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Paper Work-excess Volume

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Page 1: Paper Work-excess Volume

20

Page 2: Paper Work-excess Volume

Molar Mass Water 18.0153 g.mol-1 Molar Volume

HMI 99.176 g.mol-1

x H2O Density g/cc Density mol/ccV cc VE VE cal

0.0000 111.43621 0.000 0.00000

0.0199 0.89147 0.00914 109.44157 -0.139 -0.11414

0.0395 0.89256 0.00930 107.52235 -0.224 -0.22079

0.0821 0.89527 0.00968 103.33907 -0.432 -0.43071

0.1198 0.89759 0.01003 99.65903 -0.586 -0.59419

0.1594 0.90005 0.01044 95.81577 -0.730 -0.74591

0.1994 0.90285 0.01088 91.92423 -0.886 -0.88211

0.2498 0.90632 0.01149 87.05761 -1.043 -1.03417

0.3000 0.90981 0.01216 82.24551 -1.166 -1.16700

0.3499 0.91373 0.01291 77.45622 -1.290 -1.28104

0.4000 0.91767 0.01376 72.69685 -1.373 -1.37460

0.4529 0.92226 0.01478 67.67674 -1.449 -1.44591

0.5008 0.92661 0.01583 63.16670 -1.487 -1.48099

0.5041 0.92661 0.01590 62.87747 -1.468 -1.48227

0.5508 0.93105 0.01709 58.50249 -1.476 -1.48366

0.5992 0.93570 0.01851 54.01786 -1.444 -1.45129

0.6500 0.94101 0.02027 49.33349 -1.385 -1.38110

0.6990 0.94642 0.02230 44.84761 -1.291 -1.28169

0.7496 0.95251 0.02485 40.24938 -1.163 -1.15208

0.7994 0.95933 0.02797 35.75221 -1.010 -1.00298

0.8398 0.96550 0.03113 32.12558 -0.861 -0.86701

0.8799 0.97262 0.03503 28.54424 -0.696 -0.71503

0.9200 0.98118 0.04003 24.97822 -0.516 -0.53544

0.9599 0.99153 0.04663 21.44764 -0.315 -0.30885

0.9600 0.9916 0.04663 21.44397 -0.316 -0.30868

0.9699 0.99444 0.04862 20.56922 -0.260 -0.24112

0.9800 0.9971 0.05077 19.69568 -0.194 -0.16722

1.0000 18.021 0.000 0.00000

NEXP 26

O.F

No.of parameters= 7

A0= -5.923

A1= -0.845

A2= 1.031

A3= 1.456

A4= -2.619

A5= -2.221

A6= 0.000

-1.600

-1.400

-1.200

-1.000

-0.800

-0.600

-0.400

-0.200

0.000

0.0000 0.2000 0.4000

Ex

ce

ss

Vo

lum

e

Mol. fractionX1

Page 3: Paper Work-excess Volume

Water 18.021 cc/mol 0.999699

HMI 111.436 cc/mol 0.88998

Ecart ² Ecart

0.00000 0.00000

0.00062 -0.02496

0.00001 -0.00316

0.00000 -0.00126

0.00007 0.00815

0.00025 0.01586

0.00002 -0.00430

0.00009 -0.00930

0.00000 0.00086

0.00007 -0.00859

0.00000 0.00133

0.00001 -0.00262

0.00004 -0.00639

0.00020 0.01413

0.00006 0.00757

0.00005 0.00733

0.00001 -0.00376

0.00009 -0.00969

0.00011 -0.01071

0.00005 -0.00724

0.00004 0.00647

0.00036 0.01910

0.00038 0.01947

0.00004 -0.00601

0.00005 -0.00739

0.00034 -0.01856

0.00070 -0.02646

0.00000 0.00000

0.00369

0.01393

0.6000 0.8000 1.0000

Mol. fractionX1

Page 4: Paper Work-excess Volume

10.00 15.00 20.00 25.00 30.00 35.00

M1 0.5041 0.4959 0.92661 0.92223 0.91782 0.91338 0.90891 0.90440

M2 0.3000 0.7000 0.90981 0.90538 0.90091 0.89642 0.89191 0.88738

M3 0.6990 0.3010 0.94642 0.94229 0.93812 0.93390 0.92963 0.92532

M4 0.1594 0.8406 0.90005 0.89561 0.89115 0.88667 0.88219 0.87768

M5 0.8398 0.1602 0.96550 0.96188 0.95820 0.95447 0.95068 0.94683

M6 0.4000 0.6000 0.91767 0.91325 0.90879 0.90432 0.89981 0.89528

M7 0.5992 0.4008 0.93570 0.93142 0.92709 0.92272 0.91831 0.91386

M8 0.1198 0.8802 0.89759 0.89316 0.88870 0.88423 0.87975 0.87526

M9 0.8799 0.1201 0.97262 0.96930 0.96590 0.96245 0.95891 0.95531

M10 0.2498 0.7502 0.90632 0.90188 0.89741 0.89292 0.88842 0.88390

M11 0.7496 0.2504 0.95251 0.94850 0.94446 0.94036 0.93622 0.93202

M12 0.0395 0.9605 0.89256 0.88813 0.8837 0.87925 0.8748 0.87034

M13 0.9599 0.0401 0.99153 0.98932 0.98699 0.98454 0.98198 0.97929

M14 0.6500 0.3500 0.94101 0.93679 0.93253 0.92822 0.92388 0.91949

M15 0.3499 0.6501 0.91373 0.9093 0.90484 0.90036 0.89585 0.89132

M16 0.7994 0.2006 0.95933 0.95551 0.95164 0.94771 0.94373 0.93969

M17 0.1994 0.8006 0.90285 0.8984 0.89394 0.88946 0.88496 0.88045

M18 0.9200 0.0800 0.98118 0.97828 0.9753 0.97224 0.9691 0.96586

M19 0.0821 0.9179 0.89527 0.89084 0.88639 0.88194 0.87747 0.87299

M20 0.5508 0.4492 0.93105 0.92672 0.92234 0.91793 0.91348 0.909

M21 0.4529 0.5471 0.92226 0.91786 0.91342 0.90896 0.90446 0.89994

M22 0.9800 0.0200 0.9971 0.99556 0.9938 0.99186 0.98975 0.98748

M23 0.0199 0.9801 0.89147 0.88705 0.88262 0.87818 0.87374 0.86929

M24 0.9600 0.0400 0.9916 0.98939 0.98706 0.98461 0.98204 0.97935

M25 0.5008 0.4992 0.92661 0.92224 0.91783 0.91338 0.90891 0.9044

M26 0.9699 0.0301 0.99444 0.99249 0.9904 0.98816 0.9858 0.9833

Système H2O/Hexamethyleneimine

xH2OTemperature

xHMI

0.80000

0.85000

0.90000

0.95000

1.00000

1.05000

0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

Den

sit

y (

wate

r +

HM

I) g

/cc

X1=mol fraction of water

Page 5: Paper Work-excess Volume

X1=mol fraction of water

Page 6: Paper Work-excess Volume

40.00 45.00 50.00 55.00 60.00 65.00 70.00 75.00

0.89986 0.89528 0.89068 0.88603 0.88135 0.87663 0.87187 0.86707

0.88283 0.87826 0.87367 0.86905 0.86440 0.85973 0.85503 0.85031

0.92096 0.91655 0.91210 0.90759 0.90303 0.89842 0.89376 0.88904

0.87316 0.86863 0.86408 0.85951 0.85493 0.85032 0.84570 0.84106

0.94292 0.93893 0.93488 0.93076 0.92657 0.92230 0.91797 0.91357

0.89072 0.88614 0.88152 0.87688 0.87221 0.86750 0.86276 0.85799

0.90937 0.90485 0.90028 0.89567 0.89102 0.88632 0.88158 0.87678

0.87075 0.86623 0.86170 0.85715 0.85259 0.84800 0.84340 0.83879

0.95163 0.94787 0.94403 0.94012 0.93613 0.93206 0.92791 0.92342

0.87935 0.87479 0.87021 0.86560 0.86098 0.85633 0.85165 0.84694

0.92777 0.92347 0.91911 0.91470 0.91024 0.90571 0.90113 0.89649

0.86587 0.86139 0.8569 0.8524 0.8479 0.84337 0.83884 0.8343

0.97648 0.97355 0.9705 0.96734 0.96406 0.96066 0.95832 0.95448

0.91505 0.91058 0.90606 0.90149 0.89687 0.89221 0.8875 0.88274

0.88676 0.88218 0.87758 0.87294 0.86828 0.86359 0.85887 0.85412

0.93559 0.93144 0.92723 0.92295 0.91861 0.91421 0.90974 0.90521

0.87592 0.87137 0.86681 0.86222 0.85762 0.85299 0.84834 0.84367

0.96253 0.95911 0.95559 0.95198 0.94828 0.94447 0.9429 0.93807

0.86849 0.86399 0.85948 0.85495 0.85041 0.84586 0.84128 0.83669

0.90448 0.89993 0.89533 0.8907 0.88603 0.88131 0.87655 0.87176

0.89539 0.8908 0.88619 0.88154 0.87687 0.87215 0.86739 0.8626

0.98506 0.9825 0.9798 0.97698 0.97402 0.97094 0.96774 0.96439

0.86483 0.86037 0.8559 0.85142 0.84692 0.84242 0.83791 0.83338

0.97654 0.97361 0.97056 0.9674 0.96412 0.96072 0.9584 0.95496

0.89986 0.89529 0.89068 0.88604 0.88136 0.87663 0.87187 0.86708

0.98066 0.9779 0.97501 0.972 0.96888 0.96563 0.96325 0.96276

Système H2O/Hexamethyleneimine

Temperature

0.80000

0.85000

0.90000

0.95000

1.00000

1.05000

0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

Den

sit

y(w

ate

r+H

MI)

(g

/cc)

X2=Mol.Fraction of HMI

Series1

Series2

Series3

Series4

Series5

Page 7: Paper Work-excess Volume

X2=Mol.Fraction of HMI

Page 8: Paper Work-excess Volume

80.00

0.86222

0.84554

0.88427

0.83638

0.90909

0.85318

0.87195

0.83414

0.91878

0.84220

0.89179

0.82973

0.95636

0.87792

0.84932

0.90062

0.83895

0.93373

0.83207

0.86692

0.85776

0.9611

0.82884

0.96083

0.86224

0.9626

Système H2O/Hexamethyleneimine

Temperature

Series1

Series2

Series3

Series4

Series5

Series6

Page 9: Paper Work-excess Volume
Page 10: Paper Work-excess Volume

T Density Density.ExpDensity.Calulated Difference Diffrnc^2 Density cal.

K g/cc cm3.mol-1 cm3.mol-1 % % g/cc

273.16 0.89881 110.341 110.49584 -0.001399 0.00000 0.89755

273.66 0.89836 110.40 110.54621 -0.001354 0.00000 0.89715

274.16 0.89792 110.45 110.59667 -0.001320 0.00000 0.89674

274.66 0.89748 110.50 110.64720 -0.001287 0.00000 0.89633

275.16 0.89704 110.56 110.69781 -0.001254 0.00000 0.89592

275.66 0.89660 110.61 110.74849 -0.001221 0.00000 0.89551

276.16 0.89616 110.67 110.79925 -0.001188 0.00000 0.89510

276.66 0.89572 110.72 110.85008 -0.001156 0.00000 0.89469

277.16 0.89528 110.78 110.90100 -0.001124 0.00000 0.89428

277.66 0.89484 110.83 110.95199 -0.001092 0.00000 0.89386

278.16 0.89440 110.89 111.00305 -0.001060 0.00000 0.89345

278.66 0.89396 110.94 111.05420 -0.001029 0.00000 0.89304

279.16 0.89351 111.00 111.10542 -0.000986 0.00000 0.89263

279.66 0.89307 111.05 111.15672 -0.000955 0.00000 0.89222

280.16 0.89263 111.11 111.20810 -0.000924 0.00000 0.89181

280.66 0.89219 111.16 111.25955 -0.000894 0.00000 0.89139

281.16 0.89175 111.22 111.31109 -0.000864 0.00000 0.89098

281.66 0.89131 111.27 111.36270 -0.000834 0.00000 0.89057

282.16 0.89087 111.32 111.41440 -0.000804 0.00000 0.89015

282.66 0.89042 111.38 111.46617 -0.000763 0.00000 0.88974

283.16 0.88998 111.44 111.51802 -0.000734 0.00000 0.88933

283.66 0.88954 111.49 111.56995 -0.000705 0.00000 0.88891

284.16 0.88910 111.55 111.62196 -0.000676 0.00000 0.88850

284.66 0.88866 111.60 111.67405 -0.000648 0.00000 0.88808

285.15 0.88822 111.66 111.72518 -0.000610 0.00000 0.88768

285.66 0.88777 111.71 111.77848 -0.000581 0.00000 0.88725

286.16 0.88733 111.77 111.83081 -0.000553 0.00000 0.88684

286.66 0.88689 111.82 111.88323 -0.000525 0.00000 0.88642

287.16 0.88645 111.88 111.93572 -0.000498 0.00000 0.88601

287.66 0.88600 111.94 111.98830 -0.000460 0.00000 0.88559

288.16 0.88556 111.99 112.04096 -0.000433 0.00000 0.88518

288.66 0.88512 112.05 112.09370 -0.000407 0.00000 0.88476

289.16 0.88468 112.10 112.14652 -0.000381 0.00000 0.88434

289.66 0.88423 112.16 112.19943 -0.000344 0.00000 0.88393

290.16 0.88379 112.22 112.25242 -0.000318 0.00000 0.88351

290.66 0.88335 112.27 112.30549 -0.000293 0.00000 0.88309

291.15 0.88291 112.33 112.35758 -0.000258 0.00000 0.88268

291.65 0.88247 112.38 112.41082 -0.000234 0.00000 0.88226

292.16 0.88203 112.44 112.46521 -0.000219 0.00000 0.88184

292.65 0.88158 112.50 112.51755 -0.000174 0.00000 0.88143

293.15 0.88115 112.55 112.57103 -0.000161 0.00000 0.88101

293.65 0.88071 112.61 112.62461 -0.000137 0.00000 0.88059

294.15 0.88026 112.67 112.67827 -0.000103 0.00000 0.88017

Page 11: Paper Work-excess Volume

Density corrected

C3.mol-1

110.40881

110.46091

110.51308

110.56533

110.61766

110.67006

110.72254

110.77509

110.82772

110.88043

110.93322

110.98608

111.03903

111.09205

111.14514

111.19832

111.25158

111.30491

111.35832

111.41182

111.46539

111.51904

111.57277

111.62658

111.67940

111.73445

111.78850

111.84264

111.89686

111.95115

112.00553

112.05999

112.11454

112.16917

112.22387

112.27867

112.33244

112.38740

112.44354

112.49757

112.55278

112.60807

112.66345

Page 12: Paper Work-excess Volume

H2OMol.mass 18.0153 g.mol-1

T°C T k Density Volume.ExpVolume.Formula1Density.Formula1Volume.Calc.F1(corrected)

g/cm3

cm3/mol cm3/mol g/cm³ cm3/mol

0 273.15 0.999840 18.01818291 17.991 1.001 17.716

1 274.15 0.999899 18.01711973 17.996 1.001 17.725

2 275.15 0.999940 18.01638098 18.000 1.001 17.734

3 276.15 0.999964 18.01594857 18.005 1.001 17.743

4 277.15 0.999972 18.01580444 18.009 1.000 17.753

5 278.15 0.999964 18.01594857 18.013 1.000 17.762

6 279.15 0.999940 18.01638098 18.018 1.000 17.771

7 280.15 0.999901 18.01708369 18.022 1.000 17.780

8 281.15 0.999848 18.01803874 18.027 0.999 17.790

9 282.15 0.999781 18.01924621 18.031 0.999 17.799

10 283.15 0.999699 18.02072424 18.036 0.999 17.808

11 284.15 0.999605 18.02241886 18.041 0.999 17.818

12 285.15 0.999497 18.02436626 18.045 0.998 17.827

13 286.15 0.999377 18.02653053 18.050 0.998 17.837

14 287.15 0.999244 18.02892987 18.054 0.998 17.846

15 288.15 0.999099 18.03154642 18.059 0.998 17.856

16 289.15 0.998942 18.03438037 18.064 0.997 17.865

17 290.15 0.998774 18.03741387 18.068 0.997 17.875

18 291.15 0.998595 18.04064711 18.073 0.997 17.885

19 292.15 0.998404 18.04409838 18.077 0.997 17.894

20 293.15 0.998203 18.04773177 18.082 0.996 17.904

21 294.15 0.997991 18.0515656 18.087 0.996 17.914

22 295.15 0.997769 18.055582 18.091 0.996 17.923

23 296.15 0.997537 18.05978124 18.096 0.996 17.933

24 297.15 0.997295 18.06416356 18.101 0.995 17.943

25 298.15 0.997043 18.06872923 18.106 0.995 17.953

26 299.15 0.996782 18.0734604 18.110 0.995 17.963

27 300.15 0.996511 18.07837545 18.115 0.994 17.973

28 301.15 0.996232 18.0834384 18.120 0.994 17.982

29 302.15 0.995943 18.0886858 18.125 0.994 17.992

30 303.15 0.995645 18.0940998 18.130 0.994 18.002

31 304.15 0.995339 18.09966253 18.134 0.993 18.012

32 305.15 0.995024 18.10539243 18.139 0.993 18.022

33 306.15 0.994700 18.11128984 18.144 0.993 18.032

34 307.15 0.994369 18.11731862 18.149 0.993 18.043

35 308.15 0.994029 18.12351551 18.154 0.992 18.053

36 309.15 0.993681 18.1298626 18.159 0.992 18.063

37 310.15 0.993325 18.1363602 18.164 0.992 18.073

38 311.15 0.992962 18.14299037 18.168 0.992 18.083

39 312.15 0.992591 18.14977166 18.173 0.991 18.094

40 313.15 0.992212 18.15670441 18.178 0.991 18.104

41 314.15 0.991826 18.16377066 18.183 0.991 18.114

42 315.15 0.991432 18.17098903 18.188 0.990 18.124

43 316.15 0.991031 18.17834155 18.193 0.990 18.135

44 317.15 0.990623 18.18582851 18.198 0.990 18.145

45 318.15 0.990208 18.19345026 18.203 0.990 18.156

46 319.15 0.989786 18.20120713 18.208 0.989 18.166

47 320.15 0.989358 18.20908104 18.213 0.989 18.177

Page 13: Paper Work-excess Volume

48 321.15 0.988922 18.21710913 18.218 0.989 18.187

49 322.15 0.988480 18.22525494 18.224 0.989 18.198

50 323.15 0.988030 18.23355566 18.229 0.988 18.208

51 324.15 0.987575 18.24195631 18.234 0.988 18.219

52 325.15 0.987113 18.25049412 18.239 0.988 18.230

53 326.15 0.986644 18.25916947 18.244 0.987 18.241

54 327.15 0.986170 18.26794569 18.249 0.987 18.251

55 328.15 0.985688 18.27687869 18.254 0.987 18.262

56 329.15 0.985201 18.28591323 18.260 0.987 18.273

57 330.15 0.984708 18.29506818 18.265 0.986 18.284

58 331.15 0.984208 18.30436249 18.270 0.986 18.295

59 332.15 0.983702 18.31377795 18.275 0.986 18.306

60 333.15 0.983191 18.32329629 18.281 0.985 18.317

61 334.15 0.982674 18.33293646 18.286 0.985 18.328

62 335.15 0.982150 18.34271751 18.291 0.985 18.339

63 336.15 0.981621 18.35260248 18.296 0.985 18.350

64 337.15 0.981086 18.36261041 18.302 0.984 18.361

65 338.15 0.980546 18.37272295 18.307 0.984 18.372

66 339.15 0.980000 18.38295918 18.313 0.984 18.383

67 340.15 0.979448 18.3933195 18.318 0.983 18.394

68 341.15 0.978890 18.40380431 18.323 0.983 18.406

69 342.15 0.978328 18.41437636 18.329 0.983 18.417

70 343.15 0.977759 18.42509248 18.334 0.983 18.428

71 344.15 0.977186 18.43589654 18.340 0.982 18.440

72 345.15 0.976607 18.44682662 18.345 0.982 18.451

73 346.15 0.976022 18.45788312 18.351 0.982 18.463

74 347.15 0.975432 18.46904756 18.356 0.981 18.474

75 348.15 0.974838 18.48030134 18.362 0.981 18.486

76 349.15 0.974237 18.49170171 18.367 0.981 18.497

77 350.15 0.973632 18.50319217 18.373 0.981 18.509

78 351.15 0.973021 18.51481109 18.378 0.980 18.521

79 352.15 0.972406 18.52652082 18.384 0.980 18.532

80 353.15 0.971785 18.53835982 18.390 0.980 18.544

81 354.15 0.971159 18.55030948 18.395 0.979 18.556

82 355.15 0.970528 18.56237017 18.401 0.979 18.568

83 356.15 0.969893 18.57452317 18.407 0.979 18.579

84 357.15 0.969252 18.58680715 18.412 0.978 18.591

85 358.15 0.968606 18.59920339 18.418 0.978 18.603

86 359.15 0.967956 18.61169309 18.424 0.978 18.615

87 360.15 0.967300 18.6243151 18.430 0.978 18.627

88 361.15 0.966640 18.63703137 18.435 0.977 18.640

89 362.15 0.965975 18.64986154 18.441 0.977 18.652

90 363.15 0.965305 18.66280606 18.447 0.977 18.664

91 364.15 0.964630 18.67586536 18.453 0.976 18.676

92 365.15 0.963951 18.6890205 18.459 0.976 18.688

93 366.15 0.963266 18.70231068 18.465 0.976 18.701

94 367.15 0.962577 18.71569755 18.471 0.975 18.713

95 368.15 0.961884 18.72918148 18.476 0.975 18.725

96 369.15 0.961185 18.74280185 18.482 0.975 18.738

97 370.15 0.960482 18.75652016 18.488 0.974 18.750

98 371.15 0.959775 18.7703368 18.494 0.974 18.763

99 372.15 0.959062 18.78429132 18.500 0.974 18.776

100 373.15 0.958346 18.79832545 18.506 0.973 18.788

Page 14: Paper Work-excess Volume

44

101

Literature data

1- TRC Data bases for Chemistry and Engineering-TRC Thermodynamic tables, Version 1.1; thermodynamic research Center, The texas A&M University system: College Station, TX, 1994

2- Haar, L.; Gallagher, J.S.; Kell, G.S. NBS/NRC steam tables: Thermodynamic transport properties and computer programs for vapor and liquid states of water in SI units; Hemisphere Publishers: New York, 1984.

Page 15: Paper Work-excess Volume

dV1 d V 2

Density.Calc.F1(corrected)Volume.Deviation Deviation Deviation Volume for F2 Sp.d.Deviation

g/cm³ Mol.volume % corected % cm3/mol Mol.volume

1.017 0.091 -0.0015 -0.0171 17.8931 0.0156

1.016 0.085 -0.0012 -0.0165 17.9009 0.0135

1.016 0.080 -0.0009 -0.0159 17.9086 0.0116

1.015 0.074 -0.0006 -0.0154 17.9163 0.0099

1.015 0.069 -0.0004 -0.0148 17.9241 0.0084

1.014 0.065 -0.0001 -0.0143 17.9319 0.0071

1.014 0.060 0.0001 -0.0138 17.9396 0.0059

1.013 0.056 0.0003 -0.0133 17.9474 0.0049

1.013 0.052 0.0005 -0.0128 17.9552 0.0040

1.012 0.048 0.0007 -0.0124 17.9629 0.0032

1.012 0.045 0.0008 -0.0119 17.9707 0.0025

1.011 0.042 0.0010 -0.0115 17.9785 0.0019

1.011 0.039 0.0012 -0.0110 17.9863 0.0014

1.010 0.036 0.0013 -0.0106 17.9941 0.0010

1.009 0.033 0.0014 -0.0102 18.0020 0.0007

1.009 0.031 0.0015 -0.0098 18.0098 0.0005

1.008 0.029 0.0016 -0.0095 18.0176 0.0003

1.008 0.026 0.0017 -0.0091 18.0254 0.0001

1.007 0.024 0.0018 -0.0087 18.0333 0.0001

1.007 0.022 0.0018 -0.0084 18.0411 0.0000

1.006 0.021 0.0019 -0.0080 18.0490 0.0000

1.006 0.019 0.0019 -0.0077 18.0569 0.0000

1.005 0.017 0.0020 -0.0074 18.0647 0.0001

1.005 0.016 0.0020 -0.0071 18.0726 0.0002

1.004 0.015 0.0020 -0.0068 18.0805 0.0003

1.003 0.013 0.0020 -0.0065 18.0884 0.0004

1.003 0.012 0.0020 -0.0062 18.0963 0.0005

1.002 0.011 0.0020 -0.0059 18.1042 0.0007

1.002 0.010 0.0020 -0.0056 18.1121 0.0008

1.001 0.009 0.0020 -0.0054 18.1200 0.0010

1.001 0.008 0.0020 -0.0051 18.1279 0.0011

1.000 0.008 0.0019 -0.0048 18.1359 0.0013

1.000 0.007 0.0019 -0.0046 18.1438 0.0015

0.999 0.006 0.0018 -0.0044 18.1518 0.0016

0.998 0.006 0.0017 -0.0041 18.1597 0.0018

0.998 0.005 0.0017 -0.0039 18.1677 0.0020

0.997 0.004 0.0016 -0.0037 18.1756 0.0021

0.997 0.004 0.0015 -0.0035 18.1836 0.0022

0.996 0.004 0.0014 -0.0033 18.1916 0.0024

0.996 0.003 0.0013 -0.0031 18.1996 0.0025

0.995 0.003 0.0012 -0.0029 18.2076 0.0026

0.995 0.002 0.0011 -0.0027 18.2156 0.0027

0.994 0.002 0.0010 -0.0026 18.2236 0.0028

0.993 0.002 0.0008 -0.0024 18.2316 0.0028

0.993 0.002 0.0007 -0.0022 18.2396 0.0029

0.992 0.001 0.0005 -0.0021 18.2477 0.0029

0.992 0.001 0.0004 -0.0019 18.2557 0.0030

0.991 0.001 0.0002 -0.0018 18.2638 0.0030

Page 16: Paper Work-excess Volume

0.991 0.001 0.0001 -0.0016 18.2718 0.0030

0.990 0.001 -0.0001 -0.0015 18.2799 0.0030

0.989 0.001 -0.0003 -0.0014 18.2879 0.0030

0.989 0.001 -0.0004 -0.0013 18.2960 0.0029

0.988 0.000 -0.0006 -0.0011 18.3041 0.0029

0.988 0.000 -0.0008 -0.0010 18.3122 0.0028

0.987 0.000 -0.0010 -0.0009 18.3203 0.0027

0.986 0.000 -0.0012 -0.0008 18.3284 0.0027

0.986 0.000 -0.0014 -0.0007 18.3365 0.0026

0.985 0.000 -0.0017 -0.0006 18.3446 0.0025

0.985 0.000 -0.0019 -0.0005 18.3527 0.0023

0.984 0.000 -0.0021 -0.0004 18.3609 0.0022

0.984 0.000 -0.0023 -0.0004 18.3690 0.0021

0.983 0.000 -0.0026 -0.0003 18.3771 0.0020

0.982 0.000 -0.0028 -0.0002 18.3853 0.0018

0.982 0.000 -0.0031 -0.0002 18.3935 0.0017

0.981 0.000 -0.0033 -0.0001 18.4016 0.0015

0.981 0.000 -0.0036 0.0000 18.4098 0.0014

0.980 0.000 -0.0038 0.0000 18.4180 0.0012

0.979 0.000 -0.0041 0.0001 18.4262 0.0011

0.979 0.000 -0.0044 0.0001 18.4344 0.0009

0.978 0.000 -0.0047 0.0001 18.4426 0.0008

0.978 0.000 -0.0050 0.0002 18.4508 0.0007

0.977 0.000 -0.0052 0.0002 18.4590 0.0005

0.976 0.000 -0.0055 0.0002 18.4672 0.0004

0.976 0.000 -0.0058 0.0003 18.4755 0.0003

0.975 0.000 -0.0062 0.0003 18.4837 0.0002

0.975 0.000 -0.0065 0.0003 18.4919 0.0001

0.974 0.000 -0.0068 0.0003 18.5002 0.0001

0.973 0.000 -0.0071 0.0003 18.5085 0.0000

0.973 0.000 -0.0074 0.0003 18.5167 0.0000

0.972 0.000 -0.0078 0.0003 18.5250 0.0000

0.971 0.000 -0.0081 0.0003 18.5333 0.0000

0.971 0.000 -0.0084 0.0003 18.5416 0.0001

0.970 0.000 -0.0088 0.0003 18.5499 0.0002

0.970 0.000 -0.0091 0.0003 18.5582 0.0003

0.969 0.000 -0.0095 0.0002 18.5665 0.0004

0.968 0.000 -0.0098 0.0002 18.5748 0.0006

0.968 0.000 -0.0102 0.0002 18.5831 0.0008

0.967 0.000 -0.0106 0.0002 18.5915 0.0011

0.967 0.000 -0.0109 0.0001 18.5998 0.0014

0.966 0.000 -0.0113 0.0001 18.6082 0.0017

0.965 0.000 -0.0117 0.0001 18.6165 0.0021

0.965 0.000 -0.0121 0.0000 18.6249 0.0026

0.964 0.000 -0.0125 0.0000 18.6333 0.0031

0.963 0.000 -0.0129 -0.0001 18.6417 0.0037

0.963 0.000 -0.0133 -0.0001 18.6500 0.0043

0.962 0.000 -0.0137 -0.0002 18.6584 0.0050

0.961 0.000 -0.0141 -0.0003 18.6669 0.0058

0.961 0.000 -0.0145 -0.0003 18.6753 0.0066

0.960 0.000 -0.0149 -0.0004 18.6837 0.0075

0.960 0.000 -0.0153 -0.0005 18.6921 0.0085

0.959 0.000 -0.0158 -0.0005 18.7005 0.0096

Page 17: Paper Work-excess Volume

1.228 0.252

0.173089146 0.05074818

TRC Data bases for Chemistry and Engineering-TRC Thermodynamic tables, Version 1.1; thermodynamic research Center, The texas A&M University system: College Station, TX, 1994

Haar, L.; Gallagher, J.S.; Kell, G.S. NBS/NRC steam tables: Thermodynamic transport properties and computer programs for vapor and liquid states of water in SI units; Hemisphere Publishers: New York, 1984.

Page 18: Paper Work-excess Volume

Formule 1:

Sp.d.Deviation 273 0.005

Formule2: d =A + B T + CT² + DT³ + ET4

373 0.005

water

formula1correctedformula 1 Formule2

A 3.4020 5.4590 62.47828451

B 0.2323 0.3054 -0.02412944

C 647.1 647.1 0

D 0.1431 0.0810 0

E 0 0.0000 0

MM/ g.mol-1 18.0153

17.9

18

18.1

18.2

18.3

18.4

18.5

18.6

18.7

18.8

18.9

250 270 290 310 330 350 370 390

Sp

ecti

fic.M

ola

r D

en

sit

y(c

m3.m

ol-

1)

Temperature K

Series1

-0.0100

-0.0050

0.0000

0.0050

250 270 290 310 330 350 370 390

Devia

tio

n

CTc

T

B

Ad

)1(1(

Page 19: Paper Work-excess Volume

-0.0200

-0.0150

Temperature K

Page 20: Paper Work-excess Volume

TRC Data bases for Chemistry and Engineering-TRC Thermodynamic tables, Version 1.1; thermodynamic research Center, The texas A&M University system: College Station, TX, 1994

Haar, L.; Gallagher, J.S.; Kell, G.S. NBS/NRC steam tables: Thermodynamic transport properties and computer programs for vapor and liquid states of water in SI units; Hemisphere Publishers: New York, 1984.

Page 21: Paper Work-excess Volume

-0.005

-0.005

Series1

Series1

Series2

Page 22: Paper Work-excess Volume