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Electronics and Microelectronics AE4B34EM
10. lecture
• IC processing technology
• Lithography
• Oxidation
• Ion Implantation
• Deposition
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
How to get
1 000 000 000
Components to 1 cm2
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Oxidation
Optical mask
Next technology step
Photoresist coating
Washing, drying Etching
Photoresist processing
Exposition
Typical operation steps in one photolithographic cycle
Photolithography
Removal
photoresist
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Transfer of the design on a chip
Stepwise Exposure: Focus, deposition, exposure, step and over again
UV light source
Optical Mask - contains
one or more chip layouts
Aperture
Control of wafers shift
in X, Y, Z, q
Projection Optics
The aperture is closed during focusing and
splicing. Opened during the exposure
Composing laser
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Negative Photoresist
Projection System
UV light source (lamp)
Fotolitografic mask
Developer
Washing
Photolithography - projection method
Silicon wafer with a layer of thermal oxide.
The wafer is coated by sensitive layer to light - photoresist. During the application of the photoresist coated plate reaches fast rotation which makes steady stratification throughout the area.
Chip (layer) topology is transferred throughout the mask on the top of the board - the plate is irradiated by ultraviolet light.
Developer removes illuminated photoresist from the wafer plate.
Oxide
Substrate
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Photolithography and etching
The board is immersed into etching substance It removes the exposed oxide down to the silicon surface - wet etching
Etching substance
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Photolithography
Today we use UV light sources of 248, 195nm
Very expensive equipment 40 000 000 USD
Resolution Enhancement Techniques
Resolution Enhancement Techniques
GDSII
MDP
Mask
Manufacturing
OPC – Optical proximity correction
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
90nm and Below 130nm 180nm
OPC
Design
Mask
Wafer
OPC
0°
180°
0°
180°
PSM
Resolution enhancement techniques
diffraction
feature sizes light wave length
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
OPC – Optical proximity correction
PSM – Phase shift margin Source: IDESA
Optical Proximity Correction
Predistortion of the mask layout is needed when scaling down the technology
Needed for 90nm and below
No OPC OPC Corrections
With OPC
Original Layout
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Source: IDESA
Optical Proximity Correction
Increasing percent of mask layers
are using OPC/RET technologies
180 150 130 90 0
10
20
30
40
50
60
70
% of RET
Technology Node (nm)
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Source: IDESA
Optical Proximity Correction
Comparison by difference of OPC method
Original Moderate Aggressive
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Source: IDESA
Optical Proximity Correction: Mask Writing Time
Number of Shots by E-beam used in electron lithography (Giga)
90nm Logic 65nm Logic 45nm Logic Generation
Chip area 120mm2
45
0
135
90
180
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Source: IDESA
RET : OPC: Mask Writing Time
Time (hours)
90nm Logic 65nm Logic 45nm Logic Generation
Chip area 120mm2
Shot Time Stage Time
4
0
12
8
20
16
28
24
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Source: IDESA
90nm and Below 130nm 180nm
OPC
Design
Mask
Wafer
OPC
0°
180°
0°
180°
PSM
Phase shift mask
Wavelength: 193nm
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Source: IDESA
Phase shift mask
Design
Cross Section
Electric Field
Sum
Intensity
Conventional Mask Alternating PSM
Shifter
+ 0 -
+ 0 -
+ 0 -
Source: DNP
phase shift glass Expensive
light beam interference
light phase shifting
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Source: IDESA
Immersion photolithography
Technique which improves resolution photolithography resulution (30-40%)
DUVi – use liquid between the lens system and wafer
This will increase the depth of field (DOF)
NA value is significantly greater than 1.0
Use absolutely clean water
Necessary for technology node 45 nm (ASML, Canon and Nikon)
There are solution for 14 nm technology (Intel Ivy Bridge)
Jiří Jakovenko – Návrh Integrovaných Systémů - A2M34NIS
Source: Cymer
Jiří Jakovenko – Struktury Integrovaných Systémů - A2M34SIS
EUV Extreme ultraviolet lithography
Radiation source 13.5 nm
Requires vacuum
All optics (mirrors) including masks must be made of multilayer Mo / Si without fault
zdroj: SPIE
Jiří Jakovenko – Struktury Integrovaných Systémů - A2M34SIS Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Etching process - basic types
Wafer
Photorezist
Oxide
SiO2
Wafer
Photorezist
Oxide
SiO2
Wafer
Photorezist
Oxid
SiO2 SiO2
Wet chemical etching
Plasma etching
Reactive ion etching
Oxide
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Anisotropic and isotropic etching
Isotropic etching Anisotropic etching
Wafer Wafer
Photorezist
Oxide
Pgotorezist
Oxide
Anisotropy coefficient Af = 1 – VH / VV
The isotropic etching is coefficient Af = 0
Selectivity to resistSFM = VF / VM VF >> VM
Selectivity to wafer SFS = VF / VS
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Anisotropic etching of silicon
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Plasma etching
Rotary vacuum pump
Working chamber
RF generator
Distribution of working gases
Holder with wafers Cover
Decontamination of waste gases
N2 O2 CF4 100 Pa
Used for silicon-nitride layers and photoresist removal
The process use a high reactive fluorine atoms which is generated by the decay of Freon CF4 molecules at very high
temperature and mixed with oxygen are used
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Thermal oxidation
44%
56%
Original surface
Si Si Si Si Si Si Si
Si Si Si Si Si Si Si
Si Si Si Si Si Si Si
Si Si Si Si Si Si Si
O O
O O O O
O O
O
O
O
O O Si
Si Si
Si
Si
Si O
O
O
O O
O O O O
O O O H
O H
300 600
500
1000
Time [min]
Thic
kness
[nm
]
Oxygen Water
1000°C 1100°C
Si
1000°C
SiO2
Dependence of thickness on oxidation time.
The thin layer of oxide are created on air (1 - 2 nm) At higher temperature (800°C - 1200°C) oxygen molecules are able to diffuse through oxide layer. 44% thickness is below the original surface of silicon and 56% above.
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Oxidation (diffusion) chamber
Asanace odpadních plynů
Asanace odpadních plynů
Asanace plynů
Gas inlet
Decontamination of waste gases
Decontamination of waste gases
Temperature inside the chamber is 400 - 1200°C
The tube is made of quartz glass
Local oxidation masked by Silicon-Nitride
Limiting oxidation factors: - Bird heads forming - grow up – uneven surface
Forming of „Bird heads!“
Nitride Oxide
a) Nitride deposition
It serves as an oxidation mask b) Transferred on masks :
Nitride is etched
c ) Local oxidation
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Shallow (Silicone) trench isolation - STI
Si
Si3N4
SiO2
Oxide and nitride Si3N4 deposition
STI - Shallow Trench Isolation
Si SiO2
Si3N4
Etching Si
Masked etching Si3N4 and SiO2
Si3N4
Si
SiO2
Si3N4
Si3N4
Si
SiO2
SiO2
Oxide deposition fills the trench etched
Si SiO2
Si3N4
CMP grinding of carbon nitride layer
Si SiO2
Removal of nitride by (H3PO4)
(It's thermal oxide!)
SiO2 deep = ~ 350 nm; “shallow”
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Diffusion - the principle
Diffusion is one of the most common processes in nature Diffusion rate is strongly dependent on temperature
Blue vitriol dissolves in water
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Diffusion - the principle
H2O
H2O
H2O
H2O H2O
H2O
H2O
H2O
CuSO4 CuSO4
H2O
H2O
H2O H2O
H2O
H2O
H2O
H2O
H2O
H2O
H2O
H2O
H2O
H2O
H2O H2O
H2O
H2O
H2O H2O
H2O H2O
H2O H2O H2O
H2O H2O
H2O
H2O H2O
H2O
H2O
H2O
H2O
H2O
H2O H2O
H2O
H2O
H2O
H2O
H2O
H2O H2O
H2O
H2O
H2O
CuSO4
H2O H2O
CuSO4
CuSO4
CuSO4
CuSO4
CuSO4
CuSO4 CuSO4 Diffusion source
Diffusion rate is strongly dependent on temperature. In
the solids is almost immeasurable at room temperature . Diffusion at high temperatures is used in semiconductor
process for local subsidizing.
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Diffusion in semiconductor process
P P
P
P P
P P
P
P
1000°C
P P
P
P
P P
P
P
P
P
P P
P
P
P
P
P P
P
P P P
P
P P
P
P
P
P
P
P P
P
P
It this process dopant atoms penetrate below the silicon surface in selected areas Temperature and time adjust layer depth and dopant concentration on the surface
Annealing is the mechanism by which the dopant atoms in silicon move around without diffusion source. It positively forms dopant profile. Oxide on the surface of the silicon wafer must be sufficiently thick (about 500 nm) to stop atoms of phosphorus penetrate through it.
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Ion implantation
P
P
P P
P
P P
P
P
P P
P
P P
P
P P
P
P P
P
P P
P
P
P P
P
P P
P
P
1000°C
Ion implantation is a process in which a dopant atoms are implanted below the surface of the silicon wafer. Dopant ions are accelerated by electric field and focused to the wafer surface where penetrate to a certain depth beneath the surface of silicon
Dopant profile changes during
annealing. The quantity of dopants is an
important parameter called the dose.
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
An Ion implantation system
PCl3
P
Ion source
Magnet
Separating slit
Accelerator
P P
P
P
P
P P P P P
P
P
P
P
40 - 160 kV
Vacuum Vertical and horizontal deflection
system
Si wafer
Phosphorus (P) Si wafer doped by Phosphorus has a N type
conductivity
- +
Cl P P Cl
Cl P Cl
Cl
PCl3
P Cl
Cl Cl
-
+
40 k
iV
Cl
Cl
Cl P
P
Positive ions of P and Cl
Phosphor Chloride molecule Cl P Cl
Cl
Heavy Ions Cl
Lighter ions
Cl
Cl
The ions are accelerated
by the accelerator.
electric discharge source break the molecules into Phosphor
and Chloride atoms or clusters of atoms with an electric charge - ions.
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Ion implantation – Magnet system
Graphit
Ion source
Magnet
Ion beam
Iris
Lighter ions
Heavy ions
Neutral ions
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Accelerator system
100 MW 100 MW 100 MW 100 MW 100 MW
0 kV +100 kV +80 kV +20 kV +40 kV +60 kV
+100 kV
Ion beam
Ion beam
Into deflection system
Electrodes
Input from magnet
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Linear accelerator system
Source
Magnet End deflection
magnet
Scan disc
Substrate
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Electron shower system
+
+ +
+ +
+
+
+
+ +
+
+
+
+
Iris
Electron gun
Secondary electron target
Secondary electrons
Recombination +ion - electron
Wafer
Helps us to eliminate substrate charging
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Epitaxy is the accretion of layers of silicon on the surface of the silicon wafer. The layer has the same crystallographic characteristics as a substrate but may
have a different concentration of additives or other ingredients.
Epitaxial growth
P
H
H H
P Si
Si Si
Si Si
The process takes place at high temperature - 1200 ° C. Around the incandescent panels flows hydrogen. When you add hydrogen chloride HCl it starts to react with the silicon surface and etches boards. It is important to
remove any dirt or surface inequality of the wafer.
After surface etching the silicon tetrachloride vapor SiCl4 reacts with present hydrogen at high temperature. The result of the
reactions are free silicon atoms deposited on the surface of the silicon wafer according its crystal structure.
In case of presence of phosphine molecules PH3, phosphorus atoms cause epitaxial layer growth. Similarly, boron compounds can be
used for doping.
H H
H H
H H
H H
H H
H Cl
H Cl
H Cl
The result is a thick epitaxial
layer of a few micrometers to tens of micrometers.
Cl
Cl
Cl
Si Cl
Cl
Cl
Cl
Si Cl
Cl
Cl
Cl
Si Cl
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Sputtering
Al Al Al Al Al Al Al Al Al Al Al Al Al Al
Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al
Al Al Al Al Al Al Al Al Al Al Al Al Al Al Al
Al
Al Al Al Al Al Al Al Al Al Al Al Al Al Al
Al
Al Al Al Al Al Al Al Al Al Al Al Al
Al Al
Al Al
Ar
Argon atom (Ar) faces at high speed (tens of km/s) on the surface of aluminium
plate and scatters a few aluminium atoms. Sprayed aluminium is deposited on nearby objects. The semiconductor industry uses aluminium, silver, gold,
titanium, nickel or aluminium alloy with copper and silicon (AlCuSi) materials.
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Sputtering system
Argon
Vacuum pump
High voltage source 1000 V
Anode
Al plate - target
Magnet
Si wafers
The target is connected to the negative pole of the high voltage source and the auxiliary electrode-anode – to the positive pole. Argon atoms are ionized and discharged and accelerated by an electric field and directed at the target. Sprayed aluminium target is deposited on the plates, creating a layer of aluminium. The magnetic field located behind the target increases the efficiency of sputtering
process.
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Chemical Vapor Deposition CVD
Continuous gas flow
Deposited film
Si substrate
Border layer
Reactant difusion
SiH4(gas) + O2(gas) SiO2 (solid) + 2H2 (gas)
SiH4(gas) + H2(gas) +SiH2(gas) 2H2(gas) + PolySilicon (solid)
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Metalization – conductive couplings
Today Al is substituted by Cu – 40% less resistivity
Maximum 11 metal layers
CMP – Chemical-mechanical planarization
Chemical-mechanical planarization / Polishing
Mechanically with chemical etching, or chemically with mechanical grinding … … why? – surface planarization with removal of excess material
Chemical reaction etches surface and makes the deposited material soft, then the mechanical grinding flattens the surface .
without with CMP CMP
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
CMP – Chemical-mechanical planarization
Wafer
Suspension
Downforce
c
p
Wafer holder
Abrasive particles film
Rotating plate
wafer Clamping plate
shift
Suspension = chemicals + particles
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
CMP – Chemical-mechanical planarization
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
IC testing process
Optical control
Measurements of test structures
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Packaging
Package requirements:
Electrical – small parasitic capacitances, inductance
Mechanical – reliable and solid
Thermal – good heat dissipation
Economical - cheap
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Packaging
Diamond saw cuts the silicon wafer with chips into individual chips. Good chips are
soldered or glued into the case. Leads are connected to contacts on the chip with a thin copper wire (0.15 mm).
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Board mounting
(a) Through-Hole Mounting (b) Surface Mount
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Package types
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Package parameters
Jiří Jakovenko – Electronics and Microelectronics - Department of Microelectronics – CTU
Multi-chip modules