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Public
F. Mazzeo
BU Industrial & Consumer Specialties
Industrial & Home Care
26.07.2017
Next Generation ofSUGAR SURFACTANTS
FOR THE HOME CARE
MARKET
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Agenda
Public, Next generation of sugar surfactants2
– Clariant – Focus on innovation through R&D
– Next generation of sugar surfactants: Glucamides
– Glucamides Range
– C8-10 Glucamide: GlucoPure Wet
– C12-14 Glucamide: GlucoPure Foam
– C18:1 Glucamide: GlucoPure Sun
– Applications
– Hard surface cleaners
– Dishwashing Liquids
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
ClariantFocus on innovation through R&D
Public, Next generation of sugar surfactants3
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants4
https://www.revistahec.com.br/materias/notas-de-mercado/4324/26-07-2017/Heroi-da-bioeconomia---acucar-sera-a-materia-prima-do-futuro
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants5
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants6
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants7
GlucoseMethylamine
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants8
N-MethylGlucamine
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants9
Glucamides
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants10
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants11
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants12
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants13
GlucoPure Wet shows superior soap scum
removal against the currently used surfactants
0
20
40
60
80
100
APG Ethoxylates C8-10 Glucamides
Ave
rag
e s
oa
p s
cu
m
rem
ova
l (%
)
Ingredients (% a.i.) A B C
Alkylpolyglycoside (C8-10) 2,3 - -
C9-11 Pareth-7 - 2,3 -
C8-10 Glucamide - - 2,3
Sodium Laureth Sulfate (2EO) 1,0 1,0 1,0
Appearance clear clear clear
pH value 3,7 3,7 3,7
Soap scum removal test
00:00
All formulations with 3.0% Citric Acid, 2.0% Sodium Citrate and water
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants14
GlucoPure Wet shows superior soap scum
removal against the currently used surfactants
0
20
40
60
80
100
APG Ethoxylates C8-10 Glucamide
Ave
rag
e s
oa
p s
cu
m
rem
ova
l (%
)
Ingredients (% a.i.) A B C
Alkylpolyglycoside (C8-10) 2,3 - -
C9-11 Pareth-7 - 2,3 -
C8-10 Glucamide - - 2,3
Sodium Laureth Sulfate (2EO) 1,0 1,0 1,0
Appearance clear clear clear
pH value 3,7 3,7 3,7
Soap scum removal test
02:30
All formulations with 3.0% Citric Acid, 2.0% Sodium Citrate and water
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants15
GlucoPure Wet shows superior soap scum
removal against the currently used surfactants
0
20
40
60
80
100
APG Ethoxylates C8-10 Glucamide
Ave
rag
e s
oa
p s
cu
m
rem
ova
l (%
)
Ingredients (% a.i.) A B C
Alkylpolyglycoside (C8-10) 2,3 - -
C9-11 Pareth-7 - 2,3 -
C8-10 Glucamide - - 2,3
Sodium Laureth Sulfate (2EO) 1,0 1,0 1,0
Appearance clear clear clear
pH value 3,7 3,7 3,7
Soap scum removal test
05:00
All formulations with 3.0% Citric Acid, 2.0% Sodium Citrate and water
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants16
GlucoPure Wet shows superior soap scum
removal against the currently used surfactants
0
20
40
60
80
100
APG Ethoxylates C8-10 Glucamide
Ave
rag
e s
oa
p s
cu
m
rem
ova
l (%
)
Ingredients (% a.i.) A B C
Alkylpolyglycoside (C8-10) 2,3 - -
C9-11 Pareth-7 - 2,3 -
C8-10 Glucamide - - 2,3
Sodium Laureth Sulfate (2EO) 1,0 1,0 1,0
Appearance clear clear clear
pH value 3,7 3,7 3,7
Soap scum removal test
07:30
All formulations with 3.0% Citric Acid, 2.0% Sodium Citrate and water
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants17
GlucoPure Wet shows superior soap scum
removal against the currently used surfactants
0
20
40
60
80
100
APG Ethoxylates C8-10 Glucamide
Ave
rag
e s
oa
p s
cu
m
rem
ova
l (%
)
Ingredients (% a.i.) A B C
Alkylpolyglycoside (C8-10) 2,3 - -
C9-11 Pareth-7 - 2,3 -
C8-10 Glucamide - - 2,3
Sodium Laureth Sulfate (2EO) 1,0 1,0 1,0
Appearance clear clear clear
pH value 3,7 3,7 3,7
Soap scum removal test
10:00
All formulations with 3.0% Citric Acid, 2.0% Sodium Citrate and water
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants18
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
GlucoPure Wet is compatible with the materials
common in bathrooms – in contrast to ethoxylates
*Stress-corrosion cracking of plastic material (DIN 53449-T)
19
AAPG (C8-10)
B C9-11 Pareth-7
CC8-10 Glucamide
Material 0-7d 7-14d 0-7d 7-14d 0-7d 7-14d
ABSAcrylnitrile-Butadiene-
Styrene Copolymer
PCPolycarbonate
(transparent)
PMMA Polymethylmethacrylate
(transparent)
POM1Polyoxymethylen (grey)
POM2Polyoxymethylen (white)
Public, Next generation of sugar surfactants
Stress-corrosion test*
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants20
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
21
GlucoPure Wet shows an excellent anti-stroke performance
in a residue test
Ingredients (% a.i.) A B C
Alkylpolyglycoside (C8-10) 2,3 - -
C9-11 Pareth-7 - 2,3 -
C8-10 Glucamide - - 2,3
Sodium Laureth Sulfate (2EO) 1,0 1,0 1,0
Appearance clear clear clear
pH value 3,7 3,7 3,7
All formulations with 3.0% Citric Acid, 2.0% Sodium Citrate and water
Public, Next generation of sugar surfactants
Alkylpolyglycoside
(C8-10)C9-11 Pareth-7C8-10 Glucamide
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants22
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
GlucoPure Foam offers high performance at low aquatic
toxicity by replacing amine oxides in >95% RCI formulations
Public, Next generation of sugar surfactants23
Recipe (%a.i.) A B C D
Sodium Laurylsulfate 8 8 8 8
Lauramine Oxide (AO) 3 3 - -
C12-14 Glucamide 4 - 7 -
Lauryl-Polyglycoside (APG) - 4 - 7
Renewable % of surfactants (RCI) >95% >95% >95% >95%
GHS Labelling of the co-surfactantH 400 +
H 411
H 400 +
H 411
No
aquatox
No
aquatox
Plate Test (IKW I - Carbohydrate)
Number of Washed Plates
AO +
Glucamide
AO +
APG Glucamide APG
No solvent and no NaCl addedIKW performance test “Recommendation for the quality assessment of the cleaning performance of hand dishwashing detergents” (Nitsch. C. and Hüttmann G. SÖFW-Journal, 128, 5.
Pp. 11-15, 2002)
32 24 29 16
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
GlucoPure Foam offers high performance at low aquatic
toxicity by replacing amine oxides in >95% RCI formulations
Public, Next generation of sugar surfactants24
Recipe (%a.i.) A B C D
Sodium Laurylsulfate 8 8 8 8
Lauramine Oxide 3 3 - -
C12-14 Glucamide 4 - 7 -
Lauryl-Polyglycoside (APG) - 4 - 7
Renewable % of surfactants (RCI) >95% >95% >95% >95%
GHS Labelling of the co-surfactantH 400 +
H 411
H 400 +
H 411
No
aquatox
No
aquatox
Plate Test (IKW II - Grease)
Number of Washed Plates
AO +
Glucamide
AO +
APG Glucamide APG
No solvent and no NaCl addedIKW performance test “Recommendation for the quality assessment of the cleaning performance of hand dishwashing detergents” (Nitsch. C. and Hüttmann G. SÖFW-Journal, 128, 5.
Pp. 11-15, 2002)
23 18 21 11
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants25
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Formulations with GlucoPure Foam can be thickened by
NaCl keeping the cold cloud point at a very low level
Public, Next generation of sugar surfactants26
Recipe (%a.i.) C D C’ D’
Sodium Laurylsulfate 8 8 8 8
C12-14 Glucamide 7 - 7 -
APG - 7 - 7
Sodium chloride - - 1,1 1,25
Viscosity (mPas) 20 20 1950 1850
Cold Cloud Point (°C) -11,6 -0,5 -4,9 1,5
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants27
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Zein Test shows that Glucamides are even milder than Betaines
Public, Next generation of sugar surfactants28
0
100
200
300
400
500
Sodium DodecylSulfate
CocamidopropylBetaine
GlucoPure Foam Lauryl Glucoside
Zein
valu
e (
mg
N / 1
00 m
L)
Zein Test
The lower
the milder
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants29
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Very low Critical Dilution Volume (CDV)
CDV is the equivalent of water needed to neutralize the impact of the surfactant on the environment. It
is an additive criteria, so the lower the CDV of the individual surfactants in a formulation, the better.
CDV is one of the main criteria in evaluation of leading Ecolabels like Nordic Swan or EU Flower.
Public, Next generation of sugar surfactants30
GlucamidesLauramine OxideCocamidopropyl
Betaine
11’600 L
10 L
261 L
CDV calculation
The CDV is
calculated based on
3 criteria:
• Acute Toxicity
• Chronic Toxicity
• Degradation
All values used for the
CDV calculations on the
left can be requested to
your Clariant contact.
Considering 7% surfactant as a
common concentration of co-
surfactants in HDWL
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants31
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
GlucoPure Sun improves the sensorial of the formulations
Public, Next generation of sugar surfactants32
Recipe (%a.i.) A B
Sodium Laureth Sulfate (2EO) 8.0 8.0
Cocamidopropyl Betaine 2.8 1.8
Oleyl Glucamide - 1.0
Active matter 10.8% 10.8%
3
8
Most conditioning foam
CAB CAB + GlucoPure Sun
11 internal sensory experts washed their hands in a blind test with formulations A and B and evaluated:
3
8
Most moisturized
CAB CAB + GlucoPure Sun
Foaming behavior After feel
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants33
Recipe (%a.i.) A B
Sodium Laureth Sulfate (2EO) 8.0 8.0
Cocamidopropyl Betaine 2.8 1.8
Oleyl Glucamide - 1.0
NaCl to reach 1000 mPas 1.5 1.6
Active matter 10.8% 10.8%
IKW performance test “Recommendation for the quality assessment of the cleaning performance of hand dishwashing detergents” (Nitsch. C. and Hüttmann G. SÖFW-Journal, 128,
5. Pp. 11-15, 2002) with 0.5 g HDWL/L
17 16
Plate Test (IKW II - Grease)
CAB
CAB +
GlucoPure Sun
* Classification based on calculation and concentration thresholds
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants34
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
GlucoPure Sun show excellent performance
Public, Next generation of sugar surfactants35
Recipe (%a.i.) A B C D
Sodium Laureth Sulfate (2EO) 4.8 4.8 4.5 4.2
Cocamidopropyl Betaine 1.0 - - -
GlucoPure Sun - 1.0 2.7 4.2
Active matter 5.8% 5.8% 7.2% 8.4%
IKW performance test “Recommendation for the quality assessment of the cleaning performance of hand dishwashing detergents” (Nitsch. C. and Hüttmann G. SÖFW-Journal, 128,
5. Pp. 11-15, 2002) with 0.5 g HDWL/L
10 13
Plate Test (IKW II - Grease)
CAB GlucoPure Sun
10 15
GlucoPure Sun GlucoPure Sun
* Classification based on calculation and concentration thresholds
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
GlucoPure Sun helps to build up viscosity efficiently with less
amounts of salt
Public, Next generation of sugar surfactants36
Recipe (%a.i.) A B C D
Sodium Laureth Sulfate (2EO) 4.8 4.8 4.5 4.2
Cocamidopropyl Betaine 1.0 - - -
GlucoPure Sun - 1.0 2.7 4.2
Active matter 5.8% 5.8% 7.2% 8.4%
0
400
800
1200
1600
2000
0,00 0,50 1,00 1,50 2,00 2,50 3,00 3,50
vis
cosity
/ m
Pas
NaCl / %
ABCD
Viscosity curves
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants37
F. Mazzeo, BU Industrial & Consumer Specialties, Industrial & Home Care, 26.07.2017
Public, Next generation of sugar surfactants38
clariant.com/glucopure