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Providing micro and nano fabrication facilities for Australian researchers
Photolithography
UNSW ANFF NSW-Node
Providing micro and nano fabrication facilities for Australian researchers
• What is lithography – optical
• Considerations and limitations
• Future directions and alternatives
OVERVIEW
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
LITHO GRAPHY
λίθος + γράφειν
'stone' + ‘to write’
WHAT IS LITHOGRAPHY?
PATTERN TRANSFER
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
• For industry (e.g. chip manufacturing), photolithography has been
advanced for high volume, low cost fabrication:
• For research, standard photolithography is used for repeated, microscale
structures with sizes from 1-2 to 1000’s of microns with a standard UV lamp.
• For research, we go to EBL or laser patterning for smaller features which require
iterative development or rapid prototyping...
PHOTOLITHOGRAPHY – ROLE IN INDUSTRY
• 10 µm – 1971
• 3 µm – 1975
• 1.5 µm – 1982
• 1 µm – 1985
• 800 nm – 1989
• 600 nm – 1994
• 350 nm – 1995
• 250 nm – 1998
• 180 nm – 1999
• 130 nm– 2000
• 90 nm – 2002
• 65 nm – 2006
• 45 nm – 2008 (DOUBLE EXPOSURE)
• 32 nm – 2010 (Double + IL)
• 22 nm – 2011 (+ Introduction of 3D tri-gate)
• 16 nm – 2013 (Transition to Nanoelectronics)?
• 11 nm – 2015 (Nanoelectronics)?
INDUSTRY HALF-PITCH SIZES
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
WHAT IS PHOTOLITHOGRAPHY?
PATTERN TRANSFER WITH LIGHT
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
substrate
photomask
photoresist
Example with POSITIVE photoresist
EXAMPLE
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
UV light
substrate
photomask
photoresist
Example with POSITIVE photoresist
EXAMPLE
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
substrate
photoresist
developer
Example with POSITIVE photoresist
EXAMPLE
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
substrate
photoresist
ADDITIVE PROCESS
Metal deposition
Lift-off solvent
Example with POSITIVE photoresist
EXAMPLE
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
substrate
photoresist
SUBTRACTIVE PROCESS
etch process
Example with POSITIVE photoresist
EXAMPLE
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
PHOTOLITHOGRAPHY – TYPICAL PROCESS
FLOW AND PARAMETERS
Process
Flow
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
PHOTOLITHOGRAPHY – PRACTICAL
CONSIDERATIONS
EXPOSURE
• Different photoresists have different sensitivities to different wavelengths
of radiation
• Dose per unit volume is usually constant, but resist thickness and
differences in the exposure process can alter the dose required for good
pattern transfer. E.g. a reflective layer beneath the resist (metallic thin
film), interference effects from mask geometry in thicker films
Desired pattern
(i.e. positive resist/dark part of mask)
Over-exposed pattern Under-exposed pattern
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
PHOTOLITHOGRAPHY – PRACTICAL
CONSIDERATIONS
EXPOSURE
• Light is scattered and diffracted at the pattern edges
• Overexposed – too much resist is exposed
• Underexposed – too little resist is exposed
(positive resist)
• Uniformity across the wafer is affected by substrate topography (i.e. Bad
substrate to begin with, or underlying high aspect ratio features
Desired pattern Over-exposed pattern Under-exposed pattern
(i.e. positive resist/dark part of mask)
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
PHOTOLITHOGRAPHY – PRACTICAL
CONSIDERATIONS
Sloping walls
Deposited film is
mostly ripped off
Undercut walls
Pattern is deposited
correctly
Vertical walls
Some sidewall coating
causes thin rips and
tails (may short out)
• Resist pattern profile is important
• Desired shape depends on the type of process the mask is for
• In this example: lift-off of a deposited metallic thin film (i.e. metal gates)
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
PHOTOLITHOGRAPHY – PRACTICAL
CONSIDERATIONS
Too thick
Not enough clearance
below the mask opening
Correct thickness
Pattern is deposited
correctly
• Thickness of the resist w.r.t. Patterns (aspect ratio) is also important
• Too thick and there may not be enough clearance below the mask opening
• Too thin (similar to metal layer thickness) and the features merge with the mask
Too thin
Features merge with
metal ontop of mask
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
REGISTRATION
Features on wafer
Features on mask
Mask over wafer
Correct alignment
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
PHOTOLITHOGRAPHY CONSIDERATIONS
AND LIMITATIONS
• What kind of mask?
What projection method?
Contact or proximity masks,
projection/stepper
• Masks must be designed
and manufactured
(e.g. chrome on quartz)
• Sample or substrate must be
compatible with all the steps in
the process flow (e.g. application
of resists, various solvents and
developers, temperature processes, metals)
• There may be many steps required (e.g. modern CMOS fabrication requires
around 50 photolithography steps)
CONTACT PROXIMITY
PROJECTION
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
FACILITIES AVAILABLE
• Cleanroom (no dust or organic/inorganic contaminants,
controlled humidity and temperature)
• Fume cupboard (spinner, wet chemistry bench)
• Ovens/hotplates
• Mask aligner (alignment and UV exposure)
• Suss MA6: up to 6” wafers, 1µm resolution
and BSA
• Quintel Q6000: up to 4” wafers, 2µm
resolution
• Plasma asher (for descum)
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
Where can this be done? • ACT Node
• WA Node
• QLD Node
• NSW Node: UNSW
• SA Node
• OptoFab Node
• VIC Node
see www.anff.org.au
FACILITIES AVAILABLE
Providing micro and nano fabrication facilities for Australian researchers Providing micro and nano fabrication facilities for Australian researchers
FUTURE DIRECTIONS AND
ALTERNATIVES
• Standard photolithography uses UV light from mercury gas-discharge lamps that produce a
broad spectrum which is filtered to select a single spectral line, e.g. 436 nm or 365 nm
• Advanced lithography uses "deep ultraviolet“ (DUV)
produced by excimer lasers e.g. krypton fluoride
produces a 248-nm spectral line, and argon fluoride,
a 193-nm line.
• Further advancements produce feature sizes below
50 nm using 193 nm DUV and liquid immersion techniques
- use a liquid with refractive index greater than 1
• One major (but complementary) alternative to photolithography:
direct write lithography
– Expose each feature in the pattern by writing it with a focussed beam rather than by a
flood exposure through a patterned mask