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Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
1
OpticalProximityCorrection
*Auxiliary featuresadded on mask
Mask Wafer
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
2
Overlay Errors
+
+
+
+
Alignmentmarksfrompreviousmaskinglevel
wafer
alignmentmask
photomaskplate
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
3
(1) Thermal run-in/run-out errors
sisimm TTrR
T Tsi change of mask and wafer tempcoefficient of thermal expansion of
mask & Si
m
m si
, .,
run-outerror
waferradius
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
4
run-out
(2) Translational Error
referrer
image
n+
Al
p
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
5
(3) Rotational Error
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
6
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
7
Characterization of Overlay Errors
+ +
+
+
L
T
B
R
wafer
O
O
O
O
+
R
O
O =opticalimage
+ =alignmentmarks onwafer
y
x
C
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
8
m T R C L Bx 0.0 0.7 0.5 0.3 1.0y 0.7 1.0 0.5 0.0 0.3
* Center of wafer has only translation error
Terror = (0.5, 0.5)
After subtracting Terror,
Example
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
9
T R C L Bx -0.5 0.2 0 -0.2 0.5y 0.2 0.5 0 -0.5 -0.2
T
B
R
wafer
yx
L0.5
0.2
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
10
radianserrorRotational
cmDisdiameterwaferIf
clockwise][countermerrorRotationalmerroroutRun
510
10"4
5.02.0
R
y
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
11
Reference markson wafer
Optical imageof maskalignmentmarks
With thermal run-out, the alignment error is 1/2 ofthe image/reference difference [best scenario]
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
12
Total Overlay Tolerance
2 2total i
i
i = std. deviation of overlay error for ith masking step
total = std. deviation for total overlay error
Layout design-rule specification should be > total
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
13
Example: Contact to source/drain of MOSFET.
n+
SiO2 SiO2
Al“ideal”
p-Si
SiO2 SiO2
Al
p-Sin+ “short”, ohmic contactAlignment error
between oxide openingand n+ pattern
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
14
SiO2
n+
SiO2
Solution: Design n+ region larger than contact hole
Al
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
15
Two Resist Types
• Negative Resist– Polymer (Molecular Weight (MW) ~65000)– Light Sensitive Additive Promotes Crosslinking– Volatile Solvents– Light breaks N-N => Crosslink Chains– Sensitive, hard, Swelling during Develop
• Positive Resist– Polymer (MW~5000)– Photoactive Inhibitor (20%)– Volatile Solvents– Inhibitor Looses N2 => Alkali Soluble Acid– Develops by “etching” - No Swelling.
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
16
hv
mask
P.R.exposedpart isremoved
=E resist sensitivity
Resist contrast
T
log
100%
E1 ETexposurephotonenergy(log scale)
resist thickness remaining
(linearscale)
~ 5 to 10
LOG TO BASE 10
Note: In the 143 Reader, is defined as natural logNote: In the 143 Reader, is defined as natural log
Positive Resist
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
17
Positive P.R. Mechanism
Photons deactivatesensitizer
polymer +photosensitizer
lesscross-linking
dissolvein developersolution
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
18
Positive Resist Exposure Reaction“diazide” “ketene” - a = C = 0 group
moisture
“carboxylic acid”
“soluble ester”
The ketene is short-lived intermediate
The carboxylic acidcan react with thealkaline solution (thedeveloper) to form asoluble ester.
PAC
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
N Cheung EE243 s2010 Lec 1519
Chemical Amplified Resist (CAR)
Photo-Acidgenerator
For reference only
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
20
Negative P.R. Mechanism
hv
E1ET
remaining
photonenergy
afterdevelopment
1
1log EET
%
Log to base 10
mask
hv => cross-linking => insoluble indeveloper solution.
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
21
resistresist
substrate
resist
substrate
resist
Position x
Finitecontrast
Infinitecontrast
Optical image
Why High-Contrast Resist is desirable ?
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
22
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
23
Positive vs. Negative Photoresists
• Positive P.R.: higher resolution aqueous-based solvents less sensitive
• Negative P.R.: more sensitive => higher exposure throughput relatively tolerant of developing conditions better chemical resistance => better mask material less expensive lower resolution organic-based solvents
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
24
Standing Waves
substrate
PositivePhotoresist
hv
substrate
After developmentPositivePhotoresist.
*Photoresist has a finite thickness
Higher Intensity
Lower Intensity
Faster Development rate
Slower Development rate
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
25
reflectingsurface
OxidePhotoresistAir
E1E2
E3
E4
x=0 x=d x=dr
I23 (x) =1T
0
T(E2(x)+E3(x))2dt
=12 (E2 - E3)2 + 2E2E3sin2[k(d-x)]
I23 (max) =12(E2 + E3)2 ; I 23(min) =
12(E2 - E3)2
I (max)23
I (min)23
d
x
In ten sity m in im a occu r at :2n (d -x) = 0 , , 2 , ... .. ..
In ten sity m a x im a occu r a t :2n (d -x ) = /2 , 3 , 5 , ... .. . .
Resist profile and energydeposition depend onoxide thickness underneath(see handout for derivation)
Resist profile and energydeposition depend onoxide thickness underneath(see handout for derivation)
Standing wave effect
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
26
P.R.
Intensity = minimum whenn
mdx2
x d
m = 0, 1, 2,...
Intensity = maximum whenn
mdx4
m = 1, 3, 5,...
n = refractive index of resist
SiO2/Si substrate
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
27
Simulated Resist Cross-section as function ofdevelopment time
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
28
Proximity Scattering
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
29
Approaches for Reducing Substrate Effects
• Use absorption dyes in photoresist• Use anti-reflection coating (ARC)• Use multi-layer resist process
1: thin planar layer for high-resolution imaging2: thin develop-stop layer, used for pattern transfer to 33: thick layer of hardened resist
(imaging layer)
(etch stop)(planarization layer)
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
30
Electron-Beam Lithography
V312.
Angstroms
for V in Volts
Example: 30 kV e-beam=> = 0.07 Angstroms
NA = 0.002 – 0.005Resolution < 1 nm
But beam current needsto be 10’s of mA for athroughput of morethan 10 wafers an hour.
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
31
Low Throughputfor both raster andvector scanning (SerialProcess)
VariableBeam-shapeEBL
StencilMaskEBL
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
32
The Proximity EffectMonte Carlo simulation of electron trajectories
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
33
e-beam lithographyresolution factors
• beam quality ( ~1 nm)
• secondary electrons ( lateral range: few nm)
performance records
organic resist PMMA ~ 7 nm
inorganic resist, b.v. AlF3 ~ 1-2 nm
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
34
•A liquid with index of refraction n>1 is introduced between theimaging optics and the wafer.
Immersion Lithography
liquid = air /n
With water, the index ofrefraction at = 193 nmis 1.44, improving theresolution significantly.
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
Phase-Shifting Mask
For resolution enhancement . Example shown is an alternating PSM
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
36
EUV Lithography
=11.2 nm
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
N Cheung EE243S05 Lec 1637
Mo-SiReflective Mask
Schematic for EUV Litho
reflectivity
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
N Cheung EE243S05 Lec 1638
Nanoimprinting
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
N Cheung EE243S05 Lec 1639Empirical : Resolution (in Å) ~ 23 Areal Throughput (in um2/hr) 0.2
Why photolithography ?
Highthroughput
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
40
Professor N. Cheung, U.C. Berkeley
Lecture 5EE143 F2010
41
‘Hands On’ Exploration of Imageshttp://cuervo.eecs.berkeley.edu/
A web browser-based simulator of lithography