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Nuclear Physics
The year 1896 marked the birth of nuclear physics– Henri Becquerel accidentally discovered
natural radioactivity in uranium compounds.• Researchers tried to identify
the radiation from atomic nuclei.
1 Thorite ------->
Beta ()– Electrons or positrons– More penetrating than alpha particles– Negatively or positively charged
Rutherford’s Experiment
Rutherford bombarded gold foil with alpha particles and disproved the Thompson model of the atom..
The Strong Nuclear Force
Rutherford and his students discovered the nuclear strong force in 1911– It explained why the protons don’t go flying off
from the nucleus.
Milestones in Nuclear Physics
Nuclear reactions were observed in 1930.The neutron was discovered in 1932.Artificial radioactivity was produced in 1933.Nuclear fission was discovered in 1938.Nuclear fission was first controlled in 1942.
Atomic Nuclei
All nuclei are composed of two types of particles.– The atomic number, Z, equals the number of protons
in the nucleus.– The neutron number, N, equals the number of
neutrons n the nucleus.– The mass number, A, equals the number of
nucleons. (A = Z + N)• A nucleon can be either a proton or a neutron
Nuclear Symbols
The symbol we use to represent nuclei is
Sometimes Z is not shown when the chemical symbol is obvious.
€
ZA X
Isotopes
Isotopes have the same number of protons but different numbers of neutrons.– There are four isotopes of carbon.
C116 C12
6 C136 C14
6
Symbols for Other Particles
– alpha– beta or– gamma– neutron
( )He42
€
-10β( )
€
00γ( )
€
+10β( )
( )n10
Artificial Isotopes
Artificial isotopes do not occur naturally and are produced in the laboratory.
17-1, 17-2
Charge and Mass
The proton and electron have charges that are equal in magnitude but opposite in sign.The neutron has no charge.The masses of the proton and neutron are nearly equal. (See Table 29.1) on pg. 914.The masses of selected isotopes are in Appendix B on pg. A.14.
Unified Mass Units
Unified mass units (u) are based upon the carbon-12 atom which has a mass of exactly 12 u.– 1 u = 1.660540 x 10-27 kg– The proton and neutron each have a mass of
approximately 1 u.– The mass of the electron is much less.
Mass Energy Conversion
The energy equivalent of one atomic mass unit is 931.494 MeV.
€
1 u = 931.494 MeV
Rutherford found that an alpha particle on a head-on collision with a nucleus will stop instantaneously at a distance d from the nucleus because of Coulomb repulsion.
29.1
Nuclear Radii
The average radius of most atomic nuclei can be found by using
ro = 1.2 x 10-15 mA is the mass number
285
3
1
oArr =
Nuclear Stability
Why don’t the protons in the nucleus fly apart because of the repulsive Coulomb forces?
The Strong Nuclear Force
The strong nuclear force is an attractive force between all nuclear particles.– The strong nuclear force dominates the
Coulomb force over short distances.
Nuclear Stability
There are over 260 stable nuclei.– Hundreds more are unstable
Light nuclei are stable when N = Z.Heavier nuclei are stable when N > Z.Elements with more than 83 protons are always unstable (radioactive).
29.3
Nuclear Mass
The total mass of the nucleus is always less than the sum of the masses of its nucleons.
Nuclear Energy
The total energy of the bound nucleus is always less than the combined energy of the separated nucleons.– The difference is called the binding energy of the
nucleus.
290
Binding Energy
Nuclei with an atomic mass near 60 are the most stable.– The average binding energy per nucleon is
about 8 MeV / nucleon.
29.4, 291
Natural Radioactivity
Natural radioactivity was accidentally discovered by Becquerel in 1896.– It was later named “radioactivity” by Marie
Curie.
Radioactive Elements
Marie and Pierre Curie discovered radium and polonium after years of separating the radioactive elements from tons of pitchblende, a radioactive ore.– Experiments indicated that the radiation was
the result of nuclear decay.– Marie Curie died of leukemia in 1934.
Anti Matter
What is a positron?– It is an antiparticle with the mass of an
electron and the charge of a proton.• Symbol
€
−10e
Identifying Nuclear Particles
A magnetic field can be used to identify the particles involved in nuclear radiation.
29.5, 292
Rutherford’s Mousetrap
Rutherford’s mousetrap experimentally proved that alpha particles were composed of helium nuclei.
T-41
The Decay Constant
The decay constant () determines the rate at which isotopes decay
• A large value for indicates a rapid rate of decay.
Activity
The activity (R) is defined as the number of decays per second– 1 Bq = 1 decay / second– 1 Ci = 3.7 x 1010 decays / second = 3.7 x 1010 Bq
• This is the approximate activity of 1 gram of radium.• The mCi and the Ci are most commonly used.
Remaining Nuclei
The number of nuclei (N) remaining after a given amount of time can be found by using:
€
N = Noe−λ t
Half Life
Half–life– The time it takes or half of a given number of
radioactive nuclei to decay is given by:
6, 294, 29.6
⎟⎟⎠
⎞⎜⎜⎝
⎛
2
1T
€
T1
2
=ln 2
λ=
0.693
λ
The Decay Processes
Alpha decay– The parent nucleus emits a helium nucleus.
• The remaining nucleus is called the daughter.• The daughter nucleus has two less protons and two less
neutrons.
– ExamplesHe Th U 4
2234
9023892 +→
He Rn Ra 42
22286
22688 +→
Transmutation
Transmutation is the spontaneous decay of of one element into another.– In the decay process, excess mass is
converted into energy of other forms, mostly into the KE of the nuclei.
39-1
Artificial Transmutation
Rutherford accomplished the first artificial transmutation.– He bombarded nitrogen-14 with alpha
particles and produced Oxygen-17.
Beta decay– The parent nucleus emits an electron or a positron.
How are these particles produced?• The daughter nucleus has the same number of
nucleons as the parent nucleus.• The atomic number increases by 1 or decreases by 1.
– Examples
32-1
e C N 01
126
127 ++→e N C 0
1-147
146 +→
The Decay Chain
Radioisotopes undergo a series of decays which eventually result in the formation of a stable isotope of lead.– Radioisotopes may decay by either alpha or beta
emission.
Various half-lives are involved.
295, 74
The neutrino– No charge– Little if any mass– A spin of 1/2– Very little interaction with matter
There is also an antineutrino.
Gamma decay– The parent nucleus emits a gamma ray
photon.• This results when the nucleus is in an excited
state (*) after a collision or previous decay.• The atomic number and the mass number do not
change.– Example
C C 126
*126 +→
Natural Radioactivity
There are two groups of radioactive nuclei– Natural
• Found in nature• Nature continuously resupplies us with
radioactive isotopes with short half-lives– Artificial
• Produced in the laboratory
Radon Hazzard
Radon is produced by the decay of radium in the soil.– Which type of decay is
responsible?
Health concerns?
13
Carbon Dating
Carbon dating depends upon the beta decay of carbon-14
• Carbon-14 is produced when cosmic rays bombard nitrogen-14 in the atmosphere.
• The ratio of carbon-14 to carbon-12 in the atmosphere remains constant.
– All living things have the same ratio.– When organisms die, the ratio begins to change because of the
beta decay of carbon-14.
The Shroud of Turin
The Shroud of Turin is a centuries old linen cloth that bears the image of a crucified man. A man that millions believe to be Jesus of Nazareth. Is it really the cloth that wrapped his crucified body, or is it simply a medieval forgery, a hoax perpetrated by some clever artist?
Biological Damage
Radiation damage in matter– The amount of damage depends upon the type of
radiation and upon the absorbing material.• Cancer or death may result
– In cells, ionization is the primarycause of damage.
• Ions and free radicals may beformed.
Cancer Treatment
Radiation can be used to kill cancer cells.– Cancer cells are more vulnerable to damage
from radiation than are normal cells.
293
Biological Damage
Somatic damage– Radiation damage to any cells but the
reproductive organs
Genetic damage– Damage to the reproductive cells
• Birth defects may result
Natural Radiation
Low level radiation from natural sources– Cosmic rays– Air– Soil– Food– Water– Building materials
Biological Units of Radiation
Roentgen (R)– The amount of radiation that deposits 8.6 x
10-3 J of energy into 1 kg of air
Rad– The amount of radiation that deposits 10-2 J of
energy into 1 kg of absorbing material
RBE
Relative Biological Effectiveness is the number of rad of x-radiation or gamma radiation that will produce the same biological damage as 1 rad of the radiation being used. (Table 29.3) on pg. 930.
rem
A rem (roentgen equivalent man) is the product of the dose in rad and the RBE factor.
€
rem = rad x RBE
Radiation Exposure Standards
Government limits– 0.5 rem/year for the general population
• Roentgen Equivalent Man – 5.0 rem/year for those in occupations
involving higher levels of exposure– Higher limits are allowed for certain parts of
the body• Hands and forearms
Radiation Exposure
Ingestion is the most dangerous form of exposure.– Strontium-90 is present in the radioactive fallout from
above ground nuclear testing.– Behaves like calcium chemically
– Iodine-131(also in radioactive fallout) • Affects the thyroid gland
Sterilization of food by radiation exposure kills:– Bacteria– Worms– Insects and their eggs
Exposing food to radiation is very controversial.
Sterilization in medicine reduces the chance of infection.– Surgical equipment– Grafts
• Bone• Cartilage• Skin
– Chromium-53 is used as a radioactive tracer to locate hemorrhages.
Cholangiogram, radithor capsules
Radioactive tracers in medicine must have a short half-life!– Examples
• Iodine-131– Evaluating the
performanceof the thyroid
Radioactive tracers in agriculture are used to evaluate the effectiveness of fertilizers
• Nitrogen use is tracked
Smoke detectors use an isotope of americiumto ionize air molecules– Smoke particles interfere with
this ionization.
Computerized Axial Tomography (CAT Scan) images have greater clarity and detail than a normal x-ray picture.– X-rays enter the body from different directions and the
results are evaluated by a computer.• A brain scan can be made in about 2 seconds.• A full body scan requires about 6 seconds
– X-rays do present health risks to the patient.
CAT scan
Magnetic Resonance Imaging
Very strong magnetic fields are used to affect proton spin for ~ 30 min.Changes can be detectedand used to form a highlydetailed image.MRI is much less damaging to cells.
PET Scans
A PET scan involves injecting a very small dose of a radioactive chemical, called a radiotracer, into the vein of your arm. The tracer travels through the body and is absorbed by the organs and tissues being studied.
299
Next, you will be asked to lie down on a flat examination table that is moved into the center of a PET scanner—a doughnut-like shaped machine. This machine detects and records the energy given off by the tracer substance and, with the aid of a computer, this energy is converted into three-dimensional pictures.
A physician can then look at cross-sectional images of the body organ from any angle in order to detect any functional problems.
Particle Counters
The Geiger counter– Radiation ionizes a confined gas which
has a large potential difference applied.
292