PCCC - czech-norway-pilotccs.czczech-norway-pilotccs.cz/wp-content/uploads/2015/...2 . Monitoring and Storage Project. All three projects are contributing in a significant way to the

Post Combustion Capture ConferencePCCC3& SaskPower CCS Symposium

Conference ProgrammeRegina, Saskatchewan, Canada8th-11th September 2015

A M E S S AG E F R O M P R E M I E R B R A D WA L L

Welcome to Sask atchewan and welcome to the the third annual IEAGHG Post- Combust ion Capture Conference

and 2015 SaskPower CCS Symposium. You are v is i t ing a province k nown as one of the wor ld ’s leading producers

of potash, uranium and oi l , as wel l as an agr icultural powerhouse. But there is more to Sask atchewan than natural

resources.

I n our province, there is a lso a t radit ion of innovat ion that stretches back to our ear l iest days. Through the years,

our researchers have done leading edge work in nuclear medic ine, agr icultural b iotechnology and crop sc ience,

and that t radit ion cont inues today in carbon capture and storage (CCS) research.

Dur ing your stay, you wi l l learn about and explore the Boundar y Dam I ntegrated CCS Projec t , the Carbon Capture

Test Faci l i t y at Shand Power Stat ion, and the IEAGHG Weyburn-M idale CO 2 Monitor ing and Storage Projec t .

Al l three projec ts are contr ibut ing in a s igni f icant way to the advancement of CCS, which has been ident i f ied as

a key technology in the ef for t to reduce greenhouse gas emiss ions by the I nternat ional Energy Agenc y, and the

I ntergovernmental Panel on Cl imate Change ( IPCC ) among others.

At the Boundar y Dam Power Stat ion, you wi l l see f i rsthand how the wor ld ’s f i rst commercia l power plant with

a fu l ly integrated post- combust ion carbon capture system is operat ing, near ly a year af ter i t came into ser v ice.

The Carbon Capture Test Faci l i t y i s now operat ional so an interac t ive tour wi l l be played to showcase the f i rst

fac i l i t y in the wor ld that a l lows companies to test and develop the nex t generat ion of carbon capture technology

in a commercia l , coal - f i red power plant sett ing.

You wi l l a lso f ind out more about the IEAGHG Weyburn-M idale CO 2 Monitor ing and Storage Projec t , which is one

of the most s igni f icant global C0 2 storage research in i t iat ives ever under taken. S ince 2000, 28 mi l l ion tonnes of

C0 2 have been safely stored at the projec t .

Whi le I k now you have a busy schedule, p lease take t ime to appreciate Sask atchewan’ s renowned hospita l i t y and

our cultural amenit ies. This i s a beaut i fu l province with f r iendly people. We are glad you could v is i t . P lease have

a produc t ive conference and a great stay in Sask atchewan.

S i n ce r e l y,

H O N O U R A B L E B R A D WA L LP R E M I E R O F S A S K ATC H E WA N

The Honourable Brad Wall

Premier of Sask atchewan

226 Legis lat ive Bui ld ing

Regina, Sask atchewan

CANADA S4S 0B3

About IEAGHG

The IEA Greenhouse Gas R&D Programme (IEAGHG) is a major international collaborative programme undertaking research on greenhouse gas mitigation. IEAGHG members include 17 countries, the European Commission, OPEC and 17 multinational sponsors. IEAGHG acts as an impartial source of information on technologies capable of achieving deep reductions in greenhouse gas emissions. There are a range of technologies that could be used to substantially reduce emissions of greenhouse gases and IEAGHG’s remit involves characterising these options on a consistent basis. The important role that fossil fuels play in underpinning world economic development is recognised, and IEAGHG activities have demonstrated the opportunity for their continued use, even under scenarios involving deep reductions.

Conference Programme

Post Combustion Capture ConferencePCCC3& SaskPower CCS Symposium

About SaskPower

Saskatchewan and IEAGHG have a rich history dating back to the work done on the IEAGHG Weyburn-Midale CO2 Storage and Monitoring Project (2000-2012). With all the CCS initiatives now operating in the province, IEAGHG has decided to once again come back to Saskatchewan to host its third post-combustion capture conference (PCCC3).

SaskPower is hosting its 2015 CCS Symposium in conjunction with this year’s PCCC3 conference which will be held at the Delta Hotel in Regina, Saskatchewan, Canada. This CCS Symposium is dedicated to the learnings of the Boundary Dam Integrated CCS Project; SaskPower will use the experience and knowledge gained during the execution of its flagship CCS project to encourage future research, development and deployment of CCS. This year’s symposium will be the world’s first opportunity to learn from SaskPower’s experience in a technical way with the Boundary Dam Integrated CCS Project having now been in operation for almost a year. Confirmed operational data and learnings will be used to tell the story of SaskPower’s journey with CCS, including unique challenges, successes, and surprises.

1

The IEAGHG Post-Combustion Capture Conference (PCCC) series has established itself as one of the leading, if not the specialist Post-Combustion Capture (PCC) conferences in the world. As a dedicated conference, it is able to allow, in detail, presentation on the advancements of current technology, development and results from major demonstration projects and next generation PCC technologies.

Experts attending PCCC2 (Bergen, Norway, 2013) saw an integrated session from Technology Centre Mongstad (TCM) providing a world’s first sharing of results and experiences from the first years’ operation of the centre. Building on this, PCCC3 in conjunction with the 2015 SaskPower CCS Symposium, will offer an unprecedented sharing of knowledge and experience at the end of a first-of-its-kind project ‘s first year in operation.

The event will culminate with a visit to the Boundary Dam Integrated CCS Project site and the Carbon Storage and Research Centre (formerly Aquistore).

Technical Steering Committee

The conference content was overseen by a Steering Committee comprising of the following members:

• Mr. John Gale, IEAGHG, UK (Chair)• Prof. Hallvard Svendsen, NTNU• Dr. Paul Feron, CSIRO• Prof. Gary Rochelle, University of Texas• Prof. Paitoon Tontiwachwithikul, University of Regina• Mr. John Lytinski, U.S. DOE, USA• Dr. Jang Kyung-Rong, KEPCO, South Korea• Mr. Nils Røkke, SINTEF, Norway• Dr. Michiaki Harada, JCOAL, Japan

2

Background

3

Conference SponsorsConference Planning

The outline meeting plan on page 5 shows the overall timings for the sessions, refreshment and lunch breaks for the 3 day event. A more detailed plan, with session topics can be found on pages 8 through 9. A detailed breakdown of the presentations and posters within these sessions can be found on pages 10 to14.

The presentations and author details are correct at the time of going to print, and any changes will be notified on the event website:

http://www.ieaghg.org/conferences/pccc/52-conferences/pccc/470-3rd-post-combustion-capture-conference

Conference Sponsors

The committees have been hard at work organising the technical content and logistical issues of the conference. We would also need to thank the host of the event, SaskPower, and the conference sponsors: U.S. DOE; JCOAL; Technology Centre Mongstad (TCM); Climate Change and Emissions Management Corporation (CCEMC); and the University of Regina. Their support has been invaluable.

IEAGHG would like to thank SaskPower for it’s sponsorship and organization of the 2015 SaskPower Symposium and for the organisation of the site visits to Boundary Dam and the Carbon Storage and Research Centre.

4

Hotel Floor Plan

The conference will be held on the second floor of the Delta Hotel. Plenary, Stream 1 and Symposium sessions will be held in the Trentino room. The Tuscany room will host Stream 2 and the Campania room will host Stream 3.

The posters and sponsor stands will be available throughout the event in the prefunction area.

Breakfast, refreshment breaks and lunch will be located in the Lombardy/Umbria room.

Stay Informed

www.ieaghg.org

#PCCC3 @ieaghg

www.saskpowerccs.com

#SaskCCS @SaskPowerCCS

Stream 1 / SaskPower CCS Symposium

Breakfast/ Lunch/Refreshment Break

Stream 2 Stream 3Registration

Table

Poster Session

5

Conference at a Glance

To assist with the large numbers attending the tour, 4 groups have been allocated (groups are indicated by a coloured dot on your name badge) with buses leaving from the Delta Regina at 07.30 and 08.30, returning between 17.30 and 18.00. The day will include a tour of the Boundary Dam Power Station and Capture Facility, a visit to the Aquistore site, and an interactive tour of SaskPower’s Carbon Capture Test Facility. Full details can be found on page 19.

08.30 - 09.40 Welcome & Opening Plenary

09.40 - 10.40 Technical Session 1




10.40 - 11.10 Coffee Break

12.50 - 13.50 Lunch


08.00 - 08.40 Plenary



13.50 - 15.30 Poster Session & Refreshments



12.50 - 13.50 Lunch Sponsored by the

Univeristy of Regina

15.30 - 16.20 Plenary

08.40 - 09.30 Welcome Remarks & Keynote

09.30 - 10.00 Session 1


10.30 - 12.00 Session 2 and 3

12.00 - 13.00 Lunch

13.00 - 14.30 Session 4, 5 and 6

14.30 - 15.00Coffee Break

15.00 - 15.30 Session 7

Spotlight on Saskatchewan Tour - Friday, September 11, 2015

15.30 - 15.45 Tour Safety Orientation

18.00 - OnwardNo Planned Event

19.00 - 21.00Welcome Reception

18.00 - 22.00Conference Banquet

15.45 - 16.00 Closing Remarks

Thurs, Sept 10th

SaskPower CCS SymposiumTues, Sept 8th PCCC3 Day 1

Weds, Sept 9th PCCC3 Day 2

6

“Current status of post-combustion capture and CCS in Japan”Mr. Terufumi Kawasaki, Program Manager of JCOAL

Terufumi Kawasaki is now working for Japan Coal Energy Center, JCOAL, as a program manager who is responsible for R&D promotion related to coal-fired power plants. He has experience developing and deploying power plants with environmental facilities such as DeSOx, DeNOx and CCS.

He was formerly general manager of Hitachi Ltd’s Global Development Division and also served as Hitachi’s representative for the Global CCS Institute.

He graduated from Kyoto University with a degree in Physics and a Masters degree in Nuclear Technology. He worked for Hitachi Ltd. in the field of power generation facilities for more than 30 years until his retirement in 2013.

“Summary of United States Regulatory and RD&D Efforts to Advance Post-Combustion Capture Technologies”John Lytinski, PE, Program Manager for Carbon Capture, U.S. DOE Office of Fossil Energy

John currently serves as the Carbon Capture Program Manager in the Office of Fossil Energy. He previously served as the Technology Manager for Carbon Sequestration at the National Energy Technology Laboratory. He has over 20 years experience working on environmental compliance and technology development for the energy industry and Department of Defense. He received his B.S. in Civil Engineering from Virginia Polytechnic Institute and State University and M.S. from Johns Hopkins University in EnvironmentalEngineering and Science.

PCCC3 Keynote Speakers

“How Technology Centre Mongstad (TCM) plays a central role in progressing carbon capture globally”Roy Vardheim, Managing Director, TCM

Roy Vardheim started as Managing Director of Technology Centre Mongstad (TCM), March 1, 2015. He holds a Masters degree in Chemical Engineering from the Norwegian University of Science and Technology (NTNU) and until recently was CEO of Norske Skog Saugbrug AS. He has a long career in different Norwegian companies, i.e. CEO of Borealis plus a variety of other positions. Vardheim also has extensive international experience as a senior executive of Borealis’ business in Scandinavia and the Middle East.

7

Integrated Carbon Capture and Storage Project at SaskPower’s Boundary Dam Power Station

IEAGHG and U.S. DOE have collaborated, with the support of SaskPower, to produce a report on the CCS project at Boundary Dam. The report will be published in time for the 2015 SaskPower CCS Symposium and PCCC3 conferences.

The report outlines the journey that SaskPower has undertaken from first considering which CCS option to build, through the design, construction and operation of the post-combustion capture plant at Boundary Dam 3.

As much as the Boundary Dam Integrated CCS Project is a first-of-its-kind, this report is also a first. It is the first to provide the full history of a commercial CCS project. SaskPower has provided commentary and insight on its experiences of building and operating BD3. The report should help other project developers understand the pitfalls that might lie ahead for their own projects and its publication can only assist the implementation of CCS globally.

Special Issue commemorating the 10 year anniversary of the publication of the Intergovernmental Panel on Climate Change Special Report on CO2 Capture and Storage

The International Panel on Climate Change (IPCC) Special Report on Carbon Capture and Storage (SRCCS), published in 2005, was a major definer for the acceptance of Carbon Capture and Storage (CCS) as a mitigation tool for greenhouse gas management. Before the SRCCS was published, the IPCC view was that CCS was a research topic only. However, after the publication of the SRCCS all that changed and CCS was accepted as a credible mitigation option. CCS then took its place alongside

the other low carbon technology options and became part of the portfolio of options that was needed to be deployed to fight climate change.

The Editors of the International Journal of Greenhouse Gas Control (IJGGC) identified that there was a need to update the 10 years of extensive work that has been undertaken since the SRCCS was published. The Editors considered that IJGGC was the perfect place to launch this new initiative since the journal was conceived after the SRCCS as a home for peer reviewed papers on CCS that could be utilized for IPCC Assessment Reports post SRCCS. A vacuum that has now been filled.

The Special Issue of IJGGC commemorating ten years since the SRCSS (Vol. 40) can be found at http://www.journals.elsevier.com/international-journal-of-greenhouse-gas-control/. All papers will be free open access for one month.

The Special Issue presents to the CCS community, and to the wider stakeholder community a collection of 17 review papers covering areas in which significant progress has been made in the 10 years since the publication of the IPCC SRCCS. Just over 100 authors participated in this exercise, who referenced nearly 3000 publications to support their work, including peer reviewed scientific and technical documents as well as grey literature.

If we summarise the results of this Special Issue the take away message is:

“We can be certain that the science and the technologies supporting CCS as a climate change mitigation tool have experienced a great advance in the last 10 years, consolidating and expanding the knowledge base to estimate more accurately the impacts, risks and costs associated with large CCS projects”

Special Interest Publications

ELSE

VIE

RIn

ternation

al Journal of G

reenh

ouse Gas C

ontrol V

ol . 40 ( 2015 ) 1 –458

40 International Journal of Greenhouse Gas Control

VOLUME 40 SEPTEMBER 2015

Special Issue: Commemorating the 10th year anniversary of the publication of the Intergovernmental Panel on Climate Change Special Report on CO2 Capture and Storage

Guest Editors: J. Gale, J.C. Abanades, S. Bachu and C. Jenkins

Special Issue commemorating the 10th year anniversary of the publication of the Intergovernmental Panel on Climate Change Special Report on CO2 Capture and StorageJ. Gale, J.C. Abanades, S. Bachu and C. Jenkins (UK, Spain, Canada, Australia) 1

Practical experience in post-combustion CO2 capture using reactive solvents in large pilot and demonstration plantsR. Idem, T. Supap, H. Shi, D. Gelowitz, M. Ball, C. Campbell and P. Tontiwachwuthikul (Canada) 6

Recent progress and new developments in post-combustion carbon-capture technology with amine based solventsZ. (Henry) Liang, W. Rongwong, H. Liu, K. Fu, H. Gao, F. Cao, R. Zhang, T. Sema, A. Henni, K. Sumon, D. Nath, D. Gelowitz, W. Srisang, C. Saiwan, A. Benamor, M. Al-Marri, H. Shi, T. Supap, C. Chan, Q. Zhou, M. Abu-Zahra, M. Wilson, W. Olson, R. Idem and P. (PT) Tontiwachwuthikul (China, Canada, Thailand, Qatar, United Arab Emirates) 26

Oxyfuel combustion for CO2 capture in power plantsR. Stanger, T. Wall, R. Spörl, M. Paneru, S. Grathwohl, M. Weidmann, G. Scheffknecht, D. McDonald, K. Myöhänen, J. Ritvanen, S. Rahiala, T. Hyppänen, J. Mletzko, A. Kather and S. Santos (Australia, Germany, USA, Finland, UK) 55

Emerging CO2 capture systemsJ.C. Abanades, B. Arias, A. Lyngfelt, T. Mattisson, D.E. Wiley, H. Li, M.T. Ho, E. Mangano and S. Brandani (Spain, Sweden, Australia, UK) 126

Pre-combustion CO2 captureD. Jansen, M. Gazzani, G. Manzolini, E.v. Dijk and M. Carbo (Switzerland, Italy, The Netherlands) 167

Review of CO2 storage effi ciency in deep saline aquifersS. Bachu (Canada) 188

CO2 migration and pressure evolution in deep saline aquifersJ.T. Birkholzer, C.M. Oldenburg and Q. Zhou (USA) 203

Capillary trapping for geologic carbon dioxide storage - From pore scale physics to fi eld scale implicationsS. Krevor, M.J. Blunt, S.M. Benson, C.H. Pentland, C. Reynolds, A. Al-Menhali and B. Niu (UK, USA, Oman) 221

Abstracted/indexed in: EiCompendex, EnCompassLIT, Pollution Abstracts, Meteorological and Geoastrophysical Abstracts. Covered by Science Citation Index Expanded, Current Contents Engineering Computing & Technology, Current Contents/ Agricultural Behavioral and Environmental Sciences, Current Contents Physical Chemical & Earth Sciences. Also covered in the abstract and citation database SCOPUS®. Full text available on ScienceDirect®

ISSN 1750-5836

(Contents continued on bm I)

I N T E R N A T I O N A L J O U R N A L O F

Greenhouse Gas Control

Published in association with the IEA Greenhouse

Gas R&D Programme

Volume 40 September 2015 ISSN: 1750-5836

Available online at www.sciencedirect.com

ScienceDirect

Special Issue:Commemorating the 10th year anniversary of the publication of the Intergovernmental Panel on Climate Change Special Report on CO2 Capture and Storage

Guest Editors:J. Gale, J.C. Abanades, S. Bachu and C. Jenkins

8

TU

ES

, S

EP

T 8

TH

1 09.40 - 10.40 Solvent Degradat ion and Corros ion Pi lot Test ing & Regenerat ion Solvent Degradat ion & Process Control

2 11.10 - 12.50 New Solvent Development Novel PCC Systems Model l ing I nnovat ive Amine Processes

3 13.50 - 15.30 K inet ics and Thermal Proper t ies of Solvents Flexible & D ynamic Operat ion of PCC Systems Model l ing I nnovat ive Amines

4 15.50 - 17.30 Process Optimizat ion & I ntegrat ion Environmental I mpac ts of CO 2 Capture Model l ing Methods and Results

WE

DS

, S

EP

T 9

TH 5 08.40 - 10.40 Equi l ibr ia and New Process Conf igurat ions Solvent Based H ybr id Capture Options

6 11.10 - 12.50Results f rom Demonstrat ion and Pi lot Scale

Projec ts - ( I )


Projec ts - ( I I )

TH

UR

S,

SE

PT

10

TH

1 09.30 - 10.00 The Sask power Stor y in CCS and Spot l ight on Sask atchewan

2 10.30 - 11.00 Technical Development and Col laborat ion Going For ward

3 11.30 - 12.00 Detai ls of the IEAGHG / U.S . DOE Repor t on The Boundar y Dam CCS Projec t

4 13.00 - 13.30 Boundar y Dam Operat ional Exper ience and Oppor tunit ies for Future Projec ts

5 13.30 - 14.00 Boundar y Dam Costs, Revenues and Business Case

6 14.00 - 14.30 Regulat ion of CO 2 - EOR and CCS in Sask atchewan

7 15.00 - 15.30 The Role of EOR, Permanent Storage and Fie ld Monitor ing

Single Session

Technical Sessions at a GlanceParellel Session- Stream 1 (a)

9

Parallel Session B Parallel Session C

TU

ES

, S

EP

T 8

TH

1 09.40 - 10.40 Solvent Degradat ion and Corros ion Pi lot Test ing & Regenerat ion Solvent Degradat ion & Process Control

2 11.10 - 12.50 New Solvent Development Novel PCC Systems Model l ing I nnovat ive Amine Processes

3 13.50 - 15.30 K inet ics and Thermal Proper t ies of Solvents Flexible & D ynamic Operat ion of PCC Systems Model l ing I nnovat ive Amines

4 15.50 - 17.30 Process Optimizat ion & I ntegrat ion Environmental I mpac ts of CO 2 Capture Model l ing Methods and Results

WE

DS

, S

EP

T 9

TH 5 08.40 - 10.40 Equi l ibr ia and New Process Conf igurat ions Solvent Based H ybr id Capture Options


Projec ts - ( I )


Projec ts - ( I I )

Parellel Session- Stream 2 (b) Parellel Session- Stream 3 (c)

10

1a Solvent Degradation and Corrosion

Characterisation of Degraded Solvents from Amine Scrubbing: Rachel Lewis, University of Nottingham

Corrosivity Screening of Linear and Hindered Amines: Kent Fischer, The University of Texas at Austin

Speciation of Iron in MEA Solutions: Solubility and Corrosion: Georgios Fytianos, NTNU

Technical Session 1

1b Pilot Testing and Regeneration

CO2 Solutions Results of Pilot Testing of Enzyme-Accelerated CO2 Capture Process: Jonathan Carley, CO2 Solutions Inc.

Experimantal Measurement of Regeneration Energy in CO2 Capture System Applying Phase Seperation Process Using High-Concentrations 2-Amino-2-Methyl-1-Propanol: Takao Nakagaki, Waseda Univeristy

CO2 Post Combustion Capture from Once Through Steam Generators (OTSG) Boilers at Husky Energy in Saskatchewan, Canada: Modular Design and Construction Approach to Reduce the Capital and Operating Expenditures: Ahmed Aboudheir, HTC CO2 Systems Corp.

Technical Session 2

2a New Solvent Development

2b Novel PCC Systems

Pilot Test of a Nanoporous, Super-Hydrophobic Membrane Contactor Process for Post-Combustion CO2 Capture: S. James Zhou, Gas Technology Institute

Large Bench-Scale Testing of Mixed-Salt Technology for Post-Combustion CO2 Capture: Indira Jayaweera, SRI International

A Low-Energy Chilled Ammonia Process Exploiting Controlled Solid Formation: Holistic Development from Thermodynamics to Kinetics: Daniel Sutter, ETH Zurich

Technical Evaluation of Implementation of Carbonic Anhydrase in Post-Combustion Carbon Capture: Maria Gundersen, Technical University of Denmark

Evaluation of Membrane-Solvent Hybrid Systems for Post-Combustion CO2 Capture from a Pulversied Coal-Fired Power Plant: Travis Shultz, U.S. DOE

1c Solvent Degradation and Process Control

An On-Line Analytical Technique for Composition Determination of CO2-Loaded Formulated Amine Solvents Based on the Liquid Thermo Physical Porperties for a Post Combustion CO2 Capture Process: Fatemeh Pouryousefi, University of Regina

Oxygen Solubility and Mass Transfer in Amine Solutions for Applications in Post-Combustion CO2 Capture: Grégoire Léonard, University of Liege

Liquid-Liquid Extraction of Degradation Products in Monoethanolamine (MEA) Absorption Solution Used in Carbon Dioxide (CO2) Capture: Chintana Saiwan, Chulalongkorn University

Development of New Amines for Post-Combustion Capture of Carbon Dioxide (CO2) Absorption: Sudkanueng Singto, CETI

Development of Novel Single Amine Absorbents and their Blends for CO2 Capture: Firoz Alam Chowdhury, RITE

Determination of New Blended Amines System for CO2 Removal in Post-Combustion Capture: Nabil El Hadri, Masdar

Sterically Hindered Alkanolamines as Strong Bicarbonate Forming Solvents for Post-Combustion Capture: Inna Kim, NTNU

Method Development for Amine Analysis Using Ino-Oair Based High Performance Liquid Chromatography (IP-HPLC): Teeradet Supap, CEITI

2c Modelling Innovative Amine Processes

Exergy Analysis of Advanced Flash Stripper Using Aqueous Piperazine: Yu-Jeng Lin, the University of Texas at Austin

Optimization of an Existing 130 tonnes per day Plant Capturing CO2 from Flue Gases of a Coal-Fired Power Plant: Ahmed Aboudheir, HTC CO2 Systems Corp.

The Impact of Critical of Model Parameter Correlations on the Ratebased Model for CO2 Capture with Amine Solutions: Hanne Kvamsdal, NTNU

Assessment of Various Post-Combustion Technologies in the HiPerCap Project: Hanne Kvamsdal, SINTEF

Absorber Performance Over a Wide Range of CO2: Yue Zhang, the University of Texas at Austin

3a Kinetics and Thermal Properties of Solvents

CO2 Enthalpy and Heat Capacity Measurements in Aqueous Piperzine Blends with Different Alkanolamines: Abdurahim Abdulkadir, Masdar

A Thermally Stable Piperazine Blend for CO2 Capture: Gary Rochelle, The University of Texas at Austin

Kinetic Effects of Adding Aqueous 2-(Ethylamino) Ethenol Across Different Aqueous Tertiary Amines Using Stopped-Flow Technique: Mohammad Abu Zahra, Masdar

Kinetics of Carbonic Anhydrase in Promoted Chemical Solvents for Carbon Dioxide Absorption: Arne Gladis, Technical University of Denmark

The Effect of the Physical Liquid-Side Mass Transfer Coefficient on Absorber Performance with Aqueous Piperazine: Darshan Sachde, The University of Texas at Austin

Technical Session 3

3b Flexible and Dynamic Operation of PCC SystemsControllability Analysis of a Post-Combustion CO2 Capture Plant Integrated with a Coal and a Natural Gas Fired Power Plant:

Evgenia Mechleri, Imperial College London

A Pilot-Scale Study of Dynamic Operating Scenarios for Flexible Post-Combustion CO2 Capture: Paul Tait, the University of Edinburgh

Controllability and Flexibility Analysis of a CO2 Capture Plant using MEA and Piperazine Promoted K2CO3: Jozsef Gaspar, Technical University of Denmark

Dynamic Modelling of a Supercritical Coal-Fired Power Plant Integrated with Post-Combustion CO2 Capture: Stefanía Ósk Garðarsdóttir, Chalmers University of Technology

Modelling of MEA-Based CO2 Capture Process with Uncertainty Quantification and Validation with Steady-State and Dynamic: Debangsu Bhattacharyya, West Virginia University

3c Modelling Innovative Amines

Rate-Based Modelling and Simulation of CO2 Absorption and Desorption using Piperazine Promoted Potassium Carbonate: Philip Loldrup Fosbøl, Technical University of Denmark

Study of Heat Duty of Catalyst-Aided Amine-Based CO2 Capture Process: Wayuta Srisang, University of Regina

Modeling and Simulation of Catalytic CO2 Desorption from a CO2-loaded solvent in the Desorber: Benjamin Decardi-Nelson, University of Regina

Advanced Solid Sorbent-Based CO2 Capture Process: Thomas Nelson

Sensitivity Analysis of Post-Combustion CO2 Capture at Pilot Scale Level: Usman Ali, University of Sheffield

4a Process Optimization and Integration

Maintaining Power Output with the Addition of CO2 Capture: A Techno-Economic Assessment of Integrated Retrofits with Sequential Combustion of Gas Turbine Flue Gas: Maria Sanchez del Rio, University of Edinburgh

Technical Session 4

11

4b Environmental Impacts of CO2 Capture

5a Equilibria and New Process Configurations

Technical Session 5

5b Solvent Based Hybrid Capture Options

Kinetics of Catalyitic Desorption of Carbon Dioxide from CO2-Loaded Aqueous Solutions if Monoethanol Amine (MEA), Blended Monoethanolamine and Methyldiethanolamine (MEA-MDEA), and Monoethanolamine and 4-diethylamino-2-butanol (MEA-DEAB): Rapahel Idem, University of Regina

A Study on Risks to Human Health Due to NO2, PM2.5, and SO2 Emissions from a Post-Combustion Carbon Dioxide Capture Process in Canada: Jarotwan Koiwanit, University of Regina

Cause and Prevention of Aerosol-Based Emission - Results from the Post-Combustion Capture Pilot Plant at Niederaussem: Peter Moser, RWE

Management of Emissions in Amine CO2 Post-Combustion Carbon Capture Plants: Merched Azzi, CSIRO

Study on Reaction Mechanisms of Amine Absorbent and Aldehydes: Asato Kondo, Toshiba

Measurement and Interpretation of Amine Aerosols: Gary Rochelle, The University of Texas at Austin

12

Attempts to Predict Absorption Equilibria: Klaus Jens, Telemark University of Technology and Tel-Tek

The Role of Bicarbonate in the Vapour Liquid Equilibrium (VLE) of DEAB and Blended MEA-DEAB Systems Under Room Temperature and Regeneration Temperatures: An NMR Study: Raphael Idem, University of Regina

Solubility of Carbon Dioxide (CO2) in Highly Concentrated Aqueous Ternart Blend of 2-Amino-2-Methyl-1-Propanol (AMP), Piperazine (PZ), and Monoethanolamine (MEA): Chintana Saiwan, Chulalongkorn University

Experimental Study of Reboiler Heat Duty for CO2 Desorption from N,Diethyleanoamine (DEEA) In Randomly Packed Column: Zhiwu Liang, Hunan University

Cyclic Oxidation of Amines at the Bench and Pilot Scale: Paul Nielsen, The University of Texas at Austin

The Study of the Relationship Between the Structure and Activity of CO2 Absorption into Aqueous Tertiary Amine: Zhiwu Liang, Hunan University

Optimizing Integrated Reference Cases in the OCTAVIUS Project: Hanne Kvamsdal, SINTEF

Integration of a Precipitating CO2 Capture Process in an NGCC Power Plant: Ugochukwu Edwin Aronua, SINTEF

Fluoropolymer Heat Exchangers: The Clean and Profitable Solution for Efficiency Improvements and CO2 Reduction at Coal-Fired Power Plants with CCS Technology: Peter Dittmann, Wallstein Ingenieur

Delta Purification’s Solvent Reclaimer Operation and Performance in the Cleanup of Degraded Solvents used in CO2 Capture from Coal-Fired Power Plant Flue Gases: Ahmed Aboudheir, Delta Purification

4c Modelling Methods and Results

Enhancing the Operation and Production of an Existing 800 Tonne Per Day Plant Capturing CO2 Flue Gases of a Coal-Fired Power Plant: Ahmed Abhoudheir, Delta Purification

Multi-Scale Modelling of Carbon Capture Systems: David Miller, U.S. DOE

Simulation and Validation of CO2 Mass Transfer Processes in Aqueous MEA Solutions with Aspen Plus at CO2 Technology Centre Mongstad: Espen Steinseth Hamborg, TCM

Effect of Liquid Viscosity on Mass Transfer Area and Liquid Phase Mass Transfer Coefficient for Structured Packings: Di Song, the University of Texas at Austin

Development of Cyclic Adsorption for CO2 Capture: Process Modelling and Optimisation: Matteo Gazzani, ETH Zurich

7 Results from Demonstration and Pilot Scale Projects (II)Assessment of Whole-Chain CCS Operating Procedures: Case Study of the Peterhead CCS Project: Adekola Lawal, Process Systems Enterprise

Comparative Evaluation of a New Liquid Absorbent in a PCC Pilot Plant in China: Ashleigh Cousins, CSIRO

Research and Development on Post Combustion Carbon Capture Technology Through the CLIMIT RD&D Funding Program: Jørild Svalestuen, Gassnova

Mikawa CO2 Capture Pilot Plant Test of New Amine Solvent: Satoshi Saito, Toshiba

Pilot Plant Results for Advanced CO2 Capture Process Using AMP/PZ Solvent at Tauron’s Coal-Fired Power Plant: Adam Tatarczuk, Institute for Chemical Processing of Coal

Technical Session 7

6 Results from Demonstration and Pilot Scale Projects (I)

Project Update of the Deployment of the KM CDR Process: Takashi Kamijo, MHI

Innovative Post-Combustion CO2 Capture Process Integrated with an Existing Coal-Fired Power Plant: Kunlei Liu, University of Kentucky

CANSOLV DC201 Model Validation with TCM Demonstration Plant Results: Matthew Campbell, Shell Cansolv

Results from the Testing on a 1MWel Advanced Aqueous Amine-Based PCC Pilot Plant in Wilsonville: Torsten Stoffregen, Linde Engineering

Evaluated Pilot Plant Results for 5m Piperazine with the Advanced Flash Stripper: Eric Chen, The University of Texas at Austin

Technical Session 6

Post-Combustion CO2 Capture: Screening Tests of Solvents for the Absorption-Regeneration Process Applied to Cement Flue Gases with High CO2 Contents: Sindra Laribi, University of Mons

Analysis of the Rate-Limiting Step in Carbon Dioxide Absorption to Amine-Impregnated Solid Sorbent: Ryohei Numaguchi, RITE

CO2 Desorption Performance of Amine-Based Solvents by Membrane Flash Process: Nobuhide Takahashi, Shinshu University

Preparation of Amino-Functionalised Mesoporous Silica and its Application for CO2 Post-Combustion Capture: Mohammad Abu Zahra, Masdar

Micro-Encapsulation of Advanced Solvents for Post-Combustion Carbon Capture: Joshuah Stolaroff, LLNL

PosterSession

Computational Analysis of Nitrosamine Formation During Amine Based CO2 Capture Process with Different Groups of Nitrosating Agents (NO-X):Raphael Idem, Univesity of Regina

Predicting Environmental Concentrations of Nitramines from Sorption Potentials to Soils and Dissolved Organic Matter: Catherine Brecke Gundersen, University of Oslo

Selective CO2 Capture on Activated Carbon: Sepideh Shahkarami, University of Saskatchewan

Selective Exhaust Gas Recirculation in Combined Cycle Gas Turbine Power Plants with Post-Combustion Carbon Capture: Laura Herraiz, The Univeristy of Edinburgh

13

CO2 Absorption by Mixtures of [BMIM]BF4 and MEA: Lingjun Xu, Tsinghua University

Reactive Absorption of CO2 with Concentrated Aqueous N,N-Diethylethanolamine Solutions using Stirred Cell Reactor: Toluwanimi Kolawole, Newcastle University

Post-Combustion CO2 Capture: Optimization of the Absorption-Regeneration Process for the Application to Cement Flue Gases: Lionel Dubois, University of Mons

Mass Transfer Studies on Catalyst-Aided Desorption in an Amine Based Post Combustion CO2 Capture Plant: Raphael Idem, University of Regina

Adsorbent Characterization for the Development of Carbon Capture Processes: Marco Mazzotti, ETH Zurich

A Comparison of Impacts on Human Health due to Heavy Metal Emissions from a Conventional Lignite Coal-Fired Electricity Generation Station without Carbon Dioxide Capture and with Post-Combustion Carbon Dioxide Capture : Jarotwan Koiwanit, University of Regina

Pilot Study on Carbon Capture from Hot Stove Oven Gas of Steel Mill: Jui-Fu Shen, China Steel Corporation

Post Combustion Carbon Capture Source Emission Sampling Method Development: Raphael Idem, University of Regina

1 MWth Pilot Testing and Scale-up of the Carbonate Looping Process in the SCARLET Project: Jochen Hilz, Technische Universität Darmstadt

Less is More: the use of a Compact PTR-QMS Instrument in the Ammonia Chemical Ionization Mode for Selective On-Line Monitoring of Amines Emitted from a PCCC Facility: Armin Wisthaler, University of Oslo

Development and Optimization of a Temperature Swing Adsorption Process for Post-Combustion CO2 Capture in Integrated Steelworks: Matteo Gazzani, ETH Zurich

Experimental Demonstration of Synthetic Exhaust Gas Recirculation Impact on Carbon Capture: Thom Best, University of Leeds

The International Test Centre Network (TCN) – an Area for Knowledge and Experience Sharing: Lars Ingolf Eide, CO2 Technology Centre Mongstad

0.25 MWth Pulverized Biomass Firing Combustion Test Facility Integrated with a Post-Combustion Capture Plant: Janos Szuhanszki, University of Sheffield

Predicting Scale-up Performance using Validated CFD Model with Quantitative Confidence: Xin Sun, PNNL

Post-Combustion CO2 Capture Technology for High-Efficiency Combined Power Cycle using Low-BTU Fuel Gas in an Integrated Ironand Steel Mill: Kristin Onarheim, VTT

Assessment of Emerging Post-Combustion CO2 Capture Technologies and their Potential to Reduce Costs: Jasmin Kemper, IEAGHG

Characterization and Modelling of Aerosol Droplet in Absorption Columns: Hallvard Svendsen, NTNU

The Role of Filtration in Regenerative Solvent Scrubbing Systems for Carbon Capture for Coal Fired Power Generation: Jonathan Garrick, BHS-Sonthofen Inc.

Developing Methodology for Performance Test of Various CO2 Absorbents: Kwang-koo Kim, Korea Testing Laboratory

Assessment of Post Combustion CCS Systems Application for Fossil Fuel Power Plants in Czech Republic: Monika Vitvarova, Czech Technical University in Prague

Non-Aqueous Solvent (NAS) CO2 Capture Process: Marty Lail, RTI International

Selective CO2 Capture on Activated Carbon: Sepideh Shahkarami, University of Saskatchewan

14

15

SASKATCHEWAN, CANADAEPICENTRE OF CCS EXPERTISE

ESTEVAN

REGINA

SASKATOON

YORKTON

MOOSE JAWSWIFT CURRENT

PRINCE ALBERT

132

5

4

4. Amine Chemical Laboratory

5. IEAGHG Weyburn-Midale CO2 Monitoring and Storage Project

2. Carbon Storage and Research Centre (Aquistore)

1. The Boundary Dam Integrated CCS Project

3. Carbon CaptureTest Facility (CCTF)Led by the Boundary Dam Integrated CCS Project,

SaskPower’s flagship CCS initiative, Saskatchewan is positioned as a global leader in the areas of carbon capture, utilization and storage based on its cluster of CCS-related projects.

16

7.30 Registration and Breakfast at the Delta Regina Hotel

8.40 Opening Remarks and Introduction to Minister of SaskPower: Mike Monea, President, CCS Initiatives, SaskPower

8.45 Welcome Remarks: His Honourable Minister Bill Boyd, Minister Responsible for SaskPower, Government of Saskatchewan

9.00 Keynote - Key Developments in CCS – Saskatchewan’s Input (Introduction of IEAGHG / U.S. DOE Report on The Boundary Dam CCS Project): John Gale, General Manager, IEAGHG

9.30 Session 1 - The SaskPower Story in CCS and Spotlight on Saskatchewan: Mike Monea, President, CCS Initiatives, SaskPower

10.00 Coffee Break

10.30 Session 2 - Technical Development and Collaboration Going Forward: Max Ball, Senior Advisor, CCS Initiatives, SaskPower

11.30 Session 3 - Details of the IEAGHG / U.S. DOE Report on The Boundary Dam CCS Project: Carolyn K Preston, Principal Consultant, CKP & Associates Consulting

12.00 Lunch

13.00 Session 4 - Boundary Dam Operational Experience and Opportunities for Future Projects: Corwyn Bruce, Manager, Supply Development- Carbon Capture, SaskPower

13.30 Session 5 - Boundary Dam Costs, Revenues, and Business Case: Doug Daverne, Director, Supply Development- Carbon Capture, SaskPower

14.00 Session 6 - Regulation of CO2 - EOR and CCS in Saskatchewan: Floyd Wist, Executive Director, Energy Policy, Ministry of Economy, Government of Saskatchewan

14.30 Coffee Break

15.00 Session 7 - The Role of EOR, Permanent Storage and Field Monitoring: Erik Nickel, Senior Project Manager, PTRC

15.30 Safety Orientation for Tour: Mike Zeleny, Consultant, Boundary Dam CCS Project, SaskPower

15.45 Closing Remarks: Laurie Pushor, Deputy Minister, Ministry of Economy, Government of Saskatchewan

18.00 Cocktail Reception at the Casino Regina Show Lounge Foyer

19.00 Banquet at the Casino Regina Show Lounge

SYMPOSIUM AGENDA - TRENTINO BALLROOM, DELTA REGINA HOTEL - THURS, SEPT 10TH

BANQUET AGENDA - CASINO REGINA SHOW LOUNGE

Please note, this agenda is subject to change and may not reflect event proceedings on Sept 10th, 2015.

2015 SaskPower CCS Symposium Agenda

2015 SaskPower CCS Symposium Speakers

“The SaskPower Story in CCS and Spotlight on Saskatchewan” President, CCS Intiatives, SaskPower

Michael J. Monea joined SaskPower in 2008 as Vice-president, Carbon Capture & Storage Initiatives for SaskPower and in September, 2011 he was appointed President, of this division.

Prior to his role with SaskPower, Monea was a senior Vice-president with Canada Capital Energy Corporation. He served as Executive Director of the Petroleum Technology Research Centre at the University of Regina and later was appointed Chairman of the Board. In 2008, he was appointed to the Society of Petroleum Engineers Distinguished Lecture program as an expert in enhanced oil recovery.

Early on in his professional career he was trained in oil and gas operations in the United States. He created his own consulting/oil company in 1982, Nautilus Exploration and Associates Ltd.

Nautilus Exploration and Associates Ltd. built oil and gas assets selling its oil production in 1999. He then became one of two principal owners of a south eastern oil and gas company, Flatland Exploration Ltd. Flatland built its oil company and sold its assets in 2002. Monea then went on to form a new company for a Chinese investment group out of China in 2006. His oil field connections allowed him to build an exploration and development team. The Chinese company eventually moved its offices to Calgary, Alberta.

Monea holds professional engineer and geoscientist designations and is a member of the Canadian Institute of Corporate Directors.

“Key Developments in CCS (Saskatchewan’s Input)” John Gale, General Manager, IEAGHG

John Gale joined the IEAGHG R&D Programme in 1999 and managed the Programme’s activities on Non-CO2 greenhouse gases, greenhouse gas abatement in energy intensive industries and geological storage of CO2 before becoming General Manager in 2008. He represents IEAGHG on various IEA committees as required, such as the IEA Working Party on Fossil Fuels and coordinates IEAGHG’s input to IEA publications like World Energy Outlook and Energy Technology Perspectives. He also manages IEAGHG’s input to the GHGT (Co-Chair) and PCCC (Chair) conferences series.

In addition to his work with IEAGHG, he was one of the co-coordinating lead authors on the 2005 IPCC Special Report on CO2 Capture and Storage for which he was acknowledged as a contributor to the Nobel Peace Prize awarded to the IPCC in 2007; he has been Editor-in-Chief of the International Journal on Greenhouse Gas Control since 2007; and, is currently the Chair of the Independent Advisory Panel for the UKCCSRC.

17

“Details of the IEAGHG / U.S. DOE Report on The Boundary Dam CCS Project” Carolyn K Preston, Principal Consultant, CKP & Associates Consulting

During her 25 years working on technology innovation in oil sands, enhanced oil recovery, and coal mining, Carolyn Preston has held a variety of leadership and engineering positions in industry and government. Today, Dr. Preston runs her own consulting business in Calgary, where she supports industry in making sustainable energy and water technology choices.

Among her achievements during 2007-2010 as CEO of the Petroleum Technology Research Centre in Regina, Dr. Preston initiated the Aquistore Project, Canada’s first deep saline carbon storage monitoring project. During 2006-2007, Carolyn served as the Project Integrator for the IEAGHG Weyburn-Midale CO2 Monitoring and Storage Project, integrating science, engineering and public engagement activities on CCS issues.

Today, Dr. Preston is both a Professional Engineer and a Professional Chemist registered in Alberta, and she holds a BSc in Engineering Chemistry from Queen’s University and a PhD in Physical Chemistry from the University of Toronto.

“Technical Development and Collaboration Going Forward”Max Ball, Senior Advisor, CCS Initiatives, SaskPower

Max Ball leads SaskPower’s Shand Carbon Capture Test Facility (CCTF) development team, a group that has built a unique platform for international clients to test new and emerging systems that capture CO2 emissions from coal-fired thermal facilities.

Mr. Ball previously led the team that created the conceptual design and preliminary business case for building the Boundary Dam CCS project.

Mr. Ball holds a Bachelor of Science in Mechanical Engineering from the University of Saskatchewan and has over 35 years of experience in the planning, design, construction and operation of generating facilities for SaskPower. Prior to undertaking management of the CCTF project, he managed SaskPower’s supply planning.

“Boundary Dam Operational Experience and Opportunities for Future Projects” Corwyn Bruce, Manager, Supply Development- Carbon Capture, SaskPower

Professional Engineer Corwyn Bruce was the Associate Manager responsible for the rebuild of Boundary Dam’s Unit #3 and its integration to the carbon capture facility at the Boundary Dam Integrated CCS Project. Mr. Bruce has worked with SaskPower for the past 10 years, serving as a Project Leader completing several control system retrofits before joining the Boundary Dam CCS project. During this time, he led the control system replacement projects at Poplar River Power Station in 2006 and again in 2008, when he served as the Commissioning Engineer.

Prior to joining SaskPower, he spent 10 years working for Bailey Controls/ABB, designing, commissioning and tuning control system retrofits on thermal power plants throughout Western Canada. Mr. Bruce holds a Bachelor of Science in Mechanical Engineering from the University of Saskatchewan, graduating in 1994.

18

“Boundary Dam Costs, Revenues and Business Case”Doug Daverne, Director, Supply Development- Carbon Capture, SaskPower

Doug Daverne is Manager for SaskPower’s Boundary Dam CCS project. His role is to lead the plant engineering and project management activities for the overall Boundary Dam Unit #3 (BD3) project, including execution of the CO2 capture retrofit, life extension, and modernization of Unit #3.

Prior to undertaking the BD3 project, he was also involved in studies of new coal-fired power generation with CCS, including other technologies such as oxyfuel.

Mr. Daverne holds a Bachelor of Science in Mechanical Engineering from the University of Saskatchewan and has been working for over 20 years with SaskPower in the design, construction and operation of generating equipment and facilities.

“Regulation of CO2 - Enhanced Oil Recovery and CCS in Saskatchewan”Floyd Wist, Government of Saskatchewan

Floyd Wist is the Executive Director of Energy Policy with the Ministry of the Economy of the Province of Saskatchewan. He has been involved in funding energy technology research and development for over 35 years and has advised the government on climate change issues for over 20 years.

He chaired the joint government-industry group which managed the International Energy Agency Greenhouse Gas Weyburn-Midale CO2 Monitoring and Storage Project, the world’s largest research project involving geological storage of carbon dioxide. He is involved with a number of other CO2 capture and storage initiatives in Saskatchewan.

19

“The Role of Enhanced Oil Recovery, Permanent Storage and Field Monitoring”Erik Nickel, M.Sc., P. Geo, Senior Project Manager, PTRC

Erik Nickel graduated from the University of Saskatchewan with a degree in Geology in 1994 and obtained his Master’s degree in geology from the University of Regina in 2008. After a 5 year tour as a wellsite geological consultant, Erik spent 15 years as a research geologist with the petroleum geology branch of the Saskatchewan Geological Survey. His research interests, while there, were primarily in the Mississippian carbonates of southeast Saskatchewan, performing some of the original Midale reservoir characterization for PTRC’s Weyburn project starting in 2001. Erik also studied many other aspects of Saskatchewan’s petroleum and natural gas resources, most notably an extensive body of work on the geology of Bakken tight oil reservoirs. Erik joined the PTRC in 2014 and is primarily responsible for the management and delivery of enhanced oil recovery research programs, including STEPS and HORNET, as well as assisting in the Centre’s carbon capture and storage projects (Aquistore and Sask CO2 User).

TIME BUS DETAILS LOCATION

07.15 1 & 2 Grab TOGO Breakfast and Board Bus Verdi Room, Delta Hotel Lobby

7.30 Depart Regina Delta Hotel, Regina

10.00 Arrive at Boundary Dam Security Check-In

10.30 Introductory Presentation / Interactive Tour / Coffee Mine Building

11.30 PPE Distribution Mine Building

11.45 Boundary Dam Power Station and CCS Facility Tours BD Power Station & CCS Facility

13.15 Lunch Mine Building

14.15 Aquistore Tour Aquistore

15.00 Depart Estevan Aquistore

17.30 Arrive in Regina Delta Hotel, Regina

08.15 3 & 4 Grab TOGO Breakfast and Board Bus Verdi Room, Delta Hotel Lobby

8.30 Depart Regina Delta Hotel, Regina

11.00 Arrive at Boundary Dam Security Check-In

11.30 Introductory Presentation / Interactive Tour / Lunch Mine Building

13.00 PPE Distribution Mine Building

13.15 Aquistore Tour Aquistore

14.00 Boundary Dam Power Station and CCS Facility Tours BD Power Station & CCS Facility

15.30 Depart Estevan Mine Building

18.00 Arrive in Regina Delta Hotel, Regina

PPE will be provided onsite, please ensure you have long trousers and flat, closed toe shoes

Site Visit in Detail

20

21

22

Notes

Notes

23

Notes

24

Notes

25

IEA Greenhouse Gas R&D Programme Pure Offices, Hatherley Lane Cheltenham, Glos. GL51 6SH, U.K.

Tel: +44 (0)1242 802911 [email protected] www.ieaghg.org www.ghgt.info

Documents

PCCC - czech-norway-pilotccs.czczech-norway-pilotccs.cz/wp-content/uploads/2015/...2 . Monitoring and Storage Project. All three projects are contributing in a significant way to the