEALTH EFFECTS

INGESTION

Not an anticipated route of exposure. SKIN

Dusts may cause mechanical irritation. INHALATION

Not an anticipated route of exposure. Inhalation of dusts may cause respiratory tract irritation. EYES

Direct contact with product or dusts may cause mechanical irritation. MEDICAL CONDITIONS AGGRAVATED

Pre-existing skin or respiratory diseases. SUBCHRONIC (TARGET ORGAN )

None known.


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CHRONIC EFFECTS / CARCINOGENICITY This product or one of its ingredients present at 0.1% or more is NOT listed as a carcinogen or suspected carcinogen by NTP, IARC, or OSHA.

ROUTES OF EXPOSURE

Inhalation; Dermal

3. COMPOSITION/INFORMATION ON INGREDIENTS PRODUCT COMPOSITION CAS-No. WGT. % A. HAZARDOUS B. NON-HAZARDOUS Silica, vitreous 60676-86-0 60 - 100 %

4. FIRST AID MEASURES INGESTION

If swallowed, do NOT induce vomiting. Give a glass of water. Never give liquid to an unconscious person. Do not induce vomiting. Get medical attention if symptoms persist.

SKIN

Wash area with soap and water. Wash contaminated clothing before reuse. Get medical attention if symptoms persist.

INHALATION

If inhaled, remove to fresh air. If not breathing give artificial respiration using a barrier device. If breathing is difficult give oxygen. Get medical attention.

EYES

Do not rub eye. Immediately flush with plenty of water or eyewash solution for up to 10 minutes. The eyelids should be held open and away from the eyeball to ensure that all surfaces are flushed thoroughly. If eye irritation persists: Get medical advice/attention.


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NOTE TO PHYSICIAN There is no specific antidote. Treatment is symptomatic and supportive.

5. FIRE-FIGHTING MEASURES FLASH POINT: does not flash IGNITION TEMPERATURE: No data available. FLAMMABLE LIMITS LEL: No data available. FLAMMABLE LIMITS UEL: No data available. SENSITIVITY TO MECHANICAL IMPACT: No SENSITIVITY TO STATIC DISCHARGE

Sensitivity to static discharge is not expected. EXTINGUISHING MEDIA

All standard extinguishing agents are suitable. SPECIAL FIRE FIGHTING PROCEDURES

Firefighters must wear NIOSH/MSHA approved positive pressure self-contained breathing apparatus with full face mask and full protective clothing.

6. ACCIDENTAL RELEASE MEASURES ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILL ED

Wipe, scrape or soak up in an inert material and put in a container for disposal. Wash walking surfaces with detergent and water to reduce slipping hazard.

ENVIRONMENTAL PRECAUTIONS

Prevent runoff from entering drains, sewers, or streams.

7. HANDLING AND STORAGE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE

Avoid contact with skin and eyes. Avoid dust formation. Avoid breathing dust. Keep out of reach of children.

STORAGE

Keep away from heat, sparks and open flame. Keep container closed.


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8. EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS

Eye wash facilities and emergency shower must be available when handling this product.; Ventilation and other forms of engineering controls are preferred for controlling exposures. Respiratory protection may be needed for non-routine or emergency situations.

RESPIRATORY PROTECTION

If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Supplied air respirators may be required for non-routine or emergency situations. Respiratory protection must be provided in accordance with OSHA regulations (see 29CFR 1910.134).

PROTECTIVE GLOVES

Chemical resistant gloves EYE AND FACE PROTECTION

Safety glasses with side shields OTHER PROTECTIVE EQUIPMENT

Wear suitable protective clothing and eye/face protection. Exposure Guidelines

Component CAS-No. Source Value Absence of values indicates none found PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average; INTL REL - Internal Recommended Exposure Limit OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA) effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).

9. PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT (°C): No data available. VAPOR PRESSURE (20 C) (MM HG): Not applicable VAPOR DENSITY (AIR=1): Not applicable FREEZING POINT: No data available. PHYSICAL STATE: Solid ODOR: Odorless Color: Colorless


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EVAPORATION RATE (BUTYL ACETATE=1): Not applicable SPECIFIC GRAVITY: 2.65 DENSITY: No data available. ACID / ALKALINITY (MEQ/G): No data available. pH: No data available. SOLUBILITY IN WATER (20 C): Insoluble VOLATILE ORGANIC CONTENT: Not applicable

10. STABILITY AND REACTIVITY STABILITY

Stable HAZARDOUS POLYMERIZATION.

Hazardous polymerisation does not occur. HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUC TS

In case of fire, gives off (emits):; Carbon oxides; Oxides of silicon.; Carbon monoxide is highly toxic if inhaled; carbon dioxide in sufficient concentrations can act as an asphyxiant.; Acute overexposure to the products of combustion may result in irritation of the respiratory tract.

INCOMPATIBLE MATERIALS

Hydrofluoric acid. CONDITIONS TO AVOID

None known.

11. TOXICOLOGICAL INFORMATION GENERAL

Exposure to this product, as sold and intact, will not result in exposure to amorphous fused silica. The following information is provided for exposure to dusts from grinding, sawing, sanding, abrading, or otherwise destroying the integrity of the fused silica.

ACUTE ORAL

LD50; Species: Rat; 3,160 mg/kg; ACUTE DERMAL

Remarks: No data available. ACUTE INHALATION

Remarks: No data available.


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OTHER Exposure to dusts of amorphous silica for 6 months to 30 years may result in silicosis with symptoms of cough, chest pain, dyspnea, tachypnea, marked weakness and weight loss. This pulmonary insufficiency may be characterized by diffuse nodular fibrosis, distortion of bronchi, diminished chest expansion, decreased vital capacity progresses, cor pulmonale, cardiorespiratory failure and death may occur.

SENSITIZATION

No data available. SKIN IRRITATION.

No data available. EYE IRRITATION

No data available.

12. ECOLOGICAL INFORMATION ECOTOXICOLOGY

All available ecological data have been taken into account for the development of the hazard and precautionary information contained in this Safety Data Sheet.

13. DISPOSAL CONSIDERATIONS DISPOSAL METHODS

Disposal should be made in accordance with federal, state and local regulations.

14. TRANSPORT INFORMATION

Further Information: This product is not regarded as dangerous goods according to the

national and international regulations on the transport of dangerous goods.

15. REGULATORY INFORMATION Inventories


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Australia Inventory of Chemical Substances (AICS)

y (positive listing)

EU list of existing chemical substances


Japan Inventory of Existing & New Chemical Substances (ENCS)


China Inventory of Existing Chemical Substances


Korea Existing Chemicals Inventory (KECI)


Canada DSL Inventory y (positive listing) Canada NDSL Inventory n (Negative listing) Philippines Inventory of Chemicals and Chemical Substances (PICCS)


TSCA list y (positive listing) On TSCA Inventory For inventories that are marked as quantity restricted or special cases, please contact Momentive. US Regulatory Information SARA (311,312) HAZARD CLASS

No SARA Hazards CALIFORNIA PROPOSITION 65

This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Other SCHDLE B/HTSUS: 7002.31.0000 Tubes ( empty, like pipeline)

16. OTHER INFORMATION OTHER

These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. ,C = ceiling limit NEGL = negligible EST = estimated NF = none found NA = not applicable UNKN = unknown NE = none established REC = recommended


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ND = none determined V = recommended by vendor SKN = skin TS = trade secret R = recommended MST = mist NT = not tested STEL = short term exposure limit ppm = parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status not required under 40 CFR part 720.30(h-2).

Material Safety Data Sheet Molybdenum Products Revised 10/28/11 MSDS – 0458 1. Identification of the 1.1 Product Identified: Molybdenum Products. Substance and of the Company 1.2 Uses: Lighting, furnace, electronics, medical applications. 1.3 Supplier : Elmet Technologies, Inc., 1560 Lisbon Street, Lewiston Maine 04240 1.4 Emergency Phone Number: 1-800-333-6100 2. Hazards Identification 2.1 Classification: Not a hazardous material per Regulation (EC) N0. 1272/2008 EC

or EC Directive 67/548/EEC. 2.2 Label elements: Compact metal/alloy with no risk to human health or the

environment. 2.3 Other hazards: Dusts from powder may present a fire hazard. 3. Composition/Information 3.1 Substances: Molybdenum (CAS# 7439-98-7), additions of Lanthanum Oxide on Ingredients (CAS# 1312-81-8), Silicon (CAS# 7440-21-3), Potassium (CAS# 7440-09-7) at

< 1% mass fraction. May be in powder, wire, filament of formed/machined metal parts. 3.2 Mixtures: None

4. First Aid Measures 4.1 First aid measures: Wash dust off thoroughly with soap and water. 4.2 Symptoms, effects: Inhalation, eyes – dust may cause irritation. 4.3 Medical, treatment: Consult physician after prolonged exposure to dust. There

are no components listed as carcinogen or potential carcinogen per NTP, OSHA or IARC.

5. Firefighting Measures 5.1 Extinguishing media: Dry chemical extinguishing media recommended. 5.2 Special hazards: Auto ignition is 360 degrees C for 0 – 74 micron dust.

Flammable, explosive limits not tested. Powder is a weak fire and explosion hazard. 5.3 Firefighting advice: Breathing protection in presence of dust. 6. Accidental Release 6.1 Precautions, PPE, emergency procedures: Eliminate sources of ignition. Do not Measures create dust cloud during clean up operations. 6.2 Environmental precautions: Avoid contamination of soils and water. 6.3 Containment and clean up: Vacuum or wet-sweep powder. Protect against

inhalation of dust. 6.4 Reference to other sections: None 7. Handling and Storage 7.1 Safe handling: Avoid dust formation. Use suction cleaning methods. Avoid

sources of ignition including static sparks. 7.2 Safe storage, incompatibilities: No special measures required. Store in cool, dry,

ventilated area. 7.3 Specific end uses: None – refer to section 1.2 8. Exposure Controls/ 8.1 Control parameters: OSHA PEL: 5 mg/m3; ACGIH TLV: 10 mg/m3. Personal Protection 8.2 Exposure controls: Wear goggles and repertory protection when dealing with

dust. Wear a NIOSH approved respirator if airborne concentrations exceed limits cited above.

9. Physical and 9.1 Physical, chemical properties: Appearance: silver-grey to black. Boiling Chemical Properties point: 4325 degrees C. Specific gravity: 19.3 g/cm3 @ 20 degrees C. 9.2 Other information: Will oxidize in water and become slightly soluble. Sublimes

in air at high temperature. Page 1 of 2

Material Safety Data Sheet Molybdenum Products Revised 10/28/11 MSDS – 0458 (continued) 10. Stability and 10.1 Reactivity: Not reactive. Reactivity 10.2 Chemical stability: Stable. 10.3 Possible hazardous reactions: No known hazardous reactions. 10.4 Conditions to avoid: Avoid high temperature in air. 10.5 Incompatible materials: Avoid strong oxidizers. 10.6 Hazardous decomposition products: Heat produces trioxide or hex carbonyl

hydroxide. 11. Toxicological Information 11.1 Toxicological effects: No known toxic effects. 12. Ecological Information 12.1 Toxicity: No known toxic effects. 12.2 Persistence, degradability: Stable. 12.3 Bioaccumulative potential: No evidence of bioaccumulative potential. 12.4 Soil mobility: Will oxidize in water and become slightly soluble. 12.5 Results of PBT, vPvB assessment: Does not meet criteria for these substances. 12.6 Other adverse effects: None 13. Disposal Considerations 13.1 Waste treatment: Dispose residues as metal waste. Consider reclamation or

recycling. Follow federal, state, local, national and regional regulations. 14. Transport Information 14.1 UN number: Not dangerous to transport. 14.2 UN proper shipping name: Not dangerous to transport. 14.3 Transport hazard class: Not dangerous to transport. 14.4 Packing group: Not dangerous to transport.

14.5 Environmental hazards: Not dangerous to transport. 14.6 Special user precautions: Not dangerous to transport. 14.7 Transport per annex II of MARPOL73/78, IBC code: Not dangerous to transport.

15. Regulatory Information 15.1 Safety, health, environmental regulations/legislation: No labeling required.

Obey pertinent regulations. 15.2 Chemical safety assessment: Not considered a hazardous substance. 16. Other Information Although reasonable care has been taken in the preparation of information herein,

Elmet Technologies extends no warranties, express or implied, makes no representations and assumes no responsibility to the accuracy or suitability of information for application to the purchaser’s intended, proposed of for consequences of its use. Judgments as to the suitability of information for purchaser’s purposes are purchaser’s responsibility.

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Issue Date: March 1, 2008

MATERIAL SAFETY DATA SHEET TRADE NAME (Common Name or Synonym) Aluminum Alloy

CHEMICAL NAME Aluminum billet 6061

I. INGREDIENTS EXPOSURE LIMITS

Material or Component CAS Number % Weight OSHA PEL (mg/m³) ACGIH TLV (mg/m³) Base Metal Aluminum (Al) 7429-90-5 Remainder Not Established 10.0 Metal Dust &

Oxide 5.0 Welded Fume

Alloying Elements Chromium (Cr) 7440-47-3 0.04-0.35 1.0 Chrome Metal 0.5 Chrome Metal

Copper (Cu) 7440-50-8 0.15-0.40 0.1 Fume, 1.0 Dust 0.2 Fume, 1.0 Dust

Iron (Fe) 1309-37-1 0.2-0.70 10 Oxide Fume 5 Oxide Fume

Magnesium (Mg) 1309-48-4 0.8-1.20 15 Oxide Fume 10 Oxide Fume

Manganese (Mn) 7439-96-5 0.05-0.15 5c Dust, 5c Fume 5c Dust, 1 Fume

Silicon (Si) 7440-21-3 0.40-0.8 Not Established 10 Total Dust

Titanium (Ti) 7440-32-6 0.05-0.15 15 Ti Dioxide 10 Ti Dioxide

Zinc (Zn) 1314-13-2 0.05-0.25 5 Oxide Fume 10 Dust, 5 Fume

NOTE: Aluminum alloys will be comprised of various cominations of the elements shown above. In addition, other alloying elements may be present in minute quantities. No permissable exposure limits (PEL) or threshold limit values (TLV) exist for aluminum alloys. Values shown are applicable to component elements.

II. PHYSICAL DATA MATERIAL IS (At Normal Conditions) APPEARANCE AND ODOR % VOLATILE BY

VOLUME: VAPOR

DENSITY _ LIQUID _ SOLID _ GAS _ OTHER Silvery-Grey, Odorless N/A N/A

ACIDITY/ALKALINITY pH = N/A

Melting Point Boiling Point

900-1200 N/A

ºF ºF Specific Gravity (H20 = 1) Approx. 2.5-2.9 Solubility in water (% by weight) Negligible VAPOR

PRESSURE (mm Hg at 20ºC) N/A

III. PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY PROTECTION Appropriate respirator depending upon potential

HANDS, ARMS AND BODY Appropriate gloves to prevent abrasions.

airborne contaminants and their concentrations. If exposure limits are reached or exceeded, use NIOSH approved equipment. EYES AND FACE Safety glasses or shield for selected operations

OTHER CLOTHING AND EQUIPMENToperations and safety

codes.

As required depending on

IV. EMERGENCY MEDICAL PROCEDURES INHALATION: EYE CONTACT: SKIN CONTACT: INGESTION:

Remove to fresh air; if condition continues, consult a physician. Flush thoroughly with running water to remove particulate; obtain medical attention. Remove particles by washing thoroughly with soap and water. Seek medical attention if condition persists. If significant amounts of metal are ingested, consult physician.

V. HEALTH/SAFETY INFORMATION Health For standard operations (e.g. melting, cutting, grinding), aluminum alloys present a low health risk

by inhalation and are usually considered a nuisance dust. Toxicity by ingestion -- none expected. Skin and eyes -- not an irritant. Welding and plasma cutting of alloys high in copper (2000 and 7000 series) may present the potential for overexposure to copper fumes which can result in upper respiratory tract irritation, nausea, and metal fume fever. Nickel and chromium are other alloying elements considered hazardous as fume; however, they do not present a carcinogenic or other health concerns due to their low concentrations of the chemical form in which they are present. Overexposure to lead fumes over an extended period of time can result in such troxic effects as central nervous system disturbances, renal changes, peripheral neuropathy, gastrointestinal disturbances, anemia, and chromosomal changes. The welding of aluminum alloys may generate carbon monoxide, carbon dioxide, ozone nitrogen oxides, infrared radiation and ultraviolet radiation. OCCUPATIONAL EXPOSURE LIMITES: See Product Ingredients Section I.

FLASH POINT N/A ºF AUTO IGNITION TEMPERATURE N/A ºF

FLAMMABLE LIMITS IN AIR Lower N/A % Upper N/A %

EXTINGUISHING MEDIA For molten aluminum use dry power or sand.

Fire and Explosion

FIRE AND EXPLOSION HAZARDS Aluminum tubular products do not present fire or explosion hazards under normal conditions.

EXTINGUISHING MEDIA NOT TO BE USED Do not use water or halogen agents on molten aluminum.

STABILITY _ Stable _ Unstable

INCOMPATIBILITY (MATERIALS TO AVOID) Reacts with strong acids to form hydrogen gas.

Reactivity

CONDITIONS TO AVOID Aluminum products under normal conditions are stable during use, storage and transportation. Halogen acids and sodium hydroxide in contact with aluminum may generate explosive mixtures of hydrogen. Finely divided aluminum, such as small chips and fines, will form explosive mixtures in air. It also will form explosive mixtures in air in the presence of bromates, iodates, or ammonium nitrate. Strong oxidizers cause violent reactions with considerable heat generation.

VI. ENVIRONMENTAL SPILL OR LEAK PROCEDURES Fine turnings and small chips should be swept or vacuumed. Scrap metal can be reclaimed for reuse.

WASTE DISPOSAL METHOD* Used or unused product should be disposed of in accordance with Federal, State or Local Laws and Regulations. *Disposer must comply with Federal, State and Local disposal or discharge laws.

VII. ADDITIONAL INFORMATION Do not touch cast aluminum metal or heated aluminum product without knowing metal temperature. Aluminum experiences no color change during heating. Burns could result. Series 2000 and 7000 alloys should be stress relieved prior to sawing or cutting to avoid cracking. Aluminum power must be packaged and shipped as a flammable solid. Minimize and control operations producing dust and fume.

DISCLAIMER The information in this MSDS was obtained from sources which we believe are reliable, however, the information is provided without any representation or warranty, express or implied, regarding the accuracy or correctness. The Conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product.

Item No. : Product name: HD3942 B30 0.907KG EN/CH/JP 1 of 5

Material Safety Data Sheet

Revision Date: 02/23/2007 Issue date: 02/24/2007

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name: HD3942 B30 0.907KG EN/CH/JP Item No. : Product type: Epoxy Hardener Region: United States Company address: Henkel Corporation 211 Franklin Street Olean, New York 14760

Contact Information: Telephone: 716.372.6300 Emergency Telephone: 860.571.5100 Internet: www.electronics.henkel.us

2. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components % ACGIH TLV OSHA PEL OTHER Diethylene glycol Di-(3-aminopropyl)ether 4246-51-9

60-100 None None None

Silica, amorphous, fumed, crystalline-free 112945-52-5

10-30 10 mg/m3 TWA inhalable 3 mg/m3 TWA respirable

6 mg/m3 TWA None

3. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

HMIS: Physical state: Liquid HEALTH: 3 Color: Amber FLAMMABILITY: 1 Odor: Ammoniacal PHYSICAL HAZARD: 0 Personal Protection: See Section 8

DANGER: CAUSES EYE, SKIN AND RESPIRATORY TRACT BURNS. Relevant routes of exposure: Inhalation, Skin contact, Eye contact, Ingestion Potential Health Effects Inhalation: Respiratory tract burns. Severe respiratory tract irritation. Skin contact: This material is corrosive to eyes and skin. Brief contact may cause chemical burns. Eye contact: Contact can cause pain, burns, necrosis, permanent injury, blindness. Ingestion: Ingestion causes burns of the upper digestive and respiratory tracts. Danger of perforation of the

esophagus and the stomach. Existing conditions aggravated by exposure:

Skin allergies. Dermatitis. Eczema. Other pre-existing skin conditions. Asthma. Other respiratory disorders (bronchitis, emphysema, bronchial hyperreactivity). Pre-existing eye diseases.

See Section 11 for additional toxicological information.


4. FIRST AID MEASURES

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and

shoes. Get medical attention. Wash clothing before reuse. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Check for and

remove any contact lenses. Get medical attention. Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to

an unconscious person. Get medical attention immediately.

5. FIRE-FIGHTING MEASURES Flash point: 127.22°C (261°F) Closed cup Autoignition temperature: Not available Flammable/Explosive limits-lower %: Not available Flammable/Explosive limits-upper %: Not available Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide. Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Unusual fire or explosion hazards: None Hazardous combustion products: Toxic fumes. Ammonia. Oxides of carbon, oxides of nitrogen, irritating organic vapors.

6. ACCIDENTAL RELEASE MEASURES Environmental precautions: Prevent product from entering drains or open waters. Clean-up methods: Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective

equipment during clean-up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable and closed containers for disposal.

7. HANDLING AND STORAGE

Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after

handling. Avoid all ignition sources in storing and handling this material. Keep cool in accordance with label instructions. Wear protective equipment when handling,

Storage: Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed

until ready for use. Incompatible products: Refer to Section 10.

For information on product shelf life contact Henkel Customer Service at 1-716-372-6300.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls: Use local exhaust ventilation if the potential for airborne exposure exists. Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Skin protection: Neoprene, Butyl-rubber, or nitrile-rubber gloves. Cover as much of the exposed skin area as possible

with appropriate clothing. Eye/face protection: Chemical splash goggles or safety glasses with side shields. In a splash hazard environment, chemical

goggles should be used in combination with a full face shield.


See Section 2 for exposure limits.

9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Amber Odor: Ammoniacal Vapor pressure: 0.2 mmHg pH: Alkaline Boiling point/range: Not determined Melting point/range: Not determined Specific gravity: 1.1 Vapor density: 3.6 Evaporation rate: Less than 0.1 Solubility in water: Soluble. Partition coefficient (n-octanol/water): Not available VOC content: <1%; <10 grams/liter (estimated value for resin and hardener mixed together)

10. STABILITY AND REACTIVITY Stability: Stable at normal conditions Hazardous polymerization: None under normal processing. Hazardous decomposition products: None reasonably foreseeable Incompatability: Acids. Oxidizing agents. This product slowly corrodes copper, aluminum, zinc and galvanized surfaces. Conditions to avoid: Storage with incompatible materials. Keep away from open flames, hot surfaces and sources of ignition.

11. TOXICOLOGICAL INFORMATION

Carcinogen Status Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen Diethylene glycol Di-(3-aminopropyl)ether 4246-51-9

No No No


No No No

Literature Referenced Target Organ & Other Health Effects Hazardous components Health Effects/Target Organs Diethylene glycol Di-(3-aminopropyl)ether 4246-51-9

Corrosive


Nuisance dust

12. ECOLOGICAL INFORMATION Ecological information: Not available


13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only. Recommended method of disposal: Dispose of in accordance with Federal, State and local regulations. EPA hazardous waste number: Waste from this product may be hazardous as defined under the Resource Conservation and Recovery

Act (RCRA) 40 CFR 261. Waste must be tested to determine the applicable EPA hazardous waste numbers.


The shipping classifications in this section are for non-bulk packaging only (unless otherwise specified). Shipping classification may be different for bulk packaging. U.S. Department of Transportation Ground (49 CFR): Proper shipping name: Amines, liquid, corrosive, n.o.s. ( Diethylene glycol Di-(3-aminopropyl)ether ) Hazard class or division: 8 Identification number: UN 2735 Packing group: II Exceptions: Consumer Commodity ORM-D (Not more than 1 Liter) International Air Transportation (ICAO/IATA): Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. ( Diethylene glycol Di-(3-aminopropyl)ether ) Hazard class or division: 8 Identification number: UN 2735 Packing group: II WaterTransportation (IMO/IMDG): Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. ( Diethylene glycol Di-(3-aminopropyl)ether ) Hazard class or division: 8 Identification number: UN 2735 Packing group: II

15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: None. CERCLA/SARA Section 302 EHS: None. CERCLA/SARA Section 311/312: Immediate Health Hazard CERCLA/SARA 313: None. California Proposition 65: No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List. WHMIS hazard class: D.2.B, E


16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format. Prepared by: Dan Shaw, Product Safety and Regulatory Affairs Specialist

For Safety and Regulatory Information contact: Product Safety and Regulatory Affairs, Rocky Hill, CT. 860-571-5204

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from saleor use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of anykind, including lost profits.


Revision Number: 002.0 Issue date: 03/15/2012

IDH number: 646706 Product name: HYSOL EE4215 GAL A1Page 1 of 5

1. PRODUCT AND COMPANY IDENTIFICATION Product name: HYSOL EE4215 GAL A1 IDH number: 646706 Product type: Epoxy resin Item number: EE4215-B50A1 Region: United States Company address: Contact information: Henkel Electronic Materials LLC 14000 Jamboree Road Irvine, CA 92606

Telephone: 1.888.9.HENKEL (1.888.943.6535) MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW HMIS: Physical state: Liquid HEALTH: *2 Color: Black FLAMMABILITY: 1 Odor: Aromatic PHYSICAL HAZARD: 0 Personal Protection: See MSDS Section 8

WARNING: CAUSES EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE RESPIRATORY TRACT IRRITATION.

Relevant routes of exposure: Skin, Inhalation, Eyes

Potential Health Effects

Inhalation: May cause respiratory tract irritation. Skin contact: May cause allergic skin reaction. Causes skin irritation. Eye contact: Vapors may irritate eyes. Contact with eyes will cause irritation. Ingestion: Not expected under normal conditions of use.

Existing conditions aggravated by exposure:

Eye, skin, and respiratory disorders.

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR

1910.1200).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER %

Epichlorohydrin-4,4'-isopropylidene diphenol resin 25068-38-6 30 - 60 Quartz (SiO2) 14808-60-7 30 - 60 Kaolin 1332-58-7 1 - 5

4. FIRST AID MEASURES

Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is

difficult, give oxygen. If symptoms develop and persist, get medical attention.


Skin contact: Wash with soap and water. Remove contaminated clothing and footwear. If symptoms develop and persist, get medical attention. Wash clothing before reuse.

Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15

minutes. Get medical attention.

Ingestion: Do not induce vomiting. If individual is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person. Get medical attention.

5. FIRE FIGHTING MEASURES

Flash point: 248.9 °C (480.02 °F) Closed cup

Autoignition temperature: Not available.

Flammable/Explosive limits - lower: Not available.

Flammable/Explosive limits - upper: Not available.

Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as

turn-out gear.

Unusual fire or explosion hazards: Closed containers may rupture (due to build up of pressure) when exposed to extreme heat. In case of fire, keep containers cool with water spray.

Hazardous combustion products: Oxides of carbon. Irritating organic vapours. Hydrogen chloride. Phenolics.

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected

personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in a partly filled, closed container until disposal.

7. HANDLING AND STORAGE

Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and

clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep away from heat, spark and flame.

Storage: Keep in a cool, well ventilated area away from heat, sparks and open flame.

Keep container tightly closed until ready for use.

For information on product shelf life, please review labels on container or check the Technical Data Sheet.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed.


Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER

Epichlorohydrin-4,4'-isopropylidene diphenol resin None None None None

Quartz (SiO2) 0.025 mg/m3 TWA Respirable fraction.

2.4 MPPCF TWA Respirable.

0.1 mg/m3 TWA Respirable.

0.3 mg/m3 TWA Total dust.

None None

Kaolin 2 mg/m3 TWA Respirable fraction.

5 mg/m3 TWA Respirable fraction.

15 mg/m3 TWA Total dust.

None None

Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below

exposure limits.

Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should

be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available.

Skin protection: Chemical resistant, impermeable gloves.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid Color: Black Odor: Aromatic Odor threshold: Not available. pH: Not available. Vapor pressure: 2.0 mm hg Boiling point/range: Not available. Melting point/ range: Not available. Specific gravity: 1.7 Vapor density: 3.8 (Air = 1) Flash point: 248.9 °C (480.02 °F) Closed cup Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Autoignition temperature: Not available. Evaporation rate: < 1.0 Solubility in water: Not miscible or difficult to mix Partition coefficient (n-octanol/water): Not available. VOC content: 0 %; 0 g/l Estimated

10. STABILITY AND REACTIVITY

Stability: Stable at normal conditions.

Hazardous reactions: Will not occur.

Hazardous decomposition products: None reasonably foreseeable.

Incompatible materials: Strong oxidizing agents. Strong acids and strong bases. Amines.

Conditions to avoid: Store away from incompatible materials. High temperatures. Heat, flames,

sparks and other sources of ignition.



Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen

(Specifically Regulated)

Epichlorohydrin-4,4'-isopropylidene diphenol resin No No No

Quartz (SiO2) Known To Be Human Carcinogen. Group 1 No

Kaolin No No No

Hazardous components Health Effects/Target Organs

Epichlorohydrin-4,4'-isopropylidene diphenol resin Allergen, Irritant Quartz (SiO2) Immune system, Lung, Some evidence of carcinogenicity Kaolin Nuisance dust

12. ECOLOGICAL INFORMATION

Ecological information: Not available.

13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number: Not a RCRA hazardous waste.


U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None

International Air Transportation (ICAO/IATA)

Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (Bisphenol-A Epichlorhydrin resin)

Hazard class or division: 9 Identification number: UN 3082 Packing group: III

Water Transportation (IMO/IMDG)

Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol-A Epichlorhydrin resin)

Hazard class or division: 9 Identification number: UN 3082 Packing group: III Marine pollutant: Bisphenol-A Epichlorhydrin resin

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.

TSCA 12(b) Export Notification: None above reporting de minimus

CERCLA/SARA Section 302 EHS: None above reporting de minimus CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA 313: None above reporting de minimus


California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List.

WHMIS hazard class: D.2.A, D.2.B

16. OTHER INFORMATION

This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format.

Prepared by: Tricia Voghell, Regulatory Affairs Specialist

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.


300000004487 Page: 1


Product name: THERMOSET SC-104 RESIN Product Use/Class: ENCAPSULANT, PART A LORD CORPORATION 111 LORD DRIVE CARY, NC 27511-7923

TRANSPORTATION EMERGENCY: CHEMTREC 24 HR EMERGENCY NO. 800 424-9300 (Outside Continental U.S. 703 527-3887) NON-TRANSPORTATION EMERGENCY:

INFORMATION TELEPHONE: 814 868-0924

814 763-2345

EFFECTIVE DATE: 04/25/2011

2. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS Number Weight % Less Than

ACGIH TLV-TWA

ACGIH TLV-STEL

OSHA PEL-TWA

OSHA PEL-CEILING

Skin

Titanium dioxide 13463-67-7 5.0 % 10 mg/m3 N.E. 15 mg/m3

N.E. N.A.

N.A. - Not Applicable, N.E. - Not Established, S - Skin Designation

3. HAZARDS IDENTIFICATION *** EMERGENCY OVERVIEW ***: White Viscous liquid, with Slight odor. May cause eye irritation. This product contains a residual amount of a chemical substance that may cause an allergic skin and/or respiratory reaction. EFFECTS OF OVEREXPOSURE - EYE CONTACT: Eye contact may cause slight irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause mild skin irritation. EFFECTS OF OVEREXPOSURE - INHALATION: No inhalation hazard expected during normal workplace use. EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Ingestion is not an expected route of entry in industrial or commercial uses. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: IARC has designated titanium dioxide (TiO2) as Group 2B – possibly carcinogenic to humans in dust form. However, a number of long term animal studies and human epidemiology studies evaluating TiO2 and workplace exposure show insufficient evidence for carcinogenic affects. EPA, NTP and OSHA do not designate TiO2 as a carcinogen and ACGIH designates TiO2 as A4 - not classifiable as a human carcinogen. TiO2 is not present in this product as a dust and no airborne exposure is expected during application. This product contains methylpolysiloxanes which can generate formaldehyde at approximately 300 degrees F (150 C) and above, in atmospheres which contain oxygen. Formaldehyde is a skin and respiratory sensitizer, eye and throat irritant, acute toxicant, and known cancer hazard. Workplace exposure to formaldehyde is regulated by OSHA Standard 29 CFR 1910.1048. PRIMARY ROUTE(S) OF ENTRY: Skin Contact, Inhalation, Ingestion, Eye Contact

4. FIRST AID MEASURES FIRST AID - EYE CONTACT: Flush eyes immediately with large amount of water for at least 15 minutes holding eyelids open while flushing. Get prompt medical attention.

Product: THERMOSET SC-104 RESIN, Effective Date: 04/25/2011

Page: 2

FIRST AID - SKIN CONTACT: Flush contaminated skin with large amounts of water while removing contaminated clothing. Wash affected skin areas with soap and water. Get medical attention if symptoms occur. FIRST AID - INHALATION: This material is not likely to be hazardous by inhalation. However, if exposed to excessive levels of vapor or mist, remove to fresh air, give oxygen if breathing is difficult, and get immediate medical attention. FIRST AID - INGESTION: If swallowed, do not induce vomiting. Give victim one or two glasses of water or milk. Call a physician or poison control center immediately for further instructions. Never give anything by mouth if victim is rapidly losing consciousness, unconscious or convulsing.

5. FIRE-FIGHTING MEASURES

FLASH POINT: 201 °F, 93 °C 93 °C LOWER EXPLOSIVE LIMIT (%): Not Applicable Setaflash Closed Cup UPPER EXPLOSIVE LIMIT (%): Not Applicable

AUTOIGNITION TEMPERATURE: N.D. EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water Fog UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. Closed containers may rupture when exposed to extreme heat. Use water spray to keep fire exposed containers cool. During a fire, irritating and/or toxic gases and particulate may be generated by thermal decomposition or combustion. SPECIAL FIREFIGHTING PROCEDURES: Wear full firefighting protective clothing, including self-contained breathing apparatus (SCBA). If water is used, fog nozzles are preferable.

6. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Avoid breathing vapors. Notify appropriate authorities if necessary. Contain and remove with inert absorbent material. Avoid contact. Keep non-essential personnel away from spill area. Before attempting cleanup, refer to hazard caution information in other sections of the MSDS form.

7. HANDLING AND STORAGE HANDLING: Keep closure tight and container upright to prevent leakage. Avoid skin and eye contact. Wash thoroughly after handling. Do not handle until all safety precautions have been read and understood. Empty containers should not be re-used. Use with adequate ventilation. STORAGE: Avoid excessive heat. Avoid moisture contamination. Store only in well-ventilated areas. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Provide adequate general ventilation where this product is used. RESPIRATORY PROTECTION: Respiratory protection is not required under normal working conditions where adequate ventilation is present. Note: If the exposure limit for formaldehyde is exceeded, a formaldehyde-specific, formaldehyde/organic vapor combination, or airline respirator may be required. SKIN PROTECTION: Use neoprene, nitrile, or rubber gloves to prevent skin contact. EYE PROTECTION: Use safety eyewear including safety glasses with side shields and chemical goggles where splashing may occur. OTHER PROTECTIVE EQUIPMENT: Remove and wash contaminated clothing before reuse.


Page: 3

HYGIENIC PRACTICES: Wash hands before eating, smoking, or using toilet facility. Do not smoke in any chemical handling or storage area. Food or beverages should not be consumed anywhere this product is handled or stored. Wash thoroughly after handling.


ODOR: Slight BOILING RANGE: N.A. APPEARANCE: White VAPOR PRESSURE: N.D. PHYSICAL STATE: Viscous liquid VAPOR DENSITY: Not Applicable ODOR THRESHOLD: N.D. EVAPORATION RATE: Not Applicable SOLUBILITY IN H2O: Insoluble DENSITY, LB/GL: 17.7100 lb/gal pH: N.A. VOLATILE BY WEIGHT: 0.00 % FREEZE POINT: N.D. VOLATILE BY VOLUME: 0.00 % COEFFICIENT OF WATER/OIL DISTRIBUTION:

N.D.

(See section 16 for abbreviation legend)

10. STABILITY AND REACTIVITY CONDITIONS TO AVOID: Moisture. High temperatures. INCOMPATIBILITY: Strong oxidizing materials can cause a chemical reaction. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide., Oxides of silicon. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur under normal conditions. STABILITY: Product is stable under normal storage conditions.


PRODUCT LD50 (ORAL) No Data (DERMAL) No Data PRODUCT LC50 No Data

12. ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: No Information

13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Disposal should be done in accordance with Federal (40CFR Part 261), state and local environmental control regulations. If waste is determined to be hazardous, use licensed hazardous waste transporter and disposal facility.

14. TRANSPORT INFORMATION This product is NOT REGULATED for non-bulk road shipments. For the most accurate shipping information, refer to your transportation/compliance department regarding changes in package size, mode of shipment or other regulatory descriptors.

15. REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: AS FOLLOWS -


Page: 4

This product is considered hazardous as defined by 29 CFR 1910.1200 (OSHA HazCom Standard.) SARA SECTION 313 This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372. : NONE TOXIC SUBSTANCES CONTROL ACT: INVENTORY STATUS The chemical substances in this product are on the TSCA Section 8 Inventory. EXPORT NOTIFICATION This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: NONE

16. OTHER INFORMATION HMIS RATINGS - HEALTH: 1* FLAMMABILITY: 1 PHYSICAL HAZARD: 0 * - Indicates a chronic hazard; see Section 3 VOLATILE ORGANIC COMPOUNDS Calculated: 0 lb/gal, 0 g/l LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

DISCLAIMER The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this material. It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations.


300000004488 Page: 1


Product name: THERMOSET SC-104 HARDENER Product Use/Class: ENCAPSULANT, PART B

TRANSPORTATION EMERGENCY: CHEMTREC 24 HR EMERGENCY NO. 800 424-9300 (Outside Continental U.S. 703 527-3887)

LORD CORPORATION 111 LORD DRIVE CARY, NC 27511-7923

NON-TRANSPORTATION EMERGENCY: INFORMATION TELEPHONE: 814 868-0924

814 763-2345

EFFECTIVE DATE: 12/14/2007

2. COMPOSITION/INFORMATION ON INGREDIENTS THIS PRODUCT IS NOT CONSIDERED HAZARDOUS AS DEFINED BY 29 CFR 1910.1200 (OSHA HAZCOM STANDARD)

3. HAZARDS IDENTIFICATION *** EMERGENCY OVERVIEW ***: Black Viscous Liquid, with Slight odor. Low hazard for usual industrial or commercial handling. EFFECTS OF OVEREXPOSURE - EYE CONTACT: Eye contact may cause slight irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: No hazard expected in normal industrial use. EFFECTS OF OVEREXPOSURE - INHALATION: No inhalation hazard expected during normal workplace use. EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Ingestion is not an expected route of entry in industrial or commercial uses. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: This product contains methylpolysiloxanes which can generate formaldehyde at approximately 300 degrees F (150 C) and above, in atmospheres which contain oxygen. Formaldehyde is a skin and respiratory sensitizer, eye and throat irritant, acute toxicant, and known cancer hazard. Workplace exposure to formaldehyde is regulated by OSHA Standard 29 CFR 1910.1048. PRIMARY ROUTE(S) OF ENTRY: Skin Contact, Inhalation, Ingestion, Eye Contact

4. FIRST AID MEASURES FIRST AID - EYE CONTACT: Flush eyes immediately with large amount of water for at least 15 minutes holding eyelids open while flushing. Get prompt medical attention. FIRST AID - SKIN CONTACT: Flush contaminated skin with large amounts of water while removing contaminated clothing. Wash affected skin areas with soap and water. Get medical attention if symptoms occur. FIRST AID - INHALATION: This material is not likely to be hazardous by inhalation. However, if exposed to excessive levels of vapor or mist, remove to fresh air, give oxygen if breathing is difficult, and get immediate medical attention. FIRST AID - INGESTION: If swallowed, do not induce vomiting. Give victim one or two glasses of water or milk. Call a physician or poison control center immediately for further instructions. Never give anything by mouth if victim is rapidly losing consciousness, unconscious or convulsing.

Product: THERMOSET SC-104 HARDENER, Effective Date: 12/14/2007

Page: 2

5. FIRE-FIGHTING MEASURES

FLASH POINT: 201 °F, 93 °C 93 °C LOWER EXPLOSIVE LIMIT (%): Not Applicable Setaflash Closed Cup UPPER EXPLOSIVE LIMIT (%): Not Applicable

AUTOIGNITION TEMPERATURE: N.D. EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water Fog UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. Closed containers may rupture when exposed to extreme heat. Use water spray to keep fire exposed containers cool. During a fire, irritating and/or toxic gases and particulate may be generated by thermal decomposition or combustion. SPECIAL FIREFIGHTING PROCEDURES: Wear full firefighting protective clothing, including self-contained breathing apparatus (SCBA). If water is used, fog nozzles are preferable.

6. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Avoid breathing vapors. Notify appropriate authorities if necessary. Contain and remove with inert absorbent material. Avoid contact. Keep non-essential personnel away from spill area. Before attempting cleanup, refer to hazard caution information in other sections of the MSDS form.

7. HANDLING AND STORAGE HANDLING: Keep closure tight and container upright to prevent leakage. Avoid skin and eye contact. Wash thoroughly after handling. Do not handle until all safety precautions have been read and understood. Empty containers should not be re-used. Use with adequate ventilation. CAUTION! Releases hydrogen (flammable gas) on contact with strong acid or strong base. STORAGE: Store only in well-ventilated areas. Keep container closed when not in use. Avoid excessive heat. Avoid moisture contamination.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS: Provide adequate general ventilation where this product is used. RESPIRATORY PROTECTION: Respiratory protection is not required under normal working conditions where adequate ventilation is present. Note: If the exposure limit for formaldehyde is exceeded, a formaldehyde-specific, formaldehyde/organic vapor combination, or airline respirator may be required. SKIN PROTECTION: Use neoprene, nitrile, or rubber gloves to prevent skin contact. EYE PROTECTION: Use safety eyewear including safety glasses with side shields and chemical goggles where splashing may occur. OTHER PROTECTIVE EQUIPMENT: Remove and wash contaminated clothing before reuse. HYGIENIC PRACTICES: Wash hands before eating, smoking, or using toilet facility. Do not smoke in any chemical handling or storage area. Food or beverages should not be consumed anywhere this product is handled or stored. Wash thoroughly after handling.


ODOR: Slight BOILING RANGE: N.A. APPEARANCE: Black VAPOR PRESSURE: N.D. PHYSICAL STATE: Viscous Liquid VAPOR DENSITY: Not Applicable


Page: 3

ODOR THRESHOLD: N.D. EVAPORATION RATE: Not Applicable SOLUBILITY IN H2O: Insoluble DENSITY, LB/GL: 17.7200 lb/gal pH: N.A. VOLATILE BY WEIGHT: 0.00 % FREEZE POINT: N.D. VOLATILE BY VOLUME: 0.00 % COEFFICIENT OF WATER/OIL DISTRIBUTION:

N.D.

(See section 16 for abbreviation legend)

10. STABILITY AND REACTIVITY CONDITIONS TO AVOID: Moisture. High temperatures. Contact with acids, bases, and many metals and metallic oxides will liberate hydrogen which is a flammable gas. INCOMPATIBILITY: Strong acids, bases, and strong oxidizers. Reacts with water or alcohol in the presence of acids or bases to release hydrogen (a flammable gas). HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide. Oxides of silicon. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur under normal conditions. STABILITY: Product is stable under normal storage conditions.


PRODUCT LD50 (ORAL) No Data (DERMAL) No Data PRODUCT LC50 No Data

12. ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: No Information

13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Disposal should be done in accordance with Federal (40CFR Part 261), state and local environmental control regulations. If waste is determined to be hazardous, use licensed hazardous waste transporter and disposal facility.

14. TRANSPORT INFORMATION This product is NOT REGULATED for non-bulk road shipments. For the most accurate shipping information, refer to your transportation/compliance department regarding changes in package size, mode of shipment or other regulatory descriptors.

15. REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: AS FOLLOWS - This product is not considered hazardous as defined by 29 CFR 1910.1200 (OSHA HazCom Standard.) SARA SECTION 313 This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: NONE


Page: 4

TOXIC SUBSTANCES CONTROL ACT: INVENTORY STATUS The chemical substances in this product are on the TSCA Section 8 Inventory. EXPORT NOTIFICATION This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: NONE

16. OTHER INFORMATION HMIS RATINGS - HEALTH: 1* FLAMMABILITY: 1 PHYSICAL HAZARD: 0 * - Indicates a chronic hazard; see Section 3 VOLATILE ORGANIC COMPOUNDS

Calculated 0 lb/gal, 0 g/l LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

DISCLAIMER The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this material. It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations.

MATERIAL SAFETY DATA SHEET 3M(TM) FP-301 COLORED HEAT SHRINK TUBING 10/07/09

_________________________________________________________________________________________________ Page 1 of 7


Copyright, 2009, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: 3M(TM) FP-301 COLORED HEAT SHRINK TUBING MANUFACTURER: 3M

DIVISION: Electrical Markets Division

ADDRESS: 3M CenterSt. Paul, MN 55144-1000

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)

Issue Date: 10/07/09Supercedes Date: 02/02/01

Document Group: 07-0698-6

Product Use:Intended Use: Electrical

SECTION 2: INGREDIENTS

Ingredient C.A.S. No. % by WtFLAME RETARDANT POLYOLEFIN Mixture 100

This product complies with Directive 2002/95/EC of the European Parliament on the Restriction of Hazardous Substances ( RoHS)

SECTION 3: HAZARDS IDENTIFICATION

3.1 EMERGENCY OVERVIEW

Odor, Color, Grade: Tubing, various sizes and colorsGeneral Physical Form: Solid Immediate health, physical, and environmental hazards: May cause thermal burns.

3.2 POTENTIAL HEALTH EFFECTS

Eye Contact:Vapors from heated material may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or


_________________________________________________________________________________________________ Page 2 of 7

hazy vision.

During heating: Thermal Burns: Signs/symptoms may include severe pain, redness and swelling, and tissue destruction.

Skin Contact:During heating:

Thermal Burns: Signs/symptoms may include intense pain, redness and swelling, and tissue destruction.

Inhalation:Vapors from heated material may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

Ingestion:No health effects are expected.

SECTION 4: FIRST AID MEASURES

4.1 FIRST AID PROCEDURES

The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.

Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. DO NOT ATTEMPT TO REMOVEMOLTEN MATERIAL. Get immediate medical attention.

Skin Contact: Immediately flush skin with large amounts of cold water for at least 15 minutes. DO NOT ATTEMPT TO REMOVE MOLTEN MATERIAL. Cover affected area with a clean dressing. Get immediate medical attention.

Inhalation: If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention.

If Swallowed: No need for first aid is anticipated.

SECTION 5: FIRE FIGHTING MEASURES

5.1 FLAMMABLE PROPERTIES

Flash Point No Data Available


_________________________________________________________________________________________________ Page 3 of 7

OSHA Flammability Classification: Not Applicable

5.2 EXTINGUISHING MEDIAUse fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).

5.3 PROTECTION OF FIRE FIGHTERS

Special Fire Fighting Procedures: See Hazardous Decomposition section for products of combustion. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).

Unusual Fire and Explosion Hazards: Not applicable. No unusual effects are anticipated during fire extinguishing operations. Avoid breathing the products and substances that may result from the thermal decomposition of the product or the other substances in the fire zone. Keep containers cool with water spray when exposed to fire to avoid rupture.

Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Accidental Release Measures:

Not applicable.

In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.

SECTION 7: HANDLING AND STORAGE

7.1 HANDLINGAvoid breathing of vapors. Do not ingest. Avoid skin contact with hot material. Avoid eye contact with vapors, mists, or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. For industrial or professional use only. Avoid contact with oxidizing agents. Avoid eye contact with dust or airborne particles.

7.2 STORAGEStore under normal warehouse conditions.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 ENGINEERING CONTROLSProvide appropriate local exhaust for cutting, grinding, sanding or machining. Provide appropriate local exhaust when product is heated.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)

8.2.1 Eye/Face ProtectionAvoid eye contact with vapors, mists, or spray.The following eye protection(s) are recommended: Safety Glasses with side shields. Avoid eye contact with vapors or smoke


_________________________________________________________________________________________________ Page 4 of 7

resulting from overheating or when used in confined areas.

8.2.2 Skin ProtectionAvoid skin contact. Avoid skin contact with hot material.

8.2.3 Respiratory ProtectionAvoid breathing of dust created by cutting, sanding, grinding or machining. Use a positive pressure supplied-air respirator if there is a potential for exposure from an uncontrolled release, exposure levels are not known, or under any other circumstances where air-purifying respirators may not provide adequate protection.Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and P95 particulate prefilters. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.

8.2.4 Prevention of SwallowingNot applicable.

8.3 EXPOSURE GUIDELINES

None Established

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Odor, Color, Grade: Tubing, various sizes and colorsGeneral Physical Form: Solid

Flash Point No Data Available

Specific Gravity 1.3 [Ref Std: WATER=1]pH Not ApplicableMelting point No Data AvailableSolubility In Water Not ApplicableSolubility in Water NilEvaporation rate Not ApplicableVolatile Organic Compounds Not ApplicableKow - Oct/Water partition coef Not ApplicablePercent volatile Not ApplicableVOC Less H2O & Exempt Solvents Not ApplicableViscosity Not Applicable

SECTION 10: STABILITY AND REACTIVITY

Stability: Stable.


_________________________________________________________________________________________________ Page 5 of 7

Materials and Conditions to Avoid: 10.1 Conditions to avoidNone known 10.2 Materials to avoidNone known

Hazardous Polymerization: Hazardous polymerization will not occur.

Hazardous Decomposition or By-Products

Substance ConditionAldehydes Oxidation, heat or reactionCarbon monoxide During CombustionCarbon dioxide During CombustionHydrogen Bromide During CombustionIrritant Vapors or Gases At Elevated Temperatures - If overheated during

shrinkOxides of Antimony During CombustionOxides of Sulfur During CombustionToxic Vapor, Gas, Particulate During Combustion

Hazardous Decomposition: Heating product beyond temperature recommended by instruction sheet may cause release of the following compounds: Benzene, Toluene, Formaldehyde, Acetaldehyde, and Hydrogen Bromide.

SECTION 11: TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.

SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION

Not determined.

CHEMICAL FATE INFORMATION

Not determined.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Method: Dispose of waste product in a sanitary landfill. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste.

EPA Hazardous Waste Number (RCRA): Not regulated

Since regulations vary, consult applicable regulations or authorities before disposal.


_________________________________________________________________________________________________ Page 6 of 7

SECTION 14:TRANSPORT INFORMATION

Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.

SECTION 15: REGULATORY INFORMATION

US FEDERAL REGULATIONSContact 3M for more information.

311/312 Hazard Categories:Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No

STATE REGULATIONSContact 3M for more information.

CHEMICAL INVENTORIESThis product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.

Contact 3M for more information.

INTERNATIONAL REGULATIONSContact 3M for more information.

WHMIS: Hazardous

This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: OTHER INFORMATION


_________________________________________________________________________________________________ Page 7 of 7

NFPA Hazard ClassificationHealth: 1 Flammability: 1 Reactivity: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of the product have not changed. We encourage you to reread the MSDS and review the information.

No revision information is available.

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.

3M MSDSs are available at www.3M.com

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