89
of the most practical nuclear reactions results from d nucleus that results from A>230 nuclei absorbing n Often split into two medium mass nuclear fragments plus additional neutrons. Alpha particle energy Cross Section ,n ,2n ,3n ,4n Total NUCLEAR FISSION

One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

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Page 1: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons.

Often split into two medium mass nuclear fragments plus additional neutrons.

Alpha particle energy

Cro

ss S

ect

ion

,n

,2n

,3n,4n

Total

NUCLEAR FISSION

Page 2: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

1930 Bothe & BeckerStudying -rays bombarding berylliumproduced a very penetrating non-ionizing form of radiation

-rays?

Irène and Frédéric Joliot-Curie

knocked protons free from paraffin targetsthe proton energy range revealed the uncharged radiation from Be to carry 5.3 MeV

1932 James Chadwickin discussions with Rutherford

became convinced could not be s

Assuming Compton Scattering to be the mechanism, E>52 MeV!

Page 3: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Neutron chamber

ionization(cloud)

chamber

Replacing the paraffin with other light substances, even beryllium, the protons were still produced.

Nature, February 27, 1932

Page 4: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Chadwick developed the theory explaining the phenomena as due to a 5.3 MeV neutral particle

with mass identical to the protonundergoing head-on collisions with nucleons in the target.

1935 Nobel Prize in Physics

9Be has a loosely bound neutron (1.7 MeV binding energy)

above a closed shell:

nCBeHe 1294

5-6 MeV from someother decay

Q=5.7 MeV

Neutrons produced by many nuclear reactions (but can’t be steered, focused or accelerated!)

Page 5: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Natural sources of neutrons

Mixtures of 226Ra ( source) and 9Be ~constant rate if neutron production

also strong source

so often replaced by 210Po, 230Pu or 241Am

Spontaneous fission, e.g. 252Cf ( ½ = 2.65 yr)

only 3% of its decays are through fission 97% -decays

Yield is still 2.31012 neutrons/gramsec !

Page 6: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

PdU 119

46

238

922

A possible (and observed) spontaneous fission reaction

238U119Pd

8.5 MeV/A

7.5 MeV/A

Gains ~1 MeV per nucleon!2119 MeV = 238 MeV

released by splitting

Page 7: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

PdU 119

46

238

922

Yet

is a rare decay: ½ = 1016 yr

not as probable as the much more common -decay

½ = 4.510 9 yr

Atomic (chemical) processes ~few eV

Fission involves 108 as much energy as chemical reactions!

Page 8: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

From the curve of binding energy per nucleon the most stable form of nuclear matter is as medium mass nuclei.

Page 9: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

),(),(),(2211

ZAMZAMZAM Consider:

),(),(),(2211

ZABZABZABQ The Q value (energy release) of this process is

The mass differences cancel since the total number of constituents remains unchanged.

For simplicity, if we assume the protons and neutrons divide in the same ratio as the total nucleons:

111// yZZAA

222// yZZAA

121 yy

Page 10: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

))()(1())()(1( 3/5

2

3/5

1

3/2

2

3/2

1yyEyyEQ

CS

The difference in binding energy comes from the surface and coulomb terms

so the energy released can then be expressed in terms of the surface energy Es and the coulomb energy Ec

of the original nucleus (A,Z).

maximum Q is found by setting dQ/dy1 = 0

121 yyNote: 1/

12dydy

maximum occurs when y1 = y2 = 1/2.

SCEEQ 26.037.0

Page 11: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Fission into two equal nuclei (symmetric fission) produces the largest energy output or Q value

The process is exothermic (Q > 0) if Ec/Es > 0.7.

in terms of the fission parameter, x

50

)/()/2)(/()2/(

2

2 AZaaAZEEx

CSSC >0.35

Suggesting all nuclei with (Z2/A) > 18 (ie heavier than 90Zr) should spontaneously release energy

by undergoing symmetric fission.

However

Page 12: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Half-life of spontaneous fission as a function of x

where

criticalAZ

AZx

)/(

/2

2

and

49)/( 2 criticalAZ

R.Vandenbosch and

J.R.Huizenga.Nuclear Fusion,Academic Press,New York, 1973.

Page 13: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

There isa competition between

the nuclear force binding the nucleus together

and the coulomb repulsion

trying to tear it apart

Page 14: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Induced fission as nuclear reaction

nBrLaUUn 295

35

139

57

236

92

235

92

nCsRbUUn 2141

55

93

37

236

92

235

92

suggests the absorption of the neutron (and its energy)may induce such distortions/vibrations in the nucleus.

Page 15: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium
Page 16: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

The surface if any arbitrary figure can be expanded as

00

]),(1[l

l

lm

m

lm lYRR

If lm time-independent: permanent deformation of the nucleus

If lm time-dependent: an oscillation of the nucleus

Page 17: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

The Spherical Harmonics Y ,ℓ m(,)

ℓ = 0

ℓ = 1

ℓ = 2

ℓ = 34

100 Y

ieY sin

8

311

cos4

310

Y

ieY 2

2

sin2

15

4

122

ieY cossin

8

1521

2

12cos2

3

4

1520

Y

ieY 3

3

sin4

35

4

133

ieY 2

cos2

sin2

105

4

132

ieY 12cos5sin

4

21

4

131

cos

2

33cos2

5

4

730Y

Page 18: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

ℓ = 0

ℓ = 1

sin1~R

cos1~R

z Nuclear Charge Density

Page 19: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

ℓ = 2Lowest order to be considered:

quadrupole deformation

For which we write the nuclear radius

]),(1[2

2220

m

m

mYRR

The l=2, m=0 mode:

]1[)( )12

cos3(

2/1

16

5200

RtR

Page 20: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

]1[)( )12

cos3(

2/1

16

5200

RtR

Z

Page 21: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Example of a vibrational spectrum (levels denoted by the number of phonons, N)O.Nathan and S.G.Nilsson, Alpha- Beta- and Gamma-Ray Spectroscopy,

Vol.1, (K. Siegbahn, ed.) North Holland, Amsterdam, 1965.

Nuclei do show spectra for such vibrational modes

Page 22: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

We can approximate any small elongation from a spherical shape by

)1(2

10

Rb

)1(0

Ra

3/12123/2 )( AZaANZaAaAaBCsymSV

The semi-empirical mass formula

3/42

2

2

3/1 )(

AZaA

NZaAaa

A

BCsymSV

semi-major axis

semi-minor axis

)1( 23/1

52 AaE

SS

)1( 23/12

51 AZaE

CC

From which:

Page 23: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

)()( 23/223/12

52

51 AaAZa

EEE

SC

SC

With the surface energy (strong nuclear binding force) proportional to area

2Ewhich we can write in the form

where ][ 3/23/12 2 51 AaAZa SC

Notice > 0

(so the Coulomb force wins out) for:

.492

2

C

S

a

a

A

Z Same fission parameterintroduced when estimating available Qin symmetric fission

Coulomb force deforming nucleus

surface tension holding spherical

shape

Page 24: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

2E

r

comes from considering small perturbations from a sphere.

As long as these disturbances are slight, the Separation, r, of distinct fragments linearly follows

2r

for small r

2

04

)(

R

rQrV

separation r

V(r

)

At zero separation the potential just equals the release energy Q For Z2/A<49,

is negative.

Page 25: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

r

for small r r

eZZrV

2

21)(

separation r

V(r

)

r r

While for large r, after the fragments have been scissioned

for large r

Page 26: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

For such quadrupole distortions the figure shows the energy of

deformation (as a factorof the original sphere’s

surface energy Es)

plotted against for different values of

the fission parameter x.

When x > 1 (Z2/A>49)

the nuclei are completely unstable to such distortions.

Page 27: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

The potential energy V(r) = constant-B as a function of the separation, r, between fragments.

Z2/A=36

Z2/A=49

such unstable statesdecay in characteristicnuclear times ~10-22 sec

Tunneling does allow spontaneous fission, but it must compete with

other decay mechanisms (-decay)

Page 28: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium
Page 29: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

No stable stateswith Z2/A>49!

Tunnelingprobabilitydrops as

Z2/A drops(half-life

increases).

Page 30: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

At smaller values of x, fission by barrier penetration can occur, However recall that the transmission factor (e.g., for -decay) is

eXwhere

drh

ErVm ])([22 m

while for particles (m~4u)this gave reasonable, observable probabilities for tunneling/decay

for the masses of the nuclear fragments we’re talking about, can become huge and X negligible.

Page 31: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

nBrLaUUn 2* 95

35

139

57

236

92

235

92

nRbCsUUn 2* 93

37

141

55

236

92

235

92

Neutron absorption by heavy nuclei can create a compound nucleus in an excited state

above the activation energy barrier.As we have seen, compound nuclei have many final states into which they can decay:

nYXUUn A

Z

A

Z 2

2

1

1

236

92

235

92*

where Z1+Z2=92, A1+A2+=236

...in general:

Experimentally find the average A1/A2 peaks at 3/2

PROMPTNEUTRONS

nSrXeUUn 2* 95

38

139

54

236

92

235

92

Page 32: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

The incident neutron itself need not be of high energy.

Thermal neutrons E< 1 eVSlow neutrons E ~ 1 keVFast neutrons E ~ 100 keV – 10 MeV

Typicalof decayProducts& nuclearreactions

“Thermal neutrons” (slowed by interactions with any material they pass through) have been demonstrated to be particularly effective.

This merely reflects the general ~1/v behavior we have noted for all cross sections!

Cro

ss s

ecti

on

incident particle velocity, v

Page 33: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

At such low excitation there may be barely enough available energy to drive the two fragments of the nucleus apart.

Thus the individual nucleons settle into the lowest possible energy configurations

Division can only proceed if as much binding energy as possible

is transformed into the kinetic energy separating them out.

involving the most tightly bound final states.

(so MOST of the available Q goes into the kinetic energy of the fragments!)

Page 34: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

There is a strong tendency to produce a heavy fragment of A ~ 140 (with double magic numbers N = 82 and Z = 50).

Page 35: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

PdU 119

46

238

922

A possible (and observed) spontaneous fission reaction

238U119Pd

8.5 MeV/A

7.5 MeV/A

Gains ~1 MeV per nucleon!2119 MeV = 238 MeV

released by splitting

Page 36: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

238 MeV represented an estimate of the maximum available energyfor symmetric fission.

For the observed distribution

of final statesthe typical average is

~200 MeV per fission.

Fragment kinetic energy 165 MeV

Prompt neutrons 5 MeV

Prompt gamma rays 7 MeV

Radioactive decay fragments 25 MeV

This 200 MeV is distributed approximately as:

Page 37: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

235U

Page 38: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Isobars off the valley of stability (dark squares on preceding slide)-decay to a more stable state.

Page 39: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

and decays can leave a daughter in an excited nuclear state

187W

1/2

5/2

187Re

0.13425

0.20625

0.61890

0.68610

198Au

2

0

198Hg

0.412 MeV

1.088 MeV

Page 40: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

nKrBaUUn 3* 90

36

143

56

236

92

235

92

With the fission fragments radioactive, a decay sequence to stable nuclei must follow

143

57

143

56 eLaBa

neZrNdUUn 388* 90

40

143

60

236

92

235

92

eCe 143

58

143

59 ePr

143

59 edN

90

37

90

36 eRbKr

eSr 90

38

90

39 eY

90

40 eZr

Page 41: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

nRbCsUUn 2* 93

37

141

55

236

92

235

92

With the fission fragments radioactive, a decay sequence to stable nuclei must follow

Pr 141

59

141

58

141

57

141

56

141

55 CeLaBaCs

CeLaBaCs 140

58

140

57

140

56

140

55 n

0.03%

25 sec

18 min

4 hr

33 d

65 sec

13 d

40 h

NbZrYSrRb 93

41

93

40

93

39

93

38

93

37

ZrYSrRb 92

40

92

39

92

38

92

37 n

1.40%

6 sec

7 min

10 hr

106 yr

5 sec

3 hr

4 h

nePrCeUUn 2888* 141

59

140

58

236

92

235

92

n3 n4sometimes or

Page 42: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

nBrLaUUn 2* 95

35

139

57

236

92

235

92

nRbCsUUn 2* 93

37

141

55

236

92

235

92

nSrXeUUn 2* 95

38

139

54

236

92

235

92

nKrCsUUn 3* 90

36

143

56

236

92

235

92

For 235U fission, average number of prompt neutrons ~ 2.5

with a small number of additional delayed neutrons.

Page 43: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

with every neutron freed comes the possibility of additional fission events

This avalanche is the chain reaction.

Page 44: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

235U will fission (n,f) at all energies of the absorbed neutron.

It is a FISSILE material.

However such a reaction cannot occur in natural uranium (0.7% 235U, 99.3% 238U)

Page 45: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Total (t) and fission (f) cross sections of 235U.

1 b = 10-24 cm2

Page 46: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium
Page 47: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

238U has a threshold for fission (n,f) at a neutron energy of 1MeV.

The difference between these two isotopes of uranium is explained by the presence of the pairing term

in the semi-empirical mass formula.

Notice:

0

4/3

4/3

Aa

Aa

pair

pair for Z even, N even

for Z odd, N odd

for A odd

Like nucleons couple pairwise into especially stable configurations.

Page 48: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Note the strong resonant capture of neutrons (n, ) in the energy range

10-100 eV(particularly

for 238U where the

cross-section reaches

high values)

Page 49: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

The fission neutron energy spectrum peaks at around 1 MeV

Page 50: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

At 1 MeVthe inelastic cross-section (n,n') in 238U exceeds the

fission cross-section.

This effectively prevents fission from occurring

in 238U.

Page 51: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Natural uranium (0.7% 235U, 99.3% 238U)

undergoes thermal fission

onlythe

Fission produces mostly fast neutrons

Mev

but is most efficiently induced by slow neutrons

E (eV)

Page 52: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Consider fission neutrons created deep enough in a lump of natural uranium

that we’ll just (for now) ignore that some neutrons may simply escaping from the sample.

Page 53: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

1000

100

10

1

1000

100

10

1

10000

0.1

Cro

ss-s

ecti

on

(b

arn

s)C

ross

-sec

tio

n (

bar

ns)

The processes competing withneutron-induced fusion

have approximate cross-sections(read from the graphs at right) of

238U (n,n) elastic scattering ~ 5 barn(n,n’) inelastic scattering ~ 2 barn(n,) ~0.2 barn(n,f) fission ~0.6 barn

235U (n,n) elastic scattering ~ 5 barn(n,n’) inelastic scattering ~ 3 barn(n,) ~0.2 barn(n,f) fission ~ 2 barn

Page 54: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

238U (n,n) elastic scattering 8.3 (n,n’) inelastic scattering 3.3(n,) 0.3(n,f) fission 1

235U (n,n) elastic scattering 6.7(n,n’) inelastic scattering 1.7(n,) 0.3

(n,f) fission 3.3

Giving a relative probability to each of:

0.7/99.3

Page 55: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

With 2-3 neutrons generated by each fission,only ~20 neutrons in the second generation

- this is insufficient to sustain a chain reaction.

Of the first 100 fission neutrons we start with

238U (n,n) elastic scattering 63 (n,n’) inelastic scattering 25(n,) 2(n,f) fission 8

235U (n,n) elastic scattering 1(n,n’) inelastic scattering 0(n,) 0

(n,f) fission 0

~98 are captured in the dominant 238U

only 8 of these

captures result

in fission

Page 56: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

mixing natural uranium with a material to slow (but not absorb) neutrons to lower energies

where the fission cross-section for 235U is large.

Most fissions are then induced by neutrons with thermal energies (~0.025 eV).

FAST REACTOR

a 50-50 mix of the two isotopes will sustain a chain reaction (most fission events occurring now in 235U by neutron energies in the range 0.3 - 2.0 keV.

Enriching the 235U content

THERMAL REACTOR moderating the neutrons to thermal speeds

Page 57: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Granulated powders can be mixed for this purpose. Powdered uranium

Or blocks of uranium fuel can be alternately stacked with graphite to form a nuclear pile.

Page 58: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Moderator(Graphite)

Moderator(Graphite)

FUEL

FUEL

FUEL

1. Starting with neutrons/fission

2. Avg of neutrons after fast fission

238U

3. p survive thermalization

4. pf number captured in 235U

235U5. k = pf(f /total) number producing fission

Page 59: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

One fission event producesk = pf(f /total)

secondary fission events.

k is the reproduction factor.

A chain reaction requires k1.

If k=1 the core is “critical” and self-sustaining.

Typical values for natural uranium/graphite piles are

47.2 02.1 89.0p

88.0f 54.0/ tf

k=1.07

Page 60: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Uranium is not dumped into the core like coal shoveled into a furnace.  Instead it is processed and formed into fuel pellets (~pencil eraser size). 

The fuel pellets are stacked inside hollow metal tubes to form fuel rods 11 to 25 feet in length. 

Before it is used in the reactor, the uranium fuel is not very radioactive.

Page 61: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

The fuel rods are arranged in a regular lattice inside the moderator. The rods are typically 2-3 cm in diameter and

spaced about 25 cm apart.

The rods metal sheath or cladding – most commonly stainless steel or alloys of zirconium.

This cladding supports the fuel mechanically, prevents release of radioactive fission products into the coolant stream and

provides extended surface contact with the coolant in order to promote effective heat transfer.

Page 62: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

A single fuel rod cannot generate enough heat to make the amount of electricity needed from a power plant.  Fuel rods are carefully bound together in assemblies, each of which can contain over 200 fuel rods.  The assemblies hold the fuel rods apart so that when they are submerged in the reactor core, water can flow between them.

In nuclear power plants, the moderator is often In nuclear power plants, the moderator is often water water (though some types do still use graphite).(though some types do still use graphite).   

Page 63: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Fuel cell channelsin face

of reactor core.

Page 64: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium
Page 65: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Control rods slide in or out between the fuel rods to regulate the chain reaction.

contain cadmium or boron (high cross section for neutron absorption, without fission). 

e.g., natural Boron is 20% 10B

Control rods act like sponges to absorb excess neutrons.

with a cross section for thermal neutrons of3840 b for the process

*710 LinB

Page 66: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

When the core temperature drops too low, the control rods are slowly pulled out of the core, and fewer neutrons are absorbed. 

When the temperature in the core rises, the rods are slowly inserted.

To maintain a controlled nuclear chain reaction, the control rods are manipulated until each fission results in just one neutron on average, all other neutrons effectively absorbed by the control rods.

Temperature changes in the core are generally very gradual.  However should monitors detect a sudden change in temperature, the reactor immediately shuts down automatically by dropping all the control rods into the core.  A shutdown takes only seconds and halts the nuclear chain reaction.

Page 67: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

This very common type makes use of the excellent properties of water as both coolant and moderator (ordinary water does absorb neutrons – converting hydrogen into deuterium).

The Boiling Water Reactor (BWR) allows the water to boil in the reactor core and uses the steam to drive the turbines.

Page 68: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

The highest temperature possible for liquid water (critical temperature 374°C) is a limitation for devices that use water to convey heat.

In this ideal case the heat is received isothermally (the working fluid at T1)

but rejected isothermally (at T2) with all processes reversible.

No real power plant operates on an ideal Carnot cycle, but the expression shows the higher T1, the higher the efficiency (T2 cannot be lower than

the outside temperature).

12 /1 TTFurthermore recall: the Carnot engine efficiency   is

The core must be contained within a pressure vessel of welded steel (typically withstanding pressures of about 1.55 x107 Pa or 153 bar.

1st land based pressurized water reactor: Shippingport USA (1957).

Page 69: One of the most practical nuclear reactions results from the compound nucleus that results from A>230 nuclei absorbing neutrons. Often split into two medium

Pressure vessels are enormouswith 9 inch thick walls, often weighing more than 300 tons. 

The pressure vessel surrounds and protects the reactor core,providing a safety barrier and holding the fuel assemblies, control rods, and coolant.

Pressure vessels are made of carbon steel and lined with a layer of stainless steel to prevent rust.  The pressure vessel is located inside the containment building, a thick concrete structure reinforced with steel bars.

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A Fast Reactor has no moderator

and consequently a much smaller core.

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The very high power involved means that liquid metals have to be used as coolants!

Liquid sodium is the most common but has the disadvantage of becoming

radioactive itself through 23Na(n,  )24Na.

As well as generating power fast reactors are used for breeding fissile material.

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Breeder Reactors

If uranium fission reactors used as sole source of electrical power needs

all high-grade ores used up within a few decades!

Fermi, Zinn (1944)

Can fissile nuclei be grown? (the result of any nuclear reaction)Can we create fissile material as a by product of any reaction?

The parent nuclei that spawns the fissile material is described as being a fertile nuclide.

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Example: build a reactor core that runs on 239Pu (the fuel)

packed within a bed of 238U (the fertile nuclide)• =2.91 fast neutrons/239PU fission

Only one of these on average producing an additional fissionis sufficient for sustainability.

If the rest are incident on 238U there’s a chance of inducing

UUn 239238

U239 Np239

Pu2391/2= 25 min

1/2= 2.3 days

A well designed breeder reactor can double the amount of fissile material

in 7 – 10 years.

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While neither natural Uranium cannot maintain a chain reactioneven small lumps of pure 235U or 239Pu cannot explode

simply because of the number of neutrons that escape before inducing fission.

Recall we need k = pf(f /total) > 1

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A large enough (critical) mass of 235U or 239Pu can chain reactand the reaction set off by any accidental initial neutron

(even from a rare spontaneous fission event).

If N neutrons (initially even 1 or 2) are present at time ttheir number will increase during the next moment dt by

NdtdN where is related to k and obviously depends on

the fissile material and its geometry.

For critical samples of 235U ~108 Hz.

As long as we can treat as a constant

/)0()( teNtN where =1/ is the

“generation time.”

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Five grades of uranium are commonly recognized:

1. Depleted uranium: containing < 0.71% 235U.2. Natural uranium: containing 0.71% 235U. 3. Low-enriched uranium (LEU), between 0.71 – 20% 235U.

• commercial power reactors use 2-6 % 235U fuels. • cannot be used to make nuclear explosives

4. Highly enriched uranium (HEU): containing > 20% 235U. Research and naval reactors use either LEU or HEU fuel.5. Weapon-grade uranium: HEU containing > 90% 235U.

Uranium- 233: fissile, weapon-useable isotope, derived from irradiating 232Th with neutrons, ½ =160,000 years; 10-20 kg required for a

nuclear device; less common than U-235 for making nuclear explosives.

Uranium-235: best suited for fission bomb (or fast reactor) when enriched to > 90% purity; 6-25 kg required for a nuclear bomb; “significant quantities” standards (for UN inspections) is as little as 3 kg; a recent international study estimates 1,750 tons of highly enriched 235U have been produced worldwide.

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Plutonium-239: Highly carcinogenic ray emitter.

Unlike uranium, all (but trace quantities) of Pu are manufactured. 239Pu is produced in nuclear reactors when 238U is irradiated with neutrons.

½ = 24,000 years, and it is a fissile material.

Subsequent neutron captures lead to accumulations of 240Pu, 241Pu and 242Pu.241Pu is fissile, but 240Pu and 242Pu are not. However, all are fissionable by fast neutrons, and can be used either in combination or alone in nuclear explosives;

best fission explosive nuclear material. 3-8 kg required for nuclear explosive; "significant quantities standard" 1 kg.

Plutonium is ~10 times more toxic than nerve gas. When inhaled, the smallest particles cause cancer: inhaling 12,000 micrograms (millionths of a gram) causes death within 60 days. The dispersal of 3.5 ounces of plutonium could kill every-one in a large office building.

For weapon production, plutonium has to be at least 93% enriched. Plutonium technology for bomb construction is judged to be more difficult than 235U techniques.

The bomb dropped on Nagasaki contained 6.1 kg. There are about 1,200 metric tons of Plutonium on our planet of which some 230 tons have been produced for military purposes.

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Weapons can be made out of plutonium with low concentrations of 239Pu and high concentrations of 240Pu, 241Pu, or 242Pu.The plutonium used in nuclear weapons typically contains mostly 239Pu and relatively small fractions of other plutonium isotopes. Plutonium discharged in power reactor fuel typically contains significantly less 239Pu and more of other plutonium isotopes.

The following grades of plutonium are widely used:1. Weapon-grade plutonium: containing < 7% 240Pu.2. Fuel-grade plutonium: 7 - 18 % 240Pu.3. Reactor-grade plutonium, containing over 18 percent 240Pu.The term "super-grade plutonium" is sometimes used to describe plutonium containing less than 3 percent plutonium 240. The term "weapon-usable plutonium" is often used to describe plutonium in separated form and, thus able to be quickly turned into weapons components

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Before triggering, fissile material is kept in subcritical quantities to prevent accidental explosions. An electrical trigger sets off chemical explosives that drive the subcritical parts together.

Gun Trigger Assembly

Propellant

TamperTamper

Active Materialeach 2/3 critical

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Hiroshima

Enola Gay

Little Boy

Size: length - 3 meters, diameter - 0.7 meters.

Weight: 4 tons.

Nuclear material: Uranium 235.

Energy released: equivalent to 12.5 kilotons of TNT.

Code name:"Little Boy"

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/)0()( teNtN Once triggered the

chain reactionbuilds exponentially.

Note logarithmic scale!

After ~50 generations (0.50 sec) the energyreleased is increasing sorapidly it heats thematerial to the pointit expands explosively.

This scatters the remaining fissile material in subcriticalquantities, and the chainreaction ends.

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Dropping the first atomic bombAt 2:45am local time (August 6, 1945), the Enola Gay, a B-29 bomber took off from the US air base on Tinian Island in the western Pacific. 6½ hours later, at 8:15 A.M. Japan time, its atomic bomb was dropped and exploded a minute later at an estimated altitude of 58020 meters over central Hiroshima.

Initial explosive conditionsMaximum temperature at burst point: several million degrees C. A 15m radius fireball formed in 0.1 millisecond, with a temperature of 300,000o C, and expanded to its huge maximum size in one second. The top of the atomic cloud reached an altitude of 17,000 meters.

Black rainRadioactive debris fell in a “black rain” for > hour over a wide area.

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Damaging effects of the atomic bombThermal heatIntense thermal heat emitted by the fireball caused severe burns and loss of eyesight. Thermal burns of bare skin occurred as far as 3.5 kilometers from ground zero (directly below the burst point). Most people exposed to thermal rays within 1-kilometer radius of ground zero died. Tile and glass melted; all combustible materials were consumed.

BlastAn atomic explosion causes an enormous shock wave followed instantaneously by a rapid expansion of air (the blast); these carry ~half the explosion's released energy. Maximum wind pressure of the blast: 35 tons per square meter. Maximum wind velocity: 440 meters per second. Wooden houses within 2.3 km of ground zero collapsed. Concrete buildings nearground zero (blast from above) had ceilings crushed, windows and doors blown off.

RadiationExposure within 500 meters of ground zero was fatal. People exposed at distances of 3-5 kilometers later showed symptoms of aftereffects, including radiation-induced cancers.

DeathsWith an uncertain population figure, the death toll could only be estimated. According to data submitted to the United Nations by Hiroshima City in 1976, the death count reached 140,000 (plus or minus 10,000) by the end of December, 1945.

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Active Material(235U or 239Pu)each 1/3 critical

electricaltrigger

chemicalexplosive

Active Material(235U or 239Pu)

subcritical density

chemicalexplosive

Implosion Assembly Designs

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Nagasaki

Fat Man

The atomic bomb dropped on Nagasaki exploded at 11:02 A.M. on August 9. Using 6.1 kg of 239Pu it delivered the explosive power of 20 kilotons of TNT-equivalent,

And left an estimated 70,000 dead by the end of 1945.

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