Embed Size (px)
Citation preview
Noverr.cer 1985
Mr. William LangleyEnvironmental SErvices DivisionMonterey Park Plaza, Building C6608 Hornwood DriveHouston, TX 77074
Reference: Dioxin Case 5028, Versar Project 868EPA Contract No. 68-01-6929
Dear Mr. Langley:
Enclosed is the dioxin data package for Case 5028 which consisted ofeight samples out of Region VI. The samples were received at Versar on09/28/85.
Should you require additional information or have questions, pleasecall.
Sincerely,Versar Inc.
^ J . -
Scott E. PowersMass Spectrometry Section ChiefLaboratory Operations
cc: Viar and Company, Paula AussererUS EPA EMSL/LV, Data Audit Staff
-os coffee cVT3.1.6.9
0310^902; O V C R S A R CENTER B P 0. COX 1549 • SPRIMGFIELD. VIRGINIA 22151 • TEL5FHCME. ,703) 750-3000 • TELEX: 30^23
INC.
DIOXIN CASE DATA REPORT
CASE •50^
-GW^WT- c-L-"Q-yio^sog< -000001
6850 VERSAR CENTER • P.O. BOX 1549 • SPRINGFIELD. VIRGINIA 22151 • TELEPHONE: (703) 750-3000 • TELEX: 901125
.Vd^SftB'Nc OIOXIN CASE DATA REPORT\; OELIVERABLES INDEX
I . CASE NARRATIVE
The case narrative must contain: Case number. Contract number,summary of any QC, sample, shipment and analytical problems, anddocumentation of a11 Internal decision tree processes used.Outline problems encountered and final solutions. Be as specificand detailed as necessary.
II. SAMPLE SUMMARY DATA PACKAGEA. TCOD Data Report Form (Form B-1)B. Initial Calibration Summary 1n chronological order by
Instrument (Form B-2)C. Continuing Calibration Summary In chronological order by
Instrument (Form B-3)D . TCDO Data Report - Partial Scan Confirmation (Form B-4)E. OFTPP Form
III. SAMPLE DATA AND STANDARD DATA CALCULATION WORKSHEETS
A. 6C/MS System Performance Check (Form WS-1)B. Continuing Calibration and Sensitivity Test (Form WS-2)C. Sample Concentration Calculation (Form WS-3)D. Sample Surrogate Recovery Calculation (Form WS-4)E. Native Response Factor Initial Curve (Form WS-5)F . Surrogate Response Factor Initial Curve (Form WS-6)C. . Extraction Chronicle (Form WS-7)
IV. RAW DATA PACKAGE
A . 6C/MS System Performance SICPsB. Continuing Calibration and Sensitivity Test SICPsC. Sample Analysis SICPsD. Initial Calibration Standards SICPsE. DFTPP Bar Graph Spectra and Mass ListingF . Partial Scan Data Chromatogram and Spectra
^00v—LH
0
0
V . DOCUMENTATION
A . GC/MS Log Book Pages^ B. Parameter Request
'—'-' C . Traffic ReportsD . Chaln-of-Custody
^W^Qt38^ ^
OSW^jQ——
000002
—-, V^r^aa*^ V^l A 411 inc.
-^-
SECTION I: CASE NARRATIVE CASE -502.S
')
-0 (7??J8B9 ^--
O^W^St^"
000003
November 21, 1985
I . Dioxin Case 502B Narrative;;EPA Contract 68-01-6929Client: Region vlversar Project 868
This report contains the data -for Dioxin Case 5028. Thiscase was received at Versar on September 28, 1985. The sampleswere shipped to versar by Federal Express. The samples arrivedintact and are listed below:
Sample List
DFO19005DFO19006DF019001-DDF019001-N
DFO19001DFO19002DFO19003DFO19004
There was a problem with the extraction of this case ofsamples. The problem is discussed in detail below. Once theproblem was corrected and the system back on track, the analysesproceeded smoothly.
The initial sample processing was started on October 22,1985. The initial extracts were analyzed on October 25,1985 andthe samples had low internal standard and surrogate recoveries.The column cleanup was suspected to be the cause. We analysedthe preeluant of the silica gel and alumina columns. There wasno recovery of material -from that. It was evident that thematerial was stuck on one o-f the columns. Some work was done toimprove the lab technicians column packing techniques and toassure the correct column activity. In addition the carbopackcolumn cleanup was omitted on the subsequent re—extraction.
The samples were re—extracted and reanalyzed and the re-extraction recoveries were good. Some of the samples were foundto have dioxin in them. Should you have questions or requireadditional information please call. We regret any inconveniencethe delays in reporting may have caused.
CO
0
inoo
Sincerely,
'^^^./-Scott E. Powers
GCMS Laboratory Section ChiefLaboratory Operations 0310^06
000004 OCTCT05i ' c<_
6850 VERSAR CENTER • P.O. BOX 1549 • SPRINGFIELD, VIRGINIA 22151 • TELEPHONE: (703» 750-3000 • TELEX: 901125
0\0
T—
inoo
SECTION II: SAMPLE SUMMARY DATA PACKAGE
0310.JS07
O^C- ^^A ^ <^
000005
FORM B-l. TCDD DATA REPORT FORKLABi VERSftR INC.CASE NO: 502BBATCH/ SHIPMENT N0.1 REPORT DATE; 11-21-85
COLUMN) SP-2330
SaipleNo.
RB-IIIRB-1VDF019001-PDF019001-DDF019001-NDF019002DF019003DF019004DF019005DF019006
P'. ••3p
ri"^ty
0 •
ar0 ,w«
Ext 'n iExtraDate ;Clean
!10-2B-B5!NO10-28-B5!NO10-2B-B5SNO10-2B-B5!NO10-2B-B5!NO10-2B-85SNO10-28-85!NO10-28-B5!NO10-28-B5!NO10-28-85!NO
11
1i!ii
0 ;t-' '^ 1c !•• ' iW '0 !CD l
11
AliquotNet
Mt.(g)
10.0010.00
.84
.82
.73
.04
.87
.9410.3410.40
PPB TTCDD i 6C/MS Analysis i Pel. Itilnstr. 1
Meas. i DL !ID IDate iTiu J320/322
ND ! NA !FINN4000!10/31/B5!1040 i 1.29ND i 0 .16 !FINN4000!10-31-8511107 ! 1.267.55 !— !FINN4000!10-31-85!1137 ! 0.799.40 1— !FINN4000!10-3l-85112.131 0.77
14.75 !— !FINN4000!10-31-85!1319 ! 0.79ND ! 0.24 !FINN4000!10-31-85!1352 ! 1.05ND 1 0.07 !FINN4000!10-31-85!1423 I 0.32
3.60 1— !FINN4000!10-3l-851l450 ! 0.800.87 !— !FINN4000
ND 1 0 .14
ii! !
1
11
11
11
1i
«i
1
11
FINN400010-31-85il520 ! 0.8210-31-85J1549 1 0.61
! !i i; ;! !
i ii i! !; ;
! 11 1i ii ii ii ii i
on AbundiPPB SL
332/334!Heas.
1.00 ! NS0.81 it.200.80 il.190.810.790.79O.B10.790.800.81
1.201 . 1 7
.18
.22
.18
.18
.15
iii1iiiiiJ
Jrrogate
XAcc 'y
NS1201 1 71 1 71 1 41 1 61211 1 7122120
Integrated Peak Area (or Height) 1* !
320 1 322 ! 257 1 328 1 332 i 334 1 Corentsi 1 ! ! 1 1
20162144
490736566240
10100002848
72617945635796
3704
i;
1568 ! 2272 i 1408 1 1472 i 1472 !NO SPIKES PEASANT CHECK1696 i 2496 1 84624 1161024 !199944 iSPIKED RB
618656 !198080 i167232 1325392 i4062S6 i736984 8231872 !158871 8310256 S3B2032 SDUPLICATE
127907027202255
22390443472
6088
436640 !174560 !345904 !435976 !CLP SPIKE AHT TOO LOM1920 ! 76160 il4BB08 !187536 !562 1 69504 i131968 11624BO !
71520 1126641 !24399216384 !103089 !1918403420 1164764 S315320
1 11 1! !j ;! j! !
1 11 |
i t! !( 11 t
1 (1 t
307944 !240432 !389968 i
!!1i1ii
!1j
iiii
RB = Reagent BlankP = Part ial Scan/Confir tatory AnalysisN = Nat ive TCDD Sp ike /For t i f i ed Field B l a n kD = Dup l i ca t e
FB = Field BlankND -- Not DetectedDL = Detection Lilit
NS = No Spikes Added 0 0 5 1 1 0tCorrected for contribution by native TCDD; 0.91 of i/z 322 subtracted.
FORM B-2. INITIAL CALIBRATION SUWARY
;nstr. Sol. Peak Area (or Height)ID .Date Tune ID
^UKA -l»l-l|25 OWl PL-i-ttoo i(nl?5 >on CO^umo -KrHls U>5Z <LC5^ llnte W CLHnmx» -KniS »»5'70S,ion -ilnte »M6<^2.riyaio Th-ilas »25A Gia.ww -unite mrt CLHnxin'ThTll-r »Mm,CC5^uncmintK ISM CUL^WflHn^ <5i44PC-inMOno-KntIS- lb3SC(L<wuocb -rtn^ nn PC--nn'titt-'jnt^ '^C^n«4om^hhR »Wc^^n4Gttl(P^ ft^ WrwMron "Iln% ao&5 CC2'An nmo-Hms sia^CC/
y ——^;nnt«)D-lln^ 515-1 C^tti!OD •Tinl S J » fC
.
320 322 323 328 332 334MT?b nS4 (l^S 1&S4 l&l&O 22ftDl-»4Dfa ^^?> Nfl Sim H^3l> 54W1asu»fl» 4»tou) Kfl Mft 5toz4 'T6"»fc2!l»»M5B) fiUAfl NA Nft 13fllW 1'BSMa4ni0^n58K) Nft fl252Z 4(,m 5nb3:T5-ni, «<UCT nft SPW nssfc ^uat(»l»W> ai»59,-7l> Nfl NA Allb 4S l»^<aaft3» vu-ftc w NR fci^M^ -MOSDAa-WL HniA? Nfl AIIOt 1>(U(, '?»%^fc^b toit, Nfl Anya TW^ Rb^fc,»O.S 5153 ab '33AH ^20% WStW2rt »9LW) lift ^SSlb fet5l2 T^H*1^l^ 10Hb% K-o-5 «W2> 25^52 2M»>M3ftWD 3TO30 (W Nft L I-Ifc timIHftbTO ni(,l3fl Mft NA -l&W 40blbssafa. TWHZ NA ^si^ io<?^o i ^p.5^tt2 "IZIOM Nfl l5W^ 5«)» "l2Wo>1^ 152b3 NA <tyW 1^2 -1M.-I1
~}VD ICD&b Nfl SlaX) MlH,^ 52HU,lir L lbl20 m5 l S^^ WW -510M
Meas. Mean Meas. Mean • TCDDRF RF RF RF Iscners
»totive Native Surr. Surr. Resoiut.'nsOA'3Q o.<\1~l 2>.H'(.
O.V»b .01 0.^-7 0.^17t.O^ .OZO. b2 .02.l.Ob .02. 0.15Z 0. -7
OAV» .OZ 0.151 0^-1-1l.lt .OZO'W .OZ —1.Ob .OZ 0.<n3 Ofl"l"?0^0 .OZ. 0. 53 O. l ^
OM-7 O.m i .0. 5 1.02- O.W^ 0.1-1-T Q
r ' • O^-T^ 0. 1 l-^ol.(0 1.03.0. ^ l.o^1.0i» f.OZ O.^^ Q^-17o.<\l3 (.02 OW 0.1-77
O.<<-1^ l.OZ O.W 0.<t"l")
——————————-—O.^HO t.oz o.^fa o. -n
0.^10 0. 11 a-5*?»
Solhtion ID Oodea;
PC BBrfonaance check solutionOC1 Cancentxation calibration solution tlOC2 Qoncencratlon calibration solution «2CC3 Oonceptration calibration solution 13CC4 Goncentration calibration solution 14OC5 Oonccn&ratiott calibration solution 15N^» f\o^ •»* p^'ttAV^^o * rdwt be.-texi&aL.
0.2 ng/nl1.0 ng/tal5.0 ng/tal
20.0 no/U.40.0 ng/nl
0^103309
^00^893— < c;
tov: 5/84
000007
FORM B-3. CONTINUING CALIBRATION SUMMARY
Sol.te Time ID 320
Peak Area (or Height)322 323 328 332 334
PTcgS •
RFNative
MeanRF
Native
("teas. MeanRP RF
Surr. Surr.
TCDDIsoroers
Resolut'ns
OW^ ?C ^W8 5^W <^l^
^'^,0^ i^ Y ^^ .^ ,y- • - . 0 > ' > C.«*A- S^ ^ Wk -^^a
^'^1^ pc ^a S^'^^. '^^^aJ - i- y-:-/' /eTe>i4
(M
inoo
Solution ID Codes:
PCCC1OC2CC3CC4CC5
Perfonnance check solutionConcentration calibration solution #1Concentration calibration solution 12Concentration calibration solutionConcentration calibration solution
#3«4
= Concentration calibration solution #5
0.2 ng/mi1.0 no/mi5.0 ng/ml
20.0 ng/tal40.0 ng/TOl
GW^-8W c ^
0:110:S10Rev: 5/84
000008
FORM B-4. TCDD DATA REPORT - PARTIAL SCAN CONFIRMATION
Response Ratios % Relative Abundances:>! (relative to m/e 322)'{ \ 320/322 320/324 257/322 257/259 194/196 160 161 194 196 257 259 320 322 324
. ^.8 3 /.S?9 ^1 /-^ ^ /f.7 ^1 Z^^^^ IOQW
mo0
0
QUALITY CONTROL SUMMARY
Mean Accuracy, Surrogate Measurements: //g_____ No. o£ Data Points: 7^ ^
Accuracy, Fortified/Spike Field blank: ' /7^L*7o _/C?L) /o Sample No. p^ffi^gyl- M
Relative Di££erence(%), Duplicate Analysis: ^c- ' ^"/a _ Sanyle No. Pp-Of^if-fil- Q
^ CWW fiMOiAfir G:} 00^8^5^ ^6P(<c6^ft& S^^TA^T/A'LL'/ 7&£) H>lAj^fwL THf^ 'S^Pt^. c.^
SPlfcfc- /S /V/^0^0 Pf?^- A ^^Z) ^ft^Li Rev: 5/840^10^911
000009
GC/RAo TUNING AND MASS CALIBhATIONDecafluorotrlphenylphosphine (DFTPP)
Case No. 0^ Contractor M^YiWI C Contract No. _J^-
Instrument ID ZJ^ fi- Date _JJ_fJ^J_^_ Time J?ll -
Lab ID PA"r /-/^/ ^fiata Release Authorized By:
m/e ION ABUNDANCE CRITERIA V.RELATIVE ABUNDANCE
51
68
69
70
127
197
198
199
275
365
441
442
443
30.0-60.0%0f mass 198.
less than 2.0% of mass 69
mass 69 relative abundance
less than 2.0% of mass 69
40.0 • 60.0% of mass 198
less than 1.0% of mass 198
base peak. 100% relative abundance
5.0 • 9.0% of mass 198
10.0-30.0%0f mass 198
greater than 1.00% of mass 198
present, but less than mass 443
greater than 40.0% of mass 198
17.0 - 23.0% of mass 442
5'S"-
^/p cW^ Ci^^
/9.VO?. ^
^•^/V/P
f(^7^^n7.zz.n^^?-/57.
G^^i^7.S'-6?'?o
^ .<9o 0^*7.^ C/7-S32
THIS PERFORMANCE TUNE APPLIES TO THE FOLLOWINGSAMPLES, BLANKS AND STANDARDS.
Value in parenthesis is % mass 69.^alue in parenthesis is % mass 442.
SAMPLE ID
D F O I ^ C W l -
LAB ID
^/563
•
DATE OF ANALYSIS
///r/-? •
TIME OF ANALYSIS
/ / € H
nnnnm
FORMV oww KW^a ""
inoo
SECTION III: SAMPLE DATA AND STANDARD DATA CALCULATION
WORKSHEETS
03103313
000011~e tK?S37~<-" ^
INC
c~''-
~)
:)
•
EPA f
Q^OI^GO^
OF<x^oo4
000012f^w^Q^ Q-
............. . . . -. - .. ...... , ..... ' V3/2V34
SAMPLE COMMENTS .
CASE f^O-L^
COMMENTS
li^ Ai J <^^^t^ fl»L^w.J? 0 »Uo Li-
^s"7. ^za i-' J. Aa^<^€4 . n/)u^J ^i<^«J? ^o /OT^A.
^ftho^ JitA- 70 ^7<9 ^77, y«^ M - <^ <^Qf d^cc^h f^.( ,
. V . V 1
(^s AL^h.^ <5^u^<iaA^cA<t- ^ I'S"? / 3 z-Z- ?
3'Z^>/?Z2, ^&^LX fint/'^C^fl. >Uu, AJLD^^JL^A A CL*v-c D S..
~ u '
••J
>
l^u-'t'x-s Z^'7 ""'to . ^z'^- 4o ^c/^- v^ o^i i y^\ i i^t S i VVOAJ^ •tivna^
^^^ ^-'S'7 r^c^l >^M ? e £ ^c) '7'}^ Srcx-n.&. UO^S>J^* 'LI •' llA-lLAJL CL--S.
V^S^S ^O ^—9 ' l-Z. l^^- V^o^i^i-i^L (^) • ^0| y Sc&^s, .
TfMa-ss. '2-. '7 <?(?$-& ik>^ J?lu^^ <; c-/- c- A-^o L^ Sc^-—
OZ C^C^-JL C-Lr^^. U^a^ ^^yAr^^^l. <- ' - S<X tA^<C
(cS.' .c, -72^> ^ 3 2,-I/ MAA <n*<JC <- /fca-^d B ' -Li St-AA^v»-</
^>JJi C< ^^T^c)-^ A^ ^ r^J^^o) u^^L-4Jj<5
Z-'2?'?^ -Tc on
OL'10^514
•
v0
•s—
in00
^
^^,
SAMPLE COMMENTS
CASE 5W
EPA # COMMENTS
J-(V -^A^TA^L-a-^ t^<A^ ^Lr\ a ./L( k^ (-/ (? / (JUC-^t^^6 '
^ A^(^ ^L^- /2^(/o^- ^o PC ^^(^ CC
<^^K - -4- oJUi y^JL^' ^'i A ^Ji f^t^Le i'^Lf\ ^ £Au o(\ t/<A</^C^^^Cu/y^-<L S^tA It^ h^r\. ^-tt. C^ oJ <?<^< -t-^ \^^i
' // \^tfJid^-^-h c^,
(0^. h i^L C(^^v^t^~v\-•^ $'ec*- c.-^c^^, <.-r >S C^c<-4t/
a^ivi f^Jt cP K^»-<-» ( SA- U^^ -tt DFo » 1 o ® 1 •'v 1 n " — " — — - " " >Ji—————a—-"-—""—•'—~~'
.
0^10^315
^ ^ U00013
, 3l ^A/^s^Signature Q^^S^
1^-
^—
^—
in0
0
C („.
IN111AL CAUBRAllOH . PAGE I
QVIWMOCSMW CHECK
Criteria
PC SolutionF(l« 9 Itata/Tl—
551&-iln(l5
0^325510
-Ht-HlS»544
55'i"2--ilnllanil
55^ninns2-2.SO
AREA
320
\
1 1 V
4"»3(,
J^03
i/
ll 1!
c-
\2.3>U
•
. 322'
^
t/
5155&
ICM^/ </K.120
323
n^^^^^~7
r/O
^lbo5
,,„—^
m5
32B
70g-(•Wi:
33^•.ti-^Juu !•
nmc.
H>553
332
Al1n*—P
ll2fc0
^tW^
15162
»,
^114
334
/
^
1^02( ^tOHSI
^1
5MfcO(
*-'510^
*
m322
0.61
10.81
\/
0.10^^^^^^^^^^
O.T?
0.93
0.1-1
m322
0.01
10.2
o.(8 t
NO
0.15
0.11
212334
O.tl
10.8?
^
0.80
O.-lt
0^5
0.1'?
.
PMkHalght
^
1 4 3^
*^»/
in
tZ3
ValleyHoi t
^
5t»'
n»»•1 1<-/
4
PercentValley
!»
3. yc -
«3.%
zn.
3.A«/o
0 0 5 1 1 8
S!S
^si/* en
^81 <M
i»s^
^1^s^SSQi1
S8§^ao"»
,
ss
s0
0
0Al
•
m<MAl
•
—<.
35
XS^/
5^
Hw •
0 Z
r-CO000/•sS
(1c^0i\n<Q\n^<a-i
^SL
S?^-^
Si-a-<r-
^a0-i-r~^-PO
v»<o
v»-^0-
r»-»—}0t:0
l0^
^000«
^•i
(—-{^£en
"-7-
^^2<\/\^N
A
^a^S^a-A-
J^
(\i
-A'»-
^
oa—<c
^cJ
UT—
.—r-
•
ino0
00
00
15
o^o
oJim
c' ^-
ROUTINE CALIBKAHON CALCULA110N UURKSOEEt
Solution File »
<a^\PC lo/sil^T
OW4,1-17.
CC»1 /o/s.)^"
1 0 1 ^
AREA25»
X
nuz
320
w^
^6nZ
322
51 ^
5'KSi?
323
13^
X
328
<ol(^
32.108
332
W^O
^0<}&40
334
l^too
-Z5-fc57fe
320322
0.61
1Q.Q1
D.^l
X
332*
334
0.61
1O.B7
0^1,
X
PercentValley
$251
W.X
S/N25»
^2.5
X
Z5~
S/N322
©•»
X
3^
25» •t '
322
0.2
0.4S
X •
•
<???:
Perfonnance Check Surrogate RF • | • 0 |
Initial Calibration RF • 0^"1" ]
( 1 - ^ ) « 1 0 0 - ^7.W
(must be < 10)
0000»-*CD
CC 11 Native RF •
Initial Calibration RF -
( I - K ) x 100 -RF
o-w( • o z-
3 - 1 y. (must be < 10)
0 0 5 1 2 0
0
ROUTINE CALIBKA110N CALCULA1ION UURKStlEEl
Solution File f
(ffl^PC m-Z-
/^//^
CC 1\
AREA251
X
320
^/<^0
322
S^lp^
323
|oio4
x
328
&o3^
332
13^3r
334
/Wtd
320322
0.6)
0.87
^--77
X
332*
334
0.6?
0.87
0-&0
X
PercentValley
$251
6.Z^
X
S/M257
$2.5
X
-
S/N322
<. 1°
X
25? •t •
322
0.2
0.45 :
X •
«
Performance Check Surrogate RF • /• °
Initial Calibration RF • - 7 ^ 7
( 1 - K ) x 100-^<?7^RF
(must be < 10)
CCfl
o o0 r.?o ^<=>°^^•sl
Native RF
Initial Calibration RF
( 1 - VL } x 100 -RF
X(must be < 10)
0 0 5 1 2 1
SAMPLE CONCEN1HA1ION CALCULAUON MORKSHEE1
CASE 9 5t>1^ DATA Project ^ie ANALYSIS 2 STi T C PO
EPA 1
R8-1
(^6-2^
OPoi^cmf-p
^PO^trOl-O
Df-OI^^I-^
pFOI^OO ?
(7|?(9)'?00^
^/5^^
OF Ol^fioC
P^ 0 ' 1 /,
FILE •
(e\^~b
(?/?46. !-(<
^ 1^
^ 1 ^ ^
^ 1 ^ ?
( 0 » - ? ^
^ l^V
(J>W\
(P \<^^
320 3U ^+ X . Q + * + R F t H t = Cone.
322 ls 551
^l*-!^
^MS<?^
/305i^
2,?^6^0
,Z^
'731^
^;i^^.
^z^Wz
^0
S'0
^
.TO
^
5-0
^
^0
So
A/0
<(ploz^
^3/^/y
&9218«
ni^oiwi
^%iSS 1^
H327-T1
705M
^ ,
1-01-
/ 01^
I^Z.
1-0 Z-
/. & z/
/ '^7-
1-02,
/ •0»
1 - O Z -
^ ^^10
w^z
^•73
^•^^
. pwib-^f
1 6 - ^ O
.
——-
——
7- 5~jT ^
^ ^6? •"
/^^ ^
^P
^
3- ^ ^
^.n^
Jcnn"^p Ll
^ 1 /»——————^
EstimatedKaxinunConcentration
/^f-
•^^ ^
/
/
/
0.10
0.0^
y
^?
EstimatedDeterminedLimitation
/^-^9. f •^ • /^rV ' f Q (--/ <
«—.
——
——
0^
o'o^
D-^
Q,; is usually 50
^ * RF is either (1) the overall mean from the initial calibration if BSD <10l, or(2) the mean RF at the concentration closest to the sample.
0f.,'^8 0 0 5 1 2 2
?11
0X4JX11H*J3
•»•
'fe•»•
% * S
en
ro
•»•V
c?"
Rn>u.
gUJ
VSs.
^AS0^^l~^f>
fCO
<:
0\Q\0\0N<Q^<Q
Hw>i'&»lf\
e•3-
rA-a^"00
^s-
r-•sS
r<
(QQd
r^s,
•N.
s^
*0
^
^\<<^
T<>«»<^«-r*-(-<r•S>c
^(?
£rs>t^p
^
^\nr»s90-.000-
0u.FN
V
^^
'•S0<
«»
<io^^••s.
Q(S»
Y^00
u»rP-u~oc<»(M!•*
0-
'A
Sr~daW»^At^
<^c:§
<»•
Q4. >
.
Q\fs(^f\
^
J
•f^>
r~<rT^r-<r
S-aoisr"a§-i—r~^3J?<>-
«Uk- -^•$^^0
^^9
^.
^*
^5-
0«>
t>r^-rr-T'
srr?rr'
f^^<
Q
C-
00
c^^0Q<3-
Q'.\.
^£?(
. ^0°
<s~<<r<r.
is^
(~0°
<rn>n-y^ vI•J<3-
<-
^-T^<o--3
<I-
P"
^<Str0^\
1^.
'Q\^0>^•^
0•s.'^^<^T
-^f^<»-
•s3(Y
\'»
-"<
'QV«4
s?
^0°
^Q
-3-0«<yQu.
^-0\.
^^^0•^-
^«Q
•
^0^-1^M
~
1^(»-
<»»
f^
-5,»r'yot<Nis•y'3\^0Q<3-
0U.
Qf<k^-0-s.
^ ^^^-^^*
3-
r»f^^?r\->>%r^wt^0°•^§<3~
S
.
•*
mCMinoo
iVI
$VI
5
03103^1
00
00
19
a •">
fi. " C 't
r;(y
T—
—l-S
J—
——
.^.frJ
C
"
^
u
u
5
?
0 0
f^
0 ^
o
tu
r~-
v»
v^
'••a
<(»
i 1k
<«
» ^
4k
u>
o
in
•»
(5
N
•J
:
^1 ^
,,,
«
II ?0l
f°l
?°1
•"
I
70
1
J\
ot
•nl
-n|
•*il •
n;
-n|
i)i
^5 r
9
0 P
",
— -0 0
-0
-°c
\
^oti'^i
.4\\
x^i^
's/
50
30
30
»»
,,,,_
_^
s a
a a
a^p
^ -^
oo
^ ^
' ^^ o
-^^ -
c^>
^
g
+
I -
•
»^-»
^ 4
>. 0^
1
-^ ^
^
^
W^^^y
^^
^
^^
0^
-
0
^
m § L^ fe 00 § 8 t^ J-
00 0 • 0 M Ln ^ 0
•^ -<- *a 5 ^ 0 ( t
^ S> 0 • 0 Ln
0 ID 00 -0
<«>
^ J^
ffi
^A ^» ^ ^ t- i S\ • 0 « M
0 <T
ro § OQ (?"
N &0
Ln^ S
^
l? 3 ( 0
,
0 ^0
(A LH
-• § 0^ ^ (ft ^ -(-
0 c. IA ^
u*
0 « -0 ~o
IA
m ^ (A)
^ g g0
OJ r •a X 0 • 0 M Ul
—
•
IJt
U> J J 1 Oi
X a F p o0
0 • 0 Ul
p .A)
00
€4
( (/
-1 (D c § in !? 0 • N
» 0 6-
fs) ff -J 4> 3 M y ^ a
0 -C
•J 0 -6 J
O 0
1
- .
f\ & -4 N i -0 -o
t5
s ? m
0 JS ~A -0
•
Ut
U^ U» >.»
Is'
Cn ?' ^ 0 iV Q 0 • 0 fM Ul
« 0 00
* Cn l
-A b» S 5 ti ^ 2 oD a • 0 U
t
0 -» <-
N
u 0^ u» x oO e- 6 0 y 0° ^ 0 • (0
— 0 S~
N
g J W f 3 3 c- 3 -c 3 r*
J
0 /& o0 <r
-
•<• r
s
^ 2-
-J ^ c- ^> -*; m 0 Jft
-C 0
<^«
•*»
•-•
?n ^ ?) 'n
u
uM
<• M
M
0
•
U
Uu
<*• u
•
M
K
o
ax |
*• •
•^
30 •n
- '4 C
30
^€
^? r
,?(_
.' n
1•r",
c/
1^
^ 'ni
\ r0
05
12
4
SURROGATE RF
C^ FILE #
1 55 'S
2 ^•75
3 55-1^
1 S'5^7
2 55-1°1
3 55-1^
i .5-581
2 5'5'g^
3 ^535'
332 Q328" * * x " • RF
(0.009 X 322) 334 Q
•
55^
ay-14^
im.0!
^147
l^^o^5-I3M3'
sw15347
474^5 .
'25'SM
HH^z.
fo-ssaM
13<<4Z4-
n^W
^0551<»
|4oo^
13.0710Z^^Z
16.67
8.33
5
16.67
8.33
5
16.67
8.33
5
/ZP
0. <o
o.^s ^
O.^SZ
0.^^?^
0.^53
0.^ -13
O.W
o.mo.W
CC ^1 »/ Mean iF - Gq^1 Y RSO • Q. \ */•
CCi»2 Mean RF - Q<U»( • RSO - t.^Td
CC*3 Mean RF - O.TT4 V KSO - Z.3%
Mean RF' . 0.^7 ^ /^ (&AH^£= O.Q-l^
RSO RF' - I'^^o
/.^75-
fc^
^^'\\"^^ ^^O^IO;^^
000021
l\
>
a3?ft515
^ 1
3
u.
^
§
(f ^
-U
5;
^
5»<y
^
t^ort^^1VN<x\
r<^UJ
$
'STSt
^>amkkss15§k^
5u>01aUJ
U.
^k
msQ^u1
^Q
4('
-J^
°1U
.
1
U^
Ujl
5 U
&£
£g
Sa
— <
<£
SS
°5
u
-I
-i
-3§ ffl«
yj
Z •M
-^•* CT^i|
UJ
4
S5|
w «|
UJI 1
^
^
^<nac^
^^
cr s ^^
^0^J^6^)s -0<r-^^-
.
0V)
^[<fe:
1^
^iy\^fa1^C^
0-
~'"T
——
fcQ
0-
M§£c\
—^
—»»
r€^^-
h§8
'S
^v^<£>^^\
t>.^^US.
,0
•^/^^
i^oo0^OS0-
i
-
fc^^0
0-
m§0^
i
rf-
>-
<3~
^<^00Os.
t0.
i
•
<"?•^00»
s
^3
10
^
^
——
>
—^
—^>
—^
—^
—^>
- ^^^\o§O
s.
1S
-M
S<yi^J~s»
(Min
<3-
^^^^
^
\
^LW
WQ
0
00
02
2
SECTION IV: RAW DATA PACKAGE
/ "'\0
0 0310:'S^5
000023
ww^wr
MIDtlftSS CHROMATOGRW DATAi 5570 •I SCANS 779 TO 84597/17/85 9x32x99 CflLIi 5566 «5SAMPLEi DIOXIN COLUW PERFORWHCE CHECK 1-991 2UL FINH4999 JKCOWS.» 69H 5P2339 79/4>20M15>24W4EPARAHGEi G 1, 845 LMELi H 2.19.9 CRMNi A 9, 1.9 J 9 BASE« U 28, 3
000
•> -'/
5/ K loo • 5.4Yo'•H^
319.596323.597
0'3 \
f\ "
O'T
M». -?
V.
./A
- ^
C3C\j0000
323.897i 0.590
838 SCAN28i47 TIME
in o
^
o ^
<i
*J)
n
» ^
.^00
«n ^
sr
n0 i
P ^
°"
.
^»
^
^L
o-y
C
O
2^
0y
co
_
00
fO
?
w
r r
00
fO
t
r r
S
•'e
^ '
^
fe
u.
lii
^3
• Js
;$sSg
lg|S
.^S
ss
08"
^i3."S -
<£•$
MIDMASS CHROMATOGRAMS DATAi 5579 »1 SCANS 789 TO 83997/17/85 9l32s99 CALIi 5566 »5SAMPLES DIOXIH COLUMN PERFORMANCE CHECK 1-991 2UL FINH4999 JKCONOS.i 69n SP2339 79/4>299815>249«4EPARAHGEi G 1. 845 LABELi H 2,10.9 QUAHl A 4, 4.0 J 9 BASEi U 29, 3
11596.
0r-3CT."J0^1'0
00(0Q00
11936.
332.9991 9.599
13994.
334.199i 9.599
T799
19»47819
52
T829
29*32839 SCAN
29i47 TIME
r^
620000,
"^A IP
<S
N -
:
"^S
;
^B
l •
s^'
P^i
!g|
f: ^^
CJ
<•
g
•
9 n
g ^ a
;
(•>
0310^932
00
00
30
n^S00
^o®s^°r; oQ
1968.
320.096i e.see
2240.
322.896i 0.560
818
0 O^T 3 5
1829 SCAH29i32 TIME
€0
1
J
\DCO0000
5520.
329.9961 9.599
0.•!
»»»0(*:
PLJCO
05^r<rC?t
MIOmSS CHROMATOGRAM DATfli 5S82 •808 SCANS 775 TO 82587/17/85 17i17(88 CALIi 5566 »5SAWLEi DIOXIN COUJMH PERFORMANCE 1-891 2UL FINH4888 BRDCONDS.i 68H SP2338 78/4>288615>248MEPARANGEi G 799, 881 LABELi H I* 5.8 WMi A ^^J'5 J ° BASEt U 29, 3
1838.1685.
323
r\
MIDWtSS CHROMATOGRAM87/17/85 17sl7x0e
DATAl 5582 »1CALIt 5566 «5
SCANS 775 TO 825
SAMPLES DIOKIH COLUMN PERFORMANCE 1-091 2UL FIW44008 BRDCONDS.i 60t1 SP2338 79/4>2ee(15>24W4EPARANGEi G 1, 858 LABELt H 2*10.0 QUANt A 8,2.0 J 0 BASEi U 20, 3
7255.
""'"I 10^*. oo<\-- 11993'
hIDMASS CHROMATOGRflMS DATfti 3582 «888 SCftHS 775 TO 82507/17/85 17i17(98 CfUl 5566 •5SAMPLEi DIOXIH COLUMN PERFORMWCE 1-091 2UL nWWW BROCONDS.i 69n SP2338 7B/4>29M15>24W4EPARmGEi G 799, 881 LABELt H 2,18.9 QUAHl A 1 , 4 . 9 J 9 BCtSEl U 29, 3
14672.
COCO0000
15184.
332.9991 9.599
109.8-1
334 ,
60 •-f.' C^^ cc &LA' •*ca ^>*.•> i»0
r- r',n -:./
78919s 32
1—————T"
16969.
334.199i 9.599
799 899 81819»47 29»92 /. „ _ . 29il7
- 0 0 5 1 4 2
829 SCAN28i32 TIME
Miomss cHRomTOGpm DATA« 5539 »8e8 SCANS 775 TO 92567/17/85 22x58i99 CALIl 5566 »3SWLE» DIOXIH COLUMH PERFORWHCE CHECK 1-991 2UL FINH4999 BROCONDS.i 60)1 SP2339 7B/4>299tl5>249C4EPARANGES G 779, 803 UfiELi H 2,10.9 WMi A 8, 3.9 J 9 BASEi U 29, 3
0TT000<L.,
. )
9272.
329.9961 9.599
-T——————r
79919i47
1899
29l 92
00 0 5
I '819
1 4T7
" - •r1 •"•"""•829
29(32SCANTIME
©
MIDMASS CHROtlATOGRAH DATAi 5569 189997/17/85 22x50199 CALIi 5566 «5SAMPLES 01WW COLUm PERFORIWHCE CHECK 1-991 2UL FINH4999 BRDCOWS. i 601 5P2339 79/4>2B9815>249UEPARAHGEi G 779. 993 UffiELi N 2.19.9 QUANi A 16, 2.7 J 9 BASEi
SCANS 775 TO 925
:^i
~
-n
<n
00
00
42
u>- s'
^3^ ^
-+-
^ ^ ~t.
L^^
^ \\ ^ -< -^
ss1
82
;
SPi ^ 0 0 VJ
1—
:>
"^C
B.
cag
•
fl'0
00
04
4
MIOmSS CHROMATOGRAM DATA: 6171 «1 SCANS 750 TO 84910/31/85 9:45:00 CALI: 6170 »5SAMPLE: DIOXIN COLUMN PERFORMANCE CHECK 1-093 2UL FINN4000 MHCONDS.; 60M SP2330 70/4>200@15>240@4EPARANGE: G 1, 849 LABEL: N 2.10.0 QUAN: A 0. 1.0 J 0 BASE: U 20. 3
800I 806
kO^00
6438§
319.596323.597
SCANTIME
MIDMAS5 CHROMATOGRAMS DATA; 6171 #1 SCANS 775 TO 82510/31/85 9:45:00 CALI; 6170 #5SAMPLEt DIOXIN COLUMN PERFORMANCE CHECK 1-093 2UL FINN4000 MHCONDS.; 60M SP2330 70/4>200ei5>240fi4EPA
CD^T1
0000RANGE: G 798. 802 LABEL; N 2,10.0 QUANi A 4, 4.0 J 0 BASE: U 20, 3
80026812.44428.
320.096± 0.500
322.096i 0.500
27168.
32384.
SCANTIME
MIDMASS CHROMATOGRAM DATA; 6171 #110/31/85 9:45:00 CALI; 6170 »5SAMPLE! DIOXIN COLUMN PERFORMANCE CHECK 1-093 2UL FINN4000 MHCONDS.; 60M SP2330 70/4>200815>240@4EPARANGE: G 798, 802 LABEL; N 2,10.0 QUANi A 4, 4.0 J 0 BASE: U 20,
SCANS 775 TO 825
MIDMASS CHROMATOGRAMS DATA: 6171 #1 SCANS 775 TO 82510/31/85 9:45;00 CALI; 6170 #5SAMPLE; DIOXIN COLUMN PERFORMANCE CHECK 1-093 2UL FINN4000 MHCONDS.; 60M SP2330 70/4>200@15>240@4EPARANGE: G 798, 802 LABELi N 2,10.0 QUAN: A 4, 4.0 J 0 BASEi U 20, 3
79928229. , ., ,-
,,.,- 61168. ^^^ /73*' '5/. //^< - ^/^s ^ r~\ J-——-——— = /' <y/
CO•vf
0000
5715.
328.0981 0.500
16666.
332.0991 0.500
19738.
334.100i 0.500
SCANTIME
MIDMASS CHROMATOGRAM DATA; 6183 #1 SCANS 750 TO 85010/31/85 17;22:00 CALI: 6170 #5SAMPLE: DIOXIN COLUMN PERFORMANCE CHECK 1-093 2UL FINN4000 BRDCONDS.; 60M SP2330 70/4>200@15>24084EPARANGE; G 1, 850 LABELS N 2/19.0 QUANi A 0, 1.0 J 0 BASEi U 20/ 3
76018:57
78019:27
820
0 0 5 1 0
<73•00
61952°
5"-.z 7.
319.596323.597
833
84020:57
SCANTIME
MIOMASS CHROMATOGRAMS DATA: 6183 #110/31/85 17:22:00 CALI: 6170 #5SAMPLE: DIOXIN COLUMN PERFORMANCE CHECK 1-093 2UL PINN4000 BRDCONDS.i 60M SP2330 70/4>200815>24064EPA
SCANS 775 TO 825
RANGE: G 798. 800 LABEL: N 2,10.0 QUAN: A 4. 4.0 J 0 BASE: U 20.79924776.
3
81078019:27
79019:42
80019:57
0o o s i ^ y
0
82020:27
MIDMASS CHROMATOGRAM DATA: 6183 #1 SCANS 775 TO 82510/31/85 17;22s00 CALI: 6170 #5SAMPLES DIOXIN COLUMN PERFORMANCE CHECK 1-093 2UL FINN4000 BRDCONDS.s 60M SP2330 70/4>200815>240@4EPARANGES G 798, 800 LABEL: N 2,10.0 QUAN: A 4, 2.0 J 0 BASEi U 20, 3
5648.10704.
1000006176.
323.097i 0.500
78019:27
79019:42
/~'~
80019:57
0
810 82920:270 0 5 1 ^
0
SCANTIME
SAMPLE; DIOXIN COLUMN PERFORMANCE CHECK 1-093 2UL FINN4000 BRD
29.5-1
328
77561.
83.7-1
332
100.0-1
334
00 3f •' c
^ s-c ^c- g 780 790S ^ 19:27 19:42k&
, ' ' \,
r
MIDMASS CHROMATOGRAMS DATA:10/31/85 17:22:00 CALI;
CONDS.; 60M SP2330 70/4>200@15>24084EPARANGE: G 798. 800 LABEL: N 2,10.0 QUAN:
l ' I '
>
5^60
Z.9^7/2.
/-^ / \
^7^D~] / ^1^ \j f / ^ ^ j / fc)~17[ j \
±27'- o^o334'
^ZiW-W^Z
i • i •
334.100i 0.500
1 ' 1 '—r"
6183 #1 SCANS 775 TO 8256170 #5
A 2, 4.0 J 0 BASE: U 20. 3799
26888.
50?92- <^^-WZ--
/ \ 6"^ -W
798
130832.
A .
i 0.500
798 ' ' '92982.163880.
1———Jjs^—————,——————^——————,——
800 81019:57 QOSI2?^
.0 0
CVJ100000
27520.
328.998t 0.500
•
78080.
332.099
'
93312.
1 '820 SCAN
20:27 TIME
y s
9 ^
^ ^
M
• O
f •
^j
•
S-M
«
i i
T
ii
i"
?'
ii
i"
D^
,
?3-
y8 S2-
•M
•
^•B
-^
s2
0
•0 U
l
-ttflt
t.
^5
-J
Sa.
s-
'
^s-l
~)
^
""a
"'»
w>^
G^n
Lm-v
^ ^
^
N
6tf
U
1
V- V
V
^. iL
ftS
if
\—
<vi
ON
(n
a
>«
•
®
^i
M
SS
S8
^ SJ
S 5
S3
8
00
0053
^ .
\ )
<A ^
/
^ ^
^
-
»
N
• •}
~".
•
^"~
^i§
gL^—
—
•
/
.
) i ) >
^
) \ r~
'^•^
•^
r^ j-
\
S
.1
°}
-»
+
/ ^
-T1
ip
S I?
§C
C
^
H
""
\
CP
.
§:—
S
( ri
^ -c
) tf ^
-&
/ V
Q
^'
*•
—
' 0 V
i>
1§
PI
m ui
i^ "
5k
""^
\ S
SfS
y ^p
iS
^lf
iX^
wm
w &
J
S
^ -
s^
i 1
/
3
-
P$
2"
J'
^8=2
y?
t 'ig
^ ^
^2
8^
^s-»
• 5o
( *
sX
H
^
g^
i1
*=•"
" ll
3
^^
- ^g
7—
^^
^?
^ |
9
^
f
^5
(
u
8
^>
^
- S
<,
-=L
»
g1
i^
°Y
u
^
v
g
. c
\
^
) S
MIDMASS CHROMATOGRAH DATAi 3571 •I SCANS 779 TO 83887/17/83 leilliee CALIi 3566 »5S(WLE« DIOKIH SENSITIVITY CHECK CC«1 1-085 2UL FI(*44898 JKCOOS.i ew SP2398 78/4>208tl5>248C4EPARAHGEi G 1, See LABEL) H I* 7.0 OUANt A 7_A.e J 0 BASEl U 20, 3
3999.5?7' ^^3^0.001 =
\J
I ^^ K/ 0? ^
0)• <='
nc?sr'i0
^^®
MIOMASS CHROMATOGRWS DATAi 5571 tl SCANS 770 TO 83087/17/85 leilliM CALIi 5566 •5SAMPLEi DIOXIH SENSITIUITY CHECK CCtI 1-885 2UL FIHH4888 JKCONDS.l 6811 SP2338 78/4>29W15>24et4EPftRANGEi G L 98B UflELl H 1, 7.8 QUAHl A .L.4.8 J 8 BASEl U 29, 3
28867.43136.
J
C Jf J
C >
21128.
332.899t 8.588
29928.
334.188i 8.588
T788
19l32
T828
28i32798
19(47
T818
OO2?11!^
^838 SCAN28(47 TIME
MIDMAS10/31/SAMPLECONDS.RANGES
0-
n
5 CHROMATOGRA85 10:13109s DIOXIN CALI« 60M SP2330G 1, 845
^w'6^
H(. (ft ^l Co
^<m')v^1 •<5^ /
78619:27
115
BRATION CHECK I-(70/4>200@15>240e<LABEL: N 2,10.9
^0
TV'- ?•
r
79019:42
T "
^
Z i?f
DATA;CALI:
995 2ULtEPA
QUAN:
^P
61726170FIM
A
^H
/
/
»1«5
N4000 m
4, 4.0 J 07999402.17212.
h799
22930.40272.
k799
30440.51856.
——1——800
19:57
n
s
SCANS 775
BASE: U 20.
3^/^
3^0-»
^
"—r^-——i8^
0 0 5 1 6
TO 825
3
/
z^
±
3?
10^2
0
,(= ^/?>?
= r — — — - ^ — — — | — — — —
82020:27
- c
U f.^
S*
c.
1
t
0
^ CD^ »0^ 05 0) 0^ 0
9824.
257.077: 0.500
23200.
320.096k 0.500
30656.
322.096: 0.500
SCANTIME
•*-<
S®^f.^0
12.2-1
328
MIDMASS CHROMATOGRAMS DATA; 6172 «1 SCANS 775 TO 82510/31/85 10213!00 CALI: 6170 #5SAMPLE: DIOXIH CALIBRATION CHECK 1-095 2UL FINN4000 WCONDS.i 60n SP2338 70/4>200@15>240@4EPARANGEl G 1, 845 LABELl N 2,10.0 QUAHl A 2, 8.0 J 0 BASEi U 20, 3
79918544.32208.
^Vi« / 1
18976.
328.098t 0.500
76.5- 118912.
332 332.099± 0.500
M'^ ^+33^rfifi21(ff
334
155392.
334.100t 0.500
78019:27
79019:42 0 0 5 1 820
20:27SCANTIME
864.
257.077± 0.509
704.
329.096± 0.500
416.
322.0961 0.500
80000.
332.099i 0.500
-I815 SCAN
20:19 TIME
; \\J c^MIDMASS CNROMATOGRAMS DATA: 6174 #1 SCANS 785 TO 815 K. ^10/31/85 11:07:00 CALIt 6170 «5 fe' ^ ^SAMPLE! DIOXIN RB-IU CASE»5028 2UL FINN4000 MH ^ CD ^CONDS.i 60MSP2330 70/4>200815>24084EPA ^ 0 < i s
RANGES G 1. 850 LABELS N 2,10.9 QUANs A 4, 4.0 J 0 BASEs U 20, 3 ^ 0 ^797 ^ 0
46802. w C)
53.4-j 84^24' 47296.
328 / \ 328.098\ ± 0.500
; 797; 79769.; 90.3-j 16^024. ggggg^
; 332 / \ 332.099; ~ . / \ ± 0.500
! 796< 88183.\ 100.0-1 199944^ gg57g^
; 334 / \ 334.100\ * 0-500
785 790 795 800 Q Q 5 805. i. 810 815 SCAN19;34 19:42 19:49 19:57 '20:04-' 20:12 20:19 TIME
I /^ n '•"^
MIDMASS CHROMATOGRAM DATA; 6175 #1 SCANS 775 TO 82518/31/85 11:37100 CALI: 6170 «5SAMPLE! DIOXIH SOIL EXTRACT»DF01900l CASE«5028 2UL FINN4000 MHCOHDS.i 6011 SP2330 70/4>200ai5>240(»4EPARANGE! G 796, 799 LABELi N 2/10.0 QUAHs A 2,16.0 J 0 BASEi U 20, 3QUAHs A 2,16.0 J
79893018.198080.
(p•I-'cpc/S'*'<&
C^CO0000
97664.
(I) 53^e- Ctr ^^e^dc i<> IM\^J.^'b^e-'-^^
oC -ft-^ '^^-^^.1.&-TCOD
<;Z~) Z-^li ^>2-c:> c>^- 3'2-Z- VK^iy^i -&<', Siw^^a^t-b^i^-
(5) Z5'7i 3^0 ov»-<fi. ^ZZ o^c- ^&'1 o-l?<^^
Z.6 -H^^e^ 4 -e. \3a^V-tWirx-v^()L 1/M'i^C-
^ ^wJLc^^e/ o^ ^]z 2^ - > VK/^ 5Z^ ^ 3Z7oo^Jk. <ofr-^wt<>^_ zoy, o^^ i^^y^
(g) A<b- <to^<- o^ 3w \-o 37,2- ~- 7^ %
iyk .i-> W^"^- (''10/& " ^ %7% 257.077
1 0^500
82020:27
SCANTIME
{ } n
n
00
231424.
329.096± 0.500
295424.
322.8961 0.500
SCANTIME
MIDMASS CHROMATOG10/31/85 11:37:80SAMPLE; DIOXIN SOCOHDS.: 60M SP233RANGE: G 796, 799
78019:27
W
II8
79019:42
WS
- EXTRA(70/4>2(LABEL:
CT(39(N
IDF019001>15>240@42,10.0
\'"^
-1———
DATA: 6175 ftlCALI; 6170 «5CASE»5028 2UL FIM
£PAQUAH: A 2, 8.0 J
79881056.172800.
797157547.325392.
A,797
198352.406256.
A800 00519:57 vr^
440G
0
SCANS
)0 MH
BASE: U
32^'&
77
20,
^Jt
1 t
5 TO
3
J^
^——
2
825
?- ^ 7Z 2
82020:27
i^c
Leccft'c;
?<3
J
?-
±
t
t
CO0000
83072.
328.0980.500
159744.
332.0990.500
200704.
334.1000.500
SCANTIME
0 r\
10CO0000
133120.JA«-^<^a^^ <^oWK—
( p ^(uAirv^, Ca-C 5av^\e, e,tfY lir e . t\ UJ;^-^
2> s^c^A-s o^ -A^e- '^n.-2,?,-?.% TCOO
) Z-5^7, 37-0 tf^~<ft_ 3"2-2- ^ay;wNi?_e- 5in\i^l+a^&odsl.
g> Z?7, ?Z-0<^^cJt 3'2-Z o^e- oo&t\ a/^^<^.
'Z^S 4-1»>^<'-S 'HS.&- \)»c^-^"<>-^^(t- Y^O'lSC.
Q) /^u^A^^ ^ ^-z- 2.$7 +o "^^2- ^ S^/o
(Jk,i ^a^e-L^ Z0% o^>~A 45%
Ptte——<Ao^<. o-? '7?, 3ZO +t> ^-Z- 32.2- ^ '717o
^»^U ' W^fc^^^yo a^A^7%
257.077± 0.500
SCANTIME
11IDMASS CHROMATOGRAMS DATA: 6176 »1 SCANS 775 TO 82510/31/85 12;13;00 CALIs 6170 »5SAMPLEt DIOXIN SOIL EXTRACT#DF019001-0 CASE#5028 2UL FINN4000 mCONDS.:.60M SP2330 70/4>200815>24084EPARANGE; G 798, 800 LABELS N 2,10.0 QUANt A 2,16.0 J 0 BASE; U 20, 3
799287867.566240.
7 3 Gf^^y'^o^ -- ^ ? ^>
CDCD0000
293376.
320.096i 0.500
350720.
322.096i 0.500
78019:27
79019:42
89019:57
n810
j^A^I '20012820
20:27SCANTIME
MIDMASS CHROMATOGRAMS DATAi 6176 ftl SCANS 775 TO 82518/31/85 12:13189 CALI: 6178 #5SAMPLE; DIOXIH SOIL EXTRACT»OF019001-0 CASE#5028 2UL FINN4888 MHCONDS.i 68M SP2338 78/4>288615>24864EPARANGE; G 798, 888 LABELi N 2,18.8 QUANs A 2,16.8 J 8 BASEs U 28, 3
79871142.165504.
J l ^T.S'C''^^-1'0^^^
f3Li0D00PId
J> SCD §300
73856.
328.0981 0.590
163840.
332.899i 8.509
194048.
334.1091 0.500
78019:27
79019:42
80919:57
n0 0 ? 1 7
81030:12
82020:27
SCANTIME
78.0-1
MIDMASS CHROMATOGRAMS DATA; 6177 #110/31/85 13:19:09 CALI: 6170 #5SAMPLE: DICKON SOIL D<TRACT#DF019001-S CASE»5028 2UL FINN4000 MHCONDS.: 60M SP2330 70/4>200ei5>24084EPARANGE: G 798, 809 LABEL: N 2,10.0 QUAH: A 2/16.0 J 0 BASE: U 20,
799198304.436640.
SCANS 775 TO 825J
\ - 1 1
00CD0000
/ )
//) ^? 7/7^» =
^l) ^ia/SZ^.-
I V ) ^ > Z &-
"^. -s- /^^/.^^ ^ 205568;
^
257.077± 0.500
479744.
320.096i 0.500
.0-, in^io 4.oc><\<, DiT^
78019:27
T790
19:42
n
799607072.1279070.
81000517^ 1 2
82020:27
615424.
322.096i 0.500
SCANTIME
MIDMASS CHROMATOGRAMS DATA; 6177 «1 SCANS 775 TO 82510/31/85 13;19;08 CALI; 6178 #5SAMPLE: DIOXIN SOIL EXTRACT»DF819001-S CASE»5828 2UL FINH4888 MHCOMDS.i 6811 SP2338 78/4>288615>24884EPARANGE; G 798, 888 LABEL; N 2.18.8 QUAN; A 2. 8.8 J 8 BASE; U 20, 3
79985248.
^J?72' ^Z« c^JtcJ^^^ n^^t^O
^ ? /0 '"7,
?/ r /'/t*
^ ~-. 3&/ '" 10
/ »
78819:27
79819:42
8180 0 5 1 pe^
T828
28:27
i.'ac^r jc><:>
w ^0 0000
87688.
328.8981 8.588
162848.
332.8991 8.588
285568.
334.188i 0.588
SCANTIME
4-i
i
6-j
?
0-j
719
MIDMASS CHROMATOGRAMS DATA; 6178 #1 SCANS 785 TO 815 1 18/31/85 13:52:00 CALI: 6170 »5 . f:SAMPLE: DIOXIN SOIL EXTRACT»DF019002 CASE#5028 2UL FINN4000 MH TH nCONDS.i 60M SP2330 70/4>200ei5>24084EPA L raRANGE: G 1/850 LABEL: N 2,10.0 QUAN: A 2, 4.0 J 0 BASE: U 20, 3 Q ^
798 0 c43165. 0 ®76!60' 43776.
/ \ 328.098/ \ ± 0.500
79766020.148/308. 66560.
/ \ 332.099/ \ ± 0.500
79793928.187536' 94336.
/ \ 334.100/ \ ± 0.500
35 790 795 800 805 810 815 SCAN:34 19:42 19:49 19:57 Q Q 5 V^5 20:12 20:19 TIME
nC '
MIDMASS CHROMATOGRAMS DATA; 6179 »1 SCANS 785 TO 81510/31/85 14:23800 CALI: 6170 #5SAMPLES DIOXIH SOIL EXTRACT»DF019003 CASE»5028 2UL FINH4000 WCOMDS.i 60M SP2330 70/4>2e0815>240@4EPARANGE; G 1, 859 LABELi N 2,10.0 QUANi A 2/ 4.0 J 0 BASEi U 20, 3
79833067.
3 69504.
l-i
0-1
719
79870926.131968.
A 332.S1 0."
79880603.162480.
/V,i5 790 795 800 805 810;34 19s42 19; 49 19; 57 Q Q 520:0 -] 20:12
<i
CO ;r- <o <0 '0 ^0
3366
328. (± 0.1
716(
' ' 1
8146
334.11 0.5
" ' ' \815 SCf20s 19 TII"
^ n ^^ '-^5 0S -->•^ ^-n^ G
30.
398500
30.
?99500
58.
00)00
W1E
MIDMASS CHROMATOGRAMS DATA; 6180 #1 . SCANS 775 TO 82510/31/85 14;50:00 CALI; 6170 #5SAMPLEi DIOXIN SOIL EXTRACT#DF019004 CASE«5028 2UL FINN4000 MHCONDS.i 6011 SP2330 70/4>200ei5>24084EPARANGES G 797. 801 LABEL* N 2.10.0 QUANi A 2, 4.0 J 0 BASEi U 20. 3
79932467.
•r-o000
34048.
257.077i 0.500
81536.
320.0961 0.500
112384.
322.096i 0.500
SCANTINE
^"\( • n
MIDMASS CHROMATOGRAMS DATA: 6180 «1 SCANS 775 TO 82510/31/85 14:50100 CALIi 6170 #5SAMPLE! DIOKIN SOIL EXT RACK OF 019004 CASE«5028 2UL FINN4000 MHCONDS.s 60n SP2330 7e/4>209fil5>24084EPARAHGEl G 797, 891 LABELl H 2,10.0 QUAHl A 2, 4.0 J 0 BASEl U 20, 3
79869573.128656.
32^cowc-to^ /2€^s"fo-;?(?/< A
= f 7 ( f ( p ^ / \
101^0000
70912.
328.098i 0.500
114176.
332.0991 0.500
155904.
334.100± 0.500
78019:27
79019:42
80019:57
0
8100 0 5 1 W2
82020:27
SCANTIME
COr^ f0000
St,
rcc
^ i5 ai5 ;3 S?> ^» '••'.<1 0
MIDMASS CHROMATOGRAMS DATA; 6181 »1 SCANS 775 TO 82510/31/85 15:20:00 CALIt 6170 #5SAMPLE: DIOXIN SOIL EXTRACT»DF019005 CASEft5028 2UL FINN4000 MHCONDS.i 60M SP2330 70/4>200@15>240@4EPARANGEi G 797, 799 LABEL: N 2/10.0 QUAH: A 4, 3.0 J 0 BASE: U 20, 3
7988275.16384. 8864.
257.077± 0.500
20160.
320.096t 0.500
25216.
322.096± 0.500
SCANTIME
MIDMASS CHROflATOGRAMS DATA: 6181 #1 SCANS 775 TO 82510/31/85 15:20:00 CALI: 6170 #5SAMPLE: DIOXIN SOIL EXTRACT#DF019005 CASE#5028 2UL FINN4000 MHCONDS.i 6011 SP2330 70/4>200ai5>24084EPARANGES G 797. 799 LABELi N 2,10.0 QUAHs A 2, 6.0 J 0 BASE: U 20, 3
79850712.103480.
]>V>0000
51840.
328.0981 0.500
33y - .^0^ ——
109056.
332.0991 0.500
134912.
334.1001 0.500
78019:27
~~1790
19:42
T810
0 0 5 1 ^112
82020:27
SCANTIME
MIDMAS5 CHROMATOGRAM DATA; 6182 #1 SCANS 775 TO 82510/31/85 l5i49:00 CALIl 6170 #5SAMPLE* DIOXIN SOIL EXTRACT»DF019006 CASEft5028 2UL FINN4000 MHCONDS.l 6en SP2330 70/4>200815>24084EPARAHGEi G 797, 799 LABELS N 1, 4.0 QUAHl A 8, 2.0 J 0 BASE: U 20. 3
1716.3420.
A l ) A^Ji & hi^a, (^-v^^dc^^ c_^
CO1 .0000
<s>
•\J "r .«;3 ;"3W 3ra ^G> 1^0 •=>r'»
P <JS
2080.
257.077i 0.500
800 81019:57 0 0 5 1 8 ^0:12
0
SCANTIME
MIDMASS CHROMATOGRAMS DATA; 6182 #1 SCANS 775 TO 825 (J3r-o000
10/31/85 15;49;00 CALI; 6170 #5SAMPLE; DIOXIN SOIL DORACTHDF019006 CASE»5028 2UL FINN4000 WCONDS.i 69M SP2330 70/4>200fil5>24084EPARANGE; G 797, 799 LABEL; H 1. 4.0 QUAN; A 4, 4.0 J 0 BASEi U 20, 3
7982376.3704.
322.096± 0.500
2720.
320.0961 0.500
3872.
SCANTIME
MIDMASS CHROMATOGRAMS DATA; 6182 #110/31/85 15:49:00 CALI; 6170 #5SAMPLE! OIWW SOIL EXTRACT* DF01900 6 CASE«5028 20. FIHN4000 WCONDS.t 60M SP2330 70/4>200(»15>240@4EPARANGEi G 797, 799 LABEL; N L 4.0 QUAN: A 4, 4.0 J 0 BASEt U 20.
798
SCANS 775 TO 825
82745.164764.
0OQ0000
83584.
328.098± 0.500
167424.
332.0991 0.500
78019:27
79019:42
8100 0 5 1 8 420si2
82020:27
211968.
334.100± 0.500
SCANTIME
(if
<9
<*
» 00
h)!
"
—>
Q
<*l
CO
U»-
M
t i
l T
il
l)
il
l)
? ^
- -
i°a-
s8-
?a
-^
}B. . •
!?»(-
a".
^s^
s8.
0
.
0 S'a
-^
8.
00
U1 ^2
-^•3
•i
Si c
o.
a5.
a :
) 5^
"•«
^
"-^
oon
. • ^ - - . •
) - - •
'"
'
-.
-il8!
/^
•
2 ^
2> t
"
Vs 7
oo
r-^
3:
. ^
"
ItN
L^
5
S^
1
^
• -
- •
„
^0 ^
^ s
PI
V
^ ^
-,.
" ?
-^
— ^
l1
pi^
a
'^^
^
-7° ^
'
<s-
^\ ^
^ ^-
0 r1
- •^•^
^^ ^^^^
^^S
^s.
y- ' . •^
s^
1
/ ^
o
^L
t^-
\ S
-/
» 8
\
"
c^
^
/ w ; « •M 0
>
/
3> rs>
ss^^
u
\ ^W
Ey^
9
( -J
^ S7
>1
^^
(/\ -
e/
^
fiC
. .,
( \»
' $
?
^
x^:
«*>/
-4 ^
?
< 11
"
? ?
ICD
:> -
i;^!
MIDMASS CHROWTOGRW DftTfti 3581 »l SCAMS 789 TO 82997/17/85 16t35i99 CftLIl 5566 15SWPLEi OIOXIH STAND(«D CC«1 1-085 2UL nWWM JK^RDCONDS.i 6m SP2339 7e/4>2«HlS>24eMEPftRANGEi G 1. 850 LABELi H 2.19.9 QWHi A ^ |sAJ 9 DASE1 " 29, 3
4833.6526 •
C\2CO0000
nas^>^0^^®
<<(Ccec
5924.
328.9981 9.599
829 SCAN29i32 TIHE
00
00
83
03103984
(^W
^^-
8 -T, -^
ii^
1
"^;
% ^
^s
0^^
^^
^•-S
s1
^ ^
,'g
lB!
r~-
<D
I>J
—
'
T ^
Sl
asi
^ ^
5^
1" ^
?P
\>
••M
Q
o0
" 'P
^ £
s Sg
Jk^ ^
£
$a
Ci>
00
00
85
MIDMASS CHROHATOGRAMS DATA* 5587 »1 SCANS 775 TO 82507/17/85 21i22(99 CAUl 5566 15SAMPLEi DIOXIN STANMO CC»1 1-085 2UL FIttNOee BROCONDS.i 6011 SP233B 79/4>2eetl5>24W4EPARAHGEi G I* 859 UOELs H 2,19.0 QUAHl A 2,4.9 J 9 BASEi U 20, 3
38872.OR -> , 60152.^•^ 33^33//- /3^^ 1
CJDCO0000
£ ,;p, i0 ,
^ (t^^ Ih
39369. c
332 332.999x WOwB
199.9-1 46144.
334 334.199z 0.500
78919(32
T799
l9»47819
0 0 5 1 9 ®B»l7829
29(32SCANTIME
§
8 y
c aa
"
3
00
00
88
HIDMASS CHROMATOGRflMS DftTA* 5575 •I SCANS 760 TO 84997/17/85 12s25(99 CALIi 5566 •5SAMPLE! DIOXIH STANDARD CCt2 1-986 2UL FIHN4999 JKCONDS.i 6eH SP2339 79/4>299tl5>249UEPARANGEi G 1, 859 LABELi H 2,19.0 WMi A b (S^ B BASE1 u 2e' 3
37843.
^ ¥^'J 5^
0 ?,£ ^0 o ^0 ^0
38298.
3k30+ 205s I'71'?^ 329.996t 9.599
op ru'nL.» 'nn^ ^mTT^
^nA^1 0.^^^
49856.
322.8961 9.599
76919:92
77919»17
78919s 32
79919»47
899 81929»92 0 0 9*479 4
0
82929s32
83929(47
848 SCAN21«02 TIME
< " ^
000091
0^103992
< . C
-
'03003W
7
MIDMASS CHROMATOGRWS DATA* 5575 •I SCANS 789 TO 82997/17/85 12i25i99 CALI* 5566 «5SAMPLE* DIOXIH STAWARO CC»2 1-986 2UL FIHH4999 JKCOHDS.i 69H SP2339 79/4>299«15>24984EPARANGEi G 1, 858 LABEL* H 2,19.9 WMt A 1 ' kft J 9 BASEt U 29, 3
88939645.
^ IPg0 s ^0 0 g0 ^ 50 ^ s^ r?
49964.
332.999t 9.599
1-r . . i"r ."r" ."i" i
48448.
334.1991 9.599
i i i i | i i i i | T i i i ) i r i l | I 1 i i |—«—i i i | i i i—i | i—i—«—«—|789 785 799 795 899 895 819 815 828 SCAN
19(32 19*49 19*47 19*55 29*92 0 02^1? 9 6 20117 29125 29*32 TIME
(*)
0i\>
5 y-M ^
;ys;
b'S
T-^
^§
-n—
a>
y -n -J l u -J N 4C.
u*> u 0 r Gi u u -J u ^ N
00
00
93
ls>~
0.;10^S
94 c
c-
-03
00
.^9
MIDMASS CHROHATOGRAH DATAi 5579 11 SCANS 768 TO 84887/17/85 15ll4i88 CflLIs 5566 »5SAMPLEi DIOXIN STANDARD CCt2 1-986 2UL FIHH4888 JKCONOS.i 601 SP2338 78/4>288815>24864EPARWGEl G 1, 856 LABELl H 2*18.8 QUAHl A !' liA J 8 BASEi U 20, 3
14192.28768.
Tr
C")
0000
^
^is l®
k
^ c
-0 i14528.
Rf_ i- . W03* t'" N5krrD^»~la-' c ______
H^W »0.(Z
^^^^e 0.<\53
328.898i 8.588
76819s 82
0
7778
l9»l7
r788
19»32
T798
19»47
^^L^
818 82829i02 20117 28i32
83828»47
848 SCAN21(82 TIME
n
MIOMASS CHROMATOGRAMS DATAi 5579 •I SCANS 769 TO 84887/17/85 15s14(88 CALIi 5566 *5SAMPLE! DIOXIN STANDARD CC*2 1-886 2UL FIHN4888 JKCOHDS.t 6811 SP2338 78/4>288115>248C4EPARANGEi G L 858 LABELi H 2*18.8 QUANi A 1,4.8 J 8 BASEi U 29, 3
39187.« 77888.
i
56262.8-1 96896.
\
i 1 , „ ( . , , , , , , , , , ,
768 778 788 798 888 818 828 83819»82 19»17 19i32 19»47 28»82 28»l7 28«32 28i47
^ '^
- - /
'
0 0 5 1 9 9
i 8.588
3>33 \- 3^. »"?3^^4
^^ ^\JLO CT0^ "'.i0 ®o ^*—• f,^,
a °0
39616.
332.899t 8.588
56576.
334.188
1848 SCAN
21i82 TIME
,n
^86€00€0
'^GG
CO
TC
O
g
96
00
00
^•s' •H
•£•
<r—
u.
S^iA
<
-•ftw
r^
^
^,
il
?la
pS
s
r^i^
ag
N
|R5
ft. (
Ȥ$
tC
J
'£;!
•?
'
' :
^—
r
5"'—
——
——
——
<
£——
——
——
'——
——
—^
88t">
M1DWSS CHROHATOGRAM DATAl 5586 ft808 SCANS 775 TO 823W/17/W 28i35i9e CflLIl 5366 WSAMPLES DIOXIN STAHDffiD CC»2 1-686 2UL nWWM BROCONDS.I 6m SP2330 7e/4>2W15>24W4EPARANGEi G 1. 950 LffiELi H 2,10.9 QUAHl A 2' 1;A J e BASE* " 29, 3
19564.«Bqqc
7Z(o4^ .^^ 6^ 1 '
r^0^0000
\00^ cS7S C
s s^ (
^"^ c0 r
G
18832.
328.0981 8.590
T780
19i32790
19*47 20S02
0818
20il7829
20(32SCANTIME
G)
ma
5
i i
. T
a (•>
3
«
^
00
00
98
IM
-4
^
3
OC
10
38
99
03
00
39
04 ^
3-i
8-i
719
MIDMASS CHROWTOGRAMS DATAt 5574 •I87/17/85 11(57(80 CALIi 5566 •5SAMPLES DIOXIN STWDWO CC13 1-087 2UL FINH490e JKCONDS.i 6m SP2339 79/4>2eW15>24W4EPARANGEi G 1, 858 UfiELi H 2*10.9 QWHi A 1' li.
138<
)|——,——,——,——,——,——^——^L -
i3
- • ~ 1 , . • - - , . - - • , " J" ^ 1 1 1 1 1 1 1 I )
6 8 7 7 9 7 8 0 7 9 9 8 0 9 819 8 2 9 8 3 8 8 4 8 SCANi82 19(17 19x32 19(47 28(82 28(17 28(32 28(47 21(82 TIME
• O o
8&552
I
0
SCANS 768 TO 848 ^ §CD H;
§ s
) J 8 BASE( U 28, 3 0 b
08.r28* 139264.
330* •5s>3 = 5*^00 328.8961 8.589
^ •- . • - 1 • 1 - • 1
88.)89' 155984.
DP - SS^bOO »»• ("'ntAu^ - '——-————
K)3^^ ^ 5
322.896„(— i 9.500
^Mw^' l•ol<'
l> 0 0 5 2 0 3
00
01
00
03104001 c^
--0300906
Cx)
S
til
<H9
5
u
o5ft
- Q
^J
w-s
J i
i i
T
11
11
) S
® s°a-
^3 ^s-
y8
•
S2-
->4
) s
8"
&0
55
•
s®.
S® a •M M
)s5 "^s
3 3
> cn
(«
) e
ns
o"2
S
o
R
55
5
«.-
<,../
- -
====-||3L
0 0 01 IV)
0 m
"M (3
G
IP
*
2
SQ
M4
, y y
i \i
m m
(
-•-s
"^"am
8
S5^
--g
s'
« ig
^»
2^U
)fi
2x5
1^1 A •5 -IS '•12
gS^g
z
»-«
'
, ;
|§!
^=
::==
:==-1
1^
sta
• •
c •
U
m
-^
e^
M
y>
?Jl
"
U
^ U>
cri
<L>
-C.
00
01
(•)
CJ
IM<s
rs5
^J•
•
^u
MIDtlASS CMROMATOGRAMS DATAi 5578 •I SCANS 768 TO 84887/17^ 14i46i88 CflLIl 5566 •5SAMPLE! DIOXIN STANDARD CC»3 1-887 2UL FIHH4888 JKCOMDS.i 60)1 SP2338 79/4>298»15>24W4EPARAHGEi G 1, 858 LABELl H 2*18.8 QUAHl A 1' Id ^ 9 BASEt U 28* 3
196368.327416.
C\J0-1000
C-30c?-3"0v<j•''.S0
^o -»- ^^= IM-50^1^ < '
328.8961 8.588
253582.417688. 253952.
^ .—— ^5^^__L
322.8961 8.588
0 0 5 2 0 6
76819:82
77819:17
T788
19i32
T798
19i 47 28*82818
28(17828
28s32
T838
28»47848 SCAN
21i02 TIME
r^
00
01
04
0^
104005
93003390-
8 0J—
——
——
LJ°
fO 6
"co
-'i?
(,>>
rm2»
-^
aS
*"w,
^
2§
S8
§
00
01
05
S0
:'10
4Q
QS
'09003931
niDMASS CHROMATOGRAM DATAl 5585 •I SCANS 77S TO 82507/17/85 19x19198 CALIl 5566 •5SAMPLES DIOXIH STttlMRO CC»3 1-087 2UL FIWWW WOCONDS.i 601 SP2338 7a/4>29M15>248t«PARANGEi G 1, 858 LMELl H 2,19.8 QUAHl A 1' li5 ^ 9 BASEl U 28, 3
vwu25955.
26176.
328.998± 9.588
SCANTIME
MIDMASS CHROMATOGRAMS OATAi 5585 »1 SCANS 775 TO 82597/17/85 19il9i89 CALIi 5566 »5SAMPLES DIOXIN STANDARD CC»3 1-087 2UL FIHH4888 BRDCONDS.i OW SP2339 7B/4>29MlS>24et4EPARANGEi G 1, 858 LABG.I H 2,10.9 QUAHl A 1 , 4 . 9 J 9 BASEi U 29, 3
59489.TO o 185569.
1 35Z + 55 - Z^Z \ 52- A
r*-oT-^
000
59968.
332 332.9991 8.599
189.8-1 76832.
334 334.1881 8.589
0 0 5 2 1 1
78819(32
T799
19i47
T818
28»17828
28i32SCANTIME
f-/
00 ;0 %T-1 ^0 ^
§ fo0 °
25MIDMASS CHROHATOGRAMS DATA* 5573 »l SCANS 769 TO 84997/17/85 11129109 CALIl 5566 •5SAMPLES DIOXIN STANDARD CC»4 1-088 2UL FINH4999 JKCONDS.i 601 SP2338 79/4>299115>24984EPARAHGEi G 1, 859 LABEL* H 2.10.9 QUAHl A L 6.8 ,1 9 BASEi U 29, 3
1968219.(589.•»-
9-i
'
719
I | I | l , 1 - 1 T-oB2
1362949.3366269.
A, , ,.-.„,,....„-r. -T——-• , - • •r | >-
69 779 789 799 899t02 19il7 19(32 19s47 29i92
5DU>4 ^ * LPS^'840
1 • 1 ' 1 '
^n - ^ggT^ t
3(41,0? » ^
^F- 0.%2
0 0 5 2 1 2l •• . i • i •
819 829 83929<17 29i32 29s47
IW
3;i
1
13(
32i
84921i92
ff.MKJV.
29.996B.500
!3969.
22.9960.500
SCAHTIME
MIDtlASS CHROMATOGRWS DATAi 5977 •I07/17/85 14(19198 CflLIl 5566 »5S(WLEl OIWW STANDARD CC«4 1-088 2UL FIHH4e90 JKCONDS.l 6811 SP2338 78/4>288C15>248t4EPARANGEi G 1, 850 LABELi H 2*18.8 WWt A L ^
528661.1221938.
SCANS 768 TO 848
8 WSEt U 20, 3
0
000
'\^ J^ ic> i®»•/', '> ^ /^ S
0rs^'35525
tr
8-1
7l19
1• ' ' ' • ' ' ki
7879215294(
1 ' , 1 ' 1 ' 1 ' 1 • I ' 1 ' 168 778 788 798 888 818 828 838 848 SCANs02 19x17 19(32 19(47 28s82 28il7 28i32 28(47 21*82 TIME
K 3^1^1b.
3 0 -^CO -. 3151^10328.896
i 8.588
•—T 1 •i - -| • • » .y-.....,-.. .,
0.39' 788688.
PJ- , , 1-1511410 ^ 1I'tduUM^ '•———-———————~--~
^40(o3% ^ 30
(V' 0,9-7%322.896
Z 0.0v»
^ 0 0 5 2 1 4
—^ccooco
"2T
OW
GO
5w
ff®
TT
TO
OO
C\2
MIDMASS CWOMATOGRWS DATAi 5584 •I SCANS 775 TO 82597/17/85 18s48s99 CALIl 5566 •5SAMPLES DIOXIN STAMDARO CC»4 1-988 2UL FINH4999 WDCONDS.i 6911 SP2339 79/4>299815>24984EPARAHGEi G 1, 859 LABELi H 2*19.9 QUAHl A 1. 4.9 J 9 BASEi U 20, 3
578779.
000
579584.SZO -^3% 3^00
329.996t 9.599
781312.
322.996i 9.599
T789
19:32
T799
19s 47 29s 92
0
^ . 0 5 2 1 6
81929s 17
T829
28(32SCANTIME
s ?
.
l03
• —^
•-tf
il
^
§!
^
";
^>
^^S
Si
-.S
2*'
OD
10
'
28
98
;
^V ^s 0
yg
,-H 8
a a
00
01
13
3s
8 l3-
• 5^
——
flQ
8s
S2-
i Sa-
3s
8
§2
-S3
®
58'
ga-
^s®
ls»
3 ^ il
ss
s
-
0 0 m r\3 —s.
3<»
cx),
^
^ns7
1
^
1- t
/»
-
01
^
. ^
G
^
-.00
j§ * %.
JCt
?»
^a
s;
^
00
01
14
s<^00400
'
03
10
40
15
^
S
^
8«»
inS
^i
ii
i
T
11
11
3 s !s
-• £°
a-—
00
8s
U-
-^ ^s-
^ s
® ^s-
^® ^s-
5®
'
a !
ls> S" 5
»*•
»^
• U
C
D
^ ^s
®
'° ^
AS
83
8
gS
a
^^
——
—-
SSs®
——
——
fg
r.i m
r^^
ss •
•
•
0 0 m ro r\) 0
-ss^
-
^^^=
==
==
^—•
1 f
^
It" IT
^^
-
^r
^^
0
~ ¥• /r 0
** C
O
00
<D
CD
-^•
•
^^
^o»
i.
^ 1
^?
^0
J
^
LTl
r- 0
I
„
00
01
16
g
031040^7
<^oo
4eo^
-eoefreeeo^:>>.-'
.
99
•
99
^mm
eo |
||
|
p
||^
• H • M
-$g
t
Z<TTOO
O
•-o®J
l
3"
<?cfl
0)
s ^
.e
<^ <9
Js
)K
s
^ 1
^9
'
•
•
--
->
-8
S—
——
-—
—^
^<B81 iS
^^^—
——
—sc^
"
——
^9
c**
«^E
5
S^^j 3
cpy
SftS
)
§1
"o
«S
«
S l^
3
88
ft!38
|B5S
8
Ss^s
u^
0.;"
siill <
iOJ
C\J
in00
«^(D
—
^^
===
==^
Z^j\
-,
"a
^^-ggQ (*>
R
®S
;-S
g
98 (
-8g
S^
"^2
ffi^^
00 —»C
<nrs-
"K
m
.
gg
(
§
00
01
18
8
03104019 C
&,S
4004
-
,g
00
01
19
p
031040^
WW
SU
U^
100.0
50.0
' \ .•--"uBASE M/Z; 198RIC; 1161210.
^MASS SPECTRUM DATA; BB328 #970
CALI: CALTAB #211/05/85 8s30:00 + 16:10 .. , ,,.SAMPLE: DFTPP /e»o^ i vz<y/ '" '"/^f^CONDS.: FINNBB 60M SP2331 70/2>200@l5>235@4GC TEMP; 211 DEC. CENHANCED <S 15B 2N 0T)
198
69
51
39 57
77 127
1
81 9.3lllli.i.. ...I.. ll.i....
0
117
1 - .•'• . •'•I
1C
l , l??,.W,,161, l l ,17?,
i6
|.. ... i
206
22217
74•' 2- \4
4-
M/2 50 100 150 200
100.0-1
50.0- 2E55 44
27
1.. 265 .i
75
296 0 0 5 2 2 4i, 285 . 1. . 315 . 334 346 ... 365 . 383 403 415 . i. 1
•2
1. 451
M/Z 250 300 350 400 450
, /1 Mass List Data: BB328 ft 970CALTAB « 211/05/S5 8:30:00 + 16 :10 Call:
Sample: DFTPPConds. : FINNBB 60M SP2331 70/2>200@15>235@4Enhanced <S 15B 2N OT)
Base m/z: 198RIC: 1161210.
4Ma
39.SO.51.32.56.57.61.63.65.69.74.75.76.77.78.79.80.81.82.83.85.91.92.93.98.99.
101.104.105.107.108.110.111-116.117.123.127.128.129.130.135.137.141.142.147.148.153.155.156.< r <
35.98ISS
00?00700?00?00?00?00?00?00?00000000000000000000000000000000000000000000000000000000000000000000000000000000r>n
0.
7.
5.14.55.2.1.3.0.2.1.
65.5.8.2.
55.3.3.2.4.1.1.1.0.1.5.4.4.2.1.1.
17.2.
35.4.1.9.1.
54.4.
24.2.1.1.2.0.1.2.0.1.2.<
00
RA
04523688788686220698019783564541893304254684045916613028275759239506197387390000961668945341SS5324/• 4
0. 00
7. RIC
0. 571. 646.260. 330. 200. 440. 100. 250. 127. 460. 571. 010. 326. 280. 390. 390. 330. 490. 120. 140. 170. 090. 120. 630. 470. 520. 260. 140. 141. 990. 293. 980. 560. 121. 040.206. 210. 502. 710. 230. 220. 130. 300. 110. 170. 270. 100. 170. 25\ 16
0. M# 0 MInten.
6624.19072.72704.3776.2332.5072.1128.2920.1398.
86656.6584.
11776.3712.
72960.4536.4472.3792.5688.1372.1648.1920.1100.1360.7344.5464.6056.3020.1678.1668.
23072.3400.
46272.6504.1392.
12064.2272.
72064.5760.
31520.2628.2576.1524.3520.1240.200B.316B.1160.2010.2936.1856.
inimaaxima
Ma
165.167.168.174.175.177.179.180.181.185.186.187.192.193.196.198.199.204.205.206.207.211.217.221.223.224.225.227.229.244.245.246.255.256.258.265.273.274.275.276.277.296.323.334.365.372.423.441.442.443.
Mi
ISS
0000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000
In inte
7.
0.4.3.1.1.0.3.2.1.1.
14.4.1.1.2.
100.8.3.5.
24.3.1.5.4.1.
12.3.5.1.9.1.1.
49.7.2.1.1.4.
22.3.1.5.2.1.2.0.3.6.
47.9.
•n:
RA
8460510481964565197786250516620011477217180499832938151711142083271854025227170096280127139402645600
1090.
7. RIC
0. 090. 520. 400. 120. 200. 1 10. 390. 300. 130. 201. 680. 480. 120. 130. 30
1 1 . 310. 920. 390. 652. 730. 360. 120. 680. 550. 151. 400. 360. 580. 131. 030. 140. 215. 570. 810. 290. 110. 170. 482. 510. 340. 220. 600. 230. 140. 240. 1 10. 340. 755. 3S1. 02
Inten.
1098.6040.4616.1362.§^76.1.266.4336.S484.(K^66.3324.
19520.§584.1378.1522.3440.
131328.10656.4552.7512.
31744.4176.1366.7864.6344.1694.
16256.4136.6792.1452.
12000.1582.2408.
64704.9424.3332.1334.1994.5608.
29120.3940.2568.6929.2640.1664.
f^OlgJ3960.8720.
62464.11S24.
nMo^yo^."i?7084£
1400 SCAh23;20 TIME
0 0 0 i „MASS SPECTRUM DATA; BB332 #1260 BASE M/Z: 322 t ^11/05/85 11:54:80+21:00 CALI; CALTAB #2 RIC; 169728. g °SAMPLE: DIOXIN SOIL EXTRACT#DF019001 2UL FULL SCAN FINNBB MH § S
100.0-1
•
50.0-
"
M/Z 50 100100.0-j
•
50.0-
0001 Lp~~
ro^ M/7We.
Y 92C
74
50 K
oc36
1[42,
322
--L-T-
CONDS.» FINNBB 60M SP2331 70/2>200815>23564 ^ ^GC TEMP: 240 DEG.
#1260 - #1240 - »1275 }<1.C
54
^
107fc0' 1001 299
14 .4, ' ,sea 350 4ue 450 sea
8" 1B2 '
L
87
111-JLU1L-
334
i
C
97
.1
U
1,1 H|L
346.356 .. 371.381 391 404 419428 441 455 468 479 496
30 $ ®
W7
194
5161 204
167l l 1?2 H3 ||| 213 225 939 250
llll | i l | l l l | lfll .,,ill,.l..,.|..l I , I IH | I . . .187 1 , . , . ^ l i , ,h.,li|,.,,,l,,,., i .
150 200 250
0 0 5 2 2 7
• i ' i • i ' i • i • i ' ' ' ] ' i ' i • i ' i
1 "H-
;> n
r- 923
322.0
334.0
287.0 mvy Q1 1 . 1 1 Wl»0
lllbll.l| lllJ l lllLl.l jllL^«J^
300»^
350
356.0. ,. 378.3
400.•'"\
0 0 5 2 2 8
419,0 440.3 468.4i—jiii '-t '—<
450
MASS SPECTRUM DATA; BB332 #124011/05/85 11:54:00 + 20:40 CALI: CALTAB #2SAMPLE: DIOXIN SOIL EXTRACT#DF019001 2UL FULL SCAN FINNBB MHCONDS.; FINNBB 60M SP2331 70/2>200615>23564GC TEMP; 238 DEC. C
BASE M/Z; 41RIC: 457728.
50.0-
41.0100.0-1
.III
5?
1 Illlluui
7.1
BACKGROUND SPECTRUM
69
uJi
•I 81
,
|
i
.1 9;
hU,
5.1
191
10!
luill
j
ni|
9.1
12;
J JJ | |nia
3.1
137.2
Um16:
w3.2
;.
iL^ ,|JJibUi,,H, ihi,
.2
1 207.2
M/Z
100.0
50.0
0 0 5 2 2 9359.9289.9
Lli..^11^:-^..313-2-.--336-2-., ^^j^4..^5.^!:4,428-9.^451-1465-6.484-7. s04-1
M/Z 300 350 400.-^\
450 500
MASS SPECTRUM11/05/85 11 :54 :00+21:SAMPLE: DIOXIN SOIL EXTRflCOHDS.: FINNBB 60M SP2331GC TEMP; 240 DEG. C <-
100.0-1 41.0 57"1 r 17792?
50.0-
M/Z 50
100.0-1
50.0-
•
Jil
282.1 303.0 323.8 :-4uyl»iji'»ii"l»- ->ihiii....J...Mi 1 1 J i.... i
h• 1 • ' • '
BACK
69.1
JJl
81.1 95.1
JijLu100
339.0•,"'l|'-f •
109
ilill
15 CALI: CALTAB #2 RIC: 366080. ^-
ll
356.7 1.373,? 389.2. 410.5 426.6 442.7 465.2 493.0
DATA; 88332 #1275 BASE M/Z: 57 S
»CT#DF019001 2UL FULL SCAN FINNBB OH70/2>200@15>235@4 ^
GROUND SPECTRUM
.
- 1 14?-1 191.2123.1
1 |
III. Lt i 163.2 9fl5 9 ^—. -lllnll u 1 1 llil 1 &>wv • & ^C7 1
dlilillili|lill!iliiiiilililiiiliiil|lli)iiiiiiiill150 200 250
-
0 0 5 2 3 0
-1——»——1——1»——1--L—4——1—» ' 4—• •+ '—I ' »— • |—• I • I • 1 • 1 • | • 1 •
'J
t
• ^
C 1C)f}0>
r- 17792.
r^CM0^p0<•<
)
i
•»
400M/Z 300 350 450 500/'-•
b U
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
O 0
U0
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
0
M •b
UI
^
^
U
M
M IU
-
t»
^
IU —
•-
M
01
-t
»- »
-. (J
—
(U •
- IU
.
>•*
01 ^
ui u
ui u
i 01
u u
u
ui i
u u
i p
m
p o
iu
p'o
iu
u
si (
h o
ui
sJ
10
p 01 ^
u
p
N
p
M-s
i o'0
-(»
o
m
o
oo
R) o
oo
4> ^
-^ ^
^o
•& u
u m
-t» c
a (u -
o o
&• u
oo
>o-
o o
>o o
&-1
^-b
o 01
^-o
o m
u-a
a»
oO
lS-^
O^
O'O
Oll
UU
O^
OO
'OID
M^
UIO
OO
'O-fr
UI^
'OO
'O-tk
MN
JO
Oll
U-^
Olt
hU
l-lk
Ut^
Uo
li^
'sl'
O'O
UO
^
>
0
Kp
pp
pp
pp
pp
pp
pp
»-
lp
^p
pp
•"
l^
-lp
lU
pp
p^
-l»
->p
^••p
ptJ
pp
pp
pp
^-p
p»
*p
p^
-p
pp
p
0
M u
i U
(U U
U M
U
IU m
(J
1U ^
m
01
4» .
fr U
l »^ ^
U IJ
01
4» t
U 0
•s|
01
(J-t
* 0
U •»
» s» ^
0»
00 N
J s| u
• (
>. M
ui
4» u
4»
».
M
0•O
U U
-1 0
-t U
0 0
01
»-
• IU
CO 0
M 0
th M
00
IU -
0 M
(h
•s|
(J
IU
01
01 -
Nt u
0 •
O L
J -
M 0
M (J
'»! 0
0 U
U <
0 •*>
M 0
1 0
0
0 - *««• a 30
0
>•
»>
* M
•— •
-t M
^f-'U
M
>-*
«-*
M
01
»-
t»
-t
»-
>M
t-
ti
-t
i^
M
•-*^^
olU
alU
l(Ja
l^-•
(>c>
)al-
^>'o
•p•'
oco
N^•
^^o
^^o
u•<
^l^•
^)•^
Jo^^
lall
^'<
^^-tl^
•^^^
)s^o
tJ'o
ua
ltD
oc»
)•^•
^JO
l^^off
loo
i^o
iuiD
^a
iih
si^
iDa
isio
-ik
ai^
aio
uu
oih
UO
'ffl
O^
o'l
o's
J^
oo
^u
o^
^'o
.fk
^o
ch
^o
oo
oi-
tkN
Ji^
ma
iMtJ
t^O
-^
O-lU
CO
MO
UO
-^
-fr
OQ
^'O
CO
-tt
OO
O-^
OO
U^
^O
OO
OO
MM
lUO
O^
MC
DO
OO
MO
I^O
OQ
^IU
fUM
.fr
3; 3
0)
»-•
x 3
»•*•
»-
3 3
in a
,3 M M
3 »*•
M
3
z
»-->
3«+ a
N
3
•sa t-1 0
u 0«1-
4
(*)
3 rt-• 3
(J
OU
UU
UU
UU
tJ
IJ
t.lM
MIU
MM
IU
MIU
MM
MIU
IU
MM
IU
MM
MM
Mt-^
t-'^
^t-i-
t-i-
i-i^
^^
^^
^i-
uu
uu
lUM
Uly
lU^J
^)tu
^<lm
al'
^^s^|
(^•o
^&•(
^oso
lalo
lal^
J^)^
)^-o
o•>
o•<
)•c'
o(^
o^(^
-o^o
^(^&
>o
lal•
t»4
»-^
^(«
)p
p'^
Mp
^o
i^u
io^
p^
Nis
ioii
up
pu
ju^
p^
m^
pp
aio
iup
'^o
op
^o
i^^
ai^
p'M
^p
^m
p^
u0
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
0
IU U
l (
U -
.*
>-*
0-C
O
MM
^
M
•>
01
- M -
IU
4»
K -
»-
IU •
-p
'pN
Jp
ch
oi^
uiu
pp
luo
i^^
pm
p^
^a
i^p
p'^
oi^
oi^
^p
^^
^u
^o
iiu
^p
uu
p'u
^m
^^
ulu
^(D
luu
thU
^^
o'o
o^
mM
^M
^fr
oiN
i^u
iu^
^^
iu^
^^
aio
lUC
Os
iaio
o^
.ttN
t.it
OC
O^
o'-
lua
ioiu
.fr
sJ
s4
uo
.^o
uu
aio
^N
ifr^
^^
uiu
iuc
oa
iui^
o'a
)o-4
)(J
iuiu
oo
uiu
oi(
ho
^a
ia)^
u(>
(DU
«o
o(i
)^u
iu
pt-U
IU
^p
plU
pU
ip
^p
pp
pp
^^
-'p
^p
tU
pM
pp
pp
pp
t-p
^p
lU
pp
pp
pf^
pp
pp
pp
uu
ii^iu
^m
iu«
(h^u
iuii
uiu
ui^
-^-t
kO
'oiu
^u
uiu
mL
Jiu
iu-t
»-^
'siu
a)(
>iu
iJ-f
r(J
i's
i^tJ
Uo
-tk
iUR
)iu
iu.t
k^
alU
^th
-^
lh^
'OlD
OO
.fr'O
U^
OI'
MU
ICJ
O^
^U
imO
OO
-fk
Cil
Nll
U'O
O'O
IUN
l^i^
NJ
ui^
U^
oo
oU
UN
J^
)^
M U
I CJ
IU
>•*
^-•0
N1
M
M-
t ^
4*
4»
^ t
U ^
M
U
^ »
* M
K|>
(hU
^4
k^
^O
^IU
^O
sJ
^u
a)N
Jff
l^'^
C^
-f>
a)U
l(x
)UI'
>J
UI-
^C
J's
J^
LJ
(J-^
's|-
t>'0
0>
'OIU
IUU
lM(D
a)U
-f>
«-»
k(h
IUO
O^
)UI•
MlU
4a
.m^
l'O
OO
OC
DO
O(^
U1
0(^
(^'0
0(D
•00
00
(^^
^-t
OO
-00
(«)0
0^
•^>
0^
(^>
'ON
^(D
^»
(^^
)UO
'OIU
O>•a
)•0
•O
^O
IUtM
UO
^lM
y'O
^'O
lUIU
M.t
kO
O^
O^
lU'O
^'O
OO
^M
UO
l.^
OO
.OC
OU
l.M
Ji.
OO
CO
UO
^C
OO
^O
th
O
® i
r,..5 0
1
^ *
0
<
N>
^9 r
p *3 3 3 ^ 5 * ^
J
g
00
52
31
0 ro <z
r> (A
3
« 0
Oi
>-
b»^
3 3
-s
M(0
a-o
0
ui
0s r
t ^
Uo
• •
r••
•• oo
t*
I U
M•n
o
ci^
M
1-1
>-«
»- z
o »
-M
Z X
••
«ta
1-1
u0
0) Z
•4
x o
in o
^0
00
• 3
wo
r +
00
1 Ti m
MM
X f
*u-
< ••
U X
0»
•*> 0
0^
-10
«'S 0
M T
1 0
0V 0
0)
&M
••»
•-'
<«•
0 «
0 M
- Oi
o o
•• •
•«
0^
O
Bm
> u
v M
ru
M C
-(U
u r
> M
UI
Ura>
•n
*^F
^Er
s(0
M0 > "n ta
31
caU
1-1
bn
u)3
••
« 9 •s
o* '0 • u
MM
OO
M
C\J^CMinoo
SECTION V: DOCUMENTATION
0
000128
<^e040i4c<-03104029
u
0
0 ^
— ).;: — —
;: -
-
—
-
- - :-
-•
—
—
-•
•—
—
—
—
..
—
: -
:- -
—
•- -
:: -
- -
-• : -
.. -- : - : —
—
-- ... . .-..
—
- : -
—
—
- ...
— .,
—
-
^
,
\ (
--
—,
Sl
>A
-t i M . M ? < -<
i< .
M V £.
ci >J •n 0 S 0 S» ^ N k^ 0 a X, ? ft
^ ^ 5 ^ ^-
P-^
-g:^
^ H'i
^ ^ n 0 ^ ^T L ?i
Q K.
f ? Vk
K •>-
< » ^» T k
^ •sl Tk ^ '»> ^ < •J I ^ > K. 1
• SP « '»-
•t » p •T>
^ 0 Tl
0 5 0 0 |J \f
V e • i ^ ? ? T
C.
^ L> s J>
§ M C b^ > c »' ^ ^ ? ^
s- 3 -A £ ^ d •n a S | IA £ S3
3 K ? f\<
\». 3" ^ T A 1 ic i
•L
^ ^1 ^ •e, iO ? j s >» p,
< n ' ^ s^ t- n 1 ? i £
f ^ ^ <3 3 n a ^ > — M ?•
^ i0 ?° ^ r- ^
s-- 3 -c,
E ( ^> OS ^ y c'' r ^ flA b^
^ » 1 •c, ^ % ( ^ k v W [ /• & &->^
&•~»
Li
^ ^ si. "1 1 o^^
9 0 •St 5 P r» It ll
0? ^ i; J» 5 ^ ac\
• & •Q S9 > < 5I
-0 ^5- 3 0 1 -c f\ y x u> s oft
6" • \ Jv p ? J L>J
J;
i' 1 | ^
1t 0 Oi; r> ^ » iA V 1 ll ^ "\ ^ >ft ^ ft ^ <3 M U> r> p ^ a £ ji
lo-i- f^/^PARAMETER REQUEST SHEET PARE 1-1
DATE 9/28/85 ACD; POWERS
INIT: BH
FORM4 NO
~) PROJECT; 868.0000 CASE; 5028
BATCH; 15 SITE: REF 6
DUE DATES: LAB 10/28/85 REQUEST 10/28/85
BATCH COMMENT;
PARAMETER
LABSAMPLE
*
2063
2064
2065
2066
') -°67
2068
MATRIX
SOIL
SOIL
SOIL
SOIL
SOIL
SOIL
LABLOC
ISOL
ISOL
ISOL
ISOL
ISOL
ISOL
TCDD
%
H
»
»
»
#
—--—-5-—-—————-—i———
•; -
i
C\J— (^.——— —
00
— — — — — — C ; — — — — — — — — — —•J
000130
03004016-^03104031
BATCH: 15
DUE DATES: LAB 10/28/85
BATCH COMMENT!
PARE 1-PARAMETER REQUEST SHEET
J) PROJECT: 868.0000 CASE: 5028 DATE 9/2S/25 ACD; POMER3
SITE; REF 6 INIT; BH
REQUEST 10/28/85 FORM4 NO
PARAMETER
LABSAMPLE
t
2063
2064
2065
^'!066
2067
2068
FIE
DF
DF
DF
DF
DF
DF
;LD Sf^
0190
0190
0190
0190
0190
0190
iMPLESAMPLE
01
02
03
04
05
06
m
REMARKS ^(M
00
t
3 000131
