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www.inl.gov Next Generation Nuclear Plant Industrial Process Heat Applications and Economics Dr. Michael G. McKellar [email protected] 01 208 526-1346 Technical and Economic Assessment of Non-Electric Applications of Nuclear, NEA/IAEA Expert Workshop Paris, France, April 5, 2013

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Next Generation Nuclear Plant Industrial Process Heat Applications and Economics Dr. Michael G. McKellar [email protected] 01 208 526-1346

Technical and Economic Assessment of Non-Electric

Applications of Nuclear,

NEA/IAEA Expert Workshop

Paris, France, April 5, 2013

Outline

• Objectives

• Advantages of HTGR Process Heat

• Assumptions

• Process Heat Applications

• Hybrid Energy Systems

• Conclusions

1

Objectives

• The Next Generation Nuclear Plant (NGNP) Project, led by Idaho National Laboratory, is part of a nationwide effort under the direction of the U.S. Department of Energy to address a national strategic need identified in the Energy Policy Act of 2005—to promote the use of nuclear energy and establish a technology for hydrogen and electricity production that is free of greenhouse gas (GHG) emissions.

• This presentation is a summary of analyses performed by the NGNP project to determine whether it is technically and economically feasible to integrate high temperature gas-cooled reactor (HTGR) technology into industrial processes.

2

Advantages of HTGR High-Temperature Process Heat

3

• Reducing CO2 emissions by replacing the heat derived from burning fossil fuels, as practiced by a wide range of chemical and petrochemical processes, and co-generating electricity, steam, and hydrogen.

• Generating electricity at higher efficiencies than are possible with current nuclear power generation technology

• Providing a secure long-term domestic energy supply and reducing reliance on offshore energy sources

• Producing synthetic transportation fuels with lower life cycle, well-to-wheel (WTW) greenhouse gas (GHG) emissions than fuels derived from conventional synthetic fuel production processes and similar or lower WTW GHG emissions than fuels refined from crude oil

Advantages of HTGR High-Temperature Process Heat

4

• Producing energy at a stable long-term cost that is relatively unaffected by volatile fossil fuel prices and a potential carbon tax, a price set on GHG emissions

• Extending the availability of natural resources for uses other than a source of heat, such as a petrochemical feedstock

• Providing benefits to the national economy such as more near-term jobs to build multiple plants, more long-term jobs to operate the plants, and a reinvigorated heavy manufacturing sector.

Assumptions: Process Models

5

• No heat loss in piping between HTGRs and process applications except with SAGD

• Natural gas composition based on information published by Northwest Gas Association

• Natural gas standard volume flow: 15.56°C (60°F)

• Ambient inlet water temperature: 15.56°C (60°F)

• Ambient inlet air temperature: 21.11°C (70°F)

• Ambient pressure: Sea level (1 atmosphere absolute)

• High-efficiency compressors and turbines: 80– 90% efficient

• Steam generators: 25°C minimum temperature approach

• Process heat exchangers: 10°C minimum temperature approach (except when demonstrated industrial experience indicates differently)

• Intermediate heat exchanger: 25°C minimum approach temperature

Outputs and Assumptions: HTGR-Integrated Technology

6

• Energy products: electricity, process heat, and/or hydrogen

• Power generation efficiency: 41–48% (calculated)

• Temperature Difference across core ~ 375°C to 400°C

• Heat output: 600 MW(t)

• Primary circulator: 80% efficient

Assumptions: Economic Analyses

7

• Plant economic life: 30 years (excludes construction time)

• Construction period – Fossil plant: Three years

– HTGR plant: Three years per reactor with 6 months stagger between reactor

• Start-up assumptions for “nth-of-a-kind” HTGR – Operating costs: 120% of estimated operating costs

– Revenues: 65% of estimated revenue

• Plant availability: 90%

• Internal rate of return (IRR): 12%

• Inflation rate: 3%

• Interest rate on debt: 8%

• Repayment term: 15 years

• Reactor capital cost assumptions for HTGR modules: – $2,000/kW(t) for plants with one or two modules

– $1,400/kW(t) for plants with three or more modules

Assumptions: Economic Analyses

8

• Tax basis assumptions – Effective U.S.

income tax rate: 38.9%

– U.S. state tax: 6%

– U.S. federal tax: 35%

• MACRS depreciation: 15-year plant life

• Simplified business model in which a single entity owns and operates the industrial and associated HTGR plants

Up to 850°C

High Temperature Gas-cooled Reactors – Application Beyond Electricity

High Temperature Reactors can provide energy production that supports wide spectrum

of industrial applications including the petrochemical and petroleum industries

Reactor Temperature Range Covering Applications Evaluated To-date

Power Production

10

Hydrogen Production: High Temperature Steam Electrolysis

11

Shift & Syngas

Conditioning

Steam

System

Reformer H2

Water

CO2

H2-Rich Syngas

Sulfur

Removal

Natural

Gas

Natural

Gas

Exhaust

Natural

Gas

Natural

Gas

Plant

Water

Treatment

SteamExhaust Cooling

Towers

Water

Water

Water

Water

Hydrogen Production: High Temperature Steam Electrolysis

12

Coal to Gasoline Production

13

Coal Milling &

DryingGasification

Sulfur PlantCO2

Compression

Air Separation DME Synthesis

Gasoline

PurificationCoal Coal Syngas

N2

CO2

Slag

Methanol

Synthesis

Gasoline

Synthesis

CO2

DME

Crude

MeOH

Crude

MTG

Products

Gasoline

Sour

Gas

O2

Light

Fuel

Gas

Air

Sulfur

Tail

Gas

LPG

Water

Treatment

Power

Production

Cooling

Towers

General Plant Support

Coal Milling &

DryingGasification

Sulfur PlantCO2

Compression

DME Synthesis

Gasoline

PurificationCoal Coal Syngas

CO2

Slag

Methanol

Synthesis

Gasoline

Synthesis

CO2

DME

Crude

MeOH

Crude

MTG

Products

Gasoline

Sour

Gas

Light Fuel

Gas for

Topping Heat

Sulfur

Tail

Gas

LPG

HT Steam

ElectrolysisH2O

Nuclear Heat

for Electrolysis

(700°C)

Nuclear Power for

Electrolysis and

Gas Compression

O2 & H2

Nuclear Power for

H2S Removal

Nuclear Power for

CO2 Compressors

Nuclear Power

for Syngas

Compressors

Nuclear Heat Integration

Nuclear Power Integration

Water

Treatment

Power

Production

Cooling

Towers

General Plant Support

Coal to Gasoline Production

14

Gas to Gasoline Production

15

DME Synthesis

Gasoline

PurificationSyngas

Methanol

Synthesis

Gasoline

SynthesisDME

Crude

MeOH

Crude

MTG

Products

Gasoline

LPG

Natural Gas

Reforming

Air Separation

Natural

Gas

O2

N2

Air

Sulfur

Removal

Natural

Gas

Steam

Water

Treatment

Power

Production

Cooling

Towers

General Plant Support

Light Fuel Gas

DME Synthesis

Gasoline

PurificationSyngas

Methanol

Synthesis

Gasoline

SynthesisDME

Crude

MeOH

Crude

MTG

Products

Gasoline

LPG

Nuclear Power

for Syngas

Compressors

Nuclear Heat Integration

Nuclear Power Integration

Natural Gas

Reforming

Air Separation

Natural

Gas

O2

N2

Air

Sulfur

Removal

Natural

Gas

Steam

Nuclear Heat

for Reforming

(700°C)

Nuclear

Power for

ASU and Gas

Compression

Fuel Gas

Water

Treatment

Power

Production

Cooling

Towers

General Plant Support

Exhaust

Gas to Gasoline Production

16

Coal to Diesel Production

17

Coal Milling &

Drying

Gasification &

Syngas

Cleaning &

Conditioning

Sulfur Plant

(Claus) and

Tailgas Sulfur

Reduction

CO2

Compression

Air Separation

Fischer-Tropsch

Synthesis

Product

Upgrading &

Refining

Power

Production

N2

Coal SyngasFT

Liquids

Tail

GasTail

Gas

Sulfur CO2

Slag

LPG

Naphtha

Diesel

O2

HRSG Exhaust

Coal

Tail

Gas

CO2

Sour

Gas

Air

CO2

Plant

Water

Treatment

Cooling

Towers

Coal Milling &

Drying

Gasification &

Syngas

Conditioning

Sulfur Plant

(Claus) and

Tailgas Sulfur

Reduction

CO2

Compression

High

Temperature

Electrolysis

Units

Fischer-Tropsch

Synthesis

Product

Upgrading &

Refining

Coal SyngasFT

Liquids

Tail

Gas

Sulfur

Slag

LPG

Naphtha

Diesel

O2 & H2

Coal

Tail Gas

CO2

Sour Gas

H2OTail Gas

Recycle

CO2

Recycle

Nuclear Heat Integration

Nuclear Power Integration

Plant

Water

Treatment

Air

Power

Production

CO2

Cooling

Towers

HTGR

850°C ROT

Heat Generation

HTGR

700°C ROT

Power Gen.

Power

Nuclear Heat

(He 825°C) He Return

Coal to Diesel Production

18

Gas to Diesel Production

19

Preforming &

Autothermal

Reforming

Air Separation

Fischer-Tropsch

Synthesis

Product

Upgrading &

Refining

Natural

GasSyngas

FT

Liquids

Tail

GasTail

Gas

LPG

Naphtha

Diesel

O2

N2

Air

Sulfur

Removal

Gas

Mix

SteamPlant

Water

Treatment

Power

Production

Tail Gas

Recycle

Cooling

Towers

Fischer-Tropsch

Synthesis

Product

Upgrade &

Refining

SyngasFT

Liquids

Tail

Gas

LPG

Naphtha

Diesel

Tail Gas

Recycle

Nuclear Heat Integration

Plant

Water

Treatment

Preforming &

Autothermal

Reforming

Air Separation

Natural

Gas

O2

N2

Air

CO2 Removal,

Hydrotreating

and Sulfur

Removal

Gas

Mix

Steam

Power

Production

HTGR

850°C ROT

Heat Generation

Nuclear Heat

(He 675°C)

He Return

Hot He

Hot He

Cooling

Towers

Gas to Diesel Production

20

Ammonia Production: Gas to Ammonia

21

Primary

Reformer

Syngas

Conditioning

Ammonia

Synthesis

Sulfur

Removal

Urea

Synthesis

Natural

Gas

Syngas NH3

Water

NH3

Urea

CO2

CO2

Syngas

Stack

Gas

Nitric Acid

Synthesis

NH3

WaterAmmonium

Nitrate

Synthesis

Nitric

Acid

NH3

Ammonium

Nitrate

Urea

Nitric

Acid

Ammonium

Nitrate

Secondary

Reformer

Natural

Gas

Fuel Gas

Natural

Gas

Natural

Gas

Air

Steam

Exhaust

Syngas

CO2

To EOR or

Sequestration

Air

To UAN-32

Synthesis

Water

Treatment

Power

Production

Cooling

Towers

General Plant

Support

Nuclear Heat Integration

Nuclear Power Integration

Primary

Reformer

Syngas

Conditioning

Ammonia

Synthesis

Sulfur

Removal

Urea

Synthesis

Natural

Gas

Syngas NH3

Water

NH3

UreaCO2

CO2

Syngas

Stack

Gas

Nitric Acid

Synthesis

NH3

WaterAmmonium

Nitrate

Synthesis

Nitric

Acid

NH3

Ammonium

Nitrate

Urea

Nitric

Acid

Ammonium

Nitrate

Secondary

Reformer

Fuel Gas

Natural

Gas

Air

Steam

Exhaust

Syngas

CO2

To EOR or

Sequestration

Nuclear Heat for

Natural Gas Preheat

(> 350°C)

Nuclear Heat for

Primary Reformer –

Replaces Natural Gas

Combustion (700°C)

Nuclear Power for

Air Compressor

Nuclear Power for

Ammonia Synthesis

Compressors and

Refrigeration Unit

Nuclear Power for

CO2 Compressors

Nuclear Power for

Urea Granulator

Fans

Nuclear Power for

Compander

Nuclear Power for

Prill Tower Fans

Air

To UAN-32

Synthesis

Power

Production

Water

Treatment

Cooling

Towers

General Plant Support

Ammonia Production: Gas to Ammonia with HTSE

22

Primary

Reformer

Syngas

Conditioning

Ammonia

Synthesis

Sulfur

Removal

Urea

Synthesis

Natural

Gas

Syngas NH3

Water

NH3

Urea

CO2

CO2

Syngas

Stack

Gas

Nitric Acid

Synthesis

NH3

WaterAmmonium

Nitrate

Synthesis

Nitric

Acid

NH3

Ammonium

Nitrate

Urea

Nitric

Acid

Ammonium

Nitrate

Secondary

Reformer

Natural

Gas

Fuel Gas

Natural

Gas

Natural

Gas

Air

Steam

Exhaust

Syngas

CO2

To EOR or

Sequestration

Air

To UAN-32

Synthesis

Water

Treatment

Power

Production

Cooling

Towers

General Plant

Support

Nuclear Heat Integration

Nuclear Power Integration

Ammonia

Synthesis

Urea

Synthesis

NH3

NH3

UreaCO2

Nitric Acid

Synthesis

NH3

WaterAmmonium

Nitrate

Synthesis

Nitric

Acid

NH3

Ammonium

Nitrate

Urea

Nitric

Acid

Ammonium

Nitrate

Nuclear Power for

Ammonia Synthesis

Compressors and

Refrigeration Unit

Nuclear Power for Urea

Granulator Fans

Nuclear Power

for Compander

Nuclear Power for

Prill Tower Fans

HT Steam

ElectrolysisH2Water

Nuclear Power

for Electrolysis

Nuclear Heat

For Electrolysis

(700°C)

Hydrogen

Burner

H2

Separation

H2O,

N2

Water

H2

N2

O2

Natural Gas

Burner

O2

O2

Natural Gas

Topping

Heat for

HTE

CO2

Purification

CO2,

H2O

H2O

Air

To UAN-32

Synthesis

Cooling

Towers

Power

Production

Water

Treatment

General Plant Support

Ammonia Production

23 For this study ammonia was converted to UAN-32 fertilizer

Ammonia Production

24

Seawater Desalination: Reverse Osmosis

25

Seawater Desalination: Multi-stage Flash Distillation

26

Seawater Desalination: Multi-Effect Distillation

27

Steam Assisted Gravity Drainage

28

Oil Shale

29

Bitumen Upgrading

30

Hybrid Energy Systems Process Integration

Energy Systems Dynamics

Research & Testing

Process Modeling, Life-Cycle, and Economic

Assessments

GW-hr Battery

Storage

SMR-

1. NuScale LWR

2. GE Prism MSR

3.

Biomass

Drying &

Torrefaction

(200 - 300 C)

Grid

Wind Farm

Wind Farm

Wind Farm

Electricity

SMR-Renewable-Biomass HES

a

RIT

ROT

Hydrogen Production

Gas

Reforming

H2

Variable Power Generation

Shannon

Lee

Diana

Tom

Bob

(with Rick)

Fast Pyrolysis

(450 - 500 C)

Hyrdotreatment

UpgradingStorage

Gases

Bio-Oils

Dynamic System Modeling

Optimized Analysis – System Integration

32

HES Example: Nuclear Hybrid System to Offset Fluctuations in Wind or Solar Power

Steam turbine

generators

Methanol

synthesis

Steam

generation

Nuclear energy

Methane

reforming steam

Natural gas

Reliable base or

intermediate power

Synfuel carbon

fuel

power heat

Wind energy

Hybrid Energy Systems Integrate

• Energy sources

• Industrial Processes

Via

• Storage

• Power Production

• Process Heat

• Instrumentation and Control

Conclusions

• Integration NGNP HTGRs with process heat applications greatly reduces greenhouse gas emissions

• HTGRs produce electricity at higher thermal efficiencies (less heat loss, less water usage) than LWRs

• Many HTGR integrated process heat applications are economically feasible (i.e. SAGD, GTL (Methanol path), GTL (Fischer Tropsch path)

• A reactor outlet temperature of 850 C is ideal for many process heat applications

• Imposed carbon taxes would help promote HTGR integrated process heat applications

• Hybrid Energy Systems provides a means to effectively integrate renewable energy, nuclear energy, and process heat applications through storage, process heat, power production, instrumentation and control.

33

HTGR Process Heat Integration Team

• Rick Wood, INL

• Anastasia Gandrik, INL

• Larry Demick, NGNP Alliance

• Eric Robertson, INL

• Michael McKellar, INL

• Mike Patterson, INL

• Lee Nelson, INL

34