Upload
truongbao
View
218
Download
0
Embed Size (px)
Citation preview
156
n rmn TECHNICAL MEMORANDUMEMJ CXAIRE MUNIdKAL WELL FIELD
EAU C1AIKE, WISCCNSIN
Septarber 1987
PERFORMANCE OF REMEDIAL RESPONSEACTIVITIES AT UNCONTROLLED
HAZARDOUS WASTE SITESVS. EPA CONTRACT NO 68-O1-6939
COM Federal Programs CorporationCAMP DRE'SSER & McKEE INC
ROYF.WESTONINC.WOODWARD-CLYDE CONSULTANTS
CLEMENT ASSOCIATES, INC1CF INCORPORATED
CC JOHNSON & MALHOTRA, P.C
IIIIl'• — •——"••—
MASE U FIELD TECHNICAL MEMDRANDUMEMJ CLAIRE MUNICIPAL WELL FIELD
EALJ CLAIRE, WISCONSIN
September 1987
Prepared for:
U.S. Environmental Protection AgencyEmergency and Remedial Response BranchRegion V
230 South Dearborn StreetChicago, Illinois 60604
Document No. 257-RIl-KT-raFU-lWork Assignment No. 153-5LU
COMtnvironmentii •nprMorc.
CAMP DRESSER & McKEE INC.Suite WOO
A ™n«g«menf oonsutontt CNcago, Iftnota 00006»12 7W-1313
September 4, 1987Mr. Gregg KulmaActing Regional Project OfficerU.S. Environmental Protection Agency230 South Dearborn StreetChicago, Illinois 60604Ms. Joan CalabreseRemedial Project ManagerU.S. Environmental Protection Agency230 South Dearborn StreetChicago, Illinois 60604Project: RZM H - U.S. EPA Contract No. 68-01-6939Work Assignment No.: 153-5LL3Document No.: 275-RI1-KT-FBFU-1Subject: Riase H Technical Memorandum
Eau Claire Municipal Well FieldDear Mr. Kulma/Ms. Calabrese:Submitted herewith are five copies of the draft CTiase II TechnicalMsmcrandum for the Eau Claire Municipal Well Field. Ihe technicaljnenorandum serves to document the Ifcase II field activities conductedduring June through August, 1987.If you have any questions or require additional information, pleasecall either myself or Kort Stijrpson.Very truly yours,CAMP EKESSER & M=KEE, INC.
Jun YoshitaniRIM II Region V Manager
DE9GNER&CONSULTANTS
100 CORPORATE NORTH, SUITE 101ROUTE 22 AND LAKESIDE DRIVEBANNOCKBURN, ILLINOIS 60015(312)295-6020
4 September 1987
Mr. Jun Yoshitani, P .E .REM II Region V ManagerCamp Dresser & McKee Inc.200 W. Adams StreetSuite 1600Chicago, Illinois 60606Project:Work Assignment No. :Document No . :Subject:
Dear Jun:
REM II - U . S . EPA Contract No.68-01-6939153-5LL3257-RI1-RT-FBFU-1Phase II Technical MemorandumEau Claire Municipal Well Field
Submitted herewith is the draft Phase II Technical Memorandumfor the Eau Claire Municipal Well Field. The technicalmemorandum serves to document the Phase II field activitiesconducted during June through August, 1987. I have forwardedfive copies to the RPM, Ms. Joan Calabrese.If you have any questions or require additional information,please call.
Very truly yours,ROY F. WESTON, INC.
Kurt S. StimpsonProject Manager
KSS:kte
OF OCNIENTSij Sectioni i.o BfTRODucncN 1-1
1.1 Objective of Phase H Field Program 1-11.2 Scope of Work 1-32.0 SOIL GAS SURVEY 2-1
i 2.1 Introduction 2-1i 2.1 . 1 Probe Construction 2-1
2.1 .2 Probe Decontamination 2-12. 1 .3 Probe Installation and Extraction 2-12. 1 .4 Analytical Instrumentation 2-2
! "~ 2.1 .4.1 Miran IB 2-21 2 . 1 .4 .2 HNU 2-22.1 .5 Soil Gas Survey Analytical Procedures 2-32.1 .6 Quality Control Measures 2-3
I 2.1 .6.1 Miran IB 2-3\ 2. 1 .6 .2 HNU - 2-42. 1 .6 .3 Field Conditions 2-4j 2.2 Soil Gas Probe Locations 2-4i
2.2. 1 Hainan Property 2-72 .2 .2 Fire Protection Training Pit 2-72 .2 .3 Gibson Aviation 2-72 .2 .4 Rioenix Steel Corp. 2-10^- 2 .2 .5 Max Riillips & son 2-10
2.3 Soil Gas Survey Results 2-101 2 .2 . 1 Hillman Property 2-102 .2 .2 Fire Protection Training Pit 2-14
2 .2 .3 Gibscn Aviation 2-141 2 .2 .4 Rioenix Steel Corp. 2-17i 2 .2 .5 Max Riillips & Son 2-19I 2.4 Discussion of Soil Gas Results — 2-19
3.0 SURFACE SOIL SAMPLING 3-13.1 Introduction ' 3-1
3.1.1 Sampling Procedure 3-1j 3 . 1 .2 Analytical laboratory 3-1i 3 . 1 .3 Quality Control Measures 3-1
1ABIZ OF CONTENTS (Continued)
Section3.2 Surface Soil Sample locations 3-2
3.2 . 1 Fire Protection Training Pit 3-23.2 .2 Gibson Aviation 3-23 .2 .3 Rioenix Steel Corp. 3-23.2 .4 Max Riillips & Son 3-43.3 Results of Analysis 3-4
4.0 SOIL BORINGS AND SOURCE WELL INSTAUATICN 4-14.1 location of Borings 4-1
4.1 .1 Fire Protection Training Pit 4-14.1 .2 Gibson Aviation 4-14. 1 .3 Ehoenix Steel Corp 4-24.1 .4 Max Riillips & Son 4-24.2 Drilling Equipment and Procedures 4-34.3 Decontamination 4-34.4 Soil Borings 4-3
4.4. 1 Sampling Procedures and Analytical 4-3laboratory4.4.2 Quality Assurance 4-34.4 .3 Boring logs 4-34.5 Source Monitor Wen Installation 4-44.6 Source Monitor Well Development ' 4-4
5.0 PLUME H3ENITFICATICN WE1X IKSTAIIATICN 5-15.1 Irscation of Wells 5-15.2 Drilling Equipment and Procedures 5-15.3 Decontamination 5-35.4 Monitor Well Construction 5-35.5 Plume Identification Well Development 5-3
6.0 GRCUNDWAIER SAMPLING 6-16.1 Scope of Work - 6-16.2 Sairpling Methods " 6-16.3 Evaluation of Effect of Sampling Method on VDC Data 6-66.4 Groundwater Level Measurements 6-66.5 Monitoring Well Elevation Survey 6-8
LTST OF TABLES
Table2-1 Hillaan Property Summary of Soil Gas Probe Results 2-132-2 Fire Protection Training Pit Summary of Soil Gas 2-15Probe Results2-3 Gibson Aviation Summary of Soil Gas Probe Results 2-162-4 Rioenix Steel Corp. Summary of Soil Gas Probe Results 2-182-5 Max Riillips & Son Summary of Soil Gas Probe Results 2-203-1 Surface Soil Sample locations 3-34-1 Summary of Source Well Construction 4-54-2 Summary of Well Development 4-65-1 Summary of Plume Identification Well Construction 5-45-2 Summary of Well Development 5-56-1 Summary of Sampling Methods 6-36-2 Water Level Measurements and Well Elevations 6-76-3 Monitoring Well Survey Data 6-9
LTST OF FIGURES
Figure1-1 Site Map of Eau Claire, Wisconsin 1-22-1 Source Investigation Areas 2-52-2 location of Source Investigation Sampling at 2-6Hillman Property2-3 Location of Source Investigation Sampling at 2-8Fire Protection Training Pit2-4 Location of Source Investigation Sampling at 2-9
Gibson Aviation2-5 Lcxation of Source Investigation Sampling at 2-11Phoenix Steel Corp.2-6 Location of Source Investigation Sampling at 2-12
Max Riillips & Son5-1 Plume Identification Well Locations 5-26-1 Groundwater Sampling Locations 6-2
UST OF APPENDICES
Appendix A Soil Gas Paw DataAppendix B Surface Soil Analytical DataAppendix C Manitoring Well Construction Summary and Boring logsAppendix D Monitoring Well Survey DataAppendix E Analytical Parameter Lists
SECXICN 1INTRDDUCriCN
Technical Memo is part of the Remedial Investigation/FeasibilityStudy (KE/FS) of the Eau Claire Municipal Vfell Field at Eau Claire,Wisconsin. The Eau Claire Municipal Well Field is located along theQiippewa River, west and southwest of the county airport, in northernEau Claire, Wisconsin (Figure 1-1). The water table aquifer providingwater to the well field is contaminated with low levels of volatileorganic conpounds (VDCs), and trace or slightly greater quantities ofVDCs have been detected in water samples from all of the Eau Clairemunicipal wells. As part of U.S. EPA's remedial investigation (31) ofthe groundwater contamination, a Fhase U field program was initiatedin June 1987.1.1 OBJECTIVE OF HRSE H FIELD EKOGRAMThe Phase I investigation identified several areas where additionaldata and information were required, primarily to define the extent ofcontamination and locate the potential source or sources of thecontamination. The objective of the Hiase II field program was tocollect this additional data which was needed to complete the remedialinvestigation (RI) and to execute the feasibility study (FS).The specific data needed to define the contamination extent included:
o Groundwater quality data upgradient of the wellfield-Hillman contamination plume along the axis of theburied valley to define the extent of the plume;
o Groundwater quality data within the industrial parkcontamination plume along the axis of the buried bedrockvalley to define the distribution of contaminants within theplume;
o Groundwater quality data within and peripheral to the wellfield-Hillman contamination plume to confirm the existingdata on contaminant distributions and define the extent onthe plume;
o Groundwater quality data within and peripheral to theindustrial park contamination plume to confirm the existingdata on contaminant distributions and define the extent ofcontamination; _
o Water level data within the Eau Claire PI study area.ine specific data needed for source examination included:
o Groundwater quality data in the NPI well field to assess apotential source of contaminants in the industrial parkcontamination plume;
1-1
FIGURE 1-1 SITE MAP OF EAU CLAIRE, WISCONSIN 1-2
o Soil chemistry data from potential source areas to determinewhether they are contaminant sources and to characterize thenature and concentration of any sources;
o Groundwater quality data from the uppermost part of theoutwash aquifer of potential source areas to show, ifpresent, a linkage between soil contamination andgroundwater contamination.
Specific data needed for quality assurance included:o Groundwater quality data from selected wells sampled withdifferent equipment to evaluate the effect, if any, of
sampling method on reported contaminant concentrations.1-2 SOOPE OF W3RKOne field prixjidin developed to obtain the data required for completionof the PI and execution of the FS consists of three parts. The firstpart was a soil gas survey and soil surface soil sampling to identifypotential sources of contamination. The second part was a program ofsoil borings and source well installations to further characterize thepotential sources. The third part was installation of plumeidentification wells, collection of groundwater samples frctnmonitoring wells, and collection of water level measurements tofurther define and verify the extent of the contamination in thegroundwater. This Technical Memo is divided into six major sections,including this Introduction (Section 1). Section 2 describes the soilgas survey and the interpretation of its findings. Section 3describes the soil sampling and a summary of their volatile organicanalysis results. Section 4 describes the soil borings and the sourcemonitor well installation. Section 5 details the installation of theplume identification wells. Section 6 describes the groundwatersampling and water level measurements.
1-3
SECITCN 2SOIL GAS SURVEY
2.1 INTRODUCnCMThe soil gas survey began on 28 June 1987 and was completed on 16 July1987. The survey concentrated on properties within the industrialpark and the municipal airport at Eau Claire, Wisconsin. In total, 71soil probes were installed and the soil gas from them analyzed forselected volatile organic contaminants. The probes were subsequentlyextracted for decontamination and storage.2.1.1 Probe ConstructionThe soil gas probes consist of four metal parts. The four parts arethe probe shaft, the drive tip, the roller pin, and the drive cap.The probe shafts were constructed with thick-wall (.10-inch)galvanized pipe, with an inner diameter of .50 inches. The shaftswere threaded at one end and were six feet in length. The bottom 12inches of the shafts were slotted with equally spaced .10-inch slots.The nonthreaded end of the probes were bevelled with a one inch taper.One inch from the drive tip bottom, a .30-inch diameter hole wasdrilled through the probe to fit the roller pin. The drive tips were4.5 inches long and .60 in diameter, tapering to a .10-inch point.The tips were hanlpnpfl steel and also drilled with a .30-inch diameterhole. A compression roller-pin was inserted in the drive tip throughthe .30-inch hole to hold the tip to the shaft. The threaded end ofthe shaft was fitted with a steel drive cap.2.1 .2 Probe DecontaminationThe probes were decontaminated at a car wash by scrubbing themthoroughly with Alconox and water using a stainless steel wire brush.The probes were then pressure washed using hot water from the carwash, and thoroughly rinsed with distilled water and allowed to airdry. The probes were stored in Visqueen until installation.2.1 .3 Probe Insfr-anation and ExtractionIn many of the areas of the soil gas survey, the ground surface wasconpacted by large machinery or covered with blacktop or asphalt. Inthese cases, a rotodrill hammer, rented from U-Haul Rentals, was usedto drill a 3/4 inch diameter hole into the ground about 15 inchesdeep. The soil gas probes were then advanced into this hole using afence post "slam-bar11 drive hammer. In areas where the soil was notcompacted, the "slam-bar" drive hammer alone was used. The probeswere advanced approximately 4.5 feet into the ground. Afterinstallation, the threaded drive cap was sealed using tape andchain-of-custody seals. After all readings had been taken, the probeswere extracted by loosening them with a rocking motion, then twistingthem out using a large pipe wrench.
2-1
2.1 .4 ftnalyHcal InstrumentationTwo instruments were used for analyzing the soil gas in the probes:the Foxboro Miran IB portable ambient air analyzer and the HNuportable phcrtoionizatian analyzer. The HNu was used to analyze fortotal hydrocarbons, while the Miran IB was used to analyze forspecific contaminants.2.1 .4.1 Miran IBThe Miran IB is a micrcprocessor-controlled instrument that can detectand quantitatively measure organic vapors In ambient air inconcentrations from a few ppb to the percentage range. The instrumentuses a nichrome wire source to provide infrared radiation, filtered tospecific wavelengths. The sample is drawn into a gas cell by anintegral air pump at a rate of 25 to 30 liters per minute. The sampleabsorbs infrared energy from the beam. The amount of absorption,measured by the detector, is directly related to the concentration ofthe sample by Beer's law:
A - a x b x cWhere A is absorbance, a is the absorbtivity constant, b is thepathlength, and c is the concentration. The instruments electronicsdisplays the concentration as a digital readout. The Miran IBincorporates a curve correction term to correct for any deviationsfrom Beer's law.The Miran IB was used to analyze for three compounds in the soil gassurvey. These compounds and the Miran IB manufacturer's reporteddetection limits are listed below:
1,1-dichloroethane - 0.4 ppntrichloroethene - 0.2 ppnperchloroethene - 0.4 ppn
These three compounds were selected for the soil gas survey becausethey were among those found contaminating the municipal well field..The other contaminating compounds are not in the preprogrammedcompound library of the Miran IB and are not specifically quantifiableby that instrument without additional programming.2. 1 .4 .2 HNuThe HNu is a portable trace gas analyzer that employs the principle ofphotoionization for detection and measurement -of a wide variety oforganic vapors. Ifcotoionization is initiated by the absorption of aphoton of ultraviolet radiation energetic enough to ionize a moleculeand produce an instrument response, only if the ionization potential(IP) is equal to or slightly less than the ionizing energy supplied bythe instrument's UV lamp (9.5 eV, 10.2 eV, 11.7 eV). As thecontaminants of interest in this survey (chlorinated hydrocarbons)have a high IP, the 11.7 eV lamp was employed to ensure a wide rangeof detectable species.
2-2
2.1 .5 Soil Gas Survey Analytical ProceduresThe installation of the probes took place on 29 Jane and 30 June andduriiig the week of 6 July 1987. After installation of the probes inthe survey area, the probes were allowed to equilibrate for 24 hoursor more. Die soil gas was analyzed by the HNu during the week of 6July 1987 and by the Miran IB and the HNu during the week of 13 July1987.Analysis of the soil gas in the soil probe required the probe beattached directly to the analytical instrument. Ihe chain-of -custodyseals were broken and the steel drive cap at the threaded end of theshaft was replaced with a brass .20 inch hose fitting. Tygon tubingwas then used to connect the probe and the analytical instrument. TheMiran IB has a built-in air pump and can evacuate 60 liters of air perminute. An intermediary pump is not required. The pumping mechanismof the HNu probe was also deemed sufficient for evacuation of the gasin the soil probe. After the analytical instrument was attached to aprobe and the analysis of the soil gas initiated, measurements ofcontaminant concentration were recorded every 30 seconds until thesoil gas concentrations stabilized. Stabilization usually occurredwithin three to five minutes. After measurements were made, thethreaded drive cap of the probe was refitted and resealed until thenext contaminant was measured. Because the period of time requiredfor calibration for a specific contaminant, the probes in a givensurvey area were all measured for one contaminant, before proceedingon to the next contaminant compound.2. 1 .6 fri»i-j*y Control Measures2.1.6.1 Miran IBThe Miran IB analyzer contains a library of calibration data for over100 standard gases and vapors. The library consists of the following:name of compound, linear and curve correction terms (constants used inthe equation for converting absorbance to concentration) , alarm limit,wave length, pathlength and air. Due to the pre-set factorycalibrations, field calibration is limited to zeroing the instrumentand identifying background measurements.The Miran IB was zeroed in the field using chemical free compressedair obtained from PADI-certified Blue Waters Divers, Inc. in EauClaire, Wisconsin. A plastic bag was inflated with the chemical freeair, and placed over the hose of the Miran IB. The instrument thenpumped approximately 60 liters (2 minutes) of air into the detector todetermine a zero reading relative to the factory calibration. Duringthis period, the plastic bag was constantly replenished with chemicalfree air. Following the automated zeroing procedure, the instrumentintroduced an ambient air sample. The ambient sample volume extractedwas approximately 60 liters (2 minutes) , during which the instrumentintegrated and updated each reading every two seconds. Attempts tocross-check the Miran IB's calibration with simulated benzenecalibration gas were unsuccessful. The simulated benzene calibrationgas is designed to calibrate photoionization detector instruments
2-3
(such as the HNu). The Hiran IB has an infrared detector, and theinfrared absorptions of the simulated benzene gas and benzene are notthe same (conversation with Foxboro, 8 July).Before soil gas measurements, an unwind background sample wasobtained. If possible, the background sample was taken off theproperty to be surveyed. The soil gas survey was then conducted forthe calibrated compound. This procedure was followed for eachcompound analyzed.Duplicate analyses were completed for each compound at each surveyarea. The soil probe chosen for duplicate analysis was analyzed atthe beginning and end of a survey of a given area. Returning to theselected soil gas probe for re-analysis (duplicate sample), after allother probes had been surveyed, gave it an opportunity to restabilize.2. 1 .6 .2 HNuThe HNu was calibrated before and after each day's field screeningwith simulated benzene calibration gas (65 ppm) in accordance with theField Manual for the Operation. Calibration and Troubleshooting of theHNu Riotoionizer. prepared by the U.S. EPA Region V TAT (April 1985).Upwind background samples were taken before sampling a survey area.Each soil gas probe was analyzed at least twice during the HNu survey.2.1 .6 .3 Field ConditionsBecause of the sensitivity of the HNu and Hiran IB to humidity theprobes were surveyed on sunny, dry days. The survey was interruptedthe weekend of 11 and 12 July because of continuous rain in the EauClaire area.2.2 SOIL GAS EBOBE LOCATIONSIn January 1987, field investigations were undertaken to identifypossible source (s) of chloroethene and chlorcethane contamination tothe municipal well field. Hydrogeologic data gathered in Phase I ofthe RI and previous source investigations conducted by the WisconsinDepartment of Natural Resources (WENR) formed the basis foridentification of possible sources. Hydrogeologic data indicated thatthe outwash-filled bedrock valley, trending toward the municipal wellfield from the east, was the most likely area within which contaminantloading could inpact the well field. The WENR studies identified 22facilities within Eau Claire that potentially used chlorinatedethenes and ethanes. The locations of the facilities identified bythe WCNR were cross-checked with the position .of the bedrock valleyand those facilities situated along or near the valley were targetedfor further evaluation.The U.S. EPA Remedial Project Jtonager (RSM) and REM H personneltraveled to Eau Claire to conduct inspections of commercial facilitieswithin the target area. The inspection team interviewed owners oroperators and toured the facilities to make visual observations. Fromthese investigations, four facilities were identified warranting
2-4
Fir* Protect ion Trilnlng pit
SCALE <U«O0 400 800
Eau Culr* County Airport
Hlllman Property
Mix Phillips «nd Son
FIGURE 2-1SOURCE INVESTIGATION AREAS
2-5
Drlv«way
•8G-65
rO>
8O-52
n 8O-53
8ti«d
SQ-49 8Q-80
Hlllman Horn*
Sh«d
LEGEND
8G-51 Soil Gas Probe Sh«d
FIGURE 2-2 LOCATION OF SOURCE INVESTIGATION SAMPLING AT HILLMAN PROPERTY
further study (Figure 2-1). The four potential sources included MaxRiillips and Sons, Rioenix Steel Corp., Gibson Aviation, and the FireTraining Area, located at the Eau Claire Municipal Airport. It wasdecided to screen the soils of each of these areas using soil gasmethodology. In addition, soil probes were to be placed at a privateresidence, the Hlllman property, located northeast of the well field.Riase I RI data indicate higher concentrations of VDCs in groundwatarnear the Hillman property than all other wells.2.2. 1 pillman PiuuertySeven soil probes were placed in and near the Hillman property on June30. Iheir locations are shown in Figure 2-2. Two probes (SG-49, 50)were placed south of the house in the area of the private septicfield. One probe was placed to the east of the house near thedriveway (SO52) to monitor the areas of property cultivated bygardening. Three probes were placed near sheds (SG-51, 53, 54) whichcontained machinery. Much of the machinery was in disrepair and hadnot been used in years. The seventh probe was placed on the airportroad as an upgradient background probe for the Hillman property.2 .2 .2 Fire Protection Training PitA total of 13 probes were installed at the Fire Protection TrainingPit (FPTP) on 30 June 1987. The probe locations are showndiagraramatically in Figure 2-3. Four probes were placed within thepit (SOI, 5, 7, 8). Four other probes were placed along the edge ofthe FPTP (SO2, 4, 9, 12). The last four probes were placed outsidethe edge of the pit (SG-3, 6, 10, 11), Placing the probes in thispattern would allow monitoring of contamination (if any) as it spreadaway from the pit. Probe SG-13 was placed 150 feet south of the pitto serve as a background probe.A single probe (SG-48) was placed in a deep swale-to the east ofGibson Aviation and southwest of the Fire Protection Training Pit.This area appeared to be where soil was removed to help provide fillfor airport construction.2 .2 .3 Gibson AviationNine prcbes were installed at Gibson Aviation on 7 and 8 July. Thelocation of these prcbes are shown in Figure 2-4. Soil probes SG-40,41, and 44 were placed around the hanger area where degreasingsolvents are used. Prttoe SO47 was placed in a grassy area betweentwo buried tanks in front of the quonset hut and two turied tanksunder the small plane parking area. The grass had oval depressions,about 55-gallon drum size, at this location. The vegetation was brownand stunted in these depressions. Soil probes SG-43, 45 and 46 wereplaced near the shed storing solvents and near where aviation fueltrucks for Gibson Aviation are normally parked. Probe SO39 wasinstalled near the septic field, and soil probe SG-42 was placed toserve as a background probe for this area.
2-7
SQ-3•
roio>
SQ-10 •
RW25e
-N-Boundary of Fire Protection Training Pit
SG-8
SO-11
LEGEND
•SO-12 Soil Gas Probeffl RW25 Source Monitoring Well
0 50 FEET•SCALE
SG-13
FIGURE 2-3 LOCATION OF SOURCE tJVESTK3ATK>N SAMPUNG AT FRE PROTECTION TRAINING PfT
80-46
Concrete Airplane Runway
roiCD
RW24S
Fence88-180-43 *!'• ° 8O-4B
SolventStorage Shed
8Q-44
80-42
8Q-47 O88-2
Burled Aviation Fuel Tanks
Former Septic Field
8O-30 8Q-44 Soil Qas Probeo 88-2 Surface Soil SampleBRW24 Source Monitoring Well
0 80 FEET
SCALEFIGURE 2-4 LOCATION OF SOURCE INVESTIGATIVE SAMPLING OF GIBSON AVIATION
2 .2 .4 Rioenix Steel Corp.Sixteen probes were placed at Hioenix Steel Corporation on 8 July1987. Bie probes were installed after using a rotohammer to drillthrough the first 18 inches of compacted soil ard/or asphalt. ProbesSG-56, 57, 58, 59, 60 were installed in the asphalt near the southwestcorner of the main plant where drums of waste and sludge were stored.Soil probes SG-61, 62, 63 were placed to the south of the paintbuilding. IJiey were placed to detect any contamination from the paintsludges stored in drums on a concrete pad next to the south side ofthe building. Probe SG-64 was placed beside another drum storage areato south of the paint building. Probes SO65, 66, 67 were installedaround the buried paint sludge pit. Probes SG-70 and 71 wereinstalled downslope from the Bridge Fabrication shop and maintenanceshop. Probes SG-68 and 69 were placed in lower areas near fencesdividing Max Hiillips & Son and Ehoenix Steel, where runoff from bothproperties collect. The locations are shown in Figure 2-5.2.2 .5 Max Riillips & SonA total of 25 probes were installed at Max Hiillips & Son on 7 July1987 (Figure 2-6). Soil probes SG-15, 16, 17, and 18 were placed inthe northwest corner of Max Riillips & Son where the railroad entersthe property and large trucks are parked. Soil probes SO14, 19, 20and 21 were placed at corners of the maintenance garage anddowngradient from its operations. Solvent use had been suspected inthat area. Probes SG-22, 23, 24, 25, 26, and 27 were placed tosurround the large drum storage area on the north-central part of theproperty. Probe SG-33 was placed in the stained soil near largecrushed storage tanks. Probe SG-28 was placed near a drum storagearea in the west-central part of the property. Pcobes SG-29, and 30were positioned in the north and south corners of a building housing ametal crusher. A large amount of hydraulic fluid was pooled andsoaking the soil at this location. Probes SG-31, 32 and 35 wereplaced in the yard used for storing cut or crushed metal. ProbesSG-34, 36, and 37 were placed near the building housing a large metalcutter and its associated sorter. Probe SG-38 was placed on WhiteRoad to serve as a background probe for both the Max Riillips & Sonand Hioenix Steel properties.
2.3. 1 Hillman PropertyThe soil gas in the probes at the Hilknan property were analyzed forgeneral hydrocarbons on 7 July and 8 July and'13 July. The probeswere analyzed for 1,1-dichloroethane (DGA), trichloroethene (TCE), andperchloroethene (PCE) on 13 July. Table 2-1 summarizes the results ofthe survey.The total hydrocarbon readings on the HilLnan property were erraticand inconsistent. Several high readings were measured on 7 July atprobes SG-52, 53, 54 and 55; but were not confirmed the following day,8 July. A third round of measuring on 13 July did not yieldconsistent results either. An explanation for this very erratic
2-10
• WI1..?„
•»-•• t_»*-ao.
(——t——I——t——t
Palnt BulMlnBPetal 9*mm •!•*••• Art*
M-M••-•1
M-11
*wn_ ••-•§_ »•-••
9Q-9T
LEGEND• •«-•! SoH Q*a Prob*o 99-it Surlcc* Soil 8«mpto• mm 19 Sourc* Monitoring W«M
SCALE (t««t>0 BO 100
RotoBt«illulldlni
Bt««l Slorig*
Bridge Layout Ar««
Brldg* Fabrication Plant
M-TOV
FIGURE 2-5LOCATION OF SOURCE INVESTIGATION8AMPLINQ AT PHOENIX STEEL CORP.
•O1 I mtlTOH MC
APPHOVCD
2- t 1
MOflHTT•TORABI TANKBHAINABI ARIA \
HWIOB
•»» St-• .o^••-•« (
St-i ••-!————————— -xBTOHAM AMA ......
"S*M-S»
*•-•o*•*-!•
•Him STOHAM JMMA
•AINTtMANCI•AMAttC
•Wtl• O %0-••
••-IF
••-It
M-1*OM-1*
ABAHDONKO COMPACTOR
••-soCOMPACTOR
OMICI
• Till CTOHAOI AMA\0-S1
lilTAL •OUTIB MgTAL CUTTIB
r1M HCT OUI CAST
LEGEND••o-so Soil Gaa Prob*O»§-» Surface Solt Simpl*• mm it Sourc* Monitoring Well-•——<——•- R«Ilroi<f Spur
FIGURE 2-6LOCATION OF SOURCE INVESTIGATIONSAMPLING AT MAX PHILLIPS • SON 01* ENC OAtt Wi O NO
2-12
TABLE 2-1HILLMAN PROPERTY
EAU CLAIRE, WISCONSINSUMMARY OF SOIL GAS PROBE RESULTS
fwftO)
DATE ANALYZED:PROBESG-49SG-50SG-51SG-52SG-53SG-54SG-55
BACKGROUND ^NOTES:
7/13/87DCA4 .93.92 . 44 . 04 . 32 .92 .22 .7
MIRAN IB4
7/13/87TCE4 . 90.40 .30.10 .40 .9
-0 .4-0 .3
k7/13/87
PCE0 . 20 .20 . 10 .20 . 10 . 0
-0. 1-0 .2
7/7/87 7/7/871ST 2ND
000
0-1000 0-1700-16 0-1100-60 0-16100-700
HNu7/8/87
3RD0-40-10-20-20-20-10-2
7/13/874TH
01-3
50-10415-300
1-23
1-4
7/13/875TH
8-205-16
3-57-106-11
22
DCA - 1,1-dichloroethaneTCE - trichloroethenePCE - perchloroetheneneg - HNu detector immediately indicated negative values.— - not analyzedValues listed are the maximum stabilized values recorded over a period of time.
All values in ppm.
behavior may be the effects of humidity. Mr. Hillman has a very largegarden and a lush green lawn which he keeps well watered. If the soilhas a lot of moisture, the soil gas will be very humid. The HNUphotoionization detector is very sensitive to humidity and may not beable to measure the total hydrocarbons accurately under theseconditions.Measurements of perchloroethene in the soil gas were consistently lowin all probes in the Hillman property. Essentially, backgroundreadings in all cases. The same is true of trichloroethene, exceptfor probe SG-49. It stabilized at 4.9 ppm TC£ after four minutes ofmeasurements. The soil gas at this probe also contained the highestconcentrations of DCA (4.9 pgni). She concentrations of DCA inthe soil gas at the other probe locations were closer to thebackground measurement of 2.7 ppn.2 .3 .2 Fire Protection Training PitThe soil gas in probes installed at the Fire Protection Training Pitwere analyzed for general hydrocarbons on 8 July and 16 July. Thesoil gas was analyzed for trichloroethene, perchloroethene, and1,1-dichloroethane on 16 July 1987. Table 2-2 summarized the resultsof the survey. Because of the close proximity of the probes, it wasdecided measurements of the middle ring of probes were unnecessary.Hydrocarbon levels measured at the Fire Protection Training Pit wereat or near background levels for all probes measured, except SOI. Atthat probe, a reading of 50 ppn was detected. The reading was veryerratic and inconsistent.Trichloroethene measured in the soil gas ranged from 0.5 to 1.9 ppm.Background levels were measured at -0.1 to 0.5 ppm. Probe SG-1 hadthe highest level of measured trichloroethene. Perchloroethene wasdetected at background levels only from -0.9 to -0.4 ppn.Perchloroethene at the background station Treasured -0.8 ppm.The background reading for the 1,1-dicJiloroethane at the FireProtection Training Pit measured initially at 2.2 ppm, but as theinstrument was used to measure the soil gas in the probes, it driftedup to 8.9 ppm. Measurements mndft took the drift into account. TheDCA detected in the soil gas ranged from 3.7 to 6.7 ppn. Soil gasprobes SG-1 and SG-5 contained 6.0 and 6.7 ppm, respectively.2 .3 .3 Gibson AviationThe soil gas in the probes at Gibson Aviation property were analyzedfor general hydrocarbons on 8 July, 14 July, and 15 July. The probeswere used to analyze for DCA and TCE on 14 July. The survey wascompleted at Gibson Aviation on 15 July when the probes were used toanalyze for PCS. Table 2-3 summarizes the results of the survey.Total hydrocarbons, as measured by the HNu, were at zero or backgroundlevels for probes SG-39, 40, 41, and 42. The probes near the solventshed registered several values above background. Most consistent wasSG-43 where readings 5, 3-5, and 0-20 ppm were detected. At SG-44 one
2-14
TABLE 2-2PIRE PROTECTION TRAINI^ PIT
EAU CLAIRE, WISCONSINSUMMARY OF SOIL GAS PROBE RESULTSMIRAN IB*
DCA - 1,1-dichIoroethane
HNuDATE ANALYZED!
PROBE
SG-1SG-2SG-3SG-4SG-5SG-6
to SG-7<" SG-8
SG-9SG-10
V.SG-ilSG-1 2SG-13SG-48
BACKGROUNDNOTES:
7/16/87DCA6 . 0—3 .7—6 .74 .34 .74 . 1—5 .24 . 3—4 . 44 . 42 . 2
7/16/87TCE1 .9—1 .2—1 .71 .41 .51 .6—1 .20 . 5—0 .71 .2
-0.1
7/16/87PCE
-0 .6———
-0.4-0.9—
-0.8—;;—
-0 .8-0 .2-0 .8
7/8/871ST0-20-20-20-20-2
00-50-30-2
00-40-2
0-1 .50
7/16/872ND5-50120000
0-40-5
33-5
0neg
0
PCE - pe;chloroetheneTCE - trichloroetheneneg - HNu detector immediately indicated negative values.— - Not analyzed* Values listed are the maximum stabilized values recorded over a period of time.All analyses in ppm
TABLE 2-3GIBSON AVIATION
EAU CLAIRE, WISCONSINSUMMARY OF SOIL GAS PROBE RESULTS
MIRAN IB* HNuDATE ANALYZED:
PROBESG-39SG-40SG-41SG-42to
^ SG-43OBSG-44SG-45SG-46 ,SG-47
BACKGROUNDNOTES:
7/14/87DCA4 . 81 .96 .54.17. 15 .55 . 05 .59 . 91 .3
7/14/87TCE0 .6
-0.31 .00 . 61 .00 . 81 .01.11 .2
-0 .2
7/15/87PCE0 .90 . 81.11 .31 .41 .41 .21 .41 .50 . 5
7/8/871ST
—0-30-2
0-200
0-20-2neg
7/14/872NDneg
0negneg
515271
0-52
7/15/873RDneg
0negneg3-5negneg
120-500neg
DCA - l,i-dichloroethaneTCE - trichloroethenePCE - perchloroetheneneg - HNu detector immediately indicated negative values.— - not analyzed* Values listed are the maximum stabil ized values recorded over a period of time
All values in ppm.
measurement of 15 ppn was made en 14 July 1987. At SG-45, ameasurement of 27 ppn was also made, on 14 July 1987. At probe SG-46,a measurement of 120-500 ppn was detected on 15 July 1987. Althougherratic, these probes are grouped together in one area of the propertywhere solvents are used and aviation fuel pumped. The numbers are,therefore, not unreasonable. Itydrocarbons at a concentration of 0-52ppn were detected at SG-47. Ihis is an area between severalunderground aviation fuel tanks and fuel odor is noticeable in thisarea.Measurements for trichloroethene were consistently 1.0 ppn (0.6-1.2ppm) above background (-0.2) In the soil gas measured at GibsonAviation. When analyzed for perchloroethene, the soil gas was about0.75 jpn (0.8-1.5 ppn) above background (0.5 ppn). Therefore, neithercontaminant was detected in a significant concentration. Theconcentrations of 1,1-dichloroethane (DCA) detected did appear tobe significant. Every probe, except SG-40 (1.9 ppn), containedconcentrations of DCA (4.1-9.9 ppn), three ttmpq background of 1.3fpn. Probes SG-47 (9.9) , SG-43 (7.1) , and SG-41 (6.5) had the highestvalues. Soil gas probe SG-47 is near the underground fuel tanks andprobe SG-43 is downslope of the solvent shed.2 .3 .4 Rioenix Steel Oorp.The soil gas In the probes at Rioenix Steel Corp. were analyzed forgeneral hydrocarbons on 14 July. The probes were used to analyze forDCA, TCE, and PCS on 14 July. Table 2-4 summarizes the results of thesurvey.The survey of general hydrocarbons was generally negative. Allmeasurements were at background or just above. Exceptions were probeSG-56 (7 ppn), probe SG-57 (28 ppn) and probe SG-59 (6 ppm). All ofthese probes are in the area near the main plant where drummed wastewas stored.Measurements of perchloroethene varied from 0.3 ppn to 1.9 ppn. Themeasurement for background was 0.3 ppn. As measurements were takenthroughout the property, the background reading gradually drifted to1.5 ppn. Therefore, the PC£ concentrations were not significantlevels. Trichloroethene in the soil gas was measured in levels from0.4 to 2.0 ppn. The background reading for trichloroethene remainedbetween 0 to -0.4 pp&. The highest value of 2.0 ppa was found inprobe SG-57, which had the highest hydrocarbon value as well.Measurements of 1,1-dichloroethane varied firon 0.5 to 9.8 ppnthroughout the property. A background level of 2.2 ppm was measuredin ambient air. Tne areas around the main plant and downslope fromthe bridge plant contained the highest concentrations. The fiveprobes near the main plant contained DCA concentrations of 3.9-9.8ppm. Near the bridge plant, values were measured at 3.5-6.4 ppn.Soil gas probe SG-63 contained 4.5 ppa DCA and soil gas probeSG-64 contained 4.2 ppn DCA. Both of these probes are south ofthe paint building.
2-17
ro.*CD
DATE ANALYZEDPROBESG-56SG-57SG-58SG-59SG-60SG-61SG-62SG-63SG-64SG-65SG-66SG-67SG-68SG-69SG-70
» \SG-71
BACKGROUND
TABLE 2-4PHOENIX STEEL CORPORATION
EAU CLAIRE, WISCONSINSUMMARY OF SOIL GAS PROBE RESULTSMIRAN IB*
7/16/87 7/16/87 7/16/87DCA TCE PCE5 . 59 . 83 . 94 . 55 .93 . 51 .74 .54 . 20 .52 .93 . 06 . 44 . 53 .54 .22 .2
1 . 12 . 00 . 81 .21 .11.10 . 81.11 .30 . 41 .00 . 81 .71 .60 .81 .4
-0 .4
0 . 50 . 80 . 50 . 50 . 70 . 81 .11 .21.11 .31 .61 .51 .71 .91 .61 .80 . 3
HNu7/8/87 7/16/87
1ST 2ND7
28-1
6-1000neg1
negnegneg1 .52
negneg0-4neg0-2neg1
0neg2
neg1002
neg
NOTES:DCA - 1,1-dichloroethaneTCE - trichloroethenePCE - perchloroetheneneg - HNu detector immediately deflected to negative values.— - not analyzed
Values listed are the maximum stabilized values recorded over a period of timeAll values in ppm.
2 .3 .5 Max Riillips & SonThe soil gas in the probes installed at Max Hiillips & Son wasmeasured for general petroleum hydrocarbons on 8 July and 15 July.The probes were used to analyze for trichloroethene andperchloroethene on 15 July. Perchloroethene and 1,1-dichloroethanewas analyzed in the soil gas on 16 July. Table 2-5 summarizes theresults of the survey.Jtydrocarbon measurements at Max Riillips & Son were near backgroundlevels except at a few locations. Probe SG-14 near the Max Jhillips &Son maintenance garage measured values 0-15 ppn on 8 July. In thesteel scrap yard, measurements of 100-120 ppn were detected at probeSG-32 on 15 July. Measurements of 2-4 ppm were detected around thestored 55-gallon drums, but these were inconsistent. A measurement of60 ppm was detected in the stained soils where metal storage tanks arecrushed. Definite fuel odor was detected as well.Measurements of perchloroethene ranged from -0.2 to 0.9 ppm in thesoil gas. The background ambient air measured 0.0 ppm. Therefore,there was no significant perchloroethene concentrations measured atMax Riillips & Son. Trichloroethene was detected in concentrationsfrom 0.5 to 4.4 ppn. The highest values (3.1-4.4 ppm) were detectedin the stored drum and large storage tank areas. These areas also hadhigh background readings of ambient air (2.5-3.0 ppm), so thesignificance of these measurements is minimal. Measurements of 2.4,3.6, and 3.3 ppm were detected in probes SG-14, 20, and 21,respectively. These values may be significant.Concentrations of 1.1 to 9.5 ppn DCA were detected in the soil gasin probes at Max Riillipe & Son. The background ambient air levelsremained constant at 1.0 to 1.5 ppn throughout the property. Severalareas were high In value. The areas which drain the maintenancegarage had values of 8.5, 8.7, and 9.5 ppm (SG-14, 20, 21) . Theprobes around drums and storage tanks in the back of the property(SG22-28, 33) had values ranging from 3.4 to 5.0 ppn. The two probesin back of the metal crusher (SG-29, 30) had values of 7.6 and 9.4ppn. In the scrap metal yard, to the southeast of the crusher, valuesof 6 .5 , 6.1, 4.9, 3.8, 4 .6 , and 3.8 were detected (SG-31, 32, 34, 35,36, 37) . In the areas of the crusher, metal scrap yard, and cutterpools of hydraulic fluid and oil have stained much of the grounds.2.4 DISCUSSION OF SOIL GAS RESULTSThe soil gas survey found several indications of possiblecontamination sources in the municipal airfield and industrial parkarea. These source areas coincided with visually identified suspectareas. These areas were not strongly contaminated and cannot beconclusively identified as having contributed to the municipal wellfield contamination. 'The soil gas survey indicated the Hillman property was probably not acontamination source. The HNu survey for general hydrocarbons gavehigh readings at a number of probes; but, the readings could not be
2-19
roo
NOTES:
DATE ANALYZED:PROBESG-14SG-15SG-16SG-17SG-18SG-19SG-20SG-21SG-22SG-23SG-24SG-25SG-26SG-27SG-28SG-29SG-30SG-31SG-32SG-33SG-34SG-35SG-36SG-37SG-38
BACKGROUND
TABLE 2-5( MAX PHILLIPS & SON (
EAU CLAIRE, WISCONSINSUMMARY OF SOIL GAS PROBE RESULTS
MIRAN IB*7/16/87 7/15/87 7/15, 16/87
DCA TCE PCE8 .51 .11 .53 . 23 .71 .18 . 79 . 54 . 35 . 03 , 43 .53 . 74. 14 . 07 ,69 . 46 . 56. 13 . 64 . 93 , 84 . 63 . 83 . 21 .5
2 . 40 . 50 . 91 .31 .71 .13 .63 . 33 .74 . 23 . 43 .73 . 13 . 33 . 11 .61 .41 .21 .34 . 41 .20 . 61 . 51 .21 .00 . 0
0 . 4-0 .2-0 .2
0 . 30 . 4
-0. 11 .00 .9
' 0.50 . 60 . 30 .50 . 70 . 50 . 60 .90 . 90 . 50 .70 . 50 . 20 . 10 . 10 . 10 . 40 . 0
HNu7/8/87 7/15/87
1ST 2ND0-15
0000000000
0-30-2.5
01
0-10-10-30-10-20-10-20-3
0-1 .50
neg3
negnegnegnegnegneg0-40-4negnegnegneg—negneg
3100-1203
neg--negnegneg
DCA - 1,1-dichloroethaneTCE - trichloroethenePCE - perchloroetheneneg - HNu detector immediately deflected to negative values.— * not analyzedValues listed are the maximum stabilized values recorded over a period of time.
All values in ppm.
confirmed by repetition. Hie survey for perchloroethene,trichloroethene and 1,1-dichloroethane, gave primarily backgroundreadings, except for probe SG-49. Probe SG-49 was placed in thegrassy yard over the septic field for the Hilljnan's property. the 4.9ppm 1,1-dichloroethane and 4.9 ppm trichloroethane detected in thesoil gas at this probe are possibly from the septic field. If so,their presence is due to natural decomposition from the septic fieldor from some household waste which was flushed down the drain. Ineither case, it seems unlikely the septic field is the source ofmunicipal well field contamination.The Fire Protection Training Area does not appear to be a source ofthe municipal well field contamination. The soil gas in the probesdid not contain hydrocarbons, trichloroethene, and perchloroethene insignificant concentrations. The levels of 1,1-dichloroethaneconcentrations are suspect because of instrument drift at this time.The soil gas survey found three areas of possible source contaminationat Gibson Aviation. The first is by the solvent shed to the southwestof the main hanger (Figure 2-4). The detection of hydrocarbons in thesoil gas by the HNu, the presence of concentrations of 5.0-7.1 ppm1,1-dichloroethane in the soil gas are indications that somecontamination of the soil by operations at Gibson has occurred.Aviation fuel trucks regularly park beside the solvent shed. If thetrucks leaked at any time, they could contaminate the soil withhydrocarbons. The second area is between the underground fuel tanks.The soil is discolored at this location, and an aviation fuel odor isnoticeable. The HNu detected hydrocarbons in the 0-50 and DCA wasdetected at concentration of 9.9 ppm. It was determined in the fieldthat aviation fuels or gasoline may be a source of 1,1-dichloroethane.When the instrument was used to test the vapors emanating from anautomotive gas tank, readings of 32 ppm, DCA were measured. Analternative explanation may be that an ingredient of gasoline isdetected at the same wavelength as DCA by the Miran IB. A thirdsource may be the former septic field for Gibson Aviation, extendsfrom the buildings under the parking lot. Solvents and degreasersused in the hanger area were flushed into the septic field throughfloor tiles. The only indications of septic field contamination wereDCA detected in probes SG-39 (4 .8 ppm), SG-42 (4.1 ppm), and SG-41(6 .5 ppm). According to Mr. Gibson, the septic system of GibsonAviation is now hooked into the municipal sewer that serves theairport.At Phoenix Steel Corp., the soil gas survey detected hydrocarbons(6-28 ppm) and 1,1-dichloroethane (3.9-9.8 ppm) outside the southwestcorner of the main plant where drummed waste was stored. This area isa possible contamination source. The probes around the paint buildingwere contamination-free, except for DCA detected in probe SG-61(3 .5 ppm), SG-63 (4 .5 ppm), and SG-64 (4 .2 Ppm). But, because of thelarge volume of paints and solvents used, it still must be considereda possible source. The probes around the pit where paint sludges wereburied did not detect any significant contaminant concentrations, butit is still a possible source, as the paint sludges are highlyvolatile. The probes in the low areas southwest of the bridge plantcontained DCA contamination in levels of 3.5-6.4 ppm.
2-21
The soil gas survey pinpointed several areas of the Max Riillip & Sonproperty as possible sources for the nunicipal well fieldcontamination. The area southwest of the maintenance garage is a lowarea where runoff collects and oil residuals stain the ground. Probesin this area detected DCA in concentrations of 8.5-9.5 ppnu Inaddition, concentrations of 2.4-3.6 TCE were detected. Probes aroundthe drum storage area contained DCA in concentrations from 3.4-5.0ppn. The concentrations of TCE in these probes were 3.1-4.2 ppn.This suggests some solvents drained from the drums when they werestored. The practice of Max Riillips & Son of crushing large storagetanks and letting them drain the residuals indicates another possiblesource. The soils are heavily stained in this area and surfacereadings of 60 ppm with the HNu were recorded. The final possiblesource area is the steel storage area between the crusher and largecutter. Pools of hydraulic fluid and oil are found around thebuildings and the soil gas probes indicate values of DCA (SG-30,9.4 ppn) and hydrocarbons (SG-32, 100-120).In summary, possible contaminant sources were identified at GibsonAviation, Ricenix Steel, and Max Riillips & son. They are itemized asfollows:Possible sources at Gibeon Aviation include:
o Solvent shed to the southwest of main hanger;o Area between the underground fuel tank; and,o The former septic field.
Possible sources at Phoenix Steel include:o Haste storage area at southwest corner of main plant;o Paint sludge storage areas south of paint building; and,o The exhumed paint sludge pit.
Possible sources at Max Riillips & Son include:o Drainage area southwest of maintenance garage;o Drum storage area;o Crushed storage tank area; and,o The steel storage area around the compactor and metal
cutter.Individually, none of these possible sources would appear to be thesole contaminant source of the solvents found in the municipal wellfield, but collectively, they may be significant contributors.
2-22
SECTICN 3SURFACE SOIL SAMPLING
3.1 INTRODUCTIONAfter the soil gas survey, a program of surface soil sampling wasinitiated. The intent of the surface soil sampling was to confirmareas of contamination found ty the soil gas survey and to pinpointlocations of soil borings that were to be turned into sourcemonitoring wells. After extensive consultation with the U.S. EPArepresentative on site, 15 samples were collected on 24 July 1987 andthree samples collected on 29 July 1987.3.1.1 Sampling ProcedureSoil samples were taken from the top 6 to 12 inches of soil in theselected locations. A shovel was used to dig a shallow trench withvertical walls. A disposable sterile scoop was used to scrape soilaway from the trench wall to reveal undisturbed soils. A disposablesterile scoop was used to transfer the soil to a 40 ml glass vial witha Teflon top. The vial was labeled and sealed with plastic tape. Thesamples were stored in an iced cooler until transported to PACELaboratories, Inc. for analysis.3 . 1 .2 Analytical laboratoryThe soil samples were analyzed by PACE laboratories, Inc. ofHinneapolis, Minnesota. The samples were analyzed in accordance withU.S. EPA Method 5030 (sample preparation and extraction) and U.S. EPAAnalytical Method 601. The samples were analyzed for eight specificvolatile organic conpounds on a quick turn-around (24 hour) basisinstead of CLP (U.S. EPA Contract laboratory Program) criteria. Theeight compounds and the requested detection limits are listed below:
Compound Detection T.iTnit fug/tart1 , 1-dichloroethene 1. 0l,l-<Uchloroethane 0.51,1,1-trichloroethane 0.5trichloroethene 0.5tetrachloroethene 0.5cis-l,2-dichloroethene i.otrans-l,2-dichloroethene 1.01 , 2-dichloroethane 0_, 5
3. 1 .3 Quality Control MeasuresThe surface samples were placed in clean glassware from I Qiem.Disposable sterile scoops were used to transfer the soil to theglassware. A duplicate sample (SS-16DUP) was taken from the FireProtection Training Pit and a blank (SS-17 BLANK) of diatomaeous earthwas included. Samples SS-1 through SS-15 (sampled 24 July) were
3-1
transported in an iced cooler to PACE laboratories, Inc. by car by aU.S. EPA representative. Qiain-of -Custody forms were completed atPACE laboratories, Inc. by the EPA representative and custodytransferred to the lab. The second group of samples were shipped inan iced cooler to PACE Laboratory by Federal Express.3.2 SURFACE SOIL SAMPLE LOCATIONSThe locations of the surface soils are shown on Figures 2-2 to 2-6.Table 3-1 lists the soil samples and a brief description of theirlocation. No surface soil samples were taken at Hillman's property asthat location was not considered a probable source.3.2. 1 Fire Protection Training Pit
surface soils were sampled on 29 July 1987 at the center of theFire Protection Training Pit. Ihe first was labeled SS-16, the secondwas a duplicate sample SS-16 DUP. In addition, a blank sample wasprepared of diatomaceous earth and labeled SS-17 BLANK.3 .2 .2 Gibson Aviation
surface soil samples were taken from the Gibson Aviation property.Sample SS-1 was taken between soil gas probes SG-43 and SG-45 directlynorth of shed containing solvents. This location was chosen becauseof the solvents and because the soil gas survey had measuredhydrocarbons in concentrations of 3.5-500 ppm and 1,1-dichloroethane(DCA) in concentrations 5.0-7.1 ppm.A second sample (SS-2) was taken beside probe SG-47. The grass wasindented with curcular impressions like 55-gallon drums. When thesample was taken, a strong petroleum odor was noted. Ihe soil gassurvey had detected 1,1-dichloroethane at 9.9 ppm and hydrocarbons at50 ppm.3 .2 .3 Ehoenix Steel Corp.Four surface soil locations were sampled on 24 July 1987. Two ofthese samples (SS-9 and SS10) were taken in soils surrounding theburied paint sludge pit. Soil sample SS-9 was taken near probe SG-66and soil sample SS-10 was taken near probe SG-67. Soils were,therefore, sampled to the north and to the west of the pit.Sample SS-11 was taken beside the stored drums south of the paintbuilding. These drums were filled with sludge and some had bulgedconsiderably in the sun because of vapor pressure from materialsinside them. "'Surface soil sample SS-12 was taken in the steel storage area to thewest of the main plant. This location was the closest to the cornerof the main plant where wastes were stored in drums. Soil gasesmeasured in this area contained concentrations at 5-10 ppm DCA andup to 28 ppm total hydrocarbons.
3-2
TABLE 3-1SURFACE SOIL SAMPLE LOCATIONS
SAMPLE PROPERTYSS-1 Gibson AviationSS-2 Gibson AviationSS-3 Max Phillips & SonSS-4 Max Phillips & SonSS-5 Max Phillips & SonSS-6 Max Phillips & SonSS-7 Max Phillips & SonSS-8 Max Phillips & SonSS-9 Phoenix Steel Corp.SS-10 Phoenix Steel Corp.SS-11 Phoenix Steel Corp.SS-12 Phoenix Steel Corp.SS-13 Max Phillips & SonSS-14 Max Phillips & SonSS-15 Max Phillips & SonSS-16 Fire Protection Training PitSS-16DUP Fire Protection Training PitSS-17BLANK Fire Protection Training Pit
LOCATIONNorth of solvent shed.Between underground fuel tanks.Southwest of maintanence garage.Drum site by SG-13 on south side.Drum site by SG-25 on west side.Drum site by SG-24 on north side.Storage tank draining area by SG-33.Rear drum storage area by SG-28,North of paint sludge pit by SG-66.West of paint sludge pit by SG-67.By SG-64 just below drum platform.West 100 feet of SW corner Main Plant10 feet North of abandoned crusher.Southwest 10 feet of SG-21.West 100 feet of SG-21.In center of Pit.In center of Pit.Blank of Diatomaceous Earth.
3 .2 .4 Max Riillips & SonSeveral surface soil samples were extracted from the area downslope ofthe maintenance garage at Max Fhillips & Son. Soil sample SS-3 wastaken beside probe SG-20 in a drainage swale. Concentrations at7.7-9.5 ppm of DCA and 2.4-3.6 ppm of trichloroethene (TCE) weremeasured in probes in this area. Additional soil samples were takenfrom oil-stained soils near the abandoned crusher (SS-13); from thedrainage swale near probe SG-21 (SS-14); and from the low ponding areanear the fence dividing Max Riillips & Son from Rioenix Steel Corp.properties (SS-15).Three surface samples were extracted from soils on the north, south,and west sides of the drum storage area (SS-4, SS-5 and SS-6).Concentrations of 3.4-5.0 ppn DCA and 3.1-4.2 ppn TCE had beendetected in the soil gas in this area. Several drums were labeledtrichloroethene. Sample SS-5 was taken immediately beside one suchdrum. Sample SS-6 was taken beside several drums labeled HazardousWaste with EPA codes on them.Surface soil sample SS-7 was taken from the stained soils below largecrushed storage tanks. Petroleum hydrocarbons were detected inconcentrations up to 60 ppn on the surface next to the soils at thislocation and concentrations of 3.6 ppm DCA and 4.4 ppm TCEmeasured in the soil gas. One further soil sample (SS-8) was takenbeside drums near probe SG-28. Higher background ratings of DCAwere detected in this area. All 10 surface soil locations at the MaxRiillips & Sons' site were sampled on July 24, 1987.
3.3 RESULTS OF ANALYSISAnalysis of the surface soil samples determined none of them containedthe eight compounds listed in Section 3 . 1 .2 in concentrations at orhigher than the requested detection limits. Therefore, the solvents thatcontaminate the groundwater did not remain in the first 12 inches ofsoil or the solvent contaminatian occurs at other locations. Thecomplete report of PACE laboratories, listing the cornpounds analyzedand detection limits, is included in Appendix B.
3-4
SECITCN 4SOIL BORINGS AND SOURCE WELL INSTALLATION
4.1 LOCATION OF SOIL BORINGSThe second part of the field program consisted of source soil boringsand source monitor well installation. The Sampling and Analysis Planstates that the soil boring locations were to be based on visualobservations (such as stained soils), field conditions (topography,access, utilities, site operations, etc.), and the soil gas survey.Surface soil samples were taken with the intent of identifyinglocations with the greatest concentrations of volatile contaminants.The borings were to be placed at these locations.The soil gas survey did not identify any obvious sources. It dididentify possible contributing sources, but the surface soil samplesdid not verify any of these locations. It was, therefore, decided toplace the borings at locations downgradient from possible contributingsources identified by visual observations and the soil gas survey.The locations were also limited by the operations at the industrialpark, especially at Max Riillips & Son and Shoenix Steel Corp. Afterconsultation with the managers at the industrial sites, U.S. EPArepresentatives, and WCKR representatives, satisfactory locations wereselected. The soil borings were completed and the source wellsinstalled from 28 July to 1 August and on 11 and 12 August 1987.4.1 . 1 Fire Protection Training Pit
One soil boring and source monitor well (HW25) was installed at theFire Protection Training Pit (Figure 2-3). Although the soil gassurvey revealed no significant contamination and the soil sample takenfrom the pit showed no solvent contamination, a source well was placeddowngradient from the pit location. It was felt that since the pithad not been used for several years, the surface soil may be clean ofvolatiles, but contaminants may have reached the groundwater at thislocation. A well at this location would also helped define the extentof the well field - Hillman contamiriant plume. This source well wasdrilled and screened 10 feet into medium-grained sandstone bedrockat depths of 55 to 65 feet.4. 1 .2 Gihson AviationOne soil boring and source monitor well (IiW24)^was installed at GibsonAviation. This location was selected to be downgradient from threeareas: the underground fuel tanks, the storage solvent shed, and theformer Gibson Aviation septic field. As described in Sections 2 .3 .2and 2 .4 , the soil gas survey detected contamination from each of theseareas. The location of the well is shown in Figure 2-4 with thesource areas, soil gas probes, and soil sample locations alsoidentified. This well was screened in outwash from 66 to 76 feet.
4-1
4. 1 .3 Ricenix Steel Corp.Ciree soil borings and source monitor wells were installed at RioenixSteel Corporation (Figure 2-5). Monitor well EW21 was installed 100feet west of the Main Plant and screened in outwash at depths of 63 to73 feet. The southwest corner of the Main Plant was identified by thesoil gas survey as a source of 1,1-dichloroethane. The placement ofthe well makes it downgradient from the Main Plant. Monitor well PW22was installed at the southwest corner of the paint building andscreened in outwash at depths of 62 to 72 feet. The well wasinstalled at this location to monitor downgradient from the two paintsludge storage areas south of the paint building. The third monitorwell, IW16, was placed directly west of the paint storage pit that hadbeen recently exhumed. It was screened in outwash at depths of 63 to73 feet. As shown in Figure 2-5, the placement of these three wellsenables the entire Fhoenix Steel plant operations area to be monitoredfor groundwater contamination.4. 1 .4 Max Riillips & SonFive soil borings and source monitor wells were installed at MaxFhillips & Son (Figure 2-6). Monitor well EW17 was installed justwest of the drum storage area and screened in outwash at depths of 60to 70 feet. Although the soil gas survey and surface soil samplesrevealed very little, the fact that drums labeled trichloroethene werein the storage area warranted placing a monitor well at this location.In the area where storage tanks were crushed and drained the soilswere obviously stained. Monitor well FW20 was set at this location tocheck the depth of contamination. It was screened in outwash atdepths of 64 to 74 feet. If chemical storage tanks have been crushedand drained at this location, as well as fuel storage tanks, then thislocation may be a major contributing source. Monitor well FW18 wasplaced downgradient of the southern part of the property to monitorthe area containing the steel storage area, the crusher, and the largesteel cutter and sorter. This area had much soil staining byhydraulic oils and fuels. Also, several of the soil probes (asdescribed in Sections 2 .3 .4 and 2 .4 ) contained concentrations of1,1-dichloroethane above background. Monitor well FW18 was screenedin outwash at depths of 62 to 72 feet. A fourth monitor well (BN23)was set downgradient from the maintenance garage and northeast of theabandoned crusher by the railroad. The soil probes in the areadetected concentrations of 1,1-dichloroethane above background and thesoils are very stained by fuels and hydraulic oils. Monitor well FW23was screened in outwash at depths of 60 to 70 feet. The fifth monitorwell at Max Ifcillips & Son was placed in a low drainage-way by thefence just west of the gate connecting Rioenix Steel Corp. and MaxFhillips & Son. The well was placed so it was downslcpe from themaintenance garage of Efcoenix Steel. Soil probes in this area haddetected concentrations of 1,1-dichloroethane above background.Monitor well EW19 was screened in outwash at depths of 60 to 70 feet.
4-2
4.2 pPTTT.TMS ECXJTfMENT AND IRXEDURE5The drilling was performed by Exploration Technology, Inc. (ETI) ofMadison, Wisconsin and Wisconsin Test Drilling of Schofield,Wisconsin. BTI used a Offi 75 truck-mounted drill rig and WisconsinTest Drilling used a Central Mine Equipment CME 750 all-terrainvehicle (ATV) drill rig. Both rigs used two man crews with a fifthman used to operate the water truck and perform decontamination. Withone exception, the borings for monitor well installation were advancedusing 4.25-inch I.D. hollow stem augers. Monitor well F5-725 wasdrilled by hollow stem auger through outwash for the first 50 feet,then drilled by air rotary into sandstone to 68 feet.4.3Prior to drilling at each location, the back of the drill rigs, allhand tools, well construction materials (riser pipe and well screen)and equipment were decontaminated. Decontamination consisted of hightemperature steam cleaning using a high pressure steam jenny.
4.4 SOIL BORINGS4.4. 1 Sampling Procedures and Analytical laboratorySamples, with one exception, were taken in the soil borings at depthsof 0 feet, 2.5 feet, 5 feet, 7.5 feet, and 10 feet, and at 10 footintervals thereafter to the water table (usually to 60 feet) . Ihesamples were taken using two-inch and three-inch split spoons. Thelarger split spoon was used when a larger volume of sample wasrequired (such as when taking matrix spike or duplicate samples) .large pebbles prevented the split spoon from obtaining a sample at 5feet and 7.5 feet at IW18. The samples were successfully extracted atslightly lower depths 6 feet and 8.5 feet. The split spoons weredecontaminated by scrubbing them in an Alconcx wash, then thoroughlyrinsing them with deionized water. Ihe samples were transferred toCLP glassware (250 ml glass bottles) using sterilized disposableplastic scoops by a WESTCN geologist. The soils were examined andlogged into field books for future reference.The samples were stored in iced coolers and shipped by Federal Expressto Southwestern Lab of Tulsa, Oklahoma and Century Refining Company ofBrighton, Colorado, under the U.S. EPA's Contract laboratory Program(CLP) . The soil samples were to be analyzed for Routine AnalyticalServices (RAS) volatile organic compounds.4 .4 .2 Qnal ty Assurance -One duplicate sample was taken at every soil boring (one every 10samples) , plus one matrix spike sample was taken per 10 samples. Inaddition, trip blanks were included in each day's shipment of coolers.The duplicate samples, matrix spike samples, and trip blanks wereanalyzed for Routine Analytical Services (RAS) volatile organiccompounds.
4-3
4 ,4 . 3 Boring LogsIn general, the soil borings encountered medium to coarse, moderatelysorted quartz Bands interbedded with gravels and pebbles. Beds ofsubrounded to subangular pebbles were occasionally encountered,usually lasting six inches to a foot. In the industrial areas, thesurface soils were often stained with oils and fuels, occasionally todepths of 6 to 12 io^hes under the surface. Gravel occurredthroughout the area. FW25 was drilled into 18 feet of bedrocksandstone. The sandstone was white medium-bedded quartz arenite.Detailed descriptions are in the boring logs found in Appendix C.4.5 SOURCE MDNi'lUK WFTT. INSTALLATIONAll source monitor wells were constructed of stainless steel 2 inchI.D. casing and a 2-inch I.D. stainless steel screen with 0.010-inchcontinuous slots. Hie natural sands were allowed to collapse aroundthe well screens to form a sand pack. High parity silica sands wereused to augment the natural sands, usually to ensure the sand pack wastwo to five feet above the top of the screen.Bentonite pellets (usually two buckets per well) were poured on top ofthe sand pack to make a four-foot bentonite pellet seal. The pelletswere hydrated with about 10 gallons of water and tamped with tremmiepipe. Cement bentonite grout was then pumped by tremmie pipe from thebentonite seal to the surface. A six-inch steel protective casing wasinstalled over each well and anchored with cement. A sloping cementp*H was placed around each well and the protective casing locked witha padlock.All source monitor wells were screened 10 feet, 7 feet in the presentwater table and 3 above it. Table 4-1 lists the well screenintervals. All wells were screened in the sand and gravel outwashexcept FW25, which was screened in 10 feet of sandstone bedrock.Detailed descriptions of the wells are found in the constructionsummaries in Appendix C.4.6 SOURCE MONITOR WELL ULV^'l ORg^TAll newly installed PEM source monitor wells were developed by pumpingwith a positive-displacement pump or by bailing. This insured fullflow between the aquifer and the well screen prior to sampling. Aminimum of 11 well volumes of water was removed from each well duringdevelopment. U.S. EPA REM well FW25 was developed with a bailer sinceit was screened in bedrock, it recover very slowly. Source monitorwell development data are presented in Table 4-2.
4-4
IOl
Borehole Dlaveter\Depth of Concrete
Thickness of BentoniteSealDepth of SealRiser Stick-upIn-ground RiserScreen LengthDepth of ScreenDepth of Borehole
IH16 10117
TABLE 4-1SOURCE HELL CONSTRUCTION SUMMARYEAU CLAIRE MUNICIPAL HELL FIELD
mi 8 RW19 RH2B RW21 NN22 RH23 RH24 RH2S
8 in57 ft
3 ft
(1 ft1.4 ft63 ft11 ft73 ft
73 .5 f t
8 in53 ft
3 ft
56 ft2.5 f t68 ft19 ft78 ft
7f .5 ft
B55
4
593 .62IB7272
inftft
ft3 ftftftftft
853
3
562 .6flIB7B7B
Inftft
ft4 ftftftftft
8 In56.5 ft
3 ft
59 .5 f t2.1 ft64 ftIB ft74 ft74 ft
855
3
582.63IB7375
inftft
ft2 ftftftftft
8 in54 ft
4 ft
58 ft1.1 ft62 ftIB ft72 ft72 ft
8 In51 .5 ft
4.5 f t
56 ft2.7 ft61 ftIB ft71 ft73 ft
868
4
641.66IB7677
inftft
ft1 ftftftftft
8 in49 ft
4 ft
53 ft1 .5 ft55 ftIB ft65 ft68 ft
TABLE 4-2SOURCE MONITOR HELL OEVELOPMBNT DATA
EAD CLAIRE MUNICIPAL WELL FIELD
Well No, RN16
RH17i HH18
RW19BH20RH21RH22RH23RH24RW25
Height ofDATE Water inDEVELOPED Hell (ft)08/03/8708/01/8708/01/8708/01/8708/01/8708/03/87
1 ' 08/03/8708/03/8708/03/8708/13-14/87
8777877765
Volume ofWater inWell (gal)1 .41.21 .21 .21 .41 .21 .21 .2l.i• .9
wellDevelopment Volume of Water VolumesMethod Removed (gal) RemovedPumpingPumpingPumpingPumpingPumpingPumpingPumpingPumpingPumpingBailing
100 71100 83100 83100 83100 71100 83100 83100 8310fl 10010 11
FinalDischarge
ClearClearClearClearClearClearClearClearClear
Slightly Sllty
SECTION 5FUME IDEWITFICATICN WELLS
5.1 IDCRTION .Riase I sampling results indicated the presence of two VDCcontamination plumes. One, narrow and well defined, occurs northeastof the municipal well field with VDC concentrations exceeding 100 ppbin the center of the plume. The second, more diffuse plume, islocated within the outwash aquifer in the vicinity of the industrialpark with VDC levels ranging from 5 to 10 ppb.The Phase I sampling results did not fully define the first plume(well field-Hillman) in its upgradient extent. To address thisproblem, additional monitor wells were needed along the axis of theburied valley in the vicinity of the airport. Therefore, threemonitor wells were installed during the Riase H field program: IW10,RW11, and IW12 (Figure 5-1).The Phase I sampling results did not define the second plume's(industrial park) contaminant concentrations along the axis of theburied valley. To address this data need, monitor wells RW14 and 5W15were installed during the Phase H field program in the middle of theburied valley. Monitor well RW13 was installed along the southernedge of the buried valley (Figure 5-1).The plume identification wells were installed during the period from20 July to 24 July and 11 and 12 August during Phase H fieldinvestigations. Utility clearances had been completed and locationsstaked the previous weeks by a WESTCN geologist. Field conditions(overhanging utility lines) required that the placement of one of themonitor wells, FW15, be moved from the location identified in thePhase II work plan. The monitor well was moved from the northwestside of Route 53 to the southeast side of Route 53, just southwest ofNational Presto Industries. This relocation was still satisfactoryfor fulfilling the data need of defining the contaminant concentrationof the industrial park plume along the axis of the buried valley.5.2 npTTT.TMR EQUIPMENT ANDThe drilling was performed by Exploration Technology, Inc. of Madison,Wisconsin and Wisconsin Test Drilling of Schofield, Wisconsin. ETTused a CME 75 truck-mounted drill rig and Wisconsin Test Drilling useda Central Mine Equipment CME 750 ATV drill rig. Both rigs used twoman crews, with a fifth man used to operate the water truck andperform decontamination. With one exception, the borings for monitorwell installation were advanced using 4.25-inch I.D. hollow stemaugers. During the initial boring for RW13 the hollow stem augersbecame lodged at a depth of 95 feet after equipment failure had forcedthe drillers to leave them in the boring overnight. A longer drillrig (Olson Brothers) was brought to the site and 10-inch casingdrilled around the augers which freed the augers. The hole was then
5-1
• RW-13 Plum* McntHlcitloflW«N
FIGURE 6-1 PLUME DENTFtCATION WELL LOCATIONS 6-2
• RW-13 Ptonw M«n1Mlc*ttonWO
FIGURE B-1 PLUME IDENTFICATION WELL LOCATIONS B-2
and grouted to surface. The location for RW13 was moved 25feet upgradient (south) to prevent grout contamination from theinitial boring. The second boring for KW13 was drilled by hollow stemauger for the first 60 feet throucpi outwash, then drilled by airrotary into bedrock to 75 feet.5.3Prior to the drilling at each location, the back of the drill rigs,all hand tools, well construction materials (riser pipe and wellscreen) and equipment was decontaminated. Decontamination consistedof high temperature steam cleaning using a high-pressure steam jenny.5.4 1CNITORAll plume identification wells were constructed of PVC 2-inch I.D.casing and 2-inch I.D. PVC screen with 0.010-inch continuous slots.The natural sands were allowed to collapse around the well screens toform a sand pack. High purity silica sands were used to augment thenatural sands, usually to ensure the sand pack was two to five feetabove the top of the screen. Bentonite pellets (usually two bucketsper well) were poured on top of the sand pack to make a four footbentonite pellet seal. Die pellets were hydrated with about 10gallons of water and tamped with tremmie pipe. Cement bentonite groutwas then placed by tremmie pipe up to the surface. Six-inch steelprotective casing was installed over each well and anchored withcement. A sloping cement pad was placed around each well and theprotective casing locked with a padlock.All plume identification wells were screened in the sand and graveloutwash, except J5W13. This well was drilled into sandstone bedrockat depths of 60 feet to 75 feet. The screen is in the bedrock atdepths of 75 feet to 65 feet. The reason for this change in work planwas the presence of the saturated zone at this location in thebedrock. A monitor well screened in outwash would not yieldrepresentative groundwater samples.Table 5-1 is a summary of the construction of the plume identificationwells. A detailed description of the borings and the construction ofthe monitor wells is found in the boring logs and well constructionsummaries in Appendix C.5.5 PDJME HJK^rii-'lCKnON WELLAll newly installed REM plume identification monitor wells weredeveloped by pumping with a positive-displacement pump or by bailing.This insured full flow between the aquifer anci the well screen priorto sampling. A niinimum of 11 well volumes of water was removed fromeach well during development. U.S. EPA REM well H-713 was developedwith a bailer since it was screened in bedrock, it recover veryslowly. Plume identification well development data are presented inTable 5-2.
5-3
TABLE 5-1PLUMB IDENTIFICATION WELL CONSTRUCTION SUMMARY
EAU CLAIRE MUNICIPAL HELL FIELD
Mflf RW11 RH12 RW14 RN15
01I
Borehole DianeterDepth of ConcreteThickness of BentoniteSealDepth of SealRiser Stick-upIn-ground RiserScreen LengthDepth of Screen
\\Depth of Borehole
859
5
642.57851129
123.
in«tft
ftftftftft
5 ft
854 .53 .5
SB2 .66555121121
inftft
ftftftftftft
B52
3
552
616812812i
Inftft
ftftftftftft
856
6
621 .2651175
7 8 . 5
inftft
ftftftftftft
84 5 . 53 .5
492
5461114119
inftft
ftftftftftft
844
2
462.52489292
Inftft
ft2 ftftftftft
TABLE 5-2PL0MB IDENTIFICATION WELL DEVELOPMENT DATA
EAU CLAIRE MUNICIPAL NELL FIELD
Ol1Ol
Nell No.RH1ImilRH12RH130114
\RH15
DATEDEVELOPED•7/29/87•7/29/87•7/28/87•8/13/87•7/28/87•7/28/87
Belght OfHater inHell (ft)364148115129
Volume ofHater Inw«u (gal)5. 86 .6
8l.»8 .24 . 9
DevelopmentMethodPUMP IngPimpingPumpingBailingPUMP ingPumping
Volime of NaterRemoved (gal)21f2112112121*211
HellVolumesRemoved
363226112643
FinalDischargeSlightly SiltySlightly SiltySlightly SiltySlightly SiltySlightly SiltySlightly Silty
SECTION 6QROUNDWftTER SAMPLING PROGRAM
6.1 SAMPLDI5 ITOC53AM6.1.1 Scope of WorkDuring the Fhase U field investigation program/ the samplingactivities included the collection and analysis of groundwatersamples in addition to the soil samples discussed in previoussections. Groundwater samples were collected from four sets ofmonitoring wells including: (1) Riase I and Phase U, U.S. EPA REMwells; (2) Wisconsin ENR wells; (3) City of Eau Claire wells; and, (4)National Presto wells. The groundwater sanple locations are shown inFigure 6-1. Chemical analyses were perform^ on 97 of these samples,of which 81 were investigative.All of the groundwater samples were analyzed by the ContractLaboratory Program (CLP) for Special Analytical Services (SAS) forcertain volatile organic compounds (in order to attain low detectionlimits).6.1 .2 Sampling MethodsTwo sampling methods were used to collect the groundwater samples.These methods included extraction with a positive displacement ISCObladder pump and a Well Wizard straddle packer system. For every 10investigative samples collected, one duplicate and one blank sanplewere also collected. Field parameters collected for each sampleincluded temperature, pH and specific conductivity. Thesemeasurements were collected in accordance with the proceduresspecified in the QAFP and the Phase II Sampling and Analysis Plan.Table 6-1 presents general data pertinent to sample collection duringPhase II. Twenty-nine U.S. EPA REM wells were sampled during thePhase U field event. Six nested wells (EW02A-C, KW03A-C), ten sourcewells (FW16-EW25) and one plume well (BW13) were sampled with the ISCObladder pump. KW13, a newly installed plume well, is installed inbedrock with a 10 foot screen. Therefore, it was not necessary tocollect the sample from EW13 with the Well Wizard. The remainingsingle point, fully screened wells were sampled with the Well Wizardstraddle packer system to simulate a nested well installation. Threesamples were collected from each of the single point, fully screenedwells from selected depths. One sample was collected at the top ofthe saturated zone, one in the middle and one at the bottom of thesaturated zone. A minimum of three well volumes were purged from eachinterval before the sample was collected.Eicfct Wisconsin CNR (WENR) wells ware sampled during the Phase Usampling event. All of the WCNR wells were sampled with an ISCObladder pump. A minimum of three well volumes were purged from eachwell before the sample was collected.
6-1
LEGEND• RW2B MonHor
W*l StmpM forGround w*t«r
FIGURE 6-1 GROUNDWATER SAMPLING LOCATIONS e-2
TABLE 6-1GENERAL SAMPLING DATA
01Iw
SAMPLENUMBERRW01XRHOlYRH01XRH02ARH02BRH02CRW03ARW03BRH03CvRH04XRH04TRH04ZRW05XRH05YRH06XRWO6YRWO6ZRH07XRW07YRW07XRH08XRHO8YRWOBIRWO9XRHO9TRHO9X
HELLOWNER
REM HELLREM HELLREM HELLREM HELLREM HELLREH HELLREM HELLREH HELLREM HELLREM HELLREM HELLREM HELLREM HELLREM HELLREM HELLREM HELLREM HELLREM HELLREM HELLREM HELLREM HELLREM HELLREM HELLREM HELLREM HELLREM HELL
DATESAMPLED08/08/8708/08/8708/08/8708/06/8708/06/8708/06/8708/09/8708/89/8708/09/8708/05/8708/05/8708/05/8708/18/8708/18/8708/06/8706/06/6706/06/8708/06/8706/06/8708/86/6708/05/8708/85/8708/85/8708/04/8708/04/8708/04/87
VOLUMEREMOVED
(GALLONS)1096It222810212066610610
3 .51 .75
42424256
6 .5566
SAMPLINGMETHOD
HELL HIIARDHELL WIZARDHELL WIZARD
ISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPisco BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMP
HELL HIIARDHELL HIZARDHELL HIZARDHELL HIZARDHELL HIZARDWELL HIZARDHELL HIZARDHELL HIZARDHELL HIZARDHELL HIZARDHELL HIZARDHELL HIZARDHELL HIZARDHELL WIZARDHELL WIZARDHELL WIZARDHELL WIZARD
SAMPLEINTERVAL(rEET)
7185
10169-7991-111
118-11879-8996-116
108-11664697495
1028794
1017087
1057085
1008595
102
pH '(units)5 .585.625.716 .446 .66.416 .356.36.366.686 .566.566.56.36
6 .226 .256 . 186 .06 .07
6 .256.776 . 8 36 . 9 27 . 6 86 .8
7 . 1 3
SPECIFICCONDUCT I VITT
(unhoB/CM)9298902152052251872232299293776170749310311213073537380492848
TABLE 6-1 (CONT.)GENERAL SAMPLING DATA
SAMPLENUMBERRW10XRftllYRH10ZRH11XRHllYRW11IRW12XRH12YRH12Z\RH13XRH14XRW14YRH14ZRH15XRH15YRH15Z
RW16RH17RH18RH19RH2IRH21RH22RW23RH24RH25
HELLOWNER
REN HELLREM HELLREH HELLREM HELLREM HELLREM HELLREN HELLREH HELLREM HELLREM HELLREN HELLREM HELLREM HELLREH HELLREH HELLREM HELLREM HELLREM HELLREM HELLREH HELLREH HELLREN HELLREM HELLREM HELLREM HELLREM HELL
DATESAMPLED•8/11/87•8/10/87•8/H/87•8/89/87•8/89/87•8/09/8788/B8/87•8/88/87•8/88/87•8/18/87•8/J7/87•8/07/8788/87/87•8/87/8708/07/8708/07/87•8/18/87•8/88/87•8/V8/B708/88/87•8/08/8708/11/8718/10/8788/18/87•8/08/8708/18/87
VOLUMEREMOVED
(GALLONS)7 .51081810
7 .5101111981010
7 .58
7 .518101311li101015112
SAMPLINGMETHOD
HELL HIZARDHELL HIZARDHELL HIZARDHELL HIZARDHELL HIZARDHELL HIZARDHELL HIZARDHELL HIZARDHELL HIZARD
I6CO BLADDER PUMPHELL HIZARDHELL HIZARDHELL HIZARDHELL HIZARDHELL HIZARDHELL HIZARD
ISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPZSCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMP
SAMPLEINTERVAL(FEET)
98104118
85100115
7796
115NA6787
107677889NANANANANANANANANANA
pa(unlta)6 .66 . 66 .6
6.015 .976.3 15 .725 .926.016 . 3 96 .076. 1 16 .286 .236 .356 .456 . 536. 1 16 . 195 .956 . 136 .336 .056 . 186 .3
6 .8 1
SPECIFICCONDUCTIVITY(unho •/<;*)
181128128751211521842532535019118919815916618736028217822816024532021513061
TABLE 6-1 (COHT.)GENERAL SAMPLING DATA
OB(II
HELLNUMBER
HH06HW07HW10
HH10PHH15HW16HW17HH1B
CH 601CW B02CH 805CW 606CH 807CW 608CH 310CH 515CH 517CH 307
PHO4H-5H-6H-7
HELLOWNERHDNRHDNRHDNRHDNRHDNRHDNRHDNRHDNRCITYCITYCITYCITYCITY
fl CITYCITYCITYCITYCITY
NAT'L PRESTONAT'L PRESTONAT'L PRESTONAT'L PRESTO
DATESAMPLED08/05/8708/04/8708/05/8708/05/8798/05/8708/06/8708/05/8708/04/8708/10/8708/10/8708/07/8708/10/8708/07/8708/11/8708/11/8708/11/8708/11/8708/11/8708/11/8708/11/8708/11/8708/11/87
VOLUMEREMOVED
(GALLONS)7 . 5
6112578 .
6 .57 . 5200
604020202035
485580
457 .5
160001 100016500
SAMPLINGMETHOD
ISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMPISCO BLADDER PUMP
BAILERSAMPLING PORTSAMPLING PORTSAMPLING PORT
SAMPLEINTERVAL(FEET)N/AN/AN/AN/AN/AN/AN/AN/AN/AN/AN/AN/AN/AN/AN/AN/AN/AN/AN/AN/AN/AN/A
pH 1(unite)6 . 2 76. 15 .876 .29
6 . 46 .355 .255 .956 .256 . 0 36 . 5 96 . 5 96 .495 . 9 36 . 5 26 . 6 26 . 1
6 . 4 16 . 5 9
6 .76 . 9 77 .0 1
SPECIFICCONDUCTIVITY(unhos/cn)
652813075125120503722017210019114090170901 1012095165159140
The City of Eau Claire monitoring wells were first purged with adewatering pump since the quantity of water extracted was beyond thecapabilities of either the Well Wizard or the ISCO bladder pump. Thesamples, however, were collected with the ISCO bladder pump for all ofthe City of Eau Claire monitoring wells.Four National Presto wells were sampled during the Hiase n sampling
FW04 was sampled with a Teflon bailer due to an obstructionin the well (lhase I sample collected with a bailer also) . Threeproduction wells were also sampled (W5, W6 and W7) . The productionwells were allowed to run for 15 minutes before the sample wascollected at the sampling port. A groundwater sample was also to becollected fron W-4 during Ehase 2 ; however, this well is nownonrunctioning.All sampling equipment was decontaminated prior to sampling at eachwell. Since the samples were to be analyzed for volatile organics atvery low detection limits, it was decided in the field that acetone orjnethanol would not be used in order to prevent potential, samplecontamination. The bailers were scrubbed with an alconox detergentsolution and rinsed with distilled water. In order to decontaminatethe well wizard and ISCO bladder pump, an alconox detergent solutionwas run through the pumps for an average of five minutes. The alconoxdetergent was then purged fron the pumps by running distilled waterthrough the pumps for an average of five minutes.6.1 .3 Evaluation of Effect of Sampling Method on VDC DataDuring the Riase I field effort, groundwater samples were collectedusing three different methods. These methods include extraction witha bailer (Teflon or stainless steel) , a positive displacement ISCObladder pump and a Well Wizard straddle packer system.In order to determine if differences in sampling method have anyeffect on the level of contaminants present, several wells weresampled during Riase U with two or more sampling methods.Groundwater samples were collected from PW03A, BW03B and EW03C with abailer and the ISCO bladder pump. Samples from the water table (thetop of the water column in the wen) in 13*01 (FW01X) and BW07 (HW07X)were collected with a bailer, the ISCO bladder pump and the wellwizard. This sampling will provide three sets of data having two datapoints (pump versus bailer in J3TO3) and two sets of data having threedata points (pump versus bailer versus packer in FW01 and FW07) .6.1 .4 Groundwater Level MeasurementsIn addition to the groundwater samples collected from the monitoringwells specified in Section 6.1 .2, groundwater level measurements wereobtained from all U.S. EPA REM wells, all Wisconsin ENR monitor wells,National Presto (NPI) monitor and production wells, and City of EauClaire monitor wells. All water level measurements were collected on17 August 1987 within a 6.5 hour time period. These water levelmeasurements, in conjunction with previous measurements, will be usedin refining interpretations of the numerical groundwater modeling by
6-6
TABLE 6-2PHASE II HATER LEVEL DATA
BAD CLAIRE MUNICIPAL HELL FIELDB8/17/87
HELL NO.HELL DATUM
ELEVATION( f t . MBl )
DEPTH TOHATER
(ft . MBl)HATER LEVEL
ELEVATION(ft . nsl) HELL NO.
HELL DATUMELEVATION(ft . *Bl)
DEPTH TOHATER
(ft . «Bl)HATER LEVEL
ELEVATION(ft . HBl)
OBI
REH HELLRH-fllRH-02ARH-02BRH-02CRW-03ARH-03BRW-B3CRW-04RW-flSRW-i6RH-07RW-08RH-09RH-10RH-11RH-12RW-13RH-14RW-15RH-16RW-17RW-18RH-19RH-20RH-21RH-22RH-23RH-24RH-25
NPI HELLPH-1PW-3APH-3BPH-3CPW-4
8 8 7 . 3 28 9 7 . 3 48 9 7 . 0 5897 .838 8 1 . 9 58 8 1 . 7 06 8 1 . 5 08 8 4 . 8 9882 .35884 .2 1890 .86889 . 17886 .56B88 .658 9 0 . 6 489 1 . 6 18 8 5 . 8 56 8 8 . 2 48 9 0 . 3 86 8 9 . 1 08 9 0 . 3 78 9 0 . 8 18 8 8 . 7 96 8 9 . 6 16 9 0 . 7 66 8 7 . 6 26 9 0 . 4 98 8 6 . 7 59 2 6 . 4 1
9 1 2 . 1 38 9 9 . 9 5 *8 9 9 . 9 58 9 9 . 9 5 *6 9 8 . 9 4
6 6 . 1 669 .636 9 . 3 8
7 0 . 28 4 . 0 98 3 . 7 98 3 . 6 35 6 . 4 28 6 . 2 56 1 .8 165 .46
64 . 179 .8 18 4 . 2 37 9 . 2 27 2 . 1 3
6 3 . 662 .7 16 3 . 3 66 5 . 3 46 6 . 5 36 6 . 3 76 4 . 4 36 5 . 9 466 .9 164 . 176 5 . 9 27 1 . 0 36 5 . 6 4
4 1 . 1 86 4 . 8 36 5 . 2 56 5 . 0 66 9 . 4 4
82 1 . 1 6827 .7 18 2 7 . 6 76 2 7 . 6 37 9 7 . 8 67 9 7 . 9 17 9 7 . 8 78 2 8 . 4 7
794 . 1802 .4
6 2 5 . 4 26 2 5 . 0 7606 .758 0 4 . 4 28 1 1 . 4 28 1 9 . 4 88 2 2 . 2 5825 .53
8 2 7 . 08 2 3 . 7 68 2 3 . 8 46 2 4 . 4 46 2 4 . 3 68 2 3 . 6 76 2 3 . 6 58 2 3 . 4 58 2 4 . 5 78 1 5 . 7 28 6 0 . 7 7
8 7 0 . 9 56 3 5 . 1 2
8 3 4 . 76 3 4 . 8 9
6 2 9 . 5
MDNR HELLHW-1HH-2WH-3HW-4HH-5WW-5PHW-6HH-7HH-8HW-9HW-9PHW-10HH-10PHW-11HH-11PHW-12HH-13WW-14WH-15WW-16HH-17KH-18HW-19
CITY HELLCW-307CW-310CW-515CH-517CW-601CW-802CW-805CH-886CH-887CW-808
9 4 5 . 0 59 0 0 . 5 36 9 1 . 4 5904 . 1 88 9 2 . 5 58 9 2 . 6 98 8 9 . 4 6893 . 198 4 6 . 9 490 1 .7 19 8 1 . 6 38 8 9 . 1 0889 . 1 990 1 . 3690 1 . 1 68 9 2 . 2 59 0 5 . 4 58 9 9 . 7 2882.618 8 5 . 6 3867 .2 16 9 0 . 8 48 9 4 . 0 2
8 0 6 . 6 38 1 3 . 3 28 1 1 .4 1807 .788 1 3 . 9 58 1 4 . 4 48 13 . 568 13 . 1 98 16 .228 1 2 . 9 3
29 .6 16 1 . 636 4 . 4 674 .696 8 . 7 166 .9 160 .4 116 .9519 . 1778 . 1 378 .0660 .7 160 .9246 .794 3 . 7 32 3 . 4 8
6 8 . 56 7 . 6 656 . 15 6 . 6
1 8 . 4 616 . 5219 . 36
18 . 522 5 . 4 32 4 . 4 72 4 . 6 52 0 . 6 82 1 . 4 42 1 . 042 0 . 1 62 1 . 5 12 4 . 5 3
9 1 5 . 4 4838 .9
8 2 6 . 9 98 2 9 . 4 98 2 3 . 8 48 2 3 . 7 8829 .058 7 6 . 2 4827 .77823 .588 2 3 . 5 56 2 8 . 3 98 2 8 . 2 78 5 4 . 5 76 5 4 . 3 78 6 8 . 7 76 3 6 . 9 56 3 2 . 0 6826 .5 18 2 9 . 0 38 6 8 . 7 58 7 4 . 3 28 7 4 . 6 6
768 . 1 17 8 7 . 8 97 8 6 . 9 47 6 3 . 1 37 9 3 . 2 7
7 9 3 . 07 9 2 . 5 27 9 3 . 0 37 9 4 . 7 1
7 8 8 . 4DATUM ELEVATION ESTIMATED
providing seasonal fluctuation data for the aquifer. A third round ofgroundwater level measurements will be collected in October when thenewly installed U.S. EPA REM wells are sampled for a second time. Allgroundwater measurements collected during Riase U are Included inTable 6-2.6.1 .5 Monitoring Well Elevation SurveyDuring the period of time from 19 to 21 August 1987, the U.S. EPA REMwells were surveyed by WESTQN personnel. The purpose of the surveywas to establish references from which to measure the depth togroundwater so that the groundwater flow gradient and direction offlow could be monitored. Three elevation datum points were collectedfrom each well, including the top of the steel protective casing, thetop of the well (stainless or PVC), and the ground elevation. Themonitoring well elevations were surveyed to the nearest 0.01 foot.The monitoring well survey data is presented in Table 6-3.
6-8
HELL NO.
TABLE 6-3MONITORING HELL SURVEY DATA
BAD CLAIRE MUNICIPAL HELL FIELD(08/19-21/1987)
TOP OP STEELPROTECTIVE CASING
ELEVATION(ft. Hi)
TOP OP HELL(PVC/STEEL)ELEVATION(ft . •«!)
GROUNDSURFACE
ELEVATION(ft . »Bl)
REM HELLRH-01RH-02ARW-02BRH-02CPH-03APH-03BRW-03CRH-04FH-05RH-06RW-07RH-0BRH-09RH-10RW-11RW-12RH-13RW-14RH-15RH-16RH-17RH-18RW-19RW-20JW-21RH-22RW-23RH-24RH-25
867 .32897 .34897 .05897 .83881 .95881 .7088 1 . 50884.89882 .35884.2 1690 .88889 . 17686.56888 .658 9 0 . 6 4891 .61885 .85888 .24890 .38889 . 10890.37890 .8 1888 .79889 .6 1890 .76887.628 9 0 . 4 9866 .75926 .4 1
887 .2 1697 . 1 98 9 6 . 7 8897 . 58881 .8788 1 . 5688 1 .38884.66882 . 19883 .98890 .728 8 9 . 0 3886.446 8 8 . 2 88 9 0 . 4 5891 .0 1885 . 578 8 8 . 0 68 9 0 . 0 80 8 8 . 8 7690.24890 .628 8 8 . 5 7689 .436 9 0 . 3 9887.426 9 0 . 3 0886 .52926 .22
8 6 5 . 0 8895 .9 16 9 5 . 9 38 9 5 . 9 3879 .6 1879 .6 1879 .6 1882.42880 .43883 .258 8 8 . 6 28 8 6 . 9 0864.708 8 5 . 8 48 8 7 . 8 76 8 9 . 0 18 8 4 . 3 8686 .058 8 7 . 8 98 8 7 . 4 4887.72887 .26686 . 1 98 8 7 . 3 4688 . 1 9866 .346 8 7 . 3 48 8 5 . 4 09 2 4 . 7 3
6-9
APPENDIX ASOIL GAS RAW DATA
TIME(Minutes)0 . 0
0 . 51 .01 .52 . 02 . 53 .03 . 54 . 04 .55 . 0
BCKGRND P49
TABLE A-lSOIL GAS SURVEYHILLMAN PROPERTY
1,1-DICHLOROETHANE(Concentration in ppm)P50 P51 P52 P53 P54
1 .82 . 02. 12 .22 . 42 . 52 .7
3 .43 . 64 . 04. 14 . 24 . 34 .54 . 54 .74 .95 .0
4 .24 . 24 . 04 . 04 . 03 . 94 .04 . 04 . 03 .93 . 9
-0.5-0 .3
0 . 40 . 81 .31 .61 .82 . 12 . 32 . 32 .5
0.70 . 91 .62 .02 .53 . 03 .33 . 63 . 83 .94 . 0
0 . 20 . 71 .62 .63 . 33 . 84 .04 . 34 . 34 . 34 . 2
0 . 10 . 61 .41 .92 . 32 . 52 .62 . 82 .92 . 93 . 0
NOTES:
BCKGRND - Background sampleP - Soil Gas Probe
TIME(Minutes)
0 . 00 . 51 .01 .52 . 02 . 53 . 03 . 54 . 04 . 55 .0
BCKGRND P49
4 . 9
TABLE A-2SOIL GAS SURVEYHILLMAN PROPERTYTRICHLOROETHENE
(Concentration in ppm)P50 P51 P52 P53
0 . 4
P54- 1 .2-0 .5-0 .2-0 .2-0.3
0 , 01 ,43 . 53 ,73 .74 . 45 , 14 . 9
-0 .3-0 .20 . 10 . 20 .20 . 40 . 40 .3
-0 .4-0 .4-0. 10 . 10 .20 . 30 .3
-0 .4-0 .6-0 .3-0.10. 10 . 1
-0 .3-0. 1
0 . 00 . 10 .30 . 4
0 . 40. 10 . 40 . 50 .70 . 80 . 9
NOTES:
BCKGRND - Background sampleP - Soil Gas Probe
TIME(Minutes)0 . 0
0 . 51 .01 . 52 . 02 . 53 .03 . 54 . 04 .55 . 0
BCRGRND P49
TABLE A-3SOIL GAS SURVEYHILLMAN PROPERTYPERCHLOROETHENE
(Concentration in ppm)P50 P51 P52 P53 P54 P55-0. 1-0 .2-0. 1-0 .2
-0 .2-0.10. 10 . 20 .30 .2
0 . 00 . 00. 10 . 20 . 20 .2
-0 .20 . 00 . 00 . 10 . 10 . 2
-0 .3-0 .2
0 . 00 . 00 . 10 . 2
0 . 10 . 00 .00 . 10 . 10 . 1
-0 .2-0.1
0 . 00 . 00 . 0
-0 .4-0 .3-0 .2-0. 1-0. 1-0. 1
NOTES:
BCKGRHD - Background sampleP - Soil Gas Probe
TIME(Minutes)0 . 00 . 51 .01 . 52 . 02 . 53 . 03 .54 . 0
BCKGRND Pi P3
TABLE A-4 ~SOIL GAS SURVEY
FIRE PROTECTION TRAINING PIT1,1-DICHLOROETHANE(Concentration in ppm)P5 P6 P6DP P7 P8 P10 Pll P13
9 . 5
P48*1 .52 . 02 . 12 . 12 . 2
5 .98 . 39 . 49 .89 . 79 . 8
3 .63 . 94 . 85. 15 . 1
5 . 05 . 56 .77 . 98 . 48 . 99 . 2
3 .63 .73 . 84 . 24 .75 .35 . 4
8 .99 . 01 0 . 01 1 .011 .0
6 . 97 . 17 . 88 . 28 .89 . 29 . 4
4 . 64 . 85 . 66 . 06 .36 . 5
3 .03 . 54 . 04 . 85 .05 . 2
3 . 94 . 24 . 04 . 24 .3
2 . 22 . 42 .83 . 64 ;34 . 4
3 .94 . 04 . 14 . 34 .34 . 4
NOTES:
BCKGRND - Background sample.DP - Indicates duplicate sample.P - Soil gas probe.* Soil gas probe set in large swale southwest of fire prevention training pit
\\
TABLE A-5SOIL GAS SURVEY
FIRE PROTECTION TRAINING PITTRICHLOROETHENE(Concentration in ppm)
TIME(Minutes)
0 . 00 . 51 .01 .52 . 02 . 53 .03 . 54 . 0
BCKGRND0 . 5
-0 .2-0.1-0 .2-0.1
PI0 . 51 . 11 .41 .71 .71 .91 .9
P30 . 60 .70 .91 . 11 .21 .2
P50 . 50 . 50 .91 .31 .61 .71 .8
P60 . 90 . 91 .21 .31 .41 .4
P70 . 50 . 20 . 40 . 70 . 80 . 9
P7DP0 . 80 . 91 .01 .21 .51 .5
P81 .01 .21 .41 .51 .61 .6
P100 . 60 . 60 .91 .21 . 11 .3
Pll0 . 60 . 60 .50 . 50 . 5
P13-0. 10 . 10 .30 . 40 .70 . 7
P480 . 80 . 90 .81 .01 .31 .2
NOTES:BCKGRND - Background sample.DP - Indicates duplicate sample.
P - Soil gas probe.* Soil gas probe set in large swale southwest of fire prevention training pit
TABLE A-6SOIL GAS SURVEY
FIRE PROTECTION TRAINING PITPERCHLOROETHENE
(Concentration in ppm)TIME
(Minutes)0 . 00 . 51 .01 .52 . 02 . 53 . 03 . 54 . 0
BCKGRND Pi-0 .7-0 .7-0 .7-0 .8
-0 .9-0 .8-0 .6-0.6-0 .6-0.5
P5- 1 .0-0 .8-0 .6
0 . 4-0 .4
P6-0 .8- 1 .0-1 .0-1 .0- 1 .0-0.9
P8-1.1-1.1- 1 .0-0.9-0 .8
Pi 3-0 .9-0 .9-0 .8-0.8-0 .8
P48*- 1 .0-0 .8-0 .20 . 0-0 .2
NOTES:BCKGRND - Background sample.DP - Indicates duplicate sample.P - Soil gas probe.
* Soil gas probe placed in large swale southwestof the fire protection training pit.
TABLE A-7SOIL GAS SURVEYGIBSON AVIATION
1,1-DICHLOROETHANE(Concentration in ppm)
TIME(Minutes)0 . 00 . 51 .01 .52 . 02 . 53 . 03 .54 . 04 . 55 .0
BCKGRND1 .31 .21 .51 .41 .21 .21 .3
P391 .51 .72 .43 . 34 . 04 . 44 . 74 .84 . 9
P401 .71 .81 .91 .81 .81 .81 .9
P411 .62 . 53 .74 . 55 . 15 . 66 . 06 .36 . 56 . 6
P421 .11 .01 .72 . 43 .03 , 43 ,63 .94 . 14 , 2
P431 .82 . 94 .05 . 05 . 76 . 16 . 36 . 56 . 76 . 97 . 17 . 1
P441 .31 .82.93 . 94 . 45 .25 . 45 .6
P451 .41 .73 .04 . 54 . 95 . 05 . 05. 1
P461 .62 .53 .84 . 85 . 25 . 45 .55 .5
P471 .22 . 85 . 16 . 98 . 08 . 69 . 29 . 59 . 79 . 9
10 .0
P47D1 .53 . 65 .87 . 58 . 79 . 59 . 810 .0
10 .0
NOTES:BCKGRND
DPP
Background sample.^Indicates duplicate sampleSoil gas probe.
TABLE A-8SOIL GAS SURVEYGIBSON AVIATIONTRICHLOROETHENE
(Concentration in ppm)TIME(Minutes)0 . 0
0 . 51 .01 .52 . 02 . 53 . 03 . 54 . 04 . 55 . 0
BCKGRND P39 P40 P40DP P41 P42 P43 P44 P45 P46 P47-0 .2
0 . 0-0. 1-0.1-0 .2-0 .2-0 .2
-0 .4-0 .2
0 . 00 .30 .50 . 60 .7
0 . 00 .20 . 1
-0 .2-0 .2-0 .4-0.3
-0 .3-0 .2-0 .00 . 1
-0 .2-0 .3-0 .2
-0 .3-0.1
0 . 20 . 50 .80 . 91 .01 .21 .2
-0.6-0 .4-0 .20 . 10 . 30 . 50 . 50 . 6
-0 .5-0.6-0 .30 . 10 .30 . 60 .60 . 71 .01 .0
-0 .4-0 .50 . 10 . 40 . 50 . 60 .70 . 80 . 8
-0 .2-0,1
0 . 20 . 50 . 70 . 90 .91 .01 .0
-0 .60 . 20 . 60 . 80 . 91 . 11 .11 . 1
-0 .7-1 .0-0.1
0 . 30 . 61 .01 .11 . 21 .2
NOTES:BCKGRND
DPP
Background sample.Indicates duplicate sampleSoil gas probe.
TABLE A-9SOIL GAS SURVEYGIBSON AVIATIONPERCHLOROETHENE(Concentration in ppm)
TIME(Minutes)0 . 00 . 51 .01 .52 . 02 .53 .03 . 54 . 0
BCKGRND0 . 50 . 40 . 50 . 50 . 5
P390 .50 . 50 .70 . 80 .80 .8
P39DP0 . 60 .60 . 70 . 70 .90 .90 .9
P400 .70 . 80 . 80 . 80 . 80 . 80 .9
P410 . 80 .91 .01 .01.11 .11 .2
P421 .01 .11 . 11 .21 .21 .31 .3
P430 . 81 .01 .21 .31 .41 .31 .4
P440 . 81 .31 .31 .41 .41 .31 .4
P451 .01 .01 .11 .21 .21 .21 .2
P4t>0 . 91 .01 .11 . 21 . 31 .31 .4
P4/
0 . 81 .11 .31 .41 .41 .51 .5
NOTES:BCKGRND
DPP
Background sample.Indicates duplicate sampleSoil gas probe.
TIME(Minutes)0 . 00 . 51 .01 .52 .02 . 53 . 03 . 54 . 0
BCKGRND
TABLE A-10SOIL GAS SURVEY
PHOENIX STEEL CORP.1,1-DICHLOROETHANE
(Concentration in ppm)P56 P57 P58 P59 P60 P60DP P61 P62 P630 . 30 . 81 .72 . 42 .32 .2
-0. 10 . 42 .33 .54 .24 .75 .25 .55 .6
0. 12 . 04 . 46 . 47 .78 . 59 . 09 . 39 .79 . 8
0 . 51 .52 .73 .53 .83 . 9
003444
.3
.9
.7
.2
.4
.5
2 .62 . 13 .64 . 55 .35 . 55 . 85 .9
-0134555
.3
.2
.5
.9
.3
.4
.6
0 .41 .72 . 83 . 23 .53 . 33 . 5
-0 .50 . 10 . 91 .31 .61 .81 .9
-0 .21 .53 . 03 .94 .34 . 44 . 6
TIME(Minutes)0 . 00 . 5
, 1 .01 . 52 . 02 . 53 . 03 . 54 . 04 . 55 . 05 .56 . 06 . 5
P64 P65 P66 P67 P68 P69 P70 P710. 10 . 72 .73 . 74 . 04 . 24 .2
0 .20 .20 . 40 . 40 . 5
-0122223
.1
.0
.0
.5
.6
.9
.0
-0122333
.4
.5
.3
.9
.0
.0
.0
-013455666
.2
.0
.0.5
.4
.9
.2
.4
.4
-0023444
.3
.8
.5
.4
.2
.4
.6
-0 .3-0 .3-0 .20 . 10 . 71 .01 .51 .92 . 32 .62 . 93 . 13 . 43 . 6
-0.10 . 11 .32 . 53 . 13 .74 . 14 . 3
BCKGRMD - Background sample.DP - Indicates duplicate sample.P - Soil gas probe.
TABLE A-llSOIL GAS SURVEY
PHOENIX STEEL CORP.TRICHLOROETHENE(Concentration in ppm)
TIME(Minutes)0 . 00 . 51 .01 .52 .02 . 53 . 03 .5
BCKGRNI-0 .3-0 .2-0 .2-0 .3-0.3-0 4V m *m
5 P56-0 .30 . 10 . 40 .70 .80 Q.71 .01.1
P57-0 .4
0 . 41 .01 .41 .71 9A • y2 . 02 .0
P58-0 .3
0 . 20 .70 . 80 . 80 0. o
P59-0 .3
0 . 00 . 50 . 81 .01 .21 .3
P60-0 .50 . 10 .60 . 91 .01.1
P61-0 .2
0 . 20 . 81 .01 .01.1
P62-0 .00 . 2
0 . 40 . 70 .70 Q. O
0 . 8
P63-0 .2
0 . 50 . 80 . 91 .01 .11 . 1
P64-0 .50 . 0
0 . 50 .70 .90 9«* . y0 . 9
P64D0 . 10 , 40 .91 .11 .31 2j. . *•1 .3
4 .0
TIME(Minutes)
0 . 00 . 5
\ 1.01 .52 .02 . 53 . 03 . 54 . 0
P65 P66 P67 P68 P69 P70 P710 . 00 .20 .30 . 30 .30 . 40 . 4
-00000011
.2
.1.4
.7
.7
.8
.0
.0
-0-0
000000
.2
.1.2
.4
.5
.7
.8
.8
0001111
.2
.3
.9
.3.4.6.7
0001111
.0
.4
.9
.3
.3
.5
.6
-0-0
000000
.2
.1
.0.2
.3
.4
.6.6
0 . 00 . 00 . 60 . 81 .11 .11 .31 .4
NOTES:BCKGKND - Background sample.
DP - Indicates duplicate sample.P - Soil gas probe.
TIME(Minutes)0 . 00 . 5
3 . 54 . 0
TABLE A-12SOIL GAS SURVEY
PHOENIX STEEL CORP.PERCHLOROETHENE
(Concentration in ppm)BCKGRND P56 P57 P58 P59 P60 P61 P62 P63 P64
0 .30 .30 .30 . 30 . 3
0 . 10 .20 .30 . 20 .20 . 50 . 50 . 4
0 . 30 .20 .50 . 50 . 50 . 70 .70 .70 .8
0 . 50 . 30 .40 . 40 . 50 . 70 . 50 . 5
0. 10 . 20 .40 . 50 . 50 . 50 . 5
0 . 40 . 40 .50 . 60 . 60 . 60 . 80 .70 .7
0 .60 . 70 .80 .90 .90 . 90 . 8
0 .80 . 80 . 80 .91 .01 .01.11.1
0 . 81 .01.11 .21 .21 .31 .2
1 .00 .70 .91 . 11.11 .1
TIME(Minutes)
0 . 00 . 5
\ 1 .01 . 52 .02 . 53 . 03 . 54 . 0
NOTES:
P65 P66 P67 P67DP P68 P69 P70 P70DP P711 .21 .31 .21 .31 .31 .21 .3
1 .31.11 .21 .51 .41 .51 .6
1 .21 .31 .41 .41 .51 .51 .5
1 .01 .41 .31 .51 .41 .31 .4
1 .41 .51 .61 .61 .71 .71 .7
1 .61 .71 .91 .92 . 01 .9
1 .51 .41 .31 .41 .41 .41 .5
1 .51 .51 .51 .61 .51 ,6
1 .51 .51 .61 .61 .71 .81 .9
BCKGRND - Background sample.DP - Indicates duplicate sampleP - Soil gas probe.
TABLE A-13SOIL GAS SURVEY
MAX PHILLIPS & SON1,1-DICHLOROETHANE
(Concentration in ppm)TIME(Minutes)0 . 0
0 . 51 .01 . 52 . 02 .53 . 03 . 54 . 04 . 55 . 05 . 56 . 06 . 57 . 0
BCKGRND1 .01 . 31 .51 .51 .51 .61 .5
P141 .01 .02 . 33 . 44 . 14 .75 . 45 . 86 . 26 . 56 . 97 . 27 . 47 . 77 . 7
P14DP1 .41 .42 . 02 . 63 . 54 .55 .25 .96 .57 . 07 . 57 .78 . 28 . 58 . 5
P150 .91 .01 .01 . 11 . 1
Pi 60 . 91 .01 .01 . 11 .21 .51 .41 .5
P171 . 11 .62 .32 .62 .73 .23 .2
PI 81 .31 .72 . 32 . 83 . 23 .43 . 63 .73 .7
PI 91 .01 .11 .11 . 11 . 11.1
P201 .02 . 64 . 56 . 07 . 07 .58 .08 . 28 . 48 .68 .7
P211 .32 . 34 . 25 . 66 . 87 .68 . 18 . 58 .99 . 19 . 39 . 59 . 5
P221,12 , 23 .33 . 73 . 94, 14 . 24 . 3
P231 . 12 . 33 .64 . 24 . 64 .95 .05 . 1
P241 .32 . 23 .23 . 43 . 43 .43 . 4
P251 .11 .92 . 32 . 93 . 03 .33 . 43 . 5
P261 .31 .72 . 12 . 42 . 93 .43 . 63 . 7
TIME(Minutes) A
0 . 00 .51 .01 .52 . 02 . 53 . 03 . 54 . 0
NOTES:BCKGRND - Background sample.
DP - Indicates duplicate sampleP - Soil gas probe.
P27 P28 P29 P30 P31 P32 P33 P34 P35 P36 P37 P38 P38DP1 .12 .33 .54 . 04 . 14 . 1
1 .41 .92 . 63 .63 . 84 . 04 . 0
1 .32 .35 . 16 . 17 . 07 . 37 . 57 . 67 . 6
0 .93 .25 .36 . 87 . 68 . 69 . 09 . 39 . 4
1 .22 .33 . 84 . 95 .66 . 16 . 56 . 6
1 .01 .42 . 84 . 04 . 75 . 15 . 75 .86 . 1
1 .11 .92 .53 . 03 . 23 .63 . 6
1 .21 .62 . 63 . 44 . 04 . 54 . 84 . 95 . 0
1 .21 .52 .22 . 93 . 23 .63 . 73 . 8
1 .52 .83 . 64 . 04 . 34 . 64 . 6
1 . 52. 13 . 43 . 63 . 73 . 93 . 8
1 .61 .82 . 22 . 52 . 82 . 93 . 03 . 23 . 2
1 .51 .71 .72 . 32 . 52 . 93 . 03 . 13 . 16 . 2
BCKGRND P14 P15 P160. 10 . 00 . 00 . 10 . 0
TIME(Minutes)0 . 00 . 51 .01 .52 . 02 . 53 . 03 .54 . 04 : 5
TIME(Minutes)
0 . 00 . 51 .01 .52 . 02 . 53 . 03 . 54 . 0
NOTES:BCKGRND - Background sample.DP - Indicates duplicate sample.
P - Soil gas probe.
TABLE A-14SOIL GAS SURVEY
MAX PHILLIPS & SONTRICHLOROETHENE(Concentration in ppm)
P17 P18 P19 P20 P21 P22 P23 P24 P25 P25DP P260 . 50 . 60 . 61 .01 .41 .61 .92.12 . 32 . 5P272 . 12 .62 .83 . 13 . 23 . 33 . 3
0 .40 . 40 . 40 . 40 . 50 . 40 . 6
P282 .52 .63 . 13 . 13 . 13 . 23 . 1
0 .30 .30 . 40 .70 .80 . 80 .9
P290. 10 .30 . 81 .01 .31 .51 .6
0 . 20 .30 . 71 .01.11 .31 .3
P30-0. 1
0 . 00 .71 .01 .21 .31 .4
0 . 20 .30 . 60 . 91 .01 .01 . 1
P310 . 00. 10 . 60 .91 .01 .21 .2
0 .91 .01 .01 .11 .01.11 . 1
P32-0. 1
0 .60 . 91 .01 .31 .31 .3
1 .52 . 02 . 42 . 83 . 03 .33 . 53 .6
P333 . 23 .53 . 94 . 14 . 34 . 44 . 5
1 .31 .42 . 02 . 52 . 83 . 03 . 23 .3
P340 .00. 10 . 71 .11 .31 .2
2 .93 . 03 .43 . 53 . 73 .73 . 8
P35-0 .3
0 .00 . 30 . 60 . 60 . 6
3 . 03 . 13 . 43 . 74 . 04 . 14 . 34 . 2
P35DP-0 .20. 10 . 50 . 70 . 60 . 6
2 . 42 .73 . 03 . 23 . 23 .43 .4
P360 . 00 .40 .91 . 31 .61 .5
2 . 83 . 03 . 43 . 53 . 63 . 73 . 7
P370 . 20 .60 . 81 .01 .21 .3
2 .73 . 03 . 23 .53 . 63 .73 .6
P380 . 20 .30 . 40 . 70 . 70 . 91 .0
2 . 42 .52 .72 . 93 . 03 . 13 . 1
BCKGRND P14 P15 P16 P170 . 10. 10. 10 . 10 . 20 . 10 .0
-0.-0,0 .
0 ,0 .0 .0 .
.2
.1
.0
.2
.3
.4
.5
-0 .2-0 .2-0 .2-0 .2
-0 .2-0 .2-0 .2-0 .2
-0. 1-0 .0
0 .20 .30 .3
-0. 10 . 00 .20 .30 .40 . 4
-0-0-0-0
0
.1
.1
.0
.1
.0
0 . 00 . 10 .50 .70 . 91 .01 .0
0. 10 . 20 . 40 . 80 .90 . 90 .9
0 . 00 . 20 .50 . 70 . 60 .90 . 9
0 . 10 . 20 . 40 .50 . 6
0 . 00 . 20 . 50 .60 . 70 .7
0 . 10 . 10 .20 . 30 . 3
0 . 00 . 20 . 40 . 50 .5
0 . 40 . 50 . 60 . 70 .7
TIME(Minutes)0 . 00 . 51 .01 .52 . 02 . 53 . 03 .54 . 0
TIME(Minutes)
0 . 00 . 51 .01 .52 . 02 . 53 . 03 . 54 . 0
NOTES:BCKGRND - Background sample.DP - Indicates duplicate sample
P - Soil gas probe.
TABLE A-15SOIL GAS SURVEY
MAX PHILLIPS & SONPERCHLOROETHENE(Concentration in ppm)
P18 P19 P20 P20DP P21 P22 P23 P24 P25 P26
P27 P28 P29 P30 P31 P31DP P32 P33 P34 P35 P36 P37 P380. 10 . 20 .30 .50 . 50 . 6
0. 10 . 30 . 50 .60 . 6
0 . 20 . 20 ,50 .70 . 80 .91 .0
0 . 10 . 30 . 70 .90 .9
0 . 10 . 10 . 30 .50 . 5
-0. 10 . 00 . 10.10 . 20 . 2
-0. 1-0.1
0 . 30 .50 . 60 .70 .8
0 . 10 . 30 . 40 .50 . 60 . 6
0 . 00 . 00 . 10. 10 .20 . 2
0 . 1-0. 1
0 . 00. 10. 10 . 1
-0. 1-0 .00 . 10 . 10 . 10 . 1
-0 . 10 . 00 . 00 . 10 . 20 . 1
0 . 00 . 10 . 20 .40 . 50 . 4
TCOSa
REPORT °F LABORATORY ANALYSIS ^'Minneapolis. MinnesotaI I j • Tampa. Floridalaboratories,
August 7, 1987
Mr. Curt Stimson -«,.Roy F. Weston r100 Corporate North U
Suite 101Bannockburn, IL 60015
Dear Mr. Stimson:Enclosed is the report of laboratory analyses for samples received07/30/87, 07/24/87.If you have any questions concerning this report, please feel freeto contact Bi l l Scruton or myself.Sincerely,
CZS^Iinter, Ph .D .Director, Laboratory Services
Enclosures
1710 Douglas Drive North D Minneapolis, MN 55422 D Phon* (612) 544-5543
bborotories, ncREPORT OF LABORATORY ANALYSIS Offices:
Minneapolis. MinnesotaTampa, Florida
Roy F. Weston100 Corporate NortnSuite 101Bannockburn, 1L 6U01bAttn: Mr. Curt StimsonRoy F. WestonDate Sample(s ) Col lected:Date Sample(s ) Received:PACE Sample Number:
August 7, 1987PACE Project Number: 870724521
By Cl i en , 07/23/8707/30/87. 07/24/87
parameterChloromethaneBroinomethaneDichlorodifluoromethane(l)Vinyl Ch lor i de ( l )ChloroethaneHethylene ChlorideTrichlorofluoromethane1 ,1-Dichloroethylene1 .1-DichloroethaneTrans-l ,2-DichloroethyleneCnlorofonn1 .2-Dich loroethane1,1,1-Trichloroethanerbon Tetrachloride
^Uromodichloromethane1 ,2-Dich loropropanec i s- l ,3-Dich loro- l-propene1,1,2-TrichloroetnyleneDibromochloromethane(2)1, l,2-Trichloroethane(2)Trans-l ,3-Dichloro-l-propene2-Chloroethylvinyl EtherBromoform1,1 ,2,2-Tetrachloroethane1,1,2,2-TetrachloroethyleneChlorooenzene1 ,3-Dichlorobenzene1 ,2-Dichlorobenzene
1 2 1 9 2 0
Unitsug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kg
MDL12019019019012012050382538622562382525626212012038620120120120120500500
SS-17BlankNDNONDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
HDL Method Detection Limit
1710 Douglas Drive North D Minneapolis. MN 55422 d Phont (612) 544-5543
PCCC REPORT OF LABORATORY ANALYSIS ^"'nneapol.s. Minnesota• I I , Tampa, Floridalaboratories, nc
Mr. Curt Stimson August 7, 1987Page 2 PACE Project Number: 870724521
PACE Sample Number: 12 1920SS- 17
Parameter Units MDL Blank1 ,4-Dichlorobenzene ug/kg 500 ND
MUL Method Detection LimitND Not detected at or above the MDL.
1710 Douglas Drive North O Minneapolis, MN 55422 Q Phone (612) 544-5543
REPORT OF LABORATORY ANALYSIS, nc
Offices:Minneapolis, MinnesotaTampa, Florida
Mr. Curt StimsonPage 3 August 7, 1987PACE Project Number: 870724521
PACE Sample Number: 1 1 9 1 7 0 1 1 9 180 1 1 9 1 9 0
ParameterChloromethaneimomethanebYChlorodif luoromethane( l)Vinyl Ch lor i d e ( l )ChloroethaneMethylene ChlorideTricnlorofluoromethane1 f 1-Dichloroethylene1 . 1-Dich loroethaneTrans-l,2-DichloroethyleneChloroform1.2-Dichloroethane1 . 1 . 1 - l r i ch loroe thaneCarDon TetrachlorideBromodichloromethanes<£-Dichloropropanec i s- l ,3-Uich loro- l-propene1 . 1 .2-Trich loroethy leneUiDromochloromethane(2)U,2-Trich loroethane(2)Trans- l ,3-Dich loro- l-propene2-Chloroethylvinyl EtherBromoform1 , 1 ,2,2-Tetrach loroethane1 , 1 ,2,2-Tetrach loroethyleneChlorobenzene1 ,3-DiChlorobenzene1 ,2-Dich lorobenzene1,4-UiChlorobenzene
Units MDL SS-01 S5-02 SS-03ug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kg
120190lyu19012012050382538622562382525626212012038620120120120^120500500500
NDNONDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
NDNDNDNDND130NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
MDL Methoa Detection LimitNU Not detected at or above the MDL
1710 Douglas Drfvt North G Minneapolis, MN 55422 O Phon* (612) 544-5543
pacelaboratories,REPORT OF LABORATORY ANALYSIS Offices:
Minneapolis. MinnesotaTampa, Florida
Mr. Curt StimsonPage 4 August 7, 1987PACE Project Number: 870724521
PACE Sample Number: 1 19200 1 1 9 2 1 0 1 1 9 2 2 0
ParameterChloromethane
imoroethanetorchloroa if luoromethane(1)Vinyl Ch lo r i d e ( l )ChloroethaneMethylene ChlorideTrichlorofluoromethane1,1-Dichloroethylene1 . 1-Dich loroethaneTrans- 1 ,2-Dich loroethyleneChloroform1.2-Dicnloroethane1 . 1 . 1 -Tr i ch loroe thaneCarbon Tetrachloridebrorood i ch1oromethane>ri!-Dichloropropanec i s- l ,3-Dich loro- l-propene1 . 1 .2-Trich loroethyleneDiDromochloromethane(2)l , l ,2-Tr ich loroethane(2)Trans- 1 ,3-Di chloro-1-propene2-Chloroethylvinyl EtherBromoform1 , 1 ,2,2-Tetrach loroethane1 , 1 ,2 ,2-Te t r a c h loroethyleneChlorpbenzene1 ,3-Uich lorooenzene1 ,2-Dicn lorobenzene1,4-Dichlorooenzene
Units MDL SS-04 SS-05 SS-06ug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kg
12019019019012012050382538622562382525626212012038620120120120,120500500500
NDNDNDNDNDNDNDNDNDND94NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
MDL Method Detection LimitNU Not detected at or above the MDL
1710 Douglas Driv* North O MlnncapolU, MN 55422 O Phont (612) 544-5543
pcicelaboratories, ncREPORT OF LABORATORY ANALYSIS Offices:
Minneapolis. MinnesotaTampa. Florida
Mr. Curt StimsonPage 5 August 7, 1987PACE Project Number: 870724b21
PACE Sample Number:
ParameterChloromethaner •unometnaneb^hlorodif luoromethaneU)Vinyl Ch lo r i d e ( l )ChloroethaneMethylene ChlorideTrichlorofluoromethane1 ,1-Dicn loroethylene1.1-DichloroethaneTrans-l ,2-UichloroethyleneChloroform1 .2-Dich loroethane1 , 1 , 1-Tr icn loroethaneCarbon TetrachlorideBromodichloromethane
Units
1 19230
MDL SS-07
1 19240
SS-08
119240SS-08Dupl i cate
:-Dichloropropanec is- l ,3-Dichloro-l-propene1 , 1 ,2-Trich loroethyleneDibromochloromethane(2)l , l ,2-Tnch loroe thane (2)Trans-l ,3-Dichloro-l-propene2-Chloroethylv inyl EtherBromoform1 , 1 ,2,2-Tetrach loroethane1 , 1 ,2,2-Tetrach loroethyleneChlorooenzene1 ,3-Dichlorobenzene1 ,2-Uicn lorobenzene1,4-Dichlorobenzene
ug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kg
12019019019012012050382538622562382525626212012038620120120120120500500500
NDNDNDNDND125NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
NDNDNDNDNDNDNDNDNDND94NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
MDL Method Detection LimitNU Not detected at or above the MDL
1710 Douglas Drivt North Q Minneapolis, MN 55422 D Phont (612) 544-5543
laboratories, REPORT OF LABORATORY ANALYSIS Offices:Minneapolis. MinnesotaTampa, Florida
Mr. Curt StimsonPage 6
August 7, 1987PACE Project Number: 870724521
PACE Sample Number: 1 19250 119260 1 19270
Parameter UnitsChloromethaner imomethanewch lorodif luoromethane( 1)Vinyl Chlor ide ( l )ChloroethaneMethylene ChlorideTrich lorofluoromethane1,1-Dichloroethylene1 . 1-Uich loroethaneTrans-l,2-UichloroethyleneChloroform1.2-Dichloroethane1 . 1 . 1 -Tr i ch loroe thaneCarbon TetrachlorideBromod i enloromethane^2-Dichloropropanec i s- l ,3-Uich loro- l-propene1.1.2-TrichloroethyleneDiDromochlorometnane(2)l,1.2-Trichloroethane(2)Trans- l »3-Uichloro- l-propene2-Chloroethylvinyl EtherBromoform1,1,2,2-Tetracnloroethane1,1 ,2,2-TetrachloroethyleneChlorobenzene1 ,3-bi chlorobenzene1,2-Dichlorobenzene1 ,4-Dicn loroDenzene
MDL Method Detection LimitNO Not detected at or above the MDL.
MDL SS-09 SS- 10 SS - 1 1ug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kg .ug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kg
120190190190120120503825386225623825256262120120386201201201201'20500500500
NDNDNDND ,NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
NDNDNDNDNDNDNDNDNDND68NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
1710 Oougl.t Drlv. North a Minneapolis, MN 55422 D Phone (612) 544-5543
pacelaboratories, ncREPORT OF LABORATORY ANALYSIS Offices:
Minneapolis, MinnesotaTampa. Florida
Mr. Curt StimsonPage 7 August 7, 1987PACE Project Number: 870724521
PACE Sample Number: 1 19280 1 19290 1 1 9300
Parameterl^jromethaneBromometnaneDich loroa i f luoromethanet 1 )Vinyl Chlor ide ( l )ChloroethaneMethylene ChlorideTrichlorofluoromethane1 ,1-Dichloroethylene1 . 1-Dich loroethaneTrans-l,2-UichloroethyleneChloroform1.2-Oichloroethane1 , 1 , 1 -Tr i ch l o roe tnaneCarbon TetrachlorideI' nodich loromethane1 ,2-Di chloropropanec 1 s - 1 , 3 -D i chloro-1-propene1 , 1 ,2-Tr ich loroethy leneDlDromochloromethane(2)l , l ,2-Tr i ch loroe thane (2)Trans-1,3-Dichloro-1-propene2-Chloroethylv inyl EtherBromoform1 , 1 ,2,2-Tetrach loroethane1 , 1 ,2,2-Tetrach loroethy leneChlorobenzene1 ,3 -D i chlorobenzene1,2-Dichlorobenzene1 ,4-uich loroDenzene
Units MDL SS- 12 SS- 13 (3 ) S5 - 14ug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kg
12019019019012012050382538622562382525626212012038620120120120*"120500500500
NONDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
MDL Method Detection LimitriD Not detected at or above the MDL.
1710 Douglat Drivt North D Minneapolis, MN 55422 D Phont (612) 544-5543
poccbboratories, ncREPORT OF LABORATORY ANALYSIS Offices:
Minneapolis. MinnesotaTampa. Florida
Mr. Curt StimsonPage 8 August 7, 1987PACE Project Number: 870724521
PACE Sample Number:
ParameterChloromethaneB lomethaneD>xtfi lorodif luoromethane(1)Vinyl Ch lor i d e ( l )ChloroethaneMethylene ChlorideTrichlorof luorornethane1 , 1-Dichloroethylene1 . 1-Uien loroethaneTrans-l,2-DichloroethyleneChloroform1 .2-Dich loroethane1 . 1 . 1 -Tr i c n l o roe thaneCarbon TetrachlorideBromodichloromethanel>«~Dichloropropanec i s- l ,3-Dich loro- l-propene1 . 1 .2-Trich loroethy leneDibromoch lorometnane {2)l , l ,2-Tr i ch loroethane (2)Trans- l ,3-Dich loro- l-propene2-Chloroethylvinyl EtherBromoform1 , 1 ,2,2-Tetrach loroethane1 ,1 ,2,2-TetrachloroethyleneChlorobenzenel ,3-l) ich lorobenzene1 ,2-Dich lorobenzene1 ,4-Ui chlorobenzene
Units
1 1 9 3 1 0
MDL SS-15
1 2 1900
SS-16
1 2 1 9 1 0SS- 16Dupl icate
ug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kgug/kg-ug/kgug/kg
12019019019012012050382538622562382525626212012038620120120120_120500500500
NDNDNDNDNDNDNDNDNDND69NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
NONDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND
MDL Method Detection Limit
1710 Douglas Drive North D Minneapolis, MN 55422 D Phone (612) 544-5543
| I . •laboratories,REPORT OF LABORATORY ANALYSIS ^nneapoMs. M.nnesota
Tampa, FloridancMr. Curt Stimson August 7, 1987Page 9 PACE Project Number: 870724521
(1) These compounds co-elute.(2) These compounds co-elute.(3) The sample was diluted 1 : 10 ; al l MDLs must be Increasedby the dilution factor.
Stie data contained in this report were obtained using EPA or otherapproved methodologies. All analyses were performed by me or undermy direct supervision.
Wi l l i am H. ScrutonOrganic Chemistry Manager
1710 Douglas Drivt North O Minntapolis. MN 55422 D Phont (612) 544-5543
POCC REPORT OF LABORATORY ANALYSIS ^"nneapo,, M,nneso,a• l I , Tampa. Floridalaboratories, .xHoy F. Western Augus t 7, I y871UO Corporate Nortn PACE Pro jec t Number: 8 7 0 7 2 4 5 2 1Sui te 101Bannockburn, I I 6001 bAttn: Mr. Curt St imsonRoy F. WestonDate Sample ( s ) Col l e c ted : By Cl i en , 07/23/87Date Samp l e ( s ) Rece ived: 07/30/87, 07/24/87PACE Sample Number: 1 2 1 9 2 0
S S - 1 7"-rameter Units MDL BlankChloromethane ug/kg 120 NDBroinomethane ug/kg 190 NDDicn lorod i f luoromethane( l ) ug/kg 190 NDVinyl Ch l o r i d e ( l ) ug/kg 190 NDChloroethane ug/kg 120 NDMethylene Ch lor i d e ug/kg 120 NDTrichlorofluoromethane ug/kg 50 ND1 , 1 -Di ch l o roe thy l e n e ug/kg 38 ND1 . 1 -Di ch l o roe thane ug/kg 25 NDTrans-l,2-Dicnloroethylene ug/kg 38 NDChloroform ug/kg 62 ND1.2-Uichloroethane ug/kg 25 ND1 1 , 1 -Tr i ch lo roe thane ug/kg 62 ND^rbon Tetrach lor ide ug/kg 38 NDbromodichloromethane ug/kg 25 ND1,2-Dich loropropane .ug/kg 25 NDcis- l ,3-Dich loro- l-propene ug/kg 62 ND1 , 1 ,2-Tr i ch l o roe tny l en e ug/kg 62 NDDibromochloromethane{2) ug/kg 120 NDU,2-Tr ich loroethane(2) ug/kg 120 NDTrans- l ,3-Dich loro- l-propene ug/kg 38 ND2-Chloroethylv inyl Ether ug/kg 620 NDBromoform ug/kg 120^ ND1, 1 ,2,2-Tetrach loroethane ug/kg 120 ND1,1 ,2,2-Tetrach loroethy lene ug/kg 120 NDChlorobenzene ' ug/kg 120 ND1,3-Dich lorobenzene ug/kg 500 ND1 , 2 -D i chlorobenzene ug/kg 500 ND
MDL Method Detect ion Limit
1710 Douolas Drive North O Minncipolit. MN S5422 O Phone (6 12 ) 544-5543
OOCC REPORT OF LABORATORY ANALYSIS ""Slnn^poi... M,nneso.a• i I - Tampa, Floridalaboratories* K:Mr. Curt St imson August 7, 1987
2 PACE Project Number: 87072452 1
PACt Sample Number: 1 2 1 9 2 0SS - 17
Parameter Un i ts MDL Blank1 ,4-Dichlorobenzene ug/kg 500 ND
MUL t-letnod Uetect ion L im i tNiJ Not detected at or above the MDL.
17 10 Douglas Drive North O Minneapolis, MN 55422 G Phone (612 ) 544-5543
APPENDIX CJCNTTORING WELL OCN5TF3JCITCN SUMMARY AND BORING IOCS
t
a
WellWell Construction Summary
Locator* or ^Etevaibn: GroundP/C Top of S ("2.S
Drilling Summary:
Jorehole Diameter.
Construction Time Log:Start
TaskDrilling
25Drilling Fluid.
Surface Casing.Well Design:Basis: Geologic Log * Geophysical Log.Casing String(s): C - Casing S=Screen~?0 -
Geophys. LoggingCasing.
Filter Placement:Cementing:Development:Other:
Date
9-/Z1
Time730
IOOOM4S
1 ( 3 0
Finish1187-Date
Ci.
Well Development:Jul2.IO
10
S2.
Centrahzers.
Comments:a
Filter Materal/'tf-Jl/rtf -
Time
'*Mtt
DRILLING LOGWELL NUMBER:LOCATIONto UA/TW
OWNER:ADDRESS
6/1$ ,
SURFACE ELEVATION: fl^*? ' g *fDRILLING ^5Cf1?'/t/7 DRILLINGCOMPANY: *€DRILLER: Larry Luduji*LOGBY: _~
TOTAL DEPTH IZ.3,WATER LEVEL:. . 2
DATEDRILLED
HELPER:
SKETCH MAP
NOTES:
DESCRIPTION /SOIL CLASSIFCATON(COLOR, TEXTURE. STRUCTURES)
-*-
-/*-
-4H-
7*-
52.-
-7Z-
/ t
Jo
ri5
UM-ter
• Aftt M 011 SHEET OF
DRILLING LOGWELL OWNER:LOCATION {£.6A.h\tila.J ADDRESS
SURFACE ELEVATIONDRILLINGCOMPANY:DRILLER
TOTAL DEPTH.WATER LEVEL:
DRILLING.METHOD:.
DATEDRILLED
HELPER:
SKETCH MAP
NOTES:
DESCRIPTON / SOIL CLASSIFICATION(COLOR, TEXTURE. STRUCTURES)
loo
-w-
-112:
AS
* ASTM Dll SHEET OF
i.I1*aUl
s
0$cfcU<w
r1
WellWell Construction SummaryCfevation: Ground
Top of$3-7,8=?-
Drilling Summary:
Driller. £XA/0rvt.f?GA *¥-Bit(s) At A
Drilling Fluid
Surface Casing 5+te/Well Design:Basis: Geologic Log_£_ Geophysical LogCasing Slring(s): C= Casing S = Screen
0 . 65' ^
Casing:
C2.
. C I £> /
— hff
(SV -
Construction Time Log:_ Start
Taskfrilling:
Geophys. LoggingCasing:
Filter Placement:Cementing:Devebpment;Other:
Date Time
IH6O
13H5
FinishOate
Well Development:29
•^
Comments:
Sit&J
Time
T
DRILLING LOGWELL NUMBER OWNER
ZTfoL fLfrtRE ADDRESSi/\/rVSURFACE ELEVATION:DRILLINGCOMPANY;DRILLER _
LOG BY: _
TOTAi DEPTH.WATER LEVEL:
DATEnail I EH
HELPER:
SKETCH MAP
NOTES L£>6r
DESCRIPTON /SOIL CLASSIFICATtON(COLOR, TEXTURE. STRUCTURES)
-/*-
-3Z-
* AST M SHEET
DRILLING LOG : " '-WFII KIMURPR RMJtf OWNER Ut$*
forth nuJilLOCATION ADDRESS
SURFACE ELEVATONDRILLINGCOMPANY:DRILLER:.
IOG BY: _
TOTAL DEPTHWATER LEVEL:
DRILLING DATE.DRILLED:
HELPER:
SKETCH MAP
NOTES:
DESCRIPTCN/SOIL CLASStFICATON(COLOR. TEXTURE. STRUCTURES)
\oo —
•W-
-109-
Hlfer
-fo -irtu-i'-iectfa ce.
ptbbltf
/
100
* A.STM OHM SHEET -2^ OF
1V
1f
ct
WellWell Construction Summary
I nratinn r»r &.&/?.
Elevation: GroundTop Of Casing.
Drilling Summary:Total "•pin ' °Borehole Diameter—£.
Driller. t?n
-750
Construction Time Log:Start
TaskDrilling:
Drilling Fluid.
Surface Casing.Well Design:Basis: Geologic Log X Geophysical Log__.Casing String(s): C-Casing S-Screen
&L-
Geophys LoggingCasing:
Filter Placement:Cementing:Development:Other:
Casing: ri 3. /nHP
Screen: Si ZLi/iC.h——P \fQ
82————————
Date Time
U5O
FinishIW-Date Time
1000
\\Sfi
Well Development:Tu,ly z* /?gy-£10 -fa r
h7//
Comments:
f<4f
( F2.— bert'fosHT't. Q
pLilfJ--p
mmmt
DRILLING LOGU/FII M1IMBFR A^lv/Z.,rw-*Tinw 4;6f*f ***a
OWNER: Ht $ , fcPfr., ADDBFRS
' TOTAL DEPTH ' ZO f
ClIBFAfT PI PVATlDM &&•'(>
DRILLING *2- ,, _. ./COMPANY r^Mf- TVl //
LOG BY: Cl\&$ KnttHlA
?/ WATFRlPyf l- ^3^. /
DRILLING **uf*. ^ OATE -T/*/ -»-.METHOD1 rf'fT nan i FDTT/Z.' — Z2./«r UFI pro Jfisi tjt)j ^jtS
SKETCH MAP
NOTES: //5* /i-f-//j -/a4/r>T tf1^
'
DESCRIPTON /SOIL CLASSIFICATION(COLOR. TEXTURE, STRUCTURES)
-W-
-52-
^
* A .KTM DIM SHEET _i_ OF
mm
DRILLING LOGyi/fif UIIURPP p l r fJ/Z^ nr. ATOM fn/faA utA
••* ^jJ^tu**.*m
H £ £rpd-OWNER: (X *> • £?ffTADDRFSS
TOTAL DEPTH 17. O 'SURFACE ELEVATIONDRILLING W*$CC*J44COMPANY 7X/- L>r~i U
LOG BY CJ^n's ftnst
WiTCS 1 FUPI -
DRILLING DATE __/ , ,ucTwori1 non i cn-'Ty 2-* ^^~MPI PPD
f/V\_
SKETCH MAP
NOTES:
DESCRIPTON/SOIL CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
loo
-w-
-//*-/<*-OP
100
• A.»rw on SHEET OF
1u.
U
WellWell Construction Summaryrv Cnnrrt* i*4—— • "ElevBtion: Ground
Top ofDrilling Summary:
l/\
'&. redi 'o rei c /\ 1t\ 6 lOQ U
Rig,
Drilling Fluid
Surface Casing 4+tjJWell Design:Basis: Geologic Log X , Geophysical Log.Casing String(s): C-Casing S = Screen"JL- ° C--'S-- Je5-£-
Ci.
C2.
>-<LJt
Cement.- O'i
Other.
Construction Time Log:Start
TaskDrilling
Geophys LoggingCasing:
Filter Placement:Cementing:Development:Other:
Date Time
nog
FinishDateS-
Time
12.10
Well Development : <B-\3UJi^fU <x hai I
Comments:
Si-uJ Lr>ck4A
-h bii~,
uJ/M*\itJ -fa 7 lo '
til J~ m*.
DRILLING LOGWELL NUMBER: OWNER:_ U.S,_____
ADDRESS £X/P OP
ELEVATIONDRILLINGCOMPANY:DRILLER: Stt^ 111
DRILLING.METHOD:
TOTAL DEPTH.WATER LEVEL:R5frfc£>\Uf-bi*
"7ff,5"/i 3 1 (0
DATEHELPER: VI
SKETCH MAP
NOTES:LflfV CtLTT/AJrf-S
DESCRIPTION / SOIL CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
-4--«--12.-
-24--5«--32-
-H4-
-H9--52-
-7Z-
>
Breton , /b
/oJo +t>KJ*<£
fA/D
HO
5*
7?.5ASTM SHEET _L OF
<t
.
WellWell Construction Summarylocation nr Conrrfs: AA** -Elevation: Ground L«V»I o 86 i D S
Top of Casino _ 8 S S • O (oDrilling Summary:
Depth————[15.
f
Drilling Fluid.Surface CasingWell Design:Basis: Geologic Log Geophysical Log _ _Casing String(s): C = Casing S-Screen-5H.-_C2__fLn±-_5y_jL
Casing: cv iiuJk PVC
C2.
c 3*
Construction Time Log:Start• A 4Task
frilling:
Geophys. LoggingCasing:
Fitter Placement:Cementing:Development:Other:
Date TimeFinish
Date Time
J55§
IHS5
Well DevelopmentJLt/•f& /
Comments:
StuJ. Lctk.i<?•u.*uiif~'.<«/)
2X1
DRILLING LOGWELL NUMBERLOCATION
nK//V OWNER:ADDRESS
SURFACE ELEVATION:DRILLINGCOMPANY:DRILLER:.
TOTAL DEPTH.WATER LEVEL:
LOG BY:
DRILLINGMETHOD:.J^L
DATE.DRILLED:
HELPER:
At5
SKETCH MAP
NOTES:
DESCRIPTION /SOIL CLASSIFICATION(COLOR, TEXTURE. STRUCTURES)
-9-
*«-
u
+& ir>
A/0
' AS T U OltM •MEET _L_ Of *-
DRILLING LOGWELl NUMBER: OWNER:
ADDRESS
SURFACE ELEVATONDRILLINGCQUPANY
TOTAL DEPTH.WATER LEVEL:
./LL
DRILLING DATE
HELPER
LOG BY.
SKETCH MAP
NOTES
DESCRIPTION /SOIL CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
A.STW O
T?l
1I
^,
_*-
s^1N.^* J<rf
w»n R (jQ \ 5Well Construction Summary
l^ratinn or Cnords Elevation. GroundP V C- Top ol
Drilling Summary:Total Depth.
Driller.
Drilling Fluid HfiA
Surface CasingWell Design:Basis: Geologic Log J£— Geophysical Log-Casing Stnng(s): C=Casing S*Screen_0_-_£i._C_
_^2^^£.
Filter /i(#/r/ L/*vi
PtJJt T"
Construction Time Log:Start
TaskDrilling:
Geophys Logging:Casing:
Filter Placement:Cementing:Development:Other:
Date TimeIZ90Q700
02.Q
FinishDate Time
Well Development :ZS. 118? -*• £10 ~ i-
"
Comments:
DRILLING LOGWELL NUMBERLOCATION __
OWNER: Li, 5, E*P#ADDRESS ____________
SURFACE ELEVATONTOTAL DEPTH.WATER LEVEL: ( 7'
COMPANY:____DRILLER t-*nry
LOG BY: _
I 1II METHOD Hf# nan i pnHELPER: (*J*t k
SKETCH MAP
NOTES:
DESCRIPTION /SOIL CLASSIFCATION(COLOR. TEXTURE, STRUCTURES)
-*-tt-/t
-31-
-H1--18--52-
-72.-
•*ferhtet. Se>m.
bmo* fa -fo
tx
ft)
* Aft l .W OH SHEET _ OF
DRILLING LOGWELL NUMBER.LOCATION
OWNER:ADDRESS
• ft
SURFACE ELEVATIONDRILLINGCOMPANY:DRILLER:.
TOTAL DEPTH.WATER LEVEL:
DRILLINGftn» METHOD. .DRILLEDHELPER:
LOG BY:
SKETCH MAP
NOTES:
DESCRIPTON/SOIL CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
/CO —
-gs-
-OF
' A .E1U DIMS SHEET Of
I\<£
1!
1..0! *5
I:Va
WellWell Construction Summary
or x Elevation: Ground Level.Top of Casing.
Drilling Summary:Total Depth ? ?•Borehole Diameter———
Q.
Rig 7-5"
Drilling Fluid.Surtace CasingWell Design:Basis: Geologic LogA _ Geophysical U>g __Casing Stnng(s): C-Casing S-ScreenJ2_- JJ^-S.- 73 5
Casing: cv I A* JL
Centralizers f\Q.
Filter Material CAAJfi 11
Construction Time Log:Task
)riltmg:
Geophys. Logging:Casing:
Filter Placement:Cementing:Development:Other.
Date
if**
Timeins
1700
rtio
nzo
FinishDate
Well Development
-far
n^ -h
Comments:LuA-5
Time
DRILLING LOGWELL NUMBER: _LOCATION fo fi&*\(*
OWNER:ADDRESS
V*SURFACE E LEV AT ONDRILLINGCOMPANY:DRILLER:.
TOTAL DEPTH "7^,5""WATER LEVEL: 6 $~' ? '
LOG BY:
DRILLING.METHOD:.
DATE.DRILLED
HELPER:
SKETCH MAP
NOTES
DESCRIPTION / SOIL CLASSIFICATION(COLOR. TEXTURE, STRUCTURES)
5 -4
15 -
$5
55
$5
iu
M
I?O
\A.ST.M 01IM SHEET OF
DRILLING LOGMMUftFB
SURFACE ELEVATIONDRILLINGCOMPANY: _______DRILLER:
LOG BY: K.
OWNER:ADDRESS
TOTAL DEPTH.WATER LEVEL:
DRILLING.METHOD:.
DATE.DRILLED
HELPER
SKETCH MAP
NOTES:
DESCRIPTON/SOIL CLASSIFICATON(COLOR, TEXTURE. STRUCTURES)
30 -tIO13
A.&TM DIIM SHEET -±- OF2 OP V
DRILLING LOGWELL NUMBERLOCATION
OWNER:ADDRESS
SURFACE ELEVATIONDRILLINGCOMPANY: _______DRILLER
TOTAL DEPTH.WATER LEVEL:
DRILLING UfML..METHOD: " > rr DATE.DRILLED:
HELPER:
LOG BY:
SKETCH MAP
NOTES
DESCRIPTION /SOIL CLASSIFICATION(COLOR, TEXTURE. STRUCTURES)
/5 -
55 -
55 //
/
* A.S1M Oil SHEET
DRILLING LOGWELL NUMBERLOCATION
OWNER:ADDRESS
SURFACE ELEVATIONDRILLINGCOMPANY: ______DRILLER
TOTAL DEPTHWATER LEVEL:
DRILLINGMETHOD DATE.DRILLED
HELPER:
LOG BY:
SKETCH MAP
NOTES;
DESCRIPTION /SOIL CLASSIFICATON(COLOR, TEXTURE, STRUCTURES)
65-
a*/
10*M16
- y nets' *A
tV
* A.STM 01SM SHEET OF
§i
.0
WellWell Construction Summary3tinnorCotwdfi- €tevation: Ground
Top olSg*-i7*
Drilling Summary:Total ' 5
Lttrry UJ/'°t1
Bit(s)
Drilling FlukJ.Surface CasingWell Design:Basis: Geologic Log vf Geophysical Log __Casing String(s): C=Casing S- Screen£_-_££_-£u.tO - ~?0 ^
Screen:tO/0
cmuuT
(5&-51
Construction Time Log:tart
TaskDrilling:
Geophys Logging:Casing:
Filter Placement:Cementing:Devebpment:Other:
Date Time
0*50
0750
FinishDate Time
Well Development:' wtJU-
fJLoa
Comments:
Stud Lo<ikdf-hK.ee
TC«»<DRILLING LOGWFM MIIMRFR RUff^1 OC ATION XfftfLV ?£/ ///
A*f^/ &)AJ~
SURFACE ELEVATON 3 &~?DRILLING U)?fl6*W „COMPANY T^J-h On IfDRILLER / . LuiiuJiJ1LOG BY A. h'S V\fft^
•. J ———————— W -**& J^
**\^^r< o»«i.«— «
OWNER /y.5, P^/_* ADflBFSC/
„ TOTAi DEPTH ~?Ot3'11 '^ WATERIFVFI- &6>?f
DRILLING 'ZJ'^ OATE -J^L?MPTwon r\.j" nmi i cr»' 7*-™/o 'HE1PFH O", tA>Ltte' '
' _^* ^^L~. —————————————————
SKETCH MAP
NOTES;
DESCRIPTON /SOIL CLASSIFICATON(COLOR. TEXTURE, STRUCTURES)
5 -4
5 -4
a •* S5
Zl
57
So
Z.323
• A .STU DIMS
S#*Jb
SHEET __L Of
DRILLING LOGWELL NUMBER OWNER (1 t^.
£<;p/vfi/1LLl d ) ADDRESS
SURFACE ELEVATONDRILLINGCOMPANY:.DRILLER:_
IOG BY: _
TOTAL DEPTH.WATER LEVEL:
DRILLINGT>n '( METHOD
DATE.DRILLED:
HELPER:
SKETCH MAP
NOTES:
DESCRIPTION /SOIL CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
(2,15
konv*
A.ST.W 01) SHEET Of
DRILLING LOG
LOCATION.
(£Ql+7SI*4d)OWNERADDRESS
SURFACE ELEVATIONDRILLINGCOMPANY:DRILLER: _
TOTAL DEPTH.WATER LEVEL:
TZA+ /V?DRILLING u<&METHOD ft 3^
DATETOOL \ *n-HELPER
LOG BY:
SKETCH MAP
NOTES:
DESCRIPTION / SOIL CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
55-
HO 55
55
21
I*-! -U
AST.U Di SHEET - OF
DRILLING LOGWELLLOCATION
KU//T" OWNER:ADDRESS
U
SURFACE ELEVATONDRILLINGCOMPANY:DRILLER _
TOTAL DEPTH,WATER LEVEL:
LOG BY: /:,
6,5-
7C
// DRILLING .j <>fL DATEII METHOD H ** nailt.METHOD:HELPER:
nailt PH
SKETCH MAP
NOTES:
DESCRIPTON /SOIL CLASSIFICATON(COLOR. TEXTURE. STRUCTURES)
23HJ
2Z
n
#
OP-
* A .KTU DI SHEET J^OFj/
1§*Q.
0"?_3
WellWell Construction Summary'€tevation: Ground
Top OfDrilling Summary:
"3-2Total Depth ____!_£_
Driller.
15
Drilling Fluid
Surface Casing Pr<jit*J>V4Well Design:Basis: Geologic Log_£_ Geophysical Log__Casing Strtng(s): C=Casing S = Screen
O - ^O- C5
SV
Centraiizers
SVfA/D -5"«?
(SS-0)
Construction Time Log:Start1 Li-t-Task
Drilling :
Geophys LoggingCasing:
Filter Placement:Cementing:Development:Other:
Date Time
fooo
& to
(bio
FinishDate Time
'£,30
Well Development:
, *srSt t\rz>iAj/\
Comments:
f
DRILLING LOGWELL NUMBER OWNER Ui 5 •
Pht'/tif) S~ ADDRESS
SURFACE ELEVATON ———DRILL.NG &e£<**t4«COMPANY: __** *l~"*l*DRILLER :_2I
LOG BY: £-*
TOTAL DEPTH.WATER LEVEL:
DRILLINGHELPER: /T
PRIH FP
SKETCH MAP
NOTES:
DESCRIPTION / SOIL CLASSIFICATION(COLOR, TEXTURE. STRUCTURES)
5 -
00
It
/7
P
//
'
y.
' A .BTM DIM* SHEET __£_ Of */
DRILLING LOGWELL NUMBER OWNERLOCATON ftg*6> MO ) ADORESS
SURFACE ELEVATONDRILLINGCOMPANY: _______DRILLER_______
TOTAL DEPTH.WATER LEVEL:
DRILLING.METHOD:.DATE
.DRILLED:
LOG BY: i KrumiW
SKETCH MAP
NOTES:
DESCRIPTON/SOIL CLASSIFICATON(COLOR, TEXTURE. STRUCTURES)
35 -
5 55 3T13
10
$n?t*ts\i -f t .
A . S T M D 1 SHEET _^_ OF V
DRILLING LOGWELL NUMBER.LOCATION __
flu//* OWNER;ADDRESS
SURFACE ELEVATIONDRILLINGCOMPANY: _______DRILLER:
TOTAL DEPTH.WATER LEVEL:
DRILLING.METHOD:.
DATE.DRILLED
HELPER:
LOG BY . C<
SKETCH MAP
NOTES:
f/oDESCRIPTION /SOIL CLASSIFICATON
(COLOR. TEXTURE. STRUCTURES)
5o -
55
55 a 13 "
* A .STM Oil SHEET -^ OF V
DRILLING LOGWELL NUMBER.LOCATION __
OWNER:ADDRESS
SURFACE ELEVATONDRILLINGCOMPANY: ______DRILLER
TOTAL DEPTH,WATER LEVEL:
DRILLING.METHOD:.
DATE.DRILLED:
HELPER:
LOG BY: C. * Km W\
SKETCH MAP
NOTES:
DESCRIPTON/SOIL CLASSIFICATON(COLOR. TEXTURE, STRUCTURES)
-70
(no/A
* AST M DI RMFFT _tOF__4_
•rIrw$•i.
I
vjP
WellWell Construction Summary4- Clevalorr: Ground
Top ofDrilling Summary:Total Depth.
Driller. TJU* bn //
750
Drilling Fluid
Surface CasingWell Design:Basis: Geologic Log w Geophysical Log __Casing String(s) : C * Casing S = Screen
0 - £0 C(bO - "70
Casing: I'AcK
Filter Matera!-70)
Construction Time Log:Start
TaskDrilling:
Geophys LoggingCasing:
Filter Placement:Cementing:Development:Other:
Date Time
MM
IMZS
FinishDate Time
HOP
JS22.
Well Development :/, /IS?*
Cta^Stfl 1 (OG
f&G/H
Comments:frroud'
1 Lacker.
DRILLING LOGNUMBER.
L0£OWNER:ADDRESS
SURFACE ELEVATIONDRILLINGCOMPANY:DRILLER _
___ TOTAL DEPTH./y _ WATER LEVEL:
L&.ay.LOG av C i kru/r? w
DRILLING '*f DATE__^ .DRILLED:
HELPER: ""*"
SKETCH MAP
NOTES:
DESCRIPTON /SOIL CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
5-
15
1.5
10
45
55
(0
0
35
TZ>P
j c^ >13 Mcfc r^^
r-t cctflry
$W£}
• A .KTM Ot SHEET OF
DRILLING LOGWELL NUMBERLOCATION j£
OWNERADDRESS
TOTAL DEPTH.
LOG BY:
SURFACE ELEVATIONDRILLINGCOMPANY:DRILLER:-
WATER LEVEL:,
^s&.
- tl DRILLINGtin fl METHOD .
HELPER:
SKETCH MAP
NOTES:
^€^ DESCRIPTION /SOIL CLASSIFICATION(COLOR. TEXTURE, STRUCTURES)
«lmc«'*'*i
13
• A . STM Dtl SHEET __ OF
DRILLING LOGnU/' 7 OWNER
TOTAL OFPTHSURFACE ELEVATONDRILLING 11 DRILLING DATE
DRILLER HELPER:
V5 4
50
00
HO
* A .STW 01SM
SKETCH MAP
NOTES:
^l&5&xSKf& DESCRIPTION /SOIL CLASSIFICATON(COLOR. TEXTURE, STRUCTURES)
tl
tf- I
/
SHEET __ OF
DRILLING LOGWELL NUMBER. OWNER U.f.LOCATION fa0/\-hsiu/O. ) ADDRESS
SURFACE ELEVATIONDRILLINGCOMPANY:DRILLER _
TOTAL DEPTH.WATER LEVEL:
//H DRILLING u , #,METHOD H •> FTDATEDam FP
HELPER:
LOG BY:
SKETCH MAP
NOTES:
DESCRIPTION /SOIL CLASSIFICATON(COLOR, TEXTURE, STRUCTURES)
v*-iI
.§
u1VJ
WellWell Construction Summarylocation or Cnnrds Mati ' '&L^ Elevation .Ground
Top of Casing.Drilling Summary:
fvrf*Diameter __2_£
r,
HS*Drilling Fluid flgllSurface Casing nsWell Design:
yBasis: Geologic U>g A.. . Geophysical LogCasing String(s): C = Casing S- Screen
0 - C V £-
Casing: n 3 />vA.A+4A.I
S2.
Filter it , \A0JvS*J
Cement.Other.
Construction Time Log:Task
Drilling:
aeophys LoggingCasing:
filter Placement:Cementing:Devebpment:Other:
Date TimeMl*
I960
FinishDate Time
Well Development :f.H wiJLL
Comments: *TTtrt f^ii-t a
PRILLING LOGWELL NUMBER: OWNER
ARPPggg tb/ £
SURFACE ELEVATIONDRILLSCOMPANY
TOTAL DEPTHWATER LEVEL
DRILLING noil I FPHFLPPP
LOG BY:
SKETCH MAP
NOTES:
DESCRIPTION /SOIL CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)- -
15
it
10
<>$
11\3
/z
n
h it - / cJ«yy y
-fa
* A . S T M SHEET _A_ OF H
UVJj A^JjtAAJ
DRILLING LOGOWNER: LA i P < €>Pfr-
LOCATION
aSURFACE ELEVATIONDRK.LMGCOMPANYDRILLER _
LOG SY; J
TOTAL DEPTH,WATER
DRILLING.METHOD .
DATE.DRILLED
HELPER.v/W*y
SKETCH MAP
NOTES
DESCRIPTCN / SOIL CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
SHEET _2=_ or Ji
DRILLING LOGWELL NUMBERLOCATION
OWNER:ADDRESS
SURFACE ELEVATIONDRILLINGCOMPANYDRILLER .
TOTAL DEPTH.WATER LEVEL:
DRILLING.METHOD
DATE.DRILLED
HELPER:
LOG BY: C-
SKETCH MAP
NOTES
DESCRIPTION/SOH. CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)1 L - I?
£>—
;//
/ -
/t? c oa. rse. y
DRILLING LOGWELL NUMBERLOCATION .
SURFACE ELEVATIONDRILLMGCOMPANY: _______DRILLER .
LOG BY: C. An A
OWNER; _ADDRESS
TOTAL DEPTH.WATER LEVEL:
DRILLING.METHOD .
DATE.DRILLED
HELPER
SKETCH MAP
NOTES
DESCRIPTION / SOIL CLASSlFCATON(COLOR. TEXTURE, STRUCTURES)
fatCXttM^ -fon0uMl£ i/tey y
SHEET
§ .
IVJl
\JXsi
WellWell Construction Summarynr '€ieva«bn: Ground
Top ofDrilling Summary:
I
750
Fluid.
Surface Casing.Well DesignBasis: Geologic U>g_r— Geophysical LogCasing Sthng(s): C*Casing S*Screen-£_-.££_ _^.
- -73 3
Casing; r.i A /AC
Screen:
S2.
Construction Time Log:Start• — ^.Task
Drilling:
Geophys. LoggingCasing:
Fitter Placement:Cementing.Development:Other:
Date TimeFinish
Date? */
•2^21
Time1Q3.O
1200t2.oo
Izoo
Well Development :
ICfi
Comments
5*t4sJi
DRILLING LOGWELL NUMBERLOCATION
OWNER;ADDRESS
SURFACE ELEVATIONDRILLINGCOMPANY:non iFR LarTy
' 17TOTAL DEPTHWATER LEVEL:
DR.IUNGMETHOD
DATEPRILLED :
' 7 HELPER:
LOG BY:
0~r
SKETCH MAP
NOTES:
DESCRIPTON/SOIL CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
5 -
-\o
15 -
5
0
1-5
/*n
it
* JLS.T.U DIM
cie^Ut. rt,co* «7 10"
r Ih&
ft? f/
SHEET _1_ OF
DRILLING LOGWELLLOCATION
NUMBER _£UJ2l
SURFACE ELEVATIONDRILLINGCOMPANY: _______DRILLER
TOTAL DEPTH.WATER LEVEL:
DRILLING.METHOD:.
DATE.DRILLED:
HELPER:
LOG BY:
SKETCH MAP
NOTES
t<°
SODESCRIPTON /SOIL CLASSIFICATION
(COLOR. TEXTURE, STRUCTURES)
\5 -
30
35
30
h
1 3i2(7
* A .STM DttM SHEET OF
DRILLING LOGWFM MLJMBFH OWNER:LOCATION (_rt>A+iA*jJ ) ——— ADDRESS
TOTAL DEPTH.SURFACE ELEVATIONDRILLINGCOMPANY: _______DRILLER ________
WATER LEVEL:DRILLINGMETHOD:.
DATE -.DRILLED7
HELPER:
LOG BY: C*
^«S?SS#&#&1171
»3;
' A .STW D1IM
SKETCH MAP
NOTES:
DESCRIPTION /SOIL CLASSIFICATION(COLOR, TEXTURE. STRUCTURES)
y
SHEET _ OF
DRILLING LOG
LOCATIONOWNERADDRESS
SURFACE ELEVATIONDRILLINGCOMPANY: _ _____DRILLER:
TOTAL DEPTH.WATER LEVEL:
DRILLING.METHOD;.
DATE.DRILLED:
HELPER:
LOG BY:
65™
30
on
SKETCH MAP
NOTES:
DESCRIPTION /SOIL CLASSIFICATION(COLOR, TEXTURE. STRUCTURES)
Xe d_
fv3 - 4 "
(/
OP-
SHEET JL Of
fc
vr
cc
WellWell Construction SummaryUvatinn or Cnorrts 'Elevation: Ground
Top ol Casing.i ?T
Drilling Summary:
Diameter.
Drilling Fluid
Surface Casing.Well Design:Basis: Geotogtc Log Geophysical Log __Casing Stnng(s): C=Casing S-Screeno - 6y C-£i-J72__^_
Cv
Filter Materal ___ ,L $%- 72^5 #*JD
Construction Time Log:Start
TaskDrilling:
Geopnys. LoggingCasing:
Filter Placement:Cementing.Development:Other:
Date2/IL
Time
Well Development:
ir>n tyaJLLfiAA-ife
Comments:u/^S
FinishDate
83
Time
cc
13*0
-pc $+5
VA/LTb>J\«fe<AJWMm ^ l»«j_-i ri
DRILLING LOGWELL NUMBER. OWNER:
ADDRESSU ' $•
\f *TOTAL DEPTH.WATER « '
DRILLINGCOMPANYDRILLER -
LOG BY: _
DRILLING.METHOD .
HELPER: y*
^
SKETCH MAP
NOTES
Z2&&&* DESCRIPTION / SO* CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
(o
HO
irv\
ccf
4o c oars* -\on
>9-5
/<+
t '
\* A. ITW O^Hi SHEET
SKETCH MAP
DRILLING LOGWELLLOCATION
SURFACE ELEVATIONDRILLMGCOMPANY ._______DRILLER _______
OWNER:ADDRESS
TOTAL DEPTH.WATER LEVEL:
DRILLING.METHOD DATE.DRILLED
HELPER: NOTES
LOG BY:
DESCRIPTON/SOIL CLASSlFCATON(COLOR. TEXTURE. STRUCTURES)^&&<®&
DRILLING LOGWELL NUMBERLOCATION.,
OWNER:ADDRESS
SURFACE ELEVATCNDRILLINGCOMPANY ________DRILLER
TOTAL DEPTH.WATER LEVEL:
DRILLING.METHOD .
DATE.DRILLED
HELPER
LOG BY:
SKETCH MAP
NOTES
DESCRIPTION /SOIL CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
SKETCH MAP
DRILLING LOGWELltOCATON
SURFACE ELEVATCNDRILLINGCOMPANY _______DRILLER
LOG BY:
CWNER:ADDRESS
TOTAL DEPTH.WATER LEVEL:
DRILLING.METHOD ,
DATE.DRILLED
HELPER NOTES:
DESCRIPTION/SON. CLASStFCATON(COLOR. TEXTURE. STRUCTURES)
V*NO•>-
S sA.
,5
JCX%N
Well Construction Summaryor Coords:$CAA
Pkt /// §87Top Of Casing 1 O . 3O
Drilling Summary:Total Depth__torehoie Diameter.
Driller
Bit(s)Drilling FluidSurface CasingWell Design:Basts: Geologic Log Geophysical Log.Casing String(s): C-Casing S-Screen
_- ^/ C/^/ - -II $_
Casing;
C2
Screen: , 010S2.
Centralizers
Filtur MatPfial
Cement — k&rtttflt'fe"p 0jLt£t$
Construction Time Log:Start»^f.Task
drilling:
Geophys. Logging:Casing:
Filter Placement:Cementing:Development:Other:
Date Time
U/o
RnishTime
Well Development:
>fi&.
Comments:
n
q
SKETCH MAP
DRILLING LOGWEII MUuaPP Al*lZ3LOCATION
OWNER:ADPRE&S
U <$.
SdA fTOTAL DEPTH,
SURFACE ELEVATONDRILLINGCOMPANYDRILLER
WATER i gupt • f5, <tDRILLING
HELPER: A".DATE
.DRILLED NOTES
DESCRIPTION/SOIL CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
DRILLING LOGWELLLOCATION
OWNER:ADDRESS
SURFACE ELEVATIONDRK.LMGCOMPANY ________DRILLER
TOTAL DEPTH .WATER LEVEL:
LOG BY
DRILLING.METHOD DATE.DRILLED
HELPER:
SKETCH MAP
NOTES
OESCRIPTON/SOM. CLASSIFICATION(COLOR, TEXTURE. STRUCTURES)
:i
LJ
-to
:
In
ffoLfe ty
:
O'Mi SHEET J— Of V,
DRILLING LOGWELL NUMBERLOCATION:
OWNER:ADDRESS
SURFACE ELEVATIONDRILLINGCOMPANY _______DRILLER
TOTAL DEPTH.WATER LEVEL:
DRILLING.METHOD
DATE.DRILLED
HELPER:
LOOBY:
SKETCH MAP
NOTES:
OeSCRIPTON/SOl CLASSIFICATION(COLOR. TEXTURE, STRUCTURES)
VAA^6)UXdAKJDRILLING LOGWELL NUMBER. OWNER:
ADDRESS
SURFACE ELEVATIONDRILLINGCOMPANY ____DRU.ER _______
TOTAL DEPTH.WATER
DRILLING.METHOD:. J/^/lft ->"
DATE.DRILLED-
HELPER:
LOG BY
SKETCH MAP
NOTES:
DESCRIPTION /SON. CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
\te>n
./>C
-**
-A.8TH OiUI SHEET
-V*4
•r1
WellWell Construction SummaryLocation or Cavds EtevBtbrt: Ground
Top of . 6" Drilling Summary:
Diameter. f+CA**J
Driller &tplonxAl'dA^
Rig. "75' 2-5"
Surface Casing Przr/tJL&SlWell Design:Basis: Geologic Log Geophysical Log __Casing String(s): C- Casing S* Screen0 - bb O
Casing:
Centralizers.
f
Construction Time Log:Start
TaskDrilling:
Geophys LoggingCasing:
Filter Placement:Cementing:Development;Other:
Date Time
nco1700
FinishDate
4
Time706
1 7 Jo
Well Development
bsr
Comments:u/AS rtw **** Jf
TLLJO buitujer pasts
DRILLING LOGWELL NUMBERLOCATION
OWNER:ADDRESS
*fi Crn
SURFACE ELEVATIONDRILLINGCOMPANY:
TOTAL DEPTHWATER LEVEL:
Ti« DR.LLING\C*f<4 UCTHOO:7
DATSnan i tn
tOG BY:
SKETCH MAP
NOTES
DESCRIPTION/SOU CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
DRILLING LOGWELLLOCATION
&M2M v OWNER:ADDRESS
SURFACE ELEVATIONDRILLINGCOMPANY: _______DRILLER
TOTAL DEPTH.WATER LEVEL:
DRILLING.METHOD . DATE.DRILLED
HELPER / r
LOG BY:
SKETCH MAP
NOTES
DESCRIPTION /SOH. CLASSIFCATON(COLOR. TEXTURE. STRUCTURES)
SKETCH MAP
DRILLING LOGWELL NUMBERLOCATION .
SURFACE ELEVATCNDRILLINGCOMPANY: _______DRILLER
LOG BY:
OWNER:ADDRESS
TOTAL DEPTH.WATER LEVEL:
DRILLING DATE.DRILLED
HELPER NOTES
DESCRtPTCN/SOlL CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
SHEET _ OF & ,
WWL^U jujyu w^^^^
DRILLING LOGWELL NUMBERLOCATION. d
OWNER:
SURFACE ELEVATIONDRILLINGCOMPANY: ________DRILLER
LOG BY:
TOTAL DEPTH.WATER LEVEL:
DRILLING //<>fl-H >rr DATEHELPER
SKETCH MAP
NOTES:
DESCRIPTOR SOIL CLASSIFICATION(COLOR, TEXTURE. STRUCTURES)
p<rz>eJy
1s1
4
WellWell Construction SummaryLocation or Coords- > i( • -U;---'• €le vafbn: "Ground
_ Top ofDrilling Summary:
__£*°
J^> flltrezin A ~fofJkf(O lpq<4t
Rig. 75
Drilling Fluid
Surface Casing St&J Pro+e&£l\tfWell Design:Basis: Geologic Ljog_Casing String(s): C« Casing S= Screen
. 0 £.Geophysical Log
Casing: ci-^.C2.
U Slo-h
Filter
Construction Time Log:Start
i.4* .TaskDrilling:
Geophys LoggingCasing:
Filter Placement:Cementing:Development:Other:
9*11
Time
09W
FinishDate Time
//vr
vr
Well Develoment:i+ is t btcftoct
OL/&
clear*Comments:
'Tktef
Cement or&uf' /A/AS
drill
_~x w _/^'»JSy-—
DRILLING LOGWEiLMLiMBFB R OWNER: U i5"/ £7>/?~
£?»U.TRfaA/JAJA-
SURFACE ELEVATIONDR^L^GCOMPANY
TOTAL DEPTH £ gWATER LEVEL: 5"7y
ugTMQO DATEPPM t gn •HELPER:
LOG BY: T".
SKETCH MAP
NOTES
DESCRIPTION/SOfl. CLASSIFCATON(COLOR. TEXTURE. STRUCTURES)
SHEET -L. Of _Y.
DRILLING LOGwen MIHJBFHLOCATION
OWNER:ADDRESS:
SURFACE ELEVATIONDRlLLtNGCOMPANY _______DRILLER:
___ TOTAL DEPTH.___ WATER LEVEL:DRILLING it sA,
.METHOD: rl n DATE.DRILLED:
HELPER:
LOG BY: T,
SKETCH MAP
NOTES:
DESCRIPTON /SOIL CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
01- ss>
n)8
as before,- 3''dUxw*^-Kr spoon oseA- wvoAr\*
• 4. ITM DIMt SHEET
SKETCH MAP
DRILLING LOGWELL NUMBERLOCATION __
SURFACE ELEVATON:DRILLINGCOMPANY: _______DRILLER:
LOG BY:
OWNER:ADDRESS
TOTAL DEPTH.WATER LEVEL:
DRILLINGMETHOD:.
DATE.DRILLED:
HELPER: NOTES
DESCRIPTION /SOIL CLASSIFICATION(COLOR, TEXTURE. STRUCTURES)
* A .8TW Ol
DRILLING LOGNUMBFP
LOCATIONOWNER:ADDRESS
TOTAL DEPTHSURFACE ELEVATION:DRILLINGCOMPANY:DRILLER:
DRILLING // ffi,.METHOD: n ?nDATEnau ! en g /
HELPER:
LOG BY:
SKETCH MAP
NOTES:
^^zm%%& DESCRIPTON /SOIL CLASSIFICATION(COLOR. TEXTURE. STRUCTURES)
70-
OF
-
* A.STU 011M SHEETJ1
APPENDIX DMONITORING WELL SURVEY DMA
):11
i
1Hi
1!,'•\Js1siff.A1!iII*r. jfh
ItlpfS^fiPJVymSjif-^Lv '"$'*&'
%
1
I11fir
li
PIi1iia v111nIs
1iii*#i$#5«&1ikf
jjM$Sp$PfiW*fflISSyf« M('h-ffi")5V
OTW
lH
*«s?*ff
s1111im1IImil|:f'••«*»iite
r1"4! -*HUKM
1"tfrifl
1--
•1"II[HB >
——— - -
— — - - - - -
\ '
1Mijmi •_
iifl'iaV^B '-
»ffiWw;*ifri!)4^MK
^
/9.
^
>t
S^F^^P^
"X?£V
G , ./
0-e*^7-
•••Mmm•
^
*LAIR
'L. £mC<*^<A*
fJlHt
. ——
[T
i 2
L^^
/
X
—— -
U**"T«T^W'Sffirfst-&$M%8Kl$ml?i Jifl*W*)'l"i k&^^-l 1''
IkSwKw'af^R^^ iiiSfeM
•-—
/
—
•
-_ — — -
— -- . . - —
•ft-r
P9B^ QB9racjr'WYT/wMVrSJi'V*Uli•is
i
•
HImIMm
/it- Sto* V• /r
VsfflrwlEQ
... — ,
-
*AUd£tl47Fj: .
• — --
SBi«$T8ffiS^u
f? -
18&
clo-^-*
'J/U1*'•^
iC
- --
- —
-
^sii$9ni
IM^J
1fUpii.i
L->_«-"cT^>eyfu+J~
- -— -
— - -
I ^BQ^V4H;*$£ifc^$ET^f r-WwDi f'SflWuia'*
^r^_« « *«^C- ./*
^
_„_ — _,_
- — — -
. . . . . .-__
" *
iiHP^SBi»i?jii
iiI -.XvtM-'^ ( ' ( - ' • '- :•saps^-vr^*;:;;.11i111H•jHjH ^
REy H^
il M M kii111111•
9M|i ^
'.
•
t
r
i
23 S?
OT588w 'W8,%'wa^-»,T89
it'988T3I3
|-z"z
SZ-+7
• 3 9 - V90 "z
- t f c 'V0£'-h
2S'S
JH»I S
wmzoee
ZH88
ZU.S8f+r^*
'J 'H
i
Gfe'S
——
22'ii
TS- l^ »K9 rtJTIWiS
4-
1
i——————— ,-
\•<Jwy\N9•eaiV v
•OKH* 1»c«»V-» St•«* 1*33 /-^- -'V± ..
SJ.'0947(Ab
TJ1
^S-^ -' t/1-S_^(
"f \." w *I-JIB ff^mffi'c- JPP 'A 'WKft;
asM^mummBM^m
J liSa'aMlitM^JiMji aaafflfiKaaKB^ BHBWBBP* ^WIBwMBl"iWWB»»M™«wpBMWP^Wi ^W^ P^WW^ i ^ ^ ^ ^™^ " ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^
5TA.
" T GO.TV
i r*Tf£
1
jrs
. T?G>'
i . TPTTPi
•• TP°|
fci**
•V-5ic.nr
-
3.S5
s.uM^l _
M-.bg
5 .8 i
t.^1
H.x.
8^/.^7
8UM
g'io.a
gg5.v3
839,^
S8L*^/*97.oot" *• ->
^If iHT
4. S3
2 .5 ^ -2.15
5.S5
5 . t S
•S . ^T
5 ,77
^,Z8
5 , 4 0
1,51
eiejj
83*.&\3 f^t ^^*"
S9o.7Z
^
———— i
jwP^W^P^Pw iP! ^
IB. '. I-A. .. «M*1. J« .*..__ .*mL*,M ——.
I . - -• ». I-'V
*•,-*
&f - t '^.:h
• <
•' •
wVI
00 DO00 OD oO
r— ocoeo
LA
VIo>CM
GO ,
5!oO'ooi 00Cto CO 00 CX&
OOcr
I- <£;
«i
00CD
r
oO00
to
CXD
CD OO
OO
r- oo=H P
.00oo
drOOoo00 00CD
r-CO
fN CO CO t/7
It
m
J___L
, - *
v --
,.- * ' * . * .--•
^i-h ? _'-'""*-?;"?'*. i * -fX'. .-,-.-. ->!»._• •^-^.,——1'-.
- X « -,t ^ -
Jtt * • .•- : -*«• «
.C . " f-* .••^•..•Vi
» . . / > ' c• * • */• -« /
liil-t
ii- - L f^-. * _ . • •, f : -^- 7 > .
;^^,^-•^ •%:\--?s?Hr*;Z'--^sv)*; •«=•- :*- -t-
t •
^5^-^^T^-^-'
iSfes^SiJ-" *at*T>.: •= . * > .
>i «o! oo V
00
0%
A^l 21 ^1 °^ooi cR>; oo1 oo OO 00Oo
c\,~ i OooO Cr
or
(NQO
C9 ci . j j. t i i i
. -. '^ i ' . - " ' * " -
u - v - : JK- ^"•••••"••••^•^•••^^ ,i' .•'<*.'• irj'''**!**^-- ;*•*** ' H^ »*«-•».•• rf»f > . , . .••^^^•fj^^f^M' • -^ ' '•' ' : .^''r-^v^'^fe'
.-" -= ; * - . ' • ' ":;.. ; •• » - » * • ' . i , . •
"fr»«-TW-* » *v^-» *q-^. i . . » ^ v .k.*f «..r* *«--••*, ^1 .- .^- ,^^r
j*r•Ii>t- v - ^ - -• *
'".'*. t
* ;V. »• *1
I";.f\\
8 ' f •*.' ?" '.X,. * • * •• . 'u
• ii.-; * • •i ; .i i^ . i1 VI Ak!.:
...^1v V•':,4&^.l•y *#« '^t- .j '-
V- •!•'>- VV*..-<• *s1' V;*;?"f/-''•^s'}••',*" r .*
'* '1 /^
\7• -*,./;•«*•r .'"i> -1'f* T* • ?':S*
T;i. .k
II1
APPENDIX EANALYTICAL PARAMETER USTS
TABLE E-lSAS VDIATHE ORGANIC CCMPOUNDS
Volatile Organic Ccnpounds GAS NumberContract RequiredDetection Limits
(CRDL)
f^f t~ _~__L LL- _-_! !•• |1««SAS compoundsTrans-l , 2-dichloroethene1 , 1-dichloroethaneCis-1 , 2-dichloroethene1, 1-Dichloroethene1,1, l-JTrichloroethaneTrichloroethene1,1, 2-TrichloroethaneTetrachloroethene601 CompoundsChloromethaneBrcmomethaneVinyl ChlorideChloroethaneMethylene ChlorideChloroform1 , 2-DichloroethaneCarbon TetrachlorideBrcanodichloranethane1 , 2-DichloropropaneTrans-l , 3-dichloropropeneDibrorochloronethaneCis-1, 3-dichlorcpropene2-ChloroethylvinyletherBromoform1 , 1 , 2 , 2-TetrachloroethaneOilorobenzene
GASYK*_luMapumper156-60-575-34-3156-59-25-35-471-55-679-01-679-00-5127-18-4
74-87-374-83-975-01-475-00-375-09-267-66-3107-06-256-23-575-27-478-87-510061-02-6124-48-110061-01-5110-75-875-25-279-34-5108-90-7
ug/L0.02 U0.04 U0.03 U0.02 U0.06 U0.02 U0.1 U
0.04 U
0.1 U0.1 U0.1 U0.1 U0.5 U0.2 U0.1 U0.1 U0.1 U0.3 U0.4 U0.3 U0.3 U2.0 U0.4 U0.5 U0.3 U
TABLE E-2HSL ORGANIC CCMPOUNES
Detection Limits*Volatiles
1.2.3.4.5.6.7.8.9.
10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.31.32.33.34.35.
OiloramethaneBromomethaneVinyl ChlorideCnloroethaneMethylene ChlorideAcetoneCarbon Disulf ide1 , 1-Dichloroethene1 , 1-Dichloroethanetrans-1, 2-DichloroetheneChloroform1 , 2-Dichloroethane2-Butanone1,1, 1-TrichloroethaneCarbon TetrachlorideVinyl AcetateBrornodichloronethane1,1 ,2, 2-Tetrachloroethane1 , 2-Dichloropropanetrans-1, 3-DichlorcpropeneTrichloroetheneDibrcmocJiloromethane1,1, 2-TrichloroethaneBenzenecis-1, 3-Dichloropropene2-Oiloroethyl Vinyl EtherBromofonn2-Hexanone4-Methyl-2-pentanoneTetrachloroetheneTolueneChlorobenzeneEthyl BenzeneStyreneTotal Xylenes
Low Water0GAS Number ug/L
74-87-374-83-975-01-475-00-375-09-267-64-175-15-075-35-475-35-3
156-60-567-66-3
107-06-278-93-371-55-656-23-5
108-05-475-27-479-34-578-87-5
10061-02-679-01-6
124-48-179-00-571-43-2
10061-01-5110-75-875-25-2
591-78-6108-10-1127-18-4108-88-3 "108-90-7100-41-4100-42-5
101010105
10555555
1055
10555555555
105
1010
555555
aMedium Water Contract Required Detection Limts (O*DL) for Volatile HSLCompounds are 100 times the individual Lew Water CEDL.
TABI£ E-2 (Continued)HSL ORGANIC COMPOUNDS
Semi-Volatiles
36.37.38.39.40.41.42.43.44.45.46.47.48.49.50.51.52.53.54.55.56.57.58.59.60.61.62.63.64.65.66.67.68.
Hienolbis(2-Chloroethyl) ether2-Chlorophfinol1 , 3-Dichlorobenzene1, 4-DichlorobenzeneBenzyl Alcohol1, 2-Dichloroben2ene2-Methylphenolbis(2-Chloroiscpropyl ether4-MethylphenolN-Nitroso-DipropylamineHexachloroethaneNitrobenzeneXsophorone2-Nitrc£henol2 , 4-DimethylphenolBenzole Acidbis(2-Chloroethc(xy) methane2 , 4-Dichlorcphenol1,2, 4-TridilorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-methyl]*enol(para-chloro-meta-cresol)2-MethylnaphthaleneHexachlorocyclopentadiene2,4, e Iriciilorophenol2,4, 5- lridilorophenol2-CW.oronaphthalene2-NitroanilineDimethyl EhthalateAcenaphthylene3-Nitroaniline
CAS NUMBER
108-95-2111-44-495-57-8
541-73-1106-46-7100-51-695-50-195-48-7
39638-32-9106-44-5621-64-767-72-198-95-378-59-18-75-5
105-67-965-85-0111-91-1120-83-2120-82-191-20-3
106-47-887-68-3
59-50-791-57-677-47-488-06-295-95-491-58-788-74-4 --
131-11-3208-96-899-09-2
Low Water0ugt/L
1010101010101010101010101010101010501010101010
10101010501050101050
TABLE E-2 (Continued)HSL ORGANICS OMPOUNDS
Semi-Volatiles69. Acenaphthlene70. 2,4-DinitroEhenol71. 4-Nitrophenol72. Dibenzofuran73. 2,4-Diriitrotoluene74. 2,6-Dinitrotoluene75. Diethylphthalate76. 4-QiloroFhenyl Hienyl ether77. Fluorene78. 4-Nitroaniline79. 4,6-Dinitro-2-methylphenol80. N-nitrosodiphenylamine81. 4-Bronqphenyl Ehenyl ether82. Hexachlorobenzene83. Fentachlorophenol84. Ifcenanthrene85. Anthracene86. Di-n-butylphthalate87. Fluoranthene88. Pyrene89. Butyl Benzyl Hithalate90. 3,3f-Dichlorobenzidine91. Benzo (a) anthracene92. bis(2-ethylhexyl)Fhthalate93. Chrysene94. Di-n-octyl Rithalate95. Benzo (b) fluoranthene96. Benzo (k) fluoranthene97. Benzo (a) pyrene98. Indeno (1, 2, 3-cd) pyrene99. Dibenz (a ,h) anthracene100. Benzo (g,h,i)perylene
Low WaterwGAS Number ug/L
83-32-951-28-5
100-02-7132-64-9121-14-2606-20-284-66-2
7005-72-386-73-7
100-01-6534-52-186-30-6
101-55-3118-74-187-86-585-01-8
120-12-784-74-2
206-44-0129-00-085-68-791-94-156-55-3
117-81-7218-01-9117-84-0205-99-2207-08-950-32-8
193-39-553-70-3 „
191-24-2 "
1050501010101010105050101010501010101010102010101010101010101010
Sfedium Water Contract Required Detection Limits (CRDL) for Volatile HSLCortpounds are 100 times the individual Low Water CRDL.
TABLE E-2 (Continued)HSL QPGANICS PARAMETERS
Detection Limits*Besticides/PCBs
101.102.103.104.105.106.107.108.109.no.in.112.113.n4.115.116.117.118.119.120.121.122.123.124.125.126.
alpha-EHCbeta-EHCdelta-EHCgamma-EHC (Lindane)HeptachlorAldrinHeptachlor EfccoddeEndosulfan IDieldrin4,4'-ECEEndrinEndosulfan U4,4'-ECDEndosulfan Sulfate4,4'-nOTEndrin KetoneMethoxychlorChlordaneToxapheneAROCU3R-1016AROOJ3R-1221APOdCR-1232ARDdOR-1242AROCD3R-1248APDCD3R-1254ARDdCRrl260
GAS Number
319-84-6319-85-7319-86-858-89-976-44-8
309-00-21024-57-3959-98-860-57-172-55-972-20-8
33213-65-972-54-8
1031-07-850-29-3
53494-70-572-43-557-74-9
8001-35-212674-n-2H104-28-2ni41-16-553469-21-912672-29-6n097-69-ln096-82-5
low Waterug^O,
0,050.050.050.050.050.050.050.050.100.100.100.100.100.100.100.100.50.51.00.50.50.50.50.51.01 .0
tedium Water Contract Required Detection Limits (CRDL) for Pesticide HSLCompounds are 100 tim^s the individual l£*? Water CRDL.**Specific detection limits are highly matri 'dependent. Ihe detectionlimits listed herein are provided for guidance and may not always beachievable.
TABLE £-3HSL INORGANIC OCMPOUNDS
Contract Required^Detection IElement fug/LiDetection level172
Aluminum 200Antimony 60Arsenic 10Barium 200Beryllium 5Cadmium 5Calcium 5000Chronium 10Cobalt 50Copper 25Iron 100Tftad 5Magnesium 5000Manganese 15Mercury 0.Nickel 40Potassium 5000Selenium 5Silver 10Sodium 5000Thallium 10Vanadium 50Zinc 20cyanide 10
Any analytical method specified in Exhibit D of the ContractLaboratory Program Statement of Work may be utilized as longas the documented instrument or method detection limits meetthe Contract Required Detection Level (CRDL) requirements.Higher detection levels may only be used in the followingcircumstance:If the sample concentration exceeds two tJTnpq the detectionlimit of the instrument or method in use, the value may bereported even though the instrument or method detectionlimit may not equal the contract required detection level.These CRDL are the instrument detection limits obtained inpure water that must be met using the procedure in ExhibitE of the Contract laboratory Program Statement of Work. Thedetection limits for samples may be considerably higherdepending on the sample matrix.
TABLE £-4SAS VOIAT3IE ORGANIC COMPOUNDS
Contract RequiredVolatile Organic Compounds CAS Number Detection Limits(CBDL)
SAS CompoundsTrans-1 r 2-dichloroethene1 , l-dichloroethaneCis-1, 2-dichloroethene1 , 1-Dichloroethene1,1, 1-TrichloroethaneTrichloroethene1,1, 2-trichloroethaneTetrachloroethene
GASNumber156-60-575-34-3156-59-25-35-471-55-679-01-679-00-5127-18-4
ua/L0.02 U0.04 U0.03 U0.02 U0.06 U0.02 U0.1 U
0.04 U
TABLE E-5CCNERACT LABORATORY PROGRAM ROUTINE
ANALYTICAL SERVICES ORGANIC PARAMETERSCD
Volatile Organic Compounds CAS Number1. Chlorcmethane 74-87-32. Bronoethane 74-83-93. Vinyl Chloride 75-01-44. Chloroethane 75-00-35. Methylene Chloride 75-09-26. Acetone 67-64-17. Carbon Disulfide 75-15-08. 1,1-Dichloroethene 75-35-49. 1,1-Dichloroethane 75-35-3
10. trans-1,2-Didiloroethene 156-60-511. Chloroform 67-66-312. 1,2-Dichloroethane 107-06-213. 2-Butanone 78-93-314. 1,1,1-Trichloroethane 71-55-615. Carbon Tetrachloride 56-23-516. Vinyl Acetate 108-05-417. BamDdichlorofflethane 75-27-418. 1,1,2,2-Tetrachloroethane 79-34-519. 1,2-Dichloropropane 78-87-520. trans-1,3-Dichloropropene 10061-02-621. Trichloroethene 79-01-622. Dlbronccloromethane 124-48-123. 1,1,2-Trichloroethane 79-00-524. Benzene 71-43-225. cis-1,3-Dichloropropene 10061-01-526. 2-Chloroethyl Vinyl Ether 110-75-827. Brorooform 75-25-228. 2-Hexanone 591-78-629. 4^tethyl-2-pentanone 108-10-130. Tetrachloroethene 127-18-431. Toluene 108-88-332. Chlorobenzene 108-90-733. Ethyl Benzene 100-41-434. Syrene 100-42-535. Total Jtylenes
Contract RequiredDetectJ"" T.-imyts fCRDD*
lav Water(2)
101010105
10555555
1055
10555555555
105
101055
I 5555
lew SoilSedunent^ '
101010105
10555555
1055
10555555555
105
1010555555
1RHIE E-5 (Continued)LABORATORY PROGRAM ROUTINE
ANALYTICAL SERVICES ORGANIC PARAMETERS
Semi-Volatile Organic Compounds CAS Number36. Phenol 108-95-237. bis (2-Chloroethyl) ether 111-44-438. 2-OilaroFhenol 95-57-839. 1,3-Dichloroebenzene 541-73-140. 1,4-Dichlorobenzene 106-46-741. Benzyl Alcohol 100-51-642. 1,2-Dichlorobenzene 95-50-143. 2-Methylphenol 95-48-744. bis- (2-<3iloroisqDropyl) ether 39638-32-945. 4-Methylphenol 106-44-546. N-Nitroso-Dipropylandne 621-64-747. Hexachloroethane 67-72-148. Nitrobenzene 98-95-349. Iscphorone 78-59-150. 2-Nitrqphenol 88-75-551. 2,4-DimethylFhenol 105-67-952. Benzole Acid 65-85-053. bis(2H2iloroethyoKy)nethane 111-91-154. 2,4-Dichlorophenol 120-83-255. 1,2,4-Trichlorcbenzene 120-82-156. Naphthalene 91-20-357. 4-Chloroaniline 106-47-858. Hexachlorobutadiene 87-68-359. 4-Chloro-3-methylFhenol
(para-chloro-meta-cresol) 59-50-760. 2-Methyljnapthalene 91-57-661. Hexadilorocyclopentadiene 77-47-462. 2,4,6-Trichlorophenol 88-06-263. 2,4,5-TrichloroFhenol 95-95-464. 2-OiloronaFhthalene 91-58-765. 2-Nitroaniline 88-74-4
Contract RequiredDetection(1)
Low Water(2)
ucr/1101010101010101010101010101010105010101010101010101010501050
low Soil-.Sediment ( *VQ&3
330330330330330330330330330330330330330330330330
1600330330330330330330330330330330
1600330
1600
1MXE E-5 (Continued)LABORATORY PROGRAM ROUTINE
ANALYTICAL SERVICES ORGANIC PARAMETERSContract Required (1)
Detection Limits (CSDL)*
Semi-Volatile Organic66. Dimethyl Fhthalate67. Acenaphthylene68. 3-Nitroaniline69. Acenaphthene70. 2,4-Dirdtrotoluene71. 4-Nitrophenol72. Dibenzofuran73. 2,4-Dinitrotoluene74. 2,6-Dinitrotoluene75. Diethylphthalate76. 4-Qilorophenyl Hienyl Ether77. Fluorene78. 4-Nitroaniline79. 4,6-Dinitro-2-methylphenol80. N-nitrosodiphenylamine81. 4-Bronophenyl Rienyl Ether82. Hexachlorobenzene83. Pentachlorophenol84. Rienanthrene85. Anthracene86. Di-n-butylfhthalate87. Fluoranthene88. lyrene89. Butyl Benzyl Hithalate90. 3 ,3 ' -Dichlorobenzidlne91. Benzo (a) anthracene92. bis- (2-ethyle>tfl) phthalate93. Chrysene94. Di-n-octyl Hithalate95. Benzo (b) fluoranthene96. Benzo (k) fluoranthene97. Benzo(a) pyrene98. Indeno(1,2,3-cd)pyrene99. Dibenz (a, h) anthracene100. BenzoCg/h^Jperylene
GAS Number131-11-3208-96-899-09-283-32-951-28-5
100-02-7132-64-9121-14-2606-20-284-66-2
7005-72-386-73-7
100-01-6534-52-186-30-6
101-55-2118-74-187-86-585-01-8
120-12-784-74-2
206-44-0129-00-0085-68-791-94-156-55-3
117-81-7218-01-9117-84-0205-99-2207-08-950-32-8
193-39-553-70-3
, 191-24-2
Waterua/11010501050501010101010105050101010501010101010102010101010101010101010
(2) Low Soil..Sedimentua/ter330330
1600330
16001600
330330330330330330
16001600
330330330
1600330330330330330330660330330330330330330330330330330
E-5 (Ccntiiaied)IABORAIQRY TOX3WM ROUTINE
ANALYTICAL SERVICES ORGANIC PARAMETERSContract Required
T,i-miVg
Pesticides/PCS101. alpha-EHC102. beta-EHC103. delta-EHC104. garama-BHC (Llndane)105. Heptachlor106. Aldrln107. Heptachlor Epcodde108. Endoeulfan I109. Dieldrin110. 4,4'-COEin. Endrln112. Endosulfan n113. 4,4'-BCO114. Endosulfan Sulfate115. 4,4'-DDT116. Endrin Ketonen?. MethQExyciilor113. Chlordane119. Toxafhene120. APDCtaR-1016121. ABOCLDR-1221122. AFDOJ3R-1232123. APDdOR-1242124. AROdDR-1248125. AROCK3R-1254126. ARDCLOR-1260
Ntmiber319-84-6319-85-7319-86-858-89-976-44-8
309-00-21024-57-3959-98-860-57-172-55-972-20-8
33213-65-972-54-8
1031-07-850-29-3
53494-70-572-43-547-74-9
8001-35-212674-n-2ni04-28-2ni41-16-553469-21-912672-29-6n097-69-ln096-82-5
Low Water(2)
m/10.050.050.050.050.050.050.050.050.100.100.100.100.100.100.100.100.50.51.00.50.50.50.50.51.01.0
low SoiLj.ua/tar
8.08 .08.08.08 .08.08.08 .0
16.016.016.016.016.016.016.016.080.080.0
160.080.080.080.080.080.0
160.0160.0
OCNIRACr IABQRATQRY PROGRAM ROUTINEANALTOCAL SERVICES ORGANIC PARAMETERS
(1) Detection limits listed for soil/sediment and based on wetweight. The detection limits calculated by the laboratory forsoil/sediment, calculated on dry weight basis, as required by thecontract, will be higher.
(2) Medium Water Contract Required Detection Limits (CRDL) forVolatile Hazardous Substances List (HSL) Compounds are 100 timesthe individual low Water CRDL.(3) Medium Soil/Sediment CRDL for Volatile HSL Compounds are 100times the individual low Soil/Sediment CRDL.(5) Medium Water CRDL for Semi-Volatile HSL Compounds are 100 timesthe individual Low Water CRDL.(6) Medium Soil/Sediment CRDL for Semi-Volatile HSL Compounds are 60times the individual low Soil/Sediment CRDL.(7) Medium Water CRDL for Pesticide HSL Compounds are 100 tlmps theindividual low Water CRDL.(8) Medium Soil/Sediment CRDL for Pesticide HSL Compounds are 15times the individual low Soil/Sediment CRDL.* Specific detection limits are hi ily matrix dependent. Thedetection limits listed herein are provided for guidance any may
not always be achievable.