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Novel Dental Cements Based On Cyanoacrylates. Susannah Tomlinson March 2007 Bill Hooper, Ken Evans, Oana Ghita. Aim/Overview. Aim: to study the setting characteristics of new cements using various techniques Cement compositions Applications Oscillating rheometry - PowerPoint PPT Presentation
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Novel Dental CementsBased On Cyanoacrylates
Susannah TomlinsonMarch 2007
Bill Hooper, Ken Evans, Oana Ghita
Aim/OverviewAim: to study the setting characteristicsof new cements using various techniques • Cement compositions• Applications• Oscillating rheometry• Mid- and near-IR spectroscopy• Vickers hardness• Shear bond strength
Cement Compositions (A.J. Bennetts, C.G. Wilde, and A.D. Wilson, UK patent GB 2386121)
Hybrids Cyanoacrylate + GIC (acid solution + basic glass) Set by: (1) cyanoacrylate polymerisation
(2) GIC acid-base reaction Similar to resin-modified GICs
Composites Cyanoacrylate adhesive + acid-coated fillers (e.g. GIC
(glass), hydroxyapatite, or wollastonite powders, etc.,coated with tartaric acid and poly(acrylic acid)) Set by cyanoacrylate polymerisation
Cyanoacrylates Ethyl cyanoacrylate (R=C2H5)
n-butyl cyanoacrylate (R=C4H9) Polymerisation initiated by water
ideal in oral environments CN
CO2R
CC
H
H
CN
C
CO2R
CHO
H
H
+ y H2O
nxy
H
Incorporation of cyanoacrylate is expected to improve adhesion
Applications
General adhesive
Pre-fabricated surgical implants or prostheses
Dental adhesives, restorative materials, luting agents, liners, and as endodontic cements
Oscillating Rheometry Wilson rheometer Cement placed between one
stationary plate and one oscillating Plates coated with GIC to prevent
irreversible bonding
Working time: when oscillation amplitude is 95% of original Setting time: when oscillation
amplitude is 5% of original Ideal setting characteristics:
high working:setting time ratio (close to 1)
Tim
e
Oscillation amplitude
Rheometry results
All new cement formulations have similar or higher working-time:setting-time ratios than GIC
Near-IR (transflectance set-up):
clear peaks related to cyanoacrylate
Mid-IR (diamond ATR): clear peaks related to GIC
Mid-IR and near-IR spectroscopy
Typical mid-IR spectra of hybrid cement
Shows that the cyanoacrylate polymerisation is rapid Slow GIC reaction, continuing after cyanoacrylate polymerisation
complete
Extent of cyanoacrylate cure from near-IR
Cyanoacrylate polymerisation rapid in hybrid, in agreement with mid-IR For the composite, shape of cyanoacrylate polymerisation profile possibly
due to the limited amount of water adsorbed on the powder surface
Ethyl cyanoacrylate/GIC hybrid
Cyanoacrylate component 100% cured in ~10 min, which suggests that the increasing hardness is due to the continuing GIC acid-base reaction
Hardness of composite correlated with cyanoacrylate extent of cure
Ethyl cyanoacrylate/hydroxyapatite composite
Shear bond strength to Al*
*ASTM D 1002-05 using a single-lap-joint design
Summary New cements show favourable
handling characteristics (high W:S time ratio)
In hybrid: cyanoacrylate polymerisation is rapid, while GIC reactions are slower, and continue after polymerisation is complete
Hybrid shows improved bond strength to metal next experiments will study bonding to teeth
Thanks for your attention!