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PHASE m REMEDIAL INVESTIGATIONAND FEASIBILITY STUDY FOR
THE CONRAIL SITEELKHART, INDIANA
SITE SAFETY PLAN
Contract 68-W8-0086*Work Assignment (WA) OI-5L7Y
ecology and environment, inc.International Specialists in the Environment
ZF3164 C8094
PHASE m REMEDIAL INVESTIGATIONAND FEASIBILITY STUDY FOR
THE CONRAIL SITEEUCHART, INDIANA
SITE SAFETY PLAN
Contract 68-W8-0086Work Assignment (WA) 01-5L7Y
October 22, 1992
Prepared for:
U.S. ENVIRONMENTAL PROTECTION AGENCYARCS, Region V
Office of Superfund77 West Jackson Boulevard
Chicago, Illinois 60604
ecology and environment, inc.111 WEST JACKSON BLVD., CHICAGO, ILLINOIS 60604, TEL 312-663-9415International Specialist* in the Environment
recycled papar
•colony *nd environment, inc.
S I T E S A F E T Y P L A H
522
A. QEHESAL InTORMATIOB
Version 966
Project Title: Conrail
Project Manager; Bridget Lombard!
Location(s): Elkhart, Indiana
Prepared by: Rod Hackler
Approval by: Laura D. Evana
Site Safety Officer Review:
Project Ho.:
TDD/Pan No.:
ZF3000
NA
Project Dir.: Kevin Phillips
Scope/Objective of Work: See following page.
Date Prepared: October 2, 1992
Date Approved: October 12, 1992
Date Reviewed:
Proposed Date of Field Activities: November 1992 through Harch 1993_
Background Info: Couplet•: { X ) Preliminary: I }
Documentation/Summary:
Overall Chemical Hazard:
overall Physical Hazard
Serious ( )Low [ X ]
Serious [ ]Low ( X 1
Moderate [ ]unknown [ 1
Moderate ( 1Unknown [ }
Waste Type(s):
Liquid [ X 1 ..
Characteristic!*):
Flammable/ [ x )Ignitable
Explosive ( 1
other: Persistent
Physical Hazards:
Overhead ( X ]
Puncture [ }
Noise t X ]
B. sin/nun
Solid ( X ] Sludge ( X ) Gas/Vapor [ X I
Volatile I X ] Corrosive [ x ] Acutely ( X 1Toxic
Reactive ( X I Carcinogen [ x I Radioactive* ( I
Confined* [Space
Burn
ColdStress
I 1
I X ]
BelowGrade
Cut
others
t 1 Trip/rail
t ] Splash
Drill Rig; Trains
I X J
I X 1
'Requires completion of additional form and special approval from th« Corporate Health/Safety group. ContactRSC or HQ.8094:1
IUMUUOJUIN poo tfofoo* jadBd D«pAo8J
SCOPE/OBJECTIVE OF WORK
Tha Phasa XIX RI/FS *t tha Conrail facility will involve l«ad-icr*«n «ug»r campling, •coloqieal •••pling,drainag* network •••plin<|r shallow, int«r»«diata, and badroek monitoring wall installation, soil borings andsampling, groundwatar sampling, and slug taats.
8094:1
Sit* History/Description and Unusual Features (••• Sampling Plan for detailed description): See^ollowing
page.______________________________________________________________
Locations of Chemicals/Wastes: Assume entire sit*
Estimated Volume of Chemicals/Wastes: Unknown
Sit* Currently in Operation Y*s: [ X I Ho: 1 I
C. HAZARD EVALUATION
List Physical Hazards by Task (i.e., drum sampling - explosion hazard, drilling - noise hazard, etc.) and numberthem. (Task numbers are cross-referenced in Section D)
Task/Physical Hazard Evaluation: 1. Lead-screen auger sampling - drill tig, splash, noise, overhead, trains.
2. Soil boring - drill rig, noise, overhead, trains.______________________________•____________________
3. Monitoring well installation - drill rig, splash, overh*adt noise, trains.
1.Monitoring well sampling - splash, trains.____________________________
5. Ecological sampling - splash.___________________________________
6. Drainage network sampling - splash, trains.___________________________
7. Slug tests - splash, trains. __________________________________
ch*mical Hazard Evaluation:
Compound
Carbon tetrachloride
Chloroform
1 , 1-dichloroethylene
Diethylethanolamine
Ethyl Alcohol
Ethylenediaminetetracetic acid
PEL/TWA
2 pp«t
2 ppm
1 ppm
HA
1000 ppm
NA
Rout*of Exposure
Ingest., dermal,eye, skin, inhal.
Ingest . , eye,inhalation
Ingest. , eye,skin, inhalation
Ingest. , skin,•y« jInhalation, eye,skin
Skin, eye
AcuteSymptoms
Irr . eye/nose/throat, headache
Excitement , para-lysis of respir.
Dizziness ,drunkeness
Irr. eyes/skin,respir .
Irr. eyes/nose/throat, headache
Irr . skin/eye
OdorThreshold
340 ppm
260 ppm
HA
0.04 ppm
10 ppm
HA
odorDescription
Sweet
Sweet
Sweet
NA
NA
HA
Note: complete and attach a Hae*rd Evaluation Sheet for major known contaminant
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CHEMICAL HAZARD EVALUATION (CONTINUED)
Compound
Mineral spirits
Oils: Dieaei
Oils, miscellaneous:lubricating
Oils , miscellaneous :motor
Oils, miscellaneous:transformer
Petroleum naphtha
Tetrachloroethylen*
1 ,1,1-trichloro-ethane
Trichloroethylene
PBL/TWA
HA
HA
HA
HA
HA
400 ppm
25 ppm
350 ppm
50 ppn
Rout*of Exposure
Ingest. , akin,eyes, inhalation
Ingest. , eye,skin
Ingest. , skin,•y«ingeition, skin,•y*
Inqestion, skin,•y«
Inhal , skin, eye,ingestion
Ingest. , dermal,eye, akin, inhal.
Ingest. , dermal ,eye, skin, inhal .
Ingest ion', skin,eye, inhalation
AcuteSymptoms
Irr. respir/skin/eyes
Irr. eye/reapir.skin
Irr . eyes/skin
Irr . skin/eye
Irr . skin/eye
Intoxication
Headache, dizii-nass, drowsiness
Irr. mucou* memb/eye/akin, nausea
Irr. eye/nose/throat, nausea,blurred vision
OdorThreshold
HA
HA
HA
HA
NA
HA
47 pp»
390 ppn
82 pp»
OderDescription
NA
HA
HA
HA
NA
NA
Mildly sweet
Sweet t wChloroform-like
SITE HISTORY
Th* Conrail facility is a railyard which routes approximately 3.200 cars p*r day electronically; also carrepair, cleaning, and engine refueling. The identified groundvster plumes are situated beneath residential./commercial zoned areas in Elkhart.
The Conrail facility consists of <;75 acres, *:5i of which is co'-ered "ith concrete or ballast. The Con rail sitehas been the source of many oil discharges to the St. Joseph P,i"er and has a long history of spills and leakingtailcars. Many citizens' complaints ha'-e been filed over the years: there has also been an open dump (now-ro'-ered) and it was also reported that railroad ties, trash. «nd cleaners ha'-'* been buried on-site.
Minimal records weie maintained of spills and/or leaks ?t the.Conrail site prior to 1976. Industries locatedupgradient of the site are not expected to be sources of chlorinated aliphatic compounds. Spills that haveoccurred after 1976 are documented in the follouina outline:
Julv
December 1977
5.000 gal diesel fuel spilled on yard because of vandalism.Oil separation pond overflowed due to heavy rainfallcausing an oil spill.
10,000 gal spill of 48* Caustic Soda Solution (leaking tankcarl .
Julv 1078 An open dump was discovered by the Elkhart Fire Department.This was later "erified by ECHO. The dump was leveled andfilled.
F e b r 11 a r v 1 ° 7 a 1.100 Ib. -pill of Hydrochloric Acid from tank car.Cohered "ith soda ash to neutralize.
Hex a v-a lent Chromium was noted in the effluent (Crawf ordsDitch) f L-?m the rail yard according to a HPDES PublicMot i ce .
Julv Oil spill t? 3t. Joseph River caused by washout of oilseparation ccnd. A boom placed in St. Joseph River, toabsorb "olatiles.
Februa tv 1982 Z7.COO ?al. spill of grain alcohol from tank car that was•tllc'.--d to e-aporate.
Februa rv 1983 7,500 gal. scill of naptha-petroleum based product. Also,in another unrelated incident 25 gal. spill of fuel oil
October 198J
February 1985
November 1-985
July 1986
August 1986
: 1
250 gal. spill of Diesel Fuel.
Liquid Hydrofluoric gas spill, lime was spread over spillsite.
7,500 gal. diesel fuel spilled.
Resident well Sample Results - County Road 175.6 and SOO ppb Trichloroethylene 26.5 and 485 ppb CarbonTetrachloride.
SE corner of Indiana Ave. and Ash Road used for dumping inthe past 10 years .
SITE HISTORY (continued)
Residence W«l_l Samples
Residence well samples in the County Rd. 1 area located HW ?t Conrail site and La Rue St. Area indicated elevatedlewis ranging from 4 to 6,860 ppb of the following chlorinated aliphatic organic compounds.
DichloroethyleneCarbon Tetrachlorid«chloroformT*trachloroethyleneTrichlotroethylene
The residential well sampling conducted by th« EPA and IDEM has established a preliminary delineation of thegroundwater contamination plume in the County Road 1 area. Th« plume follows a northwest line approximately 1.5miles from the intersection of County Road 1 and State P.oute 3?. ?nd is estimated to be approximately 1500 feetin width.
The following chemicals have been stored at the tailyard:
Dj"um Storage AreaMineral SpiritsDiethylamino ethanolEDTA tetrasodium saltChemeoa BX-^5 Cleaning CompoundMIS 170? floor cleanerGlass cleaner J7-13835 class 14Ethyl AlcoholChemlube 230Transformer oilOils-reclaimed, re-refined
Th* EPA has listed the fol lov-in-a a^ soil contaminants »t *:h* Con rail site:
Carbon Tetrachlorid* .chloroformDichloroethylener-rchloro-thyleneTtichlotoethaneTrichloroethylene
1
D. SITE SAFETY WORK FLAP
Sit* Cent col: Sit* Control will be maintained by demarcating a potential hot zone around the drill rig.
revimeter identified? f :•: I "ite secured? I X"
Woi'k Areas Designated? I I Eone(s) of Contamination Identified? I
Personnel Protection (TLD badges required for all field personnel 1:
Anticipated Le>-el of Protection (Cross-reference t?s^ number? t? Section C) :
Assume entire sit*,
Task 1
Task 2
Task 3
Task 4
Task 5
Task 6
Task 7
TASK DESCRIPTION
Lead- sere en auger sampling
Soil boring
Monitoring veil installation
Monitoring well Sampling
Ecological sampling
Drainage Network Sampling
Slug tests
•' B C D
Modifications: Rad-Mini >01 mp.hr (alarm Bounds) ?nd.-or flonito?: readings '0 ppm, evacuate work zone and
then _c_a_l_l Health and Safety staff.
Action Le-els for Evacuation of Work Zone Fending Reassessment ?f Conditions : CONTACT HEALTH AMD SAFETY STAFFIF EVACUATION OCCURS.
« Level D: 0, 'L9.5* or ^2?i. explosive atmosphere -10* LEL. organic "apors above background levels,part icula tes > 11/A_ mg/m" , ?ther HA _________ .
0^ <1?.5* or 12breathing zone)
, explosi«-» atmosphereppm, particulates • M. A mg/m". other
LEL ^California-20M, unknown organic vapor (inn/A
Level B: O, <19.5\ ov >25%, explosive atmosphere -25* LEL (California-20^I, unknown organic vapors I inbreathing zone I > 500 ppm, particulates ? n/A mi/m~, other N/A
o Level A: O (19.5^ or >2S\, explosive atmosphere >25% LEL (California-20%), unknown organic vapors•>500 ppm. particulates > IJ/A mg/m", other IT/A
Air Monitoring (daily calibration unless otherwise noted):
Contaminant of Interest
Volatile Organics
Type of Sample( area , personal )
Area
MonitoringEquipment
HNU/OVA
Frequency ofSampling
On— going
Decontamination Solutions and Procedurss for Equipment. Sampling Gear. etc.:
All equipment will be washed^n an Alconox or TSP^ solution and triple-^rinsed vjith distilled water. Drilling
equipment will be steam cleaned.____________________________________________________________________
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—"f? ^ ^ ••*y;
B ; / A r y . ui i> c
ecology and environment, inc111 WHT JACKSON live,, CHICAGO. ILUNOtt«Om, TIL. HMO4*1«
USQS, OSCEOLA, IN. QUADRANGLE
Personnel Decon Protocol: Boot and gIove vash as necessary. T-f ?. s h in an Alconox or JTSP_ ao 1 u tion aind^1tip 1 e -
rinse \,ith distilled water
Decon solution Monitoring Procedures, if Applicable :
Special site Equipment, Facilities, or Procedures (Sanite ry Facilities and LightingMust Meet 29 CFR 1910.1201:
This facility is an active railyard - driving or '•.'aiding around facility requires additional caution. When
"o_r_king in the railyard. Con rail personnel la "pilot"! "ill accompany E t. E personnel____________________
Site Entry Procedures and special Considerations: Permission^'-'ill be obtained prior to site entry. Stay
upviind of contamination when possible. The buddv system '?ill be maintained at all times.____________
Work Limitations (time of day, veather conditions. etc.) »nd H»at/C?ld stress Requirements:
Wci-k jt restricted to daylight hours only and v.-ochers ?re t? be monitored f?r heat/cold stress. when
? i-^ used to pack samples, dust masks ^-'111 be ••?unj____________________________________
General spill Control, if applicable:
Investigation-Derived Material Disposal (i.e., expendables, decon vaste. cuttings I:
S»e WF PL-' F3T _j|_o_r IDW disposal procedures.____________________________________________________________
Sampl* Handling Procedures Including Protective Wear:
After samples ha^e been collected, the outside of the sample bottles v.-ill be decontaminated by waahijig_ (not
submerging! the bottles in an AleonoK solution and rinsing in distilled uater. The protective clothing level
t_i_'-g-.- • suits. gloves .boots I yorn during on-site job act i"i ties •••ill be maintained while decontaminating the
bottles. Respiratory protection^will be worn based onprofesaional judgment. Latex gloves. at •minimum,
'.-•ill be »orn, while handling the bottles after decontamination._________________________________________
Team Member* Responsibility
Bi'idoet Lombard! Team Leader
Rod Hackler Site Safety officer
other members TBD.
*A11 entries into exclusion zone require Buddy System use. All E £ E field staff participate in medicalmonitoring program and ha'-e completed applicable training per 2? CTP. 1910.120. Respiratory protection programmeets requirements of 2? CFP 1910.134, and ANSI 288.2 l l ? S O > .
309-1 : 1
E. EHEROEIICY IPFORHATIOC
I Use supplemental sheets, if necessary)
IXJCAL RESOURCES
[Obtain a local telephone book f rom y-'jr hotel, if possible)
I 219_) 295-8080_________________________________________________________
Hospital Emergency Room EAkhart General |219 > 2?i.-2<:21_______________________________
Poison Control center 1-800-382-90°7 (219) 294-3621________________________________
Police (include local, county sheriff, state! ^U. Elhhart County Sheriff (219 1533-4151
State Police 1-800-552-2959______________________________________________________
Fir* Department 911_____________________________________________________________
Airport H/A_______________________________________________________________________________
U.S. ETA Contact (RPMJ Chuck Wilk 1 3 1 2 1 353-1331
Local Loboratorv N/A
UPS/Fed. Express South Bend. IN 1-600-238-5355
IDEM Contact raul Courtney 13171 243-5056
it- Conta-rt Cgnrail : Thomas Pender-ja_st _ ( 215 ) JIT" -fi" - : Tci'Tnmal 3-^rer intendtnt (Hump Tower ) : ( 2191 396-2271
SITE TI
it* Emerqencv Evacuation Alarm Method Verbal
Wa t • r Supply 3 o u r c • Henry R. Feri-ettie/Baugo Creek c ? u n *: v F ? r )•
Telephone Location, Number Cenrajl_?f f ice I 21?>.__ fi7 ;J ~A * - - _'__vLtj trailer >
Cellular Phone, if available ri/A___________________________________
Radio N/A
other N/A
EHEROEF»CT COITACTS
1 . Dv . Raymond Htrbison ( U n i v . o f F l o r i d a ) . . . . . . . . . . . . . . . . . ' 591 i 221-0465 o r ( 9 0 4 ( 462 -3277 , 3281Alachua, Florida ' 5 0 1 ) 3 7 0 - 8 2 6 3 1 2 4 hour s )
2 . Ecology and Envi ronment , I n c . , Safe ty D i rec to rPsul Jonmai re . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . < 7 1 « ) 684-8060 ( o f f i c e )
' 7 1 6 ) 655-1260 < h o m « »
3. Laura D. Evans, Regional Safety Coordinator, Chicago .... (312) «63-?J15 (office)'708) 898-3853 (home)
J . Jerry Oskvarek, Office Manager, Chicago ................. ( 312) 775-7040 (home I
8094:1
HEDTOX HOTLINE
1. Tventy-f our hour answering service: (5011 370-8263
v.'hat to report:
State: "this is an emergency."
Your name, region, and site.
Telephone number to teach you.
Your location.
Ham* of person injured or exposed.
Mature of emergency.
Action taken.
2. A toxicologiEt, (Drs. Raymond Harbison or associate) "ill contact you. Pepeat the information givtn to th«answering service.
3. If a toxicologist does not return your call --ithin 15 minutes, call the following persons in order until•rontact is made :
=». 21 hour hotline - (716) «04-8940b. Corporate Safety Director - Paul Jonmaire - home « ?7l*i 655-1260•r. Assistant Corp. Safety officer - ste'-en Sherman - home * '7l«i «88-OOCJ•i. Chicago Health s Safety rtanagvr - Laura ET"ans - home « '70S) 998-3853
EHERGEI»CY HOVTES
(r»OTB: Field Team must Kno*» Routefsl TrioT to Start of Work I
Directions to hospital (include mapl Take Franklin St. !Route 33i east fright turn) to Arcade St. Turn left
IinofthI over bridge, toad curvea to the right. Hospital emergency entrance on the right. Total distance is
approximately 1 .5 miles. Elkhart General. 600 East Bl"-a. . Ell-.hart. Indiana IZ19) 29-1-2621_________________
Emeraency Egress Routes to Get off-site TBD on arrival.
8094:1
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111 WfIT JACK«OM »IVO . CMCAOO. N.UMO« «OM4. TIL. 1U-MM4W
HOSPITAL ROUTE MAP
""-3 "T 'r't:' :~ "''•»" - i -Hazard Eva ludt ion cf Chemicals
Region U - Chicago
- CHMOLtWC: Carboi TetrachlorideJOB NO: 3:3fo&& SYN : Carton teV^uatorinajfiercMoromethine, Tetrachloromethane, Efcnzinofori
GAS NO: K-23-5 RWULA: CQL4DOT CLASS: 1846
CHEMICAL PROPERTIES%s St: Liquid Boil Ft: ITB.WT loiz Pot : 11.47ev Ft Pt: -fcl Ht : 153.33 felt Pt: -9.4W Map PTKS: 91.M *»c IR : -*Gr : 1.59 Frz Pt : -9.40°F Mr Thr : 340.Mppm IR :-Mor : ueeti&h, resettles chlorofora, dry[NCOHPAT/REACT: allali m*tals, fine powdered m?tals, ditttiyl forvuide at tap h. ier ttw* 65 C.XXlfilLITY : aiKible H/akohc'l, ett.tr, chloroform, benzene, solvent
TOXICOLOGICAL PROPERTIESexposure Limits: TLV-TXA (ACBIH): 5.W ppm rU <OSHA)s 2.0f #•
STB.: — HOt 3M.» pp«ACC hAX PEAK: 200ppm/5min/4hr/8 hr shift.Hu» LCIofox Data: IfflAL
atper
raiORAL ratCARC04HUTAGENREPRO TQX exper teratogenAQUATICOT>€K TDX TAf.-CLT OFCWS: QJ3, Eye, Lung, Li*r, Kid»ey, *ROUTES CF Dff*: Irigestion, Eye(0cular), Cferii! ftsorption. 3kin Contact, Inhalation
PERSONAL PROTECTIVE MEASURES""ATORS : ATR: dusty/Hindy condit or knowi high concent <r >1 but <3ppt: SCtA: >5ppn,iDGE TYPE : GJC-H c^ fiP3 (RATAL)
CLDTHIM5: Cwerall: Ft Tyvek Gloves: Vitorr 13hr, FW-Shr (PWft degrades ia water)5PGC PRECAUTIOM5 : Higf c^centrations in air are dangerous to in. eyes, afcd MCOUS
FIRST AIDIMMLATION: Hove to fresli air, artf. resp. if nee., SIX COIDL ATIDfllQNiyE/SKIN : rewve contaminated clot»«s, flush H/water for 15 •!•, SEX »EDIOLD -7IGN : StH JCDIWL ATTENTION.
SYMPTOMS=CUTE : irritatiot of eyes/nose/throat, overexcitoent, headaxte, i»toKicati«,«coascio«s, narcosis, shock, liverAidney/he-
art damage, SKIN: delayed dry skin, freezing, iifliaMtioi, btist«n u/iicnd. pah^MNIC: fatigue, aaecia, Heakaess, nausea, blurred visit*, •caofy kss, paresthesias, trewrs, toss of peripheral color visi-
on, dermatitis, liver damage
DISPOSAL, FIRE, SPILLS (see attached sheet)DISPOSAL: A FIREl 11,13 LENS ft SPILLSi 1.3,4,6,9CECOWOSITION PWHJCTS: phosgene gas, carbmi monoxide, carton oiocice
REFERENCES CONSULTEDNIOSHAMUft Pocket Giide, Chris (vol. Ill), ACGD1 TLV &»kl*t, RTECSJTVER REJTFOCES: OSHA. Kandbock of Poisoning, Sigma-Aldrich, Ccad. lr*« Diet. Ut Aid for Che«
Hamilton 4 Hardy, Casarett 4 Ooull [_^g| f VBION DATElHalogenated
Ecology and Environment, Inc.Hazard Eva I uati on of Che«i ca I s
Region V - Chicago
IE j '*>// ?£- MWCAL Wrb Chloroform"2F-8 Mb "-3&&& SVN : Trichloroaethaae
OS Nth 67- *3 FQRMJLAi OCL3DOT CLASS: 1858
CHEMICAL PROPERTIESysStxLiqtid Boil Pt: IC-flM lonz Pot : 11.4&v Fl PtiI Ht I 119.38 felt Pt: -82.0TT Uap Press: Itf.* aafkj LFL :6r J 1-49 Frz Pt : -82.3r* Qdr Tlr : 2&.mu>* IF. :
or s pfeasaat, sieet, suffocatingQMftT/RBCri jir/lipjrt sensitive, bases, alniiwUBU1Y : iasolable
TOXICOLOGICAL PROPERTIESposart Liaitss VMM (MBDOi ll.« »>• PR Q9tt>s 2.01 pp«
STB.: — ffiUt 100f J« pee
Oatat OHV. 2 KM TClo:DBWL : -OWL : rat LCCff: 908 kg/kgCffidl i hill* suspectfaniul posMUTAflBI : aegativeRBPftO TOX: aepef teratoomAtJUATin iOVO IKi WWTT ORGANS: Liver, Kidwy, teart, Cyc, SkilMUTBCFEXPt Ugestion, EyeQctlar), Uhalatioa <
PERSONAL PROTECTIVE MEASURES3PDWQRS : APR: dusty/Mi id/ condit or kaoa high concent or >1 but <5pp>; SCBAs
TYPE i GMHi or A?3 (RACWJO0M16: Coverall: PE Tyvek Gloves; f>W (degrades ia niter), Vita
: Aesthetic; fatal dose 30lag/kg or 4M poi •
• FIRST AIDame to fresfc air, artf. rcsp. if MC, SBEK KD1CPL ATKNTICM
V9ON s naow cortaaiMtcd cjothes, flash N^Mater B aria, SEBt moCAL AMUHIMZSIBM s if coaacioB, indace voiitiig, SEIK IGBCAU ATTEKTIOM.
SYMPTOMS -HE x exciteata*, ocoeciots, paralysis of rtspirattoa, cardiac irregalarrty/amst, lot blood jreswr*, aatsea, vovitng
VNCs liverAidaey daaage, Jiokdice aad cirrtosis of liver, heart daaage, aMftkesia
DISPOSAL, FIRE, SPILLS <see attached sheet)FIRE: 11,7 1£M5 I SPIltSj 1,4,6,9
BffOSITIDM PBDDUCTSj bydrogt* chloride Oji*y pJio*9»* gas
REFERENCES CONSULTEDat/D3<ft Pocket Gvide, fCGfil TLV Booklet, RTECSER wrutJuSx (Oft, Hadbook of Poisoniag, Sio^a-aidrich, 1st Aid for D« Accii, Eaer Rfep Gd
LAST JEVKIDH OMEs30TJL CUaSFranot HJ logeaated H/drocarboB, Ha logeMted CO^N^OS, Al iphat ic & Al icytl ic U/19/89
!_*_ Lf 1 W -j y (J..U l_. • « • • - . i..' - •• *. , -. -
Hazard Ev a l u a t i o n of ChemicalsRegion V - Chicago
i /°/ // 9*. OeoCALHMCi Dichloro&tevlene, 1,1-JBHOs 3P%£30f) SYN t Vinyl itae chloride, 1,1-dichloroethene
GAS Mk *35-« FWULAi GC=€CI2DOT CLASS: 13nB/FU* LIO 3
CHEMICAL PROPERTIESPhys 3t: Liquid Boil Pt: SV.tt'T Io*z Pot : l»-2 ?v Ft Pta Q°F
fel Ht : 96.95 He It Ft: 1S3.5 ef Uip Pre%i 3^ MHg UT_ : 7.2 1^Gr i 1.21 Frz Pt i -18S.» °T (Mr Thr : — IR : tt.i XQkr i s»eet, like chlorofora or carbon tetrachlorifeDOWT/RBCT: nitric acid, caprolacta* soln, copper t aluiftM, sviiight, air, heat9DUBILITY : inso!4CO, so I -in organic solvents
TOXICQLOGICAL PROPERTIESExposure Lmits: TLV-TMA (ACGIH): 5.0 pp» PB. (09A): 1.6 ppa
STB.: 20.1 ppi MJt —ODER PROPERTIESTox Data: IttttL
08WLQRN.CADC1N
- WTASN
rat 40feg/kg - nutation
eicperecper
RffROTQXAQUATICOTtOTOXRdJIES QFBP: Ingest ion, Eye (Ocular), EJtia Contact, Inhalation
PERSONAL PROTECTIVE MEASURESF GATORS : AFft: dusty/Nindy condit or knoxn high concent cr >1 bit CfipM; SOBA:C .rflOE 1YFE : G*C-H or CK (RACAUHHUIEUIBC OOTHIM3: Coverall: Tyvek Gloves: FMft, Witon <PVA degrades in water)
PRHjAUTHMS :
FIRST AIDDHtATIXM: wve to fresh air, CFR if nee, SEEK «flCftL ATTDfflDN
: move contaminated clothes, flush H/lg art of wrter at least 15 wi, SEEK KD1CA. ATIENTHM: give wtnr or »ilk, DO M3T UOEE V041TTO, SEEK 10101 ATTOfnEM
SYrVTOMSAOXt i dizziness, dnoikeness, irritation to skin/eyts/wcow aentranes, narcotic in high concatrations, first degree tents-
*
QfDOCs lab «ti»als developed liver and/or kidney cancer
DISPOSAL, FIRE, SPILLS <s«« attached sh*«t>DISPOSALS A FIRE: 1,2,4, LEAKS ft 9>IU£: -DEEDfOSniON PRDOUCTS: HCI, Phosgene
REFEREMCES CONSULTEDMIQGH/03IA Pocket Glide, Chris (vol. Ill), ACGIH TLV Booklet, R1ECSODER RffOBOSi OSHft
LAST REVTSHM DATE:f 'CALOJflBinCAnDN: Minyl Halicte
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IE = t%f' ?*• OCmCAL NAME: fettylene Chloride8 NO: 'ZPZG&f) SYN : Dichlorcfctfiane, tettyleie dichloride
GAS NO: 75-09-2 FORMULAS OGC12DOT CLASS: 1593
CHEHICAL PROPERTIES(y? St: Liqim Boil Ft: 104.034 lonz ft* : 11.35ev Fl Pt: -.1 Ht : M.91' Melt Ft: -142.WF Uap rress: 35§.» « lg LFL : 12.WZ, Gr : 1.33 Fr2 rt : -142.00T Odr TV : Itf.Wppi IR : 19.00Zlor : like c:,:.jrofon, SHeet, pleasanttrUfAT/RCACT: heat, moisture, strong oxidizers, strong cavstic-, chemically active letals, alkali aetals,11BL.ITY : slightly-wter; alcohol, ether
TQXICOLOGICAL PROPERTIES;posure Lilits: TLV-TOA (ACGIW: 50.M ,ppi SKIN PEL OBW: 5W.« ppi SIC|N
sra: - nm: 5ew.» " ppiMAX ftAK: 2000ppfl /dT.y 2HF1WERTIES
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rat:human/an i«t suspectex per
TARGLT Of£ANS: 0; in, Lye, CVS, CKSROHES OF EX": Irigestioii, Eye (Ocular), Ltrw^l tti5-:rp* :*i, Skin
PERSONAL PROTECTIVE MEASURESTORS : a*y detectable oancentration - SCEA
TYPE : *o cartridge availableOimflW: Cwerall: Ft Tyvek Gloves: FW, Vitc* :FVA degrades ir, water)
PPECAUIMNS :
FIRST AID: K>W to fresh air, artf resp if nee, SEEK MEDICAL ATTENTION
/E/90N : fltsh H/»ter 15 minutes, wash skin HI th soap/Hater. 3EEX MHDICM. ATTENTIONs SH »€DIOt ATTEMnON
SY Iff* TOMS: M*tal confeioa, light headedness, naos/voot, headache, staggeriig, oconsciovs, irritation of eyes/resp/sfcin, poss-
ible din bms, heart palpitations, fatigue, giddiness, exhaustion, wlaise^teathATONIC: skin irritation.
DISPOSAL, FIRE, SPILLS (s«« attached sheet)ISrDSAU 6 FIRE: 11,13 LEWS t SKILLS: 1,4,6,9eCOHTOSITION PBOCUCTS: tCt, CO, phosgene
REFERENCES CONSULTEDI03H/03W Pock^c Guide, Chris(wl. Ill), ACG1H O-'J B«*let
RfHUDCES: NIGGH Guides, Sigu-Aldrich, f'oi^i, Kandbock. Ut Aid for Cfvi Ace id, CassarettLAST REVISION DATE;
" . OASSIFICftTHlh Halogenated c^ Chlorinated
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Region U - Chicago
OeOGft. NMCt TetrachloroethyleneHO* £P3fr<9g> SYN : Percliloroettiylene, Perk, Tetracap, Pertlene
GAS Mfe 127-18-4 FWJULAl CIX=CC12OOTOASSt 1897
CHEMICAL PROPERTIEStiys St: Liquid toil Pt: 2t0.»OT lonz tot : V.32ev Fl Pt: -ol Mt : lffi.35 felt Ft: -S-WT Map Press: M.W •rftg LR. : -pGr s 1^3 Frz Pt : - 8.30°T Mr Hr : 47.MM* UT. :-dor : Mildly SMset, etherishMUffAT/VCACT: heat, strong oxidizers, bariua, litfaiu, beryfliM, strong batesOIBB-ITY :
TOXICOLOGICAL PROPERTIESxposwv Lit its: 1LV-TW (A05IH): tt.tt pp« PEL OHWi 25.«
SIB.: 2M.M> ppa BiH: t«e.«ITtER PfOPERTIES MXOT KAX Ft«K: 3fi*f« for 5 «i« in 3 icurs of any 8 tor shift'ox Data:
OERWLCRN.CffiCINMTTAENREPRO TOXWATIC(met TOX
rat UKtf: 8K* •o/kgVES
OfJVWS: Liver, Kidicys, Eyes, Upper tesp 9y»,ROJTES OF E3P: Itigestion, Eye (Ocular), Oenul ftisorptioa, Skik Contact, Inhalation
PERSONAL PROTECTIVE MEASURESASPIRATORS : tffi: dusty/windy cowl it or knoM high ccacnt or >1 but <5ppa; SC&fe Xippa
TYFE : GKMI or «P3 tf*CWJJOIHUe: Coverall: Ft Tywk 6love&: Vitcn
PGC
FIRST AIDwe to fresh air, artf rasp if MC, SQEK KDlttL ATTBfnON
x f Itsh «/wter l ii, Mask skik uiih so^Aoter, SEBt JGttCrt. ATTEWlfJHMEESniM I give Ig art of salt.wter, i«tee voMttlag if cowcio*, SEEK WDICM. ATTBmOH
SYMPTOMSCUE s toidKte, drawiM», dizziaeu, iftCoonfiMtioi, mcaMciom, irritation of eycs/MM/throat, f lushiikg of face/tedcf
javdioe, dark via*, urcot is ki i coiceat, anjiacMDQCt stii irritation, dawgt to liverAidneys, Q6, dermatitis
DISPOSAL, FIRE, SPILLS <se« attached sh««t)JIffOSflL: A " FIRE: 11,13, LENS t SPIlLSi 1,4,6,9JtUMfQBIlllM PTODJCTB: ptosgew, ttl, CO, C02
REFERENCES CONSULTEDU03HAJ3W Pccket Guide, Chris (vol. HI), HCGC1 T1.V Booklet, fttiXSn>CR RffDQCES: N1C&I gvides, 03ft, Si^a-Aldrich
LAST REVISION DATE:CLflfiSIFiandb tblo . C^os Aliphatic ft At i cyclic
Hazard Evaluation of ChemicalsRegion V - Chicago
DATE ; P/tffe CHEMICAL NANE: Trichloro*thane, ;,i,iJB NO: -P itetg-ft? SVH : tethylcMorofon
CAS W: 71-Sr* RWUA: CH3CCI3DOT CLASS: 2S31
CHEMICAL PROPERTIESPhys St: Liquid Boil Pt: U&.«<T lonz Pot : l«.2fcv Fl Ft: -tol Mt : 133.41 felt Pt: -31 .(W Vbp Press: IM.ffi nHg IH. : 7.00X$ 6r : 1.31 Frz Pt : -33. WM (Mr Thr : 390. .u UFL : 16.(MX(Mor : s«*tish, chlccolonr-ltkt-, etheri&hDCOfAT/RCACT: strong oxidjzers, Al, ugti^iw, zrac, strong ba&es; K, Kd, dcetor.e, ruti-ates, 0, yield strong rxusSDLUBD-TTY : insoluble w^Ur; &:>! in acetone, t>eDZt«. cartKfi tet, •etfaiiol, etter
TOXICOLOGICAL PROPERTIESExposure Lit its: 1UKMA (ACGIH): 3fJ0.00 ,/pn PEL <09tt>: 350.M ppH
STEL: 4T0.M vpii ILLH:OT>ER PfUPERTIESTox Data:
Affect 0€t IWHANTt-unan Tclo:
rat: 1160: 10,300suspect
Derovt-ORALCASCINMUTAENREPRQTOXAQUATICOMKTQXROUTES OF Eff: Ingest ion, Eyattfcular). D&r»«i Absorptioc,, Skin Ox.tact, Inhalation
teratogea75-150ppb'l ptnf tsh/TLi/Salt Mater-no ti«e periodTAM£T OfCANS; CKS, Ey^s, N.JS*, Livtr,
PERSONAL PROTECTIVE MEASURESRE' \TORS : AFf;: dusty/Htnoy condit or Icxun high concent or >1 but <5pp«; SCEA: ^C-pCAK...JKE TVFt : GtC-H or Af'3 (RACAL)FWJTECTWE CUJTHINB: Covt-rd 1 1 : ft Tyvei Glc-vesj Viton
FDQMJTIONS :
FIRST AIDDHLATDK: iwe to fresh air, artf resp if »tc, SHX KDICAL ATTDfHONEVE/SKIN : rewwe contad cloth, flush HAuUr 15«fi, Hash skit Mittt soap/Hater, SOX tCDICAL ATTEHHONI not : give Hater, indite voiiting if consciov, SEEK ffDOCAL ATTQmON TMfLIATELY
SYMPTOMSAOJft : irritation to eyes/sk in/tut BMbraftes, tionrdiiatioB, utsea, coafwsioB, drowsiness, poss toss of consciousness, di
zzy, possible lung/brain damage for* high coK«atrati«KOWNIC: dermatitis, liver/kidMy
DISPOSAL, FIRE, SPILLS <s«« attached sheet)DCTOSAU A RRE: 3,7 UAKS 4 SPIliS: 6,?, 11tnafOSTTION FHOOUCTS: CO, C02, HCI, F'hosg&ne
REFERENCES CONSULTEDKIOSH/ttHA Pccket Guide, ferclc Index, Chris(vjl. CU), AC8IH TLW Bcdtlet, R1ECSOT>CR RETOOCES: Signa-Aldrich, Poison Hatidbc.j*
LAST FEVISION DATE:Qf*"CftL OASSinCATION: Halogonated Hydrocarbon K/10/89
Hazard E v a l u a t i o n of Chea ica lsRegi on V - Chi cago
CKMCAL NMC: TrichloroetbyltneJOB Mfe «Ctog? Sffl : Tric'ioran, Trictoe, Trileit
OS MO: 7V-S1-6 RHHJU: QCKC12DOT CLASS: 1713
CHEMICAL PROPERTIEStiys St: - tqu iC Boil Pt: IW.W lonz Pot : 9.4?ev FI Pt: W.WTtol Ift : 131.3V Nelt Pt: -12fc.64« Uap Press: Vi.£0 •*;< LR : 11.00Z^ 6r : 1.46 Frz Pt : -IKi-STf Qdr Thr : £L.00pF« tfl : 41.00ZJdor : :hlorcfonHike, eUierealXOQWAT/fCACT; strong caustics, chaucally active MtaUJQLUBILITY : insoluble
TQXICOLOGICAL PROPERTIESLit its: TUHW (ACGIH): 50.00 ppn PB. O&IA): 5f.« ,101
STB.: 200.00 ,>puJOCK PROPERTIESTox DaU:
CC1UNG: 200pi^tAX FtAK: 30^pW%^ IT, 31 st.iftTclo: l£0ppn/S3u i n
rati LI60: 7173 ng/kg, human-sus
DERWL'ORALcootHJTflgMREPRD TOXAOJftTICOTWRTOXROUTES OF EXP: Ingeftion, Lyt-dJcular), Skin U>ritirt.
acper teratogen660ng/ 1 /tf^r/daphn i a A i 1 1 /f resh water
Dfi S: tesp &ys, teart, Livtr, CfC, Sun
PERSONAL PROTECTIVE MEASURES£SP1MRK> : AfR: dusty/Hindy comfit or kncwri high ;. icent cr : ; :ut ^Sppi: itt'A:^RflUDg TYFt : OC41 or flP3 (RftCAL)JROIHTM: ODTWWJ: Coverall: Ft Tyv«k G!.-M^S; Uiton, r'.-A (FVA grades in ^
FIRST AIDDMUHM: «ove to fresh air, Cfft if nee, SEEX tfDXCM. ATTDfTIONEVE/gOII : f l*sh K/wter l&tn, Hash skin Hith soap/Hater, SEDC KHLDL AflDOIWDCESTKK : give large ait of water, induce waiting, SEEK KD1CAL fiTEHTlON
SYMPTOMS: irritation of lose/throat/cyM, nausea, blorrtd vision, denatitis, 'jy iltMj similar to alcohol inebriation. Narcot-
ic effects in high concent, CNS depressionOMBULs liver and/or kidney dawge, cardiac degeneration, central nervixs syst*« deoenention, dermatitis, anorexia
DISPOSAL, FIRE, SPILLS <see attached sh««t)OI9PC8U A HRE: 11,13 LEAKS & SPILLS: 1,4,6,7
rjN PRODUCTS: CO, CG2, HCI, Phosgene
REFERENCES CONSULTEDPocket Guide, Merck Index, Christvol. [ID, MXIH TLV BodHet, R1ECS
T?OCEB: Sigva-Aldrich, Poison Handbook, 1st Aid f--r Chea ^ccicLAST REVISIQN DATEl
OASSfflCftTION: Halogenated hlydrocarbon, Al iptetic 1 At icyc, ic 05/10/8?
THE SIGMA-ALDRlCH LIBRARi OF CHEMICAL SAFETY DATA
Explanation of Codes
PROCEDURES FOR SPILLS O« LEAKS FIRE-EXTINGUISHING MEDIA
1 Absorb on sand or v^rmlcullte and place In closed container lordisposal. .
3 Cover w»h dry lime. jend. or soda ash. Piece In cover™container* using non»P»rklng tools end transport ouU<°°'«-
3 Shut off all sources <>' Ignition.4 Evacuate area.5 Cover with an activated carbon adsorbent, take up ana place in
6789
1 0
1 1
1 21 31 41 51 61 71 8
•!«••* ••ntalner. Tr* .Ventilate area and wash spill site after material plckuP l» complete.Sweep up. place In a ba0 and hold for weste disposal-Avoid raising dust.Wear self-contained breathing apparatus, rubber boot' an<1 heavyrubber gloves.Wear respirator, che^'cal safety goggles, rubber boot*rubber gloves.Cover with dry lime V »oda ash, pick up, keep In a closedcontainer and hold tPr waste disposal.Carefully sweep up *"<* remove.Flush spill area with copious amounts of water.Mix with solid sodlum bicarbonate.Place In appropriate container.Wear protective equipment.Wash spill site with soap solution.Please contact the Technical Services Department. Be »ure totlon the neme and c«««IOfl number of the material.
heavy
1 Carbon dioxide.2 Dry chemical powder.3 Water spray. ;4 Alcohol or polymer foam.5 Class D fire-extinguishing material only.6 Weter may be effective for cooling, but may not effect
extinguishment.7 C*rb«n dloMlde, dry ahemleel powder, eloohol or polymer foam.8 Foam and water spray are effective but may cauae frothing.9 Do not uae dry chemical powder extinguisher on this materiel.
10 Do not use carbon dioxide extinguisher on this material.11 Noncombustlble.12 Do not use water.13 Uae extinguishing media appropriate to aurroundlng fire condition
214.060-0Slama-Aldrtch Corporation, P.O. Box 355, Milwaukee, Wisconsin 63201 USA
<<Jlgma: 314.771.6765; Aldrtch: 414.273.3660)
OpyrtghlO 1SSI by Slomc-Aldrich Cerpenllon
WASTE-DISPOSAL METHODSThe disposal methods outlined below are Intended on-
ly as guides. We do not assume responsibility lor theiruse. Careful consideration muat ba given to the chemicaland physical properties of the substance. In addition,local laws and regulations may preclude the use of thesemethods which are primarily dealgned for small quan-tities. Observe all federal, state, and local laws.
The disposal of some chemicals may require deactlva-tlon or modification of the malarial by chemical means.Chemical waste-disposal raacllona muat ba handled withthe same care and eonalderatlon uaad with aynthetlcprocedures. Appropriate eonalderatlon muat be given toreaction condltlona. /.a., atolehlomatfy, order and rata ofaddition, heat of reaction, evolution of gaseous products,pH. efficiency of stirring, rale of reaction, atmosphericsensitivity, etc.
Chemical wsste-dlapoeal resctlona should ba carriedout In a chemical fume hood and In appropriatelaboratory glaaaware. Because theee reactions are oftenvigorous, protective safety equipment such aa safetygoggles, respirator, gloves, face andfor aafety shield andother protective equipment moat ba uaad.
Initial reactions In a disposal sequence should be car-ried out on a small scale OlOg). the reeotanl concentra-tion* should not exceed 10% of the reaction volume andthe final reaction volume should not exceed BOH of theworking capacity of the reaction vessel, regardless of thereaction scale. Larger quantities of the material shouldbe handled In several small-aUe reactions. To ensurecompletion of reaction, the waata dlapoaal procedureshould be run for at least an additional 4 to a hours afterall materials have been mixed.
All reactions should be run by technically qualifiedpersona familiar with the potential hazards of thechemical reactions.
A Dissolve 01 mix the material with • oombuallble sol-vent and burn In a chemical Inclnarator equippedwith an afterburner and scrubber.
B The material should be Ignited In the presence ofsodium csiuonale and slaked lime (calcium hydrox-ide). The substance should be mixed with var-mlcullle and then with the dry caustics, wrapped Inpaper and burned In a chemical Incinerator equippedwith an elierburner and scrubber.
C This combustible material may be burned in achemical Inclnarator equipped with an afterburnerand scrubber.
0 Burn In a chemical Incinerator equipped with anafterburner and scrubber but exert extra car* In Ig-nltlng as this material Is highly flammable.
E To a solution of the product In water, add an excessof dilute suifuric acid. Let aland overnight. Removeany Insolubiea and bury In a landfill alia approvedfor hazardous-waste disposal.
r Cautiously dissolve the malarial In water. Neutralizeimmediately with sodium carbonate or, If thematerial does not dissolve completely, add a littlehydrochloric acid followed by sodium carbonate.Add calcium chloride In excaaa of the amount need-ed to precipitate the fluoride and/or carbonate.
Separate the Insolubles and bury In a landfill siteapproved for hazardous-waste disposal.
0 Under an Inert atmosphere, cautiously add thematerial to dry butanol In an appropriate solvent.The chemical reaction may be vigorous and/or ex-othermic. Provisions must ba mada tor venting oflarge volumes of highly flammable hydrogen and/orhydrocarbon gases. Neutralize the aolutlon withaqueoua acid. Filter off any solid residues fordlapoaal as hazardous waate. Burn the liquid portionIn a chemical Inclnarator equipped with an after-burner and scrubber.
H Neutralize the aolutlon and add filtering agent (I0gper 100ml). Evaporate the liquid and bag the residualsolid for burial In a landfill alia approved forhazardous-waste disposal.
I Dissolve the solid In (or dilute the solution with) alarge volume of water. Carefully add a dilute solutionof acetic acid or acetone to the mixture In a welt ven-tilated area. Provlalona should ba made to vent safelythe hydrogen gaa given off during the decomposition.Check acidity of the aolutlon and adjust to pH 1 Ifnecessary. Let stand overnight. Neutralize the aolu-tlon (pH 7). Evaporate the solution and bury theresidue In a landfill alia approved for hazardous-waate disposal.
J Cautiously acidity a 3% solution or a suspension ofthe material to pH 2 with aulfurlo acid. Gradually adda 60% exceee of aqueoua sodium blsulflte with stir-ring at room temperature. An Increase In temperatureIndicates that a reaction la taking place. If no reac-tion la observed on the addition of 10% of thesodium blsulflte solution, Initiate It by eauttoualy ad-ding more acid. If manganese, chromium, ormolybdenum Is present, adjust the pH of the solutionto 7 and treat with sulflde to precipitate for burial ashazardous waste. Destroy excess sulflde, neutralizeand flush solution down the drain.
K Please contact the Technical Services Department.Be aura to mention name, catalog number and quanti-ty of the material.
L The material should be dissolved In 1) water. 2) acidsolution or 3) oxidized to a water-soluble state.Precipitate the material aa the sulflde. adjusting thepH of the solution to 7 to complete precipitation.Filter the Insolubles and dispose of them In ahazardoua-waate site. Destroy any excess sulflde withsodium hypochlorite. Neutralize the solution beforeflushing down the drain.
at A slurry of the arenedlazonlum salt with water can bedisposed of by adding It gradually to a atlrrad aolu-tlon of S-10% excess 2-naphthol In 3% aqueouasodium hydroxide at 0-20*C. After 12 hours, theresulting azo dye la filtered and either Incinerated orburied In a landfill site approved for hazardous-wastedisposal. Neutralize the remaining solution beforedisposal.
N For smell quantities: cautiously add to a large atlrradexcess of water. Adust the pH to neutral, separateany Insoluble solids or Moulds and package them forhazardoua-waate dlapoaal. Flush the aqueoua aolu-
tlon down the drain with plenty of water. The 'hydrolysis and neutralization reactions may generateheat and fumes which can be controlled by the rateof addition.
O Bury In a landfill site approved for the disposal ofchemical and hazardous waste.
P Material In the elemental stale should be recoveredfor reuse or recycling.
0 Cautiously make a 6% aolutlon of the malarial Inwater or dilute acid. There may be a vigorous,exothermic reaction and fumes may be generated dueto the hydrolysis of the material. Control any reactionby cooling and by the rate of addition of the material.Gradually add dilute ammonium hydroxide to pH 10.Filter off any precipitate for disposal In a chemicallandfill. If there la no precipitation, gradually adjustthe pH from 10 to 6, stopping when precipitationoccurs.
R Catalysts and expensive metals should be recoveredfor reuse or recycling.
• Treat a dilute basic solution (pH 10-11) of the materialwith a 50% excess of commercial laundry bleach.Control the temperature by the addition rate ofbleach and adjuat pH If necessary. Let stand over-night. Cautiously adjuat solution io pH 7. vigorousevolution of gaa may occur. Filter any solids torburial In a chemical landfill. Precipitate any heavymetala by addition of sultlde and Isolate for burls).Additional equivalents of hypochlorlte may be neededIf the metal can ba oxidized to a higher valence state.For metal earbonyla, the reaction should be carriedout under nitrogen.
T Cautiously make a 6% aolutlon of the product Inwater; vent because ol possible vigorous evolution olflammable hydrogen gas. Acidify the solution to pH 1by adding 1M suifuric acid dropwlse. Acidificationwill cause vigorous evolution ol hydrogen gaa. Allowthe aolutlon to aland overnight. Evaporate the solu-tion to dryness and bury the residue In a landfill sit*approved for hazardoua-waate dispose).
U Take the material (or a solution) and make a 5% solu-tion In tetrahydrofuran. Cautiously add the aolutlondropwlse to an Ice-cooled, stirred basic solution ofcommercial bleach. Oxidation may release flammablehydrocarbon gases which must be vmtlotl. Let slamJovernight. Adjuat the pH to 7 and destroy excesshypochlorite with sodium blsulflte before disposal ofthe solution.
V Under an mart atmosphere cautiously add dry butanolor a mixture of dry butanol In an appropriate solvent.to a aolutlon of the material In tetrahydrofuran. Thechemical reaction may be vigorous and/or exother-mic. Provlalona muat be made for the venting of alarge volume of flammable hydrogen gas. When pasevolution ceases, cautiously add a basic hypochlorltesolution dropwlse to the reaction solution. Let standovernight. Neutralize the solution and (real with <sodium blsulflte to destroy any excess hypochlorlte. rs.Filter any solids for burial In a landfill site approved v Vfor hazardoua-waate disposal. -£
These recommendations in »nded only as guide*from their uae. See Foreword of the Sigma-AU
•igma-Aldrich shall t * hold liable for any damage resultingLibrary of Chemleai safety Data for more Information. r
3ITE DOS1HETEP. LCG
PROJECT « Z F 3 0 0 0 TITS :iAjifi ' t o n r a i l
SITE SAFETY OFFICEP. Pod Hack 1 91- !To"9mb9f 1992 through Hatch 1993
[1AHE AtlDrosin. « OirDAV T'.'ESDAV P.I DAT SATURDAY SUNDAY
To th« neairast half-hour, rscotd tim» sp«nt dcvnrana* ?s "3" 'e.g., 3: Z . 5hrs I , tim* sptnt inactive PDS operation as "F", and any tirn* scsnt dc'-nrsng» in vsscu* activity as "R".
8094 :1
Wai;*hou3« Phon* (708) 647-1713
PROTECTIVE GEAR
Level A
SCPA
STAPE AIP, TANKS
ENCAPSULATING SUIT I Type '
SURGICAL GLOVES (Lat-xl
NEOFRENE SAFETY ROOTS
BOOTIES (Latex 1
GLOVES : Tvpe
SM M L
OUTEP WORK GLOVES
CASCADE SYSTEM
5-MINUTE ESCAPE MASK
fOrtt.iNG VEST
HAPD FIAT
L*''9l C
ULTRA-TWIN RESPIRATOR
FOWEP AtP. PltpIFYIHG RESFIRATOP
CARTRIDGES (Type GMC-H 1
mOTECTIVE COVERALL: Type 3aran«x
SM (I L X
BUTYL APRON
SURGICAL GLOVES (LATEX)
GLOVES: Type Vtton or Nitrilt
SM M L X
OUTER WORK GLOVES
GLOVE LINERS
FACE SHIELD
HARDHAT
RAIN SUIT
NEOPRENE SAFETY BOOTS
BOOTIES (LATEX)
STEEL TOED BOOTS
r . EQUIPMBW
no.
V
X
X
X
Job ZF3000T CHECKLIST
T»am Leader Lomb«rdl
L9v*l B
:;CSA
:;FAP.E AIR TAIIKS
PROTECTIVE COVERALL: Typ«
sn '' L
BUTYL APRON
Sl'P.GICAL GLOVES (LATEX)
GLOVES : Tvp«
?!! M L
rrEOPP.EtJE SAFETY BOOTS
E"20TIE3 (LATEX)
HAP.D HAT
FACE SHIELD
tLAIIIFOLC SYSTEM WITH AIRLIHE
CASCADE 3 YSTEf !
F.AIIT SUIT
r'.'TEP. ',-,'OPK GLOVES
L«''*l D
ULTRA-TWIN RESPIRATOR (Available)
CARTRIDGES 'Typ« GMC-H )
5-HIHUTE ESCAPE MASK (Available)
PROTECTIVE COVERALL: Typ* Saranex
SM M L X
OUTER WORK GLOVES (VITOH OR HITRILE)
HARD HAT
FACE SHIELD
P.AIH SUIT
WHITER BOOTS
BOOTIES (LATEX*
[TEOPREHE SAFETY BOOTS
STEEL TOED BOOTS
SAFETY CLASSES
NO.
1
-
X
X
Xs.
X
X
X
X
X
X
801J : 1
I NSTRimEWT ATIOB
OVA
THERMAL DESORBER
02/EXFLOSIMETER W/CAL. KIT
FHOTOVAC TIP
HMu ' Probe 10.2)
MAGNETOMETER
FIFE LOCATOR
WEATHER STATION
DRAEGER PUMP, TUBES
RRUNTON COMPASS
MONITOX CYANIDE
HEAT STRESS MONITOR
nOISE EQUIPMENT
PERSONAL SAMPLING PUMPS (Type 1
DUST MONITOR (MDA OP GCA System)
RADIATION EOUIPHEUT
TLD BADGES
DOCUMENTATION FORMS
PORTABLE RATEMETEP
SCALER/RATEMETER
Nal Probe
SnS Probe
GM Pancake Prob*
<3M Side Window Probe
RAD-MINI
ION CHAMBER
ALERT DOSIMETER
FOCKET DOSIMETER
FIRST AID EQUIPMENT
FIRST AID KIT
OXYGEN ADMINISTRATOR
STRETCHER
PORTABLE EYE WASH
BLOOD PRESSURE MONITOR
FIRE EXTINGUISHER
tlo .
•jT
X
X
A
X
DECOF EQUIPMENT
WASH TUBS
BUCKETS
SCP.Ue BRUSHES
PRESSURISED 3FRAVER
DETERGE1IT 'Typ- TSP/Alconor. >
SOLVENT (Type )
FLA3TIC SHEETING
TARP3 AIID POLES
TRASH BAGS
TP.A3H CArlS
[-IASKIHG TAPE
DUCT TAPE
PAPER TOWELS
FACE MASK 3AI1ITISER
FOLDIIIG CHAIRS
3TEF LADDERS
DISTILLED 'A'ATEP
SAHPLIPG EQUIPHEIT
3? OZ. AJ'IBER GLASS BOTTLES
1 L. AMBER GLASS BOTTLES
JO ML. VIALS
1 L. PLASTIC
8 OS. GLASS
120 ML. GLASS
SPOONS
KtHVES
FILTER PAPER
PERSONAL SAMPLING PUMP SUPPLIES
BUCK CALIBRATOR
HAND BAILERS
THIEVING RODS WITH BULBS
DIOXIH SAMPLE KIT
PRESERVATIVES : HN03 ___ NaOH Other ___
STRING
Ho.
X
X
X
X
X
X
X
X
X
X
TBD
TBD
TBD
TBD
TBD
TBD
X
X
X
X
TBD
a o « ) 4 : l
VAN EQUIPMENT
TOOL KIT
HYDRAULIC JACK
LUG WRENCH
TOW CHAIN
VAN CHECK OUT
Gas
Oil
Antifreeze
Battery
windshield wash
Tits Pressure
MISCELLANEOUS
CHALK
LEVEL 'TRIPOD AND ROD
noWLS
PITCHER PUMP
SURVEYOR'S TAPE
100 FIBERGLASS TAPE '.-'ELL TAPE
300 NYLON ROPE
NYLON STRING
SURVEYING FLAGS
FILM
WHEEL BARROW
BUNG WRENCH
SOIL AUGER
PICK
SHOVEL
CATALYTIC HEATER
PROPANE GAS
BANNER TAPE
SURVEYING METER STICK
CHAINING PINS t RING
TABLES
WEATHER RADIO
BINOCULARS
MEGAPHONE
No .
X
"
X
X
X
X
MISCELLAHEOUS fCont.)
HEARING PROTECTION
LIFE VESTS
V'ALKIE-TALKIE
CONDUCTIVITY METER
!-H METEP.
CAMERA
WATER-LEVEL INDICATOR
SPLIT SPOON SAMPLERS
FVC HAND F'.'MP
RESISTIVITY METER
WELL POINT SAMPLERI'.OBAIR FUMF SYSTEM
THERMOMETER
ILASTERFLEX PUMP i FILTER APPARATUS
3HIPPIFG EQUIPHEFT
':C?LEF5
TAINT CANS WITH LIDS, 1 CLIPS EACH
"EP.MICVLITE
D'JST MASK
3HIPFIIIG LABELS
DOT LABELS: "DANGER"
"UP"
"INSIDE CONTAINER COMPLIES ..."
"HAZARD GROUP"
STRAPPING TAPE
BOTTLE LABELS
BAGGIES
CUSTODY SEALS
CHAIN-or-CUSTODY FORMS
FEDERAL EXPRESS FORMS
CLEAP. PACKING TAPE
No.
X
X
X
X
XV"
X
X
-X
X
>wri
5329094 : 1
and en-'i rcnment , i^.c.
r i; o i e c t ____Con r a i 1
Da t«
TDD/Pan tl/A
Job Ho. ZF3000
,\ d d r • <; s Elk hart, Indiana
"pacific Locaticn
T •/ p * of Wo i- k Soil gas -:cil bonn-a-: •«!! ir.;-?Z 1; ti?n ._pionitoring well sampling ,
'- lug t ests, ecol ooica 1 sampl in a , drainage net "•? i'1; 5 ?r*cl in 7 -jcrgen aucig L' sampling .
"AFETT
ri~otec11'•« Clothing/Equipment
Ch»mica1 Haza rds
Radiation Hazards
rhviical HaKards
Pioceduras
Hc?pital/Clinic Clhhart Genet a 1 Telechone 219) 294-2621
Hospital Address ' 00 East Bl"d.. ElV.har1-. . I"
Special Equipment _____________________________
Checklist
1. Emergency information reviewed?2 . Route to nearast hospital driven?
and madt fsnuliai- to all taam members? ___and its lo^sticn V.novn to all team members?
3. Site safety plan readily a"ailable and its location ^n-vn to ell team members?
Heating shall b« attended by all cersonnel «ho "ill b« •-'orl:in':i "ithin the exclusion area. Daily informalupdate meetings will be held when site tasks and/or conditions change.
Expand on back of shs»t if necessary)
Name Printed Signature
Meeting Conducted by:Print : Signature
'Site Safety Coordinator) ?Team Leader)
0094:1
533
TCCLCGV ,-."D E r T V I P . O M t l E V T . ~-'."~-. - ' IHICAGO
?!'-3ITE 3AFETV LCC-
• l a m e : ccn va 11Date :
Equipment'Circle All Used)
OVA
HHu
rhotovac Tip
ID»B a c k g r o u n d
R*adinasOn-Sit«Rtadings
ExplosimeteiCombo Mat* r
Rad-Hini
Monitor J
HCH Di-a*o«rM^nitox
Other:
Attendees At Ctt-:
Pi-ot«ctiv« Clothing Worn:
Comments on Monitoring or Protective Clothing:
team LeaderHam*
site Safety officerName
3ignature/D«te
Signature/Date
Please submit original to Lauja E • • i ns . ?nd t :•=?'/ to the project tile.
3094:1
Vehicle Safety ChecklistEcology & Environment, Inc.
Chicago O f f i c e
Date: Tl»e: Odometer:
Vehicle Hodel: Color: License Plate No.
INTERIOR:__ All Safety Belts-Proper Locking__ Parking Brake
START ENGINE:__ Oil Pressure__ Instrument Panel
(Varnlng Lights or Buzzers)__ Horn__ Vindshield Viper & Vasher__ Heater/Defroster__ Mirrors__ Steering (Loose)__ Interior Lights__ Eaergency fUshers__ Starts Properly
FRONT:__ Headlights (Din/Bright)
Turn Signals__ Eaergency Flashers
REAR:__ Tall Lights__ Brake Lights__ Back up Lights__ Turn Signals__ Emergency Flashers
MECHANICAL OPERATION:___ Engine (ilsses, knocks, etc.)___ Check Oil___ Vater/Anti-freeze___ Viper Fluid___ Brake Fluid
OUTSIDE:___ Tires (properly inflated)___ Gas Tank Cap
EMERGENCY EQUIPMENT:__ Fire Extinguisher___ First Aid Kit__ Flags, Flares,___ Spare tire (properly inflated)___ Tire Changing Kit
(jack, tools, etc.)
REMARKS:
TEAM KBKBB/ORUXQRs
SITE KAME/ADQUSStPAH/JOB HWOU . *
(print signature
•STURM OF VEHICLE TO DUTT STATION
Vehicle Cleanliness:Remarks:
Corrections Necessary:
TEAM KEKBO/OFBIATOR:(print name) signature
Date:
9/88
Tii Odoaeter:
!11 ecology and enviix>ninenty inc*
Tttto: SOP-HEALTH AND SAFETY ON DRILLING RIG OPERATIONS
Category: H & S, Training 2.7RwtMd: JANUARY 1990
Approved: H. Van Cleave
STANDARD OPERATING PROCEDURESFOR
HEALTH AND SAFETY ONDRILLING RIG OPERATIONS
REVISED: JANUARY 1990
Prepared by
Ecology and Environment, Inc.368 Pleasantviev Drive
Lancaster, Nev York 14086
«mnmm«m
cnp_np*iTH AMn SAFPTT ON PRILLING RTC .OPERATIONS
Category:g TPATMTMR 7.7 Revised: JANUARY 1990
CONTENTS
Section Paste
1 INTRODUCTION . . ..................... 1
2 OPERATION OF DRILL RIG BY E & E PERSONNEL ........ 1
2.1 RESPONSIBILITIES AND AUTHORITY OF SITESAFETY OFFICER ................... 1
2.2 RESPONSIBILITIES AND AUTHORITY OF E & E DRILLER ... 12.3 RESPONSIBILITIES AND AUTHORITY OF OTHER
E & E PERSONNEL ................... 3
3 TRAINING REQUIREMENTS FOR SITE PERSONNEL ......... 3
3.1 E & E SITE SAFETY OFFICER .............. 33.2 E & E DRILLER AND'HELPER .............. 43.3 OTHER E & E DRILLING PERSONNEL ........... 43.4 SUBCONTRACT DRILLER AND OTHER SUBCONTRACT DRILLING
PERSONNEL ...................... 4
4 SUPERVISION OF SUBCONTRACT DRILLERS ........... 5
4.1 RESPONSIBILITIES AND AUTHORITY OP SITESAFETY OFFICER ......... . . . ....... 5
4.2 RESPONSIBILITIES AND AUTHORITY OF OTHERE & E PERSONNEL ................... 7
5 GENERAL DRILLING SITE SAFETY CHECKLISTS ......... 8
5.1 SAFETY CHECKLISTS FOR SPECIFIC DRILLING ACTIVITIES . 85.1.1 General Drilling Sit* Safety Checklist .... 85.1.2 Roury and Cora Drilling ........... 95.1.3 Cathead Usage ................ 105.1.4 Continuous-Flight or Hollov-Staa Augers ... 125.1.5 Use of Vire Line Hoists, Vire Rope, and
Hoisting Equipment .............. 13
6 REFERENCES ........................ 16
iii
1 7Wi: fiflP.BEAt.Tli AMD SAFETY ON DRILLING RTC OPERATIONS
C*l*g0'y: H L fiT TBATMTMR 7.7 "*"*•* JANUARY 1990
1 INTRODUCTION
This document is meant to be used in conjunction with E & E SOPsfor field operations and hazardous waste site operations, andincorporates by reference all the safety precautions required therein.It specifically addresses the functions and responsibilities ofpersonnel working on or around drilling operations.
E & E personnel are frequently required to work in the field withdrill rigs, taking soil and rock samples, installing piezometers, andmonitoring veils. Two general situations discussed separately are thesupervision of Subcontract Drillers by E & E, and the direct operationof E & E's own drill rig by our personnel.
2 OPERATION OF DRILLING EQUIPMENT BY E & E
2.1 RESPONSIBILITIES AND AUTHORITY OF SITE SAFETY OFFICER
The duties of the Site Safety Officer (SSO) on drilling sites arethe same as in other types of operations vith the exception of theincreased emphasis on the hazards unique to drilling work. This sectiondetails specific drilling concerns of an SSO.
E & E personnel are restricted from the borehole area during activedrilling. Vhen E & E personnel are doing drilling, they will berestricted from the borehole area by means of a "super exclusion zone"delineated by placing a 4- by 8-foot sheet of plywood over the borehole.
2.2 RESPONSIBILITIES AND AUTHORITY OF B & E DRILLER
At the beginning of each work day, the E & E driller must inspectthe rig to ensure the following components have been properly inspected,maintained, or replaced, or procedures have been performed:
•• , - •o Kilt switches tripped and operation verified;o Chain guards in placeto Belt guards in place;o Baits «et to proper tension (visual);o Loose baits;o Presence of any fluid leaks;o Any damaged hoses, cables* ropes* chains;o Control panel is clean;o Control lever functions labeled;o Pressure relief valves function;o Cathead free of rust and grease;o Cathead grooves less than 1/8 inch in depth;o All tools in proper working order;o Rig leveled and stabilized;o Check for veld cracks in mast; ando Safety hooks operational.
ilntT nnri nrnnmmrm
i ™*: SOP.HRALTH AND SAFETY ON DRILLING RIG OPERATIONS
C*I*g0'y: H & S. TRAINING 2.7 *•**••* JANUARY 1990
The Driller has authority to direct personnel within the area whiledrilling operations are in progress. Access to the hazardous areaaround the auger and borehole is restricted by the "super exclusionzone" delineated by the 4- by 6-foot sheet of plyvood centered over theborehole before drilling. A large hole cut in the plyvood allowspenetration of the augers. No personnel are allowed in this zone pad atany time while drilling is actively underway.
Housekeeping around the rig is the responsibility of the Driller,but all teaa aeabers must participate in this effort as vail.
2.3 RESPONSIBILITY AND AUTHORITY OF OTHER E & E PERSONNEL
E & E personnel working at a drilling site aust act as support totha Drilling Teaa by providing any necessary support functions; however,it is important that personnel are careful not to interfere with thedrilling process. Personnel arc restricted froa approaching tha "superexclusion zone" while drilling is underway. If an E & E crev memberrecognizes an unsafe condition in the work area or on tha rig, he shouldbring it to the attention of tha SSO and Teaa Leader, if it isnot resolved in a timely manner. If conditions ara still deeaed to behazardous, tea* members have tha option to contact their Regional SafatyCoordinator (RSC) or Corporate Health and Safaty in Buffalo.
It is the responsibility of all E & E personnel to carry theirissued nondisposable gear, including hard hat, face shield, respirator,steel-toed boots, eyepiece inserts, safety glasses, and appropriateouterwear for tha expected climate.
All personnel should be aware of emergency facilities, egressroutes, and special medical conditions of their teaa members. As withall E & E field work, the buddy system is to be enforced.
3 TRAINING REQUIREMENTS FOR SITE PERSONNEL
3.1 E fc E SITE SAFETY OFFICER
In addition to Basic Baalth and Safaty Training and other OSHAeandated training, first aid, CPR, and necessary training in fieldaonitoring of personnel, an SSO should have previously vorked as a tea*•caber on field drilling projects in order to have a working knowledgeof the drill rig and its inherently hazardous nature. Vhcre monitoringinstrumentation is to be used, the SSO mist be properly trained prior tofield work. The SSO must have an understanding of the hazards of heatand cold stress, their associated symptoms, and proper workmodifications to protect field staff froa potential injury.
recycieo papar
I ™*: snP.HMi.TH AMD SAFETY ON DRILLING RIG OPERATIONS
<*•"* u ic f TRATNTMf: 7.7 "***•* JANUARY 1990
4 SUPERVISION OF SUBCONTRACT DRILLERS
4.1 RESPONSIBILITIES AND AUTHORITY OF SITE SAFETY OFFICER
The responsibilities of the SSO at a drilling site vheresubcontracted drillers are used include the following: rig inspections,personnel monitoring, and personnel protection.
A rig inspection starts vith, but is not United to, verifying eachItem on the following checklist:
o The aast aust be located at least 25 feet from any overhead orunderground utility lines.
o The location and operation of operational and unencumbered killswitches aust be reiterated to all site personnel.
o Outriggers* stabilizers, or jacks are in place, and the rig islevel.
o A geophysical survey (electromagnetic or ground-penetratingradar) or a reliable site history must be obtained to verifyabsence of buried obstacles, tanks, or drums.
o A first aid kit and filled eyewash aust be readily available.
o A fire extinguisher should be charged to the proper pressure andstaged at rear of rig during drilling.
o The condition of ropes, chains, and cables aust be checked.
o A lifeline or safety belt must be available if mast climbing isnecessary.
o The Site Safety Plan (SSP) must be posted vith emergency phonelist and map of hospital route.
o A "super exclusion rone" must be established around theborehole, using a 4- by 8-foot sheet of plywood* This definedarea will be entered during active drilling only by the Driller,except in emergency situation**
If any of these itema need replacement or repair, the SSO must makenecessary arrangements and later verify that repair or replacement issufficient before actual drilling begins. Working together, the SSO andthe driller should verify that the rig has been checked against theOperator's checklist.
and Environment
$ 1™*: SOP-HEALTH AND SAFETT ON DRILLING RIG OPERATIONS !
C gofy: H i S . TRAINING 2.7 *•*•** JANUARY 1990
o Location and operation of kill switches, fire extinguisher, andfirst aid kit;
o Heat and cold stress hazards;o "Super exclusion zone" around borehole; ando Warnings to Subcontractors about hazards of climbing th« mast
without safety belt and other equipment.
Because heat stress Is a constant threat during war* weather, theSSO is responsible for determining whether conditions are unsuitable forwork. Vhere workers cannot work vith the assistance of vorkmodifications, cooling vests, and other cooling means, the SSO naydecide that vork should not continue. The need for worker monitoringthrough blood pressure and oral temperature checks will be determined bythe SSO with assistance from the RSC and Buffalo Health and Safetystaff, if necessary.
The SSO will be responsible for shutdown of the drilling operationif electrical storms are in tht site area.
No refueling operations will be performed until rig engines areshut down. Motor fuels should be stored and dispensed fromspring-loaded, OSHA/FM-approv4d gas cans constructed of aetal orpolyethylene.
Tht SSO should ensure and document that no boreholes art left openor unfilled after drilling equipment is moved. In instances where ahole must be left open and unattended, suitable barricades, or theequivalent, will be staged around the hole to prevent personnel andequipment from falling in.
4.2 RESPONSIBILITIES AND AUTHORITY OP OTHER E i E PERSONNEL
All E & E personnel on site arc required to follow the tens of theSSP and the direction of the SSO. Because the SSO cannot be in allplaces at all times, the crew should observe the subcontractors andcondition of. their equipment at all times, and report immediately to theTeam Leader and SSO any safety-related issues that are unresolved.Included are such details as dressout, site functions* anddecontamination. It Is important that the SSO be involved so thatproper log entries can be made.
E t E, as policy* does not provide safety equipment or monitoringinstrumentation to subcontractors. Some projects, however, may be setup so that E & E personnel and subcontractors share the same expendablesupplies.
E & E personnel are forbidden from approaching augers duringdrilling. Activities at the borehole, such as sampling, require thatequipment be stopped.
ecology and environ mem
TKto: snp.HBAI.TH AMD SAFETY OK PRILLTHC RTC OPCTATICTfS
Category:H L S. TftATMTMH V7 JANUARY 1990
o Electrical storms vithin hearing range of tht job site villsignal work termination until the SSO and Team Leader notifypersonnel otherwise.
o The local utilities should be contacted prior to drilling sothat their lines can be located and flagged. Situations ofclose proxieity nay involve isolating utility lines (i.e.,shutdown and inerting of gas lines).
o Vhen buried drums or other material arc suspected* a full surveyof the drilling zone is required using appropriateinstrumentation prior to ground breaking*
o Only trained, experienced staff who have studied proper drillingmethods and served as a Helper under an experienced Driller villoperate the cathead.
o Only properly licensed staff vill drive tht drill rig. A dailysafety check of the vehicle, following E & E protocol, vill becarried out by the driver.
o Climbing on the vertical mast is not permitted by E & E staff.Because the boon is not equipped with a ladder, it should balowered for repairs.
5.1.2 Rotary and Core Prilling
The following precautionary measures should be taken during rotaryand core drillings
o Rotary drilling tools should be safety checked prior todrillings
- Rod* and bit should ba open and clear.
- Vater swivels and hoisting plugs should be lubricated andchecked for "frozen" bearings before use.
- Drill rod .chuck jaws should be checked periodically andreplaced whan necessary.
- The capacities of hoists and sheaves should be checkedagainst the anticipated weight of the drill rod string, inaddition to other expected hoisting loads.
- All hoses to and from the pump should be checked for properlyinstalled couplings; couplings should be secured with lockingdevices on "quick connect" fittings or wire on"Chicago-Style" couplings.
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SOP-HEALTH AND SAFETY ON DRILLING RIG OPERATIONSCatoooiv: H & S. TRAINING ?_.7_ JANUARY 1990
Check the cathead periodically, vhen the engine is not running,for rope vear grooves. If a rope groove forms to a depthgreater than 1/8 inch (3 am), the cathead should be replaced.
Always use a clean, dry, sound rope. A vet or oily rope nay"grab" the cathead and cause drill tools or other items to berapidly hoisted to the top of the mast.
Should the rope "grab" the cathead or otherwise become tangledin the drum, release the rope and sound an appropriate alarm forall personnel, including the Operator, to rapidly back away andstay clear. If the rope "grabs11 the cathead and tools archoisted to the sheaves at the top of the mast, the rope willoften break, releasing the tools. If the rope does not break,stay clear of the drill rig until the Operator can turn off thedrill rig engine and initiate other appropriate actions torelease the tools. The Operator should carefully vatch thesuspended tools, quickly backing avay after turning off theengine.
Chemicals can cause deterioration of the rope that may not bevisibly detectable, thus the rope should always be protectedfrom any chemical contact.
Never vrap the rope from the cathead (or any other rope, wirerope, or cable on the drill rig) around a hand, wrist, arm,foot* ankle, leg, or any other part of the body.
o Always maintain a minimum of 18 inches of clearance between theoperating hand and the cathead drum when driving samplers,casing, or other tools with the cathead and rope method. Beaware that the rope advances toward the cathead with each hammerblow as the sampler or other drilling tool advances into theground.
o Do not use more rope wraps than are required to hoist a load.
o Do not leave a cathead unattended with the rope wrapped on thedrum*
o Position all other hoist lines to prevent contact with theoperating cathead rope*
o Vhen using the cathead and rope for driving or back-driving,make sure that all threaded connections are tight, while stayingas far avay as possible from the hammer impact point.
o The cathead Operator oust be able to operate the catheadstanding on a level surface with sound, firm-footing conditions,without distraction or disturbance*
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SOP-HBALTB AND SAFETY OH DRILLIMC RIG OPERATIONS
C>tag0qr: S. TRAINING 2.7 JANUARY 1990
o Vhan rotating augers, stay clear of the rotating auger and otherrotating components of the drill rig. Never reach behind oraround a rotating auger.
o Use a long-handled shovel to eove auger cuttings avay from theauger. Never use your hands or feet to aove cuttings avay fromthe auger.
o Do not use hands to clean rotating augers vhen removing augersfrom tha ground.
o The use of vire line hoists, vire rope, and hoisting hardwareshould conform to stipulations developed by tha American Ironand Steel Institute Wire Rope Users Manual.
5.1.5 Use of Vire Line Hoists, Vire Rope, and Hoisting Equipment
o All vira ropes and fittings should be visually inspected duringuse and thoroughly inspected at leaat onca a weak for abrasion,broken vires, vear, reduction in ropa diameter, reduction invira diameter, fatigue, corrosion, damage fro* heat, improperweaving, jamming, crushing, bird caging, kinking, coreprotrusion, and damage to lifting hardware. All relatedequipment must conform to standards as established by thaAmerican Iron and Steal Institute Vire Rope Users Manual. Viraropes should be replaced vhen inspection indicates excaaaivedamage according to tha Vira Ropa Users Manual. All vira ropaawhich have not bean usad for a period of 1 month or more shouldbe thoroughly inspected before being returned to service.
o End fittings and connections consist of splicad eyes and variousmanufactured devices. All manufactured and fittings andconnections should be installed according to tha manufacturer'sInstructions and loaded according to tha Manufacturer'sspecification*.
o If a ball-bearing type hoisting svival is usad to hoist drillrods, svival bearings should be inspected and lubricated dailyto ensure that tha svival fraaly rotatas under load*
o If a rod slipping device is usad to hoist drill rods, do notdrill through or rotate drill rods through tha slipping device,and do not hoist tha drill rod column higher than one-half thamast,height above tha top of tha mast (derrick). Do not hoist arod column with loose tool joints and do not make up, tighten,or loosen tool joints vhile tha rod column is being supported bya rod slipping device. If drill rods should slip back into thaborehole, do not attempt to brake tha fall of tha rods vithhands or by tensioning the slipping device.
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Tltt>: SOP-HEALTH AND SAFETY ON DRILLING RIG OPERATIONS
H & S. TRAINING 2.7 JANUARY 1990
o Never carry out hoisting operations when veather conditions aresuch that hazards to personnel, the public, or property arecreated.
o Never leave a load suspended in the air vhen the hoist isunattended.
o Never hoist a load over the head* body, or feet of personnel.
o Never use a hoist line to "ride" up the vast (derrick) of adrill rig.
o Replacement of vire ropes should conform to the drill rigmanufacturer's specifications.
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10-18-89
DRILL RIG SAFETT
* Hard hats nust be worn.
* Buddy system.
* All team members oust knov th* procedure to shut the rig off and thelocation of tht "kill* svitch. (daily)
* Vhen moving a rig off the road* pay atttntion to obstacles in rout*of travel. Walk the intended routa first.
* Have someone guidt tht rig driver vh*n clearance is at a minimum orvhen hazards art in close proximity.
* Set rig brakes and block th* vhe«ls vhen rig is set up at rht desireddrilling location, (tvo hydraulic lifts on the back)
* Th« nast must be lovered vhen tha rig is Boved. (all rop«s, etc.should be secured)
* Alvays consider overhead viras to b« liva, vatch for sagging linaaand do not operate rig vithin 23 feet of overhead lines, (metalvires)
* Hake sure the site* platforms, and valkvays are free of obstructions.
* Make sure proper housekeeping is practiced around and on the rig atall timea. Tools should be stored in a manner that permitsconvenient access and provides Cor adequate safety.
* Store gasoline in approved containers that have a spark arrestor andkeep the* clear of the drilling vork area.
* Check ritf equipment prior to starting vork. Repair or replace faultyand vorn items, (hydraulics* etc.)
* Handle augers vitk care. Use proper lifting techniques vhen pickingup samplers and augers. Use a tool hoist if possible aad stay clearof rotating augers. Keep cables and ropes secured vhen not in use*
* B I B drillers must level and atabilize the drill rig prior toraising the mast.
* Vatch for slippery ground vhen working in the area, of the rig.
* All unattended boreholes must be properly covered.
* Do not drill during an electrical storm. Even rain may interferevith respiratory equipment protection.
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