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SCHEDA DI DATI DI SICUREZZA secondo il Regolamento (CE)
Num. 1907/2006
Oxone(R) Monopersulfate compound PS-16
Versione 3.0
Data di revisione 13.10.2010 Ref.130000026038
1/54
Questa SDS è conforme agli standars e prerequisiti regolamentari dell'Italia e può non essere conforme ai requisiti regolamentari di altri paesi.
1. IDENTIFICAZIONE DELLA SOSTANZA O DELLA MISCELA E DELLA SOCIETÀ/IMPRESA
Informazioni sul prodotto
Nome del prodotto : Oxone(R) Monopersulfate compound PS-16 Utilizzazione della sostanza/della miscela
: Agente pulente, Oxidizing agent ES 1 - Formulation of KPMS based products ES 2 - Denture Cleaner - Consumer Use ES 3 - Professional use of KPMS in pool and spa applications ES 4 - Pool and spa - Consumer Use ES 5 - Use of KPMS in Metal Surface Treatment - Industrial Use ES 6 - Industrial use of KPMS as processing aid in chemical synthesis ES 7 - Use of KPMS as Intermediate in chemical synthesis - Industrial Use ES 8 - Industrial use of KPMS in pulp and paper treatment/production ES 9 - Industrial use of KPMS as environmental processing aid
Società : Du Pont de Nemours (Nederland) B.V.
Baanhoekweg 22 NL-3313 LA Dordrecht Paesi Bassi
Telefono : +31-78-630.1011
Telefax : +31-78-630.1181
Numero telefonico di emergenza
: +39-02-9210.5223
Indirizzo e-mail
2. IDENTIFICAZIONE DEI PERICOLI
Nocivo per ingestione. Nocivo per gli organismi acquatici. Provoca ustioni.
3. COMPOSIZIONE/INFORMAZIONI SUGLI INGREDIENTI
Componenti pericolosi
Nome Chimico No. CAS No. CE Numero di registrazione
Classificazione Concentrazione [%]
Bis(perossimonosolfato)bis(solfato) di pentapotassio
70693-62-8 274-778-7 01-2119485567-22-0000
Xn; R22 C; R34 R52
86 - 96
SCHEDA DI DATI DI SICUREZZA secondo il Regolamento (CE)
Num. 1907/2006
Oxone(R) Monopersulfate compound PS-16
Versione 3.0
Data di revisione 13.10.2010 Ref.130000026038
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Perossodisolfato di dipotassio
7727-21-1 231-781-8 O; R 8 Xn; R22 Xi; R36/37/38 R42/43
0 - 5
Tetra[carbonato(2-)]diidrossipentamagnesio
7760-50-1 231-851-8 Xi; R36
1 - 2
Per il testo completo delle frasi R menzionate in questa sezione, riferirsi alla sezione 16.
4. MISURE DI PRIMO SOCCORSO
Informazione generale
: Non somministrare alcunchè a persone svenute. Togliere dall'esposizione, far sdraiare. In caso di incidente o di malessere consultare immediatamente il medico (se possibile, mostrargli l'etichetta).
Inalazione
: Portare all'aria aperta. Ricorrere all'ossigeno o alla respirazione artificiale se necessario. Chiamare immediatamente un medico.
Contatto con la pelle
: Sciacquare immediatamente la pelle con molto acqua. Togliere gli indumenti contaminati e le scarpe. Lavare gli indumenti contaminati prima di riutilizzarli. Consultare un medico.
Contatto con gli occhi
: Lavare immediatamente con molta acqua e sentire il parere di un medico.
Ingestione
: NON indurre il vomito. Se l'infortunato vomita mentre è supino, girarlo su un fianco. Bere 1 o 2 bicchieri d'acqua. Non somministrare alcunchè a persone svenute. Chiamare immediatamente un medico. Se il soggetto è cosciente:
5. MISURE ANTINCENDIO
Mezzi di estinzione idonei
: Utilizzare sistemi estinguenti compatibili con la situazione locale e con l'ambiente circostante.,
Mezzi di estinzione da non utilizzare per ragioni di sicurezza
: Anidride carbonica (CO2), Getto d'acqua abbondante,
Pericoli specifici contro l'incendio
: Il prodotto di per sé non brucia.
Prodotti di decomposizione pericolosi
Equipaggiamento speciale di protezione per gli addetti all'estinzione degli incendi
: Indossare un respiratore autonomo e indumenti di protezione.
Ulteriori informazioni
: Raffreddare i contenitori / cisterne con spruzzi d'acqua. Non lasciare che i mezzi di estinzione penetrino nelle fognature o nei corsi d'acqua.
6. MISURE IN CASO DI RILASCIO ACCIDENTALE
Precauzioni individuali : Evacuare il personale in aree di sicurezza. Evitare il contatto con la pelle, con gli
SCHEDA DI DATI DI SICUREZZA secondo il Regolamento (CE)
Num. 1907/2006
Oxone(R) Monopersulfate compound PS-16
Versione 3.0
Data di revisione 13.10.2010 Ref.130000026038
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occhi e con gli indumenti. Non inalare polvere. Usare i dispositivi di protezione individuali. Prevedere una ventilazione adeguata.
Precauzioni ambientali
: Non deve essere abbandonato nell'ambiente. Impedire al materiale di raggiungere le fogne, le condotte d'acqua o le zone basse. Non contaminare la falda e le acque superficiali.
Metodi di pulizia
: Spazzare via e spalare nei contenitori addatti per lo smaltimento. Evitare la formazione di polvere. Dopo la rimozione pulire ogni traccia con acqua.
Ulteriori suggerimenti
: Eliminare nel rispetto della normativa vigente in materia.
7. MANIPOLAZIONE E IMMAGAZZINAMENTO
Manipolazione
Avvertenze per un impiego sicuro
: Usare soltanto in luogo ben ventilato. Non respirare le polveri. Evitare la formazione di polvere in luoghi ristretti. Evitare il contatto con gli occhi e con la pelle. Tenere lontano da calore e fiamma. See also Annex – Section 2.2
Immagazzinamento
Requisiti del magazzino e dei contenitori
: Tenere in un luogo secco, fresco e ben ventilato. Proteggere da contaminazione. Conservare nei contenitori originali.
Indicazioni per il magazzinaggio insieme ad altri prodotti
: Conservare lontano da: Materiale combustibile Evitare assolutamente che il prodotto venga in contatto con l'acqua durante l'immagazzinaggio.
Altri informazioni
: Stabile nelle condizioni di stoccaggio raccomandate.
8. CONTROLLO DELL'ESPOSIZIONE/PROTEZIONE INDIVIDUALE
Components with DNELs/PNECs
Components CAS-No.
Pentapotassium bis(peroxymonosulphate) bis(sulphate)
70693-62-8 DNEL/DMEL (worker) Acute – systemic Effects - Dermal
80 mg/kg bw/day
DNEL/DMEL (worker) Acute – systemic Effects - Inhalation
50 mg/m³
DNEL/DMEL (worker) Acute – local Effects - Dermal
0.449 mg/cm³
DNEL/DMEL (worker) Acute – Local Effects - Inhalation
50 mg/m³
DNEL/DMEL (worker) Long Term – systemic Effects - Dermal
20 mg/kg bw/day
DNEL/DMEL (worker) Long Term – systemic Effects - Inhalation
0.28 mg/m³
DNEL/DMEL (worker) Long Term – Local Effects - Inhalation
0.28 mg/m³
SCHEDA DI DATI DI SICUREZZA secondo il Regolamento (CE)
Num. 1907/2006
Oxone(R) Monopersulfate compound PS-16
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DNEL/DMEL (consumer) Acute – systemic Effects - Dermal
40 mg/kg bw/day
DNEL/DMEL (consumer) Acute – systemic Effects - Inhalation
25 mg/m³
DNEL/DMEL (consumer) Acute – systemic Effects - oral
10 mg/kg bw/day
DNEL/DMEL (consumer) Acute – local Effects - Dermal
0.224 mg/cm³
DNEL/DMEL (consumer) Acute – Local Effects - Inhalation
25 mg/m³
DNEL/DMEL (consumer) Acute – local Effects - dermal
10 mg/kg bw/day
DNEL/DMEL (consumer) Long Term – systemic Effects - Inhalation
0.14 mg/m³
DNEL/DMEL (consumer) Long Term – systemic Effects - Oral
10 mg/kg bw/day
DNEL/DMEL (consumer) Long Term – Local Effects - Inhalation
0.14 mg/m³
PNEC aquatic - freshwater 0.022 mg/L
PNEC aquatic – marine water 0.002 mg/L
PNEC aquatic – intermittent releases 0.0109 mg/L
PNEC Sediment freshwater 0.017 mg/kg wwt
PNEC Sediment marine 1.74E-03 mg/kg wwt
PNEC Soil 0.885 mg/kg wwt
PNEC stp 108 mg/L
PNECoral 44.44 mg/kg food
Componenti con limiti di esposizione
Componenti No. CAS Tipo Tipo di esposizione
Parametri di controllo
Aggiornamento
Base
Dust (inhalable and respirable fraction)
Perossodisolfato di dipotassio
7727-21-1 TWA 0,1 mg/m3
2000
OEL (IT)
Dati di progetto
Assicurare un'adeguata areazione, specialmente in zone chiuse.
Protezione individuale
Protezione respiratoria : Quando si verificano concentrazioni superiori ai limiti di esposizione, è obbligatorio l'uso di adeguati sistemi di protezione delle vie respiratorie. Indossare un respiratore con erogatore d'aria. See also Annex – Section 2.2
Protezione delle mani : Materiale: gomma butilica Tempo di penetrazione: >= 8 h Spessore del guanto: 0,5 mm
SCHEDA DI DATI DI SICUREZZA secondo il Regolamento (CE)
Num. 1907/2006
Oxone(R) Monopersulfate compound PS-16
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See also Annex – Section 2.2
Protezione degli occhi
: Usare occhiali di sicurezza o occhialetti di protezione chimica anti-spruzzo a copertura completa.
Protezione della pelle e del corpo
: Dove esista un rischio potenziale di contatto con la pelle, disporre e indossare a seconda della situazione, guanti impermeabili, grembiule, pantaloni, rivestimento, cappa e stivali Togliere gli indumenti contaminati e lavarli prima del loro riutilizzo.
Misure di igiene
: Lavarsi le mani prima delle pause e subito dopo aver maneggiato il prodotto. Pulizia regolare dell'attrezzatura, dell'ambiente di lavoro e degli indumenti. Manipolare rispettando le buone pratiche di igiene industriale e di sicurezza adeguate.
Accorgimenti di protezione
: Non mangiare né bere durante l'impiego. Non respirare le polveri.
9. PROPRIETÀ FISICHE E CHIMICHE
Forma fisica
: Forma solida, granulare,
Colore
: bianco,
Odore
: nessuno(a),
pH
: 2,1 a 30 g/l ( 20 °C)
Punto di fusione : Si decompone prima di sciogliersi.
Punto di ebollizione : non applicabile
Punto di infiammabilità.
: non è infiammabile
Infiammabilità (solidi, gas)
: Il prodotto non è infiammabile.
Proprietà ossidanti
: Il prodotto non è ossidante
Proprietà esplosive
: Non esplosivo
Tensione di vapore
: < 0,0000017 hPa
Densità relativa
: 2,35 a 20 °C
Densità apparente
: 1 100 - 1 400 Kg/m3
Idrosolubilità
: 297 - 357 g/l a 22 °C
10. STABILITÀ E REATTIVITÀ
Condizioni da evitare
: Temperatura : > 50 °C Evitare il calore estremo.
Materiali da evitare
: Componenti alogenati, Cianuri, Sali di metalli pesanti
SCHEDA DI DATI DI SICUREZZA secondo il Regolamento (CE)
Num. 1907/2006
Oxone(R) Monopersulfate compound PS-16
Versione 3.0
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Prodotti di decomposizione pericolosi
: ossigeno Diossido di zolfo Triossido di zolfo
Reazioni pericolose
: Stabile nelle condizioni di stoccaggio raccomandate.
11. INFORMAZIONI TOSSICOLOGICHE
Tossicità acuta per via orale
Bis(perossimonosolfato)bis(solfato) di pentapotassio
: DL50/ ratto : 500 mg/kg
Tossicità acuta per inalazione
Bis(perossimonosolfato)bis(solfato) di pentapotassio
: CL50/ 4 h/ ratto : > 5 mg/l
Tossicità acuta per via cutanea
Bis(perossimonosolfato)bis(solfato) di pentapotassio
: DL50/ ratto : > 2 000 mg/kg
Irritante per la pelle
: su coniglio Risultato: Provoca ustioni.
Irritante per la pelle
Bis(perossimonosolfato)bis(solfato) di pentapotassio
: Classificazione: Provoca ustioni. Risultato: Corrosivo
Irritante per gli occhi
: su coniglio Risultato: Grave irritazione agli occhi
Irritante per gli occhi
Bis(perossimonosolfato)bis(solfato) di pentapotassio
: Classificazione: Provoca ustioni. Risultato: Corrosivo
Tetra[carbonato(2-)]diidrossipentamagnesio
: animali (specie non precisata) Risultato: Irritante per gli occhi
Sensibilizzazione
: Può causare sensibilizzazione a persone predisposte, a contatto con la pelle e con l'inalazione della polvere.
Sensibilizzazione
Bis(perossimonosolfato)bis(solfato) di pentapotassio
: porcellino d'India Classificazione: Non è un sensibilizzante della pelle. Risultato: Non causa sensibilizzazione su animali da laboratorio. 'Esistono riferimenti rari o inconclusivi sulla sensibilizzazione della pelle umana
Esperienza umana
: Esposizioni eccessive possono causare danni alla salute, come segue: Inalazione Vie respiratorie superiori: Irritazione, Disagio, Dolore, Tosse
Contatto con la pelle
SCHEDA DI DATI DI SICUREZZA secondo il Regolamento (CE)
Num. 1907/2006
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Irritazione, Disagio, Sfogo
Contatto con gli occhi Irritazione, Disagio, Lacrimazione, Vista annebbiata, Corrosione, Ulcerazione
Ingestione Stomaco: Danni, Ulcerazione, Disturbi gastrointestinali
12. INFORMAZIONI ECOLOGICHE
Dati sull'eliminazione (persistenza e degradabilità) Eliminabilità fisico-chimica
: idrolizza
Tossicità per i pesci
Bis(perossimonosolfato)bis(solfato) di pentapotassio
: CL50 / 96 h/ Oncorhynchus mykiss (Trota iridea) : 53 mg/l
Tossicità per le alghe
Bis(perossimonosolfato)bis(solfato) di pentapotassio
: / CE50r/ 72 h/ Alga: > 1 mg/l
Tossicità in acqua
Bis(perossimonosolfato)bis(solfato) di pentapotassio
: / CE50/ 48 h/ Dafnia: 3,5 mg/l
13. CONSIDERAZIONI SULLO SMALTIMENTO
Prodotto
: Eliminare come rifiuto pericoloso rispettando i regolamenti locali e nazionali. See also Annex – Section 2.1
Contenitori contaminati
: Se il riciclaggio non è praticabile, smaltire secondo le leggi locali.
14. INFORMAZIONI SUL TRASPORTO
ADR Classe: 8 Gruppo d'imballaggio: II Codice di classificazione: C2 No. HI: 80 Numero ONU: 3260 No. Etichettatura: 8 Nome di spedizione appropriato ONU:
Solido inorganico corrosivo, acido, n.a.s. (Monopersulfate Compound, )
IATA_C Classe: 8 Gruppo d'imballaggio: II Numero ONU: 3260 No. Etichettatura: 8
SCHEDA DI DATI DI SICUREZZA secondo il Regolamento (CE)
Num. 1907/2006
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Nome di spedizione appropriato ONU:
Corrosive solid, acidic, inorganic, n.o.s. (Monopersulfate Compound, )
IMDG Classe: 8 Gruppo d'imballaggio: II Numero ONU: 3260 No. Etichettatura: 8 Nome di spedizione appropriato ONU:
Corrosive solid, acidic, inorganic, n.o.s. (Monopersulfate Compound, )
15. INFORMAZIONI SULLA REGOLAMENTAZIONE
Etichettatura secondo la Direttiva CE
Simbolo(i) : C Corrosivo
Componenti pericolosi: Bis(perossimonosolfato)bis(solfato) di pentapotassio Perossodisolfato di dipotassio Frasi "R" : R22 Nocivo per ingestione.
R52 Nocivo per gli organismi acquatici. R34 Provoca ustioni.
Frasi "S" : S22 Non respirare le polveri.
S36/37/39 Usare indumenti protettivi e guanti adatti e proteggersi gli occhi/la faccia.
S45 In caso di incidente o di malessere consultare immediatamente il medico (se possibile, mostrargli l'etichetta).
S60 Questo materiale e il suo contenitore devono essere smaltiti come rifiuti pericolosi.
16. ALTRE INFORMAZIONI
Testo delle frasi-R menzionate nella Sezione 3
R 8 Può provocare l'accensione di materie combustibili. R22 Nocivo per ingestione. R34 Provoca ustioni. R36 Irritante per gli occhi. R36/37/38 Irritante per gli occhi, le vie respiratorie e la pelle. R42/43 Può provocare sensibilizzazione per inalazione e contatto con la pelle. R52 Nocivo per gli organismi acquatici.
Un cambiamento significativo dalla versione precedente viene indicato con una doppia barra.
Le informazioni riportate in questa Scheda di Sicurezza sono corrette secondo le nostre migliori conoscenze del prodotto al momento della pubblicazione. Tali informazioni vengono fornite con l'unico scopo di consentire l'utilizzo,
SCHEDA DI DATI DI SICUREZZA secondo il Regolamento (CE)
Num. 1907/2006
Oxone(R) Monopersulfate compound PS-16
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Data di revisione 13.10.2010 Ref.130000026038
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lo stoccaggio, il trasporto e lo smaltimento del prodotto nei modi più corretti e sicuri. Queste informazioni non devono considerarsi una garanzia od una specifica della qualità del prodotto. Le informazioni precedenti si riferiscono solo a quel materiale(i) indicato qui e possono essere non valide per lo stesso materiale ma usato in combinazione con altri materiali o in qualche procedimento o ancora se il materiale è alterato o ha subito un procedimento, salvo nel caso in cui si trovino indicazioni nel testo.
SCHEDA DI DATI DI SICUREZZA secondo il Regolamento (CE)
Num. 1907/2006
Oxone(R) Monopersulfate compound PS-16
Versione 3.0
Data di revisione 13.10.2010 Ref.130000026038
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1 Exposure Scenario (1) Pentapotassium bis(peroxymonosulphate) bis(sulphate)
Formulation of KPMS based products SU 3, 10
PROC 1, 2, 3, 4, 5, 8a, 8b, 9, 14, 15
PC 14, 20, 21, 35, 37, 39
ERC 2
Closed and batch processes incl. sampling and maintenance, mixing/blending, pelletting, tabletting, compression, transfers,
packaging and laboratory uses
Scenario name Process Category
(PROC) Short name
Closed continuous process PROC 1 CS 1
Closed continuous process – occasional
controlled PROC 2
CS 2
Closed batch process PROC 3 CS 3
Batch and other process with opportunity
for exposure PROC 4
CS 4
Mixing and blending PROC 5 CS 5
Transfers – non-dedicated equipment PROC 8a CS 6
Transfers – dedicated equipment PROC 8b CS 7
Transfer and packaging PROC 9 CS 8
Compression, tabletting, pelletisation PROC 14 CS 9
Laboratory use PROC 15 CS 10
2.1 Contributing scenario (1) controlling environmental exposure for …
Formulation of KPMS based products
Product characteristics
Concentration: 100%
Amounts used
1000 t/year or 3333 kg/day
Frequency and duration of use
Continuous, Release/emission: ≥ 300 days / year
Environment factors not influenced by risk management
Dilution factor river: 10
Dilution factor marine: 100
Technical conditions and measures at process level (source) to prevent release
Containment according to definition of PROCs / activities in CS
Product storage in appropriate packaging
Dry cleaning of containers and equipment and disposal via solid waste in order to minimize releases.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Air
Exhaust air passed through scrubber or dust filter (≥ 80% efficiency)
Waste water:
Minimize releases to waste water and avoid release to exceed 2 kg/day and discharge to STP.
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Use of STP (freshwater and marine): total removal > 91% If release to wastewater would exceed 2 kg/day, pre-treatment of
waste water is required by adding sodium sulfite (procedure provided results in 95% reduction).
General Product transport, delivery and storage in appropriate packaging
Immediate dry removal and disposal of spills, avoid dispersing of spilled material, minimize run-off, and release to soil,
water bodies, drains and sewers
Conditions and measures related to municipal sewage treatment plant
Effluent rate of municipal STP: 2000 m3/day
River flow arte: 18000 m3/day
Conditions and measures related to external treatment of waste for disposal
Batches out of specifications are blended or disposed according to official regulations.
Cleaning solutions are disposed of according to official local and regional regulations.
Dust filters are disposed of according to official local and regional regulations or regenerated/washed and solutions are
disposed of according to official local and regional regulations.
2.2 Contributing scenarios controlling worker exposure for …
Formulation of KPMS based products
Product characteristic
Physical state: solid
Dustiness: medium (max. 0.174% particles < 10 µm)
Concentration: 100%
Frequency and duration of use/exposure
Exposure frequency: daily for all PROCs
Contributing Scenario Duration
CS 1 >4 hours (default)
CS 2 >4 hours (default)
CS 3 >4 hours (default)
CS 4 >4 hours (default)
CS 5 1 - 4 hours
CS 6 >4 hours (default)
CS 7 >4 hours (default)
CS 8 >4 hours (default)
CS 9 >4 hours (default)
CS 10 >4 hours (default)
Other given operational conditions affecting workers exposure
Scenario name Ventilation
CS 1 Indoors without LEV
CS 2 Indoors with LEV
CS 3 Indoors with LEV
CS 4 Indoors with LEV
CS 5 Indoors with LEV
CS 6 Indoors with LEV
CS 7 Indoors with LEV
CS 8 Indoors with LEV
CS 9 Indoors with LEV
CS 10 Indoors with LEV
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Technical conditions and measures at process level (source) to prevent release
Handling in industrial settings
Containment according to definition of PROCs / activities in CS
Product storage in appropriate packaging
Technical conditions and measures to control dispersion from source towards the worker
Local exhaust ventilation as defined for PROCs in CSs
Conditions and measures related to personal protection, hygiene and health evaluation
Limit potential skin exposure to two hands and face (480 cm2) by protective clothing
Respiratory protection in table below refers to min. APF 10 (90% exposure reduction) or min. APF 20 (95% exposure
reduction), where applicable.
As the substance is corrosive, additional Personal Protection Equipment is recommended as good industrial practice advice
below.
Contributing Scenario Respiratory protection / efficiency Dermal PPE – Gloves
CS 1 No no
CS 2 No no
CS 3 No no
CS 4 0.95 no
CS 5 0.95 gloves-basic training - APF 10
CS 6 0.95 no
CS 7 0.95 no
CS 8 0.95 no
CS 9 0.9 no
CS 10 No no
See section 4 and 8 of SDS
3. Exposure estimation and reference to its source
Quantitative risk characterisation for workers Toxicity Endpoint
CS # Risk Characterisation Ratio
Inhalation Dermal Combined
Acute – systemic effects
CS 1 4.00E-04 4.29E-03 4.69E-03
CS 2 2.00E-03 1.71E-03 3.71E-03
CS 3 4.00E-03 4.29E-04 4.43E-03
CS 4 1.00E-03 8.57E-03 9.57E-03
CS 5 1.00E-03 8.57E-05 1.09E-03
CS 6 1.00E-03 1.71E-03 2.71E-03
CS 7 5.00E-04 8.57E-03 9.07E-03
CS 8 1.00E-03 8.57E-03 9.57E-03
CS 9 4.00E-04 4.29E-03 4.69E-03
CS 10 2.00E-03 4.29E-04 2.43E-03
Acute - local effects
CS 1 4.00E-04 2.17E-01 n/a
CS 2 2.00E-03 1.05E-02 n/a
CS 3 4.00E-03 2.64E-03 n/a
CS 4 1.00E-03 5.27E-02 n/a
CS 5 1.00E-03 5.27E-04 n/a
CS 6 1.00E-03 1.05E-02 n/a
CS 7 5.00E-04 5.27E-02 n/a
CS 8 1.00E-03 5.27E-02 n/a
CS 9 4.00E-04 1.09E-01 n/a
CS 10 2.00E-03 2.17E-02 n/a
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Long-term - systemic effects
CS 1 3.57E-02 1.71E-02 5.29E-02
CS 2 1.79E-01 6.86E-03 1.85E-01
CS 3 3.57E-01 1.71E-03 3.59E-01
CS 4 8.93E-02 3.43E-02 1.24E-01
CS 5 5.36E-02 3.43E-04 5.39E-02
CS 6 8.93E-02 6.86E-03 9.61E-02
CS 7 4.46E-02 3.43E-02 7.89E-02
CS 8 8.93E-02 3.43E-02 1.24E-01
CS 9 3.57E-02 1.71E-02 5.29E-02
CS 10 1.79E-01 1.71E-03 1.80E-01
Long-term – local effects
CS 1 3.57E-02 - -
CS 2 1.79E-01 - -
CS 3 3.57E-01 - -
CS 4 8.93E-02 - -
CS 5 5.36E-02 - -
CS 6 8.93E-02 - -
CS 7 4.46E-02 - -
CS 8 8.93E-02 - -
CS 9 3.57E-02 - -
CS 10 1.79E-01 - -
Quantitative risk characterisation for humans exposed via the environment
Route Risk
characterisation
ratio
Inhalation- systemic
(long-term)
2.72E-02
Oral- systemic (long-
term)
3.38E-02
Risk characterisation for the aquatic compartment
Compartments PEC/PNEC
Freshwater 4.17E-01
Marine water 4.59E-01
Sediment freshwater 4.23E-01
Sediment freshwater 4.16E-01
Aquatic freshwater food
chain
1.21E-04
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Aquatic marine water food
chain
2.57E-06
Risk characterisation for the terrestrial compartment
Compartments PEC/PNEC
Agricultural soil (average
30 days)
7.12E-06
Grassland 1.29E-05
Terrestrial food chain
(earth worm)
4.75E-07
Risk characterisation for the microbial activity
Compartments PEC/PNEC
STP 8.44E-04
Assessment method:
Worker Dermal, Inhalation: ECETOC TRA (May 2010)
Environmental: ECETOC TRA (May 2010)
4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES
Environmental exposure
If conditions differ from those listed in ES Parts 2.1 & 3, downstream user (DU) should check whether they are
still within the boundaries of the ES (i.e., RCR < 1). The following equation may be used for scaling:
ESem
Actualem
Actualem
ESem
ES
ActualESActual
f
f
T
T
M
MRCRRCR
,
,
,
,
Where
RCRES is the risk characterisation ratio (unitless) (see ES Part 3)
MES is the quantity of substance processed or used per year per site (tonnes/year) (see ES Part 2.1)
Tem,ES is the duration of emission (days/year) (see ES Part 2.1)
fem,ES is the fraction of substance emitted from the process or use to air, water or soil (unitless) (see ES Part 3)
Instead of fem,ES, the actual release rates of substance emitted may be used and the following values were used in
the assessment: Compartments Release from point source (local exposure estimation)
Air 1.67E+01 kg/d
Wastewater 2.00E+00 kg/d
Surface water 0.00E+00 kg/d
Industrial soil 3.33E-01 kg/d
Agricultural soil 0.00E+00 kg/d
MActual, Tem,Actual and fem,Actual (or release rates) are the corresponding actual parameters as known to the DU, and
RCRActual is the resulting scaled risk characterisation ratio.
Note: While scaling on conditions and RMMs related to the primary risk driving environmental compartment (i.e.
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highest RCR), be cautious not to exceed limitations set through the next limiting compartment (compare RCRs).
Worker exposure
Scaling information for worker assessments based on ECETOC TRA:
RCRs = RCRo * CFs / CFo RCRo = original exposure prediction
PCRs = scaled exposure prediction
can be used for multiple determinants in series CFo = original correction factor
e.g. CF1, CF2, CF3 CFs = correction factor for scaling
RPE
efficiency
Duration of activity
[DA]
Non-solid
substance*
in
preparation
[PREP]
Correction
factor
RPE
efficiency
[%] [-]
Correction
factor
> 4 hours > 25% 1 No RMM =
0%
0 1
1-4 hours 5-25% 0.6 90% 0.9 0.1
15 minutes to 1
hour
1-5% 0.2 95% 0.95 0.05
< 15 minutes < 1% 0.1 fraction (1-fraction)
Scaling for LEV:
LEV efficiency in professional settings: PROC 24 (solids) = 75%; PROC 8b (volatiles); PROC 17, PROC 18 =
90%, all other PROCs = 80% except: PROC 1, PROC 7, PROC 12 (solids), PROC 21 (volatiles), PROC 23
(volatiles), PROC 24 (volatiles), PROC 25 (volatiles), PROC 22 = n/a
LEV efficiency in industrial settings: PROC 12 (volatiles), PROC 24 (solids) = 80%; PROC 8b - volatiles = 97%;
PROC 7, PROC 8b - solids, PROC 17, PROC 18 = 95%, all other PROCs = 90% except: PROC 1, PROC 12
(solids), PROC 11, PROC 20, PROC 21 (volatiles), PROC 22 (volatiles), PROC 23 (volatiles), PROC 24
(volatiles), PROC 25 (volatiles) = n/a
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1 Exposure Scenario (2) Pentapotassium bis(peroxymonosulphate) bis(sulphate)
Denture Cleaner, Consumer Use
SU 21
PC 39
ERC 8b
Scenario name Product Category
(PC)
Short
name
Cosmetics, personal care products PC39 CS 1
2.1 Contributing scenario (1) controlling environmental exposure for
Denture Cleaner, Consumer Use
Product characteristics
Concentration: max. 100 % solid, max. 10% KMPS (triple salt) in preparation
Physical state: solid tablets, liquid preparation
Packaging: moisture-resistant packaging, tablets tubes
Amounts used
Annual amount supplied to consumers: max. 2000 t/year – wide dispersive use, fraction to region 0.1
Fraction of the main local source: 0.0005 (equal temporal and spatial distribution of release)
Frequency and duration of use
Continuous release – wide dispersive use; 365 days/year
Environment factors not influenced by risk management
Dilution factor river: 10
Dilution factor marine: 100
Other given operational conditions affecting environmental exposure
None.
Conditions and measures related to municipal sewage treatment plant
Effluent rate of municipal STP: 2000 m3/day
River flow arte: 18000 m3/day
Conditions and measures related to external treatment of waste for disposal
Household waste water is treated in municipal sewage treatment plants.
2.2 Contributing scenarios controlling consumer exposure for
Denture Cleaner, Consumer Use
Product characteristic
Concentration: max. 10% KMPS (triple salt) in preparation
Physical state: solid tablets, liquid preparation
Packaging: moisture-resistant packaging, tablets tubes
Amounts used
Used amount per event per day:
max. 10 g/day/consumer, usual application: in 100 mL cleaning solution
Frequency and duration of use/exposure
Duration [for contact]: max. 0.25 hours
Frequency [for one person]: once a day, 365 days/year
Human factors not influenced by risk management
Consumers may be exposed to the solid (tablet) formulation when dosing the product into water and to the preparation
(cleaning solution; inhalation, dermal, oral). Exposure to the solution predominantly occurs by misuse such as poor rinsing
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of the denture after use, spilling to skin or drinking of the cleaning solution.
Other given operational conditions affecting consumers exposure
The product is used indoors only. Indoor air volume: min. 4 m3, ventilation rate: min. 0.5/h
Conditions and measures related to information and behavioural advice to consumers
Safety and application notes on product label and/or package insert.
Conditions and measures related to personal protection and hygiene
See section 8 MSDS
3. Exposure estimation and reference to its source
Quantitative risk characterisation for ES 2 – Consumers - Adult Route Risk characterisation ratio Acute - systemic effects
Dermal (mg/kg/bw)
0.0201
Inhalation (mg/m
3)
0.0017
Oral (mg/kg/bw)
0.833
Acute - local effects
Dermal (mg/cm
2)
0.473
Inhalation (mg/m
3)
0.0017
Long-term - systemic effects
Dermal (mg/kg bw/d)
0.0833
Inhalation (mg/m
3)
0.0032
Oral (mg/kg bw/d)
0.833
Long-term – local effects
Inhalation (mg/m
3)
0.0032
Quantitative risk characterisation for ES 2 – Consumers - Children Route Risk characterisation ratio Acute - systemic effects
Dermal (mg/kg/bw)
0.0625
Inhalation (mg/m
3)
0.0017
Oral (mg/kg/bw)
0.833
Acute - local effects
Dermal (mg/cm
2)
0.473
Inhalation (mg/m
3)
0.0017
Long-term - systemic effects
Dermal (mg/kg bw/d)
0.25
Inhalation (mg/m
3)
0.0032
Oral (mg/kg bw/d)
0.50
Long-term – local effects
Inhalation (mg/m
3)
0.0032
Quantitative risk characterisation for humans exposed via the environment
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Route Risk
characterisation
ratio*
Inhalation- systemic
(long-term)
1.30E-09
Oral- systemic (long-
term)
3.08E-07
Risk characterisation for the aquatic compartment
Compartments PEC/PNEC
Freshwater 3.99E-03
Marine water 4.33E-03
Sediment freshwater 4.05E-03
Sediment freshwater 3.93E-03
Aquatic freshwater food
chain
2.39E-06
Aquatic marine water food
chain
2.04E-07
Terrestrial compartment (including secondary poisoning)
Compartments PEC/PNEC
Agricultural soil (average
30 days)
1.25E-06
Grassland 1.25E-06
Terrestrial food chain
(earth worm)
1.03E-07
Microbiological activity in sewage treatment systems
Compartments PEC/PNEC
STP 2.31E-06
Assessment method: (defaults used)
Consumer exposure (Oral, Dermal, Inhalation) ConsExpo 4.1 (May 2010)
Environmental: ECETOC TRA (May 2010)
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1 Exposure Scenario (3) Pentapotassium bis(peroxymonosulphate) bis(sulphate)
Professional use of KPMS in pool and spa applications
SU 22
PROC 8a, 13, 19
PC 35, 37
ERC 8e, 8b
Transfer, mixing/blending into aqueous solution, treatment of recreational water, cartridge cleaning by dipping.
Scenario name
Process Category
(PROC)
Type of
setting
Short
name
S1 Weigh out material for use – indoors PROC 8a industrial CS 1
S2 Dissolve in a bucket of pool water –
indoors
PROC 19 Industrial CS 2
S3 Add to pool - indoors PROC 8a industrial CS 3
S1 Weigh out material for use - outdoors PROC 8a Industrial CS 4
S2 Dissolve in a bucket of pool water -
outdoors
PROC 19 Industrial CS 5
S3 Add to pool - outdoors PROC 8a Industrial CS 6
Cartridge cleaning by dipping PROC 13 industrial CS 7
2.1 Contributing scenario (1) controlling environmental exposure for
Professional use of KPMS in pool and spa applications
Product characteristics
Concentration: solid form up to 100%,
Amounts used
Max. 2050 t/year
Frequency and duration of use
Continuous release – wide dispersive use; 365 days/year
Environment factors not influenced by risk management
Dilution factor river: 10
Dilution factor marine: 100
Technical conditions and measures at process level (source) to prevent release
Product storage in appropriate packaging
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Waste water:
Do not dispose off treated water immediately after treatment
Use of STP (freshwater and marine)
Conditions and measures related to municipal sewage treatment plant
Effluent rate of municipal STP: 2000 m3/day
River flow arte: 18000 m3/day
Conditions and measures related to external treatment of waste for disposal
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Cleaning solutions are disposed of according to official local and regional regulations.
2.2 Contributing scenarios controlling worker exposure for …
Professional use of KPMS in pool and spa applications
Product characteristic
Physical state: solid
Dustiness: medium for solid (max. 0.174% particles < 10 µm), low dustiness once in aqueous solution
Concentration: solid form 100%, in aqueous solution maximum 12%, max. 0.006 % application and post application of
recreational water; cartridge cleaning: 5% in product, 0.05% in dipping solution
Frequency and duration of use/exposure
Exposure frequency: daily for all PROCs
Scenario name Duration of activity [hours/day]
CS 1 1 - 4 hours
CS 2 15 mins to 1 hour
CS 3 15 mins to 1 hour
CS 4 1 - 4 hours
CS 5 15 mins to 1 hour
CS 6 15 mins to 1 hour
CS 7 less than 15 mins
Other given operational conditions affecting workers exposure
Scenario name Use of Ventilation
CS 1 Indoors without LEV
CS 2 Indoors without LEV
CS 3 Indoors without LEV
CS 4 Outdoors
CS 5 Outdoors
CS 6 Outdoors
CS 7 Indoors without LEV
Technical conditions and measures at process level (source) to prevent release
Handling in professional applications - indoors or outdoors
Product storage in appropriate packaging before use
Conditions and measures related to personal protection, hygiene and health evaluation
Limit potential skin exposure to two hands and face (480 cm2) by protective clothing
Respiratory protection with 90 – 95% exposure reduction (where applicable, see table below)
Gloves: at least 90% exposure reduction and basic training of workers (min. APF 10), PROC 19 at least 95% exposure
reduction and specific training of workers (min. APF 20), (e.g. butyl rubber, min. 0.5 mm, breakthrough time >8 hours) or
equivalent or higher APF, where applicable, see table below
Contributing
Scenario
Respiratory protection /
efficiency Dermal PPE – Gloves
CS 1 0.95 gloves-basic training - APF 10
CS 2 0.9 gloves-specific training - APF 20
CS 3 0.9 gloves-basic training - APF 10
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CS 4 0.95 gloves-basic training - APF 10
CS 5 0.9 gloves-specific training - APF 20
CS 6 0.9 gloves-basic training - APF 10
CS 7 0.9 gloves-basic training - APF 10
See section 8
3. Exposure estimation and reference to its source
Quantitative risk characterisation for workers Toxicity Endpoint
CS # Risk Characterisation Ratio
Inhalation Dermal Combined
Acute – systemic effects
CS 1 1.00E-02 1.71E-02 2.71E-02
CS 2 2.00E-03 8.84E-02 9.04E-02
CS 3 2.00E-03 1.71E-02 1.91E-02
CS 4 7.00E-03 1.71E-02 2.41E-02
CS 5 1.40E-03 8.84E-02 8.98E-02
CS 6 1.40E-03 1.71E-02 1.85E-02
CS 7 2.00E-03 1.71E-02 1.91E-02
Acute - local effects
CS 1 1.00E-02 1.05E-01 n/a
CS 2 2.00E-03 5.43E-01 n/a
CS 3 2.00E-03 1.05E-01 n/a
CS 4 7.00E-03 1.05E-01 n/a
CS 5 1.40E-03 5.43E-01 n/a
CS 6 1.40E-03 1.05E-01 n/a
CS 7 2.00E-03 4.35E-01 n/a
Long-term - systemic effects
CS 1 5.36E-01 6.86E-02 6.04E-01
CS 2 3.57E-02 3.54E-01 3.89E-01
CS 3 3.57E-02 6.86E-02 1.04E-01
CS 4 3.75E-01 6.86E-02 4.44E-01
CS 5 2.50E-02 3.54E-01 3.79E-01
CS 6 2.50E-02 6.86E-02 9.36E-02
CS 7 1.79E-02 6.86E-02 8.64E-02
Long-term – local effects
CS 1 5.36E-01 - -
CS 2 3.57E-02 - -
CS 3 3.57E-02 - -
CS 4 3.75E-01 - -
CS 5 2.50E-02 - -
CS 6 2.50E-02 - -
CS 7 1.79E-02 - -
Quantitative risk characterisation for humans exposed via the environment
Route Risk
characterisation
ratio*
Inhalation- systemic
(long-term)
1.30E-09
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Oral- systemic (long-
term)
5.47E-07
Risk characterisation for the aquatic compartment
Compartments PEC/PNEC
Freshwater 7.51E-03
Marine water 8.20E-03
Sediment freshwater 7.62E-03
Sediment freshwater 7.44E-03
Aquatic freshwater food
chain
3.62E-06
Aquatic marine water food
chain
2.28E-07
Terrestrial compartment (including secondary poisoning)
Compartments PEC/PNEC
Agricultural soil (average
30 days)
1.25E-06
Grassland 5.58E-06
Terrestrial food chain
(earth worm)
1.03E-07
Microbiological activity in sewage treatment systems
Compartments PEC/PNEC
STP 9.48E-06
Assessment method:
Worker Dermal, Inhalation: ECETOC TRA (May 2010)
Environmental: ECETOC TRA (May 2010)
4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES
Worker exposure
Scaling information for worker assessments based on ECETOC TRA:
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RCRs = RCRo * CFs / CFo RCRo = original exposure prediction
PCRs = scaled exposure prediction
can be used for multiple determinants in series CFo = original correction factor
e.g. CF1, CF2, CF3 CFs = correction factor for scaling
RPE
efficiency
Duration of activity
[DA]
Non-solid
substance*
in
preparation
[PREP]
Correction
factor
RPE
efficiency
[%] [-]
Correction
factor
> 4 hours > 25% 1 No RMM =
0%
0 1
1-4 hours 5-25% 0.6 90% 0.9 0.1
15 minutes to 1
hour
1-5% 0.2 95% 0.95 0.05
< 15 minutes < 1% 0.1 fraction (1-fraction)
Scaling for LEV:
LEV efficiency in professional settings: PROC 24 (solids) = 75%; PROC 8b (volatiles); PROC 17, PROC 18 =
90%, all other PROCs = 80% except: PROC 1, PROC 7, PROC 12 (solids), PROC 21 (volatiles), PROC 23
(volatiles), PROC 24 (volatiles), PROC 25 (volatiles), PROC 22 = n/a
LEV efficiency in industrial settings: PROC 12 (volatiles), PROC 24 (solids) = 80%; PROC 8b - volatiles = 97%;
PROC 7, PROC 8b - solids, PROC 17, PROC 18 = 95%, all other PROCs = 90% except: PROC 1, PROC 12
(solids), PROC 11, PROC 20, PROC 21 (volatiles), PROC 22 (volatiles), PROC 23 (volatiles), PROC 24
(volatiles), PROC 25 (volatiles) = n/a
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1 Exposure Scenario (4) Pentapotassium bis(peroxymonosulphate) bis(sulphate)
Use of KPMS as water treatment product(s) in pool and spa facilities and as cartridge cleaning by consumers
SU 21
PC 35, 37
ERC 8e
Scenario name Product Category
(PC)
Short
name
Making up of product solution and
application to pool/spa, PC35 CS 1
making up of product solution and cleaning
cartridges by dipping. PC37 CS2
2.1 Contributing scenario (1) controlling environmental exposure for
Use as water treatment products in pool and spa facilities and as cartridge cleaning by consumers
Product characteristics
Concentration: max. 100 % solid, liquid in preparation for water treatment max. 12 % mixing and
loading; max. 0.006 % application and post application, for cartridge cleaning 0.05% in solution for
dipping
Physical state: solid tablets or granules, liquid preparation
Packaging: small sachets (e.g. max. 100 g for cartridge cleaner), cans (max. 25 kg bulk bags) or pressed
into tablets up to 200 g and packed into pails.
Amounts used
Annual amount supplied to consumers: max. 2050 t/year
Frequency and duration of use
Continuous release – wide dispersive use; 365 days/year
(Indoor pool: max. 2 times/week
Outdoor pool: max. 2 times/week
Spa: max: 6 times/week
Cartridge cleaning: max 4 times/year)
Environment factors not influenced by risk management
Dilution factor river: 10
Dilution factor marine: 100
Other given operational conditions affecting environmental exposure
Effluent rate of municipal STP: 2000 m3/day
River flow rate: 18000 m3/day
Conditions and measures related to municipal sewage treatment plant
Household waste water is treated in municipal sewage treatment plants.
2.2 Contributing scenario (2) controlling consumer exposure for
Use as water treatment products in pool and spa facilities and as cartridge cleaning by consumers
Product characteristic
Concentration: solid up to 100 %; liquid in preparation for water treatment max. 12 % mixing and
loading; max. 0.006 % application and post application, for cartridge cleaning 0.05% in solution for
dipping
Physical state: solid (powder, tablets or granules)
Powder: medium dustiness max. 0.174 % particles below 10 µm;
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Granules: low dustiness
Packaging: small sachets (e.g. max. 100 g for cartridge cleaner), cans (max. 25 kg bulk bags) or pressed
into tablets up to 200 g and packed into pails.
Amounts used
Used amount per event per day:
Indoor: 1.2 kg per application (12 mg/L = g/m3 * 100 m
3 pool size)
Outdoor: 3.6 kg per application (12 mg/L = g/m3 * 300 m
3 pool size)
Spa: 0.6 kg per application (60 mg/L = g/m3 * 10 m
3 pool size)
Cartridge cleaning: max. 100 g per application
Frequency and duration of use/exposure
Frequency [for one person, adult]: up to 6 events/day (for professional swimmers)
Frequency [for one person, child]: 1 event/day
Frequency cartridge cleaning: max 4 events per year
Duration [for contact]: max. 0.5 hours/day mixing and loading
max. 1 hour/day application and post application
Duration for cartridge cleaning: 0.25 hours/day
Human factors not influenced by risk management
Consumers may be exposed during mixing and loading (dermal, oral, inhalation), during application and
post application of water treatment products and during dipping of cartridges. The exposure in treated
water may occur in public or consumer settings (inhalation, dermal, oral). No degradation effects
between dosage and exposure via treated water are considered.)
Other given operational conditions affecting consumers exposure
The product is used indoors and outdoors by consumers
Indoor air volume: min. 100 m3, 0.5/hr ventilation rate
Indoor pool size: max. 100 m3
Outdoor air volume: min. 300 m3, 0.5/hr ventilation rate
Outdoor pool size: max. 300 m3
Spa air volume: min. 10 m3, 0.5/hr ventilation rate
Spa size: max. 10 m3
Conditions and measures related to information and behavioural advice to consumers
Safety and application notes on product label and/or package insert.
3. Exposure estimation and reference to its source
Quantitative risk characterisation for ES 4 – Consumers - Adult Route Risk
characterisation ratio
Acute - systemic effects
Dermal (mg/kg/bw)
0.0003
Inhalation (mg/m
3)
0.0017
Oral (mg/kg/bw)
0.8
Acute - local effects
Dermal (mg/cm
2)
0.2727
Inhalation (mg/m
3)
0.0017
Long-term - systemic effects
Dermal (mg/kg bw/d)
0.0021
Inhalation (mg/m
3)
0.0757
Oral (mg/kg bw/d)
0.229
Long-term – Inhalation 0.0757
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local effects (mg/m3)
Quantitative risk characterisation for ES 4 - Consumers– Children Route Risk
characterisation ratio
Acute - systemic effects
Dermal (mg/kg/bw)
2.625E-03
Inhalation (mg/m
3)
4.52E-03
Oral (mg/kg/bw) 0.0299
Acute - local effects
Dermal (mg/cm
2)
0.2727
Inhalation (mg/m
3)
4.52E-03
Long-term - systemic effects
Dermal (mg/kg bw/d)
0.009
Inhalation (mg/m
3)
3.37E-03
Oral (mg/kg/bw/d)
0.0256
Long-term – local effects
Inhalation (mg/m
3)
3.37E-03
Assessment method:
Consumer exposure (Oral, Dermal, Inhalation) ConsExpo 4.1 (May 2010)
Environmental: ECETOC TRA (May 2010)
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1 Exposure Scenario (5) Pentapotassium bis(peroxymonosulphate) bis(sulphate)
Use of KPMS in Metal Surface Treatment - Industrial Use
SU 3, 14, 15, 16
PROC 1, 2, 3, 4, 5, 8a, 8b, 9, 13
PC 14
ERC 6b Closed and batch processes incl. sampling and maintenance, transfers, mixing/blending, treatment of articles by dipping and
pouring processes, pelletting, tabletting, compression, transfers
Scenario name Process Category
(PROC) Short name
Closed continuous process PROC 1 CS 1
Closed continuous process – occasional
controlled exposure
PROC 2 CS 2
Closed batch process PROC 3 CS 3
Batch and other process with opportunity for
exposure
PROC 4 CS 4
S1 RM is moved from storage area to
weighing area for scaled tank make up
PROC 8a CS 5
S1 RM is moved from storage area to
weighing area for scaled tank make up
PROC 8b CS 6
S2 Weighted RM is discharged from
bag/container for blending into water or
sulfuric acid solution.
PROC 5 CS 7
S3 Metal is processed through solution with
solution sampling/testing and replenishment
of RM
PROC 2 CS8
S4 Spent solution is dumped and tank is
cleaned
PROC 8b CS9
S5 Waste treatment of spent solution PROC 5 CS10
Dipping and pouring PROC 13 CS11
2.1 Contributing scenario (1) controlling environmental exposure for
Use in of KPMS in Metal Surface Treatment - Industrial Use
Product characteristics
Concentration: 100%
Amounts used
300 t/year or 1000 kg/day
Frequency and duration of use
Continuous, Release/emission: ≥ 300 days / year
Environment factors not influenced by risk management
Dilution factor river: 10
Dilution factor marine: 100
Other given operational conditions affecting environmental exposure
None
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Technical conditions and measures at process level (source) to prevent release
Containment according to definition of PROCs / activities in CS
Product storage in appropriate packaging
Dry cleaning of containers and equipment and disposal via solid waste in order to minimize releases
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Air
Exhaust air passed through scrubber or dust filter (≥ 80% efficiency)
Waste water:
Minimize releases to waste water and avoid release to exceed 2 kg/day and discharge to STP.
Use of STP (freshwater and marine): total removal > 91% (Ecetoc TRAM prediction)
If release to wastewater would exceed 2 kg/day, pre-treatment of waste water is required by adding sodium sulfite (procedure
provided results in 95% reduction)
Alternatively, cleaning solutions maybe collected and disposed off according to official local and regional regulations.
Conditions and measures related to municipal sewage treatment plant
Effluent rate of municipal STP: 2000 m3/days
River flow rate: 18000 m3/days
Conditions and measures related to external treatment of waste for disposal
Batches out of specifications are blended or disposed according to official regulations.
Cleaning solutions are disposed of according to official local and regional regulations.
Dust filters are disposed of according to official local and regional regulations or regenerated/washed and solutions are
disposed of according to official local and regional regulations
2.2 Contributing scenarios controlling worker exposure for …
Use in Metal Surface Treatment - Industrial Use
Product characteristic
Physical state: solid, during process also in liquid media
Dustiness: medium (max. 0.174% particles < 10 µm), low once in liquid media
Concentration: 100%
Frequency and duration of use/exposure
Exposure frequency: daily for all PROCs
Contributing Scenario Duration
CS 1 >4 hours (default)
CS 2 >4 hours (default)
CS 3 >4 hours (default)
CS 4 >4 hours (default)
CS 5 less than 15 mins
CS 6 less than 15 mins
CS 7 15 mins to 1 hour
CS 8 >4 hours (default)
CS 9 15 mins to 1 hour
CS 10 15 mins to 1 hour
CS 11 >4 hours (default)
Other given operational conditions affecting workers exposure
Scenario name Ventilation
CS 1 Indoors without LEV
CS 2 Indoors with LEV
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CS 3 Indoors with LEV
CS 4 Indoors with LEV
CS 5 Indoors without LEV
CS 6 Indoors without LEV
CS 7 Indoors with LEV
CS 8 Indoors without LEV
CS 9 Indoors without LEV
CS 10 Indoors without LEV
CS 11 Indoors without LEV
Technical conditions and measures at process level (source) to prevent release
Handling in industrial settings
Containment according to definition of PROCs
Product storage in appropriate packaging
Technical conditions and measures to control dispersion from source towards the worker
Local exhaust ventilation
Conditions and measures related to personal protection, hygiene and health evaluation
Limit potential skin exposure to two hands and face (480 cm2) by protective clothing
Respiratory protection in table below refers to min. APF 10 (90% exposure reduction) or min. APF 20 (95% exposure
reduction), where applicable.
As the substance is corrosive, additional Personal Protection Equipment is recommended as good industrial practice advice
below.
Contributing Scenario Respiratory protection / efficiency Dermal PPE – Gloves
CS 1 No no
CS 2 No no
CS 3 No no
CS 4 0.95 no
CS 5 0.95 gloves-basic training - APF 10
CS 6 0.95 gloves-basic training - APF 10
CS 7 0.9 gloves-basic training - APF 10
CS 8 No gloves-basic training - APF 10
CS 9 No gloves-basic training - APF 10
CS 10 No gloves-basic training - APF 10
CS 11 No gloves-basic training - APF 10
See section 8 of SDS
3. Exposure estimation and reference to its source
Quantitative risk characterisation for workers Toxicity Endpoint
CS # Risk Characterisation Ratio
Inhalation Dermal Combinedb
Acute – systemic effects
CS 1 4.00E-04 4.29E-03 4.69E-03
CS 2 2.00E-03 1.71E-03 3.71E-03
CS 3 4.00E-03 4.29E-04 4.43E-03
CS 4 1.00E-03 8.57E-03 9.57E-03
CS 5 1.00E-02 1.71E-02 2.71E-02
CS 6 1.00E-02 8.57E-03 1.86E-02
CS 7 2.00E-03 8.57E-05 2.09E-03
CS 8 4.00E-04 1.71E-03 2.11E-03
CS 9 4.00E-03 8.57E-03 1.26E-02
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CS 10 2.00E-02 1.71E-02 3.71E-02
CS 11 4.00E-03 1.71E-02 2.11E-02
Acute - local effects
CS 1 4.00E-04 2.17E-01 n/a
CS 2 2.00E-03 1.05E-02 n/a
CS 3 4.00E-03 2.64E-03 n/a
CS 4 1.00E-03 5.27E-02 n/a
CS 5 1.00E-02 1.05E-01 n/a
CS 6 1.00E-02 5.27E-02 n/a
CS 7 2.00E-03 5.27E-04 n/a
CS 8 4.00E-04 1.05E-02 n/a
CS 9 4.00E-03 5.27E-02 n/a
CS 10 2.00E-02 1.05E-01 n/a
CS 11 4.00E-03 4.35E-01 n/a
Long-term - systemic effects
CS 1 3.57E-02 1.71E-02 5.29E-02
CS 2 1.79E-01 6.86E-03 1.85E-01
CS 3 3.57E-01 1.71E-03 3.59E-01
CS 4 8.93E-02 3.43E-02 1.24E-01
CS 5 8.93E-02 6.86E-02 1.58E-01
CS 6 8.93E-02 3.43E-02 1.24E-01
CS 7 3.57E-02 3.43E-04 3.61E-02
CS 8 3.57E-02 6.86E-03 4.26E-02
CS 9 7.14E-02 3.43E-02 1.06E-01
CS 10 3.57E-01 6.86E-02 4.26E-01
CS 11 3.57E-01 6.86E-02 4.26E-01
Long-term – local effects
CS 1 3.57E-02 - -
CS 2 1.79E-01 - -
CS 3 3.57E-01 - -
CS 4 8.93E-02 - -
CS 5 8.93E-02 - -
CS 6 8.93E-02 - -
CS 7 3.57E-02 - -
CS 8 3.57E-02 - -
CS 9 7.14E-02 - -
CS 10 3.57E-01 - -
CS 11 3.57E-01 - -
Quantitative risk characterisation for humans exposed via the environment
Route Risk
characterisation
ratio*
Inhalation- systemic
(long-term)
3.26E-04
Oral- systemic (long-
term)
4.28E-04
Risk characterisation for the aquatic compartment
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Compartments PEC/PNEC
Freshwater 4.17E-01
Marine water 4.59E-01
Sediment freshwater 4.23E-01
Sediment freshwater 4.16E-01
Aquatic freshwater food
chain
1.21E-04
Aquatic marine water food
chain
2.57E-06
Risk characterisation for the terrestrial compartment
Compartments PEC/PNEC
Agricultural soil (average
30 days)
1.36E-06
Grassland 1.39E-06
Terrestrial food chain
(earth worm)
1.08E-07
Risk characterisation for the microbial activity
Compartments PEC/PNEC
STP 8.44E-04
Assessment method:
Worker Dermal, Inhalation: ECETOC TRA (May 2010)
Environmental: ECETOC TRA (May 2010)
4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES
Environmental exposure
If conditions differ from those listed in ES Parts 2.1 & 3, downstream user (DU) should check whether they are
still within the boundaries of the ES (i.e., RCR < 1). The following equation may be used for scaling:
ESem
Actualem
Actualem
ESem
ES
ActualESActual
f
f
T
T
M
MRCRRCR
,
,
,
,
Where
RCRES is the risk characterisation ratio (unitless) (see ES Part 3)
MES is the quantity of substance processed or used per year per site (tonnes/year) (see ES Part 2.1)
Tem,ES is the duration of emission (days/year) (see ES Part 2.1)
fem,ES is the fraction of substance emitted from the process or use to air, water or soil (unitless) (see ES Part 3)
Instead of fem,ES, the actual release rates of substance emitted may be used and the following values were used in
the assessment:
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Compartments Release from point source (local exposure estimation)
Air 1.67E+01 kg/d
Wastewater 2.00E+00 kg/d
Surface water 0.00E+00 kg/d
Industrial soil 3.33E-01 kg/d
Agricultural soil 0.00E+00 kg/d
MActual, Tem,Actual and fem,Actual (or release rates) are the corresponding actual parameters as known to the DU, and
RCRActual is the resulting scaled risk characterisation ratio.
Note: While scaling on conditions and RMMs related to the primary risk driving environmental compartment (i.e.
highest RCR), be cautious not to exceed limitations set through the next limiting compartment (compare RCRs).
Worker exposure
Scaling information for worker assessments based on ECETOC TRA:
RCRs = RCRo * CFs / CFo RCRo = original exposure prediction
PCRs = scaled exposure prediction
can be used for multiple determinants in series CFo = original correction factor
e.g. CF1, CF2, CF3 CFs = correction factor for scaling
RPE
efficiency
Duration of activity
[DA]
Non-solid
substance*
in
preparation
[PREP]
Correction
factor
RPE
efficiency
[%] [-]
Correction
factor
> 4 hours > 25% 1 No RMM =
0%
0 1
1-4 hours 5-25% 0.6 90% 0.9 0.1
15 minutes to 1
hour
1-5% 0.2 95% 0.95 0.05
< 15 minutes < 1% 0.1 fraction (1-fraction)
Scaling for LEV:
LEV efficiency in professional settings: PROC 24 (solids) = 75%; PROC 8b (volatiles); PROC 17, PROC 18 =
90%, all other PROCs = 80% except: PROC 1, PROC 7, PROC 12 (solids), PROC 21 (volatiles), PROC 23
(volatiles), PROC 24 (volatiles), PROC 25 (volatiles), PROC 22 = n/a
LEV efficiency in industrial settings: PROC 12 (volatiles), PROC 24 (solids) = 80%; PROC 8b - volatiles = 97%;
PROC 7, PROC 8b - solids, PROC 17, PROC 18 = 95%, all other PROCs = 90% except: PROC 1, PROC 12
(solids), PROC 11, PROC 20, PROC 21 (volatiles), PROC 22 (volatiles), PROC 23 (volatiles), PROC 24
(volatiles), PROC 25 (volatiles) = n/a
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1 Exposure Scenario (6) Pentapotassium bis(peroxymonosulphate) bis(sulphate)
Industrial use of KPMS as processing aid in chemical synthesis
SU 3, 9
PROC 1, 2, 3, 4, 8a, 8b, 15
PC 20
ERC 6b
Closed continuous or batch processes, including sampling and maintenance, transfers and laboratory applications
Scenario name Process Category
(PROC) Short name
Closed continuous process PROC 1 CS 1
Closed continuous process – occasional
controlled exposure
PROC 2 CS 2
Closed batch process PROC 3 CS 3
Batch and other process with opportunity
for exposure
PROC 4 CS 4
Transfers – non-dedicated equipment PROC 8a CS 5
Transfers - dedicated equipment PROC 8b CS 6
Laboratory use PROC 15 CS 7
2.1 Contributing scenario (1) controlling environmental exposure for
Industrial use of KPMS as processing aid in chemical synthesis
Product characteristics
Concentration: 100%
Amounts used
300 t/year or 1000 kg/day
Frequency and duration of use
Continuous, Release/emission: ≥ 300 days / year
Environment factors not influenced by risk management
Dilution factor river: 10
Dilution factor marine: 100
Technical conditions and measures at process level (source) to prevent release
Containment in process steps according to definition of PROCs
Product storage in appropriate packaging
Dry cleaning of containers and equipment and disposal via solid waste in order to minimize releases.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Air
Exhaust air passed through scrubber or dust filter (≥ 80% efficiency) and avoid release to air to exceed 30 kg/day
Waste water:
Minimize releases to waste water and avoid release to exceed 2 kg/day and discharge to STP.
Use of STP (freshwater and marine): total removal > 91% (Ecetoc TRAM prediction)
If release to wastewater would exceed 2 kg/day, pre-treatment of waste water is required by adding sodium sulfite (procedure
provided results in 95% reduction)
Alternatively, cleaning solutions maybe collected and disposed off according to official local and regional regulations.
Soil:
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Minimize releases to soil and avoid release to industrial soil to exceed 10 kg/day.
Conditions and measures related to municipal sewage treatment plant
Effluent rate of municipal STP: 2000 m3/days
River flow rate: 18000 m3/days
Conditions and measures related to external treatment of waste for disposal
Batches out of specifications are blended or disposed according to official regulations.
Cleaning solutions are disposed of according to official local and regional regulations.
Dust filters are disposed of according to official local and regional regulations or regenerated/washed and solutions are
disposed of according to official local and regional regulations.
2.2 Contributing scenarios controlling worker exposure for
Industrial use of KPMS as processing aid in chemical synthesis
Product characteristic
Physical state: solid
Dustiness: raw material - medium (max. 0.174% particles < 10 µm), used in liquid media – low fugacity
Concentration: 100%
Frequency and duration of use/exposure
Exposure frequency: daily for all PROCs
Contributing Scenario Duration
CS 1 >4 hours (default)
CS 2 >4 hours (default)
CS 3 >4 hours (default)
CS 4 >4 hours (default)
CS 5 >4 hours (default)
CS 6 >4 hours (default)
CS 7 >4 hours (default)
Other given operational conditions affecting workers exposure
Scenario name Ventilation
CS 1 Indoors without LEV
CS 2 Indoors without LEV
CS 3 Indoors with LEV
CS 4 Indoors with LEV
CS 5 Indoors with LEV
CS 6 Indoors with LEV
CS 7 Indoors with LEV
Technical conditions and measures at process level (source) to prevent release
Handling in industrial settings
Containment according to definition of PROCs / activities in CS
Product storage in appropriate packaging
Technical conditions and measures to control dispersion from source towards the worker
Local exhaust ventilation as specified in CSs
Conditions and measures related to personal protection, hygiene and health evaluation
See section 8
As the substance is corrosive, additional Personal Protection Equipment is recommended as good industrial practice advice
below.
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3. Exposure estimation and reference to its source
Quantitative risk characterisation for workers
Toxicity Endpoint
CS # Risk Characterisation Ratio
Inhalation Dermal Combinedb
Acute – systemic effects
CS 1 4.00E-04 4.29E-03 4.69E-03
CS 2 4.00E-04 1.71E-02 1.75E-02
CS 3 4.00E-04 4.29E-04 8.29E-04
CS 4 2.00E-03 8.57E-03 1.06E-02
CS 5 2.00E-03 1.71E-03 3.71E-03
CS 6 2.00E-04 8.57E-03 8.77E-03
CS 7 4.00E-04 4.29E-04 8.29E-04
Acute - local effects
CS 1 4.00E-04 2.17E-01 n/a
CS 2 4.00E-04 1.05E-01 n/a
CS 3 4.00E-04 2.64E-03 n/a
CS 4 2.00E-03 5.27E-02 n/a
CS 5 2.00E-03 1.05E-02 n/a
CS 6 2.00E-04 5.27E-02 n/a
CS 7 4.00E-04 2.17E-02 n/a
Long-term - systemic effects
CS 1 3.57E-02 1.71E-02 5.29E-02
CS 2 3.57E-02 6.86E-02 1.04E-01
CS 3 3.57E-02 1.71E-03 3.74E-02
CS 4 1.79E-01 3.43E-02 2.13E-01
CS 5 1.79E-01 6.86E-03 1.85E-01
CS 6 1.79E-02 3.43E-02 5.21E-02
CS 7 3.57E-02 1.71E-03 3.74E-02
Long-term – local effects
CS 1 3.57E-02 - -
CS 2 3.57E-02 - -
CS 3 3.57E-02 - -
CS 4 1.79E-01 - -
CS 5 1.79E-01 - -
CS 6 1.79E-02 - -
CS 7 3.57E-02 - -
Quantitative risk characterisation for humans exposed via the environment
Route Risk
characterisation
ratio*
Inhalation- systemic
(long-term)
3.26E-04
Oral- systemic (long-
term)
4.28E-04
Risk characterisation for the terrestrial compartment
Compartments PEC/PNEC
Agricultural soil (average
30 days)
1.36E-06
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Grassland 1.39E-06
Terrestrial food chain
(earth worm)
1.08E-07
Risk characterisation for the microbial activity
Compartments PEC/PNEC
STP 8.44E-04
Assessment method:
Worker Dermal, Inhalation: ECETOC TRA (May 2010)
Environmental: ECETOC TRA (May 2010)
4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES
Environmental exposure
If conditions differ from those listed in ES Parts 2.1 & 3, downstream user (DU) should check whether they are
still within the boundaries of the ES (i.e., RCR < 1). The following equation may be used for scaling:
ESem
Actualem
Actualem
ESem
ES
ActualESActual
f
f
T
T
M
MRCRRCR
,
,
,
,
Where
RCRES is the risk characterisation ratio (unitless) (see ES Part 3)
MES is the quantity of substance processed or used per year per site (tonnes/year) (see ES Part 2.1)
Tem,ES is the duration of emission (days/year) (see ES Part 2.1)
fem,ES is the fraction of substance emitted from the process or use to air, water or soil (unitless) (see ES Part 3)
Instead of fem,ES, the actual release rates of substance emitted may be used and the following values were used in
the assessment: Compartments Release from point source (local exposure estimation)
Air 1.67E+01 kg/d
Wastewater 2.00E+00 kg/d
Surface water 0.00E+00 kg/d
Industrial soil 3.33E-01 kg/d
Agricultural soil 0.00E+00 kg/d
MActual, Tem,Actual and fem,Actual (or release rates) are the corresponding actual parameters as known to the DU, and
RCRActual is the resulting scaled risk characterisation ratio.
Note: While scaling on conditions and RMMs related to the primary risk driving environmental compartment (i.e.
highest RCR), be cautious not to exceed limitations set through the next limiting compartment (compare RCRs).
Worker exposure
Scaling information for worker assessments based on ECETOC TRA:
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RCRs = RCRo * CFs / CFo RCRo = original exposure prediction
PCRs = scaled exposure prediction
can be used for multiple determinants in series CFo = original correction factor
e.g. CF1, CF2, CF3 CFs = correction factor for scaling
RPE
efficiency
Duration of activity
[DA]
Non-solid
substance*
in
preparation
[PREP]
Correction
factor
RPE
efficiency
[%] [-]
Correction
factor
> 4 hours > 25% 1 No RMM =
0%
0 1
1-4 hours 5-25% 0.6 90% 0.9 0.1
15 minutes to 1
hour
1-5% 0.2 95% 0.95 0.05
< 15 minutes < 1% 0.1 fraction (1-fraction)
Scaling for LEV:
LEV efficiency in professional settings: PROC 24 (solids) = 75%; PROC 8b (volatiles); PROC 17, PROC 18 =
90%, all other PROCs = 80% except: PROC 1, PROC 7, PROC 12 (solids), PROC 21 (volatiles), PROC 23
(volatiles), PROC 24 (volatiles), PROC 25 (volatiles), PROC 22 = n/a
LEV efficiency in industrial settings: PROC 12 (volatiles), PROC 24 (solids) = 80%; PROC 8b - volatiles = 97%;
PROC 7, PROC 8b - solids, PROC 17, PROC 18 = 95%, all other PROCs = 90% except: PROC 1, PROC 12
(solids), PROC 11, PROC 20, PROC 21 (volatiles), PROC 22 (volatiles), PROC 23 (volatiles), PROC 24
(volatiles), PROC 25 (volatiles) = n/a
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1 Exposure Scenario (7) Pentapotassium bis(peroxymonosulphate) bis(sulphate)
Use of KPMS as Intermediate in chemical synthesis - Industrial Use
SU 3, 9
PROC 1, 2, 3, 4, 5, 8a, 8b, 15
PC 19
ERC 6a
Closed continuous or batch processes, including sampling and maintenance, transfers and laboratory applications
Scenario name Process Category
(PROC) Short name
Closed continuous reactor process PROC 1 CS 1
Closed continuous reactor process –
occasional controlled exposure for
sampling
PROC 2 CS 2
Closed batch process with some
opportunity for exposure
PROC 3 CS 3
Batch and other process with greater
opportunity for exposure
PROC 4 CS 4
Mixing PROC 5 CS 5
Transfers – non-dedicated equipment PROC 8a CS 6
Transfers - dedicated equipment PROC 8b CS 7
Laboratory use PROC 15 CS 8
2.1 Contributing scenario (1) controlling environmental exposure for
Use of KPMS as Intermediate in chemical synthesis - Industrial Use
Product characteristics
Concentration: 100%
Amounts used
400 t/year or 1333 kg/day
Frequency and duration of use
Continuous, Release/emission: ≥ 300 days / year
Environment factors not influenced by risk management
Dilution factor river: 10
Dilution factor marine: 100
Technical conditions and measures at process level (source) to prevent release
Containment in process steps according to definition of PROCs
Product storage in appropriate packaging
Dry cleaning of containers and equipment and disposal via solid waste in order to minimize releases.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Air
Exhaust air passed through scrubber or dust filter (≥ 80% efficiency)
Waste water:
Minimize releases to waste water and avoid release to exceed 2 kg/day and discharge to STP.
Use of STP (freshwater and marine): total removal > 91% (Ecetoc TRA prediction)
If release to wastewater would exceed 2 kg/day, pre-treatment of waste water is required by adding sodium sulfite (procedure
provided results in 95% reduction)
Alternatively, cleaning solutions maybe collected and disposed off according to official local and regional regulations.
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Conditions and measures related to municipal sewage treatment plant
Effluent rate of municipal STP: 2000 m3/days
River flow rate: 18000 m3/days
Conditions and measures related to external treatment of waste for disposal
Batches out of specifications are blended or disposed according to official regulations.
Cleaning solutions are disposed of according to official local and regional regulations.
Dust filters are disposed of according to official local and regional regulations or regenerated/washed and solutions are
disposed of according to official local and regional regulations.
2.2 Contributing scenarios controlling worker exposure for
Use of KPMS as Intermediate in chemical synthesis - Industrial Use
Product characteristic
Physical state: solid
Dustiness: medium (max. 0.174% particles < 10 µm)
Concentration: 100%
Frequency and duration of use/exposure
Exposure frequency: daily for all PROCs
Contributing Scenario Duration
CS 1 >4 hours (default)
CS 2 >4 hours (default)
CS 3 >4 hours (default)
CS 4 >4 hours (default)
CS 5 1 - 4 hours
CS 6 >4 hours (default)
CS 7 >4 hours (default)
CS 8 >4 hours (default)
Other given operational conditions affecting workers exposure
Scenario name Ventilation
CS 1 Indoors without LEV
CS 2 Indoors with LEV
CS 3 Indoors with LEV
CS 4 Indoors with LEV
CS 5 Indoors with LEV
CS 6 Indoors with LEV
CS 7 Indoors with LEV
CS 8 Indoors with LEV
Technical conditions and measures at process level (source) to prevent release
Handling in industrial settings
Containment according to definition of PROCs / activities in CS
Product storage in appropriate packaging
Technical conditions and measures to control dispersion from source towards the worker
Local exhaust ventilation as specified in CSs
Conditions and measures related to personal protection, hygiene and health evaluation
Limit potential skin exposure to two hands and face (480 cm2) by protective clothing
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Respiratory protection in table below refers to min. APF 10 (90% exposure reduction) or min. APF 20 (95% exposure
reduction), where applicable.
As the substance is corrosive, additional Personal Protection Equipment is recommended as good industrial practice advice
below.
Contributing Scenario Respiratory protection / efficiency Dermal PPE – Gloves
CS 1 No no
CS 2 No no
CS 3 No no
CS 4 0.95 no
CS 5 0.95 gloves-basic training - APF 10
CS 6 0.95 no
CS 7 0.95 no
CS 8 0.9 no
See section 8
3. Exposure estimation and reference to its source
Quantitative risk characterisation for workers
Toxicity Endpoint
CS # Risk Characterisation Ratio
Inhalation Dermal Combinedb
Acute – systemic effects
CS 1 4.00E-04 4.29E-03 4.69E-03
CS 2 2.00E-03 1.71E-03 3.71E-03
CS 3 4.00E-03 4.29E-04 4.43E-03
CS 4 1.00E-03 8.57E-03 9.57E-03
CS 5 1.00E-03 8.57E-05 1.09E-03
CS 6 1.00E-03 1.71E-03 2.71E-03
CS 7 5.00E-04 8.57E-03 9.07E-03
CS 8 2.00E-04 8.57E-03 6.29E-04
Acute - local effects
CS 1 4.00E-04 2.17E-01 n/a
CS 2 2.00E-03 1.05E-02 n/a
CS 3 4.00E-03 2.64E-03 n/a
CS 4 1.00E-03 5.27E-02 n/a
CS 5 1.00E-03 5.27E-04 n/a
CS 6 1.00E-03 1.05E-02 n/a
CS 7 5.00E-04 5.27E-02 n/a
CS 8 2.00E-04 2.17E-02
Long-term - systemic effects
CS 1 3.57E-02 1.71E-02 5.29E-02
CS 2 1.79E-01 6.86E-03 1.85E-01
CS 3 3.57E-01 1.71E-03 3.59E-01
CS 4 8.93E-02 3.43E-02 1.24E-01
CS 5 5.36E-02 3.43E-04 5.39E-02
CS 6 8.93E-02 6.86E-03 9.61E-02
CS 7 4.46E-02 3.43E-02 7.89E-02
CS 8 1.79E-02 1.71E-03 1.96E-02
Long-term – local effects
CS 1 3.57E-02 - -
CS 2 1.79E-01 - -
CS 3 3.57E-01 - -
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CS 4 8.93E-02 - -
CS 5 5.36E-02 - -
CS 6 8.93E-02 - -
CS 7 4.46E-02 - -
CS 8 1.79E-02 - -
Quantitative risk characterisation for humans exposed via the environment
Route Risk
characterisation
ratio*
Inhalation- systemic
(long-term)
2.18E-02
Oral- systemic (long-
term)
2.70E-02
Risk characterisation for the aquatic compartment
Compartments PEC/PNEC
Freshwater 4.17E-01
Marine water 4.59E-01
Sediment freshwater 4.23E-01
Sediment freshwater 4.16E-01
Aquatic freshwater food
chain
1.21E-04
Aquatic marine water food
chain
2.57E-06
Risk characterisation for the terrestrial compartment
Compartments PEC/PNEC
Agricultural soil (average
30 days)
5.95E-06
Grassland 1.06E-05
Terrestrial food chain
(earth worm)
4.01E-07
Risk characterisation for the microbial activity
Compartments PEC/PNEC
STP 8.44E-04
Assessment method:
Worker Dermal, Inhalation: ECETOC TRA (May 2010)
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Environmental: ECETOC TRA (May 2010)
4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES
Environmental exposure
If conditions differ from those listed in ES Parts 2.1 & 3, downstream user (DU) should check whether they are
still within the boundaries of the ES (i.e., RCR < 1). The following equation may be used for scaling:
ESem
Actualem
Actualem
ESem
ES
ActualESActual
f
f
T
T
M
MRCRRCR
,
,
,
,
Where
RCRES is the risk characterisation ratio (unitless) (see ES Part 3)
MES is the quantity of substance processed or used per year per site (tonnes/year) (see ES Part 2.1)
Tem,ES is the duration of emission (days/year) (see ES Part 2.1)
fem,ES is the fraction of substance emitted from the process or use to air, water or soil (unitless) (see ES Part 3)
Instead of fem,ES, the actual release rates of substance emitted may be used and the following values were used in
the assessment: Compartments Release from point source (local exposure estimation)
Air 1.67E+01 kg/d
Wastewater 2.00E+00 kg/d
Surface water 0.00E+00 kg/d
Industrial soil 3.33E-01 kg/d
Agricultural soil 0.00E+00 kg/d
MActual, Tem,Actual and fem,Actual (or release rates) are the corresponding actual parameters as known to the DU, and
RCRActual is the resulting scaled risk characterisation ratio.
Note: While scaling on conditions and RMMs related to the primary risk driving environmental compartment (i.e.
highest RCR), be cautious not to exceed limitations set through the next limiting compartment (compare RCRs).
Worker exposure
Scaling information for worker assessments based on ECETOC TRA:
RCRs = RCRo * CFs / CFo RCRo = original exposure prediction
PCRs = scaled exposure prediction
can be used for multiple determinants in series CFo = original correction factor
e.g. CF1, CF2, CF3 CFs = correction factor for scaling
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RPE
efficiency
Duration of activity
[DA]
Non-solid
substance*
in
preparation
[PREP]
Correction
factor
RPE
efficiency
[%] [-]
Correction
factor
> 4 hours > 25% 1 No RMM =
0%
0 1
1-4 hours 5-25% 0.6 90% 0.9 0.1
15 minutes to 1
hour
1-5% 0.2 95% 0.95 0.05
< 15 minutes < 1% 0.1 fraction (1-fraction)
Scaling for LEV:
LEV efficiency in professional settings: PROC 24 (solids) = 75%; PROC 8b (volatiles); PROC 17, PROC 18 =
90%, all other PROCs = 80% except: PROC 1, PROC 7, PROC 12 (solids), PROC 21 (volatiles), PROC 23
(volatiles), PROC 24 (volatiles), PROC 25 (volatiles), PROC 22 = n/a
LEV efficiency in industrial settings: PROC 12 (volatiles), PROC 24 (solids) = 80%; PROC 8b - volatiles = 97%;
PROC 7, PROC 8b - solids, PROC 17, PROC 18 = 95%, all other PROCs = 90% except: PROC 1, PROC 12
(solids), PROC 11, PROC 20, PROC 21 (volatiles), PROC 22 (volatiles), PROC 23 (volatiles), PROC 24
(volatiles), PROC 25 (volatiles) = n/a
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1 Exposure Scenario (8) Pentapotassium bis(peroxymonosulphate) bis(sulphate)
Industrial use of KPMS in pulp and paper treatment/production
SU 3, 6b
PROC 2, 4, 8a
PC 26, 37
ERC 6b
Continuous or batch processes for pulp/paper treatment, transfers, waste water (pre)treatment and laboratory uses
Scenario name
Process Category
(PROC) Short name
S1 RM is relocated to the repulp area
(very stable IBC using fork lift)
PROC 2 CS 1
S2 Repulpable bag is manually
transferred to the repulper.
PROC 8a CS 2
S3 Pulp slurry is carried to down stream
processes and fiber is separated from
process water.
PROC 4 CS 3
S4 Spent process water (pre)treatment
onsite
PROC 4 CS 4
Closed batch process PROC 2 CS 5
2.1 Contributing scenario (1) controlling environmental exposure for
Industrial use of KPMS in pulp and paper treatment/production
Product characteristics
Concentration: 100%
Amounts used
300 t/year or 1000 kg/day
Frequency and duration of use
Continuous, Release/emission: ≥ 300 days / year
Environment factors not influenced by risk management
Dilution factor river: 10
Dilution factor marine: 100
Technical conditions and measures at process level (source) to prevent release
Containment in process steps according to definition of PROCs
Product storage in appropriate packaging
Dry cleaning of containers and equipment and disposal via solid waste in order to minimize releases.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Air
Exhaust air passed through scrubber or dust filter (≥ 80% efficiency)
Waste water:
Minimize releases to waste water and avoid release to exceed 2 kg/day and discharge to STP.
Use of STP (freshwater and marine): total removal > 91% (Ecetoc TRA prediction)
If release to wastewater would exceed 2 kg/day, pre-treatment of waste water is required by adding sodium sulfite (procedure
provided results in 95% reduction)
Alternatively, cleaning solutions maybe collected and disposed off according to official local and regional regulations.
Conditions and measures related to municipal sewage treatment plant
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Effluent rate of municipal STP: 2000 m3/days
River flow rate: 18000 m3/days
Conditions and measures related to external treatment of waste for disposal
Cleaning solutions are disposed of according to official local and regional regulations.
Dust filters are disposed of according to official local and regional regulations or regenerated/washed and solutions are
disposed of according to official local and regional regulations.
2.2 Contributing scenarios controlling worker exposure for
Industrial use of KPMS in pulp and paper treatment/production
Product characteristic
Physical state: solid
Dustiness: medium (max. 0.174% particles < 10 µm)
Concentration: 100%
Frequency and duration of use/exposure
Exposure frequency: daily for all PROCs
Contributing Scenario Duration Frequency
CS 1 15 mins to 1 hour Daily
CS 2 less than 15 mins Daily
CS 3 1 - 4 hours Daily
CS 4 >4 hours (default) Daily
CS 5 less than 15 mins Daily
Other given operational conditions affecting workers exposure
Scenario name Ventilation
CS 1 Indoors with LEV
CS 2 Indoors with LEV
CS 3 Indoors with LEV
CS 4 Indoors with LEV
CS 5 Indoors without LEV
Technical conditions and measures at process level (source) to prevent release
Handling in industrial settings
Containment according to definition of PROCs / activities in CS
Product storage in appropriate packaging
Technical conditions and measures to control dispersion from source towards the worker
Local exhaust ventilation as specified in CSs
Conditions and measures related to personal protection, hygiene and health evaluation
Limit potential skin exposure to two hands and face (480 cm2) by protective clothing
Respiratory protection in table below refers to min. APF 10 (90% exposure reduction) or min. APF 20 (95% exposure
reduction), where applicable.
As the substance is corrosive, additional Personal Protection Equipment is recommended as good industrial practice advice
below.
Contributing Scenario Respiratory protection / efficiency Dermal PPE – Gloves
CS 1 No No
CS 2 No No
CS 3 0.9 No
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CS 4 0.95 No
CS 5 No gloves-basic training - APF 10
See section 8
3. Exposure estimation and reference to its source
Quantitative risk characterisation for workers
Toxicity Endpoint
CS # Risk Characterisation Ratio
Inhalation Dermal Combinedb
Acute – systemic effects
CS 1 2.00E-03 1.71E-03 3.71E-03
CS 2 2.00E-02 1.71E-03 2.17E-02
CS 3 2.00E-03 8.57E-03 1.06E-02
CS 4 1.00E-03 8.57E-03 9.57E-03
CS 5 2.00E-02 1.71E-03 2.17E-02
Acute - local effects
CS 1 2.00E-03 1.05E-02 n/a
CS 2 2.00E-02 1.05E-02 n/a
CS 3 2.00E-03 5.27E-02 n/a
CS 4 1.00E-03 5.27E-02 n/a
CS 5 2.00E-02 1.05E-02 n/a
Long-term - systemic effects
CS 1 3.57E-02 6.86E-03 4.26E-02
CS 2 3.57E-01 6.86E-03 3.64E-01
CS 3 1.07E-01 3.43E-02 1.41E-01
CS 4 8.93E-02 3.43E-02 1.24E-01
CS 5 1.79E-01 6.86E-03 1.85E-01
Long-term – local effects
CS 1 3.57E-02 - -
CS 2 1.79E-01 - -
CS 3 1.07E-01 - -
CS 4 8.93E-02 - -
CS 5 1.79E-01 - -
Quantitative risk characterisation for humans exposed via the environment
Route Risk
characterisation
ratio*
Inhalation- systemic
(long-term)
3.26E-04
Oral- systemic (long-
term)
4.28E-04
Risk characterisation for the aquatic compartment
Compartments PEC/PNEC
Agricultural soil (average
30 days)
1.36E-06
Grassland 1.39E-06
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Terrestrial food chain
(earth worm)
1.08E-07
Risk characterisation for the terrestrial compartment
Compartments PEC/PNEC
Agricultural soil (average
30 days)
5.95E-06
Grassland 1.06E-05
Terrestrial food chain
(earth worm)
4.01E-07
Risk characterisation for the microbial activity
Compartments PEC/PNEC
STP 8.44E-04
Assessment method:
Worker Dermal, Inhalation: ECETOC TRA (May 2010)
Environmental: ECETOC TRA (May 2010)
4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES
Environmental exposure
If conditions differ from those listed in ES Parts 2.1 & 3, downstream user (DU) should check whether they are
still within the boundaries of the ES (i.e., RCR < 1). The following equation may be used for scaling:
ESem
Actualem
Actualem
ESem
ES
ActualESActual
f
f
T
T
M
MRCRRCR
,
,
,
,
Where
RCRES is the risk characterisation ratio (unitless) (see ES Part 3)
MES is the quantity of substance processed or used per year per site (tonnes/year) (see ES Part 2.1)
Tem,ES is the duration of emission (days/year) (see ES Part 2.1)
fem,ES is the fraction of substance emitted from the process or use to air, water or soil (unitless) (see ES Part 3)
Instead of fem,ES, the actual release rates of substance emitted may be used and the following values were used in
the assessment: Compartments Release from point source (local exposure estimation)
Air 1.67E+01 kg/d
Wastewater 2.00E+00 kg/d
Surface water 0.00E+00 kg/d
Industrial soil 3.33E-01 kg/d
Agricultural soil 0.00E+00 kg/d
MActual, Tem,Actual and fem,Actual (or release rates) are the corresponding actual parameters as known to the DU, and
RCRActual is the resulting scaled risk characterisation ratio.
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Note: While scaling on conditions and RMMs related to the primary risk driving environmental compartment (i.e.
highest RCR), be cautious not to exceed limitations set through the next limiting compartment (compare RCRs).
Worker exposure
Scaling information for worker assessments based on ECETOC TRA:
RCRs = RCRo * CFs / CFo RCRo = original exposure prediction
PCRs = scaled exposure prediction
can be used for multiple determinants in series CFo = original correction factor
e.g. CF1, CF2, CF3 CFs = correction factor for scaling
RPE
efficiency
Duration of activity
[DA]
Non-solid
substance*
in
preparation
[PREP]
Correction
factor
RPE
efficiency
[%] [-]
Correction
factor
> 4 hours > 25% 1 No RMM =
0%
0 1
1-4 hours 5-25% 0.6 90% 0.9 0.1
15 minutes to 1
hour
1-5% 0.2 95% 0.95 0.05
< 15 minutes < 1% 0.1 fraction (1-fraction)
Scaling for LEV:
LEV efficiency in professional settings: PROC 24 (solids) = 75%; PROC 8b (volatiles); PROC 17, PROC 18 =
90%, all other PROCs = 80% except: PROC 1, PROC 7, PROC 12 (solids), PROC 21 (volatiles), PROC 23
(volatiles), PROC 24 (volatiles), PROC 25 (volatiles), PROC 22 = n/a
LEV efficiency in industrial settings: PROC 12 (volatiles), PROC 24 (solids) = 80%; PROC 8b - volatiles = 97%;
PROC 7, PROC 8b - solids, PROC 17, PROC 18 = 95%, all other PROCs = 90% except: PROC 1, PROC 12
(solids), PROC 11, PROC 20, PROC 21 (volatiles), PROC 22 (volatiles), PROC 23 (volatiles), PROC 24
(volatiles), PROC 25 (volatiles) = n/a
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1 Exposure Scenario (9) Pentapotassium bis(peroxymonosulphate) bis(sulphate)
Industrial use of KPMS as environmental processing aid
SU 3
PROC 1, 2, 3, 4, 8a, 8b, 15
PC 20, 37
ERC 6b
Continuous or batch processes for pulp/paper treatment, transfers, waste water (pre)treatment and laboratory uses
Scenario name
Process Category
(PROC) Short name
Closed continuous process PROC 1 CS 1
Closed continuous process – occasional
controlled exposure
PROC 2 CS 2
Closed batch process PROC 3 CS 3
Batch and other process with opportunity
for exposure
PROC 4 CS 4
Transfers – non-dedicated equipment PROC 8a CS 5
Transfers - dedicated equipment PROC 8b CS 6
Laboratory use PROC 15 CS 7
2.1 Contributing scenario (1) controlling environmental exposure for
Industrial use of KPMS as environmental processing aid
Product characteristics
Concentration: 100%
Amounts used
300 t/year or 1000 kg/
Frequency and duration of use
Continuous, Release/emission: ≥ 300 days / year
Environment factors not influenced by risk management
Dilution factor river: 10
Dilution factor marine: 100
Technical conditions and measures at process level (source) to prevent release
Containment in process steps according to definition of PROCs
Product storage in appropriate packaging
Dry cleaning of containers and equipment and disposal via solid waste in order to minimize releases.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Air
Exhaust air passed through scrubber or dust filter (≥ 80% efficiency)
Waste water:
Minimize releases to waste water and avoid release to exceed 2 kg/day and discharge to STP.
Use of STP (freshwater and marine): total removal > 91% (Ecetoc TRA prediction)
If release to wastewater would exceed 2 kg/day, pre-treatment of waste water is required by adding sodium sulfite (procedure
provided results in 95% reduction)
Alternatively, cleaning solutions maybe collected and disposed off according to official local and regional regulations.
Conditions and measures related to municipal sewage treatment plant
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Effluent rate of municipal STP: 2000 m3/days
River flow rate: 18000 m3/days
Conditions and measures related to external treatment of waste for disposal
Batches out of specifications are blended or disposed according to official regulations.
Cleaning solutions are disposed of according to official local and regional regulations.
Dust filters are disposed of according to official local and regional regulations or regenerated/washed and solutions are
disposed of according to official local and regional regulations.
2.2 Contributing scenarios controlling worker exposure for …
Industrial use of KPMS as environmental processing aid
Product characteristic
Physical state: solid
Dustiness: medium (max. 0.174% particles < 10 µm)
Concentration: 100%
Frequency and duration of use/exposure
Exposure frequency: daily for all PROCs
Contributing Scenario Duration
CS 1 >4 hours (default)
CS 2 >4 hours (default)
CS 3 >4 hours (default)
CS 4 >4 hours (default)
CS 5 >4 hours (default)
CS 6 >4 hours (default)
CS 7 >4 hours (default)
Other given operational conditions affecting workers exposure
Scenario name Ventilation
CS 1 Indoors without LEV
CS 2 Indoors with LEV
CS 3 Indoors with LEV
CS 4 Indoors with LEV
CS 5 Indoors with LEV
CS 6 Indoors with LEV
CS 7 Indoors with LEV
Technical conditions and measures at process level (source) to prevent release
Handling in industrial settings
Containment according to definition of PROCs / activities in CS
Product storage in appropriate packaging
Technical conditions and measures to control dispersion from source towards the worker
Local exhaust ventilation as specified in CSs
Conditions and measures related to personal protection, hygiene and health evaluation
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Limit potential skin exposure to two hands and face (480 cm2) by protective clothing
Respiratory protection in table below refers to min. APF 10 (90% exposure reduction) or min. APF 20 (95% exposure
reduction), where applicable.
As the substance is corrosive, additional Personal Protection Equipment is recommended as good industrial practice advice
below.
Contributing Scenario Respiratory protection / efficiency Dermal PPE – Gloves
CS 1 No No
CS 2 No No
CS 3 No No
CS 4 0.95 No
CS 5 0.95 No
CS 6 0.95 No
CS 7 0.9 No
See section 8
3. Exposure estimation and reference to its source
Quantitative risk characterisation for workers
Toxicity Endpoint
CS # Risk Characterisation Ratio
Inhalation Dermal Combinedb
Acute – systemic effects
CS 1 4.00E-04 4.29E-03 4.69E-03
CS 2 2.00E-03 1.71E-03 3.71E-03
CS 3 4.00E-03 4.29E-04 4.43E-03
CS 4 1.00E-03 8.57E-03 9.57E-03
CS 5 1.00E-03 1.71E-03 2.71E-03
CS 6 5.00E-04 8.57E-03 9.07E-03
CS 7 2.00E-04 8.57E-03 6.29E-04
Acute - local effects
CS 1 4.00E-04 2.17E-01 n/a
CS 2 2.00E-03 1.05E-02 n/a
CS 3 4.00E-03 2.64E-03 n/a
CS 4 1.00E-03 5.27E-02 n/a
CS 5 1.00E-03 1.05E-02 n/a
CS 6 5.00E-04 5.27E-02 n/a
CS 7 2.00E-04 2.17E-02
Long-term - systemic effects
CS 1 3.57E-02 1.71E-02 5.29E-02
CS 2 1.79E-01 6.86E-03 1.85E-01
CS 3 3.57E-01 1.71E-03 3.59E-01
CS 4 8.93E-02 3.43E-02 1.24E-01
CS 5 8.93E-02 6.86E-03 9.61E-02
CS 6 4.46E-02 3.43E-02 7.89E-02
CS 7 1.79E-02 1.71E-03 1.96E-02
Long-term – local effects
CS 1 3.57E-02 - -
CS 2 1.79E-01 - -
CS 3 3.57E-01 - -
CS 4 8.93E-02 - -
CS 5 8.93E-02 - -
CS 6 4.46E-02 - -
CS 7 1.79E-02 - -
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Quantitative risk characterisation for humans exposed via the environment
Route Risk
characterisation
ratio*
Inhalation- systemic
(long-term)
3.26E-04
Oral- systemic (long-
term)
4.28E-04
Risk characterisation for the aquatic compartment
Compartments PEC/PNEC
Freshwater 4.17E-01
Marine water 4.59E-01
Sediment freshwater 4.23E-01
Sediment freshwater 4.16E-01
Aquatic freshwater food
chain
1.21E-04
Aquatic marine water food
chain
2.57E-06
Risk characterisation for the terrestrial compartment
Compartments PEC/PNEC
Agricultural soil (average
30 days)
1.36E-06
Grassland 1.39E-06
Terrestrial food chain
(earth worm)
1.08E-07
Risk characterisation for the microbial activity
Compartments PEC/PNEC
STP 8.44E-04
Assessment method:
Worker Dermal, Inhalation: ECETOC TRA (May 2010)
Environmental: ECETOC TRA (May 2010)
4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES
Environmental exposure
If conditions differ from those listed in ES Parts 2.1 & 3, downstream user (DU) should check whether they are
still within the boundaries of the ES (i.e., RCR < 1). The following equation may be used for scaling:
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ESem
Actualem
Actualem
ESem
ES
ActualESActual
f
f
T
T
M
MRCRRCR
,
,
,
,
Where
RCRES is the risk characterisation ratio (unitless) (see ES Part 3)
MES is the quantity of substance processed or used per year per site (tonnes/year) (see ES Part 2.1)
Tem,ES is the duration of emission (days/year) (see ES Part 2.1)
fem,ES is the fraction of substance emitted from the process or use to air, water or soil (unitless) (see ES Part 3)
Instead of fem,ES, the actual release rates of substance emitted may be used and the following values were used in
the assessment: Compartments Release from point source (local exposure estimation)
Air 1.67E+01 kg/d
Wastewater 2.00E+00 kg/d
Surface water 0.00E+00 kg/d
Industrial soil 3.33E-01 kg/d
Agricultural soil 0.00E+00 kg/d
MActual, Tem,Actual and fem,Actual (or release rates) are the corresponding actual parameters as known to the DU, and
RCRActual is the resulting scaled risk characterisation ratio.
Note: While scaling on conditions and RMMs related to the primary risk driving environmental compartment (i.e.
highest RCR), be cautious not to exceed limitations set through the next limiting compartment (compare RCRs).
Worker exposure
Scaling information for worker assessments based on ECETOC TRA:
RCRs = RCRo * CFs / CFo RCRo = original exposure prediction
PCRs = scaled exposure prediction
can be used for multiple determinants in series CFo = original correction factor
e.g. CF1, CF2, CF3 CFs = correction factor for scaling
RPE
efficiency
Duration of activity
[DA]
Non-solid
substance*
in
preparation
[PREP]
Correction
factor
RPE
efficiency
[%] [-]
Correction
factor
> 4 hours > 25% 1 No RMM =
0%
0 1
1-4 hours 5-25% 0.6 90% 0.9 0.1
15 minutes to 1
hour
1-5% 0.2 95% 0.95 0.05
< 15 minutes < 1% 0.1 fraction (1-fraction)
Scaling for LEV:
LEV efficiency in professional settings: PROC 24 (solids) = 75%; PROC 8b (volatiles); PROC 17, PROC 18 =
90%, all other PROCs = 80% except: PROC 1, PROC 7, PROC 12 (solids), PROC 21 (volatiles), PROC 23
(volatiles), PROC 24 (volatiles), PROC 25 (volatiles), PROC 22 = n/a
SCHEDA DI DATI DI SICUREZZA secondo il Regolamento (CE)
Num. 1907/2006
Oxone(R) Monopersulfate compound PS-16
Versione 3.0
Data di revisione 13.10.2010 Ref.130000026038
54/54
LEV efficiency in industrial settings: PROC 12 (volatiles), PROC 24 (solids) = 80%; PROC 8b - volatiles = 97%;
PROC 7, PROC 8b - solids, PROC 17, PROC 18 = 95%, all other PROCs = 90% except: PROC 1, PROC 12
(solids), PROC 11, PROC 20, PROC 21 (volatiles), PROC 22 (volatiles), PROC 23 (volatiles), PROC 24
(volatiles), PROC 25 (volatiles) = n/a