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International Journal of Applied Environmental Sciences
ISSN 0973-6077 Volume 12, Number 7 (2017), pp. 1281-1300
© Research India Publications
http://www.ripublication.com
Petrogenesis of ultramafics and mafics of batampudi
complex, Khammam district, Telangana state, South India.
1T Brahmaiah, 1O Vijaya Kumari 2K Sai Krishna
3Dr. Ch Ravi, 1Dr. K S Sai Prasad*
1Department .of Geology, Sri Venkateswara University, Tirupathi-517501,
2Dept. of Geology, Kakatiya University, Jangoan, Warangal. 3University PG College, Kakatiya University, Jangoan, Warangal.
Abstract
Present paper deals with the petrogenesis of gabbros and pyroxenites of
Batampudi Anorthositic complex, Khammam district, Telangana, South India.
The geochemical relations of gabbro and pyroxenite suggest tholeiitic to
calcalkaline signature. They are further characterised by low Th abundance
and a distinct Nb-Ta and Zr-Hf through, which are characterstic of tholeiitic
basalts produced at destrictive plate margins or within plate tholeiites
contaminated by continental crust.
Keywords: Bethampudi, Petrogenesis, Ultramafics, Mafics (gabbros) and
Pyroxenite
INTRODUCTION:
The study of ultramafics and mafic rocks is important for various aspect. It could
reveals the magmatic processes related to fractional crystallization and crystal
accumulation, both in continental lithospheric or oceanic environments. Additional,
these rocks could contain significant contents of Au, Ni, and PGE. Moreover, the
Ultramafic and mafic rocks stand out due to their ultramelonocratic nature, high
identity, less than 45% Silica, and high magnesium (MgO>12%) and low aluminium
(Al2O3 <10%) contents. Common examples of Ultramafic and mafic are peridotites
1282 T Brahmaiah, O Vijaya Kumari, K Sai Krishna, Dr. Ch Ravi, & Dr. K S Sai Prasad
and pyroxenites from the Layered and alpine complex and Komatiites and ultramafic
basalts from greenstone sequences. In all these lithotectonic associations the
composition of the mantle from where they derived is recorded. They are associated
with extensional tectonics processes that have occurred in the earth’s crust since the
Paleoarchean. For the reason the distribution of this type of magmatism is worldwide
and not restricted to a specific geotectonic environment.
The Bethampudi Anorthositie Complex (BAC) is in northern portion to Chimalpahad
Layered Complex (CLC), situated within the NSB (Appavadhunulu et al 1976;
Narasimha Reddy and Leelanandam, 2004; Brahmaiah T et al 2016). is the largest,
deformed and metamorphosed Archaean anorthosite complex in southern Peninsular
India (Leelanandam, 1987; Ashwal, 1993; Narsimha Reddy and Leelanandam, 2004;
Bose, 2007; Brahmaiah T et al 2016). The Bethampudi anorthosite Complex (BAC)
includes anorthosites, Gabbroic anorthosites and Anorthositic gabbros and
subordinate gabbros and pyroxenites and mafic and ultramafic rocks and
Amphibolites.
GEOLOGICAL SETTING
The Bathumpudi Anorthosite complex extending >100 sq. km included in the survey
of India Toposheet Nos. 65C/7 and 65C/10; and boundary by latitudes 17°30' and
17°35' N, and longitudes 80°25' and 80°35' E (Fig. 1). The BAC is syntectonically
emplaced as a “sill-like” intrusive body trending NE – SW direction within the
Khammam Schist Belt (KSB).
Fig. 1: Location& Geology map of Bethampudi Layered Complex
(Modified after M N Reddy et al 2006)
Petrogenesis of ultramafics and mafics of batampudi complex, Khammam.. 1283
The Bethampudi complex is intruded by younger intrusive dyke, and sills of mafic
nature and preserved as enclaves amphibolites. The rocks of BAC have been affected
by three phases of ductile-brittle deformation and metamorphism under upper
amphibolite to lower granulite facies (Narsimha Reddy and Leelanandam, 2004;
Brahmaiah T et al, 2016);
Gabbros are the distinctive mafic rocks of the study area, but they are parsley
distributed, typically in isolated patches that have limited aerial extent. Gabbros
occur as thin, sheet-like bodies and lenses, parallel to the anorthosites and as cross
cutting dykes in the surrounding by amphibolite and other country rocks as well as
across patches. The sheet like bodies trend NE – SW. parallel to the anorthosites and
enclosing country rocks while the dykes’ trend in many directions. The rocks are
generally garentiferous, medium-to coarse-grained and dark coloured and have
hypidiomorphic textures. Gabbros are characterized by color indices ranging from
approximately 65 to 85, with the mafic minerals being dominated by pyroxene,
amphibole, and garnet. Plagioclase feldspar is the dominant light colored mineral in
these rocks (Fig 2 A&B). Magnetite and ilmenite can also be readily identified. All
of these rocks are strongly deformed and metamorphosed and show consistent
geneissic banding. Colors range from dark grey to green-grey and grain sizes range
from very coarse to medium. The plagioclase feldspar crystals seem to preferentially
resist weathering leaving more plagioclase, whereas the hand samples tend to be
much darker, epically on freshly cut surfaces.
Ultramafic rocks (Pyroxenites) occur as scattered outcrops, as short lenses and
disconnected bands, and are surrounded by the supracrustals. The color index of the
pyroxenite generally >85% and displays green to dark green in color. These rocks are
generally coarse-grained, highly weathered and stained with yellowish tint, thus
making poor outcrops (Fig 2 C&D).
A B
1284 T Brahmaiah, O Vijaya Kumari, K Sai Krishna, Dr. Ch Ravi, & Dr. K S Sai Prasad
Fig. 2: A) Highly weathered isolated pyroxenite mound having contact with Gabbro in the study area, B) Foliation in the pyroxinites, C) Coarse grained gabbros in the study area and D) Sharp contact between gabboro and anorthosite in the study area.
PETROGRAPHY:
Petrographic analysis was performed on the pyroxenite and gabbro lithiologies of the
study area. Sixteen thin sections were prepared from the rock samples. The
petrographic descriptions of these rocks reveal the mineral content micro-textural
relationships between the grains and deformational as well as alteration structures.
Pyroxenites contains clinopyroxene and orthopyroxene in more or less equal
proportion exhibiting cumulous texture (Fig.3A). Both clino- and ortho-pyroxenes
have exsolution lamellae (Fig.3B). Plagioclase is generally absent. Alteration of
clinopyroxene into amphibole is very common. Fractured clinopyroxene is filled with
iron oxide. The accessory phase being the magnetite and ilmenite. In thin section
gabbro is relatively plagioclase poor, with average plagioclase abundances of 10 to
20%. Orthopyroxene is typically coarse grained and is characterized by subhedral
crystals provided indication of magmatic origin (Fig.3C). The plagioclase is mainly
equigranular; medium grained and display polygonal texture with angular crystal
margins (Fig.3D). The modal composition of ultramafic and gabbros are given in
Table- 1.
Table-1: Model composition of Mafic and Ultramafic rocks
S.No Mafics (Gabbros) Ultramafics (Pyroxenites)
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
Plagioclase 56 62 55 56 61 68 62 63 1.9 --- 2.2 --- 1.6 --- --- 1.2
ClinoPyroxene 23 15 34 20 18 10 18 19 83 82 82 85 81 84 83 85
Orthopyroxene 16 13 9 14 9.2 9.1 10 11 5.2 7.6 8.3 6.6 5.4 7.3 8.4 4.8
Hornblende 4.6 7.9 1 4 1.6 2.2 3.2 3.2 1.2 3.2 1.4 2.4 4.7 3.8 2.2 3.2
Biotite 0.4 0.8 --- 5 0.6 2.4 2.1 1.8 --- 1.4 --- 1.4 --- 1.8 1.6 ---
C D
Petrogenesis of ultramafics and mafics of batampudi complex, Khammam.. 1285
Olivine 0.5 2.1 --- 1.2 4.3 1.2 --- --- 2.1 --- 0.3 --- --- 1.2 --- ---
Garnet 1 0.8 1.2 --- --- --- --- --- --- --- ---
Magnetite/
ilmanite
0.3 0.5 1 2.5 4.2 5 2 --- 4.3 5.8 5.2 5.2 4.6 3.1 4.6 3.8
Apatite --- --- --- --- 0.3 0.6 --- 0.8 1.6 --- --- --- 1.1 --- --- 1.3
Fig. 3: A) Pyroxenite with cumulate olivine and chromite and intercumulus plagioclase, B) Holocrystalline pyroxenite, coarse-grained dominated by orthopyroxene, clinopyroxene and olivine, with an inequigranular texture. In some places intergranular areas are filled with a fine-grained assemblage of minerals replacing intercumulus phases, C) An olivine gabbro that contains cumulate olivine and plagioclase in a matrix of intercumulate pyroxene and magnetite (black) that crystallized from trapped intercumulate liquid and D) Plagioclase occurs as euhedral to subhedral stubby tabular laths and exhibits well developed polysynthetic twinning. Pyroxene occurs as both subhedral elongate prismatic crystals. and as smaller rounded or intergranular crystals. Both augite and orthopyroxene (hypersthene) contain well developed exsolution lamellae. Biotite is spatially associated with pyroxene occuring both as inclusions and along the margins of grains.
A B
C D
1286 T Brahmaiah, O Vijaya Kumari, K Sai Krishna, Dr. Ch Ravi, & Dr. K S Sai Prasad
PETROCHEMISTRY:
Major, trace and rare earth element (REE) data of gabbro and ultramafic roks of
Bathampudi complex are given in Table-2&3. The geochemical signatures of both
gabbro and ultramafics show consistent and complementary variation in major trace
and REE. The SiO2 abundance covers a narrow compositional range, gabbros (46.3 to
47.1 wt%) and ultramafics (43.5 to 53.7 wt%), Al2O3 from 15.1 – 201.5; MgO from
5.05 – 16.3; CaO from 9.2 – 11.0; Total iron from 9.0 – 11.0 and TiO2 from 0.09 –
1.7, while the composition of Al2O3, MgO, CaO, Total Iron and TiO2 in ultramafics
varies from 2.11 – 2.75; 10.12 – 15.06; 11.2 – 20.68; 8.96 – 11.04; 0.13 – 0.28. The
relatively high Al2O3 and Na2O) can be attributed the presence of plagioclase in
gabbros.
The Cao and Al2O3 relationship of both gabbro and ultramafics show their trend
towards primordial mantle (Al2O3/CaO= >1). The CaO/ Al2O3 ratio ranging from
0.50 to 0.60 in gabbros and from 0.11 to 0.16 in ultramafics which conforms to the
primordial mantle, where CaO/ Al2O3 ratio is 0.79 (Halfmann, 1988).
On the alkali (Na2O + K2O) vs SiO2 diagram (Fig.4) all samples are broadly classified
as gabbro and gabbroic diorite. A plot for R1 – R2 (Fig.5) after De la Roche et al
(1980) indicated that these samples are of Gaggro and ultramafic rocks. According to
peccerillo and Taylor (1976) SiO2 – K2O plot these rock samples belong to tholeiitic
series (Fig.6). Same has been conformed when all samples plot in Y vs, Zr diagram
(Fig.7). The chemical analysis indicate that the magma type is tholeiitic but trending
towards a calc-alkaline nature, this view is also supported by AFM diagram (after
Irven and Bargar, 1975) (Fig.8). Jenson (1976) Al2O3 - Feo+TiO2 – Mgo diagram
conforms that gabbros cluster on high-Fe (HFT) tholeiitic basalts and ultramafic rocks
are of basaltic komatitic (BK) in nature(Fig.9). The plot again indicates that there is
an overall tholeiitic affinity of magma trending towards calc-alkaline nature.
Fig.3.Total – alkali Silica Diagram (Le Bas et al. 1986)
Petrogenesis of ultramafics and mafics of batampudi complex, Khammam.. 1287
Fig. 5.R1-R2 plot (De la Roche et al. 1980)
Fig.6. SiO2 Vs K2O plot (Peccerillo and Taylor 1976)
1288 T Brahmaiah, O Vijaya Kumari, K Sai Krishna, Dr. Ch Ravi, & Dr. K S Sai Prasad
Fig.7: Zr vs. Y plot of Ross and Bedard (2009).
Fig.8: AFM triangular diagram, showing the demarcation in the calc-alkaline divisions. A = Wt% Na2O + K2O, F = Wt% FeO+Fe2O3 and M = Wt% MgO.
Petrogenesis of ultramafics and mafics of batampudi complex, Khammam.. 1289
Fig.9: Al2O3–Fe2O3 + TiO2–MgO (Jensen 1976) triangular plot
Condrite normalized REE plot (after Boynoton, 1984) of ultramafic rocks reflects
negative Eu anomaly with slight enrichment of LREE. The negagive Eu anomaly in
these rocks may be interpreted as due to the fractionation of plagioclase + hornblende
can be imposed when the melt phase enters the stability field of plagioclase. Gabbros
show a low LREE and slight enrichment of HREE pattern with low Al2O3, CaO, Sr
content and absence or positive Eu anomaly suggest the removal of plagioclase from
basic parent magma or may be due to the magma that might have segregated at such
depth where plagioclase is not stable and hance could not be fractionated (Barker et
al., 1976), (Fig.10)
Fig.10: REE Chondrite-normalized multi-element diagram (Boynton 1984)
1290 T Brahmaiah, O Vijaya Kumari, K Sai Krishna, Dr. Ch Ravi, & Dr. K S Sai Prasad
Table-2 Major element concentration of Mafic and Ultramafic rocks
S.No Mafics (Gabbros) Ultramafics (Pyroxenites)
1/34 2/39 3/33 4/31 5/38 6/44 7/46 8/58 9/61 10/62
SiO2 47.01 46.52 46.28 46.60 47.10 52.06 53.72 43.48 48.60 49.47
TiO2 0.13 0.18 0.28 0.23 0.21 0.26 0.09 0.72 0.36 1.78
Al2O3 20.49 15.08 17.24 17.60 17.46 12.22 19.08 20.68 19.88 17.97
Fe2O3t 11.92 9.94 11.06 10.97 11.06 8.96 10.08 11.04 10.56 10.16
MnO 0.18 0.18 0.16 0.17 0.15 0.17 1.11 0.46 0.79 0.63
MgO 5.05 16.63 10.87 10.85 7.66 21.36 10.12 15.06 12.59 14.78
CaO 11.00 9.22 9.60 9.94 10.25 2.11 2.75 2.31 2.53 2.43
Na2O 2.72 0.98 1.53 1.74 3.04 0.59 0.70 0.70 0.70 0.67
K2O 0.18 0.05 0.14 0.12 0.43 0.09 0.11 0.03 0.07 0.08
P2O5 0.01 0.01 0.06 0.03 0.04 0.02 0.10 0.01 0.06 0.05
Total 98.82 98.70 97.66 98.39 98.97 97.71 97.95 94.05 96.00 96.43
CIPW
Q 1.88 0.00 1.86 0.60 0.00 2.72 12.17 0.00 3.01 2.94
Or 1.06 0.30 0.83 0.73 2.54 0.53 0.65 0.00 0.41 0.44
Ab 23.02 8.29 12.95 14.75 25.72 4.99 5.92 0.00 5.92 5.69
An 43.17 36.60 39.76 39.84 32.73 2.84 4.04 3.07 3.55 3.38
Lc 0.00 0.00 0.00 0.00 0.00 0.00 0.00 67.95 0.00 0.00
Ne 0.00 0.00 0.00 0.00 0.00 0.00 0.00 3.21 0.00 0.00
Kp 0.00 0.00 0.00 0.00 0.00 0.00 0.00 49.14 0.00 0.00
Di 8.67 7.07 4.36 6.80 9.54 44.89 57.70 0.00 69.69 66.68
Wo 0.00 0.00 0.00 0.00 0.00 0.00 6.84 0.00 2.31 0.00
Hy 8.56 31.59 25.06 23.88 9.19 32.50 0.00 0.00 0.00 6.66
Ol 0.00 4.73 0.00 0.00 3.84 0.00 0.00 26.59 0.00 0.00
Dcs 0.00 0.00 0.00 0.00 0.00 0.00 0.00 30.79 0.00 0.00
Il 0.39 0.17 0.34 0.37 0.32 0.25 0.34 0.53 0.44 0.39
Tn 0.14 0.00 1.33 0.40 3.96 0.00 0.00 0.00 0.00 0.00
Ap 0.02 0.02 0.14 0.06 0.10 0.05 0.24 0.02 0.13 0.11
Sum 86.91 88.77 86.61 87.43 87.92 88.76 87.90 83.03 85.46 86.29
Niggle
si 137.09 104.10 120.66 119.15 130.70 110.88 138.32 92.40 113.16 112.55
al 35.21 19.88 26.48 26.52 28.55 2.65 4.17 2.89 3.47 3.25
fm 22.40 55.82 42.60 41.73 32.04 68.13 41.27 48.54 45.25 51.36
c 34.37 22.10 26.81 27.23 30.47 27.88 52.63 47.08 49.59 43.80
alk 8.02 2.20 4.10 4.52 8.94 1.34 1.93 1.48 1.68 1.59
k 0.04 0.03 0.06 0.04 0.09 0.09 0.09 0.03 0.06 0.07
mg 0.98 0.99 0.99 0.99 0.99 1.00 0.94 0.98 0.97 0.98
c_fm 0.57 0.15 1.41 0.69 3.72 0.21 0.35 0.45 0.40 0.35
ti 0.01 0.01 0.07 0.03 0.05 0.02 0.11 0.01 0.05 0.05
p 1.53 0.40 0.63 0.65 0.95 0.41 1.28 0.97 1.10 0.85
qz 5.00 -4.69 4.26 1.07 -5.05 5.52 30.61 13.53 6.43 6.19
Petrogenesis of ultramafics and mafics of batampudi complex, Khammam.. 1291
Table-3: Trace and Rare Earth Element concentration of Mafic and Ultramafic rocks.
S.No Gabbros Ultramafics
1/34 2/39 3/33 4/31 5/38 6/44 7/46 8/58 9/61 10/62
Trace (ppm)
Ni 300.40 606.20 113.00 339.87 23.00 1479.60 263.80 562.40 413.10 679.73
Cr 471.00 1534.60 41.00 682.20 41.00 2921.10 472.50 643.70 558.10 1148.85
Co 93.20 84.90 56.00 78.03 35.00 91.10 17.70 48.20 32.95 47.49
V 357.20 188.90 70.00 205.37 70.00 128.40 70.90 48.90 59.90 77.03
Sc 33.20 27.60 16.00 25.60 31.00 25.90 12.20 5.30 8.75 13.04
Rb 0.30 0.80 1.00 0.70 1.00 0.30 3.80 1.60 2.70 2.10
Sr 235.90 57.80 649.00 314.23 692.00 24.90 22.20 32.70 27.45 26.81
Ba 134.30 32.20 154.00 106.83 285.00 14.40 64.20 4.90 34.55 29.51
Y 4.92 1.61 5.50 4.01 13.50 12.16 41.31 13.76 27.54 23.69
Zr 3.60 1.45 25.00 10.02 41.00 7.76 34.11 32.40 33.26 26.88
Nb 0.06 0.00 2.00 0.69 7.00 1.92 4.13 0.46 2.30 2.20
Hf 0.07 0.05 0.40 0.17 0.70 0.26 0.98 2.20 1.59 1.26
Ta 0.47 0.87 0.16 0.50 0.34 0.07 1.07 0.35 0.71 0.55
Th 0.00 0.00 0.09 0.03 0.06 0.00 3.64 1.21 2.43 1.82
U 0.00 0.00 0.03 0.01 0.01 0.00 1.30 0.60 0.95 0.71
REE(ppm)
La 1.65 0.63 2.53 1.60 5.37 3.35 16.53 15.26 15.90 12.76
Ce 2.90 0.78 1.60 1.76 1.96 13.64 39.43 53.51 46.47 38.26
Nd 1.61 0.36 4.58 2.18 10.62 8.18 16.03 16.72 16.38 14.33
Sm 0.42 0.07 1.05 0.51 2.75 2.10 4.10 4.48 4.29 3.74
Eu 0.36 0.04 0.55 0.32 1..97 0.72 0.41 0.48 0.45 0.51
Gd 0.56 0.11 0.69 0.45 2.70 2.01 4.27 2.53 3.40 3.05
Tb 0.12 0.03 0.19 0.11 0.23 0.28 0.77 0.28 0.53 0.46
Yb 0.46 0.21 0.67 0.45 1.19 0.82 2.61 0.94 1.78 1.54
Lu 0.08 0.04 0.10 0.07 0.18 0.13 0.38 0.13 0.26 0.22
TECTONIC SETTING:
The gochemistry of mafic and ultramafic rocks is most commonly used to
discriminate tectonic setting. The idea of trying to fingerprint magmas from different
tectonic setting chemically is best attributed to Pearce and Cann (1971 & 1973). This
study show that it is possible to use geochemistry to distinguish between basalts
produced in different tectonic settings. The basalts are formed in almost every
tectonic environment and they are believed to be geochemically sensitive to the
changes in plate tectonic frame work. The Mg# ranges from 30 to 60 for gabbros and
from 50 to 70 for ultramafics indicating crystallisation from both primitive and
evolved magmas. Inorder to undetstand the tectonic environment of the studied
samples plotted in Hf – Rb/30 – 3Ta (Harris et al., 1986) diagram (Fig.11) and in
1292 T Brahmaiah, O Vijaya Kumari, K Sai Krishna, Dr. Ch Ravi, & Dr. K S Sai Prasad
different plots of Schandl and Gorton (2002) depicts that the these rocks fall in the
within plate volcanic zones (Fig.12).
Fig. 11: Triangle diagram of Hf – Rb/30 – 3Ta (Harris et al., 1986)
Fig.12: Tectonic classification Diagram of Volcanic rocks after (Schandl and Gorton
2002)
Petrogenesis of ultramafics and mafics of batampudi complex, Khammam.. 1293
The NMORB and EMORB normalised trace element plots for ultramafic and gabbro
rocks are presented (Fig.13&14). Relative to primitive mantle the both types of rocks
are enriched in LILE and LREE. They further characterised by a low Th, abundance
and a distinct Nb – Ta; Zr – Hf through. These features are characterstic of tholeiitic
basalt produced at distructive plate margins or within plate tholeiitics contaminated by
continental crust (Hawkesworth et al., 1994; Ambarasu et al., 2011; Satyanarayana et
al., 2011; and Mohammed Dar et al., 2014). The depletion of Nb is not affected by
fractional crystallisation and it is known that Nb anomaly in modern arc volcanic is
independ of the degree of crystallisation (Mohammed Dar et al., 2014).
Fig.13: N-MORB-normalized multi-element diagram (Sun and McDonough 1989)
Fig.14: E-MORB-normalized multi-element diagram (Sun and McDonough 1989)
PETROGENSIS:
Chemical data can provide useful information on the course of fractional
crystallisation/magmatic evolution. Harker variation diagrams prepared for study area
rocks (Fig.15). In the diagram Al2O3, MgO, CaO, and Na2O/K2O ratio shows a
positive correlation with SiO2, where as FeOt, P2O5, TiO2 show a negative correlation,
which is characteristics of an igneous rock. Plots of MgO versus major oxides
(Fig.16) show strong negative correlation with FeOt, Al2O3, Na2O, K2O and strong
positive correlation with SiO2, CaO and K2O/Na2O ratio. A positive correlation
between CaO and MgO supports the fractionation of clinopyroxenes. During the
1294 T Brahmaiah, O Vijaya Kumari, K Sai Krishna, Dr. Ch Ravi, & Dr. K S Sai Prasad
plagioclase removal, CaO/Al2O3 ratio increases whereas it remains constant during
olivine fractionation (Dungan and Rnodes, 1978).
Fig.15: Harkers’ Variation diagram of SiO2 vs. Major elements for Gabbros and Ultramafics of the study area.
Petrogenesis of ultramafics and mafics of batampudi complex, Khammam.. 1295
Fig.16: Binary Plots of MgO versus major oxides for Gabbros and Ultramafics of the
study area.
High values of CaO/ Al2O3 (> 0.5) in the studied gabbros may be due to plagioclase
fractionation. Fractional crystallisation associated with crustal contamination is an
important process during magmatic evolution (De-Paolo, 1981). Low concentration
and narrow range of K2O and Na2O in the study area samples suggests in favour of
their minimal crustal contamination.
The Nb/La values for gabbros and ultramafic rocks (0.51 and 0.23 respectively) are
not only very low compared to those of primitive mantle (1.02) of Taylor and
McLennan (1985) and 1.04 of Sun and McDonouth (1989), but also lower than the
average bulk crust (0.69). Such lower values are not expected to be produced by
processes of contamination by an average crustal component. Thus it can be inferred
that the enrichment of LILEs and depletion of HFSEs may also occur in within plate
tectonic setting rocks due to crustal contamination.
The ascent of the ultramafic magma through the continental lithosphere to the surface
makes crustal contamination inevitable, either through assimilation-fractional
crystallisation or thermal erosion of floor rocks, due to their higher liquidus
temperature (Halama et al. 2004; Tang et al. 2012; and Chandran kumar and Ugarkar,
1296 T Brahmaiah, O Vijaya Kumari, K Sai Krishna, Dr. Ch Ravi, & Dr. K S Sai Prasad
2017). Sylvester et al (1977) was the first person to say the use of Nb/Th ratios in
Archaean basalts as a monitor of the extent and timing of extraction of continental
crust from the mantle. The primitive mantle has Nb/Th ratio of 8, and Phanerozoic
upper continental crust a value of 1.1 (Sun and McDonogh, 1989; Rudnink and Gao,
2003; and Condie, 2005). Nb/Th value of the studied ulatramafic rocks varies
between 0.38 to 1.21 with an average of 0.73, which is similar to that of Archaean
continental crust has a value of 0.76 (Condie, 2005). The ultramafic rocks of the study
area exhibit Nb/Th value less than 1, and are characterised by negative Zr anomalies
coupled with Nb-Ta negative anamalies and enriched LREE suggests probable crustal
contamination enroute to the surface.
Contrarily, the Nb/Th values more than 8 for gabbros suggest crustal contamination
incurred by these litho units. Contamination of these litho units by the older salic
crustal basement en route to the surface is a possibility. Alternatively, contamination
of the magma source of the studied basement and gabbros due to the interaction of
mantle plumes with metasomatized continental mantle lithosphere also cannot be
ruled out. Said et al (2012) have stated that the contamination by subduction
metasomatized mantle lithosphere dominates due to interaction of mantle plumes with
the base of the lithosphere than crustal contamination. All the samples of ultramafic
and Gabbros exhibit negative Nb-Ta anomalies implying assimilation of subduction-
processed lithospheric mantle material by plume derived magma (Song et al. 2008).
Fan and Kerrich (1977) used Zr and Hf anomalies have been used to constrain the
nature of sources and melt residues. Study area gabbors and ultramafics exhibit slight
to moderave Zr and Hf anomalies in NMORB normalized spider diagram (Fig…..),
implying their derivation from a deep mantle source (~ 350 -250 km), where garnet
fractionated or was retained in the residue (Fan and Kerrilch, 1977). Strong negative
Nb anomalies on the spider diagram have been accounted for magma generation at
shallower mantle in arc environments or even crustal contamination processes (Polat
and kerrich, 2000).
CONCLUSIONS:
Present paper deals with the petrogenesis of gabbros and pyroxenites of Batampudi
Anorthositic complex, Khammam district, Telangana, South India. Pyroxinites are
composed of coarse grained clinopyroxenes, orthopyroxenes and hornblende, olivine
and magnetite as accessary minerals. Gabbros are mainly composed of plagioclase
and pyroxenes with minor amounts of amphibole and apatite and magnetite as
accessory minerals. Geochemically these gabbros and pyroxinites are broadly
classified as gabbros and ultramafics respectively and their magma type is tholeiitic
but trending towards a calc-alkaline nature. Condrite normalized REE plot of
ultramafic rocks reflects negative Eu anomaly with slight enrichment of LREE. The
negagive Eu anomaly in these rocks may be interpreted as due to the fractionation of
plagioclase. Gabbros show a low LREE and slight enrichment of HREE pattern with
Petrogenesis of ultramafics and mafics of batampudi complex, Khammam.. 1297
low Al2O3, CaO, Sr content and absence or positive Eu anomaly suggest the removal
of plagioclase from basic parent magma. Tectonic setting discrimination diagrams, in
addition to their geochemical characters such as low Th abundance and very low
Nb/La ratios, enrichment of LILE and depletion of HFSE may also indicates their
occur in within plate tectonic setting rocks due to crustal contamination. Both
pyroxenite and gabbros exhibit negative Nb-Ta, Zr-Hf anomalies, implying
assimilation of subduction-processed lithospheric mantle material by plume derived
magma.
REFERENCES
[1]. Anbarasu, K., Ali Mohammed Dar., Karthikeyan, A. and Prabhu, D. (2011).
Field characteristics and geochemistry of pyroxenite and gabbro from
Odhimalai and Thenkalmalai hillocks of Bhavani ultramafic complex-South
India. International Multidisciplinary Research Journal, 1/2:20 26.
[2]. Appavadhanulu, K., Setti, D.N., Badrinarayanan, S., Subba Raju, M., (1976).
The Chimalpahad meta-anorthosite complex, Khammam district, Andhra
Pradesh. Geology Survey of India, Miscellaneous Publication 23, 267–278.
[3]. Ashwal, L.D. (1993) Anorthosites. Springer, Berlin, 422.
http://dx.doi.org/10.1007/978-3-642-77440-9
[4]. Barker, F., Wones, D. R., Sharp, W. N. & Desborough, G. A. (1976). The
Pikes Peak batholith, Colorado Front Range and a model for the origin of the
gabbro–anorthosite–syenite–potassic granite suite. Precambrian Research, 2,97–160.
[5]. Bose Mihir, K. (2007) Chimalpahad Anorthosite Complex—An Exile from
the Eastern Ghats Belt of the India Shield. Igneous Petrology: 21st Century
Perspective. Jyotisankar and Bhattacharyya, Dept. of Geology, University of Calcutta, India
[6]. Boynton W V (1984) Cosmochemistry of the rare earth elements: meteorite
studies. In: Henderson P (eds) Rare Earth Element Geochemistry. Elsevier,
Amsterdam, pp 63-114
[7]. Brahmaiah, T., Ravi, C., Krishna, K.S., Papanna, G. and Prasad, K.S.S.
(2016) Petrography of Bethampudi Anorthosites Layered Complex from the
Khammam Schist Belt, Telangana, India. Open Journal of Geology, 6, 1434-
1456. http://dx.doi.org/10.4236/ojg.2016.611102.
[8]. Chandan-Kumar B & A. G. Ugarkar (2017): Geochemistry of mafic–
ultramafic magmatism in the Western Ghats belt (Kudremukh greenstone
belt), western Dharwar Craton, India: implications for mantle sources and
geodynamic setting, International Geology Review, DOI:
10.1080/00206814.2017.1278623
[9]. Condie, K.C., (2005), High field strength element ratios in Archaean basalts:
A window to evolving sources of mantle plumes?: Lithos, v.79, p.491–
504.10.1016/j.lithos.2004.09.014.
1298 T Brahmaiah, O Vijaya Kumari, K Sai Krishna, Dr. Ch Ravi, & Dr. K S Sai Prasad
[10]. De La Roche, H. et al. (1980). A classification of volcanic and plutonic rocks
using R1R2-diagram and major element analyses – its relationships with
current nomenclature. Chemical Geology, 29, 183- 210.
[11]. DePaolo, D.J. (1981). A neodymium and strontium isotopic study of the
mesozoic calc-alkaline granitic batholiths of the sierra Nevada and Peninsular
Ranges, California. Journal of Geophysical Research 86. doi:
10.1029/JB080i011p10470. issn: 0148-0227.
[12]. Dungan, M.D., and Rhodes, J.M. (1978) Residual glasses and melt inclusions
in basalts from DSDP legs 45 and 46: Evidence for magma mixing.
Contributions to Mineralogy and Petrology, 67 , 417-431.
[13]. Fan, J., and Kerrich, R., (1997), Geochemical characteristics of Aldepleted
and undepleted komatiites and HREE-enriched tholeiites, western Abitibi
greenstone belt: Variable HFSE/REE systematics in a heterogeneous mantle
plume: Geochimica Et Cosmochimica Acta, v.61, p.4723–
4744.10.1016/S0016-7037(97)00269-X.
[14]. Halama, R., Marks, M., Brügmann, G., Siebel, W., Wenzel, T., and Markl, G.,
(2004), Crustal contamination of mafic magmas: Evidence from a
petrological, geochemical and Sr–Nd–Os–O isotopic study of the Proterozoic
Isortoq dike swarm, South Greenland: Lithos, v.74, p.199–
232.10.1016/j.lithos.2004.03.004.
[15]. Harris N B W, Pearce J A, Tindle A G (1986) Geochemical characteristics of
collision-zone magmatism. In: Coward M P, Ries A C (eds) Collision
Tectonics. Geological Society London Special Publication 19, pp 67-81
[16]. Hawkesworth, C.J. and Clarke, C., (1994). Partial melting in the lower crust:
new constraints on crustal contamination processes in the Central Andes. In:
K.-J. Reutter, E, Scheuber and P.J. Wigger (Editors), Tectonics of the
Southern Central Andes. Springer, Berlin, pp. 93-101.
[17]. Hoffman, A.W., (1988), Chemical differentiation of the Earth: The
relationship between mantle, continental crust and oceanic crust: Earth and
Planetary Science Letters, v.90, p.297–314. 10.1016/0012-821X(88)90132-X.
[18]. Irvine, T. N. & Baragar, W. R. A., (1971). A guide to the chemical
classification of the common volcanic rocks. Canadian Journal of Earth
Sciences, 8, 523-548.
[19]. Jensen, L.S., (1976), A new method of classifying alkali volcanic rocks,
Ontario Division Mines Miscellaneous Paper 66.
[20]. Le Bas, M.J.J., Maitre, R.W.L., Streckeisen, A., Zanettin, B., Le Maitre, R.W.,
Streckeisen, A., and Zanettin, B., (1986), A chemical classification of volcanic
rocks based on the total alkali-silica diagram: Journal Petrol, v.27, p.745–
750.10.1093/petrology/27.3.745.
[21]. Leelanandam, C. (1987) Proterozoic Anorthosite Massifs: An Overview.
Indian Journal of Geology, 59, 179-194
[22]. Mohammed Dar Ali., Akhtar., Mir, R., Anbarasu, K., Sathyanarayanan, M.,
Balaram, V., Subba Rao, D. V. and Charan, S.N. (2014). Mafic and ultramafic
rocks in parts of the Bhavani complex, Tamil Nadu, Southern India:
Petrogenesis of ultramafics and mafics of batampudi complex, Khammam.. 1299
Geochemistry constraints. Journal of geology and mining research. Vol. 6(2),
pp. 18-27, March.
[23]. Narsimha Reddy, M. and Leelanandam, C. (2004) Magmatic and Tectonic
Structures from the Chimalpahad Layered Complex, Andhra Pradesh, India.
Gondwana Research, 7, 887- 896.http://dx.doi.org/10.1016/S1342-
937X(05)71072-8.
[24]. Pearce J A & Cann J R (1973) Tectonic setting of basic volcanic rocks
determined using trace element analyses. Earth Planet Sci Lett 19: 290-300.
doi: 10.1016/0012-821X(73)90129-5
[25]. Pearce, J.A., Cann, J.R., (1971). Ophiolite origin investigated by discriminant
analysis using Ti, Zr and Y. Earth Planet. Sci. Lett. 12 (3), 339– 349
[26]. Peccerillo A & Taylor S R (1976) Geochemistry of Eocene calc-alkaline
volcanic rocks from the Kastamonu area, Northern Turkey. Contrib Mineral
Petrol 58: 63-81 doi: 10.1007/BF00384745
[27]. Polat, A., and Kerrich, R., (2000), Archaean greenstone belt magmatism and
the continental growth-mantle evolution connection: Constraints from Th–U–
Nb–LREE systematics of the 2.7 Ga Wawa subprovince, Superior province,
Canada. Earth and Planetary Science Letters, v. 175, p. 41–54.
[28]. Ross, P.S., and Bédard, J.H., (2009). Magmatic affinity of modern and ancient
subalkaline volcanic rocks determined from trace-element discriminant
diagrams: Canadian Journal of Earth Sciences, v. 46 (11), p. 823–839,
10.1139/E09–054.
[29]. Rudnick, R.L., and Gao, S., (2003), Composition of the Continental Crust,
Treatise on Geochemistry. Volume 3. Editor: Roberta L. Rudnick. Executive
Editors: Heinrich D. Holland and Karl K. Turekian. pp. 659. ISBN 0-08-
043751-6. Elsevier, 2003., p.1-64. 10.1016/B0-08-043751-6/03016-4
[30]. Said, N., Kerrich, R., Cassidy, K., and Champion, D.C., (2012),
Characteristics and geodynamic setting of the 2.7 Ga Yilgarn heterogeneous
plume and its interaction with continental lithosphere: Evidence from
komatiitic-basalt and basalt geochemistry of the Eastern Goldfields
Superterrane. Aust: Journal Earth Sciences, v. 59, p. 1–27.
[31]. Satyanarayanan, M., Balaram, V., Sylveste, D.V., Subba Rao., Charan,
Michael Shaffer, S.N., Ali Mohammed Dar. and Anbarasu, K. (2011).
Geochemistry of late-Archean Bhavani mafic/ultramafic complex, southern
India: Implications for PGE metallogeny. Journal of Applied geochemistry.
Vol.13 No. 1, pp 1-14
[32]. Schandl E S & Gorton M P (2002) Application of high field strength elements
to discriminate tectonic settings in VMS environments. Economic Geology 97:
629-642. doi: 10.2113/97.3.629
[33]. Song, X.-Y., Qi, H.-W., Robinson, P.T., Zhou, M.-F., Cao, Z.-M., and Chen,
L.-M., (2008), Melting of the subcontinental lithospheric mantle by the
Emeishan mantle plume; evidence from the basal alkaline basalts in
Dongchuan, Yunan, Southwestern China: Lithos, v.100, p.93–
111.10.1016/j.lithos.2007.06.023.
1300 T Brahmaiah, O Vijaya Kumari, K Sai Krishna, Dr. Ch Ravi, & Dr. K S Sai Prasad
[34]. Sun SS, McDonough WF (1989) Chemical and isotopic systematics of oceanic
basalts: implications for mantle composition and processes. In: Saunders AD,
Norry M (eds) Magmatism in Ocean Basins. Geological Society of London
Special Publications 42, pp 313-345
[35]. Sylvester, P.J., Campbell, I.H., and Bowyer, D.A., (1997), Niobium/Uranium
evidence for early formation of continental crust: Science (80-.)., v.275,
p.521–523.10.1126/science.275.5299.521.
[36]. Tang, D.-M., Qin, K.-Z., Sun, H., Su, B.-X., and Xiao, Q.-H., (2012), The role
of crustal contamination in the formation of Ni–Cu sulfide deposits in Eastern
Tianshan, Xinjiang, Northwest China: Evidence from trace element
geochemistry, Re–Os, Sr–Nd, zircon Hf–O, and sulfur isotopes: Journal Asian
Earth Science, v.49, p.145–160.10.1016/j.jseaes.2011.11.014.
[37]. Taylor S R, McLennan S M (1985) The Continental Crust: Its Composition
and Evolution. Blackwell,Oxford, pp 1-312