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Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 1 of 39 Revision date: 06.11.2017 _______________________________________________________________________________________________________________ SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier:

Substances

Substance name CAS No Index No EC No REACH No The transition period according to REACH Regulation, article 23 has not yet expired. Authorisation No

_______________________________________________________________________

Mixtures

Trade name / designation MethaSol Other means of identification

Hazard components for labelling

Kommentiert [A1]: Yellow marked: additional information required for the extended SDS (eSDS) Blue marked sentences are illustrating the single ingredients of mixtures (Use only if appropriate, e.g. for multi component mixtures). Italic marked sentences are used as content examples. Purple = new REACH, Annex II (UN-GHS) phrases Layout examples are given in chapters 2, 3, 8, 11 and 12. Of course other illustration alternatives and alternative substructures may be used in practice too. Kommentiert [A3]: The product identifier shall be provided in accordance with Article 18(2) of Regulation (EC) No 1272/2008 in the case of a substance and in accordance with Article 18(3)(a) of Regulation (EC) No 1272/2008 in the case of a mixture, and as provided on the label in the official language(s) of the Member State(s) where the substance or mixture is placed on the market, unless the Member State(s) concerned provide(s) otherwise. For substances subject to registration, the product identifier shall be consistent with that provided in the registration and the registration number assigned under Article 20(3) of this Regulation shall also be indicated.

Kommentiert [A7]: For mixtures only CLP, Art. 18b The product identifier for a mixture shall consist of both of the following: (a) the trade name or the designation of the mixture; (b) the identity of all substances in the mixture that contribute to the classification of the mixture as regards acute toxicity, skin corrosion or serious eye damage, germ cell mutagenicity, carcinogenicity, reproductive toxicity, respiratory or skin sensitisation, specific target organ toxicity (STOT) or aspiration hazard. Where, in the case referred to in (b), that requirement leads to the provision of multiple chemical names, a maximum of four chemical names shall suffice, unless more than four names are needed to reflect the nature and the severity of the hazards. The chemical names selected shall identify the substances primarily responsible for the major health hazards which have given rise to the classification and the choice of the corresponding hazard statements. The part of the product identifier “hazard components” according to CLP, Art. 18b would better belong to Sub-SECTION 2.2 for mixtures. BUT: ECHA SDS Guidance is stated in a footnote (No. 54) as additional explanation to the header "product identifier": "Note that the product identifier, although a label element, is not given in subsection 2.2 as it is not specified as one of the elements which should appear here. It is to be given in section 1.1." For further information on the compilation of the SDS, please consult the Guidance on the compilation of safety data sheets (http://echa.europa.eu/guidancedocuments ... e-on-reach).

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 2 of 39 Revision date: 06.11.2017 ______________________________________________________________________________________________________________ 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses In compliance with the conditions described in the annex to this safety data sheet.

Summarized overview of registered and identified uses and their respective exposure scenarios: pls. see annex to this SDS. See section 16 for a comprehensive list of uses, for which an exposure scenarion is provided as an annex. Uses advised against: Do not use for injecting or spraying. Reasons:

1.3 Details of the supplier of the safety data sheet:

Supplier: Name Address Information contact E-Mail (competent person)

Importer / Only Representative: Name Address Information contact E-Mail (competent person) 1.4 EMERGENCY TELEPHONE NUMBER: Foot note (general hint): Layout examples are given in the sections 2, 3, 8, 11 and 12. Of course other illustration alternatives and alternative substructures may be used in practice too.

Kommentiert [A8]: At least the identified uses relevant for the recipient(s) of the substance or mixture shall be indicated. This shall be a brief description of what the substance or mixture is intended to do, such as “flame retardant”, “antioxidant”. The uses which the supplier advises against and the reasons why shall, where applicable, be stated. This need not be an exhaustive list. Where a chemical safety report is required, the information in this subsection of the safety data sheet shall be consistent with the identified uses in the chemical safety report and the exposure scenarios from the chemical safety report set out in the annex to the safety data sheet. ECHA FAQ: For registered substances for which a Chemical Safety Report (CSR) is required, the information appearing in section 1.2 of the SDS needs to be in line with the identified uses in the CSR (under REACH, the definition of use goes beyond the chemical function) and the Exposure Scenario (ES) annexed to the SDS. Intuitive ES titles can be reported in section 1.2. When the use descriptor system is used in the ES, it is advised that, in section 1.2, the uses of the substance are described in a generic wording while remaining consistent with that of the use descriptor system. Reporting the use descriptor codes in section 1.2 is not recommended as it may lead to lengthy lists. The Process and Product Categories in the use descriptor system can be used as an indication. For registered substances for which a CSR is not required (between 1-10 tonnes/year), substances not yet registered or not subject to registration (e.g. below 1 tonne/year or listed in Annex IV or V) and mixtures, the intended uses known to the supplier need to be indicated, with a brief description of what the substance or mixture is intended to do, such as "flame retardant in textile fibres", "antioxidant in paints, cosmetics, detergents", etc. Kommentiert [A13]: Reason why uses advised against. REACH, Article 37.3 requirement, not yet explicitely content in REACH, annex I. Example: Indoor use on large surface area will potentially exceed Consumer DNEL (assessed by ECETOC TRA). Kommentiert [A15]: manufacturer/importer/only representative/downstream user/distributor: Kommentiert [A16]: In case of non-EU Supplier

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 3 of 39 Revision date: 06.11.2017 _______________________________________________________________________________________________________________ SECTION 2: Hazards identification 2.1. Classification of the substance or mixture:

Classification according to Regulation (EC) No 1272/2008 [CLP]

SCL and/or M-factor Classification procedure

Flam. Liq. 2, H225 Acute Tox. 3, H301 Acute Tox. 3, H311 Acute Tox. 3, H331 STOT RE 1, H372 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Repr. 1A, H360D

C ≥ 1 %: STOT RE 1, H372 0,1 ≤ C < 1 %: STOT RE 2, H373 M = 100 M = 10 C ≥ 3 %

On basis of test data Practical experience / human evidence Practical experience / human evidence Practical experience / human evidence On basis of test data On basis of test data On basis of test data Legal classification

Additional information: Full text of H- and EUH-phrases: see SECTION 16.

Kommentiert [A19]: The classification of the substance or the mixture which results from the application of the classification criteria in Regulation (EC) No 1272/2008 shall be given. Where the supplier has notified information regarding the substance to the classification and labelling inventory in accordance with Article 40 of Regulation (EC) No 1272/2008, the classification given in the safety data sheet shall be the same as the classification provided in that notification. If the mixture does not meet the criteria for classification in accordance with Regulation (EC) No 1272/2008, this shall be clearly stated. Information on the substances in the mixture is provided under subsection 3.2.. The most important adverse physical, human health and environmental effects shall be listed in accordance with Sections 9 to 12 of the safety data sheet, in such a way as to allow non-experts to identify the hazards of the substance or mixture. Kommentiert [A20]: Proposed standard phrases (see www.euphrac.eu) are for example: Calculation method. Bridging principle "Dilution". Bridging principle "Batching". Bridging principle "Concentration of highly hazardous mixtures". Bridging principle "Interpolation within one toxicity category". Bridging principle "Substantially similar mixtures". Bridging principle "Aerosols". For mixtures it may be possible to use also the „calculation method“ as classification procedure.

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 4 of 39 Revision date: 06.11.2017 _______________________________________________________________________________________________________________ 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS]

Hazard pictograms

GHS02 GHS06 GHS08 GHS09 Signal word: Danger

Hazard statements: H225 Highly flammable liquid and vapour. H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled. H372 Causes damage to organs through prolonged or repeated exposure (oral, kidneys). H360D May damage the unborn child. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P308+P311 IF exposed or concerned: Call a POISON CENTER/doctor. P301+P330 IF SWALLOWED: Rinse mouth. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Supplemental Hazard information:

Special rules for supplemental label elements for certain mixtures: Additional labelling:

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 5 of 39 Revision date: 06.11.2017 ______________________________________________________________________________________________________________ 2.3 Other hazards

Adverse physicochemical effects: Adverse human health effects and symptoms: Adverse environmental effects:

Other adverse hazards: ___________________________________________________________________________________ SECTION 3. Composition/information on ingredients

3.1 Substances

Substance name: INDEX No: EC No: REACH No: CAS No: Purity:

Synonymes: Stabilisers: Hazard impurities: 3.2 Substances not applicable

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 6 of 39 Revision date: 06.11.2017 _______________________________________________________________________________________________________________ ALTERNATIVE for mixtures 3.1 Substances not applicable 3.2 Mixtures

Description of the mixture: Aqueous solution of ABC. Hazardous ingredients EXAMPLE

Substance name

CAS No. INDEX No.

EC No. Concentration

Classification according Regulation (EC) No. 1272 [CLP]

SCL and/or M-factor

ABC 123-45-6 123-456-7 50 % Flam. Liq. 2, H225 Acute Tox. 3, H301 Acute Tox. 3, H311 Acute Tox. 3, H331 STOT RE 1, H372 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Repr. 1A, H360D

C ≥ 1 %: STOT RE 1, H372 0,1 ≤ C < 1 %: STOT RE 2, H373 M = 100 M = 10 C ≥ 3 %

Substance name REACH No. ABC 01-XXXXXXXXXX-YY-ZZZZ

Additional information: Full text of H- and EUH-phrases: see SECTION 16. This mixture does not contain further substances fulfilling the criteria of hazard class "acute toxicity" according to CLP regulation.

Kommentiert [A31]: This example is different to SECTION 2! Kommentiert [A32]: CLP, article 24: The manufacturer, importer or downstream user of a substance in a mixture may submit a request to the Agency to use an alternative chemical name which refers to that substance in a mixture either by means of a name that identifies the most important functional chemical groups or by means of an alternative designation, where the substance meets the criteria set out in Part 1 of Annex I and where he can demonstrate that disclosure on the label or in the safety data sheet of the chemical identity of that substance puts the confidential nature of his business, in particular his intellectual property rights, at risk. Where the use of an alternative chemical name has been allowed, but the classification of the substance in a mixture for which the alternative name is used no longer meets the criteria set out in section 1.4.1 of Annex I, the supplier of that substance in a mixture shall use the product identifier for the substance in accordance with Article 18 on the label and in the safety data sheet, and not the alternative chemical name. Where the supplier of a mixture, before 1 June 2015, has demonstrated under Art. 15 of 1999/45/EC that the disclosure of the chemical identity of a substance in a mixture puts the confidential nature of his business at risk, he can continue to use the agreed alternative name for the purposes of this Regulation.

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 7 of 39 Revision date: 06.11.2017 _________________________________________________________________________________________________________________ SECTION 4: First aid measures 4.1 Description of first aid measures General information Following inhalation Following skin contact Following eye contact

Following ingestion Self-protection of the first aider: 4.2 Most important symptoms and effects, both acute and delayed Symptoms Effects 4.3 Indication of any immediate medical attention and special treatment needed

Notes for the doctor Special treatment

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 8 of 39 Revision date: 06.11.2017 ____________________________________________________________________________________________________________________________ SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media

Unsuitable extinguishing media

5.2 Special hazards arising from the substance or mixture Hazardous combustion products

5.3 Advice for fire-fighters Additional information

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 9 of 39 Revision date: 06.11.2017 ______________________________________________________________________________________________________________ SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel Protective equipment

Emergency procedures For emergency responders Personal protective equipment

6.2 Environmental precautions 6.3 Methods and material for containment and cleaning up For containment For cleaning up Other information 6.4 Reference to other sections

Additional information

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 10 of 39 Revision date: 06.11.2017 ___________________________________________________________________________________________________________________________ SECTION 7: Handling and storage 7.1 Precautions for safe handling

Protective measures Advice on safe handling Fire preventions Aerosol and dust generation preventions Environmental precautions

Advice on general occupational hygiene

Kommentiert [A56]: Recommendations shall be specified to: (a) allow safe handling of the substance or mixture, such as containment and measures to prevent fire as well as aerosol and dust generation; (b) prevent handling of incompatible substances or mixtures; (c) draw attention to operations and conditions which create new risks by altering the properties of the substance or mixture, and to appropriate countermeasures; and (d) reduce the release of the substance or mixture to the environment, such as avoiding spills or keeping away from drains.

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 11 of 39 Revision date: 06.11.2017 ______________________________________________________________________________________________________________ 7.2 Conditions for safe storage, including any incompatibilities Technical measures and storage conditions Packaging materials Requirements for storage rooms and vessels Hints on storage assembly

Storage class

Materials to avoid Further information on storage conditions

7.3 Specific end uses Recommendations Specific end uses

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 12 of 39 Revision date: 06.11.2017 _______________________________________________________________________________________________________________ SECTION 8: Exposure controls/personal protection Preventive industrial medical examinations are to be carried out. 8.1 Control parameters

Occupational exposure limits

Biological limit values

Exposure limits at intended use

Limit value type (country of origin) Substance name EC-No. CAS-No. Occupational exposure limit value

Monitoring and observation processes Peak limitation

Source

Long term Short term AGW (DE) TRGS 900 OEL (EU)

Limit value type (country of origin) Substance name EC-No. CAS-No. Limit Value Parameter Test material Test date Source

BGW (DE) 2-Propanol 67-63-0 50 mg/l 50 mg/l Acetone Urine (U) Whole Blood (B) b TRGS 903

Kommentiert [A65]: Not mandatory: if chosen, overflow factor, Instantaneous value, category must be given here under. See for more info: TRGS 900. Otherwise: Overflow factor x AGW = Shortterm value Kommentiert [A66]: The national occupational exposure limit values that correspond to Community occupational exposure limit values acc. 98/24/EC, including any notations as referred to in Article 2(1) of 95/320/EC Kommentiert [A67]: The national occupational exposure limit values that correspond to Community limit values acc. 2004/37/EC, including any notations as referred to in Article 2(1) of 95/320/EC Kommentiert [A68]: metabolite Kommentiert [A69]: Whole Blood (B), Erythrocytes (E), Plasma/Serum (P/S), Urine (U) Kommentiert [A70]: The national biological limit values that correspond to Union biological limit values in accordance with Directive 98/24/EC, including any notations as referred to in Article 2(3) of Decision 2014/113/EU;

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 13 of 39 Revision date: 06.11.2017 _______________________________________________________________________________________________________________

DNEL/PNEC-values Substance name

DNEL Worker DNEL type value remark Acute – dermal, local effects Long-term – dermal, local effects Long-term – dermal, systemic effects Acute – inhalation, local effects Acute – inhalation, systemic effects Long-term – inhalation, local effects Long-term – inhalation, systemic effects

DNEL Consumer

DNEL type value remark Long-term – oral, systemic effects Acute – dermal, local effects Long-term – dermal, local effects Long-term – dermal, systemic effects Acute – inhalation, local effects Acute – inhalation, systemic effects Long-term – inhalation, local effects Long-term – inhalation, systemic effects

PNEC

PNEC type value remark PNEC aquatic, freshwater PNEC aquatic, marine water PNEC aquatic, intermittent release PNEC sediment, freshwater PNEC sediment, marine water PNEC soil PNEC sewage treatment plant PNEC air PNEC secondary poisoning

Risk management measures according to used control banding approach Control banding for chemicals according to the ILO CHEMICAL CONTROL TOOLKIT (ICCT)

Task Hazard band Scale of use Ability to

become airborne

Control approach

Control guidance sheet

Kommentiert [A71]: In case of mixtures multiple entries maybe possible.

Kommentiert [A72]: If it is not possible to identify a DNEL (DMEL), then this shall be clearly stated and fully justified (REACH, Annex I, 1.4.2).

Kommentiert [A73]: If applicable

Kommentiert [A74]: In the Guidance on information requirements and chemical safety assessment Part B: Hazard Assessment it’s named PNEC water. PNEC aquatic is in compliance with terminus technicus use in CLP for the hazard class “Aquatic Toxicity”. Kommentiert [A75]: If it is not possible to derive the PNEC, then this shall be clearly stated and fully justified (REACH, Annex I, 3.3.2)

Kommentiert [A76]: No standardised procedure exists. Kommentiert [A77]: no-effect concentration in food Kommentiert [A78]: OPTIONAL: Where a control banding approach is used to decide on risk management measures in relation to specific uses, sufficient detail shall be given to enable effective management of the risk. The context and limitations of the specific control banding recommendation shall be made clear.

Kommentiert [A79]: Dustiness (Y/N) Volatility (Y/N)

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 14 of 39 Revision date: 06.11.2017 ______________________________________________________________________________________________________________ 8.2 Exposure controls

Appropriate engineering controls

Personal protective equipment Eye / Face protection Suitable eye protection

Other eye protection measures

Skin protection Hand protection

By short-term hand contact Suitable gloves type Suitable material

Breakthrough time: Thickness of the glove material Wear duration with occasional contact (splashs) By long-term hand contact Suitable gloves type

Suitable material Breakthrough time: Thickness of the glove material

Wear duration with permanent contact Unsuitable material Additional hand protection measures

Body protection

Other skin protection measures Respiratory protection

Thermal hazards

Kommentiert [A80]: The information required in the present subsection shall be provided, unless an ES containing that information is attached to the SDS. Where the supplier has waived a test under Section 3 of Annex XI, he shall indicate the specific conditions of use relied on to justify the waiving. Where a substance has been registered as an isolated intermediate (on-site or transported), the supplier shall indicate that this SDS is consistent with the specific conditions relied on to justify the registration in accordance with Article 17 or 18.

Kommentiert [A85]: When specifying protective equipment to be worn for materials that represent a thermal hazard, special consideration shall be given to the construction of the PPE.

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 15 of 39 Revision date: 06.11.2017 __________________________________________________________________________________ 8.2.3 Environmental exposure controls:

Consumer exposure control Measures related to consumer uses of the substance (as such or in mixtures): Measures related to the service life of the substance in articles:

Kommentiert [A87]: OPTIONAL for ext. SDS: REMARK - ECHA Guidance Part G, 238 ff.: Annex II does not specifically mention RMMs and OCs related to consumers, but section 8 of annex II stipulates that the RMM across all the identified uses shall be summarised in section 8 of the SDS. Potential exposure of consumers during the life of the substance resulting from identified downstream uses are to be covered in the CSA for a substance. It is therefore recommended to add a section 8.2.3 in the extended safety data sheet to include measures related to consumer uses of the substance (as such or in mixtures) and to the service life of the substance in articles. This information is addressed to the downstream users under REACH i) placing mixtures for use in the general public on the market and ii) processing substances or mixtures into articles. It may also facilitate the communication related to substances of very high concern, for which risk management advice beyond downstream uses can be required under article 7 and article 33 of REACH.

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 16 of 39 Revision date: 06.11.2017 ______________________________________________________________________________________________________________ SECTION 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties

Appearance Physical state: Colour: Odour: Odour threshold:

Value Concentration Method Temperature Pressure Remark pH Melting point/freezing point Initial boiling point/boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits

Upper explosive limits Lower explosive limits

Vapour pressure Vapour density Relative density Solubility(ies) Partition coefficient: n-octanol/water

Auto-ignition temperature Decomposition temperature Viscosity

Viscosity, dynamic Viscosity, cinematic

Explosive properties Oxidising properties

Kommentiert [A89]: The pH shall be indicated of the substance/mixture as supplied or of an aqueous solution; in the latter case, indicate the concentration and temperature, preferably for room temperature. Where the pH can be properly measured, it shall be deter-mined from the original product. Otherwise, the pH of the dissolved substance shall be indi-cated. Also specify if the alkali or acid reserve has been considered.

Kommentiert [A90]: It should be stated whether the value indicated has been measured or calculated, and which substance(s) it refers to. Kommentiert [A91]: Relative density of gases and vapors with respect to dry air. The relative density is a dimensionless quantity. Kommentiert [A92]: Relative density of liquids + solids with respect to water. Kommentiert [A93]: For mixtures, this is useful information with respect to the individual constituents only.

Kommentiert [A94]: Viscosity (dynamic or kinematic viscosity) or the flow times incl. the temperature shall be provided for the solvent separation test + the solvent content. For mixtures containing hydrocarbons in an overall concentration of 10% or more, the flow time or the kinematic viscosity at 40 °C shall be specified subject to CLP, Annex 1, 3.10. In addition: - indicate vapour pressure at 50 °C for volatile fluids (in order to enable distinction between gases + liquids referring chapter 1.2 of the GHS) - indicate most volatile component for mixtures where the vapour pressure is predominantly determined by this components - saturated vapour concentration (SVC). SVC (in ml/m3= vapour pressure (hPa) · 987.2 Kommentiert [A95]: cinematic viscosity = dynamic viscosity / density

Kommentiert [A96]: Difference between „delivery state“ and „standard conditions“ necessary

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 17 of 39 Revision date: 06.11.2017 ___________________________________________________________________________________ 9.2 Other information: Physical hazards:

If data for any of these hazard classes is not available, these hazard classes shall still be listed in the safety data sheet with a statement that data is not available or not applicable.

Explosives

Justification for data waiving: Screening procedures

Value Method Remark Exothermic decomposition energy Decomposition temperature Oxygen balance

Safety characteristics

Value Method Remark Thermal sensitivity: Number of fragments Regulation (EC) No

440/2008, Annex, A.14

Sensitiveness to impact :Impact energy Sensitiveness to friction: Friction load Limiting impact energy

UN Test series 4

Fragmented length Limiting diameter Time for a pressure rise from 690 to 2070 kPa Limiting impact energy Limiting load

Assessment / Classification: Flammable gases

Justification for data waiving: Safety characteristics:

Value Temperature Pressure Method Remark Lower explosion limit Upper explosion limit

Assessment / Classification:

Kommentiert [A99]: Option: A short standard phrase should be chosen from EuPhraC if hazard class is not applicable.

Kommentiert [A100]: For example: Molecular formula Molecular weight Kommentiert [A101]: Only if hazard class applies, please give details on test data, e.g. as follows: Kommentiert [A102]: Alternative test procedure: UN Manual of Tests and Criteria, Part I, UN Test 1 (b) Koenen test, UN Test 3 (a) (ii) BAM Fallhammer, UN Test 3 (b) (i) BAM friction apparatus.

Kommentiert [A103]: Option: A short standard phrase should be chosen from EuPhraC if hazard class is not applicable. Kommentiert [A104]: Only if hazard class applies, please give details on test data, e.g. as follows:


Flammable aerosols


Assessment / Classification: Oxidising gases


Value Method Remark Oxidising Power (OP) Xi Content of the oxidising component Coefficient of oxygen equivalency


Gases under pressure Justification for data waiving:

Safety characteristics:

Value Result Remark Molecular weight Vapour pressure at 50 °C Vapour pressure at 20 °C Critical temperature Critical pressure Critical density


Value Result Method Remark Content of flammable components Chemical heat of combustion Ignition distance Testing is not required for foam aerosols. Time equivalent Deflagration density Maximum flame height Testing is not required for spray aerosols. Flame duration

Kommentiert [A105]: Option: A short standard phrase should be chosen from EuPhraC if hazard class is not applicable. Kommentiert [A106]: Only if hazard class applies, please give details on test data, e.g. as follows: Kommentiert [A107]: X % by mass of the contents are flammable. Kommentiert [A108]: For example ΔHc(i) = Specific heat of combustion (kJ/g):


Kommentiert [A111]: Option: A short standard phrase should be chosen from EuPhraC if hazard class is not applicable. Kommentiert [A112]: Only if hazard class applies, please give details on test data, e.g. as follows: Kommentiert [A113]: For example: Compressed gas (Comp. Gas) or Liquefied gas (Liq. Gas) or Refrigerated liquefied gas (Ref. Liq. Gas) Dissolved gas (Diss. Gas)


Flammable liquids


Value Method Remark Flash point Sustaining combustion

Assessment / Classification: Flammable solids Justification for data waiving: Safety characteristics:

Value Method Remark Burning rate Burning rate with wetted zone Moisture content





Self-reactive substances and mixtures

Justification for data waiving: Screening procedures

Value Method Remark Exothermic decomposition energy Decomposition temperature

Safety characteristics:

Value Result Method Remark Propagation of detonation (Yes/Partially/No) Propagation of deflagration (Yes, rapidly/Yes, slowly/No) Effect of heating under confinement (Violent/Medium/Low/No) Explosive power (Not low/Low/None) Self-accelerating decomposition temperature (SADT)


Pyrophoric liquids


Assessment / Classification: Pyrophoric solids Justification for data waiving:

Safety characteristic: Result / Evaluation Method Remark

Ignition time on contact with air (s)


Value Result Method Remark Ignition time on contact with air No ignition within 5 minutes. Regulation (EC) No.

440/2008, Annex, A.13

Effect on filter paper


Kommentiert [A120]: Only if hazard class applies, please give details on test data, e.g. as follows: Kommentiert [A121]: As result „Yes“, „Partial“ or „No“ is obtained from a Series A test. Kommentiert [A122]: As result “Yes rapidly”, “Yes slowly” or “No“ is obtained from a Series C test. Kommentiert [A123]: As result “Violent”, “Medium”, “Low” or “No“ is obtained from a Series E test. Kommentiert [A124]: As result “Not low”, “Low” or “None“ is obtained from a Series F test.


Kommentiert [A126]: Only if hazard class applies, please give details on test data, e.g. as follows:



Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 21 of 39 Revision date: 06.11.2017

_______________________________________________________________________________________________________________ Self-heating substances and mixtures Justification for data waiving: Safety characteristics:

Value Result Method Remark Induction time Max. temperature rised


Substances or mixtures which, in contact with water emit flammable gases


Value Method Remark step of the test procedure Maximum rate of evolution of flammable gas Chemical identity of the evolved gas


Kommentiert [A129]: Option: A short standard phrase should be chosen from EuPhraC if hazard class is not applicable. Kommentiert [A130]: Only if hazard class applies, please give details on test data, e.g. as follows: Kommentiert [A131]: e.g. positive or negative

Kommentiert [A132]: Option: A short standard phrase should be chosen from EuPhraC if hazard class is not applicable. Kommentiert [A133]: Only if hazard class applies, please give details on test data, e.g. as follows: Kommentiert [A134]: Reacts vigorously with water and spontaneous ignition of the evolved gas occurs.


Oxidising liquids


Value Method Remark Preliminary test Mean pressure rise time of test mixture Mean pressure rise time of reference mixture Test with an inert substance


Oxidising solids Justification for data waiving: Safety characteristics:

Value Method Remark Preliminary test Mean burning time of test mixture Mean burning time of reference mixture




Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 23 of 39 Revision date: 06.11.2017 _________________________________________________________________________________ Organic peroxides


Value Result Method Remark Available oxygen content Percentage of hydrogen peroxide Propagation of detonation (Yes/Partial/No) Propagation of deflagration (Yes rapidly/Yes slowly/No) Effect of heating under confinement (Violent/Medium/Low/No) Explosive power (Not low/Low/None) Self-accelerating decomposition temperature (SADT)


Metal corrosion



Value Temperature Test duration Method Remark Corrosion rate (mm steel/year) Corrosion rate (mm aluminium/year) Intrusion depth

Kommentiert [A139]: Option: A short standard phrase should be chosen from EuPhraC if hazard class is not applicable. Kommentiert [A140]: Only if hazard class applies, please give details on test data, e.g. as follows: Kommentiert [A141]: As result „Yes“, „Partial“ or „No“ is obtained from a Series A test. Kommentiert [A142]: As result “Yes rapidly”, “Yes slowly” or “No“ is obtained from a Series C test. Kommentiert [A143]: As result “Violent”, “Medium”, “Low” or “No“ is obtained from a Series E test. Kommentiert [A144]: As result “Not low”, “Low” or “None“ is obtained from a Series F test.



Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 24 of 39 Revision date: 06.11.2017 _____________________________________________________________________________________________________________________________ SECTION 10: Stability and reactivity 10.1 Reactivity 10.2 Chemical stability 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid:

10.5 Incompatible materials: 10.6 Hazardous decomposition products:

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 25 of 39 Revision date: 06.11.2017 _______________________________________________________________________________________________________________ SECTION 11: Toxicological information Toxicokinetics, metabolism and distribution 11.1 Information on toxicological effects

Ithalic marked sentences are used as content examples In case that test data regarding one endpoint/differentiation exist for the mixture itself, the classification is carried out according to the substance criteria (excluding CMR!). If no test data exist, the criteria for mixture classification has to be used (calculation method); in this case the toxicological data of the ingredients are shown. The entry Substance illustrating the single ingredients/substances of mixtures (use only if appropriate, e.g. for multi component mixtures). If the mixture calculation method must be used.

Kommentiert [A156]: Absence of specific data: It may not always be possible to obtain information on the hazards of a substance or mixture. In cases where data on the specific substance or mixture are not available, data on similar substances or mixtures, if appropriate, may be used, provided the relevant similar substance or mixture is identified. Where specific data are not used, or where data are not available, this shall be clearly stated Interactive effects Information on interactions shall be included if relevant and available.

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 26 of 39 Revision date: 06.11.2017 ________________________________________________________________________________________________________________ Substance Acute toxicity Practical experience / human evidence

Animal data

Other information

Assessment / Classification

Skin corrosion/irritation Practical experience / human evidence

Acid-/Alkali reserve (buffer capacity for mixtures with extreme pH values) Acidic reserve [g NaOH/100 g product]: Alkaline reserve [g H2SO4/100 g product]: Animal data

In-vitro skin test not corrosive (OECD 439)

Other information Assessment / Classification Causes skin irritation.

Effect dose / -concentration Value Species Method Symptoms / delayed effects Remark Substance 1 Acute oral toxicity LD50 1980 mg/kg bw Rat OECD 401 Acute dermal toxicity ATE: 500 mg/kg bw converted Acute Toxicity point Estimate Acute inhalative toxicity (gas) Acute inhalative toxicity (vapour) LC50

> 20 mg/l/4h Rat Regulation (EC) No. 440/2008, Annex, B.2

Acute inhalative toxicity (dust/mist)

Substance 2

Species Method Exposure time Result /Evaluation Remark Substance 1 Rabbit OECD 404 Erythema

Scores: 2.3 irritant

Kommentiert [A157]: LD50 or ATpE/ATEmix Kommentiert [A158]: if any/relevant Kommentiert [A159]: Information shall be provided on likely routes of exposure and the effects of the substance or mixture via each possible route of exposure, that is, through ingestion (swallowing), inhalation or skin/eye exposure. If health effects are not known, this shall be stated. Kommentiert [A160]: LD50 oder ATpE/ for mixtures: ATEmix Kommentiert [A161]: LC50 or cATpE/ATEmix Kommentiert [A162]: e.g. exposure time for inhalative toxicity:4 h

Kommentiert [A163]: If appropriate, give mean scores for erythema /oedema.

Kommentiert [A164]: (Q)SAR and/or e.g. in vitro test results Kommentiert [A165]: Inclusive special effect, e. g. defatting properties (R66/EUH66), indication of ** subcategory 1A, 1B, 1C, if possible.


Eye damage/irritation Practical experience / human evidence Animal data

In vitro eye test not corrosive (OECD 438). Other information reversible.

Assessment / Classification Based on available data, the classification criteria are not met.

Sensitisation to the respiratory tract/skin

Sensitisation to the respiratory tract Practical experience / human evidence

Other information Assessment / Classification Not classifiable due to data lacking. Skin sensitisation Practical experience / human evidence Animal data

Effect dose/ -concentration Value Species Method Result / Evaluation Remark Substance 1 Guinea pig OECD

406 not sensitising

Other information Assessment / Classification Based on available data, the classification criteria are not met.

Species Method Result / Evaluation Remark Substance 1 Albino rabbit OECD 405 Corneal opacity

Scores: 0,7 Iritis Scores: 0,7 Conjunctival Redness Scores: 1,9 Conjunctival oedema (chemosis) Scores: 1,5

Kommentiert [A166]: If appropriate, give mean scores.

Kommentiert [A167]: (Q)SAR and/or e.g. in vitro test results

Kommentiert [A168]: e.g. (Q)SAR) Test results from animal test studies may give valuable indications but by now there are no validated animal test models established.


CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)

Germ cell mutagenicity In vitro mutagenicity/genotoxicity

Cell type/ Organism Genetic Endpoint Method Result / Evaluation Remark

Substance 1 Salmonella typhimurium pointmutations OECD 471 positive In vivo mutagenicity/genotoxicity

Effect dose/ -concentration Value Cell type/ Organism Genetic Endpopint Method Result/ Evaluation Remark Substance 1 NOAEL 500 mg/kg bw Bone marrow / mouse

Structural or numeric chromosome aberration.

OECD 475 positive

Other information


Carcinogenicity

Practical experience / human evidence

Animal data Effect dose/ -concentration

Value Exposure route Exposure time Exposure duration Species Method Result / Evaluation Remark

Substance 1

Other information Assessment / Classification

Kommentiert [A169]: e.g. cell lines like mouse lymphoma cells; bacteria

Kommentiert [A170]: e.g. bone marrow or liver cells; chinese hamster, mouse or rat

Kommentiert [A171]: e.g. gene mutation, structural or numeric chromosome aberration, DNA-damage

Kommentiert [A172]: e.g. interaction with genetic material of germ cells or (Q)SAR

Kommentiert [A173]: The term "Carcinogenicity" is not the correct scientificial term. Correct term "Cancerogenicity".

Kommentiert [A174]: e.g. 1 or 2 a (years) In contrary: Exposure frequency e.g. 5 x per week

Kommentiert [A175]: QSAR or non-standard methods

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 29 of 39 Revision date: 06.11.2017 ______________________________________________________________________________________________________________

Reproductive toxicity

Practical experience / human evidence Animal data Adverse effects on sexual function and fertility

Effect dose/ -concentration

Value Exposure route Exposure duration Species Method Result / Evaluation Remark

Substance 1 NOAEL 1000 mg/kg/d

oral 28 d Rat OECD 421 negative

Adverse effects on developmental toxicity Effect dose/ -concentration

Value Exposure route Exposure duration Species Method Result / Evaluation Remark

Substance 1

Effects on or via lactation Effect dose/ -concentration

Value Exposure route Exposure duration Species Method Result Evaluation Remark

Substance 1

Other information Assessment / Classification

Overall assessment on CMR properties

Kommentiert [A176]: DSD and REACH, Annex II: Toxicity for reproduction

Kommentiert [A177]: -effects / Observations -Impairment of fertility/sexual function -Developmental toxicity Effects on or via lactation( DSD: R 64)

Kommentiert [A178]: -effects / Observations -Impairment of fertility/sexual function -Developmental toxicity Effects on or via lactation( DSD: R 64)

Kommentiert [A179]: -effects / Observations -Impairment of fertility/sexual function -Developmental toxicity Effects on or via lactation (DSD: R 64)


Specific target organ toxicity (single exposure) STOT SE 1 and 2 Practical experience / human evidence Animal data


Value Exposure duration Species Method Specific effects Organs affected Remark

Substance 1 Oral specific target organ toxicity (single exposure)

Dermal specific target organ toxicity (single exposure)

Inhalative specific target organ toxicity (single exposure)

vapour

Other information


STOT SE 3 Irritation to respiratory tract Practical experience / human evidence No data available. Other information Assessment / Classification Narcotic effects Practical experience / human evidence Other information Assessment / Classification

Kommentiert [A181]: Serious Non lethal effects

Kommentiert [A182]: Delayed and immediate effects as well as chronic effects from short and long-term exposure. Information shall be provided on whether delayed or immediate effects can be expected after short or long- term exposure. Information on acute and chronic health effects relating to human exposure to the substance or mixture shall also be provided. Where human data are not available, animal data shall be summarised and the species clearly identified. It shall be indicated whether toxicological data is based on human or animal data.

Kommentiert [A183]: Transient effects (Cat 3):

-Respiratory tract irritation (DSD: R 37) -Narcotic effects (DSD: R 67) Kommentiert [A184]: Hazard class „Irritation to respiratory tract” in generally on basis of Practical experience / human evidence. STOT-SE Category 3 Kommentiert [A185]: e.g. in vitro test results

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 31 of 39 Revision date: 06.11.2017 _________________________________________________________________________________

Specific target organ toxicity (repeated exposure) STOT RE 1 and 2 Practical experience / human evidence Animal data

Other information

Assessment / Classification Based on available data, the classification criteria are not met.

Aspiration hazard Practical experience / human evidence No data available. Experimental data viscosity data: see SECTION 9. Assessment / Classification Based on available data, the classification criteria are not met.


Value Exposure duration Species Method Specific effects Organs affected Remark

Substance 1 Oral specific target organ toxicity (repeated exposure)

NOAEL 1000 mg/kg/d

oral 90 d rat OECD 408

none

Dermal specific target organ toxicity (repeated exposure)

Inhalative specific target organ toxicity (repeated exposure)

Kommentiert [A186]: Corresponds to „Repeated dose toxicity“ Main header in accordance with Annex II and IUCLID, but uknown by CLP and UN-GHS

Kommentiert [A187]: 2 years

Kommentiert [A188]: DSD: covered under Acute toxicity–R65

Kommentiert [A189]: Cinematic viscosity: …mm2/sec (cStokes) at 40 °C. Give hint to chapter 9 if appropriate

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 32 of 39 Revision date: 06.11.2017 ______________________________________________________________________________________________________________ Symptoms related to the physical, chemical and toxicological characteristics:

In case of ingestion In case of skin contact: In case of inhalation: In case of eye contact:

Mixtures Substance 1 Substance 2 Substance 3

etc.

Other information:

Kommentiert [A191]: Mixture versus substance information The substances in a mixture may interact with each other in the body resulting in different rates of absorption, metabolism and excretion. As a result, the toxic actions may be altered and the overall toxicity of the mixture may be different from that of the substances in it. This shall be taken into account when providing toxicological information in this section of the SDS. It should be indicated clearly if there are test data for the mixture as whole or whether there are only relevant test data for the ingredients. For the health effects of CMR, classification for a given health effect based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC, and relevant information for the substances listed under Section 3 shall be provided.

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 33 of 39 Revision date: 06.11.2017 ______________________________________________________________________________________________________________ SECTION 12: Ecological information In case that test data regarding one endpoint/differentiation exist for the mixture itself, the

classification is carried out according to the substance criteria (excluding biodegradation and bioaccumulation). If no test data exist, the criteria for mixture classification has to be used (calculation method); in this case the toxicological data of the ingredients are shown.

12.1 Toxicity: Aquatic toxicity

Acute (short-term) fish toxicity

Chronic (long-term) fish toxicity

Acute (short-term) toxicity to crustacea

Chronic (long-term) toxicity to crustacea

Acute (short-term) toxicity to algae and cyanobacteria Toxicity to other aquatic plants / organisms Toxicity to microorganisms

Effect dose/ -concentration Value Test duration Species Result/ Evaluation Method Remark Substance 1 LC50 XX mg/l 96 h Zebra fish OECD 203 semistatic

Effect dose/ -concentration Value Test duration Species Result/ Evaluation Method Remark Substance 1 NOEC XX mg/l 28 d Rainbow trout OECD 201 Inhibition of growth rate

Effect dose/ -concentration Value Test duration Species Result/ Evaluation Method Remark Substance 1 EC50 XX mg/l 48 h Daphnia magna OECD 202 Immobilisation

Effect dose/ -concentration Value Test duration Species Result/ Evaluation Method Remark Substance 1 NOEC XX mg/l 28 d Daphnia magna OECD 211 Reproduction test

Effect dose/ -concentration Value Test duration Species Result/ Evaluation Method Remark Substance 1 EC50 XX mg/l 72 h Scenedesmus subspicatus OECD 201 Inhibition of growth rate

Effect dose/ -concentration Value Test duration Species Result/ Evaluation Method Remark Substance 1 EC50 XX mg/l 7 d Lemna minor OECD 221 Inhibition of growth rate

Effect dose/ -concentration Value Test duration Species Result/ Evaluation Method Remark Substance 1 EC20 XX mg/l 30 min Activated sludge (ind.) OECD 209

Kommentiert [A195]: REACH-IT (IUCLID V): Short-term toxicity to fish

Kommentiert [A196]: REACH-IT (IUCLID V): Short-term toxicity to invertebrates

Kommentiert [A197]: REACH-IT (IUCLID V): Long-term toxicity to aquatic invertebrates

Kommentiert [A198]: LOEC alternative Kommentiert [A199]: REACH-IT (IUCLID V): Toxicity to aquatic algae and cyanobacteria

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 34 of 39 Revision date: 06.11.2017 __________________________________________________________________________________________________ Sediment toxicity Terrestrial toxicity Toxicity to soil macroorganisms except arthropods Toxicity to terrestrial arthropods Toxicity to terrestrial plants Toxicity to birds

Assessment / Classification Substance 1:

Harmful to aquatic organisms. 12.2 Persistence and degradability Biodegradation

Inoculum Parameter Degradation rate

Method Remark Substance 1 Activated sludge (ind.) BSB des ThSB (28d) 80-90% OECD 301 F -- Substance 2 ...

Abiotic Degradation

Test type t 1/2 Temperature pH-value

Method Remark Substance 1 Hydrolysis 0,59 h 20°C 4 OECD 111 -- Substance 2 ...

Assessment / Classification Substance 1: Readily biodegradable (according to OECD criteria).

Kommentiert [A200]: Only a header list here. If required sub-structure has to be added.

Kommentiert [A201]: This assessment may reflect the CLP/GHS classification.

Kommentiert [A203]: Biologische Abbaubarkeit ist eine stoffspezifische Eigenschaft und kann nicht am Gemisch bestimmt werden

Kommentiert [A204]: Diese Bewertung kann – muss aber nicht – die GHS-Einstufungsklassen reflektieren. Kommentiert [A205]: For mixtures for example: The single components are readily biodegradable.

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 35 of 39 Revision date: 06.11.2017 _______________________________________________________________________________________________________________ 12.3 Bioaccumulative potential

Bioconcentration factor (BCF) Species Result Method Remark Substance 1 Pimephales

promelas 123 OECD 305 by analogy


Substance 1: Based on the n-octanol/water partition coefficient accumulation in organisms is not expected.

12.4 Mobility in soil

Distribution Transport type

Parameter Result Method Remark Substance 1 Water – Air Volatility Henrys Law Constant 680 Pa m3 / mol estimated -- Substance 2 Sediment - Water Adsorption Log KOC 0,1 estimated --


12.5 Results of PBT and vPvB assessment Substance 1:

This substance does not meet the PBT/vPvB criteria of REACH, annex XIII. 12.6 Other adverse effects:

Substance 1:

The substance has a very low global warming potential. The substance has no ozone depleting potential.

Additional ecotoxicological information Substance 1:

The statement is derived from products of similar structure or composition.

Kommentiert [A207]: Diese Bewertung kann – muss aber nicht – die GHS-Einstufungsklassen reflektieren.

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 36 of 39 Revision date: 06.11.2017 _______________________________________________________________________________________________________________ SECTION 13: Disposal considerations 13.1 Waste treatment methods Directive 2008/98/EC (Waste Framework Directive) Hazardous waste according to Directive 2008/98/EC (waste framework directive).

Before intended use Properties of waste which render it hazardous Disposal operations Recovery operations

Waste codes / waste designations according to EWC / AVV After intended use Properties of waste which render it hazardous Disposal operations Recovery operations

Waste codes / waste designations according to EWC / AVV

Remark Other disposal recommendation

Additional information

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 37 of 39 Revision date: 06.11.2017 ___________________________________________________________________________________ SECTION 14: Transport information

Land transport (ADR/RID)

Inland waterway transport (ADN)

Sea transport (IMDG)

Air transport (ICAO-TI / IATA-DGR)

14.1 UN No. 14.2 UN Proper shipping name 14.3 Transport hazard class(es) Hazard label(s) 14.4 Packing group 14.5 Envirommental hazards

14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Additional information All transport carriers Land transport (ADR/RID)

Limited quantity: Special provisions: Tunnel restriction code: Classification code: Transport category: Hazard identification number (Kemler No.): Remark:

Inland waterway transport (ADN) Limited quantity: Special provisions: Category: Remark:

Sea transport (IMDG)

Limited quantity: Special provisions: Marine pollutant: Segregation group: Remark:

Air transport (ICAO-TI / IATA-DGR)

Limited quantity: Special provisions: Remark:

Kommentiert [A213]: This section of the SDS shall provide basic classification information for transporting/ shipment of substances or mixtures mentioned under Section 1 by road, rail, sea, inland waterways or air. Where information is not available or relevant this shall be stated. Where relevant, it shall provide information on the transport classification for each of the UN Model Regulations. Environmental hazards It shall be indicated whether the substance or mixture is environmentally hazardous according to the criteria of the UN Model Regulations (as reflected in the IMDG Code, ADR, RID and ADN) and/or a marine pollutant according to the IMDG Code. If authorised or intended for carriage by inland waterways in tank-vessels, it shall be indicated whether the substance or mixture is environmentally hazardous in tank-vessels only according to ADN. Kommentiert [A214]: The UN number (i.e. the four-figure identification number of the substance, mixture or article preceded by the letters ‘UN’) from the UN Model Regulations shall be provided. Kommentiert [A215]: The UN proper shipping name from the UN Model Regulations shall be provided, unless it has appeared as the product identifier in Subsection 1.1. Kommentiert [A216]: The transport hazard class (and subsidiary risks) assigned to the substances or mixtures according to the predominant hazard that they present in accordance with the UN Model Regulations shall be provided. Kommentiert [A217]: The packing group number from the UN Model Regulations shall be provided, if applicable. The packing group number is assigned to certain substances in accordance with their degree of hazard. Kommentiert [A218]: Information shall be provided on any special precautions which a user should or must take or be aware of in connection with transport or conveyance either within or outside his premises. Kommentiert [A219]: This subsection only applies when cargoes are intended to be carried in bulk according to the following IMO instruments: Annex II of Marpol and the IBC Code. The product name shall be provided (if different from that given in subsection 1.1) as required by the shipment document and in accordance with the name used in the lists of product names given in chapters 17 or 18 of the IBC Code or the latest edition of the IMO's Maritime Environment Protection Committee (MEPC).2/Circular (1). Ship type required and pollution category shall be indicated.

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 38 of 39 Revision date: 06.11.2017 ______________________________________________________________________________________________________________ SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU regulations Authorisations and/or restrictions on use

Authorisations Restrictions on use Restrictions of occupation

Other EU regulations Directive 2010/75/EC on industrial emissions

CHAPTER III: SPECIAL PROVISIONS FOR COMBUSTION PLANTS Categories of fuel: Liquid fuels Bemerkung: The fuel is no subject of use restrictions according to Directive

2010/75/EC on industrial emissions (article 34(4)).

CHAPTER V: SPECIAL PROVISIONS FOR INSTALLATIONS AND ACTIVITIES USING ORGANIC SOLVENTS

Volatile organic compounds (VOC) content in percent by weight:

Value Temperature Method Remark 33 +/-1,5 20 °C 37,5 +/-1,7 140 °C Baking temperature of the coating

Ingredients of the mixture which are CMR-VOC or halogenated VOC:

Stoffname CAS-Nr. INDEX-NR. EG-Nr. ABC 123-45-6 123-456-78-9 123-456-7 DEF 234-56-7 345-678-90-1 456-789-0

Information according to 1999/13/EC about limitation of emissions of volatile organic compounds (VOC-guideline).

Directive 2004/42/CE on the limitation of emissions of volatile organic compounds

Regulation (EC) No. 842/2006 on certain fluorinated greenhouse gases. Regulation (EC) No 1005/2009 on substances that deplete the ozone layer

Kommentiert [A223]: Some examples are listed below

Kommentiert [A224]: Examples only. Other EC regulations may be listed here too

Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH) Trade name: Product No: Print date: Version: 3.5 / EN Page 39 of 39 Revision date: 06.11.2017 ______________________________________________________________________________________________________________ National regulations Additionally, observe any national regulations! 15.2 Chemical Safety Assessment For this substance a chemical safety assessment is not required. SECTION 16: Other information 16.1 Indication of changes 16.2 Abbreviations and acronyms 16.3 Key literature references and sources for data 16.4 Classification for mixtures and used evaluation method according to regulation (EC)

1207/2008 [CLP] See SECTION 2.1 (classification).

16.5 Relevant R-, H- and EUH-phrases (number and full text) 16.6 Training advice 16.7 Further information Annex to extended safety data sheet (ext. SDS)

Kommentiert [A225]: National regulations depending on EU member states. For Germany: please see German Template.

Kommentiert [A235]: Only required for substances manufactured or imported in quantities of 10 tonnes or more per year per manufacturer or importer and for those substances which require a SDS according to REACH, article 31 (1). For all substances > 10 t/a without SDS requirement informations must be given according to article 32. See extra modul „Annex to the SDS“

Documents

New GHS SDS EN 06112017 with comments · wkh uhdvrqv zk\ vkdoo zkhuh dssolfdeoh eh vwdwhg 7klv qhhg qrw eh dq h[kdxvwlyh olvw :khuh d fkhplfdo vdihw\ uhsruw lv uhtxluhg wkh lqirupdwlrq